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6ac289bd61b1ee8b723e6720a993141044706cba | on 17 june 2017, the stars re-signed byström | on 17 june 2017, the stars re-signed byström to a one-year, two-way extension worth $650,000. on 10 november 2017 byström was traded to the florida panthers in exchange for reece scarlett. he was immediately assigned to panthers' ahl affiliate, the springfield thunderbirds. on 31 may 2018, he signed a one-year contract extension with the panthers. | wikipedia |
ed973c2d532c7d01ddf2c7abe9e4507ded3a75b8 | at the completion of the 2014–15 season with | at the completion of the 2014–15 season with färjestad bk, byström embarked on his north american career in reporting to the stars' american hockey league (ahl) affiliate in texas on 12 march 2015. | wikipedia |
030b46e197468e89827fcfd7216e1d78382bf190 | during the 2012 nhl entry draft, byström was | during the 2012 nhl entry draft, byström was drafted in the second round, 43rd overall by the dallas stars. on 16 july 2012, he signed a three-year entry-level contract with the stars. however, he was then returned on loan to modo. on 29 april 2013, byström was reassigned from modo to league rivals färjestad bk for two seasons on loan. | wikipedia |
5349ab564daa494e56e5b693142771078cf80ab7 | ludwig byström (born 20 july 1994) is a | ludwig byström (born 20 july 1994) is a swedish professional ice hockey defenceman who is currently an unrestricted free agent. he most recently played for nürnberg ice tigers of the deutsche eishockey liga (del). he was drafted 43rd overall by the dallas stars in the 2012 nhl entry draft. | wikipedia |
ee535995072074f28cb77121699617865ee7967d | the 1941 all-ireland senior hurling championship was the | the 1941 all-ireland senior hurling championship was the 55th staging of the all-ireland senior hurling championship, the gaelic athletic association's premier inter-county hurling tournament. the championship ended on 28 september 1941. limerick were the defending champions, however, they were defeated by cork in the provincial series. the championship was won by cork who secured the title following a 5-11 to 0-6 defeat of dublin in the all-ireland final. this was their 12th all-ireland title, their first in ten championship seasons. | wikipedia |
ef210c96416ba6a58d89076c7e9452023c321735 | six teams contested the leinster championship while five | six teams contested the leinster championship while five teams contested the munster championship. galway, who faced no competition in their own province, entered the championship at the all-ireland semi-final stage. no team from ulster participated in the senior championship. | wikipedia |
9fddace7d6ff8923ebbe220440e1bad4b05d487d | it was a similar story in the leinster | it was a similar story in the leinster championship as foot-and-mouth disease ravaged southern parts of the province. kilkenny were drawn to play laois in one of the earlier stages of the provincial competition, however, the match could not take place and kilkenny were given a bye into the leinster final. the department of agriculture subsequently brought out an order that kilkenny could not play in the leinster final until the county was three weeks clear of the disease. the result was that dublin were nominated to represent leinster in the all-ireland series. a delayed leinster final was played after the completion of the all-ireland final with dublin defeating kilkenny. | wikipedia |
a9ed8028d472262cdcbc82f3c14f486e0bbad91e | in the munster championship limerick defeated waterford in | in the munster championship limerick defeated waterford in the semi-final of the competition and qualified for the munster final. cork were drawn to meet tipperary in the second semi-final, however, this game was cancelled by the munster council at the behest of the department of agriculture. as a result of this it was decided that cork would play limerick and the winners would represent munster in the all-ireland series. the delayed cork-tipperary game took place after the all-ireland series, however, since cork had already beaten limerick this was now deemed to be the munster decider. tipperary won that game. | wikipedia |
e207a09add8b18cd77f304b753a21eb90e8f9f00 | there was major disruption to the format of | there was major disruption to the format of the 1941 championship due to a serious outbreak of foot-and-mouth disease in many parts of munster and south leinster. the championship was run on a knockout provincial basis as usual, however, there was a certain amount of tweaking required to cope with the situation. | wikipedia |
d6736124faedae7f78be64e77d159bdad8cba847 | the championship was won by cork who secured | the championship was won by cork who secured the title following a 5-11 to 0-6 defeat of dublin in the all-ireland final. this was their 12th all-ireland title, their first in ten championship seasons. | wikipedia |
fa2829c9fd5b6d236ea4a270c824acc348b6aacc | the 1941 all-ireland senior hurling championship was the | the 1941 all-ireland senior hurling championship was the 55th staging of the all-ireland senior hurling championship, the gaelic athletic association 's premier inter-county hurling tournament. the championship ended on 28 september 1941. | wikipedia |
ee0cbf2afb36e708a7c8b16386c2ece65e77369d | the 1917 vfl grand final was an australian | the 1917 vfl grand final was an australian rules football game contested between the collingwood football club and fitzroy football club, held at the melbourne cricket ground in melbourne on 22 september 1917. it was the 20th annual grand final of the victorian football league, staged to determine the premiers for the 1917 vfl season. the match, attended by 28,512 spectators, was won by collingwood by a margin of 35 points, marking that club's fourth premiership victory. war had restricted the competition to just six clubs during the home and away season and fitzroy, despite winning just six of their 15 games, qualified for the final by finishing fourth. fitzroy made it into the grand final by defeating minor premiers collingwood by a goal a week earlier but collingwood this time won comfortably, dominating from the opening quarter. alec mutch of collingwood was playing his 100th vfl game. | wikipedia |
b2724d691c0e39c942be7f610b4af85005f225b4 | the 1917 vfl grand final was an australian | the 1917 vfl grand final was an australian rules football game contested between the collingwood football club and fitzroy football club, held at the melbourne cricket ground in melbourne on 22 september 1917. it was the 20th annual grand final of the victorian football league, staged to determine the premiers for the 1917 vfl season. the match, attended by 28,512 spectators, was won by collingwood by a margin of 35 points, marking that club's fourth premiership victory. | wikipedia |
fe85b555024d67a0c347dd1f84141be1b32e715e | 1,4-butynediol is an organic compound that is an | 1,4-butynediol is an organic compound that is an alkyne and a diol. it is a colourless, hygroscopic solid that is soluble in water and polar organic solvents. it is a commercially significant compound in its own right and as a precursor to other products. | wikipedia |
731d876d7750a0ae9aff3a93ad1e41c8e61e0c18 | 1,4-butynediol is a precursor to 1,4-butanediol and 2-butene-1,4-diol | 1,4-butynediol is a precursor to 1,4-butanediol and 2-butene-1,4-diol by hydrogenation. it is also used in the manufacture of certain herbicides, textile additives, corrosion inhibitors, plasticizers, synthetic resins, and polyurethanes. it is the major raw material used in the synthesis of vitamin b. it is also used for brightening, preserving, and inhibiting nickel plating. | wikipedia |
caf1d0d3e2552d27e98a83db0c5d4b45ced6720d | several patented production methods use copper bismuth catalysts | several patented production methods use copper bismuth catalysts coated on an inert material. the normal temperature range for the reaction is 90 °c up to 150 °c, depending on the pressure used for the reaction which can range from 1 to 20 bar. | wikipedia |
fe85b555024d67a0c347dd1f84141be1b32e715e | 1,4-butynediol is an organic compound that is an | 1,4-butynediol is an organic compound that is an alkyne and a diol. it is a colourless, hygroscopic solid that is soluble in water and polar organic solvents. it is a commercially significant compound in its own right and as a precursor to other products. | wikipedia |
