formula stringlengths 3 12 | crystal_structure stringlengths 5 22 | morphology stringclasses 7
values | experimental_her_overpotential_V float64 0.03 0.85 | experimental_her_j_mA_cm2 int64 10 10 | experimental_oer_overpotential_V float64 0.18 0.72 | experimental_oer_j_mA_cm2 int64 10 10 | electrolyte stringclasses 4
values | ph float64 0.3 14 | T_C int64 25 25 | reference stringlengths 38 55 | reference_doi stringlengths 17 28 | notes stringlengths 12 61 | data_type stringclasses 1
value | measurement_method stringclasses 1
value | n_metal_elements int64 1 5 | oxide_type stringclasses 3
values |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
RuO2 | rutile | nanoparticles | 0.028 | 10 | 0.178 | 10 | 0.1 M KOH | 13 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Benchmark oxide OER catalyst, RuO2 standard | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
RuO2 | rutile | thin_film | 0.035 | 10 | 0.185 | 10 | 0.5 M H2SO4 | 0.3 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Acidic OER, RuO2 dissolves at high potential | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
IrO2 | rutile | thin_film | 0.045 | 10 | 0.25 | 10 | 0.1 M KOH | 13 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Benchmark oxide OER catalyst, more stable than RuO2 | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
IrO2 | rutile | thin_film | 0.05 | 10 | 0.28 | 10 | 0.5 M H2SO4 | 0.3 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Acidic OER benchmark | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
Co3O4 | spinel | nanoparticles | 0.28 | 10 | 0.31 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Spinel Co3O4, good bifunctional catalyst | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
NiCo2O4 | spinel | nanoparticles | 0.18 | 10 | 0.26 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Ni-Co spinel, excellent bifunctional | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
NiFe2O4 | inverse_spinel | nanoparticles | 0.22 | 10 | 0.24 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Inverse spinel, best non-precious OER | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
MnCo2O4 | spinel | nanoparticles | 0.3 | 10 | 0.34 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Mn-Co spinel, moderate activity | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
Fe3O4 | inverse_spinel | nanoparticles | 0.35 | 10 | 0.38 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Magnetite, earth-abundant, moderate activity | real_experimental_overpotential | rotating_disk_electrode | 1 | multimetallic_oxide |
NiO | rock_salt | nanosheets | 0.42 | 10 | 0.38 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Rock salt NiO, transforms to NiOOH during OER | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
CoO | rock_salt | nanoparticles | 0.32 | 10 | 0.35 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Rock salt CoO, moderate activity | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
MnO | rock_salt | nanoparticles | 0.48 | 10 | 0.5 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Rock salt MnO | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
MnO2 | rutile_beta | nanorods | 0.52 | 10 | 0.49 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Beta-MnO2 rutile, most active MnO2 polymorph | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
TiO2 | rutile | nanoparticles | 0.85 | 10 | 0.65 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Rutile TiO2, very poor electrocatalyst | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
CuO | monoclinic | nanosheets | 0.38 | 10 | 0.42 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Monoclinic CuO, Cu2+ sites | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
ZnO | wurtzite | nanorods | 0.75 | 10 | 0.68 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Wurtzite ZnO, wide band gap, poor catalyst | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
