{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.45, "construct": {"method_text_verbatim": "The present invention relates to the field of perfumery. In particular, the compositions of the present invention have improved or enhanced fidelity and/or longevity of the fragrance profile, which is achieved by adding a specific sucrose based fragrance modulator as defined in the appended claims. Fragrance modulators do already exist, see e.g. [EP 1 186 289 A2](https://patents.google.com/patent/EP1186289A2) (TAKASAGO PERFUMERY CO LTD \\[JP\\]) 13 March 2002 (2002-03-13).", "panel_size": null, "property_name": "longevity", "scale": "numeric_unknown", "substrate": null, "time_points": null}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "2002-03", "patent_id": "EP3307393B1", "provenance": {"citation": "EP3307393B1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3307393B1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:204", "units": null, "verbatim_quote": "The present invention relates to the field of perfumery. In particular, the compositions of the present invention have improved or enhanced fidelity and/or longevity of the fragrance profile, which is achieved by adding a specific sucrose based fragrance modulator as defined in the appended claims. Fragrance modulators do already exist, see e.g. [EP 1 186 289 A2](https://patents.google.com/patent/EP1186289A2) (TAKASAGO PERFUMERY CO LTD \\[JP\\]) 13 March 2002 (2002-03-13)."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.6, "construct": {"method_text_verbatim": "Previous attempts to overcome these problems have been through the use of various \"fixatives\" or \"modulators\" to retard the evaporation of the more volatile fragrance ingredients present in fragrance compositions. For instance, [U.S. Patent No. 4,313,855](https://patents.google.com/patent/US4313855) (Dragoco) describes the use in cosmetic compositions of 1-(2,6,6-trimethylcyclohexyl)-hexane-3-ol as an odourless fixative for increasing the perfume's intensity. [U.S. Patent No. 6,147,049](https://patents.google.com/patent/US6147049) (Givaudan) discloses a perfume fixative derived from tera-hydronaphthalenese for use in a wide range of fragrance compositions. [U.S. Patent No. 6,440,400B1](https://patents.google.com/patent/US6440400) (Takasago Perfumery) describes a composition using trimethylcyclohexane derivatives as perfuming-holding agents and melanin-formation inhibitors. [U.S. Patent No. 6,737,396B2](https://patents.google.com/patent/US6737396) (Firmenich) describes a perfume composi", "panel_size": null, "property_name": "persistence", "scale": "percent", "substrate": ["skin"], "time_points": null}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "2-30; 61-083114; 61-063612; 62-084010; 2014/090959; 2003/228334", "patent_id": "EP3307393B1", "provenance": {"citation": "EP3307393B1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3307393B1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:213", "units": "ordinal_ratio", "verbatim_quote": "Previous attempts to overcome these problems have been through the use of various \"fixatives\" or \"modulators\" to retard the evaporation of the more volatile fragrance ingredients present in fragrance compositions. For instance, [U.S. Patent No. 4,313,855](https://patents.google.com/patent/US4313855) (Dragoco) describes the use in cosmetic compositions of 1-(2,6,6-trimethylcyclohexyl)-hexane-3-ol as an odourless fixative for increasing the perfume's intensity. [U.S. Patent No. 6,147,049](https://patents.google.com/patent/US6147049) (Givaudan) discloses a perfume fixative derived from tera-hydronaphthalenese for use in a wide range of fragrance compositions. [U.S. Patent No. 6,440,400B1](https://patents.google.com/patent/US6440400) (Takasago Perfumery) describes a composition using trimethylcyclohexane derivatives as perfuming-holding agents and melanin-formation inhibitors. [U.S. Patent No. 6,737,396B2](https://patents.google.com/patent/US6737396) (Firmenich) describes a perfume composition formed by mixing 2-30%, relative to the weight of the composition, of a fixative, (1-ethoxyethoxy)cyclododecane, to fix or exalt the musky or aromatic-type notes. [U.S. Patent No. 7,538,081](https://patents.google.com/patent/US7538081) (Takasago Perfumery) approaches the same problem of fixing a perfume and/or extending the perfume release from a fragrance composition. More particularly, said document describes the use of L-menthoxy ether derivatives as fixatives in fragrance compositions comprising at least one note selected from: floral, citrus, fruity, green, mint, herb and marine. JP Patent No. 61-083114 (Kanebo) describes ether derivatives as aroma-preserving agent for fine perfume composition. JP Patent No. 61-063612 (Kanebo) discloses diethylene glycol ether derivatives as fragrance adjusting agent showing effects as a fixative and a solubilizer. JP Patent No. 62-084010 (Shiseido) describes hydroquinone glycoside as perfume fixatives applicable for all kinds of perfume and blended perfume. On the other hand, PCT Publication No. WO85/04803 (Diagnostica) describes the use of hyaluronic acid/ hyaluronate as fixatives ( _via_ molecular encapsulation) in fragrance products to improve persistence of the fragrance. EP 1 186 289 describes fragrance compositions having excellent diffusivity and a long-lasting effect by incorporating a novel fixative in the composition, wherein the fixative is a 2-(L-menthoxy)alkanol derivative. EP 1 103 250 describes oil-in-polyhydric-alcohol type warming base agents containing a polyhydric alcohol, a sucrose fatty acid ester and an oil, having superior makeup removal effect, safety, stability and warming sensation. [WO 2014/090959](https://patents.google.com/patent/WO2014090959) discloses perfuming compositions that are free of ethanol in the form of transparent, clear microemulsions containing a fragrance, a solvent, non-ionic and ionic surfactants, a cooling hydrotrope and water. [US 2003/228334](https://patents.google.com/patent/US20030228334) relates to oil-in-water emulsions having a mattifying effect on the skin. The emulsions comprise a hydrophilic, non-organically modified magnesium aluminum silicate or a bentonite clay and a polyol in the water phase; and a volatile lipophilic solvent and a high melting point lipophilic plasticizer in the oil phase; and a surfactant system incuding non-toxic metal alkyl sulfates and/or sucrose esters. [DE 197 18 777](https://patents.google.com/patent/DE19718777) discloses the use of one or more di- or oligo-saccharide fatty acid esters as anti-adhesive agents against microorganisms, viruses, parasites and protozoa."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.45, "construct": {"method_text_verbatim": "The inventors have surprisingly discovered a revolutionary new way of objectively classifying fragrance materials and then formulating those fragrance materials into complex fragrance mixtures having improved fragrance profile fidelity and longevity. Essentially, the solution is to formulate the fragrance materials having low levels (10 to 30 wt% relative to the total weight of the fragrance materials) of the low volatile fragrance materials in the presence of a substantially non-odorous fragrance modulator to provide for improved or enhanced longevity and/or fidelity of the fragrance profile, particularly amongst characters attributable to volatile fragrance materials. In fact, the inventors have discovered that in the complete absence of the low volatile fragrance materials or at very low levels of the low volatile fragrance materials (less than 10 wt% relative to the total weight of the fragrance materials), there is insufficient character complexity and roundness of the fragrance p", "panel_size": null, "property_name": "longevity", "scale": "percent", "substrate": null, "time_points": null}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "10 to 30", "patent_id": "EP3307393B1", "provenance": {"citation": "EP3307393B1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3307393B1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:240", "units": null, "verbatim_quote": "The inventors have surprisingly discovered a revolutionary new way of objectively classifying fragrance materials and then formulating those fragrance materials into complex fragrance mixtures having improved fragrance profile fidelity and longevity. Essentially, the solution is to formulate the fragrance materials having low levels (10 to 30 wt% relative to the total weight of the fragrance materials) of the low volatile fragrance materials in the presence of a substantially non-odorous fragrance modulator to provide for improved or enhanced longevity and/or fidelity of the fragrance profile, particularly amongst characters attributable to volatile fragrance materials. In fact, the inventors have discovered that in the complete absence of the low volatile fragrance materials or at very low levels of the low volatile fragrance materials (less than 10 wt% relative to the total weight of the fragrance materials), there is insufficient character complexity and roundness of the fragrance profile for consumer acceptance of the composition. Therefore the level of low volatile fragrance materials needs to be carefully chosen between 10 and 30 wt% to balance consumer acceptance and the desired improved or enhanced longevity and/or fidelity of the fragrance profile, particularly amongst characters attributable to volatile fragrance materials."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.7, "construct": {"method_text_verbatim": "At the testing facility, 50 \u00b5L samples of the compositions and the controls are applied to glass slides and placed on a hot plate at 32 \u00b0C to represent skin temperature for varying durations. It is important that glass slides of samples that are to be later compared are prepared at the same time. The panelists are asked to evaluate the perceived fragrance profile (intensity and/or character) of each glass slide sample at a given time point. Slides are presented coded so that their identity is not known by the panelists. Within a given time point panelists evaluate the slides in a random order and are able to revisit their assessment as they work through the slides at that time point. Their assessments are recorded. In the subsequent analysis, the data for strength and character comparisons are drawn from the independent assessments carried out at a given time point. Only when using the character difference scale below are any 2 products physically directly compared to each other. Panel", "panel_size": null, "property_name": "duration", "scale": "numeric_unknown", "substrate": ["skin"], "time_points": null}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "6 to 10", "patent_id": "EP3307393B1", "provenance": {"citation": "EP3307393B1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3307393B1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:336", "units": null, "verbatim_quote": "At the testing facility, 50 \u00b5L samples of the compositions and the controls are applied to glass slides and placed on a hot plate at 32 \u00b0C to represent skin temperature for varying durations. It is important that glass slides of samples that are to be later compared are prepared at the same time. The panelists are asked to evaluate the perceived fragrance profile (intensity and/or character) of each glass slide sample at a given time point. Slides are presented coded so that their identity is not known by the panelists. Within a given time point panelists evaluate the slides in a random order and are able to revisit their assessment as they work through the slides at that time point. Their assessments are recorded. In the subsequent analysis, the data for strength and character comparisons are drawn from the independent assessments carried out at a given time point. Only when using the character difference scale below are any 2 products physically directly compared to each other. Panelists are selected from individuals who are either trained to evaluate fragrances according to the scales below or who have experience with fragrance evaluation in the industry. Typically, around 6 to 10 panellists are used to evaluate a given product and its control."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.55, "construct": {"method_text_verbatim": "The panelists are asked to give a score on a scale of 0 to 5 for perceived fragrance intensity according to the odour intensity scale set out in Table 4 herein below. Table 4 - Odour Intensity Scale", "panel_size": null, "property_name": "fragrance_intensity", "scale": "numeric_unknown", "substrate": null, "time_points": null}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "0 to 5", "patent_id": "EP3307393B1", "provenance": {"citation": "EP3307393B1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3307393B1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:338", "units": null, "verbatim_quote": "The panelists are asked to give a score on a scale of 0 to 5 for perceived fragrance intensity according to the odour intensity scale set out in Table 4 herein below. Table 4 - Odour Intensity Scale"}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": "example 10", "confidence": 0.9, "construct": {"method_text_verbatim": "5\\. Multiple glass capillaries are prepared in the same way and left to evaporate at ambient temperature for pre-determined periods of time, such as for example 10, 15, 30 mins, 1 hr, 2 hrs, 3 hrs, 4 hrs, 5 hrs, and up to 6 hrs, before being introduced to the headspace vial and sealed.", "panel_size": null, "property_name": "headspace_concentration_or_intensity", "scale": "hours_or_timepoint", "substrate": ["headspace"], "time_points": ["1 hr", "2 hrs", "3 hrs", "4 hrs", "5 hrs", "6 hrs"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "1 hr; 2 hrs; 3 hrs; 4 hrs; 5 hrs; 6 hrs", "patent_id": "EP3307393B1", "provenance": {"citation": "EP3307393B1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3307393B1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:366", "units": "hours", "verbatim_quote": "5\\. Multiple glass capillaries are prepared in the same way and left to evaporate at ambient temperature for pre-determined periods of time, such as for example 10, 15, 30 mins, 1 hr, 2 hrs, 3 hrs, 4 hrs, 5 hrs, and up to 6 hrs, before being introduced to the headspace vial and sealed."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.7, "construct": {"method_text_verbatim": "Compositions disclosed in Tables 18(a) and 19(a)-19(b) are applied to glass slides in accordance with the protocol described in the Method Section and a panel of around 6-10 experienced panelists evaluate the perceived fragrance profile at initial time 0, then at various time points, typically 1 hour, 2 hours, 3 hours, 4 hours and 6 hours post application. Panelists are asked to score the compositions for the longevity of the fragrance profile on a scale of 0 to 5, wherein 0 represents a no fragrance is detected and 5 represents a very strong fragrance intensity is detected; and for fragrance profile fidelity on a scale of 0 to 3 wherein 0 represents not detectable and 3 represents it being the dominant character. The results of the panelists are then averaged and discussed below.", "panel_size": null, "property_name": "fragrance_intensity", "scale": "hours_or_timepoint", "substrate": null, "time_points": ["1 hour", "2 hours", "3 hours", "4 hours", "6 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "6-10; 1 hour; 2 hours; 3 hours; 4 hours; 6 hours; 0 to 5; 0 to 3", "patent_id": "EP3307393B1", "provenance": {"citation": "EP3307393B1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3307393B1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:440", "units": "hours", "verbatim_quote": "Compositions disclosed in Tables 18(a) and 19(a)-19(b) are applied to glass slides in accordance with the protocol described in the Method Section and a panel of around 6-10 experienced panelists evaluate the perceived fragrance profile at initial time 0, then at various time points, typically 1 hour, 2 hours, 3 hours, 4 hours and 6 hours post application. Panelists are asked to score the compositions for the longevity of the fragrance profile on a scale of 0 to 5, wherein 0 represents a no fragrance is detected and 5 represents a very strong fragrance intensity is detected; and for fragrance profile fidelity on a scale of 0 to 3 wherein 0 represents not detectable and 3 represents it being the dominant character. The results of the panelists are then averaged and discussed below."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.7, "construct": {"method_text_verbatim": "Figure 1 shows the fragrance intensity profile of Composition R as evaluated by 10 panelists, which comprises the substantially non-odorous fragrance modulator sucrose myristate and the single fragrance material, ethyl safranate. Addition of the substantially non-odorous fragrance modulator maintains the intensity of the fragrance material for up to 6 hours whilst the control, Composition S, in the absence of the substantially non-odorous fragrance modulator, drops in fragrance intensity profile over the 6 hours. The substantially non-odorous fragrance modulator acts to maintain the continued evaporation over time of the fragrance material. Statistical analysis using the Tukey correction for multiple comparisons confirms the statistically significant difference at 0 hours (p = 0.0015), 1hour (p = 0.0033), 3hours (p = 0.0015) and 6 hours ((p = 0.0152) all at 95% significance level ( _i.e.,_ p < 0.05).", "panel_size": 10, "property_name": "fragrance_intensity", "scale": "percent", "substrate": null, "time_points": ["6 hours", "0 hours", "1hour", "3hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "6 hours; 0 hours; 1hour; 3hours", "patent_id": "EP3307393B1", "provenance": {"citation": "EP3307393B1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3307393B1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:442", "units": "hours", "verbatim_quote": "Figure 1 shows the fragrance intensity profile of Composition R as evaluated by 10 panelists, which comprises the substantially non-odorous fragrance modulator sucrose myristate and the single fragrance material, ethyl safranate. Addition of the substantially non-odorous fragrance modulator maintains the intensity of the fragrance material for up to 6 hours whilst the control, Composition S, in the absence of the substantially non-odorous fragrance modulator, drops in fragrance intensity profile over the 6 hours. The substantially non-odorous fragrance modulator acts to maintain the continued evaporation over time of the fragrance material. Statistical analysis using the Tukey correction for multiple comparisons confirms the statistically significant difference at 0 hours (p = 0.0015), 1hour (p = 0.0033), 3hours (p = 0.0015) and 6 hours ((p = 0.0152) all at 95% significance level ( _i.e.,_ p < 0.05)."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.7, "construct": {"method_text_verbatim": "Figure 2 shows the fragrance intensity profile of Composition P as evaluated by 10 panellists, which comprises the substantially non-odorous fragrance modulator sucrose myristate and the single fragrance material, Dimethylbenzyl carbinol. Addition of the substantially non-odorous fragrance modulator maintains the intensity of the fragrance material for up to 6 hours whilst the control, Composition Q, in the absence of the substantially non-odorous fragrance modulator, drops in fragrance intensity profile over the 6 hours. The substantially non-odorous fragrance modulator acts to maintain the continued evaporation over time of the fragrance material. Statistical analysis using the Tukey correction for multiple comparisons confirms the statistically significant difference at 1hour (p = 0.0581) at 90% significance level ( _i.e.,_ p < 0.1), 3hours (p = 0.0311) at 95% significance level ( _i.e.,_ p < 0.05).", "panel_size": null, "property_name": "fragrance_intensity", "scale": "percent", "substrate": null, "time_points": ["6 hours", "1hour", "3hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "6 hours; 1hour; 3hours", "patent_id": "EP3307393B1", "provenance": {"citation": "EP3307393B1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3307393B1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:443", "units": "hours", "verbatim_quote": "Figure 2 shows the fragrance intensity profile of Composition P as evaluated by 10 panellists, which comprises the substantially non-odorous fragrance modulator sucrose myristate and the single fragrance material, Dimethylbenzyl carbinol. Addition of the substantially non-odorous fragrance modulator maintains the intensity of the fragrance material for up to 6 hours whilst the control, Composition Q, in the absence of the substantially non-odorous fragrance modulator, drops in fragrance intensity profile over the 6 hours. The substantially non-odorous fragrance modulator acts to maintain the continued evaporation over time of the fragrance material. Statistical analysis using the Tukey correction for multiple comparisons confirms the statistically significant difference at 1hour (p = 0.0581) at 90% significance level ( _i.e.,_ p < 0.1), 3hours (p = 0.0311) at 95% significance level ( _i.e.,_ p < 0.05)."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.7, "construct": {"method_text_verbatim": "Figure 3 shows the fragrance intensity profile of Composition T as evaluated by 10 panelists, which comprises the substantially non-odorous fragrance modulator sucrose myristate and the single fragrance material phenethyl alcohol (PEA). Addition of the substantially non-odorous fragrance modulator maintains the intensity of the fragrance material for up to 6 hours whilst the control, Composition U, in the absence of the substantially non-odorous fragrance modulator, drops in fragrance intensity profile over the 6 hours. The substantially non-odorous fragrance modulator acts to maintain the continued evaporation over time of the fragrance material. Statistical analysis using the Tukey correction for multiple comparisons confirms the statistically significant difference at 1 hour (p < 0.0001), 3 hours (p = 0.0016) and 6 hours (p= 0.0003) all at 95% significance level ( _i.e.,_ p < 0.05).", "panel_size": 10, "property_name": "fragrance_intensity", "scale": "percent", "substrate": null, "time_points": ["6 hours", "1 hour", "3 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "6 hours; 1 hour; 3 hours", "patent_id": "EP3307393B1", "provenance": {"citation": "EP3307393B1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3307393B1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:444", "units": "hours", "verbatim_quote": "Figure 3 shows the fragrance intensity profile of Composition T as evaluated by 10 panelists, which comprises the substantially non-odorous fragrance modulator sucrose myristate and the single fragrance material phenethyl alcohol (PEA). Addition of the substantially non-odorous fragrance modulator maintains the intensity of the fragrance material for up to 6 hours whilst the control, Composition U, in the absence of the substantially non-odorous fragrance modulator, drops in fragrance intensity profile over the 6 hours. The substantially non-odorous fragrance modulator acts to maintain the continued evaporation over time of the fragrance material. Statistical analysis using the Tukey correction for multiple comparisons confirms the statistically significant difference at 1 hour (p < 0.0001), 3 hours (p = 0.0016) and 6 hours (p= 0.0003) all at 95% significance level ( _i.e.,_ p < 0.05)."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.7, "construct": {"method_text_verbatim": "Figure 4 shows the fragrance intensity profile of Composition ZZ as evaluated by 11 panelists, which comprises the substantially non-odorous fragrance modulator hydroquinone beta-D-glycoside and the single fragrance material, eugenol. Addition of the substantially non-odorous modulator maintains the intensity of the fragrance material for up to 6 hours whilst the control, Composition ZZZ, in the absence of the substantially non-odorous fragrance modulator, drops in fragrance intensity profile over the 6 hours. The substantially non-odorous fragrance modulator acts to maintain the continued evaporation over time of the fragrance material. Statistical analysis using the Tukey correction for multiple comparisons confirms the statistically significant difference at 1 hour (p = 0.0008) and 3 hours (p = 0.0123) all at 95% significance level ( _i.e.,_ p < 0.05).", "panel_size": 11, "property_name": "fragrance_intensity", "scale": "percent", "substrate": null, "time_points": ["6 hours", "1 hour", "3 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "6 hours; 1 hour; 3 hours", "patent_id": "EP3307393B1", "provenance": {"citation": "EP3307393B1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3307393B1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:445", "units": "hours", "verbatim_quote": "Figure 4 shows the fragrance intensity profile of Composition ZZ as evaluated by 11 panelists, which comprises the substantially non-odorous fragrance modulator hydroquinone beta-D-glycoside and the single fragrance material, eugenol. Addition of the substantially non-odorous modulator maintains the intensity of the fragrance material for up to 6 hours whilst the control, Composition ZZZ, in the absence of the substantially non-odorous fragrance modulator, drops in fragrance intensity profile over the 6 hours. The substantially non-odorous fragrance modulator acts to maintain the continued evaporation over time of the fragrance material. Statistical analysis using the Tukey correction for multiple comparisons confirms the statistically significant difference at 1 hour (p = 0.0008) and 3 hours (p = 0.0123) all at 95% significance level ( _i.e.,_ p < 0.05)."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.45, "construct": {"method_text_verbatim": "(b) Effects of the Substantially Non-Odorous Fragrance Modulators on the Fragrance Profile Longevity of Compositions having Reduced Levels of Low Volatile Fragrance Materials (between 10 to 30 wt% relative to the total weight of the Fragrance Materials) vs. Compositions having Traditional Levels of Low Volatile Fragrance Materials (Greater than 30 wt% relative to the total weight of the Fragrance Materials) and No Substantially Non-Odorous Fragrance Modulator- \\[0119\\]", "panel_size": null, "property_name": "longevity", "scale": "percent", "substrate": null, "time_points": null}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "10 to 30", "patent_id": "EP3307393B1", "provenance": {"citation": "EP3307393B1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3307393B1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:446", "units": null, "verbatim_quote": "(b) Effects of the Substantially Non-Odorous Fragrance Modulators on the Fragrance Profile Longevity of Compositions having Reduced Levels of Low Volatile Fragrance Materials (between 10 to 30 wt% relative to the total weight of the Fragrance Materials) vs. Compositions having Traditional Levels of Low Volatile Fragrance Materials (Greater than 30 wt% relative to the total weight of the Fragrance Materials) and No Substantially Non-Odorous Fragrance Modulator- \\[0119\\]"}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.55, "construct": {"method_text_verbatim": "Panelists are asked to score the compositions for the intensity of the fragrance on a scale of 0 to 5, wherein 0 represents no fragrance intensity is detected and 5 represents a very strong fragrance intensity is detected. The results of the panel test are then averaged. The results show the effect of the substantially non-odorous fragrance modulator and reduced levels of low volatile fragrance materials for any one of the inventive Compositions A, D, G, J and M on fragrance profile longevity versus control Compositions C, F, I, L and O in the absence of a substantially non-odorous modulator. Alternatively, the results show the effect of the substantially non-odorous fragrance modulator and reduced levels of low volatile fragrance materials for any one of the inventive Compositions A, D, G, J and M on fragrance profile longevity versus traditional Compositions B, E, H, K and N in the presence of the substantially non-odorous fragrance modulator.", "panel_size": null, "property_name": "fragrance_intensity", "scale": "hours_or_timepoint", "substrate": null, "time_points": null}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "0 to 5", "patent_id": "EP3307393B1", "provenance": {"citation": "EP3307393B1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3307393B1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:447", "units": null, "verbatim_quote": "Panelists are asked to score the compositions for the intensity of the fragrance on a scale of 0 to 5, wherein 0 represents no fragrance intensity is detected and 5 represents a very strong fragrance intensity is detected. The results of the panel test are then averaged. The results show the effect of the substantially non-odorous fragrance modulator and reduced levels of low volatile fragrance materials for any one of the inventive Compositions A, D, G, J and M on fragrance profile longevity versus control Compositions C, F, I, L and O in the absence of a substantially non-odorous modulator. Alternatively, the results show the effect of the substantially non-odorous fragrance modulator and reduced levels of low volatile fragrance materials for any one of the inventive Compositions A, D, G, J and M on fragrance profile longevity versus traditional Compositions B, E, H, K and N in the presence of the substantially non-odorous fragrance modulator."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.6, "construct": {"method_text_verbatim": "Fragrance profile longevity, is maintained for up to at least 6 hours in the presence of the substantially non-odorous fragrance modulator whilst it drops in the absence of the substantially non-odorous fragrance modulator (data not shown). Without wishing to be bound by theory, it is believed that the substantially non-odorous fragrance modulator acts to maintain the continued evaporation over time of the fragrance materials, particular the volatile fragrance materials. The effect of the improved fragrance profile longevity of the present invention are noticeable at 1, 3 and 6 hours.", "panel_size": null, "property_name": "longevity", "scale": "hours_or_timepoint", "substrate": null, "time_points": ["6 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "6 hours", "patent_id": "EP3307393B1", "provenance": {"citation": "EP3307393B1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3307393B1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:448", "units": "hours", "verbatim_quote": "Fragrance profile longevity, is maintained for up to at least 6 hours in the presence of the substantially non-odorous fragrance modulator whilst it drops in the absence of the substantially non-odorous fragrance modulator (data not shown). Without wishing to be bound by theory, it is believed that the substantially non-odorous fragrance modulator acts to maintain the continued evaporation over time of the fragrance materials, particular the volatile fragrance materials. The effect of the improved fragrance profile longevity of the present invention are noticeable at 1, 3 and 6 hours."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.6, "construct": {"method_text_verbatim": "The test demonstrates the character retention over time of a fragrance composition. The results show the effect of the substantially non-odorous fragrance modulator and reduced levels of low volatile fragrance materials for any one of the inventive Compositions A, D, G, J, and M on fragrance profile longevity versus control Compositions C, F, I, L, and O, in the absence of the substantially non-odorous modulator. Alternatively, results show the effect of the substantially non-odorous fragrance modulator and reduced levels of low volatile fragrance materials for any one of the inventive Compositions A, D, G, J, and M on fragrance profile longevity versus traditional Compositions B, E, H, K, and N, in the presence of the substantially non-odorous fragrance modulator. Fragrance profile fidelity, particularly characters attributable to the volatile fragrance materials are maintained for up to at least 1 hour in the presence of the substantially non-odorous fragrance modulator whilst they d", "panel_size": null, "property_name": "longevity", "scale": "hours_or_timepoint", "substrate": null, "time_points": ["1 hour"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "1 hour", "patent_id": "EP3307393B1", "provenance": {"citation": "EP3307393B1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3307393B1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:464", "units": "hours", "verbatim_quote": "The test demonstrates the character retention over time of a fragrance composition. The results show the effect of the substantially non-odorous fragrance modulator and reduced levels of low volatile fragrance materials for any one of the inventive Compositions A, D, G, J, and M on fragrance profile longevity versus control Compositions C, F, I, L, and O, in the absence of the substantially non-odorous modulator. Alternatively, results show the effect of the substantially non-odorous fragrance modulator and reduced levels of low volatile fragrance materials for any one of the inventive Compositions A, D, G, J, and M on fragrance profile longevity versus traditional Compositions B, E, H, K, and N, in the presence of the substantially non-odorous fragrance modulator. Fragrance profile fidelity, particularly characters attributable to the volatile fragrance materials are maintained for up to at least 1 hour in the presence of the substantially non-odorous fragrance modulator whilst they drop in the absence of the substantially non-odorous fragrance modulator."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.45, "construct": {"method_text_verbatim": "17. A method to enhance the fragrance profile of a composition, preferably improve the longevity of a character, preferably a floral character, of a composition, comprising bringing into contact or mixing at least one substantially non-odorous fragrance modulator with at least one low volatile fragrance material according to a composition as defined according to any one of claims 1-16.", "panel_size": null, "property_name": "longevity", "scale": "numeric_unknown", "substrate": null, "time_points": null}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "1-16", "patent_id": "EP3307393B1", "provenance": {"citation": "EP3307393B1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3307393B1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "claims_(19)_hide_dependent_translated_fr:505", "units": null, "verbatim_quote": "17. A method to enhance the fragrance profile of a composition, preferably improve the longevity of a character, preferably a floral character, of a composition, comprising bringing into contact or mixing at least one substantially non-odorous fragrance modulator with at least one low volatile fragrance material according to a composition as defined according to any one of claims 1-16."