ID,Question_std,Question_CoT,Question_chem,Reaction1,Reaction2,Reaction3,Intermediate
0,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)OC(=O)CCCCCCC(=O)NCCCOCCOCCOCCCNC(=O)CCC(=O)ON1C(=O)CCC1=O</SMILES> starting from <SMILES>O=C1CCC(=O)O1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C1CCC(=O)O1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)OC(=O)CCCCCCC(=O)NCCCOCCOCCOCCCNC(=O)CCC(=O)ON1C(=O)CCC1=O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)OC(=O)CCCCCCC(=O)NCCCOCCOCCOCCCNC(=O)CCC(=O)ON1C(=O)CCC1=O</SMILES> starting from <SMILES>O=C1CCC(=O)O1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C1CCC(=O)O1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)OC(=O)CCCCCCC(=O)NCCCOCCOCCOCCCNC(=O)CCC(=O)ON1C(=O)CCC1=O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)OC(=O)CCCCCCC(=O)NCCCOCCOCCOCCCNC(=O)CCC(=O)ON1C(=O)CCC1=O</SMILES> starting from <SMILES>O=C1CCC(=O)O1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C1CCC(=O)O1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)OC(=O)CCCCCCC(=O)NCCCOCCOCCOCCCNC(=O)CCC(=O)ON1C(=O)CCC1=O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CC(C)(C)OC(=O)NCCCOCCOCCOCCCN.O=C1CCC(=O)O1>>CC(C)(C)OC(=O)NCCCOCCOCCOCCCNC(=O)CCC(=O)O'],['CC(C)(C)OC(=O)CCCCCCC(=O)ON1C(=O)CCC1=O.CC(C)(C)OC(=O)NCCCOCCOCCOCCCNC(=O)CCC(=O)O>O=C(O)C(F)(F)F>CC(C)(C)OC(=O)CCCCCCC(=O)NCCCOCCOCCOCCCNC(=O)CCC(=O)O'],['CC(C)(C)OC(=O)CCCCCCC(=O)NCCCOCCOCCOCCCNC(=O)CCC(=O)O.CN(C)C(ON1C(=O)CCC1=O)=[N+](C)C.F[B-](F)(F)F>>CC(C)(C)OC(=O)CCCCCCC(=O)NCCCOCCOCCOCCCNC(=O)CCC(=O)ON1C(=O)CCC1=O'],"[['CC(C)(C)OC(=O)NCCCOCCOCCOCCCNC(=O)CCC(=O)O', 'CC(C)(C)OC(=O)CCCCCCC(=O)NCCCOCCOCCOCCCNC(=O)CCC(=O)O']]"
1,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCNC(=O)Nc1cc(-c2nc(C(F)(F)F)cs2)c(-c2ccc3c(c2)c(=O)c(C(=O)N2CCN(C(=O)OC(C)(C)C)CC2)cn3C(COC)COC)cn1</SMILES> starting from <SMILES>CCOC(=O)c1cn(C(COC)COC)c2ccc(I)cc2c1=O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)c1cn(C(COC)COC)c2ccc(I)cc2c1=O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCNC(=O)Nc1cc(-c2nc(C(F)(F)F)cs2)c(-c2ccc3c(c2)c(=O)c(C(=O)N2CCN(C(=O)OC(C)(C)C)CC2)cn3C(COC)COC)cn1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCNC(=O)Nc1cc(-c2nc(C(F)(F)F)cs2)c(-c2ccc3c(c2)c(=O)c(C(=O)N2CCN(C(=O)OC(C)(C)C)CC2)cn3C(COC)COC)cn1</SMILES> starting from <SMILES>CCOC(=O)c1cn(C(COC)COC)c2ccc(I)cc2c1=O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)c1cn(C(COC)COC)c2ccc(I)cc2c1=O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCNC(=O)Nc1cc(-c2nc(C(F)(F)F)cs2)c(-c2ccc3c(c2)c(=O)c(C(=O)N2CCN(C(=O)OC(C)(C)C)CC2)cn3C(COC)COC)cn1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCNC(=O)Nc1cc(-c2nc(C(F)(F)F)cs2)c(-c2ccc3c(c2)c(=O)c(C(=O)N2CCN(C(=O)OC(C)(C)C)CC2)cn3C(COC)COC)cn1</SMILES> starting from <SMILES>CCOC(=O)c1cn(C(COC)COC)c2ccc(I)cc2c1=O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)c1cn(C(COC)COC)c2ccc(I)cc2c1=O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCNC(=O)Nc1cc(-c2nc(C(F)(F)F)cs2)c(-c2ccc3c(c2)c(=O)c(C(=O)N2CCN(C(=O)OC(C)(C)C)CC2)cn3C(COC)COC)cn1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CCOC(=O)c1cn(C(COC)COC)c2ccc(I)cc2c1=O>C1CCOC1.O.[Li+].[OH-]>COCC(COC)n1cc(C(=O)O)c(=O)c2cc(I)ccc21'],['CC(C)(C)OC(=O)N1CCNCC1.COCC(COC)n1cc(C(=O)O)c(=O)c2cc(I)ccc21>CCN=C=NCCCN(C)C.CN1CCOCC1.Cl.ClCCl.Oc1cccc2[nH]nnc12>COCC(COC)n1cc(C(=O)N2CCN(C(=O)OC(C)(C)C)CC2)c(=O)c2cc(I)ccc21'],['CCNC(=O)Nc1cc(-c2nc(C(F)(F)F)cs2)c(B2OC(C)(C)C(C)(C)O2)cn1.COCC(COC)n1cc(C(=O)N2CCN(C(=O)OC(C)(C)C)CC2)c(=O)c2cc(I)ccc21>CN(C)C=O.O.O=C([O-])[O-].[Na+].[Na+].c1ccc([P](c2ccccc2)(c2ccccc2)[Pd]([P](c2ccccc2)(c2ccccc2)c2ccccc2)([P](c2ccccc2)(c2ccccc2)c2ccccc2)[P](c2ccccc2)(c2ccccc2)c2ccccc2)cc1>CCNC(=O)Nc1cc(-c2nc(C(F)(F)F)cs2)c(-c2ccc3c(c2)c(=O)c(C(=O)N2CCN(C(=O)OC(C)(C)C)CC2)cn3C(COC)COC)cn1'],"[['COCC(COC)n1cc(C(=O)O)c(=O)c2cc(I)ccc21', 'COCC(COC)n1cc(C(=O)N2CCN(C(=O)OC(C)(C)C)CC2)c(=O)c2cc(I)ccc21']]"
2,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)N1C=Cc2nc3ccccc3c(C)c2CC1.Cl</SMILES> starting from <SMILES>CCOC(=O)N1CCc2c(nc3ccccc3c2C)C(O)C1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)N1CCc2c(nc3ccccc3c2C)C(O)C1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)N1C=Cc2nc3ccccc3c(C)c2CC1.Cl</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)N1C=Cc2nc3ccccc3c(C)c2CC1.Cl</SMILES> starting from <SMILES>CCOC(=O)N1CCc2c(nc3ccccc3c2C)C(O)C1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)N1CCc2c(nc3ccccc3c2C)C(O)C1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)N1C=Cc2nc3ccccc3c(C)c2CC1.Cl</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)N1C=Cc2nc3ccccc3c(C)c2CC1.Cl</SMILES> starting from <SMILES>CCOC(=O)N1CCc2c(nc3ccccc3c2C)C(O)C1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)N1CCc2c(nc3ccccc3c2C)C(O)C1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)N1C=Cc2nc3ccccc3c(C)c2CC1.Cl</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CCOC(=O)N1CCc2c(nc3ccccc3c2C)C(O)C1.O=S(Cl)Cl>>CCOC(=O)N1CCc2c(nc3ccccc3c2C)C(Cl)C1'],['CCOC(=O)N1CCc2c(nc3ccccc3c2C)C(Cl)C1>CCO.CC[O-].[Na+]>Cc1c2c(nc3ccccc13)C=CNCC2'],['CCOC(=O)Cl.Cc1c2c(nc3ccccc13)C=CNCC2>>CCOC(=O)N1C=Cc2nc3ccccc3c(C)c2CC1.Cl'],"[['CCOC(=O)N1CCc2c(nc3ccccc3c2C)C(Cl)C1', 'Cc1c2c(nc3ccccc13)C=CNCC2']]"
3,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC1(C(=O)O)CCC(OCc2ccccc2)CC1</SMILES> starting from <SMILES>NC(=O)C1CCC(OCc2ccccc2)CC1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>NC(=O)C1CCC(OCc2ccccc2)CC1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC1(C(=O)O)CCC(OCc2ccccc2)CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC1(C(=O)O)CCC(OCc2ccccc2)CC1</SMILES> starting from <SMILES>NC(=O)C1CCC(OCc2ccccc2)CC1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>NC(=O)C1CCC(OCc2ccccc2)CC1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC1(C(=O)O)CCC(OCc2ccccc2)CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC1(C(=O)O)CCC(OCc2ccccc2)CC1</SMILES> starting from <SMILES>NC(=O)C1CCC(OCc2ccccc2)CC1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>NC(=O)C1CCC(OCc2ccccc2)CC1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC1(C(=O)O)CCC(OCc2ccccc2)CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['NC(=O)C1CCC(OCc2ccccc2)CC1>C1CCOC1.O.O=C(OC(=O)C(F)(F)F)C(F)(F)F>N#CC1CCC(OCc2ccccc2)CC1'],['CC(=O)O.N#CC1CCC(OCc2ccccc2)CC1>Cl>O=C(O)C1CCC(OCc2ccccc2)CC1'],['CI.O=C(O)C1CCC(OCc2ccccc2)CC1>C1CCOC1.CC(C)NC(C)C.CC(C)[N-]C(C)C.[Li+].[Li]CCCC>CC1(C(=O)O)CCC(OCc2ccccc2)CC1'],"[['N#CC1CCC(OCc2ccccc2)CC1', 'O=C(O)C1CCC(OCc2ccccc2)CC1']]"
4,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOc1ccc(C(C)=NOCCOc2ccc(CC3SC(=O)N(C(c4ccccc4)(c4ccccc4)c4ccccc4)C3=O)cc2)cn1</SMILES> starting from <SMILES>ClC(c1ccccc1)(c1ccccc1)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>ClC(c1ccccc1)(c1ccccc1)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOc1ccc(C(C)=NOCCOc2ccc(CC3SC(=O)N(C(c4ccccc4)(c4ccccc4)c4ccccc4)C3=O)cc2)cn1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOc1ccc(C(C)=NOCCOc2ccc(CC3SC(=O)N(C(c4ccccc4)(c4ccccc4)c4ccccc4)C3=O)cc2)cn1</SMILES> starting from <SMILES>ClC(c1ccccc1)(c1ccccc1)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>ClC(c1ccccc1)(c1ccccc1)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOc1ccc(C(C)=NOCCOc2ccc(CC3SC(=O)N(C(c4ccccc4)(c4ccccc4)c4ccccc4)C3=O)cc2)cn1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOc1ccc(C(C)=NOCCOc2ccc(CC3SC(=O)N(C(c4ccccc4)(c4ccccc4)c4ccccc4)C3=O)cc2)cn1</SMILES> starting from <SMILES>ClC(c1ccccc1)(c1ccccc1)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>ClC(c1ccccc1)(c1ccccc1)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOc1ccc(C(C)=NOCCOc2ccc(CC3SC(=O)N(C(c4ccccc4)(c4ccccc4)c4ccccc4)C3=O)cc2)cn1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['CC(=O)Oc1ccc(CC2SC(=O)NC2=O)cc1.ClC(c1ccccc1)(c1ccccc1)c1ccccc1>CCN(CC)CC.CCOC(C)=O.ClCCl.O>CC(=O)Oc1ccc(CC2SC(=O)N(C(c3ccccc3)(c3ccccc3)c3ccccc3)C2=O)cc1', 'CC(=O)Oc1ccc(CC2SC(=O)NC2=O)cc1.ClC(c1ccccc1)(c1ccccc1)c1ccccc1>CCOC(C)=O.CN(C)C.ClCCl.O>CC(=O)Oc1ccc(CC2SC(=O)N(C(c3ccccc3)(c3ccccc3)c3ccccc3)C2=O)cc1', 'CC(=O)Oc1ccc(CC2SC(=O)NC2=O)cc1.ClC(c1ccccc1)(c1ccccc1)c1ccccc1>CCOC(C)=O.CN(C)C.ClCCl.O>CC(=O)Oc1ccc(CC2SC(=O)N(C(c3ccccc3)(c3ccccc3)c3ccccc3)C2=O)cc1']","['CC(=O)Oc1ccc(CC2SC(=O)N(C(c3ccccc3)(c3ccccc3)c3ccccc3)C2=O)cc1>CO.C[O-].Cc1ccccc1.Cl.[Na+]>O=C1SC(Cc2ccc(O)cc2)C(=O)N1C(c1ccccc1)(c1ccccc1)c1ccccc1', 'CC(=O)Oc1ccc(CC2SC(=O)N(C(c3ccccc3)(c3ccccc3)c3ccccc3)C2=O)cc1>CO.C[O-].Cc1ccccc1.Cl.[Na+]>O=C1SC(Cc2ccc(O)cc2)C(=O)N1C(c1ccccc1)(c1ccccc1)c1ccccc1', 'CC(=O)Oc1ccc(CC2SC(=O)N(C(c3ccccc3)(c3ccccc3)c3ccccc3)C2=O)cc1>CO.Cc1ccccc1.Cl>O=C1SC(Cc2ccc(O)cc2)C(=O)N1C(c1ccccc1)(c1ccccc1)c1ccccc1']","['CCOc1ccc(C(C)=NOCCO)cn1.O=C1SC(Cc2ccc(O)cc2)C(=O)N1C(c1ccccc1)(c1ccccc1)c1ccccc1>CCOC(=O)N=NC(=O)OCC.c1ccc(P(c2ccccc2)c2ccccc2)cc1>CCOc1ccc(C(C)=NOCCOc2ccc(CC3SC(=O)N(C(c4ccccc4)(c4ccccc4)c4ccccc4)C3=O)cc2)cn1', 'CCOc1ccc(C(C)=NOCCO)cn1.O=C1SC(Cc2ccc(O)cc2)C(=O)N1C(c1ccccc1)(c1ccccc1)c1ccccc1>CCOC(=O)N=NC(=O)OCC.c1ccc(P(c2ccccc2)c2ccccc2)cc1>CCOc1ccc(C(C)=NOCCOc2ccc(CC3SC(=O)N(C(c4ccccc4)(c4ccccc4)c4ccccc4)C3=O)cc2)cn1', 'CCOc1ccc(C(C)=NOCCO)cn1.O=C1SC(Cc2ccc(O)cc2)C(=O)N1C(c1ccccc1)(c1ccccc1)c1ccccc1>CCOC(=O)N=NC(=O)OCC.c1ccc(P(c2ccccc2)c2ccccc2)cc1>CCOc1ccc(C(C)=NOCCOc2ccc(CC3SC(=O)N(C(c4ccccc4)(c4ccccc4)c4ccccc4)C3=O)cc2)cn1']","[['CC(=O)Oc1ccc(CC2SC(=O)N(C(c3ccccc3)(c3ccccc3)c3ccccc3)C2=O)cc1', 'O=C1SC(Cc2ccc(O)cc2)C(=O)N1C(c1ccccc1)(c1ccccc1)c1ccccc1']]"
5,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CN1Cc2ccc(-c3ccc(-c4cncc(NC(=O)OC(C)(C)C)c4)s3)cc2C1=O</SMILES> starting from <SMILES>CN(C)B(B(N(C)C)N(C)C)N(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CN(C)B(B(N(C)C)N(C)C)N(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CN1Cc2ccc(-c3ccc(-c4cncc(NC(=O)OC(C)(C)C)c4)s3)cc2C1=O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CN1Cc2ccc(-c3ccc(-c4cncc(NC(=O)OC(C)(C)C)c4)s3)cc2C1=O</SMILES> starting from <SMILES>CN(C)B(B(N(C)C)N(C)C)N(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CN(C)B(B(N(C)C)N(C)C)N(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CN1Cc2ccc(-c3ccc(-c4cncc(NC(=O)OC(C)(C)C)c4)s3)cc2C1=O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CN1Cc2ccc(-c3ccc(-c4cncc(NC(=O)OC(C)(C)C)c4)s3)cc2C1=O</SMILES> starting from <SMILES>CN(C)B(B(N(C)C)N(C)C)N(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CN(C)B(B(N(C)C)N(C)C)N(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CN1Cc2ccc(-c3ccc(-c4cncc(NC(=O)OC(C)(C)C)c4)s3)cc2C1=O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CC(C)(O)C(C)(C)O.CN(C)B(B(N(C)C)N(C)C)N(C)C>CCOCC>CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C'],['CC(C)(C)OC(=O)Nc1cncc(Br)c1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C>C1COCCO1.CC(=O)[O-].[K+]>CC(C)(C)OC(=O)Nc1cncc(B2OC(C)(C)C(C)(C)O2)c1'],['CC(C)(C)OC(=O)Nc1cncc(B2OC(C)(C)C(C)(C)O2)c1.CN1Cc2ccc(-c3ccc(I)s3)cc2C1=O>>CN1Cc2ccc(-c3ccc(-c4cncc(NC(=O)OC(C)(C)C)c4)s3)cc2C1=O'],"[['CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C', 'CC(C)(C)OC(=O)Nc1cncc(B2OC(C)(C)C(C)(C)O2)c1']]"
6,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)OC(=O)N1CCCCC1/C=N\S(=O)C(C)(C)C</SMILES> starting from <SMILES>CCOC(=O)C1CCNCC1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)C1CCNCC1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)OC(=O)N1CCCCC1/C=N\S(=O)C(C)(C)C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)OC(=O)N1CCCCC1/C=N\S(=O)C(C)(C)C</SMILES> starting from <SMILES>CCOC(=O)C1CCNCC1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)C1CCNCC1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)OC(=O)N1CCCCC1/C=N\S(=O)C(C)(C)C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)OC(=O)N1CCCCC1/C=N\S(=O)C(C)(C)C</SMILES> starting from <SMILES>CCOC(=O)C1CCNCC1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)C1CCNCC1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)OC(=O)N1CCCCC1/C=N\S(=O)C(C)(C)C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CC(C)(C)OC(=O)OC(=O)OC(C)(C)C.CCOC(=O)C1CCNCC1>C1CCOC1>CC(C)(C)OC(=O)N1CCCCC1'],['CC(C)(C)OC(=O)N1CCCCC1.CN(C)C=O>CCOCC.CN(C)CCN(C)C.[Li]C(C)CC>CC(C)(C)OC(=O)N1CCCCC1C=O'],['CC(C)(C)OC(=O)N1CCCCC1C=O.CC(C)(C)S(N)=O>C1CCOC1.CCOC(C)=O.CC[O-].CC[O-].CC[O-].CC[O-].O.[Cl-].[Na+].[Ti+4]>CC(C)(C)OC(=O)N1CCCCC1/C=N\\S(=O)C(C)(C)C'],"[['CC(C)(C)OC(=O)N1CCCCC1', 'CC(C)(C)OC(=O)N1CCCCC1C=O']]"
7,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1cc(Nc2nc3c(c(C(C)n4nc(C)cc4C)n2)CNCC3)ccc1-n1cnc(C)c1</SMILES> starting from <SMILES>N#CN</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>N#CN</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1cc(Nc2nc3c(c(C(C)n4nc(C)cc4C)n2)CNCC3)ccc1-n1cnc(C)c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1cc(Nc2nc3c(c(C(C)n4nc(C)cc4C)n2)CNCC3)ccc1-n1cnc(C)c1</SMILES> starting from <SMILES>N#CN</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>N#CN</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1cc(Nc2nc3c(c(C(C)n4nc(C)cc4C)n2)CNCC3)ccc1-n1cnc(C)c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1cc(Nc2nc3c(c(C(C)n4nc(C)cc4C)n2)CNCC3)ccc1-n1cnc(C)c1</SMILES> starting from <SMILES>N#CN</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>N#CN</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1cc(Nc2nc3c(c(C(C)n4nc(C)cc4C)n2)CNCC3)ccc1-n1cnc(C)c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['COc1cc(N)ccc1-n1cnc(C)c1.Cl.N#CN>CCO.Cl.O>COc1cc(NC(=N)N)ccc1-n1cnc(C)c1'],['COc1cc(NC(=N)N)ccc1-n1cnc(C)c1.Cc1cc(C)n(C(C)C(=O)C2CN(C(=O)OC(C)(C)C)CCC2=O)n1>CCO.O=C([O-])[O-].[K+].[K+]>COc1cc(Nc2nc3c(c(C(C)n4nc(C)cc4C)n2)CN(C(=O)OC(C)(C)C)CC3)ccc1-n1cnc(C)c1'],['COc1cc(Nc2nc3c(c(C(C)n4nc(C)cc4C)n2)CN(C(=O)OC(C)(C)C)CC3)ccc1-n1cnc(C)c1>ClCCl.O=C(O)C(F)(F)F.O=C([O-])O.[Na+]>COc1cc(Nc2nc3c(c(C(C)n4nc(C)cc4C)n2)CNCC3)ccc1-n1cnc(C)c1'],"[['COc1cc(NC(=N)N)ccc1-n1cnc(C)c1', 'COc1cc(Nc2nc3c(c(C(C)n4nc(C)cc4C)n2)CN(C(=O)OC(C)(C)C)CC3)ccc1-n1cnc(C)c1']]"
8,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>C=C(C)C[C@]1(C(=O)OC)CC(=O)N(c2c(C)cccc2C)C1</SMILES> starting from <SMILES>C=C(C)CC1(C(=O)OC)CC(=O)N(c2c(C)cccc2C)C1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C=C(C)CC1(C(=O)OC)CC(=O)N(c2c(C)cccc2C)C1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>C=C(C)C[C@]1(C(=O)OC)CC(=O)N(c2c(C)cccc2C)C1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>C=C(C)C[C@]1(C(=O)OC)CC(=O)N(c2c(C)cccc2C)C1</SMILES> starting from <SMILES>C=C(C)CC1(C(=O)OC)CC(=O)N(c2c(C)cccc2C)C1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C=C(C)CC1(C(=O)OC)CC(=O)N(c2c(C)cccc2C)C1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>C=C(C)C[C@]1(C(=O)OC)CC(=O)N(c2c(C)cccc2C)C1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>C=C(C)C[C@]1(C(=O)OC)CC(=O)N(c2c(C)cccc2C)C1</SMILES> starting from <SMILES>C=C(C)CC1(C(=O)OC)CC(=O)N(c2c(C)cccc2C)C1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C=C(C)CC1(C(=O)OC)CC(=O)N(c2c(C)cccc2C)C1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>C=C(C)C[C@]1(C(=O)OC)CC(=O)N(c2c(C)cccc2C)C1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['C=C(C)CC1(C(=O)OC)CC(=O)N(c2c(C)cccc2C)C1>CO.[Li+].[OH-]>C=C(C)CC1(C(=O)O)CC(=O)N(c2c(C)cccc2C)C1'],['C=C(C)CC1(C(=O)O)CC(=O)N(c2c(C)cccc2C)C1>CC(C)O.COc1cc2c(cc1OC)[C@@]13CCN4CC5=CCO[C@H]6CC(=O)N2[C@H]1[C@H]6[C@H]5C[C@H]43>C=C(C)C[C@]1(C(=O)O)CC(=O)N(c2c(C)cccc2C)C1'],['C=C(C)C[C@]1(C(=O)O)CC(=O)N(c2c(C)cccc2C)C1.C[Si](C)(C)C=[N+]=[N-]>CO>C=C(C)C[C@]1(C(=O)OC)CC(=O)N(c2c(C)cccc2C)C1'],"[['C=C(C)CC1(C(=O)O)CC(=O)N(c2c(C)cccc2C)C1', 'C=C(C)C[C@]1(C(=O)O)CC(=O)N(c2c(C)cccc2C)C1']]"
9,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)COc1ccc(CCc2sc(-c3ccc(C(F)(F)F)cc3)nc2C)cc1C</SMILES> starting from <SMILES>Cc1nc(-c2ccc(C(F)(F)F)cc2)sc1CO</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Cc1nc(-c2ccc(C(F)(F)F)cc2)sc1CO</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)COc1ccc(CCc2sc(-c3ccc(C(F)(F)F)cc3)nc2C)cc1C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)COc1ccc(CCc2sc(-c3ccc(C(F)(F)F)cc3)nc2C)cc1C</SMILES> starting from <SMILES>Cc1nc(-c2ccc(C(F)(F)F)cc2)sc1CO</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Cc1nc(-c2ccc(C(F)(F)F)cc2)sc1CO</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)COc1ccc(CCc2sc(-c3ccc(C(F)(F)F)cc3)nc2C)cc1C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)COc1ccc(CCc2sc(-c3ccc(C(F)(F)F)cc3)nc2C)cc1C</SMILES> starting from <SMILES>Cc1nc(-c2ccc(C(F)(F)F)cc2)sc1CO</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Cc1nc(-c2ccc(C(F)(F)F)cc2)sc1CO</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)COc1ccc(CCc2sc(-c3ccc(C(F)(F)F)cc3)nc2C)cc1C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['Cc1nc(-c2ccc(C(F)(F)F)cc2)sc1CO>ClC(Cl)Cl.O=[Mn]=O>Cc1nc(-c2ccc(C(F)(F)F)cc2)sc1C=O', 'Cc1nc(-c2ccc(C(F)(F)F)cc2)sc1CO>ClC(Cl)Cl.[Mn+4].[O-2].[O-2]>Cc1nc(-c2ccc(C(F)(F)F)cc2)sc1C=O']","['CCOC(=O)COc1ccc(C[P+](c2ccccc2)(c2ccccc2)c2ccccc2)cc1C.Cc1nc(-c2ccc(C(F)(F)F)cc2)sc1C=O.[Cl-]>CCO.O.[H-].[Na+]>CCOC(=O)COc1ccc(C=Cc2sc(-c3ccc(C(F)(F)F)cc3)nc2C)cc1C', 'CCOC(=O)COc1ccc(C[P+](c2ccccc2)(c2ccccc2)c2ccccc2)cc1C.Cc1nc(-c2ccc(C(F)(F)F)cc2)sc1C=O.[Cl-]>CCO.O.[H-].[Na+]>CCOC(=O)COc1ccc(C=Cc2sc(-c3ccc(C(F)(F)F)cc3)nc2C)cc1C']","['CCOC(=O)COc1ccc(C=Cc2sc(-c3ccc(C(F)(F)F)cc3)nc2C)cc1C>C1COCCO1.CCO.[Pd]>CCOC(=O)COc1ccc(CCc2sc(-c3ccc(C(F)(F)F)cc3)nc2C)cc1C', 'CCOC(=O)COc1ccc(C=Cc2sc(-c3ccc(C(F)(F)F)cc3)nc2C)cc1C>C1COCCO1.CCO.[Pd]>CCOC(=O)COc1ccc(CCc2sc(-c3ccc(C(F)(F)F)cc3)nc2C)cc1C']","[['Cc1nc(-c2ccc(C(F)(F)F)cc2)sc1C=O', 'CCOC(=O)COc1ccc(C=Cc2sc(-c3ccc(C(F)(F)F)cc3)nc2C)cc1C']]"
10,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)OC(=O)n1c(CN(CCCCN2C(=O)c3ccccc3C2=O)C2CCCc3nccnc32)nc2ccccc21</SMILES> starting from <SMILES>O=C(O)CCl</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)CCl</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)OC(=O)n1c(CN(CCCCN2C(=O)c3ccccc3C2=O)C2CCCc3nccnc32)nc2ccccc21</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)OC(=O)n1c(CN(CCCCN2C(=O)c3ccccc3C2=O)C2CCCc3nccnc32)nc2ccccc21</SMILES> starting from <SMILES>O=C(O)CCl</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)CCl</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)OC(=O)n1c(CN(CCCCN2C(=O)c3ccccc3C2=O)C2CCCc3nccnc32)nc2ccccc21</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)OC(=O)n1c(CN(CCCCN2C(=O)c3ccccc3C2=O)C2CCCc3nccnc32)nc2ccccc21</SMILES> starting from <SMILES>O=C(O)CCl</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)CCl</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)OC(=O)n1c(CN(CCCCN2C(=O)c3ccccc3C2=O)C2CCCc3nccnc32)nc2ccccc21</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['Nc1ccccc1N.O=C(O)CCl>Cl.N.O.O>ClCc1nc2ccccc2[nH]1', 'Nc1ccccc1N.O=C(O)CCl>Cl.N.O.O>ClCc1nc2ccccc2[nH]1']","['CC(C)(C)OC(=O)OC(=O)OC(C)(C)C.ClCc1nc2ccccc2[nH]1>CN(C)c1ccncc1.ClCCl>CC(C)(C)OC(=O)n1c(CCl)nc2ccccc21', 'CC(C)(C)OC(=O)OC(=O)OC(C)(C)C.ClCc1nc2ccccc2[nH]1>C1CCOC1.CN(C)c1ccncc1>CC(C)(C)OC(=O)n1c(CCl)nc2ccccc21']","['CC(C)(C)OC(=O)n1c(CCl)nc2ccccc21.O=C1c2ccccc2C(=O)N1CCCCNC1CCCc2nccnc21>CC#N.CCN(C(C)C)C(C)C.O=C([O-])O.[I-].[K+].[Na+]>CC(C)(C)OC(=O)n1c(CN(CCCCN2C(=O)c3ccccc3C2=O)C2CCCc3nccnc32)nc2ccccc21', 'CC(C)(C)OC(=O)n1c(CCl)nc2ccccc21.O=C1c2ccccc2C(=O)N1CCCCNC1CCCc2nccnc21>CC#N.CCN(C(C)C)C(C)C.O=C([O-])O.[I-].[K+].[Na+]>CC(C)(C)OC(=O)n1c(CN(CCCCN2C(=O)c3ccccc3C2=O)C2CCCc3nccnc32)nc2ccccc21']","[['ClCc1nc2ccccc2[nH]1', 'CC(C)(C)OC(=O)n1c(CCl)nc2ccccc21']]"
11,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C(NC(CCCc1ccccc1)CCCc1ccccc1)C1CCN(C[C@@H](O)COc2ccc3ncccc3c2)CC1</SMILES> starting from <SMILES>CC(C)(C)OC(=O)N1CCC(C(=O)O)CC1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)OC(=O)N1CCC(C(=O)O)CC1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C(NC(CCCc1ccccc1)CCCc1ccccc1)C1CCN(C[C@@H](O)COc2ccc3ncccc3c2)CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C(NC(CCCc1ccccc1)CCCc1ccccc1)C1CCN(C[C@@H](O)COc2ccc3ncccc3c2)CC1</SMILES> starting from <SMILES>CC(C)(C)OC(=O)N1CCC(C(=O)O)CC1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)OC(=O)N1CCC(C(=O)O)CC1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C(NC(CCCc1ccccc1)CCCc1ccccc1)C1CCN(C[C@@H](O)COc2ccc3ncccc3c2)CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C(NC(CCCc1ccccc1)CCCc1ccccc1)C1CCN(C[C@@H](O)COc2ccc3ncccc3c2)CC1</SMILES> starting from <SMILES>CC(C)(C)OC(=O)N1CCC(C(=O)O)CC1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)OC(=O)N1CCC(C(=O)O)CC1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C(NC(CCCc1ccccc1)CCCc1ccccc1)C1CCN(C[C@@H](O)COc2ccc3ncccc3c2)CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['CC(C)(C)OC(=O)N1CCC(C(=O)O)CC1.Cl.NC(CCCc1ccccc1)CCCc1ccccc1>CCN(C(C)C)C(C)C.ClCCl.F[P-](F)(F)(F)(F)F.c1ccc2c(c1)nnn2O[P+](N1CCCC1)(N1CCCC1)N1CCCC1>CC(C)(C)OC(=O)N1CCC(C(=O)NC(CCCc2ccccc2)CCCc2ccccc2)CC1', 'CC(C)(C)OC(=O)N1CCC(C(=O)O)CC1.Cl.NC(CCCc1ccccc1)CCCc1ccccc1>CCN(CC)CC.CCN=C=NCCCN(C)C.Cl.ClCCl>CC(C)(C)OC(=O)N1CCC(C(=O)NC(CCCc2ccccc2)CCCc2ccccc2)CC1']","['CC(C)(C)OC(=O)N1CCC(C(=O)NC(CCCc2ccccc2)CCCc2ccccc2)CC1>ClCCl.O=C(O)C(F)(F)F>O=C(NC(CCCc1ccccc1)CCCc1ccccc1)C1CCNCC1', 'CC(C)(C)OC(=O)N1CCC(C(=O)NC(CCCc2ccccc2)CCCc2ccccc2)CC1>ClCCl.O=C(O)C(F)(F)F>O=C(NC(CCCc1ccccc1)CCCc1ccccc1)C1CCNCC1']","['O=C(NC(CCCc1ccccc1)CCCc1ccccc1)C1CCNCC1.c1cnc2ccc(OC[C@H]3CO3)cc2c1>CCO>O=C(NC(CCCc1ccccc1)CCCc1ccccc1)C1CCN(C[C@@H](O)COc2ccc3ncccc3c2)CC1', 'O=C(NC(CCCc1ccccc1)CCCc1ccccc1)C1CCNCC1.c1cnc2ccc(OC[C@H]3CO3)cc2c1>CCO>O=C(NC(CCCc1ccccc1)CCCc1ccccc1)C1CCN(C[C@@H](O)COc2ccc3ncccc3c2)CC1']","[['CC(C)(C)OC(=O)N1CCC(C(=O)NC(CCCc2ccccc2)CCCc2ccccc2)CC1', 'O=C(NC(CCCc1ccccc1)CCCc1ccccc1)C1CCNCC1']]"
