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|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
00174446 | So rare earth ions (Eu 3+ , Tb 3+ ) substitute for Lu 3+ cation in LuBO 3 vaterite structure and the solid solution is observed up to 15% and 5% for respectively europium and terbium ions. Solid solution limits have not been determined and higher concentration might be possible while keeping the vaterite structure and a monophasic material. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00174446 | The purity and the morphology have been respectively analysed by X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM). The scintillation properties of LuBO 3 :Eu 3+ and LuBO 3 :Tb 3+ powders have also been studied. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 02533932 | EXAFS spectra were recorded in pseudo physiological conditions (pH = 6.5, 150 mM NaCl) with a Pu: PEI-MP monomer molar ratio of 0.02 as explained in the experimental section (Figure 2a). The corresponding modulus of the Fourier transform (FT) is shown in Figure 2b. | 2020 | [
"chim"
] | [
"212876",
"542059",
"119523",
"212876",
"212876",
"119523",
"1744"
] | [
"1195244"
] |
00174446 | The spectral distribution of the Eu 3+ doped materials results in a global orange-red emission. LuBO 3 :Tb 3+ emission spectrum (Fig. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00174446 | The material was excited for 10s and the signal was collected using a photomultiplier. The afterglow behaviours for Eu 3+ and Tb 3+ doped LuBO 3 powders are presented in Figure 9. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 03966549 | Each microcomposite was at least 3 mm long. A drop of epoxy resin 1 was then carefully deposited so that microcomposites keep aligned on the slab as shown in figure 2.a. | 1997 | [
"chim"
] | [
"19229",
"19229",
"19229",
"19229"
] | [
"184715"
] |
00174446 | 5 D 4 → 7 F 5 transition is the most intense and confers to the materials an overall green emission. Scintillation yields
Scintillation yields have been calculated for all the powders by comparing the integrating areas of the emission spectra of the sample and Gadox. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00174446 | Our measurements have been performed under X-ray excitation, so the results given for the scintillation yields under γ-ray excitation might be under-estimated. Yields have been calculated for concentrations of Eu 3+ and Tb 3+ ions with respectively 0.005 < x < 0.15 and 0.002 < x < 0.05. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 03488531 | Sodium tert-butoxide was superior to all of the other bases tested (Table 1, entries 7-9). Strong bases such as NaOtBu promoted the reaction affording product 2a in 92% yield, whereas weak bases such as K3PO4 and Cs2CO3 were less favorable for the reaction yield. | 2020 | [
"chim"
] | [
"1004771",
"1004771",
"1004771",
"1004771"
] | [
"760518",
"768565",
"842213"
] |
00174446 | Indeed, the major advantage of this soft chemistry process is that it allows the control of the morphology and the texture of the materials and also the preparation of the material as thin films [START_REF] Schmidt | [END_REF][START_REF] Nedelec | [END_REF]5]. Moreover, the sol-gel route allows the elaboration of materials of different composition and doped easily with different ions, in various concentration and the sol-gel derived materials are synthesized at lower temperature than the ones elaborated by classical solid state synthesis. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00174446 | Micrographs were recorded using a Cambridge StereoScan 360 SEM operating at 20 kV. Samples were prepared by depositing a small quantity of powder on adhesive carbon film before coating the surface with gold. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00162537 | These interchanges can be recognized and represented by comparing the functionality of the reactants with that of the products: the removal of some (old) functions and the creation of some (new) functions can be made explicit. The comparison relies on the atom-to-atom mapping where functionality interchanges correspond to the substitution of an atom from one function to another. | 2004 | [
"chim"
] | [
"577",
"2358",
"388357",
"577",
"388357",
"577"
] | [
"837910",
"739744"
] |
00174446 | Scanning Electron Microscopy
To complete the study, Scanning Electron Microscopy has been performed on vaterite LuBO 3 powders synthesized by sol-gel process and treated at 800°C for 18h. The micrograph recorded at 30 000 x magnification, given in Figure 5, indicate that LuBO 3 powders are homogeneous and constituted of small spherical particles of about 200nm. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00174446 | All recorded spectra, displayed in Figure 3 All the bands observed in the range 500-1200 cm -1 correspond to B-O group vibration modes and the positions agree well with published results [START_REF] Nedelec | [END_REF]8]. Thermal analysis
The evolution of LuBO 3 from the amorphous to crystalline form has been studied by thermal analysis. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 03493822 | XVI. Permittivities and refractive indices for 1-alkanol + di-n-propylamine systems at[END_REF][15], we are engaged in a systematic study of the dielectric behaviour of alkan-1-ol + amine liquid mixtures by means of relative permittivities ( r ε ), refractive indices at the sodium D-line ( D n ), and the application of the Kirkwood-Fröhlich model by the calculation of the Kirkwood correlation factor [START_REF] Fröhlich | Theory of Dielectrics[END_REF][START_REF] Chelkowski | Dielectric Physics[END_REF],
which also requires the knowledge of density ( ρ ) data. | 2021 | [
"chim"
] | [
"41293",
"41293",
"41293",
"41293",
"41293"
] | [
"798999"
] |
00174446 | This xerogel is then fired at 800°C for 18h in order to obtain Lu (1-x) Ln x BO 3 (Ln :Eu or Tb) crystalline powders. Samples with 0.005 < x < 0.15 and 0.002 < x < 0.05 have been prepared respectively for LuBO 3 :Eu 3+ and LuBO 3 :Tb 3+ . | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00154713 | This paper [15] also presents results concerning the cerium oxidation state in cerium doped sol-gel derived materials indicating the presence of Ce 4+ ions, so this observation can explain the fact that the measured yields are lower than those published in the literature. However, it is always difficult to compare the results obtained on single crystals and on powders. | 2006 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 03512618 | [12][13][14][15] In this approach, the active participation of two metal centres in the mechanism of the click reaction was highlighted by the use of copper-copper [12] or copper-nickel [13] in the formation of rotaxanes. This report demonstrates that the use of a ditopic ligand able to bind both an active copper template and a coordinatively unsaturated metal leads to both active and organising template effects and provides access to mechanically linked porphyrin architectures. | 2017 | [
"chim"
] | [
"548544",
"93771",
"548544",
"93771",
"548544",
"548544",
"93771"
] | [
"773981",
"760057"
] |
00174446 | The scintillation properties of LuBO 3 :Eu 3+ and LuBO 3 :Tb 3+ powders have also been studied. Experimental section
Powders preparation
LuBO 3 :Eu 3+ and LuBO 3 :Tb 3+ powders have been prepared by a sol-gel process described elsewhere [6]. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00154713 | The afterglow measurements were performed at room temperature on the samples corresponding to concentration optima. The excitation was performed during 10 s with a X-ray source working at 40 kV and 35 mA. | 2006 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 02749795 | The incident photon energy was set to 18 keV. Samples with a thickness between 800 and 1000 μm were directly placed in the beam path. | 2020 | [
"chim"
] | [
"203996",
"203996",
"203996"
] | [
"181254",
"178663"
] |
00174446 | Yields have been calculated for concentrations of Eu 3+ and Tb 3+ ions with respectively 0.005 < x < 0.15 and 0.002 < x < 0.05. The scintillation yields for all the samples and their evolution as a fonction of the doping ion concentration is presented in Figure 8. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00154713 | FTIR spectra correspond to a unique phase identified as LuPO 4 regardless of the doping level and the nature of the doping ion. Residual hydroxyls groups coming from the hydrolysis of alkoxides precursors are observed and will be confirmed by luminescence decay measurements. | 2006 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 02353727 | Reprinted with permission from reference [234] Copyright 2017, American Chemical Society. Strategies to steer specific morphologies
Besides from studying systematically different parameters and assessing their impact on particle morphology, recently several strategies have been devised to control morphology instead of suffering from it. | 2019 | [
"chim"
] | [
"504",
"542062",
"191041"
] | [
"17577",
"737055",
"17576"
] |
00174446 | This last loss is characteristic of the mineral network reorganization and of the final elimination of residual OH groupments. Total loss of weight is approximately 17%. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00154713 | Scintillation yields under γ-rays excitation are respectively 8060 photons/MeV [12] and 78000 photons/Mev [13] for BGO and Gadox. The yields of our materials were calculated from reference values which are obtained under γ-ray excitation. | 2006 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 03214440 | The lithium content values calculated from NMR, TGA and ICP are very close (Table 1), which proves the high purity of ionic polymer. The molar mass was determined thanks to size exclusion chromatography and was calculated from both laser diffusion and refractometer signal (Fig. | 2021 | [
"chim"
] | [
"1043076",
"1087107",
"216126",
"1043076",
"1043076",
"1087107"
] | [
"1158636",
"761520",
"180721",
"21788",
"743176"
] |
00174446 | Thermogravimetric analysis was performed using a Metler Toledo 851 apparatus. Samples were heated in air with a rate of 1 °C.min -1 . | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00154713 | The afterglow of Gadox (Gd 2 O 2 S:Tb) was also measured as a reference. The materials present an afterglow of 0.9%, 0.35%, 2.5% and 0.007% at 1 s after X-rays turn-off, for LuPO 4 :Ce 3+ (0.1%), LuPO 4 :Tb 3+ (5%), LuPO 4 :Eu 3+ (10%) elaborated by sol-gel process and Gadox respectively. | 2006 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 03592593 | As it can be seen in this table, the CECA Acticarbone AB has a porosity tailored in the microporous region, i.e. with pore radius between 1 and 2 nm. | 2007 | [
"chim"
] | [
"580",
"580",
"580",
"580"
] | [
"1178043"
] |
00174446 | Scintillation yields
Scintillation yields have been calculated for all the powders by comparing the integrating areas of the emission spectra of the sample and Gadox. Scintillation yields under γ-rays excitation is 78000 photons/Mev [11] for Gadox. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00154713 | This result is in good agreement with the published value of 12000 photons/MeV [14]. The scintillation yield of LuPO 4 :Ce 3+ has been improved by optimizing the Ce concentration. | 2006 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 03805091 | Compound 1 was synthesized in two steps from 4,4'-(ethyne-1,2-diyl)bis(N,N-bis(4-methoxyphenyl)aniline) by Ag-mediated cyclization with ethyl phenylphosphinate followed by the hydrolysis of ethyl group (see the Supporting Information for details). Photophysical study of 1 was performed in DMF (Figure S5). | 2022 | [
"chim"
] | [
"146890",
"194938",
"194938"
] | [
"1458"
] |
00174446 | The scintillation spectra were recorded with a Jobin-Yvon Triax 320 monochromator coupled with a CCD camera after excitation of the samples with a tungsten X-ray tube working at 35 kV and 15 mA. The signal was collected near the sample with an optical fiber. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00154713 | Conclusion
The sol-gel process is a good technique which allows the elaboration of scintillating LuPO 4 powders doped with different rare earth ions. These sol-gel derived powders present good cristallinity and purity, a homogeneous distribution of the particles and a controlled morphology. | 2006 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 03180781 | Found: m/z 573.0310. 13 C NMR (75 MHz, Methanol-d4): δ [157.0, 154.8, 151.0, 150.6, 146.0, 142.0, 132.6, 130.7, 127.3, 126.1, 125.4, 125.1, 123.5, 121.3, 120.8, 119.8, 116.4] (CH Ar ), [55.7, 55.5, 53.0, 52.9, 52.6, 34.8, 30.7, 30.6, 27.2, 26.7, 26.4, 24.2] (CH 2 ). | 2020 | [
"chim"
] | [
"542116",
"240928",
"542116",
"240928",
"542116",
"240928",
"542116",
"240928",
"542116",
"240928",
"542116",
"240928",
"525959",
"1744",
"542116",
"240928",
"1041788",
"1041788",
"311714",
"311714",
"1041788",
"1744",
"1079644",
"413221",
"542116",
"240928",
"542... | [
"1170809",
"793034",
"781663",
"763456",
"761210",
"738957",
"22002"
] |
00174446 | The scintillation properties of Eu 3+ and Tb 3+ doped LuBO 3 powders were studied for different concentrations of doping ion and good scintillation yields were obtained. Sol-gel derived LuBO 3 :Eu 3+ and LuBO 3 :Tb 3+ appear to be promising scintillators. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00154713 | Characterization
X-Ray diffraction patterns have been measured for all powders on a Siemens D501 diffractometer working in the Bragg-Brentano configuration with Cu-K α radiation (λ = 1.5406Ǻ). Infrared spectra were recorded on a Perkin Elmer 2000 FTIR spectrometer using the KBr pellet technique. | 2006 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 02139154 | Gases (acetylene and nitrogen) are taken from gas cylinders (Air Liquide and Air Products ® ) and flow rates are adjusted by mass flow controllers (Brooks ® SLA 5850S). Two controllers are used for acetylene depending on the flow rate: they allow reaching flow rates up to 600 NmL.min -1 and 12 000 NmL.min -1 , respectively, to study the influence of gas residence time (from 0.5 to 3 s). | 2019 | [
"chim"
] | [
"211875",
"211875",
"159664",
"211875"
] | [
"777790",
"935482",
"17695"
] |
00174446 | The signal was collected near the sample with an optical fiber. For relative conversion yield estimation, the samples were placed in a quartz tube with a fixed position throughout the measurements. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00154713 | LuCl 3 and LnCl 3 were mixed together in anhydrous 2-propanol in required amounts during 2 hours. Potassium isopropoxide was prepared by reacting metallic potassium (Aldrich) with anhydrous 2-propanol (Accros). | 2006 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 03020265 | Chem. Lett. | 2019 | [
"chim"
] | [
"141329"
] | [
"737956",
"735176",
"743590",
"179943"
] |
00174446 | Figure 9 :
9 Figure 9: Afterglow measurement on Lu 0.95 Eu 0.05 BO 3 , Lu 0.95 Tb 0.05 BO 3 and Gadox under X-ray
G
, 5 D 3 and 5 D 4 transitions[10]. Acknowledgements
The authors would like to thanks the French FRT for financial support under project LuminiX (RNTS-01B262). | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00154713 | In some cases new compositions unreachable by solid state reaction are possible. Furthermore, the sol-gel process developed in this work will allow the production of these materials as thin films which is a highly desirable configuration for X-ray intensifying screens. | 2006 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 01331224 | Thus the total intercalation process up to shows multiple stepwise plateaus at different voltages, associated to the different site occupancies for Li + ions into the framework of each component of the blend. These curves are in good agreement with the data of the cyclic voltammetry. | 2016 | [
"chim"
] | [
"151969",
"150665",
"459283",
"151969",
"151969",
"459283",
"150665",
"150665",
"247182"
] | [
"1077370"
] |
00174446 | Reproducibility was tested on the gadox sample yielding values within a 5 % deviation range. The afterglow measurements were performed at room temperature on the samples corresponding to concentration optima. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00174446 | These materials, that convert high energy radiation into UV-Visible light, are used in various applications: medical imaging, high energy physics, airport security and industrial control. The use of these scintillating materials in medical equipment (X-rays, γrays, positron emission, ... ) requires improvement of their properties, in particular their conversion yield. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 03134053 | Two milliliters of organic phase was pulled in a glass vial for its analysis in Gas Chromatography equipped with Flame Ionization Detector (GC-FID) (Agilent Technologies®, Network 6850 GC System) with a capillarity C18 reverse column (30 m*0.25 mm*0.25 µm). For the analysis, 1 µL was injected with a split ration of 1/50 using helium as carrier gas. | 2021 | [