0e6b5d70413d0cd6634503b38556fbe98b57ecfa | 1578 kirkwood, provisional designation 1951 at, is a | 1578 kirkwood, provisional designation 1951 at, is a hilda asteroid from the outermost regions of the asteroid belt, approximately 52 kilometers in diameter. it was discovered on 10 january 1951, by astronomers of the indiana asteroid program at goethe link observatory in indiana, united states. the asteroid was named after american astronomer daniel kirkwood. | wikipedia |
46ed34ccad0847a127da7a55c75995cdd65d1a79 | this minor planet was named in memory of | this minor planet was named in memory of american astronomer daniel kirkwood (1814–1895), long-time professor of mathematics at indiana university. he discovered the kirkwood gaps, which are gaps in the distribution of the mean distances of the minor planets in the asteroid belt. kirkwood was the indiana asteroid program 's first numbered discovery. the official naming citation was published by the minor planet center in march 1952 (m.p.c. 738). the lunar crater kirkwood was also named in the astronomer's honor. | wikipedia |
749a4cc5da0893f81f010d1bb39627d94afb4eba | according to the surveys carried out by the | according to the surveys carried out by the japanese akari satellite, the neowise mission of nasa's wide-field infrared survey explorer and the infrared astronomical satellite iras, kirkwood measures between 47.077 and 57.14 kilometers in diameter and its surface has an albedo between 0.044 and 0.063. | wikipedia |
59674b30ed45e621c7b74e8f34882e97c25f3816 | in october 2012, a rotational lightcurve of kirkwood | in october 2012, a rotational lightcurve of kirkwood was obtained from photometric observations at the etscorn campus observatory (719) in new mexico, united states. lightcurve analysis gave a rotation period of 12.518 hours with a brightness variation of 0.05 magnitude (u=2). another lightcurve gave a period of 17.9 hours and an amplitude of 0.22 magnitude (u=2). | wikipedia |
71439479bbec21b935c655e1f4a8cd3958ff3c54 | the asteroid was first observed as 1944 df | the asteroid was first observed as 1944 df at turku observatory in february 1944. the body's observation arc begins with its observation as 1949 tf at heidelberg observatory in october 1949, fifteen months prior to its official discovery observation at goethe link. | wikipedia |
8089e1b05fad5fce428bee9f464fbb9cfa0c12b2 | it orbits the sun at a distance of | it orbits the sun at a distance of 3.0–4.9 au once every 7 years and 9 months (2,839 days). its orbit has an eccentricity of 0.24 and an inclination of 1 ° with respect to the ecliptic. | wikipedia |
01eae02e6732389f5ac582b595f3f4bed8cf6fd5 | kirkwood belongs to the orbital hilda group, which | kirkwood belongs to the orbital hilda group, which is located outermost part of the main belt. asteroids in this dynamical group have semi-major axis between 3.7 and 4.2 au and stay in a 3:2 resonance with the gas giant jupiter. kirkwood, however, is a background asteroid and not a member of the (collisional) hilda family (101). | wikipedia |
0e6b5d70413d0cd6634503b38556fbe98b57ecfa | 1578 kirkwood, provisional designation 1951 at, is a | 1578 kirkwood, provisional designation 1951 at, is a hilda asteroid from the outermost regions of the asteroid belt, approximately 52 kilometers in diameter. it was discovered on 10 january 1951, by astronomers of the indiana asteroid program at goethe link observatory in indiana, united states. the asteroid was named after american astronomer daniel kirkwood. | wikipedia |
abe1a18b808529317171fe401dcba4ff0e696af3 | super mutants are a fictional race of posthuman | super mutants are a fictional race of posthuman beings from the post-apocalyptic fallout video game franchise. the super mutants were first introduced in 1997's fallout as the results of human experimentation with a strain of the forced evolutionary virus (fev), a genetically engineered viral mutagen which transforms the subjects into a hulking monstrous humanoid form. within series lore, super mutants tend to be depicted as savage and innately violent beings who, as a result of their transformations, lost a substantial amount of intelligence and often have cannibalistic tendencies. while super mutants tend to form their own factions or societies and are usually hostile to civilized humans, some have chosen to live peacefully alongside humans in settlements across the post-apocalyptic wasteland. among the most recognizable and integral elements of the fallout intellectual property (ip), super mutants have appeared in every media of the franchise, and have been the subject of numerous fan mods of fallout series games. certain individual super mutant characters have been well received by critics for their characterization, although the role the super mutant race have played throughout the history of the franchise have been the source of contention for some commentators. | wikipedia |
f0a680fffba059d2d81e76ed5116571e56007f35 | commenting on adamowicz's developer diary post in 2008, | commenting on adamowicz's developer diary post in 2008, joseph leray from destructoid praised the creative vision and art style for the super mutants of fallout 3 as "delightfully twisted", and said these aesthetic elements were key ingredients "that makes post-apocalyptic stories work". some of the best side quests in fallout 4 according to the escapist 's ron whitaker involve conflicts with super mutants, with one that culminates in the recruitment of strong as a companion character noted to be a highlight by whitaker. some individual super mutant characters have received critical acclaim. for example, the nightkin character lily bowen has been praised for her characterization and has appeared in "top" character lists, including polygon 's "the 70 best video game characters of the decade". in a paper published by the university of leicester, conor appleton scaled an ordinary super mutant up to the size of a behemoth and used dimensional analysis to determine the plausibility and viability of such a creature's existence. after examining the behemoth's physiology using in-universe data and discussing how it may be affected by gravity, appleton concluded that it is unlikely that such a creature would survive in reality. | wikipedia |
8f647e7298890f23ce437384a03e28f7fe62fc96 | on the other hand, the portrayal of super | on the other hand, the portrayal of super mutants following the transition of the series' ownership to bethesda have been a source of contention for some fans. story elements introduced in fallout 3 contradicted lore in the first fallout, developed by series creators interplay entertainment, which established that super mutants were originally created by the master in 2103, while the vault 87 fev experiment took place in 2078. in a report about the fallout fansite, no mutants allowed, luke winkie from kotaku highlighted criticism from community members about the creative and design decisions in video games developed by bethesda game studios: one aspect of contention involved the ubiquity of super mutants as ordinary "mob bad guys" in the early game levels of fallout 3, which departed from the perspective of escalation presented in the original games' stories, gameplay mechanics and setting. the presence of super mutants in fallout 76 also proved to be a controversial retcon with series fandom, as the game established that its iteration of super mutants is native to the region and thus unrelated to the super mutants in previous games. | wikipedia |
5182a21ea51e1cc21ab46d7024560e9dcd6e2e34 | super mutants are a recognizable element of the | super mutants are a recognizable element of the fallout franchise. some characters are particularly popular with players. fawkes from fallout 3 was among the top-voted characters in a rpg character poll organized by justin davis and lucas thomas of ign in 2014. super mutant characters and their physiology are also the subject of popular works derived from fan labor, such as mods, music videos and fan films. they have been featured as part of a range of fallout -themed funko pop toys. | wikipedia |
