{
  "agreement_count": 75,
  "agreement_rate": 0.5208333333333334,
  "agreement_total": 144,
  "boundary_margin_coeff_units": 5,
  "diagnostic": "D1_substantivity_integrity",
  "disagreement_count": 69,
  "disagreements": [
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "100-52-7",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 1,
      "measured_tier": "top",
      "name": "Almonds",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "101-84-8",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 10,
      "measured_tier": "top",
      "name": "Diphenyl oxide",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "near-boundary",
      "boundary_crossed": "mid_base_60_61",
      "cas": "102-16-9",
      "distance_to_boundary_coeff_units": 0.0,
      "measured_coefficient": 60,
      "measured_tier": "mid",
      "name": "Benzyl phenylacetate",
      "poucher_tier": "base",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "near-boundary",
      "boundary_crossed": "top_mid_14_15",
      "cas": "103-26-4",
      "distance_to_boundary_coeff_units": 2.0,
      "measured_coefficient": 12,
      "measured_tier": "top",
      "name": "Methyl cinnamate",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "top_mid_14_15",
      "cas": "103-45-7",
      "distance_to_boundary_coeff_units": 13.0,
      "measured_coefficient": 1,
      "measured_tier": "top",
      "name": "Phenylethyl acetate",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "103-48-0",
      "distance_to_boundary_coeff_units": 41.0,
      "measured_coefficient": 19,
      "measured_tier": "mid",
      "name": "Phenylethyl iso-butyrate",
      "poucher_tier": "base",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "103-61-7",
      "distance_to_boundary_coeff_units": 32.0,
      "measured_coefficient": 28,
      "measured_tier": "mid",
      "name": "Cinnamyl butyrate",
      "poucher_tier": "base",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "104-65-4",
      "distance_to_boundary_coeff_units": 42.0,
      "measured_coefficient": 18,
      "measured_tier": "mid",
      "name": "Cinnamyl formate",
      "poucher_tier": "base",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "105-13-5",
      "distance_to_boundary_coeff_units": 13.0,
      "measured_coefficient": 47,
      "measured_tier": "mid",
      "name": "Anisic alcohol",
      "poucher_tier": "base",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "105-85-1",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 9,
      "measured_tier": "top",
      "name": "Citronellyl formate",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "top_mid_14_15",
      "cas": "106-22-9",
      "distance_to_boundary_coeff_units": 10.0,
      "measured_coefficient": 4,
      "measured_tier": "top",
      "name": "Citronellol",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "top_mid_14_15",
      "cas": "106-24-1",
      "distance_to_boundary_coeff_units": 8.0,
      "measured_coefficient": 6,
      "measured_tier": "top",
      "name": "Geraniol ex palmarosa",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "top_mid_14_15",
      "cas": "106-25-2",
      "distance_to_boundary_coeff_units": 9.0,
      "measured_coefficient": 5,
      "measured_tier": "top",
      "name": "Nerol",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "106-29-6",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 9,
      "measured_tier": "top",
      "name": "Geranyl butyrate",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "107-75-5",
      "distance_to_boundary_coeff_units": 19.0,
      "measured_coefficient": 80,
      "measured_tier": "base",
      "name": "Hydroxy citronellal",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "top_mid_14_15",
      "cas": "111-12-6",
      "distance_to_boundary_coeff_units": 6.0,
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Methyl heptine carbonate",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "112-14-1",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 1,
      "measured_tier": "top",
      "name": "Octyl acetate",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "112-31-2",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 100,
      "measured_tier": "base",
      "name": "Decyl aldehyde",
      "poucher_tier": "top",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "118-58-1",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Benzyl salicylate",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "top_mid_14_15",
      "cas": "122-00-9",
      "distance_to_boundary_coeff_units": 11.0,
      "measured_coefficient": 3,
      "measured_tier": "top",
      "name": "Methyl acetophenone",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "122-63-4",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 10,
      "measured_tier": "top",
      "name": "Benzyl propionate",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "124-19-6",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Nonyl aldehyde",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "126-64-7",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 9,
