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===================== Product Identification =====================
Product ID:GASOLINE, LEADED (ALL GRADES)
CAGE:JO755
CAGE:3R470
CAGE:JO755
============= Composition/Information on Ingredients =============
Ingred Name:GASOLINE - PRODUCT MIXTURE CONTAINING THE FOLLOWING
HAZARDOUS INGREDIENTS.
CAS:8006-61-9
RTECS #:LX3300000
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:300 PPM/500 STEL
ACGIH TLV:300 PPM/500STEL;9293
Ingred Name:BENZENE (SARA III)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: 0.1-4.9%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1PPM/5STEL;1910.1028
ACGIH TLV:10 PPM; A2; 9293
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:ETHYL BENZENE (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/125 STEL
ACGIH TLV:100 PPM/125STEL 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:CUMENE (SARA III)
CAS:98-82-8
RTECS #:GR8575000
Fraction by Wt: 1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 50 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:1,2,4-TRIMETHYLBENZENE (SARA III)
CAS:95-63-6
RTECS #:DC3325000
Fraction by Wt: <15%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:25 PPM
ACGIH TLV:25 PPM; 9293
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 12%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 15%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS >5G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHALATION: MODERATE RISK OF VAPOR
INTOXICATION. MAJOR RISK IS ENCLOSED SPACES WITH POOR VENTILATION.
SKIN: DEFATTING WITH DRYING AND CRACKING CAN LEAD TO DERMATITIS AND
SECONDARY INFECTION. EYE: IRRI TANT. INGESTION: BURNING OF MOUTH
AND UPPER GI TRACT, VOMITING AND DIARRHEA. PROLONGED OR REPEATED
CONTACT: DERMATITIS.
Explanation of Carcinogenicity:CONTAINS B[71-43-2] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:INHALATION MAY CAUSE EUPHORIA, LUNG IRRITATION
AND EDEMA, HEADACHE, DIZZINESS, DROWSINESS, CONVULSIONS, COMA,
CYANOSIS, GENERALIZED DEPRESSION. INGESTION MAY CAUSE GENERAL
DEPRESSION, SEDATION, RESPIR ATORY DEPRESSION, COMA.
Medical Cond Aggravated by Exposure:MAY AGGRAVATE PRE-EXISTING
DERMATITIS, RESPIRATORY ILLNESS, OR OTHER CONDITIONS WHICH HAVE THE
SAME SYMPTOMS OR EFFECTS AS STATED ABOVE.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH RUNNING WATER FOR 15 MINUTES WHILE HOLDING
EYELIDS OPEN. SKIN: REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH
SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. FOR RESPIRATORY
DISTRESS, GIVE AIR, OXYGEN, OR CPR IF NECESSARY. INGESTION: DO NOT
INDUCE VOMITING. KEEP HEAD BELOW HIPS IF VOMITING OCCURS TO PREVENT
ASPIRATION INTO LUNGS. GET MEDICAL ATTENTION IF REQUIRED IN ALL
CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:>-50F,>-46C
Lower Limits:<1
Upper Limits:8
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE ON FLAMES, BUT SHOULD
BE USED TO KEEP FIRE-EXPOSED CONTAINERS COOL. WATER SPRAY MAY BE
USED TO FLUSH SPILL AWAY FROM AREAS OF IGINTION.
Unusual Fire/Explosion Hazard:HIGHLY VOLATILE MATERIAL. FLOWING
GASOLINE CAN BE IGNITED BY SELF-GENERATED STATIC ELECTRICITY.
VAPORS MAY TRAVEL ALONG THE GROUND TO A REMOTE IGNITION SOURCE.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL: TAKE UP WITH NON COMBUSTIBLE ABSORBENT
SUCH AS FULLERS EARTH OR SAND. PLACE INTO CONTAINERS FOR LATER
DISPOSAL. LARGE: CONTAIN SPILL IN EARTHEN DIKES FOR LATER RECOVERY.
CONTROL IGNITION SOURCE S AROUND SPILL AREA. REPORT SPILLS AS
REQUIRED.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID STATIC IGNITION HAZARD WHEN
TRANSFERRING MATERIAL. KEEP CONTAINERS CLOSED AND AWAY FROM HEAT &
IGNITION SOURCES! DO NOT USE AS CLEANING AGENT.
Other Precautions:EMPTY CONTAINERS RETAIN SOME LIQUID/VAPOR RESIDUES;
HAZARD PRECAUTIONS MUST BE OBSERVED WHEN HANDLING EMPTIES. KEEP OUT
OF REACH OF CHILDREN! DO NOT USE ANY HYDROCARBON FUEL IN SPACES
WITHOUT ADEQUATE VENTILATION. USE ONLY AS A FUEL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR,
SUPPLIED AIR, OR SELF-CONTAINED BREATHING APPARATUS (SCBA) MUST BE
USED WHEN VAPOR CONCENTRATIONS EXCEED THE OCCUPATIONAL EXPOSURE
LIMITS.
Ventilation:USE ADEQUATE VENTILATION TO KEEP VAPOR CONCENTRATIONS OF
THIS MATERIAL BELOW THE OCCUPATIONAL EXPOSURE LIMITS.
Other Protective Equipment:OIL IMPERVIOUS INDUSTRIAL WORK CLOTHING TO
MINIMIZE SKIN CONTACT. EYE BATH AND SAFETY SHOWER RECOMMENDED.
Work Hygienic Practices:USE GOOD PERSONAL HYGIENE. USE WATERLESS HAND
CLEANER TO WASH EXPOSED SKIN. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
THE VARIABLE COMPOSITION MAKES IT IMPOSSIBLE TO SET A SPECIFIC EXPOSURE
LIMIT FOR ALL COMPOSITIONS OF THIS MATERIAL. SPECIFIC EXPOSURE
LIMITS FOR POTENTIAL COMPONENTS SUCH AS BENZENE SHOULD BE APPLIED
BASED ON AIR MONITORING TO ASSURE EMPLOYEES ARE NOT EXPOSED TO
EXCESSIVE VAPOR LEVELS OF COMPONENTS.
================== Physical/Chemical Properties ==================
HCC:F1
Boiling Pt:B.P. Text:>85F,>29C
Vapor Pres:275-437
Vapor Density:>1
Spec Gravity:0.70-0.77
Solubility in Water:SLIGHT
Appearance and Odor:RED-DYED, PINK OR COLORLESS LIQUID; GASOLINE ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:BURNING OR EXCESSIVE HEATING MAY
PRODUCE CARBON MONOXIDE AND OTHER HARMFUL GASES/VAPORS.
==================== Disposal Considerations ====================
Waste Disposal Methods:IT IS THE RESPONSIBILITY OF THE USER TO
DETERMINE IF THE MATERIAL IS A HAZARDOUS WASTE AT THE TIME OF
DISPOSAL. CHECK BEFORE DISPOSING TO BE SURE YOU ARE IN COMPLIANCE
WITH ALL APPLICABLE LAWS AND REG ULATIONS. CHEMTREC/RCRA EMER.
NO.:800-424-9346
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:18937 WB GLS WHT AC EPXY COMP A
Kit Part:Y
CAGE:4N775
CAGE:4N775
============= Composition/Information on Ingredients =============
Ingred Name:ETHYLENE GLYCOL *98-1*
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 1.96%
Other REC Limits:10 MG/CUM
OSHA PEL:50 PPM
ACGIH TLV:C 127 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:PROPANOIC ACID, 2-METHYL, MONOESTER
W/2,2,4-TRIMETHYL-1,3-PENTANEDIOL, TEXANOL(ESTER ALCOHOL)
CAS:25265-77-4
RTECS #:UF6000000
Fraction by Wt: 4.49%
Ingred Name:DIETHYLENE GLYCOL METHYL ETHER, 2-(2-METHOXYETHOXY) ETHANOL
METHYL CARBITOL
CAS:111-77-3
RTECS #:KL6125000
Fraction by Wt: 6.10%
Ingred Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL
CARCINOGEN, IARC GROUP 3)*98-1*
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 24.92%
OSHA PEL:15 MG/CUM
ACGIH TLV:10 MG/CUM (DUST)
Ingred Name:GLYCOL ETHERS
Fraction by Wt: 5.20%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: RESPIRATORY TRACT
IRRITATION & NERVOUS SYSTEM DEPRESSION. SKIN/EYES: MODERATE INJURY
& DERMATITIS. INGESTION: MUCOUS MEMBRANE & GI TRACT IRRITATION.
SOME SOLVENTS MAY CAUSE INJURY TO THE L IVER/KIDNEYS/BONE
MARROW/BLOOD CELLS. OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT
BRAIN & NERVOUS SYSTEM DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, STAGGERING
GAIT, CONFUSION, UNCONSCIOUSNESS, COMA, REDDENING, SWELLING,
DEFATTING.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. KEEP WARM
& QUIET. EYES: FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. SKIN:
WASH W/SOAP & WATER. INGESTION: DON'T INDUCE VOMITING. OBTAIN
MEDICAL A TTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:186F
Lower Limits:0.6
Extinguishing Media:CO2, DRY CHEMICAL/FOAM.
Fire Fighting Procedures:DON'T USE WATER EXCEPT FOR COOLING CLOSED
CONTAINERS. USE FOG NOZZLES IF WATER IS USED. FIREFIGHTERS SHOULD
BE EQUIPPED W/MASKS & SELF CONTAINED RESPIRATORS.
Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID. CLOSED CONTAINER MAY
EXPLODE WHEN EXPOSED TO EXTREME HEAT. DON'T APPLY TO HOT SURFACES.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE SOURCES OF IGNITION. AVOID BREATHING
VAPORS. VENTILATE AREA. REMOVE W/INERT ABSORBENT & NON SPARKING
TOOLS.
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T STORE >120F. STORE LARGE AMOUNTS
IN BUILDINGS DESIGNED & PROTECTED FOR STORAGE. AVOID FREE FALL OF
LIQUID IN EXCESS OF A FEW INCHES.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. DON'T TAKE INTERNALLY.
CONTAINERS SHOULD BE GROUNDED WHEN POURING. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING & INHALING THE CONTENTS OF THIS
CONTAINER MAY BE HARM FUL/FATAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN OPEN AREAS, USE NIOSH/MSHA APPROVED
MECHANICAL FILTER RESPIRATOR DURING SPRAY APPLICATION/IN RESTRICTED
AREAS, USE NIOSH/MSHA APPROVED CHEMICAL MECHANICAL FILTERS/IN
CONFINED AREAS, USE NIOSH/MSHA APPROVED AIR LINE TYPE
RESPIRATOR/HOODS.
Ventilation:GENERAL DILUTION/LOCAL EXHAUST TO KEEP TLV BELOW ACCEPTABLE
LIMITS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. DESTROY CONTAMINATED SHOES. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:380-474F
Vapor Density:>1
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:64.33
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:EXTREME HEAT.
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:BERYLLIUM AA STANDARD,AA 125
Preparer's Name:E. BRULL
CAGE:63415
CAGE:63415
============= Composition/Information on Ingredients =============
Ingred Name:BERYLLIUM (SARA 313) (CERCLA)
CAS:7440-41-7
RTECS #:DS1750000
Fraction by Wt: 0.1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.002 MG/M3, Z-2
ACGIH TLV:.002 MG/M3, A2; 9596
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 98.5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT RELEVANT
ACGIH TLV:NOT RELEVANT
Ingred Name:NITRIC ACID (SARA 302/313) (CERCLA)
CAS:7697-37-2
RTECS #:QU5775000
Fraction by Wt: 1.4%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 PPM
ACGIH TLV:2 PPM/4 STEL; 9596
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:TLV 5 MG/M3 (NITRIC ACID)
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY
& GI TRACTS. ACUTE- CORROSIVE. INHALE:MAY CAUSE INFLAMMATION,
CHOCKING, COUGHING, LUNG DAMAGE. EYE/SKIN:SEVERE BURNS. MAY CAUSE
PERMANENT EYE DAMAGE. ORAL:IMMEDIA TE PAIN & BURNS OF MOUTH,
THROAT, ESOPHAGUS & GI TRACT. MAY BE FATAL IF INHALED/INGESTED.
CHRONIC- EROSION OF TEETH.
Explanation of Carcinogenicity:CONTAINS BERYLLIUM.
Effects of Overexposure:SEVERE IRRITATION, BURNS, COUGHING, DIFFICULT
BREATHING, CHEST PAIN, ABDOMINAL PAIN, NAUSEA, VOMITING, DENTAL
EROSION, CHOCKING, ULCERATION, EYE DAMAGE, DEATH
Medical Cond Aggravated by Exposure:DAMAGED SKIN, EYE DISORDERS,
LUNG/RESPIRATORY SYSTEM DISEASES
======================= First Aid Measures =======================
First Aid:GET MEDICAL CARE IMMEDIATELY IN ALL CASES.
EYES/SKIN:IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES.
KEEP EYELIDS OPEN. TREAT FOR CHEMICAL BURNS IF NECESSARY.
INHALATION:MOVE TO FRESH AIR. PROVI DE CPR/OXYGEN IF NEEDED.
ORAL:IF CONSCIOUS & FREE FROM CONVULSION, DRINK LARGE AMOUNT OF
WATER OR MILK. DO NOT INDUCE VOMITING. DO NOT TAKE CARBONATES
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:NOT RELEVANT
Upper Limits:NOT RELEVANT
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:CONTAINER MAY RUPTURE.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROPER PROTECTIVE EQUIPMENT. VENTILATE
AREA. REMOVE IGNITION SOURCES (H2 MAY BE PRESENT). DO NOT RELEASE
INTO SOIL, SEWER. USE AN ABSORBENT SUCH AS SAND/VERMICULITE.
TRANSFER TO A SUITABLE CONTAI NER FOR DISPOSAL. PREVENT ENTRY INTO
SEWERS.
Neutralizing Agent:SODA ASH, LIME, SODIUM BICARBONATE
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, WELL-VENTILATED,
CORROSION-PROOF AREA, AWAY FROM INCOMPATIBLE MATERIALS. KEEP OUT OF
REACH OF CHILDREN.
Other Precautions:CORROSIVE. DO NOT GET IN EYES, ON SKIN OR ON
CLOTHING. AVOID BREATHING VAPORS/MIST. USE UNDER THE HOOD WITH
ADEQUATE VENTILATION. PROTECT CONTAINERS AGAINST PHYSICAL DAMAGE.
WASH THOROUGHLY AFTER HAND LING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY
AND HEALTH (NIOSH) APPROVED SELF-CONTAINED BREATHING APPARATUS
OPERATED IN POSITIVE PRESSURE MODE WHEN PERMISSIBLE EXPOSURE LIMITS
ARE EXCEEDED.
Ventilation:PROVIDE GENERAL VENTILATION OR LOCAL EXHAUST TO MEET OSHA
PERMISSIBLE EXPOSURE LIMITS (OSHA PEL).
Other Protective Equipment:USE RUBBER SPLASH APRON AND RUBBER BOOTS.
EYEWASH AND SAFETY SHOWER SHOULD BE LOCATED NEARBY.
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH BEFORE EATING OR DRINKING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:C1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:180.7F HNO3
Vapor Pres:17.92 @68F
Vapor Density:0.62;WATER
Spec Gravity:1
pH:NEUT1%
Solubility in Water:SOLUBLE
Appearance and Odor:LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
METALS, BASES, REDUCING AGENTS, COMBUSTIBLES, ORGANIC MATERIALS
Stability Condition to Avoid:EXCESSIVE HEAT
==================== Disposal Considerations ====================
Waste Disposal Methods:OBSERVE FEDERAL, STATE AND LOCAL ENVIRONMENTAL
REGULATORS FOR PROPER DISPOSAL. CONSIDER RECYCLING OR CONTRACT WITH
A LICENSED DISPOSAL AGENCY.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:CAT, MIL-C-46168D, 33538, TYPE II, A PC 03Y
Kit Part:Y
CAGE:5M511
CAGE:33461
CAGE:5M511
============= Composition/Information on Ingredients =============
Ingred Name:ALIPHATIC ISOCYANATE (FREE MONOMR CONTENT LESS THAN 0.7%
BASED ON RESIN SOLIDS AT TIME OF MFR. AFTER 3-6 MO STORAGE *
CAS:28182-81-2
RTECS #:HQ9170000
Fraction by Wt: 75%
Other REC Limits:MOBAY 0.02PPM (CEIL)
Ingred Name:** FREE MONOMER CONTENT MAY RISE TO 1.6% MAX. ACGIH TLV
0.005 PPM TWA [NOTICE OF INTENDED CHANGES 1987-88])
RTECS #:9999999ZZ
Other REC Limits:NONE SPECIFIED
Ingred Name:N-BUTYL ACETATE (SARA III) (VAPOR PRESSURE 8.4 MM HG)
CAS:123-86-4
RTECS #:AF7350000
Fraction by Wt: 15%
Other REC Limits:NONE SPECIFIED
OSHA PEL:150 PPM/200 PPM STEL
ACGIH TLV:150 PPM/200 PPM STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:XYLENE (SARA III) (VAPOR PRESSURE 21 MM HG)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 10%
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM/150 PPM STEL
ACGIH TLV:100 PPM/150 PPM STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ETHYL BENZENE (SARA III) (VAPOR PRESSURE 7.1 MM HG)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM/125 PPM STEL
ACGIH TLV:100 PPM/125 PPM STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:VOC: 264 G/L
RTECS #:9999999VO
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL: RESP TRACT IRRIT, ACUTE NERV
SYS DEPRESS. SKIN: IRRIT, DEFATTING. EYE: IRRIT. INGEST: IRRIT,
CORROSIVE ACTION IN MOUTH, STOMACH, DIGEST TRACT. VOMITING MAY
CAUSE ASPIRATION OF SOLVENT, RESULT I N CHEM PNEUMONITIS. ACUTE:
EYES/NOSE/THROAT IRRIT. CHRONIC: SOME INDIVIDUALS WILL DEVELOP
ISOCYANATE SENSITIZATION
Explanation of Carcinogenicity:N/K WHICH WILL CAUSE THEM TO REACT TO A
LATER EXPOSURE OF ISOCYANATE LEVELS WELL BELOW THE TLV OF
ISOCYANATES.
Effects of Overexposure:INHAL: CNS: HEADACHE, DIZZINESS, STAGGERING,
CONFUSION, UNCONSCIOUSNESS, COMA. SKIN: SWELLING, REDNESS, RASH,
DRYING, CRACKING SKIN. EYE: TEARING, REDNESS, SWELLING W/STINGING.
ACUTE: HEADACHES, DIFFI CULT BREATHING, LOSS OF CONSCIOUSNESS.
Medical Cond Aggravated by Exposure:ASTHMA AND ANY OTHER RESPIRATORY
DISORDERS. SKIN ALLERGIES, ECZEMA AND DERMATITIS. ISOCYANATE
SENSITIZATION.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. RESTORE BREATHING. ASTHMATIC TYPE
SYMPTOMS MAY DEVELOP IMMED/DELAYED. GET MED AID. SKIN: REMOVE
CONTAM CLOTHING. WASH THOROUGHLY W/SOAP & WATER. WASH CONTAM
CLOTHING BEFORE REUSE. EYES: FLUSH W/CLEAN LUKEWARM WATER (LOW
PRESSURE) FOR AT LEAST 15 MIN, OCCAS LIFTING EYELIDS. GET MED AID.
INGEST: DO NOT INDUCE VOMIT. DO NOT GIVE ANYTHING TO UNCONSCIOUS
PERSON. GET MED AID.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:67.0F,19.4C
Lower Limits:1%
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:WEAR FULL FIRE FIGHT EQUIP W/SCBA & FULL
PROTECT CLOTH. USE WATER TO COOL CLSD CNTNRS TO PREVENT PRESS
BLDUP/AUTO IGNIT/EXPLOS. HDI/IRRIT VAPOR DURING COMBUST.
Unusual Fire/Explosion Hazard:KEEP CNTNR CLSD. ISOLATE FROM HEAT/IGNIT
SOURCE. CLSD CNTNR MAY EXPLODE W/HEAT. APPLIC TO HOT SRFCS REQUIRES
SPCL PRECAUTION. OVEXPOS TO DECOMP PROD-HEALTH HZD.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE
ALL SOURCES OF IGNITION (FLAME, SPARK SOURCES, HOT SURFACES).
VENTILATE AREA. CONTAIN AND REMOVE WITH INERT ABSORBENT AND
NON-SPARKING TOOLS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN WELL VENTED BLDG IN
COMPLIANCE W/ OSHA 1910.106. AVOID STORING NEAR HIGH TEMPS, FIRE,
OPEN FLAMES, AND SPARK SOURCES. STORE IN CLOSED CNTNRS.
Other Precautions:KEEP CNTNR TIGHT/UPRIGHT (PREVENT LEAK). PREVENT
PROLONG BREATH (VAPOR/SPRAY MIST). OVEREXPOS MAY CAUSE ALLERGIC
REACTION. AVOID CONTACT W/SKIN & EYE. DON'T EAT. DON'T HANDLE TILL
MFR PRECAUTION READ/ UNDERSTOOD. SMOKE IN SMOKING AREAS ONLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE RSPRTR FOR ORGANIC VAPOR ENVIRONMENT (AIR
PURIFYING/FRESH AIR SUPPLIED). OBSERVE REGS--RESP USE. PROVIDE VENT
TO KEEP EXPOS BELOW PEL. VAPOR PARTIC FULL FACE RSPRTR (TC23C)
WHERE AIR MONITOR DEMON STRATES EXPOS BELOW 10X EXPOS LIMITS.
Ventilation:EXHAUST VENT SUFF TO KEEP AIRBORNE SOLVENT/HDI/
POLYISOCYANATES CONC BELOW TLV. CONSIDER ADDITIVE TOXIC EFFECTS
COND.
Other Protective Equipment:USE LONG SLEEVE AND LONG LEG CLOTHING IS
RECOMMENDED. REMOVE & WASH CONTAMINATED CLOTHING BEFORE REUSE.
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING OR USING
WASHROOM.
Supplemental Safety and Health
KEY1;F5. REMOVE ALL IGNITION SOURCES (SPARKS, HEAT, FLAME AND HOT
SURFACES).
================== Physical/Chemical Properties ==================
HCC:F5
Boiling Pt:B.P. Text:260 TO 282F
Vapor Density:> AIR.
Spec Gravity:1.06
Viscosity:**
Evaporation Rate & Reference:0.72 X N-BUTYL ACETATE.
Solubility in Water:INSOLUBLE.
Appearance and Odor:AMBER LIQUID WITH SOLVENT ODOR.
Percent Volatiles by Volume:30.5%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS AND SURFACE
ACTIVE MATERIALS.
Stability Condition to Avoid:CONTACT WITH MOISTURE, MATERIAL WHICH
REACT WITH ISOCYANATES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:BY HIGH HEAT/TEMPERATURE: CARBON
MONOXIDE, CARBON DIOXIDE, AND OXIDES OF NITROGEN, TRACES OF HCN AND
HDI.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE MUST BE DISPOSED OF IN ACCORDANCE W/FED,
STATE & LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS
MUST BE HANDLED W/CARE, DUE TO PRODUCT RESIDUE & FLAMMABLE VAPOR.
DO NOT INCINERATE CLO SED CNTNR. EPA HAZARDOUS WASTE # D001, F003,
F005.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:HYDROCHLORIC ACID, TECHNICAL 20 BAUME'
CAGE:DO735
CAGE:DO735
CAGE:0STM5
============= Composition/Information on Ingredients =============
Ingred Name:HYDROCHLORIC ACID (SARA 302/313) (CERCLA)
CAS:7647-01-0
RTECS #:MW4025000
Fraction by Wt: 31.5%
OSHA PEL:5 PPM, C
ACGIH TLV:5 PPM, C
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: BALANCE
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:FIRST AID:AIR. IF NOT BRTHG, GIVE MOUTH-TO-MOUTH
RESUSCITATION. IF BRTHG IS DFCLT, GIVE OXYG. CALL MD. NOTE TO (ING
4)
RTECS #:9999999ZZ
Ingred Name:ING 3:PHYSICIAN: CORR. MAY CAUSE STRICTURE. IF LAVAGE IS
PERFORMED, SUGGEST ENDOTRACHEAL &/ESOPHAGOSCOPIC CTRL. (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4:IF BURN IS PRESENT, TREAT AS ANY THERMAL BURN, AFTER
DECONTAMINATION. NO SPECIFIC ANTIDOTE. SUPPORTIVE (ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5:CARE. TREATMENT BASED ON JUDGEMENT OF THE PHYSICIAN
IN RESPONSE TO REACTIONS OF THE PATIENT.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: MAY CAUSE PAIN,
LACHRYMATION(TEARS), AND SEV IRRIT W/CORNEAL INJURY WHICH MAY
RESULT IN PERM IMPAIRMENT OF VISION, EVEN BLNDNESS. SKIN CONT:
SHORT SINGLE EXPOS MAY CAUSE SEV SKIN BURNS. SKIN ABSO RPTION: A
SINGLE PLNGD EXPOS IS NOT LIKELY TO RESULT IN THE MATL BEING
ABSORBED THROUGH SKIN IN (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:HARMFUL AMTS. THE DERMAL LD50 HAS NOT
BEEN DETERMINED. INGEST: MAY CAUSE GI IRRIT/ULCERATION AND SEV
BURNS OF THE MOUTH AND THROAT. INHAL:EXCESSIVE VAP CONCS ARE
READILY ATTAINABLE AND MAY CA USE SERIOUS ADVERSE EFTS, EVEN DEATH.
EXCESSIVE EXPOS MAY CAUSE SEV IRRIT & INJURY TO UPPER RESP TRACT &
LUNGS. (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: IMMED & CONTINUOUS IRRIGATION W/FLOWING H*2O @ LST 30
MINS IS IMPERATIVE. PROMPT MED CONSULTATION IS ESSENTIAL. SKIN:
IMMED CONTINUED AND THOROUGH WASHING IN FLOWING H*2O FOR 30 MINS IS
IMPERATI VE WHILE REMOVING CONTAMD CLTHG. PROMPTMED CONSULTATION
ESSENTIAL. INGEST: DO NOT INDUCE VOMIT. GIVE LRG AMTS OF H*2O/MILK
IF AVAILABLE AND TRANSPORT TO MED FACILITY. INHAL: REMOVE TO FRESH
(ING 3)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:NONE
Extinguishing Media:NON-FLAMMABLE. MEDIA SUITABLE FOR SURROUNDING FIRE
.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:HYDROCHLORIC ACID ITSELF IS
NON-FLAMMABLE. THERE IS, HOWEVER, A LATENT FIRE OR EXPLOSION HAZ
DUE TO HYDROGEN GAS GENERATED WHEN ACID IS IN CONTACT W/METALS.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL QUANTITIES MAY BE FLUSHED W/COPIOUS
QTIES OF H*2O; IN CASE OF LGR AMTS, CONTAIN LIQ. USE LIMESTONE,
LIME/SODA ASH TO CAUTIOUSLY NEUTRALIZE SINCE CONSIDERABLE AMTS OF
HEAT AND STEAM MAY BE GENERA TED ON NEUTRALIZATION.
Neutralizing Agent:LIMESTONE, LIME/SODA ASH.
======================Handling and Storage ======================
Handling and Storage Precautions:PREVENT ALL CONTACT WITH EYES AND
SKIN. AVOID BREATHING IRRITATING VAPORS.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHEN AIRBORNE EXPOS GUIDELINES &/COMFORT LEVELS
MAY BE EXCEEDED, USE A NIOSH APPRVD AIR-PURIFYING RESP. FOR
EMERGENCY & OTHER CONDTNS WHERE EXPOS GUIDELINE MAY BE GREATLY
EXCEEDED, USE A NIOSH APPROVE D POSITIVE-PRESSURE SCBA.
Ventilation:CONTROL AIRBORNE CONCS < EXPOS GUIDELINE. USE ONLY W/ADEQ
VENT. LOC EXHST VENT MAY BE NECESSARY FOR SOME OPERATIONS.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
IMPERVIOUS CLTHG,BOOTS, APRON, FULL-BODY SUIT.
Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSE.
DISPOSE OF CONTAMINATED SHOES.
Supplemental Safety and Health
FACESHIELD. EFTS OF OVEREXP: SYSTEMIC AND OTHER EFFECTS: REPEATED
EXCESSIVE EXPOSURE MAY CAUSE EROSION OF TEETH AND BLEEDING AND
ULCERATI ON OF NOSE, MOUTH AND GUMS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:178F,81C
Vapor Pres:SUP DAT
Vapor Density:11.0
Spec Gravity:1.16
Solubility in Water:INFINITE
Appearance and Odor:WHITE TO YELLOW CLEAR LIQUID. A PUNGENT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID BASES AND CORROSIVE MATLS. AVOID CONTACT W/MOST METALS. AVOID
OXIDIZING MATL, CAN OXIDIZE TO CHLORINE.
Stability Condition to Avoid:CONTACT WITH METALS MAY CAUSE GENERATION
OF FLAMM CONCS OF HYDROGEN GAS.
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTACT THE DOW CHEMICAL COMPANY FOR FURTHER
INSTRUCTIONS. DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE
AND LOCAL REGULATIONS .
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: TITE-FIT COATING WHITE, FOSTER 30-35
Cage: GO965
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 0DH19
Cage: GO965
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: DURING NORMAL USE MATERIAL WILL NOT PRESENT EXPOSURE RISK.
ONCE PRODUCT HAS REACHED ITS FINAL STATE & IS ABRADED OR DISTURBED,
DUSTING & EXPOSURE MAY OCCUR. ACUTE:EYES:CONTACT W/PRODUCT OR HIGH VAPOR
LEVELS WILL CAUSE MODERATE IRRITATION. SKIN:LIQUID CONTACT WILL DRY &
DEFAT SKIN. REPEATED OR PROLONGED(EFTS OF OVEREXP)
Explanation Of Carcinogenicity: SEE "LR" VERSION FOR ADDITIONAL INFORMATION
(FP N).
Signs And Symptions Of Overexposure: HLTH HAZ:CONTACT MAY CAUSE IRRITATION
& DERMATITIS. INHALATION:OVEREXPOSURE TO VAPORS IN POORLY VENTILATED
AREAS WILL CAUSE IRRITATION OF NOSE, THROAT & RESPIRATORY TRACT & MAY
CAUSE DIZZINESS, HEADAC HES, NAUSEA OR UNCONSCIOUSNESS. CHRONIC:LONG TERM
OVEREXPOSURE TO SOLVENTS MAY CAUSE LIVER & KIDNEY DAMAGE.