a2551c1fe604a80774c2e13efbb8e2130f4e9562 | players could recruit super mutant characters as traveling | players could recruit super mutant characters as traveling companions or allies in the sequel to 1997's fallout. noteworthy companion characters throughout the series include marcus in fallout 2, fawkes in fallout 3, lily bowen in fallout: new vegas, and strong in fallout 4. super mutants are available as a playable race in the fallout tabletop roleplaying game released in 2021. super mutants make a brief appearance in the 2024 american post-apocalyptic drama television series fallout. | wikipedia |
64c47e0260f2d3d66b0822feb65c40daef7125e1 | following the death of the master in the | following the death of the master in the canonical ending of the original fallout, the super mutant remnants of his organization are hunted by the brotherhood of steel, who would label them " frankenstein's monsters " as a derogatory term. survivors scatter from their base of operations beneath a cathedral and go their separate ways to find a new purpose: many resort to becoming raiders and resume their violent ways against baseline humanity, while some individuals congregate together in non-violent communities and attempt to live in peace with humans and ghouls. | wikipedia |
137a6c031bda646fb206c5c373e554a30140a8f2 | when the player engages the master near the | when the player engages the master near the end of the game, they can confront the master with a number of different skills and approaches. the player can enter combat with the master and his super mutant allies. the player can also convince the master to abandon his plans by revealing to him that super mutants are sterile, a revelation that causes the master to commit suicide. skipping the confrontation entirely, the player can sneak into his chambers and find a hidden nuclear arsenal that can blow up the cathedral, killing the master and his super mutant associates. the player also has the option of joining the master's campaign, which will lead to a bad ending in which vault 13 is raided by super mutants. | wikipedia |
58fb88097c115bbb8c2b035599fda4001831e9d8 | after a month of simmering, grey crawled out | after a month of simmering, grey crawled out of the vat and installed himself inside a vault. driven insane and severely mutated, he decided that humanity was inept and had to be replaced by a master race. through his experimentations on humans with the f.e.v., the master managed to create a race of virtually immortal monsters that were immune to disease and radiation. deeming super mutants to be the superior race, the master went on a campaign to replace all the humans with the super mutants by infecting them with the virus. to accomplish this, the master created a cult called the children of the cathedral as a front for his campaign, using aliases such as the "holy flame" or "father hope" when dealing with his followers. | wikipedia |
77c6af77f42ec3e929757b5f9765afe476b140d6 | super mutants have appeared in every fallout video | super mutants have appeared in every fallout video game as both hostile antagonists and supporting non-player characters, beginning with 1997's fallout which takes place after a global nuclear war had destroyed most of human civilization a century earlier. information about how the "master of super mutants" raised an army of super mutants is picked up throughout gameplay prior to the player's final confrontation with the character in the cathedral. the master was originally a human named richard moreau who was exiled from vault city as a murder suspect. he changed his surname to grey and migrated to a merchant town called the hub, where he became a physician. grey met a trader named harold in 2102, and they formed a joint expedition to discover the source of the mutant attacks on harold's caravans. this led them to mariposa military base, where the expedition group is overwhelmed by mutant forces. grey is knocked into a vat of the forced evolutionary virus (f.e.v.), which mutated him into a blob-like creature that expanded himself by absorbing other humans. | wikipedia |
6327adc7f1fddc667892017a599127d939dfa473 | obsidian entertainment, the developers of fallout: new vegas, | obsidian entertainment, the developers of fallout: new vegas, initially considered allowing players the opportunity to play as a ghoul or a super mutant for their protagonist in new vegas. the team faced technical limitations as new vegas shared the same engine as fallout 3, and the developers realized that the game engine's equipment system would not work properly for player characters which use non-human character models after bethesda provided advice discouraging the addition of the proposed feature. modiphius founder chris birch said the inclusion of super mutants as a playable race in the officially licensed fallout tabletop roleplaying game, developed by his company, to be part of their design decision to make the game "authentically fallout ". | wikipedia |
8f1223d2bb7dcae41b6ec37e3ab39b92f4525bba | adamowicz noted that his “ junkyard wars ” | adamowicz noted that his “ junkyard wars ” approach to designing the super mutants' armor and weapons inspired a number outlandish designs for homemade weapons, with some of them implemented in the final game. adamowicz incorporated numerous visual gags into the character design for the behemoths; examples given include their wielding of parking meters as if they are police batons and carrying their victims bound by shopping carts on their backs, which they will occasionally consume when they get hungry. | wikipedia |
3ad8114dd425a851a95da15bb0052ad77901c995 | concept artist adam adamowicz was responsible for conceptualizing | concept artist adam adamowicz was responsible for conceptualizing the fallout 3 iteration of the super mutant, in particular the behemoth variant. in a 2008 developmental diary titled "conceptual design", adamowicz said he was inspired by a line of dialogue from the 1974 film blazing saddles about the dim-witted but strong and tough character mongo. adamowicz wanted the game's super mutants to look like "they would step into a tree shredder, for relaxation.". he described their musculature to be straining at the bone structure underneath, evoking a caricature of a person with well developed muscles "in the throes of radioactive testosterone poisoning, and liking it". the armor and equipment used by the super mutants of fallout 3 are predominantly based on salvaged material, such as car hoods and fenders crudely pounded into chest plates and pauldrons, and lawn mower blades welded onto helmets. the idea behind this design approach is to show recognizable real world elements being twisted to a more violent purpose, which conveys a sinister resourcefulness by these creatures to survive in a highly dangerous post-apocalyptic world. | wikipedia |
f3c3141348a05b4fc99b91fdf4c8e0bddd1892c6 | according to producer tim cain, the fallout development | according to producer tim cain, the fallout development team conceived of a faction of mutants who grow their ranks by dipping people into virus vats. during the discussion, a team member wondered what would happen if more than one person was dropped into the vat. the team decided to conceptualize such a being as the "master of the super mutants", who would switch between three voices: male, female, and electronic. the master's birth surname, moreau, references the titular mad scientist of the 1896 novel the island of doctor moreau by h. g. wells, who leads a group of genetically altered beings he has created through unethical experiments. | wikipedia |
c6e452bd636ed6db2efd9d163993528674de32ff | in comparison to the series' other notable mutated | in comparison to the series' other notable mutated beings like ghouls, super mutants are very formidable opponents in combat. behemoths in particular are capable of overpowering opponents like deathclaws and hordes of feral ghouls with little difficulty, and are unexpectedly nimble for their size. in spite of their physically impressive qualities, super mutants are sterile and cannot reproduce as the gametes of the reproductive system consist of "half-cells" using split dna, which could be perceived as "damage" by the fev, and in the attempt to "repair" them, it would render the subject infertile. | wikipedia |