"chim"
] | [
"483835"
] | [
"15924"
] |
00174446 | Afterglow
Precise knowledge of the afterglow is required for practical applications. Afterglow measurements were recorded at room temperature, using an X-Ray source, which operated at 40kV with an intensity of 25mA. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00174446 | Furthermore, the solid solution for LuBO 3 vaterite is observed up to x=0.15 and x=0.05 for europium and terbium ions respectively. So doping with Eu 3+ or Tb 3+ ions does not affect the structure. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 03806430 | 1 nm) by DFT (Density Functional Theory) calculations, [START_REF] Boronat | Molecular approaches to catalysis[END_REF] taking into account that the activation of small molecules is not observed for AuNPs exhibiting diameters larger than ca. 4 nm. | 2022 | [
"chim"
] | [
"572",
"572",
"572",
"572"
] | [
"779598",
"1172272",
"179366",
"1231972"
] |
00174446 | Figure 1 :Figure 2 :
12 Figure 1: X-Ray diffraction patterns recorded for (a) Lu 0.85 Eu 0.15 BO 3 and (b) Lu 0.95 Tb 0.05 BO 3
Figure 3 :Figure 4 :Figure 5 :Figure 6 :
3456 Figure 3: IRTF spectra of (a) LuBO 3 :Eu 3+ and (b) LuBO 3 :Tb 3+ powders of vaterite form
Figure 7 :
7 Figure 7: Emission spectra recorded, at room temperature, under X-ray excitation on (a) LuBO 3 :Eu 3+ and (b) LuBO 3 :Tb 3+ of vaterite form, with different concentrations of Eu 3+ and Tb 3+ ions. Figure 8 :Figure 9 :
89 Figure 8: Relative scintillation yields of (a) LuBO 3 :Eu 3+ and (b) LuBO 3 :Tb 3+ powders
Figure 1 :
1 Figure 1: X-Ray diffraction patterns recorded for (a) Lu 0.85 Eu 0.15 BO 3 and (b) Lu 0.95 Tb 0.05 BO 3 with the corresponding ASTM reference patterns (dotted lines)
1 )Figure 3 :Figure 4 :Figure 5 :Figure 6 :Figure 7 :
134567 Figure 3: IRTF spectra of (a) LuBO 3 :Eu 3+ and (b) LuBO 3 :Tb 3+ powders of vaterite form heated at
Figure 8 :
8 Figure 8: Relative scintillation yields of (a) LuBO 3 :Eu 3+ and (b) LuBO 3 :Tb 3+ powders. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00174446 | Samples were heated in air with a rate of 1 °C.min -1 . Micrographs were recorded using a Cambridge StereoScan 360 SEM operating at 20 kV. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 01629838 | Indirect photolysis mechanisms sometimes play a major role in the overall photochemical fate of organic micro-pollutants, especially for those chemicals that do not appreciably absorb light above 290 nm [51]. For example, cyclophosphamide and iosfamide, two classical antineoplastics, were not degraded under direct solar irradiation, however, the •OH-based indirect photolysis process could remove them from aquatic environment [55]. | 2017 | [
"chim"
] | [
"26646"
] | [
"759021"
] |
00174446 | Solid solution limits have not been determined and higher concentration might be possible while keeping the vaterite structure and a monophasic material. Results and discussion
Characterisation
X-Ray diffraction
FTIR Spectroscopy
Fourier transform Infrared spectroscopy has been carried out on the different samples doped with Eu 3+ or Tb 3+ ions. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00174446 | Scanning Electron Microscopy
To complete the study, Scanning Electron Microscopy has been performed on vaterite LuBO 3 powders synthesized by sol-gel process and treated at 800°C for 18h. The micrograph recorded at 30 000 x magnification, given in Figure 5, indicate that LuBO 3 powders are homogeneous and constituted of small spherical particles of about 200nm. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 04046963 | RESULTS AND DISCUSSION
N-aryl substituted azacalixphyrin 5 was prepared by optimising the reduction step procedure of azacalixarene 6 described in the literature (Scheme 1) [6]. The four nitro functions were reduced in presence of hydrazine monohydrate and Pd/C under heating for 72 hrs (instead of 30) at 80 °C (instead of 100 °C) to afford the corresponding colourless octaamino-azacalix[4]arene intermediate (not isolated) that spontaneously oxidize to 5 under aerobic conditions. | 2023 | [
"chim"
] | [
"215109",
"300761",
"485656",
"300761",
"215109",
"215109",
"215109",
"215109",
"215109"
] | [
"1241527",
"1241528",
"172380",
"21448",
"1241529",
"172409"
] |
00174446 | Commercial polycristalline Gd 2 O 2 S:Tb 3+ powder supplied by Riedel de Haën was used as a standard for the scintillation yields measurements. The setup was kept constant between the measurements (excitation and detection), simply changing the sample tube. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00174446 | The micrograph recorded at 30 000 x magnification, given in Figure 5, indicate that LuBO 3 powders are homogeneous and constituted of small spherical particles of about 200nm. The size distribution of these particles is uniform, which is a usual consequence of using the solgel process. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 03821709 | Samples were finally quenched down to room temperature, and 18 O 2 recovered using liquid helium. Finally, the samples were taken out of the zirconia cylinder to be prepared for the Time-of-Flight Secondary Ion Mass Spectrometry (TOF-SIMS) analyses. | 2022 | [
"chim"
] | [
"40221",
"525101",
"40221",
"525101",
"525101",
"486769",
"406917",
"525101"
] | [
"823979",
"1252040",
"774147",
"956135",
"734754"
] |
00174446 | Scintillation yields
Scintillation yields have been calculated for all the powders by comparing the integrating areas of the emission spectra of the sample and Gadox. Scintillation yields under γ-rays excitation is 78000 photons/Mev [11] for Gadox. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00174446 | Soft chemistry routes and in particular the sol-gel process offer an attractive alternative solution for the production of efficient scintillators with a control of the optical properties. Rare earth activated lutetium orthoborates, which present a high density due to lutetium, appear to be good scintillators [1,[START_REF] Moses | Procceding of the International Conference on Inorganic Scintillators and Their Applications[END_REF]. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 04047063 | This results in carbon depositing on the catalyst's surface, making it more susceptible to deactivation [START_REF] Álvarez | CO2 reforming of methane over Ni-Ru supported catalysts: On the nature of active sites by operando DRIFTS study[END_REF]. Sometimes a metal promoter is added to address these deficiencies and enhance the catalytic activity [START_REF] Aouad | A Review on the Dry Reforming Processes for Hydrogen Production: Catalytic Materials and Technologies[END_REF][START_REF] Wu | Synthesis of Ni@Al2O3 nanocomposite with superior activity and stability for hydrogen production from plastic-derived syngas by CO2-sorption-enhanced reforming[END_REF]. | 2022 | [
"chim"
] | [
"219804"
] | [
"1241586"
] |
00174446 | The purity of powders has been verified by X-Ray diffraction and the results confirm that all the materials have the vaterite type even if the calcination has been performed at 800°C. Furthermore, the solid solution for LuBO 3 vaterite is observed up to x=0.15 and x=0.05 for europium and terbium ions respectively. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00174446 | The scintillation spectra were recorded with a Jobin-Yvon Triax 320 monochromator coupled with a CCD camera after excitation of the samples with a tungsten X-ray tube working at 35 kV and 15 mA. The signal was collected near the sample with an optical fiber. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 01888549 | The evaluation confirmed the inverse square proportional relationship between inter-vehicle distance d and the received power for a link range of up to 30 meters in outdoor conditions. The path-loss exponent n found to be 2 for various weather situations and also sensitive to any misalignment which is the exact reason to deploy assisting control application such as the LC in this work. | 2018 | [
"chim"
] | [
"454685",
"302798",
"454685"
] | [
"942240",
"20861"
] |
00174446 | So rare earth ions (Eu 3+ , Tb 3+ ) substitute for Lu 3+ cation in LuBO 3 vaterite structure and the solid solution is observed up to 15% and 5% for respectively europium and terbium ions. Solid solution limits have not been determined and higher concentration might be possible while keeping the vaterite structure and a monophasic material. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00174446 | Moreover, the sol-gel route allows the elaboration of materials of different composition and doped easily with different ions, in various concentration and the sol-gel derived materials are synthesized at lower temperature than the ones elaborated by classical solid state synthesis. The powders have been characterized using various techniques. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 01862162 | 4 Scheme 4. Grafting reactions of 1 onto SiO2-700
Figure 5 . | 2018 | [
"chim"
] | [
"191041",
"191041",
"191041",
"191041",
"191041",
"3209",
"1181",
"3209",
"191041",
"191041"
] | [
"775297",
"179179",
"16122",
"17826",
"17596",
"925394",
"761272"
] |
00174446 | 7b) exhibits, in the range between 475-650 nm, several lines characteristic of 5 D 4 → 7 F J (J = 3-6) transitions of Tb 3+ ions. 5 D 4 → 7 F 5 transition is the most intense and confers to the materials an overall green emission. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00174446 | Samples were heated in air with a rate of 1 °C.min -1 . Micrographs were recorded using a Cambridge StereoScan 360 SEM operating at 20 kV. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 02569951 | By plotting the ln(J+Jsc-GV) against V-RJ (Fig. 5d), the obtained intercept gave J0 values of 7.5×10 -3 and 1.3×10 -3 mA/cm 2 for SS2 and SS3 device, respectively. | 2020 | [
"chim"
] | [
"303177",
"303177",
"303177",
"303177",
"93116",
"361003",
"467838",
"467838",
"303177",
"194938",
"194938"
] | [
"757917",
"177139",
"177419"
] |
00174446 | After dissolution of chlorides, the solution of potassium isopropoxide is added and then Lu/Ln chlorides mixture is reacted with the potassium alcoholate which substitutes for chloride leading to the formation of the rare earth alkoxides and the immediate precipitation of KCl according to:
LnCl 3 + 3 K + + 3 i OPr -→ Ln( i OPr) 3 + 3 KCl↓
This mixture was then refluxed for 2h at 85°C, in order to complete the formation of the rare earth alkoxides. Secondly, an alcoholic solution of boron tri-isopropoxide is added. | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 00174446 | Excitation and emission spectra
Excitation spectra
The excitation spectra of LuBO 3 :Eu 3+ and LuBO 3 :Tb 3+ vaterite powders were recorded for different concentrations of Eu 3+ (0.05 < x < 0.15) and Tb 3+ (0.002 < x < 0.05). Figure 6 shows the excitation spectra recorded at room temperature by fixing the emission wavelength at respectively 591nm and 541nm for the optima (Lu 0.95 Eu 0.05 BO 3 and Lu 0.95 Tb 0.0 5BO 3 ). | 2007 | [
"chim"
] | [
"13918",
"13918",
"174",
"13918"
] | [
"1219020",
"6039",
"174838",
"738659"
] | 03011853 | ThT fluorescence spectroscopy data obtained after reconstitution of each peptide lot in a Tris-HCl medium at pH 7.4 were used to compare the aggregation kinetics of the three peptides under the same conditions of incubation and analysis (Table 2). Some differences in the lag phase, the saturation phase, and the fluorescence intensity at the plateau were clearly pointed out. | 2020 | [
"chim"
] | [
"1041778",
"1051091",
"1042018",
"1042018",
"1051091",
"1041778"
] | [
"750477",
"758376",
"1182653"
] |
01744529 | The emission ratio of HONO/NO X derived in Section 3.2 was
M A N U S C R I P T A C C E P T E D ACCEPTED MANUSCRIPT
then used to adjust the HONO concentrations by Eq. ( 2). | 2018 | [
"sdu",
"sde"
] | [
"474247",
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"474247",
"474628",
"474247",
"197066",
"246207",
"474247",
"474247"
] | [
"773861",
"181905",
"770416"
] | 01744529 | The measured HONO mixing ratios in Ji'nan ranged from 17 pptv to 8.36 ppbv with a mean (±SD) value of 1.15±1.07 ppbv. Elevated HONO concentrations were frequently observed during the measurement period, with the daily maximum values exceeding 2 ppbv and 4 ppbv on 156 and 50 days, respectively (see Fig. | 2018 | [
"sdu",
"sde"
] | [
"474247",
"26886",
"474247",
"474247",
"474247",
"474628",
"474247",
"197066",
"246207",
"474247",
"474247"
] | [
"773861",
"181905",
"770416"
] | 01706563 | Temporal variation (climate and discharge) are represented by lower concentrations of major and trace elements under high flow conditions (April-04) than under high flow conditions (Septtember-03, 04) due to dilution effects. Increased SPM concentration due to geological variations is an important factor that may control the physical speciation and transfer of dissolved, natural nanoparticles and colloidal forms of Fe and Mn into the particulate phase via heteroaggregation of nanoparticle and colloidal forms of Fe and Mn with SPM. | 2019 | [
"sdu",
"sde"
] | [
"202521",
"187882",
"524461",
"147619",
"18404",
"843",
"300269"
] | [
"2530",
"889384",
"762220"
] |
01744529 | According to the laboratory studies, heterogeneous reactions of NO 2 on wet surfaces should be an important contributor to the ambient HONO concentrations, and the reaction rate is first order in NO 2 . It has been also proposed that these heterogeneous reactions can be photo-enhanced [START_REF] Stemmler | Photosensitized reduction of nitrogen dioxide on humic acid as a source of nitrous acid[END_REF]. | 2018 | [
"sdu",
"sde"
] | [
"474247",
"26886",
"474247",
"474247",
"474247",
"474628",
"474247",
"197066",
"246207",
"474247",
"474247"
] | [
"773861",
"181905",
"770416"
] | 01744529 | Current laboratory studies have reported the range of γ 01 ' →2101 from 10 -6 to 10 -5 on the ground surface [START_REF] Kurtenbach | Investigations of emissions and heterogeneous formation of HONO in a road traffic tunnel[END_REF][START_REF] Vandenboer | Understanding the role of the ground surface in HONO vertical structure: High resolution vertical profiles during NACHTT-11[END_REF] and from 10 -7 to 10 -5 on the aerosol surface [START_REF] Ndour | Photoenhanced uptake of NO 2 on mineral dust: Laboratory experiments and model simulations[END_REF][START_REF] Wong | Vertical profiles of nitrous acid in the nocturnal urban atmosphere of Houston, TX[END_REF]. Obviously, the uptake coefficient in different orders of magnitude would definitely lead to different assessment of the importance of heterogeneous HONO sources [START_REF] Li | Impacts of HONO sources on the photochemistry in Mexico City during the MCMA-2006/MILAGO Campaign[END_REF]. | 2018 | [
"sdu",
"sde"
] | [
"474247",
"26886",
"474247",
"474247",
"474247",
"474628",
"474247",
"197066",
"246207",
"474247",
"474247"
] | [
"773861",
"181905",
"770416"
] | 03268861 | Moreover, algal biomass influences denitrification, as shown by stimulation of denitrification in the presence of senescing green algae [START_REF] Mcmillan | Denitrification of Nitrogen Released from Senescing Algal Biomass in Coastal Agricultural Headwater Streams[END_REF], and by the increase of denitrifier abundance upon addition of algal biomass in intertidal sediments [START_REF] Decleyre | A Doubling of Microphytobenthos Biomass Coincides with a Tenfold Increase in Denitrifier and Total Bacterial Abundances in Intertidal Sediments of a Temperate Estuary[END_REF]. Both degradation of algal biomass and the presence of extracellular polymeric substances (EPS) or transparent exopolymeric particles (TEP) secreted by microalgae [START_REF] Bohorquez | Different Types of Diatom-Derived Extracellular Polymeric Substances Drive Changes in Heterotrophic Bacterial Communities from Intertidal Sediments[END_REF][START_REF] Passow | Transparent exopolymer particles (TEP) in aquatic environments[END_REF]Underwood and Paterson, 2003) might also be responsible for this increase in denitrifying activity by providing supplementary sources of anaerobic mineralizable C in sediments. | 2021 | [
"sdu",
"sde"
] | [
"928",
"928",
"928"
] | [
"747764",
"745477"
] |
01744529 | M A N U S C R I P T A C C E P T E D ACCEPTED MANUSCRIPT L QRSRTUR ∝ l +, ' * [pq = ] * r s t u (E9)
Correlation analysis between P unknown and related parameters has been widely adopted to diagnose the potential HONO sources (e.g., Su et al., 2008b). The NO 2 concentration ([NO 2 ]) is usually used as an indicator of the heterogeneous reactions on the ground surface since the ground surface to volume ratio (S/V g ) can be assumed to be constant for the well-mixed boundary layer at noontime, whilst [NO 2 ]*[S/V a ] can be taken as a proxy for the HONO formation on the aerosol surface. | 2018 | [