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.6, "construct": {"method_text_verbatim": "According to an aspect of some embodiments of the present invention there is provided a scenting concentrate comprising: cis-3-hexenol at a concentration of at least 5 weight percents of the total weight of the concentrate; an ester of cis-3-hexenol having an evaporation number higher than 50 (a \"heavy\" ester, as described herein), at a concentration of at least 5 weight percents of the total weight of the concentrate; Galbanum resinoid at a concentration of at least 3 weight percent of the total weight of the concentrate; and an alcoholic carrier comprising at least one alcohol characterized by one or more of: a boiling temperature higher than 300 \u00b0C; substantivity of at least 300 hours; and evaporation number higher than 50, relative to diethyl ether.", "panel_size": null, "property_name": "substantivity", "scale": "percent", "substrate": null, "time_points": ["300 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "300 hours", "patent_id": "WO2016128982A1", "provenance": {"citation": "WO2016128982A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/WO2016128982A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:107", "units": "hours", "verbatim_quote": "According to an aspect of some embodiments of the present invention there is provided a scenting concentrate comprising: cis-3-hexenol at a concentration of at least 5 weight percents of the total weight of the concentrate; an ester of cis-3-hexenol having an evaporation number higher than 50 (a \"heavy\" ester, as described herein), at a concentration of at least 5 weight percents of the total weight of the concentrate; Galbanum resinoid at a concentration of at least 3 weight percent of the total weight of the concentrate; and an alcoholic carrier comprising at least one alcohol characterized by one or more of: a boiling temperature higher than 300 \u00b0C; substantivity of at least 300 hours; and evaporation number higher than 50, relative to diethyl ether."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.6, "construct": {"method_text_verbatim": "According to some of any of the embodiments of the present invention, the odoriferous material imparts a base note of the ligneous hay odor (substantivity higher than 100 hours, or 200 hours and/or evaporation number higher than 50).", "panel_size": null, "property_name": "substantivity", "scale": "hours_or_timepoint", "substrate": null, "time_points": ["100 hours", "200 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "100 hours; 200 hours", "patent_id": "WO2016128982A1", "provenance": {"citation": "WO2016128982A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/WO2016128982A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:127", "units": "hours", "verbatim_quote": "According to some of any of the embodiments of the present invention, the odoriferous material imparts a base note of the ligneous hay odor (substantivity higher than 100 hours, or 200 hours and/or evaporation number higher than 50)."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.6, "construct": {"method_text_verbatim": "According to some of any of the embodiments of the present invention, the concentrate further comprises an odoriferous material that imparts a green or floral base note (e.g., characterized by substantivity higher than 200 hours and/or evaporation number higher than 50).", "panel_size": null, "property_name": "substantivity", "scale": "hours_or_timepoint", "substrate": null, "time_points": ["200 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "200 hours", "patent_id": "WO2016128982A1", "provenance": {"citation": "WO2016128982A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/WO2016128982A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:133", "units": "hours", "verbatim_quote": "According to some of any of the embodiments of the present invention, the concentrate further comprises an odoriferous material that imparts a green or floral base note (e.g., characterized by substantivity higher than 200 hours and/or evaporation number higher than 50)."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.4, "construct": {"method_text_verbatim": "The formulation disclosed herein meets a long felt need in the field of artificial grasses and grass-related artificial products, as it imparts a long-lasting grass scent to the artificial grass or product. More specifically, the formulation disclosed herein imparts a grass scent that remains for at least 2 days, preferably for at least 3 days, at least 4 days, and even for at least 5 days or more. The formulation provided herein is", "panel_size": null, "property_name": "unknown_numeric_measure", "scale": "numeric_unknown", "substrate": null, "time_points": ["2 days", "3 days", "4 days", "5 days"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "2 days; 3 days; 4 days; 5 days", "patent_id": "WO2016128982A1", "provenance": {"citation": "WO2016128982A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/WO2016128982A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:162", "units": "days", "verbatim_quote": "The formulation disclosed herein meets a long felt need in the field of artificial grasses and grass-related artificial products, as it imparts a long-lasting grass scent to the artificial grass or product. More specifically, the formulation disclosed herein imparts a grass scent that remains for at least 2 days, preferably for at least 3 days, at least 4 days, and even for at least 5 days or more. The formulation provided herein is"}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.6, "construct": {"method_text_verbatim": "The scenting concentrate in the formulation provided herein comprises cis-3- hexenol (also known as cis-3-hexen-l-ol, and mainly as \"leaf alcohol\") as the main scenting ingredient that imparts a fresh grass scent. However, as cis-3-hexenol is a volatile compound, and features relatively low evaporation number and substantivity, the present inventors have devised and successfully prepared and practiced a concentrate and a formulation containing same, which comprise additional components that contribute to maintaining the fresh grass scent for a period of at least 48 hours.", "panel_size": null, "property_name": "substantivity", "scale": "hours_or_timepoint", "substrate": null, "time_points": ["48 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "48 hours", "patent_id": "WO2016128982A1", "provenance": {"citation": "WO2016128982A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/WO2016128982A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:165", "units": "hours", "verbatim_quote": "The scenting concentrate in the formulation provided herein comprises cis-3- hexenol (also known as cis-3-hexen-l-ol, and mainly as \"leaf alcohol\") as the main scenting ingredient that imparts a fresh grass scent. However, as cis-3-hexenol is a volatile compound, and features relatively low evaporation number and substantivity, the present inventors have devised and successfully prepared and practiced a concentrate and a formulation containing same, which comprise additional components that contribute to maintaining the fresh grass scent for a period of at least 48 hours."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.4, "construct": {"method_text_verbatim": "By \"long-lasting scenting effect\" it is meant imparting a scent for a period longer than a few hours, namely, longer than 24 hours, 37 hours, 48 hours, 60 hours, 72 hours, 84 hours, 96 hours, and even longer than 100 hours.", "panel_size": null, "property_name": "unknown_numeric_measure", "scale": "hours_or_timepoint", "substrate": null, "time_points": ["24 hours", "37 hours", "48 hours", "60 hours", "72 hours", "84 hours", "96 hours", "100 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "24 hours; 37 hours; 48 hours; 60 hours; 72 hours; 84 hours; 96 hours; 100 hours", "patent_id": "WO2016128982A1", "provenance": {"citation": "WO2016128982A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/WO2016128982A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:170", "units": "hours", "verbatim_quote": "By \"long-lasting scenting effect\" it is meant imparting a scent for a period longer than a few hours, namely, longer than 24 hours, 37 hours, 48 hours, 60 hours, 72 hours, 84 hours, 96 hours, and even longer than 100 hours."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.75, "construct": {"method_text_verbatim": "The term \"substantivity\" is used herein and in the art of fragrances and perfumes to describe the persistence of a fragrant on the substrate to which it is applied. This term is typically reflected by the time period from application of a substance to a substrate during which the scent imparted by the substance persists, while considering conditions such as removal of the vehicle, contact with water, friction and the like. Values of substantivity provided in the art usually refer to a skin substrate, and consider also conditions to which the skin substrate is subjected to, such as sweating, swimming, bathing and the like. Substantivity of ingredients in a scenting formulation can be calculated according to methods known in the art and/or which can be found in public databases. Reference is made, for example, to www(dot)thegoodscentscompany(dot)com/data; Manuel Zarzo, Sensors, 2013, 13(l):463-483; and \"Flavor, Fragrance and Odor analysis\", Ed. Ray Marsilli, CRC Press, 29 Nov. 2001\". Bas", "panel_size": null, "property_name": "substantivity", "scale": "hours_or_timepoint", "substrate": ["skin"], "time_points": ["100 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "463-483; 100 hours; 10-100", "patent_id": "WO2016128982A1", "provenance": {"citation": "WO2016128982A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/WO2016128982A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:174", "units": "hours", "verbatim_quote": "The term \"substantivity\" is used herein and in the art of fragrances and perfumes to describe the persistence of a fragrant on the substrate to which it is applied. This term is typically reflected by the time period from application of a substance to a substrate during which the scent imparted by the substance persists, while considering conditions such as removal of the vehicle, contact with water, friction and the like. Values of substantivity provided in the art usually refer to a skin substrate, and consider also conditions to which the skin substrate is subjected to, such as sweating, swimming, bathing and the like. Substantivity of ingredients in a scenting formulation can be calculated according to methods known in the art and/or which can be found in public databases. Reference is made, for example, to www(dot)thegoodscentscompany(dot)com/data; Manuel Zarzo, Sensors, 2013, 13(l):463-483; and \"Flavor, Fragrance and Odor analysis\", Ed. Ray Marsilli, CRC Press, 29 Nov. 2001\". Base notes typically have substantivity higher than 100 hours. Middle notes typically have substantivity of 10-100. Top notes typically have substantivity lower than 10."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.6, "construct": {"method_text_verbatim": "According to some of any of the embodiments of the present invention, the ester of cis-3-hexenol is a \"heavy\" ester of cis-3-hexenol, characterized by high substantivity and/or high evaporation number. In some embodiments, the ester of cis-3-hexenol is characterized by substantivity higher than 100 hours, 150 hours or 200 hours. Due to its high substantivity, such a \"heavy\" ester imparts a base note of the formulation, for example, a green, floral or grass scent base note.", "panel_size": null, "property_name": "substantivity", "scale": "hours_or_timepoint", "substrate": null, "time_points": ["100 hours", "150 hours", "200 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "100 hours; 150 hours; 200 hours", "patent_id": "WO2016128982A1", "provenance": {"citation": "WO2016128982A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/WO2016128982A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:180", "units": "hours", "verbatim_quote": "According to some of any of the embodiments of the present invention, the ester of cis-3-hexenol is a \"heavy\" ester of cis-3-hexenol, characterized by high substantivity and/or high evaporation number. In some embodiments, the ester of cis-3-hexenol is characterized by substantivity higher than 100 hours, 150 hours or 200 hours. Due to its high substantivity, such a \"heavy\" ester imparts a base note of the formulation, for example, a green, floral or grass scent base note."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.6, "construct": {"method_text_verbatim": "According to some of any of the embodiments of the present invention, additional \"heavy\" substances are included in the base formulation, for imparting a long-lasting scenting effect. These substances are characterized by substantivity higher than 100 hours, or higher than 200 hours, and even higher than 300 hours, and/or by evaporation number that is higher than 50, higher than 60 or higher than 70 (or from 35 to 100 or from 50 to 100). In some embodiments, such ingredients are present in the base formulation at a concentration ranging from 1 to 10 weight percents in total, or 3 to 7 weight percents in total.", "panel_size": null, "property_name": "substantivity", "scale": "percent", "substrate": null, "time_points": ["100 hours", "200 hours", "300 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "100 hours; 200 hours; 300 hours; 35 to 100; 50 to 100; 1 to 10; 3 to 7", "patent_id": "WO2016128982A1", "provenance": {"citation": "WO2016128982A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/WO2016128982A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:184", "units": "hours", "verbatim_quote": "According to some of any of the embodiments of the present invention, additional \"heavy\" substances are included in the base formulation, for imparting a long-lasting scenting effect. These substances are characterized by substantivity higher than 100 hours, or higher than 200 hours, and even higher than 300 hours, and/or by evaporation number that is higher than 50, higher than 60 or higher than 70 (or from 35 to 100 or from 50 to 100). In some embodiments, such ingredients are present in the base formulation at a concentration ranging from 1 to 10 weight percents in total, or 3 to 7 weight percents in total."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.6, "construct": {"method_text_verbatim": "In some embodiments the alcoholic base comprises one or more \"heavy alcohols\" characterized by substantivity higher than 100 hours, or higher than 200 hours or preferably higher than 300 hours, and/or by evaporation number higher than 60, higher than 70 or higher (or of from 50 to 100). Alternatively or additionally, the one or more \"heavy alcohol\" is characterized by a boiling temperature higher than 300 \u00b0C.", "panel_size": null, "property_name": "substantivity", "scale": "hours_or_timepoint", "substrate": null, "time_points": ["100 hours", "200 hours", "300 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "100 hours; 200 hours; 300 hours; 50 to 100", "patent_id": "WO2016128982A1", "provenance": {"citation": "WO2016128982A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/WO2016128982A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:188", "units": "hours", "verbatim_quote": "In some embodiments the alcoholic base comprises one or more \"heavy alcohols\" characterized by substantivity higher than 100 hours, or higher than 200 hours or preferably higher than 300 hours, and/or by evaporation number higher than 60, higher than 70 or higher (or of from 50 to 100). Alternatively or additionally, the one or more \"heavy alcohol\" is characterized by a boiling temperature higher than 300 \u00b0C."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.6, "construct": {"method_text_verbatim": "In some embodiments, such an odoriferous material is characterized by moderate to low substantivity (e.g., lower than 100 hours, or lower than 24 hours or lower than 10 hours), and/or moderate to low evaporation number (e.g., lower than 35,", "panel_size": null, "property_name": "substantivity", "scale": "hours_or_timepoint", "substrate": null, "time_points": ["100 hours", "24 hours", "10 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "100 hours; 24 hours; 10 hours", "patent_id": "WO2016128982A1", "provenance": {"citation": "WO2016128982A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/WO2016128982A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:198", "units": "hours", "verbatim_quote": "In some embodiments, such an odoriferous material is characterized by moderate to low substantivity (e.g., lower than 100 hours, or lower than 24 hours or lower than 10 hours), and/or moderate to low evaporation number (e.g., lower than 35,"}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.6, "construct": {"method_text_verbatim": "Exemplary such odoriferous materials are aldehydes and alcohols of moderate to low substantivity (e.g., lower than 100 hours, or lower than 24 hours, or lower than 10 hours) and/or moderate to low evaporation number (e.g., lower than 35, or lower than 15, or lower than 10), such as, but not limited to, Dihydromyrcenol, Linalyle Acetate, and Styrallyl Acetate. In some embodiments, the formulation comprises one or more, or all of such odoriferous materials.", "panel_size": null, "property_name": "substantivity", "scale": "hours_or_timepoint", "substrate": null, "time_points": ["100 hours", "24 hours", "10 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "100 hours; 24 hours; 10 hours", "patent_id": "WO2016128982A1", "provenance": {"citation": "WO2016128982A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/WO2016128982A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:209", "units": "hours", "verbatim_quote": "Exemplary such odoriferous materials are aldehydes and alcohols of moderate to low substantivity (e.g., lower than 100 hours, or lower than 24 hours, or lower than 10 hours) and/or moderate to low evaporation number (e.g., lower than 35, or lower than 15, or lower than 10), such as, but not limited to, Dihydromyrcenol, Linalyle Acetate, and Styrallyl Acetate. In some embodiments, the formulation comprises one or more, or all of such odoriferous materials."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.4, "construct": {"method_text_verbatim": "As discussed hereinabove, due to the long-lasting scenting effect provided by the formulations described herein, applying the formulation to a substrate can be effected by periodic intervals of 3 days or more. Any of the methods, systems and devices described herein can therefore be employed in accordance with these time intervals. Thus, for example, a controller in an exemplary system as described herein can operate the distribution system at periodic intervals of 3 days or more. The system also comprises a data processor which can be configured to vary the time intervals employed by the controller based on a predetermined criterion or set of criteria.", "panel_size": null, "property_name": "unknown_numeric_measure", "scale": "numeric_unknown", "substrate": null, "time_points": ["3 days"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "3 days", "patent_id": "WO2016128982A1", "provenance": {"citation": "WO2016128982A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/WO2016128982A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:252", "units": "days", "verbatim_quote": "As discussed hereinabove, due to the long-lasting scenting effect provided by the formulations described herein, applying the formulation to a substrate can be effected by periodic intervals of 3 days or more. Any of the methods, systems and devices described herein can therefore be employed in accordance with these time intervals. Thus, for example, a controller in an exemplary system as described herein can operate the distribution system at periodic intervals of 3 days or more. The system also comprises a data processor which can be configured to vary the time intervals employed by the controller based on a predetermined criterion or set of criteria."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.6, "construct": {"method_text_verbatim": "substantivity of at least 300 hours; and/or", "panel_size": null, "property_name": "substantivity", "scale": "hours_or_timepoint", "substrate": null, "time_points": ["300 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "300 hours", "patent_id": "WO2016128982A1", "provenance": {"citation": "WO2016128982A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/WO2016128982A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "claims_()_hide_dependent_translated_from:320", "units": "hours", "verbatim_quote": "substantivity of at least 300 hours; and/or"}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.6, "construct": {"method_text_verbatim": "substantivity higher than 100 hours; and/or", "panel_size": null, "property_name": "substantivity", "scale": "hours_or_timepoint", "substrate": null, "time_points": ["100 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "100 hours", "patent_id": "WO2016128982A1", "provenance": {"citation": "WO2016128982A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/WO2016128982A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "claims_()_hide_dependent_translated_from:344", "units": "hours", "verbatim_quote": "substantivity higher than 100 hours; and/or"}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.6, "construct": {"method_text_verbatim": "substantivity higher than 200 hours; and/or", "panel_size": null, "property_name": "substantivity", "scale": "hours_or_timepoint", "substrate": null, "time_points": ["200 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "200 hours", "patent_id": "WO2016128982A1", "provenance": {"citation": "WO2016128982A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/WO2016128982A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "claims_()_hide_dependent_translated_from:353", "units": "hours", "verbatim_quote": "substantivity higher than 200 hours; and/or"}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.6, "construct": {"method_text_verbatim": "There are at least one of several drawbacks to the above described classical formulation approach. Firstly, classification of fragrance materials by their characters is subjective and therefore results in inconsistency in the fragrance profile under classical fragrance pyramid construction rules. Secondly, the perceived intensity of the fragrance profile of the conventional perfume compositions, particularly those characters attributable to the more volatile fragrance materials, decreases rapidly over time due to their quick evaporation. Accordingly, conventional perfume compositions will typically change their overall fragrance profile over time. This is a problem because it is desirable to maintain \"fragrance profile fidelity\" over time. In other words, it is desirable to maintain the same or substantively similar fragrance profile for a commercial fragrance over time, particularly over long periods of time (at least 4 hrs, 6 hrs, or even 8 hours after application). Thirdly, with the", "panel_size": null, "property_name": "fragrance_intensity", "scale": "hours_or_timepoint", "substrate": null, "time_points": ["4 hrs", "6 hrs", "8 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "4 hrs; 6 hrs; 8 hours", "patent_id": "EP3141239A1", "provenance": {"citation": "EP3141239A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3141239A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:182", "units": "hours", "verbatim_quote": "There are at least one of several drawbacks to the above described classical formulation approach. Firstly, classification of fragrance materials by their characters is subjective and therefore results in inconsistency in the fragrance profile under classical fragrance pyramid construction rules. Secondly, the perceived intensity of the fragrance profile of the conventional perfume compositions, particularly those characters attributable to the more volatile fragrance materials, decreases rapidly over time due to their quick evaporation. Accordingly, conventional perfume compositions will typically change their overall fragrance profile over time. This is a problem because it is desirable to maintain \"fragrance profile fidelity\" over time. In other words, it is desirable to maintain the same or substantively similar fragrance profile for a commercial fragrance over time, particularly over long periods of time (at least 4 hrs, 6 hrs, or even 8 hours after application). Thirdly, with the classical fragrance pyramid construction, the possible types of fragrance profiles have been somewhat limited. The consequence of using base notes at high levels is that many fragrance dry-downs appear repetitive, boring, non-memorable and uninteresting to consumers. However, if base notes are reduced or excluded then the fragrance intensity weakens over time and does not last for a sufficient duration. Lastly, it is generally accepted that some consumers desire prolonged intensity of select characters, particularly the floral, spicy or aromatic characters derived from the heart notes. Unfortunately, the consequence of using high levels of base notes is that they may impart particularly undesirable characters, such as for example, musky, woody, ambery, warm and sweet, which overpower and dominate the more desirable fragrance characters over time, particular over long periods of time. Thus, the unique challenge remains of selectively extending the more desirable characters attributable from the heart and/or top notes, particularly the heart notes, and even more particularly extending these desirable characters over long periods of time."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.6, "construct": {"method_text_verbatim": "Thus, it is an advantage of the present invention to provide new rules for objectively classifying fragrance materials according to their volatility using their their vapor pressures defined at suitable temperature, instead of their characters. The new rules operate irrespective of perfumers performing the classification. In particular, the new rules classify the fragrance materials into low, moderate or high volatile fragrance materials for formulating into fragrance mixtures, particularly ones having a diamond construction. It is a further advantage of the present invention to provide compositions having improved fidelity to the perceived fragrance profile over time. It is yet a further advantage to provide a composition, wherein the character attributable to moderate and high volatile fragrance materials, particularly the moderate volatile fragrance materials, remains significantly consistent from its initial impression to the end. It is yet a further advantage to provide compositio", "panel_size": null, "property_name": "longevity", "scale": "hours_or_timepoint", "substrate": null, "time_points": ["8 hours"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "8 hours", "patent_id": "EP3141239A1", "provenance": {"citation": "EP3141239A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3141239A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:191", "units": "hours", "verbatim_quote": "Thus, it is an advantage of the present invention to provide new rules for objectively classifying fragrance materials according to their volatility using their their vapor pressures defined at suitable temperature, instead of their characters. The new rules operate irrespective of perfumers performing the classification. In particular, the new rules classify the fragrance materials into low, moderate or high volatile fragrance materials for formulating into fragrance mixtures, particularly ones having a diamond construction. It is a further advantage of the present invention to provide compositions having improved fidelity to the perceived fragrance profile over time. It is yet a further advantage to provide a composition, wherein the character attributable to moderate and high volatile fragrance materials, particularly the moderate volatile fragrance materials, remains significantly consistent from its initial impression to the end. It is yet a further advantage to provide compositions having improved longevity of the perceived fragrance profile, preferably the characters attributable from the moderate or high volatile fragrance materials, particularly the moderate volatile fragrance material. It is yet a further advantage to provide compositions having stable quality of end product ( _e.g.,_ fragrance profile, visual appearance) substantially comparable to the classical fragrance pyramid three-tiered structure, preferably even after three months storage at 40 \u00b0C. It is yet a further advantage to be able to create new to the world fragrance profiles wherein one, or several, well-recognized moderate volatile fragrance material characters, are maintained over time, preferably for long periods of time ( _e.g.,_ greater than 4, 6, or even 8 hours)."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.85, "construct": {"method_text_verbatim": "The present invention provides a method for imparting, intensifying, or modifying an odour on human skin or human hair, comprising applying to human skin and/or human hair the composition of the present invention. It is preferred that the method is for imparting, intensifying or modifying the longevity of a floral character or aromatic/spicy character on human skin or human hair, wherein the perceived intensity of the floral character or aromatic/spicy character at 1 hr, 2 hrs, 3 hrs or 6 hrs after application is greater than a control composition that does not include the substantially non-odorous fragrance modulator as determined by the panel method as disclosed herein.", "panel_size": null, "property_name": "longevity", "scale": "hours_or_timepoint", "substrate": ["hair", "skin"], "time_points": ["1 hr", "2 hrs", "3 hrs", "6 hrs"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "1 hr; 2 hrs; 3 hrs; 6 hrs", "patent_id": "EP3141239A1", "provenance": {"citation": "EP3141239A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3141239A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:265", "units": "hours", "verbatim_quote": "The present invention provides a method for imparting, intensifying, or modifying an odour on human skin or human hair, comprising applying to human skin and/or human hair the composition of the present invention. It is preferred that the method is for imparting, intensifying or modifying the longevity of a floral character or aromatic/spicy character on human skin or human hair, wherein the perceived intensity of the floral character or aromatic/spicy character at 1 hr, 2 hrs, 3 hrs or 6 hrs after application is greater than a control composition that does not include the substantially non-odorous fragrance modulator as determined by the panel method as disclosed herein."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": "Compound 1", "confidence": 0.95, "construct": {"method_text_verbatim": "| **No.** | **CAS Number** | **IUPAC Name** | **Common Name\\*\\*** | **Vapor Pressure (Torr at 25 \u00b0C)\\*** | | --- | --- | :-: | :-: | :-: | | 1. | 24168-70-5 | Pyrazine, 2-methoxy-3-(1-methylpropyl)- | Methoxyisobutylpyrazine | 0.09950000 | | 2. | 89-79-2 | Cyclohexanol, 5-methyl-2-(1-methylethenyl)-, (1 _R_, 2 _S_,5 _R_)- | Iso-Pulegol | 0.09930000 | | 3. | 112-12-9 | 2-Undecanone | Methyl Nonyl Ketone | 0.09780000 | | 4. | 103-05-9 | Benzenepropanol, \u03b1,\u03b1-dimethyl- | Phenyl Ethyl Dimethyl Carbinol | 0.09770000 | | 5. | 125-12-2 | Bicyclo\\[2.2.1\\]heptan-2-ol, 1,7,7-trimethyl-, 2-acetate, | Iso Bornyl Acetate | 0.09590000 | | | | (1 _R_,2 _R_,4 _R_)-rel- | | | | 6. | 78-70-6 | 1,6-Octadien-3-ol, 3,7-dimethyl- | Linalool | 0.09050000 | | 7. | 101-97-3 | Benzeneacetic acid, ethyl ester | Ethyl Phenyl Acetate | 0.08970000 | | 8. | 100-86-7 | Benzeneethanol, \u03b1,\u03b1-dimethyl- | Dimethyl Benzyl Carbinol | 0.08880000 | | 9. | 188570-78-7 | Cyclopropanecarboxylic acid, (3 _Z_)-3-hexen-1-yl ester | ", "panel_size": 10, "property_name": "headspace_concentration_or_intensity", "scale": "percent", "substrate": ["fabric", "hair", "headspace", "skin"], "time_points": ["1H", "4H", "1 hr", "2 hrs", "3 hrs", "4 hrs", "5 hrs", "6 hrs", "8 hrs", "12 hrs", "1 hour", "2 hours", "3 hours", "4 hours", "6 hours", "0 hours", "0 hour"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "24168-70; 89-79; 112-12; 103-05; 125-12; 78-70; 101-97; 100-86; 188570-78; 67634-25; 112-44; 32669-00; 98-53; 35854-86; 5331-14; 80-57; 22471-55; 60-12; 106-26; 5392-40; 89-48; 119-36; 4180-23; 7549-37; 25225-08; 3913-81; 15373-31; 6485-40; 16587-71; 62406-73; 3720-16; 13816-33; 67019-89; 53398-85; 208041-98; 16510-27; 111-80; 103-45; 2550-26; 13491-79; 7786-44; 103-28; 104-62; 28462-85; 122-03; 358331-95; 562-74; 68527-77; 35852-46; 2756-56; 14374-92; 6784-13; 8000-41; 41884-28; 22457-23; 104-50; 143-08; 3613-30; 67634-00; 464-45; 124-76; 67874-72; 80-26; 498-81; 112-45; 35044-57; 106-21; 84560-00; 82461-14; 56011-02; 103-37; 6378-65; 118-61; 98-52; 115-99; 112-54; 53046-97; 76649-25; 141-25; 1975-78; 2216-51; 3658-77; 103-93; 24717-86; 67845-46; 67883-79; 33885-51; 105-85; 70214-77; 215231-33; 120-72; 2463-77; 675-09; 98-55; 81786-73; 122-97; 39212-23; 53767-93; 35044-59; 104-55; 144-39; 61931-80; 102-13; 65443-14; 141-12; 105-87; 68141-17; 2206-94; 10528-67; 123-11; 57576-09; 51566-62; 60335-71; 30385-25; 101-84; 136-60; 93939-86; 83926-73; 125109-85; 104-21; 1365-19; 137-03; 2563-07; 1128-08; 7493-57; 216970-21; 319002-92; 85-91; 13828-37; 26330-65; 7540-51; 106-22; 543-39; 7775-00; 18479-54; 29214-60; 1209-61; 57934-97; 14901-07; 64001-15; 95-41; 134-20; 100-06; 105-86; 154171-77; 154171-76; 127-41; 151-05; 2500-83; 150-84; 30310-41; 68845-00; 106-24; 106-25; 75975-83; 19870-74; 87-44; 54440-17; 110-98; 41890-92; 71077-31; 65-85; 61444-38; 116044-44; 104-54; 78-35; 23495-12; 103-26; 67634-14; 5454-19; 93-16; 81782-77; 67845-30; 97-53; 120-57; 93-04; 4826-62; 20407-84; 5462-06; 94-60; 57378-68; 17283-81; 1885-38; 103-48; 488-10; 7492-67; 68683-20; 3025-30; 103-54; 18127-01; 3738-00; 51519-65; 148-05; 6790-58; 86-26; 68738-94; 2705-87; 7011-83; 61792-11; 692-86; 103-95; 13019-22; 94201-19; 104-61; 706-14; 24720-09; 39872-57; 705-86; 67634-15; 40527-42; 56973-85; 128-51; 103-36; 5182-36; 42604-12; 33885-52; 92015-65; 63767-86; 3288-99; 35044-68; 41724-19; 75147-23; 25634-93; 55066-48; 495-62; 2785-87; 87-19; 4430-31; 38462-22; 77-83; 37677-14; 103-60; 18096-62; 63500-71; 65405-84; 171102-41; 10339-55; 23267-57; 97-54; 67663-01; 23696-85; 80-71; 67662-96; 2437-25; 141-14; 54992-90; 55066-49; 7493-74; 80-54; 86803-90; 68991-97; 18871-14; 58567-11; 94400-98; 79-69; 65442-31; 87731-18; 173445-65; 23911-56; 52474-60; 139539-66; 80858-47; 32764-98; 78417-28; 140-26; 105-90; 41816-03; 7070-15; 93-29; 476332-65; 68901-15; 107-75; 68611-23; 313973-37; 137-00; 7779-30; 127-51; 72903-27; 7388-22; 104-67; 1205-17; 33704-61; 36306-87; 97384-48; 141-13; 2110-18; 27606-09; 67634-20; 1H; 65405-72; 122-40; 103694-68; 13215-88; 25152-85; 406488-30; 121-33; 77-54; 76842-49; 121-39; 211299-54; 4H; 285977-85; 10094-34; 40785-62; 75490-39; 55418-52; 3943-74; 72089-08; 3155-71; 2050-08; 41199-20; 12262-03; 107-74; 91-64; 68901-32; 68039-44; 106-29; 5471-51; 109-42; 0.1 to 0.001; 1-9; 11-12; 14-15; 17-18; 20-25; 27-35; 37-38; 39-43; 45-46; 48-53; 55-61; 67-71; 73-77; 81-84; 86-91; 93-122; 124-125; 130-131; 133-135; 139-145; 147-149; 153-155; 161-162; 164-169; 171-191; 195-198; 200-203; 205-215; 218-219; 223-241; 245-250; 252-255; 257-262; 264-265; 267-268; 273-276; 279-300; 302-304; 308-310; 312-319; 1-5; 30-31; 34-35; 41-42; 51-53; 57-59; 65-70; 75-77; 79-80; 86-89; 91-94; 101-107; 111-113; 115-122; 130-133; 139-143; 157-159; 164-168; 171-180; 182-183; 187-191; 205-213; 221-222; 224-229; 231-241; 254-255; 257-263; 267-269; 314-319; 6-8; 107-31; 75-18; 141-78; 105-37; 110-19; 105-54; 14765-30; 7452-79; 123-92; 66576-71; 110-43; 6728-26; 123-51; 1191-16; 57366-77; 7785-70; 79-92; 94087-83; 39255-32; 3387-41; 127-91; 105-68; 123-35; 124-13; 7392-19; 111-13; 123-66; 470-82; 99-87; 104-93; 13877-91; 138-86; 5989-27; 106-68; 110-41; 142-92; 110-93; 81925-81; 3681-71; 97-64; 586-62; 51115-64; 106-27; 99-85; 18640-74; 928-96; 100-52; 141-97; 928-95; 928-94; 24691-15; 19872-52; 3016-19; 69103-20; 189440-77; 67633-96; 123-68; 106-72; 106-30; 68039-49; 101-48; 16409-43; 925-78; 100-47; 589-98; 58430-94; 10250-45; 105-79; 2349-07; 23250-42; 122-78; 5405-41; 105-53; 93-58; 16356-11; 65405-70; 54546-26; 13254-34; 98-86; 93-53; 80118-06; 557-48; 24683-00; 104-57; 104-45; 491-07; 89-80; 2463-53; 55739-89; 150-78; 64988-06; 76-22; 67674-46; 112-31; 16251-77; 93-92; 143-13; 122-00; 24237-00; 41519-23; 93-89; 20780-48; 101-41; 40853-55; 933-48; 35158-25; 18479-58; 140-11; 20125-84; 142-19; 100-51; 10032-15; 695-06; 21722-83; 111-79; 16491-36; 111-12; 59323-76; 62439-41; 13851-11; 115-95; 18479-57; 78-69; 111-87; 71159-90; 80-25; 88-41; 32210-23; 124-19; 929253-05; 68039-47; 6413-10; 106-23; 131-135; 6 to 9; 1 to 4; 7 to 11; 1 to 5; 6 to 8; 1 to 3; 2 to 4; 7 to 10; 2 to 5; 8 to 18; 1 to 8; 61849-72; 68239-42; 68515-73; 36653-82; 28510-23; 25339-99; 25915-57; 27216-47; 26446-38; 25168-73; 27195-16; 27923063-3; 9004-61; 9067-32; 497-76; 1569-01; 4113-12; 25618-55; 69364-63; 68929-04; 3055-96; 27841-07; 90411-68; 70455-33; 667-83; 16485-10; 141-04; 6624-70; 25231-21; 72934-15; 107647-13; 936645-35; 61791-12; 70445-33; 99509-00; 43-47; 12-13; 50-53; 61-083114; 61-063612; 62-084010; 12-25; 54-56; 68131-40; 9038-95; 37311-01; 5703-94; 9087-53; 45-7; 68951-67; 68131-39; 66455-14; 68439-49; 68439-46; 61791-13; 68439-50; 9004-74; 68002-97; 9005-00; 9004-95; 9003-11; 34398-01; 12/18; 6540-99; 9002-92; 109-86; 27306-79; 05-0; 52292-17; 9035-85; 24938-91; 10-8; 26183-52; 4536-30; 61791-26; 26635-93; 9004-98; 8065-81; 61791-28; 34150-35; 23436-19; 111-46; 110-80; 107-98; 54-0; 109-87; 2517-43; 111-76; 5131-66; 8/29387; 86-8; 15821-83; 112-34; 52019-36; 2136-71; 9003-13; 30136-13; 29387-86; 8/5131; 66-8; 34590-94; 111109-77; 13429-07; 111-77; 111-90; 111-96; 37286-64; 7529-22; 5274-66; 55934-93; 24800-44; 25498-49; 112-27; 112-35; 3055-94; 112-60; 4439-32; 4484-59; 26826-30; 5274-61; 5274-65; 16057-43; 68959-25; 109292-17; 1733-93; 71032-90; 544-62; 5117-19; 66082-42; 59113-36; 6297-03; 10438-94; 506-03; 68130-24; 110-91; 51200-87; 68140-98; 14408-42; 637-58; 57448-83; 55852-14; 646-06; 5464-28; 55852-13; 68002-20; 11111-34; 27177-05; 27177-08; 2315-66; 68987-90; 94349-40; 55837-16; 14548-60; 27176-93; 2315-62; 27176-95; 7311-27; 51437-95; 27177-03; 27177-01; 20636-48; 26264-02; 27176-97; 102051-00; 33940-99; 34424-98; 79777-30; 79665-93; 87390-32; 34406-66; 51033-38; 126928-07; 27321-96; 9003-96; 9038-43; 17517-01; 55353-19; 629-82; 60-29; 4747-07; 94159-75; 14529-40; 13149-86; 3055-99; 71976-00; 24871-34; 6790-09; 3386-18; 2615-15; 25791-96; 31694-55; 3055-98; 27040-03; 3055-97; 66146-84; 1012-6.0; 5168-89; 2420-29; 5168-91; 136207-49; 92669-01; 71093-13; 4478-97; 5353-27; 95-6; 59970-10; 5274-68; 39034-24; 5274-63; 5353-26; 103622-85; 497926-97; 56709-13; 6542-37; 7747-35; 32647-67; 135861-56; 3055-93; 51-03; 63187-91; 68332-79; 67674-36; 87061-04; 147-24; 29911-27; 1994-2013; 6-10; 0 to 5; 0 to 3; 100%; 90 to 95; 99 to 99.75; 1 hr; 2 hrs; 3 hrs; 4 hrs; 5 hrs; 6 hrs; 8 hrs; 12 hrs; 5 to 10; 25 to 40; 50/30; 20 to 40; 9 to 16; 101-86; 198404-98; 1222-05; 110-27; 65113-99; 30168-23; 67801-20; 141773-73; 37609-25; 28645-51; 65405-77; 118-58; 63314-79; 24851-98; 54464-57; 107898-54; 6-7; 93-08; 4707-47; 68155-66; 111879-80; 1 - 31.48; 535-86; 28940-11; 14595-54; 2 - 9.37; 105-95; 1-3; 7-17; 2-15; 60-99.99; 0-0.07; 0.1-20; 0 - 0.07; 101-103; 0.25 to 1.0; 1-15.0; 1-6; 9-99; 1-189; 0.5 -1; 0.5-1; 0.1-5; 1-4; 0.1-3; 20-50; 0.1-1; 1-7; 64-17; 7732-18; 25265-71; 127-82; 128446-36; 74-98; 72-28; 75-37; 64-02; 9003-01; 9063-87; 68037-01; 63148-62; 102-71; 1 hour; 2 hours; 3 hours; 4 hours; 6 hours; 0 hours; 0 hour; 1-112; 4-6; 12-16; 22-25; 27-28; 34-37; 52-55; 69-74; 83-84; 106-108; 8-9; 12-14; 18-19; 25-28; 47-49; 53-55; 57-60; 71-73; 78-79; 84-85; 1-319; 1-130; 1-103; 1-15; 1-18", "patent_id": "EP3141239A1", "provenance": {"citation": "EP3141239A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/EP3141239A1/en"}, "pub_date": null, "resolution_confidence": 1.0, "resolution_method": "printed-cas", "resolved_cas": "24168-70-5", "resolved_smiles": null, "source_locus": "description_translated_from:284", "units": "hours", "verbatim_quote": "| **No.