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      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "8016-96-4",
      "coefficient_tier_recomputed": "base",
      "distance_to_boundary_coeff_units": 39.0,
      "measured_coefficient": 100,
      "measured_tier": "base",
      "name": "Vetivert",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "8021-15-0",
      "coefficient_tier_recomputed": "mid",
      "distance_to_boundary_coeff_units": 8.0,
      "measured_coefficient": 52,
      "measured_tier": "mid",
      "name": "Opoponax oil",
      "poucher_tier": "base",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "near-boundary",
      "boundary_crossed": "top_mid_14_15",
      "cas": "8022-09-9",
      "coefficient_tier_recomputed": "top",
      "distance_to_boundary_coeff_units": 5.0,
      "measured_coefficient": 9,
      "measured_tier": "top",
      "name": "Spike lavender",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "8022-62-6",
      "coefficient_tier_recomputed": "top",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 14,
      "measured_tier": "top",
      "name": "Reseda absolute",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "near-boundary",
      "boundary_crossed": "top_mid_14_15",
      "cas": "8023-70-5",
      "coefficient_tier_recomputed": "top",
      "distance_to_boundary_coeff_units": 4.0,
      "measured_coefficient": 10,
      "measured_tier": "top",
      "name": "Ginger",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "near-boundary",
      "boundary_crossed": "top_mid_14_15",
      "cas": "8023-82-3",
      "coefficient_tier_recomputed": "top",
      "distance_to_boundary_coeff_units": 4.0,
      "measured_coefficient": 10,
      "measured_tier": "top",
      "name": "Myrrh oil",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "8023-87-6",
      "coefficient_tier_recomputed": "top",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 14,
      "measured_tier": "top",
      "name": "Mimosa absolute",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "8023-91-4",
      "coefficient_tier_recomputed": "mid",
      "distance_to_boundary_coeff_units": 8.0,
      "measured_coefficient": 52,
      "measured_tier": "mid",
      "name": "Galbanum resin",
      "poucher_tier": "base",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "near-boundary",
      "boundary_crossed": "mid_base_60_61",
      "cas": "83-54-5",
      "coefficient_tier_recomputed": "mid",
      "distance_to_boundary_coeff_units": 0.0,
      "measured_coefficient": 60,
      "measured_tier": "mid",
      "name": "Rhodinyl formate",
      "poucher_tier": "base",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "9000-50-6",
      "coefficient_tier_recomputed": "base",
      "distance_to_boundary_coeff_units": 39.0,
      "measured_coefficient": 100,
      "measured_tier": "base",
      "name": "Oakmoss",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "91-64-5",
      "coefficient_tier_recomputed": "base",
      "distance_to_boundary_coeff_units": 39.0,
      "measured_coefficient": 100,
      "measured_tier": "base",
      "name": "Coumarin",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "91771-61-8",
      "coefficient_tier_recomputed": "mid",
      "distance_to_boundary_coeff_units": 42.0,
      "measured_coefficient": 18,
      "measured_tier": "mid",
      "name": "Citronella, Java",
      "poucher_tier": "base",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "94-48-4",
      "coefficient_tier_recomputed": "top",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 4,
      "measured_tier": "top",
      "name": "Geranyl benzoate",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "94-59-7",
      "coefficient_tier_recomputed": "top",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 3,
      "measured_tier": "top",
      "name": "Sassafras",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "98-86-2",
      "coefficient_tier_recomputed": "top",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 1,
      "measured_tier": "top",
      "name": "Acetophenone",
      "poucher_tier": "base",
      "tier_step_distance": 2
    }
  ],
  "histogram": {
    "near-boundary": 12,
    "wild": 57
  },
  "histogram_by_pair": {
    "base->mid:wild": 5,
    "base->top:wild": 1,
    "mid->base:near-boundary": 4,
    "mid->base:wild": 8,
    "top->base:wild": 26,
    "top->mid:near-boundary": 8,
    "top->mid:wild": 17
  },
  "pimt_version": "v8",
  "verdict": {
    "measured_170_stands": true,
    "phase1_conclusion_survives": true,
    "phase1_recompute_reason": "Wild cases are mostly same-CAS source/construct disagreements or form mismatches in the auxiliary tier source, not measured-side join errors. The 170 measured coefficients remain the Phase 1 target.",
    "phase1_recomputed": false,
    "phase1_saved_best_baseline_r2": 0.24057748815493107,
    "phase1_saved_best_baseline_spearman_rho": 0.6130893034049266,
    "phase1_saved_best_structure_r2": 0.3990232662101132,
    "phase1_saved_best_structure_spearman_rho": 0.6633801733693918,
    "phase1_test_wild_non_join_cas": [
      "106-29-6",
      "112-14-1",
      "118-58-1",
      "141-78-6",
      "141-97-9",
      "68127-65-1",
      "8000-29-1",
      "8000-41-7",
      "8008-45-5",
      "8014-09-3"
    ],
    "tier_fold_policy": "Do not fold disagreeing auxiliary tiers as substantivity supervision. Only near-boundary-consistent rows, and future join-corrected rows if any, may be folded with provenance poucher-tier; poucher-measured remains uncontaminated."
