{ "problem_id": "Exam-07-T6", "header": "The Phases and Properties of Water and the Evolution of Temperature-Scale Definitions\nWater is the source of life, and its unique physicochemical properties play a crucial role in nature. The phase diagram below describes the phase equilibria of water at different temperatures and pressures. ", "header_images": [ { "file": "Exam-07-T6-header-1.png", "description": "Schematic physicochemical phase diagram drawn with black lines on a white background. The origin of the rectangular coordinate system is labeled “O”; the vertical axis points upward and is labeled “p,” and the horizontal axis points rightward and is labeled “T/K.” The value “273.16” appears toward the left of the horizontal axis, with a vertical dashed line rising from it to the triple point, which is also labeled “O.” Four lines meet at triple point O: a solid solid-gas coexistence curve bending down and left to point B; a slightly curved solid-liquid coexistence line with negative slope extending up and left to point C; dashed line OD extending leftward; and a solid liquid-gas coexistence curve bending up and right to point A, the critical point. Point P lies on solid curve OA. A double-slash break symbol “//” appears midway along this curve, with a corresponding “//” break on the right side of the horizontal axis. A vertical dashed line fq passes through point P on curve OA, with f above and q below. Above and to the right of point A is a right-angled boundary extending rightward and upward; the top of its vertical segment is labeled “E,” and the right end of its horizontal segment is labeled “F.” The regions are labeled as follows: “ice” to the left of line OC, “water” between OC and OA, “water vapor” below OA and OB, and “supercritical water,” written vertically, inside the upper-right right-angled region bounded by E and F." } ], "subquestions": [ { "sub_id": "Exam-07-T6-1", "tags": [ "3.1" ], "text_open": "6.1.2 State the physical meaning of curve OD.", "text_images": [], "full_mark": 2, "rubric": [ "Line OD is the metastable equilibrium line between supercooled liquid water and water vapor, or equivalently the vapor-pressure curve of supercooled water (2 points)." ], "rubric_images": [] } ] }