** | **CAS Number** | **IUPAC Name** | **Common Name\\*\\*** | **Vapor Pressure (Torr at 25 \u00b0C)\\*** | | --- | --- | :-: | :-: | :-: | | 1. | 24168-70-5 | Pyrazine, 2-methoxy-3-(1-methylpropyl)- | Methoxyisobutylpyrazine | 0.09950000 | | 2. | 89-79-2 | Cyclohexanol, 5-methyl-2-(1-methylethenyl)-, (1 _R_, 2 _S_,5 _R_)- | Iso-Pulegol | 0.09930000 | | 3. | 112-12-9 | 2-Undecanone | Methyl Nonyl Ketone | 0.09780000 | | 4. | 103-05-9 | Benzenepropanol, \u03b1,\u03b1-dimethyl- | Phenyl Ethyl Dimethyl Carbinol | 0.09770000 | | 5. | 125-12-2 | Bicyclo\\[2.2.1\\]heptan-2-ol, 1,7,7-trimethyl-, 2-acetate, | Iso Bornyl Acetate | 0.09590000 | | | | (1 _R_,2 _R_,4 _R_)-rel- | | | | 6. | 78-70-6 | 1,6-Octadien-3-ol, 3,7-dimethyl- | Linalool | 0.09050000 | | 7. | 101-97-3 | Benzeneacetic acid, ethyl ester | Ethyl Phenyl Acetate | 0.08970000 | | 8. | 100-86-7 | Benzeneethanol, \u03b1,\u03b1-dimethyl- | Dimethyl Benzyl Carbinol | 0.08880000 | | 9. | 188570-78-7 | Cyclopropanecarboxylic acid, (3 _Z_)-3-hexen-1-yl ester | Montaverdi | 0.08640000 | | 10. | 67634-25-7 | 3-Cyclohexene-1-methanol, 3,5-dimethyl-, 1-acetate | Floralate | 0.08500000 | | 11. | 112-44-7 | Undecanal | Undecyl Aldehyde | 0.08320000 | | 12. | 32669-00-4 | Ethanone, 1-(3-cycloocten-1-yl)- | Tanaisone\u00ae | 0.08150000 | | 13. | 98-53-3 | Cyclohexanone, 4-(1,1-dimethylethyl)- | Patchi | 0.07780000 | | 14. | 35854-86-5 | 6-Nonen-1-ol, (6Z)- | cis-6-None-1-ol | 0.07770000 | | 15. | 5331-14-6 | Benzene, (2-butoxyethyl)- | Butyl phenethyl ether | 0.07760000 | | 16. | 80-57-9 | Bicycle\\[3.1.1\\]hept-3-en-2-one, 4,6,6-trimethyl- | Verbenone | 0.07730000 | | 17. | 22471-55-2 | Cyclohexanecarboxylic acid, 2,2,6-trimethyl-, ethyl ester, (1 _R_,6 _S_)-rel- | Thesaron | 0.07670000 | | 18. | 60-12-8 | Benzeneethanol | Phenethyl alcohol | 0.07410000 | | 19. | 106-26-3 | 2,6-Octadienal, 3,7-dimethyl-, (2Z)- | Neral | 0.07120000 | | 20. | 5392-40-5 | 2,6-Octadienal, 3,7-dimethyl- | Citral | 0.07120000 | | 21. | 89-48-5 | Cyclohexanol, 5-methyl-2-(1-methylethyl)-, 1-acetate, (1 _R_,2 _S_,5 _R_)-rel- | Menthyl Acetate | 0.07070000 | | 22. | 119-36-8 | Benzoic acid, 2-hydroxy-, methyl ester | Methyl salicylate | 0.07000000 | | 23. | 4180-23-8 | Benzene, 1-methoxy-4-(1 _E_)-1-propen-1-yl- | Anethol | 0.06870000 | | 24. | 7549-37-3 | 2,6-Octadiene, 1,1-dimethoxy-3,7-dimethyl- | Citral Dimethyl Acetal | 0.06780000 | | 25. | 25225-08-5 | Cyclohexanemethanol, \u03b1, 3,3-trimethyl-, 1-formate | Aphermate | 0.06780000 | | 26. | 3913-81-3 | 2-Decenal, (2 _E_)- | 2-Decene-1-al | 0.06740000 | | 27. | 15373-31-6 | 3-Cyclopentene-1-acetonitrile, 2,2,3-trimethyl- | Cantryl\u00ae | 0.06700000 | | 28. | 6485-40-1 | 2-Cyclohexen-1-one, 2-methyl-5-(1-methylethenyl)-, (5 _R_)- | Laevo carvone | 0.06560000 | | 29. | 16587-71-6 | Cyclohexanone, 4-(1,1-dimethylpropyl)- | Orivone | 0.06490000 | | 30. | 62406-73-9 | 6,10-Dioxaspiro\\[4.5\\]decane, 8,8-dimethyl-7-(1-methylethyl)- | Opalal CI | 0.06290000 | | 31. | 3720-16-9 | 2-Cyclohexen-1-one, 3-methyl-5-propyl- | Livescone | 0.06270000 | | 32. | 13816-33-6 | Benzonitrile, 4-(1-methylethyl)- | Cumin Nitrile | 0.06230000 | | 33. | 67019-89-0 | 2,6-Nonadienenitrile | Violet Nitrile | 0.06200000 | | 34. | 53398-85-9 | Butanoic acid, 2-methyl-, (3 _Z_)-3-hexen-1-yl ester | cis-3-Hexenyl Alpha Methyl Butyrate | 0.06130000 | | 35. | 208041-98-9 | n/a | Jasmonitrile | 0.05920000 | | 36. | 16510-27-3 | Benzene, 1-(cyclopropylmethyl)-4-methoxy- | Toscanol | 0.05870000 | | 37. | 111-80-8 | 2-Nonynoic acid, methyl ester | Methyl Octine Carbonate | 0.05680000 | | 38. | 103-45-7 | Acetic acid, 2-phenylethyl ester | Phenyl Ethyl Acetate | 0.05640000 | | 39. | 2550-26-7 | 2-Butanone, 4-phenyl- | Benzyl Acetone | 0.05570000 | | 40. | 13491-79-7 | Cyclohexanol, 2-(1,1-dimethylethyl)- | Verdol | 0.05430000 | | 41. | 7786-44-9 | 2,6-Nonadien-1-ol | 2,6-Nonadien-1-ol | 0.05370000 | | 42. | 103-28-6 | Propanoic acid, 2-methyl-, phenylmethyl ester | Benzyl Iso Butyrate | 0.05130000 | | 43. | 104-62-1 | Formic acid, 2-phenylethyl ester | Phenyl Ethyl Formate | 0.05050000 | | 44. | 28462-85-3 | Bicyclo\\[2.2.1\\]heptan-2-ol, 1,2,3,3-tetramethyl-, (1 _R_, 2 _R_,4 _S_)-rel- | Humus Ether | 0.04870000 | | 45. | 122-03-2 | Benzaldehyde, 4-(1-methylethyl)- | Cuminic Aldehyde | 0.04820000 | | 46. | 358331-95-0 | 2,5-Octadien-4-one, 5,6,7-trimethyl-, (2 _E_)- | Pomarose | 0.04810000 | | 47. | 562-74-3 | 3-Cyclohexen-1-ol, 4-methyl-1-(1-methylethyl)- | Terpinenol-4 | 0.04780000 | | 48. | 68527-77-5 | 3-Cyclohexene-1-methanol, 2,4,6-trimethyl- | Isocyclogeraniol | 0.04640000 | | 49. | 35852-46-1 | Pentanoic acid, (3 _Z_)-3-hexen-1-yl ester | Cis-3-Hexenyl Valerate | 0.04580000 | | 50. | 2756-56-1 | Bicyclo\\[2.2.1\\]heptan-2-ol, 1,7,7-trimethyl-, 2-propanoate, (1 _R_,2 _R_,4 _R_)-rel- | Iso Bornyl Propionate | 0.04540000 | | 51. | 14374-92-6 | Benzene, 1-methyl-4-(1-methylethyl)-2-(1-propen-1-yl)- | Verdoracine | 0.04460000 | | 52. | 6784-13-0 | 3-Cyclohexene-1-propanal, \u03b2,4-dimethyl- | Limonenal | 0.04380000 | | 53. | 8000-41-7 | 2-(4-methyl-1-cyclohex-3-enyl)propan-2-ol | Alpha Terpineol | 0.04320000 | | 54. | 41884-28-0 | 1-Hexanol, 5-methyl-2-(1-methylethyl)-, (2R)- | Tetrahydro Lavandulol | 0.04230000 | | 55. | 22457-23-4 | 3-Heptanone, 5-methyl-, oxime | Stemone\u00ae | 0.04140000 | | 56. | 104-50-7 | 2(3 _H_)-Furanone, 5-butyldihydro- | Gamma Octalactone | 0.04080000 | | 57. | 143-08-8 | 1-Nonanol | Nonyl Alcohol | 0.04070000 | | 58. | 3613-30-7 | Octanal, 7-methoxy-3,7-dimethyl- | Methoxycitronellal | 0.04020000 | | 59. | 67634-00-8 | Acetic acid, 2-(3-methylbutoxy)-, 2-propen-1-yl ester | Allyl Amyl Glycolate | 0.04000000 | | 60. | 464-45-9 | Bicyclo\\[2.2.1\\]heptan-2-ol, 1,7,7-trimethyl-, (1 _S_,2 _R_, 4 _S_)- | 1-Borneol | 0.03980000 | | 61. | 124-76-5 | Bicyclo\\[2.2.1\\]heptan-2-ol, 1,7,7-trimethyl-, (1 _R_,2 _R_, 4R)-rel- | 1.7.7-Trimethyl-Bicyclo-1.2.2-Heptanol-2 | 0.03980000 | | 62. | 67874-72-0 | Cyclohexanol, 2-(1,1-dimethylpropyl)-, 1-acetate | Coniferan | 0.03980000 | | 63. | 80-26-2 | 3-Cyclohexene-1-methanol, \u03b1,\u03b1,4-trimethyl-, 1-acetate | Terpinyl Acetate | 0.03920000 | | 64. | 498-81-7 | Cyclohexanemethanol, \u03b1, \u03b1,4-trimethyl- | Dihydro Terpineol | 0.03920000 | | 65. | 112-45-8 | 10-Undecenal | Undecylenic aldehyde | 0.03900000 | | 66. | 35044-57-6 | 2,4-Cyclohexadiene-1-carboxylic acid, 2,6,6-trimethyl-, ethyl ester | Ethyl Safranate | 0.03880000 | | 67. | 106-21-8 | 1-Octanol, 3,7-dimethyl- | Dimethyl Octanol | 0.03860000 | | 68. | 84560-00-9 | Cyclopentanol, 2-pentyl- | Cyclopentol | 0.03790000 | | 69. | 82461-14-1 | Furan, tetrahydro-2,4-dimethyl-4-phenyl- | Rhubafuran\u00ae | 0.03780000 | | 70. | 56011-02-0 | Benzene, \\[2-(3-methylbutoxy)ethyl\\]- | Phenyl Ethyl Isoamyl Ether | 0.03690000 | | 71. | 103-37-7 | Butanoic acid, phenylmethyl ester | Benzyl Butyrate | 0.03660000 | | 72. | 6378-65-0 | Hexyl hexanoate | Hexyl hexanoate | 0.03490000 | | 73. | 118-61-6 | Benzoic acid, 2-hydroxy-, ethyl ester | Ethyl salicylate | 0.03480000 | | 74. | 98-52-2 | Cyclohexanol, 4-(1,1-dimethylethyl)- | Patchon | 0.03480000 | | 75. | 115-99-1 | 1,6-Octadien-3-ol, 3,7-dimethyl-, 3-formate | Linalyl Formate | 0.03440000 | | 76. | 112-54-9 | Dodecanal | Lauric Aldehyde | 0.03440000 | | 77. | 53046-97-2 | 3,6-Nonadien-1-ol, (3 _Z_, 6 _Z_)- | 3,6 Nonadien-1-ol | 0.03360000 | | 78. | 76649-25-7 | 3,6-Nonadien-1-ol | 3,6-Nonadien-1-ol | 0.03360000 | | 79. | 141-25-3 | 3,7-Dimethyloct-6-en-1-ol | Rhodinol | 0.03290000 | | 80. | 1975-78-6 | Decanenitrile | Decanonitrile | 0.03250000 | | 81. | 2216-51-5 | Cyclohexanol, 5-methyl-2-(1-methylethyl)-, (1 _R_,2 _S_, 5 _R_)- | L-Menthol | 0.03230000 | | 82. | 3658-77-3 | 4-hydroxy-2,5-dimethylfuran-3-one | Pineapple Ketone | 0.03200000 | | 83. | 103-93-5 | Propanoic acid, 2-methyl-, 4-methylphenyl ester | Para Cresyl iso-Butyrate | 0.03120000 | | 84. | 24717-86-0 | Propanoic acid, 2-methyl-, (1 _R_,2 _S_,4 _R_)-1,7,7-trimethylbicyclo \\[2.2.1\\] hept-2-yl ester, rel- | Abierate | 0.03110000 | | 85. | 67845-46-9 | Acetaldehyde, 2-(4-methylphenoxy)- | Aldehyde XI | 0.03090000 | | 86. | 67883-79-8 | 2-Butenoic acid, 2-methyl-, (3 _Z_)-3-hexen-1-yl ester, (2E)- | Cis-3-Hexenyl Tiglate | 0.03060000 | | 87. | 33885-51-7 | Bicyclo\\[3.1.1\\]hept-2-ene-2-propanal, 6,6-dimethyl- | Pino Acetaldehyde | 0.03040000 | | 88. | 105-85-1 | 6-Octen-1-ol, 3,7-dimethyl-, 1-formate | Citronellyl Formate | 0.03000000 | | 89. | 70214-77-6 | 2-Nonanol, 6,8-dimethyl- | Nonadyl | 0.03010000 | | 90. | 215231-33-7 | Cyclohexanol, 1-methyl-3-(2-methylpropyl)- | Rossitol | 0.02990000 | | 91. | 120-72-9 | 1 _H_-Indole | Indole | 0.02980000 | | 92. | 2463-77-6 | 2-Undecenal | 2-Undecene-1-al | 0.02970000 | | 93. | 675-09-2 | 2 _H_-Pyran-2-one, 4,6-dimethyl- | Levistamel | 0.02940000 | | 94. | 98-55-5 | 3-Cyclohexene-1-methanol, \u03b1,\u03b1,4-trimethyl- | Alpha-Terpineol | 0.02830000 | | 95. | 81786-73-4 | 3-Hepten-2-one, 3,4,5,6,6-pentamethyl-, (3 _Z_)- | Koavone | 0.02750000 | | 96. | 122-97-4 | Benzenepropanol | Phenyl Propyl Alcohol | 0.02710000 | | 97. | 39212-23-2 | 2(3 _H_)-Furanone, 5-butyldihydro-4-methyl- | Methyl Octalactone | 0.02700000 | | 98. | 53767-93-4 | 7-Octen-2-ol, 2,6-dimethyl-, 2-acetate | Dihydro Terpinyl Acetate | 0.02690000 | | 99. | 35044-59-8 | 1,3-Cyclohexadiene-1-carboxylic acid, 2,6,6-trimethyl-, ethyl ester | Ethyl Safranate | 0.02660000 | | 100. | 104-55-2 | 2-Propenal, 3-phenyl- | Cinnamic Aldehyde | 0.02650000 | | 101. | 144-39-8 | 1,6-Octadien-3-ol, 3,7-dimethyl-, 3-propanoate | Linalyl Propionate | 0.02630000 | | 102. | 61931-80-4 | 1,6-Nonadien-3-ol, 3,7-dimethyl-, 3-acetate | 3,7-Dimethyl-1,6-nonadien-3-yl acetate | 0.02630000 | | 103. | 102-13-6 | Benzeneacetic acid, 2-methylpropyl ester | Iso Butyl Phenylacetate | 0.02630000 | | 104. | 65443-14-3 | Cyclopentanone, 2,2,5-trimethyl-5-pentyl- | Veloutone | 0.02610000 | | 105. | 141-12-8 | 2,6-Octadien-1-ol, 3,7-dimethyl-, 1-acetate, (2 _Z_)- | Neryl Acetate | 0.02560000 | | 106. | 105-87-3 | 2,6-Octadien-1-ol, 3,7-dimethyl-, 1-acetate, (2 _E_)- | Geranyl acetate | 0.02560000 | | 107. | 68141-17-3 | Undecane, 1,1-dimethoxy-2-methyl- | Methyl Nonyl Acetaldehyde Dimethyl Acetal | 0.02550000 | | 108. | 2206-94-2 | Benzenemethanol, \u03b1-methylene-, 1-acetate | Indocolore | 0.02550000 | | 109. | 10528-67-3 | Cyclohexanepropanol, \u03b1-methyl- | Cyclohexylmagnol | 0.02550000 | | 110. | 123-11-5 | Benzaldehyde, 4-methoxy- | Anisic Aldehyde | 0.02490000 | | 111. | 57576-09-7 | Cyclohexanol, 5-methyl-2-(1-methylethenyl)-, 1-acetate, (1 _R_,2 _S_,5 _R_)- | Iso Pulegol Acetate | 0.02480000 | | 112. | 51566-62-2 | 6-Octenenitrile, 3,7-dimethyl- | Citronellyl Nitrile | 0.02470000 | | 113. | 60335-71-9 | 2 _H_-Pyran, 3,6-dihydro-4-methyl-2-phenyl- | Rosyrane Super | 0.02470000 | | 114. | 30385-25-2 | 6-Octen-2-ol, 2,6-dimethyl- | Dihydromyrcenol | 0.02440000 | | 115. | 101-84-8 | Benzene, 1,1'-oxybis- | Diphenyl Oxide | 0.02230000 | | 116. | 136-60-7 | Benzoic acid, butyl ester | Butyl Benzoate | 0.02170000 | | 117. | 93939-86-7 | 5,8-Methano-2 _H_-1-benzopyran, 6-ethylideneoctahydro- | Rhuboflor | 0.02120000 | | 118. | 83926-73-2 | Cyclohexanepropanol, \u03b1,\u03b1-dimethyl- | Coranol | 0.02100000 | | 119. | 125109-85-5 | Benzenepropanal, \u03b2-methyl-3-(1-methylethyl)- | Florhydral | 0.02070000 | | 120. | 104-21-2 | Benzenemethanol, 4-methoxy-, 1-acetate | Anisyl Acetate | 0.02050000 | | 121. | 1365-19-1 | 2-Furanmethanol, 5-ethenyltetrahydro-\u03b1,\u03b1,5-trimethyl- | Linalool Oxide | 0.02050000 | | 122. | 137-03-1 | Cyclopentanone, 2-heptyl- | Frutalone | 0.02040000 | | 123. | 2563-07-7 | Phenol, 2-ethoxy-4-methyl- | Ultravanil | 0.02030000 | | 124. | 1128-08-1 | 2-Cyclopenten-1-one, 3-methyl-2-pentyl- | Dihydrojasmone | 0.02020000 | | 125. | 7493-57-4 | Benzene, \\[2-(1-propoxyethoxy)ethyl\\]- | Acetaldehyde | 0.01990000 | | 126. | 141-25-3 | 7-Octen-1-ol, 3,7-dimethyl- | Rhodinol | 0.01970000 | | 127. | 216970-21-7 | Bicyclo\\[4.3.1\\]decane, 3-methoxy-7,7-dimethyl-10-methylene- | 3-Methoxy-7,7-dimethyl-10-methylenebicyclo\\[4.3 .1\\]decane | 0.01960000 | | 128. | 319002-92-1 | Propanoic acid, 2-(1,1-dimethylpropoxy)-, propyl ester, (2 _S_)- | Sclareolate\u00ae | 0.01960000 | | 129. | 85-91-6 | Benzoic acid, 2-(methylamino)-, methyl | Dimethyl anthranilate | 0.01930000 | | | | ester | | | | 130. | 13828-37-0 | Cyclohexanemethanol, 4-(1-methylethyl)-, cis- | Mayol | 0.01920000 | | 131. | 26330-65-4 | ( _E_)-6-ethyl-3-methyloct-6-en-1-ol | Super Muguet | 0.01850000 | | 132. | 7540-51-4 | 6-Octen-1-ol, 3,7-dimethyl-, (3 _S_)- | L-Citronellol | 0.01830000 | | 133. | 106-22-9 | 6-Octen-1-ol, 3,7-dimethyl- | Citronellol | 0.01830000 | | 134. | 543-39-5 | 7-Octen-2-ol, 2-methyl-6-methylene- | Myrcenol | 0.01820000 | | 135. | 7775-00-0 | Benzenepropanal, 4-(1-methylethyl)- | Cyclemax | 0.01820000 | | 136. | 18479-54-4 | 4,6-Octadien-3-ol, 3,7-dimethyl- | Muguol | 0.01800000 | | 137. | 29214-60-6 | Octanoic acid, 2-acetyl-, ethyl ester | Gelsone | 0.01790000 | | 138. | 1209-61-6 | 5-Oxatricyclo\\[8.2.0.04,6\\] dodecane, 4,9,12,12-tetramethyl- | Tobacarol | 0.01730000 | | 139. | 57934-97-1 | 2-Cyclohexene-1-carboxylic acid, 2-ethyl-6, 6-dimethyl-, ethyl ester | Givescone | 0.01710000 | | 140. | 14901-07-6 | 3-Buten-2-one, 4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-, (3 _E_)- | Beta-Ionone | 0.01690000 | | 141. | 64001-15-6 | 4,7-Methano-1 _H_-inden-5-ol, octahydro-, 5-acetate | Dihydro Cyclacet | 0.01630000 | | 142. | 95-41-0 | 2-Cyclopenten-1-one, 2-hexyl- | Iso Jasmone T | 0.01600000 | | 143. | 134-20-3 | Benzoic acid, 2-amino-, methyl ester | Methyl Anthranilate | 0.01580000 | | 144. | 100-06-1 | Ethanone, 1-(4-methoxyphenyl)- | Para Methoxy Acetophenone | 0.01550000 | | 145. | 105-86-2 | 2,6-Octadien-1-ol, 3,7-dimethyl-, 1-formate, (2 _E_) | Geranyl Formate | 0.01540000 | | 146. | 154171-77-4 | Spiro\\[1,3-dioxolane-2, 8'(5' _H_)-\\[2 _H_-2,4a\\] methanonaphthalene\\], hexahydro-1',1',5',5'-tetramethyl-, (2' _S_,4'a _S_, 8'aS)- (9CI) | Ysamber K\u00ae | 0.01470000 | | 147. | 154171-76-3 | Spiro\\[1,3-dioxolane-2,8'(5' _H_)-\\[2 _H-_ 2,4a\\]methanonaphthalenel, | Ysamber | 0.01470000 |\\ | | | hexahydro-1',1',5',5'-tetramethyl- | | |\\ | 148. | 127-41-3 | 3-Buten-2-one, 4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-, (3 _E_)- | Alpha-Ionone | 0.01440000 |\\ | 149. | 151-05-3 | Benzeneethanol, \u03b1,\u03b1-dimethyl-, 1-acetate | Dimethyl Benzyl Carbinyl Acetate | 0.01390000 |\\ | 150. | 2500-83-6 | 4,7-Methano-1 _H_-inden-5-ol, 3a,4,5,6,7,7a-hexahydro-, 5-acetate | Flor Acetate | 0.01370000 |\\ | 151. | 150-84-5 | 6-Octen-1-ol, 3,7-dimethyl-, 1-acetate | Citronellyl acetate | 0.01370000 |\\ | 152. | 30310-41-9 | 2 _H_-Pyran, tetrahydro-2-methyl-4-methylene-6-phenyl- | Pelargene | 0.01350000 |\\ | 153. | 68845-00-1 | Bicyclo\\[3.3.1\\]nonane, 2-ethoxy-2,6,6-trimethyl-9-methylene- | Boisiris | 0.01350000 |\\ | 154. | 106-24-1 | 2,6-Octadien-1-ol, 3,7-dimethyl-, (2 _E_)- | Geraniol | 0.01330000 |\\ | 155. | 106-25-2 | 2,6-Octadien-1-ol, 3,7-dimethyl-, (2 _Z_)- | Nerol | 0.01330000 |\\ | 156. | 75975-83-6 | Bicyclo \\[7.2.0\\]undec-4-ene, 4,11,11-trimethyl-8-methylene-, (1 _R_,4 _E_,9 _S_)- | Vetyvenal | 0.01280000 |\\ | 157. | 19870-74-7 | 1 _H_-3a,7-Methanoazulene, octahydro-6-methoxy-3,6, 8,8-tetramethyl-, (3 _R_,3a _S_, 6 _S_,7 _R_,8a _S_)- | Cedryl methyl ether | 0.01280000 |\\ | 158. | 87-44-5 | Bicyclo \\[7.2.0\\]undec-4-ene, 4,11,11-trimethyl-8-methylene-, (1 _R_,4 _E_,9 _S_)- | Caryophyllene Extra | 0.01280000 |\\ | 159. | 54440-17-4 | 1 _H_-Inden-1-one, 2,3-dihydro-2,3,3-trimethyl- | Safraleine | 0.01260000 |\\ | 160. | 110-98-5 | 2-Propanol, 1,1'-oxybis- | Dipropylene Glycol | 0.01250000 |\\ | 161. | 41890-92-0 | 2-Octanol, 7-methoxy-3,7-dimethyl- | Osyrol\u00ae | 0.01250000 |\\ | 162. | 71077-31-1 | 4,9-Decadienal, 4,8-dimethyl- | Floral Super | 0.01230000 |\\ | 163. | 65-85-0 | Benzoic Acid | Benzoic Acid | 0.01220000 |\\ | 164. | 61444-38-0 | 3-Hexenoic acid, (3 _Z_)-3-hexen-1-yl ester, (3 _Z_)- | cis-3-hexenyl-cis-3-hexenoate | 0.01220000 |\\ | 165. | 116044-44-1 | Bicyclo\\[2.2.1\\]hept-5-ene-2-carboxylic acid, 3-(1- | Herbanate | 0.01210000 |\\ | | | methylethyl)-, ethyl ester, (1 _R_,2 _S_,3 _S_,4 _S_)-rel- | | |\\ | 166. | 104-54-1 | 2-Propen-1-ol, 3-phenyl- | Cinnamic Alcohol | 0.01170000 |\\ | 167. | 78-35-3 | Propanoic acid, 2-methyl-, 1-ethenyl-1,5-dimethyl-4-hexen-1-yl ester | Linalyl Isobutyrate | 0.01170000 |\\ | 168. | 23495-12-7 | Ethanol, 2-phenoxy-, 1-propanoate | Phenoxy Ethyl Propionate | 0.01130000 |\\ | 169. | 103-26-4 | 2-Propenoic acid, 3-phenyl-, methyl ester | Methyl Cinnamate | 0.01120000 |\\ | 170. | 67634-14-4 | Benzenepropanal, 2-ethyl-\u03b1,\u03b1-dimethyl- | Florazon (ortho-isomer) | 0.01110000 |\\ | 171. | 5454-19-3 | Propanoic acid, decyl ester | _N_-Decyl Propionate | 0.01100000 |\\ | 172. | 93-16-3 | Benzene, 1,2-dimethoxy-4-(1-propen-1-yl)- | Methyl Iso Eugenol | 0.01100000 |\\ | 173. | 81782-77-6 | 3-Decen-5-ol, 4-methyl- | 4-Methyl-3-decen-5-ol | 0.01070000 |\\ | 174. | 67845-30-1 | Bicyclo \\[2.2.2\\] oct-5-ene-2-carboxaldehyde, 6-methyl-8-(1-methylethyl)- | Maceal | 0.01060000 |\\ | 175. | 97-53-0 | Phenol, 2-methoxy-4-(2-propen-1-yl)- | Eugenol | 0.01040000 |\\ | 176. | 120-57-0 | 1,3-Benzodioxole-5-carboxaldehyde | Heliotropin | 0.01040000 |\\ | 177. | 93-04-9 | Naphthalene, 2-methoxy- | Beta Naphthyl Methyl Ether Extra 99 | 0.01040000 |\\ | 178. | 4826-62-4 | 2-Dodecenal | 2 Dodecene-1-al | 0.01020000 |\\ | 179. | 20407-84-5 | 2-Dodecenal, (2 _E_)- | Aldehyde Mandarin | 0.01020000 |\\ | 180. | 5462-06-6 | Benzenepropanal, 4-methoxy-\u03b1-methyl- | Canthoxal | 0.01020000 |\\ | 181. | 94-60-0 | 1,4-Cyclohexanedicarboxy lic acid, 1,4-dimethyl ester | Dimethyl | 1,4-cyclohexanedicarboxylate | 0.01020000 |\\ | 182. | 57378-68-4 | 2-Buten-1-one, 1-(2,6,6-trimethyl-3-cyclohexen-1-yl)- | delta-Damascone | 0.01020000 |\\ | 183. | 17283-81-7 | 2-Butanone, 4-(2,6,6-trimethyl-1-cyclohexen-1-yl)- | Dihydro Beta Ionone | 0.01020000 |\\ | 184. | 1885-38-7 | 2-Propenenitrile, 3-phenyl-, (2 _E_)- | Cinnamalva | 0.01010000 |\\ | 185. | 103-48-0 | Propanoic acid, 2-methyl-, 2-phenylethyl ester | Phenyl Ethyl Iso Butyrate | 0.00994000 |\\ | 186. | 488-10-8 | 2-Cyclopenten-1-one, 3-methyl-2-(2 _Z_)-2-penten-1-yl- | Cis Jasmone | 0.00982000 |\\ | 187. | 7492-67-3 | Acetaldehyde, 2-\\[(3,7-dimethyl-6-octen-1-yl) oxy\\]- | Citronellyloxyacetaldehyde | 0.00967000 |\\ | 188. | 68683-20-5 | 1-Cyclohexene-1-ethanol, 4-(1-methylethyl)-, 1-formate | Iso Bergamate | 0.00965000 |\\ | 189. | 3025-30-7 | 2,4-Decadienoic acid, ethyl ester, (2 _E_,4 _Z_)- | Ethyl 2,4-Decadienoate | 0.00954000 |\\ | 190. | 103-54-8 | 2-Propen-1-ol, 3-phenyl-, 1-acetate | Cinnamyl Acetate | 0.00940000 |\\ | 191. | 18127-01-0 | Benzenepropanal, 4-(1,1-dimethylethyl)- | Bourgeonal | 0.00934000 |\\ | 192. | 3738-00-9 | Naphtho\\[2,1-b\\]furan, dodecahydro-3a,6,6,9a-tetramethyl- | Ambrox\u00ae or Cetalox\u00ae or Synambran | 0.00934000 |\\ | 193. | 51519-65-4 | 1,4-Methanonaphthalen-5(1 _H_)-one, 4,4a,6,7,8,8a-hexahydro- | Tamisone | 0.00932000 |\\ | 194. | 148-05-1 | Dodecanoic acid, 12-hydroxy-, \u03bb-lactone (6CI, 7CI); 1,12- | Dodecalactone | 0.00931000 |\\ | 195. | 6790-58-5 | (3a _R_,5a _S_,9a _S_,9b _R_)-3a,6,6,9a-tetramethyl-2,4,5,5a,7,8,9,9b-octahydro-1 _H-_ benzo\\[e\\]\\[1\\]benzofuran | Ambronat\u00ae or Ambroxan\u00ae | 0.00930000 |\\ | 196. | 86-26-0 | 1,1'-Biphenyl, 2-methoxy- | Methyl Diphenyl Ether | 0.00928000 |\\ | 197. | 68738-94-3 | 2-Naphthalenecarboxaldehy de, octahydro-8,8-dimethyl | Cyclomyral\u00ae | 0.00920000 |\\ | 198. | 2705-87-5 | Cyclohexanepropanoic acid, 2-propen-1-yl ester | Allyl Cyclohexane Propionate | 0.00925000 |\\ | 199. | 7011-83-8 | 2(3 _H_)-Furanone, 5-hexyldihydro-5-methyl- | Lactojasmone\u00ae | 0.00885000 |\\ | 200. | 61792-11-8 | 2,6-Nonadienenitrile, 3,7-dimethyl- | Lemonile\u00ae | 0.00884000 |\\ | 201. | 692-86-4 | 10-Undecenoic acid, ethyl ester | Ethyl Undecylenate | 0.00882000 |\\ | 202. | 103-95-7 | Benzenepropanal, \u03b1-methyl-4-(1-methylethyl)- | Cymal | 0.00881000 |\\ | 203. | 13019-22-2 | 9-Decen-1-ol | Rosalva | 0.00879000 |\\ | 204. | 94201-19-1 | 1-Oxaspiro\\[4.5\\]decan-2-one, 8-methyl- | Methyl Laitone 10% TEC | 0.00872000 |\\ | 205. | 104-61-0 | 2(3 _H_)-Furanone, dihydro-5-pentyl- | \u03b3-Nonalactone | 0.00858000 |\\ | 206. | 706-14-9 | 2(3 _H_)-Furanone, 5-hexyldihydro- | \u03b3 -Decalactone | 0.00852000 |\\ | 207. | 24720-09-0 | 2-Buten-1-one, 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-, (2 _E_)- | \u03b1-Damascone | 0.00830000 |\\ | 208. | 39872-57-6 | 2-Buten-1-one, 1-(2,4,4-trimethyl-2-cyclohexen-1-yl)-, (2 _E_)- | Isodamascone | 0.00830000 |\\ | 209. | 705-86-2 | 2 _H_-Pyran-2-one, tetrahydro-6-pentyl- | Decalactone | 0.00825000 |\\ | 210. | 67634-15-5 | Benzenepropanal, 4-ethyl-\u03b1,\u03b1-dimethyl- | Floralozone | 0.00808000 |\\ | 211. | 40527-42-2 | 1,3-Benzodioxole, 5-(diethoxymethyl)- | Heliotropin Diethyl Acetal | 0.00796000 |\\ | 212. | 56973-85-4 | 4-Penten-1-one, 1-(5,5-dimethyl-1-cyclohexen-1-yl)- | Neobutenone \u03b1 | 0.00763000 |\\ | 213. | 128-51-8 | Bicyclo\\[3.1.1\\]hept-2-ene-2-ethanol, 6,6-dimethyl-, 2-acetate | Nopyl Acetate | 0.00751000 |\\ | 214. | 103-36-6 | 2-Propenoic acid, 3-phenyl-, ethyl ester | Ethyl Cinnamate | 0.00729000 |\\ | 215. | 5182-36-5 | 1,3-Dioxane, 2,4,6-trimethyl-4-phenyl- | Floropal\u00ae | 0.00709000 |\\ | 216. | 42604-12-6 | Cyclododecane, (methoxymethoxy)- | Boisambrene | 0.00686000 |\\ | 217. | 33885-52-8 | Bicyclo\\[3.1.1\\]hept-2-ene-2-propanal, \u03b1,\u03b1,6,6-tetramethyl- | Pinyl Iso Butyrate Alpha | 0.00685000 |\\ | 218. | 92015-65-1 | 2(3 _H_)-Benzofuranone, hexahydro-3,6-dimethyl- | Natactone | 0.00680000 |\\ | 219. | 63767-86-2 | Cyclohexanemethanol, \u03b1-methyl-4-(1-methylethyl)- | Mugetanol | 0.00678000 |\\ | 220. | 3288-99-1 | Benzeneacetonitrile, 4-(1, 1-dimethylethyl)- | Marenil CI | 0.00665000 |\\ | 221. | 35044-68-9 | 2-Buten-1-one, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)- | beta-Damascone | 0.00655000 |\\ | 222. | 41724-19-0 | 1,4-Methanonaphthalen-6(2 _H_)-one, octahydro-7- | Plicatone | 0.00652000 |\\ | | | methyl- | | |\\ | 223. | 75147-23-8 | Bicyclo\\[3.2.1\\]octan-8-one, 1,5-dimethyl-, oxime | Buccoxime\u00ae | 0.00647000 |\\ | 224. | 25634-93-9 | 2-Methyl-5-phenylpentan-1-ol | Rosaphen\u00ae 600064 | 0.00637000 |\\ | 225. | 55066-48-3 | 3-Methyl-5-phenylpentanol | Phenyl Hexanol | 0.00637000 |\\ | 226. | 495-62-5 | Cyclohexene, 4-(1,5-dimethyl-4-hexen-1-ylidene)-1-methyl- | Bisabolene | 0.00630000 |\\ | 227. | 2785-87-7 | Phenol, 2-methoxy-4-propyl- | Dihydro Eugenol | 0.00624000 |\\ | 228. | 87-19-4 | Benzoic acid, 2-hydroxy-, 2-methylpropyl ester | Iso Butyl Salicylate | 0.00613000 |\\ | 229. | 4430-31-3 | 2 _H_-1-Benzopyran-2-one, octahydro- | Octahydro Coumarin | 0.00586000 |\\ | 230. | 38462-22-5 | Cyclohexanone, 2-(1-mercapto-1-methylethyl)-5-methyl- | Ringonol 50 TEC | 0.00585000 |\\ | 231. | 77-83-8 | 2-Oxiranecarboxylic acid, 3-methyl-3-phenyl-, ethyl ester | Ethyl Methyl Phenyl Glycidate | 0.00571000 |\\ | 232. | 37677-14-8 | 3-Cyclohexene-1-carboxaldehyde, 4-(4-methyl-3-penten-1-yl)- | Iso Hexenyl Cyclohexenyl Carboxaldehyde | 0.00565000 |\\ | 233. | 103-60-6 | Propanoic acid, 2-methyl-, 2-phenoxyethyl ester | Phenoxy Ethyl iso-Butyrate | 0.00562000 |\\ | 234. | 18096-62-3 | Indeno\\[1,2-d\\]-1,3-dioxin, 4,4a,5,9b-tetrahydro- | Indoflor\u00ae | 0.00557000 |\\ | 235. | 63500-71-0 | 2 _H_-Pyran-4-ol, tetrahydro-4-methyl-2-(2-methylpropyl)- | Florosa Q/ Florol | 0.00557000 |\\ | 236. | 65405-84-7 | Cyclohexanebutanal, \u03b1,2, 6,6-tetramethyl- | Cetonal\u00ae | 0.00533000 |\\ | 237. | 171102-41-3 | 4,7-Methano-1 _H_-inden-6-ol, 3a,4,5,6,7,7a-hexahydro-8,8-dimethyl-, 6-acetate | Flor Acetate | 0.00530000 |\\ | 238. | 10339-55-6 | 1,6-Nonadien-3-ol, 3,7-dimethyl- | Ethyl linalool | 0.00520000 |\\ | 239. | 23267-57-4 | 3-Buten-2-one, 4-(2,2,6-trimethyl-7-oxabicyclo\\[4.1.0\\]hept-1-yl)- | Ionone Epoxide Beta | 0.00520000 |\\ | 240. | 97-54-1 | Phenol, 2-methoxy-4-(1-propen-1-yl)- | Isoeugenol | 0.00519000 |\\ | 241. | 67663-01-8 | 2(3 _H_)-Furanone, 5-hexyldihydro-4-methyl- | Peacholide | 0.00512000 |\\ | 242. | 33885-52-8 | Bicyclo\\[3.1.1\\]hept-2-ene-2-propanal, \u03b1,\u03b1,6,6-tetramethyl- | Pinyl Iso Butyrate Alpha | 0.00512000 |\\ | 243. | 23696-85-7 | 2-Buten-1-one, 1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)- | Damascenone | 0.00503000 |\\ | 244. | 80-71-7 | 2-Cyclopenten-1-one, 2-hydroxy-3-methyl- | Maple Lactone | 0.00484000 |\\ | 245. | 67662-96-8 | Propanoic acid, 2,2-dimethyl-, 2-phenylethyl ester | Pivarose Q | 0.00484000 |\\ | 246. | 2437-25-4 | Dodecanenitrile | Clonal | 0.00480000 |\\ | 247. | 141-14-0 | 6-Octen-1-ol, 3,7-dimethyl-, 1-propanoate | Citronellyl Propionate | 0.00469000 |\\ | 248. | 54992-90-4 | 3-Buten-2-one, 4-(2,2,3,6-tetramethylcyclohexyl)- | Myrrhone | 0.00460000 |\\ | 249. | 55066-49-4 | Benzenepentanal, \u03b2-methyl- | Mefranal | 0.00455000 |\\ | 250. | 7493-74-5 | Acetic acid, 2-phenoxy-, 2-propen-1-yl ester | Allyl Phenoxy Acetate | 0.00454000 |\\ | 251. | 80-54-6 | Benzenepropanal, 4-(1,1-dimethylethyl)-\u03b1-methyl- | Lilial\u00ae | 0.00444000 |\\ | 252. | 86803-90-9 | 4,7-Methano-1 _H_-indene-2-carboxaldehyde, octahydro-5-methoxy- | Scentenal\u00ae | 0.00439000 |\\ | 253. | 68991-97-9 | 2-Naphthalenecarboxald ehyde, 1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl- | Melafleur | 0.00436000 |\\ | 254. | 18871-14-2 | Pentitol, 1,5-anhydro-2,4-dideoxy-2-pentyl-, 3-acetate | Jasmal | 0.00434000 |\\ | 255. | 58567-11-6 | Cyclododecane, (ethoxymethoxy)- | Boisambren Forte | 0.00433000 |\\ | 256. | 94400-98-3 | Naphth\\[2,3-b\\]oxirene, 1a,2,3,4,5,6,7,7a-octahydro-1a,3,3,4,6,6-hexamethyl-, (1a _R_,4 _S_,7a _S_)-rel- | Molaxone | 0.00425000 |\\ | 257. | 79-69-6 | 3-Buten-2-one, 4-(2,5,6,6-tetramethyl-2-cyclohexen-1-yl)- | alpha-Irone | 0.00419000 |\\ | 258. | 65442-31-1 | Quinoline, 6-(1-methylpropyl)- | Iso Butyl Quinoline | 0.00408000 |\\ | 259. | 87731-18-8 | Carbonic acid, 4-cycloocten-1-yl methyl ester | Violiff | 0.00401000 |\\ | 260. | 173445-65-3 | 1 _H_-Indene-5-propanal, 2, 3-dihydro-3,3-dimethyl- | Hivernal (A-isomer) | 0.00392000 |\\ | 261. | 23911-56-0 | Ethanone, 1-(3-methyl-2-benzofuranyl)- | Nerolione | 0.00383000 |\\ | 262. | 52474-60-9 | 3-Cyclohexene-1-carboxaldehyde, 1-methyl-3-(4-methyl-3-penten-1-yl) | Precyclemone B | 0.00381000 |\\ | 263. | 139539-66-5 | 6-Oxabicyclo\\[3.2.1\\] octane, 5-methyl-1-(2,2,3-trimethyl-3-cyclopenten-1-yl)- | Cassifix | 0.00381000 |\\ | 264. | 80858-47-5 | Benzene, \\[2-(cyclohexyloxy)ethyl\\]- | Phenafleur | 0.00380000 |\\ | 265. | 32764-98-0 | 2 _H_-Pyran-2-one, tetrahydro-6-(3-penten-1-yl)- | Jasmolactone | 0.00355000 |\\ | 266. | 78417-28-4 | 2,4,7-Decatrienoic acid, ethyl ester | Ethyl | | 2,4,7-decatrienoate | 0.00353000 |\\ | 267. | 140-26-1 | Butanoic acid, 3-methyl-, 2-phenylethyl ester | Beta Phenyl Ethyl Isovalerate | 0.00347000 |\\ | 268. | 105-90-8 | 2,6-Octadien-1-ol, 3,7-dimethyl-, 1-propanoate, (2E)- | Geranyl Propionate | 0.003360000 |\\ | 269. | 41816-03-9 | Spire\\[1,4-methanonaphthalene-2(1 _H_),2'-oxirane\\], 3,4,4a, 5,8,8a-hexahydro-3',7-dimethyl- | Rhubofix\u00ae | 0.00332000 |\\ | 270. | 7070-15-7 | Ethanol, 2-\\[\\[(1 _R_,2 _R_,4 _R_)-1, 7,7-trimethylbicyclo\\[2.2.1\\] hept-2-yl\\]oxy\\]-, rel- | Arbanol | 0.00326000 |\\ | 271. | 93-29-8 | Phenol, 2-methoxy-4-(1-propen-1-yl)-, 1-acetate | Iso Eugenol Acetate | 0.00324000 |\\ | 272. | 476332-65-7 | 2 _H_-Indeno\\[4,5-b\\]furan, decahydro-2,2,6,6,7,8,8-heptamethyl- | Amber Xtreme Compound 1 | 0.00323000 |\\ | 273. | 68901-15-5 | Acetic acid, 2-(cyclohexyloxy)-, 2-propen-1-yl ester | Cyclogalbanate | 0.00323000 |\\ | 274. | 107-75-5 | Octanal, 7-hydroxy-3,7-dimethyl- | Hydroxycitronellal | 0.00318000 |\\ | 275. | 68611-23-4 | Naphtho\\[2,1-b\\]furan, 9b-ethyldodecahydro-3a,7,7-trimethyl- | Grisalva | 0.00305000 |\\ | 276. | 313973-37-4 | 1,6-Heptadien-3-one, 2-cyclohexyl- | Pharaone | 0.00298000 |\\ | 277. | 137-00-8 | 5-Thiazoleethanol, 4-methyl- | Sulfurol | 0.00297000 |\\ | 278. | 7779-30-8 | 1-Penten-3-one, 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)- | Methyl Ionone | 0.00286000 |\\ | 279. | 127-51-5 | 3-Buten-2-one, 3-methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)- | Isoraldeine Pure | 0.00282000 |\\ | 280. | 72903-27-6 | 1,4-Cyclohexanedicarboxy lic acid, 1,4-diethyl ester | Fructalate\u2122 | 0.00274000 |\\ | 281. | 7388-22-9 | 3-Buten-2-one, 4-(2,2-dimethyl-6-methylenecyclohexyl)-3-methyl- | Ionone Gamma Methyl | 0.00272000 |\\ | 282. | 104-67-6 | 2(3 _H_)-Furanone, 5-heptyldihydro- | gamma-Undecalactone (racemic) | 0.00271000 |\\ | 283. | 1205-17-0 | 1,3-Benzodioxole-5-propanal, \u03b1-methyl- | Helional | 0.00270000 |\\ | 284. | 33704-61-9 | 4 _H_-Inden-4-one, 1,2,3,5,6, 7-hexahydro-1,1,2,3,3-pentamethyl- | Cashmeran | 0.00269000 |\\ | 285. | 36306-87-3 | Cyclohexanone, 4-(1-ethoxyethenyl)-3,3,5,5-tetramethyl- | Kephalis | 0.00269000 |\\ | 286. | 97384-48-0 | Benzenepropanenitrile, \u03b1-ethenyl-\u03b1-methyl- | Citrowanil\u00ae B | 0.00265000 |\\ | 287. | 141-13-9 | 9-Undecenal, 2,6,10-trimethyl- | Adoxal | 0.00257000 |\\ | 288. | 2110-18-1 | Pyridine, 2-(3-phenylpropyl)- | Corps Racine VS | 0.00257000 |\\ | 289. | 27606-09-3 | Indeno\\[1,2-d\\]-1,3-dioxin, 4,4a,5,9b-tetrahydro-2,4-dimethyl- | Magnolan | 0.00251000 |\\ | 290. | 67634-20-2 | Propanoic acid, 2-methyl-, 3a,4,5,6,7,7a-hexahydro-4, 7-methano-1H-inden-5-yl ester | Cyclabute | 0.00244000 |\\ | 291. | 65405-72-3 | 1-Naphthalenol, 1,2,3,4, 4a,7,8,8a-octahydro-2,4a, 5,8a-tetramethyl-, 1-formate | Oxyoctaline Formate | 0.00236000 |\\ | 292. | 122-40-7 | Heptanal, 2-(phenylmethylene)- | Amyl Cinnamic Aldehyde | 0.00233000 |\\ | 293. | 103694-68-4 | Benzenepropanol, \u03b2,\u03b2,\u03b2-trimethyl- | Majantol\u00ae | 0.00224000 |\\ | 294. | 13215-88-8 | 2-Cyclohexen-1-one, 4-(2-buten-1-ylidene)-3,5,5-trimethyl- | Tabanone Coeur | 0.00223000 |\\ | 295. | 25152-85-6 | 3-Hexen-1-ol, 1-benzoate, (3Z)- | Cis-3-Hexenyl Benzoate | 0.00203000 |\\ | 296. | 406488-30-0 | 2-Ethyl- _N_-methyl- _N_-(m-tolyl)butanamide | Paradisamide | 0.00200000 |\\ | 297. | 121-33-5 | Benzaldehyde, 4-hydroxy-3-methoxy- | Vanillin | 0.00194000 |\\ | 298. | 77-54-3 | 1 _H_-3a,7-Methanoazulen-6-ol, octahydro-3,6,8,8-tetramethyl-, 6-acetate, (3 _R_,3a _S_,6 _R_,7 _R_,8a _S_)- | Cedac | 0.00192000 |\\ | 299. | 76842-49-4 | 4,7-Methano-1 _H_-inden-6-ol, 3a,4,5,6,7,7a-hexahydro-8,8-dimethyl-, 6-propanoate | Frutene | 0.00184000 |\\ | 300. | 121-39-1 | 2-Oxiranecarboxylic acid, 3-phenyl-, ethyl ester | Ethyl Phenyl Glycidate | 0.00184000 |\\ | 301. | 211299-54-6 | 4H-4a,9-Methanoazuleno\\[5,6-d\\]-1, 3-dioxole, octahydro-2,2, 5,8,8,9a-hexamethyl-, (4a _R_,5 _R_,7a _S_,9 _R_)- | Ambrocenide\u00ae | 0.00182000 |\\ | 302. | 285977-85-7 | (2,5-Dimethyl-1,3-dihydroinden-2-yl)methanol | Lilyflore | 0.00180000 |\\ | 303. | 10094-34-5 | Butanoic acid, 1,1-dimethyl-2-phenylethyl ester | Dimethyl Benzyl Carbinyl Butyrate | 0.00168000 |\\ | 304. | 40785-62-4 | Cyclododeca\\[c\\]furan, 1,3, 3a,4,5,6,7,8,9,10,11,13a-dodecahydro- | Muscogene | 0.00163000 |\\ | 305. | 75490-39-0 | Benzenebutanenitrile, \u03b1,\u03b1, \u03b3-trimethyl- | Khusinil | 0.00162000 |\\ | 306. | 55418-52-5 | 2-Butanone,4-(1,3-benzodioxol-5-yl)- | Dulcinyl | 0.00161000 |\\ | 307. | 3943-74-6 | Benzoic acid, 4-hydroxy-3-methoxy-, methyl ester | Carnaline | 0.00157000 |\\ | 308. | 72089-08-8 | 3-Cyclopentene-1-butanol, \u03b2,2,2,3-tetramethyl-2-Methyl-4-(2,2,3- | Brahmanol\u00ae | 0.00154000 |\\ | | | trimethyl-3-cyclopenten-1-yl)butanol | | |\\ | 309. | 3155-71-3 | 2-Butenal, 2-methyl-4-(2, 6,6-trimethyl-1-cyclohexen-1-yl)- | Boronal | 0.00147000 |\\ | 310. | 2050-08-0 | Benzoic acid, 2-hydroxy-, pentyl ester | Amyl Salicylate | 0.00144000 |\\ | 311. | 41199-20-6 | 2-Naphthalenol, decahydro-2,5,5-trimethyl- | Ambrinol | 0.00140000 |\\ | 312. | 12262-03-2 | ndecanoic acid, 3-methylbutyl ester | Iso Amyl Undecylenate | 0.00140000 |\\ | 313. | 107-74-4 | 1,7-Octanediol, 3,7-dimethyl- | Hydroxyol | 0.00139000 |\\ | 314. | 91-64-5 | 2 _H_-1-Benzopyran-2-one | Coumarin | 0.00130000 |\\ | 315. | 68901-32-6 | 1,3-Dioxolane,2-\\[6-methyl-8-(1-methylethyl) bicyclo\\[2.2.2\\]oct-5-en-2-yl\\]- | Glycolierral | 0.00121000 |\\ | 316. | 68039-44-1 | Propanoic acid, 2,2-dimethyl-, 3a,4,5,6,7,7a-hexahydro-4,7-methano-1 _H_-inden-6-yl ester | Pivacyclene | 0.00119000 |\\ | 317. | 106-29-6 | Butanoic acid, (2 _E_)-3,7-dimethyl-2,6-octadien-1-yl ester | Geranyl Butyrate | 0.00116000 |\\ | 318. | 5471-51-2 | 2-Butanone, 4-(4-hydroxyphenyl)- | Raspberry ketone | 0.00106000 |\\ | 319. | 109-42-2 | 10-Undecenoic acid, butyl ester | Butyl Undecylenate | 0.00104000 |\\ \\ \\ \\ | |\\ | --- |\\ | \\\\* Vapor Pressures are acquired as described in the Test Methods Section.