"sdu",
"sde"
] | [
"474247",
"26886",
"474247",
"474247",
"474247",
"474628",
"474247",
"197066",
"246207",
"474247",
"474247"
] | [
"773861",
"181905",
"770416"
] | 01744529 | V ZMW was calculated by assuming a HONO daytime dry deposition velocity of 2 cm s -1 and an effective mixing height of 200 m. Due to the rapid photolysis of HONO at daytime, most of HONO cannot reach the height above 200 m [START_REF] Alicke | Impact of nitrous acid photolysis on the total hydroxyl radical budget during the Limitation of Oxidant Production/Pianura Padana Produzione di Ozono study in Milan[END_REF]. m ,.D+, is the rate constant for the reaction of OH with NO, using a value of 9.8×10 -12 cm 3 molecules -1 s -1 from [START_REF] Atkinson | Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I -gas phase reactions of Ox, HOx, NOx and SOx species[END_REF]. | 2018 | [
"sdu",
"sde"
] | [
"474247",
"26886",
"474247",
"474247",
"474247",
"474628",
"474247",
"197066",
"246207",
"474247",
"474247"
] | [
"773861",
"181905",
"770416"
] | 04283847 | Once a seismic wavefield is obtained, several kinds of analysis can be applied, such as the study of dispersion behaviors to infer seismic velocity models of the subsurface [START_REF] Brenguier | 3-D surface wave tomography of the Piton de la Fournaise volcano using seismic noise correlations[END_REF], or the production of seismic images like what is obtained in active seismic studies [START_REF] Draganov | Reflection images from ambient seismic noise[END_REF]. Regarding monitoring applications, the classical approach consists of measuring the changes in the seismic waves phase arrivals, hence following the seismic velocity variations of the studied medium [START_REF] Olivier | Decrease in seismic velocity observed prior to the 2018 eruption of Kīlauea volcano with ambient seismic noise interferometry[END_REF]. | 2022 | [
"sdu",
"sde"
] | [
"1179186",
"1179186",
"460722",
"1088006",
"1043225",
"1042703"
] | [
"739254"
] |
01744529 | Besides, the elevated HONO levels in August under the condition of intense solar radiation suggests the presence of strong HONO sources as well as the important contributions of HONO as a potential source of OH radicals to the atmospheric oxidation chemistry. were adopted to select the cases: (a) only data in the morning rush hours (6:00-8:30 LT) in winter (e.g., November-February) were used; (b) NO/NO X>0.7; (c) good correlation between HONO and NO X ; (d) short duration of the plumes (<2 hours). | 2018 | [
"sdu",
"sde"
] | [
"474247",
"26886",
"474247",
"474247",
"474247",
"474628",
"474247",
"197066",
"246207",
"474247",
"474247"
] | [
"773861",
"181905",
"770416"
] | 01744529 | The emission source strength was estimated from the HONO/NO X emission ratio of 0.53% as determined in Sec. 3.2. | 2018 | [
"sdu",
"sde"
] | [
"474247",
"26886",
"474247",
"474247",
"474247",
"474628",
"474247",
"197066",
"246207",
"474247",
"474247"
] | [
"773861",
"181905",
"770416"
] | 00732944 | Ages relatifs 26 Al des chondres comparés aux compositions chimiques en roche totale normalisées à Mg et aux CI. Les cercles vides et remplis correspondent respectivement aux données de Tachibana et al. | 2012 | [
"sdu",
"sde"
] | [
"187882",
"262474",
"262474",
"262474",
"268504"
] | [
"181799",
"757831"
] |
01744529 | (2009); 2: Acker et al. (2006a); 3: Yu et al. | 2018 | [
"sdu",
"sde"
] | [
"474247",
"26886",
"474247",
"474247",
"474247",
"474628",
"474247",
"197066",
"246207",
"474247",
"474247"
] | [
"773861",
"181905",
"770416"
] | 01744529 | Considering the land use of the study site, the ground was treated as an uneven surface, and a factor of 2.2 per unit ground surface measured by [START_REF] Voogt | Complete urban surface temperatures[END_REF] was adopted to calculate the total
M A N U S C R I P T A C C E P T E D ACCEPTED MANUSCRIPT
12 active surface. Hence, S/? | 2018 | [
"sdu",
"sde"
] | [
"474247",
"26886",
"474247",
"474247",
"474247",
"474628",
"474247",
"197066",
"246207",
"474247",
"474247"
] | [
"773861",
"181905",
"770416"
] | 01136020 | Nitrogen removal in the SAV WWTP has significantly increased since the addition of nitrification and denitrification units in 2007 and 2011, and changed the nitrogen dynamics in the Seine River [START_REF] Rocher | La production de nitrites lors de la dénitrification des eaux usées: un sujet sensible et complexe ! L' Eau[END_REF]. | 2015 | [
"sdu",
"sde"
] | [
"43221",
"43221",
"178403",
"928"
] | [
"2871",
"1083429",
"745571"
] |
01744529 | In comparison with sources, the sink pathways of HONO are relatively well established. The chemical losses of HONO include the photolysis (R1) and reactions with OH radicals (R5). | 2018 | [
"sdu",
"sde"
] | [
"474247",
"26886",
"474247",
"474247",
"474247",
"474628",
"474247",
"197066",
"246207",
"474247",
"474247"
] | [
"773861",
"181905",
"770416"
] | 01741196 | Pseudomonas cichorii, which is usually isolated from the soil, shows pathogenicity in plants including eggplant, lettuce, celery, and chrysanthemum crops and has important economic effects [START_REF] Hojo | The hrp genes of Pseudomonas cichorii are essential for pathogenicity on eggplant but not on lettuce[END_REF]Pauwelyn et al., 2010). Our results show that long-term exposure to high concentrations of these ambient bacteria would pose a risk to people living in such hostile environments. | 2017 | [
"sdv",
"sde"
] | [
"530745",
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"530745",
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"246207",
"530745",
"530745",
"530745",
"474628"
] | [
"770416",
"773861",
"181905"
] | 01021890 | Spherical cavity with radius R C embedded at elevation H C over sea level. Axi-symetrical representation of Arenal topography used in mechanical model. | 2013 | [
"sdu",
"sde"
] | [
"234546",
"389111",
"222134",
"260866",
"260866"
] | [
"18132"
] |
01744529 | Daytime HONO budget analysis
In this section, we examine the potential unknown source(s) of daytime HONO by a detailed budget analysis. Equation ( 6) summarizes the main factors affecting the ambient concentrations of HONO. | 2018 | [
"sdu",
"sde"
] | [
"474247",
"26886",
"474247",
"474247",
"474247",
"474628",
"474247",
"197066",
"246207",
"474247",
"474247"
] | [
"773861",
"181905",
"770416"
] | 01741196 | However, the abundance of Actinomycetales in the submicron particles in Ji'nan was very low in this study (less than 1%, about 0.001%). This result was also markedly different from that reported by [START_REF] Bertolini | Temporal variability and effect of environmental variables on airborne bacterial communities in an urban area of Northern Italy[END_REF] who showed that Actinobacteridae, Clostridiales, and Sphingobacteriales were the major taxa in the airborne bacterial community in an urban area of Northern Italy. | 2017 | [
"sdv",
"sde"
] | [
"530745",
"530745",
"246207",
"530745",
"530745",
"530745",
"530745",
"246207",
"246207",
"530745",
"530745",
"530745",
"474628"
] | [
"770416",
"773861",
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] | 00796995 | The sedimentological study unravels also the tendency to uplift at the end of the Ordovician, in agreement with the tectono-magmatic history. On the western side, Yangtze foreland, the detrital zircon age spectrum indicates a derivation from the southeast with Precambrian grains derived from the basement of Cathaysia Block and the Early Neoproterozoic Jiangshan-Shaoxing suture [START_REF] Xu | Detrital zircon provenance of Upper Ordovician and Silurian strata in the northeastern Yangtze Block: Response to orogenesis in South China[END_REF]. | 2013 | [
"sdu",
"sde"
] | [
"187882"
] | [
"833139"
] |
01744529 | Where, > +, ' is the mean molecular velocity of NO 2 (370 m s -1 ); S/? @ and S/? | 2018 | [
"sdu",
"sde"
] | [
"474247",
"26886",
"474247",
"474247",
"474247",
"474628",
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] | [
"773861",
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] | 01741196 | The size distribution of these airborne bacteria in submicron particles were similar to the trend observed in coarse particles that Dong et al. reported, with two peaks at 1.1-2.1 µm and 4.7-7.0 µm, which occupied 18.6% and 19.2% of the total airborne microbes collected from October 2013 to August 2014 in Qingdao [START_REF] Dong | Concentration and size distribution of total airborne microbes in hazy and foggy weather[END_REF]. | 2017 | [
"sdv",
"sde"
] | [
"530745",
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] | [
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] | 01797619 | ! ! | 2018 | [
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] | [
"143009",
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] | [
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] |
01744529 | (2009); 4: Bernard et al. (2016); 5: Qin et al. | 2018 | [
"sdu",
"sde"
] | [
"474247",
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] | [
"773861",
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] | 01741196 | 2012). Active bacteria can serve as a medium for the spread of allergens and pathogens in a crowd [START_REF] Creamean | Dust and biological aerosols from the Sahara and Asia influence precipitation in the Western U[END_REF][START_REF] Husman | Health effects of indoor-air microorganisms[END_REF]. | 2017 | [
"sdv",
"sde"
] | [
"530745",
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] | [
"770416",
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] | 04155430 | The total pH scale is based on a reference state in a constant ionic medium. It considers amount contents (expressed in moles per kilogram of solution, noted mol/kg sol), of free hydrogen ions, [H + ]F, and hydrogen ions combined with sulphate ions, [HSO4 -], involved in the following equilibria, and defined according to equations 1.a and 1.b. | 2023 | [
"sdu",
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] | [
"559909",
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"559909",
"191652",
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] | [
"1268513",
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] |
01744529 | The seasonal variations of ambient HONO and related parameters are depicted in Fig. 3. | 2018 | [
"sdu",
"sde"
] | [
"474247",
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"474247",
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] | [
"773861",
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] | 01741196 | Meanwhile the use of firecrackers and fireworks on the eve of Chinese New Year was also identified as the cause for the same phenomenon [START_REF] Zhang | Physical characterization of aerosol particles during the Chinese New Year's firework events[END_REF]. The mass concentration of K + in the eve of 2014 Chinese New Year in Jinan was 18-folds higher than that in February 26, 2014. | 2017 | [
"sdv",
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] | [
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] | [
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] | 00766089 | The use of HS in studies of the complexation and sorption properties of NOM has generated a large body of work. Although HS remains poorly characterized, some general features have emerged. | 2012 | [
"sdu",
"sde"
] | [
"40015"
] | [
"7397"
] |
01744529 | Markedly poor air quality was observed as expected. Throughout the 1-yr period, 137 haze episodes occurred with daily mass concentration of PM 2.5 exceeding the National Ambient Air Quality Standard (Class II: 75 µg m -3 ), including 9 severe polluted haze episodes with daily average PM 2.5 concentrations above 250 µg m -3 . | 2018 | [
"sdu",
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] | [
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] | [
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] | 01741196 | In the present study, high bacterial concentration and significant negative correlation with the NO2, SO2, and O3 in atmosphere were detected. The diverse bacteria and pathogens in submicron particles during haze episodes was observed for the first time by the high-throughput sequencing, yet no significant difference for the dominant bacterial genus between haze and non-haze days were observed. | 2017 | [
"sdv",
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] | [
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] | 03337100 | 2 and SM Fig. 2), and by applying a multivariate statistical analysis such as Principal Component Analysis (PCA), it is possible to disentangle the forcing mechanisms behind the temporal variability (e.g., Avsar et al., 2014). | 2021 | [
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] | [
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01744529 | Up to now, the contribution of the ground surfaces to the overall production of HONO is still under discussion and subject to intensive research activity [START_REF] Wong | Vertical profiles of nitrous acid in the nocturnal urban atmosphere of Houston, TX[END_REF][START_REF] Zhang | Potential Sources of Nitrous Acid (HONO) and Their Impacts on Ozone: A WRF-Chem study in a Polluted Subtropical Region[END_REF]. 2NO 2 + H 2 O → HONO + HNO 3(ads) (R3)
In addition, the heterogeneous reduction of NO 2 on soot particles, mineral dust, and surfaces containing organic substrates was also proposed as a source of HONO (R4) [START_REF] Ammann | Heterogeneous production of nitrous acid on soot in polluted air masses[END_REF]2005;[START_REF] Ma | SO 2 initiates the efficient conversion of NO 2 to HONO on MgO surface[END_REF], and these processes can be further photo-enhanced during the daytime [START_REF] George | Photoenhanced uptake of gaseous NO 2 on solid organic compounds: a photochemical source of HONO? | 2018 | [
"sdu",
"sde"
] | [
"474247",
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] | [
"773861",
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] | 01741196 | In this study, 37 phyla, 71 classes, 137 orders, 236 families, and 378 genera were observed during the haze episodes. The predominant bacterial phyla (relative abundance more than 1%) were Firmicutes (78.9%), Proteobacteria (16.5%), Bacteroidetes (2.4%), and Actinobacteria (1.7%), which corresponded to the following bacterial classes: Bacilli (78.6%), Gammaproteobacteria (15.1%), Flavobacteria (2.0%), and Actinobacteria (1.7%) (Figure 3). | 2017 | [
"sdv",
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] | [
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] | [
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] | 03398817 | Submarine volcanic cones (VCs) concentrate in the channel between SE Pico and S. Jorge as well as south of Topo Volcano. Along the channel between the islands of Pico and S. Jorge, the 42 km long seismic profile elucidates the upper 400-500 ms TWT, which corresponds to 300 to 500 m if average velocities between 1.5 km/s and 2 km/s are assumed (Fig. | 2021 | [
"sdu",
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] | [
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01744529 | (2009); 6: Tong et al. (2015); 7: Su et al. | 2018 | [
"sdu",
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] | [
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] | [
"773861",
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] | 01741196 | The airborne bacterial concentration in the near-surface ranged from 10 4 to 10 6 cells•m -3 [START_REF] Bowers | Seasonal variability in airborne bacterial communities at a high-elevation site[END_REF][START_REF] Haas | The concentrations of culturable microorganisms in relation to particulate matter in urban air[END_REF][START_REF] Murata | Transport of bacterial cells toward the Pacific in Northern Hemisphere westerly winds[END_REF][START_REF] Goudarzi | Particulate matter and bacteria characteristics of the Middle East Dust (MED) storms over Ahvaz, Iran[END_REF][START_REF] Murata | Concentration of bacterial aerosols in response to synoptic weather and land-sea breeze at a seaside site downwind of the Asian continent[END_REF]. Bower et al. | 2017 | [
"sdv",
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] | [
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] | [
"770416",
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] | 02073572 | Planation surfaces can also be preserved within sedimentary basins as large unconformities (e.g [START_REF] Coltorti | Planation surfaces in northern Ethiopia[END_REF]. The latest can subsequently be exhumed by stripping of the less resistant overlying sedimentary covers (e.g. | 2019 | [
"sdu",
"sde"
] | [
"179899",
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] | [
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] |