Medical Cond Aggravated By Exposure: NO KNOWN EFFECTS ON OTHER ILLNESSES.
First Aid: INGEST:CALL MD IMMEDIATELY (FP N). EYES:FLUSH IMMEDIATELY W/LARGE
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. CALL MD. SKIN:WASH AFFECTED AREA
W/SOAP & WATER. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. INHAL:REMOVE
FROM EXPOSURE. RESTORE BREATHING IF NECESSARY. KEEP WARM & QUIET. CALL
MD.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: REMOVE ALL SOURCES OF IGNITION. VENTILATE AREA. AVOID
BREATHING VAPORS. DIKE & CONTAIN SPILL W/INERT ABSORBENT & TRANSFER
TO CONTAINER FOR DISPOSAL. USE NON-SPARKING TOOLS. KEEP SPILL OUT OF SEWERS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISP MUST BE I/A/W FED, STATE & LOC REGS (FP N).
THIS PROD MEETS DEFINITION OF HAZ WASTE UNDER U.S. EPA HAZ WASTE REGS 40 CFR
261. IT IS IGNITABLE WASTE CLASS D001. DISP VIA INCIN IS REC. CONSULT YOUR
STATE/LOC AUTHS FOR PROPER DISP IN EVENT (SUPDAT)
Handling And Storage Precautions: STORE IN COMPLIANCE W/OSHA 1910.106. DO NOT
STORE NEAR HEAT, SPARKS OR FLAMES. DRUMS OF THIS MATERIAL SHOULD BE GROUNDED
WHEN POURING.
Other Precautions: COMBUSTIBLE. EYE IRRIT. CONT WILL DRY & DEFAT SKIN. VAPS
HARMFUL. HARMFUL IF SWALLOWED. KEEP AWAY FROM HEAT, SPARKS & FLAME. AVOID
BRTHG VAPS. USE ONLY W/ADEQ VENT. AVOID CONT W/EYES, SKIN & CLTHG. KE EP
CNTNRS CLSD. EMPTIED CNTNR (SUPDAT)
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: SCC
Flash Point Text: 107F,42C
Lower Limits: SEE ING 2
Extinguishing Media: USE WATER SPRAY, FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: THERE IS POSSIBILITY OF PRESSURE BUILDUP IN
CLOSED CONTAINERS WHEN HEATED. WATER SPRAY MAY BE USED TO COOL CONTAINERS.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE NIOSH/MSHA APPROVED EQUIPMENT - ORGANIC VAPOR
RESPIRATORS WHEN AIRBORNE EXPOSURE LIMITS ARE EXCEEDED.
Ventilation: LOCAL EXHAUST VENTILATION PREFERRED. PROVIDE VENTILATION TO
CONTROL CONTAMINATION LEVELS BELOW AIRBORNE EXPOSURE LIMITS.
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI
DESIGN CRITERIA (FP N). PVNT CONT BY USING APPROP PROT CLTHG.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE.
Supplemental Safety and Health: NOTE:USERS OF "L" VERSION SHOULD CONSULT "LR"
VERSION FOR ADDNL INFO (FP N). % VOLAT:61.5 (WT). WASTE DISP METH:MORE
RESTRICTIVE REQUIREMENTS APPLY. FOR ADDNL WASTE DISP ASSISTANCE, CONSULT H.B.
FULLE R ENVIRON SERVICES AT 612/481-1588. OTHER PREC:RETAINS VAP & PROD
RESIDUE. OBSERVE ALL LABELED SAFEGUARDS UNTIL
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >200F,>93C
Vapor Pres: SEE INGS
Spec Gravity: 1.17 (FP N)
Solubility in Water: NON-MISCIBLE
Appearance and Odor: LIQUID.
Percent Volatiles by Volume: SUPDAT
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NOT ESTABLISHED.
Hazardous Decomposition Products: INCOMPLETE COMBUST CAN YIELD LOW MOLECULAR
WEIGHT HYDROCARBONS, CARBON MONOXIDE, CHLORINE COMPOUNDS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: TITE-FIT COATING WHITE, FOSTER 30-35
Cage: GO965
Assigned IND: Y
Company Name: HB FULLER CO
Street: 1200 WOLTERS BLVD
Zipcode: 55110
Label Required IND: Y
Date Of Label Review: 03/07/1996
Status Code: C
Label Date: 03/07/1996
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE:EYES:CONTACT WITH PRODUCT OR HIGH
VAPOR LEVELS WILL CAUSE MODERATE IRRITATION. SKIN:LIQUID CONTACT WILL DRY
& DEFAT SKIN. REPEATED OR PROLONGED CONTACT MAY CAUSE IRRITATION &
DERMAT ITIS. INHALATION:IRRITATION OF RESPIRATORY TRACT, DIZZINESS,
HEADACHES, NAUSEA OR UNCONSCIOUSNESS. CHRONIC:CANCER HAZARD. CONTAINS
MATERIAL WHICH IS LISTED AS AN ANIMAL CARCINOGEN (FP N). MAY DAMAGE L IVER
& KIDNEYS.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:GLYCERINE 10440 BP229-4
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:GLYCERINE, 1,2,3,-TRIHYDROXYPROPANE, GLYCEROL, ANHYDROUS
GLYCERINE, GLYCERIN *97-1*
CAS:56-81-5
RTECS #:MA8050000
Fraction by Wt: 100%
ACGIH TLV:10 MG/CUM (VAPOR)
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): 12,600 MG/KG GLYCERINE
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES/SKIN: MAY CAUSE IRRITATION.
INGESTION: GASTROINTESTINAL IRRITANT. INHALATION: RESPIRATORY
IRRITANT. MAY CAUSE KIDNEY INJURY.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, NAUSEA, VOMITING, DIARRHEA,
HEADACHE
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: FLUSH
W/PLENTY OF SOAP & WATER FOR 15 MINS. INGESTION: IF CONSCIOUS &
ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH
IF UNCONSCIOU S. INHALATION: REMOVE TO FRESH AIR IMMEDIATELY. GIVE
CPR/OXYGEN IF NECESSARY. TREAT SYMPTOMATICALLY & SUPPORTIVELY.
OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:379.4F
Lower Limits:1.1
Extinguishing Media:WATER, DRY CHEMICAL, CHEMICAL
FOAM/ALCOHOL-RESISTANT FOAM
Fire Fighting Procedures:WEAR A SELF CONTAINED BREATHING APPARATUS IN
PRESSURE-DEMAND, MSHA/NIOSH APPROVED & FULL PROTECTIVE GEAR. USE
WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:AUTOIGNITION TEMP: 752F.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB W/INERT MATERIAL, DRY SAND/EARTH. THEN
PLACE INTO CHEMICAL WASTE CONTAINER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA AWAY FROM INCOMPATIBLE SUBSTANCES. USE W/ADEQUATE VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE A NIOSH APPROVED REPIRATOR WHEN NECESSARY.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL
AIRBORNE LEVELS.
Other Protective Equipment:PROTECTIVE CLOTHING
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
INCOMPATIBILITIES CONT'D: PERCHLORIC ACID, LEAD OXIDES.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:554F
Melt/Freeze Pt:M.P/F.P Text:20F
Decomp Temp:Decomp Text:554F
Vapor Pres:0.0025
Vapor Density:3.17
Spec Gravity:1.4746
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAR VISCOUS LIQUID W/BLAND ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, HYDROGEN PEROXIDE, POTASSIUM PERMANGANATE, CALCIUM
HYPOCHLORITE, NITRIC ACID, SULFURIC ACID (SEE SUPP)
Stability Condition to Avoid:EXCESSIVE HEAT, OTHER IGNITION SOURCES
Hazardous Decomposition Products:CO, CO2
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:GELATIN, G73
Resp. Party Other MSDS Num.:ACC 10345
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:GELATIN EINECS/ELINCS: 232-554-6.
CAS:9000-70-8
RTECS #:LX8580000
= Wt:100.
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT AVAILABLE.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: DUST MAY CAUSE MECHANICAL
IRRITATION. SKIN: DUST MAY CAUSE MECHANICAL IRRITATION.
INTRAPERITONEAL INJECTION HAS RESULTED IN FETAL EFFECTS. INGESTION:
LOW HAZARD FOR USUAL INDUSTRIAL HANDLI NG. THE TOXICOLOGICAL
PROPERTIES OF THIS SUBSTANCE HAVE NOT BEEN FULLY INVESTIGATED.
INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION. THE
TOXICOLOGICAL PROPERTIES OF THIS SUBSTANCE HAVE NOT BEEN FU LLY
INVESTIGATED. CHRONIC: INTRAPERITONEAL INJECTION HAS RESULTED IN
FETAL EFFECTS. TARGET ORGANS: NONE.
Explanation of Carcinogenicity:NOT LISTED BY ACGIH, IARC, NIOSH, NTP OR
OSHA.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
First Aid:EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES, OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MEDICAL AID.
SKIN: FLUSH WITH PLENTY OF SOAP & WATER FOR AT LEAST 15 MINUTES
WHILE RE MOVING CONTAMINATED CLOTHING & SHOES. GET MEDICAL AID IF
IRRITATION DEVELOPS OR PERSISTS. INGESTION: IF VICTIM IS CONSCIOUS
& ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. GET MEDICAL AID.
INHALATION: REM OVE FROM EXPOSURE TO FRESH AIR IMMEDIATELY. IF NOT
BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG. GET MED AID IF
COUGH OR OTHER SYMPTOMS APPEAR. NOTES TO MD: TREAT SYMPTOMATICALLY
& SUPPORTIVELY . ANTIDOTE: NO SPECIFIC ANTIDOTE EXISTS.
===================== Fire Fighting Measures =====================
Lower Limits:NOT AVAIL
Upper Limits:NOT AVAIL
Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL, OR CARBON DIOXIDE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:COMBUSTION GENERATES TOXIC FUMES. NFPA
RATING: NOT PUBLISHED.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS
INDICATED IN EXPOSURE CONTROLS, PERSONAL PROTECTION SECTION. SWEEP
UP OR ABSORB MATERIAL, THEN PLACE INTO A SUITABLE CLEAN, DRY,
CLOSED CONTAINER FOR DISPOS AL.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED
AREA AWAY FROM INCOMPATIBLE SUBSTANCES.
Other Precautions:USE WITH ADEQUATE VENTILATION. AVOID CONTACT WITH
SKIN AND EYES. AVOID INGESTION AND INHALATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS
LOW.
FACESHIELD .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN
EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PHYSICAL AND CHEMICAL PROPERTIES: MOLECULAR FORMULA: VARIES. MOLECULAR
WEIGHT: N/P.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Pres:NEGLIGIBLE
Vapor Density:NOT AVAIL
Spec Gravity:0.68 (WATER=1)
pH:6.0 (6% SOLN)
Viscosity:NOT AVAILABLE
Solubility in Water:SOLUBLE
Appearance and Odor:WHITE TO PALE-YELLOW SOLID; NO ODOR REPORTED.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES. AVOID HIGH TEMPERATURES, INCOMPATIBLE MATERIALS.
Hazardous Decomposition Products:CARBON MONOXIDE, OXIDES OF NITROGEN,
CARBON DIOXIDE.
Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED.
=================== Toxicological Information===================
Toxicological Information:CAS # 9000-70-8: RTECS # LX8580000.
EPIDEMIOLOGY: NO INFORMATION AVAILABLE. TERATOGENICITY: EFFECTS ON
NEWBORN: REDUCED WEIGHT GAIN, INTRAPERITONEAL MOUSE TDLO=700 MG/KG.
SPECIFIC DEVELOPMENTAL ABNORM ALITIES: UROGENITAL, INTRAPERITONEAL
MOUSE TDLO=700 MG/KG. REPRODUCTIVE EFFECTS: NO INFORMATION
AVAILABLE. NEUROTOXICITY: NO INFORMATION AVAILABLE. MUTAGENICITY:
PLEASE REFER TO RTECS # LX8580000 FOR SPECIFIC INFORMATION. OTHER
STUDIES: NONE.
===================== Ecological Information =====================
Ecological:ECOTOXICITY: NO INFORMATION AVAILABLE. ENVIRONMENTAL FATE:
NO INFORMATION REPORTED. PHYSICAL/CHEMICAL: NO INFORMATION
AVAILABLE. OTHER STUDIES: NONE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS. RCRA: D-SERIES MAXIMUM CONCENTRATION
OF CONTAMANTS; D-SERIES CHRONIC TOXICITY REFERENCE LEVELS;
F-SERIES; P-SERIES; & U-SER IES: NONE LISTED.
=================== MSDS Transport Information ===================
Transport Information:U.S. DOT: SHIPPING NAME: NO INFORMATION
AVAILABLE. IATA: SHIPPING NAME: NO INFORMATION AVAILABLE. RID/ADR:
SHIPPING NAME: NO INFORMATION AVAILABLE. IMO: SHIPPING NAME: NO
INFORMATION AVAILABLE. CANADA TDG: SHIPPING NAME: NO INFORMATION
AVAILABLE.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ): NONE OF THE CHEMICALS IN
THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ): NONE OF THE CHEMICALS
IN THIS PRODUCT HAVE A TPQ. SECTION 313: NO CHEMICALS ARE
REPORTABLE UNDER SECTION 313.
Federal Regulatory Information:TSCA: CAS #9000-70-8 IS LISTED ON THE
TSCA INVENTORY. HEALTH & SAFETY REPORTING LIST: NONE OF THE CHEMS
ARE ON THE HEALTH & SAFETY REPORTING LIST. CHEM TEST RULES: NONE OF
THE CHEMS IN THIS PROD ARE U NDER A CHEM TEST RULE. SECTION 12B:
NONEOF THE CHEMS ARE LISTED UNDER TSCA SECTION 12B. TSCA
SIGNIFICANT NEW USE RULE: NONE OF THE CHEMS IN THIS MATL HAVE A
SNUR UNDER TSCA. CLEAN AIR ACT: THIS MATL D OES NOT CONTAIN ANY HAZ
AIR POLLUTANTS. THIS MATL DOES NOT CONTAIN ANY CLASS 1 OZONE
DEPLETORS. THIS MATL DOES NOT CONTAIN ANY CLASS 2 OZONE DEPLETORS.
CLEAN WATER ACT: NONE OF THE CHEMS IN THIS PROD ARE LISTED AS(STATE
REGULATORY INFO)
State Regulatory Information:CAS # 9000-70-8 IS NOT PRESENT ON STATE
LISTS FROM CA, PA, MN, MA, FL, OR NJ. CALIFORNIA NO SIGNIFICANT
RISK LEVEL: NONE OF THE CHEMICALS IN THIS PRODUCT ARE LISTED. --
FEDERAL REGULATORY: HAZ SUBSTAN CES UNDER THE CWA. NONE OF THE
CHEMS IN THIS PROD ARE LISTED AS PRIORITY POLLUTANTS UNDER THE CWA.
NONE OF THE CHEMS IN THIS PROD ARE LISTED AS TOXIC POLLUTANTS UNDER
THE CWA. OSHA: NONE OF THE CHEMS IN THIS PROD ARE CONSIDERED
HIGHLY HAZ BY OSHA. EUROPEAN/INTERNATIONAL REGS: EUROPEAN LABELING
I/A/W EC DIRECTIVES: HAZ SYMBOLS: NOT AVAIL. RISK PHRASES: N/P.
SAFETY PHRASES: N/P. WGK (WATER DANGER/PROT): CAS # 9000-70-8: 0.
(OTHER INFO)
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:8700/8790/9700/9790 MICR DEVELOPER, 5R138
CAGE:0E6G9
CAGE:0E6G9
CAGE:26921
============= Composition/Information on Ingredients =============
Ingred Name:IRON NICKEL ZINC OXIDE; (CARRIER) (NI-ZN FERRITE POWDER)
CAS:12645-50-0
RTECS #:NO7118000
Fraction by Wt: >95%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TONER CONSISTING OF INGS 3-6
Fraction by Wt: <5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:STYRENE POLYMER WITH 1/3-BUTADIENE; (STYRENE/BUTADIENE
COPOLYMER)
CAS:9003-55-8
RTECS #:WL6478000
Fraction by Wt: 70-75%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:BLACK IRON OXIDE; (MAGNETITE)
CAS:12227-89-3
Fraction by Wt: 25-30%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:AMORPHOUS SILICA
CAS:112945-86-9
Fraction by Wt: <1%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SILICA GEL; (AMORPHOUS SILICA)
CAS:112945-52-5
RTECS #:VV7310000
Fraction by Wt: <1%
OSHA PEL:6 MG/M3
ACGIH TLV:10 MG/M3
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50(ORAL,RAT):>9G/KG PRACTICALLY NONTOX
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MIN RESP TRACT IRRIT MAY OCCUR AS
W/EXPOS TO LG AMTS OF ANY NON-TOX DUST. IN XEROX SPONSORED CHRONIC
INHAL STUDY IN RATS USING SPECIAL TEST TONER, THERE WERE NO LUNG
CHANGES AT ALL IN LOWEST EXPOS LEV EL (1MG/M3), MOST RELEVANT LEVEL
TO POTNTL HUMAN EXPOS. VERY SLIGHT DEGREE OF FIBROSIS WAS NOTED IN
25%(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:OF ANIMALS AT MIDDLE EXPOS LEVEL
(4MG/M3) WHILE SLIGHT DEGREE OF FIBROSIS WAS OBSERVED AT HIGHEST
EXPOS LEVEL (16MG/M3) IN ALL ANIMALS. THESE FINDINGS ARE ATTRIBUTED
TO "LUNG OVERLOADING," A GENERIC RESPONSE TO EXCESSIVE AMTS OF ANY
DUST RETAINED IN LUNGS FOR PRLNGD INTERVAL. SPECIAL TEST TONER WAS
(SUP DAT)
Medical Cond Aggravated by Exposure:NONE WHEN USED AS DESCRIBED BY
PRODUCT LITERATURE.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SKIN:WASH WITH
SOAP AND WATER. INHALATION:REMOVE FROM EXPOSURE. INGESTION:DILUTE
STOMACH CONTENT WITH SEVERAL GLASSES OF WATER.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . AVOID INHALATION OF SMOKE.
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:IF SPILLED, SWEEP UP OR VACUUM.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN . NONE REQUIRED WHEN USED AS INTENDED.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:FOR USE OTHER THAN NORM CUSTOMER-OPERATING
PROC (SUCH AS IN BULK TONER PROCESSING FACILITIES), GOGGS & RESPS
MAY(SUPDAT)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP:TEN TIMES MORE RESPIRABLE THAN COMMERCIALLY AVAILABLE
XEROX TONER TO COMPLY WITH EPA TESTING PROTOCOL AND WOULD NOT
FUNCTION PROPERLY IN XEROX EQUIPMENT. OTHER PROT EQUIP:BE REQUIRED.
FOR MORE INFORMATION, CONTACT XEROX.
================== Physical/Chemical Properties ==================
Spec Gravity:5 (H*2O=1)
Appearance and Odor:BLACK GRANULAR/FAINT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:AVOID PROLONGED INHALATION OF EXCESSIVE
DUST.
Hazardous Decomposition Products:PRODUCTS OF COMBUSTION MAY BE TOXIC.
AVOID BREATHING SMOKE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHEN DISPOSED, THIS MATERIAL IS NOT A HAZARDOUS
WASTE ACCORDING TO FEDERAL REGULATION 40 CFR 261. HOWEVER, STATE
AND LOCAL REQUIREMENTS MAY BE MORE RESTRICTIVE. THEREFORE,
CONSULTATION WITH APPROP STA TE, LOC & FED WASTE DISP AUTHORITIES
ISADVISED.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SEMSTONE 145 PART A
Kit Part:Y
Preparer's Name:LYNN STAVINOHA
CAGE:0DXD3
CAGE:0DXD3
============= Composition/Information on Ingredients =============
Ingred Name:PROPANE, 1-BUTOXY-2, 3-EPOXY-; (BUTYL GLYCIDYL ETHER)
CAS:2426-08-6
RTECS #:TX4200000
OSHA PEL:50 PPM
ACGIH TLV:25 PPM; 9293
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) 2 GM/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IRRITATION OF THROAT, EYES, SKIN RASH,
HEADACHE. HIGH EXPOSURES: IRRITATION TO SKIN, MAY CAUSE SKIN
SENSITIZER, THROAT, EYES, HEADACHE.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE: WASH REPEATEDLY FOR AT LEAST 15 MINUTES. CALL MD. SKIN:
FLUSH WITH SOAP AND WATER. INHAL: REMOVE TO FRESH AIR. CALL MD IF
BREATHING IS LABORED. INGEST: GIVE MILK OR WATER, INDUCE VOMITING
AND CAL L MD. (NEVER INDUCE VOMITING IN UNCONSCIOUS PERSON).
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:170F,77C
Extinguishing Media:DRY CHEMICAL - CO2, FOAM PREFERRED.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:WHEN MIXED WITH STRONG ACIDS (ORGANIC AND
INORGANIC), STRONG OXIDIZING AGENTS AND BASES.
================== Accidental Release Measures ==================
Spill Release Procedures:SOAK UP WITH SAND OR FLOOR DRIER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT AND FLAMES.
Other Precautions:WHEN SEMSTONE 145 PART A IS MIXED WITH SEMSTONE 145
PART B AND THE RESULTING MIXTURE IS LEFT IN A MASS, SIGNIFICANT
EXOTHERM MAY BE GENERATED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF VAPORS EXCEED TLV'S, USE APPROPRIATE
NIOSH/MSHA APPROVED MASK.
Ventilation:LOCAL EXHAUST AND MECHANICAL EXHAUST.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:V4
Solubility in Water:INSOLUBLE
Appearance and Odor:OFF WHITE WITH SLIGHT AROMATIC ODOR.
Percent Volatiles by Volume:<1/2
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS (ORGANIC OR INORGANIC), STRONG OXIDIZING AGENTS & BASES.
Stability Condition to Avoid:EXCESSIVE HEATING OVER LONG PERIODS OF
TIME DEGRADES THE RESIN, INCREASES VISCOSITY, AND EPOXIDE
EQUIVALENT WEIGHT.
Hazardous Decomposition Products:NONE UNDER NORMAL CONDITIONS.
Conditions to Avoid Polymerization:MASSES OF >1 LB OF PROD PLUS AN
ALIPHATIC AMINE WILL CAUSE IRREVERSIBLE POLYMERIZATION
W/CONSIDERABLE HEAT BUILD-UP.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE CARRIED OUT IN ACCORDANCE WITH
LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:121 6225,EKTAPRINT 2 DEVEL REPLNSHR, PART B
CAGE:19139
CAGE:19139
============= Composition/Information on Ingredients =============
Ingred Name:HYDROXYLAMINE SULFATE; WT % RANGE:8-13%;(THIS DISSOCIATES
TO SULFURIC ACID IN SOLUTION)
CAS:10039-54-0
RTECS #:NC5425000
Fraction by Wt: 10.5%
Ingred Name:AQUEOUS SOLUTION,NON-HAZARDOUS,UNIDENTIFIED COMPONENTS
Fraction by Wt: 89.5%
===================== Hazards Identification =====================
Effects of Overexposure:EYES:IRRITATION;SKIN:REPEATED CONTACT MAY CAUSE
IRRITATION OR ALLERGIC SKIN REACTON.
======================= First Aid Measures =======================
First Aid:EYES,SKIN,MUCOUS MEMBRANES:FLUSH W LG AMTS H*2O AT LEAST 15
MIN;INHALE:REMOVE TO FRESH AIR,KEEP CALM;INGEST:RINSE MOUTH,GET
MEDICAL ATTENTION;FOR EYES OR SKIN REACTION,GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Extinguishing Media:NOT COMBUSTIBLE:USE MEDIA SUITABLE FOR ADJACENT
FIRE.
Fire Fighting Procedures:WEAR SELF-CNTND BRTHG APP;H*2O SPRAY COOL
CONT.
Unusual Fire/Explosion Hazard:CONTANERS MAY RUPTURE IN HEAT OF FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:DO NOT TOUCH SPILLED MATERIAL WEAR PROTECTIVE
EQUIPMENT.STOP LEAK IF POSSIBLE WITHOUT RISK.SM SP:ABSORB W
COMMERCIAL ABSORBENT & PUT IN APPR CONTAINERS.LG SP: CONTAIN W DIKE
& TRANSFER TO APPR CONTAIN ERS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED,LOW
FIRE RISK AREA.PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL
CONTACT.KEEP CONTAINERS TIGHTLY CLOSED.
Other Precautions:AVOID PROLONGED OR REPEATED CONTACT W CHEMICAL.REMOVE
& EASH CONTAMINATED CLOTHING.MAINTAIN STRICT HYGIENE.USE OF
NON-ALKALINE(ACID) TYPE HAND CLEANER REDUCES ALLERGIC SKIN REACTION
RISK.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:APPROVED ORGANIC VAPOR RESPORATOR IF VENTIALTION
IS INADEQUATE
Ventilation:MECHANICAL(GEN./LOCAL EXHAUST) AS NECESSARY TO CONTROL MIST
Other Protective Equipment:NORMAL FULL WORK CLOTHING COVERING
ARMS,LEGS.
Supplemental Safety and Health
ITEM WAS 4 PARTS KIT UNDER CAT NO.121 6225 WHICH WAS CHANGED TO 180
5886 ON OR ABOUT JUN 79.FORMULATION WAS ALSO CHANGED AT THE SAME
TIME.LATER THE NSN WAS CANCLD & REPLACED BY 6750-01-079-9722.ENTRY
DESCRBS PART-B OF OLD CAT #; SEE PNI A,C,&D FOR OTHER PARTS:FOR NEW
FORMULATION SEE PNI E,F,G,&H.KEY1:B2
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres:17
Vapor Density:0.6
Spec Gravity:1.23
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR,WHITE AQUEOUS SOLUTION;ODORLESS
Percent Volatiles by Volume:70
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE NOTED
Stability Condition to Avoid:NONE NOTED
Hazardous Decomposition Products:NONE NOTED
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN FULL ACCORD WITH ALL APPLICABLE
INTERNATIONAL,FEDERAL,STATE,& LOCAL REGULATIONS.MFG SUGGESTS
FLUSHING TO SEWER WITH EXCESS WATER.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:RESORCINOL
CAGE:DO501
CAGE:DO501
CAGE:0G9K0
============= Composition/Information on Ingredients =============
Ingred Name:RESORCINOL (CERCLA). LD50: (ORAL, RAT) 301 MG/KG.
CAS:108-46-3
RTECS #:VG9625000
Fraction by Wt: 100%
OSHA PEL:10 PPM
ACGIH TLV:10 PPM; 20 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:EFTS OF OVEREXP: ACUTE INGEST. RARELY, ALLERGIC SKIN RXN
MAY OCCUR IN PERS PREVIOUSLY EXPOS. EYES:CNTCT MAY CAUSE(ING 3)
RTECS #:9999999ZZ
Ingred Name:ING 2: SEV IRRIT W/REDNESS, PAIN & BLURRED VISION.
INGEST:MAY CAUSE NECROSIS OF MUC MEMBS & ABDOM PAIN. READILY (ING
4)
RTECS #:9999999ZZ
Ingred Name:ING 3: ABSORBED FROM GI TRACT & MAY CAUSE SYSTEMIC POIS.
SYMPS MAY INCL SWEATING, GREENISH/BLUISH COLORED URINE, (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4: METHEMOGLOBINEMIA, HEINZ BODIES, CYANOSIS, CONVLS,
HEMOLYTIC ANEMIA, DYSPNEA, HEPATOMEGALY, JAUN, EDEMA & (ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5: SPLENOMEGALY. CNS STIMULATION W/RESTLESSNESS, DIZZ,
TACHYCARDIA & CONVLS, FOLLOWED BY SOMNOLENCE & UNCON (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6: MAY OCCUR. DEATH IS DUE TO RESP FAILURE.
PATHOLOGICAL FINDINGS IN HUMANS INCL NECROSIS OF MUC MEMBS, (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7: MARKED TUBULAR CHGS OF KIDNEY, FATTY CHGS & ANEMIA
OF LIVER, POSS BLADDER NECROSIS, FATTY CHGS OF HEART (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8: MUSC, EDEMA & EMPHYSEMA OF LUNGS & CEREBRAL EDEMA.
LETHAL ORAL DOSES IN RATS PRDCED HYPEREMIA & STOM & (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:INTESTINE DISTENTION. CHRONIC: SKIN:RPTD APPLICATN OF
RESORCINOL CNTNG OINTMENT TO ULCERATED SKIN REPORTED(ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:TO GIVE RISE TO MYXEDEMA. RPTD APPLICATN SHOWED NO
CARCIN EFT IN MICE. EYE:EFTS DEPEND ON CONC & DURATION(ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11: OF EXPOS. CONJ/EFTS SIMILAR TO ACUTE EXPOS MAY
OCCUR. INGEST:DRINKING WATER CONTAMD W/RESORCINOL & (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:OTHER ORG CHEMS RSLTD IN HIGH INCIDENCE OF GOITERS
IN HUMANS. ADMIN TO ANIMALS PRDCED GOITERS & (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13: ANTITHYROID EFTS, ATAXIA, HYPEREXCITABILITY,
PROSTATION & TREMORS. CONTACT NEHC FOR MORE INFO .
RTECS #:9999999ZZ
Ingred Name:FIRST AID: CHEM REMAINS (AT LST 15-20 MIN). CONTINUE W/NORM
SALINE UNTIL PH RETURNS TO NORM (30-60 MIN). COVER (ING 16)
RTECS #:9999999ZZ
Ingred Name:ING 15: W/STERILE BANDAGES. GET MED ATTN IMMED. INGEST:IN
ABSENCE OF CORR INJURY, REMOVE POIS BY IPECAC EMESIS. (ING 17)
RTECS #:9999999ZZ
Ingred Name:ING 16: ACTIVATED CHARCOAL ALSO USEFUL. FOLLOW W/240 ML OF
MILK. GASTRIC LAVAGE & EMESIS CONTRAINDICATED IN (ING 18)
RTECS #:9999999ZZ
Ingred Name:ING 17: PRESENCE OF ESOPHAGEAL INJURY. GET MED ATTN IMMED.
FOLLOWING ANTIDOTE RECD, HOWEVER, DECISION TO ADMIN (ING 19)
RTECS #:9999999ZZ
Ingred Name:ING 18: & DOSE REQD SHOULD BE MADE BY QUALIFIED MED PERS.