  },
  "wild_case_causes": [
    {
      "cas": "100-52-7",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 1 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Almonds, Benzaldehyde; tier row name: Almonds.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 1,
      "measured_tier": "top",
      "name": "Almonds",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "101-84-8",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 10 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Diphenyl oxide; tier row name: Diphenyl oxide.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 10,
      "measured_tier": "top",
      "name": "Diphenyl oxide",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "103-45-7",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 1 maps to top; auxiliary Poucher profile tier is mid.",
        "Measured source names: Phenylethyl acetate; tier row name: Phenylethyl acetate.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 1,
      "measured_tier": "top",
      "name": "Phenylethyl acetate",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "mid"
    },
    {
      "cas": "103-48-0",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 19 maps to mid; auxiliary Poucher profile tier is base.",
        "Measured source names: Phenylethyl iso-butyrate; tier row name: Phenylethyl iso-butyrate.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 19,
      "measured_tier": "mid",
      "name": "Phenylethyl iso-butyrate",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "103-61-7",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 28 maps to mid; auxiliary Poucher profile tier is base.",
        "Measured source names: Cinnamyl butyrate; tier row name: Cinnamyl butyrate.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 28,
      "measured_tier": "mid",
      "name": "Cinnamyl butyrate",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "104-65-4",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 18 maps to mid; auxiliary Poucher profile tier is base.",
        "Measured source names: Cinnamyl formate; tier row name: Cinnamyl formate.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 18,
      "measured_tier": "mid",
      "name": "Cinnamyl formate",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "105-13-5",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 47 maps to mid; auxiliary Poucher profile tier is base.",
        "Measured source names: Anisic alcohol; tier row name: Anisic alcohol.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 47,
      "measured_tier": "mid",
      "name": "Anisic alcohol",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "105-85-1",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 9 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Citronellyl formate; tier row name: Citronellyl formate.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 9,
      "measured_tier": "top",
      "name": "Citronellyl formate",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "106-22-9",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 4 maps to top; auxiliary Poucher profile tier is mid.",
        "Measured source names: Citronellol; tier row name: Citronellol.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 4,
      "measured_tier": "top",
      "name": "Citronellol",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "mid"
    },
    {
      "cas": "106-24-1",
      "cause": "join-error",
      "evidence": [
        "Measured coefficient 6 maps to top; auxiliary Poucher profile tier is mid.",
        "Measured source names: Geraniol ex palmarosa, Geraniol, Java; tier row name: Geraniol ex palmarosa.",
        "Measured extraction has an intra-CAS coefficient conflict, so identity/name aggregation must be manually corrected before folding this row."
      ],
      "measured_coefficient": 6,
      "measured_tier": "top",
      "name": "Geraniol ex palmarosa",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "mid"
    },
    {
      "cas": "106-25-2",
      "cause": "join-error",
      "evidence": [
        "Measured coefficient 5 maps to top; auxiliary Poucher profile tier is mid.",
        "Measured source names: Nerol, Neroli bigarade, Neroli, Italian; tier row name: Nerol.",
        "Measured extraction has an intra-CAS coefficient conflict, so identity/name aggregation must be manually corrected before folding this row."