12,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CON(C)C(=O)C=Cc1cc(Br)ccc1F</SMILES> starting from <SMILES>O=C(O)CC(=O)O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)CC(=O)O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CON(C)C(=O)C=Cc1cc(Br)ccc1F</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CON(C)C(=O)C=Cc1cc(Br)ccc1F</SMILES> starting from <SMILES>O=C(O)CC(=O)O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)CC(=O)O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CON(C)C(=O)C=Cc1cc(Br)ccc1F</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CON(C)C(=O)C=Cc1cc(Br)ccc1F</SMILES> starting from <SMILES>O=C(O)CC(=O)O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)CC(=O)O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CON(C)C(=O)C=Cc1cc(Br)ccc1F</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['O=C(O)CC(=O)O.O=Cc1cc(Br)ccc1F>C1CCNCC1.c1ccncc1>O=C(O)C=Cc1cc(Br)ccc1F'],['O=C(O)C=Cc1cc(Br)ccc1F.O=S(Cl)Cl>>O=C(Cl)C=Cc1cc(Br)ccc1F'],['CNOC.Cl.O=C(Cl)C=Cc1cc(Br)ccc1F>ClCCl.c1ccncc1>CON(C)C(=O)C=Cc1cc(Br)ccc1F'],"[['O=C(O)C=Cc1cc(Br)ccc1F', 'O=C(Cl)C=Cc1cc(Br)ccc1F']]"
13,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC1=C(C#N)C(c2cc3c(NC(=O)c4ccccc4)nccc3o2)c2c(C)noc2N1</SMILES> starting from <SMILES>O=C(Nc1nccc2occc12)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(Nc1nccc2occc12)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC1=C(C#N)C(c2cc3c(NC(=O)c4ccccc4)nccc3o2)c2c(C)noc2N1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC1=C(C#N)C(c2cc3c(NC(=O)c4ccccc4)nccc3o2)c2c(C)noc2N1</SMILES> starting from <SMILES>O=C(Nc1nccc2occc12)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(Nc1nccc2occc12)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC1=C(C#N)C(c2cc3c(NC(=O)c4ccccc4)nccc3o2)c2c(C)noc2N1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC1=C(C#N)C(c2cc3c(NC(=O)c4ccccc4)nccc3o2)c2c(C)noc2N1</SMILES> starting from <SMILES>O=C(Nc1nccc2occc12)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(Nc1nccc2occc12)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC1=C(C#N)C(c2cc3c(NC(=O)c4ccccc4)nccc3o2)c2c(C)noc2N1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CN(C)C=O.O=C(Nc1nccc2occc12)c1ccccc1>C1CCOC1.[Cl-].[Li]CCCC.[NH4+]>O=Cc1cc2c(NC(=O)c3ccccc3)nccc2o1'],['C/C([O-])=C/C#N.O=Cc1cc2c(NC(=O)c3ccccc3)nccc2o1.[Na+]>C1CCNCC1.CC(=O)O.ClCCl.O=C([O-])O.[Na+]>CC(=O)C(C#N)=Cc1cc2c(NC(=O)c3ccccc3)nccc2o1'],['CC(=O)C(C#N)=Cc1cc2c(NC(=O)c3ccccc3)nccc2o1.Cc1cc(N)on1>CC(C)O>CC1=C(C#N)C(c2cc3c(NC(=O)c4ccccc4)nccc3o2)c2c(C)noc2N1'],"[['O=Cc1cc2c(NC(=O)c3ccccc3)nccc2o1', 'CC(=O)C(C#N)=Cc1cc2c(NC(=O)c3ccccc3)nccc2o1']]"
14,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CN(C)C[C@@H](CC(=O)OCc1ccccc1)NC(=O)CCCCCCCOCc1ccc(F)c(F)c1</SMILES> starting from <SMILES>CNC.Cl</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CNC.Cl</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CN(C)C[C@@H](CC(=O)OCc1ccccc1)NC(=O)CCCCCCCOCc1ccc(F)c(F)c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CN(C)C[C@@H](CC(=O)OCc1ccccc1)NC(=O)CCCCCCCOCc1ccc(F)c(F)c1</SMILES> starting from <SMILES>CNC.Cl</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CNC.Cl</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CN(C)C[C@@H](CC(=O)OCc1ccccc1)NC(=O)CCCCCCCOCc1ccc(F)c(F)c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CN(C)C[C@@H](CC(=O)OCc1ccccc1)NC(=O)CCCCCCCOCc1ccc(F)c(F)c1</SMILES> starting from <SMILES>CNC.Cl</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CNC.Cl</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CN(C)C[C@@H](CC(=O)OCc1ccccc1)NC(=O)CCCCCCCOCc1ccc(F)c(F)c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['CC(C)(C)OC(=O)N[C@H](CC(=O)OCc1ccccc1)C(=O)O.CNC.Cl>CCN(CC)CC.CCOC(=O)Cl.ClCCl>CN(C)C(=O)[C@@H](CC(=O)OCc1ccccc1)NC(=O)OC(C)(C)C', 'CC(C)(C)OC(=O)N[C@H](CC(=O)OCc1ccccc1)C(=O)O.CNC.Cl>CCN(CC)CC.CCOC(=O)Cl.ClCCl>CN(C)C(=O)[C@@H](CC(=O)OCc1ccccc1)NC(=O)OC(C)(C)C']","['CN(C)C(=O)[C@@H](CC(=O)OCc1ccccc1)NC(=O)OC(C)(C)C.Cl>>CN(C)C[C@H](N)CC(=O)OCc1ccccc1.Cl.Cl', 'CN(C)C(=O)[C@@H](CC(=O)OCc1ccccc1)NC(=O)OC(C)(C)C.Cl>>CN(C)C[C@H](N)CC(=O)OCc1ccccc1.Cl.Cl']","['CN(C)C[C@H](N)CC(=O)OCc1ccccc1.Cl.Cl.O=C(O)CCCCCCCOCc1ccc(F)c(F)c1>CCN(C(C)C)C(C)C.CN(C)C=O>CN(C)C[C@@H](CC(=O)OCc1ccccc1)NC(=O)CCCCCCCOCc1ccc(F)c(F)c1', 'CN(C)C[C@H](N)CC(=O)OCc1ccccc1.Cl.Cl.O=C(O)CCCCCCCOCc1ccc(F)c(F)c1>CCN(C(C)C)C(C)C.CN(C)C(On1nnc2cccnc21)=[N+](C)C.CN(C)C=O.F[P-](F)(F)(F)(F)F>CN(C)C[C@@H](CC(=O)OCc1ccccc1)NC(=O)CCCCCCCOCc1ccc(F)c(F)c1']","[['CN(C)C(=O)[C@@H](CC(=O)OCc1ccccc1)NC(=O)OC(C)(C)C', 'CN(C)C[C@H](N)CC(=O)OCc1ccccc1.Cl.Cl']]"
15,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)c1cccc(OCC(=O)NCCNC(=O)OC(C)(C)C)c1C(=O)OC</SMILES> starting from <SMILES>NCCN</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>NCCN</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)c1cccc(OCC(=O)NCCNC(=O)OC(C)(C)C)c1C(=O)OC</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)c1cccc(OCC(=O)NCCNC(=O)OC(C)(C)C)c1C(=O)OC</SMILES> starting from <SMILES>NCCN</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>NCCN</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)c1cccc(OCC(=O)NCCNC(=O)OC(C)(C)C)c1C(=O)OC</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)c1cccc(OCC(=O)NCCNC(=O)OC(C)(C)C)c1C(=O)OC</SMILES> starting from <SMILES>NCCN</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>NCCN</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)c1cccc(OCC(=O)NCCNC(=O)OC(C)(C)C)c1C(=O)OC</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['CC(C)(C)OC(=O)OC(=O)OC(C)(C)C.NCCN>CCN(CC)CC.ClCCl>CC(C)(C)OC(=O)NCCN', 'CC(C)(C)OC(=O)OC(=O)OC(C)(C)C.NCCN>C1COCCO1>CC(C)(C)OC(=O)NCCN']","['CC(C)(C)OC(=O)NCCN.O=C(Cl)CCl>C1CCOC1.CCN(C(C)C)C(C)C.CCOC(C)=O>CC(C)(C)OC(=O)NCCNC(=O)CCl', 'CC(C)(C)OC(=O)NCCN.O=C(Cl)CCl>C1CCOC1.CCN(C(C)C)C(C)C.CCOC(C)=O>CC(C)(C)OC(=O)NCCNC(=O)CCl']","['CC(C)(C)OC(=O)NCCNC(=O)CCl.COC(=O)c1cccc(O)c1C(=O)OC>CC#N.CCOC(C)=O.O=C([O-])[O-].[Cs+].[Cs+]>COC(=O)c1cccc(OCC(=O)NCCNC(=O)OC(C)(C)C)c1C(=O)OC', 'CC(C)(C)OC(=O)NCCNC(=O)CCl.COC(=O)c1cccc(O)c1C(=O)OC>CC#N.CCOC(C)=O.O=C([O-])[O-].[Cs+].[Cs+]>COC(=O)c1cccc(OCC(=O)NCCNC(=O)OC(C)(C)C)c1C(=O)OC']","[['CC(C)(C)OC(=O)NCCN', 'CC(C)(C)OC(=O)NCCNC(=O)CCl']]"
16,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1cccc2c(=O)c3ccccc3oc12</SMILES> starting from <SMILES>Oc1ccccc1O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Oc1ccccc1O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1cccc2c(=O)c3ccccc3oc12</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1cccc2c(=O)c3ccccc3oc12</SMILES> starting from <SMILES>Oc1ccccc1O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Oc1ccccc1O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1cccc2c(=O)c3ccccc3oc12</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1cccc2c(=O)c3ccccc3oc12</SMILES> starting from <SMILES>Oc1ccccc1O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Oc1ccccc1O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1cccc2c(=O)c3ccccc3oc12</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CO.Oc1ccccc1O>>COc1ccccc1O'],['COc1ccccc1O.O=C(O)c1ccccc1Br>CC#N.CC#N.CC#N.CC#N.CCOC(C)=O.Cc1ccccc1.Cl.F[P-](F)(F)(F)(F)F.O=C([O-])[O-].[Cs+].[Cs+].[Cu+]>COc1ccccc1Oc1ccccc1C(=O)O'],['COc1ccccc1Oc1ccccc1C(=O)O>CCOCC.ClCCl.FB(F)F.O.O=C(OC(=O)C(F)(F)F)C(F)(F)F>COc1cccc2c(=O)c3ccccc3oc12'],"[['COc1ccccc1O', 'COc1ccccc1Oc1ccccc1C(=O)O']]"
17,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)c1cc([N+](=O)[O-])c(Cl)cc1NC(=O)Cc1cccs1</SMILES> starting from <SMILES>CCOC(=O)Cc1cccs1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)Cc1cccs1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)c1cc([N+](=O)[O-])c(Cl)cc1NC(=O)Cc1cccs1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)c1cc([N+](=O)[O-])c(Cl)cc1NC(=O)Cc1cccs1</SMILES> starting from <SMILES>CCOC(=O)Cc1cccs1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)Cc1cccs1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)c1cc([N+](=O)[O-])c(Cl)cc1NC(=O)Cc1cccs1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)c1cc([N+](=O)[O-])c(Cl)cc1NC(=O)Cc1cccs1</SMILES> starting from <SMILES>CCOC(=O)Cc1cccs1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)Cc1cccs1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)c1cc([N+](=O)[O-])c(Cl)cc1NC(=O)Cc1cccs1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['CCOC(=O)Cc1cccs1>CCO.Cl.[Na+].[OH-]>O=C(O)Cc1cccs1', 'CCOC(=O)Cc1cccs1>CCO.Cl.[Na+].[OH-]>O=C(O)Cc1cccs1']","['O=C(O)Cc1cccs1.O=S(Cl)Cl>ClCCl>O=C(Cl)Cc1cccs1', 'O=C(Cl)C(=O)Cl.O=C(O)Cc1cccs1>CN(C)C=O>O=C(Cl)Cc1cccs1']","['COC(=O)c1cc([N+](=O)[O-])c(Cl)cc1N.O=C(Cl)Cc1cccs1>>COC(=O)c1cc([N+](=O)[O-])c(Cl)cc1NC(=O)Cc1cccs1', 'COC(=O)c1cc([N+](=O)[O-])c(Cl)cc1N.O=C(Cl)Cc1cccs1>>COC(=O)c1cc([N+](=O)[O-])c(Cl)cc1NC(=O)Cc1cccs1']","[['O=C(O)Cc1cccs1', 'O=C(Cl)Cc1cccs1']]"
18,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>C[C@H]1CN(c2ccncc2NC(=O)c2ccc3occ(C4CC4)c3n2)C[C@@H](N)[C@@H]1O</SMILES> starting from <SMILES>C[C@H]1CN(c2ccncc2N)C[C@@H](NC(=O)[O-])[C@@H]1O[Si](C)(C)C(C)(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C[C@H]1CN(c2ccncc2N)C[C@@H](NC(=O)[O-])[C@@H]1O[Si](C)(C)C(C)(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>C[C@H]1CN(c2ccncc2NC(=O)c2ccc3occ(C4CC4)c3n2)C[C@@H](N)[C@@H]1O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>C[C@H]1CN(c2ccncc2NC(=O)c2ccc3occ(C4CC4)c3n2)C[C@@H](N)[C@@H]1O</SMILES> starting from <SMILES>C[C@H]1CN(c2ccncc2N)C[C@@H](NC(=O)[O-])[C@@H]1O[Si](C)(C)C(C)(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C[C@H]1CN(c2ccncc2N)C[C@@H](NC(=O)[O-])[C@@H]1O[Si](C)(C)C(C)(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>C[C@H]1CN(c2ccncc2NC(=O)c2ccc3occ(C4CC4)c3n2)C[C@@H](N)[C@@H]1O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>C[C@H]1CN(c2ccncc2NC(=O)c2ccc3occ(C4CC4)c3n2)C[C@@H](N)[C@@H]1O</SMILES> starting from <SMILES>C[C@H]1CN(c2ccncc2N)C[C@@H](NC(=O)[O-])[C@@H]1O[Si](C)(C)C(C)(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C[C@H]1CN(c2ccncc2N)C[C@@H](NC(=O)[O-])[C@@H]1O[Si](C)(C)C(C)(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>C[C@H]1CN(c2ccncc2NC(=O)c2ccc3occ(C4CC4)c3n2)C[C@@H](N)[C@@H]1O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CCN(C(C)C)C(C)C.CN(C)C(On1nnc2cccnc21)=[N+](C)C.C[C@H]1CN(c2ccncc2N)C[C@@H](NC(=O)[O-])[C@@H]1O[Si](C)(C)C(C)(C)C.F[P-](F)(F)(F)(F)F.O=C(O)c1ccc2occ(Br)c2n1>CN(C)C=O>C[C@H]1CN(c2ccncc2NC(=O)c2ccc3occ(Br)c3n2)C[C@@H](NC(=O)OC(C)(C)C)[C@@H]1O[Si](C)(C)C(C)(C)C'],['C[C@H]1CN(c2ccncc2NC(=O)c2ccc3occ(Br)c3n2)C[C@@H](NC(=O)OC(C)(C)C)[C@@H]1O[Si](C)(C)C(C)(C)C.F[B-](F)(F)C1CC1.[K+]>CC(=O)[O-].CC(=O)[O-].CCCCP(C12CC3CC(CC(C3)C1)C2)C12CC3CC(CC(C3)C1)C2.O=C([O-])[O-].[Cs+].[Cs+].[Pd+2]>C[C@H]1CN(c2ccncc2NC(=O)c2ccc3occ(C4CC4)c3n2)C[C@@H](NC(=O)OC(C)(C)C)[C@@H]1O[Si](C)(C)C(C)(C)C'],['C[C@H]1CN(c2ccncc2NC(=O)c2ccc3occ(C4CC4)c3n2)C[C@@H](NC(=O)OC(C)(C)C)[C@@H]1O[Si](C)(C)C(C)(C)C>C1COCCO1.Cl.ClCCl.N.O=C(O)C(F)(F)F>C[C@H]1CN(c2ccncc2NC(=O)c2ccc3occ(C4CC4)c3n2)C[C@@H](N)[C@@H]1O'],"[['C[C@H]1CN(c2ccncc2NC(=O)c2ccc3occ(Br)c3n2)C[C@@H](NC(=O)OC(C)(C)C)[C@@H]1O[Si](C)(C)C(C)(C)C', 'C[C@H]1CN(c2ccncc2NC(=O)c2ccc3occ(C4CC4)c3n2)C[C@@H](NC(=O)OC(C)(C)C)[C@@H]1O[Si](C)(C)C(C)(C)C']]"
19,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCC(CCOC)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21</SMILES> starting from <SMILES>CCC(CC(=O)OC)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCC(CC(=O)OC)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCC(CCOC)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCC(CCOC)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21</SMILES> starting from <SMILES>CCC(CC(=O)OC)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCC(CC(=O)OC)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCC(CCOC)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCC(CCOC)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21</SMILES> starting from <SMILES>CCC(CC(=O)OC)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCC(CC(=O)OC)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCC(CCOC)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CCC(CC(=O)OC)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21>C1CCOC1.[Al+3].[H-].[H-].[H-].[H-].[Li+]>CCC(CCO)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21'],['CCC(CCO)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21.CS(=O)(=O)Cl>CN1CCOCC1.ClCCl>CCC(CCOS(C)(=O)=O)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21'],['CCC(CCOS(C)(=O)=O)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21.CO[Na]>CO>CCC(CCOC)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21'],"[['CCC(CCO)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21', 'CCC(CCOS(C)(=O)=O)(c1ccc(Cl)cc1)n1ccc2c(NS(C)(=O)=O)cccc21']]"
20,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCCCC(=O)Nc1cnc2cccnc2c1OS(=O)(=O)C(F)(F)F</SMILES> starting from <SMILES>O=[N+]([O-])c1cnc2cccnc2c1O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=[N+]([O-])c1cnc2cccnc2c1O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCCCC(=O)Nc1cnc2cccnc2c1OS(=O)(=O)C(F)(F)F</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCCCC(=O)Nc1cnc2cccnc2c1OS(=O)(=O)C(F)(F)F</SMILES> starting from <SMILES>O=[N+]([O-])c1cnc2cccnc2c1O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=[N+]([O-])c1cnc2cccnc2c1O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCCCC(=O)Nc1cnc2cccnc2c1OS(=O)(=O)C(F)(F)F</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCCCC(=O)Nc1cnc2cccnc2c1OS(=O)(=O)C(F)(F)F</SMILES> starting from <SMILES>O=[N+]([O-])c1cnc2cccnc2c1O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=[N+]([O-])c1cnc2cccnc2c1O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCCCC(=O)Nc1cnc2cccnc2c1OS(=O)(=O)C(F)(F)F</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['O=[N+]([O-])c1cnc2cccnc2c1O>CO.[NH4+].[OH-].[Pt]>Nc1cnc2cccnc2c1O', 'O=[N+]([O-])c1cnc2cccnc2c1O>CCN(CC)CC.O>Nc1cnc2cccnc2c1O']","['CCCCC(=O)Cl.Nc1cnc2cccnc2c1O>CCN(CC)CC.ClCCl>CCCCC(=O)Nc1cnc2cccnc2c1O', 'CCCCC(=O)Cl.Nc1cnc2cccnc2c1O>CCN(CC)CC.ClCCl>CCCCC(=O)Nc1cnc2cccnc2c1O']","['CCCCC(=O)Nc1cnc2cccnc2c1O.O=S(=O)(N(c1ccccc1)S(=O)(=O)C(F)(F)F)C(F)(F)F>CCN(CC)CC.CN(C)C=O>CCCCC(=O)Nc1cnc2cccnc2c1OS(=O)(=O)C(F)(F)F', 'CCCCC(=O)Nc1cnc2cccnc2c1O.O=S(=O)(N(c1ccccc1)S(=O)(=O)C(F)(F)F)C(F)(F)F>CCN(CC)CC.CN(C)C=O>CCCCC(=O)Nc1cnc2cccnc2c1OS(=O)(=O)C(F)(F)F']","[['Nc1cnc2cccnc2c1O', 'CCCCC(=O)Nc1cnc2cccnc2c1O']]"
21,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)C1CCc2ccc(Oc3cccc(NCc4ccccc4)c3)cc2C1</SMILES> starting from <SMILES>O=Cc1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=Cc1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)C1CCc2ccc(Oc3cccc(NCc4ccccc4)c3)cc2C1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)C1CCc2ccc(Oc3cccc(NCc4ccccc4)c3)cc2C1</SMILES> starting from <SMILES>O=Cc1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=Cc1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)C1CCc2ccc(Oc3cccc(NCc4ccccc4)c3)cc2C1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)C1CCc2ccc(Oc3cccc(NCc4ccccc4)c3)cc2C1</SMILES> starting from <SMILES>O=Cc1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=Cc1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)C1CCc2ccc(Oc3cccc(NCc4ccccc4)c3)cc2C1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CC(=O)O.CC(=O)c1ccccc1.O=Cc1ccccc1>B.CCc1ccc(C)nc1>OCCc1ccccc1.OCc1ccccc1'],['OCc1ccccc1.OO>CC(=O)O.CC(=O)[O-].CC(=O)[O-].O.O.O.O.[Br-].[Co+2].[Na+]>O=C(O)c1ccccc1.O=Cc1ccccc1'],['COC(=O)C1CCc2ccc(Oc3cccc(N)c3)cc2C1.Cl.O=Cc1ccccc1>CC(=O)O.CCN(CC)CC.CO.[BH3-]C#N.[Na+]>COC(=O)C1CCc2ccc(Oc3cccc(NCc4ccccc4)c3)cc2C1'],"[['OCc1ccccc1', 'O=Cc1ccccc1']]"
22,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC1(C)CCC2=C(C1=O)C(/C=C/c1ccc(-c3cccc(F)c3)cn1)c1cn[nH]c1N2.NC(=O)CC1CC1</SMILES> starting from <SMILES>O=C(O)c1cc([N+](=O)[O-])[nH]n1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)c1cc([N+](=O)[O-])[nH]n1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC1(C)CCC2=C(C1=O)C(/C=C/c1ccc(-c3cccc(F)c3)cn1)c1cn[nH]c1N2.NC(=O)CC1CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC1(C)CCC2=C(C1=O)C(/C=C/c1ccc(-c3cccc(F)c3)cn1)c1cn[nH]c1N2.NC(=O)CC1CC1</SMILES> starting from <SMILES>O=C(O)c1cc([N+](=O)[O-])[nH]n1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)c1cc([N+](=O)[O-])[nH]n1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC1(C)CCC2=C(C1=O)C(/C=C/c1ccc(-c3cccc(F)c3)cn1)c1cn[nH]c1N2.NC(=O)CC1CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC1(C)CCC2=C(C1=O)C(/C=C/c1ccc(-c3cccc(F)c3)cn1)c1cn[nH]c1N2.NC(=O)CC1CC1</SMILES> starting from <SMILES>O=C(O)c1cc([N+](=O)[O-])[nH]n1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)c1cc([N+](=O)[O-])[nH]n1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC1(C)CCC2=C(C1=O)C(/C=C/c1ccc(-c3cccc(F)c3)cn1)c1cn[nH]c1N2.NC(=O)CC1CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['Cl.NCC1CC1.O=C(O)c1cc([N+](=O)[O-])[nH]n1>CCN(CC)CC.CN(C)C(On1nnc2cccnc21)=[N+](C)C.CN(C)C=O.F[P-](F)(F)(F)(F)F>NC(=O)CC1CC1.O=[N+]([O-])c1ccn[nH]1'],['NC(=O)CC1CC1.O=[N+]([O-])c1ccn[nH]1>CC(=O)O.CO.[Pd]>NC(=O)CC1CC1.Nc1ccn[nH]1'],['CC1(C)CCC(=O)CC1=O.NC(=O)CC1CC1.Nc1ccn[nH]1.O=C/C=C/c1ccc(-c2cccc(F)c2)cn1>>CC1(C)CCC2=C(C1=O)C(/C=C/c1ccc(-c3cccc(F)c3)cn1)c1cn[nH]c1N2.NC(=O)CC1CC1'],"[['NC(=O)CC1CC1.O=[N+]([O-])c1ccn[nH]1', 'NC(=O)CC1CC1.Nc1ccn[nH]1']]"
23,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1ccc(S(=O)(=O)Oc2ccc(S(=O)(=O)c3c(C(C)C)cn4ccccc34)cc2)cc1</SMILES> starting from <SMILES>Cc1ccccn1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Cc1ccccn1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1ccc(S(=O)(=O)Oc2ccc(S(=O)(=O)c3c(C(C)C)cn4ccccc34)cc2)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1ccc(S(=O)(=O)Oc2ccc(S(=O)(=O)c3c(C(C)C)cn4ccccc34)cc2)cc1</SMILES> starting from <SMILES>Cc1ccccn1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Cc1ccccn1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1ccc(S(=O)(=O)Oc2ccc(S(=O)(=O)c3c(C(C)C)cn4ccccc34)cc2)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1ccc(S(=O)(=O)Oc2ccc(S(=O)(=O)c3c(C(C)C)cn4ccccc34)cc2)cc1</SMILES> starting from <SMILES>Cc1ccccn1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Cc1ccccn1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1ccc(S(=O)(=O)Oc2ccc(S(=O)(=O)c3c(C(C)C)cn4ccccc34)cc2)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['Cc1ccccn1.Cl.O=c1n(Cl)c(=O)n(Cl)c(=O)n1Cl>CN(C)C=O.ClC(Cl)Cl>Cl.ClCc1ccccn1', 'Cc1ccccn1.Cl.O=c1n(Cl)c(=O)n(Cl)c(=O)n1Cl>CN(C)C=O.ClC(Cl)Cl>Cl.ClCc1ccccn1']","['Cl.ClCc1ccccn1.O=S([O-])c1ccccc1.[Na+]>C1CCC2=NCCCN2CC1.CC#N.CCC[N+](CCC)(CCC)CCC.[Br-]>O=S(=O)(Cc1ccccn1)c1ccccc1', 'Cl.ClCc1ccccn1.O=S([O-])c1ccccc1.[Na+]>C1CCC2=NCCCN2CC1.CC#N.CCC[N+](CCC)(CCC)CCC.[Br-]>O=S(=O)(Cc1ccccn1)c1ccccc1']","['CC(C)C(=O)CBr.O=C([O-])[O-].O=S(=O)(Cc1ccccn1)c1ccccc1.[K+].[K+]>>Cc1ccc(S(=O)(=O)Oc2ccc(S(=O)(=O)c3c(C(C)C)cn4ccccc34)cc2)cc1', 'CC(C)C(=O)CBr.O=C([O-])[O-].O=S(=O)(Cc1ccccn1)c1ccccc1.[K+].[K+]>C1CCOC1.CCC(C)=O>Cc1ccc(S(=O)(=O)Oc2ccc(S(=O)(=O)c3c(C(C)C)cn4ccccc34)cc2)cc1']","[['Cl.ClCc1ccccn1', 'O=S(=O)(Cc1ccccn1)c1ccccc1']]"