      "measured_tier": "top",
      "name": "Linalyl benzoate",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "1335-46-2",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 14,
      "measured_tier": "top",
      "name": "Methyl ionone",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "top_mid_14_15",
      "cas": "140-11-4",
      "distance_to_boundary_coeff_units": 13.0,
      "measured_coefficient": 1,
      "measured_tier": "top",
      "name": "Benzyl acetate",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "141-78-6",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 1,
      "measured_tier": "top",
      "name": "Ethyl acetate",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "141-97-9",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 1,
      "measured_tier": "top",
      "name": "Ethyl acetoacetate",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "144-39-8",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 5,
      "measured_tier": "top",
      "name": "Linalyl propionate",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "150-84-5",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Citronellyl acetate",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "top_mid_14_15",
      "cas": "2050-08-0",
      "distance_to_boundary_coeff_units": 6.0,
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Amyl salicylate",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "top_mid_14_15",
      "cas": "60-12-8",
      "distance_to_boundary_coeff_units": 6.0,
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Phenylethyl alcohol",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "68127-65-1",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 5,
      "measured_tier": "top",
      "name": "Rhodinol",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "near-boundary",
      "boundary_crossed": "top_mid_14_15",
      "cas": "68606-83-7",
      "distance_to_boundary_coeff_units": 0.0,
      "measured_coefficient": 14,
      "measured_tier": "top",
      "name": "Cananga",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "near-boundary",
      "boundary_crossed": "mid_base_60_61",
      "cas": "7212-44-4",
      "distance_to_boundary_coeff_units": 5.0,
      "measured_coefficient": 55,
      "measured_tier": "mid",
      "name": "Nerolidol",
      "poucher_tier": "base",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "8000-27-9",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Cedarwood",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "top_mid_14_15",
      "cas": "8000-28-0",
      "distance_to_boundary_coeff_units": 6.0,
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Lavender",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "top_mid_14_15",
      "cas": "8000-29-1",
      "distance_to_boundary_coeff_units": 6.0,
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Citronella, Ceylon",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "top_mid_14_15",
      "cas": "8000-41-7",
      "distance_to_boundary_coeff_units": 11.0,
      "measured_coefficient": 3,
      "measured_tier": "top",
      "name": "Terpineol",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "near-boundary",
      "boundary_crossed": "top_mid_14_15",
      "cas": "8000-42-8",
      "distance_to_boundary_coeff_units": 5.0,
      "measured_coefficient": 9,
      "measured_tier": "top",
      "name": "Caraway",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "8000-48-4",
      "distance_to_boundary_coeff_units": 45.0,
      "measured_coefficient": 15,
      "measured_tier": "mid",
      "name": "Eucalyptus",
      "poucher_tier": "base",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "8006-78-8",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 6,
      "measured_tier": "top",
      "name": "Bay",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "8006-84-6",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 14,
      "measured_tier": "top",
      "name": "Fennel",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "near-boundary",
      "boundary_crossed": "top_mid_14_15",
      "cas": "8006-90-4",
      "distance_to_boundary_coeff_units": 5.0,
      "measured_coefficient": 9,
      "measured_tier": "top",
      "name": "Peppermint, American",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "near-boundary",
      "boundary_crossed": "top_mid_14_15",
      "cas": "8007-02-1",
      "distance_to_boundary_coeff_units": 0.0,
      "measured_coefficient": 14,
      "measured_tier": "top",
      "name": "Lemongrass",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "top_mid_14_15",
      "cas": "8007-35-0",
      "distance_to_boundary_coeff_units": 9.0,
      "measured_coefficient": 5,
      "measured_tier": "top",
      "name": "Terpinyl acetate",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "top_mid_14_15",
      "cas": "8007-46-3",
      "distance_to_boundary_coeff_units": 8.0,
      "measured_coefficient": 6,
      "measured_tier": "top",
      "name": "Thyme white",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "top_mid_14_15",