      ],
      "measured_coefficient": 5,
      "measured_tier": "top",
      "name": "Nerol",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "mid"
    },
    {
      "cas": "106-29-6",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 9 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Geranyl butyrate; tier row name: Geranyl butyrate.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 9,
      "measured_tier": "top",
      "name": "Geranyl butyrate",
      "phase1_scaffold_test_member": true,
      "poucher_tier": "base"
    },
    {
      "cas": "107-75-5",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 80 maps to base; auxiliary Poucher profile tier is mid.",
        "Measured source names: Hydroxy citronellal; tier row name: Hydroxy citronellal.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 80,
      "measured_tier": "base",
      "name": "Hydroxy citronellal",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "mid"
    },
    {
      "cas": "111-12-6",
      "cause": "join-error",
      "evidence": [
        "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is mid.",
        "Measured source names: Methyl heptine carbonate, Methyl octine carbonate; tier row name: Methyl heptine carbonate.",
        "Measured extraction has an intra-CAS coefficient conflict, so identity/name aggregation must be manually corrected before folding this row."
      ],
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Methyl heptine carbonate",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "mid"
    },
    {
      "cas": "112-14-1",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 1 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Octyl acetate; tier row name: Octyl acetate.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 1,
      "measured_tier": "top",
      "name": "Octyl acetate",
      "phase1_scaffold_test_member": true,
      "poucher_tier": "base"
    },
    {
      "cas": "112-31-2",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 100 maps to base; auxiliary Poucher profile tier is top.",
        "Measured source names: Decyl aldehyde; tier row name: Decyl aldehyde.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 100,
      "measured_tier": "base",
      "name": "Decyl aldehyde",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "top"
    },
    {
      "cas": "118-58-1",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Benzyl salicylate; tier row name: Benzyl salicylate.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Benzyl salicylate",
      "phase1_scaffold_test_member": true,
      "poucher_tier": "base"
    },
    {
      "cas": "122-00-9",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 3 maps to top; auxiliary Poucher profile tier is mid.",
        "Measured source names: Methyl acetophenone; tier row name: Methyl acetophenone.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 3,
      "measured_tier": "top",
      "name": "Methyl acetophenone",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "mid"
    },
    {
      "cas": "122-63-4",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 10 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Benzyl propionate; tier row name: Benzyl propionate.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 10,
      "measured_tier": "top",
      "name": "Benzyl propionate",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "124-19-6",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Nonyl aldehyde; tier row name: Nonyl aldehyde.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Nonyl aldehyde",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "126-64-7",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 9 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Linalyl benzoate; tier row name: Linalyl benzoate.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 9,
      "measured_tier": "top",
      "name": "Linalyl benzoate",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "1335-46-2",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 14 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Methyl ionone; tier row name: Methyl ionone.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 14,
      "measured_tier": "top",
      "name": "Methyl ionone",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "140-11-4",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 1 maps to top; auxiliary Poucher profile tier is mid.",
        "Measured source names: Benzyl acetate; tier row name: Benzyl acetate.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 1,
      "measured_tier": "top",
      "name": "Benzyl acetate",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "mid"
    },
    {
      "cas": "141-78-6",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 1 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Ethyl acetate; tier row name: Ethyl acetate.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 1,
      "measured_tier": "top",
      "name": "Ethyl acetate",
      "phase1_scaffold_test_member": true,
      "poucher_tier": "base"
    },
    {
      "cas": "141-97-9",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 1 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Ethyl acetoacetate; tier row name: Ethyl acetoacetate.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 1,
      "measured_tier": "top",
      "name": "Ethyl acetoacetate",
      "phase1_scaffold_test_member": true,
      "poucher_tier": "base"
    },
    {
      "cas": "144-39-8",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 5 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Linalyl propionate; tier row name: Linalyl propionate.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 5,
      "measured_tier": "top",
      "name": "Linalyl propionate",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "150-84-5",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Citronellyl acetate; tier row name: Citronellyl acetate.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Citronellyl acetate",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "2050-08-0",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is mid.",