24,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(=O)n1ncc2cc(Oc3ccc(C=O)cc3)ccc21</SMILES> starting from <SMILES>Cc1cc(Oc2ccc(C3OCCO3)cc2)ccc1[N+](=O)[O-]</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Cc1cc(Oc2ccc(C3OCCO3)cc2)ccc1[N+](=O)[O-]</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(=O)n1ncc2cc(Oc3ccc(C=O)cc3)ccc21</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(=O)n1ncc2cc(Oc3ccc(C=O)cc3)ccc21</SMILES> starting from <SMILES>Cc1cc(Oc2ccc(C3OCCO3)cc2)ccc1[N+](=O)[O-]</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Cc1cc(Oc2ccc(C3OCCO3)cc2)ccc1[N+](=O)[O-]</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(=O)n1ncc2cc(Oc3ccc(C=O)cc3)ccc21</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(=O)n1ncc2cc(Oc3ccc(C=O)cc3)ccc21</SMILES> starting from <SMILES>Cc1cc(Oc2ccc(C3OCCO3)cc2)ccc1[N+](=O)[O-]</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Cc1cc(Oc2ccc(C3OCCO3)cc2)ccc1[N+](=O)[O-]</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(=O)n1ncc2cc(Oc3ccc(C=O)cc3)ccc21</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['Cc1cc(Oc2ccc(C3OCCO3)cc2)ccc1[N+](=O)[O-]>CCOC(C)=O.[Pd]>Cc1cc(Oc2ccc(C3OCCO3)cc2)ccc1N'],['CC(=O)OC(C)=O.CC(C)CCON=O.Cc1cc(Oc2ccc(C3OCCO3)cc2)ccc1N>C1CCOC1.C1COCCOCCOCCOCCOCCO1.CC(=O)[O-].O=C([O-])O.[K+].[Na+]>CC(=O)n1ncc2cc(Oc3ccc(C4OCCO4)cc3)ccc21'],['CC(=O)n1ncc2cc(Oc3ccc(C4OCCO4)cc3)ccc21>CC(C)=O.Cc1ccc(S(=O)(=O)O)cc1>CC(=O)n1ncc2cc(Oc3ccc(C=O)cc3)ccc21'],"[['Cc1cc(Oc2ccc(C3OCCO3)cc2)ccc1N', 'CC(=O)n1ncc2cc(Oc3ccc(C4OCCO4)cc3)ccc21']]"
25,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C(CC(=O)N1CCN(C(=O)c2ccccc2Br)CC1)Nc1ccc(N2CCOCC2)cc1</SMILES> starting from <SMILES>CC(C)(C)OC(=O)CC(=O)[O-].[Li+]</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)OC(=O)CC(=O)[O-].[Li+]</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C(CC(=O)N1CCN(C(=O)c2ccccc2Br)CC1)Nc1ccc(N2CCOCC2)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C(CC(=O)N1CCN(C(=O)c2ccccc2Br)CC1)Nc1ccc(N2CCOCC2)cc1</SMILES> starting from <SMILES>CC(C)(C)OC(=O)CC(=O)[O-].[Li+]</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)OC(=O)CC(=O)[O-].[Li+]</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C(CC(=O)N1CCN(C(=O)c2ccccc2Br)CC1)Nc1ccc(N2CCOCC2)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C(CC(=O)N1CCN(C(=O)c2ccccc2Br)CC1)Nc1ccc(N2CCOCC2)cc1</SMILES> starting from <SMILES>CC(C)(C)OC(=O)CC(=O)[O-].[Li+]</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)OC(=O)CC(=O)[O-].[Li+]</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C(CC(=O)N1CCN(C(=O)c2ccccc2Br)CC1)Nc1ccc(N2CCOCC2)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CC(C)(C)OC(=O)CC(=O)[O-].Cl.O=C(c1ccccc1Br)N1CCNCC1.[Li+]>CCN(C(C)C)C(C)C.CCN=C=NCCCN(C)C.CN(C)C=O.Cl.O.On1nnc2ccccc21>CC(C)(C)OC(=O)CC(=O)N1CCN(C(=O)c2ccccc2Br)CC1'],['CC(C)(C)OC(=O)CC(=O)N1CCN(C(=O)c2ccccc2Br)CC1>C1COCCO1.Cl>O=C(O)CC(=O)N1CCN(C(=O)c2ccccc2Br)CC1'],['Nc1ccc(N2CCOCC2)cc1.O=C(O)CC(=O)N1CCN(C(=O)c2ccccc2Br)CC1>CCN=C=NCCCN(C)C.CN(C)C=O.CN(C)c1ccncc1.Cl.O.On1nnc2ccccc21>O=C(CC(=O)N1CCN(C(=O)c2ccccc2Br)CC1)Nc1ccc(N2CCOCC2)cc1'],"[['CC(C)(C)OC(=O)CC(=O)N1CCN(C(=O)c2ccccc2Br)CC1', 'O=C(O)CC(=O)N1CCN(C(=O)c2ccccc2Br)CC1']]"
26,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>N#Cc1ccc(C2C3=C(CCCC3=O)N(c3cccc(C(F)(F)F)c3)C(=O)N2C(=O)NC2CCS(=O)CC2)cc1</SMILES> starting from <SMILES>O=C(Cl)Oc1ccc([N+](=O)[O-])cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(Cl)Oc1ccc([N+](=O)[O-])cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>N#Cc1ccc(C2C3=C(CCCC3=O)N(c3cccc(C(F)(F)F)c3)C(=O)N2C(=O)NC2CCS(=O)CC2)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>N#Cc1ccc(C2C3=C(CCCC3=O)N(c3cccc(C(F)(F)F)c3)C(=O)N2C(=O)NC2CCS(=O)CC2)cc1</SMILES> starting from <SMILES>O=C(Cl)Oc1ccc([N+](=O)[O-])cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(Cl)Oc1ccc([N+](=O)[O-])cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>N#Cc1ccc(C2C3=C(CCCC3=O)N(c3cccc(C(F)(F)F)c3)C(=O)N2C(=O)NC2CCS(=O)CC2)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>N#Cc1ccc(C2C3=C(CCCC3=O)N(c3cccc(C(F)(F)F)c3)C(=O)N2C(=O)NC2CCS(=O)CC2)cc1</SMILES> starting from <SMILES>O=C(Cl)Oc1ccc([N+](=O)[O-])cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(Cl)Oc1ccc([N+](=O)[O-])cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>N#Cc1ccc(C2C3=C(CCCC3=O)N(c3cccc(C(F)(F)F)c3)C(=O)N2C(=O)NC2CCS(=O)CC2)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['N#Cc1ccc(C2NC(=O)N(c3cccc(C(F)(F)F)c3)C3=C2C(=O)CCC3)cc1.O=C(Cl)Oc1ccc([N+](=O)[O-])cc1>CCN(C(C)C)C(C)C.CN(C)c1ccncc1.ClCCl.O>N#Cc1ccc(C2C3=C(CCCC3=O)N(c3cccc(C(F)(F)F)c3)C(=O)N2C(=O)Oc2ccc([N+](=O)[O-])cc2)cc1'],['N#Cc1ccc(C2C3=C(CCCC3=O)N(c3cccc(C(F)(F)F)c3)C(=O)N2C(=O)Oc2ccc([N+](=O)[O-])cc2)cc1.NC1CCSCC1>CC#N>N#Cc1ccc(C2C3=C(CCCC3=O)N(c3cccc(C(F)(F)F)c3)C(=O)N2C(=O)NC2CCSCC2)cc1'],['N#Cc1ccc(C2C3=C(CCCC3=O)N(c3cccc(C(F)(F)F)c3)C(=O)N2C(=O)NC2CCSCC2)cc1.OO>CCO.C[Re](=O)(=O)=O.O.O=C1O[C@H]([C@@H](O)CO)C([O-])=C1O.[Na+]>N#Cc1ccc(C2C3=C(CCCC3=O)N(c3cccc(C(F)(F)F)c3)C(=O)N2C(=O)NC2CCS(=O)CC2)cc1'],"[['N#Cc1ccc(C2C3=C(CCCC3=O)N(c3cccc(C(F)(F)F)c3)C(=O)N2C(=O)Oc2ccc([N+](=O)[O-])cc2)cc1', 'N#Cc1ccc(C2C3=C(CCCC3=O)N(c3cccc(C(F)(F)F)c3)C(=O)N2C(=O)NC2CCSCC2)cc1']]"
27,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1cc2c(Cl)ncnc2cc1OCCCN(C)C</SMILES> starting from <SMILES>COc1cc2c(=O)[nH]cnc2cc1OCc1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COc1cc2c(=O)[nH]cnc2cc1OCc1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1cc2c(Cl)ncnc2cc1OCCCN(C)C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1cc2c(Cl)ncnc2cc1OCCCN(C)C</SMILES> starting from <SMILES>COc1cc2c(=O)[nH]cnc2cc1OCc1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COc1cc2c(=O)[nH]cnc2cc1OCc1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1cc2c(Cl)ncnc2cc1OCCCN(C)C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1cc2c(Cl)ncnc2cc1OCCCN(C)C</SMILES> starting from <SMILES>COc1cc2c(=O)[nH]cnc2cc1OCc1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COc1cc2c(=O)[nH]cnc2cc1OCc1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1cc2c(Cl)ncnc2cc1OCCCN(C)C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CC(=O)OC(C)=O.COc1cc2c(=O)[nH]cnc2cc1OCc1ccccc1>CC(=O)[O-].Cc1ccccc1.[Na+].[Pd]>COc1cc2c(=O)[nH]cnc2cc1OC(C)=O'],['COc1cc2c(=O)[nH]cnc2cc1OC(C)=O.O=S(Cl)Cl>CN(C)C=O>COc1cc2c(Cl)ncnc2cc1O'],['CN(C)CCCO.COc1cc2c(Cl)ncnc2cc1O>>COc1cc2c(Cl)ncnc2cc1OCCCN(C)C'],"[['COc1cc2c(=O)[nH]cnc2cc1OC(C)=O', 'COc1cc2c(Cl)ncnc2cc1O']]"
28,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cn1nnc(N2CCC(CCCOc3ccc4c(c3)CCN(S(C)(=O)=O)C4)CC2)n1</SMILES> starting from <SMILES>N#CBr</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>N#CBr</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cn1nnc(N2CCC(CCCOc3ccc4c(c3)CCN(S(C)(=O)=O)C4)CC2)n1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cn1nnc(N2CCC(CCCOc3ccc4c(c3)CCN(S(C)(=O)=O)C4)CC2)n1</SMILES> starting from <SMILES>N#CBr</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>N#CBr</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cn1nnc(N2CCC(CCCOc3ccc4c(c3)CCN(S(C)(=O)=O)C4)CC2)n1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cn1nnc(N2CCC(CCCOc3ccc4c(c3)CCN(S(C)(=O)=O)C4)CC2)n1</SMILES> starting from <SMILES>N#CBr</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>N#CBr</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cn1nnc(N2CCC(CCCOc3ccc4c(c3)CCN(S(C)(=O)=O)C4)CC2)n1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CS(=O)(=O)N1CCc2cc(OCCCC3CCNCC3)ccc2C1.N#CBr>ClCCl.O.O=C([O-])O.[Na+]>CS(=O)(=O)N1CCc2cc(OCCCC3CCN(C#N)CC3)ccc2C1'],['CS(=O)(=O)N1CCc2cc(OCCCC3CCN(C#N)CC3)ccc2C1.[N-]=[N+]=[N-].[Na+]>CN(C)C=O.[Cl-].[NH4+]>CS(=O)(=O)N1CCc2cc(OCCCC3CCN(c4nnn[nH]4)CC3)ccc2C1'],['CI.CS(=O)(=O)N1CCc2cc(OCCCC3CCN(c4nnn[nH]4)CC3)ccc2C1.O=C([O-])[O-].[K+].[K+]>CN(C)C=O>Cn1nnc(N2CCC(CCCOc3ccc4c(c3)CCN(S(C)(=O)=O)C4)CC2)n1.Cn1nnnc1N1CCC(CCCOc2ccc3c(c2)CCN(S(C)(=O)=O)C3)CC1'],"[['CS(=O)(=O)N1CCc2cc(OCCCC3CCN(C#N)CC3)ccc2C1', 'CS(=O)(=O)N1CCc2cc(OCCCC3CCN(c4nnn[nH]4)CC3)ccc2C1']]"
29,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(Oc1cccnc1)c1ccc(Br)cn1</SMILES> starting from <SMILES>Brc1ccc(Br)nc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Brc1ccc(Br)nc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(Oc1cccnc1)c1ccc(Br)cn1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(Oc1cccnc1)c1ccc(Br)cn1</SMILES> starting from <SMILES>Brc1ccc(Br)nc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Brc1ccc(Br)nc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(Oc1cccnc1)c1ccc(Br)cn1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(Oc1cccnc1)c1ccc(Br)cn1</SMILES> starting from <SMILES>Brc1ccc(Br)nc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Brc1ccc(Br)nc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(Oc1cccnc1)c1ccc(Br)cn1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['Brc1ccc(Br)nc1.CN(C)C=O>Cc1ccccc1.[Li]CCCC>O=Cc1ccc(Br)cn1'],['C[Mg]Br.O=Cc1ccc(Br)cn1>C1CCOC1.[Cl-].[NH4+]>CC(O)c1ccc(Br)cn1'],['CC(O)c1ccc(Br)cn1.Oc1cccnc1>C1CCOC1.CC(C)OC(=O)N=NC(=O)OC(C)C.c1ccc(P(c2ccccc2)c2ccccc2)cc1>CC(Oc1cccnc1)c1ccc(Br)cn1'],"[['O=Cc1ccc(Br)cn1', 'CC(O)c1ccc(Br)cn1']]"
30,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCS(=O)(=O)N1CCC(c2n[nH]c3c(C(N)=O)cc(-c4cccc(CO)c4)cc23)CC1</SMILES> starting from <SMILES>O=C(O)c1cccc(Br)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)c1cccc(Br)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCS(=O)(=O)N1CCC(c2n[nH]c3c(C(N)=O)cc(-c4cccc(CO)c4)cc23)CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCS(=O)(=O)N1CCC(c2n[nH]c3c(C(N)=O)cc(-c4cccc(CO)c4)cc23)CC1</SMILES> starting from <SMILES>O=C(O)c1cccc(Br)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)c1cccc(Br)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCS(=O)(=O)N1CCC(c2n[nH]c3c(C(N)=O)cc(-c4cccc(CO)c4)cc23)CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCS(=O)(=O)N1CCC(c2n[nH]c3c(C(N)=O)cc(-c4cccc(CO)c4)cc23)CC1</SMILES> starting from <SMILES>O=C(O)c1cccc(Br)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)c1cccc(Br)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCS(=O)(=O)N1CCC(c2n[nH]c3c(C(N)=O)cc(-c4cccc(CO)c4)cc23)CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['O=C(O)c1cccc(Br)c1>C1CCOC1>OCc1cccc(Br)c1'],['COB(OC)OC.OCc1cccc(Br)c1>C1CCOC1.Cl.O.[Cl-].[Na+]>OCc1cccc(B(O)O)c1'],['CCS(=O)(=O)N1CCC(c2n[nH]c3c(C(N)=O)cc(Br)cc23)CC1.OCc1cccc(B(O)O)c1>C1COCCO1.O.O=C([O-])[O-].[Cs+].[Cs+].c1ccc([P](c2ccccc2)(c2ccccc2)[Pd]([P](c2ccccc2)(c2ccccc2)c2ccccc2)([P](c2ccccc2)(c2ccccc2)c2ccccc2)[P](c2ccccc2)(c2ccccc2)c2ccccc2)cc1>CCS(=O)(=O)N1CCC(c2n[nH]c3c(C(N)=O)cc(-c4cccc(CO)c4)cc23)CC1'],"[['OCc1cccc(Br)c1', 'OCc1cccc(B(O)O)c1']]"
31,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)c1ccc(CC(C(=O)Nc2ccc(Cl)cc2)N(Cc2ccc(OC)cc2OC)C(=O)c2ccccc2)cc1</SMILES> starting from <SMILES>COC(=O)c1ccc(C=O)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COC(=O)c1ccc(C=O)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)c1ccc(CC(C(=O)Nc2ccc(Cl)cc2)N(Cc2ccc(OC)cc2OC)C(=O)c2ccccc2)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)c1ccc(CC(C(=O)Nc2ccc(Cl)cc2)N(Cc2ccc(OC)cc2OC)C(=O)c2ccccc2)cc1</SMILES> starting from <SMILES>COC(=O)c1ccc(C=O)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COC(=O)c1ccc(C=O)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)c1ccc(CC(C(=O)Nc2ccc(Cl)cc2)N(Cc2ccc(OC)cc2OC)C(=O)c2ccccc2)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)c1ccc(CC(C(=O)Nc2ccc(Cl)cc2)N(Cc2ccc(OC)cc2OC)C(=O)c2ccccc2)cc1</SMILES> starting from <SMILES>COC(=O)c1ccc(C=O)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COC(=O)c1ccc(C=O)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)c1ccc(CC(C(=O)Nc2ccc(Cl)cc2)N(Cc2ccc(OC)cc2OC)C(=O)c2ccccc2)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['COC(=O)c1ccc(C=O)cc1.COC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Cl-]>C1CCOC1.CC(C)(C)[O-].[K+]>COC=Cc1ccc(C(=O)OC)cc1', 'COC(=O)c1ccc(C=O)cc1.COC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Cl-]>C1CCOC1.CC(C)(C)[O-].[K+]>CO/C=C/c1ccc(C(=O)OC)cc1']","['COC=Cc1ccc(C(=O)OC)cc1>C1CCOC1.Cl.O>COC(=O)c1ccc(CC=O)cc1', 'CO/C=C/c1ccc(C(=O)OC)cc1>C1CCOC1.Cl>COC(=O)c1ccc(CC=O)cc1']","['COC(=O)c1ccc(CC=O)cc1.COc1ccc(CN)c(OC)c1.O=C(O)c1ccccc1.[C-]#[N+]c1ccc(Cl)cc1>CO.OCC(F)(F)F>COC(=O)c1ccc(CC(C(=O)Nc2ccc(Cl)cc2)N(Cc2ccc(OC)cc2OC)C(=O)c2ccccc2)cc1', 'COC(=O)c1ccc(CC=O)cc1.COc1ccc(CN)c(OC)c1.O=C(O)c1ccccc1.[C-]#[N+]c1ccc(Cl)cc1>CO.OCC(F)(F)F>COC(=O)c1ccc(CC(C(=O)Nc2ccc(Cl)cc2)N(Cc2ccc(OC)cc2OC)C(=O)c2ccccc2)cc1']","[['COC=Cc1ccc(C(=O)OC)cc1', 'COC(=O)c1ccc(CC=O)cc1'], ['CO/C=C/c1ccc(C(=O)OC)cc1', 'COC(=O)c1ccc(CC=O)cc1']]"
32,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC1=NC(CC(Cc2ccc3cccc(OCCOC)c3c2)C(C)C)C(OCC)=NC1</SMILES> starting from <SMILES>COCCOc1cccc2ccc(CC(C(=O)O)C(C)C)cc12</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COCCOc1cccc2ccc(CC(C(=O)O)C(C)C)cc12</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC1=NC(CC(Cc2ccc3cccc(OCCOC)c3c2)C(C)C)C(OCC)=NC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC1=NC(CC(Cc2ccc3cccc(OCCOC)c3c2)C(C)C)C(OCC)=NC1</SMILES> starting from <SMILES>COCCOc1cccc2ccc(CC(C(=O)O)C(C)C)cc12</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COCCOc1cccc2ccc(CC(C(=O)O)C(C)C)cc12</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC1=NC(CC(Cc2ccc3cccc(OCCOC)c3c2)C(C)C)C(OCC)=NC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC1=NC(CC(Cc2ccc3cccc(OCCOC)c3c2)C(C)C)C(OCC)=NC1</SMILES> starting from <SMILES>COCCOc1cccc2ccc(CC(C(=O)O)C(C)C)cc12</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COCCOc1cccc2ccc(CC(C(=O)O)C(C)C)cc12</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC1=NC(CC(Cc2ccc3cccc(OCCOC)c3c2)C(C)C)C(OCC)=NC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['B.C1CCOC1.COCCOc1cccc2ccc(CC(C(=O)O)C(C)C)cc12>C1CCOC1.CO>COCCOc1cccc2ccc(CC(CO)C(C)C)cc12'],['COCCOc1cccc2ccc(CC(CO)C(C)C)cc12.O=C1CCC(=O)N1Br>ClCCl.c1ccc(P(c2ccccc2)c2ccccc2)cc1>COCCOc1cccc2ccc(CC(CBr)C(C)C)cc12'],['CCOC1=NCC(OCC)=NC1.COCCOc1cccc2ccc(CC(CBr)C(C)C)cc12>C1CCOC1.[Li]CCCC>CCOC1=NC(CC(Cc2ccc3cccc(OCCOC)c3c2)C(C)C)C(OCC)=NC1'],"[['COCCOc1cccc2ccc(CC(CO)C(C)C)cc12', 'COCCOc1cccc2ccc(CC(CBr)C(C)C)cc12']]"
33,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CS(=O)(=O)[C@H]1C[C@@H](n2c(CCl)nc3cc(Cl)ccc32)C1</SMILES> starting from <SMILES>CS(=O)(=O)[C@H]1C[C@@H](N)C1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CS(=O)(=O)[C@H]1C[C@@H](N)C1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CS(=O)(=O)[C@H]1C[C@@H](n2c(CCl)nc3cc(Cl)ccc32)C1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CS(=O)(=O)[C@H]1C[C@@H](n2c(CCl)nc3cc(Cl)ccc32)C1</SMILES> starting from <SMILES>CS(=O)(=O)[C@H]1C[C@@H](N)C1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CS(=O)(=O)[C@H]1C[C@@H](N)C1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CS(=O)(=O)[C@H]1C[C@@H](n2c(CCl)nc3cc(Cl)ccc32)C1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CS(=O)(=O)[C@H]1C[C@@H](n2c(CCl)nc3cc(Cl)ccc32)C1</SMILES> starting from <SMILES>CS(=O)(=O)[C@H]1C[C@@H](N)C1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CS(=O)(=O)[C@H]1C[C@@H](N)C1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CS(=O)(=O)[C@H]1C[C@@H](n2c(CCl)nc3cc(Cl)ccc32)C1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CS(=O)(=O)[C@H]1C[C@@H](N)C1.O=[N+]([O-])c1cc(Cl)ccc1F>CC#N.O=C([O-])[O-].[Cs+].[Cs+]>CS(=O)(=O)[C@H]1C[C@@H](Nc2ccc(Cl)cc2[N+](=O)[O-])C1'],['CS(=O)(=O)[C@H]1C[C@@H](Nc2ccc(Cl)cc2[N+](=O)[O-])C1>CO.[Ni]>CS(=O)(=O)[C@H]1C[C@@H](Nc2ccc(Cl)cc2N)C1'],['COC(CCl)(OC)OC.CS(=O)(=O)[C@H]1C[C@@H](Nc2ccc(Cl)cc2N)C1>CCO>CS(=O)(=O)[C@H]1C[C@@H](n2c(CCl)nc3cc(Cl)ccc32)C1'],"[['CS(=O)(=O)[C@H]1C[C@@H](Nc2ccc(Cl)cc2[N+](=O)[O-])C1', 'CS(=O)(=O)[C@H]1C[C@@H](Nc2ccc(Cl)cc2N)C1']]"
34,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1ccccc1-c1c(F)ccc2c(N)c3c(nc12)CN(C1CC1)C3=O</SMILES> starting from <SMILES>COc1ccccc1I</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COc1ccccc1I</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1ccccc1-c1c(F)ccc2c(N)c3c(nc12)CN(C1CC1)C3=O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1ccccc1-c1c(F)ccc2c(N)c3c(nc12)CN(C1CC1)C3=O</SMILES> starting from <SMILES>COc1ccccc1I</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COc1ccccc1I</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1ccccc1-c1c(F)ccc2c(N)c3c(nc12)CN(C1CC1)C3=O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1ccccc1-c1c(F)ccc2c(N)c3c(nc12)CN(C1CC1)C3=O</SMILES> starting from <SMILES>COc1ccccc1I</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COc1ccccc1I</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1ccccc1-c1c(F)ccc2c(N)c3c(nc12)CN(C1CC1)C3=O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['COc1ccccc1I.[Li]CCCC>C1CCOC1.CCCCCC>[Li]c1ccccc1OC'],['COB(OC)OC.[Li]c1ccccc1OC>CCOCC>COc1ccccc1B(O)O'],['COc1ccccc1B(O)O.Nc1c2c(nc3c(Br)c(F)ccc13)CN(C1CC1)C2=O>>COc1ccccc1-c1c(F)ccc2c(N)c3c(nc12)CN(C1CC1)C3=O'],"[['[Li]c1ccccc1OC', 'COc1ccccc1B(O)O']]"
35,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(=O)N[C@@H](C)COc1ccccc1C(=O)O</SMILES> starting from <SMILES>C[C@H](N)CO</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C[C@H](N)CO</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(=O)N[C@@H](C)COc1ccccc1C(=O)O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(=O)N[C@@H](C)COc1ccccc1C(=O)O</SMILES> starting from <SMILES>C[C@H](N)CO</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C[C@H](N)CO</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(=O)N[C@@H](C)COc1ccccc1C(=O)O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(=O)N[C@@H](C)COc1ccccc1C(=O)O</SMILES> starting from <SMILES>C[C@H](N)CO</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C[C@H](N)CO</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(=O)N[C@@H](C)COc1ccccc1C(=O)O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['CC(C)(C)OC(=O)OC(=O)OC(C)(C)C.C[C@H](N)CO>CCN(CC)CC.CN(C)C=O.O.O>C[C@@H](CO)NC(=O)OC(C)(C)C', 'CC(C)(C)OC(=O)OC(=O)OC(C)(C)C.C[C@H](N)CO>C1CCOC1.CCN(CC)CC>C[C@@H](CO)NC(=O)OC(C)(C)C', 'CC(C)(C)OC(=O)OC(=O)OC(C)(C)C.C[C@H](N)CO>CCN(CC)CC.ClCCl>C[C@@H](CO)NC(=O)OC(C)(C)C', 'CC(C)(C)OC(=O)OC(C)(C)C.C[C@H](N)CO>C1CCOC1.CCN(CC)CC>C[C@@H](CO)NC(=O)OC(C)(C)C']","['CCOC(=O)N=NC(=O)OCC.COC(=O)c1ccc(O)cc1.C[C@@H](CO)NC(=O)OC(C)(C)C>C1CCOC1.Cc1ccccc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1>COC(=O)c1ccc(OC[C@H](C)NC(C)=O)cc1', 'CCOC(=O)N=NC(=O)OCC.COC(=O)c1ccc(O)cc1.C[C@@H](CO)NC(=O)OC(C)(C)C>C1CCOC1.Cc1ccccc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1>COC(=O)c1ccc(OC[C@H](C)NC(C)=O)cc1', 'CCOC(=O)N=NC(=O)OCC.COC(=O)c1ccc(O)cc1.C[C@@H](CO)NC(=O)OC(C)(C)C>C1CCOC1.Cc1ccccc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1>COC(=O)c1ccc(OC[C@H](C)NC(C)=O)cc1', 'CCOC(=O)N=NC(=O)OCC.COC(=O)c1ccc(O)cc1.C[C@@H](CO)NC(=O)OC(C)(C)C>C1CCOC1.Cc1ccccc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1>COC(=O)c1ccc(OC[C@H](C)NC(C)=O)cc1']","['COC(=O)c1ccc(OC[C@H](C)NC(C)=O)cc1>CO.Cl.[Na+].[OH-]>CC(=O)N[C@@H](C)COc1ccccc1C(=O)O', 'COC(=O)c1ccc(OC[C@H](C)NC(C)=O)cc1>CO.Cl.[Na+].[OH-]>CC(=O)N[C@@H](C)COc1ccccc1C(=O)O', 'COC(=O)c1ccc(OC[C@H](C)NC(C)=O)cc1>CO.Cl.[Na+].[OH-]>CC(=O)N[C@@H](C)COc1ccccc1C(=O)O', 'COC(=O)c1ccc(OC[C@H](C)NC(C)=O)cc1>CO.Cl.[Na+].[OH-]>CC(=O)N[C@@H](C)COc1ccccc1C(=O)O']","[['C[C@@H](CO)NC(=O)OC(C)(C)C', 'COC(=O)c1ccc(OC[C@H](C)NC(C)=O)cc1']]"
36,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1</SMILES> starting from <SMILES>CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1.O=C(O)[C@@](O)(C(=O)c1ccccc1)[C@@](O)(C(=O)O)C(=O)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1.O=C(O)[C@@](O)(C(=O)c1ccccc1)[C@@](O)(C(=O)O)C(=O)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1</SMILES> starting from <SMILES>CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1.O=C(O)[C@@](O)(C(=O)c1ccccc1)[C@@](O)(C(=O)O)C(=O)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1.O=C(O)[C@@](O)(C(=O)c1ccccc1)[C@@](O)(C(=O)O)C(=O)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1</SMILES> starting from <SMILES>CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1.O=C(O)[C@@](O)(C(=O)c1ccccc1)[C@@](O)(C(=O)O)C(=O)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1.O=C(O)[C@@](O)(C(=O)c1ccccc1)[C@@](O)(C(=O)O)C(=O)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1.O=C(O)[C@@](O)(C(=O)c1ccccc1)[C@@](O)(C(=O)O)C(=O)c1ccccc1>O.[Na+].[OH-]>CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1'],['CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1.O=C(O)[C@](O)(C(=O)c1ccccc1)[C@](O)(C(=O)O)C(=O)c1ccccc1>CCO.CCOCC>CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1.O=C(O)[C@](O)(C(=O)c1ccccc1)[C@](O)(C(=O)O)C(=O)c1ccccc1'],['CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1.O=C(O)[C@](O)(C(=O)c1ccccc1)[C@](O)(C(=O)O)C(=O)c1ccccc1>O.[Na+].[OH-]>CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1'],"[['CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1', 'CC(C)(C)NC(CO)c1cc(Cl)c(N)c(C#N)c1.O=C(O)[C@](O)(C(=O)c1ccccc1)[C@](O)(C(=O)O)C(=O)c1ccccc1']]"