ecd7faf6b6c90440190d1b7f434ec76f91b86688 | the physiology of a super mutant is very | the physiology of a super mutant is very different compared to ordinary humans; the most immediately noticeable effects are their immense size and strength, their different skin color, and their immunity to radiation damage. a standard super mutant's skin tone is usually green or yellow and stands approximately 10.4 feet tall, 7.8 feet when hunching, and weighs around 800 pounds. the nightkin, an elite super mutant caste, have gray-blue colored skin and largely retain their pre-existing intellect unlike their lesser brethren. they are often equipped with cloaking devices known as "stealth boys" and developed schizophrenia from prolonged use. other varieties of super mutants encountered in fallout 3 and fallout 4 grow much larger when they age. an immensely large variety first introduced in fallout 3, the behemoth, stands at roughly 20 feet tall and can grow up to 30 feet in height. | wikipedia |
59fafcfaba49bbee7d9014685fc5e1a2ffc2cb3a | super mutants are first introduced in the first | super mutants are first introduced in the first fallout as part of an ambitious effort by a grotesque mutated being known as "the master of the super mutants", to create a single, perfect " master race " and remove inequalities which have been the cause of strife among humans. the fev, an artificially-created virus by a defense contractor and research corporation contracted by the american government, was originally meant to protect against various forms of biological warfare. subsequent games in the fallout series feature other antagonistic factions that employ different strains of the fev to create super mutants. for example, vault tec, the technology company which built the nuclear fallout shelter facilities called vaults, deliberately exposed the occupants of vault 87 to a modified strain of the fev as part of an unethical experiment called the evolutionary experimentation program. the institute, an elusive faction of scientists in fallout 4, kidnap the inhabitants of the surrounding region and subject their victims to another strain of fev for experimentation. | wikipedia |
40fe6751327d58b92ce8d445fa9396209c8ff1cc | among the most recognizable and integral elements of | among the most recognizable and integral elements of the fallout intellectual property (ip), super mutants have appeared in every media of the franchise, and have been the subject of numerous fan mods of fallout series games. certain individual super mutant characters have been well received by critics for their characterization, although the role the super mutant race have played throughout the history of the franchise have been the source of contention for some commentators. | wikipedia |
f710f657613e3494a4118982d3d671660ffc6b86 | within series lore, super mutants tend to be | within series lore, super mutants tend to be depicted as savage and innately violent beings who, as a result of their transformations, lost a substantial amount of intelligence and often have cannibalistic tendencies. while super mutants tend to form their own factions or societies and are usually hostile to civilized humans, some have chosen to live peacefully alongside humans in settlements across the post-apocalyptic wasteland. | wikipedia |
a49dea1ff968ba899d2d7de9d07a3a4d0fc081f5 | super mutants are a fictional race of posthuman | super mutants are a fictional race of posthuman beings from the post-apocalyptic fallout video game franchise. the super mutants were first introduced in 1997's fallout as the results of human experimentation with a strain of the forced evolutionary virus (fev), a genetically engineered viral mutagen which transforms the subjects into a hulking monstrous humanoid form. | wikipedia |
fa77b0284a86fec0371a4a54fa9cf5f0d9f2fcd9 | "untitled" (america) is an artwork by felix gonzalez-torres | "untitled" (america) is an artwork by felix gonzalez-torres that is currently in the collection of the whitney museum of american art. the work consists of twelve individual parts/light strings, each part has 42 light bulbs. the artist purposefully chose not to specify how the work should be installed. an integral part of the artwork is that each time it is installed the exhibitor's choice of configuration completes the work. the light bulbs needed to install the work are most often sourced by the exhibitor and the original light bulbs are used as a guideline when choosing the brightness, shape and finish of the bulbs used for an installation. “untitled” (america) is the only light string in gonzalez-torres's oeuvre that is ideally intended to be installed outdoors. the exhibitor may choose to install the piece, in its entirety or using any number of the twelve parts, outdoors and/or indoors. | wikipedia |
537ef8225add25e0baf9a029a339533828451d06 | a more recent installation of the work occurred | a more recent installation of the work occurred at museu d'art contemporani de barcelona (macba) in 2021. four light strings were hung vertically on the exterior facade of the museum, and eight light strings were installed horizontally between street lights at the rambla del raval (a large public space with a central pedestrian area that has a perimeter of trees). | wikipedia |
4ad2a9d0c1c544187641f59892a1e0db0befc3ce | the work was installed in 2015 for the | the work was installed in 2015 for the inaugural exhibition celebrating the new whitney museum of american art building in the meatpacking district of new york city all 12 light strings were installed in a stairwell; suspended from the ceiling to the floor at the base of the stairs. | wikipedia |
bb4c0fa959a23ecca3a4ab4dc60c11d7aa0d306f | at the third and final venue of the | at the third and final venue of the solo exhibition, filipovic chose to install the 12 light strings across paulsplatz public square in frankfurt. for tino seghal ’s installation at mmk, 12 light strings were installed hanging vertically on the exterior of the museum. | wikipedia |
c5a4f8e34da9e98fbaa745b9f0e29202c9965661 | for dahn vo ’s installation at wiels he | for dahn vo ’s installation at wiels he chose to install the 12 light strings outside the home of charles gohy, the museum technician who was overseeing the manifestation and maintenance of the exhibition. located in the village of gesves, the work was hung from lamp posts along a country road, and situated so that it would be visible from gohy's bedroom window. | wikipedia |
ff99f65a9e83a325103bace613a827d7a123103d | “untitled” (america), 1994 was installed in five out | “untitled” (america), 1994 was installed in five out of six versions of the 2010/2011 solo exhibition, felix gonzalez-torres: specific objects without specific form [ felix gonzalez-torres: specific objects without specific form. wiels contemporary art centre, brussels, belgium. 16 jan. – 2 may 2010. [additional venues: fondation beyeler, basel, switzerland. 21 may – 29 aug. 2010; mmk museum für moderne kunst, frankfurt, germany. 28 jan. – apr. 2011. in addition to being the main curator of the exhibition, elena filipovic chose three artists, carol bove, dahn vo, and tino seghal to curate an additional version of the exhibition at each venue. | wikipedia |
025feb3826a7ad99018b70872eb9f83e5f4cc409 | “untitled” (america) was included in the 2007 exhibition | “untitled” (america) was included in the 2007 exhibition felix gonzalez-torres: america which was on view in the united states pavilion, giardini della biennale, as part of the 52nd venice biennial. the u.s. commissioner, nancy spector, chose to install eight of the individual light strings around an indoor rotunda and four of the light strings across an outdoor courtyard off of the exhibition building. | wikipedia |
02d3402738eade7655efbf52587873b6701dd441 | in 2000, the work was included in the | in 2000, the work was included in the american century: art and culture, 1950 – 2000 on view at the whitney museum of american art in new york. all twelve light strings were strung vertically side-by-side against a wall in a sunken outdoor courtyard at the whitney's original breuer building at 945 madison avenue. | wikipedia |
979e4ee9f5d33578d89a5301c45d038ced326c86 | the initial outdoor installation of the work took | the initial outdoor installation of the work took place in limerick, ireland in 1996. for this installation the light strings were installed in a zigzag pattern over a city street, suspended from buildings at a height slightly above shop signs. | wikipedia |