      "cas": "8007-75-8",
      "distance_to_boundary_coeff_units": 8.0,
      "measured_coefficient": 6,
      "measured_tier": "top",
      "name": "Bergamot",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "8008-45-5",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 14,
      "measured_tier": "top",
      "name": "Nutmeg",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "top_mid_14_15",
      "cas": "8008-56-8",
      "distance_to_boundary_coeff_units": 9.0,
      "measured_coefficient": 5,
      "measured_tier": "top",
      "name": "Lemon",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "8014-09-3",
      "distance_to_boundary_coeff_units": 39.0,
      "measured_coefficient": 100,
      "measured_tier": "base",
      "name": "Patchouli",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "top_mid_14_15",
      "cas": "8014-17-3",
      "distance_to_boundary_coeff_units": 6.0,
      "measured_coefficient": 8,
      "measured_tier": "top",
      "name": "Petitgrain, French",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "8014-19-5",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 14,
      "measured_tier": "top",
      "name": "Palmarosa",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "near-boundary",
      "boundary_crossed": "mid_base_60_61",
      "cas": "8015-64-3",
      "distance_to_boundary_coeff_units": 2.0,
      "measured_coefficient": 58,
      "measured_tier": "mid",
      "name": "Angelica root",
      "poucher_tier": "base",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "8015-73-4",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 14,
      "measured_tier": "top",
      "name": "Basilic",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "8016-96-4",
      "distance_to_boundary_coeff_units": 39.0,
      "measured_coefficient": 100,
      "measured_tier": "base",
      "name": "Vetivert",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "8021-15-0",
      "distance_to_boundary_coeff_units": 8.0,
      "measured_coefficient": 52,
      "measured_tier": "mid",
      "name": "Opoponax oil",
      "poucher_tier": "base",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "near-boundary",
      "boundary_crossed": "top_mid_14_15",
      "cas": "8022-09-9",
      "distance_to_boundary_coeff_units": 5.0,
      "measured_coefficient": 9,
      "measured_tier": "top",
      "name": "Spike lavender",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "8022-62-6",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 14,
      "measured_tier": "top",
      "name": "Reseda absolute",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "near-boundary",
      "boundary_crossed": "top_mid_14_15",
      "cas": "8023-70-5",
      "distance_to_boundary_coeff_units": 4.0,
      "measured_coefficient": 10,
      "measured_tier": "top",
      "name": "Ginger",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "near-boundary",
      "boundary_crossed": "top_mid_14_15",
      "cas": "8023-82-3",
      "distance_to_boundary_coeff_units": 4.0,
      "measured_coefficient": 10,
      "measured_tier": "top",
      "name": "Myrrh oil",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "8023-87-6",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 14,
      "measured_tier": "top",
      "name": "Mimosa absolute",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "8023-91-4",
      "distance_to_boundary_coeff_units": 8.0,
      "measured_coefficient": 52,
      "measured_tier": "mid",
      "name": "Galbanum resin",
      "poucher_tier": "base",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "near-boundary",
      "boundary_crossed": "mid_base_60_61",
      "cas": "83-54-5",
      "distance_to_boundary_coeff_units": 0.0,
      "measured_coefficient": 60,
      "measured_tier": "mid",
      "name": "Rhodinyl formate",
      "poucher_tier": "base",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "9000-50-6",
      "distance_to_boundary_coeff_units": 39.0,
      "measured_coefficient": 100,
      "measured_tier": "base",
      "name": "Oakmoss",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "91-64-5",
      "distance_to_boundary_coeff_units": 39.0,
      "measured_coefficient": 100,
      "measured_tier": "base",
      "name": "Coumarin",
      "poucher_tier": "mid",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": "mid_base_60_61",
      "cas": "91771-61-8",
      "distance_to_boundary_coeff_units": 42.0,
      "measured_coefficient": 18,
      "measured_tier": "mid",
      "name": "Citronella, Java",
      "poucher_tier": "base",
      "tier_step_distance": 1
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "94-48-4",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 4,
      "measured_tier": "top",
      "name": "Geranyl benzoate",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "94-59-7",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 3,
      "measured_tier": "top",
      "name": "Sassafras",
      "poucher_tier": "base",
      "tier_step_distance": 2
    },
    {
      "agrees": false,