WHEN METHEMOGLOBIN CONC IS >25-40% OR W/SYMPS PRESENT,(ING 20)
RTECS #:9999999ZZ
Ingred Name:ING 19:GIVE METHYLENE BLUE, 1% SOLN, 0.1ML/KG IV OVER
10-MIN. CYANOSIS MAY DISAPPEAR W/IN MIN OR PERSIST LONGER (ING 21)
RTECS #:9999999ZZ
Ingred Name:ING 20: DEPENDING ON DEGREE OF METHEMOGLOBINEMIA. IV ADMIN
OF THERAPEUTIC DOSES OF METHYLENE BLUE MAY CAUSE RISE(ING 22)
RTECS #:9999999ZZ
Ingred Name:ING 21: IN BLOOD PRESS, NAUS & DIZZ. LARGER DOSES (>500MG)
CAUSE VOMIT, DIARR, CHEST PAIN, MENTAL CONFUSN, SWEAT(ING 23)
RTECS #:9999999ZZ
Ingred Name:ING 22:& CYANOSIS. HEMOLYTIC ANEMIA HAS OCCURRED SEVERAL
DAYS AFTER ADMIN; EFTS TEMPORARY; NO RPTS OF FATALITY. (ING 24)
RTECS #:9999999ZZ
Ingred Name:ING 23:IF METHYLENE BLUE NOT AVAIL, GIVE ASCORBIC ACID, 1G
SLOWLY IV. W/OUT TREATMENT, METHEMOGLOBINEMIA LEVELS (ING 25)
RTECS #:9999999ZZ
Other REC Limits:NONE RECOMMENDED
Ingred Name:ING 24: OF 20-30% REVERT TO NORMAL W/IN 3 DAYS. ANTIDOTE
SHOULD BE ADMIN BY QUALIFIED MED PERS.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT 1
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL:A SURVEY OF 180 MEN
EMPLOYED IN WORKING W/RESORCINOL REVEALED NO COMPALINTS OF
IRRIT/DISCOMFORT AT 10PPM EXPOS LEVEL. LAB ANIMALS SHOWED NO TOX
SIGNS/SYMPS AT 7800 MG/M3 FOR 1 HR OR 2800MG/M3 FOR 8 HRS.
HOWEVER, EXPOS TO VERYHIGH CONCS MAY RSLT IN SYSTEMIC POIS AS IN
ACUTE INGEST. SKIN: (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: APPLICATN OF 3-25% SOLN OF RESORCINOL
TO SKIN MAY CAUSE REDNESS, ITCH, DERM, HYPEREMIA, EDEMA & LOSS OF
SUPERFICIAL LAYER OF SKIN. CORR POSS. CNTCT W/HAIR MAY CAUSE IT TO
DARKEN IN COLOR. DI SCOLORED RESORCINOL MAY PRDCE YELLOW-ORANGE
DISCOLOR OF FINGERNAILS. SYSTEMIC POIS POSS DUE TO ABSORPTION AS IN
(ING 2)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR IMMED. IF BRTHG STOPS, PERFORM ARTF
RESP. KEEP WARM & AT REST. TREAT SYMP & SUPPORTIVELY. GET MED ATTN
IMMED. SKIN:REMOVE CONTAMD CLTHG & SHOES IMMED. WASH AREA W/SOAP OR
MIL D DETERGENT & LG AMTS OF WATER UNTIL NOEVID OF CHEM REMAINS
(APPROX 15-20 MIN). GET MED ATTN IMMED. EYES:WASH IMMED W/LG AMTS
OF WATER, OCCASNLY LIFTING UPPER & LOWER LIDS, UNTIL NO EVID OF
(ING 15)
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:261F,127C
Lower Limits:1.4%
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR
REGULAR FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR
FOAM.
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE
CNTNR FROM FIRE AREA IF W/OUT RISK. EXTING ONLY IF FLOW CAN BE
STOPPED; USE FLOODING AMTS OF WATER AS (SUPDAT)
Unusual Fire/Explosion Hazard:SLIGHT FIRE HAZARD WHEN EXPOSED TO HEAT
OR FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:DO NOT TOUCH. STOP LEAK IF W/OUT RISK. TAKE UP
SM SPILLS W/ABSORB MATL & PLACE INTO CNTNRS. FOR SM DRY SPILLS,
W/CLEAN SHOVEL PLACE MATL IN CLEAN, DRY CNTNR, COVER & REMOVE FROM
AREA. LG SPILLS:DIKE F OR LATER DISP. CONTACT NEHC FOR MORE INFO .
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. PROTECT
FROM EXPOSURE TO AIR OR LIGHT. STORE AWAY FROM INCOMPATIBLE
SUBSTANCES.
Other Precautions:MAY BURN BUT DOES NOT IGNITE READILY. PREVENT
DISPERSION OF DUST IN AIR. DO NOT ALLOW SPILLED MATERIAL TO
CONTAMINATE WATER SOURCES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SPECIFICE RESP SELECTED MUST BE BASED ON CONTAM
LEVELS FOUND IN WORK PLACE, MUST BE BASED ON SPECIFIC OPERATION,
MUST NOT EXCEED WORKING LIMS OF RESP & MUST BE NIOSH APPRVD.
CONTACT NEHC FOR A LIST OFSPECIFIC RESPS .
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION TO MEET PUBLISHED
EXPOSURE LIMITS. VENTILATION EQUIPMENT MUST BE EXPLOSION-PROOF.
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR
APPROP PROT (IMPERVIOUS) CLTHG & EQUIP TO PVNT ANY CNTCT
W/SUBSTANCE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
PH: ACIDIC IN SOLN. APPEAR/ODOR: WHEN NOT PURE, W/SWEETISH TASTE &
FAINT AROMATIC ODOR. FIRE FIGHT PROC: FOG. COOL CNTNRS W/FLOODING
QTYS OF WATER. APPLY FROM AS FAR DIST AS POSS. AVOID BRTHG CORR VAP
S. KEEP UPWIND. MATL TO AVOID: ETHER, URETHAN:REACTS. NITRIC ACID.
CONTACT NEHC FOR MORE INFO ON NITRIC ACID.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:352F,178C
Melt/Freeze Pt:M.P/F.P Text:232F,111C
Vapor Pres:1 @ 108C
Vapor Density:3.80
Spec Gravity:1.2717
pH:SUPDAT
Solubility in Water:110%
Appearance and Odor:WHITE, NEEDLE-LIKE CRYSTALS WHICH CAN TURN PINK ON
EXPOS TO LIGHT & AIR (SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACETANILIDES, ALBUMIN, ALKALIES, ANTIRPYRINE, CAMPHOR, FERRIC SALTS,
METHOL, OXIDIZING MATLS, SPIRITS OF NITROUS(SUPDAT)
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATUES &
PRESSURES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC OXIDES OF CARBON.
==================== Disposal Considerations ====================
Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS
WHEN STORING OR DISPOSING OF THIS SUBSTANCE.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:2101 CHERRY RED
CAGE:09800
CAGE:09800
============= Composition/Information on Ingredients =============
Ingred Name:PROPANE VAPOR PRESSURE=760.00 MM HG
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 14%
OSHA PEL:1000 PPM
Ingred Name:ETHYL BENZENE VAPOR PRESSURE=7.10MM HG (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
OSHA STEL:125 PPM
ACGIH TLV:100 PPM/125STEL;9394
ACGIH STEL:125 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:XYLENES VAPOR PRESSURE=5.90 MM HG (SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 10%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
OSHA STEL:150 PPM
ACGIH TLV:100 PPM/150STEL;9394
ACGIH STEL:150 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ACETONE VAPOR PRESSURE=180.00 MM HG (SARA III)
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 34%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:750 PPM
OSHA STEL:1000 PPM
ACGIH TLV:750 PPM
ACGIH STEL:1000 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:METHYL ETHYL KETONE VAPOR PRESSURE=70.00 MM HG (SARA III)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 9%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM
OSHA STEL:300 PPM
ACGIH TLV:200 PPM/300STEL;9394
ACGIH STEL:300 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:METHYL ISOBUTYL KETONE VAPOR PRESSURE=16.00 MM HG (SARA
III)
CAS:108-10-1
RTECS #:SA9275000
Fraction by Wt: 3%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:50 PPM
OSHA STEL:75 PPM
ACGIH TLV:50 PPM/75 STEL; 9394
ACGIH STEL:75 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:BUTANE VAPOR PRESSURE=760.00 MM HG
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: 6%
OSHA PEL:800 PPM
ACGIH TLV:800 PPM
Ingred Name:1-METHOXY-2-PROPANOL ACETATE VAPOR PRESSURE=1.80 MM HG
CAS:108-65-6
RTECS #:AI8925000
Fraction by Wt: 8%
Ingred Name:MANGANESE COMPOUND (% MANGANESE)
CAS:7439-96-5
RTECS #:OO9275000
Fraction by Wt: 1(0.2%)
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRITATION OF EYES/SKIN/RESP
TRACT. MAY CAUSE NERV SYS DEPRES. EXTREME OVEREXPOSURE MAY RESULT
IN UNCONSCIOUSNESS & POSSIBLE DEATH. CHRONIC: METHYLETHYL KETONE
MAY INCREASE NERVOUS SYS EFFECTS OF OTHER SOLVENTS. PROLONGED
OVEREXPOSURE TO SOLVENT INGRED MAY CAUSE ADVERSE AFFECTS TO LIVER,
URINARY, BLOOD-FORMING, REPRODUCTIVE SYSTEMS.
Explanation of Carcinogenicity:PER MSDS:NO INGREDIENTS IN THIS PRODUCT
IS AN IARC/NTP/OSHA LISTED CARCINOGEN.
Effects of Overexposure:HEADACHE, DIZZINESS, NAUSEA, LOSS OF
COORDINATION ARE INDICATIONS OF EXCESSIVE EXPOSURE TO VAPORS OR
SPRAY MISTS. REDNESS & ITCHING OR BURNING SENSATION MAY INDICATE
EYE OR EXCESSIVE SKIN EXPOSURE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE FROM EXPOUSRE. RESTORE BREATHING. KEEP WARM &
QUIET. SKIN:WASH AREA THOROUGHLY W/SOAP & WATER. REMOVE CONTAMIN
CLOTHING & LAUNDER BEFORE REUSE. EYE:FLUSH W/LG AMTS OF WATER FOR
15MINS. GE T MED ATTN. INGEST: NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING. GIVE CONSCIOUS PATIENT
SEVERAL GLASSES OF WATER. GET IMMED MED ATTN.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:<-17.8C, 0.F
EXTREME FLAMMABL
Lower Limits:1.0
Upper Limits:13.1
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM
Fire Fighting Procedures:EXTREMELY FLAMMABLE! FULL PROTECTIVE EQPMT
INCLUDING SCBA SHOULD BE USED.WATER SPRAY MAY BE INEFFECTIVE.IF
WATER USED FOG NOZ PREFERRED.COOL FIRE-EXPOSED CONTAINERS W/WATER.
Unusual Fire/Explosion Hazard:REMOVE FROM HEAT/ELECT EQPMT/SPARKS/OPEN
FLAMES.CLOSED CNTNRS MAY EXPLODE WHEN EXPOSED TO EXTREME
HEAT.APPLICATION TO HOT SURFACES REQUIRES SPECIAL
PRECAUTIONS.DURING EMERGENCY CONDITIONS,OVEREXPOSURE TO DECOMP
PRODUCTS MAY CAUSE HEALTH HAZARD.SYMPTOMS MAY NOT BE IMMED
APPARENT. OBTAIN MED ATTN.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITIN. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MFG.
======================Handling and Storage ======================
Handling and Storage Precautions:USE ONLY W/ADEQUATE VENTILATION. DON'T
SMOKE/EXTINGUISH ALL FLAMES/PILOT LIGHTS/HEATERS.TURN OFF
STOVES,ELECTRIC TOOLS,APPLIANCES & ANY OTHER IGNIT SOURCES.CONSULT
NFPA CODE.USE APPROVED BONDING/GROUN DING PROCEDURES.KEEP AWAY FROM
HEAT/OPEN FLAMES.VAPORS ACCUMULATE READILY & MAY IGNITE
EXPLOSIVELY.
Other Precautions:CONTENTS UNDER PRESSURE:DON'T
PUNCTURE,INCINERATE,EXPOSE TO TEMPS >120F.KEEP FROM
SUNLIGHT,RADIATORS,STOVES,HOT H*2O.HEAT SOURCES CAUSE CONTR TO
BURST.DON'T TAKE INTERNALLY.KEEP OUT OF REACH OF CHILDR EN.DOL
STORAGE CATEGORY:1A.INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING & INHALING CONTENTS CAN BE HARMFUL/FATAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPO CAN'T BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTI WEAR NIOSH/MSHA APPROVED PROPERLY FITTED
ORG VAP/PARTICULATE RESP FOR PROTECTION AGIANST INGREDIENTS. WHEN
SANDING OR ABRADING THE DRIED FILM, WEAR A DUST/MIST RESPIRATOR
(NIOSH/MSHA APPROVED) FOR GENERATED DUST FROM UNDERLYING PAINT OR
THE ABRASIVE.
Ventilation:LOCAL EXHAUST PREFERRED.GENERAL EXHAUST ACCEPTABLE IF
EXPOSURE TO MATERIAL IS BELOW APPLICABLE EXPOSURE LIMITS.REFER TO
OSHA STDS1910.94,107,108.
FOR PROLONG/REPEAT CONTACT
Other Protective Equipment:NONE SPECIFIED BY MFG.
Work Hygienic Practices:WASH HANDS AFTER HANDLING. LAUNDER CONTAMIN
CLOTHING PRIOR TO REUSE.
Supplemental Safety and Health
PRECAUTIONS:USE ONLY W/ADEQUATE VENT. AVOID BREATHING VAPOR/SPRAY
MISTS.AVOID CONTACT W/SKIN/EYES.WASH HANDS AFTER USE. APPLICABLE
LIMITS FOR NUISANCE DUSTS: ACGIH TLV=10 MG/M3 (TOTAL DUST); OSHA
PEL= 15 MG/M3, 5 MG/M3(RESPIRABLE FRACTION).
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:<0-302F
Vapor Density:>AIR
VOC Grams/Liter:3.33
Evaporation Rate & Reference:FASTER THAN ETHER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MFG. HOWEVER AVOID HIGH
TEMPS & SOURCES OF IGNITION. APPLICATION TO HOT SURFACES REQ
SPECIAL PRECAUTIONS.
Hazardous Decomposition Products:BY FIRE: CARBON MONOXIDE AND CARBON
DIOXIDE, OXIDES OF METALS AS LISTED IN THE INGREDIENTS SECTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM MATL MAY BE HAZ UNDER RCRA 40CFR261.
WASTE MUST BE TESTED FOR IGNITIBILITY TO DETERMINE APPLICABLE EPA
HAZ WASTE NOS. DO NOT INCINERATE. DEPRESSURIZE CNTAINER. DISPOSE OF
IN ACCORDANCE W/ A LL FED/STATE/LOCAL REGULATIONS.
===================== Regulatory Information =====================
SARA Title III Information:ETHYLBENZENE; XYLENE; METHYLETHYL KETONE;
METHYL ISOBUTYL KETONE, MANGANESE COMPOUND.
Federal Regulatory Information:ALL CHEMICALS IN THIS PRODUCT ARE LISTED
OR ARE EXEMPT FROM LISTING ON THE TSCA INVENTORY.
State Regulatory Information:WARNING: THIS PRODUCT CONTAINS CHEMICALS
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS
OR OTHER REPRODUCTIVE HARM.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:NORDEL HYDROCARBON RUBBER,1440
DIV)
CAGE:1N612
CAGE:1N612
============= Composition/Information on Ingredients =============
Ingred Name:1,4-HEXADIENE, POLYMER WITH ETHENE AND 1-PROPENE; (EPDM
RUBBER)
CAS:25038-37-3
Other REC Limits:PEL:5 MG/M3 RDUST(M)
OSHA PEL:15 MG/M3 TDUST
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) >7,500 MG/KG.
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PROLONGED OR REPEATED CONTACT MAY
CAUSE MILD SKIN IRRITATION IN SENSITIVE INDIVIDUALS. HOT POLYMER
CAUSES THERMAL BURNS. EXPOSURE LIMITS: FOR PRODUCT - USE STANDARD
FOR PARTICULATES, N.O.C. OSHA PEL/T WA: 15 MG/ CU M (TOTAL DUST), 5
MG/CU M (RESPIRABLE DUST).
Explanation of Carcinogenicity:NONE.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:UNKNOWN.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES REPEATED BY
HOLDING EYELIDS OPEN TO ENSURE PROPER IRRIGATION. SKIN: IF MOLTEN
POLYMER GETS ON SKIN, COOL RAPIDLY WITH COLD WATER. DO NOT ATTEMPT
TO PEEL POLYMER FROM SKIN. OBTAIN MEDICAL TREATMENT FOR THERMAL
BURNS. INHALATION: REMOVE TO FRESH AIR. KEEP WARM & QUIET. GIVE
ARTIFICIAL RESPIRATION IF NOT BREATHING. CONSULT MD. INGESTION:
SEEK MEDICAL ATT ENTION IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:>260.C, 500.F
Autoignition Temp:>300.C, 572.F
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . REGULAR PROCEDURES FOR RUBBER FIRES.
Unusual Fire/Explosion Hazard:NORDEL SOMETIMES CONTAINS LOWER MOLECULAR
WEIGHT COMPONENTS WHICH CAN VOLATILIZE & MAY IGNITE DURING
PROCESSING. MIXERS SHOULD BE VENTILATED & IGNITION SOURCES AVOIDED
TO ELIMINATE POSSIBILITY OF A FI RE. NFPA ID SYSTEM: HEALTH: 1,
FLAMMABILITY: 1, REACTIVITY: 0.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP SPILLAGE AND TRANSFER INTO A CLOSED
CONTAINER FOR DISPOSAL. RECOVER UNDAMAGED MATERIAL FOR REUSE AND
RECLAMATION.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID INHALING DUST OR FUMES. USE WITH
ADEQUATE VENTILATION. STORE IN A WELL VENTILATED COOL PLACE. AVOID
CONTACT WITH SKIN AND EYES.
Other Precautions:READ BULLETIN ND-110.1 ENTITLED "TOXICITY AND
HANDLING GUIDELINES FOR NORDEL" BEFORE USING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATORS SHOULD DUST OR FUMES
BE GENERATED.
Ventilation:EFFECTIVE VENTILATION TO DRAW VAPOR OR FUMES AWAY FROM
WORKERS TO PREVENT ROUTINE INHAL. LOCAL EXHAUST IS REC W/MINIMUM
CAPTURE VELOCITY OF 100-15O PPM.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . IF
THERE IS A POTENTIAL CONTACT WITH HOT/MOLTEN MATERIAL, WEAR HEAT
RESISTANT CLOTHING & FOOTWEAR.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
FIRE & EXPLO HAZ: AUTO-OXIDATION TEMP: >190C,>374F.
================== Physical/Chemical Properties ==================
HCC:T6
Spec Gravity:0.85-0.90 MG/M3 @ 25C
Solubility in Water:INSOLUBLE
Appearance and Odor:AMBER-GRAY PELLETS OR BALES'; SLIGHT AROMATIC ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:AVOID TEMPERATURES ABOVE 290C. PROCESSING
AT TEMPERATURES ABOVE 295C MAY PRODUCE IRRITANTS.
Hazardous Decomposition Products:OXIDES OF CARBON, HYDROCARBON
OXIDATION PRODUCTS INCLUDING ORGANIC ACIDS, ALDEHYDES AND ALCOHOLS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information===================
Toxicological Information:A HIGH VISCOSITY TYPE OF NORDEL HAS BEEN
TESTED IN ORDER TO ASSESS THE ACUTE TOXICOLOGY. IT IS EXPECTED THAT
ALL TYPES OF NORDEL HAVE SIMILAR LEVELS OF TOXICITY. SKIN
IRRITATION: PATCH TESTS CONDUCTED ON RABBITS SHOWED NO SIGNS OF
IRRITATION AFTER 24 HOURS CONTACT TIME. SKIN IRRITATION AND
SENSITIZATION STUDIES ON HUMAN SUBJECTS SHOWED NO EVIDENCE OF
IRRITATION AFTER 6 DAYS CONTACT TIME.
==================== Disposal Considerations ====================
Waste Disposal Methods:NOT A RCRA HAZARDOUS WASTE. DISPOSE OF BY
INCINERATION OR LANDFILL IN COMPLIANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:DOT CLASSIFICATION: NOT REGULATED.
===================== Regulatory Information =====================
SARA Title III Information:SARA TITLE III SECTION 313 INGREDIENTS:
NONE.
Federal Regulatory Information:TSCA INVENTORY STATUS: LISTED.
State Regulatory Information:
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:E90YY11 ZINC CHROMATE PRIMER YELLOW
CAGE:54636
CAGE:54636
============= Composition/Information on Ingredients =============
Ingred Name:NAPHTHA (PETROLEUM SPIRITS OR BENZIN)
CAS:8030-30-6
RTECS #:SE7555000
Fraction by Wt: 20%
OSHA PEL:100 PPM
Ingred Name:CHROMIUM ION (CR 6+)
CAS:18540-29-9
RTECS #:GB6262000
Fraction by Wt: 8.45%
OSHA PEL:C, 0.1 MG/M3 (CRO3)
ACGIH TLV:0.05 MG/M3 (CR);8990
Ingred Name:LEAD (SARA III)
CAS:7439-92-1
RTECS #:OF7525000
Fraction by Wt: 0.10%
OSHA PEL:0.05 MG/M3;1910.1025
ACGIH TLV:0.15 MG/M3;DUST 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ISOBUTYL ALCOHOL (SARA III)
CAS:78-83-1
RTECS #:NP9625000
Fraction by Wt: 5%
OSHA PEL:100 PPM
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: <5%
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Effects of Overexposure:VAP:H1 CONC ANESTH;SKIN & RESP IRRIT;
LTHDNESS,STAG; MIST,PRLNGD:PRFRATN-NAS SEPTUM & ULCERS OF SKIN
======================= First Aid Measures =======================
First Aid:REMOVE FR EXPOS, RESTORE BREATH; KEEP QUIET & WARM; EYES:
FLUSH W/H*2O 15 MIN. WASH AFFCTD AREA W/H*2O. REMOVE CONTAMTD CLOTH
& WASH BEFORE REUSE.
===================== Fire Fighting Measures =====================
Flash Point:37 F (PMCC)
Lower Limits:0.9
Extinguishing Media:CO*2,DRY CHEMICAL
Fire Fighting Procedures:KEEP CONTAIERS ISOLATED FROM HEAT, SPARKS &
OPEN FLAME
Unusual Fire/Explosion Hazard:WATER MAY BE INEFFECTIVE. WATER SHOUL BE
USED TO KEEP FIRE EXPOSED CONTNRS COOL
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE SOURCES OF IGNITION. VENTILATE & REMOVE
W/INERT ABSORBENT
======================Handling and Storage ======================
Handling and Storage Precautions:FLAMMABLE LABEL.KEEP FROM ALL IGNITION
SOURCES. DO NOT TRANSFR TO OTHER CONTAINERS FOR STORABE. VAPOR
PRESSURE GINE IS FOR ISPOROPYL ALCOHOL
Other Precautions:USE ADEQ VENTIL; AVOID SKIN CNTCT/WASH AFT USE; CLOSE
WHEN NOT USE; RESP PRTCT WHEN ABRADNG.WELDNG; DONT APPLY TO CHILDS
ARTCLS OR SURF TO WHCH SHILD EXPOSD. USE APPRVD BONDNG & GROUND
PROCEDR
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPRVD DEVICE FOR MIST & VAPORS IF
NEXESSARY
Ventilation:LOCAL FOR SPRAY APPLCTN; GENRL DILUTN FOR OTHER METHODS
Supplemental Safety and Health
ADD HAZ INGRED:AMYL ACETATE, <5% 100 PPM:XYLENE,<5%,S-100PPM:MINERAL
SPIRITS,5%, 100 PPM(MFG):ISOPROPYL ALCOHOL,<5%,400 PPM:2ETHOXYETHYL
ACETATE, <5%,S-50PPM:METHYL ETHYL METHOXIME,<0.5% 600 P
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:176-390 5
Vapor Pres:33.
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:61.8
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:FIRE: CO*2, CO,OXIDES OF LEAD &
CHROMIUM
==================== Disposal Considerations ====================
Waste Disposal Methods:INCIN IN AOPVD FACILITY. DO NOT INCIN CLOSD
CONTAINER. DISPOSE IN ACCORDANCE W/FED,STATE & LOCAL REGS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:RPC-037 2,3,4,5,6-PENTACHLOROBIPHENYL
CAGE:0MU35
CAGE:0MU35
============= Composition/Information on Ingredients =============
Ingred Name:2,3,4,5,6-PENTACHLOROBIPHENYL
CAS:18259-05-7
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TOXIC; IRRITANT. TOXIC MATERIAL
CAUSING OTHER TOXIC EFFECTS.
Explanation of Carcinogenicity:NONE
======================= First Aid Measures =======================
First Aid:EYES/SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER. INHALATION:
REMOVE TO FRESH AIR. GIVE OXYGEN IF NECESSARY. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:CO2, DRY CHEMICAL POWDER/WATER SPRAY.
================== Accidental Release Measures ==================
Spill Release Procedures:LEAKING BOTTLE MAY BE PLACED IN A PLASTIC BAG
& NORMAL DISPOSAL PROCEDURES FOLLOWED. LIQUID SAMPLES MAY BE
ABSORBED ON VERMICULITE/SAND.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP TIGHTLEY CLOSED & STORE IN A
COOL/DRY PLACE.
Other Precautions:THIS MATERIAL SHOULD ONLY BE USED BY THOSE PERSONS
TRAINED IN THE SAFE HANDLING OF HAZARDOUS CHEMICALS. PREVENT
CONTACT W/SKIN, EYES & CLOTHING. ALL CHEMICALS SHOULD BE CONSIDERED
HAZARDOUS, DIRECT PH YSICAL CONTACT SHOULD BE AVOIDED.
============= Exposure Controls/Personal Protection =============
Other Protective Equipment:CHEMICAL RESISTANT LABORATORY COAT &/RUBBER
APRON, USE APPROPRIATE OSHA/MSMA APPROVED SAFETY EQUIPMENT.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:253.4F
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
==================== Disposal Considerations ====================
Waste Disposal Methods:BURN IN CHEMICAL INCINERATOR EQUIPPED W/AN
AFTERBURNER & SCRUBBER IAW/FEDERAL, STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:530-2935 PANTONE 293 BLUE RUBBER BASE INK 5LBS
CAGE:FO004
CAGE:FO004
CAGE:09177
============= Composition/Information on Ingredients =============
Ingred Name:LINSEED OIL
Fraction by Wt: 5-10%
Ingred Name:POLYETHYLENE WAX
Fraction by Wt: 2-3%
Ingred Name:VOLATILE ORGANIC CONTENT: 0.42 LBS/GAL; (51 GM/L)
RTECS #:9999999VO
Ingred Name:WHITE MINERAL OIL
CAS:8042-47-5
RTECS #:PY8047000
Fraction by Wt: 30-35%
Other REC Limits:STEL 10 MG/CUM
OSHA PEL:5 MG/CUM MIST
ACGIH TLV:5 MG/CUM MIST
Ingred Name:MODIFIED ROSIN ESTERS
Fraction by Wt: 25-30%
Ingred Name:HYDROCARBON RESIN
Fraction by Wt: 10-15%
Ingred Name:COPPER (DUST & MIST), BRONZE POWDER *95-3*
CAS:7440-50-8
RTECS #:GL5325000
Fraction by Wt: 12%
Other REC Limits:1 MG(CU)/M3 (DUST)
OSHA PEL:0.1 MG(CU)/M3 (FUME)
ACGIH TLV:0.2 MG/M3 (FUME)
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: MAY CAUSE BURNING & IRRITATION.
SKIN: PROLONGED/REPEATED EXPOSURE CAUSES IRRITATION/DERMATITIS.
INGESTION: MAY CAUSE IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:BURNING, IRRITATION, HEADACHE, DIZZINESS,
DROWSINESS, NAUSEA, GASTRIC DISTURBANCE
Medical Cond Aggravated by Exposure:SOME SKIN DISORDERS SUCH AS
DERMATITIS.
======================= First Aid Measures =======================
First Aid:EYES: RINSE THOROUGHLY W/WATER FOR 15 MINS. SKIN: WASH W/MILD
SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF
NECESSARY. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:245F
Extinguishing Media:FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:WATER CAN BE USED TO KEEP MATERIAL COOL. USE
SELF CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:DENSE SMOKE MAY BE GENERATED WHILE
BURNING.
================== Accidental Release Measures ==================
Spill Release Procedures:WIPE UP W/RAGS. DISPOSE OF RAGS IN CONTAINERS
APPROVED FOR OILY WASTE.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN
USE. KEEP AWAY FROM EXCESSIVE HEAT, SPARKS & OPEN FLAME. DON'T
REUSE CONTAINER. FOR COMMERCIAL/INDUSTRIAL USE ONLY.
Other Precautions:KEEP FROM REACH OF CHILDREN. PREVENT EXCESSIVE SKIN
CONTACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NORMALLY REQUIRED
Ventilation:GENERAL VENTILATION
Other Protective Equipment:APRON, BOOTS, IMPERVIOUS CLOTHING
Work Hygienic Practices:WASH HANDS & FACE W/SOAP & WATER BEFORE
EAING/SMOKING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>200F
Vapor Pres:0.1 @ 70F
Vapor Density:>1
Spec Gravity:>1
Evaporation Rate & Reference:SLOWER THAN BU ACETATE
Solubility in Water:INSOLUBLE
Appearance and Odor:COLORED PASTE W/OILY ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:EXCESS HEAT, SPARKS & OPEN FLAME
Hazardous Decomposition Products:WHEN BURNING: DENSE SMOKE, CO, CO2
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATION IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:8200 BIG BARE WATER - BASED INDUSTRIAL CLEANER/DEGREASER
CAGE:0U826
CAGE:0U826
CAGE:32204
============= Composition/Information on Ingredients =============
Ingred Name:NONYLPHENOXYPOLY-(ETHYLENEOXY) ETHANOL, NP-9, NONIONIC
SURFACTANT
CAS:26027-38-3
RTECS #:MD0906000
Fraction by Wt: 2-4%
Ingred Name:SILICATE BINDERS (SODIUM SILICATE) *95-1*
CAS:1344-09-8
Fraction by Wt: 3-5%
ACGIH TLV:10 MG/CUM
Ingred Name:SODIUM HYDROXIDE, CAUSTIC SODA, LYE
CAS:1310-73-2
RTECS #:WB4900000
Fraction by Wt: 1-3%
Other REC Limits:2MG/M3 CEILING NIOSH
OSHA PEL:2 MG/CUM
ACGIH TLV:2 MG/CUM CEILING
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:POTASSIUM CARBONATE, POTASH, PEARL ASH
CAS:584-08-7
RTECS #:TS7750000
Fraction by Wt: 1-3%
Ingred Name:TETRASODIUM SALT OF ETHYLENEDIAMINETETRAACETIC ACID, SODIUM
EDTA, SODIUM (DI) ETHYLENEDIAMINE TETRAACETATE
CAS:64-02-8
RTECS #:AH5075000
Fraction by Wt: 2-4%
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 75-85%
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): >5000 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITANT, CORROSIVE, MAY CAUSE
PERMANENT DAMAGE. SKIN: CORROSIVE, MAY CAUSE CHEMICAL BURNS.