37,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1cnc2c(c1)c(I)cn2[Si](C(C)C)(C(C)C)C(C)C</SMILES> starting from <SMILES>CC(C)[Si](Cl)(C(C)C)C(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)[Si](Cl)(C(C)C)C(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1cnc2c(c1)c(I)cn2[Si](C(C)C)(C(C)C)C(C)C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1cnc2c(c1)c(I)cn2[Si](C(C)C)(C(C)C)C(C)C</SMILES> starting from <SMILES>CC(C)[Si](Cl)(C(C)C)C(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)[Si](Cl)(C(C)C)C(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1cnc2c(c1)c(I)cn2[Si](C(C)C)(C(C)C)C(C)C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1cnc2c(c1)c(I)cn2[Si](C(C)C)(C(C)C)C(C)C</SMILES> starting from <SMILES>CC(C)[Si](Cl)(C(C)C)C(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)[Si](Cl)(C(C)C)C(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1cnc2c(c1)c(I)cn2[Si](C(C)C)(C(C)C)C(C)C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['Brc1cnc2[nH]ccc2c1.CC(C)[Si](Cl)(C(C)C)C(C)C>C1CCOC1.[H-].[Na+]>CC(C)[Si](C(C)C)(C(C)C)n1ccc2cc(Br)cnc21', 'Brc1cnc2[nH]ccc2c1.CC(C)[Si](Cl)(C(C)C)C(C)C>C1CCOC1.CCOCC.C[Si](C)(C)[N-][Si](C)(C)C.[Li+]>CC(C)[Si](C(C)C)(C(C)C)n1ccc2cc(Br)cnc21']","['CC(C)[Si](C(C)C)(C(C)C)n1ccc2cc(Br)cnc21.C[Mg]Br>Cc1ccccc1.Cl[Pd]Cl.O=C(O)CC(O)(CC(=O)O)C(=O)O.[Fe+2].c1ccc(P(c2ccccc2)[c-]2cccc2)cc1.c1ccc(P(c2ccccc2)[c-]2cccc2)cc1>Cc1cnc2c(ccn2[Si](C(C)C)(C(C)C)C(C)C)c1', 'CC(C)[Si](C(C)C)(C(C)C)n1ccc2cc(Br)cnc21.C[Mg]Br>Cc1ccccc1.Cl[Pd]Cl.O=C(O)CC(O)(CC(=O)O)C(=O)O.[Fe+2].c1ccc(P(c2ccccc2)[c-]2cccc2)cc1.c1ccc(P(c2ccccc2)[c-]2cccc2)cc1>Cc1cnc2c(ccn2[Si](C(C)C)(C(C)C)C(C)C)c1']","['Cc1cnc2c(ccn2[Si](C(C)C)(C(C)C)C(C)C)c1.O=C1CCC(=O)N1I>ClCCl>Cc1cnc2c(c1)c(I)cn2[Si](C(C)C)(C(C)C)C(C)C', 'Cc1cnc2c(ccn2[Si](C(C)C)(C(C)C)C(C)C)c1.O=C1CCC(=O)N1I>ClCCl>Cc1cnc2c(c1)c(I)cn2[Si](C(C)C)(C(C)C)C(C)C']","[['CC(C)[Si](C(C)C)(C(C)C)n1ccc2cc(Br)cnc21', 'Cc1cnc2c(ccn2[Si](C(C)C)(C(C)C)C(C)C)c1']]"
38,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>Clc1cc(N2CCOCC2)nc(CCc2cccnc2)n1</SMILES> starting from <SMILES>c1ccc(P(c2ccccc2)c2ccccc2)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>c1ccc(P(c2ccccc2)c2ccccc2)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Clc1cc(N2CCOCC2)nc(CCc2cccnc2)n1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Clc1cc(N2CCOCC2)nc(CCc2cccnc2)n1</SMILES> starting from <SMILES>c1ccc(P(c2ccccc2)c2ccccc2)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>c1ccc(P(c2ccccc2)c2ccccc2)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Clc1cc(N2CCOCC2)nc(CCc2cccnc2)n1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Clc1cc(N2CCOCC2)nc(CCc2cccnc2)n1</SMILES> starting from <SMILES>c1ccc(P(c2ccccc2)c2ccccc2)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>c1ccc(P(c2ccccc2)c2ccccc2)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Clc1cc(N2CCOCC2)nc(CCc2cccnc2)n1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['Clc1cc(N2CCOCC2)nc(CBr)n1.c1ccc(P(c2ccccc2)c2ccccc2)cc1>Cc1ccccc1>Clc1cc(N2CCOCC2)nc(C[P+](c2ccccc2)(c2ccccc2)c2ccccc2)n1.[Br-]'],['Clc1cc(N2CCOCC2)nc(C[P+](c2ccccc2)(c2ccccc2)c2ccccc2)n1.O=Cc1cccnc1.[Br-]>CCN(CC)CC.Cc1ccccc1>Clc1cc(N2CCOCC2)nc(C=Cc2cccnc2)n1.O=P(c1ccccc1)(c1ccccc1)c1ccccc1'],['Clc1cc(N2CCOCC2)nc(C=Cc2cccnc2)n1>CC(=O)O.CCO.[Pd]>Clc1cc(N2CCOCC2)nc(CCc2cccnc2)n1'],"[['Clc1cc(N2CCOCC2)nc(C[P+](c2ccccc2)(c2ccccc2)c2ccccc2)n1.[Br-]', 'Clc1cc(N2CCOCC2)nc(C=Cc2cccnc2)n1']]"
39,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>NNC(=O)CCCN1C(=O)C=CC1=O.O=C(O)C(F)(F)F</SMILES> starting from <SMILES>NCCCC(=O)O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>NCCCC(=O)O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>NNC(=O)CCCN1C(=O)C=CC1=O.O=C(O)C(F)(F)F</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>NNC(=O)CCCN1C(=O)C=CC1=O.O=C(O)C(F)(F)F</SMILES> starting from <SMILES>NCCCC(=O)O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>NCCCC(=O)O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>NNC(=O)CCCN1C(=O)C=CC1=O.O=C(O)C(F)(F)F</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>NNC(=O)CCCN1C(=O)C=CC1=O.O=C(O)C(F)(F)F</SMILES> starting from <SMILES>NCCCC(=O)O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>NCCCC(=O)O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>NNC(=O)CCCN1C(=O)C=CC1=O.O=C(O)C(F)(F)F</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['NCCCC(=O)O.O=C1C=CC(=O)O1>CC(=O)O>O=C(O)CCCN1C(=O)C=CC1=O'],['CC(C)(C)OC(=O)NN.O=C(O)CCCN1C(=O)C=CC1=O>ClCCCl.ClCCl>CC(C)(C)OC(=O)NNC(=O)CCCN1C(=O)C=CC1=O'],['CC(C)(C)OC(=O)NNC(=O)CCCN1C(=O)C=CC1=O.O=C(O)C(F)(F)F>CCO.Cc1ccccc1.ClCCl>NNC(=O)CCCN1C(=O)C=CC1=O.O=C(O)C(F)(F)F'],"[['O=C(O)CCCN1C(=O)C=CC1=O', 'CC(C)(C)OC(=O)NNC(=O)CCCN1C(=O)C=CC1=O']]"
40,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCC(CC)(c1ccc2c(c1)nc(C)n2C)c1c[nH]c2c(NS(C)(=O)=O)cccc12</SMILES> starting from <SMILES>O=[N+]([O-])c1ccc(Cl)c2cc[nH]c12</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=[N+]([O-])c1ccc(Cl)c2cc[nH]c12</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCC(CC)(c1ccc2c(c1)nc(C)n2C)c1c[nH]c2c(NS(C)(=O)=O)cccc12</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCC(CC)(c1ccc2c(c1)nc(C)n2C)c1c[nH]c2c(NS(C)(=O)=O)cccc12</SMILES> starting from <SMILES>O=[N+]([O-])c1ccc(Cl)c2cc[nH]c12</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=[N+]([O-])c1ccc(Cl)c2cc[nH]c12</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCC(CC)(c1ccc2c(c1)nc(C)n2C)c1c[nH]c2c(NS(C)(=O)=O)cccc12</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCC(CC)(c1ccc2c(c1)nc(C)n2C)c1c[nH]c2c(NS(C)(=O)=O)cccc12</SMILES> starting from <SMILES>O=[N+]([O-])c1ccc(Cl)c2cc[nH]c12</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=[N+]([O-])c1ccc(Cl)c2cc[nH]c12</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCC(CC)(c1ccc2c(c1)nc(C)n2C)c1c[nH]c2c(NS(C)(=O)=O)cccc12</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['O=[N+]([O-])c1ccc(Cl)c2cc[nH]c12>CO.[Na+].[OH-].[Pd]>Nc1cccc2cc[nH]c12'],['CS(=O)(=O)Cl.Nc1cccc2cc[nH]c12>ClCCl.c1ccncc1>CS(=O)(=O)Nc1cccc2cc[nH]c12'],['CCC(O)(CC)c1ccc2c(c1)nc(C)n2C.CS(=O)(=O)Nc1cccc2cc[nH]c12>ClCCl.O=C(O)C(F)(F)F>CCC(CC)(c1ccc2c(c1)nc(C)n2C)c1c[nH]c2c(NS(C)(=O)=O)cccc12'],"[['Nc1cccc2cc[nH]c12', 'CS(=O)(=O)Nc1cccc2cc[nH]c12']]"
41,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>OCc1cc2c(Br)coc2cn1</SMILES> starting from <SMILES>C[Si](C)(C)c1cc2cc(CO)ncc2o1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C[Si](C)(C)c1cc2cc(CO)ncc2o1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>OCc1cc2c(Br)coc2cn1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>OCc1cc2c(Br)coc2cn1</SMILES> starting from <SMILES>C[Si](C)(C)c1cc2cc(CO)ncc2o1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C[Si](C)(C)c1cc2cc(CO)ncc2o1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>OCc1cc2c(Br)coc2cn1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>OCc1cc2c(Br)coc2cn1</SMILES> starting from <SMILES>C[Si](C)(C)c1cc2cc(CO)ncc2o1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C[Si](C)(C)c1cc2cc(CO)ncc2o1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>OCc1cc2c(Br)coc2cn1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['C[Si](C)(C)c1cc2cc(CO)ncc2o1>CO.[Na+].[OH-]>OCc1cc2ccoc2cn1'],['CC(=O)OC(C)=O.OCc1cc2ccoc2cn1>c1ccncc1>CC(=O)OCc1cc2ccoc2cn1'],['BrBr.CC(=O)OCc1cc2ccoc2cn1>ClCCl.O=C([O-])O.O=C([O-])[O-].[K+].[K+].[Na+]>OCc1cc2c(Br)coc2cn1'],"[['OCc1cc2ccoc2cn1', 'CC(=O)OCc1cc2ccoc2cn1']]"
42,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C(O)C(CO)Cc1ccccc1</SMILES> starting from <SMILES>C=C(C(=O)OC)C(O)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C=C(C(=O)OC)C(O)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C(O)C(CO)Cc1ccccc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C(O)C(CO)Cc1ccccc1</SMILES> starting from <SMILES>C=C(C(=O)OC)C(O)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C=C(C(=O)OC)C(O)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C(O)C(CO)Cc1ccccc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C(O)C(CO)Cc1ccccc1</SMILES> starting from <SMILES>C=C(C(=O)OC)C(O)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C=C(C(=O)OC)C(O)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C(O)C(CO)Cc1ccccc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['C=C(C(=O)OC)C(O)c1ccccc1.CC(=O)OC(C)=O>O=S(=O)(O)O>COC(=O)C(=Cc1ccccc1)COC(C)=O', 'C=C(C(=O)OC)C(O)c1ccccc1.CC(=O)OC(C)=O>O=S(=O)(O)O>COC(=O)C(=Cc1ccccc1)COC(C)=O']","['COC(=O)C(=Cc1ccccc1)COC(C)=O>CO.O.[Na+].[OH-]>O=C(O)C(=Cc1ccccc1)CO', 'COC(=O)C(=Cc1ccccc1)COC(C)=O>CO.O.[Na+].[OH-]>O=C(O)C(=Cc1ccccc1)CO']","['O=C(O)C(=Cc1ccccc1)CO>CCN(CC)CC.CO.[C].[H][H].[Pd]>O=C(O)C(CO)Cc1ccccc1', 'O=C(O)C(=Cc1ccccc1)CO>CO.N.O.[C].[H][H].[Pd]>O=C(O)C(CO)Cc1ccccc1']","[['COC(=O)C(=Cc1ccccc1)COC(C)=O', 'O=C(O)C(=Cc1ccccc1)CO']]"
43,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1cc(OC)nc(-n2c(=S)[nH]c3cc(C(=O)NCc4ccc(S(C)(=O)=O)cc4)ccc3c2=O)n1</SMILES> starting from <SMILES>COC(=O)c1ccc(C(=O)OC)c(N)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COC(=O)c1ccc(C(=O)OC)c(N)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1cc(OC)nc(-n2c(=S)[nH]c3cc(C(=O)NCc4ccc(S(C)(=O)=O)cc4)ccc3c2=O)n1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1cc(OC)nc(-n2c(=S)[nH]c3cc(C(=O)NCc4ccc(S(C)(=O)=O)cc4)ccc3c2=O)n1</SMILES> starting from <SMILES>COC(=O)c1ccc(C(=O)OC)c(N)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COC(=O)c1ccc(C(=O)OC)c(N)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1cc(OC)nc(-n2c(=S)[nH]c3cc(C(=O)NCc4ccc(S(C)(=O)=O)cc4)ccc3c2=O)n1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1cc(OC)nc(-n2c(=S)[nH]c3cc(C(=O)NCc4ccc(S(C)(=O)=O)cc4)ccc3c2=O)n1</SMILES> starting from <SMILES>COC(=O)c1ccc(C(=O)OC)c(N)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COC(=O)c1ccc(C(=O)OC)c(N)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1cc(OC)nc(-n2c(=S)[nH]c3cc(C(=O)NCc4ccc(S(C)(=O)=O)cc4)ccc3c2=O)n1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['COC(=O)c1ccc(C(=O)OC)c(N)c1.S=C(Cl)Cl>ClC(Cl)Cl.O=C([O-])O.[Na+]>COC(=O)c1ccc(C(=O)OC)c(N=C=S)c1'],['COC(=O)c1ccc(C(=O)OC)c(N=C=S)c1.COc1cc(OC)nc(N)n1>CN(C)C=O.Cl.[Na+].[OH-]>COc1cc(OC)nc(-n2c(=S)[nH]c3cc(C(=O)O)ccc3c2=O)n1'],['COc1cc(OC)nc(-n2c(=S)[nH]c3cc(C(=O)O)ccc3c2=O)n1.CS(=O)(=O)c1ccc(CN)cc1.Cl>CCN(C(C)C)C(C)C.CN(C)C(On1nnc2cccnc21)=[N+](C)C.CN(C)C=O.F[P-](F)(F)(F)(F)F>COc1cc(OC)nc(-n2c(=S)[nH]c3cc(C(=O)NCc4ccc(S(C)(=O)=O)cc4)ccc3c2=O)n1'],"[['COC(=O)c1ccc(C(=O)OC)c(N=C=S)c1', 'COc1cc(OC)nc(-n2c(=S)[nH]c3cc(C(=O)O)ccc3c2=O)n1']]"
44,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>Nc1cccc(C(=O)Nc2nnn[nH]2)c1</SMILES> starting from <SMILES>O=C(O)c1cccc([N+](=O)[O-])c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)c1cccc([N+](=O)[O-])c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Nc1cccc(C(=O)Nc2nnn[nH]2)c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Nc1cccc(C(=O)Nc2nnn[nH]2)c1</SMILES> starting from <SMILES>O=C(O)c1cccc([N+](=O)[O-])c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)c1cccc([N+](=O)[O-])c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Nc1cccc(C(=O)Nc2nnn[nH]2)c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Nc1cccc(C(=O)Nc2nnn[nH]2)c1</SMILES> starting from <SMILES>O=C(O)c1cccc([N+](=O)[O-])c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)c1cccc([N+](=O)[O-])c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Nc1cccc(C(=O)Nc2nnn[nH]2)c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['O=C(Cl)C(=O)Cl.O=C(O)c1cccc([N+](=O)[O-])c1>CN(C)C=O.c1ccccc1>O=C(Cl)c1cccc([N+](=O)[O-])c1', 'O=C(O)c1cccc([N+](=O)[O-])c1.O=S(Cl)Cl>>O=C(Cl)c1cccc([N+](=O)[O-])c1']","['Nc1nnn[nH]1.O.O=C(Cl)c1cccc([N+](=O)[O-])c1>C1CCOC1.O>O=C(Nc1nnn[nH]1)c1cccc([N+](=O)[O-])c1', 'Nc1nnn[nH]1.O.O=C(Cl)c1cccc([N+](=O)[O-])c1>C1CCOC1.O>O=C(Nc1nnn[nH]1)c1cccc([N+](=O)[O-])c1']","['O=C(Nc1nnn[nH]1)c1cccc([N+](=O)[O-])c1>CCO.Cl.[Pd]>Nc1cccc(C(=O)Nc2nnn[nH]2)c1', 'O=C(Nc1nnn[nH]1)c1cccc([N+](=O)[O-])c1>CCO.Cl.[Pd]>Nc1cccc(C(=O)Nc2nnn[nH]2)c1']","[['O=C(Cl)c1cccc([N+](=O)[O-])c1', 'O=C(Nc1nnn[nH]1)c1cccc([N+](=O)[O-])c1']]"
45,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOP(=O)(CP(=O)(OCC)c1ccc(OP(=O)(CC)CC)c(C(C)(C)CC(=O)N2CCN(c3c(F)cc4c(=O)c(C(=O)O)cn(C5CC5)c4c3OC)CC2C)c1)OCC</SMILES> starting from <SMILES>CCOC(=O)c1cn(C2CC2)c2c(OC)c(F)c(F)cc2c1=O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)c1cn(C2CC2)c2c(OC)c(F)c(F)cc2c1=O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOP(=O)(CP(=O)(OCC)c1ccc(OP(=O)(CC)CC)c(C(C)(C)CC(=O)N2CCN(c3c(F)cc4c(=O)c(C(=O)O)cn(C5CC5)c4c3OC)CC2C)c1)OCC</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOP(=O)(CP(=O)(OCC)c1ccc(OP(=O)(CC)CC)c(C(C)(C)CC(=O)N2CCN(c3c(F)cc4c(=O)c(C(=O)O)cn(C5CC5)c4c3OC)CC2C)c1)OCC</SMILES> starting from <SMILES>CCOC(=O)c1cn(C2CC2)c2c(OC)c(F)c(F)cc2c1=O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)c1cn(C2CC2)c2c(OC)c(F)c(F)cc2c1=O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOP(=O)(CP(=O)(OCC)c1ccc(OP(=O)(CC)CC)c(C(C)(C)CC(=O)N2CCN(c3c(F)cc4c(=O)c(C(=O)O)cn(C5CC5)c4c3OC)CC2C)c1)OCC</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOP(=O)(CP(=O)(OCC)c1ccc(OP(=O)(CC)CC)c(C(C)(C)CC(=O)N2CCN(c3c(F)cc4c(=O)c(C(=O)O)cn(C5CC5)c4c3OC)CC2C)c1)OCC</SMILES> starting from <SMILES>CCOC(=O)c1cn(C2CC2)c2c(OC)c(F)c(F)cc2c1=O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)c1cn(C2CC2)c2c(OC)c(F)c(F)cc2c1=O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOP(=O)(CP(=O)(OCC)c1ccc(OP(=O)(CC)CC)c(C(C)(C)CC(=O)N2CCN(c3c(F)cc4c(=O)c(C(=O)O)cn(C5CC5)c4c3OC)CC2C)c1)OCC</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CCOC(=O)c1cn(C2CC2)c2c(OC)c(F)c(F)cc2c1=O>CO.Cl.[Na+].[OH-]>COc1c(F)c(F)cc2c(=O)c(C(=O)O)cn(C3CC3)c12'],['CC1CNCCN1.COc1c(F)c(F)cc2c(=O)c(C(=O)O)cn(C3CC3)c12>CS(C)=O.O>COc1c(N2CCNC(C)C2)c(F)cc2c(=O)c(C(=O)O)cn(C3CC3)c12'],['CCOP(=O)(CP(=O)(OCC)c1ccc(OP(=O)(CC)CC)c(C(C)(C)CC(=O)O)c1)OCC.COc1c(N2CCNC(C)C2)c(F)cc2c(=O)c(C(=O)O)cn(C3CC3)c12>CCN(C(C)C)C(C)C.CCOC(C)=O.CN(C)C(On1nnc2ccccc21)=[N+](C)C.CN(C)C=O.F[P-](F)(F)(F)(F)F>CCOP(=O)(CP(=O)(OCC)c1ccc(OP(=O)(CC)CC)c(C(C)(C)CC(=O)N2CCN(c3c(F)cc4c(=O)c(C(=O)O)cn(C5CC5)c4c3OC)CC2C)c1)OCC'],"[['COc1c(F)c(F)cc2c(=O)c(C(=O)O)cn(C3CC3)c12', 'COc1c(N2CCNC(C)C2)c(F)cc2c(=O)c(C(=O)O)cn(C3CC3)c12']]"
46,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cn1nc(NCC(=O)NC2CN(C3CCC(O)(c4cncs4)CC3)C2)c2cc(C(F)C(F)(F)F)ccc21</SMILES> starting from <SMILES>C[Si](C)(C)c1nccs1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C[Si](C)(C)c1nccs1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cn1nc(NCC(=O)NC2CN(C3CCC(O)(c4cncs4)CC3)C2)c2cc(C(F)C(F)(F)F)ccc21</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cn1nc(NCC(=O)NC2CN(C3CCC(O)(c4cncs4)CC3)C2)c2cc(C(F)C(F)(F)F)ccc21</SMILES> starting from <SMILES>C[Si](C)(C)c1nccs1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C[Si](C)(C)c1nccs1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cn1nc(NCC(=O)NC2CN(C3CCC(O)(c4cncs4)CC3)C2)c2cc(C(F)C(F)(F)F)ccc21</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cn1nc(NCC(=O)NC2CN(C3CCC(O)(c4cncs4)CC3)C2)c2cc(C(F)C(F)(F)F)ccc21</SMILES> starting from <SMILES>C[Si](C)(C)c1nccs1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C[Si](C)(C)c1nccs1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cn1nc(NCC(=O)NC2CN(C3CCC(O)(c4cncs4)CC3)C2)c2cc(C(F)C(F)(F)F)ccc21</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['C[Si](C)(C)c1nccs1.O=C1CCC2(CC1)OCCO2>C1CCOC1.CCOC(C)=O.O.[Li]CCCC>OC1(c2cncs2)CCC2(CC1)OCCO2'],['OC1(c2cncs2)CCC2(CC1)OCCO2>C1CCOC1.Cl.O=C([O-])[O-].[Na+].[Na+]>O=C1CCC(O)(c2cncs2)CC1'],['Cn1nc(NCC(=O)NC2CNC2)c2cc(C(F)C(F)(F)F)ccc21.O=C(O)C(F)(F)F.O=C1CCC(O)(c2cncs2)CC1>>Cn1nc(NCC(=O)NC2CN(C3CCC(O)(c4cncs4)CC3)C2)c2cc(C(F)C(F)(F)F)ccc21'],"[['OC1(c2cncs2)CCC2(CC1)OCCO2', 'O=C1CCC(O)(c2cncs2)CC1']]"
47,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)c1cnc2cc(C(F)(F)F)ccc2c1Nc1ccc(C(=O)Cl)cc1.Cl</SMILES> starting from <SMILES>O=C(O)c1ccccc1[N+](=O)[O-]</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)c1ccccc1[N+](=O)[O-]</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)c1cnc2cc(C(F)(F)F)ccc2c1Nc1ccc(C(=O)Cl)cc1.Cl</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)c1cnc2cc(C(F)(F)F)ccc2c1Nc1ccc(C(=O)Cl)cc1.Cl</SMILES> starting from <SMILES>O=C(O)c1ccccc1[N+](=O)[O-]</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)c1ccccc1[N+](=O)[O-]</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)c1cnc2cc(C(F)(F)F)ccc2c1Nc1ccc(C(=O)Cl)cc1.Cl</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)c1cnc2cc(C(F)(F)F)ccc2c1Nc1ccc(C(=O)Cl)cc1.Cl</SMILES> starting from <SMILES>O=C(O)c1ccccc1[N+](=O)[O-]</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)c1ccccc1[N+](=O)[O-]</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)c1cnc2cc(C(F)(F)F)ccc2c1Nc1ccc(C(=O)Cl)cc1.Cl</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['O=C(O)c1ccccc1[N+](=O)[O-]>CC(=O)O.CCO.[H][H].[Pd]>Nc1ccc(C(=O)O)cc1'],['CCOC(=O)c1cnc2cc(C(F)(F)F)ccc2c1Cl.Nc1ccc(C(=O)O)cc1>C1CCOC1>CCOC(=O)c1cnc2cc(C(F)(F)F)ccc2c1Nc1ccc(C(=O)O)cc1.Cl'],['CCOC(=O)c1cnc2cc(C(F)(F)F)ccc2c1Nc1ccc(C(=O)O)cc1.Cl>O=S(Cl)Cl>CCOC(=O)c1cnc2cc(C(F)(F)F)ccc2c1Nc1ccc(C(=O)Cl)cc1.Cl'],"[['Nc1ccc(C(=O)O)cc1', 'CCOC(=O)c1cnc2cc(C(F)(F)F)ccc2c1Nc1ccc(C(=O)O)cc1.Cl']]"
48,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>Clc1ccc(C(=CC=Cc2cccc(Oc3ccccc3)c2)C2CC2)cc1</SMILES> starting from <SMILES>OCc1cccc(Oc2ccccc2)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>OCc1cccc(Oc2ccccc2)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Clc1ccc(C(=CC=Cc2cccc(Oc3ccccc3)c2)C2CC2)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Clc1ccc(C(=CC=Cc2cccc(Oc3ccccc3)c2)C2CC2)cc1</SMILES> starting from <SMILES>OCc1cccc(Oc2ccccc2)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>OCc1cccc(Oc2ccccc2)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Clc1ccc(C(=CC=Cc2cccc(Oc3ccccc3)c2)C2CC2)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Clc1ccc(C(=CC=Cc2cccc(Oc3ccccc3)c2)C2CC2)cc1</SMILES> starting from <SMILES>OCc1cccc(Oc2ccccc2)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>OCc1cccc(Oc2ccccc2)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Clc1ccc(C(=CC=Cc2cccc(Oc3ccccc3)c2)C2CC2)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['O=S(Cl)Cl.OCc1cccc(Oc2ccccc2)c1>ClC(Cl)Cl>ClCc1cccc(Oc2ccccc2)c1', 'ClC(Cl)(Cl)Cl.OCc1cccc(Oc2ccccc2)c1>c1ccc(P(c2ccccc2)c2ccccc2)cc1>ClCc1cccc(Oc2ccccc2)c1', 'O=S(Cl)Cl.OCc1cccc(Oc2ccccc2)c1>CN(C)C=O.ClCCl>ClCc1cccc(Oc2ccccc2)c1']","['ClCc1cccc(Oc2ccccc2)c1.c1ccc(P(c2ccccc2)c2ccccc2)cc1>Cc1ccccc1>[Cl-].c1ccc(Oc2cccc(C[P+](c3ccccc3)(c3ccccc3)c3ccccc3)c2)cc1', 'ClCc1cccc(Oc2ccccc2)c1.c1ccc(P(c2ccccc2)c2ccccc2)cc1>Cc1ccccc1>[Cl-].c1ccc(Oc2cccc(C[P+](c3ccccc3)(c3ccccc3)c3ccccc3)c2)cc1', 'ClCc1cccc(Oc2ccccc2)c1.c1ccc(P(c2ccccc2)c2ccccc2)cc1>Cc1ccccc1>[Cl-].c1ccc(Oc2cccc(C[P+](c3ccccc3)(c3ccccc3)c3ccccc3)c2)cc1']","['O=CC=C(c1ccc(Cl)cc1)C1CC1.[Cl-].c1ccc(Oc2cccc(C[P+](c3ccccc3)(c3ccccc3)c3ccccc3)c2)cc1>C1CCOC1.[Li]CCCC>Clc1ccc(C(=CC=Cc2cccc(Oc3ccccc3)c2)C2CC2)cc1', 'O=CC=C(c1ccc(Cl)cc1)C1CC1.[Cl-].c1ccc(Oc2cccc(C[P+](c3ccccc3)(c3ccccc3)c3ccccc3)c2)cc1>C1CCOC1.[Li]CCCC>Clc1ccc(C(=CC=Cc2cccc(Oc3ccccc3)c2)C2CC2)cc1', 'O=CC=C(c1ccc(Cl)cc1)C1CC1.[Cl-].c1ccc(Oc2cccc(C[P+](c3ccccc3)(c3ccccc3)c3ccccc3)c2)cc1>C1CCOC1.[Li]CCCC>Clc1ccc(C(=CC=Cc2cccc(Oc3ccccc3)c2)C2CC2)cc1']","[['ClCc1cccc(Oc2ccccc2)c1', '[Cl-].c1ccc(Oc2cccc(C[P+](c3ccccc3)(c3ccccc3)c3ccccc3)c2)cc1']]"
49,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1nccc2[nH]c(=O)ccc12</SMILES> starting from <SMILES>CC(=O)c1cc(C#N)c(=O)[nH]c1C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(=O)c1cc(C#N)c(=O)[nH]c1C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1nccc2[nH]c(=O)ccc12</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1nccc2[nH]c(=O)ccc12</SMILES> starting from <SMILES>CC(=O)c1cc(C#N)c(=O)[nH]c1C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(=O)c1cc(C#N)c(=O)[nH]c1C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1nccc2[nH]c(=O)ccc12</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1nccc2[nH]c(=O)ccc12</SMILES> starting from <SMILES>CC(=O)c1cc(C#N)c(=O)[nH]c1C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(=O)c1cc(C#N)c(=O)[nH]c1C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1nccc2[nH]c(=O)ccc12</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['CC(=O)c1cc(C#N)c(=O)[nH]c1C>Cl>CC(=O)c1ccc(=O)[nH]c1C', 'CC(=O)c1cc(C#N)c(=O)[nH]c1C>Cl>CC(=O)c1ccc(=O)[nH]c1C', 'CC(=O)c1cc(C#N)c(=O)[nH]c1C>Cl>CC(=O)c1ccc(=O)[nH]c1C', 'CC(=O)c1cc(C#N)c(=O)[nH]c1C>Cl>CC(=O)c1ccc(=O)[nH]c1C']","['CC(=O)c1ccc(=O)[nH]c1C.COC(OC)N(C)C>>CC(=O)c1ccc(=O)[nH]c1C=CN(C)C', 'CC(=O)c1ccc(=O)[nH]c1C.COC(OC)N(C)C>CN(C)C=O>CC(=O)c1ccc(=O)[nH]c1C=CN(C)C', 'CC(=O)c1ccc(=O)[nH]c1C.COC(OC)N(C)C>>CC(=O)c1ccc(=O)[nH]c1C=CN(C)C', 'CC(=O)c1ccc(=O)[nH]c1C.COC(OC)N(C)C>CN(C)C=O>CC(=O)c1ccc(=O)[nH]c1C=CN(C)C']","['CC(=O)c1ccc(=O)[nH]c1C=CN(C)C>CC(=O)[O-].N=CN.[NH4+]>Cc1nccc2[nH]c(=O)ccc12', 'CC(=O)c1ccc(=O)[nH]c1C=CN(C)C>CC(=O)[O-].N=CN.[NH4+]>Cc1nccc2[nH]c(=O)ccc12', 'CC(=O)c1ccc(=O)[nH]c1C=CN(C)C>CC(=O)O.CN(C)C=O.N=CN>Cc1nccc2[nH]c(=O)ccc12', 'CC(=O)c1ccc(=O)[nH]c1C=CN(C)C>CC(=O)O.CN(C)C=O.N=CN>Cc1nccc2[nH]c(=O)ccc12']","[['CC(=O)c1ccc(=O)[nH]c1C', 'CC(=O)c1ccc(=O)[nH]c1C=CN(C)C']]"
