"""E916 six-cell conservative extraction teaching model, NOT hardware control. 1.1: the firmware functions behind the front-panel menus (positions, preheat setpoint / EcoMode, method editor fields and the method store, SKIP and the three STOP presses, leak test, flush, instrument settings, solvent list, service functions) and the front panel itself (panel.press / turn / switch / capture / frame; panel_ui.json beside the contract, generic engine _panel_ui.py).""" from __future__ import annotations import copy,json,math from asset_runtime import _annotations as _ann from pathlib import Path from asset_runtime.mt_hx204 import ActionRejected,number,obj,BOOL,TEXT from asset_runtime.antonpaar_abbematadvanced import validate ROOT=Path(__file__).resolve().parents[2];ASSET_TYPE_ID='instrument.buchi_speedextractore';CATALOG_ID='CHEM-028';PROTOCOL_VERSION='1.0.0';TEMPLATE_REL='assets/reactions/buchi_speedextractore_extraction_library/templates.json';LIB=ROOT/Path(TEMPLATE_REL).parent PHASE={'type':'string','enum':['idle','running','succeeded','cancelled','failed']} def arr(s):return {'type':'array','items':s} def nullable(s):return {'anyOf':[s,{'type':'null'}]} MASS=number('kg',0);VOL=number('m^3',0);PRESS=number('Pa',0);TEMP=number('K',273.15,473.15);FRAC=number('1',0,1) SOLVENTS=['acetone','ethanol','methanol','n_hexane'];INT=lambda lo,hi:{'type':'integer','minimum':lo,'maximum':hi,'x-unit':'1'} PLANT=obj({'ambient_k':number('K',288.15,303.15),'ambient_pa':number('Pa',80000,110000),'reservoir_m3':arr(number('m^3',0,.02)),'nitrogen_gauge_pa':number('Pa',6e5,1e6),'nitrogen_mol':number('mol',.001,1000),'nitrogen_mol_s_per_cell':number('mol/s',1e-6,.01),'exhaust_connected':BOOL,'dry_matrix_reviewed':BOOL,'thermal_tau_s':number('s',.5,300),'pressure_tau_s':number('s',.1,30),'discharge_m3_s_per_cell':number('m^3/s',1e-9,1e-5),'residual_holdup_fraction':number('1',0,.2),'vial_capacity_m3':number('m^3',60e-6,240e-6),'coefficient_evidence':TEXT}) EXAMPLE=dict(ambient_k=295.15,ambient_pa=101325.,reservoir_m3=[.001]*4,nitrogen_gauge_pa=7e5,nitrogen_mol=10.,nitrogen_mol_s_per_cell=.001,exhaust_connected=True,dry_matrix_reviewed=True,thermal_tau_s=10.,pressure_tau_s=1.,discharge_m3_s_per_cell=2e-6,residual_holdup_fraction=.02,vial_capacity_m3=240e-6,coefficient_evidence='synthetic_host_heat_hydraulic_transfer_and_holdup; NOT factory calibration') METHOD=obj({'temperature_k':number('K',303.15,473.15),'pressure_gauge_pa':number('Pa',5e6,15e6),'cycles':INT(1,10),'hold_s':number('s',0,3600),'discharge_s':number('s',0,3600),'pump_total_m3_s':number('m^3/s',1e-6/60,50e-6/60),'solvent_fractions':arr(FRAC),'solvent_flush_s':number('s',0,540),'nitrogen_flush_s':number('s',60,1800)}) METHOD_EXAMPLE=dict(temperature_k=373.15,pressure_gauge_pa=10e6,cycles=2,hold_s=30.,discharge_s=30.,pump_total_m3_s=50e-6/60,solvent_fractions=[.5,.5,0.,0.],solvent_flush_s=0.,nitrogen_flush_s=60.) SAMPLE=obj({'position':INT(0,5),'sample_id':TEXT,'substance_id':TEXT,'cell_volume_m3':{'type':'number','enum':[10e-6,20e-6,40e-6],'x-unit':'m^3'},'matrix_mass_kg':number('kg',1e-9,.1),'matrix_solid_volume_m3':number('m^3',1e-10,39e-6),'target_mass_kg':number('kg',1e-15,.001),'kd_m3_kg_by_solvent':arr(number('m^3/kg',1e-8,1e3)),'mass_transfer_s_inv':number('1/s',1e-6,10),'activation_energy_j_mol':number('J/mol',0,1e5),'adsorption_energy_j_mol':number('J/mol',0,1e5),'solubility_kg_m3':number('kg/m^3',1e-9,1000),'degradation_s_inv':number('1/s',0,1),'gripper_confirmed':BOOL,'parameters_evidence':TEXT}) SAMPLE_EXAMPLE=dict(position=0,sample_id='soil_1',substance_id='phenol',cell_volume_m3=20e-6,matrix_mass_kg=.005,matrix_solid_volume_m3=5e-6,target_mass_kg=1e-6,kd_m3_kg_by_solvent=[.0001,.0002,.00015,.01],mass_transfer_s_inv=.02,activation_energy_j_mol=10000.,adsorption_energy_j_mol=5000.,solubility_kg_m3=10.,degradation_s_inv=0.,gripper_confirmed=True,parameters_evidence='synthetic_host_soil_partition_transfer; NOT measured E916 recovery') RESULT=obj({'phase':PHASE,'stage':TEXT,'fault':TEXT,'temperature_k':nullable(TEMP),'max_pressure_gauge_pa':nullable(PRESS),'cycle':INT(0,10),'stage_elapsed_s':number('s',0),'evidence':TEXT,'template_source':TEXT}) ITEM=obj({'position':INT(0,5),'sample_id':TEXT,'substance_id':TEXT,'extract_target_kg':MASS,'residual_target_kg':MASS,'degraded_target_kg':MASS,'matrix_mass_kg':MASS,'extract_solvent_m3':VOL,'residual_solvent_m3':VOL,'modeled_absolute_recovery_fraction':FRAC,'measured_e916_recovery_fraction':{'type':'null'},'reference_ase_soxtec_ratio':number('1',0),'reference_instrument':TEXT}) PRODUCT=obj({'items':arr(ITEM),'evidence':TEXT,'template_source':TEXT}) REFERENCE=obj({'substance_id':TEXT,'name':TEXT,'ase_soxtec_ratio':number('1',0),'measured_e916_recovery_fraction':{'type':'null'},'source':TEXT,'conditions':TEXT,'evidence':TEXT,'template_source':TEXT}) # ---------------------------------------------------------------- device functions behind the front panel (E-916 operation manual 093218, 'om p.N' = PDF page) # Positions, preheat setpoint / EcoMode, the method editor fields (vial, cell, solvent names, per-cycle hold / discharge / vial change / port), the # method store (100), SKIP and the three STOP presses, leak test, flush, instrument settings, solvent list and the service functions (valves, # sensors, pump, flow test, lifts, fans, operating hours). The 1.0 commands keep their behaviour: with positions never set every loaded sample # cell takes part, as before. MLMIN=1e-6/60;BAR=1e5 CELL_VOLUMES=[10e-6,20e-6,40e-6];VIALS={'60':60e-6,'150':150e-6,'220':220e-6,'240':240e-6,'unspecified':None,'waste':None} DEFAULT_SOLVENTS=['Acetone','Acetonitrile','Cyclohexane','Dichloromethane','Hexane','Isopropyl alcohol','Methanol','Petrolether','Toluene','Water'] # om p.38 (entry 010 hidden: assumed) LANGUAGES=['English','Deutsch','Francais','Italiano','Espanol'] SETTINGS={'language':dict(type='enum',options=LANGUAGES,default='English'),'contrast':dict(type='int',min=10,max=100,default=70), 'beep_key':dict(type='bool',default=False),'beep_end':dict(type='bool',default=True),'preheat_demand':dict(type='bool',default=False)} # om p.40 figure DEFAULT_METHOD=dict(temperature_k=373.15,pressure_gauge_pa=10e6,cycles=1,hold_s=120.,discharge_s=120.,pump_total_m3_s=50*MLMIN,solvent_fractions=[1.,0.,0.,0.], solvent_flush_s=60.,nitrogen_flush_s=180.,vial='240',cell_volume_m3=20e-6,solvent_names=['Acetone','Ethanol','Methanol','Hexane'], cycle_steps=[dict(hold_s=120.,discharge_s=120.,vial_change=False,port=0)]) # om p.55-56 defaults; cell and names assumed LEAK_DEFAULT=dict(temperature_k=373.15,pressure_gauge_pa=10e6,solvent_fractions=[1.,0.,0.,0.],hold_s=240.,flush_into='vial',gas_flush_s=120.) # om p.43 reference FLUSH_DEFAULT=dict(solvent_s=120.,flush_into='waste',flow_m3_s=50*MLMIN,gas_s=180.,solvent_fractions=[1.,0.,0.,0.]) # om p.44 E-916 table FLOW_DEFAULT=dict(flush_into='vial',port=1,position=1) VALVES=['solvent_1','solvent_2','solvent_3','solvent_4','media_solvent','media_gas']+['position_%d'%i for i in range(1,7)]+['outlet_vial','outlet_waste','solvent_all','position_all'] LIFT_SPEED=.01;LIFT_CURRENT_A=.35;OVERALL_HOLD=.97;BACK_PA_PER_M3S=3*BAR/(50*MLMIN) # assumptions: lift motor current while moving; 3 bar back pressure per line at 50 mL/min FAN_FACTORY=30;FAN_LOSS=.1 # extraction fan (om p.88: factory 30 %, 100 % in a fault, the setting changes the heating-block temperature): extra loss # conductance FAN_LOSS*(fan-30 %)/100 relative to the heater control (assumption: 100 % fan ~5 K low at 100 C) NAME_CHARS=set('ABCDEFGHIJKLMNOPQRSTUVWXYZabcdefghijklmnopqrstuvwxyz0123456789 .,-+*:%&/()=?!_') UNIT_INFO=dict(line_voltage='230V',firmware='01.03',serial='') # om p.88 figure (serial number blank there) FRAC4={'type':'array','items':FRAC,'minItems':4,'maxItems':4};POS6={'type':'array','items':BOOL,'minItems':6,'maxItems':6};FREE={'type':'object'} VIAL_ENUM={'type':'string','enum':list(VIALS)};INTO={'type':'string','enum':['vial','waste']};CELL_ENUM={'type':'number','enum':CELL_VOLUMES,'x-unit':'m^3'} STEP=obj({'hold_s':number('s',0,3600),'discharge_s':number('s',0,3600),'vial_change':BOOL,'port':INT(0,4)}) METHOD_EXTRA={'vial':VIAL_ENUM,'cell_volume_m3':CELL_ENUM,'solvent_names':{'type':'array','items':TEXT,'minItems':4,'maxItems':4},'cycle_steps':{'type':'array','items':STEP,'minItems':1,'maxItems':10}} NAMED=obj({'slot':INT(1,100),'name':TEXT});SLOT_ONLY=obj({'slot':INT(1,100)}) LEAK=obj({'temperature_k':number('K',303.15,473.15),'pressure_gauge_pa':number('Pa',5e6,15e6),'solvent_fractions':FRAC4,'hold_s':number('s',60,1800),'flush_into':INTO,'gas_flush_s':number('s',60,1800)},optional=('temperature_k','pressure_gauge_pa','solvent_fractions','hold_s','flush_into','gas_flush_s')) FLUSH=obj({'solvent_s':number('s',0,540),'flush_into':INTO,'flow_m3_s':number('m^3/s',1*MLMIN,50*MLMIN),'gas_s':number('s',60,1800),'solvent_fractions':FRAC4},optional=('solvent_s','flush_into','flow_m3_s','gas_s','solvent_fractions')) FLOW=obj({'flush_into':INTO,'port':INT(1,4),'position':INT(1,6)},optional=('flush_into','port','position')) STATUS_OUT=obj({'status':FREE}) POSITIONS=[f'position_valve_{i}' for i in range(6)];SENSORS=[f'pressure_sensor_{i}' for i in range(6)];CELLS=[f'cell_{i}' for i in range(6)] DEVICE_CAPS={ 'positions.set':(obj({'active':POS6,'position':INT(1,6),'enabled':BOOL},optional=('active','position','enabled')),obj({'active':POS6}),POSITIONS,'激活/停用萃取位置(OCCUPIED POSITIONS:全部、或单个位置;停用位置的位置阀全程关闭,只冲洗激活位置;om p.40-41)','device_command','agent',{'active':[True]*6},['positions.active']), 'method.save':(NAMED,obj({'slot':INT(1,100),'name':TEXT}),['panel'],'把当前方法存入方法表(1–100号,名称≤16字符;覆盖已占用号;之后主屏标题为该名且不再划掉;om p.55)','configuration','agent',{'slot':1,'name':'PAH-01'},['method.library','method.name','method.modified']), 'method.open':(SLOT_ONLY,obj({'slot':INT(1,100),'name':TEXT}),['panel','pump','heater_lift'],'打开方法表中的方法作为当前方法(与method.configure同样的前提:装样与首次运行之前;om p.57)','configuration','agent',{'slot':1},['method.configured','thermal.target_k','method.current','method.name','method.modified']), 'method.delete':(SLOT_ONLY,obj({'slot':INT(1,100)}),['panel'],'删除方法表中的一个方法(当前方法不变;om p.27)','configuration','agent',{'slot':1},['method.library']), 'thermal.set_eco_mode':(obj({'enabled':BOOL}),obj({'enabled':BOOL}),['heater_lift'],'EcoMode:下一次萃取结束后自动关加热;关机再开机自动取消(om p.45)','device_command','agent',{'enabled':True},['thermal.eco_mode']), 'acquisition.skip':(obj({}),obj({'stage':TEXT}),['pump','media_valve','outlet_valve'],'SKIP:跳过当前萃取步骤(Hold→排液、溶剂冲洗→氮吹;氮吹在至少60 s安全期且压力≤1 bar后才可跳到结束;om p.28、58)','device_command','agent',{},['cycle.stage','cycle.stage_elapsed_s']), 'acquisition.halt':(obj({}),obj({'phase':PHASE,'stage':TEXT}),['pump','media_valve','outlet_valve','heater_lift','collection_rack'],'第三次按STOP:立即停止,各组件停在当时位置(压力、液体与升降架保持;之后只能用服务菜单手动泄压、降架;om p.26、59)','device_command','agent',{},['cycle.phase','cycle.stage']), 'leak_test.configure':(LEAK,obj({'settings':FREE}),['panel'],'检漏参数(上次所用值保存在仪器中):温度、压力、四溶剂比例、保持时间、冲洗去向(瓶/废液)、氮吹时间(om p.41-43)','configuration','agent',{'hold_s':240.