INHALATION: MAY CAUSE IRRITATION OF RESPIRATORY TRACT. INGESTION:
HARMFUL, CORROSIVE TO MOUTH & DIGEST IVE TRACT.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, BURNS.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH IMMEDIATELY W/WATER FOR 20 MINS. SKIN: WASH
CONTAMINATED AREA W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR.
INGESTION: DRINK 1-2 GLASSES OF WATER/MILK. DON'T ADMINISTER
ANYTHING BY MOUT H TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:NORMAL FIRE FIGHTING PROCEDURE MAY BE USED.
COOL & USE CAUTION WHEN APPROACHING/HANDLING FIRE EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:CORROSIVE MATERIAL.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB W/OIL-DRI/SIMILAR INERT MATERIAL.
SWEEP/SCRAPE UP & CONTAINERIZE. RINSE AFFFECTED AREA THOROUGHLY
W/WATER. WEAR/USE APPROPRIATE PROTECTIVE EQUIPMENT.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE W/ADEQUATE
VENTILATION. KEEP FROM FREEZING. KEEP CONTAINER WELL CLOSED WHEN
NOT IN USE. FOR INDUSTRIAL USE ONLY.
Other Precautions:AVOID CONTACT W/EYES, PROLONGED CONTACT W/SKIN &
BREATHING SPRAY MIST/VAPORS. KEEP OUT OF REACH OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE RESPIRATORY PROTECTION IF
MISTS/VAPORS AREN'T ADEQUATELY CONTROLLED BY LOCAL VENTILATION.
Ventilation:GENERAL ROOM VENTILATION ADEQUATE. LOCAL EXHAUST IF
SUBSTANTIAL AMOUNTS OF MISTS/VAPORS PRESENT.
Other Protective Equipment:APPROPRIATE PROTECTIVE EQUIPMENT
Work Hygienic Practices:USE GOOD PERSONAL HYGIENE PRACTICES.
REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY
AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F
Melt/Freeze Pt:M.P/F.P Text:32F
Spec Gravity:1.11
pH:12.7
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR WATER WHITE LIQUID W/MILD ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS/MURIATIC ACID/STRONG OXIDIZING MATERIALS/LIQUID
CHLORINE/NON-FERROUS METALS/ZINC/ALUMINUM.
Stability Condition to Avoid:FREEZING.
Hazardous Decomposition Products:NORMAL PRODUCTS OF COMBUSTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF UNDILUTED PRODUCT AS CORROSIVE WASTE
IAW/FEDERAL, STATE & LOCAL REGULATIONS. CORROSIVE LIQUID UN1760
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===================== Product Identification =====================
Product ID:LEAD/ACID STORAGE BATTERY - HYBRID
CAGE:KO557
CAGE:0FGN2
CAGE:90660
CAGE:KO557
============= Composition/Information on Ingredients =============
Ingred Name:LEAD (SARA III)
CAS:7439-92-1
RTECS #:OF7525000
Fraction by Wt: >60%
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.05 MG/M3;1910.1025
ACGIH TLV:0.15 MG/M3;DUST 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ANTIMONY (SARA III)
CAS:7440-36-0
RTECS #:CC4025000
Fraction by Wt: >2%
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.5 MG/M3
ACGIH TLV:0.5 MG SB/M3; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ARSENIC (SARA III)
CAS:7440-38-2
RTECS #:CG0525000
Fraction by Wt: <0.2%
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.5 MG/M3 (AS)
ACGIH TLV:0.01,A1 MG/M3; 9394
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:CALCIUM, METAL
CAS:7440-70-2
RTECS #:EV8040000
Fraction by Wt: <0.2%
Other REC Limits:NONE SPECIFIED
Ingred Name:SULFURIC ACID (SARA III)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 10-30%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:POLYPROPYLENE
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE:INHALATION OF ACID VAPORS MAY
CAUSE SEVERE IRRITATION OR BURNS OF THE RESPIRATORY SYSTEM,
PULMONARY EDEMA, OR LUNG INFLAMMATION. MAY CAUSE SEVERE BURNS TO
SKIN OR EYES. INGESTION MAY CAUSE SEVER E BURNS TO MOUTH, THROAT,
AND STOMACH. MAY AFFECT KIDNEY FUNCTION. CHRONIC:MAY DAMAGE
LUNGS,TEETH EROSION.
Explanation of Carcinogenicity:ARSENIC IS LISTED BY IARC, NTP, & OSHA
AS A CARCINOGEN. LEAD IS LISTED AS A POSSIBLE CARCINOGEN.
Effects of Overexposure:ACID:SEVERE IRRITATION OR BURNS TO EYES, NOSE
AND THROAT. PULMONARY EDEMA, BRONICAL EMPHYSEMA, CONJUNCTIVITIS,
STOMATITIS, DENTAL EROSION, NAUSEA AND VOMITING. LEAD:STOMACH
CRAMPS, ANEMIA AND NERVE DA MAGE.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE RESPIRATORY TRACT MAY
BE AT INCREASED RISK FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING.
GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER
FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION.
SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH PLENTY OF WATER FOR
15 MINUTES. GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING.
GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Lower Limits:4.1( FOR H2)
Upper Limits:74.2(FOR H2)
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:IF ON CHARGE, SHUT OFF POWER.
Unusual Fire/Explosion Hazard:WILL GENERATE HYDROGEN ON OVERCHARGE. MAY
EXPLODE IN FIRE AND PRODUCE HAZARDOUS FUMES AND OXIDE OF SULFUR
GASES.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE CLOTHING. STOP LEAK IF YOU CAN DO SO WITHOUT RISK.
DO NOT USE WATER. NEUTRALIZE SPILL AND/OR WASHINGS WITH SODA ASH OR
LIME. WITH CLEAN SHOV EL, PLACE MATERIAL INTO CLEAN, DRY CONTAINER.
Neutralizing Agent:J.T.BAKER'S NEUTRASORB (R) OR TEAM 'LOW NA+' ACID
NEUTRALIZERS ARE RECOMMENDED.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE
IN CORROSION-PROOF AREA. KEEP CONTAINERS OUT OF SUN AND AWAY FROM
HEAT. ISOLATE FROM INCOMPATIBLE MATERIALS.
Other Precautions:DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. DO NOT
BREATHE VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. LOOSEN CLOSURE
CAUTIOUSLY. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING. IN CASE OF SPILL NEUTRALIZE WITH SODA ASH OR LIME.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION EXCEEDS TLV, A NIOSH
APPROVED SELF-CONTAINED BREATHING APPARATUS IS RECOMMENDED.
Ventilation:USE MECHANICAL (GENERAL) OR LOCAL EXHAUST VENTILATION TO
MEET TLV REQUIREMENTS.
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO
NOT BREATHE VAPORS OR MISTS.
================== Physical/Chemical Properties ==================
pH:<2.0
Appearance and Odor:LEAD/ACID BATTERY, POLYPROPYLENE CASING.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, COMBUSTIBLES, ORGANIC MATERIAL, PROLONGED
OVERCHARGE.
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES .
Hazardous Decomposition Products:OXIDES OF SULFUR, HYDROGEN GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:125-08 HI-HIDING WHITE, WASHABLE WALLPLATE (SUPDAT)
CAGE:EO376
CAGE:EO376
CAGE:85520
============= Composition/Information on Ingredients =============
Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA)
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 0-3.9%
OSHA PEL:N/K
ACGIH TLV:50 PPM, VAPOR, C
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:1,2-PROPANEDIOL; (PROPYLENE GLYCOL)
CAS:57-55-6
RTECS #:TY2000000
Fraction by Wt: 1-5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:VOLATILE ORGANIC COMPOUNDS: 1.16-1.37.
RTECS #:9999999VO
Ingred Name:SUPDAT:THESE PRODS MAY BECOME AIRBORNE IN FORM OF VAP/DUST.
WEAR APPROP PROPERLY FITTED NIOSH/MSHA APPRVD RESP (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4:DURING & AFTER APPLICATION UNLESS AIR MONITORING
DEMONSTRATES VAP/MIST LEVELS ARE BELOW APPLIC LIMS. FOLLOW(ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5:RESP MFR'S DIRECTIONS FOR RESPIRATOR USE.
RTECS #:9999999ZZ
Ingred Name:VENT:APPRVD RESP TO PVNT OVEREXP. PROVIDE GEN DILUTION/LOC
EXHST VENT IN VOL & PATTERN TO KEEP TLV OF MOST HAZ (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7:ING BELOW ACCEPT LIM, LEL BELOW STATED LIM & TO
REMOVE DECOMP PRODS DURING WELDING/FLAME CUTTING ON SURFS (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8:COATED W/THESE PRODUCTS.
RTECS #:9999999ZZ
RTECS #:9999999ZZ
Ingred Name:HYGIENE PRACT:PROPERLY LAUNDERED.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:REPORTS HAVE ASSOCIATED REPEATED &
PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS W/PERMANENT BRAIN &
NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING & INHALING CONTENTS MAY B E HARMFUL OR FATAL. THESE
PRODUCTS CAN BE IRRITATING TO EYES. THESE PRODUCTS MAY CONTAIN ONE
OR MORE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:REPORTED TERATOGENS OR SUSPECTED
TERATOGENS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/LUKE WARM WATER FOR AT LST 15 MINS. SEEK MD
IMMED. SKIN:FLUSH WASH W/COPIOUS AMTS OF WARM WATER. REMOVE CONTAM
CLTHG PROMPTLY. CONT MD IMMED. INHAL:REMOVE EXPOS INDIVIDUAL TO
FRESH AIR. R ESTORE BRTHG IF REQD. CONT MD IMMED. INGEST:RINSE
MOUTH IMMED. GIVE EXPOS INDIVIDUALS 6-8 OZS OF LIQ (NEVER GIVE
ANYTHING BY MOUTH TO UNCON PERS.) DO NOT INDUCE VOMIT UNLESS
ADVISED BY MD. (SUPP DATA)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CONTAINERS EXPOSED TO INTENSE HEAT FROM
FIRES SHOULD BE COOLED W/WATER TO PREVENT VAPOR PRESSURE BUILDUP
WHICH COULD RESULT IN CONTAINER RUPTURE.
================== Accidental Release Measures ==================
Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP FROM FREEZING. DO NOT STORE
>120F. DO NOT TAKE INTERNALLY. CLOSE CNTNR AFTER EACH USE. KEEP OUT
OF REACH OF CHILDREN! AVOID CONT W/EYES.
Other Precautions:DO NOT BREATHE VAPORS OR SPRAY MIST. THESE PRODUCTS
CONTAIN PIGMENTS WHICH MAY BECOME A DUST NUISANCE WHEN REMOVED BY
ABRASIVE BLASTING, SANDING OR GRINDING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN OUTDOOR/OPEN AREAS, USE NIOSH/MSHA APPRVD
MECH FILTER RESP TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY
DURING SPRAY APPLICATION. IN RESTRICTED VENT AREAS, USE NIOSH/MSHA
APPRVD CHEM-MECH FILTER S DESIGNED TO REMOVE COMBINATION(SUPDAT)
Ventilation:USE VENT AS REQD TO CONTROL VAP CONCS. AVOID PRLNG/RPTD
BRTHG OF VAPS. IF EXPOS EXCEEDS TLV, USE NIOSH/MSHA (ING 7)
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . AN APRON SHOULD BE WORN TO AVOID SKIN
CONTACT.
Work Hygienic Practices:WASH HANDS THORO BEFORE EATING & USING
WASHROOM. REMOVE CONTAM CLTHG IMMED & DO NOT WEAR IT UNTIL IT HAS
BEEN (ING 11)
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:INTERIOR LATEX FLAT ENAMEL. %
VOLAT:57.88-62.91. HAZ DECOMP PROD:OXIDES OF NITROGEN. FIRST AID
PROC:CONT MD IMMED. RESP PROT:OF PARTICULATE & GAS & VAP. IN
CONFINED AREAS, USE NIOSH/MSHA APPRVD AIR LINE TYPE RESPS/HOODS.
RESP PROT MAY ALSO BE NEC IN ANY LATER MFG OPERATIONS IN WHICH (ING
4)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres:17 @ 68F
Vapor Density:HVR/AIR
Spec Gravity:1.28-1.4
Evaporation Rate & Reference:SLOWER THAN BUTYL ACETATE
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
THESE PRODUCTS ARE INCOMPATIBLE W/STRONG ACIDS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY PRDCE HAZ FUMES WHEN HEATED TO
DECOMP AS IN WELDING. FUMES MAY CONTAIN CARBON MONOXIDE, CARBON
DIOXIDE & (SUPP DATA)
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT FLUSH TO SEWER, WATERSHED OR WATERWAY.
DISPOSE OF THESE PRODUCTS I/A/W APPLICABLE LOCAL, COUNTY, STATE &
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:25216 LAV-16 VINYL UNFILLED OMNI-PAK LACQUER ACRYLIC VINYL
CAGE:54626
CAGE:54626
CAGE:09800
============= Composition/Information on Ingredients =============
Ingred Name:PROPANE (DIMETHYLMETHANE)*98-2*
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 22%
Other REC Limits:1800 MG/CUM
OSHA PEL:1000 PPM
ACGIH TLV:SIMPLE ASPHYXIANT
Ingred Name:ACETONE; DIMETHYL KETONE; 2-PROPANONE *98-2*
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 70%
OSHA PEL:2400 MG/CUM
ACGIH TLV:750 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *98-2*
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 4%
Other REC Limits:100 PPM
OSHA PEL:100 PPM
ACGIH TLV:100 PPM, SKIN
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:DIACETONE ALCOHOL
CAS:123-42-2
RTECS #:SA9100000
Fraction by Wt: 4%
Other REC Limits:50 PPM
OSHA PEL:240 MG/CUM
ACGIH TLV:238 MG/CUM
Ingred Name:VOLATILE ORGANIC CONTENT: 30% BY WEIGHT
RTECS #:9999999VO
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IRRITATION OF EYES, SKIN & RESPIRATORY
SYSTEM. NERVOUS SYSTEM DEPRESSION & POSSIBLE DEATH. PROLONGED
OVEREXPOSURE TO SOLVENT MAY CAUSE ADVERSE EFFECTS TO THE LIVER &
URINARY SYSTEMS. REPEATED/PROLONGE D OVEREXPOSURE TO SOLVENTS MAY
CAUSE PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, UNCONSCIOUSNESS, HEADACHE,
DIZZINESS, NAUSEA, LOSS OF COORDINATION, REDNESS, ITCHING, BURNING
SENSATION.
Medical Cond Aggravated by Exposure:NONE
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. KEEP WARM
& QUIET. SKIN: WASH THOROUGHLY W/SOAP & WATER. EYES: FLUSH W/LARGE
AMOUNTS OF WATER FOR 15 MINS. INGESTION: NEVER GIVE ANYTHING BY
MOUTH T O AN UNCONSCIOUS PERSON. DON'T INDUCE VOMITING. GIVE
SEVERAL GLASSES OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:<0F
Lower Limits:1
Upper Limits:12.8
Extinguishing Media:CO2, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE FULL PROTECTIVE EQUIPMENT & SCBA. WATER
SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS.
Unusual Fire/Explosion Hazard:CONTAINERS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT. APPLICATIONS TO HOT SURFACES REQUIRES SPECIAL
PRECAUTIONS. OVEREXPOSURE MAY CAUSE A HEALTH HAZARD. (SUPP)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE SOURCES OF IGNITION. VENTILATE & REMOVE
W/INERT ABSORBENT.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & OPEN
FLAME. KEEP AREA VENTILATED. USE APPROVED BONDING & GROUNDING
PROCEDURES. DON'T PUNCTURE/INCINERATE TEMPS >120F.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. DON'T TAKE INTERNALLY.
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE
CONTENTS CAN BE HARMFUL/FATAL. AVOID BREATHING VAPOR & SPRAY MIST.
AVOID CONTACT W /SKIN & EYES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOSURE CAN'T BE CONTROLLED BELOW
APPLICABLE LIMITS, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE
RESPIRATOR APPROVED BY NIOSH/MSHA.
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF
EXPOSURE IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE HZRD CONT'D: CONTENTS ARE EXTREMELY FLAMMABLE. VAPORS WILL
ACCUMULATE READILY & MAY IGNITE EXPLOSIVELY. CONTENTS UNDER
PRESSURE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:<0-342F
Vapor Density:>1
Evaporation Rate & Reference:FASTER THAN ETHER
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CO2, CO.
Stability Condition to Avoid:HEAT, SPARKS & OPEN FLAME.
Hazardous Decomposition Products:BY FIRE: CO2, CO.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. WASTE MAY BE HAZARDOUS UNDER THE RCRA & MUST BE TESTED
FOR IGNITABILITY FOR APPLICABLE EPA HAZARDOUS WASTE NUMBERS.
DEPRESSURIZE CONTAINER. DON'T INC INERATE.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SSR ULTRA COOLANT
CAGE:65131
CAGE:6K358
CAGE:65131
Contract Num:SP0450-00-D-4021
CAGE:29913
============= Composition/Information on Ingredients =============
Ingred Name:POLYOXYALKYLENE GLYCOL
Ingred Name:PENTAERYTHRITOL ESTER
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 FOR RATS IS >4000MG/KG.
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN CONTACT: PROLONGED CONTACT
ESSENTIALLY NON-IRRITATING TO SKIN. SKIN ABSORPTION: SINGLE
PROLONGED EXPOSURE UNLIKELY TO RESULT IN ABSORPTION OF HARMFUL
AMOUNTS. MATERIAL SOMETIMES ENCOUNTERED IN EL EVATED TEMP; MORE
INTENSE EFFECTS AS WELL AS THERMAL BURNS POSSIBLE. INGESTION:
SINGLE DOSE ORAL TOXICITY IS LOW. AMOUNTS INGESTED INCIDENTAL TO
INDUSTRIAL HANDLING NOT LIKELY TO CAUSE INJURY; HOWEVER , INGESTION
OF LARGER AMOUNTS MAY CAUSE INJURY. INHLATION: ROOM TEMPERATURE
EXPOSURES TO VAPORS ARE UNLIKELY; HIGHER TEMP/MIST MAY GENERATE
VAPORS WHICH CAUSE IRRITATION. EYES: ESSENTIALLY NON-IRRITAT ING.
Explanation of Carcinogenicity:NONE OF THE INGREDIENTS HAVE BEEN
LISSTED AS HAZARDOUS OR TOXIC BY OSHA, NTP, IARC, AND SARA 313.
Effects of Overexposure:SKIN: THERMAL BURNS AT ELEVATED TEMPERATURES.
INGESTION: NOT PROVIDED. EYE: NON-IRRITATING.
Medical Cond Aggravated by Exposure:NOT PROVIDED
======================= First Aid Measures =======================
First Aid:EYES: IRRIGATE IMMEDIATELY WITH WATER FOR AT LEAST 5 MINUTES.
SKIN: WASH OFF IN FLOWING WATER OR SHOWER. INGESTION: INDUCE
VOMITING IF LARGE AMOUNTS ARE INGESTED. CONSULT MEDICAL PERSONNEL.
INHALATION : REMOVE TO FRESH AIR IF AFFECTED. CONSULT PHYSICIAN.
NOTE TO PHYSICIAN: NO SPECIFIC ANTIDOTE. SUPPORTIVE CARE. TREATMENT
BASED ON JUDGEMENT OF THE PHYSICIAN IN RESPONSE TO REACTIONS OF THE
PATIENT.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:=271.1C, 520.F
Autoignition Temp:=388.3C, 731.F
Lower Limits:N/D
Upper Limits:N/D
Extinguishing Media:WATER FOG, FOAM, ALCOHOL-RESISTANT FOAM, CO2, DRY
CHEMICAL
Fire Fighting Procedures:NONE WEAR POSITIVE PRESSURE, SELF-CONTAINED
BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:NONE KNOWN
================== Accidental Release Measures ==================
Spill Release Procedures:SOAK UP WITH SUITABLE ABSORBENT MATERIAL, THEN
SWEEP INTO PLASTIC BAG FOR DISPOSAL.
Neutralizing Agent:NOT PROVIDED
======================Handling and Storage ======================
Handling and Storage Precautions:REASONABLE CARE SHOULD BE TAKEN IN
HANDLING THIS PRODUCT.
Other Precautions:READ LABEL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY NEEDED
Ventilation:GOOD ROOM VENTILATION USUALLY ADEQUATE FOR MOST OPERATIONS.
Other Protective Equipment:CLEAN BODY COVERING CLOTHING
Work Hygienic Practices:REASONABLE CARE SHOULD BE TAKEN IN HANDLING
THIS PRODUCT.
Supplemental Safety and Health
SSR ULTRA COOLANT SYNTHETIC COOLANT IS SPECIFFICALLY FORMULATED FOR USE
IN INGERSOLL-RAND ROTARY AIR COMPRESSORS.
================== Physical/Chemical Properties ==================
HCC:V5
Melt/Freeze Pt:M.P/F.P Text:N/E
Vapor Pres:<0.01 MMHG@20C
Vapor Density:N/D
Spec Gravity:0.9901@25/25C
pH:9
Viscosity:2400 CST @ 0F
Solubility in Water:<1GM/100GM
Appearance and Odor:LIGHT AMBER LIQUID; LOW ODOR
Percent Volatiles by Volume:N/E
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS
Stability Condition to Avoid:STABLE UNDER NORMAL CONDITIONS
Hazardous Decomposition Products:BURNING PRODUCES CARBON DIOXIDE,
CARBON MONOXIDE AND WATER
=================== Toxicological Information===================
Toxicological Information:LD50 FOR SKIN ABSORPTION IN RABBITS >2000
MG/KG. SYSTEMIC & OTHER EFFECTS: OBSERVATIONS IN ANIMALS EXPOSED TO
EXCESSIVE AMOUNTS OF POLYGLYCOL IN PRODUCT INCLUDE SLIGHT KIDNEY &
LIVER EFFECTS.
===================== Ecological Information =====================
Ecological:NOT PROVIDED
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
===================== Regulatory Information =====================
Federal Regulatory Information:NOT A HAZARDOUS CHEMICAL UNDER OSHA
HAZARD COMMUNICATION STANDARD.
State Regulatory Information:NOT PROVIDED
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:MIL-H-46001D, ISO VG 68 HYDRAULIC FLUID
Preparer's Name:PATRICK KAINES
CAGE:DO685
CAGE:8Y842
CAGE:2X769
CAGE:DO685
============= Composition/Information on Ingredients =============
Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES,HYDROTREATED
(MILD),HEAVY PARAFFINIC/PETROELUM BASE STOCK
CAS:64742-54-7
RTECS #:PY8035500
Fraction by Wt: 90- 100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3 (OIL MIST)
ACGIH TLV:5 MG/M3 (OIL MIST)
===================== Hazards Identification =====================
LD50 LC50 Mixture:TLV FOR OIL MIST IS 5 MG/M3.
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:NONE. ACUTE-
EYES/SKIN/ORAL:NOT NORMALLY EXPECTED TO CAUSE ANY ILL EFFECTS
EXCEPT IN VERY SENSITIVE INDIVIDUALS. INHALE:NO SIGNIFICANT ADVERSE
HEALTH EFFECTS ARE EXPECTED TO OCCUR ON SHO RT TERM EXPOSURE.
CHRONIC- MAY CAUSE MILD SKIN IRRITATION & INFLAMMATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:MILD SKIN IRRITATION AND INFLAMMATION
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH
AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15
MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:DO
NOT IN DUCE VOMITING. IF CONSCIOUS, RINSE MOUTH WITH WATER. SEEK
IMMEDIATE MEDICAL ATTENTION. IF SPONTANEOUS VOMITING OCCURS, KEEP
HEAD BELOW HIPS.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:>437F,>225C
Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATERFOG.
Fire Fighting Procedures:DO NOT ENTER ANY ENCLOSED OR CONFINED AREA
WITHOUT PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING
APPARATUS.
Unusual Fire/Explosion Hazard:SLIGHTLY COMBUSTIBLE, WHEN HEATED ABOVE
FLASH POINT WILL RELEASE FLAMMABLE VAPORS WHICH CAN BURN IN OPEN OR
BE EXPLOSIVE IN CONFINED SPACES IF IGNITED.
================== Accidental Release Measures ==================
Spill Release Procedures:PICK UP SPILL WITH INERT MATERIAL SUCH AS
SAND, CLAY, EARTH. SHOVEL INTO CONTAINERS FOR DISPOSAL. PREVENT
RUN-OFF TO ENTER WATERWAYS, SEWERS.
Neutralizing Agent:NOT RELEVANT
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM OPEN FLAMES AND STRONG
OXIDIZERS. KEEP OUT OF REACH OF CHILDREN. EXCESSIVE MISTING MAY
CAUSE SLIPPERY FLOOR.
Other Precautions:AVOID CONTACT WITH EYES AND SKIN. WASH THOROUGHLY
AFTER HANDLING. LAUNDER CLOTHING BEFORE REUSE. AVOID INHALING
MISTS. EMPTY CONTAINERS OF THIS PRODUCT MAY BE HAZARDOUS DUE TO THE
RETENTION OF RESIDUE S. DO NOT TAKE INTERNALLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED. IF WORKING IN CONFINED
AREAS, IF EXCESSIVE MISTING IS EXPECTED OR IF EXPOSURE MAY OR DOES
EXCEED RECOMMENDED PERMISSIBLE EXPOSURE LIMITS (PEL), WEAR
NIOSH-APPROVED ORGANIC VAPO R RESPIRATOR.
Ventilation:GENERAL ROOM VENTILATION SHOULD BE SUFFICIENT.
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
SHOES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:V6
Boiling Pt:B.P. Text:>617F/325C
Vapor Pres:>.01 MMHG
Vapor Density:>1.0
Spec Gravity:0.879
Evaporation Rate & Reference:LESS THAN ETHER
Solubility in Water:INSOLUBLE
Appearance and Odor:AMBER OILY LIQUID, PETROLEUM ODOR.
Percent Volatiles by Volume:NIL
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:DO NOT HEAT ABOVE FLASH POINT
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN AN APPROPRIATE DISPOSAL FACILITY
IN COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
INCINERATION IS RECOMMENDED.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:BRAYCO 340
CAGE:DO827
CAGE:DO827
DIV
CAGE:2R128
============= Composition/Information on Ingredients =============
Ingred Name:PETROLEUM HYDROCARBONS
Fraction by Wt: 100%
ACGIH TLV:5MG/CUM OIL MST
===================== Hazards Identification =====================
Effects of Overexposure:EYES:IRRITATION,OTHERWISE NOT EXPECTED TO CAUSE
ANY ILL EFFECTS IN VERY SENSITIVE INDIVIDUALS.
======================= First Aid Measures =======================
First Aid:INHAL:RMV TO FRESH AIR. IF NOT BRTHNG GIVE CPR; IF BRTHNG
DIFF GIVE OXYGEN. EYE:IMMED FLUSH W/PLENTY OF WATER. SKIN:WASH
W/SOAP & WATER. RMV CONTAM CLTHG & SHOES. INGEST:DO NOT INDUCE
VOMIT. NOTHG BY MOUTH IF UNCONSC. GET MEDICAL ATTN.
===================== Fire Fighting Measures =====================
Flash Point:300F,148.9C,COC
Extinguishing Media:CO*2,FOAM,DRY CHEM. AND WTR FOG.
Fire Fighting Procedures:USE SCBA IN ENCLSD AREAS.USE WTR ONLY AS
FOG/SPRAY
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:USE OIL ABS.GRANULES.DO NOT ALLOW OIL TO ENTER
STREAMS,WATERWAYS.STORE IN METAL CONTAINERS.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CNTNRS CLSD.KEEP AWAY FROM
HEAT,OPEN FLAMES.DO NOT STORE NEAR FLAME OR STRG OXIDANTS.
Other Precautions:AVOID PROLONGED SKIN CONTACT,OR PROLONGED BREATHING
OF VAPORS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NORMALY NOT NEEDED.USE SUPPLIED AIR
RESP.PROTECTN IN ENCLSD AREAS.
Ventilation:LOCAL EXHAUST,PROVIDE GRT.THAN 60 FPM VEL. FOR ENCLSD
SPACES
Other Protective Equipment:CHEM.RESISTANT APRON
Supplemental Safety and Health
MSDS DATED 9-29-85
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:>500F,260C
Spec Gravity:0.923
Solubility in Water:COMPLETE
Appearance and Odor:AMBER LIQ,PETROLEUM ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRG OXIDIZING AGTS.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:CO,SMOKE,ASPHYXIANTS
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATION OR SANITARY LANDFILL.DISPOSE OF IAW
LOCAL,STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:DECONTAMINATING AGENT, STB
Preparer's Name:DGSC-SSH
CAGE:PENNS
CAGE:PENNS
============= Composition/Information on Ingredients =============
Ingred Name:CHLORINATED LIME
Fraction by Wt: 93.4%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.5 PPM (CHLORINE)
ACGIH TLV:0.5 PPM (CHLORINE)
Ingred Name:CALCIUM OXIDE
CAS:1305-78-8
RTECS #:EW3100000
Fraction by Wt: 6.6%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3
ACGIH TLV:2 MG/M3; 9293
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS 900 MG/KG (HCL)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE, SKIN & RESPIRATORY TRACT
IRRITATION.
Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS
LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:CAN CAUSE BURNS TO EYES AND SKIN. INHALATION OF
VAPORS, FUMES AND DUST CAN CAUSE IRRITATION TO MUCOUS MEMBRANES.
Medical Cond Aggravated by Exposure:OVEREXPOSURE MAY AGGRAVATE EXISTING
CHRONIC RESPIRATORY CONDITIONS SUCH AS ASTHMA, BRONCHITIS AND
INFLAMMATORY OR FIBROTIC RESPIRATORY DISEASE.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION. EYES: IMMEDIATELY
FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION.