<br>\\\\*\\\\* Origin: Same as for Table 1 hereinabove. |\\ \\ - \\[0084\\]\\ \\ Exemplary moderate volatile fragrance materials selected from the group of Table 2 Moderate Volatile Fragrance Materials are preferred. However, it is understood by one skilled in the art that other moderate volatile fragrance materials, not recited in Table 2, would also fall within the scope of the present invention, so long as they have a vapor pressure of 0.1 to 0.001 Torr at 25 \u00b0C.\\ \\ - \\[0085\\]\\ \\ Preferably, the compositions of the present invention, wherein: (i)(b) the moderate volatile fragrance material is selected from the group of Table 2 Moderate Volatile Fragrance Materials 1-9, 11-12, 14-15, 17-18, 20-25, 27-35, 37-38, 39-43, 45-46, 48-53, 55-61, 63, 65, 67-71, 73-77, 79, 81-84, 86-91, 93-122, 124-125, 130-131, 133-135, 137, 139-145, 147-149, 151, 153-155, 157, 161-162, 164-169, 171-191, 193, 195-198, 200-203, 205-215, 218-219, 221, 223-241, 243, 245-250, 252-255, 257-262, 264-265, 267-268, 272, 273-276, 279-300, 302-304, 306, 308-310, 312-319, and mixtures thereof, and (ii) the substantially non-odorous fragrance modulator is selected from the group of Table 4(a) Substantially Non-Odorous Fragrance Modulators 1-5, and mixtures thereof.\\ \\ - \\[0086\\]\\ \\ Preferably, the compositions of the present invention, wherein: (i)(a) the moderate volatile fragrance material is selected from the group consisting of Table 2 Moderate Volatile Fragrance Materials 1, 3, 4, 6, 7, 9, 11-12, 14, 15, 17-18, 20-25, 30-31, 34-35, 37-38, 41-42, 45-46, 49, 51-53, 55, 57-59, 65-70, 73, 75-77, 79-80, 82, 86-89, 91-94, 98, 101-107, 111-113, 115-122, 124-125, 130-133, 135, 137, 139-143, 145, 147-149, 151, 153-155, 157-159, 161-162, 164-168, 171-180, 182-183, 187-191, 193, 195-198, 200-203, 205-213, 218-219, 221-222, 224-229, 231-241, 243, 245-250, 252, 253, 254-255, 257-263, 264-265, 267-269, 271, 273-276, 279-300, 302-304, 306, 308-310, 312, 314-319, and mixtures thereof; and (ii) the substantially non-odorous fragrance modulator is selected from the group of Table 4(a) Substantially Non-Odorous Fragrance Modulators 6-8, and mixtures thereof.\\ \\ - \\[0087\\]\\ \\ Preferably, the compositions of the present invention, the low volatile fragrance material is selected from the group (as described herein above), and wherein this group of low volatile fragrance material has at least about 20 wt%, at least about 30 wt%, at least about 40 wt%, at least about 50 wt%, at least about 60 wt%, or at least about 70 wt%, relative to the total weight of the low volatile fragrance material.\\ \\ (iii) High Volatile Fragrance Materials- \\[0088\\]\\ \\ Preferable examples of high volatile fragrance materials having a vapor pressure greater than 0.1 (0.0133 kPa) Torr at 25 \u00b0C are provided in Table 3 High Volatile Fragrance Materials. Preferably, the high volatile fragrance material is selected from at least 1 material, or at least 2 materials, or at least 3 materials, or at least 5 materials, or at least 7 high volatile fragrance materials as disclosed in Table 3.\\ Table 3 - High Volatile Fragrance Materials\\ \\ \\ | **No.** | **CAS Number** | **IUPAC Name** | **Common Name\\*\\*** | **Vapor Pressure (Torr at 25 \u00b0C)\\*** |\\ | --- | --- | :-: | :-: | :-: |\\ | 1. | 107-31-3 | Formic acid, methyl ester | Methyl Formate | 732.00000000 |\\ | 2. | 75-18-3 | Methane, 1,1'-thiobis- | Dimethyl Sulfide 1.0% In DEP | 647.00000000 |\\ | 3. | 141-78-6 | Acetic acid ethyl ester | Ethyl Acetate | 112.00000000 |\\ | 4. | 105-37-3 | Propanoic acid, ethyl ester | Ethyl Propionate | 44.50000000 |\\ | 5. | 110-19-0 | Acetic acid, 2-methylpropyl ester | Isobutyl Acetate | 18.00000000 |\\ | 6. | 105-54-4 | Butanoic acid, ethyl ester | Ethyl Butyrate | 13.90000000 |\\ | 7. | 14765-30-1 | 1-Butanol | Butyl Alcohol | 8.52000000 |\\ | 8. | 7452-79-1 | Butanoic acid, 2-methyl-, ethyl ester | Ethyl-2-Methyl Butyrate | 7.85000000 |\\ | 9. | 123-92-2 | 1-Butanol, 3-methyl-, 1-acetate | Iso Amyl Acetate | 5.68000000 |\\ | 10. | 66576-71-4 | Butanoic acid, 2-methyl-, 1-methylethyl ester | Iso Propyl 2-Methylbutyrate | 5.10000000 |\\ | 11. | 110-43-0 | 2-Heptanone | Methyl Amyl Ketone | 4.73000000 |\\ | 12. | 6728-26-3 | 2-Hexenal, (2 _E_)- | Trans-2 Hexenal | 4.62000000 |\\ | 13. | 123-51-3 | 1-Butanol, 3-methyl- | Isoamyl Alcohol | 4.16000000 |\\ | 14. | 1191-16-8 | 2-Buten-1-ol, 3-methyl-, 1-acetate | Prenyl acetate | 3.99000000 |\\ | 15. | 57366-77-5 | 1,3-Dioxolane-2-methanamine, _N_-methyl- | Methyl Dioxolan | 3.88000000 |\\ | 16. | 7785-70-8 | Bicyclo\\[3.1.1\\]hept-2-ene, 2,6,6-trimethyl-, (1 _R_,5 _R_)- | Alpha Pinene | 3.49000000 |\\ | 17. | 79-92-5 | Bicyclo\\[2.2.1\\]heptane, 2, 2-dimethyl-3-methylene- | Camphene | 3.38000000 |\\ | 18. | 94087-83-9 | 2-Butanethiol, 4-methoxy-2-methyl- | 4-Methoxy-2-Methyl-2-Butanenthiol | 3.31000000 |\\ | 19. | 39255-32-8 | Pentanoic acid, 2-methyl-, ethyl ester | Manzanate | 2.91000000 |\\ | 20. | 3387-41-5 | Bicyclo\\[3.1.0\\]hexane, 4-methylene-1-(1-methylethyl)- | Sabinene | 2.63000000 |\\ | 21. | 127-91-3 | Bicyclo\\[3.1.1\\]heptane, 6, 6-dimethyl-2-methylene- | Beta Pinene | 2.40000000 |\\ | 22. | 105-68-0 | 1-Butanol, 3-methyl-, 1-propanoate | Amyl Propionate | 2.36000000 |\\ | 23. | 123-35-3 | 1,6-Octadiene, 7-methyl-3-methylene- | Myrcene | 2.29000000 |\\ | 24. | 124-13-0 | Octanal | Octyl Aldehyde | 2.07000000 |\\ | 25. | 7392-19-0 | 2 _H_-Pyran, 2-ethenyltetrahydro-2,6,6-trimethyl- | Limetol | 1.90000000 |\\ | 26. | 111-13-7 | 2-Octanone | Methyl Hexyl Ketone | 1.72000000 |\\ | 27. | 123-66-0 | Hexanoic acid, ethyl ester | Ethyl Caproate | 1.66000000 |\\ | 28. | 470-82-6 | 2-Oxabicyclo\\[2.2.2\\] octane, 1,3,3-trimethyl- | Eucalyptol | 1.65000000 |\\ | 29. | 99-87-6 | Benzene, 1-methyl-4-(1-methylethyl)- | Para Cymene | 1.65000000 |\\ | 30. | 104-93-8 | Benzene, 1-methoxy-4-methyl- | Para Cresyl Methyl Ether | 1.65000000 |\\ | 31. | 13877-91-3 | 1,3,6-Octatriene, 3,7-dimethyl- | Ocimene | 1.56000000 |\\ | 32. | 138-86-3 | Cyclohexene, 1-methyl-4-(1-methylethenyl)- | dl-Limonene | 1.54000000 |\\ | 33. | 5989-27-5 | Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (4R)- | d-limonene | 1.54000000 |\\ | 34. | 106-68-3 | 3-Octanone | Ethyl Amyl Ketone | 1.50000000 |\\ | 35. | 110-41-8 | Undecanal, 2-methyl- | Methyl Nonyl Acetaldehyde | 1.43000000 |\\ | 36. | 142-92-7 | Acetic acid, hexyl ester | Hexyl acetate | 1.39000000 |\\ | 37. | 110-93-0 | 5-Hepten-2-one, 6-methyl- | Methyl Heptenone | 1.28000000 |\\ | 38. | 81925-81-7 | 2-Hepten-4-one, 5-methyl- | Filbertone 1% in TEC | 1.25000000 |\\ | 39. | 3681-71-8 | 3-Hexen-1-ol, 1-acetate, (3 _Z_)- | cis-3-Hexenyl acetate | 1.22000000 |\\ | 40. | 97-64-3 | Propanoic acid, 2-hydroxy-, ethyl ester | Ethyl Lactate | 1.16000000 |\\ | 41. | 586-62-9 | Cyclohexene, 1-methyl-4-(1-methylethylidene)- | Terpineolene | 1.13000000 |\\ | 42. | 51115-64-1 | Butanoic acid, 2-methylbutyl ester | Amyl butyrate | 1.09000000 |\\ | 43. | 106-27-4 | Butanoic acid, 3-methylbutyl ester | Amyl Butyrate | 1.09000000 |\\ | 44. | 99-85-4 | 1,4-Cyclohexadiene, 1-methyl-4-(1-methylethyl)- | Gamma Terpinene | 1.08000000 |\\ | 45. | 18640-74-9 | Thiazole, 2-(2-methylpropyl)- | 2-Isobutylthiazole | 1.07000000 |\\ | 46. | 928-96-1 | 3-Hexen-1-ol, (3 _Z_)- | cis-3-Hexenol | 1.04000000 |\\ | 47. | 100-52-7 | Benzaldehyde | Benzaldehyde | 0.97400000 |\\ | 48. | 141-97-9 | Butanoic acid, 3-oxo-, ethyl ester | Ethyl Acetoacetate | 0.89000000 |\\ | 49. | 928-95-0 | 2-Hexen-1-ol, (2 _E_)- | Trans-2-Hexenol | 0.87300000 |\\ | 50. | 928-94-9 | 2-Hexen-1-ol, (2 _Z_)- | Beta Gamma Hexenol | 0.87300000 |\\ | 51. | 24691-15-4 | Cyclohexane, 3-ethoxy-1, 1,5-trimethyl-, cis- (9CI) | Herbavert | 0.85200000 |\\ | 52. | 19872-52-7 | 2-Pentanone, 4-mercapto-4-methyl- | 4-Methyl-4-Mercaptopentan-2-one 1ppm TEC | 0.84300000 |\\ | 53. | 3016-19-1 | 2,4,6-Octatriene, 2,6-dimethyl-, (4 _E_,6 _E_)- | Allo-Ocimene | 0.81600000 |\\ | 54. | 69103-20-4 | Oxirane, 2,2-dimethyl-3-(3-methyl-2,4-pentadien-1-yl)- | Myroxide | 0.80600000 |\\ | 55. | 189440-77-5 | 4,7-Octadienoic acid, methyl ester, (4 _E_)- | Anapear | 0.77700000 |\\ | 56. | 67633-96-9 | Carbonic acid, (3 _Z_)-3-hexen-1-yl methyl ester | Liffarome\u2122 | 0.72100000 |\\ | 57. | 123-68-2 | Hexanoic acid, 2-propen-1-yl ester | Allyl Caproate | 0.67800000 |\\ | 58. | 106-72-9 | 5-Heptenal, 2,6-dimethyl- | Melonal | 0.62200000 |\\ | 59. | 106-30-9 | Heptanoic acid, ethyl ester | Ethyl Oenanthate | 0.60200000 |\\ | 60. | 68039-49-6 | 3-Cyclohexene-1-carboxaldehyde, 2,4-dimethyl- | Ligustral or Triplal | 0.57800000 |\\ | 61. | 101-48-4 | Benzene, (2,2-dimethoxyethyl)- | Phenyl Acetaldehyde Dimethyl Acetal | 0.55600000 |\\ | 62. | 16409-43-1 | 2 _H_-Pyran, tetrahydro-4-methyl-2-(2-methyl-1-propen-1-yl)- | Rose Oxide | 0.55100000 |\\ | 63. | 925-78-0 | 3-Nonanone | Ethyl Hexyl Ketone | 0.55100000 |\\ | 64. | 100-47-0 | Benzonitrile | Benzyl Nitrile | 0.52400000 |\\ | 65. | 589-98-0 | 3-Octanol | Octanol-3 | 0.51200000 |\\ | 66. | 58430-94-7 | 1-Hexanol, 3,5,5-trimethyl-, 1-acetate | Iso Nonyl Acetate | 0.47000000 |\\ | 67. | 10250-45-0 | 4-Heptanol, 2,6-dimethyl-, 4-acetate | Alicate | 0.45400000 |\\ | 68. | 105-79-3 | Hexanoic acid, 2-methylpropyl ester | Iso Butyl Caproate | 0.41300000 |\\ | 69. | 2349-07-7 | Propanoic acid, 2-methyl-, hexyl ester | Hexyl isobutyrate | 0.41300000 |\\ | 70. | 23250-42-2 | Cyclohexanecarboxylic acid, 1,4-dimethyl-, methyl ester, trans- | Cyprissate | 0.40500000 |\\ | 71. | 122-78-1 | Benzeneacetaldehyde | Phenyl acetaldehyde | 0.36800000 |\\ | 72. | 5405-41-4 | Butanoic acid, 3-hydroxy-, ethyl ester | Ethyl-3-Hydroxy Butyrate | 0.36200000 |\\ | 73. | 105-53-3 | Propanedioic acid, 1,3-diethyl ester | Diethyl Malonate | 0.34400000 |\\ | 74. | 93-58-3 | Benzoic acid, methyl ester | Methyl Benzoate | 0.34000000 |\\ | 75. | 16356-11-9 | 1,3,5-Undecatriene | Undecatriene | 0.33600000 |\\ | 76. | 65405-70-1 | 4-Decenal, (4 _E_)- | Decenal (Trans-4) | 0.33100000 |\\ | 77. | 54546-26-8 | 1,3-Dioxane, 2-butyl-4,4, 6-trimethyl- | Herboxane | 0.33000000 |\\ | 78. | 13254-34-7 | 2-Heptanol, 2,6-dimethyl- | Dimethyl-2 6-Heptan-2-ol | 0.33000000 |\\ | 79. | 98-86-2 | Ethanone, 1-phenyl- | Acetophenone | 0.29900000 |\\ | 80. | 93-53-8 | Benzeneacetaldehyde, \u03b1-methyl- | Hydratropic aldehyde | 0.29400000 |\\ | 81. | 80118-06-5 | Propanoic acid, 2-methyl-, 1,3-dimethyl-3-buten-1-yl ester | Iso Pentyrate | 0.28500000 |\\ | 82. | 557-48-2 | 2,6-Nonadienal, (2 _E_,6 _Z_)- | E Z-2,6-Nonadien-1-al | 0.28000000 |\\ | 83. | 24683-00-9 | Pyrazine, 2-methoxy-3-(2-methylpropyl)- | 2-Methoxy-3-Isobutyl Pyrazine | 0.27300000 |\\ | 84. | 104-57-4 | Formic acid, phenylmethyl ester | Benzyl Formate | 0.27300000 |\\ | 85. | 104-45-0 | Benzene, 1-methoxy-4-propyl- | Dihydroanethole | 0.26600000 |\\ | 86. | 491-07-6 | Cyclohexanone, 5-methyl-2-(1-methylethyl)-, (2 _R_, 5 _R_)-rel- | Iso Menthone | 0.25600000 |\\ | 87. | 89-80-5 | Cyclohexanone, 5-methyl-2-(1-methylethyl)-, (2 _R_, 5 _S_)-rel- | Menthone Racemic | 0.25600000 |\\ | 88. | 2463-53-8 | 2-Nonenal | 2 Nonen-1-al | 0.25600000 |\\ | 89. | 55739-89-4 | Cyclohexanone, 2-ethyl-4, 4-dimethyl- | Thuyacetone | 0.25000000 |\\ | 90. | 150-78-7 | Benzene, 1,4-dimethoxy- | Hydroquinone Dimethyl Ether | 0.25000000 |\\ | 91. | 64988-06-3 | Benzene, 1-(ethoxymethyl)-2-methoxy- | Rosacene | 0.24600000 |\\ | 92. | 76-22-2 | Bicyclo\\[2.2.1\\]heptan-2-one, 1,7,7-trimethyl- | Camphor gum | 0.22500000 |\\ | 93. | 67674-46-8 | 2-Hexene, 6,6-dimethoxy-2,5,5-trimethyl- | Methyl Pamplemousse | 0.21400000 |\\ | 94. | 112-31-2 | Decanal | Decyl Aldehyde | 0.20700000 |\\ | 95. | 16251-77-7 | Benzenepropanal, \u03b2-methyl- | Trifernal | 0.20600000 |\\ | 96. | 93-92-5 | Benzenemethanol, \u03b1-methyl-, 1-acetate | Methylphenylcarbinol Acetate | 0.20300000 |\\ | 97. | 143-13-5 | Acetic acid, nonyl ester | Nonyl Acetate | 0.19700000 |\\ | 98. | 122-00-9 | Ethanone, 1-(4-methylphenyl)- | Para Methyl Acetophenone | 0.18700000 |\\ | 99. | 24237-00-1 | 2 _H_-Pyran, 6-butyl-3,6-dihydro-2,4-dimethyl- | Gyrane | 0.18600000 |\\ | 100. | 41519-23-7 | Propanoic acid, 2-methyl-, (3 _Z_)-3-hexen-1-yl ester | Hexenyl Isobutyrate | 0.18200000 |\\ | 101. | 93-89-0 | Benzoic acid, ethyl ester | Ethyl Benzoate | 0.18000000 |\\ | 102. | 20780-48-7 | 3-Octanol, 3,7-dimethyl-, 3-acetate | Tetrahydro Linalyl Acetate | 0.18000000 |\\ | 103. | 101-41-7 | Methyl 2-phenylacetate | Methylphenyl acetate | 0.17600000 |\\ | 104. | 40853-55-2 | 1-Hexanol, 5-methyl-2-(1-methylethyl)-, 1-acetate | Tetrahydro Lavandulyl Acetate | 0.17300000 |\\ | 105. | 933-48-2 | Cyclohexanol, 3,3,5-trimethyl-, (1 _R_,5 _R_)-rel- | Trimethylcyclohexanol | 0.17300000 |\\ | 106. | 35158-25-9 | 2-Hexenal, 5-methyl-2-(1-methylethyl)- | Lactone of Cis Jasmone | 0.17200000 |\\ | 107. | 18479-58-8 | 7-Octen-2-ol, 2,6-dimethyl- | Dihydromyrcenol | 0.16600000 |\\ | 108. | 140-11-4 | Acetic acid, phenylmethyl ester | Benzyl acetate | 0.16400000 |\\ | 109. | 14765-30-1 | Cyclohexanone, 2-(1-methylpropyl)- | 2-sec-Butyl Cyclo Hexanone | 0.16300000 |\\ | 110. | 20125-84-2 | 3-Octen-1-ol, (3 _Z_)- | Octenol | 0.16000000 |\\ | 111. | 142-19-8 | Heptanoic acid, 2-propen-1-yl ester | Allyl Heptoate | 0.16000000 |\\ | 112. | 100-51-6 | Benzenemethanol | Benzyl Alcohol | 0.15800000 |\\ | 113. | 10032-15-2 | Butanoic acid, 2-methyl-, hexyl ester | Hexyl-2-Methyl Butyrate | 0.15800000 |\\ | 114. | 695-06-7 | 2(3 _H_)-Furanone, 5-ethyldihydro- | Gamma Hexalactone | 0.15200000 |\\ | 115. | 21722-83-8 | Cyclohexaneethanol, 1-acetate | Cyclohexyl Ethyl Acetate | 0.15200000 |\\ | 116. | 111-79-5 | 2-Nonenoic acid, methyl ester | Methyl-2-Nonenoate | 0.14600000 |\\ | 117. | 16491-36-4 | Butanoic acid, (3 _Z_)-3-hexen-1-yl ester | Cis | 3 Hexenyl Butyrate | 0.13500000 |\\ | 118. | 111-12-6 | 2-Octynoic acid, methyl ester | Methyl Heptine Carbonate | 0.12500000 |\\ | 119. | 59323-76-1 | 1,3-Oxathiane, 2-methyl-4-propyl-, (2 _R_,4 _S_)-rel- | Oxane | 0.12300000 |\\ | 120. | 62439-41-2 | Heptanal, 6-methoxy-2,6-dimethyl- | Methoxy Melonal | 0.11900000 |\\ | 121. | 13851-11-1 | Bicyclo\\[2.2.1\\]heptan-2-ol, 1,3,3-trimethyl-, 2-acetate | Fenchyl Acetate | 0.11700000 |\\ | 122. | 115-95-7 | 1,6-Octadien-3-ol, 3,7-dimethyl-, 3-acetate | Linalyl acetate | 0.11600000 |\\ | 123. | 18479-57-7 | 2-Octanol, 2,6-dimethyl- | Tetra-Hydro Myrcenol | 0.11500000 |\\ | 124. | 78-69-3 | 3,7-dimethyloctan-3-ol | Tetra-Hydro Linalool | 0.11500000 |\\ | 125. | 111-87-5 | 1-Octanol | Octyl Alcohol | 0.11400000 |\\ | 126. | 71159-90-5 | 3-Cyclohexene-1-methanethiol, \u03b1,\u03b1,4-trimethyl- | Grapefruit mercaptan | 0.10500000 |\\ | 127. | 80-25-1 | Cyclohexanemethanol, \u03b1, \u03b1,4-trimethyl-, 1-acetate | Menthanyl Acetate | 0.10300000 |\\ | 128. | 88-41-5 | Cyclohexanol, 2-(1,1-dimethylethyl)-, 1-acetate | Verdox\u2122 | 0.10300000 |\\ | 129. | 32210-23-4 | Cyclohexanol, 4-(1,1-dimethylethyl)-, 1-acetate | Vertenex | 0.10300000 |\\ | 130. | 112-44-7 | Undecanal | n-Undecanal | 0.10200000 |\\ | 131. | 124-19-6 | Nonanal | Nonanal Aldehyde C-9 | 0.53200000 |\\ | 132. | 929253-05-4 | 6-methoxy-2,6-dimethyloctanal | 6-methoxy-2,6-dimethyl octanal | 0.04020000 |\\ | 133. | 68039-47-4 | 2-propan-2-yloxyethylbenzene | Phenethyl Isopropyl Ether | 0.24900000 |\\ | 134. | 6413-10-1 | ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate | Apple Ketal | 0.21900000 |\\ | 135. | 106-23-0 | 3,7-dimethyloct-6-enal | citronellal | 0.21500000 |\\ \\ \\ \\ | |\\ | --- |\\ | \\\\* Vapor Pressures are acquired as described in the Test Methods Section.<br>\\\\*\\\\* Origin: Same as for Table 1 hereinabove. |\\ \\ - \\[0089\\]\\ \\ Exemplary high volatile fragrance materials selected from the group of Table 3 High Volatile Fragrance Materials are preferred. However, it is understood by one skilled in the art that other high volatile fragrance materials, not recited in Table 3, would also fall within the scope of the present invention, so long as they have a vapor pressure of greater than 0.1 Torr (0.0133 kPa) at 25 \u00b0C.\\ \\ - \\[0090\\]\\ \\ Preferably, the compositions of the present invention, wherein: (i)(c) the high volatile fragrance material is selected from the group of Table 3 High Volatile Fragrance Materials 1, 2, 6, 8, 9, 12, 14, 19, 36, 39, 46, 47, 56, 57, 58, 60, 62, 74, 78, 93, 94, 96, 100, 106, 111, 117, 119, 120, 128, 129, 131-135 and mixtures thereof; and (ii) the substantially non-odorous fragrance modulator is selected from the group of Table 4(a) Substantially Non-Odorous Fragrance Modulators 1-5, and mixtures thereof.\\ \\ - \\[0091\\]\\ \\ Preferably, the compositions of the present invention, wherein: (i)(c) the high volatile fragrance material is selected from the group consisting of Table 3 high Volatile Fragrance Materials 1, 2, 6, 8, 9, 12, 14, 19, 36, 39, 46, 47, 56, 57, 58, 60, 62, 74, 78, 93, 94, 96, 100, 106, 111, 117, 119, 120, 128, 129, 131-135, and mixtures thereof; and (ii) the substantially non-odorous fragrance modulator is selected from the group of Table 4(a) Substantially Non-Odorous Fragrance Modulators 6-8, and mixtures thereof.\\ \\ - \\[0092\\]\\ \\ Preferably, the compositions of the present invention, the high volatile fragrance material is selected from the group (as described herein above), and wherein this group of high volatile fragrance material has at least about 20 wt%, at least about 30 wt%, at least about 40 wt%, at least about 50 wt%, at least about 60 wt%, or at least about 70 wt%, relative to the total weight of the high volatile fragrance material.\\ \\ Fragrance Modulators- \\[0093\\]\\ \\ In one aspect, compositions of the present invention comprise at least one substantially non-odorous modulator selected from the group consisting of:\\ \\ \\ 01. (a) Methyl Glucoside Polyol; Ethyl Glucoside Polyol; Propyl Glucoside Polyol; and their mixtures;\\ 02. (b) Isocetyl Alcohol;\\ 03. (c) PPG-3 Myristyl Ether; Neopentyl Glycol Diethylhexanoate; and their mixtures;\\ 04. (d) Sucrose Laurate, Sucrose Dilaurate, Sucrose Myristate, Sucrose Palmitate, Sucrose Stearate, Sucrose Distearate, Sucrose Tristearate, and mixtures thereof;\\ 05. (e) Trimethylcyclohexane derivatives having the formula (I):\\ \\ \\ \\ \\ \\ wherein:\\ - n is 0, 1 or 2;\\ - A is C=O or CH-OH;\\ - R1a is hydrogen or methyl;\\ - R2a is a C2-C10 hydrocarbon group; and\\ - \\-\\-\\-\\-\\-\\- is a saturated or unsaturated carbon-carbon bond;\\ 06. (f) L-menthoxy ether derivatives having the formula (II):\\ \\ \\ \\ \\ \\ wherein:\\ - m is 0, 1 or 2;\\ - B is hydrogen or OH; and\\ - C is hydrogen or methyl;\\ 07. (g) Tetra-hydronaphthalene derivatives having the formula (III):\\ \\ \\ \\ \\ \\ wherein:\\ - R1b is hydrogen or methyl; and\\ - R2b is alkyl;\\ 08. (h) Hyaluronic acid disaccharide sodium salt, sodium hyaluronate and their mixtures;\\ 09. (i) Ether derivatives having the formula (IV) or formula (V):\\ \\ \\ \\ \\ C5H _l_ Om-(OR1c)n (IV)\\ \\ \\ \\ \\ wherein:\\ \\ \\ - C5H _l_ Om is a pentose residue, wherein _l_ is an integer from 6 to 9, and m is an integer from 1 to 4;\\ - n is an integer from 1 to 4; and\\ - R1c is C4-C20 hydrocarbon group; and\\ \\ C6HxOy-(OR1d)z (V)\\ \\ wherein:\\ \\ - C6HxOy is a hexose residue, wherein x is an integer from 7 to 11, and y is an integer from 1 to 5;\\ - z is an integer from 1 to 5; and\\ - R1d is C4-C20 hydrocarbon group; and\\ 10. (j) Diethylene Glycol Ether derivatives having the formula (VI) or formula (VII):\\ \\ \\ \\ \\ C5HcOd-(OCH2CH2-O-CH2CH2-O-R1e)e (VI)\\ \\ \\ \\ \\ wherein:\\ \\ \\ - C5HcOd is a pentose residue, wherein c is an integer from 6 to 8, and d is an integer from 1 to 3;\\ - e is an integer from 2 to 4; and\\ - R1e is C1-C6 alkyl group; and\\ \\ C6HfOg-(OCH2CH2O-CH2CH2O-R1f)h (VII)\\ \\ wherein:\\ \\ - C6HfOg is a hexose residue, wherein f is an integer from 7 to 10, and g is an integer from 1 to 4;\\ - h is an integer from 2 to 5; and\\ - R1f is C1-C6 alkyl group;\\ 11. (k) Hydroquinone Glycoside derivatives having the formula (VIII):\\ \\ \\ \\ \\ \\ wherein:\\ - R1g is selected from the group consisting of: (i) pentose residue, hexose residue, aminosaccharide residue, uronic acid residue and their mixtures; (ii) methylated versions of group (i); and (iii) mixtures of groups (i) and (ii); and\\ 12. (l) Propylene Glycol Propyl Ether; Dicetyl Ether; Polyglycerin-4 Ethers; Isoceteth-5; Isoceteth-7, Isoceteth-10; Isoceteth-12; Isoceteth-15; Isoceteth-20; Isoceteth-25; Isoceteth-30; Disodium Lauroamphodipropionate; Hexaethylene glycol monododecyl ether; and their mixtures;\\ 13. (m)Neopentyl Glycol Diisononanoate; Cetearyl Ethylhexanoate; and their mixtures;\\ 14. (n) Glyceryl Ether derivatives having the formula (IX):\\ \\ \\ \\ \\ \\ wherein:\\ - R1h is C4-C12 aliphatic hydrocarbon group;\\ 15. (o) Panthenol Ethyl Ether, DL-Panthenol and their mixtures;\\ 16. (p) Aliphatic Dibasic Acid Diester derivatives having the formula (X):\\ \\ \\ \\ \\ R1iOCOR2iCOOR3i (X)\\ \\ \\ \\ \\ wherein:\\ \\ - R1i is C4-C5 alkyl;\\ - R2i is C4 alkylene; and\\ - R31 is C4-C5 alkyl; and\\ 17. (q) Aliphatic Ether derivatives having the formula (XI):\\ \\ \\ \\ \\ R4i-O-(CH(CH3)-CH2O)a(CH2-CH2O)b-H (XI)\\ \\ \\ \\ \\ wherein:\\ \\ - a and b are integers such that the sum of a and b is from 1 to 4; and\\ - R4i is an aliphatic chain comprising from 8 to 18 carbons; (r) _N_-hexadecyl n-nonanoate, Noctadecyl n-nonanoate and their mixtures; (s)Tricyclodecane Amide derivatives selected from the group consisting of:\\ \\ 1. (i) the compounds of formula (XII):\\ \\ \\ \\ \\ \\ wherein:\\ - X is selected from:\\ \\ \\ \\ \\ \\ \\ \\ \\ \\ \\ \\ \\ - t is 1 to 8;\\ - Y is hydrogen,\\ \\ \\ \\ \\ \\ or a halogen; and each R1j is independently selected from a hydrogen, or C1-C4 alkyl;\\ 2. (ii) the compounds of formula (XIII):\\ \\ \\ \\ \\ \\ wherein:\\ - each R2j is independently selected from a hydrogen, methyl, ethyl or C3-C18 alkyl, cycloalkyl or cycloheteroalkyl, with the proviso that both R2e groups are not hydrogen; and\\ 3. (iii) mixtures of the compounds of formulae (XII) and (XIII); and (t) mixtures thereof.\\ \\ - \\[0094\\]\\ \\ Preferably, the substantially non-odorous fragrance modulator is selected from the group of materials disclosed in Table 4(a).\\ Table 4(a): Substantially Non-Odorous Fragrance Modulators\\ \\ \\ | **No.** | **Group** | **Chemical Name** | **CAS Number** | **Supplier** | |\\ | :-: | :-: | :-: | :-: | :-: | :-: |\\ | 1. | (a) | PPG-10 Methyl Glucose Ether | 61849-72-7 | Lubrizol |\\ | 2. | PPG-20 Methyl Glucose Ether _1_ | 61849-72-7 |\\ | 3. | Ethoxylated Methyl Glucose Ether _2_ | 68239-42-9 |\\ | 4. | Caprylyl/Capryl Glucoside _3_ | 68515-73-1 | BASF |\\ | 5. | Undecyl Glucoside _3a_ | -- | SEPPIC (France) |\\ | 6. | (b) | Isocetyl Alcohol _4_ | 36653-82-4 | Ashland Speciality Ingredients |\\ | 7. | (c) | PPG-3 Myristyl Ether _5_ | -- | Evonik |\\ | 8. | Neopentyl Glycol Diethylhexanoate _6_ | 28510-23-8 | Lubrizol |\\ | 9 | (d) | Sucrose Laurate | 25339-99-5 | Alfa Chemicals Ltd. (UK) |\\ | 10. | Sucrose dilaurate | 25915-57-5 | Alfa Chemicals Ltd. (UK) |\\ | 11. | Sucrose Myristate | 27216-47-3 | Mitsubishi Chemicals |\\ | 12. | Sucrose Palmitate | 26446-38-8 | Alfa Chemicals Ltd. (UK) |\\ | 13. | Sucrose Stearate | 25168-73-4 |\\ | 14. | | Sucrose Distearate | 27195-16-0 | Mitsubishi Chemicals (JP) |\\ | 15. | | Sucrose Tristearate | 27923063-3 | Mitsubishi Chemicals (JP) |\\ | 16. | (e) | ( _E_)-1-(2,2,6-trimethylcyclohexyl)oct-1-en-3-one _8_ | -- | Takasago (Japan) |\\ | 17. | (f) | 2-(1-menthoxy)ethane-1-ol _9_ | -- | Takasago (Japan) |\\ | 18. | 1-(1-menthoxy)propane-2-ol _9_ | -- |\\ | 19. | 3-(1-menthoxy)propane-1-ol _9_ | -- |\\ | 20. | 3-(1-menthoxy)propane-1,2-diol _9_ | -- |\\ | 21. | | 2-methyl-3-(1-menthoxy)propane-1,2-diol _9_ | -- | |\\ | 22. | 4-(1-menthoxy) butane-1-ol _9_ | -- |\\ | 23. | (g) | 1,1,4,4-tetramethyl-6-acetyl-7-formyl-1,2,3,4-tetrahydronaphthalene _10_ | -- | Givaudan (Switzerland) |\\ | 24. | 1,1,2,4,4-pentamethyl-6-acetyl-7-formyl-1,2,3,4-tetrahydronaphthalene _10_ | -- |\\ | 25. | (h) | Hyaluronic acid disaccharide sodium salt _11_ | 9004-61-9 | Sigma Aldrich (UK) |\\ | 26. | Sodium Hyaluronate _11_ | 9067-32-7 |\\ | 27. | | Mono-o-(linalyl)-glucopyranose _12_ | -- | |\\ | 28. | | Di-o-(linalyl)-glucopyranose _12_ | -- | |\\ | 29. | | Tri-o-(linalyl)-glucopyranose _12_ | -- | |\\ | 30. | | Tetra-o-(linalyl)-glucopyranose _12_ | -- | |\\ | 31. | (i) | Penta-o-(linalyl)-glucopyranose _12_ | -- | |\\ | 32. | Mono-o-(cis-3-hexenyl)-glactopyranose _12_ | -- | |\\ | 33. | | Di-o-(cis-3-hexenyl)-glactopyranose _12_ | -- | |\\ | 34. | | Tri-o-(cis-3-hexenyl)-glactopyranose _12_ | -- | |\\ | 35. | | Tetra-o-(cis-3-hexenyl)-glactopyranose _12_ | -- | |\\ | 36. | | Penta-o-(cis-3-hexenyl)-glactopyranose _12_ | -- | Kanebo (Japan) |\\ | 37. | | Bis-O-(3,6-dioxadecanyl)-glucopyranose _13_ | -- |\\ | 38. | | Tris-O-(3,6-dioxadecanyl)-glucopyranose _13_ | -- | |\\ | 39. | | Tetrakis-O-(3,6-dioxadecanyl)-glucopyranose _13_ | -- | |\\ | 40. | | Pentakis-O-(3,6-dioxadecanyl)-glucopyranose _13_ | -- | |\\ | 41. | (j) | Bis-O-(3,6-dioxaoctanyl)-galactopyranose _13_ | -- | |\\ | 42. | Tris-O-(3,6-dioxaoctanyl)-galactopyranose _13_ | -- | |\\ | 43. | | Tetrakis-O-(3,6-dioxaoctanyl)-galactopyranose _13_ | -- | |\\ | 44. | | Pentakis-O-(3,6-dioxaoctanyl)-galactopyranose _13_ | -- | |\\ | 45. | | Bis-O-(3,6-dioxaheptanyl)-xylopyranose _13_ | -- | |\\ | 46. | | Tris-O-(3,6-dioxaheptanyl)-xylopyranose _13_ | -- | |\\ | 47. | | Tetrakis-O-(3,6-dioxaheptanyl)-xylopyranose _13_ | -- | |\\ | 48. | | Bis-O-(3,6-dioxadodecanyl)-glucopyranose _13_ | -- | |\\ | 49. | | Tris-O-(3,6-dioxadodecanyl)-glucopyranose _13_ | -- | |\\ | 50. | | Tetrakis-O-(3,6-dioxadodecanyl)-glucopyranose _13_ | -- | |\\ | 51. | | Pentakis-O-(3,6-dioxadodecanyl)-glucopyranose _13_ | -- | |\\ | 52. | (k) | Hydroquinone beta-D-glycoside _14_ | 497-76-7 | Shiseido |\\ | 53. | | Propylene Glycol Propyl Ether | 1569-01-3 | Sigma Aldrich (UK) |\\ | 54. | | Dicetyl Ether | 4113-12-6 |\\ | 55. | | Polyglycerin-4 Ethers | 25618-55-7 | Solvay Chemicals |\\ | 56. | | Isoceteth-5 | 69364-63-2 | |\\ | 57. | | Isoceteth-7 | 69364-63-2 | |\\ | 58. | | Isoceteth-10 | 69364-63-2 | |\\ | 59. | (l) | Isoceteth-12 | 69364-63-2 | Nihon Emulsion Company Ltd. |\\ | 60. | | Isoceteth-15 | 69364-63-2 |\\ | 61. | | Isoceteth-20 | 69364-63-2 | |\\ | 62. | | Isoceteth-25 | 69364-63-2 | |\\ | 63. | | Isoceteth-30 | 69364-63-2 | |\\ | 64. | | Disodium Lauroamphodipropionate | 68929-04-4 | Rhodia |\\ | 65. | | Hexaethylene glycol monododecyl ether _14b_ | 3055-96-7 | Sigma Aldrich (UK) |\\ | 66. | (m) | Neopentyl Glycol Diisononanoate _15_ | 27841-07-2 | Symrise (Germany) |\\ | 67. | Cetearyl Ethylhexnoate _16_ | 90411-68-0 |\\ | 68. | (n) | 2-ethylhexyloxypropanediol _17_ | 70455-33-9 | Takasago (JP) |\\ | 69. | (o) | Panthenol Ethyl Ether _18_ | 667-83-4 | DSM Nutritional Products, Inc. |\\ | | | | | (USA) |\\ | 70. | DL-Panthenol | 16485-10-2 | Roche Inc. (USA) |\\ | 71. | (p) | Diisobutyl Adipate _19_ | 141-04-8 | Sigma Aldrich (UK) |\\ | 72. | Diisoamyl Adipate _19_ | 6624-70-0 |\\ | 73. | (q) | PPG-11 Stearyl Ether _19a_ | 25231-21-4 | Kao (JP) |\\ | 74. | (r) | _N_-hexadecyl n-nonanoate _19b_ (i.e., cetyl nonanoate) | 72934-15-7 | Symrise (Germany) |\\ | 75. | Noctadecyl n-nonanoate _19b_ (i.e., stearyl nonanoate) | 107647-13-2 |\\ | 76. | | methanone, (morphonyl)tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 77. | | methanone, (piperidinyl)tricyclo\\[3.3.1.1 _3,7_\\]dec-l-yl- _20_ | -- | |\\ | 78. | | methanone, (pyrrolidinyl)tricyclo\\[3.3.1.13,7\\]dec-1-yl _20_ | -- | |\\ | 79. | | methanone, (azetidinyl)tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 80. | | methanone, (hexahydroazepinyl)tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 81. | | methanone, (4-cyano-piperidinyl)tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 82. | | methanone, (4-amido-piperidmyl)tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 83. | (s) | methanone, (Tricyclo\\[3.3.1.13,7\\]decanyl)- _N-_ tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | Unilever (UK) |\\ | 84. | | methanone, (decahydroisoqumolinyl)tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 85. | | methanone, (decahydroisoquinolinyl)tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 86. | | methanone, (decahydroqumolinyl)tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 87. | | methanone, (3,3-dimethyl-1-piperidinyl)tricyclo\\[3.3.1.13,7\\]dec-1-yl _20_ | -- | |\\ | 88. | | methanone, (2-methyl-1-piperidinyl)tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 89. | | methanone, (4-methyl-1-piperidinyl)tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 90. | | methanone, (3-methyl-1-piperidinyl)tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 91. | | methanone, (3,5-dimethyl-1 piperidinyl)tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 92. | | methanone, (4-methyl-4-ethy-piperidinyl)tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 93. | | methanone, (3,3-diethyl-1-pyrrolidinyl)tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 94. | | methanone, ( _N_, _N_-diisopropyl) tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 95. | | methanone, (3,3-dimethylbutylaminyl) tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 96. | | methanone, (2,2-dimethylpropylaminyl) tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 97. | | methanone, (1,1-dimethyl-3,3-dimethylbutylaminyl) tricyclo\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 98. | | methanone, (1,3-dimethyl-butylaminyl) tricycle\\[3.3.1.13,7\\]dec-1-yl- _20_ | -- | |\\ | 99. | (t) | Bis-methoxy PEG-13 PEG-438/PPG-110 SMDI Copolymer _21_ | 936645-35-1 | PolymerExpert S.A. (Pessac, France) |\\ | 100. | (u) | propyl {4-\\[2-(diethylamino)-2-oxoethoxy\\]-3-methoxyphenyl} acetate _22_ | 61791-12-6 | Sigma Aldrich (US) |\\ | 101. | (v) | 3-((2-ethylhexyl)oxy)propane-1,2-diol _23_ | 70445-33-9 | -- |\\ | 102. | 3-((2-propylheptyl)oxy)propane-1,2-diol _23_ | -- | -- |\\ | 103. | 1-amino-3-((2-ethylhexyl)oxy)propan-2-ol _23_ | 99509-00-9 | -- |\\ \\ \\ \\ | |\\ | --- |\\ | _1_ available as GLUCAM\u2122 P-20.<br>_2_ available as Glucam\u2122 E-20.<br>_3_ available as Plantacare\u00ae 810 UP.<br>_3a_ available as Simulsol\u00ae SL 11W.<br>_4_ available as CERAPHYL\u00ae ICA.<br>_5_ available as Tegosoft\u00ae APM.<br>_6_ available as Schercemol\u2122 NGDO.<br>_7_ disclosed in U.S. Patent No. 6,737,396B2 (Firmenich), column 1, lines 43-47.<br>_8_ diclosed as compound 1'i in [U.S. Patent No. 6,440,400B1](https://patents.google.com/patent/US6440400)(Takasago Int. Corp.), col. 5.<br>_8a_ diclosed in [U.S. Patent No. 4,313,855](https://patents.google.com/patent/US4313855) (Dragoco Gerberding & Co. GmbH), col. 1, lines 12-13.<br>_9_ disclosed in [U.S. Patent No. 7,538,081B2](https://patents.google.com/patent/US7538081)(Takasago Int. Corp.), column 7, lines 50-53.<br>_10_ disclosed in [U.S. Patent No. 6,147,049](https://patents.google.com/patent/US6147049) (Givaudan Roure), col. 5, line 24, to col. 6, line 17.<br>_11_ disclosed in PCT Publication No. WO85/04803 (Diagnostic), pg. 2, line 1 to pg. 4, line 2.<br>_12_ disclosed in JP Patent No. 61-083114 (Kanebo).<br>_13_ disclosed in JP Patent No. 61-063612 (Kanebo).<br>_14_ disclosed in JP Patent No. 62-084010 (Shiseido).<br>_14b_ available as: Laureth-6.<br>_15_ disclosed in [U.S. Patent Publication No. 2011/0104089A1](https://patents.google.com/patent/US20110104089) (Symrise), para. \\[0001\\].<br>_16_ available as PCL-Liquid\u00ae 100.<br>_17_ disclosed in [U.S. Patent No. 7,196,052](https://patents.google.com/patent/US7196052) (Takasago Int. Corp.), col. 4, lines 34-35.<br>_18_ disclosed in EP Patent Publication No. 616800A2 (Givaudan), pg. 2, lines 12-25.<br>_19_ disclosed in [U.S. Patent No. 4,110,626](https://patents.google.com/patent/US4110626) (Shiseido), column 3, lines 54-56.<br>_19a_ disclosed in [PCT Publication No. WO2014/155019](https://patents.google.com/patent/WO2014155019) (LVMH).<br>_19b_ disclosed in U.S. Patent No. 9,050,261 (Symrise).<br>_20_ disclosed as compounds C1-C22 in [WO2014/139952](https://patents.google.com/patent/WO2014139952) (Unilever).<br>_21_ available as Expert Gel\u00ae EG56.<br>_22_ available as Kolliphor\u00ae EL.<br>_23_ disclosed in U.S. Patent No. 9,050,261 (Symrise). |\\ \\ - \\[0095\\]\\ \\ Preferably, the substantially non-odorous fragrance modulator is selected from the group of materials disclosed in Table 4(b).\\ Table 4(b): Substantially Non-Odorous Fragrance Modulators\\ \\ \\ | **No.