},['leak_test.settings']), 'leak_test.start':(obj({'start_anyway':BOOL},optional=('start_anyway',)),STATUS_OUT,['pump','heater_lift','collection_rack','outlet_valve']+SENSORS,'检漏(功能键START,不是绿色START):密封、氮气7 bar气密检查、泵入溶剂升到设定压力、关阀保持观察各位压力、排液与氮吹、降架;结果按手册判据(各位差≤15 bar、≥95 %设定)给出(om p.41-43)','device_command','agent',{},['leak_test.status','service.counters']), 'leak_test.stop':(obj({}),STATUS_OUT,['outlet_valve'],'检漏中按SKIP:提前结束,出液阀打开排液、氮吹,测得压力保留在屏上(om p.42)','device_command','agent',{},['leak_test.status']), 'flush.configure':(FLUSH,obj({'settings':FREE}),['panel'],'冲洗参数:溶剂冲洗时间、去向(废液/收集瓶)、流量1–50 mL/min、氮吹时间、四溶剂比例(om p.44-45)','configuration','agent',{'flush_into':'waste'},['flush.settings']), 'flush.start':(obj({}),STATUS_OUT,['pump','mixer','media_valve','outlet_valve','heater_lift'],'冲洗(功能键START):密封、气密检查池是否在位、按设定总流量冲洗激活位置(停用位置不降低流量)、氮吹、降架(om p.44-45)','device_command','agent',{},['flush.status']), 'flush.stop':(obj({}),STATUS_OUT,['pump','heater_lift'],'冲洗菜单中按STOP:停止冲洗,泵停、降架(池内残液保留;om p.45)','device_command','agent',{},['flush.status']), 'flow_test.configure':(FLOW,obj({'settings':FREE}),['panel'],'流动测试参数:去向、溶剂口1–4、位置1–6(om p.86)','configuration','agent',{'position':1},['flow_test.settings']), 'flow_test.start':(obj({}),STATUS_OUT,['pump']+POSITIONS+SENSORS,'流动测试:泵以50 mL/min经所选位置送入空池并排出,显示背压与时间(未堵约3 bar,手册上限8 bar);须先用LIFT手动关闭池与瓶升降架(om p.86-87)','device_command','agent',{},['flow_test.status']), 'flow_test.stop':(obj({}),STATUS_OUT,['pump'],'停止流动测试','device_command','agent',{},['flow_test.status']), 'pump.run':(obj({'enabled':BOOL,'flow_m3_s':number('m^3/s',1*MLMIN,50*MLMIN)},optional=('flow_m3_s',)),obj({'pump':FREE}),['pump'],'服务菜单泵:独立于方法以1–50 mL/min运行(实际值收敛到设定);必须有通路(溶剂阀、介质阀溶剂位、位置阀、出液阀),否则泵压过高(Error 51)停泵(om p.85)','device_command','agent',{'enabled':True,'flow_m3_s':10*MLMIN},['service.pump']), 'valve.set':(obj({'valve':{'type':'string','enum':VALVES},'open':BOOL}),obj({'valves':FREE}),['mixer','media_valve','outlet_valve']+POSITIONS,'服务菜单阀门:溶剂阀1–4、介质旋转阀(溶剂/氮气)、位置阀1–6、出液旋转阀(收集瓶/废液),可单开单关或全开全关(om p.84);开位置阀与出液阀可手动泄压','device_command','agent',{'valve':'solvent_1','open':True},['service.valves']), 'valve.calibrate':(obj({'valve':{'type':'string','enum':['media','outlet']}}),obj({'valves':FREE}),['media_valve','outlet_valve'],'旋转阀回到定义的初始位置(关闭;om p.83-84)','device_command','agent',{'valve':'media'},['service.valves']), 'pressure.calibrate':(obj({}),obj({'sensors':FREE}),['divider']+SENSORS,'压力传感器校零:把七个传感器当前读数记为0 bar(必须先打开加热块与位置阀使仪器不带压,否则零点被记错;om p.85)','device_command','agent',{},['pressure.sensors']), 'sensor.configure_error':(obj({'sensor':INT(0,6),'offset_pa':number('Pa',-2e6,2e6)}),obj({'sensors':FREE}),['divider']+SENSORS,'评测者:压力传感器偏差(0为泵压,1–6为位置;默认0即理想;之后由校零修正)','configuration','evaluator',{'sensor':1,'offset_pa':0.},['pressure.sensors']), 'seal.configure_leak':(obj({'position':INT(1,6),'leak_pa_s':number('Pa/s',0,1e6)}),obj({'position':INT(1,6),'leak_pa_s':number('Pa/s',0)}),[f'lower_seal_{i}' for i in range(6)],'评测者:某位杯形密封的泄漏率(默认0即密封完好;检漏保持阶段该位压力按此下降)','configuration','evaluator',{'position':1,'leak_pa_s':0.},['leak_test.status']), 'lift.move':(obj({'lift':{'type':'string','enum':['cell','vial']},'direction':{'type':'string','enum':['up','down','stop']}}),obj({'lifts':FREE}),['heater_lift','collection_rack'],'服务菜单:池升降(加热块)或瓶升降(收集架)上升/下降/停止;保护屏未关不动(Error 10),加热块不在中位不动(Error 9);带压降下加热块会泄压喷出池内液体(om p.88)','device_command','agent',{'lift':'cell','direction':'up'},['service.lifts','heater.lift_m','rack.lift_m']), 'service.reset_current_max':(obj({}),obj({'counters':FREE}),['heater_lift','collection_rack'],'运行时间页Reset:清除升降电机最大电流记录(om p.88)','device_command','agent',{},['service.counters']), 'fan.set':(obj({'fan':{'type':'string','enum':['extraction','electronic']},'percent':INT(0,100)}),obj({'fans':FREE}),['rear_fan','tower_fan'],'风扇功率(出厂30 %;手册不建议改,会影响加热块温度;om p.88)','device_command','agent',{'fan':'extraction','percent':30},['service.fans']), 'settings.configure':(obj({'key':{'type':'string','enum':list(SETTINGS)},'value':{'anyOf':[TEXT,{'type':'number','x-unit':'1'},BOOL]}}),obj({'settings':FREE}),['panel'],'仪器设定:语言、显示对比度、按键蜂鸣、结束蜂鸣、开机预热询问(om p.40)','configuration','agent',{'key':'preheat_demand','value':True},['device.settings']), 'solvents.set_name':(obj({'index':INT(1,20),'name':TEXT}),obj({'solvents':{'type':'array','items':TEXT}}),['panel'],'溶剂表(20条)改名或新增;空名删除该条(om p.38-39)','configuration','agent',{'index':11,'name':'Chlorobenzene'},['solvents.list']), 'solvents.load_default':(obj({}),obj({'solvents':{'type':'array','items':TEXT}}),['panel'],'DEFAULT:前10条恢复为出厂溶剂表,011–020不变(om p.39)','configuration','agent',{},['solvents.list']), 'vials.exchange':(obj({'gripper_confirmed':BOOL}),obj({'exchanged':BOOL}),['collection_rack']+[f'collection_vial_{i}' for i in range(6)],'宿主换收集瓶(瓶架降下时;换瓶暂停或运行结束后):取走瓶中萃取液,放入空瓶(om p.54)','configuration','evaluator',{'gripper_confirmed':True},['truth.removed_target_kg','truth.removed_solvent_m3','truth.extract_solvent_m3']), 'cell.insert_empty':(obj({'position':INT(1,6),'cell_volume_m3':CELL_ENUM,'gripper_confirmed':BOOL}),obj({'occupancy':{'type':'array','items':nullable(TEXT)}}),['heater_lift']+CELLS,'宿主放入空萃取池(检漏、冲洗、流动测试与停用位置用;开屏抽块,夹具确认;om p.41、44、49)','configuration','evaluator',{'position':1,'cell_volume_m3':20e-6,'gripper_confirmed':True},['cells.occupancy']), 'cell.remove_empty':(obj({'position':INT(1,6),'gripper_confirmed':BOOL}),obj({'occupancy':{'type':'array','items':nullable(TEXT)}}),['heater_lift']+CELLS,'宿主取出空池(不带压、开屏抽块;池内残液随池取走)','configuration','evaluator',{'position':1,'gripper_confirmed':True},['cells.occupancy','truth.removed_solvent_m3'])} DEVICE_ERRORS={'NO_POSITION_SELECTED':'没有激活位置(Error 58)','SHIELD_OPEN':'保护屏未关(Error 10)','HEATER_NOT_IN_POSITION':'加热块不在中位(Error 9)', 'HEATER_TEMPERATURE_OUT_OF_RANGE':'加热块温度与设定差超过30 °C(Error 2)','HEATER_TOO_HOT':'加热块比设定高3 °C以上,须确认仍要开始(Error 3)', 'PUMP_PRESSURE_TOO_HIGH':'泵对着关闭的阀运行(Error 51)','NO_CELL':'所选位置没有萃取池(Error 45–50)','LIFT_OPEN':'池或瓶升降架未关闭','SLOT_EMPTY':'方法表该号为空', 'SKIP_NOT_AVAILABLE':'当前步骤不能跳过','RATIO_SUM':'溶剂比例之和不是100 %','SETTING_INVALID':'设定值不在范围或选项内','NAME_INVALID':'名称为空、超过16字符或含不可输入字符'} NEW_PRE={'positions.set':('不在萃取/检漏/冲洗过程中',['cycle.phase','cycle.stage']),'method.open':('与method.configure相同:装样与首次运行之前,方法完整且通过液相检查',['sample.configured','cycle.phase']), 'method.save':('名称1–16个可输入字符',[]),'thermal.set_eco_mode':('通电',['power.enabled']),'acquisition.skip':('萃取运行中且处于Hold、溶剂冲洗或(≥60 s且压力≤1 bar的)氮吹',['cycle.stage','cycle.stage_elapsed_s','pressure.max_gauge_pa']), 'acquisition.halt':('萃取过程已开始且未结束/未急停',['cycle.stage']),'leak_test.start':('通电、无萃取过程、屏关、加热块中位、有激活位置;加热块温度与检漏温度差≤30 °C,高于3 °C以上须start_anyway',['power.enabled','shield.lift_m','drawer.extension_m','positions.active','thermal.indicated_k']), 'leak_test.stop':('检漏处于气密、升压或保持阶段',['leak_test.status']),'flush.start':('通电、无萃取过程、屏关、加热块中位、有激活位置',['power.enabled','shield.lift_m','drawer.extension_m','positions.active']), 'flush.stop':('冲洗进行中',['flush.status']),'flow_test.start':('通电、空闲、池与瓶升降架已关闭、所选位置有池',['power.enabled','heater.lift_m','rack.lift_m','cells.occupancy']),'flow_test.stop':('流动测试进行中',['flow_test.status']), 'pump.run':('通电、空闲;开泵时必须有通路',['power.enabled','service.valves']),'valve.set':('通电、萃取未在运行、无检漏/冲洗/流动测试',['power.enabled','cycle.phase']),'valve.calibrate':('通电、空闲',['power.enabled']), 'pressure.calibrate':('通电、空闲(零点记为当前读数)',['power.enabled']),'lift.move':('通电、空闲;上升须屏关(池升降另需加热块中位)',['power.enabled','shield.lift_m','drawer.extension_m']), 'vials.exchange':('瓶架降下、萃取未在运行',['rack.lift_m','cycle.phase']),'cell.insert_empty':('屏全开、加热块抽出、该位空、夹具确认',['shield.lift_m','drawer.extension_m','cells.occupancy']), 'cell.remove_empty':('屏全开、加热块抽出、该位为空池、不带压、夹具确认',['shield.lift_m','drawer.extension_m','cells.occupancy'])} NEW_CAP_ERRORS={'positions.set':['BUSY','PRECONDITION_FAILED'],'method.save':['NAME_INVALID'],'method.open':['SLOT_EMPTY','PRECONDITION_FAILED','LIQUID_PHASE_GUARD','BUSY'],'method.delete':['SLOT_EMPTY'], 'thermal.set_eco_mode':['PRECONDITION_FAILED'],'acquisition.skip':['SKIP_NOT_AVAILABLE'],'acquisition.halt':['PRECONDITION_FAILED'],'leak_test.configure':['BUSY'], 'leak_test.start':['BUSY','PRECONDITION_FAILED','NO_POSITION_SELECTED','SHIELD_OPEN','HEATER_NOT_IN_POSITION','HEATER_TEMPERATURE_OUT_OF_RANGE','HEATER_TOO_HOT','RATIO_SUM'], 'leak_test.stop':['PRECONDITION_FAILED'],'flush.configure':['BUSY'],'flush.start':['BUSY','PRECONDITION_FAILED','NO_POSITION_SELECTED','SHIELD_OPEN','HEATER_NOT_IN_POSITION','RATIO_SUM'], 'flush.stop':['PRECONDITION_FAILED'],'flow_test.configure':['BUSY'],'flow_test.start':['BUSY','PRECONDITION_FAILED','LIFT_OPEN','NO_CELL'],'flow_test.stop':['PRECONDITION_FAILED'], 'pump.run':['BUSY','PRECONDITION_FAILED','PUMP_PRESSURE_TOO_HIGH'],'valve.set':['BUSY','PRECONDITION_FAILED'],'valve.calibrate':['BUSY','PRECONDITION_FAILED'],'pressure.calibrate':['BUSY','PRECONDITION_FAILED'], 'sensor.configure_error':[],'seal.configure_leak':[],'lift.move':['BUSY','PRECONDITION_FAILED','SHIELD_OPEN','HEATER_NOT_IN_POSITION'],'service.reset_current_max':[],'fan.set':['PRECONDITION_FAILED'], 'settings.configure':['SETTING_INVALID'],'solvents.set_name':['NAME_INVALID'],'solvents.load_default':[],'vials.exchange':['PRECONDITION_FAILED'],'cell.insert_empty':['PRECONDITION_FAILED'],'cell.remove_empty':['PRECONDITION_FAILED']} CHANGES_PROCESS={'fan.set','thermal.set_eco_mode','thermal.preheat','valve.set','valve.calibrate','pump.run','lift.move','pressure.calibrate'} # caller rules RUN_OK={'power.set','acquisition.stop','acquisition.abort','acquisition.skip','acquisition.halt','method.save','method.delete','settings.configure','solvents.set_name','solvents.load_default', 'sensor.configure_error','seal.configure_leak','thermal.set_eco_mode','leak_test.stop','flush.stop','flow_test.stop','fan.set','service.reset_current_max'} STAGE_TEXT={'standby':'Ready','sealing':'Close lift','tightness':'Tightness','fill':'Fill','heatup_1':'Heat up','heatup_2':'Heat up','heatup_3':'Heat up','hold':'Hold', 'discharge':'Discharge','solvent_flush':'Flush solv.','nitrogen_flush':'Flush gas','release':'Open lift','complete':'Ready','vial_change':'Vial change','halted':'Stop', 'pump':'Pump','solvent':'Flush solv.','gas':'Flush gas','running':'Running'} def _name_ok(name,empty=False): return isinstance(name,str) and (bool(name.strip()) or empty) and len(name)<=16 and set(name)<=NAME_CHARS class _E916Device: """State and commands of the E-916 firmware functions reached from the menus (mixed into BuchiSpeedextractoreRuntime).""" def _device_init(self): self.positions=None;self.blanks={};self.method_name='DEFAULT';self.method_modified=False;self.library={};self.preheat_k=None;self.eco=False self.aux=None;self.aux_last={};self.leak=copy.deepcopy(LEAK_DEFAULT);self.flush_set=copy.deepcopy(FLUSH_DEFAULT);self.flow_set=copy.deepcopy(FLOW_DEFAULT) self.valves=dict(solvent=[False]*4,media=None,position=[False]*6,outlet=None);self.calibrations=dict(media=0,outlet=0) self.pump=dict(on=False,set_m3_s=1*MLMIN,actual_m3_s=0.);self.pump_p=0.;self.lift_cmd=dict(cell=None,vial=None);self.current_max=dict(cell=0.,vial=0.) self.fans=dict(extraction=30,electronic=30);self.counters=dict(extractions=0,leak_tests=0,operating_s=0.,heater_s=0.,max_temperature_k=None,max_pressure_pa=0.) self.sensor_error=[0.]*7;self.sensor_zero=[0.]*7;self.seal_leak=[0.]