01744529 | To understand the sources and impact of HONO in the polluted atmosphere of northern China, continuous measurements of HONO and related parameters were conducted from September 2015 to August 2016 at an urban site in Ji'nan, the capital city of Shandong province. HONO showed well-defined seasonal and diurnal variation patterns with clear wintertime and nighttime concentration peaks. | 2018 | [
"sdu",
"sde"
] | [
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] | [
"773861",
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] | 01741196 | The total water-soluble inorganic ions accounted for 64% of the PM2.5 mass concentration and sulfate, nitrate, and ammonia were the most abundant compositions, which were consistent with the previous report by [START_REF] Wang | Severe haze episodes and seriously polluted fog water in Ji'nan, China[END_REF] who showed that SO4 2-, NH4 + and NO3 -accounted for majority of the total water-soluble ions in PM2.5 during the winter haze in Ji'nan. Cl -(8.9 μg•m -3 ) and K + (1.5 μg•m -3 ) derived from the biomass burning cannot be ignored in the heating season. | 2017 | [
"sdv",
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] | [
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] | [
"770416",
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] | 03985097 | NANO, PROCHL, CRYPTO and HtP represents less than 15 % of the total communities. Figure 5 :
5 Figure 5: Principal Components Analysis (PCA) applied to data from LiB (A) and LaB (B). | 2023 | [
"sdu",
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] | [
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"300022",
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"191652"
] | [
"753443"
] |
01744529 | ( 4). Where, > +, ' is the mean molecular velocity of NO 2 (370 m s -1 ); S/? | 2018 | [
"sdu",
"sde"
] | [
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] | [
"773861",
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] | 01741196 | Results
General Characteristics of the Haze Episodes in Ji'nan. The environmental factors including PM2.5, water soluble inorganic ions, trace gases, wind speed and wind direction were determined during sampling period. | 2017 | [
"sdv",
"sde"
] | [
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] | [
"770416",
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] | 02935639 | Precipitation and temperature data originate from [START_REF] Williams | Central Asia Temperature and Precipitation Data, 1879-2003[END_REF]. Fig. | 2020 | [
"sdu",
"sde"
] | [
"1002357",
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] | [
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] |
01744529 | Results and discussion
Data overview
Figure 2 shows an overview of the measured HONO, NO, NO 2 , PM 2.5 , PM 1.0 , J HONO , and meteorological parameters in the present study. During the 1-yr measurement period, the prevailing winds were from the east and southwest sectors, indicating the general influence of industrial emissions on the study site (see Fig. | 2018 | [
"sdu",
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] | [
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] | [
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] | 01744529 | However, the potential sources that could explain the observed elevated daytime HONO are still under controversial discussion. The well accepted HONO sources include direct emissions from vehicle exhaust [START_REF] Kurtenbach | Investigations of emissions and heterogeneous formation of HONO in a road traffic tunnel[END_REF] and homogeneous gas phase reaction of NO with OH (R2) [START_REF] Pagsberg | Kinetics of the gas phase reaction OH + NO(+M) →HONO(+M) and the determination of the UV absorption cross sections of HONO[END_REF]. | 2018 | [
"sdu",
"sde"
] | [
"474247",
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] | [
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] | 00905925 | A lengthy validation period with a good fit allows us to evaluate the model's ability to predict the evolution of the system under other constraints (for example climate change and/or resource management scenarios). The modeling approach used in this study provides a very satisfactory reproduction of the daily time series of the groundwater level measured since 1974, with a Nash criterion of 0.68 and a low standard deviation (0.06). | 2014 | [
"sdu",
"sde"
] | [
"18404",
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] | [
"745100",
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] |
01744529 | (3) the meteorological conditions, especially surface winds, should be stable. Figure 5 presents an example of the heterogeneous HONO formation case occurring on 6-7 September, 2015. | 2018 | [
"sdu",
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] | [
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] | [
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] | 01744529 | 89 Figure 8. Scatter plots of the unknown daytime HONO source strength (P unknown ) with (a) NO 2 , (b) NO 2 *(S/V) a , (c) NO 2 *J NO2 , and (d) NO 2 *J NO2 *(S/V) a during August 2016. | 2018 | [
"sdu",
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] | [
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] | [
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] | 00698435 | This indicator is affected even for extremely small storage values (i*=0.01 mm): this corresponds to the infiltration effect of filter strips providing no storage (see Scenarios of SC implementation). In Figure 5 is plotted the runoff volume exceeding the treatment unit flow capacity (V 0.8 ). | 2011 | [
"sdu",
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] | [
"155441",
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] | [
"900989",
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] |
01744529 | (2012); 10: this study. Figure 1 . | 2018 | [
"sdu",
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] | [
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] | [
"773861",
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] | 01744529 | Some studies have reported much lower L QRSRTUR obtained from a rural site in Guangzhou, China (0.76 ppb h -1 ; [START_REF] Li | Exploring the atmospheric chemistry of nitrous acid (HONO) at a rural site in Southern China[END_REF], a mountain site in Hohenpeissenberg, Germany (0.40 ppb h -1 ; Acker et al., 2006), and a forest site in Julich, Germany (0.50 ppb h -1 ; [START_REF] Kleffmann | Daytime formation of nitrous acid: A major source of OH radicals in a forest[END_REF]. We further explored the potential unknown daytime source(s) of HONO based on our measurement data. | 2018 | [
"sdu",
"sde"
] | [
"474247",
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"474247",
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] | [
"773861",
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] | 01319092 | [END_REF] also sustain chemosynthesis in the deep-sea. Besides these peculiar environments, chemosynthetic fauna in sediment accumulation areas of continental margins has been described only once in relation with large particulate matter deposition in the Laurentian fan [START_REF] Mayer | Dense biological communities at 3850 m on the Laurentian Fan and their relationship to the deposits of the 1929 Grand Banks earthquake[END_REF]. | 2017 | [
"sdu",
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] | [
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"... | [
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01744529 | Furthermore, the total area of ground surface is much larger than the reactive surface provided by aerosols, suggesting that the heterogeneous reactions of NO 2 on ground surface may play a dominant role. It should be noted that the exact uptake coefficients of NO 2 on ground and aerosol surfaces are variable and should be different, and the present analysis simplified this process by treating the ground and aerosol surfaces the same. | 2018 | [
"sdu",
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] | [
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] | [
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] | 01744529 | During the nighttime, the heterogeneous conversion of NO 2 on the ground surface is an important source of HONO. The average conversion frequency of NO 2 to HONO was derived as 0.0068 h -1 from over hundred cases. | 2018 | [
"sdu",
"sde"
] | [
"474247",
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] | [
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] | 01327324 | MIRAGES-2 is designed for injection of a CO2-rich aqueous solution in an injection well at the 1/20 th scale. The well is made of a steel tube that is fixed to the core plug with a class G Portland cement. | 2016 | [
"sdu",
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] | [
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] | [
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] |
01744529 | The effect of HONO on OH production was also quantified. HONO photolysis was the uppermost source of local OH radical throughout the daytime. | 2018 | [
"sdu",
"sde"
] | [
"474247",
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] | [
"773861",
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] | 01744529 | The relatively higher springtime HONO mixing ratios might be related to some degree to the more intense heterogeneous reactions of NO 2 on the surface of mineral particles [START_REF] Nie | Asian dust storm observed at a rural mountain site in southern China: chemical evolution and heterogeneous photochemistry[END_REF], as indicated by the coincident higher concentrations of NO 2 and PM 2.5 (note that PM 10 was not measured in the present study). Indeed, the air quality of Ji'nan in the spring of 2016 was characterized by high levels The diurnal profiles of HONO and related supporting parameters are shown in Figure 4. | 2018 | [
"sdu",
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] | [
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] | [
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] | 01373346 | Measured depth-averaged velocity at the interface right-hand FP / MC, U int.rm , and measured average velocities in the MC and right-hand FP, U m and U r . Table 1 . | 2016 | [
"sdu",
"sde"
] | [
"182887",
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"182887",
"182887",
"182887"
] | [
"736126",
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] |
01744529 | (2006a); 3: Yu et al. (2009); 4: Bernard et al. | 2018 | [
"sdu",
"sde"
] | [
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] | [
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] | 01741196 | Conflict of Interest
The authors declare no conflict of interest. Figure 4 Heatmap of the dominant genus (relative abundance higher than 0.05%) in PM0.56-1, PM0.32-0.56, and PM0.18-0.32 at the genus level. | 2017 | [
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] | [
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] | [
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] | 02933822 | europaeus[END_REF], and V. ichthyoenteri [START_REF] Ishimaru | Vibrio ichthyoenteri sp. nov. a pathogen of Japanese flounder Paralichthys olivaceus larvae[END_REF]). | 2020 | [
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"173601",
"19871",
"20210",
"8334",
"20177"
] |
01744529 | Thus, the higher ratios at noontime indicated the existence of additional daytime sources of HONO. Moreover, the HONO/NO 2 ratios increased with solar radiation (e.g., J HONO ), implying that the additional sources may be related to the solar radiation intensity. | 2018 | [
"sdu",
"sde"
] | [
"474247",
"26886",
"474247",
"474247",
"474247",
"474628",
"474247",
"197066",
"246207",
"474247",
"474247"
] | [
"773861",
"181905",
"770416"
] | 01741196 | This result was also markedly different from that reported by [START_REF] Bertolini | Temporal variability and effect of environmental variables on airborne bacterial communities in an urban area of Northern Italy[END_REF] who showed that Actinobacteridae, Clostridiales, and Sphingobacteriales were the major taxa in the airborne bacterial community in an urban area of Northern Italy. The results may be caused by the different analysis method and sequencing platform. | 2017 | [
"sdv",
"sde"
] | [
"530745",
"530745",
"246207",
"530745",
"530745",
"530745",
"530745",
"246207",
"246207",
"530745",
"530745",
"530745",
"474628"
] | [
"770416",
"773861",
"181905"
] | 00581775 | 1.2 cm yr -1 ) spreading stage until present [START_REF] Mercuriev | Evolution de la dorsale de Carlsberg: évidence pour une phase d'expansion très lente entre 40 et 25 Ma (A18 à A7)[END_REF]. It is presently characterized by orthogonal accretion at a full rate of 2.2 ±0.1 cm yr -1 in its northwestern part [START_REF] Merkouriev | Constraints on Indian plate motion since 20 Ma from dense Russian magnetic data: Implications for Indian plate dynamics[END_REF]. | 2008 | [
"sdu",
"sde"
] | [
"1308",
"1023",
"1023",
"1308",
"57629",
"1023",
"1023",
"1023"
] | [
"11878",
"180774",
"13254",
"757211",
"12277",
"872949",
"833505"
] |
01744529 | The highest concentrations of HONO occurred in winter (i.e., December-January), followed by spring (i.e., April-May), summer (especially August) and autumn, with seasonal mean (±SD) values of 1.71±1.62, 1.16±0.90, 1.12±0.93 and 0.78±0.60 ppbv, respectively. Overall, the seasonal variation of HONO coincided with that of NO 2 , an important precursor of HONO. | 2018 | [
"sdu",
"sde"
] | [
"474247",
"26886",
"474247",
"474247",
"474247",
"474628",
"474247",
"197066",
"246207",
"474247",
"474247"
] | [
"773861",
"181905",
"770416"
] | 01741196 | nov. a new Lactococcus species from salmonid fish[END_REF], Pseudomonas fragi is responsible for bacteriological spoilage in dairy products and causes great economic losses in the dairy industry [START_REF] Pereira | Nutrition and physiology of Pseudomonas fragi[END_REF]. Streptococcus agalactiae can result in invasive infections such as skin and skin structure infections, urinary tract infections, osteomyelitis, endocarditis, and meningitis in adults [START_REF] Farley | Group B streptococcal disease in nonpregnant adults[END_REF]. | 2017 | [
"sdv",
"sde"
] | [
"530745",
"530745",
"246207",
"530745",
"530745",
"530745",
"530745",
"246207",
"246207",
"530745",
"530745",
"530745",
"474628"
] | [
"770416",
"773861",
"181905"
] | 00413033 | Maps of the divergence (a,c) and vorticity (b,d) of the horizontal flow field. Higher divergence values indicate strain localization in the 'inherited texture domain' or in the surroundings, when the former is at 45 • (a) or normal (b) to the imposed extension. | 2009 | [
"sdu",
"sde"
] | [
"24484",
"24484",
"57693",
"24484",
"1158"
] | [
"862981",
"861995",
"738319"
] |
01744529 | M A N U S C R I P T A C C E P T E D ACCEPTED MANUSCRIPT
Table 1 documents the measured levels of HONO, NOx, HONO/NOx ratios and the comparison with the results obtained previously elsewhere. The measured HONO mixing ratios in Ji'nan ranged from 17 pptv to 8.36 ppbv with a mean (±SD) value of 1.15±1.07 ppbv. | 2018 | [
"sdu",
"sde"
] | [
"474247",
"26886",
"474247",
"474247",
"474247",
"474628",
"474247",
"197066",
"246207",
"474247",
"474247"
] | [
"773861",
"181905",
"770416"
] | 01741196 | [START_REF] Cao | Inhalable microorganisms in Beijing's PM2.5 and PM10 pollutants during a severe smog event[END_REF] found that the relative abundance of microbial pathogens in PM2.5 increased with increase of air pollution level. While in this study, no obvious correlation with visibility, relative humidity and PM2.5 were observed. | 2017 | [
"sdv",
"sde"
] | [
"530745",
"530745",
"246207",
"530745",
"530745",
"530745",
"530745",
"246207",
"246207",
"530745",
"530745",
"530745",
"474628"
] | [
"770416",
"773861",
"181905"
] | 00665359 | Whereas carbonate dissolution due to the formation of an acidic plume from leakage of CO 2 has been intensively studied and described, a discussion about the glauconite (Phyllosilicate group) dissolution mechanism, which plays a prominent role in Albian chemical impact, is necessary. Indeed, the glauconite dissolution rate was estimated by [START_REF] Palandri | A compilation of rate parameters of water-mineral interaction kinetics for application to geochemical modeling[END_REF] and this assumes that dissolution is fast enough so that the glauconite is rapidly in equilibrium with a fast release of iron and silicon, which triggers the precipitation of kaolinite and quartz around the intrusion point. | 2011 | [
"sdu",
"sde"
] | [
"18404",
"18404",
"18404",
"18404",
"18404"
] | [
"919544",
"734932",
"755051",
"1337362",
"739978"
] |
01744529 | (vqpq) was 1.88 ppb h -1 , almost 3 times higher than L ,. (q w ). | 2018 | [
"sdu",
"sde"
] | [
"474247",
"26886",
"474247",
"474247",
"474247",
"474628",
"474247",
"197066",
"246207",
"474247",
"474247"
] | [
"773861",
"181905",
"770416"