      "boundary_classification": "wild",
      "boundary_crossed": null,
      "cas": "98-86-2",
      "distance_to_boundary_coeff_units": null,
      "measured_coefficient": 1,
      "measured_tier": "top",
      "name": "Acetophenone",
      "poucher_tier": "base",
      "tier_step_distance": 2
    }
  ],
  "histogram": {
    "near-boundary": 12,
    "wild": 57
  },
  "histogram_by_pair": {
    "base->mid:wild": 5,
    "base->top:wild": 1,
    "mid->base:near-boundary": 4,
    "mid->base:wild": 8,
    "top->base:wild": 26,
    "top->mid:near-boundary": 8,
    "top->mid:wild": 17
  },
  "pimt_version": "v8",
  "verdict": {
    "measured_170_affected": false,
    "phase1_eval_summary": {
      "best_structure_model": "structure_full_gbm",
      "best_structure_spearman_rho": 0.6633801733693918,
      "n_model_ready": 170,
      "split": {
        "n_test": 34,
        "n_train": 136,
        "scaffold_overlap": [],
        "seed": 20260710,
        "test_scaffolds": 34,
        "train_scaffolds": 49,
        "type": "scaffold-disjoint Murcko scaffold split"
      }
    },
    "phase1_result_affected": false,
    "phase1_rho_recompute": "not_recomputed_no_measured_join_error_identified; diagnostics script does not import training/RDKit code",
    "phase1_split_screen": "local reproduction of train_substantivity.greedy_scaffold_split from saved enriched scaffold keys; avoids importing training/RDKit code in diagnostics",
    "phase1_test_wild_genuine_or_form_cas": [
      "106-29-6",
      "112-14-1",
      "118-58-1",
      "141-78-6",
      "141-97-9",
      "8000-29-1",
      "8000-41-7",
      "8007-46-3",
      "8008-45-5",
      "8014-09-3",
      "8014-17-3"
    ],
    "rationale": "Wild disagreements are not mostly join-errors. Local evidence points primarily to genuine source/construct disagreement between measured duration coefficients and profile role tiers; measured coefficients remain the rigorous Phase 1 target because they do not depend on auxiliary tiers.",
    "tier_fold_verdict": "DO_NOT_FOLD_DISAGREEING_TIERS; only near-boundary-consistent rows or future join-corrected rows may be considered as poucher-tier provenance."
  },
  "wild_case_causes": [
    {
      "cas": "100-52-7",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 1,
      "measured_names": [
        "Almonds",
        "Benzaldehyde"
      ],
      "measured_tier": "top",
      "name": "Almonds",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "101-84-8",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 10,
      "measured_names": [
        "Diphenyl oxide"
      ],
      "measured_tier": "top",
      "name": "Diphenyl oxide",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "103-45-7",
      "cause": "join-error",
      "evidence": [
        "Per-wild-case audit found local identity evidence for alias fragmentation, CAS conflation, or variant collision."
      ],
      "measured_coefficient": 1,
      "measured_names": [
        "Phenylethyl acetate"
      ],
      "measured_tier": "top",
      "name": "Phenylethyl acetate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "103-48-0",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 19,
      "measured_names": [
        "Phenylethyl iso-butyrate"
      ],
      "measured_tier": "mid",
      "name": "Phenylethyl iso-butyrate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "103-61-7",
      "cause": "unresolved-needs-manual-review",
      "evidence": [
        "Per-wild-case audit found insufficient local identity/source-name evidence for a stronger assignment."
      ],
      "measured_coefficient": 28,
      "measured_names": [
        "Cinnamyl butyrate"
      ],
      "measured_tier": "mid",
      "name": "Cinnamyl butyrate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "104-65-4",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 18,
      "measured_names": [
        "Cinnamyl formate"
      ],
      "measured_tier": "mid",
      "name": "Cinnamyl formate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "105-13-5",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 47,
      "measured_names": [
        "Anisic alcohol"
      ],
      "measured_tier": "mid",
      "name": "Anisic alcohol",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "105-85-1",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 9,
      "measured_names": [
        "Citronellyl formate"
      ],
      "measured_tier": "top",
      "name": "Citronellyl formate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "106-22-9",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 4,
      "measured_names": [
        "Citronellol"
      ],
      "measured_tier": "top",
      "name": "Citronellol",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "106-24-1",
      "cause": "form-mismatch",
      "evidence": [
        "Per-wild-case audit found source names comparing natural/geographic/material forms rather than one clean material form.",
        "measured extraction records a coefficient conflict, but the per-case audit classification above is retained."