*6;self.settings={k:v['default'] for k,v in SETTINGS.items()} self.solvent_list=list(DEFAULT_SOLVENTS)+['']*10;self.notice=None;self._notices=0;self.end_beeps=0;self.exchanged=[0.]*4;self.removed_blank=[0.]*4;self.power_epoch=0 # ---- cells and positions def _free(self,c):return c['volume'] if c.get('blank') else c['spec']['cell_volume_m3']-c['spec']['matrix_solid_volume_m3'] def _records(self): out={i:c for i,c in self.blanks.items() if not c['removed']};out.update({i:c for i,c in self.cells.items() if not c['removed']});return out def _active(self): if self.positions is None:return sorted(i for i,c in self.cells.items() if not c['removed']) # 1.0 API: every loaded sample cell takes part return [i for i,on in enumerate(self.positions) if on] def _run_cells(self): r=self._records();return [r[i] for i in self._active() if i in r] def _missing(self): r=self._records();return [i for i in self._active() if i not in r] def _occupancy(self): r=self._records();return [None if i not in r else ('empty' if r[i].get('blank') else 'sample') for i in range(6)] def _notify(self,code): self._notices+=1;self.notice=dict(id=self._notices,code=code,time_s=self.time_s) def _in_operation(self): return self._operation_count>0 and self.stage not in ('complete','standby') def _idle(self): return self.phase!='running' and self.aux is None # ---- method helpers def _full_method(self): m=copy.deepcopy(self.method or DEFAULT_METHOD) m.setdefault('vial','unspecified');m.setdefault('cell_volume_m3',None);m.setdefault('solvent_names',list(DEFAULT_METHOD['solvent_names'])) m.setdefault('cycle_steps',[dict(hold_s=m['hold_s'],discharge_s=m['discharge_s'],vial_change=False,port=0) for _ in range(m['cycles'])]);return m def _step(self,key): steps=(self.method or {}).get('cycle_steps') return steps[min(max(self.cycle,1),len(steps))-1][key] if steps else self.method[key] def _fractions(self): steps=(self.method or {}).get('cycle_steps') port=steps[min(max(self.cycle,1),len(steps))-1]['port'] if steps else 0 return [1. if i==port-1 else 0. for i in range(4)] if port else self.method['solvent_fractions'] def _cell_volume(self,cells): if self.method and self.method.get('cell_volume_m3'):return self.method['cell_volume_m3'] c=cells[0] if cells else next(iter(self.cells.values())) return c['volume'] if c.get('blank') else c['spec']['cell_volume_m3'] def _vial_change_due(self,cells): steps=self.method.get('cycle_steps') if steps and steps[min(self.cycle,len(steps))-1]['vial_change']:return True cap=VIALS.get(self.method.get('vial')) # Error 4: the declared vial would overflow in the next cycle return bool(cap) and any(sum(c['vial'])+self._free(c)>cap+1e-12 for c in cells) def _overflow_possible(self): m=self._full_method();cap=VIALS.get(m['vial']);cell=m['cell_volume_m3'] if not cap or not cell:return False n=0 for s in m['cycle_steps'][:m['cycles']]: n+=1 if n*cell>cap+1e-12:return True if s['vial_change']:n=0 return False def _check_method_extras(self,a): n=a['cycles'] if 'cycle_steps' in a: if len(a['cycle_steps'])!=n:raise ActionRejected('PRECONDITION_FAILED') for s in a['cycle_steps']: if isinstance(s['port'],bool) or not isinstance(s['port'],int) or not 0<=s['port']<=4:raise ActionRejected('INVALID_ARGUMENT') if s['port'] and a['pressure_gauge_pa']/3+101325<1.1*self.saturation_pressure(a['temperature_k'],[1. if i==s['port']-1 else 0. for i in range(4)]):raise ActionRejected('LIQUID_PHASE_GUARD') if 'solvent_names' in a and any(len(x)>20 for x in a['solvent_names']):raise ActionRejected('INVALID_ARGUMENT') # ---- commands (called from BuchiSpeedextractoreRuntime.invoke) def _device_invoke(self,cap,a): if cap=='positions.set': if self.aux or self._in_operation():raise ActionRejected('BUSY' if self.phase=='running' or self.aux else 'PRECONDITION_FAILED') if ('active' in a)==('position' in a) or ('position' in a)!=('enabled' in a):raise ActionRejected('INVALID_ARGUMENT') act=list(a['active']) if 'active' in a else list(self.positions or [i in self._active() for i in range(6)]) if 'position' in a:act[a['position']-1]=a['enabled'] self.positions=act;return dict(active=list(act)) if cap=='method.save': if not _name_ok(a['name']):raise ActionRejected('NAME_INVALID') self.library[a['slot']]=dict(name=a['name'],method=copy.deepcopy(self.method or DEFAULT_METHOD));self.method_name=a['name'];self.method_modified=False return dict(slot=a['slot'],name=a['name']) if cap=='method.open': e=self.library.get(a['slot']) if e is None:raise ActionRejected('SLOT_EMPTY') self.invoke('method.configure',**e['method']);self.method_name=e['name'];self.method_modified=False;return dict(slot=a['slot'],name=e['name']) if cap=='method.delete': if a['slot'] not in self.library:raise ActionRejected('SLOT_EMPTY') del self.library[a['slot']];return dict(slot=a['slot']) if cap=='thermal.set_eco_mode': if not self.powered:raise ActionRejected('PRECONDITION_FAILED') self.eco=a['enabled'];return dict(enabled=self.eco) if cap=='acquisition.skip': if self.phase!='running' or self.stage not in ('hold','solvent_flush','nitrogen_flush') or (self.stage=='nitrogen_flush' and (self.stage_elapsed<60 or self._measured_max()>BAR)):raise ActionRejected('SKIP_NOT_AVAILABLE') self._next({'hold':'discharge','solvent_flush':'nitrogen_flush','nitrogen_flush':'release'}[self.stage]);return dict(stage=self.stage) if cap=='acquisition.halt': if not self._operation_count or self.stage in ('standby','complete','halted'):raise ActionRejected('PRECONDITION_FAILED') self.phase='cancelled';self.aborting=False;self._next('halted');return dict(phase=self.phase,stage=self.stage) if cap in ('leak_test.configure','flush.configure','flow_test.configure'): if not a:raise ActionRejected('INVALID_ARGUMENT') for k in ('port','position'): if k in a and (isinstance(a[k],bool) or not isinstance(a[k],int)):raise ActionRejected('INVALID_ARGUMENT') store={'leak_test.configure':self.leak,'flush.configure':self.flush_set,'flow_test.configure':self.flow_set}[cap] if self.aux and self.aux['settings'] is store:raise ActionRejected('BUSY') store.update(copy.deepcopy(a));return dict(settings=copy.deepcopy(store)) if cap in ('leak_test.start','flush.start'): self._check_aux_start() if abs(sum((self.leak if cap=='leak_test.start' else self.flush_set)['solvent_fractions'])-1)>1e-9:raise ActionRejected('RATIO_SUM') if cap=='leak_test.start': dt=self.temperature-self.leak['temperature_k'] if abs(dt)>30:raise ActionRejected('HEATER_TEMPERATURE_OUT_OF_RANGE') if dt>3 and not a.get('start_anyway'):raise ActionRejected('HEATER_TOO_HOT') self.counters['leak_tests']+=1 kind='leak_test' if cap=='leak_test.start' else 'flush' self.aux=dict(kind=kind,stage='sealing',stage_elapsed=0.,elapsed=0.,settings=self.leak if kind=='leak_test' else self.flush_set,fault=None,result=None,hold_elapsed=0., owner=self.__dict__.get('_caller')) self.valves=dict(solvent=[False]*4,media=None,position=[False]*6,outlet=None);self.pump['on']=False return dict(status=self._aux_status()) if cap=='leak_test.stop': if not self.aux or self.aux['kind']!='leak_test' or self.aux['stage'] not in ('tightness','pump','hold'):raise ActionRejected('PRECONDITION_FAILED') if self.aux['stage']=='hold':self._leak_result(stopped=True) self._aux_next('discharge');return dict(status=self._aux_status()) if cap=='flush.stop': if not self.aux or self.aux['kind']!='flush':raise ActionRejected('PRECONDITION_FAILED') self.aux['stopped']=True;self._aux_next('release');return dict(status=self._aux_status()) if cap=='flow_test.start': if not self.powered or not self.plant:raise ActionRejected('PRECONDITION_FAILED') if self.phase=='running' or self.aux:raise ActionRejected('BUSY') if self._in_operation():raise ActionRejected('PRECONDITION_FAILED') if self.heater<.035-1e-9 or self.rack<.035-1e-9:raise ActionRejected('LIFT_OPEN') if self.flow_set['position']-1 not in self._records():raise ActionRejected('NO_CELL') self.aux=dict(kind='flow_test',stage='running',stage_elapsed=0.,elapsed=0.,settings=self.flow_set,fault=None,result=None,owner=self.__dict__.get('_caller'));self.pump['on']=False return dict(status=self._aux_status()) if cap=='flow_test.stop': if not self.aux or self.aux['kind']!='flow_test':raise ActionRejected('PRECONDITION_FAILED') self._aux_done();return dict(status=self._aux_status()) if cap=='pump.run': self._check_service() if 'flow_m3_s' in a:self.pump['set_m3_s']=a['flow_m3_s'] if a['enabled'] and not self._pump_path():raise ActionRejected('PUMP_PRESSURE_TOO_HIGH') self.pump['on']=a['enabled'] if not a['enabled']:self.pump['actual_m3_s']=0. return dict(pump=copy.deepcopy(self.pump)) if cap=='valve.set': self._check_service();v,op=a['valve'],a['open'];V=self.valves if v=='solvent_all':V['solvent']=[op]*4 elif v=='position_all':V['position']=[op]*6 elif v.startswith('solvent_'):V['solvent'][int(v[-1])-1]=op elif v.startswith('position_'):V['position'][int(v[-1])-1]=op elif v.startswith('media_'):V['media']=v[6:] if op else (None if V['media']==v[6:] else V['media']) # rotary: one path at a time else:V['outlet']=v[7:] if op else (None if V['outlet']==v[7:] else V['outlet']) if self.pump['on'] and not self._pump_path():self.pump.update(on=False,actual_m3_s=0.);self._notify('pump_pressure_too_high') return dict(valves=copy.deepcopy(V)) if cap=='valve.calibrate': self._check_service();self.valves[a['valve']]=None;self.calibrations[a['valve']]+=1 if self.pump['on'] and not self._pump_path():self.pump.update(on=False,actual_m3_s=0.);self._notify('pump_pressure_too_high') return dict(valves=copy.deepcopy(self.valves)) if cap=='pressure.calibrate': self._check_service();self.sensor_zero=self._raw_pressures();return dict(sensors=self._sensors()) if cap=='sensor.configure_error': self.sensor_error[a['sensor']]=float(a['offset_pa']);return dict(sensors=self._sensors()) if cap=='seal.configure_leak': self.seal_leak[a['position']-1]=float(a['leak_pa_s']);return dict(position=a['position'],leak_pa_s=float(a['leak_pa_s'])) if cap=='lift.move': self._check_service() if a['direction']=='up': if self.shield>1e-9:raise ActionRejected('SHIELD_OPEN') if a['lift']=='cell' and self.drawer>1e-9:raise ActionRejected('HEATER_NOT_IN_POSITION') self.lift_cmd[a['lift']]=None if a['direction']=='stop' else a['direction'];return dict(lifts=self._lifts()) if cap=='service.reset_current_max': self.current_max=dict(cell=0.,vial=0.);return dict(counters=self._counters()) if cap=='fan.set': if not self.powered:raise ActionRejected('PRECONDITION_FAILED') self.fans[a['fan']]=a['percent'];return dict(fans=dict(self.fans)) if cap=='settings.configure': f=SETTINGS[a['key']];v=a['value'] ok=(isinstance(v,bool) if f['type']=='bool' else v in f['options'] if f['type']=='enum' else (not isinstance(v,bool) and isinstance(v,(int,float)) and float(v).is_integer() and f['min']<=v<=f['max'])) if not ok:raise ActionRejected('SETTING_INVALID') self.settings[a['key']]=int(v) if f['type']=='int' else v;return dict(settings=dict(self.settings)) if cap=='solvents.set_name': if len(a['name'])>20 or not set(a['name'])<=NAME_CHARS:raise ActionRejected('NAME_INVALID') self.solvent_list[a['index']-1]=a['name'].strip();return dict(solvents=list(self.solvent_list)) if cap=='solvents.load_default': self.solvent_list[:10]=list(DEFAULT_SOLVENTS);return dict(solvents=list(self.solvent_list)) if cap=='vials.exchange': if self.rack>1e-9 or self.phase=='running' or not a['gripper_confirmed']:raise ActionRejected('PRECONDITION_FAILED') for c in list(self.cells.values())+list(self.blanks.values()): for i in range(4):self.exchanged[i]+=c['vial'][i];c['vial'][i]=0. c['collected']+=c['extract'];c['extract']=0. return dict(exchanged=True) if cap=='cell.insert_empty': i=a['position']-1 if self.shield<.179 or self.drawer<.159 or not a['gripper_confirmed'] or i in self._records():raise ActionRejected('PRECONDITION_FAILED') self.blanks[i]=dict(blank=True,volume=a['cell_volume_m3'],liquid=[0.]