** | **Chemical or INCI Name** | **Trade Name** | **CAS Number** | **Supplier** | |\\ | :-: | :-: | :-: | :-: | :-: | :-: |\\ | 1. | C12-14 Sec-Pareth-3 | Tergitol\u00ae 15-S-7 | 68131-40-8 | Sigma Aldrich (UK) |\\ | 2. | Poly(ethylene glycol-ran-propylene glycol) monobutyl ether | PPG-7-Buteth-10 | 9038-95-3 | Sigma Aldrich (UK) |\\ | 3. | PPG-4-Ceteth-10 | Nikkol PBC-33 | 37311-01-6 | Chemical Navi |\\ | 4. | Deceth-4 | Ethal DA-4 | 5703-94-6 | Ethox Chemicals, Inc. |\\ | 5. | PPG-5-Ceteth-20 | AEC PPG-5-Ceteth-20 | 9087-53-0 | A&E Connock (Perfumery & Cosmetics) |\\ | | | | | Ltd. |\\ | 6. | C14-15 Pareth-7 | Neodol 45-7 alcohol ethoxylate | 68951-67-7 | Shell Chemical Company |\\ | 7. | Linear alcohol (C12-15) Pareth-3ethoxylate, POE-7 | Bio-soft N25-7 | 68131-39-5 | Stephan Company (USA) |\\ | 8. | Linear alcohol (C12-13) Pareth-3ethoxylated, POE-6.5) | Bio-soft N23-6.5 | 66455-14-9 |\\ | 9. | Polyethylene glycol 1100 mono(hexadecyl/octadecyl) ether | Cremophor\u00ae A 25 | 68439-49-6 | Sigma Aldrich (UK) |\\ | 10. | Linear alcohol (C9-11) ethoxylated POE -8 Pareth-3 | Bio-soft N91-8 | 68439-46-3 | Stephan Company (USA) |\\ | 11. | Coceth-10 or Polyoxyethylene (10) dodecyl ether | Genapol\u00ae C-100 | 61791-13-7 | Sigma Aldrich (UK) |\\ | 12. | Alcohols, C12-14, ethoxylated | Rhodasurf\u00ae LA 30 | 68439-50-9 | Solvay Solutions Italia S.p.A. |\\ | 13. | Poly(ethylene glycol) methyl ether | Poly(ethylene glycol) methyl ether | 9004-74-4 | Sigma Aldrich (UK) |\\ | 14. | C10-16 Pareth-1 | Neodol\u00ae PC 110 | 68002-97-1 | Shell Chemical Company |\\ | 15. | PPG-11 Stearyl Ether | Arlamol\u2122 PS11E | 25231-21-4 | Croda (UK) |\\ | 16. | Steareth-100 | Brij\u00ae S100 | 9005-00-9 | Sigma Aldrich (UK) |\\ | 17. | Polyethylene glycol hexadecyl ether | Brij\u00ae C-58 | 9004-95-9 | Sigma Aldrich (UK) |\\ | 18. | Pluronic\u00ae F-127 | Pluronic\u00ae F-127 | 9003-11-6 | Sigma Aldrich (UK) |\\ | 19. | Linear Alcohol (C11) Ethoxylate, POE-5 | Bio-soft N1-5 | 34398-01-1 | Stepan Canada Inc. |\\ | 20. | Laureth-10 | Intrasol FA 12/18/10 | 6540-99-4 | Evonik Industries AG |\\ | 21. | Decaethylene glycol mono-dodecyl ether | Polyoxyethylene (10) lauryl ether | 9002-92-0 | Sigma Aldrich (UK) |\\ | 22. | Ethylene glycol monomethyl ether | 2-Methoxyethanol | 109-86-4 | Sigma Aldrich (UK) |\\ | 23. | Myreth-4 | Homulgator 920 G | 27306-79-2 | Grau Aromatics GmbH & Company KG |\\ | 24. | Oleth-16 | Pegnol O-16A | 25190- | Toho |\\ \\ \\ \\ \\ | | Alkoxylated Alcohols | | 05-0 | Chemical Industry Co., Ltd. |\\ | :-: | :-: | :-: | :-: | :-: |\\ | 25. | Isosteareth-5 | Emalex 1805 | 52292-17-8 | Nihon Emulsion Company, Ltd. |\\ | 26. | PPG-10 Cetyl Ether | Arlamol\u2122 PC 10 | 9035-85-2 | Croda (UK) |\\ | 27. | Polyoxy(ethylene glycol) (18) tridecyl ether | Poly(ethylene glycol) (18) tridecyl ether | 24938-91-8 | Sigma-Aldrich (UK) |\\ | 28. | Poly(oxy-1,2-ethanediyl), a-decyl-w-hydroxy- | ALFONIC\u00ae 10-8 Ethoxylate | 26183-52-8 | Sasol Chemicals (USA) LLC |\\ | 29. | Laureth- 1 | Mackam\u2122 2LSF | 4536-30-5 | Rhodia (DE) |\\ | 30. | PEG-5 Hydrogenated Tallow Amine | Ethox HTAM-5 | 61791-26-2 | Ethox Chemicals, Inc. |\\ | 31. | PEG-15 Oleamine | Nikkol TAMNO-15 | 26635-93-8 | Nikko Chemicals Co., Ltd. |\\ | 32. | Polyoxyethylene (20) oleyl ether | Brij\u00ae O20-SS | 9004-98-2 | Sigma Aldrich (UK) |\\ | 33. | Cetoleth-10 | Brij\u00ae CO10 | 8065-81-4 | Croda, Inc. |\\ | 34. | Talloweth-7 | Emulmin 70 | 61791-28-4 | Sanyo Chemical Industries Ltd. |\\ | 35. | Isobutoxypropanol Alcohols | Isobutoxypropanol | 34150-35-1 | MolPort |\\ | 36. | Isobutoxypropanol Alcohols | Isobutoxypropanol | 23436-19-3 | AKos Consulting & Solutions |\\ | 37. | Diethylene Glycol | Twincide EDG | 111-46-6 | Roda |\\ | 38. | Methoxyethanol | Hisolve MC | 109-86-4 | Toho Chemical Industry Co., Ltd. |\\ | 39. | Ethoxyethanol Alcohols | 2-Ethoxyethanol | 110-80-5 | Sigma-Aldrich (UK) |\\ | 40. | Methoxyisopropanol Alcohols | Dowanol\u2122 PM | 107-98-2 | The Dow Chemical Company |\\ | 41. | Methoxyethanol | Hisolve MC | 32718- | Toho |\\ \\ \\ \\ \\ | | | | 54-0 | Chemical Industry Co., Ltd. |\\ | :-: | :-: | :-: | :-: | :-: |\\ | 42. | Methylal Ethers | Dimethoxymethane | 109-87-5 | Sigma-Aldrich (UK) |\\ | 43. | 3-Methoxybutanol | Methoxybutanol | 2517-43-3 | Hans Schwarzkopf GmbH / Co. KG |\\ | 44. | Butoxyethanol | Butyl OXITOL | 111-76-2 | Shell Chemical Company |\\ | 45. | Propylene Glycol n-Butyl Ether | Dowanol\u2122 PnB | 5131-66-8/29387 -86-8 | The Dow Chemical Company |\\ | 46. | Propylene Glycol Butyl Ether | Propylene Glycol Butyl Ether | 15821-83-7 | Sigma Aldrich (UK) |\\ | 47. | 2-(2-butoxyethoxy)ethanol | Diethylene glycol butyl ether | 112-34-5 | Sigma Aldrich (UK) |\\ | 48. | Deceth-4 Phosphate | Crodafos\u2122 D4A | 52019-36-0 | Croda, Inc. |\\ | 49. | 2-(Hexadecyloxy)ethanol | Ethylene glycol monohexadecyl ether | 2136-71-2 | Sigma-Aldrich (UK) |\\ | 50. | Poly(propylene glycol) monobutyl ether | Poly(propylene glycol) monobutyl ether | 9003-13-8 | Sigma-Aldrich (UK) |\\ | 51. | Propylene Glycol Propyl Ether | Dowanol\u2122 PnP | 30136-13-1 | The Dow Chemical Company |\\ | 52. | Propylene Glycol n-Butyl Ether | Dowanol\u2122 PnB | 29387-86-8/5131-66-8 | The Dow Chemical Company |\\ | 53. | Dipropylene glycol monomethyl ether | Di(propylene glycol) methyl ether, mixture of isomers | 34590-94-8 | Sigma Aldrich (UK) |\\ | 54. | Dipropylene Glycol Dimethyl Ether | Proglyde\u2122 DMM | 111109-77-4 | The Dow Chemical Company |\\ | 55. | PPG-2 Methyl Ether | Dowanol\u2122 DPM | 13429-07-7 | The Dow Chemical Company |\\ | 56. | Methoxydiglycol Ethers | OriStar DEGME | 111-77-3 | Orient Stars LLC |\\ | 57. | Diethylene glycol ethyl ether | Di(ethylene glycol) ethyl ether | 111-90-0 | Sigma Aldrich (UK) |\\ | 58. | Dimethoxydiglycol Ethers | Dimethyldiglycol | 111-96-6 | H&V Chemicals |\\ | 59. | PPG-3 Methyl Ether | Dowanol\u2122 TPM | 37286-64-9 | The Dow Chemical Company |\\ | 60. | Methyl Morpholine Oxide Amine Oxides | 224286 ALDRICH 4-Methylmorpholine N-oxide | 7529-22-8 | Sigma-Aldrich (UK) |\\ | 61. | Oleth-3 | Brij\u00ae 03 | 5274-66-8 | Croda Europe, Ltd. |\\ | 62. | Tri(propylene glycol) n-butyl ether | Dowanol\u2122 TPnB | 55934-93-5 | Sigma-Aldrich (UK) |\\ | 63. | Tripropylene Glycol | Tripropylene Glycol | 24800-44-0 | Sigma-Aldrich (UK) |\\ | 64. | PPG-3 Methyl Ether Alkoxylated Alcohols | Dowanol\u2122 TPM | 25498-49-1 | The Dow Chemical Company |\\ | 65. | Triethylene glycol | Triglycol | 112-27-6 | Sigma Aldrich (UK) |\\ | 66. | PEG-3 Methyl Ether | Hymol\u2122 | 112-35-6 | Toho Chemical Industry Co., Ltd. |\\ | 67. | Laureth-3 | AEC Laureth-3 | 3055-94-5 | A&E Connock (Perfumery & Cosmetics) Ltd. |\\ | 68. | Ethylhexylglycerin | AG-G-75008 | 70445-33-9 | Angene Chemical |\\ | 69. | Tetra(ethylene glycol) | Tetraethylene glycol | 112-60-7 | Sigma Aldrich (UK) |\\ | 70. | Steareth-3 | Isoxal 5 | 4439-32-1 | Vevy Europe SpA |\\ | 71. | Ceteth-3 | Emalex 103 | 4484-59-7 | Nihon Emulsion Company, Ltd. |\\ | 72. | Myreth-3 | Isoxal 5 | 26826-30-2 | Vevy Europe SpA |\\ | 73. | Trideceth-3 | Alfonic\u00ae TDA-3 Ethoxylate | - | Sasol North America, Inc. |\\ | 74. | Ceteth-2 | Brij\u00ae C2 | 5274-61-3 | Croda Europe, Ltd. |\\ | 75. | Oleth-2 | Brij\u00ae 02 | 5274-65-7 | Croda, Inc. |\\ | 76. | Steareth-2 | Brij\u00ae S2 | 16057-43-5 | Croda, Inc. |\\ | 77. | Cetoleth-10 | Brij\u00ae CO10 | 8065-81-4 | Croda, Inc. |\\ | 78. | Trimethyl Pentanol Hydroxyethyl Ether Alcohols | Trimethyl Pentanol Hydroxyethyl Ether | 68959-25-1 | Angene Chemical |\\ | 79. | Steareth-10 Allyl Ether | Salcare\u00ae SC80 | 109292-17-3 | BASF |\\ | 80. | TEA-Lauryl Ether | material ID- AG-J-99109 | 1733-93-3 | Angene Chemical |\\ | 81. | Polyglyceryl-2 Oleyl Ether | Chimexane NB | 71032-90-1 | Chimex |\\ | 82. | Batyl Alcohol | B402 ALDRICH | 544-62-7 | Sigma-Aldrich (UK) |\\ | 83. | Octaethylene Glycol | 15879 ALDRICH | 5117-19-1 | Sigma-Aldrich (UK) |\\ | 84. | Triglycerol diisostearate | Cithrol\u2122 | 66082-42-6 | Croda (UK) |\\ | 85. | Diglycerin | Diglycerin 801 | 59113-36-9 | Sakamoto Yakuhin Kogyo Co., Ltd. |\\ | 86. | Polyglycerin #310 | Polyglycerin #310 | 25618-55-7 | Sakamoto Yakuhin Kogyo Co., Ltd. |\\ | 87. | Distearyl Ether | Cosmacol\u00ae SE | 6297-03-6 | Sasol Germany GmbH |\\ | 88. | Caprylyl Glyceryl Ether | Caprylyl Glyceryl Ether | 10438-94-5 | AKos Consulting & Solutions |\\ | 89. | Chimyl Alcohol | Chimyl Alcohol | 506-03-6 | Nikko Chemicals Co., Ltd. |\\ | 90. | Dipentaerythrityl Hexacaprylate/Hexacaprate | Liponate\u00ae DPC-6 | 68130-24-5 | Lipo Chemicals, Inc. |\\ | 91. | Morpholine | 394467 ALDRICH | 110-91-8 | Sigma-Aldrich (UK) |\\ | 92. | Dimethyl Oxazolidine | OXABAN\u2122 -A | 51200-87-4 | The Dow Chemical Company |\\ | 93. | Ethyl Hydroxymethyl Oleyl Oxazoline | 4-Oxazolemethanol | 68140-98-7 | Angene Chemical |\\ | 94. | Methyl Hydroxymethyl Oleyl Oxazoline | Adeka Nol GE-RF | 14408-42-5 | Adeka Corporation |\\ | 95. | Pramoxine HCl | OriStar PMHCL | 637-58-1 | Orient Stars LLC |\\ | 96. | Allantoin Ascorbate | Allantoin Ascorbate | 57448-83-6 | ABI Chem |\\ | 97. | Stearamidopropyl Morpholine Lactate | Mackalene\u2122 326 | 55852-14-7 | Rhodia Inc. |\\ | 98. | Dioxolane | Elcotal DX | 646-06-0 | Lambiotte & CIE S.A. |\\ | 99. | Glycerol Formal | Glycerol Formal | 5464-28-8 | Sigma Aldrich (UK) |\\ | 100. | Stearamidopropyl Morpholine | Mackine 321 | 55852-13-6 | Rhodia Inc. |\\ | 101. | 2,4,6-Tris\\[bis(methoxymethyl)amino\\] -1,3,5-triazine | Poly(melamine-co-formaldehyde) methylated | 68002-20-0 | Sigma-Aldrich (UK) |\\ | 102. | Poloxamine 1307 | Pluracare\u00ae 1307 | 11111-34-5 | BASF |\\ | 103. | Nonoxynol-8 | Igepal\u00ae CO-610 | 27177-05-5 | Rhodia Inc. |\\ | 104. | Nonoxynol-10 | Igepal\u00ae CO-710 | 27177-08-8 | Rhodia Inc. |\\ | 105. | Octoxynol-10 | Nikkol OP-10 | 2315-66-4 | Nikko Chemicals Co., Ltd. |\\ | 106. | Nonoxynol-9 | Igepal\u00ae CO-630 | 68987-90-6 | Rhodia Inc. |\\ | 107. | Nonoxynol-9 Iodine | Nonoxynol-9 iodine | 94349-40-3 | Angene Chemical |\\ | 108. | Octylphenoxy poly(ethyleneoxy)ethanol, branched | Igepal\u00ae CA-630 | 68987-90-6 | Rhodia Inc. |\\ | 109. | Sodium Octoxynol-2 Ethane Sulfonate | Triton\u2122 X-200 | 55837-16-6 | The Dow Chemical Company |\\ | 110. | Benzylhemiformal | Preventol D2 | 14548-60-8 | Lanxess Corporation |\\ | 111. | Nonoxynol-2 | Igepal\u00ae CO-210 | 27176-93-8 | Rhodia Inc. |\\ | 112. | Octoxynol-3 | Igepal\u00ae CA-420 | 2315-62-0 | The Dow Chemical Company |\\ | 113. | Nonoxynol-3 | Marlophen NP 3 | 27176-95-0 | Sasol Germany GmbH |\\ | 114. | Alkoxylated Alcohols | Alkasurf NP-4 | 7311-27-5 | Rhodia Inc. |\\ | 115. | Nonoxynol-3 | Triethylene Glycol Mono(p-nonylphenyl) Ether | 51437-95-7 | Santa Cruz Biotechnolog y |\\ | 116. | Nonoxynol-7 | Lowenol 2689 | 27177-03-3 | Jos. H. Lowenstein & Sons, Inc. |\\ | 117. | Nonoxynol-6 | Igepal\u00ae CO-530 | 27177-01-1 | Rhodia Inc. |\\ | 118. | Nonoxynol-5 | Igepal\u00ae CO-520 | 20636-48-0 | Rhodia Inc. |\\ | 119. | Nonoxynol-5 | Igepal\u00ae CO-520 | 26264-02-8 | Rhodia Inc. |\\ | 120. | Nonoxynol-4 | Alkasurf NP-4 | 27176-97-2 | Rhodia Inc. |\\ | 121. | Polyglyceryl-10 Trioleate | Nikkol Decaglyn 3-OV | 102051-00-3 | Nikko Chemicals Co., Ltd. |\\ | 122. | Polyglycetyl-10 Dioleate | Nikkol Decaglyn 2-O | 33940-99-7 | Nikko Chemicals Co., Ltd. |\\ | 123. | Polyglyceryl-10 Tetraoleate | Caprol 10G40 | 34424-98-1 | Abitec Corporation |\\ | 124. | Polyglyceryl-10 Stearate | Nikkol Decaglyn 1-SV EX | 79777-30-3 | Nikko Chemicals Co., Ltd. |\\ | 125. | Polyglyceryl-10 Oleate | S-Face O-1001 P | 79665-93-3 | Sakamoto Yakuhin Kogyo Co., Ltd. |\\ | 126. | Polyglyceryl-10 Myristate | Nikkol Decaglyn 1-MV EX | 87390-32-7 | Nikko Chemicals Co., Ltd. |\\ | 127. | Dermofeel\u00ae G 10 L | Dermofeel\u00ae G 10 L | 34406-66-1 | Dr. Straetmans |\\ | 128. | Polyglyceryl-6 Laurate | NIKKOL Hexaglyn 1-L | 51033-38-6 | Chemical Navi |\\ | 129. | Polyglyceryl-6 Isostearate | S-Face IS-601 P | 126928-07-2 | Sakamoto Yakuhin Kogyo Co., Ltd. |\\ | 130. | Choleth-10 | Emalex CS-10 | 27321-96-6 | Nihon Emulsion Company, Ltd. |\\ | 131. | Steareth-10 Allyl Ether/Acrylates Copolymer | Salcare\u00ae SC80 | 109292-17-3 | BASF |\\ | 132. | Polyvinyl Stearyl Ether | Giovarez\u00ae1800 | 9003-96-7 | Phoenix Chemical, Inc. |\\ | 133. | Dicetyl Ether | Cosmacol Ether | 16 | -- | Sasol Germany GmbH |\\ | 134. | PPG-23-Steareth-34 | Unisafe 34S-23 | 9038-43-1 | Pola Chemical Industries, Inc. |\\ | 135. | Stearoxypropyl Dimethylamine | Farmin DM E-80 | 17517-01-0 | Kao Corp. |\\ | 136. | Distearyl Ether | Cosmacol SE | 6297-03-6 | Sasol Germany GmbH |\\ | 137. | Polyquaternium-10 | AEC Polyquaternium-10 | 55353-19-0 | A&E Connock (Perfumery & Cosmetics) Ltd. |\\ | 138. | Octyl ether | Dioctyl ether | 629-82-3 | Sigma Adlrich (UK) |\\ | 139. | Ethyl Ether | Diethyl Ether | 60-29-7 | EMD Chemicals |\\ | 140. | Methyl Hexyl Ether Ethers | methyl hexyl ether | 4747-07-3 | TCI AMERICA |\\ | 141. | Ceteth-12 | Emalex 112 | 94159-75-8 | Nihon Emulsion Company, Ltd. |\\ | 142. | Ceteth-10 or cetyl alcohol POE-10 | Jeecol CA-10 | 14529-40-9 | Jeen International |\\ | 143. | Steareth-10 | Jeecol SA-10 | 13149-86-5 | Jeen International |\\ | 144. | Nonaethylene glycol monododecyl ether | Nonaethylene glycol monododecyl ether | 3055-99-0 | Sigma Aldrich (UK) |\\ | 145. | Oleth-10 | Brij\u00ae O10 | 71976-00-6 | Croda, Inc. |\\ | 146. | Oleth-10 | Brij\u00ae O10 | 24871-34-9 | Croda, Inc. |\\ | 147. | PEG-12 | Carbowax\u2122 PEG 600 | 6790-09-6 | The Dow Chemical Company |\\ | 148. | PEG-9 | Sabopeg 400 | 3386-18-3 | Sabo s.p.a. |\\ | 149. | PEG-10 | DECAETHYLENE | 5579- | MolPort |\\ | | | GLYCOL | 66-8 | |\\ | 150. | PEG-6 | Carbowax\u2122 PEG 300 | 2615-15-8 | The Dow Chemical Company |\\ | 151. | Glycerol propoxylate | Glycerol propoxylate | 25791-96-2 | Sigma Aldrich (UK) |\\ | 152. | Glycerol ethoxylate | Glycerol ethoxylate | 31694-55-0 | Sigma Aldrich (UK) |\\ | 153. | Laureth-8 | AEC Laureth-8 | 3055-98-9 | A&E Connock (Perfumery & Cosmetics) Ltd. |\\ | 154. | Oleth-8 | Emalex 508 | 27040-03-5 | Nihon Emulsion Company, Ltd. |\\ | 155. | Laureth-7 | Alfonic 1216CO-7 Ethoxylate | 3055-97-8 | Sasol North America, Inc. |\\ | 156. | Steareth-7 | Polyoxyethylene (7) stearyl ether | 66146-84-7 | Sigma Aldrich |\\ | 157. | Deceth-6 | Alfonic 1012-6.0 Ethoxylate | 5168-89-8 | Sasol North America, Inc. |\\ | 158. | Steareth-6 | Emalex 606 | 2420-29-3 | Nihon Emulsion Company, Ltd. |\\ | 159. | Hexaethylene glycol monododecyl ether | Hexaethylene glycol monododecyl ether | 3055-96-7 | Sigma-Aldrich (UK) |\\ | 160. | Hexaethylene glycol monohexadecyl ether | Hexaethylene glycol monohexadecyl ether | 5168-91-2 | Sigma-Aldrich (UK) |\\ | 161. | Beheneth-5 | Nikkol BB-5 | 136207-49-3 | Nikko Chemicals Co., Ltd. |\\ | 162. | Myreth-5 | Isoxal 12 | 92669-01-7 | Vevy Europe SpA |\\ | 163. | Steareth-5 | Jeecol SA-5 | 71093-13-5 | Jeen International Corporation |\\ | 164. | Ceteth-5 | Emalex 105 | 4478-97-1 | Nihon Emulsion Company, Ltd. |\\ | 165. | Oleth-5 | Brij\u00ae O5 | 5353-27-5 | Croda, Inc. |\\ | 166. | Laureth-5 | Safol\u00ae 23E5 Ethoxylate | 3055- | Sasol North |\\ | | | | 95-6 | America, Inc. |\\ | 167. | Steareth-4 | Jeecol SA-4 | 59970-10-4 | Jeen International Corporation |\\ | 168. | Laureth-4 | Brij\u00ae L4 | 5274-68-0 | Croda, Inc. |\\ | 169. | Myreth-4 | Homulgator 920 G | 39034-24-7 | Grau Aromatics GmbH & Company KG |\\ | 170. | Ceteth-4 | Procol CA-4 | 5274-63-5 | Protameen Chemicals |\\ | 171. | Oleth-4 | Chemal OA-4 | 5353-26-4 | Chemax, Inc. |\\ | 172. | Oleth-4 | Chemal OA-4 | 103622-85-1 | Chemax, Inc. |\\ | 173. | Polyimide-1 | Aquaflex\u2122 XL-30 | 497926-97-3 | Chemwill |\\ | 174. | Polymethoxy Bicyclic Oxazolidine | Caswell No. 494CA | 56709-13-8 | Angene Chemical |\\ | 175. | Hydroxymethyl Dioxoazabicyclooctane | Zoldine\u2122 ZT | 6542-37-6 | Angus Chemical Company |\\ | 176. | Dihydro-7a-ethyloxazolo\\[3,4-c\\]oxazole | 5-Ethyl-1-aza-3,7-dioxabicyclo\\[3.3.0\\]octan e | 7747-35-5 | Sigma Aldrich (UK) |\\ | 177. | Dibenzylidene Sorbitol | Disorbene\u00ae | 32647-67-9 | Roquette America, Inc. |\\ | 178. | Dimethyldibenzylidene Sorbitol | Millad\u00ae 3988 | 135861-56-2 | Milliken Chemicals |\\ | 179. | Laureth-2 | Alfonic 1216CO-2 Ethoxylate | 3055-93-4 | Sasol North America, Inc. |\\ | 180. | 2-(2-Butoxyethoxy)ethyl (6-propylpiperonyl) ether | Piperonyl Butoxide | 51-03-6 | Sigma-Aldrich (UK) |\\ | 181. | Menthone Glycerin Acetal | Frescolat\u00ae MGA | 63187-91-7 | Symrise |\\ | 182. | Propylene Glycol Caprylate | Mackadenn PGC | 68332-79-6 | Rhodia Inc. |\\ | 183. | Diethoxynonadiene | SBB016951 | 67674-36-6 | Ambinter |\\ | 184. | Menthoxypropanediol Alcohols | Coolact | \u00ae 10 | 87061-04-9 | Takasago International Corporation |\\ | 185. | 2-Diphenylmethoxy-N,N-dimethylethylamine hydrochloride | Diphenhydramine HCl | 147-24-0 | Sigma-Aldrich (UK) |\\ | 186. | 3-((2-ethylhexyl)oxy)propane-1,2-diol | -- | 70445-33-9 | -- |\\ | 187. | 3-((2-propylheptyl)oxy)propane-1,2-diol | -- | -- | -- |\\ | 188. | 1-amino-3-((2-ethylhexyl)oxy)propan-2-ol | -- | 99509-00-9 | -- |\\ | 189. | 1-(1-Methyl-2-propoxyethoxy)-2-propanol | Di(propylene glycol) propyl ether | 29911-27-1 | Sigma Aldrich (UK) |\\ \\ - \\[0096\\]\\ \\ The compounds, as described above in Tables 4(a) and 4(b), act as a substantially non-odorous fragrance modulator of the perceived fidelity and/or longevity of the fragrance profile of the composition of the present invention. For example, the substantially non-odorous fragrance modulators, with a fragrance component having a diamond construction, act to prolong the duration during which the fragrance profile, preferably the characters attributable from the moderate and high volatile fragrance materials, can be perceived as compared to a control composition in the absence of the modulators or having the classical fragrance pyramid three-tiered structure. As another example, the substantially non-odorous fragrance modulators, with a fragrance component having a diamond construction, can improve the fidelity of the fragrance profile, preferably the characters attributable from the moderate and high volatile fragrance materials, such that it remains significantly the same from initial impression to the end as compared to a control composition in the absence of the modulators or having the classical fragrance pyramid three-tiered structure. While not wishing to be bound by theory, it is believed that the substantially non-odorous fragrance modulators associate to the fragrance materials and retard evaporation.\\ \\ TEST METHODS- \\[0097\\]\\ \\ The following assays set forth must be used in order that the invention described and claimed herein may be more fully understood.\\ \\ Test Method 1: Determining Vapor Pressure- \\[0098\\]\\ \\ In order to determine the vapor pressure for the fragrance materials, go to the website _https:_// _scifinder.cas.org_/ _scifinder_/ _view_/ _scifinder_/ _scifinderExplore.jsf_ and follow these steps to acquire the vapor pressure.\\ \\ \\ 1. 1\\. Input the CAS registry number for the particular fragrance material.\\ 2. 2\\. Select the vapor pressure from the search results.\\ 3. 3\\. Record the vapor pressure (given in Torr at 25 \u00b0C).\\ \\ - \\[0099\\]\\ \\ SciFinder uses Advanced Chemistry Development (ACD/Labs) Software Version 11.02. (\u00a9 1994-2013). If the CAS number for the particular fragrance material is unknown or does not exist, you can utilize the ACD/Labs reference program to directly determine the vapor pressure. Vapor Pressure is expressed in 1 Torr, which is equal to 0.133 kilopascal (kPa).\\ \\ Test Method 2: Olfactory Tests- \\[0100\\]\\ \\ In order to show the effect of the substantially non-odorous fragrance modulators and fragrance component having a diamond construction on the perception of fragrance profile in a composition of the present invention, test compositions are made, as described in the Example section, and given to panelists to evaluate.\\ \\ - \\[0101\\]\\ \\ At the testing facility, 50 \u00b5L samples of the compositions and the controls are applied to glass slides and placed on a hot plate at 32 \u00b0C to represent skin temperature for varying durations. It is important that glass slides of samples that are to be later compared are prepared at the same time. The panelists are asked to evaluate the perceived fragrance profile (intensity and/or character) of each glass slide sample at a given time point. Slides are presented coded so that their identity is not known by the panelists. Within a given time point panelists evaluate the slides in a random order and are able to revisit their assessment as they work through the slides at that time point. Their assessments are recorded. In the subsequent analysis, the data for strength and character comparisons are drawn from the independent assessments carried out at a given time point. Only when using the character difference scale below are any 2 products physically directly compared to each other. Panelists are selected from individuals who are either trained to evaluate fragrances according to the scales below or who have experience of fragrance evaluation in the industry. Typically, around 6-10 panellists are used to evaluate a given product and its control.\\ \\ (a) Fragrance Intensity:- \\[0102\\]\\ \\ The panelists are asked to give a score on a scale of 0 to 5 for perceived fragrance intensity according to the odour intensity scale set out in Table 4 herein below.\\ Table 4 - Odour Intensity Scale\\ \\ \\ | **Score** | **Fragrance Intensity** | |\\ | :-: | :-: | :-: |\\ | 0 | None |\\ | 1 | Very Weak |\\ | 2 | Weak |\\ | 3 | Moderate |\\ | 4 | Strong |\\ | 5 | Very Strong |\\ \\ (b) Fragrance Character:- \\[0103\\]\\ \\ The panelists are asked to assess the fragrance character in one of 2 ways:\\ \\ \\ 1. i) a score on a scale of 0 to 3 for the dominance of particular characters that are relevant to that particular fragrance, e.g.: fresh, green, watery, floral, rose, muguet, fruity, apple, berry, citrus, creamy, woody, balsamic, amber, musk just to name a few, according to the odour grading scale set out in Table 5(i) herein below;\\ 2. ii) a score on a scale of 1 to 5 for changes in the perceived fragrance profile change for the test compositions versus the controls according to the odour grading scale set out in Table 5(ii) herein below.\\ \\ Table 5(i) - Character Dominance Odour Grading Scale\\ \\ | **Score** | **Fragrance Character Dominance** |\\ | :-: | :-: |\\ | 0 | Not noticeable |\\ | 1 | Slight presence of the character |\\ | 2 | Moderate presence of the character |\\ | 3 | Dominance of the character |\\ \\ Table 5(ii) - Character Difference Odour Grading Scale\\ \\ | **Score** | **Fragrance Profile Change** |\\ | :-: | :-: |\\ | 1 | Frargrance profile is unchanged, i.e., no difference between the sample vs. the control. |\\ | 2 | Slight fragrance profile change when compared directly with the control. |\\ | 3 | Moderate fragrance profile but similar character to the control, |\\ | 4 | Large difference in fragrance profile from the control. |\\ | 5 | Total difference in the fragrance profile from the control. |\\ \\ - \\[0104\\]\\ \\ The results of the panelists are averaged and then analysed using Analysis of Variance methods. The model treats the subject as a random effect and looks at the impact of product, time and the interaction between product and time. From the analysis the least square means for the product and time interaction are obtained. These means (as well as their confidence intervals) are then plotted to enable comparisons between products at each time point. It should be noted that the confidence levels plotted are intended as a guide, and not as a statistical comparison, as they do not take into account that multiple testing has been performed. As well as a graphical assessment, statistical comparisons between the two products at each of the time points are performed with a Sidak correction for multiple comparisons. The p-values for the product differences are obtained, with p-values < 0.05 indicating a statistical difference between the two products at 5% significance (or 95% confidence).\\ \\ Test Method 3: Analytical Evaporation Tests- \\[0105\\]\\ \\ The following test is carried out to demonstrate the improved or enhanced longevity of a fragrance profile of a composition of the present invention vs. a control. In particular, the test measures the effect of a substantially non-odorous fragrance modulator on the evaporation rate of one or more fragrance materials (e.g., 10 PRMs) formulated in a composition. The evaporation response of the fragrance materials to the modulator, as a function of time, is measured through the use of gas chromatography (\"GC\").\\ \\ \\ 1\\. A test composition may comprise a substantially non-odorous fragrance modulator (any one of the modulators as disclosed in Tables 4(a) and 4(b)) with either: (i) a fragrance material (any one of the moderate volatile fragrance materials as disclosed in Table 2 and high volatile fragrance materials as disclosed in Table 3), or (ii) a blend of fragrance materials from Tables 2 and 3 (as disclosed as Fragrance Example 6 in Table 11). The test compositions also contain high purity ethanol, such as Hayman 100%EP/BP grade, and deionized water. Samples test compositions are provided in Tables 19(a)-19(b). All of the ingredients are admixed until evenly distributed in the test compositions.\\ \\ \\ 2\\. A control composition to the test composition described in 1 above, without the substantially non-odorous fragrance modulator is made in a similar manner to Step 1, except that the missing substantially non-odorous modulator is replaced by deionized water. Sample control compositions are provided in Tables 19(a)-19(b).\\ \\ \\ 3\\. An internal standard is needed to correct for variations of the amount of composition dispensed in the evaporation test as well as loss during the GC analysis. The internal standard has a vapor pressure of less than 0.001 Torr (0.000133 kPa) at 25 \u00b0C and is soluble in the composition and fragrance material. A suitable non-limiting example of an internal standard is triethyl citrate. The internal standard and fragrance material are admixed until evenly distributed at a level of 90 to 95 parts by weight of fragrance material and the required amount of internal standard to reach 100 parts. This mixture is then use to prepare the sample compositions in Step 1 and 2. Alternatively, the internal standard and test or control composition are admixed until evenly distributed at a level of 99 to 99.75 parts by weight of composition and the required amount of internal standard to reach 100 parts. This resultant solution is used in subsequent steps.\\ \\ \\ 4\\. A hotplate is set to a temperature of 32 \u00b0C. An aluminum container, such as TA Instruments T-Zero\u2122 pan, is placed on the hotplate. 20 \u00b5L of the test or control composition is introduced in the aluminum container using a micropipette. Alternatively, the aluminum container may be filled with the test or control composition to its full capacity. The time at which this takes place is determined to be time zero ( _i.e.,_ T = 0). Multiple aluminum containers are prepared and left at the set temperature for pre-determined periods of time, such as for example 30 mins, 1 hr, 2 hrs, 3 hrs, 4 hrs, 5 hrs, 6 hrs, 8 hrs and up to 12 hrs.\\ \\ \\ 5\\. The aluminum container is removed from the hotplate at the end of the pre-determined time period and transferred by being inserted into a 4 mL glass vial already containing at least 2 mL of highly volatile solvent, such as high purity ethanol or hexane.\\ \\ \\ 6\\. The glass vial is mixed using a Heidolph multi REAX shaker, or equivalent, for 5 to 10 mins to extract the fragrance materials into the solvent phase. 1.5 mL of the resultant solution is transferred to a 2 mL GC vial.\\ \\ \\ 7\\. The GC vial is analysed on an Agilent GC system 6890 equipped with an autosampler, or equivalent. A GC column such as a DB-5MS, Rxi-5 SilMS model or equivalent phase, with a length of 30 m, an inner diameter of 0.25 mm and a film thickness of 1 \u00b5m is used. The GC parameters are set to the values indicated as follows:\\ Table 5(iii) - GC Parameters\\ \\ | | |\\ | --- | --- |\\ | Injector temperature: | 270 \u00b0C |\\ | Initial gas velocity: | 25 to 40 cm/sec (for Helium as the carrier gas) |\\ | Initial oven temperature: | 50 \u00b0C |\\ | Temperature ramp: | 8 \u00b0C/min |\\ | Final oven temperature: | 310 \u00b0C |\\ \\ \\ Gas chromatography with flame ionization detection (\"FID\") or with mass spectrometry (\"MS\") can be used for the identification and quantification of fragrance material in the compositions. Either detection system can be used in conjunction with GC. The column dimensions as well as GC settings described in this method, such as injector temperature, carrier gas velocity, temperature ramp and final oven temperature can be adjusted to optimize the response of the fragrance material and internal standard being monitored. The detection system settings, such as FID gas flows and temperature or MS parameters, should be optimized by a trained analyst to enable the precise detection and quantification of the analytes of interest.\\ \\ \\ 8\\. The peak area of the fragrance material and internal standard are recorded. The peak area ratio of the fragrance material and the internal standard is calculated at each time point for each sample composition. The % of non-evaporated fragrance material remaining from T = 0 is calculated at each time point for each sample composition. The % fragrance material remaining in each composition is plotted to give an evaporation profile over time. This is done for both the test and control compositions. Significance is determined by comparison of the evaporation profile for the same fragrance material or same fragrance mixture in the test and control compositions.\\ \\ Test Method 4: Analytical Headspace Tests- \\[0106\\]\\ \\ The following test is carried out to demonstrate the character retention over time of a fragrance composition of the present invention vs. a control. It is necessary for the test and control samples to be run at approximately the same time to ensure that ambient conditions are the same. The test measures the presence of one or more fragrance materials in the headspace formed in a sealed vial by the test composition, after set evaporation times. The fragrance profile in the headspace is measured at specific time points through the use of headspace (\"HS\") gas chromatography (\"GC\").\\ \\ \\ 1\\. The test and control compositions as described in the Example section are used for the evaluation.\\ \\ \\ 2\\. Capillaries of about 2 cm to 3.5 cm, with one sealed end are cut from a Sigma Aldrich \"Stuart\u2122 melting point tube\" product code Z673269, or equivalent. A suitable fixed volume chosen between 50 and 200 \u00b5L of the composition is pipetted into the well of a VWR Tissue Culture 96 F well plate, or equivalent. The sealed end of the glass capillary is dipped into the filled well and left for at least 15 secs to wet the surface of the glass. Care must be taken not to contact the glass capillary with the sides of the well by maintaining it straight and approximately in the center of the well.\\ \\ \\ 3\\. The glass capillary is then removed from the well and inverted or transferred onto a stable surface or into a holder and allowed to evaporate at ambient conditions for a set period of time. A windshield may be used to reduce high air turbulence.\\ \\ \\ 4\\. The glass capillary is then introduced into an empty 20 mL HS vial, which is immediately closed with a PTFE cap. The time at which this takes place is determined to be time T = initial ( _i.e.,_ T = 10 mins).\\ \\ \\ 5\\. Multiple glass capillaries are prepared in the same way and left to evaporate at ambient temperature for pre-detennined periods of time, such as for example 10, 15, 30 mins, 1 hr, 2 hrs, 3 hrs, 4 hrs, 5 hrs, and up to 6 hrs, before being introduced to the headspace vial and sealed.\\ \\ \\ 6\\. The HS vial is then analysed on an Agilent GC system 6890 equipped with a Gerstel MPS 2 autosampler, or equivalent, capable of performing SPME injections. A SPME fiber assembly DVB/CAR/PDMS (50/30 \u00b5m, 1 cm length) is required. A GC column such as a DB-5MS, ZB-5MSi models, or equivalent phase, with a length of 30 m, an inner diameter of 0.25 mm and a film thickness of 1 \u00b5m is used.\\ \\ \\ 7\\. The SPME HS parameters are set to the values indicated as follows:\\ Table 5(iv) - SPME Parameters\\ \\ | | |\\ | --- | --- |\\ | Incubation chamber temperature: | 40 \u00b0C |\\ | Incubation time: | 20 mins |\\ | Agitation of sample | 250 RPM |\\ | Extraction time |\\ | | 5 mins |\\ | Desorption time |\\ | | 2 mins |\\ \\ \\ 8\\. The GC parameters are set to the values indicated as follows:\\ Table 5(v) - GC Parameters\\ \\ | | |\\ | --- | --- |\\ | Injector temperature: | 270 \u00b0C |\\ | Initial gas velocity: | 20 to 40 cm/sec (for Helium as the carrier gas) |\\ | Initial oven temperature: | 45\u00b0C with 2 mins Hold Time |\\ | Temperature ramp 1: | 30 \u00b0C/min |\\ | Temperature 1: | 80 \u00b0C |\\ | Temperature ramp 2: | 8\u00b0C/min |\\ | Final temperature: | 300 \u00b0C |\\ \\ \\ Gas chromatography with flame ionization detection (\"FID\") or with mass spectrometry (\"MS\") can be used for the identification and quantification of fragrance material in the compositions. Either detection system can be used in conjunction with GC. The column dimensions as well as GC settings described in this method, such as injector temperature, carrier gas velocity, temperature ramp and final oven temperature can be adjusted to optimize the response of the fragrance material being monitored. The detection system settings, such as FID gas flows and temperature or MS parameters, should be optimized by a trained analyst to enable the precise detection and identification of the analytes of interest.\\ \\ \\ 9\\. A qualitative assessment of the chromatograms obtained is performed by comparing the peak height of the fragrance materials and overall chromatogram at time T = 10 mins to other time points. A dotted line is drawn around an estimated retention time where fragrance materials with a vapour pressure of 0.001 Torr or less (0.000133 kPa or less) elute during the analysis. The difference between the peaks present at each measured time point for the test and control compositions provides evidence of the retention of the character of the fragrance over time.\\ \\ \\ 10\\. This test set-up is designed to enable the collection of the headspace in a manner that does not saturate the SPME fiber. If the fiber is saturated it does not provide an accurate analysis of the headspace composition. Therefore the quantity of liquid and the evaporation surface area are very different from those in the olfactive evaluation of the same samples. For this reason it is not possible to compare directly the evaporation time frames used in the 2 experiments. It is expected that the evaporation profile is much faster in this headspace experiments compared to the olfactive evaluations.\\ \\ EXAMPLES- \\[0107\\]\\ \\ The following examples are provided to further illustrate the present invention and are not to be construed as limitations of the present invention, as many variations of the present invention are possible without departing from its spirit or scope.\\ \\ Example 1 - Fragrance Oils- \\[0108\\]\\ \\ \\ - Fragrance examples 1, 2, 3, 4b and 5b are provided below in Tables 6, 7, 8, 9 and 10, respectively, as non-limiting examples of formulations of fragrance materials intended to form the fragrance component of the compositions of the present invention. The exemplary formulations of the fragrance materials span the range from \"simple accords\" (less than 10 fragrance materials) to \"complex fragrances\" (greater than 30 fragrance materials). Typically, full bodied fragrance compositions do not comprise less than about 30 fragrance materials.\\ - Fragrance examples 4a and 5a provided in Table 9 and 10, respectively, below are examples of traditional formulations of fragrance materials that fall outside the scope of the present invention.\\ - Fragrance example 6 provided in Table 11 below as an example of a formulation of volatile fragrance materials.\\ - Fragrance examples 7 and 8 are provided in Tables 12 and 13 below as examples of a formulation of fragrance materials intended to form the fragrance component that fall outside the scope of the present invention.\\ - Fragrance examples 9 to 16 are provided in Tables 14 and 15 below as examples of formulations of fragrance materials containing higher than 30 wt% of the low volatile fragrance materials.\\ - Fragrance examples 17 and 18 are provided in Tables 16 and 17 below as comparative samples of formulations of fragrance materials intended to form the fragrance component.\\ \\ - \\[0109\\]\\ \\ The following fragrance formulations are made by mixing the listed ingredients in the listed proportions (wt%) at room temperature, wherein the wt% is relative to the total weight of the fragrance component.