      ],
      "measured_coefficient": 6,
      "measured_names": [
        "Geraniol ex palmarosa",
        "Geraniol, Java"
      ],
      "measured_tier": "top",
      "name": "Geraniol ex palmarosa",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "106-25-2",
      "cause": "join-error",
      "evidence": [
        "Per-wild-case audit found local identity evidence for alias fragmentation, CAS conflation, or variant collision.",
        "measured extraction records a coefficient conflict, but the per-case audit classification above is retained."
      ],
      "measured_coefficient": 5,
      "measured_names": [
        "Nerol",
        "Neroli bigarade",
        "Neroli, Italian"
      ],
      "measured_tier": "top",
      "name": "Nerol",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "106-29-6",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 9,
      "measured_names": [
        "Geranyl butyrate"
      ],
      "measured_tier": "top",
      "name": "Geranyl butyrate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "107-75-5",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 80,
      "measured_names": [
        "Hydroxy citronellal"
      ],
      "measured_tier": "base",
      "name": "Hydroxy citronellal",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "111-12-6",
      "cause": "join-error",
      "evidence": [
        "Per-wild-case audit found local identity evidence for alias fragmentation, CAS conflation, or variant collision.",
        "measured extraction records a coefficient conflict, but the per-case audit classification above is retained."
      ],
      "measured_coefficient": 8,
      "measured_names": [
        "Methyl heptine carbonate",
        "Methyl octine carbonate"
      ],
      "measured_tier": "top",
      "name": "Methyl heptine carbonate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "112-14-1",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 1,
      "measured_names": [
        "Octyl acetate"
      ],
      "measured_tier": "top",
      "name": "Octyl acetate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "112-31-2",
      "cause": "unresolved-needs-manual-review",
      "evidence": [
        "Per-wild-case audit found insufficient local identity/source-name evidence for a stronger assignment."
      ],
      "measured_coefficient": 100,
      "measured_names": [
        "Decyl aldehyde"
      ],
      "measured_tier": "base",
      "name": "Decyl aldehyde",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "top"
    },
    {
      "cas": "118-58-1",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 8,
      "measured_names": [
        "Benzyl salicylate"
      ],
      "measured_tier": "top",
      "name": "Benzyl salicylate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "122-00-9",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 3,
      "measured_names": [
        "Methyl acetophenone"
      ],
      "measured_tier": "top",
      "name": "Methyl acetophenone",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "122-63-4",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 10,
      "measured_names": [
        "Benzyl propionate"
      ],
      "measured_tier": "top",
      "name": "Benzyl propionate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "124-19-6",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 8,
      "measured_names": [
        "Nonyl aldehyde"
      ],
      "measured_tier": "top",
      "name": "Nonyl aldehyde",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "126-64-7",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 9,
      "measured_names": [
        "Linalyl benzoate"
      ],
      "measured_tier": "top",
      "name": "Linalyl benzoate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "1335-46-2",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 14,
      "measured_names": [
        "Methyl ionone"
      ],
      "measured_tier": "top",
      "name": "Methyl ionone",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "140-11-4",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 1,
      "measured_names": [
        "Benzyl acetate"
      ],
      "measured_tier": "top",
      "name": "Benzyl acetate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "141-78-6",
      "cause": "unresolved-needs-manual-review",
      "evidence": [
        "Per-wild-case audit found insufficient local identity/source-name evidence for a stronger assignment."