*4,vial=[0.]*4,pressure=0.,dissolved=0.,extract=0.,wasted=0.,collected=0.,removed=False) return dict(occupancy=self._occupancy()) if cap=='cell.remove_empty': i=a['position']-1;c=self.blanks.get(i) if self.shield<.179 or self.drawer<.159 or not a['gripper_confirmed'] or c is None or c['removed'] or c['pressure']>BAR:raise ActionRejected('PRECONDITION_FAILED') for k in range(4):self.removed_blank[k]+=c['liquid'][k]+c['vial'][k] del self.blanks[i];return dict(occupancy=self._occupancy()) raise ActionRejected('UNKNOWN_CAPABILITY') def _check_service(self): if not self.powered or not self.plant:raise ActionRejected('PRECONDITION_FAILED') if self.phase=='running' or self.aux:raise ActionRejected('BUSY') def _check_aux_start(self): if not self.powered or not self.plant:raise ActionRejected('PRECONDITION_FAILED') if self.phase=='running' or self.aux:raise ActionRejected('BUSY') if self._in_operation():raise ActionRejected('PRECONDITION_FAILED') if self.shield>1e-9:raise ActionRejected('SHIELD_OPEN') if self.drawer>1e-9:raise ActionRejected('HEATER_NOT_IN_POSITION') if not self._active():raise ActionRejected('NO_POSITION_SELECTED') # ---- supplies (aux and service paths: shortfalls do not fail the extraction) def _supply(self,c,vol,f): v=min([vol]+[self.reservoir[i]/x for i,x in enumerate(f) if x>0]) for i,x in enumerate(f):self.reservoir[i]-=v*x;c['liquid'][i]+=v*x return v+1e-15>=vol def _gas_use(self,n,h): req=self.plant['nitrogen_mol_s_per_cell']*n*h;x=min(self.nitrogen,req);self.nitrogen-=x;self.nitrogen_out+=x;return x+1e-12>=req def _drain_to(self,c,vol,holdup,target): if target=='waste': v=sum(c['liquid']);x=min(max(0.,v-holdup),vol);frac=x/v if v else 0.;m=c['dissolved']*frac;c['dissolved']-=m;c['wasted']+=m for i in range(4):y=c['liquid'][i]*frac;c['liquid'][i]-=y;self.waste[i]+=y return True v=sum(c['liquid']);x=min(max(0.,v-holdup),vol);space=self.plant['vial_capacity_m3']-sum(c['vial']);ok=x<=space+1e-15;x=min(x,max(0.,space)) frac=x/v if v else 0.;m=c['dissolved']*frac;c['dissolved']-=m;c['extract']+=m for i in range(4):y=c['liquid'][i]*frac;c['liquid'][i]-=y;c['vial'][i]+=y return ok def _spill(self,c): """The cell lift opens on a pressurised cell (no safety checks in the service menu): the content sprays out (to the waste ledger).""" self._drain_to(c,sum(c['liquid']),0.,'waste');c['pressure']=0. # ---- leak test / flush / flow test def _aux_next(self,stage): self.aux['stage']=stage;self.aux['stage_elapsed']=0. def _aux_fail(self,code): self.aux['fault']=code;self._notify(code);self._aux_next('release' if self.aux['kind']!='flow_test' else 'done') if self.aux['kind']=='flow_test':self._aux_done() def _aux_done(self): a=self.aux;self.aux_last[a['kind']]=self._aux_status();self.aux=None if self.settings['beep_end']:self.end_beeps+=1 def _aux_status(self,a=None): a=a or self.aux if a is None:return dict(active=False) return dict(active=True,kind=a['kind'],stage=a['stage'],stage_elapsed_s=a['stage_elapsed'],elapsed_s=a['elapsed'],fault=a['fault'],result=copy.deepcopy(a['result']), hold_elapsed_s=a.get('hold_elapsed',0.),pressures_pa=self._readings()[1:],pump_pressure_pa=self._readings()[0]) def _leak_result(self,stopped=False): rd=self._readings();act=self._active();pos=[rd[1+i] for i in act];setp=self.leak['pressure_gauge_pa'] diff=max(pos)-min(pos) if pos else 0.;low=min(pos+[rd[0]])/setp if pos else 0. self.aux['result']=dict(positions=[i+1 for i in act],pressures_pa=pos,overall_pa=rd[0],max_pa=max(pos) if pos else 0.,max_difference_pa=diff,min_fraction_of_set=low, passed=bool(pos) and diff<=15*BAR+1e-6 and low>=.95-1e-12,completed=not stopped) # om p.43 criteria (first two) def _aux_tick(self,h): a=self.aux;p=self.plant;s=a['settings'];cells=self._run_cells();n=max(1,len(cells)) a['elapsed']+=h;a['stage_elapsed']+=h;st=a['stage'] if a['kind']=='flow_test': c=self._records().get(s['position']-1);v=50*MLMIN*h;f=[1. if i==s['port']-1 else 0. for i in range(4)] if c is None:return self._aux_fail('position_pressure_too_low:'+str(s['position'])) ok=self._supply(c,v,f);self._drain_to(c,v,0.,s['flush_into']);c['pressure']=BACK_PA_PER_M3S*50*MLMIN;self.pump_p=c['pressure'] if not ok:self._aux_fail('solvent_supply_empty') return if st=='sealing': self.heater=min(.035,self.heater+.01*h);self.rack=min(.035,self.rack+.01*h) if self.heater>=.035 and self.rack>=.035:self._aux_next('tightness') elif st=='tightness': # nitrogen pre-pressure 7 bar checks that the cells are there if not self._gas_use(n,h):return self._aux_fail('nitrogen_supply_empty') for c in cells:c['pressure']+=(7*BAR-c['pressure'])*-math.expm1(-h/p['pressure_tau_s']) if a['stage_elapsed']>=10: miss=self._missing() if miss:return self._aux_fail('position_pressure_too_low:'+str(miss[0]+1)) self._aux_next('pump' if a['kind']=='leak_test' else 'solvent') elif st=='pump': for c in cells: if not self._supply(c,min(50*MLMIN/6*h,max(0.,self._free(c)-sum(c['liquid']))),s['solvent_fractions']):return self._aux_fail('solvent_supply_empty') if all(abs(sum(c['liquid'])-self._free(c))<1e-12 for c in cells): idx=self._run_indexed() # the pump controls on the position sensors (their error and zero) for i,c in idx:c['pressure']+=(max(0.,s['pressure_gauge_pa']-self._offset(i))-c['pressure'])*-math.expm1(-h/p['pressure_tau_s']) self.pump_p=max(c['pressure'] for c in cells);rd=self._readings() if all(abs(rd[1+i]-s['pressure_gauge_pa'])<1e4 for i,_ in idx):self._aux_next('hold') elif st=='hold': a['hold_elapsed']=a['stage_elapsed'] for i,c in self._records().items(): if i in self._active():c['pressure']=max(0.,c['pressure']-self.seal_leak[i]*h) if a['stage_elapsed']>=s['hold_s']:self._leak_result();self._aux_next('discharge') elif st=='discharge': for c in cells:c['pressure']*=math.exp(-h/p['pressure_tau_s']);self._drain_to(c,p['discharge_m3_s_per_cell']*h,self._free(c)*p['residual_holdup_fraction'],s['flush_into']) if a['stage_elapsed']>=10 and self._measured_max()<=BAR and all(sum(c['liquid'])<=self._free(c)*p['residual_holdup_fraction']+1e-12 for c in cells):self._aux_next('gas') elif st=='solvent': # FLUSH: the set flow is not reduced when positions are off v=s['flow_m3_s']/n*h for c in cells: fill=max(0.,self._free(c)-sum(c['liquid'])) if not self._supply(c,v,s['solvent_fractions']):return self._aux_fail('solvent_supply_empty') self._drain_to(c,max(0.,v-fill),0.,s['flush_into']) if a['stage_elapsed']>=s['solvent_s']:self._aux_next('gas') elif st=='gas': if not self._gas_use(n,h):return self._aux_fail('nitrogen_supply_empty') gas_s=s['gas_flush_s'] if a['kind']=='leak_test' else s['gas_s'] for c in cells:self._drain_to(c,p['discharge_m3_s_per_cell']*h,0.,s['flush_into']);c['pressure']*=math.exp(-h/p['pressure_tau_s']) if a['stage_elapsed']>=gas_s and self._measured_max()<=BAR:self._aux_next('release') elif st=='release': for c in self._records().values(): if c['pressure']>BAR and self.heater<.035:self._spill(c) self.heater=max(0.,self.heater-.01*h);self.rack=max(0.,self.rack-.01*h) if self.heater<=1e-12 and self.rack<=1e-12:self.heater=self.rack=0.;self._aux_done() if self.aux is not None and st=='hold': # position valves closed: the overall pressure drops a little (om p.43) self.pump_p+=(OVERALL_HOLD*s['pressure_gauge_pa']-self.pump_p)*-math.expm1(-h/60.) elif self.aux is not None and st!='pump':self.pump_p*=math.exp(-h/p['pressure_tau_s']) # ---- service functions (instrument idle) def _pump_path(self): V=self.valves;return any(V['solvent']) and V['media']=='solvent' and any(V['position']) and V['outlet'] is not None def _service_tick(self,h): p=self.plant;V=self.valves;recs=self._records();sealed=self.heater>=.035-1e-9 for lift in ('cell','vial'): cmd=self.lift_cmd[lift];attr='heater' if lift=='cell' else 'rack';x=getattr(self,attr) if cmd: nx=min(.035,x+LIFT_SPEED*h) if cmd=='up' else max(0.,x-LIFT_SPEED*h);setattr(self,attr,nx);self.current_max[lift]=max(self.current_max[lift],LIFT_CURRENT_A) if nx in (0.,.035):self.lift_cmd[lift]=None if self.heater<.035-1e-9: for c in recs.values(): if c['pressure']>BAR:self._spill(c) open_pos=[i for i in range(6) if V['position'][i]] if V['outlet'] and sealed: # an open position valve and outlet valve relieve that cell gas=V['media']=='gas' if gas and open_pos and not self._gas_use(len(open_pos),h):self._notify('nitrogen_supply_empty');V['media']=None for i in open_pos: c=recs.get(i) if c is None:continue c['pressure']*=math.exp(-h/p['pressure_tau_s']);self._drain_to(c,p['discharge_m3_s_per_cell']*h,0. if gas else self._free(c)*p['residual_holdup_fraction'],V['outlet']) P=self.pump if P['on']: if not self._pump_path():P.update(on=False,actual_m3_s=0.);self._notify('pump_pressure_too_high');return P['actual_m3_s']+=(P['set_m3_s']-P['actual_m3_s'])*-math.expm1(-h/2.) opn=[i for i in range(4) if V['solvent'][i]];f=[1./len(opn) if i in opn else 0. for i in range(4)];per=P['actual_m3_s']/len(open_pos)*h for i in open_pos: c=recs.get(i) if c is not None and sealed: ok=self._supply(c,per,f);fill=max(0.,self._free(c)-sum(c['liquid']));self._drain_to(c,per,0.,V['outlet']) if not fill else None c['pressure']=BACK_PA_PER_M3S*P['actual_m3_s']/len(open_pos) else: # no cell or lift open: the solvent runs into the instrument tmp=dict(liquid=[0.]*4,dissolved=0.,wasted=0.);ok=self._supply(tmp,per,f);self._drain_to(tmp,per,0.,'waste') if not ok:P.update(on=False,actual_m3_s=0.);self._notify('solvent_supply_empty');break self.pump_p=BACK_PA_PER_M3S*P['actual_m3_s']/max(1,len(open_pos)) else: self.pump_p*=math.exp(-h/p['pressure_tau_s']) # ---- readings and views def _raw_pressures(self): r=self._records();true=[self.pump_p]+[r[i]['pressure'] if i in r else 0. for i in range(6)] return [t+e for t,e in zip(true,self.sensor_error)] def _readings(self): return [x-z for x,z in zip(self._raw_pressures(),self.sensor_zero)] def _offset(self,i): """Reading minus true pressure of the sensor of position i (0-5): evaluator error minus the stored service zero.""" return self.sensor_error[1+i]-self.sensor_zero[1+i] def _measured_max(self): """Highest position pressure as the instrument measures it (sensors 1-6 with error and zero, not below 0): the display, pressure.max_gauge_pa, extraction.measure, the operating-hours peak and the device's own decisions (skip, release, control) use it; _maxp() stays the true cell pressure (physics, host interlocks and the truth slot).""" return max(0.,max(self._readings()[1:])) def _run_indexed(self): r=self._records();return [(i,r[i]) for i in self._active() if i in r] def _sensors(self): return dict(readings_pa=self._readings(),zero_pa=list(self.sensor_zero)) def _lifts(self): return dict(cell=self.heater,vial=self.rack,moving=dict(self.lift_cmd),current_a={k:(LIFT_CURRENT_A if v else 0.) for k,v in self.lift_cmd.items()}) def _counters(self): return dict(self.counters,current_max_a=dict(self.current_max)) def _counters_tick(self,h,heat): c=self.counters if self.powered: c['operating_s']+=h if heat:c['heater_s']+=h c['max_temperature_k']=max(c['max_temperature_k'] or 0.,self.temperature) c['max_pressure_pa']=max(c['max_pressure_pa'],self._measured_max()) def _valve_view(self): """Valves as the STATUS diagram shows them: the automatic sequence while a process runs, else the service-menu states.""" st=self.aux['stage'] if self.aux else (self.stage if self.phase=='running' else None) if st is None:return copy.deepcopy(self.valves) kind=self.aux['kind'] if self.aux else 'extraction';act=self._active() f=self.aux['settings'].get('solvent_fractions',[0.]