\\ Table 6 - Fragrance Example 1 (Fresh Floral Accord - 10 wt% of Low Volatile Fragrance Materials\\ \\ \\ | **Ingredients** | **CAS Number** | **Vapor Pressure (Torr at 25 \u00b0C)** | **Parts (wt%)** |\\ | :-: | :-: | :-: | :-: |\\ | Benzyl acetate | 140-11-4 | 0.1640 | 10.8 |\\ | Linalool | 78-70-6 | 0.0905 | 9.8 |\\ | Phenethyl alcohol | 60-12-8 | 0.0741 | 15.7 |\\ | Indole | 120-72-9 | 0.0298 | 1.0 |\\ | \u03b1-Terpineol | 98-55-5 | 0.0283 | 2.9 |\\ | Geranyl acetate | 105-87-3 | 0.0256 | 4.9 |\\ | Cymal | 103-95-7 | 0.00881 | 5.9 |\\ | Hydroxycitronellal | 107-75-5 | 0.00318 | 22.4 |\\ | Majantol | 103694-68-4 | 0.00224 | 16.6 |\\ | Hexyl cinnamic aldehyde | 101-86-0 | 0.000697 | 10.0 |\\ | Total | 100.00 |\\ \\ Table 7 - Fragrance Example 2 (Fresh Male Accord - 13.51 wt% of Low Volatile Fragrance Materials\\ \\ \\ | **Ingredients** | **CAS Number** | **Vapor Pressure (Torr at 25 \u00b0C)** | **Parts (wt%)** |\\ | --- | :-: | :-: | :-: |\\ | d-Limonene | 5989-27-5 | 1.540000 | 10.0 |\\ | Dihydromyrcenol | 18479-58-8 | 0.166000 | 10.0 |\\ | Boisiris | 68845-00-1 | 0.013500 | 6.5 |\\ | Canthoxal | 5462-06-6 | 0.010200 | 8.0 |\\ | Helional | 1205-17-0 | 0.002700 | 10.0 |\\ | Kephalis | 36306-87-3 | 0.002690 | 20.0 |\\ | Majantol | 103694-68-4 | 0.002240 | 15.5 |\\ | Javanol\u00ae | 198404-98-7 | 0.000902 | 5.0 |\\ | Galaxolide\u00ae \\* | 1222-05-5 | 0.000414 | 7.5 |\\ | Isopropyl Myristate | 110-27-0 | -- | 7.5 |\\ | Total | 100.00 |\\ \\ \\ \\ | |\\ | --- |\\ | \\\\* Supplied at 50% in Isopropyl myristate. |\\ \\ Table 8 - Fragrance Example 3 (Sweet Dream 18 Fragrance - 11.15 wt% of Low Volatile Fragrance Materials)\\ \\ \\ | **Ingredients** | **CAS Number** | **Vapor Pressure (Torr at 25 \u00b0C)** | **Parts (wt%)** |\\ | :-: | :-: | :-: | :-: |\\ | Prenyl acetate | 1191-16-8 | 3.99000000 | 0.100 |\\ | Manzanate | 39255-32-8 | 2.91000000 | 0.200 |\\ | Hexyl acetate | 142-92-7 | 1.39000000 | 0.700 |\\ | cis-3-Hexenyl acetate | 3681-71-8 | 1.22000000 | 0.200 |\\ | Benzaldehyde | 100-52-7 | 0.97400000 | 0.200 |\\ | Liffarome | 67633-96-9 | 0.72100000 | 0.150 |\\ | Hexyl isobutyrate | 2349-07-7 | 0.41300000 | 0.055 |\\ | Dihydromyrcenol | 18479-58-8 | 0.16600000 | 2.500 |\\ | Benzyl acetate | 140-11-4 | 0.16400000 | 0.700 |\\ | Linalyl acetate | 115-95-7 | 0.11600000 | 2.500 |\\ | Verdox | 88-41-5 | 0.10300000 | 4.000 |\\ | Phenethyl alcohol | 60-12-8 | 0.07410000 | 8.000 |\\ | Rossitol | 215231-33-7 | 0.02990000 | 1.500 |\\ | alpha-Terpineol | 98-55-5 | 0.02830000 | 1.500 |\\ | Geranyl acetate | 105-87-3 | 0.02560000 | 1.500 |\\ | Rhodinol | 141-25-3 | 0.01970000 | 0.700 |\\ | Givescone | 57934-97-1 | 0.01710000 | 0.700 |\\ | Methyl anthranilate | 134-20-3 | 0.01580000 | 0.050 |\\ | Ysamber K | 154171-77-4 | 0.01470000 | 1.000 |\\ | alpha-Ionone | 127-41-3 | 0.01440000 | 3.000 |\\ | Citronellyl acetate | 150-84-5 | 0.01370000 | 0.500 |\\ | cis-3-hexenyl-cis-3-hexenoate | 61444-38-0 | 0.01220000 | 0.200 |\\ | Cinnamic alcohol | 104-54-1 | 0.01170000 | 0.100 |\\ | delta-damascone | 57378-68-4 | 0.01020000 | 0.200 |\\ | Citronellyloxyacetal dehyde | 7492-67-3 | 0.00967000 | 0.100 |\\ | Cymal | 103-95-7 | 0.00881000 | 0.500 |\\ | Floralozone | 67634-15-5 | 0.00808000 | 0.100 |\\ | Ethylmethylphenylg lycidate | 77-83-8 | 0.00571000 | 0.200 |\\ | Florosa Q | 63500-71-0 | 0.00557000 | 3.000 |\\ | Ethyl linalool | 10339-55-6 | 0.00520000 | 6.400 |\\ | Pivarose | 67662-96-8 | 0.00484000 | 2.500 |\\ | Hydroxycitronellal | 107-75-5 | 0.00318000 | 7.500 |\\ | Methyl Ionone | 7779-30-8 | 0.00286000 | 4.000 |\\ | gamma-Undecalactone | 104-67-6 | 0.00271000 | 0.500 |\\ | Kephalis | 36306-87-3 | 0.00269000 | 5.000 |\\ | Cashmeran | 33704-61-9 | 0.00269000 | 1.000 |\\ | Magnolan | 27606-09-3 | 0.00251000 | 3.000 |\\ | Majantol | 103694-68-4 | 0.00224000 | 6.900 |\\ | Brahmanol | 72089-08-8 | 0.00154000 | 3.000 |\\ | Coumarin | 91-64-5 | 0.00130000 | 0.500 |\\ | Glycolierral | 68901-32-6 | 0.00121000 | 0.100 |\\ | Raspberry ketone | 5471-51-2 | 0.00106000 | 0.100 |\\ | Top Mango base _3_ | -- | -- | 0.500 |\\ | Cherry base _3_ | -- | -- | 0.200 |\\ | Cassis base _3_ | -- | -- | 0.300 |\\ | Bergamot Oil _4_ | -- | -- | 6.000 |\\ | Prunella base _3_ | -- | -- | 0.500 |\\ | Hexyl cinnamic aldehyde | 101-86-0 | 0.00069700 | 1.500 |\\ | Sandalore | 65113-99-7 | 0.00062500 | 3.000 |\\ | Dupical | 30168-23-1 | 0.00044100 | 0.005 |\\ | Galaxolide\u00ae _1_ | 1222-05-5 | 0.00041400 | 1.500 |\\ | Ebanol | 67801-20-1 | 0.00028100 | 2.000 |\\ | Helvetolide | 141773-73-1 | 0.00005790 | 2.000 |\\ | Warm Milk base _5_ | -- | -- | 0.200 |\\ | Vanilla Absolute _2,6_ | -- | -- | 0.100 |\\ | Isopropyl Myristate | -- | -- | 1.500 |\\ | Dipropylene Glycol | -- | -- | 6.040 |\\ | | | Total | 100.00 |\\ \\ \\ \\ | |\\ | --- |\\ | _1_ Supplied at 50% in IPM.<br>_2_ Supplied at 50% in DiPG.<br>_3_ Proprietary bases that contain a mixture of perfume raw materials, judged to be of high volatility for the purposes of calculating % of low volatility PRMs.<br>_4_ Natural oils or extracts that contain a mixture of perfume raw materials, judged to be of high volatility for the purposes of calculating % of low volatility PRMs.<br>_5_ Proprietary bases that contain a mixture of perfume raw materials, judged to be of low volatility for the purposes of calculating % of low volatility PRMs.<br>_6_ Natural oils or extracts that contain a mixture of perfume raw materials, judged to be of low volatility for the purposes of calculating % of low volatility PRMs. |\\ \\ Table 9 - Fragrance Examples 4a and 4b (\"Traditional Floral Magnifica\" Example 4a - 37 wt% of Low Volatile Fragrance Materials; 55 wt% of Moderate Volatile Fragrance Materials; 7 wt% of High Volatile Fragrance Materials; and \"Diamond Floral Magnifica\" Example 4b - 13 wt% of Low Volatile Fragrance Materials; 80 wt% of Moderate Volatile Fragrance Materials; 7 wt% of High Volatile Fragrance Materials)\\ \\ \\ | | | | **Parts (wt%)** |\\ | --- | :-: | :-: | :-: |\\ | **Ingredients** | **CAS Number** | **Vapor Pressure (Torr at 25 \u00b0C)** | **Example 4a (Traditional)** | **Example 4b (Diamond)** |\\ | :-: | :-: | :-: | :-: | :-: |\\ | Beta Gamma Hexenol | 928-96-1 | 2.126000 | 0.20 | 0.20 |\\ | Cis 3 Hexenyl Acetate | 3681-71-8 | 1.219000 | 0.30 | 0.30 |\\ | Benzyl Acetate | 140-11-4 | 0.16400000 | 3.01 | 3.01 |\\ | Liffarome | 67633-96-9 | 0.721000 | 0.20 | 0.20 |\\ | Ligustral Or Triplal | 68039-49-6 | 0.578000 | 0.10 | 0.10 |\\ | Methyl Pamplemousse | 67674-46-8 | 0.214000 | 0.40 | 0.40 |\\ | d-Limonene | 5989-27-5 | 1.54000000 | 3.01 | 3.01 |\\ | Phenyl Acetaldehyde _1_ | | 0.368000 | 0.0002 | 0.0002 |\\ \\ \\ \\ \\ | **Total High Volatile Fragrance Materials** | **7.2%** | **7.2%** |\\ | --: | :-: | :-: |\\ | Alpha Damascone | 24720-09-0 | 0.008300 | 0.04 | 0.06 |\\ | Ethyl 2 4-Decadienoate | 3025-30-7 | 0.009540 | 0.20 | 0.20 |\\ | Ambronat | 6790-58-5 | 0.009340 | 2.00 | 2.01 |\\ | cis-3-Hexenyl cis-3-Hexenoate | 61444-38-0 | 0.012200 | 0.10 | 0.10 |\\ | Citronellol | 106-22-9 | 0.032900 | 4.01 | 4.01 |\\ | Cyclemax | 7775-00-0 | 0.018200 | 0.40 | 0.40 |\\ | Cyclo Galbanate | 68901-15-5 | 0.003230 | 0.10 | 0.10 |\\ | Cymal | 103-95-7 | 0.008810 | 0.90 | 1.51 |\\ | Dimethyl Benzyl Carbinyl Butyrate | 10094-34-5 | 0.001680 | 0.50 | 0.50 |\\ | Ethyl 2,4-Decadienoate | 3025-30-7 | 0.00954000 | 0.20 | 0.20 |\\ | Ethyl Linalool | 10339-55-6 | 0.005200 | 7.23 | 12.04 |\\ | Florol | 63500-71-0 | 0.005570 | 6.43 | 10.71 |\\ | Gamma Decalactone | 706-14-9 | 0.008520 | 0.20 | 0.20 |\\ | Geraniol | 106-24-1 | 0.013300 | 3.01 | 5.02 |\\ | Geranyl Acetate | 105-87-3 | 0.009760 | 2.01 | 2.01 |\\ | Helional | 1205-17-0 | 0.002700 | 2.41 | 4.01 |\\ | Heliotropin | 120-57-0 | 0.010400 | 0.20 | 0.20 |\\ | Hivernal | 173445-65-3 | 0.00392000 | 0.20 | 0.20 |\\ | Hydroxycitronellal | 107-75-5 | 0.003180 | 2.41 | 4.01 |\\ | Ionone Beta | 14901-07-6 | 0.003080 | 0.24 | 0.40 |\\ | Ionone Gamma Methyl | 127-51-5 | 0.002820 | 1.81 | 3.01 |\\ | Jasmal | 18871-14-2 | 0.004340 | 5.02 | 5.02 |\\ | Jasmolactone | 32764-98-0 | 0.003550 | 0.20 | 0.20 |\\ | Linalyl Propionate | 144-39-8 | 0.026300 | 1.20 | 1.20 |\\ | Magnolan 690304 | 27606-09-3 | 0.002510 | 3.01 | 5.02 |\\ | Majantol | 103694-68-4 | 0.002240 | 2.41 | 4.01 |\\ | Para Hydroxy Phenyl Butanone | 5471-51-2 | 0.001060 | 0.20 | 0.20 |\\ | Phenyl Ethyl Alcohol | 60-12-8 | 0.074100 | 3.01 | 5.02 |\\ | Phenyl Hexanol | 55066-48-3 | 0.006370 | 3.61 | 6.02 |\\ | Undecavertol | 81782-77-6 | 0.010700 | 2.01 | 2.01 |\\ | Vanillin | 121-33-5 | 0.001940 | 0.10 | 0.10 |\\ | **Total Moderate Volatile Fragrance Materials** | **55.4%** | **79.7%** |\\ | Ambretone | 37609-25-9 | 0.00003310 | 1.00 | 1.00 |\\ | Ambrettolide | 28645-51-4 | 0.00000139 | 1.00 | 1.00 |\\ | Cis 3 -Hexenyl Salicylate | 65405-77-8 | 0.000246 | 1.51 | 0.50 |\\ | Benzyl salicylate | 118-58-1 | 0.00017500 | 10.79 | 1.51 |\\ | Delta Muscenone | 63314-79-4 | 0.00005650 | 1.00 | 1.00 |\\ | Hedione HC | 24851-98-7 | 0.000710 | 10.54 | 3.51 |\\ | Iso-E Super\u00ae | 54464-57-2 | 0.00053800 | 10.54 | 3.51 |\\ | Polysantol\u00ae | 107898-54-4 | 0.00011700 | 0.50 | 0.50 |\\ | **Total Low Volatile Fragrance Materials** | **36.9%** | **12.5%** |\\ | Total | 100 | 100 |\\ \\ \\ \\ | |\\ | --- |\\ | _1_ delivered as 1% in DPG. |\\ \\ Table 10 - Fragrance Examples 5a and 5b (\"Traditional Muguesia Magnifica\" Example 5a - 37 wt% of Low Volatile Fragrance Materials; 54 wt% of Moderate Volatile Fragrance Materials; 9 wt% of High Volatile Fragrance Materials; and \"Diamond Muguesia Magnifica\" Example 5b - 13 wt% of Low Volatile Fragrance Materials; 76 wt% of Moderate Volatile Fragrance Materials; 11 wt% of High Volatile Fragrance Materials)\\ \\ \\ | **Ingredients** | **CAS Number** | **Vapor Pressure (Torr at 25 \u00b0C)** | **Parts (wt%)** |\\ | :-: | :-: | :-: | :-: |\\ | **Example 5a (Traditional)** | **Example 5b (Diamond)** |\\ | :-: | :-: |\\ | Benzyl Acetate | 140-11-4 | 0.304000 | 5.86 | 7.32 |\\ | Benzyl Alcohol | 100-51-6 | 0.158000 | 0.10 | 0.10 |\\ | Beta Gamma Hexenol | 928-96-1 | 2.126000 | 0.40 | 0.40 |\\ | Cis 3 Hexenyl Acetate | 3681-71-8 | 1.219000 | 0.20 | 0.20 |\\ | Linalyl Acetate | 115-95-7 | 0.077400 | 1.00 | 1.00 |\\ | Methyl Phenyl Carbinyl Acetate | 93-92-5 | 0.203000 | 0.32 | 0.40 |\\ | d-Limonene | 5989-27-5 | 1.54000000 | 1.00 | 1.00 |\\ | Phenyl Acetaldehyde Dimethyl Acetal | 101-48-4 | 0.000538 | 0.20 | 0.10 |\\ \\ \\ \\ \\ | **Total High Volatile Fragrance Materials** | **9**. **1**% | **10**. **5**% |\\ | --: | :-: | :-: |\\ | Cis Jasmone | 488-10-8 | 0.020100 | 0.50 | 0.50 |\\ | Cinnamic Alcohol | 104-54-1 | 0.005720 | 0.20 | 0.20 |\\ | Cinnamic Aldehyde | 104-55-2 | 0.02650000 | 0.06 | 0.06 |\\ | Citronellol | 106-22-9 | 0.032900 | 4.01 | 5.01 |\\ | Citronellyl Acetate | 150-84-5 | 0.013700 | 3.21 | 4.01 |\\ | Citronellyl Oxyacetaldehyde | 7492-67-3 | 0.009670 | 0.10 | 0.10 |\\ | Cyclemax | 7775-00-0 | 0.018200 | 0.32 | 0.40 |\\ | Cyclo Galbanate | 68901-15-5 | 0.003230 | 0.20 | 0.20 |\\ | Cymal | 103-95-7 | 0.008810 | 1.61 | 2.01 |\\ | Ethyl Linalool | 10339-55-6 | 0.005200 | 8.03 | 10.03 |\\ | Florhydral | 125109-85-5 | 0.020700 | 0.16 | 0.20 |\\ | Geraniol | 106-24-1 | 0.013300 | 4.01 | 5.02 |\\ | Geranyl Acetate | 105-87-3 | 0.009760 | 3.21 | 4.01 |\\ | Helional | 1205-17-0 | 0.002700 | 4.01 | 5.02 |\\ | Hydroxycitronellal | 107-75-5 | 0.003180 | 3.21 | 4.01 |\\ | Indol | 120-72-9 | 0.029800 | 0.10 | 0.10 |\\ | Jasmal | 18871-14-2 | 0.004340 | 3.21 | 4.01 |\\ | Majantol | 103694-68-4 | 0.002240 | 3.21 | 4.01 |\\ | Phenyl Ethyl Acetate | 103-45-7 | 0.056400 | 0.40 | 0.40 |\\ | Phenyl Ethyl Alcohol | 60-12-8 | 0.074100 | 14.45 | 18.06 |\\ | Florosa Q | 63500-71-0 | 0.005570 | 0 | 9.03 |\\ \\ \\ \\ \\ | **Total Moderate Volatility Fragrance Materials** | **54**. **2**% | **76**. **4**% |\\ | --: | :-: | :-: |\\ | Ambrettolide | 28645-51-4 | 0.000001 | 1.00 | 1.00 |\\ | Cis-3-Hexenyl | 65405-77-8 | 0.000246 | 1.00 | 0.50 |\\ | Salicylate | | | | |\\ | Benzyl Salicylate | 118-58-1 | 0.00017500 | 16.61 | 2.51 |\\ | Hedione\u00ae Hc | 24851-98-7 | 0.000710 | 8.03 | 4.01 |\\ | Iso-E Super\u00ae | 54464-57-2 | 0.000538 | 10.03 | 5.02 |\\ | **Total Low Volatile Fragrance Materials** | **36**. **7**% | **13**. **0**% |\\ | **Total** | **100** | **100** |\\ \\ Table 11 - Fragrance Example 6 (10 Volatile Fragrance Materials)\\ \\ \\ | **Ingredients** | **CAS Number** | **Vapor Pressure (Torr at 25\u00b0C)** | **Parts (wt%)** |\\ | :-: | :-: | :-: | :-: |\\ | Tetra-Hydro Linalool | 78-69-3 | 0.115 | 9.85 |\\ | Terpinyl acetate | 80-26-2 | 0.0392 | 12.21 |\\ | Dimethyl Benzyl Carbinyl Acetate | 151-05-3 | 0.0139 | 11.96 |\\ | Dimethyl Benzyl Carbinol | 100-86-7 | 0.0888 | 9.35 |\\ | Phenyl Ethyl alcohol | 60-12-8 | 0.074100 | 7.60 |\\ | Laevo Carvone | 6485-40-1 | 0.0656 | 9.35 |\\ | Indole | 120-72-9 | 0.0298 | 7.29 |\\ | Ethyl Safranate | 35044-59-8 | 0.0266 | 12.09 |\\ | Indocolore | 2206-94-2 | 0.0255 | 10.09 |\\ | Eugenol | 97-53-0 | 0.0104 | 10.21 |\\ | Total | 100.00 |\\ \\ Table 12 - Fragrance Example 7 (Fresh Floral GF 6-7 Accord - 40.14 wt% of Low Volatile Fragrance Materials)\\ \\ \\ | **Ingredients** | **CAS Number** | **Vapor Pressure (Torr at 25 \u00b0C)** | **Parts (wt%)** |\\ | :-: | :-: | :-: | :-: |\\ | Ligustral or Triplal | 68039-49-6 | 0.578000 | 0.15 |\\ | Benzyl acetate | 140-11-4 | 0.164000 | 0.31 |\\ | Verdox | 88-41-5 | 0.103000 | 5.38 |\\ | Phenethyl alcohol | 60-12-8 | 0.074100 | 1.54 |\\ | Indole | 120-72-9 | 0.029800 | 0.02 |\\ | Heliotropin | 120-57-0 | 0.010400 | 1.23 |\\ | gamma-Decalactone | 706-14-9 | 0.008520 | 0.38 |\\ | Florol | 63500-71-0 | 0.005570 | 15.38 |\\ | Ethyl linalool | 10339-55-6 | 0.005200 | 26.15 |\\ | Isoeugenol | 97-54-1 | 0.005190 | 0.08 |\\ | alpha-Irone | 79-69-6 | 0.004190 | 1.54 |\\ | Vanillin | 121-33-5 | 0.001940 | 6.15 |\\ | Dimethyl benzyl carbinyl butyrate | 10094-34-5 | 0.001680 | 1.54 |\\ | Methyl beta-naphthyl ketone | 93-08-3 | 0.000957 | 0.77 |\\ | Methyl dihydrojasmonate | 24851-98-7 | 0.000710 | 30.60 |\\ | Benzyl salicylate | 118-58-1 | 0.000175 | 7.69 |\\ | Polysantol | 107898-54-4 | 0.000117 | 0.77 |\\ | Lrg 201 | 4707-47-5 | 0.000029 | 0.31 |\\ | | | Total | 100.00 |\\ \\ Table 13 - Fragrance Example 8 (Traditional Floral Accord - 54.00 wt% of Low Volatile Fragrance Materials)\\ \\ \\ | **Ingredients** | **CAS Number** | **Vapor Pressure (Torr at 25 \u00b0C)** | **Parts (wt%)** |\\ | :-: | :-: | :-: | :-: |\\ | Benzyl acetate | 140-11-4 | 0.1640 | 5.5 |\\ | Linalool | 78-70-6 | 0.0905 | 5.0 |\\ | Phenethyl alcohol | 60-12-8 | 0.0741 | 8.0 |\\ | Indole | 120-72-9 | 0.0298 | 0.5 |\\ | \u03b1-Terpineol | 98-55-5 | 0.0283 | 1.5 |\\ | Geranyl acetate | 105-87-3 | 0.0256 | 2.5 |\\ | Cymal | 103-95-7 | 0.00881 | 3.0 |\\ | Hydroxycitronellal | 107-75-5 | 0.00318 | 11.5 |\\ | Majantol | 103694-68-4 | 0.00224 | 8.5 |\\ | Hexyl cinnamic aldehyde | 101-86-0 | 0.000697 | 4.0 |\\ | iso gamma super | 68155-66-8 | 0.000565 | 12.50 |\\ | Sandalore | 65113-99-7 | 0.000625 | 18.75 |\\ | Habanolide | 111879-80-2 | 0.00000431 | 18.75 |\\ | Total | 100.00 |\\ \\ Table 14 - Fragrance Examples 9, 10, 11 and 12 (Traditional Flora Magnifica - Greater than 30 wt% of Low Volatile Fragrance Materials)\\ \\ \\ | **Ingredients** | **Fragrance Example 9** | **Fragrance Example 10** | **Fragrance Example 11** | **Fragrance Example 12** |\\ | :-: | :-: | :-: | :-: | :-: |\\ | **Weight %** | **Weight %** | **Weight %** | **Weight %** |\\ | :-: | :-: | :-: | :-: |\\ | Traditional Flora Magnifica _1_ | 86.96 | 83.33 | 74.07 | 68.97 |\\ | Ethylene Brassylate | 4.35 | 4.167 | 3.704 | 6.90 |\\ | Methyl Dihydro Jasmonate | 4.35 | 8.33 | 14.82 | 13.79 |\\ | Iso E super | 4.35 | 4.167 | 7.407 | 10.35 |\\ | Total | 100 | 100 | 100 | 100.00 |\\ | Wt% Low Volatile Fragrance Materials | 44.33 | 46.66 | 52.60 | 55.87 |\\ | Wt% Moderate Volatile Fragrance Materials | 49.57 | 47.50 | 42.22 | 39.31 |\\ | Wt% High Volatile Fragrance Materials | 6.09 | 5.83 | 5.18 | 4.83 |\\ \\ \\ \\ | |\\ | --- |\\ | _1_ Fragrance Example 4a. |\\ \\ Table 15 - Fragrance Examples 13, 14, 15 and 16 (Traditional Muguesia Magnifica - Greater than 30wt% of Low Volatile Fragrance Materials)\\ \\ \\ | **Ingredients** | **Fragrance Example 13** | **Fragrance Example 14** | **Fragrance Example 15** | **Fragrance Example 16** |\\ | :-: | :-: | :-: | :-: | :-: |\\ | **Weight %** | **Weight %** | **Weight %** | **Weight %** |\\ | :-: | :-: | :-: | :-: |\\ | Traditional Muguesia Magnifica _1_ | 86.96 | 83.33 | 74.07 | 68.97 |\\ | Ethylene Brassylate | 4.35 | 4.17 | 3.70 | 6.90 |\\ | Methyl Dihydro Jasmonate | 4.35 | 8.33 | 14.82 | 13.79 |\\ | Iso E super | 4.35 | 4.17 | 7.41 | 10.35 |\\ | Total | 100.00 | 100.00 | 100.00 | 100.00 |\\ | Wt% Low Volatile Fragrance Materials | 45.23 | 47.50 | 53.34 | 49.08 |\\ | Wt% Moderate Volatile Fragrance Materials | 46.96 | 45.00 | 40.00 | 37.24 |\\ | Wt% High Volatile Fragrance Materials | 7.83 | 7.50 | 6.67 | 6.21 |\\ \\ \\ \\ | |\\ | --- |\\ | _1_ Fragrance Example 5a. |\\ \\ - \\[0110\\]\\ \\ Fragrance example 17 (as disclosed in Table 16) is composed of 30.28 wt% of high volatile fragrance materials, 38.21 wt% of moderate volatile fragrance materials and 31.48 wt% of low volatile fragrance materials, wherein the wt% is relative to the total weight of the fragrance component.\\ Table 16 - Fragrance Example 17 (Comparative Fragrance 1 - 31.48 wt% of Low Volatile Fragance Materials)\\ \\ \\ | **Ingredients** | **CAS Number** | **Vapor Pressure (Torr at 25 \u00b0C)** | **Amount** |\\ | :-: | :-: | :-: | :-: |\\ | **Parts by Weight** | **Parts (wt%)** |\\ | :-: | :-: |\\ | Limonene | 5989-27-5 | 1.541 | 2576 | 30.04 |\\ | Cis-3-Hexenol | 928-96-1 | 1.039 | 21 | 0.24 |\\ | Zestover _6_ | 78-70-6 | 0.578 | 1 | 0.01 |\\ | Linalol | 78-70-6 | 0.0905 | 553 | 6.45 |\\ | Aphermate _4_ (10% DIPG) _7_ | 25225-08-5 | 0.0678 | 7 | 0.08 |\\ | Cyclosal | 535-86-4 | 0.0311 | 35 | 0.41 |\\ | Coranol | 83926-73-2 | 0.0210 | 371 | 4.33 |\\ | Sclareolate\u00ae\\* _1_ | 319002-92-1 | 0.0196 | 630 | 7.35 |\\ | 3-Methoxy -7,7 -dimethyl-1 0-methylene-bicyclo\\[4.3.1\\]decane | 216970-21-7 | 0.0196 | 371 | 4.33 |\\ | Cedramber _2_ | 19870-74-8 | 0.0128 | 1050 | 12.24 |\\ | Ambrox\u00ae\\* | 3738-00-9 | 0.00934 | 1 | 0.01 |\\ | Decal | 706-14-9 | 0.00852 | 21 | 0.24 |\\ | Damascone Alpha\\* (10% DIPG) _7_ | 24720-09-0 | 0.00830 | 9.1 | 0.11 |\\ | (Methoxymethoxy)Cyclododecane | 42604-12-6 | 0.00686 | 182 | 2.12 |\\ | Lilial\u00ae | 80-54-6 | 0.00444 | 26 | 0.30 |\\ | \u03b3-Undecalactone\\* | 104-67-6 | 0.00271 | 21 | 0.24 |\\ | Calone\u00ae\\\\* _3_ | 28940-11-6 | 0.000831 | 50 | 0.58 |\\ | Paradisone _5_ \u00ae\\* | 24851-98-7 | 0.000710 | 1000 | 11.66 |\\ | Galaxolide\u00ae (70% MIP Extra) _7_ | 1222-05-5 | 0.000414 | 700 | 8.16 |\\ | Exaltenone | 14595-54-1 | 0.0000964 | 950 | 11.08 |\\ | Total | 8575.10 | 100 wt% |\\ \\ \\ \\ | |\\ | --- |\\ | \\\\* origin: Firmenich SA (Geneva, Switzerland).<br>_1_ Propyl ( _S_)-2-(1,1-dimethylpropxy)propanoate.<br>_2_ 8-Methoxy-2,6,6,8-tetramethyl-tricyclo\\[5.3.1.0(1,5)\\]undecane.<br>_3_ 7-Methyl-2 _H_,4 _H_-1,5-benzodioxepin-3-one.<br>_4_ 1-(3,3-dimethyl-1-cyclohexyl)ethyl formate; origin: International Flavors & Fragrances.<br>_5_ Methyl dihydrojasmonate.<br>_6_ Linalool.<br>_7_ Fragrance materials added as dilutions in a non-volatile solvent. For the purposes of calculating the fragrance oil composition actual fragrance materials levels added are used. |\\ \\ - \\[0111\\]\\ \\ Fragrance example 18 (as disclosed in Table 17) is composed of 26.71 wt% of high volatile fragrance materials, 63.88 wt% of moderate volatile fragrance materials and 9.37 wt% of low volatile fragrance materials, wherein the wt% is relative to the total weight of the fragrance component.\\ Table 17 - Fragrance Example 18 (Comparative Fragrance 2 - 9.37 wt% of Low Volatile Fragance Materials)\\ \\ \\ | **Ingredients** | **CAS Number** | **Vapor Pressure (Torr at 25 \u00b0C)** | **Amount** |\\ | :-: | :-: | :-: | :-: |\\ | **Parts by Weight** | **Parts (wt%)** |\\ | :-: | :-: |\\ | D-Limonene | 5989-27-5 | 1.540 | 50.00 | 5.21 |\\ | cis-3-Hexenol (10% in DPG) _4_ | 928-96-1 | 1.040 | 0.5 | 0.05 |\\ | Acetophenone (10% in DPG) _4_ | 98-86-2 | 0.299 | 1.00 | 0.10 |\\ | Methylphenyl Acetate | 101-41-7 | 0.176 | 10.00 | 1.04 |\\ | Dihydromyrcenol | 18479-58-8 | 0.166 | 50.00 | 5.21 |\\ | Benzyl acetate | 140-11-4 | 0.164 | 60.00 | 6.25 |\\ | Tetra-Hydro Linalool | n/a | 0.115 | 50.00 | 5.21 |\\ | n-Undecanal | n/a | 0.102 | 5.00 | 0.52 |\\ | Linalool | 78-70-6 | 0.0905 | 40.00 | 4.17 |\\ | Phenylethyl Alcohol | 60-12-8 | 0.0741 | 245.00 | 25.53 |\\ | Allyl amyl glycolate (10% in DPG) _4_ | 67634-00-8 | 0.04000 | 2.00 | 0.21 |\\ | Indole (10% in DPG) _4_ | 120-72-9 | 0.02980 | 1.00 | 0.10 |\\ | Alpha-Terpineol | 98-55-5 | 0.02830 | 30.00 | 3.13 |\\ | Diphenyl Oxide | 101-84-8 | 0.02230 | 5.00 | 0.52 |\\ | L-Citronellol | 7540-51-4 | 0.01830 | 80.00 | 8.34 |\\ | Beta-Ionone | 14901-07-6 | 0.01690 | 5.00 | 0.52 |\\ | Alpha-Ionone | 127-41-3 | 0.01440 | 15.00 | 1.56 |\\ | Dimethyl benzyl carbinyl acetate | 151-05-3 | 0.01390 | 30.00 | 3.13 |\\ | Geraniol | 106-24-1 | 0.01330 | 40.00 | 4.17 |\\ | Nerol | n/a | 0.01330 | 20.00 | 2.08 |\\ | Lilial\u00ae _1_ | 80-54-6 | 0.00444 | 60.00 | 6.25 |\\ | Gamma-Undecalactone | 104-67-6 | 0.00271 | 15.00 | 1.56 |\\ | Amyl salicylate | 2050-08-0 | 0.00144 | 25.00 | 2.61 |\\ | Galaxolide\u00ae | 1222-05-5 | 0.000414 | 20.00 | 2.08 |\\ | cis-3-Hexenyl salicylate | 65405-77-8 | 0.000246 | 20.00 | 2.08 |\\ | Ethylene Brassylate | 105-95-3 | 0.00000000313 | 30.00 | 3.13 |\\ | Styrolyl Acetate5 | n/a | n/a | 20.00 | 2.08 |\\ | Decenol trans-9 _3_ | n/a | n/a | 15.00 | 1.56 |\\ | Geranium oil _2_ | n/a | n/a | 15.00 | 1.56 |\\ | Total | 959.5 | 100 wt% |\\ \\ \\ \\ | |\\ | --- |\\ | _1_ Benzenepropanal, 4-(1,1-dimethylethyl)-\u03b1-methyl-.<br>_2_ Natural oil that is judged to be volatile for the purposes of calculating levels of the volatile fragrance materials.<br>_3_ Proprietary oil that is judged to be volatile for the purposes of calculating levels of the volatile fragrance materials.<br>_4_ Fragrance materials added as dilutions in a non-volatilee solvent. For the purposes of calculating the fragrance oil composition actual fragrance materials levels added are used.<br>_5_ Unknown oil that is judged to be of low volatility for the purposes of calculating levels of the volatile fragrance materials. |\\ \\ Example 2 - Compositions Comprising Fragrance Oils and Substantially Non-Odorous Fragrance Modulators- \\[0112\\]\\ \\ Compositions A1, D1, G1, J1 and M1 are examples of fragrance compositions according to the present invention, made with any one of fragrance examples 1-3, 4b, 5b and 18, respectively. Compositions B, E, H, K and N are examples of fragrance compositions containing any one of the following fragrance examples 4a, 5a, and 7-17, and which are outside the scope of the present invention. In parallel, control compositions C1, F1, I1, L1 and O1 are prepared by replacing the different substantially non-odorous fragrance modulators by the same amount of deionized water. All of the compositions are prepared by admixture of the components described in Table 18(a), in the proportions indicated.\\ \\ \\ \\ \\ \\ \\ \\ \\ - \\[0113\\]\\ \\ Compositions A2, D2, G2, J2 and M2 are examples of fine fragrance compositions according to the present invention, made with any of the fragrance examples 1 to 3, 4b, 5b, and 18 respectively. Compositions B2, E2, H2, K2 and N2 are examples of fragrance compositions containing traditional or higher levels of low volatile fragrance materials, made with any of the fragrance examples 4a, 5a, and 7-17, respectively. In parallel, control compositions C2, F2, I2, L2 and O2 are prepared by replacing the different substantially non-odorous fragrance modulators by the same amount of deionized water. All of the compositions are prepared by admixture of the components described in Table 18(b), in the proportions indicated.\\ \\ \\ \\ \\ \\ \\ \\ \\ - \\[0114\\]\\ \\ Composition A3 is an example of a fragrance composition according to the present invention, made with any of the fragrance examples 1-3, 4b, 5b and 18, respectively. Composition B3 is an example of a fragrance composition containing traditional or higher levels of low volatile fragrance materials, made with any of the fragrance examples 4a, 5a, and 7-17, respectively. In parallel, a control composition C3 is prepared by replacing the different substantially non-odorous fragrance fixative by the same amount of deionized water. All of the compositions are prepared by admixture of the components described in Table 18(c) in the proportions indicated.\\ Table 18(c) - Fragrance Composition\\ \\ \\ | **Ingredients** | **Fragrance Composition (wt%) _1_** |\\ | --- | :-: |\\ | | **A3** | **B3** | **C3** |\\ | Fragrance A1 _2_ | 2-15 | - | - |\\ | Fragrance B _3_ | - | 2-15 | - |\\ | Fragrance A1 or B | - | - | 2-15 |\\ | Ethanol | 60-99.99 |\\ | Butylated Hydroxy Toluene | 0-0.07 |\\ | Modulator A _4_ | 0.1-20 | 0.1-20 | - |\\ | Deionized water | | to 100.00 | |\\ \\ \\ \\ | |\\ | --- |\\ | _1_ Wt% is relative to the total weight of the composition.<br>_2_ Can be any one of fragrance examples 1-3, 4b, 5b, and 18.<br>_3_ Can be any one of fragrance examples 4a, 5a, and 7-17.<br>_4_ Can be any one of the substantially non-odorous fragrance modulator as disclosed in Table 4(b). |\\ \\ - \\[0115\\]\\ \\ Compositions A4, D4, G4, and J4 are examples of fragrance compositions according to the present invention, made with any one of fragrance examples 1-3, 4b, 5b, and 18, respectively. Compositions B4, E4, H4, and K4 are examples of fragrance compositions containing any one of the following fragrance examples 4a, 5a, and 7-17, and which are outside the scope of the present invention. In parallel, control compositions C4, F4,14, and L4 are prepared by replacing the different substantially non-odorous fragrance modulators by the same amount of deionized water or ethanol. All of the compositions are prepared by admixture of the components described in Table 18(d), in the proportions indicated.\\ Table 18(d) - Fragrance Compositions\\ \\ \\ | **Ingredients** | **Fragrance Composition (wt%) _1_** |\\ | --- | :-: |\\ | **A4** | **B4** | **C4** | **D4** | **E4** | **F4** | **G4** | **H4** | **I4** | **J4** | **K4** | **L4** |\\ | :-: | :-: | :-: | :-: | :-: | :-: | :-: | :-: | :-: | :-: | :-: | :-: |\\ | Fragrance A1 _2_ | 7 | - | - | 7 | - | - | 7 | - | - | 7 | - | - |\\ | Fragrance B 3 | - | 7 | - | - | 7 | - | - | 7 | - | - | 7 | - |\\ | Fragrance A1 or B | - | - | 7 | - | - | 7 | - | - | 7 | - | - | 7 |\\ | Ethanol | 75 |\\ | Butylated Hydroxy Toluene | 0-0.07 |\\ | PPG-20 Methyl Glucose Ether _4_ | 15 | 15 | 0 | - | - | - | - | - | - | - | - | - |\\ | Caprylyl/Ca pryl Glucoside _5_ | - | - | - | 15 | 15 | 0 | - | - | - | - | - | - |\\ | Undecyl Glucoside _6_ | - | - | - | - | - | - | 15 | 15 | 0 | - | - | - |\\ | Isocetyl Aclohol _7_ | - | - | - | - | - | - | - | - | - | 15 | 15 | 0 |\\ | Deionized water | to 100.00 |\\ \\ \\ \\ | |\\ | --- |\\ | _1_ Wt% is relative to the total weight of the composition.<br>_2_ Can be any one of fragrance examples 1-3, 4b, 5b, and 18.<br>_3_ Can be any one of fragrance examples 4a, 5a, and 7-17.<br>_4_ Available as GLUCAM\u2122 P-20.<br>_5_ Available as Plantacare\u00ae 810 UP.<br>_6_ Available as Simulsol\u00ae SL 11W.<br>_7_ Available as Ceraphyl\u00ae ICA. |\\ \\ - \\[0116\\]\\ \\ Compositions A5 is an example of a fragrance composition according to the present invention, made with any one of fragrance examples 1-3, 4b, 5b, and 18, respectively. Compositions C5 is an example of a fragrance composition containing traditional or higher levels of low volatile fragrance materials, made with any one of the following fragrance examples 4a, 5a, and 7-17, respectively. In parallel, control compositions C5 is prepared by replacing the different substantially non-odorous fragrance modulator by the same amount of deionized water. All of the compositions are prepared by admixture of the components described in Table 18(e), in the proportions indicated.\\ Table 18(e) - Fragrance Composition\\ \\ \\ | **Ingredients** | **Fragrance Composition (wt%)** _1_ |\\ | --- | :-: |\\ | | **A5** | **B5** | **C5** |\\ | Fragrance A1 _2_ | 2-15 | - | - |\\ | Fragrance B _3_ | - | 2-15 | - |\\ | Fragrance A1 or B | - | - | 2-15 |\\ | Ethanol | 60-99.99 |\\ | Butylated Hydroxy Toluene | 0 - 0.07 |\\ | Modulator A _4_ | 0.1-20 | 0.1-20 | - |\\ | Deionized water | to 100.00 |\\ \\ \\ \\ | |\\ | --- |\\ | _1_ Wt% is relative to the total weight of the composition.<br>_2_ Can be any one of fragrance examples 1-3, 4b, 5b, and 18.<br>_3_ Can be any one of fragrance examples 4a, 5a, and 7-17.<br>_4_ Can be any one of the substantially non-odorous fragrance modulators nos. 1, 3, 7, 8, 99, 100, and 101-103 as disclosed in Table 4(a). |\\ \\ - \\[0117\\]\\ \\ Tables 19(a) provides test compositions (MOD1 to MOD3) comprising the volatile fragrance formulation of fragrance example 6 (as disclosed in Table 11) with a substantially non-odorous fragrance modulator (as disclosed in Tables 4(a) and 4(b)) that are particularly suited to analytical measurements. All of the compositions are prepared by admixture of the components described in Table 19(a) in the proportions indicated.\\ Table 19(a) - Fragrance Example (Compositions Comprising 10 Volatile Fragrance Materials)\\ \\ \\ | **Ingredients** | **Test composition (wt%** _1_) | **Reference composition (wt% _1_)** |\\ | --- | :-: | :-: |\\ | **MOD 1 to 3** | **REF** |\\ | :-: | :-: |\\ | Fragrance A _2_ | 7.0 | 7.0 |\\ | Triethyl citrate | 0.25 to 1.0 | 0.25 to 1.0 |\\ | Ethanol | 75.0 | 75.0 |\\ | Modulator _3_ | 15.0 | 0.0 |\\ | Water | qsp | qsp |\\ | Total | 100.0 | 100.0 |\\ \\ \\ \\ | |\\ | --- |\\ | _1_ Wt% is relative to the total weight of the composition.<br>_2_ Fragrance Example 6 (as disclosed in Table 11).<br>_3_ Can be any one of the substantially non-odorous fragrance modulator nos. 7, 8 and 100 as disclosed in Table 4(a). |\\ \\ - \\[0118\\]\\ \\ Tables 19(b) provides test compositions comprising the volatile fragrance formulation of fragrance example 6 (as disclosed in Table 11) with a substantially non-odorous fragrance modulator (as disclosed in Tables 4(a) and 4(b)) that are particularly suited to analytical measurements. All of the compositions are prepared by admixture of the components described in Table 19(b) in the proportions indicated.\\ Table 19(b) - Compositions comprising fragrance with 10 Volatile Fragrance Materials\\ \\ \\ | **Ingredients** | **Test composition (wt% _1_)** | **Reference composition (wt% _1_)** |\\ | --- | :-: | :-: |\\ | Fragrance A _2_ | 7.0 | 7.0 |\\ | Triethyl citrate | 0.25 to 1.0 | 0.25 to 1.0 |\\ | Ethanol | 75.0 | 75.0 |\\ | Modulator _3_ | 1-15.0 | 0.0 |\\ | Water | qsp | qsp |\\ | Total | 100.0 | 100.0 |\\ \\ \\ \\ | |\\ | --- |\\ | _1_ Wt% is relative to the total weight of the composition.<br>_2_ Fragrance Example 6 (as disclosed in Table 11).<br>_3_ Can be any one of the substantially non-odorous fragrance modulator nos. 1-6, 9-99, and 101-103 as disclosed in Table 4(a) and substantially non-odorous fragrance modulator nos. 1-189 as disclosed in Table 4(b). |\\ \\ Example 3 - Single Fragrance Material Compositions containing Substantially Non-Odorous Fragrance Modulators- \\[0119\\]\\ \\ Compositions A6, C6, E6, and G6-L6 are examples of compositions according to the present invention, made with single fragrance materials and the substantially non-odorous fragrance modulators, respectively. In parallel, control Compositions B6, D6, F6 and M6 are prepared without a substantially non-odorous fragrance modulator as a control. All the compositions are prepared by admixture of the components in Table 20, in the proportions indicated.\\ Table 20 - Single Fragrance Material Compositions\\ \\ \\ | **Ingredients** | **Single PRM Composition (wt%)** _1_ |\\ | --- | :-: |\\ | **A6** | **B6** | **C6** | **D6** | **E6** | **F6** | **G6** | **H6** | **I6** | **J6** | **K6** | **L6** | **M6** |\\ | :-: | :-: | :-: | :-: | :-: | :-: | :-: | :-: | :-: | :-: | :-: | :-: | :-: |\\ | Dimethyl Benzyl Carbinol | 1 | 1 | - | - | - | - | - | - | - | - | - | - | - |\\ | Ethyl Safranate | - | - | 1 | 1 | - | - | - | - | - | - | - | - | - |\\ | Phenylethyl alcohol | - | - | - | - | 1 | 1 | - | - | - | - | - | - | - |\\ | Eugenol | - | - | - | - | - | - | - | - | - | - | - | 1 | 1 |\\ | Fragrance C _6_ | - | - | - | - | - | - | 0.5 -1 | 0.5-1 | 0.5-1 | 0.5-1 | 0.5-1 | - | - |\\ | Sucrose Myristate | 3.8 | 0 | 3\\. 0 | 0 | 4.6 | 0 | - | - | - | - | - | - | - |\\ | Modulator A2 _2_ | - | - | - | - | - | - | 1-5 | - | - | - | - | - | - |\\ | Modulator B _3_ | - | - | - | - | - | - | - | 0.1 | - | - | - | - | - |\\ | Modulator C _4_ | - | - | - | - | - | - | - | - | 0.1-5 | - | - | - | - |\\ | Modulator D _5_ | - | - | - | - | - | - | - | - | - | 1-4 | - | 1.6 | 0 |\\ | Modulator E _7_ | | | | | | | | | | | 0.1-3 | - | - |\\ | Ethanol | to 100 |\\ \\ \\ \\ | |\\ | --- |\\ | _1_ Wt% is relative to the total weight of the composition.<br>_2_ Can be any one of the substantially non-odorous modulators examples: sucrose laurate, sucrose dilaurate, sucrose palmitate, sucrose stearate, sucrose distearate, or sucrose tristearate.<br>_3_ Can be any one of the substantially non-odorous modulators examples: ( _E_)-1-(2,2,6-trimethylcyclohexyl)oct-1-en-3-one.<br>_4_ Can be any one of the substantially non-odorous modulators examples: 2-(1-menthoxy) ethane-1-ol; 1-(1-menthoxy) propane-2-ol; 3-(1-menthoxy) propane-1-ol; 3-(1-menthoxy) propane-1,2-diol; 2-methyl-3-(1-menthoxy)propane-1,2-diol; or 4-(1-menthoxy) butane-1-ol.<br>_5_ Substantially non-odorous fragrance modulator is Hydroquinone beta-D-glycoside (available as Arbutin from Sigma-Aldrich).<br>_6_ Can be any one of the single fragrance materials: Dimethyl Benzyl Carbinol; Ethyl Safranate, Phenyl ethyl alcohol or Eugenol.<br>_7_ Substantially non-odorous fragrance modulator is Hyaluronic acid disaccharide sodium salt or Sodium Hyaluronate (20-50 kDa). |\\ \\ - \\[0120\\]\\ \\ Compositions A7, C7 and E7-I7 are examples of compositions according to the present invention, made with single fragrance materials and the substantially non-odorous fragrance modulators, respectively. In parallel, control Compositions B7, D7 and J7 are prepared without a substantially non-odorous fragrance modulator as a control. All the compositions are prepared by admixture of the components in Table 21, in the proportions indicated.\\ Table 21 - Single Fragrance Material Compositions\\ \\ \\ | **Ingredients** | **Single PRM Composition (wt%) _1_** |\\ | --- | :-: |\\ | **A7** | **B7** | **C7** | **D7** | **E7** | **F7** | **G7** | **H7** | **I7** | **J7** |\\ | :-: | :-: | :-: | :-: | :-: | :-: | :-: | :-: | :-: | :-: |\\ | Dimethyl Benzyl Carbinyl Acetate | - | - | 1.0 | 1.0 | - | - | - | - | - | - |\\ | Eugenol | 1.0 | 1.0 | - | - | - | - | - | - | - | - |\\ | Fragrance C _6_ | - | - | - | - | 0.1-1 | 0.1-1 | 0.1-1 | 0.1-1 | 0.1-1 | 0.1-1 |\\ | Propylene Glycol Propyl Ether | 0.8 | 0.0 | - | - | - | - | - | - | - | - |\\ | Diisobutyl adipate | - | - | 1.4 | 0.0 | - | - | - | - | - | - |\\ | Modulator A2 _2_ | - | - | - | - | 0.1-5 | - | - | - | - | 0 |\\ | Modulator B _3_ | - | - | - | - | - | 0.1-5 | - | - | - | 0 |\\ | Modulator C _4_ | - | - | - | - | - | - | 0.1-5 | - | - | 0 |\\ | Modulator D _5_ | - | - | - | - | - | - | - | 0.1-5 | - | 0 |\\ | Modulator E _7_ | - | - | - | - | - | - | - | - | 0.1-5 | 0 |\\ | Ethanol | to 100 |\\ \\ \\ \\ | |\\ | --- |\\ | _1_ Wt% is relative to the total weight of the composition.<br>_2_ Can be any one of the substantially non-odorous modulators examples: Hexaethylene glycol monododecyl ether, Panthenol Ethyl Ether, DL-Panthenol, or Diisoamyl Adipate.<br>_3_ Neopentyl Glycol Diisononanoate.<br>_4_ 2-ethylhexyloxypropanediol.<br>_5_ PPG-11 Stearyl Ether.<br>6 Can be any one of the single fragrance materials examples: Dimethyl Benzyl Carbinyl Acetate or Eugenol.<br>_7_ Can be any one of the substantially non-odorous modulators examples: Dicetyl Ether; Polyglycerin-4 Ethers; Isoceteth-5; Isoceteth-7, Isoceteth-10; Isoceteth-12; Isoceteth-15; Isoceteth-20; Isoceteth-25; Isoceteth-30; Disodium Lauroamphodipropionate; Hexaethylene glycol monododecyl ether or Cetearyl Ethylhexnoate. |\\ \\ - \\[0121\\]\\ \\ Compositions A8, C8, E8, G8, I8, K8, M8, Q8, S8, U8, W8, Y8, AA8, and CC8 are examples of compositions according to the present invention, made with single fragrance materials and the substantially non-odorous fragrance fixatives, respectively. In parallel, control Compositions B8, D8, F8, H8, J8, L8, N8, P8, R8, T8, V8, X8, Z8, BB8, and DD8 are prepared without a substantially non-odorous fragrance fixative as a control. All of the compositions are prepared by admixture of the components in Tables 22(a) and 22(b), in the proportions indicated.\\ \\ \\ \\ \\ \\ \\ \\ \\ \\ \\ \\ \\ - \\[0122\\]\\ \\ Compositions A9, C9, E9, G9 and I9 are examples of compositions according to the present invention, made with single fragrance materials and the substantially non-odorous fragrance modulators, respectively. In parallel, control Compositions B9, D9, F9, H9 and J9 are prepared without a substantially non-odorous fragrance modulator as a control. All the compositions are prepared by admixture of the components in Table 22(c), in the proportions indicated.\\ Table 22(c) - Single Fragrance Material Compositions\\ \\ \\ | **Ingredients** | **Single Fragrance Material Composition (wt%)** _1_ |\\ | --- | :-: |\\ | **A9** | **B9** | **C9** | **D9** | **E9** | **F9** | **G9** | **H9** | **I9** | **J9** |\\ | :-: | :-: | :-: | :-: | :-: | :-: | :-: | :-: | :-: | :-: |\\ | Indocolore | 1.0 | 1.0 | - | - | - | - | - | - | - | - |\\ | Dimethyl Benzyl Carbinol | - | - | 1.0 | 1.0 | - | - | - | - | - | - |\\ | Eugenol | - | - | - | - | 1.0 | 1.0 | - | - | - | - |\\ | Phenylethyl alcohol | - | - | - | - | - | - | 1.0 | 1.0 | - | - |\\ | Fragrance C _2_ | - | - | - | - | - | - | - | - | 1.0 | 1.0 |\\ | Expert Gel\u00ae EG56 _3_ | 5.0 | 0.0 | - | - | - | - | - | - | - | - |\\ | Kolliphor\u00ae EL4 | - | - | 16.6 | 0.0 | 15.2 | 0.0 | 13.0 | 0.0 | - | - |\\ | Glycerol Alkxoylates _5_ | - | - | - | - | - | - | - | - | 0.1-20 | 0.0 |\\ | Ethanol | to 100 |\\ \\ \\ \\ | |\\ | --- |\\ | _1_ Wt% is relative to the total weight of the composition.