] | 01741196 | Apart from the bacterial community structure in submicron particles, the source of the bacteria should be identified in order to understand the inhalable microbes further. The natural biosphere provides various natural environment sources for primary biological aerosol particles. | 2017 | [
"sdv",
"sde"
] | [
"530745",
"530745",
"246207",
"530745",
"530745",
"530745",
"530745",
"246207",
"246207",
"530745",
"530745",
"530745",
"474628"
] | [
"770416",
"773861",
"181905"
] | 00976088 | The age model, established using 210 Pb and 14 C dates, indicates that core VEN09P3 covers the last 2,600 years. The H1 layer may correspond to gravity reworking of slope sediment, as a response to the major Ligure earthquake in AD 1887. | 2014 | [
"sdu",
"sde"
] | [
"199954",
"20150",
"239385",
"239385",
"239385",
"222134",
"20150",
"199954",
"188653",
"154635",
"664"
] | [
"180274",
"1128465",
"1127001",
"8405",
"1753",
"16349",
"859469"
] |
00174455 | A clear correlation was found between the amounts of solvent undergoing the two transitions (both free and confined) demonstrating that the formation of the adsorbed layer t does not interfere with the second transition. The thickness of this layer and the porous volumes of the two silica samples were measured and found to be in very close agreement with the values determined by gas sorption. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 00174455 | Because of the overlapping of peaks 1 and 2 we can only use the sum H1+H2. If we plot the evolution of H3 and H4 as a function of (H1+H2) we obtained the curves presented in Figure 5. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 04038212 | [START_REF] Sathya | CoxFe3-XO4 Nanocubes for Theranostic Applications: Effect of Cobalt Content and Particle Size[END_REF][START_REF] Zhou | Correlation between Structure and Intervalence Charge-Transfer Transitions in Nanocrystalline CoFe2-XMxO4 (M=Mn, Al, Sc) Thin Films[END_REF] In addition, the shape of the hysteresis loop has evolved after the chemical microemulsion-based treatment, with two reversals of magnetization (one of them much larger), seen as two inflection points (0HS1 and 0HS2 magnetic fields) around 5 and 10 mT and 1.14 and 1.55 T when comparing the derivatives (dM/dH), shown in Figure 1j. The significantly larger reversal contribution at low field in the CoFe2O4@Ox sample clearly hints that a cationic modification took place. | 2023 | [
"chim"
] | [
"301759",
"3346",
"245096",
"1004998",
"245096",
"301759"
] | [
"1239187",
"1239188",
"778265",
"799136"
] |
00174455 | Theoretical considerations
According to Equation (1), the shift of the transition temperature of a confined liquid ∆T is inversely proportional to the radius of the pore in which it is confined. In fact it is well known that not all the solvent takes part in the transition and that a significant part of it remains adsorbed on the surface of the pore. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 00174455 | Takei et al. [24] showed that both solid-to-solid and liquid-to-solid transitions of CCl 4 were strongly dependent on the average pore size of the material in which the liquid is confined. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 02395794 | Before all the measurements the solutions were purged with nitrogen for 10 minutes. Computational studies
All the electronic structure calculations have been carried out with the Gaussian09 package, [START_REF] Adamo | Gaussian 09, Revision D.01[END_REF] and, following the computational protocol employed in our previous work, 25 the B3LYP functional [START_REF] Becke | [END_REF] in combination with a 6-311G** basis set was adopted. | 2020 | [
"chim"
] | [
"473775",
"1043287",
"1043287",
"238187",
"1001113"
] | [
"798861",
"777319"
] |
00174455 | T (°C) Following the same procedure, we can plot the evolution of H3 and H4 as a function of m CCl4 as performed in Figure 9. The plot of H1 and H2 as a function of m CCl4 (not shown here) can also be performed. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 00174455 | Thermal behaviour of CCl 4 confined in sample A
The objective is to get quantitative information on the solvent undergoing both transitions (both confined and free solvent). In order to do so, we performed sequential addition of precise quantities of CCl 4 in the sample as described in [26]. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 01410521 | This method was initially developed for identification and quantification of pyrazines [START_REF] Rey | Amine degradation in CO 2 capture. 2. | 2016 | [
"chim"
] | [
"300006",
"300006",
"301585",
"301585",
"301585",
"301585",
"301585",
"300006",
"300006"
] | [
"779916",
"178667"
] |
00174455 | It was equipped with an intracooler set allowing a scanning range of temperature between -70 and 600 °C. About 10 or 20 mg of the studied material was introduced into an aluminium DSC pan to undergo an appropriate temperature program. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 00174455 | A clear correlation was found between the amounts of solvent undergoing the two transitions (both free and confined) demonstrating that the formation of the adsorbed layer t does not interfere with the second transition. The thickness of this layer and the porous volumes of the two silica samples were measured and found to be in very close agreement with the values determined by gas sorption. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 03760944 | Fig. 4 . | 2023 | [
"chim"
] | [
"483835",
"1060208",
"483835",
"483835",
"1060208"
] | [
"14468"
] |
00174455 | In this figure, 4 peaks can be observed which are labelled from 1 to 4 starting from low temperature to room temperature. The assignment of all peaks is presented in Table 2. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 00174455 | These values are known for free solvent transiting at regular temperatures but not for confined solvent which undergoes transitions at lower temperature. From Figure 4, we can measure H3 Max at the point where all pores are filled in the constant part of the curve. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 01612065 | This plateau is not observed anymore at high pH and Currie et al associated it to a mushroomsbrushes transition of the PAA block. Wang et al studied these monolayers at pH 7 by BAM using DMF as solvent [START_REF] Wang | Aggregation behavior of polystyrene-b-poly(acrylic acid) at the air-water interface[END_REF]. | 2017 | [
"chim"
] | [
"101592",
"498",
"1744",
"439880",
"464914",
"101592",
"464914",
"1744",
"129486",
"439880",
"498"
] | [
"775473",
"864359",
"759468",
"862484"
] |
00174455 | For the M-to-R transition, the situation is different. Because of the overlapping of peaks 1 and 2 we can only use the sum H1+H2. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 01336146 | 56 Figure 5. Inductively coupled plasma analysis of the evolution of Ca 2+ , Si 4+ , PO 4 3-
Figure 7 .Figure 8 . | 2016 | [
"sdv",
"chim"
] | [
"460133",
"460133",
"179392",
"177286",
"177286"
] | [
"6039"
] | 00790597 | Nevertheless, because of the high symmetry of phase I the pattern collected at 120 K was indexed once the 2 theta regions containing the Bragg peaks of phase I were excluded. 2.2. | 2013 | [
"chim"
] | [
"136813",
"92418",
"136813"
] | [
"13893",
"905447",
"170942"
] |
00174455 | [24,25]. Theoretical considerations
According to Equation (1), the shift of the transition temperature of a confined liquid ∆T is inversely proportional to the radius of the pore in which it is confined. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 01336146 | Contact angle and surface free energy measurements using the Owens-Wendt method
The surface free energy (ɣ) and its dispersive (ɣ d ) and polar (ɣ p ) components were determined for the obtained materials using contact angle measurements and the Owens-Wendt method [START_REF] Rudawska | Analysis of determining surface free energy uncertainty with the Owens-Wendt method[END_REF][START_REF] Kubies | The interaction of osteoblasts with bone-implant materials: 1. The effect of physicochemical surface properties of implant materials[END_REF]. | 2016 | [
"sdv",
"chim"
] | [
"460133",
"460133",
"179392",
"177286",
"177286"
] | [
"6039"
] | 02773988 | In that respect, the Fe3(PO4)2(OH)2 barbosalite, belonging to the P21/c MgAl2(PO4)2(OH)2 lazurite group, has just been recently
shown to be less performing than LiFePO4 with the possibility to exchange only 0.7 Li at 2.6V [START_REF] Sandineni | Electrochemistry of Illusive Barbosalite, Fe 2+ Fe 3+ 2(PO4)2(OH)2: An Iron Phosphate Related to Lipscombite Structure[END_REF]. However, barbosalite exhibits the best catalytic properties of the Fe-P-OH-H system [START_REF] Rouzies | Isobutyric acid oxidative dehydrogenation over iron hydroxyphosphates. | 2020 | [
"chim"
] | [
"498349",
"560529",
"1087107",
"2037",
"2037",
"1744",
"1087107",
"2037"
] | [
"179092",
"757292",
"739105"
] |
00174455 | The enthalpy of transition ∆H1 can then be deduced ∆H1= 27.22 J.g -1 . Knowing ∆H1 and ∆H3, we can now calculate the masses of solvent which undergo the various transitions for all points. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 01336146 | This was confirmed using FT-IR spectroscopy. These analyses also suggest that ion exchange in the case of strontium-doped material 1HCPSP has an effect, since an equilibrium in the concentrations of selected ions is achieved more quickly and fluctuations at the beginning of soaking are not as spectacular as those noticed for 1HCPP. | 2016 | [
"sdv",
"chim"
] | [
"460133",
"460133",
"179392",
"177286",
"177286"
] | [
"6039"
] | 01652173 | Thus with 90 GLD-RGD, higher amount of lipoplexes were left undelivered. Similarly, GLD-RGD: pyrene was able to tag higher % of cells compared to the GLD: pyrene while NIH3T3 showed no enhancement in surface binding (Figure 7), indicating a selective targeting induced by the RGD peptide (Figure S5). | 2014 | [
"chim"
] | [
"86671",
"86671",
"86671",
"303242",
"520221",
"753",
"24488"
] | [
"172021",
"756507"
] |
00174455 | In order to do so, we performed sequential addition of precise quantities of CCl 4 in the sample as described in [26]. Briefly, a known mass of silica gel (about 20 mg) is set in the DSC pan which is sealed. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 01336146 | Cylindrical specimens from each type of material with a "diameter x height" dimensions: 6 mm x 2 mm and 12 mm x 10 mm for monoliths and scaffolds, respectively were investigated. In the SRB assay 1 sample (monolith or scaffold) per well of plate was added.Cells in the exponential growth phase were seeded at 0.2 × 10 6 cells/well on 24-well plates (Becton Dickinson, USA), and then incubated for 24 h. On the second day, after fixing the cells, the culture medium was refreshed and the following biocomposite samples were placed on the cells: 1HCP, 1HCP_H, 1HCPP, 1HCPS, 1HCPS_H, and 1HCPSP. | 2016 | [
"sdv",
"chim"
] | [
"460133",
"460133",
"179392",
"177286",
"177286"
] | [
"6039"
] | 02612037 | Then, we evidenced that Speed-OPIOM successfully overcame the strong autofluorescence of growth media that are currently used in microbiology and realized multiplexed fluorescence observation of colonies of spectrally similar fluorescent bacteria. Finally, we easily discriminated fluorescent labels from the autofluorescent and reflective background in labeled leaves, even under the interference of incident light at intensities that are comparable to sunlight. | 2020 | [
"chim"
] | [
"541777",
"541777",
"541810",
"55324",
"541777",
"541777"
] | [
"1163778",
"757602",
"736738",
"758636"
] |
00174455 | 2 :
2 Labelling of the different peaks observed in the DSC curves. Figure 3
3 Figure 3 presents the DSC curves recorded upon desorbing the CCl 4 by gas flushing. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 01336146 | Since the development of strontium ranelate, which is a drug that reduces the incidence of fractures in patients with osteoporosis, there has been an increasing awareness of the biological role of strontiumespecially its role in bone and in interactions with calcium ions [START_REF] Nielsen | The biological role of strontium[END_REF].Furthermore, in the literature there are several examples of various biomaterials, including scaffolds, containing Sr 2+ ions [START_REF] Wang | Surface modification of strontium-doped porous bioactive ceramic scaffolds via poly(DOPA) coating and immobilizing silk fibroin for excellent angiogenic and osteogenic properties[END_REF][START_REF] Ray | Effects of macroporous, strontium loaded xerogel-scaffolds on new bone formation in critical-size metaphyseal fracture defects in ovariectomized rats[END_REF][START_REF] Weng | Highly controlled coating of strontium-doped hydroxyapatite on electrospun poly(ɛ-caprolactone) fibers[END_REF]. Among the trace metals present in human bone, strontium is mainly, but not solely, correlated with bone compression strength [START_REF] Jensen | Relationship between trace element content and mechanical bone strength[END_REF]. | 2016 | [
"sdv",
"chim"
] | [
"460133",
"460133",
"179392",
"177286",
"177286"
] | [
"6039"
] | 00808254 | The resulting protein band was measured by a densitometer (Bio imaging system) (Synoptics, Cambridge, UK) and analysed by Gene tools software (Synoptics). SP-D concentration in the BALF was measured by ELISA as 109.62 ng/ml. | 2007 | [
"chim"
] | [
"218832",
"218833",
"218833",
"580",
"218834",
"125823",
"218832",
"218833"
] | [
"740213",
"735929"
] |
00174455 | The thickness of this layer was measured for both samples and is found to be slightly dependant on the pore radius. Finally the porous volumes of the silica gels have been measured and the values agree very closely with those derived from nitrogen sorption isotherm. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 00154725 | It was reported that covalently attached benzil pendant groups on the polymer backbone undergo efficient peroxidation through irradiation in air at λ>400 nm of the solid copolymer films. The conversion of α-dicarbonyl on peroxy moieties is almost quantitative. | 2006 | [
"chim"
] | [
"899",
"37987",
"899",
"37987",
"37987",
"13918",
"899"
] | [
"6039"
] | 01341574 | With the help of Mg, the glasses have flat and wide IR optical transmission windows. Near-IR absorption spectra and optical band gap
B
Optical Density/a. | 2016 | [
"chim"
] | [
"343874",
"343874",
"343874",
"343874",
"343874",
"343874",
"343874",
"343874",
"343874",
"343874",
"194938"
] | [
"177139"
] |
00174455 | Sample SSA (m 2 /g)
Vp (cm 3 /g) R av (nm) R p (nm) A 183 1,
DSC measurements
A Mettler-Toledo DSC821 instrument calibrated (both for temperature and enthalpy) with metallic standards (In, Pb, Zn) and with n-heptane was used to record the thermal curves. It was equipped with an intracooler set allowing a scanning range of temperature between -70 and 600 °C. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 00154725 | The periods of each treatment ranged between 0 and 240 minutes. The cross linking step leads to significant changes in the IR absorption spectra. | 2006 | [
"chim"
] | [
"899",
"37987",
"899",
"37987",
"37987",
"13918",
"899"
] | [
"6039"
] | 03097013 | The strong interaction between pyridine molecules in the case of the triplet state is clear: it induces a pyramidal coordination (one pyridine molecule) or octahedral coordination (two pyridine molecules) around the nickel atom and significantly affects the distances of the coordination bonds (Table
Figure 7
7 Figure 7 Optimized DFT structures of 7 for triplet systems considering DMSO (left) (with one or two explicit molecules, considering the most stable binding in each case) and pyridine (right) with one or two explicit molecules) as environment. Hydrogen atoms omitted for clarity. | 2020 | [
"chim"
] | [
"215109",
"663",
"663",
"59514",
"752",
"215109"
] | [
"174360",
"895275",
"178111",
"172409"
] |
00174455 | Sample
V p (cm 3 .g -1 ) V N2 (cm The calculated value of V p are in very good agreement with the value measured by nitrogen sorption, the error is less than 2%. The values of t determined for samples A and B are also in good agreement with average value given in [25] after calibration procedure with samples of various pore size. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 00154725 | To confirm this assumption prior to use the Rav data, some experiments have been performed in order to compare the thermoporometry results with gravimetric swelling measurement which is the more conventional method to characterize the three-dimensional network. For four new samples, irradiated respectively for 2, 5 15 and 180 minutes, the degrees of swelling (Gv) were determined by the gravimetric method. | 2006 | [
"chim"
] | [
"899",
"37987",
"899",
"37987",
"37987",
"13918",
"899"
] | [
"6039"
] | 02917003 | 2D or 3D) and grafting density on the recognition parameters. The evaluation of the interaction between L-Tym and the aptamer (Apt 49 ) was performed on aptasensors based either on a 2D-like or a 3D platform. | 2020 | [