*4) if self.aux else self._fractions() if self.method else [0.]*4 if kind=='flow_test': s=self.aux['settings'];return dict(solvent=[i==s['port']-1 for i in range(4)],media='solvent',position=[i==s['position']-1 for i in range(6)],outlet=s['flush_into']) liquid=st in ('fill','heatup_1','heatup_2','heatup_3','solvent_flush','pump','solvent');gas=st in ('tightness','nitrogen_flush','gas') into=(self.aux['settings']['flush_into'] if self.aux else ('waste' if (self.method or {}).get('vial')=='waste' else 'vial')) return dict(solvent=[liquid and f[i]>0 for i in range(4)],media='solvent' if liquid else 'gas' if gas else None, position=[i in act and st not in ('hold','sealing','release') for i in range(6)], outlet=into if st in ('discharge','solvent_flush','nitrogen_flush','solvent','gas') else None) def _pumping(self): st=self.aux['stage'] if self.aux else (self.stage if self.phase=='running' else None) return self.pump['on'] or st in ('fill','heatup_1','heatup_2','heatup_3','solvent_flush','pump','solvent','running') def _status_text(self): if not self.powered:return '' if self.aux:return {'leak_test':'Leak test','flush':'Flush','flow_test':'Flow test'}[self.aux['kind']] if self.phase=='failed':return 'Error' if self._operation_count and self.stage not in ('standby','complete'): if self.stage=='halted':return 'Stop' if self.phase=='cancelled':return 'Vial change' if self.stage=='vial_change' else 'Pause' if self.aborting:return 'Abort' return STAGE_TEXT.get(self.stage,self.stage) tgt=self.preheat_k if self.preheat_k is not None else (self.method['temperature_k'] if self.method else None) return 'Preheat' if self.preheat and tgt is not None and abs(self.temperature-tgt)>1 else 'Ready' def _plan(self): """Rough stage plan of the current method for the remaining-time displays (the device also estimates; om p.52).""" m=self._full_method();cells=self._run_cells() or list(self.cells.values());n=max(1,len(cells)) free=max([self._free(c) for c in cells] or [(m['cell_volume_m3'] or 20e-6)*.75]);vol=m['cell_volume_m3'] or (self._cell_volume(cells) if cells else 20e-6) fill=free/(m['pump_total_m3_s']/6);dwell=10*vol/20e-6;plan=[('sealing',0,3.5),('tightness',0,10.)] for k in range(1,m['cycles']+1): s=m['cycle_steps'][k-1];plan+=[('fill',k,fill),('heatup_1',k,dwell),('heatup_2',k,dwell),('heatup_3',k,dwell),('hold',k,s['hold_s']),('discharge',k,max(s['discharge_s'],free*n/(self.plant['discharge_m3_s_per_cell'] if self.plant else 2e-6)/n))] if k0:plan.append(('solvent_flush',m['cycles'],m['solvent_flush_s'])) return plan+[('nitrogen_flush',m['cycles'],m['nitrogen_flush_s']),('release',m['cycles'],3.5)] def _times(self): """(time to the end of the cycle, time to the next vial change, time to the end) in s; None when nothing runs.""" if not (self._operation_count and self.stage not in ('standby','complete','halted')) or self.method is None:return None,None,None plan=self._plan();cyc=max(1,self.cycle) idx=next((j for j,(s,k,_) in enumerate(plan) if s==self.stage and (k==cyc or k==0 or s in ('solvent_flush','nitrogen_flush','release'))),None) if idx is None:return None,None,None rest=[max(0.,plan[idx][2]-self.stage_elapsed)]+[d for _,_,d in plan[idx+1:]];names=[s for s,_,_ in plan[idx:]];cycles=[k for _,k,_ in plan[idx:]] total=sum(rest);end_c=sum(d for d,s,k in zip(rest,names,cycles) if k<=cyc and s not in ('solvent_flush','nitrogen_flush','release','vial_change')) vc=next((sum(rest[:j]) for j,s in enumerate(names) if s=='vial_change' and j>0),None) return end_c,vc,total CAPS={ 'power.set':(obj({'enabled':BOOL}),obj({'enabled':BOOL}),['power_inlet'],'电源;断电关闭主动阀,不消除残压','device_command','agent',{'enabled':True},['power.enabled','cycle.phase','thermal.indicated_k','pressure.max_gauge_pa','thermal.eco_mode','service.pump','service.lifts','leak_test.status','flush.status','flow_test.status']), 'shield.set_lift':(obj({'lift_m':number('m',0,.18)}),obj({'lift_m':number('m',0,.18)}),['shield'],'上推屏;只在非运行、脱压、两升降架降下时移动','device_command','agent',{'lift_m':.18},['shield.lift_m']), 'drawer.set_extension':(obj({'extension_m':number('m',0,.16)}),obj({'extension_m':number('m',0,.16)}),['heater_drawer'],'上推屏后向前抽加热块','device_command','agent',{'extension_m':.16},['drawer.extension_m']), 'plant.configure':(PLANT,obj({'configured':BOOL}),['pump','mixer','nitrogen_inlet','exhaust'],'有限四溶剂/氮气、宿主工程系数;仅首次','configuration','evaluator',EXAMPLE,['plant.configured']), 'method.configure':(METHOD,obj({'configured':BOOL}),['panel','pump','heater_lift'],'温压循环时间、单泵总流量、四溶剂体积分数、氮吹;可选vial(收集瓶60/150/220/240 mL、unspecified、waste)、cell_volume_m3、solvent_names与cycle_steps(各周期保持/排液/换瓶/溶剂口,EDIT METHOD,om p.52-56)','configuration','agent',METHOD_EXAMPLE,['method.configured','thermal.target_k','method.current','method.modified']), 'thermal.preheat':(obj({'temperature_k':number('K',303.15,473.15),'enabled':BOOL},optional=('temperature_k','enabled')),obj({'enabled':BOOL}),['heater_lift'],'装池前预热;step推进,不能装冷池后密封加热;可选temperature_k(PREHEAT菜单的预热温度,缺省跟随方法温度)与enabled=false(OFF,随时可关;带temperature_k只存设定)','device_command','agent',{},['thermal.preheat_enabled','thermal.preheat_target_k']), 'sample.configure':(SAMPLE,obj({'configured':BOOL,'attachment_event':TEXT}),['heater_lift','cell_0','cell_1','cell_2','cell_3','cell_4','cell_5'],'宿主装入干燥/已审查固体;六位置必须同容量','configuration','evaluator',SAMPLE_EXAMPLE,['sample.configured','cells.occupancy']), 'acquisition.start':(obj({}),obj({'phase':PHASE,'operation_id':TEXT}),['pump','media_valve','outlet_valve','heater_lift','collection_rack'],'密封、气密代理、充液、分级升压、保持、排液、最终冲洗/氮吹、解封','device_command','agent',{},['cycle.phase','cycle.stage','service.valves','service.pump']), 'acquisition.stop':(obj({}),obj({'phase':PHASE}),['media_valve','pump'],'暂停/取消主动动作;保留残压/库存,热和传质继续','device_command','agent',{},['cycle.phase']), 'acquisition.abort':(obj({}),obj({'phase':PHASE}),['media_valve','outlet_valve'],'宿主有序终止:排液、氮吹、解封;不是第三次急停固件','device_command','agent',{},['cycle.phase','cycle.stage']), 'extraction.measure':(obj({}),RESULT,['display_digits','pressure_sensor_0'],'仪器读数及阶段:压力为位置传感器读数的最大值(含评测者偏差与服务校零,默认理想);不是校准仪表','query','agent',{},[]), 'product.read':(obj({}),PRODUCT,['collection_rack','heater_lift'],'宿主条件回收率与真实跨仪器参考比值分开','query','evaluator',{},[]), 'reference.lookup':(obj({'substance_id':TEXT}),REFERENCE,['display_digits'],'54真实ASE/Soxtec比较数据,不能当本机绝对回收率','query','agent',{'substance_id':'phenol'},[]), 'sample.unload':(obj({'position':INT(0,5),'sample_id':TEXT,'gripper_confirmed':BOOL}),obj({'unloaded':BOOL,'attachment_event':TEXT}),['heater_lift','collection_rack'],'完整或有序终止后,开屏抽块,用夹具取池','configuration','evaluator',{'position':0,'sample_id':'soil_1','gripper_confirmed':True},['truth.removed_target_kg','cells.occupancy'])} METHOD['properties'].update(METHOD_EXTRA);CAPS.update(DEVICE_CAPS) SLOTS={} def slot(k,s,u,o='derived',v='agent',c='display_digits',w=None):SLOTS[k]=(s,u,o,v,[c],w) slot('power.enabled',BOOL,'1','setpoint',c='power_inlet',w=('power.set','enabled'));slot('shield.lift_m',number('m',0,.18),'m','scene',c='shield',w=('shield.set_lift','lift_m'));slot('drawer.extension_m',number('m',0,.16),'m','scene',c='heater_drawer',w=('drawer.set_extension','extension_m')) for k,c in [('heater.lift_m','heater_lift'),('rack.lift_m','collection_rack')]:slot(k,number('m',0,.035),'m','scene',c=c) for k,s,u in [('plant.configured',BOOL,'1'),('sample.configured',BOOL,'1'),('method.configured',BOOL,'1'),('thermal.preheat_enabled',BOOL,'1'),('thermal.target_k',nullable(TEMP),'K'),('thermal.indicated_k',nullable(TEMP),'K'),('pressure.max_gauge_pa',nullable(PRESS),'Pa'),('cycle.phase',PHASE,'1'),('cycle.stage',TEXT,'1'),('cycle.fault',TEXT,'1'),('cycle.index',INT(0,10),'1'),('cycle.elapsed_s',number('s',0),'s'),('cycle.stage_elapsed_s',number('s',0),'s')]:slot(k,s,u) for k,u in [('initial_target_kg','kg'),('sorbed_target_kg','kg'),('dissolved_target_kg','kg'),('extract_target_kg','kg'),('degraded_target_kg','kg'),('removed_target_kg','kg'),('initial_solvent_m3','m^3'),('reservoir_solvent_m3','m^3'),('cell_solvent_m3','m^3'),('extract_solvent_m3','m^3'),('waste_solvent_m3','m^3'),('removed_solvent_m3','m^3'),('initial_nitrogen_mol','mol'),('remaining_nitrogen_mol','mol'),('exhaust_nitrogen_mol','mol'),('max_pressure_gauge_pa','Pa')]:slot('truth.'+k,number(u,0),u,'process_truth','evaluator','heater_lift') NEW_SLOT_ZH={'positions.active':'激活位置(6个布尔;null=从未设定,1.0接口:装了样品池的位置都参与)','cells.occupancy':'各位置所放的池:sample样品池、empty空池或无', 'method.current':'当前方法全部参数(未设定时为DEFAULT方法;含瓶、池、溶剂名与各周期参数)','method.name':'当前方法名(主屏标题)','method.modified':'当前方法改过且未保存(主屏标题划掉)', 'method.library':'方法表(号与名称,最多100个)','thermal.preheat_target_k':'PREHEAT菜单的预热温度(null=跟随方法温度)','thermal.eco_mode':'EcoMode:下一次萃取结束后关加热', 'leak_test.settings':'检漏参数(上次所用)','leak_test.status':'检漏状态:阶段、保持时间、各位压力读数、结果(各位最大差、最低占设定比例、是否符合手册判据)', 'flush.settings':'冲洗参数','flush.status':'冲洗状态','flow_test.settings':'流动测试参数','flow_test.status':'流动测试状态(背压、时间)', 'service.valves':'服务菜单阀门状态(溶剂阀、介质阀、位置阀、出液阀)','service.pump':'服务菜单泵:开关、设定与实际流量','service.lifts':'池/瓶升降位置、运动方向与电机电流', 'service.fans':'两个风扇的功率设定(%)','service.counters':'运行次数与时间:萃取、检漏、运行/加热时间、最高温度/压力、升降电机最大电流','pressure.sensors':'七个压力传感器读数与零点(泵压+6位置)', 'device.settings':'仪器设定:语言、对比度、按键蜂鸣、结束蜂鸣、开机预热询问','solvents.list':'溶剂表(20条名称)'} for k,s,u,o,c,w in [('positions.active',nullable(POS6),'1','setpoint','heater_lift',None),('cells.occupancy',{'type':'array','items':nullable(TEXT)},'1','scene','heater_lift',None), ('method.current',FREE,'1','setpoint','panel',None),('method.name',TEXT,'1','setpoint','panel',None),('method.modified',BOOL,'1','derived','panel',None), ('method.library',{'type':'array','items':FREE},'1','setpoint','panel',None),('thermal.preheat_target_k',nullable(TEMP),'K','setpoint','heater_lift',None), ('thermal.eco_mode',BOOL,'1','setpoint','heater_lift',('thermal.set_eco_mode','enabled')),('leak_test.settings',FREE,'1','setpoint','panel',None), ('leak_test.status',FREE,'1','derived','pressure_sensor_0',None),('flush.settings',FREE,'1','setpoint','panel',None),('flush.status',FREE,'1','derived','pump',None), ('flow_test.settings',FREE,'1','setpoint','panel',None),('flow_test.status',FREE,'1','derived','pump',None),('service.valves',FREE,'1','setpoint','media_valve',None), ('service.pump',FREE,'1','derived','pump',None),('service.lifts',FREE,'1','derived','heater_lift',None),('service.fans',FREE,'1','setpoint','rear_fan',None), ('service.counters',FREE,'1','derived','panel',None),('pressure.sensors',FREE,'Pa','derived','pressure_sensor_0',None),('device.settings',FREE,'1','setpoint','panel',None), ('solvents.list',{'type':'array','items':TEXT},'1','setpoint','panel',None)]:slot(k,s,u,o,c=c,w=w) NEW_SLOTS=list(NEW_SLOT_ZH) # ---------------------------------------------------------------- front