084824f9a7c9a675e015879b4bea3dab5b34881e | “untitled” (america) is the only light string in | “untitled” (america) is the only light string in gonzalez-torres's oeuvre that is ideally intended to be installed outdoors. the exhibitor may choose to install the piece, in its entirety or using any number of the twelve parts, outdoors and/or indoors. | wikipedia |
f2840bc388ec793331de4e472d2c6c7799a0e31f | "untitled" (america) is an artwork by felix gonzalez-torres | "untitled" (america) is an artwork by felix gonzalez-torres that is currently in the collection of the whitney museum of american art. the work consists of twelve individual parts/light strings, each part has 42 light bulbs. the artist purposefully chose not to specify how the work should be installed. an integral part of the artwork is that each time it is installed the exhibitor's choice of configuration completes the work. | wikipedia |
18ee5bf380cdd4b53f06a21771ba7c980a18fed7 | the 1952–53 season was the 69th scottish football | the 1952–53 season was the 69th scottish football season in which dumbarton competed at national level, entering the scottish football league, the scottish cup and the scottish league cup. in addition dumbarton competed in the stirlingshire cup. | wikipedia |
d2c8bc2649ba8ad220c443d62e6db75364933b08 | despite an unbeaten home record in the league | despite an unbeaten home record in the league cup sectional games, with two wins and a draw - three away defeats, including a 1-11 thrashing by ayr united (matching dumbarton's heaviest defeat recorded in the 1925-26 season) ensured that dumbarton finished 3rd of 4, resulting in no further progress in this competition. | wikipedia |
f7ac6141749526f2ca2a91cb081454e9753eee26 | an uncharacteristic good start to the league campaign | an uncharacteristic good start to the league campaign saw 5 points taken from the first 3 games, but this form was unable to be maintained and dumbarton finished in a mid-table 10th place, 16 behind champions stirling albion. | wikipedia |
18ee5bf380cdd4b53f06a21771ba7c980a18fed7 | the 1952–53 season was the 69th scottish football | the 1952–53 season was the 69th scottish football season in which dumbarton competed at national level, entering the scottish football league, the scottish cup and the scottish league cup. in addition dumbarton competed in the stirlingshire cup. | wikipedia |
20d51cfbdfd0e4c64bc5b7878108dc50f337b21a | the 1957 cork senior hurling championship was the | the 1957 cork senior hurling championship was the 69th staging of the cork senior hurling championship since its establishment by the cork county board in 1887. the competition was held between 31 march and 15 september 1957. blackrock were the defending champions, however, they were defeated by glen rovers in the second round. on 15 september 1957, sarsfields won the championship following a 5–10 to 4–6 defeat of university college cork in the final. it was their second championship title overall and their first title in six championship seasons. paddy barry was the championship's top scorer with 7–11. | wikipedia |
5b7edac266a3ed5ebca3cfe2316db03b64bf1b60 | the 1957 cork senior hurling championship was the | the 1957 cork senior hurling championship was the 69th staging of the cork senior hurling championship since its establishment by the cork county board in 1887. the competition was held between 31 march and 15 september 1957. | wikipedia |
2596a81d1a8a519d99aaad7815e81609f06101c8 | juventus football club did not manage to win | juventus football club did not manage to win the domestic championship for the seventh year in succession, but the legacy of the season was saved when it beat borussia dortmund by 3–1 away from home, then 3–0 in turin, to clinch the 1992–93 edition of the uefa cup. prior to the season, juventus had bought andreas möller and gianluca vialli for multi-million £ fees. vialli was considered a disappointment relative to his sampdoria form, but möller quickly established himself as a key midfielder and easily came to terms with the italian game. the third big-money signing david platt from relegated bari, spent his season mostly injured, and was sold to sampdoria at the end of it. roberto baggio was the club topscorer for the third successive season, scoring 21 goals, despite being used as a trequartista, playing just behind the forwards. | wikipedia |
5978ec9184befc5fe14918a83881c47e58950484 | prior to the season, juventus had bought andreas | prior to the season, juventus had bought andreas möller and gianluca vialli for multi-million £ fees. vialli was considered a disappointment relative to his sampdoria form, but möller quickly established himself as a key midfielder and easily came to terms with the italian game. the third big-money signing david platt from relegated bari, spent his season mostly injured, and was sold to sampdoria at the end of it. roberto baggio was the club topscorer for the third successive season, scoring 21 goals, despite being used as a trequartista, playing just behind the forwards. | wikipedia |
97ab89ece4403e9640c2fbd7e34677d03a11d699 | juventus football club did not manage to win | juventus football club did not manage to win the domestic championship for the seventh year in succession, but the legacy of the season was saved when it beat borussia dortmund by 3–1 away from home, then 3–0 in turin, to clinch the 1992–93 edition of the uefa cup. | wikipedia |
e05f71e9cc11d5dabba6e1dde21539506ef4066e | the 1997 tickford 500 was an endurance motor | the 1997 tickford 500 was an endurance motor race for v8 supercars. it was held on 14 september 1997 at the sandown raceway and was the 32nd running of the sandown 500. the race was won by craig lowndes and greg murphy, driving a holden vs commodore for the holden racing team. | wikipedia |
689d6f38428823edca445e37be7d28c52f8bf021 | the race was started in the rain under | the race was started in the rain under the control of the safety car. the weather conditions resulted in a slower than expected average speed and the race did not run to its full 161 lap distance, being halted on lap 157 after 3 hours 45 minutes and 22.3508 seconds. | wikipedia |
4e6eb3f2980eeb8018cb75dcea53de97df0df940 | the 1986 hockey world cup was the sixth | the 1986 hockey world cup was the sixth hockey world cup men's field hockey tournament. it was held in london, england. the competition was won by australia, who defeated host nation england 2–1 in the final. west germany finished third after defeating the soviet union. england, as hosts – and also as olympic bronze medallists – were viewed as having quite a tough group, containing olympic champions pakistan, and a highly fancied dutch side, with the soviet union seen as potential dark-horse outsiders. but in the event pakistan failed badly, winning only a single group match against minnows new zealand – blaming their poor play on failure to adjust to the astroturf surface, used in a major hockey tournament for the first time instead of grass. the soviets scored surprise victories over both pakistan and england, leaving england in danger of going out of their own tournament in the group stages: however they recovered to win their final match, against the dutch. this left england, the ussr and the netherlands all level on points with four wins and one loss each. england and the soviets were equal on goal difference as well as points, england being ahead on goals scored: the dutch unfortunate to be in third thanks to an inferior goal difference to both. in the other group, things were expected to be more straightforward, with west germany and australia being the two favourites. australia duly topped the group by defeating everybody except the germans, with whom they drew: the germans also finished the group undefeated to qualify comfortably in second place, though they also drew with spain and india. the latter, hockey giants of the past, were nowhere near the same force in the present: in the play-offs for the minor places, india ended up losing both matches, including the 11th–12th place play-off to the otherwise hapless pakistan. the first semi-final, between england and west germany, was an absolute classic. a replay of the semi-final of the 1984 olympic tournament, won 1–0 by the germans, meant that the english had a score to settle. england dominated most of the first half, but in the end had only one goal to show for it, scored by star centre-forward sean kerly. in the second half, the germans found their form, equalising from a penalty corner, and then going into the lead with a smart strike from | wikipedia |