<br>_2_ Can be any one of the single fragrance materials examples: Indocolore, Dimethyl Benzyl Carbinol, Eugenol or Phenethyl alcohol.<br>_3_ Chemical name is Bis-methoxy PEG-13 PEG-438/PPG-110 SMDI Copolymer and listed as a substantially non-odorous modulator no. 99 as disclosed in Table 4(a).<br>_4_ Chemical name is propyl {4-\\[2-(diethylamino)-2-oxoethoxy\\]-3-methoxyphenyl} acetate and listed as a substantially non-odorous modulator no.100 as disclosed in Table 4(a).<br>_5_ Can be any one of the substantially non-odorous modulators examples: 3-((2-ethylhexyl)oxy)propane-1,2-diol (modulator no. 101 as disclosed in Table 4(a)); 3-((2-propylheptyl)oxy)propane-1,2-diol (modulator no. 102 as disclosed in Table 4(a)); or 1-amino-3-((2-ethylhexyl)oxy)propan-2-ol (modulator no. 103 as disclosed in Table 4(a)). |\\ \\ - \\[0123\\]\\ \\ Composition A10 is an example of a composition according to the present invention, made with single fragrance material and the substantially non-odorous fragrance modulator, respectively. In parallel, control Composition B10 is prepared without a substantially non-odorous fragrance modulator. All the compositions are prepared by admixture of the components in Table 22(d), in the proportions indicated.\\ Table 22(d) - Single Fragrance Material Compositions\\ \\ \\ | **Ingredients** | **Single Fragrance Material Composition (wt%)** _1_ |\\ | --- | :-: |\\ | **A10** | **B10** |\\ | :-: | :-: |\\ | Fragrance A _2_ | 1-7 | 1-7 |\\ | Modulator _3_ | 1-15.0 | 0.0 |\\ | Ethanol | to 100 |\\ \\ \\ \\ | |\\ | --- |\\ | _1_ Wt% is relative to the total weight of the composition.<br>_2_ Can be any one of the fragrance materials disclosed in Tables 2 and 3.<br>_3_ Can be any one of the substantially non-odorous fragrance modulator not already disclosed in Tables 20, 21, and 22(a)-22(c) above. |\\ \\ Example 4 - Exemplary Product Compositions- \\[0124\\]\\ \\ Compositions I, II, III and IV are examples of body spray compositions according to the present invention. They are prepared by admixture of the components described in Table 23, in the proportions indicated.\\ Table 23 - Body Spray Compositions\\ \\ \\ | **Ingredients** | **CAS Number** | **Compositions (wt%** _1_) |\\ | :-: | :-: | :-: |\\ | **I** | **II** | **III** | **IV** |\\ | :-: | :-: | :-: | :-: |\\ | Denatured Ethanol | 64-17-5 | 39.70 | 59.45 | 39.70 | 39.70 |\\ | Water | 7732-18-5 | -- | 0.75 | -- | -- |\\ | Dipropylene Glycol | 25265-71-8 | 15.00 | -- | 15.00 | 15.00 |\\ | Isopropyl Myristate | 110-27-0 | 1.00 | -- | 1.00 | 1.00 |\\ | Zinc Phenosulphonate | 127-82-2 | 0.50 | -- | 0.50 | 0.50 |\\ | Cavasol\u00ae W7 methylated Beta-cyclodextrin | 128446-36-6 | -- | 1.00 | -- | -- |\\ | Fragrance _2_ | -- | 1.20 | 1.20 | 1.20 | 1.20 |\\ | Fragrance Modulator _3_ | -- | 2.60 | 2.60 | 2.60 | 2.60 |\\ | Propane | 74-98-6 | 4.86 | -- | 4.86 | 4.86 |\\ | Isobutane | 72-28-5 | 27.14 | -- | 27.14 | 27.14 |\\ | 1,1-Difluoroethane (HFC-152a) | 75-37-6 | 8.00 | 35.00 | 8.00 | 8.00 |\\ | Total | 100.00 | 100.00 | 100.00 | 100.00 |\\ \\ \\ \\ | |\\ | --- |\\ | _1_ wt% relative to the total weight of the composition.<br>_2_ Can be any one of Fragrances Examples 1, 2, 3, 4b, 5b or 18.<br>_3_ Can be any one of the substantially non-odorous fragrance modulators disclosed in Tables 4(a) and 4(b). |\\ \\ - \\[0125\\]\\ \\ Composition V, VI and VII are examples of body lotion compositions according to the present invention. They are prepared by admixture of the components as described in Table 24, in the proportions indicated.\\ Table 24 - Body Lotion Composition\\ \\ \\ | **Ingredients** | **CAS Number** | **Compositions (wt% _1_)** |\\ | :-: | :-: | :-: |\\ | **V** | **VI** | **VII** |\\ | :-: | :-: | :-: |\\ | Water | 7732-18-5 | qsp 100 % | qsp 100 % | qsp 100 % |\\ | Trilon\u00ae B | 64-02-8 | 0.05 | 0.05 | 0.05 |\\ | Carbopol\u00ae ETD 2050 | 9003-01-4 | 0.2 | 0.2 | 0.2 |\\ | Pemulen\u2122 TR1 | 9063-87-0 | 0.2 | 0.2 | 0.2 |\\ | Nexbase\u00ae 2008 | 68037-01-4 | 8 | 8 | 8 |\\ | Silicone V100 | 63148-62-9 | 6 | 6 | 6 |\\ | Fragrance Modulator _3_ | -- | 3 | 3 | 3 |\\ | Tris Amino\u2122 Ultra Pur | 102-71-6 | 0.4 | 0.4 | 0.4 |\\ | Fragrance _2_ | -- | 3 | 3 | 3 |\\ | Preservatives | -- | qs | qs | qs |\\ | Total | 100.00 | 100.00 | 100.00 |\\ \\ \\ \\ | |\\ | --- |\\ | _1_ wt% relative to the total weight of the composition.<br>_2_ Can be any one of the Fragrances Examples 1, 2, 3, 4b, 5b or 18.<br>_3_ Can be any one of the substantially non-odorous fragrance modulators disclosed in Tables 4(a) and 4(b). |\\ \\ Example 5 - Olfactive Test Results- \\[0126\\]\\ \\ Compositions disclosed in Tables 18(a)-18(d), 20, 21, and 22(a)-22(d) are applied to glass slides in accordance with the protocol described in the Method Section and a panel of 6-10 experienced panelists evaluate the perceived fragrance profile at initial time 0, then at various time points, typically 1 hour, 2 hours, 3 hours, 4 hours and 6 hours post application. Panelists are asked to score the compositions for the longevity and/or fidelity of the fragrance profile on a scale of 0 to 5, wherein 0 represents a no fragrance is detected and 5 represents a very strong fragrance intensity is detected. The results of the panelists are then averaged and discussed below.\\ \\ (a) Efffects of the Substantially Non-Odorous Fragrance Modulators on Single Fragrance Material Compositions- \\[0127\\]\\ \\ Figure 2 shows the fragrance intensity profile of Composition A9 (as disclosed in Table 22(c)) as evaluated by 10 panelists, which comprises the substantially non-odorous fragrance modulator Bis-methoxy PEG-13 PEG-438/PPG-110 SMDI Copolymer ( _i.e.,_ Expert Gel\u00ae 56) and the single fragrance material Indocolore. Addition of the substantially non-odorous fragrance modulator (Expert Gel\u00ae 56) maintains the intensity of the fragrance material for up to at least 6 hours whilst the control, Composition B9, in the absence of the substantially non-odorous fragrance modulator, drops in fragrance intensity profile much more over this time. The substantially non-odorous fragrance modulator acts to maintain the continued initial evaporation over time of the fragrance material. Statistical analysis using the Tukey correction for multiple comparisons confirms the statistically significant difference at 1, 3 and 6 hours (p < 0.0001) at 95% significance level ( _i.e.,_ p < 0.05) at all these time points.\\ \\ - \\[0128\\]\\ \\ Figure 3 shows the fragrance intensity profile of Composition C9 (as disclosed in Table 22(c)) as evaluated by 9 panelists, which comprises the substantially non-odorous fragrance modulator propyl {4-\\[2-(diethylamino)-2-oxoethoxy\\]-3-methoxyphenyl}acetate ( _i.e_., Kolliphor\u00ae EL) and the single fragrance material Dimethyl Benzyl Carbinol. Addition of the substantially non-odorous fragrance modulator (Kolliphor\u00ae EL) maintains the intensity of the fragrance material for up to at least 6 hours whilst the control, Composition D9, in the absence of the substantially non-odorous fragrance modulator, drops in fragrance intensity profile much more over this time. The substantially non-odorous fragrance modulator acts to maintain the reduced rate of evaporation over time of the fragrance material. Statistical analysis using the Tukey correction for multiple comparisons confirms the statistically significant difference at 1 hour (p < 0.0001), 3 hours (p = 0.0265) and 6 hours (p = 0.0388) at 95% significance level ( _i.e.,_ p < 0.05) at all these time points.\\ \\ - \\[0129\\]\\ \\ Figure 4 shows the fragrance intensity profile of Composition E9 (as disclosed in Table 22(c)) as evaluated by 9 panelists, which comprises the substantially non-odorous fragrance modulator propyl {4-\\[2-(diethylamino)-2-oxoethoxy\\]-3-methoxyphenyl}acetate ( _i.e_., Kolliphor\u00ae EL) and the single fragrance material Eugenol. Addition of the substantially non-odorous fragrance modulator (Kolliphor\u00ae EL) maintains the intensity of the fragrance material for up to at least 6 hours whilst the control, Composition F9, in the absence of the substantially non-odorous fragrance modulator, drops in fragrance intensity profile much more over this time. The substantially non-odorous fragrance modulator acts to supress the initial display of Eugenol and then maintains that continued initial evaporation over time. Statistical analysis using the Tukey correction for multiple comparisons confirms the statistically significant difference at 0 hours (p = 0.0025), 1 hour (p < 0.0001), 3 hours (p < 0.0001) and 6 hours (p < 0.0001) at 95% significance level ( _i.e.,_ p < 0.05) at all time points.\\ \\ - \\[0130\\]\\ \\ Figure 5 shows the fragrance intensity profile of Composition G9 (as disclosed in Table 22(c)) as evaluated by 9 panelists, which comprises the substantially non-odorous fragrance modulator propyl {4-\\[2-(diethylamino)-2-oxoethoxy\\]-3-methoxyphenyl}acetate ( _i.e_., Kolliphor\u00ae EL) and the single fragrance material Phenethyl alcohol (PEA). Addition of the substantially non-odorous fragrance modulator (Kolliphor\u00ae EL) maintains the intensity of the fragrance material from 1 hour to 3 hours whilst the control, Composition H9, in the absence of the substantially non-odorous fragrance modulator, drops in fragrance intensity profile over this time. The substantially non-odorous fragrance modulator acts to maintain the reduced rate of evaporation over time of the fragrance material. Statistical analysis using the Tukey correction for multiple comparisons confirms the statistically significant difference at 1 hour (p < 0.0001) at 95% significance level ( _i.e.,_ p < 0.05) and at 3 hours (p = 0.0876) at 90% significance level ( _i.e.,_ p < 0.1).\\ \\ (b) Effects of the Substantially Non-Odorous Fragrance Modulatorson the Fragrance Profile Longevity of Compositions having Diamond Construction of Fragrance Component _vs_. Compositions having Traditional Levels of Fragrance Component (Greater than 30wt% relative to the total weight of the Fragrance Component) and No Substantially Non-Odorous Fragrance Modulator- \\[0131\\]\\ \\ Panelists are asked to score the compositions for the intensity of the fragrance on a scale of 0 to 5, wherein 0 represents a no fragrance intensity is detected and 5 represents a very strong fragrance intensity is detected. The results of the panel test are then averaged. The results show the effect of the substantially non-odorous fragrance modulator and diamond constructed fragrance materials for any one of the inventive Compositions A1, A2, A3, A4, A5, D1, D2, D4, G1, G2, G4, J1, J2, J4, M1, and M2 on fragrance profile longevity versus control Compositions C1, C2, C3, C4, C5, F1, F2, F4, I1, I2, I4, L1, L2, L4, O1, and 02 in the absence of the substantially non-odorous modulator. Alternatively, the results show the effect of the substantially non-odorous fragrance modulator and diamond constructed fragrance materials for any one of the inventive Compositions A1, A2, A3, A4, A5, D1, D2, D4, G1, G2, G4, J1, J2, J4, M1, and M2 on fragrance profile longevity versus traditional Compositions B1, B2, B3, B4, B5, E1, E2, E4, H1, H2, H4, K1, K2, K4, N1, and N2 in the presence of the substantially non-odorous fragrance modulator. Fragrance profile longevity, particularly intensity of the characters attributable to the volatile fragrance materials are maintained for up to at least 6 hours in the presence of the substantially non-odorous fragrance modulator whilst it drops in the absence of the substantially non-odorous fragrance modulator.\\ \\ - \\[0132\\]\\ \\ Figure 6 provides the fragrance intensity profile of Composition A4 (as disclosed in Table 18(d)), which comprises the substantially non-odorous fragrance modulator PPG-20 Methyl Glucose Ether ( _i.e_., Glucam\u2122 P-20) and the Diamond Floral Magnifica Fragrance Example 4b. Addition of the substantially non-odorous fragrance modulator Glucam\u2122 P-20 maintains the intensity of the fragrance material for up to 6 hours. As compared to the control Composition C4, in the absence of the substantially non-odorous fragrance modulator Glucam\u2122 P-20, and comprising the Traditional Floral Magnifica Fragrance Example 4a drops in fragrance intensity over the 6 hours.\\ \\ - \\[0133\\]\\ \\ Figure 7 provides the fragrance intensity profile of Composition A4 (as disclosed in Table 18(d)), which comprises the substantially non-odorous fragrance modulator PPG-20 Methyl Glucose Ether ( _i.e_., Glucam\u2122 P-20) and the Diamond Muguesia Magnifica Fragrance Example 5b. Addition of the substantially non-odorous fragrance modulator Glucam\u2122 P-20 maintains the intensity of the fragrance material for up to 6 hours. As compared to the control Composition C4, in the absence of the substantially non-odorous fragrance modulator Glucam\u2122 P-20, and comprising the Traditional Muguesia Magnifica Fragrance Example 5a drops in fragrance intensity over the 6 hours.\\ \\ - \\[0134\\]\\ \\ Figure 8 provides the fragrance intensity profile of Composition A2 (as disclosed in Table 18(b)), which comprises 15 wt% substantially non-odorous fragrance modulator Diisobutyl Adipate and 7 wt% Diamond Floral Magnifica Fragrance Example 4b. Addition of the substantially non-odorous fragrance modulator Diisobutyl Adipate maintains the intensity of the fragrance material for up to 6 hours. As compared to the control Composition C2, in the absence of the substantially non-odorous fragrance modulator Diisobutyl Adipate, and comprising 7 wt% Traditional Floral Magnifica Fragrance Example 4a drops in fragrance intensity over the 6 hours.\\ \\ - \\[0135\\]\\ \\ Figure 9 provides the fragrance intensity profile of Composition A2 (as disclosed in Table 18(b)), which comprises 15 wt% substantially non-odorous fragrance modulator Diisobutyl Adipate and 7 wt% Diamond Muguesia Magnifica Fragrance Example 5b. Addition of the substantially non-odorous fragrance modulator Diisobutyl Adipate maintains the intensity of the fragrance material for up to 6 hours. As compared to the control Composition C2, in the absence of the substantially non-odorous fragrance modulator Diisobutyl Adipate, and comprising 7 wt% Traditional Muguesia Magnifica Fragrance Example 5a drops in fragrance intensity over the 6 hours.\\ \\ - \\[0136\\]\\ \\ Panelists are also asked to score the Compositions B1, B2, B3, B4, B5, E1, E2, E4, H1, H2, H4, K1, K2, K4, N1, and N2 for the intensity of the fragrance profile. The results show the effect of the substantially non-odorous fragrance modulator and excessive levels of low volatile fragrance materials for any one of Compositions B1, B2, B3, B4, B5, E1, E2, E4, H1, H2, H4, K1, K2, K4, N1, and N2 on fragrance profile longevity and fidelity. Two outcomes are observed: (i) either the fragrance profile longevity is unaffected by the addition of the substantially non-odorous fragrance modulator or (ii) the fragrance profile appears to be suppressed with a loss of strength (data not shown).\\ \\ - \\[0137\\]\\ \\ Without wishing to be bound by theory, it is believed that the substantially non-odorous fragrance modulator acts to maintain the continued evaporation over time of the fragrance materials, particular the volatile fragrance materials. The effects of the improved fragrance profile longevity of the present invention are noticeable at, any one of, 1, 3 and 6 hours post application.\\ \\ (c) Effects of the Substantially Non-Odorous Fragrance Modulators on the Fragrance Profile Fidelity of Compositions having Diamond Fragrance Materials (between 10 wt% to 30 wt% relative to the total weight of the Fragrance Component) _vs_. Compositions having Traditional Levels of Low Volatile Fragrance Materials (Greater than 30 wt% relative to the total weight of the Fragrance Component) and No Substantially Non-Odorous Fragrance Modulator- \\[0138\\]\\ \\ Panelists are are also asked to score the composition for the fragrance profile fidelity. In particular, the panelists are asked to score the dominance of the floral character attributable to the volatile fragrance materials on a scale of 0 to 3 wherein 0 represents not detectable and 3 represents it being the dominant character. The results of the panel test are then averaged. The results show the effect of the substantially non-odorous fragrance modulator and diamond fragrance materials for the inventive Compositions A1, A2, A3, A4, A5, D1, D2, D4, G1, G2, G4, J1, J2, J4, M1, and M2 on the floral character dominance versus control Compositions C1, C2, C3, C4, C5, F1, F2, F4, I1, I2, I4, L1, L2, L4, O1, and 02 in the absence of the substantially non-odorous fragrance modulator. Alternatively, the results show the effect of the substantially non-odorous fragrance modulator and diamond fragrance materials for any one of the inventive Compositions A1, A2, A3, A4, A5, D1, D2, D4, G1, G2, G4, J1, J2, J4, M1, and M2 on fragrance profile fidelity versus traditional Compositions B1, B2, B3, B4, B5, E1, E2, E4, H1, H2, H4, K1, K2, K4, N1, and N2 in the presence of the substantially non-odorous fragrance modulator. Fragrance profile fidelity, particularly floral character attributable to the volatile fragrance materials, are maintained by the substantially non-odorous fragrance modulator over time for up to 6 hours in the presence of the substantially non-odorous fragrance modulator whilst it drops in the absence of the substantially non-odorous fragrance modulator.\\ \\ - \\[0139\\]\\ \\ Figure 10 provides the fragrance fidelity profile of Composition A4 (as disclosed in Table 18(d)), which comprises the substantially non-odorous fragrance modulator PPG-20 Methyl Glucose Ether (i.e., Glucam\u2122 P-20) and the Diamond Floral Magnifica Fragrance Example 4b. Addition of the substantially non-odorous fragrance modulator Glucam\u2122 P-20 maintains the overwhelmingly dominate floral character for up to 6 hours. It is observed for Composition C4 comprising the Traditional Floral Magnifica Fragrance Example 4a and no modulator, the floral character is perceived initially but then drops quickly over time. Addition of the substantially non-odorous fragrance modulator Glucam\u2122 P-20 to Composition B4 comprising Traditional Floral Magnifica Fragrance Example 4a does not result in improved fidelity of the floral character (data not shown).\\ \\ - \\[0140\\]\\ \\ Figure 11 provides the fragrance fidelity profile of Composition A4 (as disclosed in Table 18(d)), which comprises the substantially non-odorous fragrance modulator PPG-20 Methyl Glucose Ether (i.e., Glucam\u2122 P-20) and the Diamond Muguesia Magnifica Fragrance Example 5b. Addition of the substantially non-odorous fragrance modulator Glucam\u2122 P-20 maintains the overwhelmingly dominate floral character for up to 6 hours. It is observed for Composition C4 comprising the Traditional Muguesia Magnifica Fragrance Example 5a and no modulator, the floral character is perceived initially but then drops quickly over time. Addition of the substantially non-odorous fragrance modulator Glucam\u2122 P-20 to Composition B4 comprising Traditional Muguesia Magnifica Fragrance Example 5a does not result in improved fidelity of the floral character (data not shown).\\ \\ - \\[0141\\]\\ \\ Figure 12 provides the fragrance fidelity profile of Composition D4 (as disclosed in Table 18(d)), which comprises the substantially non-odorous fragrance modulator Caprylyl/Capryl Glucoside (i.e., Plantacare\u00ae 810 UP) and the Diamond Floral Magnifica Fragrance Example 4b. Addition of the substantially non-odorous fragrance modulator Plantacare\u00ae 810 UP maintains the overwhelmingly dominate floral character for up to 6 hours. It is observed for Composition F4 comprising the Traditional Floral Magnifica Fragrance Example 4a and no modulator, the floral character is perceived initially but then drops quickly over time. Addition of the substantially non-odorous fragrance modulator Plantacare\u00ae 810 UP to Composition E4 comprising Traditional Floral Magnifica Fragrance Example 4a does not result in improved fidelity of the floral character (data not shown).\\ \\ - \\[0142\\]\\ \\ Figure 13 provides the fragrance fidelity profile of Composition G4 (as disclosed in Table 18(d)), which comprises the substantially non-odorous fragrance modulator Undecyl Glucoside (i.e., Simulsol\u00ae SL 11W) and the Diamond Floral Magnifica Fragrance Example 4b. Addition of the substantially non-odorous fragrance modulator Simulsol\u00ae SL 11W maintains the overwhelmingly dominate floral character for up to 6 hours. It is observed for Composition I4 comprising the Traditional Floral Magnifica Fragrance Example 4a and no modulator, the floral character is perceived initially but then drops quickly over time. Addition of the substantially non-odorous fragrance modulator Simulsol\u00ae SL 11W to Composition H4 comprising Traditional Floral Magnifica Fragrance Example 4a does not result in improved fidelity of the floral character (data not shown).\\ \\ - \\[0143\\]\\ \\ Figure 14 provides the fragrance fidelity profile of Composition J4 (as disclosed in Table 18(d)), which comprises the substantially non-odorous fragrance modulator Isocetyl Aclohol (i.e., Ceraphyl\u00ae ICA) and the Diamond Floral Mangifica Fragrance Example 4b. Addition of the substantially non-odorous fragrance modulator Ceraphyl\u00ae ICA maintains the overwhelmingly dominate floral character for up to 6 hours. It is observed for Composition L4 comprising the Traditional Floral Magnifica Fragrance Example 4a and no modulator, the floral character is perceived initially but then drops quickly over time. Addition of the substantially non-odorous fragrance modulator Ceraphyl\u00ae ICA to Composition K4 comprising the Traditional Floral Magnifica Fragrance Example 4a does not result in improved fidelity of the floral character (data not shown).\\ \\ - \\[0144\\]\\ \\ Figure 15 provides the fragrance fidelity profile of Composition A2 (as disclosed in Table 18(b)), which comprises 15 wt% substantially non-odorous fragrance modulator Diisobutyl Adipate and 7 wt% Diamond Floral Magnifica Fragrance Example 4b. Addition of the substantially non-odorous fragrance modulator Diisobutyl Adipate maintains the overwhelmingly dominate floral character for up to 6 hours. It is observed for Composition C2 comprising 7 wt% Traditional Floral Magnifica Fragrance Example 4a and no modulator, the floral character is perceived initially but then drops quickly over time. Addition of the substantially non-odorous fragrance modulator Diisobutyl Adipate to Composition B2 comprising 7 wt% Traditional Floral Magnifica Fragrance Example 4a does not result in improved fidelity of the floral character (data not shown).\\ \\ - \\[0145\\]\\ \\ Figure 16 provides the fragrance fidelity profile of Composition A2 (as disclosed in Table 18(b)), which comprises 15 wt% substantially non-odorous fragrance modulator Diisobutyl Adipate and 7 wt% Diamond Muguesia Magnifica Fragrance Example 5b. Addition of the substantially non-odorous fragrance modulator Diisobutyl Adipate maintains the overwhelmingly dominate floral character for up to 6 hours. It is observed for Composition C2 comprising 7 wt% Traditional Muguesia Magnifica Fragrance Example 5a and no modulator, the floral character is perceived initially but then drops quickly over time. Addition of the substantially non-odorous fragrance modulator Diisobutyl Adipate to Composition B2 comprising 7 wt% Traditional Muguesia Magnifica Fragrance Example 5a does not result in improved fidelity of the floral character (data not shown).\\ \\ - \\[0146\\]\\ \\ Figure 17 provides the fragrance fidelity profile of Composition J2 (as disclosed in Table 18(b)), which comprises 15 wt% substantially non-odorous fragrance modulator PPG-11 Stearyl Ether and 7 wt% Diamond Floral Magnifica Fragrance Example 4b. Addition of the substantially non-odorous fragrance modulator PPG-11 Stearyl Ether maintains the overwhelmingly dominate floral character for up to 6 hours. It is observed for Composition L2 comprising 7 wt% Traditional Floral Magnifica Fragrance Example 4a and no modulator, the floral character is perceived initially but then drops quickly over time. Addition of the substantially non-odorous fragrance modulator PPG-11 Stearyl Ether to Composition K2 comprising 7 wt% Traditional Floral Magnifica Fragrance Example 4a does not result in improved fidelity of the floral character (data not shown).\\ \\ - \\[0147\\]\\ \\ Figure 18 provides the fragrance fidelity profile of Composition J2 (as disclosed in Table 18(b)), which comprises 15 wt% substantially non-odorous fragrance modulator PPG-11 Stearyl Ether and 7 wt% Diamond Muguesia Magnifica Fragrance Example 5b. Addition of the substantially non-odorous fragrance modulator PPG-11 Stearyl Ether maintains the overwhelmingly dominate floral character for up to 6 hours. It is observed for Composition L2 comprising 7 wt% Traditional Muguesia Magnifica Fragrance Example 5a and no modulator, the floral character is perceived initially but then drops quickly over time. Addition of the substantially non-odorous fragrance modulator PPG-11 Stearyl Ether to Composition K2 comprising 7 wt% Traditional Muguesia Magnifica Fragrance Example 5a does not result in improved fidelity of the floral character (data not shown).\\ \\ - \\[0148\\]\\ \\ Panelists are also asked to score the Compositions B1, B2, B3, B4, B5, E1, E2, E4, H1, H2, H4, K1, K2, K4, N1, and N2 for the dominance of the floral character. The results show the effect of the substantially non-odorous fragrance modulator and excessive levels of low volatile fragrance materials for any one of Compositions B1, B2, B3, B4, B5, E1, E2, E4, H1, H2, H4, K1, K2, K4, N1, and N2 on fidelity of the floral character attributable to the volatile fragrance materials. It is observed that the floral character is perceived initially but then drops quickly over time. Addition of the substantially non-odorous fragrance modulator does not result in improved fidelity of the floral character as seen in any one of Compositions B1, B2, B3, B4, B5, E1, E2, E4, H1, H2, H4, K1, K2, K4, N 1, and N2 (data not shown).\\ \\ - \\[0149\\]\\ \\ Panelists are further asked to score the compositions on a scale of 1 to 5, wherein 1 represents the fragrance profile remains unchanged and 5 represents a total change in the fragrance profile versus a control. The results of the panel test are averaged and plotted together with the confidence intervals. The results show the effect of the substantially non-odorous fragrance modulator and diamond fragrance materials for Compositions A1, A2, A3, A4, A5, D1, D2, D4, G1, G2, G4, J1, J2, J4, M1, and M2. The presence of the substantially non-odorous fragrance modulator and diamond fragrance materials result in noticeable fidelity in fragrance characters. Particularly, noticeable fidelity in the floral aroms attributable to the volatile fragrance materials (data not shown).\\ \\ Example 6 - Analytical Evaporation Test Results- \\[0150\\]\\ \\ Using the analytical evaporation Test Method 3, it is possible to measure the amount of each component of a perfume mixture that remains as the fragrance mixture evaporates. Test compositions (MOD1 to MOD3) comprising a mixture of 10 volatile perfume materials, as disclosed in Table 11 (Fragrance Example 6), and a substantially non-odorous fragrance modulators, as disclosed in Tables 4(a) and 4(b), are introduced in the aluminum containers at the set temperature for pre-determined periods of time in accordance with the protocol described in Test Method 3\\. Indole is one of the components of the 10 PRMs mixture of Table 11. Control compositions containing the full 10 PRMs mixture as disclosed in Table 11 without the substantially non-odorous fragrance modulator are run alongside the test compositions. The average profile for the control composition is plotted against the individual profile for the indole component from the test composition containing the 10 PRMs mixture of Table 11 with the substantially non-odorous fragrance modulators. The error associated with the method is determined by running replicate evaporation experiments on the control composition. An average evaporation profile of the control composition as well as the 95% confidence interval at each time point are calculated from the replicates.\\ \\ - \\[0151\\]\\ \\ It is useful to consider the difference (\u0394) in the % of remaining fragrance material between each of the test composition (MOD) and their respective control composition (REF) at each experimental time points ( _e.g.,_ 30 mins, 60 mins and 180 mins) to determine the effect of the substantially non-odorous fragrance modulator on the volatile PRMs in a mixture. The difference (\u0394) in the % of remaining of a given fragrance material is calculated as follows: \u0394=%remaining of given fragrance material in test compositionMOD\u2212%remaining of same fragrance material in control compositionREF\\ \\ \\ \\ - \\[0152\\]\\ \\ The difference (\u0394) can then be plotted (data not shown) for each of the perfume materials in the mixture at each of the time points. For ease of reference, the applicant has summarize the effect of the substantially non-odorous fragrance modulator on only one volatile fragrance component ( _e.g.,_ indole) of the mixture, to serve as a representative of all of the volatile fragrance materials.\\ \\ (a) Effect of PPG-3 Myristyl Ether on Compositions having Volatile Fragrance Materials- \\[0153\\]\\ \\ Figure 19 shows the effect of the substantially non-odorous fragrance modulator PPG-3 Myristyl Ether (i.e., available as Tegosoft\u00ae APM/ Modulator 7 from Table 4(a)) on the evaporation profile for a representative component (i.e., indole) of the test composition (MOD1). With reference to Figure 19, PPG-3 Myristyl Ether has a difference (\u0394) of 12 % after 30 mins, 22 % after 60 mins, and 60 % after 3 hours. Addition of the PPG-3 Myristyl Ether in the test composition (MOD1) maintains the concentration of the volatile fragrance material indole from 0 hour up to 3 hours whilst the control composition (REF), in the absence of PPG-3 Myristyl Ether, drops in fragrance concentration over the 3 hours. Thus, PPG-3 Myristyl Ether acts to maintain the continued evaporation of the volatile fragrance material over time. Similar results are observed for the other volatile fragrance materials in the mixture (data not shown).\\ \\ (b) Effect of Neopentyl Glycol Diethylhexanoate on Compositions having Volatile Fragrance Materials- \\[0154\\]\\ \\ Figure 20 shows the effect of the substantially non-odorous fragrance modulator Neopentyl Glycol Diethylhexanoate ( _i.e_., available as Schercemol\u2122 NGDO/ Modulator 8 from Table 4(a)) on the evaporation profile for a representative component ( _i.e_., indole) of the test composition (MOD2). With reference to Figure 20, Neopentyl Glycol Diethylhexanoate has a difference (\u0394) of 11 % after 30 mins, 21 % after 60 mins, and 53 % after 3 hours. Addition of the Neopentyl Glycol Diethylhexanoate in the test composition (MOD2) maintains the concentration of the volatile fragrance material indole from 0 hour up to 3 hours whilst the control composition (REF), in the absence of Neopentyl Glycol Diethylhexanoate, drops in fragrance concentration over the 3 hours. Thus, Neopentyl Glycol Diethylhexanoate acts to maintain the continued evaporation of the volatile fragrance material over time. Similar results are observed for the other volatile fragrance materials in the mixture (data not shown).\\ \\ (c) Effect of Kolliphor\u00aeEL on Compositions having Volatile Fragrance Materials- \\[0155\\]\\ \\ Figure 21 shows the effect of the substantially non-odorous fragrance modulator Kolliphor\u00ae EL (disclosed as modulator 99 from Table 4(a)) on the evaporation profile for a representative component ( _i.e_., indole) of the test composition (MOD3). With reference to Figure 21, indole has a difference (\u0394) of 15 % after 30 mins, 28 % after 60 mins, and 80 % after 3 hours. Addition of the Kolliphor\u00ae EL in the test composition (MOD3) maintains the concentration of the volatile fragrance material indole from 0 hour up to 3 hours whilst the control composition (REF), in the absence of Kolliphor\u00ae EL, drops in fragrance concentration over the 3 hours. Thus, Kolliphor\u00ae EL acts to maintain the continued evaporation of the volatile fragrance material over time. Similar results are observed for the other volatile fragrance materials in the mixture (data not shown).\\ \\ Example 7 - Analytical Headspace Test Results- \\[0156\\]\\ \\ Using the analytical headspace Test Method 4, it is possible to demonstrate the character retention over time of a perfume mixture of a fragrance composition of the present invention vs. a control. Compositions disclosed in Tables 18(a)-18(e) are added to sealed vials in accordance with the procotol described in the Method Section, and the fragrance profile in the headspace are measured at specific time points through the use of headspace gas chromatography.\\ \\ (a) Effects of the Substantially Non-Odorous Fragrance Modulators on Character Retention of Compositions having Diamond Constructions _vs_. Compositions having Traditional Levels of Fragrance Materials- \\[0157\\]\\ \\ The test demonstrates the character retention over time of a fragrance composition. The results show the effect of the substantially non-odorous fragrance modulator and fragrance materials in a diamond construction for any one of the inventive Compositions A1, A2, A3, A4, A5, D1, D2, D4, G1, G2, G4, J1, J2, J4, M1, and M2 on fragrance profile versus control Compositions C1, C2, C3, C4, C5, F1, F2, F4, I1, I2, I4, L1, L2, L4, O1, and 02 in the absence of the substantially non-odorous fragrance modulator. Alternatively, results show the effect of the substantially non-odorous fragrance modulator and fragrance materials in a diamond construction for any one of the inventive Compositions A1, A2, A3, A4, A5, D1, D2, D4, G1, G2, G4, J1, J2, J4, M1, and M2 on fragrance profile longevity versus traditional Compositions B1, B2, B3, B4, B5, E1, E2, E4, H1, H2, H4, K1, K2, K4, N1, and N2 in the presence of the substantially non-odorous fragrance modulator. Fragrance profile fidelity, particularly of floral characters attributable to the volatile fragrance materials are maintained for up to at least 1 hour in the presence of the substantially non-odorous fragrance modulator whilst it drops in the absence of the substantially non-odorous fragrance modulator.\\ \\ - \\[0158\\]\\ \\ Figure 22(a)(i) provides the headspace chromatogram for control Composition L2 after 10 mins of evaporation, wherein Composition L2 comprises 7 wt% Traditional Muguesia Magnifica Fragrance Example 5a and no modulator. The headspace is a complex fragrance and many perfume materials can be observed spanning a range of volatility and characters. This includes: (1) moderate volatile fragrance materials having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25 \u00b0C, for example: Cyclogalbanate or Majantol\u00ae, Helional, Cymal or Jasmal and hydroxycitronellal; and (2) low volatile fragrance materials having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25 \u00b0C, for example: Hedione\u00ae HC and Iso-E Super\u00ae. As the fragrance evaporates, the height of the peaks reduces significantly, particularly the peaks due to the high and moderate volatile fragrance materials. After 60 mins of evaporation, as shown in Figure 22(a)(ii), only one substantial moderate volatile fragrance material peak remains, for example Helional. In contrast, the low volatile fragrance materials remain with substantial peaks for many perfume materials, for example Hedione\u00ae HC and Iso-E Super\u00ae. These chromatograms illustrate the loss of fragrance materials during evaporation, particularly the loss of the moderate volatile fragrance materials. Olfactively this is perceived as a loss in intensity and perception of these particular fragrance materials, particularly those that provide the floral characters.