        "Measured source names: Amyl salicylate; tier row name: Amyl salicylate.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Amyl salicylate",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "mid"
    },
    {
      "cas": "60-12-8",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is mid.",
        "Measured source names: Phenylethyl alcohol; tier row name: Phenylethyl alcohol.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Phenylethyl alcohol",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "mid"
    },
    {
      "cas": "68127-65-1",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 5 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Rhodinol; tier row name: Rhodinol.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 5,
      "measured_tier": "top",
      "name": "Rhodinol",
      "phase1_scaffold_test_member": true,
      "poucher_tier": "base"
    },
    {
      "cas": "8000-27-9",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Cedarwood; tier row name: Cedarwood.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Cedarwood",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "8000-28-0",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is mid.",
        "Measured source names: Lavender; tier row name: Lavender.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Lavender",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "mid"
    },
    {
      "cas": "8000-29-1",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is mid.",
        "Measured source names: Citronella, Ceylon; tier row name: Citronella, Ceylon.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Citronella, Ceylon",
      "phase1_scaffold_test_member": true,
      "poucher_tier": "mid"
    },
    {
      "cas": "8000-41-7",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 3 maps to top; auxiliary Poucher profile tier is mid.",
        "Measured source names: Terpineol; tier row name: Terpineol.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 3,
      "measured_tier": "top",
      "name": "Terpineol",
      "phase1_scaffold_test_member": true,
      "poucher_tier": "mid"
    },
    {
      "cas": "8000-48-4",
      "cause": "join-error",
      "evidence": [
        "Measured coefficient 15 maps to mid; auxiliary Poucher profile tier is base.",
        "Measured source names: Eucalyptus, Eucalyptus citriodora; tier row name: Eucalyptus.",
        "Measured extraction has an intra-CAS coefficient conflict, so identity/name aggregation must be manually corrected before folding this row."
      ],
      "measured_coefficient": 15,
      "measured_tier": "mid",
      "name": "Eucalyptus",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "8006-78-8",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 6 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Bay; tier row name: Bay.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 6,
      "measured_tier": "top",
      "name": "Bay",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "8006-84-6",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 14 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Fennel; tier row name: Fennel.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 14,
      "measured_tier": "top",
      "name": "Fennel",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "8007-35-0",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 5 maps to top; auxiliary Poucher profile tier is mid.",
        "Measured source names: Terpinyl acetate; tier row name: Terpinyl acetate.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 5,
      "measured_tier": "top",
      "name": "Terpinyl acetate",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "mid"
    },
    {
      "cas": "8007-46-3",
      "cause": "join-error",
      "evidence": [
        "Measured coefficient 6 maps to top; auxiliary Poucher profile tier is mid.",
        "Measured source names: Thyme red, Thyme white; tier row name: Thyme white.",
        "Measured extraction has an intra-CAS coefficient conflict, so identity/name aggregation must be manually corrected before folding this row."
      ],
      "measured_coefficient": 6,
      "measured_tier": "top",
      "name": "Thyme white",
      "phase1_scaffold_test_member": true,
      "poucher_tier": "mid"
    },
    {
      "cas": "8007-75-8",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 6 maps to top; auxiliary Poucher profile tier is mid.",
        "Measured source names: Bergamot; tier row name: Bergamot.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 6,
      "measured_tier": "top",
      "name": "Bergamot",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "mid"
    },
    {
      "cas": "8008-45-5",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 14 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Nutmeg; tier row name: Nutmeg.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 14,
      "measured_tier": "top",
      "name": "Nutmeg",
      "phase1_scaffold_test_member": true,
      "poucher_tier": "base"
    },
    {
      "cas": "8008-56-8",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 5 maps to top; auxiliary Poucher profile tier is mid.",
        "Measured source names: Lemon; tier row name: Lemon.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 5,
      "measured_tier": "top",
      "name": "Lemon",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "mid"
    },
    {
      "cas": "8014-09-3",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 100 maps to base; auxiliary Poucher profile tier is mid.",
        "Measured source names: Patchouli; tier row name: Patchouli.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 100,
      "measured_tier": "base",
      "name": "Patchouli",
      "phase1_scaffold_test_member": true,
      "poucher_tier": "mid"
    },
    {
      "cas": "8014-17-3",
      "cause": "join-error",
      "evidence": [
        "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is mid.",
        "Measured source names: Petitgrain para, Petitgrain, French; tier row name: Petitgrain, French.",
        "Measured extraction has an intra-CAS coefficient conflict, so identity/name aggregation must be manually corrected before folding this row."