53d648f98c6e58ad104c292b27462169dbc666ef | the 1986 hockey world cup was the sixth | th–12th place play-off to the otherwise hapless pakistan. the first semi-final, between england and west germany, was an absolute classic. a replay of the semi-final of the 1984 olympic tournament, won 1–0 by the germans, meant that the english had a score to settle. england dominated most of the first half, but in the end had only one goal to show for it, scored by star centre-forward sean kerly. in the second half, the germans found their form, equalising from a penalty corner, and then going into the lead with a smart strike from their captain, heiner dopp. the remainder of the match was end-to-end stuff as england pressed hard for an equaliser. several times they came close from both open play and penalty corners: shots whizzed past the post, crosses were desperately intercepted, the keeper himself made a few useful saves – but the germans were themselves dangerous on the breakaway. fischer thought he had scored a german third from a penalty corner, but it was disallowed as the ball flew dangerously high off his stick: dopp, too, nearly scored another, but was denied by a last-ditch deflection from england's own captain, richard dodds. finally, in the last minute, with england on the verge of going out, they were awarded a penalty corner, from which paul barber scored an equalizer – almost blocked by a german stick, but it deflected into the roof of the net, forcing extra time. the extra period was as thrilling as the last minutes of the main game, both sides going for all-out attack: the game was finally settled by another english penalty corner, from which barber scored an action-replay of his earlier goal to send england into the final. the second semi-final, after all that, was an anti-climax, australia hammering the soviet union by 5–0. the soviets made a slightly better fist of the third-place play-off against the germans, but in the end it was the germans who clinched third place. the final was also a rematch of sorts – england having defeated australia in the olympic third-place play-off, the aussies were out for revenge. england started slowly, and terry walsh scored an early goal to put australia into a deserved lead. england soon began to find their feet, with some typically mazy dribbles by imran sherwani | wikipedia |
a455bf9d0a8273c9c51ba9ddead671d9c329585d | the 1986 hockey world cup was the sixth | -climax, australia hammering the soviet union by 5–0. the soviets made a slightly better fist of the third-place play-off against the germans, but in the end it was the germans who clinched third place. the final was also a rematch of sorts – england having defeated australia in the olympic third-place play-off, the aussies were out for revenge. england started slowly, and terry walsh scored an early goal to put australia into a deserved lead. england soon began to find their feet, with some typically mazy dribbles by imran sherwani threatening the australian lines: but another goal soon followed for the australians, this time against the run of play, from a penalty corner. this goal was in fact briefly disputed by england, who claimed that the shot had flown too high, above the back board of the net: but the referee ruled that it had brushed the goalkeeper's glove on the way, so the "too high" was counted as a deflection off an english player rather than a straight hit from the australian scorer, and england were 2–0 behind at half-time. the second half was a more scrappy affair – england by and large having the greater amount of possession, but unable to create any significant chances against a well-drilled australian defensive line. late on in the game, a defensive error finally allowed jon potter in to score, but it was too little, too late: australia hung on for a 2–1 victory. | wikipedia |
91d3c34a24562a1415373c431323ea6e8cb3606c | england ian taylor, david faulkner, paul barber, jon | england ian taylor, david faulkner, paul barber, jon potter, richard dodds (capt), martyn grimley, stephen batchelor (sub kulbir bhaura), richard leman (sub john shaw), sean kerly, norman hughes, imran sherwani | wikipedia |
61b6e254c3cfd67e3f68c74f39b8da6e59f5d243 | australia neil snowden, john bestall, craig davies, david | australia neil snowden, john bestall, craig davies, david bell (capt), warren birmingham, treva king, grant mitton (sub dean evans), colin batch, terry walsh, ric charlesworth, neil hawgood (sub peter haselhurst) | wikipedia |
59ef64173b02a98437511903b4b2531f06bd3c84 | the final was also a rematch of sorts | the final was also a rematch of sorts – england having defeated australia in the olympic third-place play-off, the aussies were out for revenge. england started slowly, and terry walsh scored an early goal to put australia into a deserved lead. england soon began to find their feet, with some typically mazy dribbles by imran sherwani threatening the australian lines: but another goal soon followed for the australians, this time against the run of play, from a penalty corner. this goal was in fact briefly disputed by england, who claimed that the shot had flown too high, above the back board of the net: but the referee ruled that it had brushed the goalkeeper's glove on the way, so the "too high" was counted as a deflection off an english player rather than a straight hit from the australian scorer, and england were 2–0 behind at half-time. the second half was a more scrappy affair – england by and large having the greater amount of possession, but unable to create any significant chances against a well-drilled australian defensive line. late on in the game, a defensive error finally allowed jon potter in to score, but it was too little, too late: australia hung on for a 2–1 victory. | wikipedia |
2c83146c9ce50e1c6bae53a138e4baa2b2fdf102 | the second semi-final, after all that, was an | the second semi-final, after all that, was an anti-climax, australia hammering the soviet union by 5–0. the soviets made a slightly better fist of the third-place play-off against the germans, but in the end it was the germans who clinched third place. | wikipedia |
c412183da14024a26c98afeda354a6dd9c185ab4 | the first semi-final, between england and west germany, | the first semi-final, between england and west germany, was an absolute classic. a replay of the semi-final of the 1984 olympic tournament, won 1–0 by the germans, meant that the english had a score to settle. england dominated most of the first half, but in the end had only one goal to show for it, scored by star centre-forward sean kerly. in the second half, the germans found their form, equalising from a penalty corner, and then going into the lead with a smart strike from their captain, heiner dopp. the remainder of the match was end-to-end stuff as england pressed hard for an equaliser. several times they came close from both open play and penalty corners: shots whizzed past the post, crosses were desperately intercepted, the keeper himself made a few useful saves – but the germans were themselves dangerous on the breakaway. fischer thought he had scored a german third from a penalty corner, but it was disallowed as the ball flew dangerously high off his stick: dopp, too, nearly scored another, but was denied by a last-ditch deflection from england's own captain, richard dodds. finally, in the last minute, with england on the verge of going out, they were awarded a penalty corner, from which paul barber scored an equalizer – almost blocked by a german stick, but it deflected into the roof of the net, forcing extra time. the extra period was as thrilling as the last minutes of the main game, both sides going for all-out attack: the game was finally settled by another english penalty corner, from which barber scored an action-replay of his earlier goal to send england into the final. | wikipedia |