panel (panel_ui.json beside the contract, generic engine _panel_ui.py) ASSET_VERSION='1.2.0';ASSET_DIR=ROOT/'assets/expansion_batch03/t2_vacuum/buchi_speedextractore' NOTICE_TEXT={'solvent_supply_empty':('Error 66',['Pressure not reached. Pump timeout.','Please check solvent reservoir.','Please refer to user manual.']), 'nitrogen_supply_empty':('Error 59',['Nitrogen inlet pressure out of range.','Please check nitrogen supply.','']), 'collection_vial_full':('Error 4',['Change vials.','','']),'change_vials':('Error 4',['Change vials.','Press START to continue.','']), 'pump_pressure_too_high':('Error 51',['Pump pressure too high.','Please refer to user manual.',''])} # om p.70-74 def _notice_text(code): if code.startswith('position_pressure_too_low:'): n=int(code.split(':')[1]);return f'Error {44+n}',[f'Position {n}: Pressure too low.','Please check whether a cell','is inserted.'] return NOTICE_TEXT.get(code,('Error',[code,'',''])) def _panel_engine(): try: from . import _panel_ui as engine # imported as asset_runtime.buchi_speedextractore return engine except ImportError: # loaded from its file path import importlib.util,sys if '_chemsim_panel_ui' not in sys.modules: spec=importlib.util.spec_from_file_location('_chemsim_panel_ui',Path(__file__).with_name('_panel_ui.py'));sys.modules['_chemsim_panel_ui']=importlib.util.module_from_spec(spec);spec.loader.exec_module(sys.modules['_chemsim_panel_ui']) return sys.modules['_chemsim_panel_ui'] # hooks of the panel spec: compose whole-method / list arguments from one edited value (the commands themselves check everything) LOCKED=[{'do':'set_var','var':'msg','value':{'const':'locked'}},{'do':'goto','screen':'message'}] def _write_method(panel,m,ctx): return panel._invoke('method.configure',m,{'PRECONDITION_FAILED':LOCKED},ctx) def _hook_method_set(panel,ctx,a): h=panel.host;m=h._method_args();v=panel._src(a['value'],ctx);f=a['field'] if f=='cycles': n=int(round(v));steps=m['cycle_steps'];m['cycle_steps']=(steps+[copy.deepcopy(steps[-1]) for _ in range(n)])[:n];m['cycles']=n elif v is None:m.pop(f,None) else:m[f]=v return _write_method(panel,h._sync_steps(m),ctx) def _hook_method_default(panel,ctx,a): return _write_method(panel,copy.deepcopy(DEFAULT_METHOD),ctx) def _hook_cycle_value(panel,ctx,s): k=int(panel.ui['vars'].get('cyc') or 1);steps=panel.host._full_method()['cycle_steps'];return steps[min(k,len(steps))-1][s['param']] def _hook_cycle_set(panel,ctx,a): h=panel.host;m=h._method_args();k=int(panel.ui['vars'].get('cyc') or 1);v=panel._src(a['value'],ctx) if k>m['cycles']:return False m['cycle_steps'][k-1][a['key']]=int(v) if a['key']=='port' else bool(v) if a['key']=='vial_change' else float(v) return _write_method(panel,h._sync_steps(m),ctx) def _hook_cycle_paste(panel,ctx,a): h=panel.host;m=h._method_args();src=panel.ui['vars'].get('clip');it=panel._current_item()[0] if not src or not it or it.get('cycle',99)>m['cycles'] or src>m['cycles']:return False m['cycle_steps'][it['cycle']-1]=copy.deepcopy(m['cycle_steps'][src-1]);return _write_method(panel,h._sync_steps(m),ctx) def _hook_solvent_open(panel,ctx,a): m=panel.host._full_method();V=panel.ui['vars'] for k in range(4):V[f'sol_n{k+1}']=m['solvent_names'][k];V[f'sol_r{k+1}']=int(round(m['solvent_fractions'][k]*100)) return True def _write_solvents(panel,ctx): V=panel.ui['vars'];r=[V[f'sol_r{k}'] for k in range(1,5)] if sum(r)!=100:return True # kept on the screen until the ratios sum to 100 % (om p.53) h=panel.host;m=h._method_args();m['solvent_fractions']=[x/100. for x in r];m['solvent_names']=[V[f'sol_n{k}'] for k in range(1,5)] return _write_method(panel,h._sync_steps(m),ctx) def _hook_solvent_store(panel,ctx,a): V=panel.ui['vars'] for fid,val in (ctx.get('buffer') or {}).items(): if fid.startswith('type'):V['sol_n'+fid[4:]]=val elif fid.startswith('ratio'):V['sol_r'+fid[5:]]=int(round(val)) return _write_solvents(panel,ctx) def _hook_solvent_name(panel,ctx,s): return panel.ui['vars'].get(f"sol_n{panel.ui['vars'].get('name_port') or 1}",'') def _hook_solvent_rename(panel,ctx,a): V=panel.ui['vars'];V[f"sol_n{V.get('name_port') or 1}"]=V.get('name_buf') or '';return _write_solvents(panel,ctx) def _hook_list_name(panel,ctx,s): return panel.host.solvent_list[int(panel.ui['vars'].get('list_index') or 1)-1] def _hook_slot_name(panel,ctx,s): it=panel._current_item()[0];h=panel.host return h.library[it['slot']]['name'] if it and it.get('slot') in h.library else h.method_name def _hook_grid_select(panel,ctx,a): V=panel.ui['vars'];ch=a['chars'][int(V.get('grid_pos') or 0)];buf=V.get('name_buf') or '' limit=16 if V.get('name_target')=='method' else 20 if ch=='BACKSPACE':V['name_buf']=buf[:-1];return True if len(buf)>=limit:panel._accepted=False;return True V['name_buf']=buf+ch;return True def _hook_aux_ratio(panel,ctx,a): cap=a['capability'];h=panel.host;store=h.leak if cap=='leak_test.configure' else h.flush_set f=list(store['solvent_fractions']);f[a['port']-1]=max(0.,min(1.,panel._src(a['value'],ctx)/100.)) return panel._invoke(cap,dict(solvent_fractions=f),None,ctx) PANEL_HOOKS={k[6:]:v for k,v in dict(globals()).items() if k.startswith('_hook_')} _panel_ui=_panel_engine() PANEL_SPEC=_panel_ui.load_spec(ASSET_DIR/'panel_ui.json',capabilities=set(CAPS)) if (ASSET_DIR/'panel_ui.json').is_file() else None PANEL_CAPS=_panel_ui.capability_definitions(PANEL_SPEC) if PANEL_SPEC else {} _PANEL_FX=list(dict.fromkeys(e for c in (_panel_ui.spec_capabilities(PANEL_SPEC) if PANEL_SPEC else []) for e in CAPS[c][7])) for _k,_d in PANEL_CAPS.items(): CAPS[_k]=(_d['input_schema'],_d['output_schema'],_d['component_ids'],_d['function_zh'],_d['kind'],_d['visibility'],_d['example_arguments'],[] if _d['kind']=='query' else list(_PANEL_FX)) def _hms(s): if s is None:return '--:--:--' s=int(round(s));return f'{s//3600:02d}:{s%3600//60:02d}:{s%60:02d}' def _bar(pa):return f'{max(0.,pa)/BAR:.1f} bar' class _E916Panel: """Panel-host protocol of the engine: what the controller firmware shows, and the panel.* commands.""" def _method_args(self): m=self._full_method();return {k:v for k,v in m.items() if v is not None} def _sync_steps(self,m): s=m['cycle_steps'][0];m['hold_s']=float(s['hold_s']);m['discharge_s']=float(s['discharge_s']);return m def panel_time(self):return self.time_s def panel_invoke(self,capability_id,arguments): try: validate(CAPS[capability_id][0],arguments);return self.invoke(capability_id,**arguments) except ActionRejected as exc: raise _panel_ui.PanelRejected(str(exc)) from None def _panel_cmd(self,cap,a): err=_panel_ui.check_arguments(CAPS[cap][0],a) if err:raise ActionRejected('INVALID_ARGUMENT') if cap=='panel.frame':return dict(frame=self.panel.frame()) if cap=='panel.capture': import hashlib,tempfile data,w,h=self.panel.png_bytes(a['display_id']);sha=hashlib.sha256(data).hexdigest() d=Path(self.panel_capture_dir) if self.panel_capture_dir else Path(tempfile.gettempdir())/'chemistry_sim_panel'/self.instance_id;d.mkdir(parents=True,exist_ok=True) path=d/f"{a['display_id']}_{sha[:16]}.png" if not path.exists():path.write_bytes(data) return dict(display_id=a['display_id'],time_s=self.time_s,image=dict(path=str(path),format='png',width=w,height=h,sha256=sha)) try: if cap=='panel.press':ok=self.panel.press(a['input_id'],float(a.get('duration_s',.1))) elif cap=='panel.turn':ok=self.panel.turn(a['input_id'],int(a['detents'])) else:ok=self.panel.switch(a['input_id'],a['position']) except _panel_ui.PanelError: raise ActionRejected('INVALID_ARGUMENT') from None if ok and cap=='panel.press' and self.settings['beep_key']:self.key_beeps+=1 return dict(accepted=bool(ok)) def panel_read(self): out=self.read('agent');m=self._full_method();rd=self._readings();act=self._active();occ=self._occupancy() end_c,vc,total=self._times() if self.plant else (None,None,None) V=self._valve_view();on=lambda b:'[x]' if b else '[ ]' # noqa: E731 skip=(self.phase=='running' and (self.stage in ('hold','solvent_flush') or (self.stage=='nitrogen_flush' and self.stage_elapsed>=60 and self._measured_max()<=BAR))) skip_leak=bool(self.aux and self.aux['kind']=='leak_test' and self.aux['stage'] in ('tightness','pump','hold')) cells=self._run_cells();vol=self._cell_volume(cells) if (cells or self.cells or (self.method or {}).get('cell_volume_m3')) else (m['cell_volume_m3'] or 20e-6) rows=[] for k in range(1,11): if k>m['cycles']:rows.append(f'{k:>3} n/a n/a n/a n/a Mix');continue s=m['cycle_steps'][k-1];mn=lambda x:(f'{x/60:.0f} min' if abs(x/60-round(x/60))<1e-9 else f'{x/60:.1f} min') # noqa: E731 rows.append(f"{k:>3} {max(1,math.ceil(10*vol/20e-6/60)):>3} min {mn(s['hold_s']):>7} {mn(s['discharge_s']):>9} {on(s['vial_change'])} {'P'+str(s['port']) if s['port'] else 'Mix'}") lt=self.aux if (self.aux and self.aux['kind']=='leak_test') else None;last=self.aux_last.get('leak_test') lr_pos=[rd[1+i] for i in range(6)] names=[n for n in self.solvent_list if n]+[n for n in m['solvent_names'] if n and n not in self.solvent_list] notice=None if self.notice: t,ls=_notice_text(self.notice['code']);notice=dict(id=self.notice['id'],title=t,lines=ls) c=self.counters;hm=lambda s:f'{int(s)//3600}:{int(s)%3600//60:02d} h:m' # noqa: E731 lifts=self._lifts();amb=self.plant['ambient_k'] if self.plant else 295.15 stage=(STAGE_TEXT.get(lt['stage'],lt['stage']) if lt else ('Finished' if last else 'Ready')) out.update({ 'host.power_epoch':self.power_epoch,'host.head':f"{self.cycle} / {m['cycles']}",'host.name':self.method_name,'host.modified':self.method_modified, 'host.remain':_hms(total),'host.status':self._status_text(),'host.heating':bool(self.powered and self.preheat),'host.pumping':bool(self.powered and self._pumping()), 'host.active':[i in act for i in range(6)],'host.any_active':bool(act),'host.temp_c':round(self.temperature-273.15) if self.powered else None, 'host.max_bar':max(0.,max(rd[1:]))/BAR,'host.skip':bool(skip or skip_leak),'host.skip_leak':skip_leak,'host.in_operation':self._in_operation(), 'host.aborting':bool(self.aborting),'host.ready':bool(self.method and abs(self.temperature-self.method['temperature_k'])<=1), 'host.progress':[_hms(end_c),_hms(vc),_hms(total)],'host.overflow':self._overflow_possible(),'host.cycle_rows':rows, 'host.heatup_text':f'{max(1,math.ceil(10*vol/20e-6/60))}min','host.library':[self.library[k]['name'] if k in self.library else '' for k in range(1,101)], 'host.library_slots':sorted(self.library),'host.solvent_options':[{'name':n} for n in names], 'host.diagram':[ 'Solvent valves '+' '.join(f'{i+1}{on(V["solvent"][i])}' for i in range(4)), 'Media valve '+{'solvent':'Solvent','gas':'Gas',None:'closed'}[V['media']], 'Pump '+(f"on {round((self.pump['actual_m3_s'] if self.pump['on'] else (self.method or m)['pump_total_m3_s'])*6e7)} mL/min" if self._pumping() else 'off'), 'Position valves '+' '.join(f'{i+1}{on(V["position"][i])}' for i in range(6)), 'Cells '+' '.join({'sample':'S','empty':'E',None:'-'}[occ[i]] for i in range(6)), 'Pressure [bar] '+' '.join(f'{max(0.,x)/BAR:.0f}' for x in rd[1:]), 'Outlet valve '+{'vial':'Vial','waste':'Waste',None:'closed'}[V['outlet']], 'Total pressure '+_bar(rd[0]),'',''], 'host.leak_run':dict(stage=stage,overall=f'{max(0.,rd[0])/BAR:.0f}',cells=' '.join(f'[{i+1}]' if i in act else ' -- ' for i in range(6)), pressures=' '.join(f'{max(0.,x)/BAR:3.0f}' if i in act else ' ' for i,x in enumerate(lr_pos)), hold=(f"{int(lt['hold_elapsed'])//60:02d}:{int(lt['hold_elapsed'])%60:02d}" if lt else '00:00'), max=f'{max([lr_pos[i] for i in act] or [0.])