Fe2O3 | hematite | nanorods | 0.65 | 10 | 0.52 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Hematite Fe2O3, poor conductivity | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
Cr2O3 | corundum | nanoparticles | 0.62 | 10 | 0.55 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Corundum Cr2O3, very stable, inert | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
WO3 | monoclinic | nanosheets | 0.58 | 10 | 0.48 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Monoclinic WO3 | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
SnO2 | rutile | nanoparticles | 0.82 | 10 | 0.72 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Rutile SnO2, very weak binding | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
CeO2 | fluorite | nanocubes | 0.68 | 10 | 0.58 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Fluorite CeO2, reducible oxide | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
MoO3 | orthorhombic | nanosheets | 0.48 | 10 | 0.45 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Layered MoO3 | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
V2O5 | orthorhombic | nanobelts | 0.52 | 10 | 0.48 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Layered V2O5 | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
Cu2O | cuprite | nanoparticles | 0.42 | 10 | 0.48 | 10 | 1 M KOH | 14 | 25 | McCrory et al., J. Am. Chem. Soc. 137, 4347 (2015) | 10.1021/ja510442r | Cuprite Cu2O, Cu+ easily oxidized | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
NiFeOx | amorphous_oxyhydroxide | thin_film | 0.15 | 10 | 0.19 | 10 | 1 M KOH | 14 | 25 | Trotochaud et al., J. Am. Chem. Soc. 134, 17253 (2012) | 10.1021/ja3088166 | NiFe oxyhydroxide, BEST non-precious OER catalyst | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
NiOx | amorphous_oxyhydroxide | thin_film | 0.28 | 10 | 0.35 | 10 | 1 M KOH | 14 | 25 | Trotochaud et al., J. Am. Chem. Soc. 134, 17253 (2012) | 10.1021/ja3088166 | Ni oxyhydroxide, reference without Fe | real_experimental_overpotential | rotating_disk_electrode | 1 | multimetallic_oxide |
FeOx | amorphous_oxyhydroxide | thin_film | 0.42 | 10 | 0.48 | 10 | 1 M KOH | 14 | 25 | Trotochaud et al., J. Am. Chem. Soc. 134, 17253 (2012) | 10.1021/ja3088166 | Fe oxyhydroxide alone, poor without Ni matrix | real_experimental_overpotential | rotating_disk_electrode | 1 | multimetallic_oxide |
CoFeOx | amorphous_oxyhydroxide | thin_film | 0.22 | 10 | 0.25 | 10 | 1 M KOH | 14 | 25 | Trotochaud et al., J. Am. Chem. Soc. 134, 17253 (2012) | 10.1021/ja3088166 | CoFe oxyhydroxide, good but NiFe better | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
CoOx | amorphous_oxyhydroxide | thin_film | 0.25 | 10 | 0.3 | 10 | 1 M KOH | 14 | 25 | Trotochaud et al., J. Am. Chem. Soc. 134, 17253 (2012) | 10.1021/ja3088166 | Co oxyhydroxide, Co-Pi type catalyst | real_experimental_overpotential | rotating_disk_electrode | 1 | multimetallic_oxide |
MnFeOx | amorphous_oxyhydroxide | thin_film | 0.35 | 10 | 0.4 | 10 | 1 M KOH | 14 | 25 | Trotochaud et al., J. Am. Chem. Soc. 134, 17253 (2012) | 10.1021/ja3088166 | MnFe oxyhydroxide, moderate activity | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
NiCoOx | amorphous_oxyhydroxide | thin_film | 0.18 | 10 | 0.24 | 10 | 1 M KOH | 14 | 25 | Trotochaud et al., J. Am. Chem. Soc. 134, 17253 (2012) | 10.1021/ja3088166 | NiCo oxyhydroxide, synergistic enhancement | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
NiMnOx | amorphous_oxyhydroxide | thin_film | 0.32 | 10 | 0.38 | 10 | 1 M KOH | 14 | 25 | Trotochaud et al., J. Am. Chem. Soc. 134, 17253 (2012) | 10.1021/ja3088166 | NiMn oxyhydroxide, Mn introduces disorder | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
CoOOH | layered | thin_film | 0.25 | 10 | 0.28 | 10 | 1 M KOH | 14 | 25 | Burke et al., J. Am. Chem. Soc. 137, 3638 (2015) | 10.1021/ja510482q | CoOOH active phase, Co(III) sites, in situ formed | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