bd291e553700c554dede49e8f0735219e29adb9d | in the other group, things were expected to | in the other group, things were expected to be more straightforward, with west germany and australia (olympic silver medallists and fourth place respectively) being the two favourites. australia duly topped the group by defeating everybody except the germans, with whom they drew: the germans also finished the group undefeated to qualify comfortably in second place, though they also drew with spain and india. the latter, hockey giants of the past, were nowhere near the same force in the present: in the play-offs for the minor places, india ended up losing both matches, including the 11th–12th place play-off to the otherwise hapless pakistan. | wikipedia |
bf7efeb5f937201c8c1479c7a5d3857a5382595c | england, as hosts – and also as olympic | england, as hosts – and also as olympic bronze medallists – were viewed as having quite a tough group, containing olympic champions pakistan, and a highly fancied dutch side, with the soviet union seen as potential dark-horse outsiders. but in the event pakistan failed badly, winning only a single group match against minnows new zealand – blaming their poor play on failure to adjust to the astroturf surface, used in a major hockey tournament for the first time instead of grass. the soviets scored surprise victories over both pakistan and england, leaving england in danger of going out of their own tournament in the group stages: however they recovered to win their final match, against the dutch. this left england, the ussr and the netherlands all level on points with four wins and one loss each. england and the soviets were equal on goal difference as well as points, england being ahead on goals scored: the dutch unfortunate to be in third thanks to an inferior goal difference to both. | wikipedia |
aae5705e75a5a24520a278de731a2ca9dc81749a | the 1986 hockey world cup was the sixth | the 1986 hockey world cup was the sixth hockey world cup men's field hockey tournament. it was held in london, england. the competition was won by australia, who defeated host nation england 2–1 in the final. west germany finished third after defeating the soviet union. | wikipedia |
145b102670c529a0e654515c2889f4b06b342061 | the 1939 vfl grand final was an australian | the 1939 vfl grand final was an australian rules football game contested between the melbourne football club and collingwood football club, held at the melbourne cricket ground in melbourne on 30 september 1939. it was the 41st annual grand final of the victorian football league, staged to determine the premiers for the 1939 vfl season. | wikipedia |
145b102670c529a0e654515c2889f4b06b342061 | the 1939 vfl grand final was an australian | the 1939 vfl grand final was an australian rules football game contested between the melbourne football club and collingwood football club, held at the melbourne cricket ground in melbourne on 30 september 1939. it was the 41st annual grand final of the victorian football league, staged to determine the premiers for the 1939 vfl season. | wikipedia |
8a587dde25ced03aa60e63a58474ef0dccbdecb4 | 1,4-butane sultone is a six-membered δ-sultone and the | 1,4-butane sultone is a six-membered δ-sultone and the cyclic ester of 4-hydroxybutanesulfonic acid. as a sulfo-alkylating agent, 1,4-butanesultone is used to introduce the sulfobutyl group (–(ch2)4–so3−) into hydrophobic compounds possessing nucleophilic functional groups, for example hydroxy groups (as in the case of β-cyclodextrin) or amino groups (as in the case of polymethine dyes). in such, the sulfobutyl group is present as neutral sodium salt and considerably increases the water solubility of the derivatives. | wikipedia |
481623e96bd051a7b549cccb11bdd95a2c6a7d2b | thereby, the water solubility of the β-cyclodextrin increases | thereby, the water solubility of the β-cyclodextrin increases from 18.5 g · l-1 to more than 900 g · l-1 at 25 °c. sulfobutyl ether-beta-cyclodextrin also finds a wide range of applications as an inert vehicle for drug delivery (the drugs transport and release). | wikipedia |
6c4405807e9af9b36f61cd8da80102b023aff421 | already in 1949 the reaction of 1,4-butanesultone with | already in 1949 the reaction of 1,4-butanesultone with the water-insoluble polysaccharide cellulose in sodium hydroxide solution was reported, which leads to a water-soluble product. derived from this the derivatization of β-cyclodextrin to sulfobutyl ether-beta-cyclodextrin (sbecd) is by now an important application of 1,4-butanesultone. sulfobutyl ether-beta-cyclodextrin is a water-soluble inclusion compound for the solubilization and stabilization of sparsely water-soluble and chemically instable components. β-cyclodextrin can be reacted with 1,4-butanesultone in sodium hydroxide solution at 70 °c to the sulfobutyl ether in yields of up to 80% and a degree of substitution of 6.68. | wikipedia |
ac3f272d4c21093179da5d046e593cb9cb124f24 | the chlorine atom in the 4-chlorobutylsulfonate anion can | the chlorine atom in the 4-chlorobutylsulfonate anion can be substituted by heating with inorganic (e.g. potassium fluoride) or organic salts (e.g. sodium acetate) by the respective anion. | wikipedia |
3b6d70d946be109b029adf6178080fce0563a1eb | the ionic liquid 4-triethylammonium butane-1-sulfonic acid hydrogensulfate (tebsa | the ionic liquid 4-triethylammonium butane-1-sulfonic acid hydrogensulfate (tebsa hso) is formed by the reaction of 1,4-butanesultone with triethylamine in acetonitrile to the zwitterion (85% yield) and subsequent reaction with concentrated sulfuric acid. | wikipedia |
fd92c56fbe3cbf5dcc189a02eac81163ba991612 | aminoalkylphosphonic acids (such as aminomethane diphosphonic acid, accessible | aminoalkylphosphonic acids (such as aminomethane diphosphonic acid, accessible from phosphorus trichloride, formamide and phosphonic acid) form with 1,4-butanesultone n-(sulfobutyl)aminomethane diphosphonic acids: | wikipedia |
6ea5a7b2ebe19a149a30a31ce0e10b570bb89a88 | 1-butylimidazolium-3-(n-butylsulfonate) catalyses as a component of multifunctional catalysts | 1-butylimidazolium-3-(n-butylsulfonate) catalyses as a component of multifunctional catalysts the reaction of platform chemicals from biomass (for example levulinic acid or itaconic acid) into the corresponding lactones, diols or cyclic ethers. | wikipedia |
c780a8f9bc0fe4ed0f5131d0d12c49fe6ec5a703 | in the reaction of n - n -butylimidazole | in the reaction of n - n -butylimidazole with 1,4-butansultone in toluene in a 98% yield is formed 1-butylimidazolium-3-(n-butylsulfonate) | wikipedia |
c7b8051b28d2ad494a869b633f56769dae84920d | 1,4-butanesultone is a viscous, clear, colorless and odorless | 1,4-butanesultone is a viscous, clear, colorless and odorless liquid which reacts in boiling water (to 4-hydroxybutanesulfonic acid) and alcohols (to 4-alkoxybutanesulfonic acid) and dissolves in many organic solvents. at temperatures below the melting point, the compound crystallizes giving "large, magnificent plates". compared to the homologous γ-sultone 1,3-propanesultone, 1,4-butanesultone is significantly less reactive as alkylating agent, but classified as mutagenic and carcinogenic. | wikipedia |
5dc0c10e1399b456b56ee82a9e370f62d208b93a | the free-radical initiated sulfochlorination of 1-chlorobutane leads to | the free-radical initiated sulfochlorination of 1-chlorobutane leads to a mixture of positionally isomeric sulfochlorides and chlorination products and is therefore not suitable for the direct preparation of 1,4-butanesultone. | wikipedia |
5d1ec7f080ae1766825e77153fce0285b63cb47a | the vacuum distillation of the sodium salt of | the vacuum distillation of the sodium salt of 4-hydroxybutanesulfonic acid leads in the presence of concentrated sulfuric acid directly to 1,4-butanesultone. the sodium salt of 4-chlorobutane-1-sulfonic acid, which is obtained from 1,4-dichlorobutane with sodium sulfite, can also be cyclized to 1,4-butanesultone by heating to 180-250 °c. | wikipedia |
edbcf49691e649b2daa571640a770a99ab4a26e1 | the cyclization of 4-hydroxybutanesulfonic acid in aqueous solution | the cyclization of 4-hydroxybutanesulfonic acid in aqueous solution proceeds particularly efficiently when heated with high-boiling, water-immiscible solvents (for example 1,2-dichlorobenzene or diethylbenzene, both boiling at about 180 °c) in which 1,4-butane-sultone dissolves and is thereby protected from hydrolysis in the aqueous medium. 1,4-butanesultone is obtained in yields of up to 99% upon reflux within one hour. | wikipedia |