      ],
      "measured_coefficient": 1,
      "measured_names": [
        "Ethyl acetate"
      ],
      "measured_tier": "top",
      "name": "Ethyl acetate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "141-97-9",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 1,
      "measured_names": [
        "Ethyl acetoacetate"
      ],
      "measured_tier": "top",
      "name": "Ethyl acetoacetate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "144-39-8",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 5,
      "measured_names": [
        "Linalyl propionate"
      ],
      "measured_tier": "top",
      "name": "Linalyl propionate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "150-84-5",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 8,
      "measured_names": [
        "Citronellyl acetate"
      ],
      "measured_tier": "top",
      "name": "Citronellyl acetate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "2050-08-0",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 8,
      "measured_names": [
        "Amyl salicylate"
      ],
      "measured_tier": "top",
      "name": "Amyl salicylate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "60-12-8",
      "cause": "join-error",
      "evidence": [
        "Per-wild-case audit found local identity evidence for alias fragmentation, CAS conflation, or variant collision."
      ],
      "measured_coefficient": 8,
      "measured_names": [
        "Phenylethyl alcohol"
      ],
      "measured_tier": "top",
      "name": "Phenylethyl alcohol",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "68127-65-1",
      "cause": "join-error",
      "evidence": [
        "Per-wild-case audit found local identity evidence for alias fragmentation, CAS conflation, or variant collision."
      ],
      "measured_coefficient": 5,
      "measured_names": [
        "Rhodinol"
      ],
      "measured_tier": "top",
      "name": "Rhodinol",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "8000-27-9",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement."
      ],
      "measured_coefficient": 8,
      "measured_names": [
        "Cedarwood"
      ],
      "measured_tier": "top",
      "name": "Cedarwood",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "8000-28-0",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement."
      ],
      "measured_coefficient": 8,
      "measured_names": [
        "Lavender"
      ],
      "measured_tier": "top",
      "name": "Lavender",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "8000-29-1",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement."
      ],
      "measured_coefficient": 8,
      "measured_names": [
        "Citronella, Ceylon"
      ],
      "measured_tier": "top",
      "name": "Citronella, Ceylon",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "8000-41-7",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 3,
      "measured_names": [
        "Terpineol"
      ],
      "measured_tier": "top",
      "name": "Terpineol",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "8000-48-4",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement.",
        "measured extraction records a coefficient conflict, but the per-case audit classification above is retained."
      ],
      "measured_coefficient": 15,
      "measured_names": [
        "Eucalyptus",
        "Eucalyptus citriodora"
      ],
      "measured_tier": "mid",
      "name": "Eucalyptus",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "8006-78-8",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement."
      ],
      "measured_coefficient": 6,
      "measured_names": [
        "Bay"
      ],
      "measured_tier": "top",
      "name": "Bay",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "8006-84-6",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement."
      ],
      "measured_coefficient": 14,
      "measured_names": [
        "Fennel"
      ],
      "measured_tier": "top",
      "name": "Fennel",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "8007-35-0",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 5,
      "measured_names": [
        "Terpinyl acetate"
      ],
      "measured_tier": "top",
      "name": "Terpinyl acetate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "8007-46-3",
      "cause": "form-mismatch",
      "evidence": [
        "Per-wild-case audit found source names comparing natural/geographic/material forms rather than one clean material form.",
        "measured extraction records a coefficient conflict, but the per-case audit classification above is retained."
      ],
      "measured_coefficient": 6,
      "measured_names": [
        "Thyme red",
        "Thyme white"
      ],
      "measured_tier": "top",
      "name": "Thyme white",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "8007-75-8",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement."
      ],
      "measured_coefficient": 6,
      "measured_names": [
        "Bergamot"
      ],
      "measured_tier": "top",
      "name": "Bergamot",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "8008-45-5",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement."
      ],
      "measured_coefficient": 14,
      "measured_names": [
        "Nutmeg"
      ],
      "measured_tier": "top",
      "name": "Nutmeg",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "8008-56-8",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement."
      ],
      "measured_coefficient": 5,
      "measured_names": [
        "Lemon"
      ],
      "measured_tier": "top",
      "name": "Lemon",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "8014-09-3",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement."