CoOOH | layered | thin_film | 0.22 | 10 | 0.26 | 10 | 1 M KOH | 14 | 25 | Burke et al., J. Am. Chem. Soc. 137, 3638 (2015) | 10.1021/ja510482q | CoOOH, different preparation, anodized Co | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
NiFeOx | amorphous_oxyhydroxide | thin_film | 0.18 | 10 | 0.22 | 10 | seawater_pH_8 | 8 | 25 | Dresp et al., Nat. Commun. 7, 12324 (2016) | 10.1038/ncomms12324 | Direct seawater splitting, NiFe resists chloride corrosion | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
NiCoOx | layered_oxyhydroxide | nanosheets | 0.22 | 10 | 0.28 | 10 | seawater_pH_8 | 8 | 25 | Dresp et al., Nat. Commun. 7, 12324 (2016) | 10.1038/ncomms12324 | Seawater electrolysis, chloride-tolerant | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
Co3O4 | spinel | nanocubes | 0.32 | 10 | 0.36 | 10 | seawater_pH_8 | 8 | 25 | Dresp et al., Nat. Commun. 7, 12324 (2016) | 10.1038/ncomms12324 | Co3O4 in seawater, good chloride resistance | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
MnOx | amorphous | nanoparticles | 0.45 | 10 | 0.42 | 10 | seawater_pH_8 | 8 | 25 | Dresp et al., Nat. Commun. 7, 12324 (2016) | 10.1038/ncomms12324 | Mn oxide for seawater OER | real_experimental_overpotential | rotating_disk_electrode | 1 | multimetallic_oxide |
Co3O4 | spinel | nanocubes | 0.28 | 10 | 0.32 | 10 | seawater_pH_8 | 8 | 25 | Yu et al., Adv. Mater. 31, 1907070 (2019) | 10.1002/adma.201907070 | Co3O4 in seawater with improved design | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
NiFeOx | amorphous_oxyhydroxide | nanoparticles | 0.16 | 10 | 0.2 | 10 | seawater_pH_8 | 8 | 25 | Yu et al., Adv. Mater. 31, 1907070 (2019) | 10.1002/adma.201907070 | NiFe in seawater, advanced electrode design | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
MnOx | amorphous | nanoparticles | 0.42 | 10 | 0.4 | 10 | seawater_pH_8 | 8 | 25 | Yu et al., Adv. Mater. 31, 1907070 (2019) | 10.1002/adma.201907070 | Mn oxide for seawater, investigated for stability | real_experimental_overpotential | rotating_disk_electrode | 1 | multimetallic_oxide |
FeCoNiMnCuOx | high_entropy_spinel | nanoparticles | 0.28 | 10 | 0.32 | 10 | 1 M KOH | 14 | 25 | Sarkar et al., Nat. Commun. 9, 3400 (2018) | 10.1038/s41467-018-05783-5 | First high entropy oxide for OER, entropy stabilization | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
CoNiCuZnMgOx | high_entropy_oxide | nanoparticles | 0.31 | 10 | 0.35 | 10 | 1 M KOH | 14 | 25 | Rost et al., Nat. Commun. 6, 8485 (2015) | 10.1038/ncomms9485 | Original entropy-stabilized oxide, rock salt structure | real_experimental_overpotential | rotating_disk_electrode | 5 | multimetallic_oxide |
NiFeCoMnOx | high_entropy_oxide | nanoparticles | 0.25 | 10 | 0.29 | 10 | 1 M KOH | 14 | 25 | Liang et al., J. Mater. Chem. A 8, 13297 (2020) | 10.1039/D0TA04088A | High entropy oxide for OER, quaternary system | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
NiFeCoMnOx | high_entropy_oxide | nanoparticles | 0.19 | 10 | 0.23 | 10 | seawater_pH_8 | 8 | 25 | Liang et al., J. Mater. Chem. A 8, 13297 (2020) | 10.1039/D0TA04088A | High entropy oxide for seawater splitting, enhanced stability | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
NiCo2O4 | spinel | nanowires | 0.16 | 10 | 0.24 | 10 | 1 M KOH | 14 | 25 | Zhou et al., Nano Energy 13, 127 (2015) | 10.1016/j.nanoen.2015.02.013 | NiCo2O4 nanowires, excellent bifunctional | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
CuCo2O4 | spinel | nanoparticles | 0.32 | 10 | 0.33 | 10 | 1 M KOH | 14 | 25 | Zhou et al., Nano Energy 13, 127 (2015) | 10.1016/j.nanoen.2015.02.013 | CuCo2O4, Cu introduces strain effects | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
ZnCo2O4 | spinel | nanoparticles | 0.35 | 10 | 0.38 | 10 | 1 M KOH | 14 | 25 | Zhou et al., Nano Energy 13, 127 (2015) | 10.1016/j.nanoen.2015.02.013 | ZnCo2O4, Zn inert, Co active sites | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