38b15dfced70e7d9b4bf7374f764114ef0a370bb | starting from 4-chlorobutan-1-ol (from tetrahydrofuran and hydrogen chloride | starting from 4-chlorobutan-1-ol (from tetrahydrofuran and hydrogen chloride in 54 to 57% yield), the sodium salt of 4-hydroxybutan-1-sulfonic acid is obtained with sodium sulfite. this salt is converted with strong acids (such as hydrochloric acid) into the very hygroscopic 4-hydroxybutanesulfonic acid and cyclized to 1,4-butanesultone under elimination of water. | wikipedia |
953490c8a5c82cb8c205dd3f7b996000a061426e | a lab scale synthesis of 1,4-butanesultone starts from | a lab scale synthesis of 1,4-butanesultone starts from 4,4'-dichlorodibutyl ether (accessible from tetrahydrofuran treated with phosphorus oxychloride and concentrated sulfuric acid), which reacts with sodium sulfite forming the corresponding 4,4'-butanedisulfonic disodium salt. by passing it through an acidic ion exchanger, the disodium salt is converted into the disulphonic acid which forms two molecules of 1,4-butanesultone at elevated temperature and reduced pressure under elimination of water. the yields obtained range from 72 to 80%. | wikipedia |
e26741ed0d70d0e236d8ab9e9e06a1f00f420251 | 1,4-butane sultone is a six-membered δ- sultone and | 1,4-butane sultone is a six-membered δ- sultone and the cyclic ester of 4-hydroxybutanesulfonic acid. as a sulfo-alkylating agent, 1,4-butanesultone is used to introduce the sulfobutyl group (–(ch) –so) into hydrophobic compounds possessing nucleophilic functional groups, for example hydroxy groups (as in the case of β-cyclodextrin) or amino groups (as in the case of polymethine dyes). in such, the sulfobutyl group is present as neutral sodium salt and considerably increases the water solubility of the derivatives. | wikipedia |
fd2589d51eec3c5022c68f8eead71f989f7733c0 | the 1950 limerick senior hurling championship was the | the 1950 limerick senior hurling championship was the 56th staging of the limerick senior hurling championship since its establishment by the limerick county board. st. patrick's were the defending champions. st. patrick's won the championship after a 4–05 to 3–05 defeat of city gaels in the final. it was their second championship title overall and their second title in succession. it remains their last championship triumph. | wikipedia |
0759d1a24615916e0ae4da93963fa85a5bd9937b | the 2002–03 season was the 107th year in | the 2002–03 season was the 107th year in non-league football and sixth season since their return to the football conference played by yeovil town football club, an english football club based in yeovil, somerset. yeovil began the season playing their home matches at the avenue stadium, home of dorchester town, while the huish park pitch was being relaid. yeovil occupied top spot in the conference from late september until the end of the season, eventually winning the title by a records points margin and earning promotion to the football league for the first time in the club's 108-year history. the team reached the first round of the fa cup but lost 2–0 at home to second division side cheltenham town. the team failed to defend their fa trophy title being knocked out in the quarter-final after being beaten 2–0 by northern premier league side burscough. kirk jackson was the club's top goalscorer after joining in november scored 20 goals, with 19 in the league and one in the fa trophy. | wikipedia |
fedd27d321869e8de9416c930096ae1b1742df4b | the end of the season saw manager gary | the end of the season saw manager gary johnson release four players, including jimmy aggrey, kim grant, neil mustoe, jon sheffield, while defender tom white was invited back to pre-season training to prove his fitness. seven players all signed new contracts at the end of the season including striker kevin gall, midfielder abdou el-kholti, defenders roy o'brien and stephen reed as well as forwards adam stansfield, andy lindegaard and chris giles. while yeovil dominated the end of season conference awards, johnson walked away with manager of the year, winger michael mcindoe winning the player of the year award and he was joined in the team of the year by goalkeeper chris weale, captain terry skiverton and darren way. | wikipedia |
09672024b93b7411c25d3793545b57d9f0181ef6 | after a sluggish start to the season, yeovil | after a sluggish start to the season, yeovil occupied top spot in the conference from late september until the end of the season, before eventually winning the title by a record 17-point margin and earning promotion to the football league for the first time in the club's 108-year history. in the league the team were unbeaten at home winning 16 matches and drawing 5, compared to winning 12, drawing 6 and losing 3 away from home. the three defeats yeovil suffered was the joint fewest of any team since the formation of the conference. the club scored 100 league goals the most in the conference and had a record goal difference of +63. the club also recorded the highest average attendance ever in the conference of 4,741, despite starting the season playing at dorchester. michael mcindoe recorded the highest number of appearances during the season, appearing in 49 of yeovil's 51 matches, excluding the somerset premier cup. after joining in november, kirk jackson was the club's top goalscorer with 19 goals in the conference and 20 goals for the club in all competitions, and finished as runner-up in the conference golden boot. | wikipedia |
8b54472f64a5f32db2eddc23e5cc8b63d7ef9a5a | on 5 april, a 3–0 home win against | on 5 april, a 3–0 home win against telford united took yeovil to within one point of winning the conference title. before they could wrap it up they faced clevedon town in the semi-finals of the somerset premier cup and a strong yeovil side was to good for their lower league rivals winning 4–0. yeovil's promotion was confirmed before kick-off against doncaster rovers, on 12 april, after chester city 's 2–2 draw with woking. the glovers celebrated their title, and promotion to the football league for the first time in their 108-year history, with an emphatic 4–0 rout of doncaster at belle vue. yeovil continued their form with a 6–1 win over burton albion, on 19 april, with kevin gall scoring four. yeovil's penultimate match of the season saw them travel to face play-off qualifiers dagenham & redbridge, a sixth goal in three matches from kevin gall and a kirk jackson hat-trick saw yeovil record an impressive 4–0 away win, and their seventh successive win in the conference a club record at that level. the match also saw the league debut of youth team player stephen reed. yeovil completed their record breaking season against chester city in front of 8,111 fans, the highest crowd in the conference that season, and opened the scoring through kevin gall with their 100th goal in the conference but a late equaliser forced them to settle for a 1–1 draw. after recording a further four wins and a draw from their five league matches in april, johnson was awarded his third manager of the month award of the season, shared with jim harvey of morecambe. yeovil then faced taunton town, on 29 april 2003, in the final of the somerset premier cup played at the home of clevedon town, but failed to add the cup to their conference title losing 2–1. | wikipedia |
950836e7ddc5d6b55fefefa5f1ea34d968ca2780 | yeovil began march, with a 4–0 thrashing of | yeovil began march, with a 4–0 thrashing of rivals hereford united, and then a second half hat-trick from kevin gall saw yeovil come from two goals down to beat halifax town 3–2. on 8 march, top scorer kirk jackson grabbed his 18th goal of the season, including seven for stevenage, to earn 10-man yeovil a 1–1 draw at woking. yeovil got back to winning ways and opened up a 12-point lead at the top of the conference with a 3–1 victory against leigh rmi, with jackson grabbing a brace. yeovil's hopes of a conference and fa trophy double, were ended on 15 march, after a 2–0 home defeat against burscough in the sixth round ended their defence of the title. yeovil bounced back from their fa trophy defeat with a 2–1 victory over margate with another brace from kirk jackson. on 28 march, yeovil ended the month with a 1–0 home victory over scarborough. after recording four wins and a draw from their five league matches in march, johnson picked up his second manager of the month award of the season. | wikipedia |
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