      ],
      "measured_coefficient": 100,
      "measured_names": [
        "Patchouli"
      ],
      "measured_tier": "base",
      "name": "Patchouli",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "8014-17-3",
      "cause": "form-mismatch",
      "evidence": [
        "Per-wild-case audit found source names comparing natural/geographic/material forms rather than one clean material form.",
        "measured extraction records a coefficient conflict, but the per-case audit classification above is retained."
      ],
      "measured_coefficient": 8,
      "measured_names": [
        "Petitgrain para",
        "Petitgrain, French"
      ],
      "measured_tier": "top",
      "name": "Petitgrain, French",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "8014-19-5",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement."
      ],
      "measured_coefficient": 14,
      "measured_names": [
        "Palmarosa"
      ],
      "measured_tier": "top",
      "name": "Palmarosa",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "8015-73-4",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 14,
      "measured_names": [
        "Basilic"
      ],
      "measured_tier": "top",
      "name": "Basilic",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "8016-96-4",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement."
      ],
      "measured_coefficient": 100,
      "measured_names": [
        "Vetivert"
      ],
      "measured_tier": "base",
      "name": "Vetivert",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "8021-15-0",
      "cause": "form-mismatch",
      "evidence": [
        "Per-wild-case audit found source names comparing natural/geographic/material forms rather than one clean material form.",
        "measured extraction records a coefficient conflict, but the per-case audit classification above is retained."
      ],
      "measured_coefficient": 52,
      "measured_names": [
        "Opoponax oil",
        "Opoponax resin"
      ],
      "measured_tier": "mid",
      "name": "Opoponax oil",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "8022-62-6",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement."
      ],
      "measured_coefficient": 14,
      "measured_names": [
        "Reseda absolute"
      ],
      "measured_tier": "top",
      "name": "Reseda absolute",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "8023-87-6",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement."
      ],
      "measured_coefficient": 14,
      "measured_names": [
        "Mimosa absolute"
      ],
      "measured_tier": "top",
      "name": "Mimosa absolute",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "8023-91-4",
      "cause": "form-mismatch",
      "evidence": [
        "Per-wild-case audit found source names comparing natural/geographic/material forms rather than one clean material form.",
        "measured extraction records a coefficient conflict, but the per-case audit classification above is retained."
      ],
      "measured_coefficient": 52,
      "measured_names": [
        "Galbanum oil",
        "Galbanum resin"
      ],
      "measured_tier": "mid",
      "name": "Galbanum resin",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "9000-50-6",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement."
      ],
      "measured_coefficient": 100,
      "measured_names": [
        "Oakmoss"
      ],
      "measured_tier": "base",
      "name": "Oakmoss",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "91-64-5",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 100,
      "measured_names": [
        "Coumarin"
      ],
      "measured_tier": "base",
      "name": "Coumarin",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "mid"
    },
    {
      "cas": "91771-61-8",
      "cause": "form-mismatch",
      "evidence": [
        "Per-wild-case audit found source names comparing natural/geographic/material forms rather than one clean material form."
      ],
      "measured_coefficient": 18,
      "measured_names": [
        "Citronella, Java"
      ],
      "measured_tier": "mid",
      "name": "Citronella, Java",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "94-48-4",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 4,
      "measured_names": [
        "Geranyl benzoate"
      ],
      "measured_tier": "top",
      "name": "Geranyl benzoate",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "94-59-7",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement."
      ],
      "measured_coefficient": 3,
      "measured_names": [
        "Sassafras"
      ],
      "measured_tier": "top",
      "name": "Sassafras",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    },
    {
      "cas": "98-86-2",
      "cause": "genuine-source-disagreement",
      "evidence": [
        "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier."
      ],
      "measured_coefficient": 1,
      "measured_names": [
        "Acetophenone"
      ],
      "measured_tier": "top",
      "name": "Acetophenone",
      "policy": "identity/form audit only; no odour character inferred",
      "poucher_tier": "base"
    }
  ],
  "wild_cause_counts": {
    "form-mismatch": 6,
    "genuine-source-disagreement": 43,
    "join-error": 5,
    "unresolved-needs-manual-review": 3
  }
}