diff --git "a/ethno_sample_400.json" "b/ethno_sample_400.json"
--- "a/ethno_sample_400.json"
+++ "b/ethno_sample_400.json"
@@ -1,4802 +1,4802 @@
 [
- {
-  "chemical": "LEDENE",
-  "plant_species": "Ocimum basilicum",
-  "application": null,
-  "dosage": null,
-  "pubmed_mentions_2026": 33,
-  "clinical_trials_count_2026": 0,
-  "chembl_bioactivity_count": 0,
-  "patent_count_since_2020": 0,
-  "pubchem_cid": 10910653,
-  "canonical_smiles": "CC1CCC2=C(CCC3C(C12)C3(C)C)C"
- },
- {
-  "chemical": "BETA-PINENE",
-  "plant_species": "Citrus paradisi",
-  "application": "Allergenic",
-  "dosage": null,
-  "pubmed_mentions_2026": 2094,
-  "clinical_trials_count_2026": 0,
-  "chembl_bioactivity_count": 53,
-  "patent_count_since_2020": 13,
-  "pubchem_cid": 14896,
-  "canonical_smiles": "CC1(C2CCC(=C)C1C2)C"
- },
- {
-  "chemical": "BETA-CAROTENE",
-  "plant_species": "Citrus sinensis",
-  "application": "Allergenic",
-  "dosage": null,
-  "pubmed_mentions_2026": 17942,
-  "clinical_trials_count_2026": 17,
-  "chembl_bioactivity_count": 233,
-  "patent_count_since_2020": 8,
-  "pubchem_cid": 5280489,
-  "canonical_smiles": "CC1=C(C(CCC1)(C)C)C=CC(=CC=CC(=CC=CC=C(C)C=CC=C(C)C=CC2=C(CCCC2(C)C)C)C)C"
- },
- {
-  "chemical": "LIMONENE",
-  "plant_species": "Agastache rugosa",
-  "application": "AChE-Inhibitor",
-  "dosage": null,
-  "pubmed_mentions_2026": 6286,
-  "clinical_trials_count_2026": 13,
-  "chembl_bioactivity_count": 433,
-  "patent_count_since_2020": 70,
-  "pubchem_cid": 22311,
-  "canonical_smiles": "CC1=CCC(CC1)C(=C)C"
- },
- {
-  "chemical": "6-ISO-PENTENYL-NARINGENIN",
-  "plant_species": "Humulus lupulus",
-  "application": null,
-  "dosage": null,
-  "pubmed_mentions_2026": 0,
-  "clinical_trials_count_2026": 0,
-  "chembl_bioactivity_count": 0,
-  "patent_count_since_2020": 0,
-  "pubchem_cid": null,
-  "canonical_smiles": null
- },
- {
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-  "plant_species": "Levisticum officinale",
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-  "dosage": null,
-  "pubmed_mentions_2026": 4,
-  "clinical_trials_count_2026": 0,
-  "chembl_bioactivity_count": 0,
-  "patent_count_since_2020": 0,
-  "pubchem_cid": 57459455,
-  "canonical_smiles": "CC(C)(C1C(C2=C(O1)C=CC3=C2OC(=O)C=C3)O)OC4C(C(C(C(O4)CO)O)O)O"
- },
- {
-  "chemical": "10-(ALPHA)-CADINOL",
-  "plant_species": "Origanum vulgare",
-  "application": null,
-  "dosage": null,
-  "pubmed_mentions_2026": 0,
-  "clinical_trials_count_2026": 0,
-  "chembl_bioactivity_count": 0,
-  "patent_count_since_2020": 0,
-  "pubchem_cid": null,
-  "canonical_smiles": null
- },
- {
-  "chemical": "TOCOPHEROL",
-  "plant_species": "Panicum maximum",
-  "application": "Allergenic",
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-  "pubmed_mentions_2026": 22812,
-  "clinical_trials_count_2026": 59,
-  "chembl_bioactivity_count": 615,
-  "patent_count_since_2020": 81,
-  "pubchem_cid": 14986,
-  "canonical_smiles": "CC1=C(C=C2CCC(OC2=C1C)(C)CCCC(C)CCCC(C)CCCC(C)C)O"
- },
- {
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-  "plant_species": "Artemisia vulgaris",
-  "application": "Allelopathic",
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-  "pubmed_mentions_2026": 2078,
-  "clinical_trials_count_2026": 0,
-  "chembl_bioactivity_count": 804,
-  "patent_count_since_2020": 7,
-  "pubchem_cid": 2758,
-  "canonical_smiles": "CC1(C2CCC(O1)(CC2)C)C"
- },
- {
-  "chemical": "N-ACETYLDJENKOLIC-ACID",
-  "plant_species": "Acacia tortilis",
-  "application": null,
-  "dosage": null,
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-  "clinical_trials_count_2026": 0,
-  "chembl_bioactivity_count": 0,
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-  "pubchem_cid": 78061794,