"chim"
] | [
"1043100",
"1043100",
"1043265",
"1043100",
"1043100",
"1043100"
] | [
"1283261",
"760098",
"802608"
] |
00174455 | Textural data for the two samples are displayed in Table 1. In this table, the modal pore diameter R p is also shown. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 00154725 | This fact resulted in copolymer with much more uniform distribution of new monomer bearing benzil in copolymer with styrene. In this paper, some kinetic parameters of the cross linking reaction are given and the structure of the network obtained upon irradiation is discussed in comparison with those formed by thermal treatment. | 2006 | [
"chim"
] | [
"899",
"37987",
"899",
"37987",
"37987",
"13918",
"899"
] | [
"6039"
] | 02051356 | Effect of dry grinding on particle size and shape[END_REF][START_REF] Dellisanti | Changes of the main physical and technological properties of talc due to mechanical strain[END_REF]Cavaida et al., 2015;[START_REF] Bonino | MAS NMR and EPR study of structural changes in talc and montmorillonite induced by grinding[END_REF]. In this context, in the aim to obtain the combination of the three needs (purity, nanosize without amorphization of the structure and hydrophilic character), bottom up approaches have been investigated in the last 20 years and the unique technique is the hydrothermal synthesis [START_REF] Martin | Experimental study of Si-Ge tetrahedral solid solution in Ni-Co-Mg talcs[END_REF][START_REF] Martin | Random distribution of Ge and Si in synthetic talc: an EXAFS and FTIR study[END_REF][START_REF] Martin | Etude cristallographique et cristallochimique de l'incorporation du Germanium et du Gallium dans les phyllosilicates : approche par synthèse minérale[END_REF]Dumas et al., 2011a;[START_REF] Martin | Method for preparing a synthetic talc composition from a kerolite composition[END_REF][START_REF] Lèbre | Elaboration et caractérisation de talcs synthétiques pour l'amélioration des propriétés physiques des matériaux composites industriels[END_REF]Arseguel, 2006;[START_REF] Le Roux | Method for preparing a composition including synthetic inorganic particles[END_REF]Dumas et al., 2013a, b;[START_REF] Dumas | Elaboration de nouveaux procédés de synthèse et caractérisation de talcs sub-microniques : de la recherche fondamentale vers des applications industrielles[END_REF][START_REF] Claverie | Synthetic talc and talc-like structures: preparation, features and applications[END_REF]. | 2019 | [
"chim"
] | [
"151875",
"525101",
"554749",
"312334",
"151875",
"312334",
"525101",
"151875",
"554749",
"151875",
"554749",
"151875",
"525101",
"525101",
"151875",
"151875",
"151875",
"151875",
"571"
] | [
"735027",
"785779",
"179301",
"173187"
] |
00174455 | The cross sectional area of the adsorbate was taken to be 0.162 nm 2 for SSA calculations purposes. Prior to N 2 sorption, all samples were degassed at 100°C for 12 h under reduced pressure. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 00154725 | Figure 4 gives a comparison between PSDs calculated from the gas adsorption technique with the BJH model and the thermoporometry experiments. The two series of data seem in good agreement thus validating our calibration procedure. | 2006 | [
"chim"
] | [
"899",
"37987",
"899",
"37987",
"37987",
"13918",
"899"
] | [
"6039"
] | 03279285 | The kinetically favored furanosides (α/β-propargyl furanoside, kinetic products) rearranged then to the more stable pyranosides (α/β-propargyl pyranoside, thermodynamic products), affording in total four different cyclic forms of the glycosides (two α/β-anomers for each sugar cycle). The signals found and assigned to furanosidic compounds in the GC spectrum (peak 6 + 7, Figure 19), supported the proposed mechanism. | 2021 | [
"chim"
] | [
"184101"
] | [
"807988"
] |
00174455 | For higher amounts of CCl 4 , peak 3 appears at a temperature shifted with respect to the normal melting temperature of solid CCl 4 . At about the same time, peak 1 also appears corresponding to the M-to-R transition for the confined solvent. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 01336146 | After this, the mixture was warmed up on a water bath at 80 °C. Depending on the amount of carbohydrates, a red to blue-violet color appears throughout the whole mixture. | 2016 | [
"sdv",
"chim"
] | [
"460133",
"460133",
"179392",
"177286",
"177286"
] | [
"6039"
] | 01674779 | . The CF was sequentially exposed to diethyl zinc (DEZ), Zn(CH2CH3)2, and deionized water, separated by a purge step with dry argon (Ar flow rate of 100 sccm) at 100°C, thus forming a ZnO thin layer onto the CF surface. | 2017 | [
"chim"
] | [
"1087310",
"1087310",
"1087310",
"1087310",
"1087310",
"1087310",
"1087310",
"1087310"
] | [
"751439",
"183852",
"746155",
"751688",
"753971"
] |
00174455 | In this table, the modal pore diameter R p is also shown. This value fairly matches the R av derived from S BET measurement with cylindrical shape assumption thus confirming the validity of the hypothesis on the pore shape. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 01336146 | The sugar template was
1HCPS_H, and 1HCPSP, were prepared using the sol-gel process. There are two types then washed out using warm distilled water (40-50 °C) until the filtrate had no traces of
of sample. | 2016 | [
"sdv",
"chim"
] | [
"460133",
"460133",
"179392",
"177286",
"177286"
] | [
"6039"
] | 03810268 | 222 Silylated TLEs were analyzed in MRM mode using the following specific transitions selected 223 on the basis of the fragmentation pathways described above (Figure 2): m/z 293 → 219 (d + → 224 c + ) and m/z 323 → 279 (d + → e + ) for unlabelled p-coumaric and ferulic acids, respectively, and 225 m/z 302 → 228 (d + → c + ) and m/z 333 → 288 (d + → e + ) for the fully 13 C-labelled corresponding 226 internal standards.227The limits of detection (10 pg and 30 pg for the TMS derivatives of p-coumaric and ferulic 228 acids, respectively) were determined for a signal-to-noise ratio greater than 5. Linear responses 229 with coefficients of determination R 2 > 0.99 could be obtained in the ranges 0.01-1 ng and 230 0.03-3 ng for the TMS derivatives of p-coumaric and ferulic acids, respectively.231Comparison of mass spectral data and retention times with those of standards allowed 232 unambiguous characterization of TMS derivatives of trans-p-coumaric and trans-ferulic acids samples analysed (see example in Figure4). | 2022 | [
"chim"
] | [
"191652",
"251578",
"251578",
"251578",
"191652",
"554200"
] | [
"20191",
"1228126",
"1228127",
"19878"
] |
00174455 | The state of this adsorbed layer has been discussed extensively in the case of water. Consequently, the radius measured by application of the Gibbs-Thomson equation should be written R=R p -t where t is the thickness of the adsorbed layer leading to a reformulation [7] of Equation 1as 2)
t T H k R m p + ∆ ∆ = (Equation
The value of t can be determined by the calibration procedure using materials of various pore sizes and this is the traditionally adopted procedure. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 01336146 | Samples TEVS : HEMA ratio Ca 2+ (%) PO 4 3-(%) Sr 2+ (%) Comments
Table 2 . 2 Mechanical properties of organic-inorganic hybrids and some examples of selected systems. | 2016 | [
"sdv",
"chim"
] | [
"460133",
"460133",
"179392",
"177286",
"177286"
] | [
"6039"
] | 04359828 | In the absence of reliable mechanistic models of the process it is advantageous to explore and develop alternative strategies for comprehending these interactions. A statistical tool such as response surface methodology (RSM) is often employed to illustrate the relationship between the various operating parameters as well as the synergistic effect of different operating variables on the outputs due to its simplicity. | 2023 | [
"chim"
] | [
"1061772",
"1061772",
"191041"
] | [
"1329100",
"180823"
] |
00174455 | -
(R) (M) (Liquid) (Liquid) (Liquid) (M) (M) (R) (R) (FCC) (FCC) Heat Flow (mW.g -1 )
T (°C) As it is cooled down, liquid CCl 4 crystallizes into Face-Centered-Cubic phase (FCC) which follows a phase transition upon further cooling to a Rhombohedral one (R) which, in turn, transforms to Monoclinic crystalline structure (M) around -48°C. Heating the (M) phase leads to (R) in a reversible way but upon heating (R) melts directly without transforming into the (FCC) phase. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 01336146 | Selected samples were also covered with synthetic bone-like hydroxyapatite in order to compare their in vitro behavior to new systems reported in this paper. To prepare mentioned above materials we used well-known monomers, e.g. | 2016 | [
"sdv",
"chim"
] | [
"460133",
"460133",
"179392",
"177286",
"177286"
] | [
"6039"
] | 02196509 | CYP3A4, the most promiscuous enzyme, was also the most flexible, whereas CYP2A6, the most selective enzyme, was the most rigid. Furthermore, distinct domains were identified in terms of flexibility, namely, a relatively rigid heme-binding pocket, a more flexible proximal domain responsible for the interaction with redox partners, and a highly malleable distal domain responsible for the interaction with membranes and substrate channeling. | 2010 | [
"chim"
] | [
"157706",
"157706",
"302308",
"157706",
"300707",
"302308",
"157706"
] | [
"176761"
] |
00174455 | Finally the porous volumes of the silica gels have been measured and the values agree very closely with those derived from nitrogen sorption isotherm. It has been demonstrated that using porous samples of known porosity (measured by mercury intrusion porosimetry or gas sorption analysis) could allow the measurement of thermodynamical data of confined liquids (Enthalpy of transition, density,….). | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 01336146 | In this study, biological medium was used because it additionally contains amino acids and vitamins and provides better biomimetic conditions. However, owing to the presence of various proteins in this solution, lower rates for the material"s dissolution and a subsequent delay in surface layer formation are expected [START_REF] Jallot | Imaging physicochemical reactions occuring at the pore surface in binary bioactive glass foams by micro ion beam analysis[END_REF]. | 2016 | [
"sdv",
"chim"
] | [
"460133",
"460133",
"179392",
"177286",
"177286"
] | [
"6039"
] | 01613136 | Background colors have been used to highlight the three families: IV (purple), V-III (green) and IIb-VI (light orange). Lengths are in Å, charges in electrons. | 2017 | [
"chim"
] | [
"417625",
"556732"
] | [
"784416"
] |
00174455 | The authors would like to thank A. Gordon and Pr S. Turrell for careful reading of the paper. Contact author for correspondence and return of proofs:
e-mail : j-marie.nedelec@univ-bpclermont.fr | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 00154672 | Figure 2 should around be here Figure 3
n a t kt α = - - (Eq. 2)
where k a is Avrami rate constant and n Avrami exponent. | 2007 | [
"chim"
] | [
"899",
"13918",
"789",
"899"
] | [
"6039"
] | 03871576 | A detailed overview of the changes in nib pH with fermentation time can be found in SI Figure S 3. Within the first hour after application, the average nib pH decreased significantly from 5.3 ± 0.2 (stdev) to 4.6 ± 0.1 with lactic acid and from 5.3 ± 0.1 to 4.7 ± 0.1 with acetic acid application (Students t-test, P-value <0.05). | 2022 | [
"chim"
] | [
"483835"
] | [
"1191568",
"1191569",
"1191570",
"14728",
"785381",
"1191571",
"1191572",
"763349"
] |
00174455 | The amount of solvent was varied through two sets of experiments, sequential addition and original progressive evaporation allowing the measurement of the DSC signals for the various transitions as a function of the amount of CCl 4 . These experiments allowed the determination of transition enthalpies in the confined state which in turn allowed the determination of the exact quantities of solvent undergoing the transitions. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 00154672 | A relevant kinetic characterisation, obtained by derivation from the relative crystallinity plots, is the crystallization half time (t 0.5 ). This time corresponds to the time necessary for the polymer to reach 50 % of its maximum crystallinity. | 2007 | [
"chim"
] | [
"899",
"13918",
"789",
"899"
] | [
"6039"
] | 01616374 | Electrochemistry. Electrochemical measurements were performed at room temperature using an Eco Chemie Autolab PGSTAT 100 potentiostat running GPES 4.9 software or a Biologic VMP3Multi Potentiostat with EC-lab software. | 2017 | [
"chim"
] | [
"1041872",
"1041872",
"393642",
"408955",
"1041872",
"1041872",
"393642"
] | [
"738749",
"740654",
"17876",
"739571",
"757867"
] |
00174455 | [24] showed that both solid-to-solid and liquid-to-solid transitions of CCl 4 were strongly dependent on the average pore size of the material in which the liquid is confined. In particular, they demonstrated that the FCC-to-R transition is no longer observed when the pore radius is smaller than 16.5 nm, which is the case for our silica samples (see Table 1). | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 00154672 | Table 1 :
1 Crystallization half-times (t 0.5exp ) and experimental crystallization rate (G exp ) for photo-oxidation of PEO at 15 °C. Tc was 55°C. | 2007 | [
"chim"
] | [
"899",
"13918",
"789",
"899"
] | [
"6039"
] | 03335630 | LIBS images were validated by comparison with MRI and Raman imaging. This work aims to emphasize LIBS potential as a unique characterization technique to simultaneously monitor the transport of the metallic precursor and organic additive at the very initial times of the maturation stage, which can give new insights to optimize the preparation step of heterogeneous catalysts. | 2021 | [
"chim"
] | [
"300006",
"401841",
"300006",
"300006",
"300006",
"300006",
"401841"
] | [
"772419",
"993111",
"1015599"
] |
00174455 | In our systematic work, we observed that some solvents presenting a low temperature phase transition in the solid state offered even more interest [23]. Indeed, this transition is also affected by the confinement and is an interesting alternative to the use of liquid to solid transition since it is usually much more energetic. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 00154672 | The chosen isothermal temperature (T c ) was 55°C that corresponds to a very low supercooling. So, as stated in reference [5], it can be assumed that the global kinetics of crystallization is controlled by the nucleation step. | 2007 | [
"chim"
] | [
"899",
"13918",
"789",
"899"
] | [
"6039"
] | 03547589 | This may indicate that there was no selectivity between all NADESs for these metabolites. Interestingly, SP-Glu/Gly/W exhibited an HPLC profile closer to hydrophobic NADESs than hydrophilic ones. | 2021 | [
"chim"
] | [
"531015",
"243927",
"531015",
"243927",
"180126",
"180126",
"531015",
"243927",
"531015"
] | [
"1326262",
"766197",
"1109308",
"862741",
"17489",
"19030"
] |
00174455 | The measurement of ∆T by calorimetry or NMR technique leads to thermoporosimetry [16] and NMR cryoporometry [17] respectively. The advantages of both techniques have been discussed extensively [18]. | 2007 | [
"chim"
] | [
"899",
"789",
"13918",
"899"
] | [
"6039"
] | 00154672 | ∆T= T 0 -Tc). It is known that G decreases when T c increases. | 2007 | [
"chim"
] | [
"899",
"13918",
"789",
"899"
] | [
"6039"
] | 03093310 | The reduction profiles are characterized by the presence of one single reduction peak for all investigated catalysts, that however differs in terms of temperature range and maximum. For Ni catalysts containing the rutile titania phase, both the maximum of hydrogen consumption (at 465°C and 460°C for 10 % Ni/P90 and 10 % Ni/P25, respectively) and the peak tail are located at high temperature. | 2020 | [
"chim"
] | [
"439562",
"439562",
"439562",
"439562",
"255208",
"439562"
] | [
"741796",
"1087163"
] |
01744623 | In his final model, [START_REF] Snodgrass | A textbook of arthropod anatomy[END_REF][START_REF] Snodgrass | Evolution of arthropod mechanisms[END_REF][START_REF] Snodgrass | A contribution toward an encyclopedia of insect anatomy[END_REF] considered the whole pleural region of arthropods as resulting from differential sclerotisation of the body-wall or from fragmentation of the coxa. In doing so, he totally abandoned his former subcoxal theory. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | 14"), whereas in other beetles they have become closely associated with gonopods IX to form an ovipositor and then regress. Concomitantly, the previously lateral epipleurites VIII become connected to each other ventromedially. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 00457350 | 2
MEN
Variables Beta coefficient Wald p OR 95 % IC *
APOE 4 genotype 0.77 16.61 < 0.001 2.17 [1.44-3.29]
Stroke 0.77 5.94 0.015 2.17 [1.16-4.05]
IADL 0.54 4.02 0.040 1.72 [1.01-3.00]