SKIN: FLUSH W ITH WATER. REMOVE CONTAMINATED CLOTHING. INGESTION:
POISON! IF CONSCIOUS, GIVE MILK, EGG WHITE, STARCH PASTE OR MILK OF
MAGNESIA BY MOUTH. DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:NONE
Extinguishing Media:USE WATER, PREFERABLY IN FORM OF SPRAY.
Fire Fighting Procedures:WEAR A NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT WHEN FIGHTING FIRES.
Unusual Fire/Explosion Hazard:POWERFUL OXIDIZING MATERIAL. NOT
COMBUSTIBLE BUT EVOLVES OXYGEN AT HIGHER TEMPERATURES. READILY
IGNITES COMBUSTIBLE OR ORGANIC MATERIALS WHEN IN CONTACT.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE SOURCES OF IGNITION. WEAR NIOSH
FROM ORGANIC MATERIAL. MIX WITH DRY EARTH OR SAND AND PLACE IN
DISPOSAL DRUM. FLUSH RESIDUE WI TH LARGE QUANTITIES WATER.
Neutralizing Agent:DILUTE WITH LARGE AMOUNTS OF WATER
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY PLACE AWAY FROM ALL
SOURCES OF HEAT. DO NOT STORE NEAR COMBUSTIBLES, ACIDS OR OTHER
ORGANIC MATTER. PROTECT & INSPECT CONTAINERS.
Other Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN USE. PROTECT
AGAINST PHYSICAL DAMAGE. DRUMS MAY RUPTURE FROM EXPOSURE TO HEAT.
AVOID STORAGE FOR PROLONGED PERIODS, PARTICULARLY AT SUMMER
TEMPERATURES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SELECT A NIOSH APPROVED RESPIRATOR BASED ON
CONTAMINATION LEVELS FOUND IN THE WORK PLACE. FOR HIGH LEVELS, A
SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN
PRESSURE DEMAND OR POSIT IVE PRESSURE IS RECOMMENDED.
Ventilation:LOCAL EXHAUST WHERE DUST MIGHT OCCUR.
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED. SHOULD WEAR
SAFETY BOOTS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING, DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
SUPERTROPICAL BLEACH IS A MIXTURE OF CHLORINATED LIME AND CALCIUM OXIDE
IN A WHITE POWDER FORM. WHEN MANUFACTURED IT CONTAINS 30 PERCENT
AVAILABLE CHLORINE. STB DECOMPOSES SLOWLY IN STORAGE EASILY REC
OGNIZED BY THE CHLORINE LIKE ODOR. IT IS CORROSIVE TO MOST METALS
AND INJURIOUS TO MOST FABRICS.
================== Physical/Chemical Properties ==================
HCC:D1
Decomp Temp:Decomp Text:>120F,>49C
Vapor Density:1.2 (HCL)
Spec Gravity:0.75
pH:BASIC
Solubility in Water:APPRECIABLE
Appearance and Odor:WHITE POWDER, STRONG CHLORINE ODOR.
Corrosion Rate:FAST
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:NO
MOISTURE, SOLVENTS, ACIDS, AND ORGANIC MATERIALS.
Stability Condition to Avoid:HIGH TEMPERATURES AND MOIST CONDITIONS.
Hazardous Decomposition Products:MAY UNDERGO ACCELERATED DECOMPOSITION
WITH EVOLUTION OF HEAT, HYDROGEN CHLORIDE AND CHLORINE GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:28F1037G2
CAGE:KO200
CAGE:KO200
CAGE:01002
============= Composition/Information on Ingredients =============
Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III)
CAS:1336-36-3
RTECS #:TQ1350000
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES
CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA)
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/WATER IMMED.SKIN:WASH W/SOAP IMMED.INHAL:REMOVE
TO FRESH AIR.GIVE ART.RESPIR. AS NEEDED.INGEST:GET MEDICAL
ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING BUT DO NOT MAKE
UNCONSCIOUS PE RSON VOMIT.
================== Accidental Release Measures ==================
Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT
RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD
Ventilation:LOCAL EXHAUST
Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT
Supplemental Safety and Health
OVEREXPOS:CAN CAUSE FORMATION OF CYSTS.CAUSES STILLBIRTHS.IRRITATES
EYES,NOSE,THROAT.
================== Physical/Chemical Properties ==================
HCC:Z3
Appearance and Odor:LIGHT STRAW COLORED LIQUID,AROMATIC ODOR.
================= Stability and Reactivity Data =================
STRONG OXIDIZERS
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH
TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ULTRA ERA
CAGE:04547
CAGE:5B465
CAGE:04547
============= Composition/Information on Ingredients =============
Ingred Name:ETHANOL (ETHYL ALCOHOL), TECSOL, ALCOHOL
CAS:64-17-5
RTECS #:KQ6300000
Other REC Limits:1900 MG/CUM
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM
Ingred Name:2-AMINOETHANOL, ETHANOLAMINE, MONOETHANOLAMINE
CAS:141-43-5
RTECS #:KJ5775000
Other REC Limits:3 PPM
OSHA PEL:3 PPM
ACGIH TLV:7.5 MG/CUM
Ingred Name:ANIONIC SURFACTANT
Ingred Name:SURFACTANT (NON IONIC)
Ingred Name:ENZYMES
Ingred Name:WATER SOFTENERS
Ingred Name:DISPERSAL AGENT
Ingred Name:BUFFERING AGENTS
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Ingred Name:STABILIZING AGENT
Ingred Name:SOIL SUSPENDING AGENT
Ingred Name:FABRIC WHITENER
Ingred Name:COLORANT
Ingred Name:PERFUME,TYPE UNSPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INGESTION: MAY CAUSE MILD GI TRACT
IRRITATION. EYES: MAY CAUSE MILD-MODERATE TRANSIENT IRRITATION.
SKIN: TRANSIENT IRRITATION W/PROLONGED EXPOSURE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, NAUSEA, VOMITING, DIARRHEA,
STINGING, TEARING, ITCHING, SWELLING, REDNESS, DRYING.
======================= First Aid Measures =======================
First Aid:INGESTION: DRINK A GLASSFUL OF WATER. EYES: FLUSH W/WATER FOR
10-15 MINS. SKIN: RINSE THOROUGHLY W/WATER. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:>200F
Extinguishing Media:C02, WATER.
Fire Fighting Procedures:PRODUCT IS AN AQUEOUS SOLUTION CONTAINING
ETHYL ALCOHOL & DOESN'T SUSTAIN COMBUSTION.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL: FLUSH DOWN ACCEPTABLE SEWER. PREVENT
FROM REACHING A WATERWAY. SORBENTS MAY BE USED.
======================Handling and Storage ======================
Handling and Storage Precautions:NO UNUSUAL PRECAUTIONS NECESSARY.
Other Precautions:KEEP OUT OF REACH OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED W/NORMAL USE.
Ventilation:MECHANICAL (GENERAL): NORMAL/GENERAL DILUTION IS
ACCEPTABLE.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:191F
Spec Gravity:1.107
Solubility in Water:COMPLETE
Appearance and Odor:BLUE COLOR W/PERFUMED ODOR.
Percent Volatiles by Volume: 67
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:SMALL/HOUSEHOLD: DISPOSE OF IN REFUSE/IN SEWER.
LARGE: INCINERATION IS PREFERRED. DON'T LANDFILL. DISPOSE OF
IAW/FEDERAL, STATE & LOCAL REGULATIONS.
| 0 | eyes_protection_not_mandatory |
===================== Product Identification =====================
Product ID:S76970 PHENOLPHTHALEIN SOLUTION 1 %
Resp. Party Other MSDS Num.:ACC#45376
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:ISOPROPYL ALCOHOL. LD50:(ORAL,RAT) 5045 MG/KG. EXPOSURE
LIMITS: NIOSH - 400 PPM TWA; 980 MG/M3 TWA; 2000 PPM IDLH (10%
LOWER EXPLO LIMIT). EINECS/ELINC = 200-661-7.
CAS:67-63-0
RTECS #:NT8050000
= Wt:99.
OSHA PEL:980 MG/M3;400 PPM
ACGIH TLV:983 MG/M3;400 PPM
ACGIH STEL:1230 MG/M3;500 PPM
Ingred Name:PHENOLPHTHALEIN. EINECS/ELINC = 201-004-7.
CAS:77-09-8
RTECS #:SM8380000
= Wt:1.
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS & TOXICOLOGICAL INFO.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYE:MAY CAUSE IRRIT. PRDCES
IRRIT, CHARACT BY BURNING SENSATION, REDNESS, TEARING INFLAMM &
POSS CORNEAL INJURY. SKIN:MAY CAUSE IRRIT. MAY CAUSE SENSIT,
ALLERGIC RXN, WHICH BECOMES EVID UPON RE- EXPOS TO THIS MATL. PRLNG
&/OR RPTD CONT MAY CAUSE DEFAT OF SKIN & DERM. MAY CAUSE IRRIT
W/PAIN & STINGING, ESP IF SKIN IS ABRADED. MAY BE ABSORBED THRU
SKIN. INGEST:MAY CAUSE IRRIT OF DIGEST TRACT. M AY CAUSE GI IRRIT
W/NAUS, VOMIT & DIARR. MAY CAUSE KIDNEY DMG. MAY CAUSE CNS DEPRESS,
CHARACT BY EXCITEMENT, FOLLOWED BY HDCH, DIZZ, DROW, COMA & POSS
DEATH DUE TO RESP FAILURE. EXPECTED TO BE LOW ING EST HAZ.
INHAL:INHAL OF(EFTS OF OVEREXP)
Explanation of Carcinogenicity:ISOPROPYL ALCOHOL - CAS #67-63-0; IARC:
GROUP 3 CARCINOGEN. PHENOLPHTHALEIN - CAS #77-09-8; NOT LISTED BY
ACGIH, IARC, NIOSH, NTP OR OSHA.
Effects of Overexposure:HLTH HAZ:HIGH CONCS MAY CAUSE CNS EFTS CHARACT
BY HDCH, DIZZ, UNCON & COMA. MAY CAUSE RESP TRACT IRRIT. INHAL OF
VAP MAY CAUSE RESP TRACT IRRIT. LOW HAZ FOR USUAL INDUS HNDLG.
CHRONIC: POSS CANCER HAZ BASED ON TESTS W/LAB ANIMALS. PRLNG/RPTD
SKIN CONT MAY CAUSE DEFAT & DERM. MAY CAUSE KIDNEY INJURY. MAY
CAUSE CANCER ACCORDING TO ANIMAL STUDIES. MAY CAUSE ALLERGIC SKIN
RXN IN SOME INDIVIDUALS. MAY CAUSE REPRO & FETAL EFTS. TARGET
ORGANS: KIDNEYS, CENTRAL NERVOUS SYSTEM.
======================= First Aid Measures =======================
First Aid:EYES:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS, OCCAS
LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. SKIN:FLUSH W/PLENTY
OF SOAP & WATER FOR AT LST 15 MINS WHILE REMOVING CONTAM CLTHG &
SHOES. GET MED AID IF IRRIT DEVELS/PERSISTS. FLUSH SKIN W/PLENTY
OF SOAP & WATER. INGEST:IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4
CUPFULS OF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS.
GET MED AI D IMMED IF IRRIT/SYMPS OCCUR. INHAL:REMOVE FROM EXPOS TO
FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT,
GIVE OXYG. GET MED AID IMMED IF COUGH/OTHER SYMPS APPEAR. NOTE TO
MD:TREAT SY MPTOMATICALLY & SUPPORTIVELY.
===================== Fire Fighting Measures =====================
Flash Point:=12.8C, 55.F
Autoignition Temp:=398.9C, 750.F
Lower Limits:2.0%
Upper Limits:12.7%
Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE,
WATER SPRAY OR ALCOHOL-RESISTANT FOAM. FOR SMALL FIRES, USE WATER
SPRAY, DRY CHEMICAL, CARBON DIOXIDE OR CHEMICAL FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . VAPORS CAN TRAVEL TO A SOURCE OF IGNITION & FLASH BACK.
USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. WATER MAY BE
INEFFECTIVE.
Unusual Fire/Explosion Hazard:CNTNRS MAY EXPLODE IN HEAT OF FIRE. THIS
CHEM POSES AN EXPLOSION HAZ. MAY FORM EXPLOSIVE PEROXIDES. VAPS MAY
BE HVR/AIR. THEY CAN SPREAD ALONG THE GROUND & COLLECT IN LOW OR
CONFINED AREAS. NFPA RATIN G: NOT PUBLISHED.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PPE AS INDICATED IN EXPOS CONTROLS,
PERSONAL PROT SECTION. ABSORB SPILL W/INERT MATL (E.G., DRY
SAND/EARTH), THEN PLACE INTO CHEM WASTE CNTNR. SWEEP UP, THEN PLACE
INTO SUITABLE CNTNR FOR D ISP. REMOVE ALL SOURCES OF IGNIT.
======================Handling and Storage ======================
Handling and Storage Precautions:USE SPK-PROOF TOOLS & EXPLO PROOF
EQUIP. AVOID CONT W/EYES, SKIN & CLTHG. EMPTY CNTNRS RETAIN PROD
RESIDUE, (LIQ &/OR VAP) & CAN BE DANGEROUS. KEEP CNTNR TIGHTLY
CLSD. AVOID INGEST & INHAL. DO NOT PRE SSURIZE, CUT, WELD, BRAZE,
SOLDER, DRILL, GRIND/EXPOSE EMPTY CNTNRS TO HEAT, SPKS/OPEN FLAMES.
Other Precautions:USE W/ADEQ VENT. KEEP AWAY FROM HEAT, SPKS & FLAME.
KEEP AWAY FROM SOURCES OF IGNIT. KEEP CNTNR CLSD WHEN NOT IN USE.
KEEP FROM CONT W/OXIDIZING MATLS. STORE IN COOL, DRY, WELL-VENTED
AREA AWAY FROM I NCOMPAT SUBSTANCES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A NIOSH APPRVD/EUROPEAN STD EN 149 AIR PURIFYING
RESP W/ORG VAP CARTRIDGE/CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCS ARE EXPECTED. A RESP PROT
PROGRAM THAT MEETS OSHA 'S 29 CFR 1910.134 & ANSI Z88.2
REQUIREMENTS/EUROPEAN STD EN 149 MUST BE FOLLOWED WHENEVER
WORKPLACE CNDTNS WARRANT RESP'S USE. FOLLOW OSHA RESP (SUPP DATA)
Ventilation:GOOD GENERAL VENT SHOULD BE SUFFICIENT TO CONTROL AIRBORNE
LEVELS. USE ADEQUATE GENERAL OR LOCAL EXHAUST VENT TO KEEP AIRBORNE
CONCS BELOW PELS.
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . WEAR APPROP PROT CLTHG TO MIN CONT W/SKIN OR TO PREVENT
SKIN EXPOS.
Work Hygienic Practices:WASH THORO AFTER HNDLG. WASH HANDS BEFORE
EATING. REMOVE CONTAM CLTHG & WASH BEFORE REUSE.
Supplemental Safety and Health
RESP PROT:REGS FOUND IN 29 CFR 1910.134/EUROPEAN STD EN 149. ALWAYS USE
NIOSH/EUROPEAN STD EN 149 NIOSH APPRVD RESP WHEN NEC. PHYSICAL
DATA: MOLECULAR FORMULA:MIXTURE. TOX INFO:NEUROTOXICITY:NO DATA A
VAIL. MUTAGENICITY:SIGNIFICANT INCRS IN CHROMOSOMAL ABERRATIONS
WERE OBSERVED AFTER TREATMENT OF CULTURED (OTHER INFO)
================== Physical/Chemical Properties ==================
Boiling Pt:=83.C, 181.4F
Melt/Freeze Pt:=89.C, 192.2F
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Pres:40 MM HG
Vapor Density:2.1
Spec Gravity:0.7855
pH:NOT AVAILABLE
Viscosity:NOT AVAILABLE
Solubility in Water:SOLUBLE
Appearance and Odor:COLORLESS LIQUID; ALCOHOL-LIKE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, ISOPROPANOL IS SUSCEPTIBLE TO AUTOXIDATION &
THEREFORE SHOULD BE CLASSIFIED AS PEROXIDIZABLE.
Stability Condition to Avoid:THIS MATERIAL MAY BE SENSITIVE TO PEROXIDE
FORMATION, INCOMPATIBLE MATERIALS, IGNITION SOURCES, EXCESS HEAT.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, ACRID
SMOKE & FUMES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information===================
Toxicological Information:LD50/LC50:CAS #67-63-0: LD50:(ORAL,MOUSE)
3600 MG/KG; LD50:(ORAL,RABBIT) 6410 MG/KG; LD50:(SKIN,RABBIT)
12,800 MG/KG. EPIDEMIOLOGY:NTP REPORTED THAT THERE WAS CLEAR EVID
OF CARCIN ACTIVITY IN MALE RAT S BASED ON MARKEDLY INCRD INCIDENCES
OFBENIGN PHEOCHROMOCYTOMA OF ADRENAL MEDULLA & OTHERS. THERE WAS
CLEAR EVID IN MICE BASED ON INCR INCIDENCES OF HISTIOCYTIC SARCOMA
& MALIGNANT LYMPHOMA OF THYMIC ORIGIN. THERE WAS ALSO CLEAR EVID
IN FEMALE MICE BASED ON INCR INCIDENCES OF HISTIOCYTIC SARCOMA,
MALIGNANT LYMPHOMAS & BENIGN SEX-CORD STROMAL TUMORS OF OVARY.
TERATOGENICITY:NO DATA AVAIL. REPRO EFT S:NO DATA AVAIL.(SUPP DATA)
===================== Ecological Information =====================
Ecological:ECOTOXICITY:NOT AVAIL. ENVIRON FATE:NOT AVAIL.
PHYSICAL/CHEM:NOT AVAIL. OTHER:NOT AVAIL. -- OTHER INFO:PHRASES:S16
KEEP AWAY FROM SOURCES OF IGNIT - NO SMOKING. S24/25 AVOID CONT
W/SKIN & EYES. WGK (W ATER DANGER/PROT):CAS #67-63-0: 1; CAS
#77-09-8: 1. CANADA: CAS #67-63-0 IS LISTED ON CANADA'S DSL/NDSL
LIST. CAS #77-09-8 IS LISTED ON CANADA'S DSL/NDSL LIST. THIS PROD
HAS WHMIS CLASSIFICATION OF B2 , D2B. CAS #67-63-0 IS NOT LISTED ON
CANADA'S ING DISCLOSURE LIST. CAS # 77-09-8 IS NOT LISTED ON
CANADA'S ING DISCLOSURE LIST. EXPOS LIMS: CAS #67-63-0:
OEL-AUSTRALIA:TWA 400 PPM (980 MG/M3); STEL 50 0 PPM (1225 MG/M3)
(TRANSPORT INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT W/FEDERAL,
STATE & LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF
CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE
LEVELS: NONE LISTED. RCRA F-SERIES: NONE LISTED. RCRA P-SERIES:
NONE LISTED. RCRA U-SERIES: NONE LISTED.
=================== MSDS Transport Information ===================
Transport Information:U.S. DOT:SHIPPING NAME:FLAMM LIQ, N.O.S. (CNTNS
2-PROPANOL). HAZ CLASS: 3. UN #:UN1993. PACKING GRP:II.
IATA:SHIPPING NAME:NO INFO AVAIL. RID/ADR:SHIPPING NAME:NO INFO
AVAIL. IMO: SHIPPING NAME:NO INF O AVAIL. FLAMM LIQ N.O.S.
(2-PROPANOL). HAZ CLASS: 3. UN #:UN1993. PACKING GRP:II. ADDNL
INFO:FL PT 12C. -- ECOLOGICAL INFO:OEL-BELGIUM:TWA 400 PPM (985
MG/M3); STEL 500 PPM (1230 MG/M3) OEL-DENMARK:T WA 200 PPM (490
MG/M3); SKIN OEL-FRANCE:STEL 400 PPM (980 MG/M3) OEL GERMANY:TWA
400 PPM (980 MG/M3) OEL-JAPAN:STEL 400 PPM (980 MG/M3) OEL-THE
NETHERLANDS:TWA 400 PPM (980 MG/M3); SKIN OEL-THE PHILIP PINES:TWA
400 PPM (SARA TITLE III)
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ & TPQ):NONE OF CHEMS IN THIS
MATL HAVE RQ/TPQ. SARA CODES:CAS #67-63-0:ACUTE, CHRONIC, FLAMM.
CAS #77-09-8:ACUTE. SECTION 313: THIS MATL CNTNS ISOPROPYL ALCOHOL
(CAS #67-63-0, 99%), WH ICH IS SUBJECT TO REPORTING REQUIREMENTS OF
SECTION 313 OF SARA TITLE III & 40 CFR PART 373. -- TRANSPORT
INFO:(980 MG/M3) OEL-RUSSIA:STEL 400 PPM (10 MG/M3 OEL-SWEDEN:TWA
150 PPM (350 MG/M3; STEL 250 PPM (600 MG/M3) OEL-SWITZERLAND:TWA
400 PPM (980 MG/M3); STEL 800 PPM OEL-TURKEY:TWA 200 PPM (500 MG/M3
OEL-UNITED KINGDOM:TWA 400 PPM (980 MG/M3); STEL 500 PPM; SKIN OEL
IN BULGARIA, COLOMBIA, JORDA N, KOREA CHECK (STATE REGULATORY INFO)
Federal Regulatory Information:TSCA:CAS #67-63-0 IS LISTED ON TSCA
INVENTORY. CAS #77-09-8 IS LISTED ON TSCA INVENTORY. HLTH & SFTY
REPORTING LIST:CAS #67-63-0: EFTIVE DATE: DEC 15, 1986; SUNSET
DATE: DEC 15, 1996. CHEM TEST RULES: CAS #67-63-0:TESTING REQD
BY:MFRS, IMPORTERS; PROCESSORS (40. SECTION 12B:CAS #67-63-0:EXPORT
NOTIFICATION REQD - SECTION 4. TSCA SIGNIFICANT NEW USE RULE:NONE
OF CHEMS IN THIS MATL HAVE SNUR UNDER TS CA. CLEAN AIR ACT:THIS
MATL DOES NOT CNTN ANY HAZ AIR POLLUTANTS. THIS MATL DOES NOT CNTN
ANY CLASS 1 OZONE DEPLETORS. THIS MATL DOES NOT CNTN ANY CLASS 2
OZONE DEPLETORS. CLEAN WATER ACT:NONE OF CHEMS IN THIS PROD ARE
LISTED (OTHER INFO)
State Regulatory Information:CAS #67-63-0 CAN BE FOUND ON FOLLOWING
STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY, FLORIDA,
PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. CAS #77-09-8 IS NOT PRESENT
ON STATE LISTS FROM CA, PA, MN, M A, FL OR NJ. CALIFORNIA NO
SIGNIFICANT RISK LEVEL:NONE OF CHEMS IN THIS PROD ARE LISTED. --
SARA TITLE III: ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM
CHECK ACGIH TLV.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:REGULAR RXL GASOLINE
CAGE:15445
CAGE:15445
============= Composition/Information on Ingredients =============
Ingred Name:BENZENE (SARA III)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: 2%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1PPM/5STEL;1910.1028
ACGIH TLV:10 PPM; A2; 9192
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:ETHYL BENZENE (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 2%
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM/125 STEL
ACGIH TLV:100 PPM/125STEL 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:CUMENE (SARA III)
CAS:98-82-8
RTECS #:GR8575000
Fraction by Wt: 1%
Other REC Limits:NONE SPECIFIED
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 50 PPM; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:1,2,4-TRIMETHYLBENZENE (SARA III)
CAS:95-63-6
RTECS #:DC3325000
Fraction by Wt: 2%
Other REC Limits:NONE SPECIFIED
OSHA PEL:25 PPM
ACGIH TLV:25 PPM; 9192
Ingred Name:METHYL TERT-BUTYL ETHER (SARA III)
CAS:1634-04-4
RTECS #:KN5250000
Fraction by Wt: <15%
Other REC Limits:NONE SPECIFIED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 15%
Other REC Limits:NONE SPECIFIED
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 12%
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:"NOT HAZARDOUS" - INFORMATION IS WITHHELD AS TRADE SECRET.
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE:EYE/SKIN/INHALATION:PROLONGED OR
REPEATED EXPOSURE MAY CAUSE IRRITATION.CHRONIC-INHALATION:HIGH
CONCENTRATION OF BENZENE HAVE CAUSED A SLIGHTLY HIGHER INCIDENCE OF
LEUKEMIA.
Explanation of Carcinogenicity:BENZENE
Effects of Overexposure:OVEREXPOSURE MAY CAUSE
WEAKNESS,HEADACHE,NAUSEA,CONFUSION,BLURRED VISION,DROWSINESS &
OTHER NERVOUS SYSTEM EFFECTS.GREATER EXPOSURE MAY CAUSE
DIZZINESS,SLURRED SPEECH,FLUSHED FACE,UNCONSCIOUSNESS OR C
ONVULSIONS.
Medical Cond Aggravated by Exposure:SEE OVEREXPOSURE SECTION.
======================= First Aid Measures =======================
First Aid:CALL A PHYSICIAN.SKIN:WASH IMMEDIATELY WITH SOAP AND
WATER.INHALATION:REMOVE TO FRESH AIR.GIVE CPR/OXYGEN IF
NEEDED.EYE:IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES.INGESTION:DO
NOT INDUCE VOMITING.GIV E LARGE QUANTITIES OF WATER.NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:-50F,-46C
Lower Limits:<1
Upper Limits:8
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.WATER MAY
BE INEFFECTIVE TO EXTINGUISH,BUT USE TO COOL FIRE-EXPOSED
CONTAINERS
Fire Fighting Procedures:IF A LEAK OR SPILL HAS NOT IGNITED,USE WATER
SPRAY TO DISPERSE THE VAPORS AND TO PROTECT PERSONNEL.WATER SPRAY
MAY BE USED TO FLUSH SPILLS AWAY.
Unusual Fire/Explosion Hazard:HIGHLY FLAMMABLE.PRODUCTS OF COMBUSTION
MAY CONTAIN CARBON MONOXIDE,CARBON DIOXIDE & OTHER TOXIC
MATERIALS.DO NOT ENTER ENCLOSED SPACE WITHOUT PROTECTIVE EQUIP.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN SPILL IMMEDIATELY IN SMALLEST POSSIBLE
AREA.RECOVER AS MUCH OF THE PRODUCT AS POSSIBLE BY SUCH METHODS AS
VACUUMING,FOLLOWED BY RECOVERING RESIDUAL FLUIDS BY USING ABSORBENT
MATERIALS.AVOID WA SHING MATERIAL TO STORM OR SANITARY SEWERS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN ACCORDANCE WITH NATIONAL FIRE
PROTECTION ASSOCIATION REGULATIONS.
Other Precautions:WORK IN A WELL VENTILATED AREA. AVOID CONTACT WITH
EYES, SKIN OR CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR. AIR-SUPPLIED
OR FILTERING TYPE WITH ORGANIC VAPOR CARTRIDGES ARE RECOMMENDED.
Ventilation:USE SUFFICIENT VENTILATION TO MAINTAIN ATMOSPHERIC
CONCENTRATIONS BELOW PERMISSIBLE EXPOSURE LIMITS.
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices:DO NOT TAKE INTERNALLY. AVOID SKIN CONTACT.
WASH SKIN AFTER USING PRODUCT. DO NOT EAT, DRINK OR SMOKE IN WORK
AREA.
Supplemental Safety and Health
NOTE TO PHYSICIAN:GASTRIC LAVAGE BY QUALIFIED MEDICAL PERSONNEL MAY BE
CONSIDERED, DEPENDING ON QUANTITY OF MATERIAL INGESTED.
================== Physical/Chemical Properties ==================
HCC:F1
Boiling Pt:B.P. Text:85.0F,29.4C
Vapor Pres:275 - 475
Vapor Density:>1
Spec Gravity:0.70 - 0.77
Solubility in Water:MAY BE SLIGHT
Appearance and Odor:BRONZE LIQUID WITH GASOLINE ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS AND AIR
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES
Hazardous Decomposition Products:CARBON MONOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:RECYCLE AS MUCH OF THE RECOVERABLE PRODUCT AS
POSSIBLE.TREATMENT,STORAGE,TRANSPORTATION AND DISPOSAL MUST BE IN
ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL LAWS AND
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:('R)-(+)-CAMPHOR, 85730-0
CAGE:60928
CAGE:60928
============= Composition/Information on Ingredients =============
Ingred Name:CAMPHOR, (1R, 4R)-(+)-; ((1R)-(+)-CAMPHOR)
CAS:464-49-3
RTECS #:EX1260000
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL MUS):1310 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE EFTS:HARMFUL IF SWALLOWED,
INHALED, OR ABSORBED THROUGH SKIN. CAUSES SEVERE EYE IRRITATION.
CAUSES SKIN IRRITATION. SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING
SENSATION, COUGHING, WHEEZING, LARYNG ITIS, SHORTNESS OF BREATH,
HEADACHE, NAUSEA, AND VOMITING. EXPOSURE CAN CAUSE:CONVULSIONS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/COPIOUS AMTS OF WATER FOR AT LEAST 15 MIN.
ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS WITH
FINGERS. SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. WHILE REMOVING
CONTAM CLTHG AND SHOES. REMOVE AND WASH CONTAM CLTHGPROMPTLY.
INHAL:REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTF RESP. IF
BRTHG IS DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN. INGEST:CALL MD
IMMED .
===================== Fire Fighting Measures =====================
Flash Point:148F,64C
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER,
ALCOHOL OR POLYMER FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:FLAMMABLE SOLID.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. SHUT OFF ALL SOURCES OF
UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. VENTILATE AREA AND
WASH SPILL SITE AFTER MATERIA L PICKUP IS COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT BREATHE DUST. DO NOT GET IN
EYES, ON SKIN, ON CLTHG. AVOID PRLNGD/RPTD EXPOS. SEV EYE IRRITANT.
HARMFUL SOLID AND FUMES. KEEP TIGHTLY CLSD.
Other Precautions:KEEP AWAY FROM HEAT/SPARKS/OPEN FLAME. STORE IN COOL
DRY PLACE. AVOID MIXING WITH AND STORING NEAR:CHLORATES,
NAPHTHALENE, P-DICHLOROBENZENE, ORGANIC SOLV, POTASSIUM
PERMANGANATE.SALTS OF ANY KIND SHO ULD NOT BE ADDED TO CAMPHOR
WATER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Other Protective Equipment:PROTECTIVE CLOTHING. SAFETY SHOWER AND EYE
BATH.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:F8
Melt/Freeze Pt:M.P/F.P Text:>349F,>176C
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG REDUCING AGENTS, CHLORINATED SOLVENTS.