-  "canonical_smiles": "CC(=O)NC(CSCSCC(C(=O)O)N)C(=O)O"
- },
- {
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-  "plant_species": "Stellaria media",
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-  "dosage": null,
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-  "clinical_trials_count_2026": 0,
-  "chembl_bioactivity_count": 13,
-  "patent_count_since_2020": 1,
-  "pubchem_cid": 8914,
-  "canonical_smiles": "CCCCCCCCCO"
- },
- {
-  "chemical": "NEROLIDOL",
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-  "clinical_trials_count_2026": 0,
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-  "patent_count_since_2020": 1,
-  "pubchem_cid": 5284507,
-  "canonical_smiles": "CC(=CCCC(=CCCC(C)(C=C)O)C)C"
- },
- {
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-  "plant_species": "Zea mays",
-  "application": null,
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-  "pubmed_mentions_2026": 3,
-  "clinical_trials_count_2026": 0,
-  "chembl_bioactivity_count": 2,
-  "patent_count_since_2020": 0,
-  "pubchem_cid": 14254,
-  "canonical_smiles": "CCCCCCCCC(C)O"
- },
- {
-  "chemical": "BICYCLOELEMENE",
-  "plant_species": "Centella asiatica",
-  "application": null,
-  "dosage": null,
-  "pubmed_mentions_2026": 8,
-  "clinical_trials_count_2026": 0,
-  "chembl_bioactivity_count": 0,
-  "patent_count_since_2020": 0,
-  "pubchem_cid": 101973934,
-  "canonical_smiles": "CC(=C)C1C2C(C2(C)C)CCC1(C)C=C"
- },
- {
-  "chemical": "LYFOLINE",
-  "plant_species": "Heimia salicifolia",
-  "application": null,
-  "dosage": null,
-  "pubmed_mentions_2026": 3,
-  "clinical_trials_count_2026": 0,
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-  "pubchem_cid": 6436825,
-  "canonical_smiles": "COC1=C(C=C2C3CC(CC4N3CCCC4)OC(=O)C=CC5=CC(=C(C=C5)O)C2=C1)O"
- },
- {
-  "chemical": "1-METHYL-3,5-DIMETHOXY-4-HYDROXYBENZENE",
-  "plant_species": "Elaeis guineensis",
-  "application": null,
-  "dosage": null,
-  "pubmed_mentions_2026": 0,
-  "clinical_trials_count_2026": 0,
-  "chembl_bioactivity_count": 0,
-  "patent_count_since_2020": 0,
-  "pubchem_cid": 240925,
-  "canonical_smiles": "CC1=CC(=C(C(=C1)OC)O)OC"
- },
- {
-  "chemical": "LIMONENE",
-  "plant_species": "Origanum vulgare",
-  "application": "AChE-Inhibitor",
-  "dosage": null,
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-  "clinical_trials_count_2026": 13,
-  "chembl_bioactivity_count": 433,
-  "patent_count_since_2020": 70,
-  "pubchem_cid": 22311,
-  "canonical_smiles": "CC1=CCC(CC1)C(=C)C"
- },
- {
-  "chemical": "PHYTIN",
-  "plant_species": "Solanum tuberosum",
-  "application": null,
-  "dosage": null,
-  "pubmed_mentions_2026": 153,
-  "clinical_trials_count_2026": 1,
-  "chembl_bioactivity_count": 0,
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-  "pubchem_cid": 19234,
-  "canonical_smiles": "C1(C(C(C(C(C1OP(=O)([O-])[O-])OP(=O)([O-])[O-])OP(=O)([O-])[O-])OP(=O)([O-])[O-])OP(=O)([O-])[O-])OP(=O)([O-])[O-].[Mg+2].[Ca+2]"
- },
- {
-  "chemical": "(Z)-3-HEXENOL",
-  "plant_species": "Nepeta racemosa",
-  "application": null,
-  "dosage": null,
-  "pubmed_mentions_2026": 160,
-  "clinical_trials_count_2026": 0,
-  "chembl_bioactivity_count": 0,
-  "patent_count_since_2020": 0,
-  "pubchem_cid": 5281167,
-  "canonical_smiles": "CCC=CCCO"
- },
- {
-  "chemical": "TRANS-PINOCARVEOL",
-  "plant_species": "Eucalyptus citriodora",
-  "application": "Antimalarial",
-  "dosage": "IC50=5-50 ug/ml",
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-  "clinical_trials_count_2026": 0,
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-  "patent_count_since_2020": 0,
-  "pubchem_cid": 88302,
-  "canonical_smiles": "CC1(C2CC1C(=C)C(C2)O)C"
- },
- {