      ],
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Petitgrain, French",
      "phase1_scaffold_test_member": true,
      "poucher_tier": "mid"
    },
    {
      "cas": "8014-19-5",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 14 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Palmarosa; tier row name: Palmarosa.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 14,
      "measured_tier": "top",
      "name": "Palmarosa",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "8015-73-4",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 14 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Basilic; tier row name: Basilic.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 14,
      "measured_tier": "top",
      "name": "Basilic",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "8016-96-4",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 100 maps to base; auxiliary Poucher profile tier is mid.",
        "Measured source names: Vetivert; tier row name: Vetivert.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 100,
      "measured_tier": "base",
      "name": "Vetivert",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "mid"
    },
    {
      "cas": "8021-15-0",
      "cause": "join-error",
      "evidence": [
        "Measured coefficient 52 maps to mid; auxiliary Poucher profile tier is base.",
        "Measured source names: Opoponax oil, Opoponax resin; tier row name: Opoponax oil.",
        "Measured extraction has an intra-CAS coefficient conflict, so identity/name aggregation must be manually corrected before folding this row."
      ],
      "measured_coefficient": 52,
      "measured_tier": "mid",
      "name": "Opoponax oil",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "8022-62-6",
      "cause": "form-mismatch",
      "evidence": [
        "Measured coefficient 14 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Reseda absolute; tier row name: Reseda absolute.",
        "The measured/tier evidence names a natural, source-geographic, or material-form variant rather than one clean isolate."
      ],
      "measured_coefficient": 14,
      "measured_tier": "top",
      "name": "Reseda absolute",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "8023-87-6",
      "cause": "form-mismatch",
      "evidence": [
        "Measured coefficient 14 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Mimosa absolute; tier row name: Mimosa absolute.",
        "The measured/tier evidence names a natural, source-geographic, or material-form variant rather than one clean isolate."
      ],
      "measured_coefficient": 14,
      "measured_tier": "top",
      "name": "Mimosa absolute",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "8023-91-4",
      "cause": "join-error",
      "evidence": [
        "Measured coefficient 52 maps to mid; auxiliary Poucher profile tier is base.",
        "Measured source names: Galbanum oil, Galbanum resin; tier row name: Galbanum resin.",
        "Measured extraction has an intra-CAS coefficient conflict, so identity/name aggregation must be manually corrected before folding this row."
      ],
      "measured_coefficient": 52,
      "measured_tier": "mid",
      "name": "Galbanum resin",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "9000-50-6",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 100 maps to base; auxiliary Poucher profile tier is mid.",
        "Measured source names: Oakmoss; tier row name: Oakmoss.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 100,
      "measured_tier": "base",
      "name": "Oakmoss",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "mid"
    },
    {
      "cas": "91-64-5",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 100 maps to base; auxiliary Poucher profile tier is mid.",
        "Measured source names: Coumarin; tier row name: Coumarin.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 100,
      "measured_tier": "base",
      "name": "Coumarin",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "mid"
    },
    {
      "cas": "91771-61-8",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 18 maps to mid; auxiliary Poucher profile tier is base.",
        "Measured source names: Citronella, Java; tier row name: Citronella, Java.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 18,
      "measured_tier": "mid",
      "name": "Citronella, Java",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "94-48-4",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 4 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Geranyl benzoate; tier row name: Geranyl benzoate.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 4,
      "measured_tier": "top",
      "name": "Geranyl benzoate",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "94-59-7",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 3 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Sassafras; tier row name: Sassafras.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 3,
      "measured_tier": "top",
      "name": "Sassafras",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    },
    {
      "cas": "98-86-2",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Measured coefficient 1 maps to top; auxiliary Poucher profile tier is base.",
        "Measured source names: Acetophenone; tier row name: Acetophenone.",
        "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure."
      ],
      "measured_coefficient": 1,
      "measured_tier": "top",
      "name": "Acetophenone",
      "phase1_scaffold_test_member": false,
      "poucher_tier": "base"
    }
  ],
  "wild_cause_counts": {
    "form-mismatch": 2,
    "genuine-source-disagreement": 47,
    "join-error": 8
  }
}