Glycemia 0.56 6.36 0.012 1.72 [1.13-2.71]
*Model adjusted by age, education level, centre
WOMEN
Variables Beta coefficient Wald p OR 95 % IC *
APOE 4 genotype 0.82 20.63 < 0.001 2.27 [1.59-3.24]
Depression (cesdt>16) 0.67 12.25 < 0.001 1.96 [1.34-2.87]
Anticholinergic drugs 0.46 4.15 0.041 1.59 [1.05-2.28]
low BMI 0.43 3.39 0.027 1.54 [1.05-2.28]
IADL 0.40 3.39 0.065 1.49 [0.97-2.30]
*Model adjusted by age, education level, centre
† Discrepancies in % reported due to missing values
Acknowledgments
We thank the Génopôle of Lille, the Laboratories of Biochemistry of the University Hospitals of Dijon (Pr Gambert) and Montpellier (Dr Dupuy), the Town Council of Dijon and the Conseil Général of Côte d'Or and the clinical case validation committee of the 3C study. Governments of Aquitaine, Bourgogne and Languedoc-Roussillon and, the Fondation de France, France Alzheimer, the Ministry of Research-Inserm Programme 'Cohorts and collection of biological material'. | 2010 | [
"sdv"
] | [
"139836",
"139836",
"139836",
"101530",
"2951",
"3066",
"139836",
"33166",
"108411",
"139836",
"139836"
] | [
"181466",
"758563",
"756206",
"834297",
"9730"
] |
01744623 | )[END_REF] was progressively led to generalise the term laterocoxite. Bitsch has named "laterocoxite" a small angular scleritesometimes visible in the genital segments of certain Archaeognatha, more rarely in the pregenital segments, and sometimes merged with the coxa-, that was already known as the "subcoxa" [START_REF] Bekker | K stroyeniyu i proiskhozhdeniyu naruzhnykh polovykh pridatkov Thysanura I Hymenoptera [Structure and origin of the external genital appendages of Thysanura and Hymenoptera[END_REF], the "laterosternite" [START_REF] Gustafson | The origin and evolution of the geniatlia of the Insecta[END_REF] or "laterotergite IX" [START_REF] Livingstone | On the morphology and bionomics of Tingis. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | a. In the female, the exodermal genital ducts are well shaped, with oviduct, bursa copulatrix, spermatheca and spermathecal gland. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 03091339 | If during dysbiosis, a SIgA-targeted strain begins to grow faster than crosslinks break, enchained clumps will be formed and a selective pressure will be generated. An alternative to escape this pressure (besides phase variation) is to reduce the growth rate, and in fact for a given antibody crosslinking strength, there is an optimal growth rate for generating planktonic cells [START_REF] Moor | High-avidity IgA protects the intestine by enchaining growing bacteria[END_REF][START_REF] Bansept | Enchained growth and cluster dislocation: A possible mechanism for microbiota homeostasis[END_REF]. | 2020 | [
"sdv"
] | [
"515357",
"515357",
"178899",
"542057",
"352028"
] | [
"804678",
"761270",
"1085703",
"1085704"
] |
01744623 | Le plan structural de l'abdomen des Insectes souligne l'importance morphologique et fonctionnelle de la subcoxa dans l'architecture fondamentale, mais l'étude de tous les Hexapodes indique aussi la présence d'un article plus proximal de l'appendice, la precoxa, qui appartiendrait au plan de base mais serait plus discret car souvent étroitement associé à la subcoxa et/ou au lobe paranotal. Sa position, souvent au flanc ventral du lobe paranotal, s'accorde avec l'hypothèse d'une origine duale de l'aile des Ptérygotes. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | 1. The abdominal spiracles[END_REF] documented the migration of abdominal spiracles in some Scarabaeoidea (Coleoptera), but it is mainly the areas of sclerification of the abdominal wall that differ, depending on whether they are covered and protected by elytra or, in contrast, exposed to the environment. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 03487767 | For that purpose mechanical radial strength tests were performed on fenestrations with a MTS Insight™ tensile testing machine (MTS system corporation, Eden Prairie, Minnesota, USA). The test consisted in inserting two half cylinders (radius 3 mm) in a 7mm diameter fenestration. | 2021 | [
"sdv"
] | [
"1063942",
"300151",
"472222",
"300151",
"472222",
"211628",
"1051097",
"300151",
"472222"
] | [
"1076222",
"1002332"
] |
01744623 | In this context, it should be noted that [START_REF] Bekker | K stroyeniyu i proiskhozhdeniyu naruzhnykh polovykh pridatkov Thysanura I Hymenoptera [Structure and origin of the external genital appendages of Thysanura and Hymenoptera[END_REF] was the first author to correctly interpret epipleurite IX as the subcoxa in machilids (Archaeognatha), lepismatids and nicoletiids (Zygentoma), as well as in Gryllidea (Bekker 1932a,b). This consensus might be extended further: [START_REF] Kukalová-Peck | Origin of the insect wing articulation from the arthropodan leg[END_REF][START_REF] Kukalová-Peck | New Carboniferous Diplura, Monura, and Thysanura, the hexapod ground plan, and the role of thoracic side lobes in the origin of wings of Insecta[END_REF], 1992, 1997, 2008) proposed an original model of the structure of the insect segment and limb based on study of some Carboniferous fossil hexapods. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | The subcoxal theory
The idea that a proximal segment of the appendage, named subcoxa by [START_REF] Heymons | Beiträge zur Morphologie und Entwicklungsgeschichte der Rhynchoten[END_REF], would make up most, if not all, of the pleural and ventral regions, is called the "subcoxal theory". Following the embryological observations of Heymons on Heteroptera, [START_REF] Börner | Die Gliedmassen der Arthropoden[END_REF] promoted and extended this idea to many arthropods, distinguishing (p. 690) between subcoxae that are free, pleural, or integrated into a subcoxosternum. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 00396217 | The MeDi may also indirectly constitute an indicator of a complex set of favorable social and lifestyle factors that contribute to better health. Further research is needed to allow the generalization of these results to other populations and to establish whether the MeDi slows cognitive decline or reduces incident dementia in addition to its cardiovascular benefits. | 2009 | [
"sdv"
] | [
"55677",
"55677",
"55677",
"139836",
"55677",
"96172",
"55677"
] | [
"761369"
] |
01744623 | 11 Figure 11. Distal extremity of the abdomen in beetles, illustrating the dissociation of epipleurites and coxosternites. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | He also described the presence of a small "laterotergite" lying near the spiracle of the pregenital segments, but also on segment VIII, where it is adjacent to the subgenital plate. [START_REF] Kristensen | Heterobathmia valvifer n. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 03142841 | The Compliance Questionnaire of Rheumatology (CQR) was validated in 85 patients with CIRD against as external standard with an electronic medication monitoring; the MASRI (Medication Adherence Self-report Inventory) was validated in 55 patients with SLE against adherence based on pharmacy refill information. The MMAS was validated in 91 patients with gout against medication possession ratio and the MARS (Medication Adherence Report Scale) in 108 patients with RA. | 2021 | [
"sdv"
] | [
"353778",
"353778",
"542132",
"460879",
"1069752",
"107396",
"181744",
"262230",
"412239",
"1002409",
"18258",
"542132",
"18258"
] | [
"1037230",
"756184",
"929631",
"841010",
"984216",
"1091114"
] |
01744623 | (Coleoptera, Carabidae). a. Abdominal segment of a larva, lateral view. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | 7 Figure 7. Diagrams illustrating the rearward displacement of the gonopore in a female insect. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 03196397 | The results from this investigation will help gain a better understanding of the qualitative and quantitative molecular mechanisms controlling the establishment of GA qualities. Material and methods:
Acacia gum samples
Forty seven GA samples from Acacia senegal were provided by NEXIRA company (Rouen, France). | 2020 | [
"sdv"
] | [
"570637",
"570637",
"570637"
] | [
"1092272",
"864938",
"744848"
] |
01744623 | In females, a location of the secondary gonopore at the rear of segment VIII, or even at the rear of segment IX, is observed in most pterygotes. In contrast, gonopore orthotopy corresponds to the primitive condition, in which the primary female gonopore lies at the posterior margin of segment VII, corresponding to its original metameric position. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | This in turn raises new questions. The fundamental pattern of insect abdomen has been illustrated by diagrams that explain the specialisation of the female genital segments with internalisation of the subcoxosternal plates (Deuve 2001a). | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 02390138 | This limitation may be lifted using FRET-based probes, [19] though at the expense of adding two fluorophores, complex antibody-DNA constructs and finely-tuned complementary strands. Noteworthy, this technique has so far only been demonstrated for fixed cells. | 2019 | [
"sdv"
] | [
"541959",
"541959",
"122857",
"559220",
"559220",
"122857",
"122857",
"559220"
] | [
"759112",
"1165696",
"1019342",
"846795",
"782373"
] |
01744623 | The resulting secondary gonopore is then displaced to the rear of segment IX. The primitive (plesiomorphic) seripleural type is present in Archaeognatha, Zygentoma, Dictyoptera and Dermaptera, as well as some exceptional coleopterans belonging to the genus Eustra, which have retained a neotenic abdominal structure [START_REF] Deuve | L'abdomen et les genitalia des femelles de Coléoptères Adephaga[END_REF](Deuve , 2001b) ) (Figure 5). | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | On the genital segments, the gonopods are dissociated from the subcoxosternum and therefore the epipleurites must a fortiori be dissociated. This dissociation is fundamental in the pterygote groundplan. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 03346351 | Then, they could decide to collaborate with epidemiologists to link the collected data with long-term outcomes and response to treatment of patients, collected from patient-reported outcomes and administrative databases. Potential challenges and solutions for COOP' e-cohorts
First, similar to all prospective cohorts, COOP' e-cohorts are threatened by missing follow-up data and attrition bias. | 2020 | [
"sdv"
] | [
"1002414"
] | [
"756868"
] |
01744623 | I. The genus Dendroctonus[END_REF] and [START_REF] Böving | An illustrated synopsis of the principal larval forms of the order Coleoptera[END_REF] became "paratergites" or "laterotergites". | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | Whereas the hypothesis of the internalisation of the whole subcoxosternum in the genital segments of Holometabola seems to be firmly established, the possibility in hemimetabolan insects that some marginal subcoxosternal elements might remain external and, if so, in what proportions, still needs to be evaluated. Also, we have yet to identify the nature of certain small enigmatic sclerites, such as the "tergopleurites" described by [START_REF] Prell | Das Chitinskelett von Eosentomon[END_REF] and the "laterotergites" described by [START_REF] François | Le squelette thoracique des Protoures[END_REF][START_REF] François | Squelette et musculature thoraciques des Protoures[END_REF] in Protura and by [START_REF] Bäcker | A forgotten homology supporting the monophyly of Tracheata: the subcoxa of insects and myriapods re-visited[END_REF] in some Chilopoda. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01332333 | The concentrations of the stock solutions of Paraquat were checked by high-performance liquid chromatography with a method optimized for Paraquat solutions that enables reaching a limit of quantification of 8 ng/L and a limit of detection of 2.4 ng/ L in simple matrices [START_REF] Wang | Determination of Paraquat in vegetables by high performance liquid chromatography[END_REF][START_REF] Restek | Simple, sensitive HPLC/UV analysis for Paraquat and Diquat, using high-recovery solid phase extraction and an ultra Quat HPLC column[END_REF]. The difference between nominal and measured concentrations did not exceed 4%. | 2013 | [
"sdv"
] | [
"430655",
"459316",
"133431",
"1001393"
] | [
"1202803",
"751829",
"735661"
] |
01744623 | Paranotal lobe: Often considered as lateral lobes of the tergum, the paranotal lobes may be tergopleural formations [START_REF] Deuve | Sur la présence d'un "épipleurite" dans le plan de base du segment des Hexapodes[END_REF]). In the theory of the dual origin of the pterygote wing [START_REF] Rasnitsyn | A modified paranotal theory of insect wing origin[END_REF], they have become associated themselves with basal elements of the appendage (eupleural elements) to form the functional wing. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | Cependant, les épipleurites sont habituellement séparés et fonctionnellement dissociés du coxosternum, lequel intègre la composante ventrale de la subcoxa. Chez les femelles, l'épipleurite du segment IX de l'abdomen correspond au gonangulum, comme déjà indiqué par Deuve en 1994 et 2001, et participe à l'articulation du gonopode. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 03821424 | Implications for fitness, selection, and population dynamics
Intraspecific phenotypic variation can also influence population dynamics [START_REF] Pelletier | The evolutionary demography of ecological change: linking trait variation and population growth[END_REF][START_REF] Gibert | The effect of phenotypic variation on metapopulation persistence[END_REF][START_REF] Wright | The more things change, the more they stay the same? When is trait variability important for stability of ecosystem function in a changing environment[END_REF]. | 2022 | [
"sdv"
] | [
"360045",
"1100830",
"25887",
"25887",
"360045",
"1100830"
] | [
"741841"
] |
01744623 | This dissociation is fundamental in the pterygote groundplan. In female Coleoptera, [START_REF] Verhoeff | Zur vergleichenden Morphologie des Abdomens der Coleopteren und über die phylogenetische Bedeutung desselben, zugleich ein zusammenfassender kritischer Rückblick und neuer Beitrag[END_REF] had already pointed out the presence of a "bipartite sternite 8" and Tanner (1927) had written: "in some cases it [the VIIIth sternite] is shield-shaped and divided into two parts on the middle by a small strip of membrane". | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | : a moth with large apparent 'ovipositor valves' (Lepidoptera: Heterobathmiidae)[END_REF] referred to Mickoleit's model, with internalisation of the only primary sternum. It is also important to clearly distinguish between two different types of 'subgenital plates', which are not homologous and should not be confused. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 03359393 | Using this mode of calculation, they report a higher percentage reduction in LDL-C with evolocumab in patients with lower baseline LDL-C levels, compared with a less marked percentage LDL-C reduction with simvastatin at lower baseline LDL-C levels, and no significant reduction of LDL-C levels with ezetimibe at lower baseline values. However, the use of percentage changes might be misleading since it is influenced by absolute baseline values, e.g. | 2020 | [
"sdv"
] | [
"353778",
"542105"
] | [
"990274"
] |
01744623 | Généralités. Composition de l'Embranchement[END_REF] pointed out that this trisegmentation is not primitive, but derived from secondary divisions of a primordial coxa. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | A sclerite of the tergum is a tergite. (Plural: terga)
Venter: The ventral face of the body. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01902490 | Moreover, it is noteworthy that there was a significant increase in turnaround time of the RAS test performed in their institution between 2015 and 2017, for a reason that would be interesting to know. In accordance with our data, results of Barel et al. | 2018 | [
"sdv"
] | [
"185180",
"357175",
"300147",
"182184",
"353860",
"478928",
"28519"
] | [
"855720",
"757353"
] |
01744623 | In theory, ventral components of the precoxae would also be included. The coxosternum, often termed "secondary sternum" in the context of the subcoxal theory, or just ventrite, is clearly visible as the only ventral sclerite of the pterygote pregenital abdominal segments. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | Although the subgenital plate has often been interpreted as resulting from a rearward expansion of segment VII (see review in [START_REF] Bitsch | Morphologie abdominale des Insectes[END_REF], [START_REF] Kristensen | Heterobathmia valvifer n. sp. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 03487650 | Ces résultats sont présentés dans le tableau 2.