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-  "plant_species": "Teucrium polium",
-  "application": "Perfumery",
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-  "clinical_trials_count_2026": 0,
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-  "patent_count_since_2020": 10,
-  "pubchem_cid": 6434062,
-  "canonical_smiles": "CC(C)C=CC=C(C)C=C"
- },
- {
-  "chemical": "BETA-SITOSTEROL",
-  "plant_species": "Hordeum vulgare",
-  "application": "Androgenic",
-  "dosage": null,
-  "pubmed_mentions_2026": 5284,
-  "clinical_trials_count_2026": 0,
-  "chembl_bioactivity_count": 334,
-  "patent_count_since_2020": 2,
-  "pubchem_cid": 222284,
-  "canonical_smiles": "CCC(CCC(C)C1CCC2C1(CCC3C2CC=C4C3(CCC(C4)O)C)C)C(C)C"
- },
- {
-  "chemical": "OLEANOLIC-ACID",
-  "plant_species": "Cornus officinalis",
-  "application": "Abortifacient",
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-  "clinical_trials_count_2026": 0,
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- },
- {
-  "chemical": "ARGININE",
-  "plant_species": "Brassica napus var. napobrassica var. napobrassica",
-  "application": "Antidiabetic?",
-  "dosage": null,
-  "pubmed_mentions_2026": 115707,
-  "clinical_trials_count_2026": 283,
-  "chembl_bioactivity_count": 167,
-  "patent_count_since_2020": 433,
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-  "canonical_smiles": "C(CC(C(=O)O)N)CN=C(N)N"
- },
- {
-  "chemical": "PETUNIDIN-3-CAFFEOYLGLUCOSIDE",
-  "plant_species": "Vitis vinifera",
-  "application": null,
-  "dosage": null,
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-  "pubchem_cid": null,
-  "canonical_smiles": null
- },
- {
-  "chemical": "KAEMPFEROL-3-TRIGLUCOSIDE-7-RHAMNOSIDE",
-  "plant_species": "Solanum tuberosum",
-  "application": null,
-  "dosage": null,
-  "pubmed_mentions_2026": 0,
-  "clinical_trials_count_2026": 0,
-  "chembl_bioactivity_count": 0,
-  "patent_count_since_2020": 0,
-  "pubchem_cid": 157010006,
-  "canonical_smiles": "CC1C(C(C(C(O1)OC2=CC(=C3C(=C2)OC(=C(C3=O)OC4C(C(C(C(O4)COC5C(C(C(C(O5)COC6C(C(C(C(O6)CO)O)O)O)O)O)O)O)O)O)C7=CC=C(C=C7)O)O)O)O)O"
- },
- {
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-  "plant_species": "Pyrus communis",
-  "application": null,
-  "dosage": null,
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-  "pubchem_cid": null,
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- },
- {
-  "chemical": "7-O-METHYLAGATHISFLAVONE",
-  "plant_species": "Araucaria bidwillii",
-  "application": null,
-  "dosage": null,
-  "pubmed_mentions_2026": 0,
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-  "pubchem_cid": null,
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- },
- {
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-  "plant_species": "Teucrium salviastrum",
-  "application": "Allelopathic",
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-  "canonical_smiles": "CC1(C2CCC(O1)(CC2)C)C"
- },
- {
-  "chemical": "2-METHYL-HEXANOATE",
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- {
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-  "canonical_smiles": "C(C(C(=O)O)O)(C(=O)O)O"
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- {
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-  "plant_species": "Swertia chirata",
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-  "pubchem_cid": null,
-  "canonical_smiles": null
- },
- {
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-  "plant_species": "Simaba multiflora",
-  "application": "Allelochemic",
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-  "pubchem_cid": 5280460,
-  "canonical_smiles": "COC1=C(C=C2C(=C1)C=CC(=O)O2)O"
- },
- {
-  "chemical": "APIGENIN",
-  "plant_species": "Pimpinella anisum",