50,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>COCCN1C(=O)c2ccccc2C(C(=O)Nc2ccc(N3CCOCC3)cc2)C1c1cccs1</SMILES> starting from <SMILES>O=[N+]([O-])c1ccc(Cl)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=[N+]([O-])c1ccc(Cl)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COCCN1C(=O)c2ccccc2C(C(=O)Nc2ccc(N3CCOCC3)cc2)C1c1cccs1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COCCN1C(=O)c2ccccc2C(C(=O)Nc2ccc(N3CCOCC3)cc2)C1c1cccs1</SMILES> starting from <SMILES>O=[N+]([O-])c1ccc(Cl)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=[N+]([O-])c1ccc(Cl)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COCCN1C(=O)c2ccccc2C(C(=O)Nc2ccc(N3CCOCC3)cc2)C1c1cccs1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COCCN1C(=O)c2ccccc2C(C(=O)Nc2ccc(N3CCOCC3)cc2)C1c1cccs1</SMILES> starting from <SMILES>O=[N+]([O-])c1ccc(Cl)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=[N+]([O-])c1ccc(Cl)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COCCN1C(=O)c2ccccc2C(C(=O)Nc2ccc(N3CCOCC3)cc2)C1c1cccs1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['C1COCCN1.O=[N+]([O-])c1ccc(Cl)cc1>CS(C)=O.O=C([O-])[O-].[K+].[K+]>O=[N+]([O-])c1ccc(N2CCOCC2)cc1', 'C1COCCN1.O=[N+]([O-])c1ccc(Cl)cc1>CS(C)=O.O=C([O-])[O-].[K+].[K+]>O=[N+]([O-])c1ccc(N2CCOCC2)cc1', 'C1COCCN1.O=[N+]([O-])c1ccc(Cl)cc1>CS(C)=O.O=C([O-])[O-].[K+].[K+]>O=[N+]([O-])c1ccc(N2CCOCC2)cc1', 'C1COCCN1.O=[N+]([O-])c1ccc(Cl)cc1>CS(C)=O.O=C([O-])[O-].[K+].[K+]>O=[N+]([O-])c1ccc(N2CCOCC2)cc1']","['O=[N+]([O-])c1ccc(N2CCOCC2)cc1>CCOC(C)=O.CO.[C].[Pd]>Nc1ccc(N2CCOCC2)cc1', 'O=[N+]([O-])c1ccc(N2CCOCC2)cc1>CO.N.[Pd]>Nc1ccc(N2CCOCC2)cc1', 'O=[N+]([O-])c1ccc(N2CCOCC2)cc1>CO.[H][H].[Pd]>Nc1ccc(N2CCOCC2)cc1', 'O=[N+]([O-])c1ccc(N2CCOCC2)cc1>O=C[O-].OCC1CCCO1.[NH4+].[Pd]>Nc1ccc(N2CCOCC2)cc1']","['COCCN.Nc1ccc(N2CCOCC2)cc1.O=C1Cc2ccccc2C(=O)O1.O=Cc1cccs1>>COCCN1C(=O)c2ccccc2C(C(=O)Nc2ccc(N3CCOCC3)cc2)C1c1cccs1', 'COCCN.Nc1ccc(N2CCOCC2)cc1.O=C1Cc2ccccc2C(=O)O1.O=Cc1cccs1>>COCCN1C(=O)c2ccccc2C(C(=O)Nc2ccc(N3CCOCC3)cc2)C1c1cccs1', 'COCCN.Nc1ccc(N2CCOCC2)cc1.O=C1Cc2ccccc2C(=O)O1.O=Cc1cccs1>>COCCN1C(=O)c2ccccc2C(C(=O)Nc2ccc(N3CCOCC3)cc2)C1c1cccs1', 'COCCN.Nc1ccc(N2CCOCC2)cc1.O=C1Cc2ccccc2C(=O)O1.O=Cc1cccs1>>COCCN1C(=O)c2ccccc2C(C(=O)Nc2ccc(N3CCOCC3)cc2)C1c1cccs1']","[['O=[N+]([O-])c1ccc(N2CCOCC2)cc1', 'Nc1ccc(N2CCOCC2)cc1']]"
51,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>Brc1ccc2cc(OCCc3cccnc3)ccc2c1</SMILES> starting from <SMILES>Cl.O=C(O)Cc1cccnc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Cl.O=C(O)Cc1cccnc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Brc1ccc2cc(OCCc3cccnc3)ccc2c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Brc1ccc2cc(OCCc3cccnc3)ccc2c1</SMILES> starting from <SMILES>Cl.O=C(O)Cc1cccnc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Cl.O=C(O)Cc1cccnc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Brc1ccc2cc(OCCc3cccnc3)ccc2c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Brc1ccc2cc(OCCc3cccnc3)ccc2c1</SMILES> starting from <SMILES>Cl.O=C(O)Cc1cccnc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Cl.O=C(O)Cc1cccnc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Brc1ccc2cc(OCCc3cccnc3)ccc2c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['CCO.Cl.O=C(O)Cc1cccnc1>O=S(=O)(O)O.[NH4+].[OH-]>CCOC(=O)Cc1cccnc1', 'CCO.Cl.O=C(O)Cc1cccnc1>O=S(=O)(O)O.[NH4+].[OH-]>CCOC(=O)Cc1cccnc1', 'CCO.Cl.O=C(O)Cc1cccnc1>O=S(=O)(O)O.[NH4+].[OH-]>CCOC(=O)Cc1cccnc1', 'CCO.Cl.O=C(O)Cc1cccnc1>O=S(=O)(O)O.[NH4+].[OH-]>CCOC(=O)Cc1cccnc1']","['CCOC(=O)Cc1cccnc1>C1CCOC1.O.[Al+3].[H-].[H-].[H-].[H-].[Li+].[Na+].[OH-]>OCCc1cccnc1', 'CCOC(=O)Cc1cccnc1>CO.[BH4-].[Na+]>OCCc1cccnc1', 'CCOC(=O)Cc1cccnc1>C1CCOC1.O.[Al+3].[H-].[H-].[H-].[H-].[Li+].[Na+].[OH-]>OCCc1cccnc1', 'CCOC(=O)Cc1cccnc1>CO.[BH4-].[Na+]>OCCc1cccnc1']","['OCCc1cccnc1.Oc1cccc2cc(Br)ccc12>C1CCOC1.O=C([O-])N=NC(=O)[O-].c1ccc(P(c2ccccc2)c2ccccc2)cc1>Brc1ccc2cc(OCCc3cccnc3)ccc2c1', 'OCCc1cccnc1.Oc1cccc2cc(Br)ccc12>C1CCOC1.O=C([O-])N=NC(=O)[O-].c1ccc(P(c2ccccc2)c2ccccc2)cc1>Brc1ccc2cc(OCCc3cccnc3)ccc2c1', 'OCCc1cccnc1.Oc1cccc2cc(Br)ccc12>C1CCOC1.CC(C)OC(=O)N=NC(=O)OC(C)C.c1ccc(P(c2ccccc2)c2ccccc2)cc1>Brc1ccc2cc(OCCc3cccnc3)ccc2c1', 'OCCc1cccnc1.Oc1cccc2cc(Br)ccc12>C1CCOC1.CC(C)OC(=O)N=NC(=O)OC(C)C.c1ccc(P(c2ccccc2)c2ccccc2)cc1>Brc1ccc2cc(OCCc3cccnc3)ccc2c1']","[['CCOC(=O)Cc1cccnc1', 'OCCc1cccnc1']]"
52,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1cc(-c2nc3cc(F)cc(F)c3c(=O)[nH]2)cc(C)c1OCCN1CCCC1</SMILES> starting from <SMILES>O=C1Nc2cc(F)cc(F)c2C1=O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C1Nc2cc(F)cc(F)c2C1=O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1cc(-c2nc3cc(F)cc(F)c3c(=O)[nH]2)cc(C)c1OCCN1CCCC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1cc(-c2nc3cc(F)cc(F)c3c(=O)[nH]2)cc(C)c1OCCN1CCCC1</SMILES> starting from <SMILES>O=C1Nc2cc(F)cc(F)c2C1=O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C1Nc2cc(F)cc(F)c2C1=O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1cc(-c2nc3cc(F)cc(F)c3c(=O)[nH]2)cc(C)c1OCCN1CCCC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1cc(-c2nc3cc(F)cc(F)c3c(=O)[nH]2)cc(C)c1OCCN1CCCC1</SMILES> starting from <SMILES>O=C1Nc2cc(F)cc(F)c2C1=O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C1Nc2cc(F)cc(F)c2C1=O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1cc(-c2nc3cc(F)cc(F)c3c(=O)[nH]2)cc(C)c1OCCN1CCCC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['O=C1Nc2cc(F)cc(F)c2C1=O>[Na+].[OH-]>Nc1cc(F)cc(F)c1C(=O)O', 'O=C1Nc2cc(F)cc(F)c2C1=O.[Na+].[OH-]>O.O=CO.OO>Nc1cc(F)cc(F)c1C(=O)O']","['Nc1cc(F)cc(F)c1C(=O)O.[NH4+].[OH-]>C1CCOC1.CCN(CC)CC.CCN=C=NCCCN(C)C.Cl.Cl.On1nnc2ccccc21>NC(=O)c1c(N)cc(F)cc1F', 'Nc1cc(F)cc(F)c1C(=O)O.[NH4+].[OH-]>C1CCOC1.CCN(CC)CC.CCN=C=NCCCN(C)C.Cl.On1nnc2ccccc21>NC(=O)c1c(N)cc(F)cc1F']","['Cc1cc(C=O)cc(C)c1OCCN1CCCC1.NC(=O)c1c(N)cc(F)cc1F>CC(=O)N(C)C.Cc1ccc(S(=O)(=O)O)cc1.O.O=S([O-])O.[Na+]>Cc1cc(-c2nc3cc(F)cc(F)c3c(=O)[nH]2)cc(C)c1OCCN1CCCC1', 'Cc1cc(C=O)cc(C)c1OCCN1CCCC1.NC(=O)c1c(N)cc(F)cc1F>CC(=O)N(C)C.Cc1ccc(S(=O)(=O)O)cc1.O.O=S([O-])O.[Na+]>Cc1cc(-c2nc3cc(F)cc(F)c3c(=O)[nH]2)cc(C)c1OCCN1CCCC1']","[['Nc1cc(F)cc(F)c1C(=O)O', 'NC(=O)c1c(N)cc(F)cc1F']]"
53,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>NC(=O)C(c1ccccc1)(c1ccccc1)C1CCN(CCc2ccc3c(c2)CCC3)C1</SMILES> starting from <SMILES>N#CC(c1ccccc1)(c1ccccc1)C1CCN(Cc2ccccc2)C1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>N#CC(c1ccccc1)(c1ccccc1)C1CCN(Cc2ccccc2)C1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>NC(=O)C(c1ccccc1)(c1ccccc1)C1CCN(CCc2ccc3c(c2)CCC3)C1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>NC(=O)C(c1ccccc1)(c1ccccc1)C1CCN(CCc2ccc3c(c2)CCC3)C1</SMILES> starting from <SMILES>N#CC(c1ccccc1)(c1ccccc1)C1CCN(Cc2ccccc2)C1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>N#CC(c1ccccc1)(c1ccccc1)C1CCN(Cc2ccccc2)C1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>NC(=O)C(c1ccccc1)(c1ccccc1)C1CCN(CCc2ccc3c(c2)CCC3)C1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>NC(=O)C(c1ccccc1)(c1ccccc1)C1CCN(CCc2ccc3c(c2)CCC3)C1</SMILES> starting from <SMILES>N#CC(c1ccccc1)(c1ccccc1)C1CCN(Cc2ccccc2)C1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>N#CC(c1ccccc1)(c1ccccc1)C1CCN(Cc2ccccc2)C1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>NC(=O)C(c1ccccc1)(c1ccccc1)C1CCN(CCc2ccc3c(c2)CCC3)C1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['N#CC(c1ccccc1)(c1ccccc1)C1CCN(Cc2ccccc2)C1.O=C(Cl)Oc1ccccc1>ClCCl.c1ccncc1>N#CC(c1ccccc1)(c1ccccc1)C1CCN(C(=O)Oc2ccccc2)C1'],['N#CC(c1ccccc1)(c1ccccc1)C1CCN(C(=O)Oc2ccccc2)C1>O=S(=O)(O)O.[Na+].[OH-]>NC(=O)C(c1ccccc1)(c1ccccc1)C1CCNC1'],['BrCCc1ccc2c(c1)CCC2.NC(=O)C(c1ccccc1)(c1ccccc1)C1CCNC1>CC#N.O=C([O-])[O-].[K+].[K+]>NC(=O)C(c1ccccc1)(c1ccccc1)C1CCN(CCc2ccc3c(c2)CCC3)C1'],"[['N#CC(c1ccccc1)(c1ccccc1)C1CCN(C(=O)Oc2ccccc2)C1', 'NC(=O)C(c1ccccc1)(c1ccccc1)C1CCNC1']]"
54,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)/C=C\[C@H]1CC[C@H](NC(=O)OC(C)(C)C)CC1</SMILES> starting from <SMILES>CCOC(=O)[C@H]1CC[C@H](NC(=O)OC(C)(C)C)CC1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)[C@H]1CC[C@H](NC(=O)OC(C)(C)C)CC1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)/C=C\[C@H]1CC[C@H](NC(=O)OC(C)(C)C)CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)/C=C\[C@H]1CC[C@H](NC(=O)OC(C)(C)C)CC1</SMILES> starting from <SMILES>CCOC(=O)[C@H]1CC[C@H](NC(=O)OC(C)(C)C)CC1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)[C@H]1CC[C@H](NC(=O)OC(C)(C)C)CC1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)/C=C\[C@H]1CC[C@H](NC(=O)OC(C)(C)C)CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)/C=C\[C@H]1CC[C@H](NC(=O)OC(C)(C)C)CC1</SMILES> starting from <SMILES>CCOC(=O)[C@H]1CC[C@H](NC(=O)OC(C)(C)C)CC1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)[C@H]1CC[C@H](NC(=O)OC(C)(C)C)CC1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)/C=C\[C@H]1CC[C@H](NC(=O)OC(C)(C)C)CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['CCOC(=O)[C@H]1CC[C@H](NC(=O)OC(C)(C)C)CC1>CCOCC.CO.[BH4-].[Li+]>CC(C)(C)OC(=O)N[C@H]1CC[C@H](CO)CC1', 'CCOC(=O)[C@H]1CC[C@H](NC(=O)OC(C)(C)C)CC1>CCOCC.CO.[BH4-].[Li+]>CC(C)(C)OC(=O)N[C@H]1CC[C@H](CO)CC1']","['CC(C)(C)OC(=O)N[C@H]1CC[C@H](CO)CC1>CCN(C(C)C)C(C)C.CS(C)=O.ClCCl.O=S(=O)=O.c1ccncc1>CC(C)(C)OC(=O)N[C@H]1CC[C@H](C=O)CC1', 'CC(C)(C)OC(=O)N[C@H]1CC[C@H](CO)CC1>CC(=O)OI1(OC(C)=O)(OC(C)=O)OC(=O)c2ccccc21.ClCCl>CC(C)(C)OC(=O)N[C@H]1CC[C@H](C=O)CC1']","['CC(C)(C)OC(=O)N[C@H]1CC[C@H](C=O)CC1.CC(C)C[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Br-]>CC(C)(C)[O-].CN(C)C=O.[Cl-].[K+].[NH4+]>CC(C)/C=C\\[C@H]1CC[C@H](NC(=O)OC(C)(C)C)CC1', 'CC(C)(C)OC(=O)N[C@H]1CC[C@H](C=O)CC1.CC(C)C[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Br-]>CC(C)(C)[O-].CN(C)C=O.[Cl-].[K+].[NH4+]>CC(C)/C=C\\[C@H]1CC[C@H](NC(=O)OC(C)(C)C)CC1']","[['CC(C)(C)OC(=O)N[C@H]1CC[C@H](CO)CC1', 'CC(C)(C)OC(=O)N[C@H]1CC[C@H](C=O)CC1']]"
55,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(NCCC1(C(C)C)OCCO1)c1ccc(Br)cc1</SMILES> starting from <SMILES>COC(=O)CC1(C(C)C)OCCO1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COC(=O)CC1(C(C)C)OCCO1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(NCCC1(C(C)C)OCCO1)c1ccc(Br)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(NCCC1(C(C)C)OCCO1)c1ccc(Br)cc1</SMILES> starting from <SMILES>COC(=O)CC1(C(C)C)OCCO1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COC(=O)CC1(C(C)C)OCCO1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(NCCC1(C(C)C)OCCO1)c1ccc(Br)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(NCCC1(C(C)C)OCCO1)c1ccc(Br)cc1</SMILES> starting from <SMILES>COC(=O)CC1(C(C)C)OCCO1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COC(=O)CC1(C(C)C)OCCO1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(NCCC1(C(C)C)OCCO1)c1ccc(Br)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['COC(=O)CC1(C(C)C)OCCO1>C1CCOC1.[Al+3].[H-].[H-].[H-].[H-].[Li+]>CC(C)C1(CCO)OCCO1'],['CC(C)C1(CCO)OCCO1.CS(=O)(=O)Cl>CCN(CC)CC.ClCCl>CC(C)C1(CCOS(C)(=O)=O)OCCO1'],['CC(C)C1(CCOS(C)(=O)=O)OCCO1.CC(N)c1ccc(Br)cc1>>CC(NCCC1(C(C)C)OCCO1)c1ccc(Br)cc1'],"[['CC(C)C1(CCO)OCCO1', 'CC(C)C1(CCOS(C)(=O)=O)OCCO1']]"
56,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1[nH]c(=O)cc(-c2ccc(Cl)cc2)c1Br</SMILES> starting from <SMILES>O=Cc1ccc(Cl)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=Cc1ccc(Cl)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1[nH]c(=O)cc(-c2ccc(Cl)cc2)c1Br</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1[nH]c(=O)cc(-c2ccc(Cl)cc2)c1Br</SMILES> starting from <SMILES>O=Cc1ccc(Cl)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=Cc1ccc(Cl)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1[nH]c(=O)cc(-c2ccc(Cl)cc2)c1Br</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1[nH]c(=O)cc(-c2ccc(Cl)cc2)c1Br</SMILES> starting from <SMILES>O=Cc1ccc(Cl)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=Cc1ccc(Cl)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1[nH]c(=O)cc(-c2ccc(Cl)cc2)c1Br</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CC(C)=O.O=Cc1ccc(Cl)cc1>CCOC(C)=O.O.[Na+].[OH-]>CC(=O)/C=C/c1ccc(Cl)cc1'],['CC(=O)/C=C/c1ccc(Cl)cc1.CC(=O)[O-].CCOC(=O)C[n+]1ccccc1.[Cl-].[NH4+]>CCO>Cc1cc(-c2ccc(Cl)cc2)cc(=O)[nH]1'],['Cc1cc(-c2ccc(Cl)cc2)cc(=O)[nH]1.O=C1CCC(=O)N1Br>CN(C)C=O>Cc1[nH]c(=O)cc(-c2ccc(Cl)cc2)c1Br'],"[['CC(=O)/C=C/c1ccc(Cl)cc1', 'Cc1cc(-c2ccc(Cl)cc2)cc(=O)[nH]1']]"
57,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(=O)N1c2cc([N+](=O)[O-])c(-c3cnn(C4CC4)c3)cc2N(C(=O)OC(C)C)C[C@@H]1C</SMILES> starting from <SMILES>CC(C)OB([O-])[O-]</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)OB([O-])[O-]</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(=O)N1c2cc([N+](=O)[O-])c(-c3cnn(C4CC4)c3)cc2N(C(=O)OC(C)C)C[C@@H]1C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(=O)N1c2cc([N+](=O)[O-])c(-c3cnn(C4CC4)c3)cc2N(C(=O)OC(C)C)C[C@@H]1C</SMILES> starting from <SMILES>CC(C)OB([O-])[O-]</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)OB([O-])[O-]</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(=O)N1c2cc([N+](=O)[O-])c(-c3cnn(C4CC4)c3)cc2N(C(=O)OC(C)C)C[C@@H]1C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(=O)N1c2cc([N+](=O)[O-])c(-c3cnn(C4CC4)c3)cc2N(C(=O)OC(C)C)C[C@@H]1C</SMILES> starting from <SMILES>CC(C)OB([O-])[O-]</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)OB([O-])[O-]</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(=O)N1c2cc([N+](=O)[O-])c(-c3cnn(C4CC4)c3)cc2N(C(=O)OC(C)C)C[C@@H]1C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CC(C)(O)C(C)(C)O.CC(C)OB([O-])[O-]>>CC(C)OB1OC(C)(C)C(C)(C)O1'],['CC(C)OB1OC(C)(C)C(C)(C)O1.Ic1cnn(C2CC2)c1>C1CCOC1.CC(C)[Mg]Cl>CC1(C)OB(c2cnn(C3CC3)c2)OC1(C)C'],['CC(=O)N1c2cc([N+](=O)[O-])c(Br)cc2N(C(=O)OC(C)C)C[C@@H]1C.CC1(C)OB(c2cnn(C3CC3)c2)OC1(C)C>C1COCCO1.CC(C)c1cc(C(C)C)c(-c2ccccc2P(C2CCCCC2)C2CCCCC2)c(C(C)C)c1.O.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C([O-])[O-].[Cs+].[Cs+].[Pd].[Pd]>CC(=O)N1c2cc([N+](=O)[O-])c(-c3cnn(C4CC4)c3)cc2N(C(=O)OC(C)C)C[C@@H]1C'],"[['CC(C)OB1OC(C)(C)C(C)(C)O1', 'CC1(C)OB(c2cnn(C3CC3)c2)OC1(C)C']]"
58,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CSc1ncc2c(N)c(C)c(=O)n(C3CCCC3)c2n1</SMILES> starting from <SMILES>CSc1ncc(C#N)c(=O)[nH]1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CSc1ncc(C#N)c(=O)[nH]1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CSc1ncc2c(N)c(C)c(=O)n(C3CCCC3)c2n1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CSc1ncc2c(N)c(C)c(=O)n(C3CCCC3)c2n1</SMILES> starting from <SMILES>CSc1ncc(C#N)c(=O)[nH]1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CSc1ncc(C#N)c(=O)[nH]1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CSc1ncc2c(N)c(C)c(=O)n(C3CCCC3)c2n1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CSc1ncc2c(N)c(C)c(=O)n(C3CCCC3)c2n1</SMILES> starting from <SMILES>CSc1ncc(C#N)c(=O)[nH]1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CSc1ncc(C#N)c(=O)[nH]1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CSc1ncc2c(N)c(C)c(=O)n(C3CCCC3)c2n1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CSc1ncc(C#N)c(=O)[nH]1.O=P(Cl)(Cl)Cl>>CSc1ncc(C#N)c(Cl)n1'],['CSc1ncc(C#N)c(Cl)n1.NC1CCCC1>C1CCOC1.CCN(CC)CC>CSc1ncc(C#N)c(NC2CCCC2)n1'],['CCC(=O)OC(=O)CC.CSc1ncc(C#N)c(NC2CCCC2)n1>CN(C)C=O.[H-].[Na+]>CSc1ncc2c(N)c(C)c(=O)n(C3CCCC3)c2n1'],"[['CSc1ncc(C#N)c(Cl)n1', 'CSc1ncc(C#N)c(NC2CCCC2)n1']]"
59,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(=O)NC[C@H]1CN(c2ccc(N3CCC(C)(F)CC3)c(F)c2)C(=O)O1</SMILES> starting from <SMILES>C/C(=N\[Si](C)(C)C)O[Si](C)(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C/C(=N\[Si](C)(C)C)O[Si](C)(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(=O)NC[C@H]1CN(c2ccc(N3CCC(C)(F)CC3)c(F)c2)C(=O)O1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(=O)NC[C@H]1CN(c2ccc(N3CCC(C)(F)CC3)c(F)c2)C(=O)O1</SMILES> starting from <SMILES>C/C(=N\[Si](C)(C)C)O[Si](C)(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C/C(=N\[Si](C)(C)C)O[Si](C)(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(=O)NC[C@H]1CN(c2ccc(N3CCC(C)(F)CC3)c(F)c2)C(=O)O1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(=O)NC[C@H]1CN(c2ccc(N3CCC(C)(F)CC3)c(F)c2)C(=O)O1</SMILES> starting from <SMILES>C/C(=N\[Si](C)(C)C)O[Si](C)(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C/C(=N\[Si](C)(C)C)O[Si](C)(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(=O)NC[C@H]1CN(c2ccc(N3CCC(C)(F)CC3)c(F)c2)C(=O)O1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['C/C(=N\\[Si](C)(C)C)O[Si](C)(C)C.CCNCC>>CCN(CC)[Si](C)(C)C'],['CCN(CC)[Si](C)(C)C.FS(F)(F)F>FC(Cl)(Cl)Cl>CCN(CC)S(F)(F)F'],['CC(=O)NC[C@H]1CN(c2ccc(N3CCC(C)(O)CC3)c(F)c2)C(=O)O1.CCN(CC)S(F)(F)F>ClCCl>CC(=O)NC[C@H]1CN(c2ccc(N3CCC(C)(F)CC3)c(F)c2)C(=O)O1'],"[['CCN(CC)[Si](C)(C)C', 'CCN(CC)S(F)(F)F']]"
60,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1cc(OC)c(Cl)c(NC(C)=O)c1F</SMILES> starting from <SMILES>FF</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>FF</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1cc(OC)c(Cl)c(NC(C)=O)c1F</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1cc(OC)c(Cl)c(NC(C)=O)c1F</SMILES> starting from <SMILES>FF</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>FF</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1cc(OC)c(Cl)c(NC(C)=O)c1F</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1cc(OC)c(Cl)c(NC(C)=O)c1F</SMILES> starting from <SMILES>FF</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>FF</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1cc(OC)c(Cl)c(NC(C)=O)c1F</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['ClC[N+]12CCN(CC1)CC2.FF.F[B-](F)(F)F.F[B-](F)(F)F.[Na+]>CC#N>F[B-](F)(F)F.F[B-](F)(F)F.F[N+]12CC[N+](CCl)(CC1)CC2'],['COc1cc(NC(C)=O)cc(OC)c1.F[B-](F)(F)F.F[B-](F)(F)F.F[N+]12CC[N+](CCl)(CC1)CC2>CC#N>COc1cc(NC(C)=O)c(F)c(OC)c1'],['COc1cc(NC(C)=O)c(F)c(OC)c1.O=S(=O)(Cl)Cl>CC#N>COc1cc(OC)c(Cl)c(NC(C)=O)c1F'],"[['F[B-](F)(F)F.F[B-](F)(F)F.F[N+]12CC[N+](CCl)(CC1)CC2', 'COc1cc(NC(C)=O)c(F)c(OC)c1']]"
61,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC1(Nc2c([N+](=O)[O-])cnc3c2ccn3S(=O)(=O)c2ccccc2)CCN(C(=O)OC(C)(C)C)CC1</SMILES> starting from <SMILES>O=P(Cl)(c1ccccc1)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=P(Cl)(c1ccccc1)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC1(Nc2c([N+](=O)[O-])cnc3c2ccn3S(=O)(=O)c2ccccc2)CCN(C(=O)OC(C)(C)C)CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC1(Nc2c([N+](=O)[O-])cnc3c2ccn3S(=O)(=O)c2ccccc2)CCN(C(=O)OC(C)(C)C)CC1</SMILES> starting from <SMILES>O=P(Cl)(c1ccccc1)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=P(Cl)(c1ccccc1)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC1(Nc2c([N+](=O)[O-])cnc3c2ccn3S(=O)(=O)c2ccccc2)CCN(C(=O)OC(C)(C)C)CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC1(Nc2c([N+](=O)[O-])cnc3c2ccn3S(=O)(=O)c2ccccc2)CCN(C(=O)OC(C)(C)C)CC1</SMILES> starting from <SMILES>O=P(Cl)(c1ccccc1)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=P(Cl)(c1ccccc1)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC1(Nc2c([N+](=O)[O-])cnc3c2ccn3S(=O)(=O)c2ccccc2)CCN(C(=O)OC(C)(C)C)CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['C[Si](C)(C)N=[N+]=[N-].O=P(Cl)(c1ccccc1)c1ccccc1>>[N-]=[N+]=NP(=O)(c1ccccc1)c1ccccc1', 'O=P(Cl)(c1ccccc1)c1ccccc1.[N-]=[N+]=[N-].[Na+]>CC(C)=O>[N-]=[N+]=NP(=O)(c1ccccc1)c1ccccc1']","['CC(C)(C)OC(=O)N1CCC(C)(C(=O)O)CC1.[N-]=[N+]=NP(=O)(c1ccccc1)c1ccccc1>CCN(CC)CC.Cc1ccccc1>CC1(N)CCN(C(=O)OC(C)(C)C)CC1', 'CC(C)(C)OC(=O)N1CCC(C)(C(=O)O)CC1.[N-]=[N+]=NP(=O)(c1ccccc1)c1ccccc1>CCN(CC)CC.Cc1ccccc1>CC1(N)CCN(C(=O)OC(C)(C)C)CC1']","['CC1(N)CCN(C(=O)OC(C)(C)C)CC1.O=[N+]([O-])c1cnc2c(ccn2S(=O)(=O)c2ccccc2)c1Cl>CC(C)O.CCN(C(C)C)C(C)C>CC1(Nc2c([N+](=O)[O-])cnc3c2ccn3S(=O)(=O)c2ccccc2)CCN(C(=O)OC(C)(C)C)CC1', 'CC1(N)CCN(C(=O)OC(C)(C)C)CC1.O=[N+]([O-])c1cnc2c(ccn2S(=O)(=O)c2ccccc2)c1Cl>CC(C)O.CCN(C(C)C)C(C)C>CC1(Nc2c([N+](=O)[O-])cnc3c2ccn3S(=O)(=O)c2ccccc2)CCN(C(=O)OC(C)(C)C)CC1']","[['[N-]=[N+]=NP(=O)(c1ccccc1)c1ccccc1', 'CC1(N)CCN(C(=O)OC(C)(C)C)CC1']]"