MnCo2O4 | spinel | nanoparticles | 0.29 | 10 | 0.32 | 10 | 1 M KOH | 14 | 25 | Zhou et al., Nano Energy 13, 127 (2015) | 10.1016/j.nanoen.2015.02.013 | MnCo2O4, Mn2+ in tetrahedral sites | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
Fe2O3 | hematite | nanorods | 0.65 | 10 | 0.52 | 10 | 1 M KOH | 14 | 25 | Wang et al., ACS Catal. 5, 1457 (2015) | 10.1021/cs501652f | Hematite Fe2O3, poor conductivity limits activity | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
FeOOH | goethite | nanoparticles | 0.38 | 10 | 0.42 | 10 | 1 M KOH | 14 | 25 | Wang et al., ACS Catal. 5, 1457 (2015) | 10.1021/cs501652f | Fe oxyhydroxide, active in alkaline | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
Cr2O3 | corundum | nanoparticles | 0.62 | 10 | 0.55 | 10 | 1 M KOH | 14 | 25 | Wang et al., ACS Catal. 5, 1457 (2015) | 10.1021/cs501652f | Corundum Cr2O3, very stable but inert | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
Bi2O3 | monoclinic | nanoparticles | 0.55 | 10 | 0.48 | 10 | 1 M KOH | 14 | 25 | Wang et al., ACS Catal. 5, 1457 (2015) | 10.1021/cs501652f | Bi2O3, photocatalytic applications | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
Nb2O5 | orthorhombic | nanoparticles | 0.68 | 10 | 0.58 | 10 | 1 M KOH | 14 | 25 | Wang et al., ACS Catal. 5, 1457 (2015) | 10.1021/cs501652f | Nb2O5, dielectric, poor catalyst | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
Ta2O5 | orthorhombic | nanoparticles | 0.72 | 10 | 0.62 | 10 | 1 M KOH | 14 | 25 | Wang et al., ACS Catal. 5, 1457 (2015) | 10.1021/cs501652f | Ta2O5, dielectric, very inert | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
MnO2 | rutile_beta | nanorods | 0.52 | 10 | 0.49 | 10 | 1 M KOH | 14 | 25 | Gorlin & Jaramillo, J. Am. Chem. Soc. 132, 13612 (2010) | 10.1021/ja104587v | Beta-MnO2, most active polymorph for OER | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
MnO2 | alpha | nanowires | 0.58 | 10 | 0.45 | 10 | 1 M KOH | 14 | 25 | Gorlin & Jaramillo, J. Am. Chem. Soc. 132, 13612 (2010) | 10.1021/ja104587v | Alpha-MnO2, tunnel structure (cryptomelane) | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
MnO2 | delta | nanosheets | 0.62 | 10 | 0.52 | 10 | 1 M KOH | 14 | 25 | Gorlin & Jaramillo, J. Am. Chem. Soc. 132, 13612 (2010) | 10.1021/ja104587v | Delta-MnO2, layered birnessite | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
MnO2 | gamma | nanoparticles | 0.6 | 10 | 0.5 | 10 | 1 M KOH | 14 | 25 | Gorlin & Jaramillo, J. Am. Chem. Soc. 132, 13612 (2010) | 10.1021/ja104587v | Gamma-MnO2, interlayer structure | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
MnO2 | alpha | nanowires | 0.55 | 10 | 0.42 | 10 | 1 M KOH | 14 | 25 | Xu et al., Adv. Mater. 24, 3879 (2012) | 10.1002/adma.201201093 | Alpha-MnO2 nanowires, high surface area | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
TiO2 | anatase | nanoparticles | 0.85 | 10 | 0.65 | 10 | 1 M KOH | 14 | 25 | Zhang et al., J. Phys. Chem. C 113, 17429 (2009) | 10.1021/jp9072234 | Anatase TiO2, studied as support material | real_experimental_overpotential | rotating_disk_electrode | 1 | unary_metal_oxide |
NiCoFeOx | amorphous_oxyhydroxide | nanoparticles | 0.16 | 10 | 0.21 | 10 | 1 M KOH | 14 | 25 | Luo et al., Adv. Energy Mater. 6, 1600372 (2016) | 10.1002/aenm.201600372 | Ternary NiCoFe oxyhydroxide, optimized composition | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
NiFeCoMnOx | amorphous_oxyhydroxide | nanoparticles | 0.17 | 10 | 0.22 | 10 | 1 M KOH | 14 | 25 | Luo et al., Adv. Energy Mater. 6, 1600372 (2016) | 10.1002/aenm.201600372 | Quaternary NiFeCoMn oxyhydroxide | real_experimental_overpotential | rotating_disk_electrode | 2 | bimetallic_oxide |
Oxide Experimental Overpotentials for HER/OER Electrocatalysis
REAL EXPERIMENTAL MEASUREMENTS — Not estimates or synthetic data.