Stability Condition to Avoid:HEAT & DIRECT SUNLIGHT
Hazardous Decomposition Products:TOXIC FUMES OF:CARBON MONOXIDE, CARBON
DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE & LOCAL LAWS.
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: ABRASIVE DISCS, SILICONE CARBIDE, 810-203-200
Cage: FO436
=======================================================
Contractor Summary
=======================================================
Cage: 94174
Cage: FO436
Box: NK/
=======================================================
Ingredients
=======================================================
Cas: 409-21-2
RTECS #: VW0450000
% Wt: 20-50
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
% Wt: 15-60
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
% Wt: 10-40
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:EYES:DUST FROM ABRADED SURFACE MAY CAUSE MECHANICAL
IRRITATION. SKIN/INGESTION:NO ADVERSE HEALTH EFFECTS EXPECTED.
INHALATION:OVEREXPOSURE TO DUST FROM ABRADED SURFACE MAY CAUSE RESPIRATORY
SYST EM IRRITATION. HAZARD DEGREE BASED ON MATERIAL BEING ABRADED.
CHRONIC:NOT AVAILABLE.
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NOT AVAILABLE.
First Aid: INGEST:CALL MD IMMEDIATELY (FP N). SKIN:FLUSH W/COPIOUS AMOUNTS OF
WATER. CALL MD (FP N). EYES:FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES
& CALL MD IF IRRITATION PERSISTS. INHAL:PROVIDE FRESH AIR , TREAT FOR
SUBSTRATE MATERIAL BEING ABRADED.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: NO SPECIAL PROCEDURES.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: COLLECT MATERIAL & DISPOSE IN A LOCAL SANITARY
LANDFILL. FOLLOW FEDERAL, STATE & LOCAL REGULATIONS.
Handling And Storage Precautions: KEEP CONTAINER CLOSED. NO SPECIAL HANDLING
PRECAUTIONS.
Other Precautions: AVOID BREATHING DUST FROM MATERIAL BEING GROUND. PREVENT
SKIN OR EYE CONTACT W/DUST CREATED FROM GRINDING SUBSTRATE. NO UNUSUAL FIRE
OR SPILL HAZARD; NUISANCE-LEVEL HEALTH RISK.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NONE
Lower Limits: NONE
Upper Limits: NONE
Extinguishing Media: WATER, CARBON DIOXIDE, FOAM.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NON-FLAMMABLE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: WEAR A NIOSH APPROVED PARTICULATE FACE MASK WHERE DUST
IS GENERATED.
Ventilation: NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI
DESIGN CRITERIA (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Physical/Chemical Properties
=======================================================
Appearance and Odor: SOLID ABRASIVE PRODUCT; NO ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NOT DETERMINED.
Hazardous Decomposition Products: THERMAL DEGRADATION WILL PRODUCE CARBON
MONOXIDE, CARBON DIOXIDE & SMOKE PARTICULATES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: ABRASIVE DISCS, SILICONE CARBIDE, 810-203-200
Cage: FO436
Assigned IND: Y
Company Name: LECO CORPORATION
Street: 3000 LAKEVIEW AVENUE
PO Box: NK/
Zipcode: 49085
Label Required IND: Y
Date Of Label Review: 11/16/1998
Status Code: C
Label Date: 11/16/1998
Origination
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE:EYES:DUST FROM ABRADED SURFACE MAY CAUSE
MECHANICAL IRRITATION. INHALATION:OVEREXPOSURE TO DUST FROM ABRADED SURFACE
MAY CAUSE RESPIRATORY SYSTEM IRRITATION. HAZARD DEGREE BASED ON MATERIAL BEIN
G ABRADED. CHRONIC:NONE LISTED BY MANUFACTURER.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:140-0571, SUPERACRYLIC CONTROLS RUST SPRAY ENAMEL
CAGE:54636
CAGE:54636
============= Composition/Information on Ingredients =============
Ingred Name:PROPANE (PROPELLANT) VP: 760
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 14%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT
Ingred Name:PROPANE, 2-METHYL-; (2-METHYLPROPANE (PROPELLANT))VP: 760
CAS:75-28-5
RTECS #:TZ4300000
Fraction by Wt: 14%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TOLUENE (SARA III) VP: 22
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 4%
OSHA PEL:100 PPM; 150 STEL
ACGIH TLV:50 PPM; S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:BENZENE, ETHYL-; (ETHYLBENZENE) (SARA III) VP:7.1
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 2%
OSHA PEL:100 PPM; 125 STEL
ACGIH TLV:100 PPM; 125 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:XYLENE (SARA III)VP: 5.9
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 16%
OSHA PEL:100 PPM; 150 STEL
ACGIH TLV:100 PPM; 150 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ACETONE (SARA III) VP: 180
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 26%
OSHA PEL:750 PPM; 1000 STEL
ACGIH TLV:750 PPM; 1000 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:PROPIONIC ACID, 3-ETHOXY-, ETHYL ESTER; (ETHYL
3-ETHOXYPROPIONATE) VP: 1.1
CAS:763-69-9
RTECS #:UF3325000
Fraction by Wt: 4%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 7%
OSHA PEL:10 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:SUPDAT:NOT SMOKE. EXTING ALL FLAMES, PILOT LIGHTS &
HEATERS. TURN OFF STOVES, ELEC TOOLS & APPLIANCES & OTHER (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:SOURCES OF IGNIT. CONSULT NFPA CODE. USE APPRVD
BONDING & GROUNDING PROC. CONTENTS UNDER PRESS. DO NOT (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:PUNCTURE, INCIN/EXPOSE TO TEMP > 120F. HEAT FROM
SUNLIGHT, RADIATORS, STOVES, HOT WATER & OTHER HEAT (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11:SOURCES COULD CAUSE CNTNR TO BURST. DO NOT TAKE
INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC:AT HAZ LEVELS ONLY DURING SANDING/ABRADING OF
DRIED FILM. APPLIC LIM FOR NUISANCE DUSTS ARE ACGIH (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13:TLV 10 MG/M3 (TOTAL DUST), OSHA PEL 15 MG/M3 (TOTAL
DUST), 5 MG/M3 (RESPIRABLE FRACTION).
RTECS #:9999999ZZ
Ingred Name:RESP PROT:NIOSH/MSHA FOR PROT AGAINST NON-VOLATILE
MATERIALS.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:IRRIT OF EYES, SKIN & RESP SYS.
MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON &
POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORDINATION ARE INDICATIONS
OF EXCESSIVE EXPOS TO VAP/S PRAY MISTS. REDNESS & ITCHING/BURNING
SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS. CHRONIC:TOLUENE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:APPEARS ON NAVY LISTING OF OCCUP CHEM
REPROD HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS
CONCERNING LATEST HAZ LIST INFORMATION & SAFE HNDLG & EXPOS
INFORMATION . RATS EXPOS TO TITANIUM DIOXIDE DUST @ 250 MG/M3
DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS LEVELS ARE NOT
ATTAINABLE IN (SUPDAT)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP
WARM & QUIET. SKIN: WASH AREA THORO WITH SOAP & WATER. REMOVE
CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. EYES:FLUSH WITH LARGE
AMOUNTS OF W ATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO
NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. SEEK MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:0.7%
Upper Limits:6.0%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFTIVE. IF WATER USED, FOG NOZZ PREF. WATER
MAY BE USED TO COOL CLSD CNTNRS (SUPDAT)
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:CONTENTS EXTREMELY FLAM. KEEP AWAY
FROM HEAT, SPK, & OPEN FLAME. VAP WILL ACCUM READILY & MAY IGNITE
EXPLOS. DURING USE & UNTIL ALL VAP GONE: (SUPDAT)
Other Precautions:INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS CAN
BE HARMFUL/FATAL. USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY
MIST. AVOID CNTCT W/SKIN & EYES. COATING MAY CONTAIN MATLS CLASSED
AS NUISANCE PAR TICULATES WHICH MAY BE PRESENT (ING 13)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED < APPLIC
LIM BY VENT, WEAR PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD
BY NIOSH/MSHA. WHEN SANDING, WIREBRUSHING, ABRADING,
BURNING/WELDING DRIED FILM, WEAR PARTICULATE RESP APPRVD BY (ING
15)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS TO MATL
MAINTAINED < APPLIC EXPOS LIM. REFER TO OSHA STDS 1910.94,107,108.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC:TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLOS WHEN
EXPOS TO EXTREME HEAT. EFTS OF OVEREXP:PRLNG OVEREXP TO SOLV INGRED
IN PROD MAY CAUSE ADVERSE EFTS TO LIVER, URINARY & REPROD SYS. R
PTS HAVE ASSOC RPTD & PRLNG OVEREXP TO SOLV W/PERM BRAIN & NERVOUS
SYS DMG. HNDLG/STOR PREC:KEEP AREA VENT. DO (ING 9)
================== Physical/Chemical Properties ==================
HCC:V3
Boiling Pt:B.P. Text:>0F,>-18C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:>75
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS LISTED IN INGREDIENTS.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER RCRA
40 CFR 261. WASTE MUST BE TESTED FOR IGNIT TO DETERM APPLIC EPA HAZ
WASTE NUMBERS. DO NOT INCIN. DEPRESSURIZE CNTNR. DISPOSE OF IN
ACCORDANCE W/FEDERAL , STATE & LOCAL REGULATIONS REGARDING
POLLUTION.
| 1 | eyes_protection_mandatory |
=======================================================
NIIN: 01-208-6003
Product ID: EA 960 PART A, (AA9042)
Kit Part: Y
Cage: 33564
Box: 312
Proprietary Ind: Y
=======================================================
Preparer Co. when other than Responsible Party Co.
=======================================================
Cage: 33564
Box: 312
=======================================================
Contractor Summary
=======================================================
Cage: 33564
Box: 312
Cage: 03355
=======================================================
Item Description Information
=======================================================
Item Manager: GSA
Item Name: ADHESIVE
Unit of Issue: KT
UI Container Qty: 0
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: MIXTURE HAS NOT BEEN TESTED AS A WHOLE.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: BRIEF CONTACT MAY IRRIT SKIN OR CAUSE A RASH. REPEATED OR
PROLONGED SKIN CONTACT MAY RESULT IN ALLERGIC SENSITIZATION. CARCINOGENICITY
NOTE: BISPHENOL A/EPICHLOROHYDRIN EPOXY RESIN HAS EXHIBITED MUTAG ENICITY IN
BACTERIA.
Explanation Of Carcinogenicity: TALC IS AN IARC GRP 3 MAT'L (NOT A HUMAN
CARCINOGEN).
Signs And Symptions Of Overexposure: SKIN RASH, IRRITATION.
Medical Cond Aggravated By Exposure: SKIN SENSITIZATION.
First Aid: EYE:FLUSH W/WATER FOR 15MINS. IF IRRIT PERSISTS GET MED ATTN.
SKIN:WASH THOROUGHLY W/SOAP & WATER. IF IRRIT PERSISTS GET MED ATTN.
INHAL:REMOVE VICTIM TO FRESH AIR. IF SYMPTOMS PERSIST GET MED ATTN. I
NGEST:DRINK PLENTY OF WATER. GET MED ATTN IMMED.
=======================================================
Handling and Disposal
=======================================================
GLASSES. SCRAPE UP OR SHOVEL INTO DOT APPROVED WASTE CONTAINERS.
Waste Disposal Methods: NOT RCRA HAZ WASTE.HOWEVER, INCINERATION IN EPA
APPROVED WASTE INCINERATOR IS PREFERRED.CHEM ADDITIONS/ PROCESSING/OTHERWISE
ALTERING MATL MAY MAKE WASTE MANAGEMENT INFOR HEREIN INCOMPLETE/INACCURATE/
INAPPROPRIATE.CONSULT STATE/LOC REGULATIONS.
Handling And Storage Precautions: REFRIGERATED STORAGE IS RECOMMENDED TO
MAINTAIN PRODUCT QUALITY. THIS PRODUCT MAY BE STORED @ ROOM TEMP (77F) FOR UP
TO 12 MONTHS.
Other Precautions: FOLLOW CURING SCHEDULE AS RECOMMENDED IN PRODUCT
LITERATURE.DON'T CUT/GRIND/WELD/DRILL ON/NEAR CONTAINER.AVOID MIXING PARTS
A&B IN BATCHES >1LB UNLESS PLAN TO USE IMMED.DON'T HEAT MIXED ADHESIVE
>75F UNLESS CURING SURFACES TO BE BONDED.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NOT TESTED
Lower Limits: NOT TESTED
Upper Limits: NOT TESTED
Extinguishing Media: DRY CHEMICAL, OR HALON FIRE EXTINGUISHER, OR WATER SPRAY,
FOAM OR FOG.
Fire Fighting Procedures: WEAR SCBA & FULL PROTECTIVE CLOTHING, SUCH AS
TURN-OUT GEAR. CARTRIDGE RESP DO NOT PROVIDE ADEQUATE PROTECTION FOR
FIREFIGHTERS OR EXOTHERM MITIGATION.
Unusual Fire/Explosion Hazard: MAY LIBERATE LARGE QUANTITIES OF DENSE
FOUL-SMELLING SMOKE WHICH MAY CONTAIN UNIDENTIFIED TOXIC GASES.
=======================================================
Control Measures
=======================================================
Respiratory Protection: UNNECESSARY WITH ADEQUATE EXHAUST VENTILATION.
Ventilation: LOCAL EXHAUST VENTILATION AT THE POINT OF USE.
Other Protective Equipment: AN EYEWASH AND SAFETY SHOWER SHOULD BE NEARBY AND
READY FOR USE.
Work Hygienic Practices: WASH HANDS THOROUGHLY AFTER HANDLING MATERIALS.
Supplemental Safety and Health: VISCOSITY:BROOKFIELD, SPDKL 5. FAILURE TO
OBSERVE PRECAUTIONS IN MIXING/HEATING MAY RESULT IN EXCESSIVE HEAT BUILD-UP
CAUSING AN EXOTHERM. THE EXOTHERM HAS POTENTIAL FOR RELEASE OF TOXIC GASES.
SEE SA ME NSN/CAGE PN/IND: F FOR PART B OF 2-PART KIT.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: UNDEFINED
Decomp Text: UNTESTED
Vapor Pres: NIL
Vapor Density: >1
Spec Gravity: >1
Viscosity: 400-10000 BRK
Solubility in Water: NEGLIGIBLE.
Appearance and Odor: PASTE, DARK ORANGE PASTE WITH EPOXY ODOR.
Corrosion Rate: NA
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AVOID MIXING PARTS A&B IN BATCHES >1LB & HEATING
MIXTURE >75F.
Materials To Avoid: STRONG OXIDIZING AGENTS, STRONG LEWIS OR MINERAL ACIDS.
Hazardous Decomposition Products: CO, NOX, ALDEHYDES, ACIDS & UNDETERMINED
ORGANICS.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: NO INFORMATION PROVIDED BY MFG.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
Transportation Information
=======================================================
Trans ID NO: 115316
Product ID: EA 960 PART A, (AA9042)
Review Date: 02/20/1996
Multiple KIT Number: 0
Kit Part IND: Y
Review IND: Y
Unit Of Issue: KT
Container QTY: 0
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: AJJ
Symbols: G
DOT Proper Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S. OR POLYAMINES,
LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN ID Num: UN2735
DOT Packaging Group: III
Label: CORROSIVE
Special Provision: T8
Non Bulk Pack: 203
Bulk Pack: 241
Max Qty Pass: 5 L
Max Qty Cargo: 60 L
Vessel Stow Req: A
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: AQA
IMO Proper Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S. o
IMDG Page Number: 8109-2
UN Number: 2735
UN Hazard Class: 8
IMO Packaging Group: I/II/III
Subsidiary Risk Label: -
EMS Number: 8-05
MED First Aid Guide NUM: 320
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: AWR
IATA UN ID Num: 2735
IATA Proper Shipping Name: ALKYLAMINES, N.O.S. (POLYALKYLAMINES, N.O.S.)
IATA PSN Modifier: * CORROSIVE
IATA UN Class: 8
Subsidiary Risk Class: -
IATA Label: CORROSIVE
UN Packing Group: II
Packing Note Passenger: 808
Max Quant Pass: 1L
Max Quant Cargo: 30L
Packaging Note Cargo: 812
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: AWR
AFI Proper Shipping Name: ALKYLAMINES, N.O.S., OR POLYALKYLAMINES, N.O.S.
AFI PSN Modifier: ,CORROSIVE
AFI Hazard Class: 8
AFI UN ID NUM: UN2735
AFI Packing Group: II
AFI Label: CORROSIVE
Special Provisions: N34
Back Pack Reference: A12.3
=======================================================
HAZCOM Label
=======================================================
Product ID: EA 960 PART A, (AA9042)
Cage: 33564
Company Name: DEXTER CORPORATION ADHESIVE & COATING SYSTEMS
Street: 2850 WILLOW PASS ROAD
PO Box: 312
Zipcode: 94565-3299
Label Required IND: Y
Date Of Label Review: 12/16/1998
Status Code: C
Label Date: 12/16/1998
Origination Code: G
Hazard And Precautions: BRIEF CONTACT MAY IRRIT SKIN OR CAUSE A RASH. REPEATED
OR PROLONGED SKIN CONTACT MAY RESULT IN ALLERGIC SENSITIZATION.
CARCINOGENICITY NOTE: BISPHENOL A/EPICHLOROHYDRIN EPOXY RESIN HAS EXHIBITED
MUTAG ENICITY IN BACTERIA.
SKIN RASH, IRRITATION.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:JET FUEL A
CAGE:0VZA7
CAGE:0VZA7
============= Composition/Information on Ingredients =============
Ingred Name:ALIPHATIC PETROLEUM SOLVENT(JET FUEL A, C8-C16).
CAS:8008-20-6
RTECS #:OA5500000
Fraction by Wt: 99.83%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 ORAL, RAT 25GM/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY IRRIT RESP TRACT & EYES.MAY DAMAGE
NERVES & AFFECT CENTRAL NERVOUS SYSTEM. INHAL:NARCOTIC,IRRIT UPPER
RESP TRACT,HI CONCEN RESULTS IN CHEM PNEUITIS,CNS
DEPRESSION.SKIN:NO INFO AVAILABLE ON SIGNIFI CANT ADVERSE
EFFECTS.CHRONIC
CONTACT:DEFAT,DRYNESS,DERM.INGEST:MOUTH/THROAT/STOMACEH,LUNG &
KIDNEY DAMAGE.
Explanation of Carcinogenicity:PER MSDS:CARCINOGEN
STATUS:OSHA/NTP/IARC:NO. CARCINOGEN STATUS:NONE.
Effects of Overexposure:INHAL:LACK OF APPETITE, NAU, HEADACHE,
WEAKNESS, DRUNKENESS, GIDDINESS, LUNG DAMAGE, UNCONSCIOUSNESS,
ANXIETY, NERVE DAMAGE. SKIN:REDNESS, SWELLLING, LACK OF APPETITE.
INGEST:COUGHING, NAU, VOMIT, DIA RR, DIFFICULTY BREATHING,
DRUNKENESS, BLUISH SKIN COLOR, LUNG & KIDNEY DAMAGE. DEATH/FATAL.
CNS DEPRESSION.
Medical Cond Aggravated by Exposure:PERSONS WITH CHRONIC SKIN OR RESP
DISEASE. TARGET ORGANS:CENTRAL NERVOUS SYSTEM DEPRESSANT.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR. IMMED.PERFORM ART RESP IF
NECESSARY.MAINTAIN AIRWAY,BLOOD PRESSURE,RESP.KEEP WARM/@REST.TREAT
SYMPTOMATICALLY/SUPPORTIVELY.QUAL MED PER SHOULD CONSIDER GIVING
OXY.SKIN:REMOV E CONTAMIN CLOTH/SHOES IMMED.WASH W/SOAP OR MILD
DETERGENT & LG AMTS OF WATER @ LEAST 15-20MINS.EYE:WASH IMMED W/LG
AMTS OF WATER OR NORMAL SALINE LIFTING EYELIDS @ LEAST
15-20MINS.INGEST:SEE SUPPLEM
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:120F,49C
Lower Limits:0.7
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR
REGULAR FOAM.LG FIRES:WATER SPRAY, FOG OR REGULAR FOAM.FLAMM
CLASS:II(OSHA)
Fire Fighting Procedures:MOVE CNTNR FROM FIRE W/O RISK.COOL CNTNR SIDES
EXPO TO FLAMES W/WATER.HUGE FIRE IN CARGO:UNMANNED HOSE
HOLDER/MONITOR NOZ.LEAVE IMMED IF RISING SOUND FROM VE
Unusual Fire/Explosion Hazard:MODERATE FIRE HAZ WHEN EXPO TO
HEAT/FLAME.VAP HEAVIER THAN AIR;MAY TRAVEL CONSIDERABLE DISTANCE TO
IGN SOURCE & FLASHBACK.VAP/AIR MIXTURES ARE EXPLO >FLASHPOINT
================== Accidental Release Measures ==================
Spill Release Procedures:SHUT OFF IGN SOURCES.STOP LEAK W/O RISK.USE
WATERSPRAY TO REDUCE VAP.SM:TAKE UP W/SAND/OTHER ABSORBENT
MATL.PLACE INTO CNTNR.LG:DIKE FOR LATER DISPOSAL.NO
SMOKING/FLAMES/FLARES IN HAZ AREA.KEEP PEOPLE AWAY.ISOLATE AREA.
======================Handling and Storage ======================
Handling and Storage Precautions:OBSERVE ALL FED/STATE/LOC REGS WHEN
STORING SUBSTANCE.STORE IAW 29CFR1910.106.BOND/GROUND CNTNRS IAW
NFPA77-1983,RECOMMENDED PRACT ON STATIC ELECTRICI
Other Precautions:STORE AWAY FROM INCOMPATIBLE SUBSTANCES.KEEP AWAY
FROM ALL IGN SOURCES.AVOID BREATHING VAP/MIST.AVOID CONTACT
W/EYES/SKIN/CLOTHING.KEEP CONTAINER TIGHTLY CLOSED.USE ONLY
W/ADEQUATE VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR SPECIFIC RESP BASED ON CONTAMIN LEVELS IN
WORKPLACE,SPECIFIC OPERATOR,DOES NOT EXCEED WORKING LIMITS OF RESP
& APPROVED BY NIOSH/MSHA.REQUIRED FOR FIREFIGHTING & OTHER IMMED
DANGEROUS TO LIFE/HEA LTH CONDITIONS.
Ventilation:PROVIDE LOC EXHA/GEN DILUTION VENTI TO MEET PUBLISHED EXPO
LIMITS.EXPLOSION-PROOF IF EXPLO CONCEN OF DUST/VAP/FUME PRESE
Other Protective Equipment:EYEWASH FOUNTAIN.WEAR APPROPRIATE PROT
IMPERVIOUS CLOTH/EQPMT TO PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFT HANDLING. WASH CONTAMIN
CLOTH PRIOR TO REUSE.
Supplemental Safety and Health
1STAID:PREVENT ASPIRATION.GASTRIC LAVAGE W/CUFFED ENDOTRACHEAL TUBE IN
PLACE SHOULD BE DONE W/IN 15MINS.ABSENCE OF
DEPRESSION/CONVULSIONS/IMPAIRED GAG REFLEX,EMESIS CAN BE INDUCED
USING SYRUP OF IPECA C W/O INCREASING HAZ OF ASPIRATION.TREAT
SYMPTOMATICALLY/SUPPORTIVELY.IN ALL CASES GET MED ATTN.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:>315F,>157C
Melt/Freeze Pt:M.P/F.P Text:-40F,-40C
Vapor Density:>1
Spec Gravity:0.62
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR,WHITE OR LIGHT STRAW-COLORED LIQUID WITH ODOR
LIKE DEROSENE.
Percent Volatiles by Volume:NIL
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS (STRONG):FIRE/EXPLOSION HAZARD.
Stability Condition to Avoid:AVOID CONTACT W/HEAT/SPARKS/FLAMES/OTHER
SOURCES OF IGNITION.AVOID OVERHEATING CNTNRS.AVOID CONTAMIN OF
WATER SOURCES.
Hazardous Decomposition Products:THERMAL DECOMP PROD MAY INCLUDE TOXIC
OXIDES OF CARBON.
==================== Disposal Considerations ====================
Waste Disposal Methods:OBSERVE ALL LOCAL, STATE AND FEDERAL REGULATIONS
WHEN DISPOSING OF THIS SUBSTANCE.DISPOSAL MUST BE IAW STANDARDS
APPLICABLE TO GENERATORS OF HAZ WASTE 40CFR262. EPA HAZ WASTE
#:D001. 100 LBS CERCLA SE C 103 RQ.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:NALFLEET 2865 GENERAL CLEANER
Preparer's Name:RICKY A. STACKHOUSE
CAGE:89524
CAGE:89524
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM METASILICATE PENTAHYDRATE; (SODIUM METASILICATE)
CAS:10213-79-3
Fraction by Wt: 1-10%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL). LD50:(ORAL,RAT) 470
MG/KG.
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: 1-10%
OSHA PEL:50 PPM, S
ACGIH TLV:25 PPM, S
Ingred Name:SUPDAT:WERE OBSERVED IN HUMANS EXPOS TO ING 2 @ LEVELS AS
HIGH AS 200 PPM. ANIMAL STUDIES CLEARLY DEMONSTRATED (ING 4)
RTECS #:9999999ZZ
Ingred Name:ING 3:DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISS,
BLOOD, KIDNEYS & LIVER, ASSOC W/ADMIN OF ETHYLENE (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4:GLYCOL MONOBUTYL ETHER (EGBE). (EXTRACTED FROM DHHS
(NIOSH) PUBLICATION NO.90-118) .
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC:CONTROL SYMPS & CLINICAL CNDTN. CAUTION:IF
UNCON, HAVING TROUBLE BRTHG/IN CONVLS, DO NOT INDUCE (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6:VOMITING OR GIVE WATER.
RTECS #:9999999ZZ
Ingred Name:SPILL PROC:TRUCK FOR DISP. FOR LG INDOOR SPILLS, EVACUATE
EMPLOYEES & VENTILATE AREA. THOSE RESPONSIBLE FOR (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8:CONTROL & RECOVERY SHOULD WEAR PROTECTIVE EQUIPMENT
SPECIFIED IN PERSONAL PROT EQUIP SECTION.
RTECS #:9999999ZZ
Ingred Name:WASTE DISP METH:TO LICENSED INDUS WASTE LANDFILL (HAZ WASTE
TREATMENT, STOR & DISP FACILITY). HAZ LIQ WASTE CAN (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:ALSO BE DEEP-WELL INJECTED I/A/W LOCAL, STATE &
FEDERAL REGULATIONS.
RTECS #:9999999ZZ
Ingred Name:EYE PROT:& FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ
Ingred Name:OTHER PROT EQUIP:SAFETY SHOWER IS RECOMMENDED.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT 2.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYE/SKIN CONT:CAN CAUSE SEV
IRRIT. INGEST:CAN CAUSE LIVER, KIDNEY DMG. INHAL:PRLNG INHAL OF
MIST/VAP MAY CAUSE NAUS, DIZZ, LT-HEAD, VOMIT/UNCON DEPENDING ON
LGTH OF EXPOS & FIRST AID ACTION GIVE N. CHRONIC:RPTD/WIDESPREAD
DERMAL CONT/PRLNG BRTHG OF VAPS/INGEST MAY RSLT IN INJURY TO LIVER,
KIDNEY/ (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:BLOOD CELLS CAUSING BLOOD IN URINE.
TOX RSLTS:WHEN PREGNANT RABBITS WERE EXPOS VIA INHAL TO ING 2 AT
CONC OF 200 PPM, MATERNAL TOX ALONG W/INCR INCIDENCE OF
EMBRYOLETHALITY & FETOTOXICITY WER E OBSERVED. SIMILAR FINDINGS IN
RATS WERE OBSERVED AT EXPOS LEVELS OF 200 & 100 PPM. STUDIES TO
DETERMINE IF (SUPP DATA)
Medical Cond Aggravated by Exposure:A REVIEW OF AVAILABLE DATA DOES NOT
IDENTIFY ANY WORSENING OF EXISTING CONDITIONS.
======================= First Aid Measures =======================
First Aid:EYES:IMMED FLUSH FOR AT LST 15 MINS WHILE HOLDING EYELIDS
OPEN. CALL MD AT ONCE. SKIN:IMMED FLUSH W/WATER FOR AT LST 15 MINS.
FOR LG SPLASH, FLOOD BODY UNDER SHOWER. CALL MD AT ONCE. INGEST:DO
NOT IND UCE VOMIT. GIVE WATER. CALL MD. INHAL:REMOVE TO FRESH AIR.
TREAT SYMPS. CALL MD. NOTE TO MD:NO SPECIFIC ANTIDOTE IS KNOWN.
BASED ON INDIVIDUAL RXNS OF PATIENT, MD'S JUDGMENT SHOULD BE USED
TO (ING 6)
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CONTACT W/REACTIVE METALS (E.G.,
ALUMINUM) MAY RESULT IN THE GENERATION OF FLAMMABLE HYDROGEN GAS.
================== Accidental Release Measures ==================
Spill Release Procedures:SM LIQ SPILLS:CONTAIN W/ABSORB MATL, SUCH AS
CLAY, SOIL/ANY COMMERCIALLY AVAIL ABSORB. SHOVEL RECLAIMED LIQ &
ABSORB INTO RECOVERY/SALVAGE DRUMS FOR DISP. LG LIQ SPILLS:DIKE TO
PVNT FURTHER MOVEMENT & RECLAIM INTO RECOVERY/SALVAGE DRUMS/TANK
(ING 8)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:CAUSES EYE INJURY & SKIN IRRITATION.
DO NOT GET IN EYES. AVOID CONTACT W/SKIN & CLOTHING. AVOID
PROLONGED OR REPEATED BREATHING OF VAPORS.
Other Precautions:DO NOT TAKE INTERNALLY. EMPTY CONTAINERS MAY CONTAIN
RESIDUAL PRODUCT. DO NOT REUSE CONTAINER UNLESS PROPERLY
RECONDITIONED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF IT IS POSS TO GENERATE SIGNIFICANT LEVELS OF
VAPS/MISTS, A NIOSH/MSHA APPRVD/EQUIV RESP IS REC. FOR LARGE
SPILLS, ENTRY INTO LARGE TANKS, VESSELS/ENCLOSED SMALL SPACES
W/INADEQ VENT, A NIOSH/MSHA A PPRVD PRESS DEMAND SCBA IS REC.