62,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1c(CO)nc(-c2ccc(C(F)(F)F)cc2)n1C</SMILES> starting from <SMILES>COC(=O)OC</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COC(=O)OC</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1c(CO)nc(-c2ccc(C(F)(F)F)cc2)n1C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1c(CO)nc(-c2ccc(C(F)(F)F)cc2)n1C</SMILES> starting from <SMILES>COC(=O)OC</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COC(=O)OC</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1c(CO)nc(-c2ccc(C(F)(F)F)cc2)n1C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1c(CO)nc(-c2ccc(C(F)(F)F)cc2)n1C</SMILES> starting from <SMILES>COC(=O)OC</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COC(=O)OC</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1c(CO)nc(-c2ccc(C(F)(F)F)cc2)n1C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['COC(=O)OC.O=S(=O)(OS(=O)(=O)C(F)(F)F)C(F)(F)F>>COS(=O)(=O)C(F)(F)F'],['C#CCN.COS(=O)(=O)C(F)(F)F.N#Cc1ccc(C(F)(F)F)cc1>CC#N.ClCCl.[Na+].[OH-]>Cc1cnc(-c2ccc(C(F)(F)F)cc2)n1C'],['C=O.Cc1cnc(-c2ccc(C(F)(F)F)cc2)n1C>CC(=O)O.CC(=O)[O-].[Na+].[Na+].[OH-]>Cc1c(CO)nc(-c2ccc(C(F)(F)F)cc2)n1C'],"[['COS(=O)(=O)C(F)(F)F', 'Cc1cnc(-c2ccc(C(F)(F)F)cc2)n1C']]"
63,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C1CN(c2ccc(CCc3ccn[nH]3)cc2O)S(=O)(=O)N1</SMILES> starting from <SMILES>C[Si](C)(C)CCN1C(=O)CN(c2ccc(I)cc2OCc2ccccc2)S1(=O)=O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C[Si](C)(C)CCN1C(=O)CN(c2ccc(I)cc2OCc2ccccc2)S1(=O)=O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C1CN(c2ccc(CCc3ccn[nH]3)cc2O)S(=O)(=O)N1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C1CN(c2ccc(CCc3ccn[nH]3)cc2O)S(=O)(=O)N1</SMILES> starting from <SMILES>C[Si](C)(C)CCN1C(=O)CN(c2ccc(I)cc2OCc2ccccc2)S1(=O)=O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C[Si](C)(C)CCN1C(=O)CN(c2ccc(I)cc2OCc2ccccc2)S1(=O)=O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C1CN(c2ccc(CCc3ccn[nH]3)cc2O)S(=O)(=O)N1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C1CN(c2ccc(CCc3ccn[nH]3)cc2O)S(=O)(=O)N1</SMILES> starting from <SMILES>C[Si](C)(C)CCN1C(=O)CN(c2ccc(I)cc2OCc2ccccc2)S1(=O)=O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C[Si](C)(C)CCN1C(=O)CN(c2ccc(I)cc2OCc2ccccc2)S1(=O)=O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C1CN(c2ccc(CCc3ccn[nH]3)cc2O)S(=O)(=O)N1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['C=Cc1ccnn1COCc1ccccc1.C[Si](C)(C)CCN1C(=O)CN(c2ccc(I)cc2OCc2ccccc2)S1(=O)=O>CC#N.CC(=O)[O-].CC(=O)[O-].CCN(CC)CC.Cc1ccccc1P(c1ccccc1C)c1ccccc1C.[Pd+2]>C[Si](C)(C)CCN1C(=O)CN(c2ccc(/C=C/c3ccnn3COCc3ccccc3)cc2OCc2ccccc2)S1(=O)=O'],['C[Si](C)(C)CCN1C(=O)CN(c2ccc(/C=C/c3ccnn3COCc3ccccc3)cc2OCc2ccccc2)S1(=O)=O>CN(C)C=O.[Cs+].[F-]>O=C1CN(c2ccc(/C=C/c3ccnn3COCc3ccccc3)cc2OCc2ccccc2)S(=O)(=O)N1'],['O=C1CN(c2ccc(/C=C/c3ccnn3COCc3ccccc3)cc2OCc2ccccc2)S(=O)(=O)N1>CO.[Pd]>O=C1CN(c2ccc(CCc3ccn[nH]3)cc2O)S(=O)(=O)N1'],"[['C[Si](C)(C)CCN1C(=O)CN(c2ccc(/C=C/c3ccnn3COCc3ccccc3)cc2OCc2ccccc2)S1(=O)=O', 'O=C1CN(c2ccc(/C=C/c3ccnn3COCc3ccccc3)cc2OCc2ccccc2)S(=O)(=O)N1']]"
64,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>C=CCC1(C(C#N)CC(=O)OCC)CCC2(CC1)OCC(C)(C)CO2</SMILES> starting from <SMILES>CC(C)(CO)CO</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(CO)CO</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>C=CCC1(C(C#N)CC(=O)OCC)CCC2(CC1)OCC(C)(C)CO2</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>C=CCC1(C(C#N)CC(=O)OCC)CCC2(CC1)OCC(C)(C)CO2</SMILES> starting from <SMILES>CC(C)(CO)CO</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(CO)CO</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>C=CCC1(C(C#N)CC(=O)OCC)CCC2(CC1)OCC(C)(C)CO2</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>C=CCC1(C(C#N)CC(=O)OCC)CCC2(CC1)OCC(C)(C)CO2</SMILES> starting from <SMILES>CC(C)(CO)CO</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(CO)CO</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>C=CCC1(C(C#N)CC(=O)OCC)CCC2(CC1)OCC(C)(C)CO2</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['CC(C)(CO)CO.O=C1CCC(=O)CC1>CCCCCC.O.O=S(=O)(O)O>CC1(C)COC2(CCC(=O)CC2)OC1', 'CC(C)(CO)CO.O=C1CCC(=O)CC1>ClCCl.O=S(=O)(O)O>CC1(C)COC2(CCC(=O)CC2)OC1', 'CC(C)(CO)CO.O=C1CCC(=O)CC1>ClC(Cl)Cl.O=S(=O)(O)O>CC1(C)COC2(CCC(=O)CC2)OC1']","['CC1(C)COC2(CCC(=O)CC2)OC1.CCOC(=O)CC#N>C1CCNCC1.CC(=O)O.CCO>CCOC(=O)C(C#N)=C1CCC2(CC1)OCC(C)(C)CO2', 'CC1(C)COC2(CCC(=O)CC2)OC1.CCOC(=O)CC#N>C1CCNCC1.CC(=O)O.CCO>CCOC(=O)C(C#N)=C1CCC2(CC1)OCC(C)(C)CO2', 'CC1(C)COC2(CCC(=O)CC2)OC1.CCOC(=O)CC#N>C1CCNCC1.CC(=O)O.CCO>CCOC(=O)C(C#N)=C1CCC2(CC1)OCC(C)(C)CO2']","['C=CC[Mg]Cl.CCOC(=O)C(C#N)=C1CCC2(CC1)OCC(C)(C)CO2>C1CCOC1.[Cl-].[Cu]I.[NH4+]>C=CCC1(C(C#N)CC(=O)OCC)CCC2(CC1)OCC(C)(C)CO2', 'C=CC[Mg]Cl.CCOC(=O)C(C#N)=C1CCC2(CC1)OCC(C)(C)CO2>C1CCOC1.[Cl-].[Cu]I.[NH4+]>C=CCC1(C(C#N)CC(=O)OCC)CCC2(CC1)OCC(C)(C)CO2', 'C=CC[Mg]Cl.CCOC(=O)C(C#N)=C1CCC2(CC1)OCC(C)(C)CO2>C1CCOC1.[Cl-].[Cu]I.[NH4+]>C=CCC1(C(C#N)CC(=O)OCC)CCC2(CC1)OCC(C)(C)CO2']","[['CC1(C)COC2(CCC(=O)CC2)OC1', 'CCOC(=O)C(C#N)=C1CCC2(CC1)OCC(C)(C)CO2']]"
65,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)OC(=O)N1CCC[C@@H]1c1nc2ccccc2o1</SMILES> starting from <SMILES>CC(C)(C)OC(=O)N1CCC[C@]1(C)C(=O)[O-]</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)OC(=O)N1CCC[C@]1(C)C(=O)[O-]</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)OC(=O)N1CCC[C@@H]1c1nc2ccccc2o1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)OC(=O)N1CCC[C@@H]1c1nc2ccccc2o1</SMILES> starting from <SMILES>CC(C)(C)OC(=O)N1CCC[C@]1(C)C(=O)[O-]</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)OC(=O)N1CCC[C@]1(C)C(=O)[O-]</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)OC(=O)N1CCC[C@@H]1c1nc2ccccc2o1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)OC(=O)N1CCC[C@@H]1c1nc2ccccc2o1</SMILES> starting from <SMILES>CC(C)(C)OC(=O)N1CCC[C@]1(C)C(=O)[O-]</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)OC(=O)N1CCC[C@]1(C)C(=O)[O-]</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)OC(=O)N1CCC[C@@H]1c1nc2ccccc2o1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CC(C)(C)OC(=O)N1CCC[C@]1(C)C(=O)[O-]>C1CCOC1.CO.[Na+].[OH-]>CC(C)(C)OC(=O)N1CCC[C@@H]1C(=O)O'],['CC(C)(C)OC(=O)N1CCC[C@@H]1C(=O)O.Nc1ccccc1Br>CC(C)COC(=O)Cl.CN1CCOCC1.ClCCl>CC(C)(C)OC(=O)N1CCC[C@@H]1C(=O)Nc1ccccc1Br'],['CC(C)(C)OC(=O)N1CCC[C@@H]1C(=O)Nc1ccccc1Br>COCCOC.O=C([O-])[O-].[Cs+].[Cs+].[Cu]I.c1cnc2c(c1)ccc1cccnc12>CC(C)(C)OC(=O)N1CCC[C@@H]1c1nc2ccccc2o1'],"[['CC(C)(C)OC(=O)N1CCC[C@@H]1C(=O)O', 'CC(C)(C)OC(=O)N1CCC[C@@H]1C(=O)Nc1ccccc1Br']]"
66,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1c(CNC(=O)C(C)(C)C)ccc(Cl)c1C(=O)O</SMILES> starting from <SMILES>CCOC(=O)c1c(Cl)ccc(C=NO)c1F</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)c1c(Cl)ccc(C=NO)c1F</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1c(CNC(=O)C(C)(C)C)ccc(Cl)c1C(=O)O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1c(CNC(=O)C(C)(C)C)ccc(Cl)c1C(=O)O</SMILES> starting from <SMILES>CCOC(=O)c1c(Cl)ccc(C=NO)c1F</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)c1c(Cl)ccc(C=NO)c1F</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1c(CNC(=O)C(C)(C)C)ccc(Cl)c1C(=O)O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1c(CNC(=O)C(C)(C)C)ccc(Cl)c1C(=O)O</SMILES> starting from <SMILES>CCOC(=O)c1c(Cl)ccc(C=NO)c1F</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)c1c(Cl)ccc(C=NO)c1F</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1c(CNC(=O)C(C)(C)C)ccc(Cl)c1C(=O)O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CCOC(=O)c1c(Cl)ccc(C=NO)c1F>CCO.CO.Cl.[Zn]>CCOC(=O)c1c(Cl)ccc(CN)c1F'],['CC(C)(C)C(=O)Cl.CCOC(=O)c1c(Cl)ccc(CN)c1F>C1CCOC1.CCN(CC)CC.CCOC(C)=O>CCOC(=O)c1c(Cl)ccc(CNC(=O)C(C)(C)C)c1F'],['CCOC(=O)c1c(Cl)ccc(CNC(=O)C(C)(C)C)c1F.[K+].[OH-]>C1CCOC1.CO.O.O=C(O)CC(O)(CC(=O)O)C(=O)O>COc1c(CNC(=O)C(C)(C)C)ccc(Cl)c1C(=O)O'],"[['CCOC(=O)c1c(Cl)ccc(CN)c1F', 'CCOC(=O)c1c(Cl)ccc(CNC(=O)C(C)(C)C)c1F']]"
67,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=NC(=O)c1ccc(OC(F)(F)F)cc1)N1Cc2ccccc2-c2ccccc2C1</SMILES> starting from <SMILES>c1ccc2c(c1)CNCc1ccccc1-2</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>c1ccc2c(c1)CNCc1ccccc1-2</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=NC(=O)c1ccc(OC(F)(F)F)cc1)N1Cc2ccccc2-c2ccccc2C1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=NC(=O)c1ccc(OC(F)(F)F)cc1)N1Cc2ccccc2-c2ccccc2C1</SMILES> starting from <SMILES>c1ccc2c(c1)CNCc1ccccc1-2</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>c1ccc2c(c1)CNCc1ccccc1-2</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=NC(=O)c1ccc(OC(F)(F)F)cc1)N1Cc2ccccc2-c2ccccc2C1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=NC(=O)c1ccc(OC(F)(F)F)cc1)N1Cc2ccccc2-c2ccccc2C1</SMILES> starting from <SMILES>c1ccc2c(c1)CNCc1ccccc1-2</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>c1ccc2c(c1)CNCc1ccccc1-2</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=NC(=O)c1ccc(OC(F)(F)F)cc1)N1Cc2ccccc2-c2ccccc2C1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['N#CBr.c1ccc2c(c1)CNCc1ccccc1-2>ClC(Cl)Cl>N#CN1Cc2ccccc2-c2ccccc2C1'],['CC[O-].N#CN1Cc2ccccc2-c2ccccc2C1.[Na+]>CCO>CCOC(=N)N1Cc2ccccc2-c2ccccc2C1'],['CCOC(=N)N1Cc2ccccc2-c2ccccc2C1.O=C(Cl)c1ccc(OC(F)(F)F)cc1>>CCOC(=NC(=O)c1ccc(OC(F)(F)F)cc1)N1Cc2ccccc2-c2ccccc2C1'],"[['N#CN1Cc2ccccc2-c2ccccc2C1', 'CCOC(=N)N1Cc2ccccc2-c2ccccc2C1']]"
68,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)[C@H](NC(=O)OCc1ccccc1)C(=O)OCC(OC(=O)[C@@H](NC(=O)OCc1ccccc1)C(C)C)C(=O)OC[C@H]1O[C@@H](n2cnc3c(=O)[nH]c(N)nc32)C[C@@H]1F</SMILES> starting from <SMILES>CC(C)(C)OC(=O)C(O)CO</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)OC(=O)C(O)CO</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)[C@H](NC(=O)OCc1ccccc1)C(=O)OCC(OC(=O)[C@@H](NC(=O)OCc1ccccc1)C(C)C)C(=O)OC[C@H]1O[C@@H](n2cnc3c(=O)[nH]c(N)nc32)C[C@@H]1F</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)[C@H](NC(=O)OCc1ccccc1)C(=O)OCC(OC(=O)[C@@H](NC(=O)OCc1ccccc1)C(C)C)C(=O)OC[C@H]1O[C@@H](n2cnc3c(=O)[nH]c(N)nc32)C[C@@H]1F</SMILES> starting from <SMILES>CC(C)(C)OC(=O)C(O)CO</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)OC(=O)C(O)CO</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)[C@H](NC(=O)OCc1ccccc1)C(=O)OCC(OC(=O)[C@@H](NC(=O)OCc1ccccc1)C(C)C)C(=O)OC[C@H]1O[C@@H](n2cnc3c(=O)[nH]c(N)nc32)C[C@@H]1F</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)[C@H](NC(=O)OCc1ccccc1)C(=O)OCC(OC(=O)[C@@H](NC(=O)OCc1ccccc1)C(C)C)C(=O)OC[C@H]1O[C@@H](n2cnc3c(=O)[nH]c(N)nc32)C[C@@H]1F</SMILES> starting from <SMILES>CC(C)(C)OC(=O)C(O)CO</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)OC(=O)C(O)CO</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)[C@H](NC(=O)OCc1ccccc1)C(=O)OCC(OC(=O)[C@@H](NC(=O)OCc1ccccc1)C(C)C)C(=O)OC[C@H]1O[C@@H](n2cnc3c(=O)[nH]c(N)nc32)C[C@@H]1F</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['C(=NC1CCCCC1)=NC1CCCCC1.CC(C)(C)OC(=O)C(O)CO.CC(C)[C@H](NC(=O)OCc1ccccc1)C(=O)O>CN(C)c1ccncc1.ClCCl>CC(C)[C@H](NC(=O)OCc1ccccc1)C(=O)OCC(OC(=O)[C@@H](NC(=O)OCc1ccccc1)C(C)C)C(=O)OC(C)(C)C'],['CC(C)[C@H](NC(=O)OCc1ccccc1)C(=O)OCC(OC(=O)[C@@H](NC(=O)OCc1ccccc1)C(C)C)C(=O)OC(C)(C)C>ClCCl.O=C(O)C(F)(F)F>CC(C)[C@H](NC(=O)OCc1ccccc1)C(=O)OCC(OC(=O)[C@@H](NC(=O)OCc1ccccc1)C(C)C)C(=O)O'],['CC(C)[C@H](NC(=O)OCc1ccccc1)C(=O)OCC(OC(=O)[C@@H](NC(=O)OCc1ccccc1)C(C)C)C(=O)O.Nc1nc2c(ncn2[C@H]2C[C@H](F)[C@@H](CO)O2)c(=O)[nH]1>C(=NC1CCCCC1)=NC1CCCCC1.CN(C)C=O.CN(C)c1ccncc1.On1nnc2ccccc21>CC(C)[C@H](NC(=O)OCc1ccccc1)C(=O)OCC(OC(=O)[C@@H](NC(=O)OCc1ccccc1)C(C)C)C(=O)OC[C@H]1O[C@@H](n2cnc3c(=O)[nH]c(N)nc32)C[C@@H]1F'],"[['CC(C)[C@H](NC(=O)OCc1ccccc1)C(=O)OCC(OC(=O)[C@@H](NC(=O)OCc1ccccc1)C(C)C)C(=O)OC(C)(C)C', 'CC(C)[C@H](NC(=O)OCc1ccccc1)C(=O)OCC(OC(=O)[C@@H](NC(=O)OCc1ccccc1)C(C)C)C(=O)O']]"
69,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>C[C@H]1CCCCN1c1nnc2ccc(O[C@@H]3CC[C@H](NC(=O)Nc4cc(C(C)(C)C)nn4-c4cccc(CO)c4)c4ccccc43)cn12</SMILES> starting from <SMILES>CCOC(=O)c1cccc(-n2nc(C(C)(C)C)cc2N)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)c1cccc(-n2nc(C(C)(C)C)cc2N)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>C[C@H]1CCCCN1c1nnc2ccc(O[C@@H]3CC[C@H](NC(=O)Nc4cc(C(C)(C)C)nn4-c4cccc(CO)c4)c4ccccc43)cn12</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>C[C@H]1CCCCN1c1nnc2ccc(O[C@@H]3CC[C@H](NC(=O)Nc4cc(C(C)(C)C)nn4-c4cccc(CO)c4)c4ccccc43)cn12</SMILES> starting from <SMILES>CCOC(=O)c1cccc(-n2nc(C(C)(C)C)cc2N)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)c1cccc(-n2nc(C(C)(C)C)cc2N)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>C[C@H]1CCCCN1c1nnc2ccc(O[C@@H]3CC[C@H](NC(=O)Nc4cc(C(C)(C)C)nn4-c4cccc(CO)c4)c4ccccc43)cn12</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>C[C@H]1CCCCN1c1nnc2ccc(O[C@@H]3CC[C@H](NC(=O)Nc4cc(C(C)(C)C)nn4-c4cccc(CO)c4)c4ccccc43)cn12</SMILES> starting from <SMILES>CCOC(=O)c1cccc(-n2nc(C(C)(C)C)cc2N)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)c1cccc(-n2nc(C(C)(C)C)cc2N)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>C[C@H]1CCCCN1c1nnc2ccc(O[C@@H]3CC[C@H](NC(=O)Nc4cc(C(C)(C)C)nn4-c4cccc(CO)c4)c4ccccc43)cn12</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CCOC(=O)c1cccc(-n2nc(C(C)(C)C)cc2N)c1>CCN(CC)CC.CCO.O.[BH4-].[Na+]>CC(C)(C)c1cc(N)n(-c2cccc(CO)c2)n1'],['CC(C)(C)c1cc(N)n(-c2cccc(CO)c2)n1.O=C(Cl)OCC(Cl)(Cl)Cl>CCOC(C)=O.[Na+].[OH-]>CC(C)(C)c1cc(NC(=O)OCC(Cl)(Cl)Cl)n(-c2cccc(CO)c2)n1'],['CC(C)(C)c1cc(NC(=O)OCC(Cl)(Cl)Cl)n(-c2cccc(CO)c2)n1.C[C@H]1CCCCN1c1nnc2ccc(O[C@@H]3CC[C@H](N)c4ccccc43)cn12>C1COCCO1.CCN(C(C)C)C(C)C.CO.ClCCl>C[C@H]1CCCCN1c1nnc2ccc(O[C@@H]3CC[C@H](NC(=O)Nc4cc(C(C)(C)C)nn4-c4cccc(CO)c4)c4ccccc43)cn12'],"[['CC(C)(C)c1cc(N)n(-c2cccc(CO)c2)n1', 'CC(C)(C)c1cc(NC(=O)OCC(Cl)(Cl)Cl)n(-c2cccc(CO)c2)n1']]"
70,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)c1cc2c(Oc3cc(C)ccc3N)cccc2[nH]1</SMILES> starting from <SMILES>CCOC(=O)c1cc2c(OCc3ccccc3)cccc2[nH]1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)c1cc2c(OCc3ccccc3)cccc2[nH]1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)c1cc2c(Oc3cc(C)ccc3N)cccc2[nH]1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)c1cc2c(Oc3cc(C)ccc3N)cccc2[nH]1</SMILES> starting from <SMILES>CCOC(=O)c1cc2c(OCc3ccccc3)cccc2[nH]1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)c1cc2c(OCc3ccccc3)cccc2[nH]1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)c1cc2c(Oc3cc(C)ccc3N)cccc2[nH]1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)c1cc2c(Oc3cc(C)ccc3N)cccc2[nH]1</SMILES> starting from <SMILES>CCOC(=O)c1cc2c(OCc3ccccc3)cccc2[nH]1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)c1cc2c(OCc3ccccc3)cccc2[nH]1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)c1cc2c(Oc3cc(C)ccc3N)cccc2[nH]1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CCOC(=O)c1cc2c(OCc3ccccc3)cccc2[nH]1>CO.ClCCl.[Pd]>CCOC(=O)c1cc2c(O)cccc2[nH]1'],['CCOC(=O)c1cc2c(O)cccc2[nH]1.Cc1ccc([N+](=O)[O-])c(F)c1>CN(C)C=O.O=C([O-])[O-].[K+].[K+]>CCOC(=O)c1cc2c(Oc3cc(C)ccc3[N+](=O)[O-])cccc2[nH]1'],['CCOC(=O)c1cc2c(Oc3cc(C)ccc3[N+](=O)[O-])cccc2[nH]1>CCOC(C)=O.[Pd]>CCOC(=O)c1cc2c(Oc3cc(C)ccc3N)cccc2[nH]1'],"[['CCOC(=O)c1cc2c(O)cccc2[nH]1', 'CCOC(=O)c1cc2c(Oc3cc(C)ccc3[N+](=O)[O-])cccc2[nH]1']]"
71,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>c1cc(N2CCC(N3CCCC3)CC2)ccc1CN1CCOCC1</SMILES> starting from <SMILES>O=Cc1ccc(N2CCC3(CC2)OCCO3)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=Cc1ccc(N2CCC3(CC2)OCCO3)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>c1cc(N2CCC(N3CCCC3)CC2)ccc1CN1CCOCC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>c1cc(N2CCC(N3CCCC3)CC2)ccc1CN1CCOCC1</SMILES> starting from <SMILES>O=Cc1ccc(N2CCC3(CC2)OCCO3)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=Cc1ccc(N2CCC3(CC2)OCCO3)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>c1cc(N2CCC(N3CCCC3)CC2)ccc1CN1CCOCC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>c1cc(N2CCC(N3CCCC3)CC2)ccc1CN1CCOCC1</SMILES> starting from <SMILES>O=Cc1ccc(N2CCC3(CC2)OCCO3)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=Cc1ccc(N2CCC3(CC2)OCCO3)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>c1cc(N2CCC(N3CCCC3)CC2)ccc1CN1CCOCC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['C1COCCN1.O=Cc1ccc(N2CCC3(CC2)OCCO3)cc1>>c1cc(N2CCC3(CC2)OCCO3)ccc1CN1CCOCC1'],['c1cc(N2CCC3(CC2)OCCO3)ccc1CN1CCOCC1>Cl.[Na+].[OH-]>O=C1CCN(c2ccc(CN3CCOCC3)cc2)CC1'],['C1CCNC1.O=C1CCN(c2ccc(CN3CCOCC3)cc2)CC1>>c1cc(N2CCC(N3CCCC3)CC2)ccc1CN1CCOCC1'],"[['c1cc(N2CCC3(CC2)OCCO3)ccc1CN1CCOCC1', 'O=C1CCN(c2ccc(CN3CCOCC3)cc2)CC1']]"
72,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C(NCC1CCOC1)c1noc(COCc2ccc3ccccc3c2)c1Br</SMILES> starting from <SMILES>CCOC(=O)c1cc(COCc2ccc3ccccc3c2)on1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)c1cc(COCc2ccc3ccccc3c2)on1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C(NCC1CCOC1)c1noc(COCc2ccc3ccccc3c2)c1Br</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C(NCC1CCOC1)c1noc(COCc2ccc3ccccc3c2)c1Br</SMILES> starting from <SMILES>CCOC(=O)c1cc(COCc2ccc3ccccc3c2)on1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)c1cc(COCc2ccc3ccccc3c2)on1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C(NCC1CCOC1)c1noc(COCc2ccc3ccccc3c2)c1Br</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C(NCC1CCOC1)c1noc(COCc2ccc3ccccc3c2)c1Br</SMILES> starting from <SMILES>CCOC(=O)c1cc(COCc2ccc3ccccc3c2)on1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)c1cc(COCc2ccc3ccccc3c2)on1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C(NCC1CCOC1)c1noc(COCc2ccc3ccccc3c2)c1Br</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CCOC(=O)c1cc(COCc2ccc3ccccc3c2)on1>CCO.O.[K+].[OH-]>O=C(O)c1cc(COCc2ccc3ccccc3c2)on1'],['Cl.NCC1CCOC1.O=C(O)c1cc(COCc2ccc3ccccc3c2)on1>CCN(CC)CC.CCN=C=NCCCN(C)C.Cl.ClC(Cl)Cl.On1nnc2ccccc21>O=C(NCC1CCOC1)c1cc(COCc2ccc3ccccc3c2)on1'],['ClC(Cl)(Cl)Br.O=C(NCC1CCOC1)c1cc(COCc2ccc3ccccc3c2)on1>C1CCOC1.CCCCCC.Cl.[Li]CCCC>O=C(NCC1CCOC1)c1noc(COCc2ccc3ccccc3c2)c1Br'],"[['O=C(O)c1cc(COCc2ccc3ccccc3c2)on1', 'O=C(NCC1CCOC1)c1cc(COCc2ccc3ccccc3c2)on1']]"
73,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1ccc(F)cc1-c1ccc2cc(NCC3CC3)ncc2c1</SMILES> starting from <SMILES>N#Cc1c(N)ncc2cc(Br)ccc12</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>N#Cc1c(N)ncc2cc(Br)ccc12</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1ccc(F)cc1-c1ccc2cc(NCC3CC3)ncc2c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1ccc(F)cc1-c1ccc2cc(NCC3CC3)ncc2c1</SMILES> starting from <SMILES>N#Cc1c(N)ncc2cc(Br)ccc12</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>N#Cc1c(N)ncc2cc(Br)ccc12</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1ccc(F)cc1-c1ccc2cc(NCC3CC3)ncc2c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1ccc(F)cc1-c1ccc2cc(NCC3CC3)ncc2c1</SMILES> starting from <SMILES>N#Cc1c(N)ncc2cc(Br)ccc12</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>N#Cc1c(N)ncc2cc(Br)ccc12</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1ccc(F)cc1-c1ccc2cc(NCC3CC3)ncc2c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['N#Cc1c(N)ncc2cc(Br)ccc12>O.O=S(=O)(O)O.[Na+].[OH-]>Nc1cc2ccc(Br)cc2cn1'],['Cc1ccc(F)cc1B(O)O.Nc1cc2ccc(Br)cc2cn1>CC#N.Cl[Pd]Cl.O.O=C([O-])[O-].[Cs+].[Cs+].[Fe+2].c1ccc(P(c2ccccc2)[c-]2cccc2)cc1.c1ccc(P(c2ccccc2)[c-]2cccc2)cc1>Cc1ccc(F)cc1-c1ccc2cc(N)ncc2c1'],['BrCC1CC1.Cc1ccc(F)cc1-c1ccc2cc(N)ncc2c1>CN(C)C=O.[H-].[Na+]>Cc1ccc(F)cc1-c1ccc2cc(NCC3CC3)ncc2c1'],"[['Nc1cc2ccc(Br)cc2cn1', 'Cc1ccc(F)cc1-c1ccc2cc(N)ncc2c1']]"
74,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)c1cccc2nc(C)n(-c3ccccc3)c12</SMILES> starting from <SMILES>O=CNc1ccccc1.Oc1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=CNc1ccccc1.Oc1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)c1cccc2nc(C)n(-c3ccccc3)c12</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)c1cccc2nc(C)n(-c3ccccc3)c12</SMILES> starting from <SMILES>O=CNc1ccccc1.Oc1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=CNc1ccccc1.Oc1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)c1cccc2nc(C)n(-c3ccccc3)c12</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)c1cccc2nc(C)n(-c3ccccc3)c12</SMILES> starting from <SMILES>O=CNc1ccccc1.Oc1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=CNc1ccccc1.Oc1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)c1cccc2nc(C)n(-c3ccccc3)c12</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['O=CNc1ccccc1.Oc1ccccc1>O=C(Oc1ccccc1)Oc1ccccc1.O=CNc1ccccc1.Oc1ccccc1>O=C=Nc1ccccc1'],['CC(=O)O.O=C=Nc1ccccc1>CCCC[Sn](Cl)(Cl)CCCC.ClCCl>CC(=O)Nc1ccccc1'],['CC(=O)Nc1ccccc1.COC(=O)c1cccc([N+](=O)[O-])c1Br>>COC(=O)c1cccc2nc(C)n(-c3ccccc3)c12'],"[['O=C=Nc1ccccc1', 'CC(=O)Nc1ccccc1']]"