-  "application": "11B-HSD-Inhibitor",
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-  "canonical_smiles": "C1=CC(=CC=C1C2=CC(=O)C3=C(C=C(C=C3O2)O)O)O"
- },
- {
-  "chemical": "ISOMENTHONE",
-  "plant_species": "Pycnanthemum albescens",
-  "application": "Antiacetylcholinesterase",
-  "dosage": "IC50=1.6 mM",
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-  "pubchem_cid": 6432469,
-  "canonical_smiles": "CC1CCC(C(=O)C1)C(C)C"
- },
- {
-  "chemical": "ALPHA-TOCOPHEROL",
-  "plant_species": "Berberis vulgaris",
-  "application": "Anticonvulsant",
-  "dosage": "Synergen",
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-  "chembl_bioactivity_count": 615,
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-  "canonical_smiles": "CC1=C(C2=C(CCC(O2)(C)CCCC(C)CCCC(C)CCCC(C)C)C(=C1O)C)C"
- },
- {
-  "chemical": "ARSENIC",
-  "plant_species": "Celosia cristata",
-  "application": "Anorexic",
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-  "pubchem_cid": 5359596,
-  "canonical_smiles": "[As]"
- },
- {
-  "chemical": "IODINE",
-  "plant_species": "Piper nigrum",
-  "application": "Acnegenic",
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-  "patent_count_since_2020": 436,
-  "pubchem_cid": 807,
-  "canonical_smiles": "II"
- },
- {
-  "chemical": "BETA-CAROTENE",
-  "plant_species": "Lepidium sativum",
-  "application": "Allergenic",
-  "dosage": null,
-  "pubmed_mentions_2026": 17942,
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-  "pubchem_cid": 5280489,
-  "canonical_smiles": "CC1=C(C(CCC1)(C)C)C=CC(=CC=CC(=CC=CC=C(C)C=CC=C(C)C=CC2=C(CCCC2(C)C)C)C)C"
- },
- {
-  "chemical": "SYRINGIC-ACID",
-  "plant_species": "Maranta arundinacea",
-  "application": "Antioxidant",
-  "dosage": "IC39=30 ppm",
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-  "pubchem_cid": 10742,
-  "canonical_smiles": "COC1=CC(=CC(=C1O)OC)C(=O)O"
- },
- {
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-  "dosage": null,
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-  "clinical_trials_count_2026": 29,
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-  "patent_count_since_2020": 439,
-  "pubchem_cid": 5355457,
-  "canonical_smiles": "[Ba]"
- },
- {
-  "chemical": "LYSOLECITHIN",
-  "plant_species": "Oryza sativa",
-  "application": "Immunostimulant",
-  "dosage": "0.01-1 ug/ml",
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-  "chembl_bioactivity_count": 0,
-  "patent_count_since_2020": 5,
-  "pubchem_cid": 86554,
-  "canonical_smiles": "CCCCCCCCCCCCCCCC(=O)OCC(COP(=O)([O-])OCC[N+](C)(C)C)O"
- },
- {
-  "chemical": "MELANOL",
-  "plant_species": "Melia azedarach",
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-  "dosage": null,
-  "pubmed_mentions_2026": 2,
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-  "pubchem_cid": null,
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- },
- {
-  "chemical": "OXALIC-ACID",
-  "plant_species": "Papaver somniferum",
-  "application": "Antiseptic",
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-  "clinical_trials_count_2026": 0,
-  "chembl_bioactivity_count": 0,
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-  "pubchem_cid": 971,
-  "canonical_smiles": "C(=O)(C(=O)O)O"
- },
- {
-  "chemical": "3,5-DI-O-(BETA-GLUCOPYRANOSYL)-CYANIDIN-6''-O-4,6'''-O-1-CYCLIC-MALATE",
-  "plant_species": "Dianthus caryophyllus",
-  "application": null,
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-  "pubchem_cid": null,
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- },
- {
-  "chemical": "PINORESINOL",
-  "plant_species": "Pinus strobus",
-  "application": "Antioxidant",
-  "dosage": "(> tocopherol)",
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 ]
\ No newline at end of file