Ventilation:GENERAL VENT IS RECOMMENDED. ADDITIONALLY, LOCAL EXHAUST
VENT IS RECOMMENDED WHERE VAPORS OR MISTS MAY BE RELEASED.
Other Protective Equipment:WEAR APRON, SHOES, ETC. A FULL SLICKER SUIT
IS REC IF GROSS EXPOS IS POSS. AVAILABILITY OF EYE WASH FOUNTAIN &
(ING 13)
Work Hygienic Practices:IF CLOTHING IS CONTAMINATED, REMOVE CLOTHING &
THORO WASH AFFECTED AREA. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
PH:13(NEAT); 11.9(@ 5%). MATLS TO AVOID:GENERATE HEAT,
SPLATTERING/BOILING & RELS OF TOX FUMES. AVOID CONT W/ALUMINUM,
BRASS/POLYURETHANE. EFTS OF OVEREXP:ING 2 INCRS RED BLOOD CELL
(RBC) FRAGILITY IN DICATED THAT THIS EFT APPEARS TO BE MORE
PRONOUNCED IN MICE, RATS & RABBITS. NONE OF BLOOD EFTS NOTED IN
ANIMALS (ING 3)
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:21.0F,-6.1C
Spec Gravity:1.06
pH:SUPDAT
Solubility in Water:COMPLETELY
Appearance and Odor:PALE YELLOW LIQUID; PINE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONT W/STRONG ACID, (E.G., SULFURIC, PHOSPHORIC, NITRIC,
HYDROCHLORIC, CHROMIC, SULFONIC) WHICH CAN (SUPP DATA)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:IN THE EVENT OF COMBUSTION CO, CO*2
MAY BE FORMED. DO NOT BREATHE SMOKE OR FUMES. WEAR SUITABLE
PROTECTIVE EQUIPMENT.
==================== Disposal Considerations ====================
Waste Disposal Methods:IF THIS PROD BECOMES A WASTE, IT MEETS CRITERIA
OF HAZ WASTE AS DEFINED UNDER RCRA 40 CFR 261. HAZ WASTE D002. AS
HAZ LIQ WASTE, IT MUST BE SOLIDIFIED W/STABLIZING AGENTS (SUCH AS
SAND, FLY ASH/CEMENT ) SO THAT NO FREE LIQ REMAINS BEFORE DISP (ING
10)
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===================== Product Identification =====================
Product ID:EM8116, MIL T6096A
CAGE:92108
CAGE:92108
============= Composition/Information on Ingredients =============
Ingred Name:ETHYL ACETATE 85%
CAS:141-78-6
RTECS #:AH5425000
Fraction by Wt: 40.00%
Other REC Limits:NONE SPECIFIED
OSHA PEL:400 PPM
ACGIH TLV:400 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:NORMAL BUTYL ACETATE
CAS:123-86-4
RTECS #:AF7350000
Fraction by Wt: 15.00%
Other REC Limits:NONE SPECIFIED
OSHA PEL:150 PPM/200 PPM STEL
ACGIH TLV:150 PPM/200 PPM STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:DIACETONE ALCOHOL-DAA
CAS:123-42-2
RTECS #:SA9100000
Fraction by Wt: 10.00%
Other REC Limits:NONE SPECIFIED
OSHA PEL:50 PPM
ACGIH TLV:50 PPM
Ingred Name:METHYL ETHYL KETONE (SARA 313)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 35.00%
Other REC Limits:NONE SPECIFIED
OSHA PEL:200 PPM/300 PPM STEL
ACGIH TLV:200 PPM/300 PPM STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Health Hazards Acute and Chronic:SKIN & EYES: CONTACT IRRITATION.
INHALATION: MAY CAUSE NAUSEA, HEADACHE, DIZZINESS AND IRRITATION OF
THE RESPIRATORY TRACT.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH WATER. CONTACT A PHYSICIAN. SKIN: WASH WITH
SOAP AND WATER. INHALATION: PROVIDE FRESH AIR. OXYGEN OR ARTIFICIAL
RESPIRATION AS NEEDED.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:24.0F,-4.4C
Extinguishing Media:CO2, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR SCBA GEAR & PROTECTIVE COTHING. COOL
SEALED DRUMS WITH WATER SPRAY TO LESSEN CHANCE OF RUPTURE. DIRECT
WATER JET WILL SPREAD BURNING MATERIAL.
Unusual Fire/Explosion Hazard:MATERIAL IS EXTREMELY FLAMMABLE.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. PERMIT ONLY
PROPERLY PROTECTED WORKERS IN THE AREA (I.E. WITH EYE/SKIN
PROTECTION AND SELF-CONTAINED BREATHING GEAR. ABSORB SMALL SPILLS
WITH INERT ABSORBENT. PUMP L ARGE SPILLS INTO SALVAGE TANK.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE DRUMS, WELL SEALED, IN A COOL,
DRY, WELL VENTILATED AREA AWAY FROM ALL IGNITION SOURCES. GROUND
CONTAINERS WHEN TRANSFERRING MATERIAL.
Other Precautions:EMPTY CONTAINERS ARE HAZARDOUS. OBSERVE ALL LABEL
PRECAUTIONS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:ABOVE PEL/TLV, USE NIOSH/MSHA APPROVED
RESPIRATOR FOR ORGANIC VAPORS.
Ventilation:LOCAL EXHAUST (TO A FIRE-SAFE AREA) RECOMMENDED.
Other Protective Equipment:AS NEEDED TO ELIMINATE SKIN CONTACT. EYEWASH
STATIONS AND SAFETY SHOWERS SHOULD BE IN WORK AREA.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:171F,77C
Vapor Density:> AIR
Spec Gravity:.8667
Solubility in Water:NIL
Appearance and Odor:WATER-WHITE LIQUID WITH A CHARACTERISTIC ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Hazardous Decomposition Products:CO AND CO2 UPON INCOMPLETE COMBUSTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTACT FEDERAL, STATE AND LOCAL AGENCIES TO
ENSURE COMPLIANCE OF DISPOSAL METHOD WITH CURRENT REGULATIONS.
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===================== Product Identification =====================
Product ID:MIL-L-16785A
CAGE:76736
CAGE:76736
============= Composition/Information on Ingredients =============
Ingred Name:SEVERELY HYDROTREATED PETROLEUM HYDROCARBON BASE STOCK, CAS
NO 64742-58-1
Other REC Limits:NONE SPECIFIED
OSHA PEL:5 MG/M3 AS OIL MIST
ACGIH TLV:5 MG/M3 AS OIL MIST
Ingred Name:COCONUT OIL
CAS:8001-31-8
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL RAT) IS NOT AVAILABLE
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE/CHRONIC-SKIN:PROLONGED CONTACT
MAY CAUSE IRRITATION.INHALATION:INHALING MIST/FUMES MAY CAUSE
MUCOUS MEMBRANE IRRITATION.
Effects of Overexposure:MILD IRRITATION OF SKIN AND MUCOUS MEMBRANE
Medical Cond Aggravated by Exposure:NOT RELEVANT
======================= First Aid Measures =======================
First Aid:GET MEDICAL AID.INHALATION:REMOVE TO FRESH AIR.EYE:FLUSH WITH
WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN.SKIN:WIPE OFF AND
WASH WITH SOAP AND WATER.REMOVE CONTAMINATED CLOTHING.INGESTION:DO
NOT I NDUCE VOMITING.DRINK WATER.SEEK MEDICALHELP.
===================== Fire Fighting Measures =====================
Flash Point:360F,182C
Lower Limits:1
Upper Limits:6
Extinguishing Media:WATER FOG (CAREFUL TO PREVENT FROTHING), CARBON
DIOXIDE, FOAM, OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS WITH
ORGANIC VAPOR FILTER AND FACE SHIELD IN ENCLOSED AREAS. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:STOP FLOW. ELIMINATE IGNITION SOURCE. RECOVER
FREE PRODUCT. ADD ABSORBENT MATERIAL SUCH AS CLAY TO SPILL AREA.
SWEEP OR SCRAPE UP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE-STORE IN A COOL,DRY,VENTILATED
AREA AWAY FROM FLAME,HEAT & OXIDIZING AGENTS.KEEP CONTAINERS
TIGHTLY CLOSED.
Other Precautions:MINIMIZE SKIN CONTACT. WASH THOROUGHLY AFTER HANDLING
AND BEFORE EATING OR DRINKING. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. DO NOT GET IN EYES. AVOID INHALATION OF FUMES, VAPORS OR
MIST. DO NOT I NGEST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NON REQUIRED UNDER NORMAL CONDITIONS. IN CASE OF
EXPOSURE TO FUMING OR MISTING, WEAR NIOSH APPROVED SUPPLIED AIR
RESPIRATOR, PARTICULARLY IF MATERIAL HAS BEEN HEATED.
Ventilation:LOCAL/MECHANICAL EXHAUST
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:V6
Boiling Pt:B.P. Text:500F,260C
Vapor Density:>1
Spec Gravity:0.9
Evaporation Rate & Reference:<0.001(N-BUTYL ACETATE=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:PALE STRAW LIQUID, MILD CHARACTERISTIC ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:EXCESSIVE HEAT AND FLAMES
Hazardous Decomposition Products:OXIDES OF CARBON
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN AN APPROPRIATE DISPOSAL FACILITY
IN COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
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===================== Product Identification =====================
Product ID:10JX63 FILTER
Preparer's Name:DSGS-SSH
CAGE:56289
CAGE:56289
============= Composition/Information on Ingredients =============
Ingred Name:NON-HAZARDOUS INGREDIENTS
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NONE.
Explanation of Carcinogenicity:NOT CARCINOGENIC.
Effects of Overexposure:NONE.
Medical Cond Aggravated by Exposure:NONE.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH RUNNING WATER FOR 15 MINUTES WHILE HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION IMMEDIATELY. SKIN: WASH WITH
SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL ADVICE.
INHALATIO N: REMOVE TO FRESH AIR. GET MEDICAL ADVICE.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS IF
NEEDED.
Unusual Fire/Explosion Hazard:COMBUSTION MAY PRODUCE HAZARDOUS FUMES
AND VAPORS OF DECOMPOSITION PRODUCTS.
================== Accidental Release Measures ==================
Spill Release Procedures:HANDLE CAREFULLY.
Neutralizing Agent:NONE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, AREA.
Other Precautions:NONE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE.
Ventilation:NONE NORMALLY REQUIRED.
Other Protective Equipment:SAFETY SHOWER AND EYE BATH.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR DRINKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
THIS DEVICE DOES NOT CONTAIN PCB'S. AS A RESULT, IT IS NOT SUBJECT TO
ANY SPECIAL HANDLING NORMALLY ASSOCIATED WITH ELECTRONIC COMPONENTS
CONTAINING PCB'S. INFORMATION RECIEVED FROM DAVE RICHARDSON, F IELD
APPLICATION ENGINEEER, FOR SPRAGUE, 11-6-96.
================== Physical/Chemical Properties ==================
HCC:N1
Appearance and Odor:HERMETICALLY SEALED FILTER WITH 9 ROUND
TERMINALS/TERMINALS ON OPPOSITE SURFACE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:HEAT, OPEN FLAMES AND SOURCES OF IGNITION.
Hazardous Decomposition Products:TOXIC COMPOUNDS MAY BE FORMED.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
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=======================================================
Product ID: UNSANDED WALL GROUT, TA-610
Cage: TECIN
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 7P551
Cage: TECIN
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: EYE AND SKIN IRRITANT. EYE CONTACT MAY BE ABRASIVE.
CHRONIC: LONG TERM EXCESSIVE CRYSTALLINE SILICA EXPOSURE CAN CAUSE PERMANENT
LUNG DAMAGE.
Explanation Of Carcinogenicity: USERS OF THE "L" VERSION OF SHOULD CONSULT
"LR" VERSION INGREDIENT 6 FOR ADDITIONAL INFORMATION (FP N).
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: PERSONS WITH PREEXISTING LUNG CONDITIONS
MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF DUST EXPOSURE.
First Aid: INGESTION: GIVE ONE GLASS OF WATER OR MILK. CONSULT MD. EYES: FLUSH
IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. GET IMMEDIATE MEDICAL
ATTENTION. SKIN: WASH AFFECTED AREA WITH SOAP AND WATER. INHAL ATION: REMOVE
TO FRESH AIR.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: SWEEP UP SPILLED MATERIAL. MOP UP RESIDUE WITH WATER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: LANDFILL IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
Handling And Storage Precautions: NONE SPECIFIED BY MANUFACTURER.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: NON-FLAMMABLE. USE MEDIA SUITABLE FOR SURROUNDING FIRE (FP
N).
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH/MSHA APPROVED PARTICULATE RESPIRATOR RECOMMENDED
IN SITUATIONS WHERE DUSTING MAY OCCUR.
Ventilation: NO SPECIAL REQUIREMENTS.
Other Protective Equipment: EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: USERS OF THE "L" VERSION OF TO CONSULT "LR"
VERSION FOR ADDITIONAL INFORMATION (FP N).
=======================================================
Physical/Chemical Properties
=======================================================
Appearance and Odor: SOLID
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE KNOWN.
Hazardous Decomposition Products: NONE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: UNSANDED WALL GROUT, TA-610
Cage: TECIN
Company Name: TEC INC
Street: 315 S HICKS RD
Zipcode: 60087
Label Required IND: Y
Date Of Label Review: 09/06/1995
Status Code: C
Label Date: 09/06/1995
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: EYE AND SKIN IRRITANT. EYE CONTACT MAY BE
ABRASIVE. CHRONIC: CANCER HAZARD. CONTAINS MATERIAL WHICH IS LISTED AS AN
ANIMAL LUNG CARCINOGEN (FP N). LONG TERM EXCESSIVE CRYSTALLINE SILICA EXPOSUR
E CAN CAUSE PERMANENT LUNG DAMAGE.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SOAP PELLETS; PERK & ARCONOMY PRODUCT
CAGE:KO684
CAGE:KO684
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM SOAP
Fraction by Wt: 100%
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE, SKIN & RESPIRATORY TRACT
IRRITATION. CHRONIC: PROLONGED OR REPEATED SKIN CONTACT CAN CAUSE
SKIN IRRITATION AND MAY RESULT IN AN ALLERGIC SKIN REACTION.
Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS
LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:INHALATION: NASAL DISCOMFORT, SNEEZING &
COUGHING; SKIN: MAY CAUSE ITCHING, BURNING OR REDNESS. PROLONGED
AND REPEATED EXPOSURE MAY PRODUCE LOCAL IRRITATION. EYES: UPON
DIRECT CONTANT PRODUCT CAN IRRI TATE EYE. MAY ALSO CAUSE BURNING OR
BLUURED VISION. INGESTION: MAY CAUSE GI IRRITATIN, NAUSEA,VOMITING
AND DIARRHEA.
Medical Cond Aggravated by Exposure:PRE-EXISTING EYES AND SKIN DISORDER
MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:INHALATION:REMOVE TO FRESH AIR. EYES:IMMEDIATELY FLUSH WITH
PLENTY OF WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL
ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH WATER. IF
IRRITATIO N PERSISTS, GET MED ATTN. INGESTION:LOWHAZARD FOR USUAL
INDUSTRIAL HANDLING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET
IMMEDIATE MEDICAL ATTENTION IF ANY PROBLEM OCCURS.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:USE APPROPRIATE PROTECTIVE & SAFETY GEARS.
SMALL SPILL:SCOOP UP AND PLACE IN DISPOSAL CONTAINER.AVOID CREATING
DUST. LARGE SPILL:SHOVEL UP POWDER INTO SALVAGE DRUMS.CLEAN SURFACE
WITH WATER.AVOID CREA TING DUST.
Neutralizing Agent:NOT APPLICABLE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT
CONTAINERS FROM PHYSICAL DAMAGE.
Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE DUST. AVOID
PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID CONTACT WITH EYES.
USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED PARTICLE MASK.
Ventilation:MECHANICAL (GENERAL) ROOM VENTILATION IS NORMALLY ADEQUATE.
LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA NOT VENTED.
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:1.040
Solubility in Water:COMPLETE
Appearance and Odor:OPAQUE, WHITE PELLETS WITH MILD FATTY ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS AND STRONG OXIDIZING AGENTS
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:CH-1 CULLEX STRONG ACID CATION EXCHANGE MEDIA
Kit Part:Y
CAGE:71762
CAGE:71762
============= Composition/Information on Ingredients =============
Ingred Name:SULPHONATED COPOLYMER OF STYRENE & DIVINYL BENZENE IN
SODIUM FORM
CAS:69011-22-9
Fraction by Wt: 40-60%
Other REC Limits:NONE RECOMMENDED
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 40-60%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES-CAN PRODUCE MECHANICAL IRRITATION
TO THE EYES. SKIN-MAY CAUSE SKIN IRRITATION OF HYPERSENTIVE
PERSONNEL. INGESTION-NO INFORMATION AVAILABLE. INHALATION-NO
INFORMATION AVAILABLE. CHRONIC: MECHANIC AL IRRITATION TO THE EYES
AND SKIN IRRITATION OF HYPERSENSITIVE PERSONNEL.
Explanation of Carcinogenicity:NOT CARCINOGENIC.
Effects of Overexposure:EYES-SYMPTOMS INCLUDE RED, IRRITATED EYES,
ITCHING AND FEELING THAT A PARTICLE EXISTS BETWEEN THE EYELID AND
THE EYES.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES-FLUSH EYES WITH COPIOUS QUANTITIES OF WATER. PRODUCT HAS
A TENDENCY TO CLING TO SKIN DUE TO STATIC CHARGE. CARE MUST BE
EXERCISED TO REMOVE ALL PRODUCT FROM SKIN. IF IRRITATION PERSISTS,
SEE A PH YSICIAN. SKIN-FLUSH WITH COPIOUS QUANTITIES OF SOAPY
WATER. IF IRRITATION PERSISTS, SEE A PHYSICIAN.
===================== Fire Fighting Measures =====================
Autoignition Temp:Autoignition Temp Text:>930F
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR WATER FOG ARE
RECOMMENDED TO EXTINGUISH FIRES INVOLVING THIS PRODUCT.
Fire Fighting Procedures:WEAR MSHA/NIOSH APPROVED PRESSURE DEMAND,
SELF-CONTAINED BREATHING APPARATUS. GUARD AGAINST CONTACT OF THE
PRODUCT WITH THE EYES DURING SALVAGE OPERATIONS.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:IN CASE OF SPILL OR LEAK SWEEP AREA OF
PRODUCT, COLLECTING IN A CONTAINER FOR DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID FREEZING OR PROLONGED STORAGE
ABOVE 120F. BECAUSE PRODUCT CONTAINS WATER WHICH WILL FREEZE &
DAMAGE PRODUCT OR DRY-OUT ALSO DAMAGING PRODUCT.
Other Precautions:AVOID PACKING PRODUCT IN AN UNPROTECTIVE GLASS
COLUMN. EXPANSION OF THIS PRODUCT CAN CAUSE THE GLASS COLUMN TO
SHATTER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT AVAILABLE.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:LONG SLEEVE SHIRTS & LONG TROUSERS ARE
RECOMMENDED TO PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH HANDS THOROUGHLY.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:N1
Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C
Vapor Pres:17 MMHG
Vapor Density:0.62
Spec Gravity:1.3
pH:6-9
Solubility in Water:INSOLUBLE
Appearance and Odor:SMALL SOLID SPHERICAL BEAD. ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS SUCH AS NITRIC ACID.
Stability Condition to Avoid:AT TEMPERATURES ABOVE 400F DECOMPOSITION
OCCURS.
Hazardous Decomposition Products:HAZARDOUS DECOMPOSITION PRODUCTS
INCLUDE CARBON MONOXIDE, CARBON DIOXIDE, STYRENE AND DIVINYL
BENZENE.
==================== Disposal Considerations ====================
Waste Disposal Methods:AS SUPPLIED, NEW OR USED ION EXCHANGE RESINS ARE
GENERALLY NOT HAZARDOUS AND THEREFORE ARE NOT CONSIDERED AS
HAZARDOUS WASTES. USED RESINS MAY MEET THE REGULATORY DEFINITION OF
HAZARDOUS WASTE AS A RE SULT OG THEIR SERVICES.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:RESTAURANT PAK 3
Preparer's Name:K. WOODS
CAGE:5T372
CAGE:5T372
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM METASILICATE, ANHYDROUS
CAS:6834-92-0
RTECS #:VV9275000
Fraction by Wt: <10.0%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: IRRITATION. SKIN: IRRITATION.
INGEST: NAUSEA, DIARRHEA, IRRITATION, BURNS. INHAL: IRRITATION.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH THOROUGHLY W/PLENTY OF WATER FOR SEVERAL MINUTES,
CALL DR. SKIN: FLUSH THOROUGHLY W/WATER, CALL DR. INGEST: DRINK
PLENTY OF WATER, CALL DR IMMED. DONT INDUCE VOMIT UNLESS INSTRUCTED
BY DR. INHAL: GET FRESH AIR, CALL DR.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:WATER, CO2, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:REPLACE UNBROKEN PACKETS IN CONTAINER. SCOOP
UP ANY LOOSE POWDER & PLACE IN CLOSED CONTAINER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN CLOSED CONTAINER IN DRY
PLACE. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:NONE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED.
Ventilation:NONE REQUIRED.
Other Protective Equipment:NONE REQUIRED.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:NA
Vapor Pres:NA
Vapor Density:NA
Spec Gravity:NA
Solubility in Water:APPRECIABLE.
Appearance and Odor:WHITE GRANULES, PERFUMED ODOR IN DISOLVEABLE
PACKETS.
Percent Volatiles by Volume:NA
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS.
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:IN ACCORDANCE W/FEDERAL/STATE/LOCAL REGULATIONS.
| 0 | eyes_protection_not_mandatory |
===================== Product Identification =====================
Product ID:9441, 9450, TETRAHYDROFURAN
Resp. Party Other MSDS Num.:T1222
Preparer's Name:STRATEGIC SERVICES DIV
CAGE:70829
CAGE:70829
============= Composition/Information on Ingredients =============
Ingred Name:TETRAHYDROFURAN
CAS:109-99-9
RTECS #:LU5950000
Minumum % Wt:99.
Maxumum % Wt:100.
OSHA PEL:590 MG/M3;200 PPM
ACGIH TLV:590 MG/M3;200 PPM
ACGIH STEL:737 MG/M3;250 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): 1650 MG/KG
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: CAUSES IRRITATION TO THE
RESPIRATORY TRACT. INGESTION: CAUSES IRRITATION TO THE
GASTROINTESTINAL TRACT. SKIN: CAUSES IRRITATION TO THE SKIN. EYE:
CAUSES IRRITATION AND MAY CAUSE PERMANENT EYE DAMAGE. CHRONIC:
REPEATED OR HIGH EXPOSURES MAY CAUSE KIDNEY OR LIVER DAMAGE, MAY
AFFECT THE LUNGS. REPEATED SKIN EXPOSURE CAN CAUSE DRYNESS,
CRACKING OF SKIN & RASH
Explanation of Carcinogenicity:THERE IS NO DATA LINKING THF EXPOSURE TO
CANCER IN HUMANS. THE DATA SHOWS CARCINOGENIC ACTIVITY IN THE LIVER
& KIDNEYS OF LABORATORY ANIMALS.
Effects of Overexposure:INHALTION: SYMPTOMS MAY INCLUDE COUGHING,
SHORTNESS OF BREATH. OVEREXPOSURE MAY CAUSE DIZZINESS, HEADACHE,
NAUSEA, AND POSSIBLE FLUID IN THE LUNGS. INGESTION: SYMPTOMS MAY
INCLUDE VOMITING, NAUSEA AND DISRRHEA. MAY CAUSE SORE THROAT AND
ABDOMINAL PAIN. MAY CAUSE LIVER AND KIDNEY INJURY. SKIN: SYMPTOMS
INCLUDE REDNESS, ITCHING AND PAIN. EYE: CAUSES IRRITATION, REDNESS
AND PAIN. CONTACT MAY CAUSE PE RMANENT EYE DAMAGE.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS OR EYE PROBLEMS OR IMPAIRED LIVER OR KIDNEY FUNCTION MAY
BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.
======================= First Aid Measures =======================
First Aid:INHALATION-REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET
MEDICAL AID. INGESTION-INDUCE VOMITING IMMEDIATELY AS DIRECTED BY
MEDICAL PER SONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. GET MEDICAL AID. SKIN-IMMEDIATELY FLUSH WITH PLENTY OF
WATER FOR 15 MIN. REMOVE CONTAMINATED CLOTHING & SHOES. GET MEDICAL
AID. WASH CLOT HING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE
REUSE. EYE-IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINS.
LIFTING LOWER & UPPER EYELIDS OCCASIONALLY. GET MEDICAL AID
IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:=-14.C, 6.8F
Autoignition Temp:=321.C, 609.8F
Lower Limits:2.0
Upper Limits:11.8
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE. WATER SPRAY MAY
BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL. WATER SPRAY MAY BE
USED TO KEEP FIRE EXPOSED CONTAINERS COOL.
Fire Fighting Procedures:IN THE EVENT OF FIRE, WEAR FULL PROTECTIVE
CLOTHING & NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH
FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE
PRESSURE MODE. WATER MAY BE USED TO FLUSH SPILLS AWAY FROM
EXPOSURES & TO DILUTE SPILLS TO NON-FLAMMABLE MIX.
Unusual Fire/Explosion Hazard:ABOVE FLASH POINT, VAPOR MIXTURES ARE
EXPLSOIVE WITHIN FLAMMABLE LIMITS NOTED ABOVE. MAY FORM EXPLOSIVE
ORGANIC PEROXIDES WHEN EXPOSED TO AIR OR LIGHT OR WITH AGE. VAPORS
CAN FLOW ALONG SURFACES TO DI STANT IGNITION SOURCE & FLASH BACK.
SEALED CONTAINERS MAY RUPTURE WHEN HEATED.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. REMOVE ALL
SOURCES OF IGNITION. WEAR APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT. KEEP UNNECESSARY & UNPROTECTED PERSONNEL FROM ENTERING.
CONTAIN & RECOVER LIQUID WHEN P OSSIBLE. USE NON-SPARKING TOOLS &
EQUIPMENT. COLLECT LIQUID IN AN APPROPRIATE CONTAINER OR ABSORB
WITH AN INERT MATERIAL(VERMICULITE, DRY SAND, EARTH), & PLACE IN
CHEMICAL WASTE CONTAINER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN DARK GLASS BOTTLES OR STEEL
DRUMS. PROTECT AGAINST PHYSICAL DAMAGE. STORE IN A COOL, DRY
WELL-VENTILATED LOCATION, AWAY FROM DIRECT SUNLIGHT AND ANY AREA
WHERE THE FIRE HAZARD MAY BE ACUTE. STORE IN TIGHTLY CLOSED
CONTAINERS (PREFERABLY UNDER NITROGEN ATMOSPHERE.
Other Precautions:RELEASE: DO NOT USE COMBUSTIBLE MATERIAL SUCH AS SAW
DUST. DO NOT FLUSH TO SEWER! US REGULATIONS (CERCLA) REQUIRE
REPORTING SPILLS & RELEASES TO SOIL, WATER & AIR IN EXCESS OF
REPORTABLE QUANTITIES. T HE TOOL FREE NUMBER FOR THE COAST GUARDS
NATIONAL RESPONSE CENTER IS 800-424-8802.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF THE EXPOSURE LIMIT IS EXCEEDED, A HALF-FACE
ORGANIC VAPOR RESPIRATOR MAY BE WORN FOR UP TO TEN TIMES THE
EXPOSURE LIMIT OR THE MINIMUM USE CONCENTRATION SPECIFIED BY THE
APPROPRIATE REGULATORY AGEN CY OR RESPIRATOR SUPPLIER, WHICHEVER IS
LOWEST. A FULL-FACE PIECE ORGANIC RESPIRATOR MAY BE WORN UP TO 50
TIMES THE EXPOSURE LIMIT/MAXIMUM USE CONCENTRATION.
Ventilation:A SYSTEM OR LOCAL AND/OR GENERAL EXHAUST IS RECOMMENDED TO
KEEP EMPLOYEE EXPOSURE BELOW THE AIRBORNE EXPOSURE LIMITS.
PROTECTION INCLUDING IMPERVIOUS BOOTS, APRON, OR COVERALLS, AS
NEEDED IN AREAS OF UNUSUAL EXPOSURE. MAINTAIN EYEWASH FOUNTAIN AND
QUICK-DRENCH FACILITIES.
Work Hygienic Practices:WASH CLOTHING BEFORE REUSE. THOROUGHLY CLEAN
SHOES BEFORE REUSE.
Supplemental Safety and Health
BAKER P/N:9439, 9441, 9442, 9446, 9450, V530. MALLINCKRODT P/N:2858,
8497, 8498, 8499, V558. RESPIRATORS-FOR EMERGENCIES OR INSTANCES
WHERE EXPOSURE LEVELS ARE UNKNOWN, USE FULL-FACE PIECE POSITIVE-P
RESSURE AIR-SUPPLIED RESPIRATOR. WARNING:AIR-PURIFYING RESPIRATOR
DO NOT PROTECT WORKER IN OXYGEN-DEFICIENT ATMOSPHERES.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:=66.C, 150.8F
Melt/Freeze Pt:=-108.C, -162.4F
Vapor Pres:129
Vapor Density:2.5
Spec Gravity:0.88
pH:7
Evaporation Rate & Reference:8.0 (BUAC=1)
Solubility in Water:MISCIBLE
Appearance and Odor:COLORLESS, MOBILE LIQUID; ETHER ODOR
Percent Volatiles by Volume:100%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
TEETRAHYDROFURAN REACTS VIOLENTLY WITH AIR ON STANDING LIA1H2, STRONG
OXIDIZERS, NAALH2 AND POTASSIUM HYDROXIDE. WILL ATTACK SOME FORMS
OF PLASTICS, RUBBERS AND COATINGS.
Stability Condition to Avoid:HEAT, FLAME, IGNITION SOURCES,
INCOMPATIBLES, LIGHT AND AIR.
Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE MAY
FORM WHEN HEATED TO DECOMPOSITION. MAY ALSO RELEASE TOXIC AND
IRRITATING VAPORS.