/BAR:.0f} bar'), 'host.valve_text':{**{f'solvent_{i+1}':'[open]' if self.valves['solvent'][i] else '[close]' for i in range(4)}, **{f'position_{i+1}':'[open]' if self.valves['position'][i] else '[close]' for i in range(6)}, 'media_solvent':'[open]' if self.valves['media']=='solvent' else '[close]','media_gas':'[open]' if self.valves['media']=='gas' else '[close]', 'outlet_vial':'[open]' if self.valves['outlet']=='vial' else '[close]','outlet_waste':'[open]' if self.valves['outlet']=='waste' else '[close]'}, 'host.lights':{'cell_upper':'[X]' if self.heater>=.035-1e-9 else '[ ]','cell_lower':'[X]' if self.heater<=1e-9 else '[ ]', 'vial_upper':'[X]' if self.rack>=.035-1e-9 else '[ ]','vial_lower':'[X]' if self.rack<=1e-9 else '[ ]', 'heater_middle':'[X]' if self.drawer<=1e-9 else '[ ]','shield_upper':'[X]' if self.shield>=.179 else '[ ]', 'shield_lower':'[X]' if self.shield<=1e-9 else '[ ]','rack_present':'[X]'}, 'host.pressures':[_bar(x) for x in rd],'host.temps':dict(heater=f'{self.temperature-273.15:.0f}°C',electronic=f'{amb-273.15+5:.0f}°C' if self.powered else '---'), 'host.pump':dict(actual=f"{self.pump['actual_m3_s']*6e7:.0f} mL/min",pressure=_bar(rd[0])), 'host.flow':dict(pressure=_bar(rd[self.flow_set['position']]) if (self.aux and self.aux['kind']=='flow_test') else _bar(0.), time=f"{int(self.aux['elapsed'])} s" if (self.aux and self.aux['kind']=='flow_test') else '0 s'), 'host.lift_current':f"{max(lifts['current_a'].values()):.3f} A", 'host.counters':dict(extractions=str(c['extractions']),leak_tests=str(c['leak_tests']),operating=hm(c['operating_s']),heater=hm(c['heater_s']), cell_ma=f"{self.current_max['cell']*1000:.0f} mA",vial_ma=f"{self.current_max['vial']*1000:.0f} mA", max_t=f"{c['max_temperature_k']-273.15:.0f} °C" if c['max_temperature_k'] else '---',max_p=_bar(c['max_pressure_pa'])), 'host.unit':dict(UNIT_INFO),'host.notice':notice}) return out class BuchiSpeedextractoreRuntime(_E916Device,_E916Panel): def __init__(self,instance_id='speedextractor_01'): self.instance_id=instance_id;self.time_s=0.;self.revision=0;self.powered=False;self.shield=0.;self.drawer=0.;self.heater=0.;self.rack=0.;self.plant=None;self.method=None;self.cells={};self.phase='idle';self.stage='standby';self.fault='';self.elapsed_s=0.;self.stage_elapsed=0.;self.cycle=0;self.operation_id=None;self._operation_count=0;self.preheat=False;self.temperature=295.15;self.reservoir=[0.]*4;self.waste=[0.]*4;self.nitrogen=0.;self.nitrogen_out=0.;self.aborting=False;self.history=[];self.next_sample=0.;self.templates={x['substance_id']:x for x in json.loads((ROOT/TEMPLATE_REL).read_text())['templates']};self.solvents={x['substance_id']:x for x in json.loads((LIB/'solvents.json').read_text())['solvents']};self._principals={'__public_agent__':'agent'};self._requests={};self._owners={};self._caller=None self._device_init();self.key_beeps=0;self.panel_capture_dir=None;self.panel=_panel_ui.PanelUI(PANEL_SPEC,self,PANEL_HOOKS) if PANEL_SPEC else None def register_principal(self,principal_id,visibility='agent'): if visibility not in ('agent','evaluator','debug'):raise ActionRejected('INVALID_ARGUMENT') if principal_id in self._principals:raise ActionRejected('REQUEST_CONFLICT') self._principals[principal_id]=visibility def session(self,principal_id='__public_agent__'): if principal_id not in self._principals:raise ActionRejected('ACCESS_DENIED') return BuchiSpeedextractoreSession(self,principal_id) def describe(self):return self.session().describe(instance_id=self.instance_id) def _maxp(self):return max((c['pressure'] for c in self._records().values()),default=0.) def _inventory(self): active=[c for c in self.cells.values() if not c['removed']];removed=[c for c in self.cells.values() if c['removed']];blanks=list(self.blanks.values()) return dict(initial_target_kg=sum(c['spec']['target_mass_kg'] for c in self.cells.values()),sorbed_target_kg=sum(c['sorbed'] for c in active),dissolved_target_kg=sum(c['dissolved'] for c in active),extract_target_kg=sum(c['extract'] for c in active),degraded_target_kg=sum(c['degraded'] for c in active),removed_target_kg=sum(c['sorbed']+c['dissolved']+c['extract']+c['degraded'] for c in removed)+sum(c['wasted']+c['collected'] for c in self.cells.values()),initial_solvent_m3=sum(self.plant['reservoir_m3']) if self.plant else 0.,reservoir_solvent_m3=sum(self.reservoir),cell_solvent_m3=sum(sum(c['liquid']) for c in active+blanks),extract_solvent_m3=sum(sum(c['vial']) for c in active+blanks),waste_solvent_m3=sum(self.waste),removed_solvent_m3=sum(sum(c['liquid'])+sum(c['vial']) for c in removed)+sum(self.exchanged)+sum(self.removed_blank),initial_nitrogen_mol=self.plant['nitrogen_mol'] if self.plant else 0.,remaining_nitrogen_mol=self.nitrogen,exhaust_nitrogen_mol=self.nitrogen_out,max_pressure_gauge_pa=self._maxp()) def _values(self): v={'power.enabled':self.powered,'shield.lift_m':self.shield,'drawer.extension_m':self.drawer,'heater.lift_m':self.heater,'rack.lift_m':self.rack,'plant.configured':self.plant is not None,'sample.configured':bool(self.cells),'method.configured':self.method is not None,'thermal.preheat_enabled':self.preheat,'thermal.target_k':self.method['temperature_k'] if self.method else None,'thermal.indicated_k':self.temperature if self.powered else None,'pressure.max_gauge_pa':self._measured_max() if self.powered else None,'cycle.phase':self.phase,'cycle.stage':self.stage,'cycle.fault':self.fault,'cycle.index':self.cycle,'cycle.elapsed_s':self.elapsed_s,'cycle.stage_elapsed_s':self.stage_elapsed};v.update({'truth.'+k:x for k,x in self._inventory().items()});v.update(self._device_values());return v def _device_values(self): return {'positions.active':list(self.positions) if self.positions is not None else None,'cells.occupancy':self._occupancy(),'method.current':self._full_method(),'method.name':self.method_name, 'method.modified':self.method_modified,'method.library':[dict(slot=k,name=e['name']) for k,e in sorted(self.library.items())],'thermal.preheat_target_k':self.preheat_k, 'thermal.eco_mode':self.eco,'leak_test.settings':copy.deepcopy(self.leak),'leak_test.status':self._aux_status(self.aux if self.aux and self.aux['kind']=='leak_test' else None) if self.aux and self.aux['kind']=='leak_test' else dict(self.aux_last.get('leak_test',dict(active=False)),active=False), 'flush.settings':copy.deepcopy(self.flush_set),'flush.status':self._aux_status() if self.aux and self.aux['kind']=='flush' else dict(self.aux_last.get('flush',dict(active=False)),active=False), 'flow_test.settings':copy.deepcopy(self.flow_set),'flow_test.status':self._aux_status() if self.aux and self.aux['kind']=='flow_test' else dict(self.aux_last.get('flow_test',dict(active=False)),active=False), 'service.valves':copy.deepcopy(self.valves),'service.pump':copy.deepcopy(self.pump),'service.lifts':self._lifts(),'service.fans':dict(self.fans),'service.counters':self._counters(), 'pressure.sensors':self._sensors(),'device.settings':dict(self.settings),'solvents.list':list(self.solvent_list)} def read(self,visibility='agent'):return copy.deepcopy({k:v for k,v in self._values().items() if visibility!='agent' or SLOTS[k][3]=='agent'}) def _measure(self):return dict(phase=self.phase,stage=self.stage,fault=self.fault,temperature_k=self.temperature if self.powered else None,max_pressure_gauge_pa=self._measured_max() if self.powered else None,cycle=self.cycle,stage_elapsed_s=self.stage_elapsed,evidence='synthetic_host_lumped_partition_and_control; NOT validated recovery or safety',template_source=TEMPLATE_REL) def _product(self): items=[] for i,c in self.cells.items(): s=c['spec'];ref=self.templates[s['substance_id']];items.append(dict(position=i,sample_id=s['sample_id'],substance_id=s['substance_id'],extract_target_kg=c['extract']+c['collected'],residual_target_kg=c['sorbed']+c['dissolved'],degraded_target_kg=c['degraded'],matrix_mass_kg=s['matrix_mass_kg'],extract_solvent_m3=sum(c['vial']),residual_solvent_m3=sum(c['liquid']),modeled_absolute_recovery_fraction=min(1.,(c['extract']+c['collected'])/s['target_mass_kg']),measured_e916_recovery_fraction=None,reference_ase_soxtec_ratio=ref['values']['ase_to_soxtec_recovery_ratio'],reference_instrument=ref['conditions']['instrument'])) return dict(items=items,evidence='synthetic_absolute_yield_from_host_Kd_transfer; measured_literature_relative_ASE200_to_Soxtec_is_NOT_E916_yield',template_source=TEMPLATE_REL) def saturation_pressure(self,temperature,volume_fractions): total=0.;parts=[] for sid,f in zip(SOLVENTS,volume_fractions): s=self.solvents[sid];points=s['vapor_pressure_reference_points'];t=temperature if not points[0]['temperature_k']<=t<=points[-1]['temperature_k']:raise ActionRejected('TEMPLATE_RANGE_UNAVAILABLE') j=min(len(points)-2,int((t-points[0]['temperature_k'])/5));lo,hi=points[j:j+2];weight=(t-lo['temperature_k'])/(hi['temperature_k']-lo['temperature_k']);ps=math.exp((1-weight)*math.log(lo['pressure_pa'])+weight*math.log(hi['pressure_pa']));moles=f*s['density_298_15_kg_m3']/s['molar_mass_kg_mol'];parts.append((moles,ps));total+=moles return sum(n*p for n,p in parts)/total if total else 0. def invoke(self,capability,**a): if capability not in CAPS:raise ActionRejected('UNKNOWN_CAPABILITY') validate(CAPS[capability][0],a) if capability in PANEL_CAPS: out=self._panel_cmd(capability,a) if CAPS[capability][4]!='query':self.revision+=1 return out if capability in DEVICE_CAPS: if _panel_ui.check_arguments(CAPS[capability][0],a):raise ActionRejected('INVALID_ARGUMENT') else: for k in ('position','cycles'): if k in a and (isinstance(a[k],bool) or not isinstance(a[k],int) or not (1<=a[k]<=10 if k=='cycles' else 0<=a[k]<=5)):raise ActionRejected('INVALID_ARGUMENT') if self._foreign_process(capability,a):raise ActionRejected('ACCESS_DENIED') if self.phase=='running' and CAPS[capability][4]!='query' and capability not in RUN_OK:raise ActionRejected('BUSY') if capability in DEVICE_CAPS: out=self._device_invoke(capability,a);self.revision+=1;return copy.deepcopy(out) if capability=='power.set': if a['enabled'] and not self.powered:self.power_epoch+=1 if not a['enabled'] and self.powered: self.eco=False;self.pump.update(on=False,actual_m3_s=0.);self.lift_cmd=dict(cell=None,vial=None) if self.aux:self.aux['fault']='power_off';self.aux_last[self.aux['kind']]=self._aux_status();self.aux=None self.powered=a['enabled'] if not self.powered and self.phase=='running':self.phase='cancelled' out=a elif capability in ('shield.set_lift','drawer.set_extension'): if self._maxp()>1e5 or self.heater>1e-9 or self.rack>1e-9:raise ActionRejected('PRECONDITION_FAILED') if capability=='shield.set_lift': if a['lift_m']<.179 and self.drawer>1e-9:raise ActionRejected('PRECONDITION_FAILED') self.shield=a['lift_m'] else: if self.shield<.179:raise ActionRejected('PRECONDITION_FAILED') self.drawer=a['extension_m'] out=a elif capability=='plant.configure': if self.plant or not a['exhaust_connected'] or not a['dry_matrix_reviewed'] or len(a['reservoir_m3'])!