\\ \\ - \\[0159\\]\\ \\ Figure 22(b)(i) provides the headspace chromatogram for inventive Composition J2 after 10 mins of evaporation, wherein Composition J2 comprises 7 wt% Diamond Muguesia Magnifica Fragrance Example 5b and 15 wt% PPG-11 Stearyl Ether substantially non-odorous fragrance modulator. The headspace is a complex fragrance and many perfume materials can be observed spanning a range of volatility and characters. This includes: (1) moderate volatile fragrance materials having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25 \u00b0C, for example: Cyclogalbanate or Majantol\u00ae, Helional, Cymal or Jasmal and hydroxy citronellal; and (2) low volatile fragrance material having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25 \u00b0C, for example Hedione\u00ae HC and Iso-E Super\u00ae. As the fragrance evaporates the height of the peaks reduces but not as much as compared to the control Composition L2, particularly the peaks due to the moderately volatile fragrance materials are maintained. After 60 mins of evaporation, as shown in Figure 22(b)(ii), most of the moderate volatile fragrance materials peaks remain. This includes Cyclogalbanate or Majantol\u00ae, Helional, Cymal or Jasmal and hydroxy citronellal. The low volatile fragrance materials, Hedione\u00ae HC and Iso-E Super , remain in the headspace but are not dominant when compared to Composition L2. These chromatograms illustrate the prolonged presence of the volatile fragrance materials in Composition J2 and the dominance of the headspace after 60 mins by the moderate volatile fragrance materials at the expense of the low volatile fragrance materials. Consumers will experience this as a fragrance with a prolonged intensity, particularly of the characters attributable to the volatile fragrance materials, most particularly of the floral characters.\\ \\ - \\[0160\\]\\ \\ Figure 23(a)(i) provides the headspace chromatogram for control Composition C4 after 10 mins of evaporation, wherein Composition C4 comprises the Traditional Muguesia Magnifica Fragrance Example 5a and no modulator. The headspace is a complex fragrance and many perfume materials can be observed spanning a range of volatility and characters. This includes: (1) moderate volatile fragrance materials having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25 \u00b0C, for example: Cyclogalbanate or Majantol\u00ae, Phenethyl alcohol, Cymal or Jasmal, and hydroxy citronellal and (2) low volatile fragrance materials having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25 \u00b0C, for example: Hedione\u00ae HC and Iso-E Super\u00ae. As the fragrance evaporates, the height of the peaks reduces significantly, particularly the peaks due to the moderate volatile fragrance materials. After 60 mins of evaporation, as shown in Figure 23(a)(ii), only two small moderate volatile fragrance material peaks remain, Helional and Cyclogalbante or Majantol. In contrast, the low volatile fragrance materials remain with many peaks for many perfume materials, for example Hedione\u00ae HC and Iso-E Super . These chromatograms illustrate the loss of fragrance materials during evaporation, particularly the loss of the moderate volatile fragrance materials. Olfactively this is perceived as a loss in intensity and perception of these particular fragrance materials, particularly those that provide the floral characters.\\ \\ - \\[0161\\]\\ \\ Figure 23(b)(i) provides the headspace chromatogram for inventive Composition A4 after 10 mins of evaporation, wherein Composition A4 comprises the Diamond Muguesia Magnifica Fragrance Example 5b and PPG-20 Methyl Glucose Ether (i.e., GLUCAM\u2122 P-20) substantially non-odorous fragrance modulator. The headspace is a complex fragrance and many perfume materials can be observed spanning a range of volatility and characters. This includes: (1) moderate volatile fragrance materials having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25 \u00b0C, for example: Cyclogalbanate or Majantol\u00ae, Phenethyl alcohol, Cymal or Jasmal, and hydroxycitronellal; and (2) low volatile fragrance material having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25 \u00b0C, for example Hedione\u00ae HC and Iso-E Super\u00ae. As the fragrance evaporates the height of the peaks reduces but not as much as compared to the control Composition C4, particularly the peaks due to the moderate volatile fragrance materials are maintained. After 60 mins of evaporation, as shown in Figure 23(b)(ii), most of the moderate volatile fragrance materials peaks remain. This includes Cyclogalbanate or Majantol\u00ae, Phenethyl alcohol, Cymal or Jasmal, and hydroxycitronellal. The low volatile fragrance materials, Hedione\u00ae HC and Iso-E Super\u00ae, remain in the headspace but are not dominant when compared to Composition C4. These chromatograms illustrate the prolonged presence of the volatile fragrance materials in Composition A4 and the dominance of the headspace after 60 mins by the moderate volatile fragrance materials at the expense of the low volatile fragrance materials. Olfactively this is perceived as a fragrance with a prolonged intensity, particularly of the characters attributable to the moderate volatile fragrance materials, most particularly of the floral characters.\\ \\ - \\[0162\\]\\ \\ Figure 24(a)(i) provides the headspace chromatogram for control Composition L4 after 10 mins of evaporation, wherein Composition L4 comprises the Traditional Floral Magnifica Fragrance Example 4a and no modulator. The headspace is a complex fragrance and many perfume materials can be observed spanning a range of volatility and characters. This includes: (1) moderate volatile fragrance materials having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25 \u00b0C, for example: Pyranol (Florol), Cyclogalbanate or Majantol\u00ae, Cymal or Jasmal, and hydroxycitronellal and (2) low volatile fragrance materials having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25 \u00b0C, for example: Hedione\u00ae HC and Iso-E Super\u00ae. As the fragrance evaporates, the height of the peaks reduces significantly, particularly the peaks due to the moderate volatile fragrance materials. After 60 mins of evaporation, as shown in Figure 24(a)(ii), only a few small moderate volatile fragrance material peaks remain, Cymal or Jasmal and Helional. In contrast, the low volatile fragrance materials remain with many peaks for many perfume materials, for example Hedione\u00ae HC and Iso-E Super\u00ae. These chromatograms illustrate the loss of fragrance materials during evaporation, particularly the loss of the moderate volatile fragrance materials. Olfactively this is perceived as a loss in intensity and perception of these particular fragrance materials, particularly those that provide the floral characters.\\ \\ - \\[0163\\]\\ \\ Figure 24(b)(i) provides the headspace chromatogram for inventive Composition J4 after 10 mins of evaporation, wherein Composition J4 comprises the Diamond Floral Magnifica Fragrance Example 4b and Isocetyl Alcohol (i.e., Ceraphyl\u00ae ICA) substantially non-odorous fragrance modulator. The headspace is a complex fragrance and many perfume materials can be observed spanning a range of volatility and characters. This includes: (1) moderate volatile fragrance materials having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25 \u00b0C, for example: Pyranol (Florol), Cyclogalbanate or Majantol\u00ae, Cymal or Jasmal, and hydroxy citronellal; and (2) low volatile fragrance material having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25 \u00b0C, for example Hedione\u00ae HC and Iso-E Super\u00ae. As the fragrance evaporates the height of the peaks reduces but not as much as compared to the control Composition C4, particularly the peaks due to the moderate volatile fragrance materials are maintained. After 60 mins of evaporation, as shown in Figure 24(b)(ii), most of the moderate volatile fragrance materials peaks remain. This includes Pyranol (Florlol), Cyclogalbanate or Majantol\u00ae, Cymal or Jasmal, and hydroxy citronellal. The low volatile fragrance materials, Hedione\u00ae HC and Iso-E Super\u00ae, remain in the headspace but are not dominant when compared to Composition C4. These chromatograms illustrate the prolonged presence of the volatile fragrance materials in Composition A4 and the dominance of the headspace after 60 mins by the moderate volatile fragrance materials at the expense of the low volatile fragrance materials. Olfactively this is perceived as a fragrance with a prolonged intensity, particularly of the characters attributable to the moderate volatile fragrance materials, most particularly of the floral characters.\\ \\ - \\[0164\\]\\ \\ Figure 25(a)(i) provides the headspace chromatogram for control Composition I4 after 10 mins of evaporation, wherein Composition I4 comprises the Traditional Muguesia Magnifica Fragrance Example 5a and no modulator. The headspace is a complex fragrance and many perfume materials can be observed spanning a range of volatility and characters. This includes: (1) moderate volatile fragrance materials having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25 \u00b0C, for example: Cyclogalbanate or Majantol\u00ae, Helional, Cymal or Jasmal, and hydroxy citronellal and (2) low volatile fragrance materials having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25 \u00b0C, for example: Hedione\u00ae HC and Iso-E Super\u00ae. As the fragrance evaporates, the height of the peaks reduces significantly, particularly the peaks due to the high and moderate volatile fragrance materials. After 60 mins of evaporation, as shown in Figure 25(a)(ii), only one substantial moderate volatile fragrance material peak remains, Helional. In contrast, the low volatile fragrance materials remain with substantial peaks for many perfume materials, for example Hedione\u00ae HC and Iso-E Super\u00ae. These chromatograms illustrate the loss of fragrance materials during evaporation, particularly the loss of the moderate volatile fragrance materials. Olfactively this is perceived as a loss in intensity and perception of these particular fragrance materials, particularly those that provide the floral characters.\\ \\ - \\[0165\\]\\ \\ Figure 25(b)(i) provides the headspace chromatogram for inventive Composition G4 after 10 mins of evaporation, wherein Composition G4 comprises the Diamond Muguesia Magnifica Fragrance Example 5b and Undecyl Glucoside (i.e., Simulsol\u00ae SL 11W) substantially non-odorous fragrance modulator. The headspace is a complex fragrance and many perfume materials can be observed spanning a range of volatility and characters. This includes: (1) moderate volatile fragrance materials having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25 \u00b0C, for example: Cyclogalbanate or Majantol\u00ae, Helional, Cymal or Jasmal and hydroxy citronellal; and (2) low volatile fragrance material having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25 \u00b0C, for example Hedione\u00ae HC and Iso-E Super\u00ae. As the fragrance evaporates the height of the peaks reduces but not as much as compared to the control Composition I4, particularly the peaks due to the moderately volatile fragrance materials are maintained. After 60 mins of evaporation, as shown in Figure 25(b)(ii), most of the moderate volatile fragrance materials peaks remain. This includes Cyclogalbanate or Majantol\u00ae, Helional, Cymal or Jasmal and hydroxycitronellal. The low volatile fragrance materials, Hedione\u00ae HC and Iso-E Super\u00ae, remain in the headspace but are not dominant when compared to Composition I4. These chromatograms illustrate the prolonged presence of the volatile fragrance materials in Composition G4 and the dominance of the headspace after 60 mins by the moderate volatile fragrance materials at the expense of the low volatile fragrance materials. Olfactively this is perceived as a fragrance with a prolonged intensity, particularly of the characters attributable to the moderate volatile fragrance materials, most particularly of the floral characters.\\ \\ - \\[0166\\]\\ \\ It should be understood that every maximum numerical limitation given throughout this specification includes every lower numerical limitation, as if such lower numerical limitations were expressly written herein. Every minimum numerical limitation given throughout this specification will include every higher numerical limitation, as if such higher numerical limitations were expressly written herein. Every numerical range given throughout this specification will include every narrower numerical range that falls within such broader numerical range, as if such narrower numerical.\\ \\ - \\[0167\\]\\ \\ The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as \"40 mm\" is intended to mean \"about 40 mm.\"\\ \\ \\ ### Claims (21) Hide Dependent translated from\\ \\ 01. A composition comprising:\\ \\ \\ (i) a fragrance component present in an amount of from about 0.04 wt% to about 30 wt%, relative to the total weight of the composition, and wherein the fragrance component comprises:\\ \\ \\ (a) at least one low volatile fragrance material having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25 \u00b0C present in an amount of from about 10 wt% to about 30 wt%, relative to the total weight of the fragrance component;\\ \\ \\ \\ (b) at least one moderate volatile fragrance material having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25 \u00b0C present in an amount of from about 40 wt% to about 80 wt%, relative to the total weight of the fragrance component; and\\ \\ \\ \\ (c) at least one high volatile fragrance material having a vapor pressure greater than 0.1 Torr (0.0133 kPa) at 25 \u00b0C present in an amount of from about 1 wt% to about 30 wt%, relative to the total weight of the fragrance component;\\ \\ \\ \\ \\ \\ (ii) at least one substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt% to about 20 wt%, relative to the total weight of the composition;\\ \\ \\ \\ (iii) a volatile solvent present in an amount of from about 50 wt% to about 80 wt%, relative to the total weight of the composition; and\\ \\ \\ \\ (iv) optionally water.\\ \\ 02. The composition according to claim 1, wherein:\\ \\ \\ (i) the fragrance component is present in an amount from about 1 wt% to about 30 wt%, preferably less than about 25 wt%, more preferably less than about 20 wt%, yet even more preferably less than about 15 wt%, yet even more preferably less than about 10 wt% or yet even more preferably less than about 8 wt%, relative to the total weight of the composition; and wherein the fragrance component comprises:\\ \\ \\ (a) at least one low volatile fragrance material present in an amount less than about 30 wt%, or less than about 28 wt%, or less than about 25 wt%, relative to the total weight of the fragrance component;\\ \\ \\ \\ (b) at least one moderate volatile fragrance material present in an amount of at least about 45 wt%, or preferably at least about 50 wt%, relative to the total weight of the fragrance component; and\\ \\ \\ \\ (c) at least one high volatile fragrance material present in an amount of less than about 25 wt%, preferably less than about 22 wt% or more preferably less than about 20 wt%, relative to the total weight of the fragrance component;\\ \\ \\ \\ \\ \\ (ii) at least one substantially non-odorous fragrance modulator present in the amount of from about 0.5 wt% to about 18 wt%, or preferably from about 2.5 wt% to about 15 wt%, relative to the total weight of the composition;\\ \\ \\ \\ (iii) the volatile solvent present in an amount of from about 55 wt% to about 75 wt%, relative to the total weight of the composition; and\\ \\ \\ \\ (iv) the water present in an amount of from 0 wt% to about 20 wt%, relative to the total weight of the composition.\\ \\ 03. The composition according to any one of the preceding claims, wherein:\\ \\ \\ (i)(a) the low volatile fragrance material is selected from at least 1 material, or at least 2 materials, or at least 3 materials from the group of Table 1 Low Volatile Fragrance Materials 1-112, and mixtures thereof.\\ \\ 04. The composition according to claim 3, wherein:\\ \\ \\ (i)(a) the low volatile fragrance material is selected from the group of Table 1 Low Volatile Fragrance Materials 1, 4-6, 8, 12-16, 18, 22-25, 27-28, 31, 34-37, 41, 45, 47, 52-55, 57, 60, 61, 63, 65, 68, 69-74, 75, 78, 80, 83-84, 89, 94, 99, 102, 104, 106-108, and mixtures thereof; and\\ \\ \\ \\ (ii) the substantially non-odorous fragrance modulator is selected from the group of Table 4(a) Substantially Non-Odorous Fragrance Modulators 1-5, and mixtures thereof.\\ \\ 05. The composition according to claim 3, wherein:\\ \\ \\ (i)(a) the low volatile fragrance material is selected from the group of Table 1 Low Volatile Fragrance Materials 1-6, 8-9, 12-14, 16, 18-19, 23, 25-28, 31, 34-35, 37, 41-42, 45, 47-49, 53-55, 57-60, 63, 65, 69, 71-73, 75, 78-79, 81, 84-85, 95, 100, 103, 105, 107, 109, and mixtures thereof; and\\ \\ \\ \\ (ii) the substantially non-odorous fragrance modulator is selected from the group of Table 4(a) Substantially Non-Odorous Fragrance Modulators 6-8, and mixtures thereof.\\ \\ 06. The composition according to any one of the preceding claims, wherein:\\ \\ \\ (i)(b) the moderate volatile fragrance material is selected from at least 1 material, or at least 2 materials, or at least 3 materials from the group of Table 2 Moderate Volatile Fragrance Materials 1-319, and mixtures thereof.\\ \\ 07. The composition according to claim 6, wherein:\\ \\ \\ (i)(b) the moderate volatile fragrance material is selected from the group of Table 2 Moderate Volatile Fragrance Materials 1-9, 11-12, 14-15, 17-18, 20-25, 27-35, 37-38, 39-43, 45-46, 48-53, 55-61, 63, 65, 67-71, 73-77, 79, 81-84, 86-91, 93-122, 124-125, 130-131, 133-135, 137, 139-145, 147-149, 151, 153-155, 157, 161-162, 164-169, 171-191, 193, 195-198,200-203, 205-215, 218-219, 221, 223-241, 243, 245-250, 252-255, 257-262, 264-265, 267-268, 272, 273-276, 279-300, 302-304, 306, 308-310, 312-319, and mixtures thereof; and\\ \\ \\ \\ (ii) the substantially non-odorous fragrance modulator is selected from the group of Table 4(a) Substantially Non-Odorous Fragrance Modulators 1-5, and mixtures thereof.\\ \\ 08. The composition according to claim 6, wherein:\\ \\ \\ (i)(b) the moderate volatile fragrance material is selected from the group of Table 2 Moderate Volatile Fragrance Materials 1-9, 11-12, 14-15, 17-18, 20-25, 27-35, 37-38, 41-42, 45-46, 49, 51-53, 55, 57-59, 65-70, 73, 75-77, 79-80, 82, 86-89, 91-94, 98, 101-107, 111-113, 115-122, 124-125, 130-133, 135, 137, 139-143, 145, 147-149, 151, 153-155, 157-159, 161-162, 164-168, 171-180, 182-183, 187-191, 193, 195-198, 200-203, 205-213, 218-219, 221-222, 224-229, 231-241, 243, 245-250, 252, 253, 254-255, 257-263, 264-265, 267-269, 271, 273-276, 279-300, 302-304, 306, 308-310, 312, 314-319, and mixtures thereof; and\\ \\ \\ \\ (ii) the substantially non-odorous fragrance modulator is selected from the group of Table 4(a) Substantially Non-Odorous Fragrance Modulators 6-8, and mixtures thereof.\\ \\ 09. The composition according to any one of the preceding claims, wherein:\\ \\ \\ (i)(c) the high volatile fragrance material is selected from at least 1 material, or at least 2 materials, or at least 3 materials from the group of Table 3 High Volatile Fragrance Materials 1-130, and mixtures thereof.\\ \\ 10. The composition according to claim 9, wherein:\\ \\ \\ (i)(c) the high volatile fragrance material is selected from the group of Table 3 High Volatile Fragrance Materials 1, 2, 6, 8, 9, 12, 14, 19, 36, 39, 46, 47, 56, 57, 58, 60, 62, 74, 78, 93, 94, 96, 100, 106, 111, 117, 119, 120, 128, 129, 131-135, and mixtures thereof; and\\ \\ \\ \\ (ii) the substantially non-odorous fragrance modulator is selected from the group of Table 4(a) Substantially Non-Odorous Fragrance Modulators 1-5, and mixtures thereof.\\ \\ 11. The composition according to claim 9, wherein:\\ \\ \\ (i)(c) the high volatile fragrance material is selected from the group of Table 3 High Volatile Fragrance Materials 1, 2, 6, 8, 9, 12, 14, 19, 36, 39, 46, 47, 56, 57, 58, 60, 62, 74, 78, 93, 94, 96, 100, 106, 111, 117, 119, 120, 128, 129, 131-135, and mixtures thereof; and\\ \\ \\ \\ (ii) the substantially non-odorous fragrance modulator is selected from the group of Table 4(a) Substantially Non-Odorous Fragrance Modulators 6-8, and mixtures thereof.\\ \\ 12. The composition according to any one of the preceding claims, wherein the substantially non-odorous fragrance modulator is selected from the group consisting of:\\ \\ \\ (a) Methyl Glucoside Polyol; Ethyl Glucoside Polyol; Propyl Glucoside Polyol; and their mixtures;\\ \\ \\ \\ (b) Isocetyl Alcohol;\\ \\ \\ \\ (c) PPG-3 Myristyl Ether; Neopentyl Glycol Diethylhexanoate; and their mixtures;\\ \\ \\ \\ (d) Sucrose Laurate, Sucrose Dilaurate, Sucrose Myristate, Sucrose Palmitate, Sucrose Stearate, Sucrose Distearate, Sucrose Tristearate, and their mixtures;\\ \\ \\ \\ (e) Trimethylcyclohexane derivatives having the formula (I):\\ \\ \\ \\ \\ \\ wherein:\\ \\ \\ n is 0, 1 or 2;\\ \\ \\ \\ A is C=O or CH-OH;\\ \\ \\ \\ R1a is hydrogen or methyl;\\ \\ \\ \\ R2a is a C2-C10 hydrocarbon group; and\\ \\ \\ \\ \\-\\-\\-\\-\\-\\- is a saturated or unsaturated carbon-carbon bond;\\ \\ \\ \\ \\ \\ (f) L-menthoxy ether derivatives having the formula (II):\\ \\ \\ \\ \\ \\ wherein:\\ \\ \\ m is 0, 1 or 2;\\ \\ \\ \\ B is hydrogen or OH; and\\ \\ \\ \\ C is hydrogen or methyl;\\ \\ \\ \\ \\ \\ (g) Tetra-hydronaphthalene derivatives having the formula (III):\\ \\ \\ \\ \\ \\ wherein:\\ \\ \\ R1b is hydrogen or methyl; and\\ \\ \\ \\ R2b is alkyl;\\ \\ \\ \\ \\ \\ (h) Hyaluronic acid disaccharide sodium salt, sodium hyaluronate and their mixtures;\\ \\ \\ \\ (i) Ether derivatives having the formula (IV) or formula (V):\\ \\ \\ \\ \\ C5H _l_ Om-(OR1c)n (IV)\\ \\ \\ \\ \\ wherein:\\ \\ \\ C5H _l_ Om is a pentose residue, wherein _l_ is an integer from 6 to 9, and m is an integer from 1 to 4;\\ \\ \\ \\ n is an integer from 1 to 4; and\\ \\ \\ \\ R1c is C4-C20 hydrocarbon group; and\\ \\ \\ \\ \\ \\ \\ C6HxOy-(OR1d)z (V)\\ \\ \\ \\ \\ wherein:\\ \\ \\ C6HxOy is a hexose residue, wherein x is an integer from 7 to 11, and y is an integer from 1 to 5;\\ \\ \\ \\ z is an integer from 1 to 5; and\\ \\ \\ \\ R1d is C4-C20 hydrocarbon group; and\\ \\ \\ \\ \\ \\ (j) Diethylene Glycol Ether derivatives having the formula (VI) or formula (VII):\\ \\ \\ \\ \\ C5HcOd-(OCH2CH2-O-CH2CH2-O-R1e)e (VI)\\ \\ \\ \\ \\ wherein:\\ \\ \\ C5HcOd is a pentose residue, wherein c is an integer from 6 to 8, and d is an integer from 1 to 3;\\ \\ \\ \\ e is an integer from 2 to 4; and\\ \\ \\ \\ R1e is C1-C6 alkyl group; and\\ \\ \\ C6HfOg-(OCH2CH2O-CH2CH2O-R1f)h (VII)\\ \\ \\ \\ \\ wherein:\\ \\ \\ C6HfOg is a hexose residue, wherein f is an integer from 7 to 10, and g is an integer from 1 to 4;\\ \\ \\ \\ h is an integer from 2 to 5; and\\ \\ \\ \\ R1f is C1-C6 alkyl group;\\ \\ \\ \\ \\ \\ (k) Hydroquinone Glycoside derivatives having the formula (VIII):\\ \\ \\ \\ \\ \\ wherein:\\ \\ \\ R1g is selected from the group consisting of: (i) pentose residue, hexose residue,\\ \\ \\ \\ aminosaccharide residue, uronic acid residue and their mixtures; (ii) methylated versions of group (i); and (iii) mixtures of groups (i) and (ii); and\\ \\ \\ \\ \\ \\ (l) Propylene Glycol Propyl Ether; Dicetyl Ether; Polyglycerin-4 Ethers; Isoceteth-5; Isoceteth-7, Isoceteth-10; Isoceteth-12; Isoceteth-15; Isoceteth-20; Isoceteth-25; Isoceteth-30; Disodium Lauroamphodipropionate; Hexaethylene glycol monododecyl ether; and their mixtures;\\ \\ \\ \\ (m)Neopentyl Glycol Diisononanoate; Cetearyl Ethylhexanoate; and their mixtures;\\ \\ \\ \\ (n) Glyceryl Ether derivatives having the formula (IX):\\ \\ \\ \\ \\ \\ wherein:\\ \\ \\ R1h is C4-C12 aliphatic hydrocarbon group;\\ \\ \\ \\ \\ \\ (o) Panthenol Ethyl Ether, DL-Panthenol and their mixtures;\\ \\ \\ \\ (p) Aliphatic Dibasic Acid Diester derivatives having the formula (X):\\ \\ \\ \\ \\ R1iOCOR2iCOOR3i (X)\\ \\ \\ \\ \\ wherein:\\ \\ \\ R1i is C4-C5 alkyl;\\ \\ \\ \\ R2i is C4 alkylene; and\\ \\ \\ \\ R3i is C4-C5 alkyl; and\\ \\ \\ \\ \\ \\ (q) Aliphatic Ether derivatives having the formula (XI):\\ \\ \\ \\ \\ R4i-O-(CH(CH3)-CH2O)a-(CH2-CH2O)b-H (XI)\\ \\ \\ \\ \\ wherein:\\ \\ \\ a and b are integers such that the sume of a and b is from 1 to 4; and\\ \\ \\ \\ R4i is an aliphatic chain comprising from 8 to 18 carbons;\\ \\ \\ \\ \\ \\ (r) _N_-hexadecyl n-nonanoate, Noctadecyl n-nonanoate and their mixtures;\\ \\ \\ \\ (s)Tricyclodecane Amide derivatives selected from the group consisting of:\\ \\ \\ (i) the compounds of formula (XII):\\ \\ \\ \\ \\ \\ wherein:\\ \\ \\ X is selected from:\\ \\ \\ \\ \\ \\ \\ \\ \\ \\ \\ \\ \\ \\ \\ \\ \\ t is 1 to 8;\\ \\ \\ \\ Y is hydrogen,\\ \\ \\ \\ \\ \\ or a halogen; and each R1j is independently selected from a hydrogen, or C1-C4 alkyl;\\ \\ \\ \\ \\ \\ (ii) the compounds of formula (XIII):\\ \\ \\ \\ \\ \\ \\ \\ wherein:\\ \\ \\ each R2j is independently selected from a hydrogen, methyl, ethyl or C3-C18 alkyl, cycloalkyl or cycloheteroalkyl, with the proviso that both R2e groups are not hydrogen; and\\ \\ \\ \\ (iii) mixtures of the compounds of formulae (XII) and (XIII); and (t) mixtures thereof.\\ \\ 13. The composition according to any one of the preceding claims, wherein the substantially non-odorous fragrance modulator is selected from the group of Table 4(a) Substantially Non-Odorous Fragrance Modulators 1-103, Table 4(b) Substantially Non-Odorous Fragrance Modulators 1-189, and mixtures thereof.\\ \\ 14. The composition according to any one of the preceding claims, wherein the volatile solvent is a branch or unbranched C1 to C10 alkyl, akenyl or alkynyl group having at least one alcohol moiety, preferably ethanol, isopropanol, or glycol.\\ \\ 15. The composition according to any one of the preceding claims, wherein the composition maintains the perceived fragrance profile, particularly the characters attributable to the moderate volatile fragrance material and/or high volatile fragrance material, to remain substantively unchanged from application up to 2 hrs, 3 hrs, 4 hrs, 5 hrs, 6 hrs or 8 hrs after application vs. a control composition that does not include a diamond construction fragrance formulation and the substantially non-odorous fragrance modulator, as determined according to the Odour Test as described herein.\\ \\ 16. The composition according to any one of the preceding claims, wherein the composition is a fine fragrance composition, preferably in the form of a perfume concentrate, a perfume, a parfum, an eau de toilette, an eau de parfum, or a cologne.\\ \\ 17. The composition according to any one of claims 1-15, wherein the composition is in the form of a body splash or a body spray.\\ \\ 18. The composition according to any one of the preceding claims, wherein the substantially non-odorous fragrance modulator does not comprise:\\ \\ \\ (i) isocetyl alcohol, PPG-3 myristyl ether, neopentyl glycol diethylhexanoate or their mixtures; and\\ \\ \\ \\ (ii) n-hexadecyl n-nonanoate, n-octadecyl n-nonanoate or their mixtures.\\ \\ 19. A method for imparting, intensifying, or modifying an odour on human skin or human hair, comprising applying to human skin and/or human hair the composition according to any one of claims 1-18.\\ \\ 20. The method according to claim 19, wherein the method is preferably for imparting, intensifying or modifying the longevity of a floral character on human skin or human hair, wherein the perceived intensity of the floral character at 1 hr, 2 hrs, 3 hrs or 6 hrs after application is greater than a control composition that does not include the substantially non-odorous fragrance modulator as determined by the panel method as disclosed herein, and wherein the floral character is selected from the group consisting of lavender-type note, a rose-type note, a lily of the valley-type note, a muguet-type note, a jasmine-type note, a magnolia-type note, a cyclamen-type note, a hyacinth-type note, a lilac-type note, an orange blossom-type note, a cherry blossom-type note, a peony-type note, a lotus-type note, a linden blossom-type note, an osmanthus-type note, a lilac-type note, a heliotrope-type note, a violet-type note, an orris-type note, a tiare-type note, a patchouli-type note and the like.\\ \\ 21. A perfuming consumer product or article comprising a composition according to any one of the claims 1-18, wherein the perfuming consumer product is selected from the group consisting of a fabric care product, an air care product or a home care product."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.45, "construct": {"method_text_verbatim": "Surprisingly, it was found that in particular the compounds of formula (I), and in particular compounds 1 to 8, are suitable as sandalwood-like fragrances. These compounds show additionally superior secondary properties, such as an elevated tenacity, a low odor threshold value, elevated impact (odor intensity), as well as an elevated substantivity.", "panel_size": null, "property_name": "odor_intensity", "scale": "numeric_unknown", "substrate": null, "time_points": null}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "1 to 8", "patent_id": "US20230126581A1", "provenance": {"citation": "US20230126581A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/US20230126581A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:212", "units": null, "verbatim_quote": "Surprisingly, it was found that in particular the compounds of formula (I), and in particular compounds 1 to 8, are suitable as sandalwood-like fragrances. These compounds show additionally superior secondary properties, such as an elevated tenacity, a low odor threshold value, elevated impact (odor intensity), as well as an elevated substantivity."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.45, "construct": {"method_text_verbatim": "- | TABLE 3 | | --- | | | | Comparison of the tenacity of compounds | | 1 to 3 according to formula (I). |", "panel_size": null, "property_name": "tenacity", "scale": "numeric_unknown", "substrate": null, "time_points": null}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "1 to 3", "patent_id": "US20230126581A1", "provenance": {"citation": "US20230126581A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/US20230126581A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:223", "units": null, "verbatim_quote": "- | TABLE 3 | | --- | | | | Comparison of the tenacity of compounds | | 1 to 3 according to formula (I). |"}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": "compound 3", "confidence": 0.6, "construct": {"method_text_verbatim": "Therefore, among the above novel compounds specified in Table 1, compounds 1 to 4 are preferred due to their property to exhibit the most natural, the strongest and the most persistent sandalwood odor based on their high threshold intensity and superior tenacity, being superior to any existing synthetic, commercially available materials exhibiting a sandalwood odor, such as Brahmanol\u00ae (Symrise AG). However, compound 3 (2-ethyl-4-\\[3-(methoxymethyl)-2,2-dimethyl-cyclopent-3-en-1-yl\\]but-2-en-1-ol) is particularly preferred, showing the best olfactoric properties of the above indicated compounds as demonstrated in Tables 2 and 3.", "panel_size": null, "property_name": "tenacity", "scale": "numeric_unknown", "substrate": null, "time_points": null}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "1 to 4", "patent_id": "US20230126581A1", "provenance": {"citation": "US20230126581A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/US20230126581A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:226", "units": null, "verbatim_quote": "Therefore, among the above novel compounds specified in Table 1, compounds 1 to 4 are preferred due to their property to exhibit the most natural, the strongest and the most persistent sandalwood odor based on their high threshold intensity and superior tenacity, being superior to any existing synthetic, commercially available materials exhibiting a sandalwood odor, such as Brahmanol\u00ae (Symrise AG). However, compound 3 (2-ethyl-4-\\[3-(methoxymethyl)-2,2-dimethyl-cyclopent-3-en-1-yl\\]but-2-en-1-ol) is particularly preferred, showing the best olfactoric properties of the above indicated compounds as demonstrated in Tables 2 and 3."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.45, "construct": {"method_text_verbatim": "In particular, it was found, that the compounds of formula (I) in general and in particular, compounds 1 to 4 are particularly excellent for imparting, modifying and/or enhancing a woody sandalwood-like fragrance being confusingly similar to the odor profile of natural sandalwood essential oil. The fact that the compounds have such an expressive scent and long tenacity is surprising. Furthermore, the combination of high intensity and tenacity allows for the use of said compounds and composition to achieve a pleasant odor in conjunction with an improved fixation of a fragrance compound resulting in an harmonic and long-lasting overall odor impression with the reminiscence of natural sandalwood, applicable for various perfumed products and for the production thereof.", "panel_size": null, "property_name": "tenacity", "scale": "numeric_unknown", "substrate": null, "time_points": null}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "1 to 4", "patent_id": "US20230126581A1", "provenance": {"citation": "US20230126581A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/US20230126581A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from:316", "units": null, "verbatim_quote": "In particular, it was found, that the compounds of formula (I) in general and in particular, compounds 1 to 4 are particularly excellent for imparting, modifying and/or enhancing a woody sandalwood-like fragrance being confusingly similar to the odor profile of natural sandalwood essential oil. The fact that the compounds have such an expressive scent and long tenacity is surprising. Furthermore, the combination of high intensity and tenacity allows for the use of said compounds and composition to achieve a pleasant odor in conjunction with an improved fixation of a fragrance compound resulting in an harmonic and long-lasting overall odor impression with the reminiscence of natural sandalwood, applicable for various perfumed products and for the production thereof."}
{"alignment_to_poucher": {"correlation": null, "overlap_n": null}, "assignee": null, "compound_ref_verbatim": null, "confidence": 0.6, "construct": {"method_text_verbatim": "1 Stunde; 3 Stunden; 10 Stunden; 1 Tag; 3 Tage; 10 Tage; 1 Monat; 3 Monate. Die Probanden bewerten die Geruchsintensit\u00e4t auf einer Skala von 1 = geruchlos bis 9 = sehr stark. 1 hour; 3 hours; 10 hours; 1 day; 3 days; 10 days; 1 month; 3 months. The subjects rate the odor intensity on a scale from 1 = odorless to 9 = very strong.", "panel_size": null, "property_name": "odor_intensity", "scale": "hours_or_timepoint", "substrate": null, "time_points": ["1 hour", "3 hours", "10 hours", "1 day", "3 days", "10 days"]}, "construct_group_id": null, "dedup_tag": null, "extraction_method": "regex_span_probe", "measured_value_verbatim": "1 hour; 3 hours; 10 hours; 1 day; 3 days; 10 days", "patent_id": "WO2014183883A1", "provenance": {"citation": "WO2014183883A1", "retrieval_source": "Firecrawl scrape of Google Patents public page", "tos_note": "Fetched public patent page; stored extracted spans only, not bulk full text.", "url": "https://patents.google.com/patent/WO2014183883A1/en"}, "pub_date": null, "resolution_confidence": 0.0, "resolution_method": "unresolved", "resolved_cas": null, "resolved_smiles": null, "source_locus": "description_translated_from_german:841", "units": "hours", "verbatim_quote": "1 Stunde; 3 Stunden; 10 Stunden; 1 Tag; 3 Tage; 10 Tage; 1 Monat; 3 Monate. Die Probanden bewerten die Geruchsintensit\u00e4t auf einer Skala von 1 = geruchlos bis 9 = sehr stark. 1 hour; 3 hours; 10 hours; 1 day; 3 days; 10 days; 1 month; 3 months. The subjects rate the odor intensity on a scale from 1 = odorless to 9 = very strong."}