75,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)OC(=O)N1CCCC1(COCc1ccccc1)C(=O)O</SMILES> starting from <SMILES>C[Si](C)(C)N[Si](C)(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C[Si](C)(C)N[Si](C)(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)OC(=O)N1CCCC1(COCc1ccccc1)C(=O)O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)OC(=O)N1CCCC1(COCc1ccccc1)C(=O)O</SMILES> starting from <SMILES>C[Si](C)(C)N[Si](C)(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C[Si](C)(C)N[Si](C)(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)OC(=O)N1CCCC1(COCc1ccccc1)C(=O)O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)OC(=O)N1CCCC1(COCc1ccccc1)C(=O)O</SMILES> starting from <SMILES>C[Si](C)(C)N[Si](C)(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C[Si](C)(C)N[Si](C)(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)OC(=O)N1CCCC1(COCc1ccccc1)C(=O)O</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['C[Si](C)(C)N[Si](C)(C)C.[Li]CCCC>C1CCOC1.CCCCCC>C[Si](C)(C)[N-][Si](C)(C)C.[Li+]'],['C1CCOC1.COC(=O)C1CCCN1C(=O)OC(C)(C)C.C[Si](C)(C)[N-][Si](C)(C)C.[Li+]>[Cl-]>COC(=O)C1(COCc2ccccc2)CCCN1C(=O)OC(C)(C)C'],['COC(=O)C1(COCc2ccccc2)CCCN1C(=O)OC(C)(C)C>CO.[Na+].[OH-]>CC(C)(C)OC(=O)N1CCCC1(COCc1ccccc1)C(=O)O'],"[['C[Si](C)(C)[N-][Si](C)(C)C.[Li+]', 'COC(=O)C1(COCc2ccccc2)CCCN1C(=O)OC(C)(C)C']]"
76,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)Cc1ccc([N+](=O)[O-])c(SCc2ccc(OC)cc2)c1</SMILES> starting from <SMILES>O=C(O)Cc1cccc(F)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)Cc1cccc(F)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)Cc1ccc([N+](=O)[O-])c(SCc2ccc(OC)cc2)c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)Cc1ccc([N+](=O)[O-])c(SCc2ccc(OC)cc2)c1</SMILES> starting from <SMILES>O=C(O)Cc1cccc(F)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)Cc1cccc(F)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)Cc1ccc([N+](=O)[O-])c(SCc2ccc(OC)cc2)c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)Cc1ccc([N+](=O)[O-])c(SCc2ccc(OC)cc2)c1</SMILES> starting from <SMILES>O=C(O)Cc1cccc(F)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)Cc1cccc(F)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)Cc1ccc([N+](=O)[O-])c(SCc2ccc(OC)cc2)c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CO.O=C(O)Cc1cccc(F)c1>Cl>COC(=O)Cc1cccc(F)c1'],['COC(=O)Cc1cccc(F)c1.O=[N+]([O-])O>O=S(=O)(O)O>COC(=O)Cc1ccc([N+](=O)[O-])c(F)c1'],['COC(=O)Cc1ccc([N+](=O)[O-])c(F)c1.COc1ccc(CS)cc1>CN1CCCC1=O.O.[H-].[Na+]>COC(=O)Cc1ccc([N+](=O)[O-])c(SCc2ccc(OC)cc2)c1'],"[['COC(=O)Cc1cccc(F)c1', 'COC(=O)Cc1ccc([N+](=O)[O-])c(F)c1']]"
77,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>C[C@H](Nc1ncnc(N)c1C#N)c1nn2ccc(Sc3ccccc3NCCN(C)C)c2c(=O)n1-c1ccccc1</SMILES> starting from <SMILES>ON=Cc1c(Cl)ncnc1Cl</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>ON=Cc1c(Cl)ncnc1Cl</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>C[C@H](Nc1ncnc(N)c1C#N)c1nn2ccc(Sc3ccccc3NCCN(C)C)c2c(=O)n1-c1ccccc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>C[C@H](Nc1ncnc(N)c1C#N)c1nn2ccc(Sc3ccccc3NCCN(C)C)c2c(=O)n1-c1ccccc1</SMILES> starting from <SMILES>ON=Cc1c(Cl)ncnc1Cl</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>ON=Cc1c(Cl)ncnc1Cl</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>C[C@H](Nc1ncnc(N)c1C#N)c1nn2ccc(Sc3ccccc3NCCN(C)C)c2c(=O)n1-c1ccccc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>C[C@H](Nc1ncnc(N)c1C#N)c1nn2ccc(Sc3ccccc3NCCN(C)C)c2c(=O)n1-c1ccccc1</SMILES> starting from <SMILES>ON=Cc1c(Cl)ncnc1Cl</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>ON=Cc1c(Cl)ncnc1Cl</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>C[C@H](Nc1ncnc(N)c1C#N)c1nn2ccc(Sc3ccccc3NCCN(C)C)c2c(=O)n1-c1ccccc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['ON=Cc1c(Cl)ncnc1Cl>ClC(Cl)Cl.O=S(Cl)Cl>N#Cc1c(Cl)ncnc1Cl', 'ON=Cc1c(Cl)ncnc1Cl>ClC(Cl)Cl.O=S(Cl)Cl>N#Cc1c(Cl)ncnc1Cl']","['N.N#Cc1c(Cl)ncnc1Cl>C1CCOC1>N#Cc1c(N)ncnc1Cl', 'N.N#Cc1c(Cl)ncnc1Cl>C1COCCO1>N#Cc1c(N)ncnc1Cl']","['C[C@H](N)c1nn2ccc(Sc3ccccc3NCCN(C)C)c2c(=O)n1-c1ccccc1.N#Cc1c(N)ncnc1Cl>CC(C)(C)O.CCN(C(C)C)C(C)C>C[C@H](Nc1ncnc(N)c1C#N)c1nn2ccc(Sc3ccccc3NCCN(C)C)c2c(=O)n1-c1ccccc1', 'C[C@H](N)c1nn2ccc(Sc3ccccc3NCCN(C)C)c2c(=O)n1-c1ccccc1.N#Cc1c(N)ncnc1Cl>CC(C)(C)O.CCN(C(C)C)C(C)C>C[C@H](Nc1ncnc(N)c1C#N)c1nn2ccc(Sc3ccccc3NCCN(C)C)c2c(=O)n1-c1ccccc1']","[['N#Cc1c(Cl)ncnc1Cl', 'N#Cc1c(N)ncnc1Cl']]"
78,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)c1cccnc1CN1CCC(c2c[nH]c3ccccc23)CC1</SMILES> starting from <SMILES>CCOC(=O)/C=C(/C)N</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)/C=C(/C)N</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)c1cccnc1CN1CCC(c2c[nH]c3ccccc23)CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)c1cccnc1CN1CCC(c2c[nH]c3ccccc23)CC1</SMILES> starting from <SMILES>CCOC(=O)/C=C(/C)N</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)/C=C(/C)N</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)c1cccnc1CN1CCC(c2c[nH]c3ccccc23)CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)c1cccnc1CN1CCC(c2c[nH]c3ccccc23)CC1</SMILES> starting from <SMILES>CCOC(=O)/C=C(/C)N</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)/C=C(/C)N</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)c1cccnc1CN1CCC(c2c[nH]c3ccccc23)CC1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['C=CC=O.CCOC(=O)/C=C(/C)N>C1CCNCC1.CC(C)O>CCOC(=O)c1cccnc1C'],['CCOC(=O)c1cccnc1C.O=C1CCC(=O)N1Br>ClC(Cl)(Cl)Cl.c1ccc(COOCc2ccccc2)cc1>CCOC(=O)c1cccnc1CBr'],['CCOC(=O)c1cccnc1CBr.c1ccc2c(C3CCNCC3)c[nH]c2c1>>CCOC(=O)c1cccnc1CN1CCC(c2c[nH]c3ccccc23)CC1'],"[['CCOC(=O)c1cccnc1C', 'CCOC(=O)c1cccnc1CBr']]"
79,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC[C@H](C)COc1ccc([C@H](CO)NC(=O)OC(C)(C)C)cc1</SMILES> starting from <SMILES>COC(=O)[C@H](N)c1ccc(O)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COC(=O)[C@H](N)c1ccc(O)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC[C@H](C)COc1ccc([C@H](CO)NC(=O)OC(C)(C)C)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC[C@H](C)COc1ccc([C@H](CO)NC(=O)OC(C)(C)C)cc1</SMILES> starting from <SMILES>COC(=O)[C@H](N)c1ccc(O)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COC(=O)[C@H](N)c1ccc(O)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC[C@H](C)COc1ccc([C@H](CO)NC(=O)OC(C)(C)C)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC[C@H](C)COc1ccc([C@H](CO)NC(=O)OC(C)(C)C)cc1</SMILES> starting from <SMILES>COC(=O)[C@H](N)c1ccc(O)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COC(=O)[C@H](N)c1ccc(O)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC[C@H](C)COc1ccc([C@H](CO)NC(=O)OC(C)(C)C)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CC(C)(C)OC(=O)OC(=O)OC(C)(C)C.COC(=O)[C@H](N)c1ccc(O)cc1>CCN(CC)CC.CO.ClCCl.O=C([O-])O.[Cl-].[NH4+].[Na+]>COC(=O)[C@H](NC(=O)OC(C)(C)C)c1ccc(O)cc1'],['CC[C@H](C)CO.COC(=O)[C@H](NC(=O)OC(C)(C)C)c1ccc(O)cc1>C1CCOC1.CC(C)OC(=O)/N=N/C(=O)OC(C)C.c1ccc(P(c2ccccc2)c2ccccc2)cc1>CC[C@H](C)COc1ccc([C@@H](NC(=O)OC(C)(C)C)C(=O)OC)cc1'],['CC[C@H](C)COc1ccc([C@@H](NC(=O)OC(C)(C)C)C(=O)OC)cc1>C1CCOC1.CCOC(C)=O.[Al+3].[H-].[H-].[H-].[H-].[K+].[Li+].[OH-]>CC[C@H](C)COc1ccc([C@H](CO)NC(=O)OC(C)(C)C)cc1'],"[['COC(=O)[C@H](NC(=O)OC(C)(C)C)c1ccc(O)cc1', 'CC[C@H](C)COc1ccc([C@@H](NC(=O)OC(C)(C)C)C(=O)OC)cc1']]"
80,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1cccc(C(=O)NCc2cc(F)cc(-c3cccc(C=O)c3)c2)c1</SMILES> starting from <SMILES>COC(=O)c1cccc(C(=O)O)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COC(=O)c1cccc(C(=O)O)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1cccc(C(=O)NCc2cc(F)cc(-c3cccc(C=O)c3)c2)c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1cccc(C(=O)NCc2cc(F)cc(-c3cccc(C=O)c3)c2)c1</SMILES> starting from <SMILES>COC(=O)c1cccc(C(=O)O)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COC(=O)c1cccc(C(=O)O)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1cccc(C(=O)NCc2cc(F)cc(-c3cccc(C=O)c3)c2)c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1cccc(C(=O)NCc2cc(F)cc(-c3cccc(C=O)c3)c2)c1</SMILES> starting from <SMILES>COC(=O)c1cccc(C(=O)O)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COC(=O)c1cccc(C(=O)O)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1cccc(C(=O)NCc2cc(F)cc(-c3cccc(C=O)c3)c2)c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CN.COC(=O)c1cccc(C(=O)O)c1>CCN(C(C)C)C(C)C.CN(C)C(On1nnc2ccccc21)=[N+](C)C.ClCCl.F[P-](F)(F)(F)(F)F>CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1cccc(C(=O)OC)c1', 'CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CN.COC(=O)c1cccc(C(=O)O)c1>CCN(C(C)C)C(C)C.CN(C)C(On1nnc2ccccc21)=[N+](C)C.ClCCl.F[P-](F)(F)(F)(F)F>CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1cccc(C(=O)OC)c1']","['CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1cccc(C(=O)OC)c1>C1CCOC1.Cl.O.[Li+].[OH-]>CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1cccc(C(=O)O)c1', 'CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1cccc(C(=O)OC)c1>CO.Cl.O.O.[Li]O>CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1cccc(C(=O)O)c1']","['CC(C)(C)OC(=O)NCc1cc(F)cc(-c2cccc(C=O)c2)c1.CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1cccc(C(=O)O)c1>C1COCCO1.CCN(CC)CC.CN(C)C(On1nnc2ccccc21)=[N+](C)C.Cl.ClCCl.F[P-](F)(F)(F)(F)F>CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1cccc(C(=O)NCc2cc(F)cc(-c3cccc(C=O)c3)c2)c1', 'CC(C)(C)OC(=O)NCc1cc(F)cc(-c2cccc(C=O)c2)c1.CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1cccc(C(=O)O)c1>C1COCCO1.CCN(CC)CC.CN(C)C(On1nnc2ccccc21)=[N+](C)C.Cl.ClCCl.F[P-](F)(F)(F)(F)F>CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1cccc(C(=O)NCc2cc(F)cc(-c3cccc(C=O)c3)c2)c1']","[['CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1cccc(C(=O)OC)c1', 'CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1cccc(C(=O)O)c1']]"
81,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)[C@@H](N)Cc1ccc(N)cc1</SMILES> starting from <SMILES>CC(C)(C)OC(=O)N[C@@H](Cc1ccc([N+](=O)[O-])cc1)C(=O)O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)OC(=O)N[C@@H](Cc1ccc([N+](=O)[O-])cc1)C(=O)O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)[C@@H](N)Cc1ccc(N)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)[C@@H](N)Cc1ccc(N)cc1</SMILES> starting from <SMILES>CC(C)(C)OC(=O)N[C@@H](Cc1ccc([N+](=O)[O-])cc1)C(=O)O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)OC(=O)N[C@@H](Cc1ccc([N+](=O)[O-])cc1)C(=O)O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)[C@@H](N)Cc1ccc(N)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COC(=O)[C@@H](N)Cc1ccc(N)cc1</SMILES> starting from <SMILES>CC(C)(C)OC(=O)N[C@@H](Cc1ccc([N+](=O)[O-])cc1)C(=O)O</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)OC(=O)N[C@@H](Cc1ccc([N+](=O)[O-])cc1)C(=O)O</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COC(=O)[C@@H](N)Cc1ccc(N)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CC(C)(C)OC(=O)N[C@@H](Cc1ccc([N+](=O)[O-])cc1)C(=O)O.CO.O=S(Cl)Cl>>COC(=O)[C@@H](N)Cc1ccc([N+](=O)[O-])cc1.Cl'],['COC(=O)[C@@H](N)Cc1ccc([N+](=O)[O-])cc1.Cl>C1CCOC1.CC(C)COC(=O)Cl.CCN(CC)CC>COC(=O)[C@@H](N)Cc1ccc([N+](=O)[O-])cc1'],['COC(=O)[C@@H](N)Cc1ccc([N+](=O)[O-])cc1>CO.[Pd]>COC(=O)[C@@H](N)Cc1ccc(N)cc1'],"[['COC(=O)[C@@H](N)Cc1ccc([N+](=O)[O-])cc1.Cl', 'COC(=O)[C@@H](N)Cc1ccc([N+](=O)[O-])cc1']]"
82,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOCc1nn2c(-c3ccc(F)cc3)cc(NCCO)nc2c1-c1ccc(C)cc1</SMILES> starting from <SMILES>CCOC(=O)CC(=O)c1ccc(F)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)CC(=O)c1ccc(F)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOCc1nn2c(-c3ccc(F)cc3)cc(NCCO)nc2c1-c1ccc(C)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOCc1nn2c(-c3ccc(F)cc3)cc(NCCO)nc2c1-c1ccc(C)cc1</SMILES> starting from <SMILES>CCOC(=O)CC(=O)c1ccc(F)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)CC(=O)c1ccc(F)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOCc1nn2c(-c3ccc(F)cc3)cc(NCCO)nc2c1-c1ccc(C)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOCc1nn2c(-c3ccc(F)cc3)cc(NCCO)nc2c1-c1ccc(C)cc1</SMILES> starting from <SMILES>CCOC(=O)CC(=O)c1ccc(F)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)CC(=O)c1ccc(F)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOCc1nn2c(-c3ccc(F)cc3)cc(NCCO)nc2c1-c1ccc(C)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CCOC(=O)CC(=O)c1ccc(F)cc1.CCOCc1n[nH]c(N)c1-c1ccc(C)cc1>c1ccncc1>CCOCc1nn2c(-c3ccc(F)cc3)cc(=O)[nH]c2c1-c1ccc(C)cc1'],['CCOCc1nn2c(-c3ccc(F)cc3)cc(=O)[nH]c2c1-c1ccc(C)cc1.O=P(Cl)(Cl)Cl>c1ccncc1>CCOCc1nn2c(-c3ccc(F)cc3)cc(Cl)nc2c1-c1ccc(C)cc1'],['CC(N)O.CCOCc1nn2c(-c3ccc(F)cc3)cc(Cl)nc2c1-c1ccc(C)cc1>CC#N.CCN(C(C)C)C(C)C>CCOCc1nn2c(-c3ccc(F)cc3)cc(NCCO)nc2c1-c1ccc(C)cc1'],"[['CCOCc1nn2c(-c3ccc(F)cc3)cc(=O)[nH]c2c1-c1ccc(C)cc1', 'CCOCc1nn2c(-c3ccc(F)cc3)cc(Cl)nc2c1-c1ccc(C)cc1']]"
83,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)COc1ccc(S(=O)(=O)N2CC(C(C)C)c3cc(Br)cc(C)c32)cc1C</SMILES> starting from <SMILES>CCOC(=O)CBr</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)CBr</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)COc1ccc(S(=O)(=O)N2CC(C(C)C)c3cc(Br)cc(C)c32)cc1C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)COc1ccc(S(=O)(=O)N2CC(C(C)C)c3cc(Br)cc(C)c32)cc1C</SMILES> starting from <SMILES>CCOC(=O)CBr</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)CBr</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)COc1ccc(S(=O)(=O)N2CC(C(C)C)c3cc(Br)cc(C)c32)cc1C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)COc1ccc(S(=O)(=O)N2CC(C(C)C)c3cc(Br)cc(C)c32)cc1C</SMILES> starting from <SMILES>CCOC(=O)CBr</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)CBr</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)COc1ccc(S(=O)(=O)N2CC(C(C)C)c3cc(Br)cc(C)c32)cc1C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CCOC(=O)CBr.Cc1ccccc1O>CN(C)C=O.O=C([O-])[O-].[K+].[K+]>CCOC(=O)COc1ccccc1C'],['CCOC(=O)COc1ccccc1C.O=S(=O)(O)Cl>ClC(Cl)Cl>CCOC(=O)COc1ccc(S(=O)(=O)Cl)cc1C'],['CCOC(=O)COc1ccc(S(=O)(=O)Cl)cc1C.Cc1cc(Br)cc2c1NCC2C(C)C>C1CCOC1.CCN(CC)CC.CN(C)c1ccncc1>CCOC(=O)COc1ccc(S(=O)(=O)N2CC(C(C)C)c3cc(Br)cc(C)c32)cc1C'],"[['CCOC(=O)COc1ccccc1C', 'CCOC(=O)COc1ccc(S(=O)(=O)Cl)cc1C']]"
84,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1ccc(Cn2cnc3ncc(Br)cc32)cc1</SMILES> starting from <SMILES>Nc1ncc(Br)cc1[N+](=O)[O-]</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Nc1ncc(Br)cc1[N+](=O)[O-]</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1ccc(Cn2cnc3ncc(Br)cc32)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1ccc(Cn2cnc3ncc(Br)cc32)cc1</SMILES> starting from <SMILES>Nc1ncc(Br)cc1[N+](=O)[O-]</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Nc1ncc(Br)cc1[N+](=O)[O-]</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1ccc(Cn2cnc3ncc(Br)cc32)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1ccc(Cn2cnc3ncc(Br)cc32)cc1</SMILES> starting from <SMILES>Nc1ncc(Br)cc1[N+](=O)[O-]</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Nc1ncc(Br)cc1[N+](=O)[O-]</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1ccc(Cn2cnc3ncc(Br)cc32)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['Nc1ncc(Br)cc1[N+](=O)[O-]>CCO.Cl.[Fe].[Na+].[OH-]>Nc1cc(Br)cnc1N', 'Nc1ncc(Br)cc1[N+](=O)[O-]>CC(C)O.CCOC(C)=O.O.[Cl-].[Fe].[NH4+]>Nc1cc(Br)cnc1N', 'Nc1ncc(Br)cc1[N+](=O)[O-]>CC(C)(C)O.CCOC(C)=O.Cl[Sn](Cl)(Cl)Cl.O.O.[BH4-].[Na+]>Nc1cc(Br)cnc1N', 'Nc1ncc(Br)cc1[N+](=O)[O-]>CC(C)(C)O.CCOC(C)=O.Cl[Sn]Cl.O.O.[BH4-].[Na+]>Nc1cc(Br)cnc1N']","['Nc1cc(Br)cnc1N.O=CO>>Brc1cnc2nc[nH]c2c1', 'Nc1cc(Br)cnc1N.O=CO>>Brc1cnc2nc[nH]c2c1', 'Nc1cc(Br)cnc1N.O=CO>>Brc1cnc2nc[nH]c2c1', 'Nc1cc(Br)cnc1N.O=CO>>Brc1cnc2nc[nH]c2c1']","['Brc1cnc2nc[nH]c2c1.COc1ccc(CCl)cc1>CN(C)C=O.O=C([O-])[O-].[Cs+].[Cs+]>COc1ccc(Cn2cnc3ncc(Br)cc32)cc1', 'Brc1cnc2nc[nH]c2c1.COc1ccc(CCl)cc1>CN(C)C=O.O=C([O-])[O-].[Cs+].[Cs+]>COc1ccc(Cn2cnc3ncc(Br)cc32)cc1', 'Brc1cnc2nc[nH]c2c1.COc1ccc(CCl)cc1>CN(C)C=O.O=C([O-])[O-].[Cs+].[Cs+]>COc1ccc(Cn2cnc3ncc(Br)cc32)cc1', 'Brc1cnc2nc[nH]c2c1.COc1ccc(CCl)cc1>CN(C)C=O.O=C([O-])[O-].[Cs+].[Cs+]>COc1ccc(Cn2cnc3ncc(Br)cc32)cc1']","[['Nc1cc(Br)cnc1N', 'Brc1cnc2nc[nH]c2c1']]"
85,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOc1cc2nc(C)ccc2cc1F</SMILES> starting from <SMILES>COc1cc(N)ccc1F</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COc1cc(N)ccc1F</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOc1cc2nc(C)ccc2cc1F</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOc1cc2nc(C)ccc2cc1F</SMILES> starting from <SMILES>COc1cc(N)ccc1F</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COc1cc(N)ccc1F</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOc1cc2nc(C)ccc2cc1F</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOc1cc2nc(C)ccc2cc1F</SMILES> starting from <SMILES>COc1cc(N)ccc1F</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>COc1cc(N)ccc1F</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOc1cc2nc(C)ccc2cc1F</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['C/C=C/C=O.COc1cc(N)ccc1F>Cl.[NH4+].[OH-]>COc1cc2nc(C)ccc2cc1F'],['COc1cc2nc(C)ccc2cc1F>Br.[NH4+].[OH-]>Cc1ccc2cc(F)c(O)cc2n1'],['CCBr.Cc1ccc2cc(F)c(O)cc2n1>CC(C)=O.O=C([O-])[O-].[K+].[K+]>CCOc1cc2nc(C)ccc2cc1F'],"[['COc1cc2nc(C)ccc2cc1F', 'Cc1ccc2cc(F)c(O)cc2n1']]"
86,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>Oc1cc2ccccc2nc1-c1ccc(F)cc1</SMILES> starting from <SMILES>O=[N+]([O-])c1ccccc1CO</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=[N+]([O-])c1ccccc1CO</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Oc1cc2ccccc2nc1-c1ccc(F)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Oc1cc2ccccc2nc1-c1ccc(F)cc1</SMILES> starting from <SMILES>O=[N+]([O-])c1ccccc1CO</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=[N+]([O-])c1ccccc1CO</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Oc1cc2ccccc2nc1-c1ccc(F)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Oc1cc2ccccc2nc1-c1ccc(F)cc1</SMILES> starting from <SMILES>O=[N+]([O-])c1ccccc1CO</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=[N+]([O-])c1ccccc1CO</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Oc1cc2ccccc2nc1-c1ccc(F)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['O=[N+]([O-])c1ccccc1CO>CO.NN.O.[Pd]>Nc1ccccc1CO'],['Nc1ccccc1CO>ClC(Cl)Cl.[Mn+4].[O-2].[O-2]>Nc1ccccc1C=O'],['Nc1ccccc1C=O.O=C(CBr)c1ccc(F)cc1>CO.Cl.O.[Na+].[OH-]>Oc1cc2ccccc2nc1-c1ccc(F)cc1'],"[['Nc1ccccc1CO', 'Nc1ccccc1C=O']]"
87,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CSc1nccc(C#Cc2ccc(F)cc2)n1</SMILES> starting from <SMILES>C#C[Si](C)(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C#C[Si](C)(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CSc1nccc(C#Cc2ccc(F)cc2)n1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CSc1nccc(C#Cc2ccc(F)cc2)n1</SMILES> starting from <SMILES>C#C[Si](C)(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C#C[Si](C)(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CSc1nccc(C#Cc2ccc(F)cc2)n1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CSc1nccc(C#Cc2ccc(F)cc2)n1</SMILES> starting from <SMILES>C#C[Si](C)(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>C#C[Si](C)(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CSc1nccc(C#Cc2ccc(F)cc2)n1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['C#C[Si](C)(C)C.Fc1ccc(I)cc1>C1CCOC1.CCN(CC)CC.Cl[Pd](Cl)([P](c1ccccc1)(c1ccccc1)c1ccccc1)[P](c1ccccc1)(c1ccccc1)c1ccccc1.[Cu]I>C[Si](C)(C)C#Cc1ccc(F)cc1'],['C[Si](C)(C)C#Cc1ccc(F)cc1>CO.O=C([O-])[O-].[K+].[K+]>C#Cc1ccc(F)cc1'],['C#Cc1ccc(F)cc1.CSc1nccc(I)n1>CCN(CC)CC.Cl[Pd](Cl)([P](c1ccccc1)(c1ccccc1)c1ccccc1)[P](c1ccccc1)(c1ccccc1)c1ccccc1.I[Cu]I>CSc1nccc(C#Cc2ccc(F)cc2)n1'],"[['C[Si](C)(C)C#Cc1ccc(F)cc1', 'C#Cc1ccc(F)cc1']]"