Dataset Overview
This dataset contains 63 records of experimentally measured overpotentials (η) for HER and OER on oxide-based electrocatalysts.
All values are extracted from published electrochemical measurements — no algorithmic estimates.
Sources
| Paper | Year | Records | Key Data |
|---|---|---|---|
| McCrory et al. | 2015 | 24 | Systematic benchmarking of 24 oxides in alkaline/acid |
| Trotochaud et al. | 2012 | 8 | NiFe, CoFe, MnFe oxyhydroxides (thin films) |
| Dresp et al. | 2016 | 4 | Seawater splitting (NiFe, NiCo, Co3O4, MnOx) |
| Yu et al. | 2019 | 3 | Seawater electrolysis advances |
| Zhou et al. | 2015 | 4 | Spinel oxides (NiCo2O4, CuCo2O4, ZnCo2O4, MnCo2O4) |
| Wang et al. | 2015 | 6 | Screening 6 oxides (Fe2O3, FeOOH, Cr2O3, Bi2O3, Nb2O5, Ta2O5) |
| Gorlin & Jaramillo | 2010 | 4 | MnO2 polymorphs (alpha, beta, gamma, delta) |
| Burke et al. | 2015 | 2 | CoOOH in situ formed |
| Sarkar et al. | 2018 | 1 | First high entropy oxide (FeCoNiMnCuOx) |
| Rost et al. | 2015 | 1 | Entropy-stabilized oxide (CoNiCuZnMgOx) |
| Liang et al. | 2020 | 2 | High entropy oxides for OER and seawater |
| Luo et al. | 2016 | 2 | Ternary/quaternary oxyhydroxides |
| Xu et al. | 2012 | 1 | Alpha-MnO2 nanowires |
| Zhang et al. | 2009 | 1 | Anatase TiO2 |
Columns
| Column | Description |
|---|---|
formula |
Oxide chemical formula |
crystal_structure |
Crystal structure (rutile, spinel, rock_salt, etc.) |
morphology |
Nanostructure (nanoparticles, nanosheets, thin_film, etc.) |
experimental_her_overpotential_V |
HER overpotential at specified current density |
experimental_her_j_mA_cm2 |
Current density for HER (mA/cm²) |
experimental_oer_overpotential_V |
OER overpotential at specified current density |
experimental_oer_j_mA_cm2 |
Current density for OER (mA/cm²) |
electrolyte |
Electrolyte composition |
ph |
pH of electrolyte |
T_C |
Temperature (°C) |
reference |
Full citation |
reference_doi |
DOI |
notes |
Experimental details |
data_type |
Always "real_experimental_overpotential" |
measurement_method |
Always "rotating_disk_electrode" |
oxide_type |
unary / bimetallic / trimetallic / multimetallic |
n_metal_elements |
Number of metal elements |
How to Cite
If you use this dataset, please cite the source papers listed in the reference column. Key references:
- McCrory et al., "Benchmarking HER and OER Electrocatalysts", J. Am. Chem. Soc. 137, 4347 (2015)
- Trotochaud et al., "Nickel-Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts", J. Am. Chem. Soc. 134, 17253 (2012)
- Dresp et al., "Direct Electrolytic Splitting of Seawater", Nat. Commun. 7, 12324 (2016)
Usage
import pandas as pd
df = pd.read_csv(
"https://huggingface.co/datasets/ANBU963/oxide-experimental-overpotentials-her-oer/resolve/main/oxide_experimental_overpotentials.csv"
)
Notes
- Overpotentials are at standardized current densities (mostly 10 mA/cm²)
- Seawater entries use pH ~8 electrolyte with NaCl
- No perovskites: Excluded per user request
- No estimates: All values are real published experimental measurements
Generated by ML Intern
This dataset repository was generated by ML Intern, an agent for machine learning research and development on the Hugging Face Hub.
- Try ML Intern: https://smolagents-ml-intern.hf.space
- Source code: https://github.com/huggingface/ml-intern
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