et al. (35) décrit, avec un suivi médian de 4,1 ans, une progression pour 43 % des patients, la majorité dans la première année de surveillance. | 2019 | [
"sdv"
] | [
"417758",
"417758",
"505887",
"541278",
"417758",
"417758",
"417758",
"111046",
"182215",
"111046",
"417758",
"182215"
] | [
"766691"
] |
01744623 | [START_REF] Snodgrass | Morphology and mechanism of the insect thorax[END_REF] and [START_REF] Weber | Die Gliederung der Sternopleuralregion des Lepidopterenthorax. Eine vergleichende morphologische Studie zur Subcoxaltheorie[END_REF] later discussed, employed and developed this theory. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | Female ectodermal genitalia of Pachyteles granulatus (Coleoptera, Paussidae). The dashed line separates the oviductal components (segment VII) from the vaginal components (segments VIII and IX). | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 02573103 | Bcr1, biofilm and cell wall regulator 1; Ndt80, non-dityrosine 80; Tec1, transposon enhancement control 1. ). | 2019 | [
"sdv"
] | [
"303242",
"28088",
"303242",
"44110",
"303242",
"434643",
"28088",
"498589",
"28088",
"303242"
] | [
"801320"
] |
01744623 | This area would represent a large part of the dorsal precoxal territory. The same situation can be observed in Coleoptera, but the dorsal part of the subcoxa (epipleurite) and of the precoxa may merge together, or merge with the tergum and even with the coxosternum or with the subcoxosternum such as in segment VIII of certain Scarabaeoidea [START_REF] Ritcher | Spiracles of adult Scarabaeoidea (Coleoptera) and their phylogenetical significance. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | Résumé. Qu'est-ce qu'un épipleurite ? | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 03372832 | 3 Results
Physicochemical characteristics of the nanoparticles
Characteristics of the nanoparticles synthesized for this work were summarized in the figure 1 (for Full data see table S1 in supporting information). The few formulations included in the series known from previous works showed consistent characteristics (R-C (Bertholon et al., 2006a, Bravo-Osuna et al., 2007a,b, Palazzo et al., 2017), R-Dex, A-C (Bertholon et al., 2006a), R-CP2, [START_REF] Petit | The Counterbalanced Effect of Size and Surface Properties of Chitosan-Coated poly(isobutylcyanoacrylate) Nanoparticles on Mucoadhesion Due to Pluronic F68 Addition[END_REF]). | 2021 | [
"sdv"
] | [
"1041778",
"1041778",
"1041778",
"1041778"
] | [
"770729",
"738493"
] |
01744623 | This is precisely what [START_REF] Kobayashi | Embryonic development of Carabus insulicola (Insecta, Coleoptera, Carabidae) with special reference to external morphology and tangible evidence for the subcoxal theory[END_REF] observed in the embryo. In my 2001 paper, I showed that the epipleural areas participate in specialisation of the genital segments by serving as a substitute for the internalised subcoxosternum (formation of the vaginal ducts) through a medio-ventrad shift. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | [START_REF] Uchifune | Embryonic development of Galloisiana yuasai Asahina, with special reference to external morphology (Insecta: Grylloblattodea)[END_REF]. In addition, developmental genetic techniques have definitively confirmed the existence of the subcoxa as a proximal segment of the appendage of the Hexapoda, not only in the thorax, but also in the cephalic segments [START_REF] Coulcher | Molecular developmental evidence for a subcoxal origin of pleurites in insects and identity of the subcoxa in the gnathal appendages[END_REF]. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 03167208 | We assessed the amount of available ivy berries in the orchard hedgerows by counting the number of trees carrying fruiting ivy in all hedgerows bordering each orchard. This defined the ivy independent variable for data analysis. | 2020 | [
"sdv"
] | [
"1002099",
"1002346",
"1002099"
] | [
"1206217",
"753351",
"743451"
] |
01744623 | : defensive gland
ej.duct: ejaculatory duct
epl. : epipleurite
eppd: epipodite
exo: exite
fm: femur plate
fun. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | [START_REF] Emeljanov | The evolutionary role and fate of the primary ovipositor in insects[END_REF] used Klass' observation to give the gonangulum a fundamentally dual nature, with "sternal" and "pleural or pleuroparatergal" components. The question of the identity of the antelaterocoxa in Odonata still deserves scrutiny, but Klass' ( 2008) interpretation of a gonangulum with either one-piece or bipartite condition sounds as corresponding to the nature of epipleurite in either subcoxal or subcoxal + precoxal identity. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 03620393 | L'autophagie peut donc présenter des rôles différents selon le type cellulaire concerné. Plusieurs fonctions essentielles au maintien de l'homéostasie endothéliale sont régulées par l'autophagie. | 2017 | [
"sdv"
] | [
"1004693",
"481195",
"1004693",
"1090311",
"1004693"
] | [
"798060",
"793129",
"781186"
] |
01744623 | I. Das Exoskelet[END_REF], who admits the absence of the true sternum. Indeed, it is certainly in Mecoptera that this bipartite nature of ventrite VIII is most clearly visible. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | Their presence in the abdominal segments of insects illustrates the fundamental importance of the subcoxa in segmental structure, with a function of anchoring and supporting the appendage when the latter is present. However, the epipleurites are normally separated and functionally dissociated from the coxosternum, which integrates the ventral component of the subcoxa. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 03401768 | Validation of the best combination has still to be investigated. Lastly, psychotherapy was also considered in our recommendations and we recommend it for neuropathic pain treatment, particularly cognitive behavioural therapy (CBT) and mindfulness. | 2021 | [
"sdv"
] | [
"166422",
"166422"
] | [
"1077158"
] |
01744623 | [END_REF], 1993, p. 145, "Fig. 219"). | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | Indeed, Snodgrass (1935a) interpreted this larval thoracic anepimerite as a laterotergite or, later (1958), as a pleurite more dorsal than the anapleurite. It must be noted in this respect that Snodgrass himself reproduced an error of Hopkins (1909, "Fig. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 04168571 | This rat had a history of frequent sneezing which had worsened during the previous weeks. The two rats had been in close contact with their owner for cuddles. | 2023 | [
"sdv"
] | [
"1144874",
"1090735",
"1090735",
"1090844"
] | [
"945442",
"734968"
] |
01744623 | While awaiting precise analyses, it is important to assume that an epipleurite, in its current broad sense, may include a precoxal component, often merged with the subcoxal one. This is consistent with the delineation of the epipleurite as initially given by [START_REF] Hopkins | Contributions toward a monograph of the scolytid beetles. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | Certainly, this theory may be extended to more or less all segments, including those of the abdomen. Despite the bitter opposition of [START_REF] Hansen | Studies on Arthropoda II[END_REF], the subcoxal theory prevailed in the following decades, before [START_REF] Snodgrass | A textbook of arthropod anatomy[END_REF][START_REF] Snodgrass | Evolution of arthropod mechanisms[END_REF][START_REF] Snodgrass | A contribution toward an encyclopedia of insect anatomy[END_REF] changed his own mind, and [START_REF] Bekker | Evolution of the leg in Tracheata. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 04021327 | Discussion
Plasma lithography is a practical option for conducting cell micropatterning in which a plasma-shielding mask having microholes or microfeatures of desired shapes is used to spatially restrict originally hydrophobic surfaces to be exposed to oxygen plasma for functionalization [START_REF] Goessl | Control of shape and size of vascular smooth muscle cells in vitro by plasma lithography[END_REF][START_REF] Rossi | Plasma-micropatterning of albumin nanoparticles: Substrates for enhanced cell-interactive display of ligands[END_REF][START_REF] Junkin | Probing cell migration in confined environments by plasma lithography[END_REF][START_REF] Deguchi | Development of motorized plasma lithography for cell patterning[END_REF]. The remaining hydrophobic regions are treated with protein-resistant chemicals such as Pluronic F-127. | 2015 | [
"sdv"
] | [
"1155465",
"1155466",
"1155467",
"1155467"
] | [
"1235446"
] |
01744623 | I. Das Exoskelet[END_REF], who admits the absence of the true sternum. Indeed, it is certainly in Mecoptera that this bipartite nature of ventrite VIII is most clearly visible. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | Respiratory organs-the spiracles in Hexapoda and Myriapoda-are located in this laterodorsal region. [START_REF] Crampton | Notes on the thoracic sclerites of winged insects[END_REF] proposed the name eupleurites for the pleural sclerites belonging to the limb, and [START_REF] Prell | Das Chitinskelett von Eosentomon[END_REF] introduced the term tergopleurites for those which, being 'not appendicular', are located between the base of the limb and the genuine tergum (the paranotal lobes could probably be included among these). | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 04223158 | FRC, functional residual capacity. Figure 17 :
17 Figure 17: illustration of Airway Opening Index on clinical capnograms
Figure 17 :
17 Figure 17: Clinical capnograms obtained from Grieco et al. | 2023 | [
"sdv"
] | [
"484896"
] | [
"1288867"
] |
01744623 | with a median relictual subcoxosternal area) has never been reported. In pterygote insects, it appears that the coxosternum of each abdominal segment forms an undivided ventral plate (= ventrite), with only few examples of fragmentation being known. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | (2012) reported the existence of these two joints as "a cranial element of gonocoxite IX articulating with the laterotergite IX [what I named epipleurite IX], and a caudal element bearing a stylus". In his most recent studies on adephagans, Ball names these joints "gonocoxite 1" and "gonocoxite 2", i.e. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01981546 | Both are partially metabolized by CYP3A4 and the main route of excretion is into faeces, with <1% in urine. Both drugs are extensively bound to plasma proteins. | 2018 | [
"sdv"
] | [
"300992",
"542085",
"353778",
"541997",
"353778"
] | [
"890276",
"759698"
] |
01744623 | I. The genus Dendroctonus[END_REF] with respect to the abdomen. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | Subcoxal theory and a critique of it[END_REF] criticised Heymons' observations and Börner's old interpretations of the articulation of the limb on the pleuron, but he seems to have been unaware of the fundamental works of Snodgrass and Weber, not citing any bibliographical reference after 1913. For [START_REF] Sharov | Basic arthropodan stock[END_REF], the pleuron of the pterygotes was essentially precoxal in nature ("pleuron" or "basal joint corresponding to the crustacean precoxopodite", p. 186-187, see also the present Figure 2), the true subcoxa being reduced to the trochantin (the latter would then be a genuine segment-the subcoxa-and not a fragment of the coxa as Snodgrass claimed in his subcoxal theory). | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 03491552 | Therefore, particles size measurements were performed on mango purees to assess the size distribution of their suspended insoluble solids in relation with mango maturation stage and puree rheological properties. Fig. | 2020 | [
"sdv"
] | [
"31878",
"301405",
"31878",
"31878",
"94474",
"31878",
"301405"
] | [
"785977",
"785953"
] |
01744623 | In contrast, gonopore orthotopy corresponds to the primitive condition, in which the primary female gonopore lies at the posterior margin of segment VII, corresponding to its original metameric position. True orthotopy has been reported in Archaeognatha, Zygentoma and, very exceptionally, in partially neotenic Coleoptera belonging to the genus Eustra [START_REF] Deuve | L'abdomen et les genitalia des femelles de Coléoptères Adephaga[END_REF](Deuve , 2001a)). | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | The primitive (plesiomorphic) seripleural type is present in Archaeognatha, Zygentoma, Dictyoptera and Dermaptera, as well as some exceptional coleopterans belonging to the genus Eustra, which have retained a neotenic abdominal structure [START_REF] Deuve | L'abdomen et les genitalia des femelles de Coléoptères Adephaga[END_REF](Deuve , 2001b) ) (Figure 5). The sympleural-I type is present in Odonata, orthopteroids, Hymenoptera, Neuropterida, Coleoptera and Diptera; the sympleural-II type occurs in Trichoptera, Lepidoptera and Mecoptera (Deuve 2001a). | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 03510360 | They are characterized by the presence of basophilic granules, several Pattern Recognition Receptors (PRRs) and the strong expression of the Fragment crystallizable (Fc) Receptor (R) epsilon (FcεR), the immunoglobulin E receptor. With critical roles in allergy-related inflammation processes, basophils can be activated either in an Immunoglobulin (Ig) E mediated way or in cytokine-related manners. | 2019 | [
"sdv"
] | [
"93800"
] | [
"795410"
] |
01744623 | In the 'sympleural-I' type the eighth epipleurites merge and participate in the formation of a 'subgenital plate', while gonopods VIII move rearwards to form a functional ovipositor in association with gonopods IX. In the 'sympleural-II' type, the eighth epipleurites form the first subgenital plate, but the ninth epipleurites also merge together to form a second subgenital plate, while the gonopods are no longer visible. | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 01744623 | In contrast, gonopore orthotopy corresponds to the primitive condition, in which the primary female gonopore lies at the posterior margin of segment VII, corresponding to its original metameric position. True orthotopy has been reported in Archaeognatha, Zygentoma and, very exceptionally, in partially neotenic Coleoptera belonging to the genus Eustra [START_REF] Deuve | L'abdomen et les genitalia des femelles de Coléoptères Adephaga[END_REF](Deuve , 2001a)). | 2018 | [
"sdv"
] | [
"519585"
] | [
"1240975"
] | 02361752 | This allowed us to control the characteristics of the polyphasic spike of the cell studied in order to insure that the same cell was recorded over all the experimental procedure. 13. | 1999 | [
"sdv"
] | [
"550",
"550",
"550"
] | [
"766399"
] |
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