88,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CS(=O)(=O)Nc1noc2cc(COc3ccc(F)c(Cl)c3)c(Cl)cc12</SMILES> starting from <SMILES>Oc1ccc(F)c(Cl)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Oc1ccc(F)c(Cl)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CS(=O)(=O)Nc1noc2cc(COc3ccc(F)c(Cl)c3)c(Cl)cc12</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CS(=O)(=O)Nc1noc2cc(COc3ccc(F)c(Cl)c3)c(Cl)cc12</SMILES> starting from <SMILES>Oc1ccc(F)c(Cl)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Oc1ccc(F)c(Cl)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CS(=O)(=O)Nc1noc2cc(COc3ccc(F)c(Cl)c3)c(Cl)cc12</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CS(=O)(=O)Nc1noc2cc(COc3ccc(F)c(Cl)c3)c(Cl)cc12</SMILES> starting from <SMILES>Oc1ccc(F)c(Cl)c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Oc1ccc(F)c(Cl)c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CS(=O)(=O)Nc1noc2cc(COc3ccc(F)c(Cl)c3)c(Cl)cc12</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CC(C)(C)OC(=O)N(C(=O)OC(C)(C)C)c1noc2cc(CBr)c(Cl)cc12.Oc1ccc(F)c(Cl)c1>CN(C)C=O.O=C([O-])[O-].[K+].[K+]>CC(C)(C)OC(=O)N(C(=O)OC(C)(C)C)c1noc2cc(COc3ccc(F)c(Cl)c3)c(Cl)cc12'],['CC(C)(C)OC(=O)N(C(=O)OC(C)(C)C)c1noc2cc(COc3ccc(F)c(Cl)c3)c(Cl)cc12>ClCCl.O=C(O)C(F)(F)F>Nc1noc2cc(COc3ccc(F)c(Cl)c3)c(Cl)cc12'],['CS(=O)(=O)Cl.Nc1noc2cc(COc3ccc(F)c(Cl)c3)c(Cl)cc12>CCN(CC)CC.ClCCl>CS(=O)(=O)Nc1noc2cc(COc3ccc(F)c(Cl)c3)c(Cl)cc12'],"[['CC(C)(C)OC(=O)N(C(=O)OC(C)(C)C)c1noc2cc(COc3ccc(F)c(Cl)c3)c(Cl)cc12', 'Nc1noc2cc(COc3ccc(F)c(Cl)c3)c(Cl)cc12']]"
89,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1ccc2nc(N3CCS(=O)c4ccccc4C3)nc(N[C@@H]3CN(C(=O)OCc4ccccc4)C[C@H]3F)c2c1</SMILES> starting from <SMILES>Cc1ccc2nc(Cl)nc(Cl)c2c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Cc1ccc2nc(Cl)nc(Cl)c2c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1ccc2nc(N3CCS(=O)c4ccccc4C3)nc(N[C@@H]3CN(C(=O)OCc4ccccc4)C[C@H]3F)c2c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1ccc2nc(N3CCS(=O)c4ccccc4C3)nc(N[C@@H]3CN(C(=O)OCc4ccccc4)C[C@H]3F)c2c1</SMILES> starting from <SMILES>Cc1ccc2nc(Cl)nc(Cl)c2c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Cc1ccc2nc(Cl)nc(Cl)c2c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1ccc2nc(N3CCS(=O)c4ccccc4C3)nc(N[C@@H]3CN(C(=O)OCc4ccccc4)C[C@H]3F)c2c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>Cc1ccc2nc(N3CCS(=O)c4ccccc4C3)nc(N[C@@H]3CN(C(=O)OCc4ccccc4)C[C@H]3F)c2c1</SMILES> starting from <SMILES>Cc1ccc2nc(Cl)nc(Cl)c2c1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Cc1ccc2nc(Cl)nc(Cl)c2c1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>Cc1ccc2nc(N3CCS(=O)c4ccccc4C3)nc(N[C@@H]3CN(C(=O)OCc4ccccc4)C[C@H]3F)c2c1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['Cc1ccc2nc(Cl)nc(Cl)c2c1.[Na+].[OH-]>C1CCOC1.CC(=O)O>Cc1ccc2nc(Cl)[nH]c(=O)c2c1'],['Cc1ccc2nc(Cl)[nH]c(=O)c2c1.O=S1CCNCc2ccccc21>CCN(CC)CC.Cc1ccccc1>Cc1ccc2nc(N3CCS(=O)c4ccccc4C3)[nH]c(=O)c2c1'],['Cc1ccc2nc(N3CCS(=O)c4ccccc4C3)[nH]c(=O)c2c1.N[C@@H]1CN(C(=O)OCc2ccccc2)C[C@H]1F>C1CCC2=NCCCN2CC1.CN(C)C=O.CN(C)[P+](On1nnc2ccccc21)(N(C)C)N(C)C.F[P-](F)(F)(F)(F)F.O>Cc1ccc2nc(N3CCS(=O)c4ccccc4C3)nc(N[C@@H]3CN(C(=O)OCc4ccccc4)C[C@H]3F)c2c1'],"[['Cc1ccc2nc(Cl)[nH]c(=O)c2c1', 'Cc1ccc2nc(N3CCS(=O)c4ccccc4C3)[nH]c(=O)c2c1']]"
90,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)[Si]1(C(C)C)OC[C@H]2[C@H]3O[C@H]3C(O)[C@@H]2O[Si](C(C)C)(C(C)C)O1</SMILES> starting from <SMILES>O=C(O[C@@H]1[C@@H](CO)C=C[C@@H]1OC(=O)c1ccccc1)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O[C@@H]1[C@@H](CO)C=C[C@@H]1OC(=O)c1ccccc1)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)[Si]1(C(C)C)OC[C@H]2[C@H]3O[C@H]3C(O)[C@@H]2O[Si](C(C)C)(C(C)C)O1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)[Si]1(C(C)C)OC[C@H]2[C@H]3O[C@H]3C(O)[C@@H]2O[Si](C(C)C)(C(C)C)O1</SMILES> starting from <SMILES>O=C(O[C@@H]1[C@@H](CO)C=C[C@@H]1OC(=O)c1ccccc1)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O[C@@H]1[C@@H](CO)C=C[C@@H]1OC(=O)c1ccccc1)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)[Si]1(C(C)C)OC[C@H]2[C@H]3O[C@H]3C(O)[C@@H]2O[Si](C(C)C)(C(C)C)O1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)[Si]1(C(C)C)OC[C@H]2[C@H]3O[C@H]3C(O)[C@@H]2O[Si](C(C)C)(C(C)C)O1</SMILES> starting from <SMILES>O=C(O[C@@H]1[C@@H](CO)C=C[C@@H]1OC(=O)c1ccccc1)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O[C@@H]1[C@@H](CO)C=C[C@@H]1OC(=O)c1ccccc1)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)[Si]1(C(C)C)OC[C@H]2[C@H]3O[C@H]3C(O)[C@@H]2O[Si](C(C)C)(C(C)C)O1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['O=C(O[C@@H]1[C@@H](CO)C=C[C@@H]1OC(=O)c1ccccc1)c1ccccc1>CO.C[O-].[Na+]>OC[C@H]1C=C[C@H](O)[C@@H]1O'],['CC(C)[Si](Cl)(O[Si](Cl)(C(C)C)C(C)C)C(C)C.OC[C@H]1C=C[C@H](O)[C@@H]1O>CN(C)C=O.c1c[nH]cn1>CC(C)[Si]1(C(C)C)OC[C@H]2C=C[C@H](O)[C@@H]2O[Si](C(C)C)(C(C)C)O1'],['CC(C)[Si]1(C(C)C)OC[C@H]2C=C[C@H](O)[C@@H]2O[Si](C(C)C)(C(C)C)O1.O=C(OO)c1cccc(Cl)c1>ClCCl>CC(C)[Si]1(C(C)C)OC[C@H]2[C@H]3O[C@H]3C(O)[C@@H]2O[Si](C(C)C)(C(C)C)O1'],"[['OC[C@H]1C=C[C@H](O)[C@@H]1O', 'CC(C)[Si]1(C(C)C)OC[C@H]2C=C[C@H](O)[C@@H]2O[Si](C(C)C)(C(C)C)O1']]"
91,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOCc1nc2c[n+]([O-])c3ccccc3c2n1NC(C)C</SMILES> starting from <SMILES>CCOCc1nc2cnc3ccccc3c2n1NC(=O)OC(C)(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOCc1nc2cnc3ccccc3c2n1NC(=O)OC(C)(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOCc1nc2c[n+]([O-])c3ccccc3c2n1NC(C)C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOCc1nc2c[n+]([O-])c3ccccc3c2n1NC(C)C</SMILES> starting from <SMILES>CCOCc1nc2cnc3ccccc3c2n1NC(=O)OC(C)(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOCc1nc2cnc3ccccc3c2n1NC(=O)OC(C)(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOCc1nc2c[n+]([O-])c3ccccc3c2n1NC(C)C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOCc1nc2c[n+]([O-])c3ccccc3c2n1NC(C)C</SMILES> starting from <SMILES>CCOCc1nc2cnc3ccccc3c2n1NC(=O)OC(C)(C)C</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOCc1nc2cnc3ccccc3c2n1NC(=O)OC(C)(C)C</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOCc1nc2c[n+]([O-])c3ccccc3c2n1NC(C)C</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CCOCc1nc2cnc3ccccc3c2n1NC(=O)OC(C)(C)C>CCO.Cl.O.[NH4+].[OH-]>CCOCc1nc2cnc3ccccc3c2n1N'],['CC(=O)O.CC(=O)O[BH-](OC(C)=O)OC(C)=O.CCOCc1nc2cnc3ccccc3c2n1N.[Na+]>CC(C)=O.CO.ClCCCl.[BH4-].[Na+]>CCOCc1nc2cnc3ccccc3c2n1NC(C)C'],['CCOCc1nc2cnc3ccccc3c2n1NC(C)C.O=C(OO)c1cccc(Cl)c1>ClCCl>CCOCc1nc2c[n+]([O-])c3ccccc3c2n1NC(C)C'],"[['CCOCc1nc2cnc3ccccc3c2n1N', 'CCOCc1nc2cnc3ccccc3c2n1NC(C)C']]"
92,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C1CCN(Cc2ccccc2)CCN1</SMILES> starting from <SMILES>Cl.O.O=C1CCNCC1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Cl.O.O=C1CCNCC1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C1CCN(Cc2ccccc2)CCN1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C1CCN(Cc2ccccc2)CCN1</SMILES> starting from <SMILES>Cl.O.O=C1CCNCC1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Cl.O.O=C1CCNCC1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C1CCN(Cc2ccccc2)CCN1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C1CCN(Cc2ccccc2)CCN1</SMILES> starting from <SMILES>Cl.O.O=C1CCNCC1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Cl.O.O=C1CCNCC1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C1CCN(Cc2ccccc2)CCN1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['BrCc1ccccc1.Cl.O.O=C1CCNCC1>CN(C)C=O.O=C([O-])[O-].[K+].[K+]>O=C1CCN(Cc2ccccc2)CC1', 'BrCc1ccccc1.Cl.O.O=C1CCNCC1>CN(C)C=O.O=C([O-])[O-].[K+].[K+]>O=C1CCN(Cc2ccccc2)CC1', 'BrCc1ccccc1.Cl.O.O=C1CCNCC1>CN(C)C=O.O=C([O-])[O-].[K+].[K+]>O=C1CCN(Cc2ccccc2)CC1']","['Cl.NO.O=C1CCN(Cc2ccccc2)CC1>CC(=O)[O-].CCO.[Na+]>ON=C1CCN(Cc2ccccc2)CC1', 'Cl.O=C1CCN(Cc2ccccc2)CC1.[NH-]O>CC(=O)[O-].CCO.[Na+]>ON=C1CCN(Cc2ccccc2)CC1', 'Cl.NO.O=C1CCN(Cc2ccccc2)CC1>c1ccncc1>ON=C1CCN(Cc2ccccc2)CC1']","['ON=C1CCN(Cc2ccccc2)CC1>CC#N.CC(C)=O.O=S(=O)(Cl)c1ccccc1.[Na+].[OH-]>O=C1CCN(Cc2ccccc2)CCN1', 'ON=C1CCN(Cc2ccccc2)CC1>CC#N.CC(C)=O.O=S(=O)(Cl)c1ccccc1.[Na+].[OH-]>O=C1CCN(Cc2ccccc2)CCN1', 'ON=C1CCN(Cc2ccccc2)CC1>CC#N.CC(C)=O.O=S(=O)(Cl)c1ccccc1.[Na+].[OH-]>O=C1CCN(Cc2ccccc2)CCN1']","[['O=C1CCN(Cc2ccccc2)CC1', 'ON=C1CCN(Cc2ccccc2)CC1']]"
93,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCn1cc(-c2ccnc3[nH]ccc23)c(-c2ccc(NC(=O)C3CCCCC3)cc2)n1</SMILES> starting from <SMILES>CCn1cc(B2OC(C)(C)C(C)(C)O2)c(-c2ccc([N+](=O)[O-])cc2)n1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCn1cc(B2OC(C)(C)C(C)(C)O2)c(-c2ccc([N+](=O)[O-])cc2)n1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCn1cc(-c2ccnc3[nH]ccc23)c(-c2ccc(NC(=O)C3CCCCC3)cc2)n1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCn1cc(-c2ccnc3[nH]ccc23)c(-c2ccc(NC(=O)C3CCCCC3)cc2)n1</SMILES> starting from <SMILES>CCn1cc(B2OC(C)(C)C(C)(C)O2)c(-c2ccc([N+](=O)[O-])cc2)n1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCn1cc(B2OC(C)(C)C(C)(C)O2)c(-c2ccc([N+](=O)[O-])cc2)n1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCn1cc(-c2ccnc3[nH]ccc23)c(-c2ccc(NC(=O)C3CCCCC3)cc2)n1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCn1cc(-c2ccnc3[nH]ccc23)c(-c2ccc(NC(=O)C3CCCCC3)cc2)n1</SMILES> starting from <SMILES>CCn1cc(B2OC(C)(C)C(C)(C)O2)c(-c2ccc([N+](=O)[O-])cc2)n1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCn1cc(B2OC(C)(C)C(C)(C)O2)c(-c2ccc([N+](=O)[O-])cc2)n1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCn1cc(-c2ccnc3[nH]ccc23)c(-c2ccc(NC(=O)C3CCCCC3)cc2)n1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['Brc1ccnc2[nH]ccc12.CCn1cc(B2OC(C)(C)C(C)(C)O2)c(-c2ccc([N+](=O)[O-])cc2)n1>C1COCCO1.O=C([O-])[O-].[K+].[K+].c1ccc([P](c2ccccc2)(c2ccccc2)[Pd]([P](c2ccccc2)(c2ccccc2)c2ccccc2)([P](c2ccccc2)(c2ccccc2)c2ccccc2)[P](c2ccccc2)(c2ccccc2)c2ccccc2)cc1>CCn1cc(-c2ccnc3[nH]ccc23)c(-c2ccc([N+](=O)[O-])cc2)n1'],['CCn1cc(-c2ccnc3[nH]ccc23)c(-c2ccc([N+](=O)[O-])cc2)n1>CC(=O)O.[Zn]>CCn1cc(-c2ccnc3[nH]ccc23)c(-c2ccc(N)cc2)n1'],['CCn1cc(-c2ccnc3[nH]ccc23)c(-c2ccc(N)cc2)n1.O=C(Cl)C1CCCCC1>>CCn1cc(-c2ccnc3[nH]ccc23)c(-c2ccc(NC(=O)C3CCCCC3)cc2)n1'],"[['CCn1cc(-c2ccnc3[nH]ccc23)c(-c2ccc([N+](=O)[O-])cc2)n1', 'CCn1cc(-c2ccnc3[nH]ccc23)c(-c2ccc(N)cc2)n1']]"
94,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)C(Cc1ccc(OCc2ccccc2)cc1)Oc1ccc(C)cc1</SMILES> starting from <SMILES>CCOC(=O)C1OC1c1ccc(OCc2ccccc2)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)C1OC1c1ccc(OCc2ccccc2)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)C(Cc1ccc(OCc2ccccc2)cc1)Oc1ccc(C)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)C(Cc1ccc(OCc2ccccc2)cc1)Oc1ccc(C)cc1</SMILES> starting from <SMILES>CCOC(=O)C1OC1c1ccc(OCc2ccccc2)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)C1OC1c1ccc(OCc2ccccc2)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)C(Cc1ccc(OCc2ccccc2)cc1)Oc1ccc(C)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CCOC(=O)C(Cc1ccc(OCc2ccccc2)cc1)Oc1ccc(C)cc1</SMILES> starting from <SMILES>CCOC(=O)C1OC1c1ccc(OCc2ccccc2)cc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CCOC(=O)C1OC1c1ccc(OCc2ccccc2)cc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CCOC(=O)C(Cc1ccc(OCc2ccccc2)cc1)Oc1ccc(C)cc1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['CCOC(=O)C1OC1c1ccc(OCc2ccccc2)cc1>C1COCCO1.[H][H].[Ni]>CCOC(=O)C(O)Cc1ccc(OCc2ccccc2)cc1', 'CCOC(=O)C1OC1c1ccc(OCc2ccccc2)cc1>C1COCCO1.[H][H].[Pd]>CCOC(=O)C(O)Cc1ccc(OCc2ccccc2)cc1']","['CCOC(=O)C(O)Cc1ccc(OCc2ccccc2)cc1.CS(=O)(=O)Cl>CCN(CC)CC.ClCCl>CCOC(=O)C(Cc1ccc(OCc2ccccc2)cc1)OS(C)(=O)=O', 'CCOC(=O)C(O)Cc1ccc(OCc2ccccc2)cc1.CS(=O)(=O)Cl>CCN(CC)CC.ClCCl>CCOC(=O)C(Cc1ccc(OCc2ccccc2)cc1)OS(C)(=O)=O']","['CCOC(=O)C(Cc1ccc(OCc2ccccc2)cc1)OS(C)(=O)=O.Cc1ccc(O)cc1>CN(C)C=O.O=C([O-])[O-].[K+].[K+]>CCOC(=O)C(Cc1ccc(OCc2ccccc2)cc1)Oc1ccc(C)cc1', 'CCOC(=O)C(Cc1ccc(OCc2ccccc2)cc1)OS(C)(=O)=O.Cc1ccc(O)cc1>CN(C)C=O.O=C([O-])[O-].[K+].[K+]>CCOC(=O)C(Cc1ccc(OCc2ccccc2)cc1)Oc1ccc(C)cc1']","[['CCOC(=O)C(O)Cc1ccc(OCc2ccccc2)cc1', 'CCOC(=O)C(Cc1ccc(OCc2ccccc2)cc1)OS(C)(=O)=O']]"
95,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C1CN(CCc2ccccc2)CCN1</SMILES> starting from <SMILES>O=C(O)Cc1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)Cc1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C1CN(CCc2ccccc2)CCN1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C1CN(CCc2ccccc2)CCN1</SMILES> starting from <SMILES>O=C(O)Cc1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)Cc1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C1CN(CCc2ccccc2)CCN1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>O=C1CN(CCc2ccccc2)CCN1</SMILES> starting from <SMILES>O=C(O)Cc1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>O=C(O)Cc1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>O=C1CN(CCc2ccccc2)CCN1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['O=C(O)Cc1ccccc1>C1CCOC1.O.[Al+3].[H-].[H-].[H-].[H-].[Li+]>OCCc1ccccc1'],['BrC(Br)(Br)Br.OCCc1ccccc1>ClCCl.c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccncc1>BrCCc1ccccc1'],['BrCCc1ccccc1.O=C1CNCCN1>CS(C)=O.O=C([O-])[O-].[K+].[K+]>O=C1CN(CCc2ccccc2)CCN1'],"[['OCCc1ccccc1', 'BrCCc1ccccc1']]"
96,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>C[C@H]1CN(c2csc3cc(F)ccc23)CCN1CCC1OCCc2cc(C(N)=O)ccc21</SMILES> starting from <SMILES>CC(C)(C)[Si](C)(C)OCCC1OCCc2cc(C(N)=O)ccc21</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)[Si](C)(C)OCCC1OCCc2cc(C(N)=O)ccc21</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>C[C@H]1CN(c2csc3cc(F)ccc23)CCN1CCC1OCCc2cc(C(N)=O)ccc21</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>C[C@H]1CN(c2csc3cc(F)ccc23)CCN1CCC1OCCc2cc(C(N)=O)ccc21</SMILES> starting from <SMILES>CC(C)(C)[Si](C)(C)OCCC1OCCc2cc(C(N)=O)ccc21</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)[Si](C)(C)OCCC1OCCc2cc(C(N)=O)ccc21</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>C[C@H]1CN(c2csc3cc(F)ccc23)CCN1CCC1OCCc2cc(C(N)=O)ccc21</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>C[C@H]1CN(c2csc3cc(F)ccc23)CCN1CCC1OCCc2cc(C(N)=O)ccc21</SMILES> starting from <SMILES>CC(C)(C)[Si](C)(C)OCCC1OCCc2cc(C(N)=O)ccc21</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>CC(C)(C)[Si](C)(C)OCCC1OCCc2cc(C(N)=O)ccc21</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>C[C@H]1CN(c2csc3cc(F)ccc23)CCN1CCC1OCCc2cc(C(N)=O)ccc21</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ",['CC(C)(C)[Si](C)(C)OCCC1OCCc2cc(C(N)=O)ccc21>CC(=O)O.O>NC(=O)c1ccc2c(c1)CCOC2CCO'],['CS(=O)(=O)Cl.NC(=O)c1ccc2c(c1)CCOC2CCO>C1CCOC1.CCN(CC)CC.CN(C)C=O>CS(=O)(=O)OCCC1OCCc2cc(C(N)=O)ccc21'],['CS(=O)(=O)OCCC1OCCc2cc(C(N)=O)ccc21.C[C@H]1CN(c2csc3cc(F)ccc23)CCN1>>C[C@H]1CN(c2csc3cc(F)ccc23)CCN1CCC1OCCc2cc(C(N)=O)ccc21'],"[['NC(=O)c1ccc2c(c1)CCOC2CCO', 'CS(=O)(=O)OCCC1OCCc2cc(C(N)=O)ccc21']]"
97,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1ccccc1C(=O)C[N+]12CCC(CC1)[C@@H](OC(=O)C(NC(=O)OC(C)(C)C)c1ccccc1)C2.[Br-]</SMILES> starting from <SMILES>NC(C(=O)O)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>NC(C(=O)O)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1ccccc1C(=O)C[N+]12CCC(CC1)[C@@H](OC(=O)C(NC(=O)OC(C)(C)C)c1ccccc1)C2.[Br-]</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1ccccc1C(=O)C[N+]12CCC(CC1)[C@@H](OC(=O)C(NC(=O)OC(C)(C)C)c1ccccc1)C2.[Br-]</SMILES> starting from <SMILES>NC(C(=O)O)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>NC(C(=O)O)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1ccccc1C(=O)C[N+]12CCC(CC1)[C@@H](OC(=O)C(NC(=O)OC(C)(C)C)c1ccccc1)C2.[Br-]</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>COc1ccccc1C(=O)C[N+]12CCC(CC1)[C@@H](OC(=O)C(NC(=O)OC(C)(C)C)c1ccccc1)C2.[Br-]</SMILES> starting from <SMILES>NC(C(=O)O)c1ccccc1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>NC(C(=O)O)c1ccccc1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>COc1ccccc1C(=O)C[N+]12CCC(CC1)[C@@H](OC(=O)C(NC(=O)OC(C)(C)C)c1ccccc1)C2.[Br-]</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['CC(C)(C)OC(=O)OC(=O)OC(C)(C)C.NC(C(=O)O)c1ccccc1>>CC(C)(C)OC(=O)NC(C(=O)O)c1ccccc1', 'CC(C)(C)OC(=O)OC(=O)OC(C)(C)C.NC(C(=O)O)c1ccccc1>CC(C)=O.[Na+].[OH-]>CC(C)(C)OC(=O)NC(C(=O)O)c1ccccc1']","['CC(C)(C)OC(=O)NC(C(=O)O)c1ccccc1.O[C@H]1CN2CCC1CC2>C(=NC1CCCCC1)=NC1CCCCC1.C1CCOC1.On1nnc2ccccc21>CC(C)(C)OC(=O)NC(C(=O)O[C@H]1CN2CCC1CC2)c1ccccc1', 'CC(C)(C)OC(=O)NC(C(=O)O)c1ccccc1.O[C@H]1CN2CCC1CC2>C(=NC1CCCCC1)=NC1CCCCC1.C1CCOC1.On1nnc2ccccc21>CC(C)(C)OC(=O)NC(C(=O)O[C@H]1CN2CCC1CC2)c1ccccc1']","['CC(C)(C)OC(=O)NC(C(=O)O[C@H]1CN2CCC1CC2)c1ccccc1.COc1ccccc1C(=O)CBr>CC#N>COc1ccccc1C(=O)C[N+]12CCC(CC1)[C@@H](OC(=O)C(NC(=O)OC(C)(C)C)c1ccccc1)C2.[Br-]', 'CC(C)(C)OC(=O)NC(C(=O)O[C@H]1CN2CCC1CC2)c1ccccc1.COc1ccccc1C(=O)CBr>CC#N>COc1ccccc1C(=O)C[N+]12CCC(CC1)[C@@H](OC(=O)C(NC(=O)OC(C)(C)C)c1ccccc1)C2.[Br-]']","[['CC(C)(C)OC(=O)NC(C(=O)O)c1ccccc1', 'CC(C)(C)OC(=O)NC(C(=O)O[C@H]1CN2CCC1CC2)c1ccccc1']]"
98,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)OC(=O)N(Cc1ccc(Cl)cc1)c1ccc(C=O)cn1</SMILES> starting from <SMILES>Nc1ccc(Br)cn1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Nc1ccc(Br)cn1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)OC(=O)N(Cc1ccc(Cl)cc1)c1ccc(C=O)cn1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)OC(=O)N(Cc1ccc(Cl)cc1)c1ccc(C=O)cn1</SMILES> starting from <SMILES>Nc1ccc(Br)cn1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Nc1ccc(Br)cn1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)OC(=O)N(Cc1ccc(Cl)cc1)c1ccc(C=O)cn1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>CC(C)(C)OC(=O)N(Cc1ccc(Cl)cc1)c1ccc(C=O)cn1</SMILES> starting from <SMILES>Nc1ccc(Br)cn1</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>Nc1ccc(Br)cn1</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>CC(C)(C)OC(=O)N(Cc1ccc(Cl)cc1)c1ccc(C=O)cn1</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['Nc1ccc(Br)cn1.O=Cc1ccc(Cl)cc1>CC[SiH](CC)CC.Cc1ccccc1.O=C(O)C(F)(F)F>Clc1ccc(CNc2ccc(Br)cn2)cc1', 'Nc1ccc(Br)cn1.O=Cc1ccc(Cl)cc1>CC[SiH](CC)CC.Cc1ccccc1.O=C(O)C(F)(F)F>Clc1ccc(CNc2ccc(Br)cn2)cc1']","['CN(C)C=O.Clc1ccc(CNc2ccc(Br)cn2)cc1>C1CCOC1.[Cl-].[Li]C(C)(C)C.[NH4+]>O=Cc1ccc(NCc2ccc(Cl)cc2)nc1', 'CN(C)C=O.Clc1ccc(CNc2ccc(Br)cn2)cc1>C1CCOC1.[Cl-].[Li]C(C)(C)C.[NH4+]>O=Cc1ccc(NCc2ccc(Cl)cc2)nc1']","['CC(C)(C)OC(=O)OC(=O)OC(C)(C)C.O=Cc1ccc(NCc2ccc(Cl)cc2)nc1>C1CCOC1.CCN(C(C)C)C(C)C.CN(C)c1ccncc1>CC(C)(C)OC(=O)N(Cc1ccc(Cl)cc1)c1ccc(C=O)cn1', 'CC(C)(C)OC(=O)OC(=O)OC(C)(C)C.O=Cc1ccc(NCc2ccc(Cl)cc2)nc1>CCN(CC)CC.CN(C)c1ccncc1.ClCCl>CC(C)(C)OC(=O)N(Cc1ccc(Cl)cc1)c1ccc(C=O)cn1']","[['Clc1ccc(CNc2ccc(Br)cn2)cc1', 'O=Cc1ccc(NCc2ccc(Cl)cc2)nc1']]"
99,"
Please design a three-step chemical reaction scheme to synthesize <SMILES>N#Cc1cnn(-c2ccc(Cl)c(Cl)c2Cl)c1NC(=O)CCCCl</SMILES> starting from <SMILES>N#CCC#N</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>N#CCC#N</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>N#Cc1cnn(-c2ccc(Cl)c(Cl)c2Cl)c1NC(=O)CCCCl</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
No explanations and other information. Only return the answer in the specified format. ","
Please design a three-step chemical reaction scheme to synthesize <SMILES>N#Cc1cnn(-c2ccc(Cl)c(Cl)c2Cl)c1NC(=O)CCCCl</SMILES> starting from <SMILES>N#CCC#N</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>N#CCC#N</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>N#Cc1cnn(-c2ccc(Cl)c(Cl)c2Cl)c1NC(=O)CCCCl</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. The final answer should be formatted as follows:Intermediate product x1: <SMILES>[x1_SMILES]</SMILES>;Intermediate product x2: <SMILES>[x2_SMILES]</SMILES>.
Think step by step, and present the final answer in the specified format.","
Please design a three-step chemical reaction scheme to synthesize <SMILES>N#Cc1cnn(-c2ccc(Cl)c(Cl)c2Cl)c1NC(=O)CCCCl</SMILES> starting from <SMILES>N#CCC#N</SMILES>. 
The reaction consists of three sequential steps: in the first step, <SMILES>N#CCC#N</SMILES> undergoes a complete chemical reaction to produce an intermediate product <SMILES>[x1_SMILES]</SMILES>. 
In the second step, <SMILES>[x1_SMILES]</SMILES> is used as a reactant to produce an intermediate product <SMILES>[x2_SMILES]</SMILES>. 
In the third step, <SMILES>[x2_SMILES]</SMILES> is used as a reactant to  to obtain the final product <SMILES>N#Cc1cnn(-c2ccc(Cl)c(Cl)c2Cl)c1NC(=O)CCCCl</SMILES>. 
Please provide a set of possible SMILES representations for the intermediate products x1 and x2. ","['CCOC(OCC)OCC.N#CCC#N>>CCOC=C(C#N)C#N', 'CCOC(OCC)OCC.N#CCC#N>CC(=O)OOOC(C)=O>CCOC=C(C#N)C#N', 'CCOC(OCC)OCC.N#CCC#N>CC(=O)OOOC(C)=O>CCOC=C(C#N)C#N']","['CCOC=C(C#N)C#N.NNc1ccc(Cl)c(Cl)c1Cl>CCO>N#Cc1cnn(-c2ccc(Cl)c(Cl)c2Cl)c1N', 'CCOC=C(C#N)C#N.NNc1ccc(Cl)c(Cl)c1Cl>CCOC(C)O.O>N#Cc1cnn(-c2ccc(Cl)c(Cl)c2Cl)c1N', 'CCOC=C(C#N)C#N.NNc1ccc(Cl)c(Cl)c1Cl>CCO>N#Cc1cnn(-c2ccc(Cl)c(Cl)c2Cl)c1N']","['N#Cc1cnn(-c2ccc(Cl)c(Cl)c2Cl)c1N.O=C(Cl)CCCCl>CC#N>N#Cc1cnn(-c2ccc(Cl)c(Cl)c2Cl)c1NC(=O)CCCCl', 'N#Cc1cnn(-c2ccc(Cl)c(Cl)c2Cl)c1N.O=C(Cl)CCCCl>CC#N>N#Cc1cnn(-c2ccc(Cl)c(Cl)c2Cl)c1NC(=O)CCCCl', 'N#Cc1cnn(-c2ccc(Cl)c(Cl)c2Cl)c1N.O=C(Cl)CCCCl>CC#N>N#Cc1cnn(-c2ccc(Cl)c(Cl)c2Cl)c1NC(=O)CCCCl']","[['CCOC=C(C#N)C#N', 'N#Cc1cnn(-c2ccc(Cl)c(Cl)c2Cl)c1N']]"