=4 or not a['coefficient_evidence']:raise ActionRejected('PRECONDITION_FAILED') self.plant=copy.deepcopy(a);self.reservoir=list(a['reservoir_m3']);self.nitrogen=a['nitrogen_mol'];self.temperature=a['ambient_k'];out={'configured':True} elif capability=='method.configure': f=a['solvent_fractions'] if self._operation_count or self.cells or len(f)!=4 or abs(sum(f)-1)>1e-9 or self.aux:raise ActionRejected('PRECONDITION_FAILED') if a['pressure_gauge_pa']/3+101325<1.1*self.saturation_pressure(a['temperature_k'],f):raise ActionRejected('LIQUID_PHASE_GUARD') self._check_method_extras(a) self.method=copy.deepcopy(a);self.method_modified=True;out={'configured':True} elif capability=='thermal.preheat': if not a.get('enabled',True): if 'temperature_k' in a:self.preheat_k=a['temperature_k'] self.preheat=False;out={'enabled':False} else: if not self.powered or not self.plant or (not self.method and 'temperature_k' not in a) or self.cells or self.heater>0:raise ActionRejected('PRECONDITION_FAILED') self.preheat_k=a.get('temperature_k');self.preheat=True;out={'enabled':True} elif capability=='sample.configure': if not self.plant or not self.method or not self.preheat or abs(self.temperature-self.method['temperature_k'])>1 or self.shield<.179 or self.drawer<.159 or not a['gripper_confirmed'] or self._operation_count or a['position'] in self.cells or a['position'] in self.blanks or not a['sample_id'] or any(c['spec']['sample_id']==a['sample_id'] for c in self.cells.values()) or a['matrix_solid_volume_m3']>=a['cell_volume_m3']*.9 or a['target_mass_kg']>a['matrix_mass_kg']*.01 or len(a['kd_m3_kg_by_solvent'])!=4 or not a['parameters_evidence']:raise ActionRejected('PRECONDITION_FAILED') if a['substance_id'] not in self.templates:raise ActionRejected('TEMPLATE_RANGE_UNAVAILABLE') if any(c['spec']['cell_volume_m3']!=a['cell_volume_m3'] for c in self.cells.values()):raise ActionRejected('PRECONDITION_FAILED') self.cells[a['position']]=dict(spec=copy.deepcopy(a),pressure=0.,liquid=[0.]*4,vial=[0.]*4,sorbed=a['target_mass_kg'],dissolved=0.,extract=0.,degraded=0.,removed=False,wasted=0.,collected=0.);out=dict(configured=True,attachment_event='host_attach:'+a['sample_id']) elif capability=='acquisition.start': if not self.powered or not self.plant or not self.method or not self.cells or any(c['removed'] for c in self.cells.values()) or self.shield>1e-9 or self.drawer>1e-9 or self.phase not in ('idle','cancelled') or self.stage in ('complete','halted') or abs(self.temperature-self.method['temperature_k'])>1 or not self._active():raise ActionRejected('PRECONDITION_FAILED') if self.aux:raise ActionRejected('BUSY') if not self._operation_count:self._next('sealing');self.cycle=1;self.counters['extractions']+=1 self.valves=dict(solvent=[False]*4,media=None,position=[False]*6,outlet=None);self.pump.update(on=False,actual_m3_s=0.);self.lift_cmd=dict(cell=None,vial=None) self.phase='running';self._operation_count+=1;self.operation_id=self.instance_id+':'+str(self._operation_count);out=dict(phase=self.phase,operation_id=self.operation_id) elif capability=='acquisition.stop': if self.phase!='running':raise ActionRejected('PRECONDITION_FAILED') self.phase='cancelled';out=dict(phase=self.phase) elif capability=='acquisition.abort': if not self.powered or not self._operation_count or self.phase not in ('running','cancelled') or self.stage in ('complete','halted'):raise ActionRejected('PRECONDITION_FAILED') self.aborting=True;self.phase='running';self._next('discharge');out=dict(phase=self.phase) elif capability=='extraction.measure':return self._measure() elif capability=='product.read':return self._product() elif capability=='reference.lookup': q=self.templates.get(a['substance_id']) if q is None:raise ActionRejected('TEMPLATE_RANGE_UNAVAILABLE') return dict(substance_id=q['substance_id'],name=q['name'],ase_soxtec_ratio=q['values']['ase_to_soxtec_recovery_ratio'],measured_e916_recovery_fraction=None,source=q['source'],conditions=json.dumps(q['conditions'],ensure_ascii=False),evidence=q['evidence'],template_source=TEMPLATE_REL) elif capability=='sample.unload': c=self.cells.get(a['position']) if not c or c['spec']['sample_id']!=a['sample_id'] or c['removed'] or self.stage not in ('complete','halted') or self._maxp()>1e5 or self.shield<.179 or self.drawer<.159 or not a['gripper_confirmed']:raise ActionRejected('PRECONDITION_FAILED') c['removed']=True;out=dict(unloaded=True,attachment_event='host_release:'+a['sample_id']) self.revision+=1;return copy.deepcopy(out) def _fan_percent(self): """Extraction fan performance: the service setting, 100 % while a fault event is active (om p.88: to get rid of leaking solvent).""" return 100 if (self.phase=='failed' or (self.aux is not None and self.aux['fault'])) else self.fans['extraction'] def _foreign_process(self,k,a): """An agent may not stop, skip, resume or change (heater, fan, EcoMode, service valves / pump / lifts / sensor zero) another agent's extraction (in progress, also while paused) or its leak test / flush / flow test: direct calls and the same commands from the panel keys (the session sets _caller around the call); unowned processes and evaluators are not restricted. 1.2.0 (lead rule 10-19): the green mains rocker switch (and power.set, which models it) is a hard switch - a physical action that is never refused; switching off acts as a power loss.""" c=self.__dict__.get('_caller') if c is None or self._principals.get(c)!='agent':return False off=False;change=k in CHANGES_PROCESS if self._in_operation() and (off or change or k in ('acquisition.start','acquisition.stop','acquisition.abort','acquisition.halt','acquisition.skip')): o=self._owners.get(self.operation_id) if o is not None and o!=c:return True if self.aux and (off or change or k in ('leak_test.stop','flush.stop','flow_test.stop')): o=self.aux.get('owner') if o is not None and o!=c:return True return False def _next(self,stage): self.stage=stage;self.stage_elapsed=0.;self.history.append(dict(time_s=self.time_s,stage=stage,cycle=self.cycle)) def _fail(self,reason):self.phase='failed';self.fault=reason;self._notify(reason) def _feed(self,c,vol): f=self._fractions();v=min([vol]+[self.reservoir[i]/x for i,x in enumerate(f) if x>0]) for i,x in enumerate(f):self.reservoir[i]-=v*x;c['liquid'][i]+=v*x if v+1e-15space+1e-15:self._fail('collection_vial_full');x=max(0.,space) frac=x/v if v else 0.;m=c['dissolved']*frac;c['dissolved']-=m;c['extract']+=m for i in range(4):x=c['liquid'][i]*frac;c['liquid'][i]-=x;c['vial'][i]+=x def _transfer(self,c,h): if c['removed']:return s=c['spec'];v=sum(c['liquid']);t=self.temperature;total=c['sorbed']+c['dissolved'] if v>1e-15: kd=math.exp(sum(c['liquid'][i]/v*math.log(s['kd_m3_kg_by_solvent'][i]) for i in range(4)))*math.exp(s['adsorption_energy_j_mol']/8.314462618*(1/t-1/298.15));eq=min(total*v/(v+kd*s['matrix_mass_kg']),s['solubility_kg_m3']*v);k=s['mass_transfer_s_inv']*math.exp(s['activation_energy_j_mol']/8.314462618*(1/298.15-1/t));delta=(eq-c['dissolved'])*-math.expm1(-k*h);delta=max(-c['dissolved'],min(c['sorbed'],delta));c['sorbed']-=delta;c['dissolved']+=delta d=-math.expm1(-s['degradation_s_inv']*h) for key in ('sorbed','dissolved'):x=c[key]*d;c[key]-=x;c['degraded']+=x def _gas(self,h): requested=self.plant['nitrogen_mol_s_per_cell']*len(self._run_cells())*h;x=min(self.nitrogen,requested);self.nitrogen-=x;self.nitrogen_out+=x if x+1e-12=.035 and self.rack>=.035:self._next('tightness') elif self.stage=='tightness': self._gas(h) if self.stage_elapsed>=10 and self.phase=='running': miss=self._missing() if miss:self._fail('position_pressure_too_low:'+str(miss[0]+1)) # Error 45-50: an active position without a cell else:self._next('fill') elif self.stage=='fill': for c in cells:self._feed(c,min(m['pump_total_m3_s']/6*h,max(0.,self._free(c)-sum(c['liquid'])))) if self.phase=='running' and all(abs(sum(c['liquid'])-self._free(c))<1e-12 for c in cells):self._next('heatup_1') elif self.stage.startswith('heatup_') or self.stage=='hold': fraction={'heatup_1':1/3,'heatup_2':2/3,'heatup_3':1.,'hold':1.}[self.stage] idx=self._run_indexed() # the pump holds the position sensors at the set point (their error and zero) for i,c in idx:c['pressure']+=(max(0.,m['pressure_gauge_pa']*fraction-self._offset(i))-c['pressure'])*-math.expm1(-h/p['pressure_tau_s']) self.pump_p=self.pump_p+(OVERALL_HOLD*m['pressure_gauge_pa']-self.pump_p)*-math.expm1(-h/60.) if self.stage=='hold' else max([c['pressure'] for c in cells]+[0.]) dwell=10*self._cell_volume(cells)/20e-6;rd=self._readings() if self.stage.startswith('heatup_') and self.stage_elapsed>=dwell and all(abs(rd[1+i]-m['pressure_gauge_pa']*fraction)<1e4 for i,_ in idx) and abs(self.temperature-m['temperature_k'])<=1:self._next({'heatup_1':'heatup_2','heatup_2':'heatup_3','heatup_3':'hold'}[self.stage]) elif self.stage=='hold' and self.stage_elapsed>=self._step('hold_s'):self._next('discharge') elif self.stage=='discharge': self.rack=min(.035,self.rack+.01*h) for c in cells: c['pressure']*=math.exp(-h/p['pressure_tau_s']);free=self._free(c);self._drain(c,p['discharge_m3_s_per_cell']*h,free*p['residual_holdup_fraction']) drained=all(sum(c['liquid'])<=self._free(c)*p['residual_holdup_fraction']+1e-12 for c in cells) if self.phase=='running' and drained and self._measured_max()<=1e5 and self.stage_elapsed>=self._step('discharge_s'): if self.cycle0 and not self.aborting else 'nitrogen_flush') elif self.stage=='vial_change': self.rack=min(.035,self.rack+.01*h) if self.rack>=.035:self.cycle+=1;self._next('fill') elif self.stage=='solvent_flush': for c in cells: v=m['pump_total_m3_s']/6*h;self._feed(c,v);self._drain(c,v) if self.stage_elapsed>=m['solvent_flush_s'] and self.phase=='running':self._next('nitrogen_flush') elif self.stage=='nitrogen_flush': self.rack=min(.035,self.rack+.01*h);self._gas(h) for c in cells:self._drain(c,p['discharge_m3_s_per_cell']*h);c['pressure']*=math.exp(-h/p['pressure_tau_s']) if self.stage_elapsed>=m['nitrogen_flush_s'] and self.phase=='running' and all(sum(c['liquid'])<1e-15 for c in cells) and self._measured_max()<=1e5:self._next('release') elif self.stage=='release': self.heater=max(0.,self.heater-.01*h);self.rack=max(0.,self.rack-.01*h) if self.heater<=1e-12 and self.rack<=1e-12:self.heater=self.rack=0.;self._next('complete');self.phase='cancelled' if self.aborting else 'succeeded';self._run_end() if not (self.stage.startswith('heatup_') or self.stage=='hold'):self.pump_p*=math.exp(-h/p['pressure_tau_s']) def _run_end(self): if self.eco:self.preheat=False;self.eco=False # EcoMode: heater off after the run (om p.45) if self.settings['beep_end']:self.end_beeps+=1 def step(self,dt): if isinstance(dt,bool) or not isinstance(dt,(int,float)) or not math.isfinite(dt) or not 0