=================== Toxicological Information===================
Toxicological Information:TOXICOLOGICAL DATA: ORAL, RAT, LD50=1650
MG/KG. INHALATION, RAT, LC50-27,000 PPM/3H. CARCINOGENICITY: UNDER
THE NATIONAL TOXCOLOGY PROGRAM (NTP), THE U.S. PUBLIC HEALTH
SERVICES COMPLETED A 2-YEAR (L IFETIME) INHALATION STUDY IN RATS &
MICE ON TETRAHYDROFURAN (THF) WHICH SUGGESTS THAT THF IS A
CARCINOGEN IN LABORATORY ANIMALS. THERE IS NO DATA LINKING THF
EXPOSURE TO CANCER IN HUMANS. THE DATA SHO WS CARCINOGENIC ACTIVITY
IN THE LIVER & KIDNEYS OF LABORATORY ANIMALS.
===================== Ecological Information =====================
Ecological:WHEN RELEASED INTO THE SOIL, THIS MATERIAL IS EXPECTED TO
LEACH INTO GROUNDWATER. WHEN RELEASED INTO THE SOIL, THIS MATERIAL
IS EXPECTED TO QUICKLY EVAPORATE. WHEN RELEASED INTO WATER, THIS
MATERIAL M AY BIODEGRADE TO A MODERATE EXTENT. THIS MATERIAL IS NOT
EXPECTED TO SIGNIFICANTLY BIOACCUMULATE. WHEN RELEASED INTO THE
AIR, THIS MATERIAL MAY BE REMOVED FROM THE ATMOSPHERE TO A
MODERATE EXTENT BYWET DEPOSITION. ENVIRONMENTAL TOXICITY: 96-HOUR
LC50 FATHEAD MINNOW: 2160 MG/L.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR
RECYCLING SHOULD BE HANDLED AS HAZARDOUS WASTE & SENT TO RCRA
APPROVED WASTE FACILITY. PROCESSING, USE OR CONTAMINATION OF
PRODUCT MAY CHANGE THE WASTE MANAGEM ENT OPTIONS. STATE & LOCAL
DISPOSAL REGS MAY DIFFER FROM FEDERAL DISPOSAL REGS. DISPOSE OF
CONTAINER & UNUSED CONTENTS I/A/W FEDERAL REQUIREMENTS.
=================== MSDS Transport Information ===================
Transport Information:DOMESTIC (LAND, D.O.T.) PROPER SHIPPING NAME:
TETRAHYDROFURAN. HAZARD CLASS: 3. UN/NA NUMBER: UN2056. PACKING
GROUP: II. INFORMATION REPORTED FOR PRODUCT/SIZE: 400 LBS.
INTERNATIONAL (WATER, I.M.O.) P ROPER SHIPPING NAME:
TETRAHYDROFURAN. HAZARD CLASS: 3.2. UN/NA NUMBER: UN2056. PACKING
GROUP: II. INFORMATION REPORTED FOR PRODUCT/SIZE: 400 LBS.
===================== Regulatory Information =====================
SARA Title III Information:SARA 302: NO. SARA 313: NO. SARA 311/312:
ACUTE: YES. CHRONIC: NO. FIRE: YES. PRESSURE: NO. REACTIVITY: YES.
(PURE/LIQUID).
Federal Regulatory Information:TSCA: YES. CERCLA: 1000. RCRA: U213.
TSCA 8(D): YES.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:S00805, HEAVY DUTY SILICONE, MOLD RELEASE (SUPP DATA)
CAGE:JO606
CAGE:JO606
CAGE:09800
============= Composition/Information on Ingredients =============
Ingred Name:HEPTANE. VP:50.
CAS:142-82-5
RTECS #:MI7700000
Fraction by Wt: 5%
OSHA PEL:500 PPM
ACGIH TLV:400 PPM;500 STEL
Ingred Name:ETHANE, 1,1,1,2-TETRAFLUORO-; (1,1,1,2-TETRAFLUOROETHANE).
VP:760.
CAS:811-97-2
RTECS #:KI8842500
Fraction by Wt: 59%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:METHYL ETHER; (DIMETHYL ETHER). VP:760.
CAS:115-10-6
RTECS #:PM4780000
Fraction by Wt: 32%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:VOLATILE ORGANIC COMPOUNDS (BAAQMD RULE 49): 37% BY WT;
2.83 LBS/GAL.
RTECS #:9999999VO
Ingred Name:EXPLO HAZ:APPLICATION TO HOT SURFS REQS SPECIAL PRECS.
DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH (ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5:HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT.
OBTAIN MEDICAL ATTENTION.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC:CONSULT NFPA CODE. USE APPRVD BONDING &
GROUNDING PROCS. CONTENTS UNDER PRESS. DO NOT PUNCTURE, INCIN/(ING
8)
RTECS #:9999999ZZ
Ingred Name:ING 7:EXPOSE TO TEMP >170F. HEAT FROM SUNLIGHT, RADIATORS,
STOVES, HOT WATER & OTHER HEAT SOURCES COULD CAUSE (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8:CNTNR TO BURST. DO NOT TAKE INTERNALLY. KEEP OUT OF
REACH OF CHILDREN. ADDN OF REDUCERS/OTHER ADDITIVES TO(ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:THESE PRODUCTS MAY SUBSTANTIALLY ALTER COMPOSITION &
HAZARDS OF PRODUCTS.
RTECS #:9999999ZZ
Ingred Name:VENT:1910.94, 1910.107, 1910.108.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE
CONT, DEPENDING ON CNDTNS OF USE. TO MIN EXPOS, FOLLOW RECS FOR
PROPER USE, VENT & PPE. ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY
CAUSE NERV SYS DEPRESS. EXTREME OV EREXP MAY RSLT IN UNCON &
POSSIBLY DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF
EXCESSIVE(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:EXPOS TO VAPS/SPRAY MIST. REDNESS &
ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS.
CHRONIC:PRLNG OVEREXP TO SOLV INGS MAY CAUSE ADVERSE EFTS TO LIVER
& URINARY SYS. RPTS HAVE A SSOC RPTD & PRLNG OVEREXP TO SOLVS
W/PERM BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY DELIB CONC &
INHAL (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM &
QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE
CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE
AMOUNTS OFWATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGEST:NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS. DO NOT INDUCE
VOMIT. GIVE CONSCIOUS PATIENT SEVERAL GLASSES OF WATER. SEEK MED
ATTN.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:1.1%
Upper Limits:27%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF.
WATER MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT)
Unusual Fire/Explosion Hazard:EXTREMELY FLAMM. CLSD CNTNRS MAY EXPLODE
(DUE TO BUILD-UP OF PRESS) WHEN EXPOS TO EXTREME HEAT. ISOLATE FROM
HEAT, ELEC EQUIP, SPKS & OPEN FLAME. (ING 5)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE &
REMOVE W/INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP
& SPRAY MIST. AVOID CONT W/SKIN & EYES. CONTENTS ARE EXTREMELY
FLAMM. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME.
Other Precautions:VAPS WILL ACCUM READILY & MAY IGNITE EXPLOSIVELY.
DURING USE & UNTIL ALL VAPS ARE GONE:KEEP AREA VENTED; DO NOT
SMOKE; EXTING ALL FLAMES, PILOT LIGHTS & HEATERS; TURN OFF STOVES,
ELEC TOOLS & APPLIANC ES & ANY OTHER SOURCES OF IGNIT. (ING 7)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED NIOSH
APPROVED ORGANIC VAPOR/PARTICULATE RESPIRATOR FOR PROTECTION
AGAINST INGREDIENTS.
Ventilation:USE LOC EXHST PREF. GEN EXHST ACCEPT IF EXPOS TO INGS IS
MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STD (ING 11)
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:AGENTS & MOLD MAINTENANCE N.O.D. - 4. FIRE
FIGHT PROC:PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS TO
EXTREME HEAT. EFTS OF OVEREXP:CONTENTS CAN BE HARMFUL/FATAL. WAR
NING:THESE PRODS CONTAIN CHEMS KNOWN TOSTATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS/OTHER REPRO HARM.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:<212F,<100C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.92
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM THESE PRODS MAY BE HAZ AS DEFINED
UNDER THE RCRA (40 CFR 261). WASTE MUST BE TESTED FOR IGNITABILITY
TO DETERMINE APPLIC EPA HAZ WASTE NUMBERS. DO NOT INCIN.
DEPRESSURIZE CNTNR. DISPOSE OF I/A/W FED, STATE & LOC REGS
REGARDING POLLUTION.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:PETROBOND GREEN SAND
CAGE:HO821
CAGE:HO821
CAGE:20064
============= Composition/Information on Ingredients =============
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
CAS:14808-60-7
RTECS #:VV7330000
OSHA PEL:10 MG/M3 RDUST
ACGIH TLV:0.1 MG/M3 RDUST
Ingred Name:SILICA, CRYSTALLINE-CRISTOBALITE
CAS:14464-46-1
RTECS #:VV7325000
OSHA PEL:5 MG/M3 RDUST
ACGIH TLV:5 MG/M3 RDUST
Ingred Name:SILICA, CRYSTALLINE-TRIDYMITE
CAS:15468-32-3
RTECS #:VV7335000
OSHA PEL:5 MG/M3 RDUST
ACGIH TLV:5 MG/M3 RDUST
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES:SLIGHT IRRITATION. SKIN:POTENTIAL
IRRITANT. INHAL:PROLONGED INHALATION MAY CAUSE LUNG INJURY OR
DISEASE. TLV FOR RESPIRABLE DUST: 10MG/M3/ % RESPIRABLE QUARTZ + 2.
TLV FOR "TOTAL DUST":30 MG/M3/ % QUARTZ + 3.
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ, CRISTOBALITE
AND TRIDYMITE:IARC MONOGRAPHS, SUPPLEMENT. VOL 7, PG 341,
1987:GROUP (SUPDAT)
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:FLUSH WITH WATER FOR
AT LEAST 15 MINUTES; IF IRRITATION PERSISTS, CONSULT PHYSICIAN. S
KIN:WASH WITH SOAP AND WATER.
===================== Fire Fighting Measures =====================
Flash Point:NON FLAMMABLE
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN AND COLLECT FOR REUSE OR DISPOSAL.
Neutralizing Agent:NOT APPLICABLE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN SHELTERED AREAS OR COVER FOR
MOISTURE PROTECTION.
Other Precautions:AVOID INHALATION OF MIST OR DUST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC
VAPORS AND/OR NONTOXIC DUSTS.
Ventilation:IF AIRBORNE CONCENTRATIONS EXCEED TLV (SEE HEALTH HAZARD
SECTION), USE LOCAL EXHAUST VENTILATION.
Other Protective Equipment:APRON, EYEWASH STATION.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN:2A. NTP 7TH ANNUAL REPORT ON CARCINOGENS.
1994:ANTICIPATED TO BE CARCINOGEN.
================== Physical/Chemical Properties ==================
Evaporation Rate & Reference:N/K (BUTYL ACETATE=1)
Solubility in Water:LOW
Appearance and Odor:RED SOLIDS WITH SLIGHT ORGANIC ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:NO
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
ALDEHYDES, KETONES AND COMBUSTION PRODUCTS OF NITROGEN AND SULFUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:CHECK WITH LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:USA 505-16
CAGE:JO533
CAGE:0AZS7
CAGE:JO533
============= Composition/Information on Ingredients =============
Ingred Name:IRON
CAS:7439-89-6
RTECS #:NO4565500
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:NICKEL (SARA 313) (CERCLA) (MFR'S CAS #7440-02-2)
CAS:7440-02-0
RTECS #:QR5950000
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Ingred Name:MOLYBDENUM
CAS:7439-98-7
RTECS #:QA4680000
OSHA PEL:10 PPM
ACGIH TLV:10 PPM
Ingred Name:MANGANESE (SARA 313)
CAS:7439-96-5
RTECS #:OO9275000
OSHA PEL:5 MG/M3 DUST, C
ACGIH TLV:5 MG/M3 DUST
Ingred Name:CHROMIUM (SARA 313) (CERCLA)
CAS:7440-47-3
RTECS #:GB4200000
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:SILICON
CAS:7440-21-3
RTECS #:VW0400000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:NIOBIUM; (COLUMBIUM)
CAS:7440-03-1
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:CALCIUM CARBONATE
CAS:1317-65-3
RTECS #:EV9580000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:CALCIUM FLUORIDE
CAS:7789-75-5
RTECS #:EW1760000
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SODIUM SILICATE
CAS:1344-09-8
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:CLAY (KAOLIN); (ALUMINUM SILICATES)
CAS:1332-58-7
RTECS #:GF1670500
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:2 MG/M3 TDUST
Ingred Name:POTASSIUM SILICATES
CAS:1312-76-1
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:CRYOLITE
CAS:15096-52-3
RTECS #:WA9625000
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ZIRCONIUM SILICATES
CAS:7440-42-6
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:COPPER (SARA 313) (CERCLA)
CAS:7440-50-8
RTECS #:GL5325000
OSHA PEL:0.1MG/M3 FUME;1 DUST
ACGIH TLV:0.2 MG/M3 FUME
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (QUARTZ)
CAS:14808-60-7
RTECS #:VV7330000
OSHA PEL:N/K
ACGIH TLV:0.1 MG/M3 RDUST
Ingred Name:SUPDAT: BE REACHED BEFORE LIM OF 5 MG/M3 FOR GEN WELDING
FUMES IS REACHED. WATCH CR(VI) LEVEL. GASEOUS RXN PRODS(ING 19)
RTECS #:9999999ZZ
Ingred Name:ING 18:MAY INCL CO & CO*2. OZONE & NITROGEN OXIDES MAY BE
FORMED BY RADIA FROM ARC. CONTACT NEHC FOR MORE INFO .
RTECS #:9999999ZZ
Ingred Name:EXPLAN OF CARCIN:CRYSTALLINE-QUARTZ:IARC MONO, V 68,
1997:GRP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO BE CARCIN.
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP: IN LUNG) & IS BELIEVED TO AFFECT PULM
FUNC. REPETITIVE EXPOS TO FLUORIDE FUMES &/OR GASES MAY (ING 22)
RTECS #:9999999ZZ
Ingred Name:ING 21: CAUSE EXCESS CALCIFICATION OF BONES & LIGAMENTS OF
RIBS, PELVIS & SPINAL COLUMN. CHROMIUM(VI) CMPDS MAY (ING 23)
RTECS #:9999999ZZ
Ingred Name:ING 22:CAUSE ULCERATION & PERFORATION OF NASAL SEPTUM &
LIVER & KIDNEY DMG. REPETITIVE OVEREXP TO NICKEL OXIDES (ING 24)
RTECS #:9999999ZZ
Ingred Name:ING 23: MAY LEAD TO LUNG FIBROSIS OR PNEUMOCONIOSIS. ARC
RAYS CAN INJURE EYES & BURN SKIN. ELEC SHOCK CAN KILL.
RTECS #:9999999ZZ
Ingred Name:EYE PROT:& FULL LNGTH FSHLD W/FILTER LENS SHADE
#12-14/DARKER. SHIELD OTHERS BY PROVIDING SCREENS & FLASH GOGGS.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE OVEREXP TO WELDING FUMES MAY
RSLT IN DISCOMFORT SUCH AS DIZZ, NAUS OR DRYNESS/IRRIT OF NOSE,
THROAT/EYES. INHAL OF EXTREMELY HIGH LEVELS OF FLUORIDES MAY CAUSE
ABDOM PAIN, DIARR, MUSC WEAK & CON VLS. CONTINUED INHAL COULD CAUSE
UNCON & DEATH. CHROMIUM (VI) CMPDS PRESENT IN FUME MAY CAUSE SEV
IRRIT(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NICKEL: IARC MONO, VOL 49, PG 257,
1990:GRP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO BE
CARCIN. SILICA, (ING 20)
Effects of Overexposure:HLTH HAZ: OF BRONCH TUBES & LUNGS. INGEST OF
CHROMIUM (VI) SALTS MAY CAUSE INJURY/DEATH. CHROMIUM(VI) CMPDS MAY
BURN EYES. CHROMIUM CMPDS MAY CAUSE ALLERGIC RXNS. NICKEL OXIDES IN
FUME MAY CAUSE TIGHT NESS AROUND CHEST, FEVER & ALLERGIC RXNS.
CHRONIC OVEREXP TO WELDING FUMES CAN LEAD TO SIDEROSIS (IRON
DEPOSITS (ING 21)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST: CALL MD IMMED . EYES: IMMED FLUSH W/POTABLE WATER FOR
A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD . SKIN: FLUSH
W/COPIOUS AMTS OF WATER. CALL MD . CALL FOR MED ASSISTANC E. USE
FIRST AID PROCEDURERS RECOM BY AMERICAN RED CROSS. IF BREATHING IS
DFCLT, GIVE OXYGEN. IF NOT BREATHING USE CPR. CONSULT MD IF
IRRITATION OF EYES & SKIN OR FLASH BURNS DEVELOP AFTER EXPOSURE.
===================== Fire Fighting Measures =====================
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NON-FLAMMABLE: WELDING ARC AND SPARKS CAN
IGNITE COMBUSTIBLES. SEE Z-49.1 SAFETY IN WELDING & CUTTING,
PUBLISHED BY AWS, 550 NW LEJEUNE RD, MIAMI, FL 33126.
================== Accidental Release Measures ==================
Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:READ & UNDERSTAND MFR'S INSTRUCTIONS &
PREC LABEL ON PROD. ADVISE WELDERS TO KEEP THEIR HEAD OUT OF FUMES.
SEE ANSI Z49.1 & 29 CFR 1910 FOR MORE INFO.
Other Precautions:ONE METHOD OF DETERMINING COMPOSITION & QTY OF FUMES
& GASES TO WHICH WORKERS ARE EXPOSED IS TO TAKE AIR SAMPLE FROM
INSIDE WELDER'S HELMET WHILE WORN OR IN WORKER'S BREATHING ZONE.
SEE ANSI/AWS F1.1 AVAIL FROM AMERICAN WELDING SOCIETY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED RESPIRABLE FUME RESPIRATOR OR
AIR SUPPLIED RESPIRATOR WHEN WELDING IN CONFINED SPACE OR GENERAL
WORK AREA WHERE LOCAL EXHAUST AND/OR VENTILATION DOES NOT KEEP
EXPOSURE BELOW THE THR ESHOLD LIMIT VALUE.
Ventilation:USE PLENTY OF VENT &/OR LOC EXHST AT ARC TO KEEP FUMES &
GASES BELOW TLV W/IN WORKER'S BRTHG ZONE & GEN WORK AREA.
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . ARM
PROTECTORS, APRON, HATS, SHOULDER PROT & DARK SUBSTANTIAL CLTHG.
Work Hygienic Practices:TRAIN WELDER NOT TO ALLOW ELEC LIVE PARTS TO
GROUND.
Supplemental Safety and Health
HAZ DECOMP PRODS: WELDED, PROCS FOLLOWED & ELECTRODES USED. REASONABLE
EXPECTED FUME CONSTITUENTS OF PROD WOULD INCL: COMPLEX OXIDES OF
ALUMINUM, IRON, MANGANESE, SILICON, TITANIUM, CHROMIUM, NICKEL,
CALCIUM, COLUMBIAN, MOLYBDENUM & COPPER. FLUORIDES WILL ASLO BE
PRESENT. FUME LIM FOR (CR(VI)(0.05 MG/M3) MAY (ING 18)
================== Physical/Chemical Properties ==================
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:WELDING FUMES & GASES CANNOT BE
CLASSIFIED SIMPLY. COMPOSITION & QTY OF FUMES & GASES DEPEND ON
METAL BEING (SUPDAT)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER
OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER APPROVED BY
FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:E S L ANTIWEAR HYDRAULIC OIL
Preparer's Name:R. R. ROGERS
CAGE:18056
CAGE:18056
============= Composition/Information on Ingredients =============
Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY
PARAFFINIC. PEL/TLV AS OIL MIST.
CAS:64742-65-0
RTECS #:PY8038500
Fraction by Wt: 95%
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3;10 STEL
Ingred Name:NON HAZARDOUS INGREDIENTS
Fraction by Wt: BALANCE
Ingred Name:SUPP DATA:AS OILY WASTE I/A/W LOCAL, STATE AND FEDERAL LAWS
FOR OILY WASTES.
RTECS #:9999999ZZ
Ingred Name:HYGIENE PRACT:EXPOSURE. AVOID HARSH SOLVENTS.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: BELIEVED TO BE MINIMALLY
IRRITATING IF NOT IN EXCESS OF TLV. EYES/SKIN: BELIEVED TO BE
MINIMALLY IRRITATING. INGEST: POSSIBLE NAUSEA, DIARRHEA. CHRONIC:
NONE DETERMINED.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:PREEXISTING DISORDERS OF THE EYE,
SKIN AND RESPIRATORY SYSTEM.
======================= First Aid Measures =======================
First Aid:INHAL: (AS MIST): REMOVE TO FRESH AIR. SUPPORT BRTHG/GIVE O*2
IF NECESSARY. EYES: REMOVE CONTACT LENSES. HOLDING LIDS OPEN, FLUSH
W/WATER FOR AT LEAST 15 MINUTES. SKIN: WASH EXPOSED AREA WITH MILD
SOA P AND WARM WATER. NEVER USE HARSH SOLVENTS. INGEST: KEEP PERSON
QUIET AND WARM. GET MEDICAL ADVICE BEFORE TAKING FURTHER ACTION. IF
IRRITATION OR DISCOMFORT PERSISTS, GET MEDICAL ATTENTION PROMPTLY
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:400F,204C
Extinguishing Media:ACCORDING TO NFPA, WATER SPRAY, FOAM, CARBON
DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
(PF N). WATER/FOAM MAY CAUSE FROTHING. USE WATER TO COOL FIRE EXPOS
CNTNRS.IF A LEAK/SPILL HAS IGNITED,(SUPP DATA)
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN SPILL TO PREVENT ENTRY INTO SEWERS,
PUBLIC WATERWAYS, AND ONTO GROUND. LARGE SPILLS: SOAK UP WITH INERT
ABSORBENT, SHOVEL INTO TIGHT CONTAINERS. SMALL SPILLS: MOP UP WITH
STRONG SOAP AND HOT W ATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:PERIODS OF EXPOSURE TO EXTREME
TEMPERATURES SHOULD BE MINIMIZED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF TLV EXCEEDED: ANY NIOSH/MSHA APPROVED
AIR-SUPPLIED RESPIRATOR.
Ventilation:LOCAL EXHAUST/MECHANICAL (GENERAL): ADEQUATE.
Work Hygienic Practices:USE REASONABLE PERSONAL HYGIENE PRACT TO
INCLUDE WASHING EXPOS SKIN W/MILD SOAP & WARM WATER AFTER EACH (ING
4)
Supplemental Safety and Health
FIRE FIGHT PROC:USE WATER SPRAY TO DISPERSE VAPS & TO PROVIDE PROT FOR
PERSONS ATTEMTPING TO STOP LEAK. WASTE DISP METH: AS RECIEVED, PROD
DOES NOT MEET RCRA CRITERIA FOR HAZ SUBSTANCE. AFTER USE, EVA LUATE
FOR CONTAM FROM ENVIRON TO DETERMINE CHANGE IN STATUS. DISPOSE OF
USED PROD & MOP UP WATER (ING 3)
================== Physical/Chemical Properties ==================
Spec Gravity:0.8762 (H*2O=1)
Appearance and Odor:PALE BROWN LIQUID WITH MILD PETROLEUM ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:COMBUSTION PRODUCTS OF NITROGEN,
SULFUR, CARBON MONOXIDE, CO*2, ALDEHYDES AND KETONES.
==================== Disposal Considerations ====================
Waste Disposal Methods:UNDER RCRA, IT IS THE RESPONSIBILITY OF USER OF
PRODS TO DETERMINE, AT TIME OF DISP, WHETHER PROD MEETS RCRA
CRITERIA FOR HAZ WASTE. THIS IS BECAUSE PROD USES, TRANSFORMATIONS,
MIX, PROCESSES, ETC., M AY RENDER THE RSLTG MATL NONHAZ/HAZ. (SUPP
DATA)
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:177 GOLD FLAKE
Preparer's Name:STEPHEN M FUGLSANG
CAGE:EO514
CAGE:EO514
============= Composition/Information on Ingredients =============
Ingred Name:COPPER (DUST & MIST), BRONZE POWDER
CAS:7440-50-8
RTECS #:GL5325000
Fraction by Wt: 70-90%
Other REC Limits:1 MG(CU)/M3 (DUST)
OSHA PEL:0.1 MG(CU)/M3 (FUME)
ACGIH TLV:0.2 MG/M3 (FUME)
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ZINC
CAS:7440-66-6
RTECS #:ZG8600000
Fraction by Wt: 6-25%
ACGIH TLV:10 MG/CUM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ALUMINUM (POWDER)
CAS:7429-90-5
RTECS #:BD0330000
Fraction by Wt: 2-6%
OSHA PEL:15 MG/CUM
ACGIH TLV:10 MG/CUM (DUST)
Ingred Name:STEARIC ACID
CAS:57-11-4
RTECS #:WI2800000
Fraction by Wt: <2%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: IRRITATION &
SENSITIZATION. INHALATION: MUCOUS MEMBRANE IRRITATION, METAL FUME
FEVER, NASAL ULCERATION/PERFORATION. INGESTION: METALLIC TASTE,
DISCOLORATION OF SKIN/HAIR, VOMIT ING, COLLAPSE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN: SENSITIZATION DERMATITIS. INHALATION:
RESPIRATORY SYSTEM, NASAL SEPTUM, & CARDIOVASCULAR SYSTEM EFFECTS.
INGESTION: ACUTE POISONING IS CHARACTERIZED BY HEMOLYSIS, JAUNDICE,
ANURIA, HYPOTENSION, & CONVULSIONS, GASTROINTESTINAL/KIDNEY/LIVER
EFFECTS.
======================= First Aid Measures =======================
First Aid:EYES: IMMEDIATELY WASH W/LARGE AMOUNTS OF WATER. DON'T WEAR
CONTACT LENSES. SKIN: FLUSH W/WATER. INHALATION: REMOVE TO FRESH
AIR. IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION. KEEP
WARM & AT REST. INGESTION: DILUTE W/WATER OR MILK. REMOVE BY
GASTRIC LAVAGE (I.E. STOMACH TUBE) UNLESS PATIENT IS VOMITING.
OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP GENTLY TO AVOID DUST CLOUD FORMATION.
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T WEAR CONTACT LENSES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE DUST MASK IN CONFINED OR ENCLOSED SPACES IF
NEEDED.
Ventilation:SUFFICIENT IN VOLUME & PATTERN TO KEEP AIR CONTAMINATION
BELOW CURRENT APPLICABLE OSHA PERMISSIBLE LIMITS.
Other Protective Equipment:EYE WASH FOUNTAIN, SOAP & WATER WASH STATION
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Vapor Pres:1
Solubility in Water:INSOLUBLE
Appearance and Odor:GOLD COLOR, ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, BASES, & METALS
Hazardous Decomposition Products:HYDROGEN, NOXIOUS COPPER, & ZINC
COMPOUNDS
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:6602880 PLT-1
Preparer's Name:S HEALY
CAGE:FO645
CAGE:FO645
CAGE:6Z677
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM AZIDE, AZIDE *96-4*
CAS:26628-22-8
RTECS #:VY8050000
Other REC Limits:0.1 PPM
ACGIH TLV:C 0.29 MG/CUM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: NASAL IRRITATION. SKIN:
IRRITATION, ABSORPTION, ALLERGIC REACTION. EYES: IRRITATIONS,
CONJUNCTIVITIS. INGESTION: BRONCHIAL IRRITATION, RESPIRATORY
IRRITATION, RESPIRATORY FAILURE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, FAINTNESS,
NAUSEA, LOW BLOOD PRESSURE, BLURRED VISION, SHORTNESS OF BREATH,
COLLAPSE, BRONCHITIS, PALPITATION, WEAKNESS & UNSTEADINESS, COMA,
CONVULSIONS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE CPR.
IF BREATHING IS DIFFICULT GIVE OXYGEN. SKIN: WASH OFF THOROUGHLY
FOR 15 MINS. EYES: RINSE THOROUGHLY W/WATER & GIVE PLENTY OF WATER
TO DRIN K. INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICALS SUCH AS AN SODIUM CARBONATE/SAND.
Fire Fighting Procedures:BURNING SODIUM AZIDE WILL EXPLODE IF WATER IS
USED AS AN EXTINGUISHING MEDIA. SCBA MUST BE WORN.
Unusual Fire/Explosion Hazard:MAY EXPLODE & RELEASE TOXIC FUMES UPON
HEATING. DON'T ALLOW TO CONTACT METALS AT HIGH TEMPS.
(SUPP)
================== Accidental Release Measures ==================
Spill Release Procedures:DILUTE W/RUNNING WATER BEFORE DISCHARGE.
DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM METALS & ACIDS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED
Ventilation:GENERAL/LOCAL EXHAUST TO MEET TLV REQUIREMENTS
Other Protective Equipment:ADEQUATE LABORATORY ATTIRE
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
UNUSUAL FIRE CONT'D: FORMS HIGHLY SENSITIVE EXPLOSIVE COMPOUNDS W/HEAVY
METALS SUCH AS LEAD, SILVER & COPPER. WHEN HEATED TO 662F IT
DECOMPOSES EXOTHERMICALLY, BURNING W/A VERY HOT FLAME & PRODUCING N
ITROGEN & MOLTEN SODIUM.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:527F
Spec Gravity:1.85
Solubility in Water:40.16
Appearance and Odor:WHITE-COLORLESS CRYSTALS/POWDER, ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
METALS, ACIDS, ACID CHLORIDES & STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT
Hazardous Decomposition Products:NITROGEN OXIDES, HYDRAZOIC ACID
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:CONGO RED; CATALOG NO. C58025
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:1-NAPHTHALENESULFONIC ACID, 3,3'-(4,4'-BIPHENYLENEBIS(AZO))
BIS(4-AMINO-), DISODIUM SALT
CAS:573-58-0
RTECS #:QK1400000
Fraction by Wt: >99%
Other REC Limits:NONE SPECIFIED
OSHA PEL:NOT ESTABLISHED.
ACGIH TLV:NOT ESTABLISHED.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE- HARMFUL IF SWALLOWED, INHALED
OR ABSORBED THROUGH SKIN. ORAL LDL0 IN MAN IS 143 MG/KG. MAY CAUSE
EYE, SKIN, RESPIRATORY TRACT IRRITATION. CHRONIC- PULMONARY EDEMA
OR CONGESTION. THE CHEMICAL, P HYSICAL AND TOXICOLOGICAL PROPERTIES
HAVE NOT BEEN THOROUGHLY INVESTIGATED.
Explanation of Carcinogenicity:NOT STATED BY MANUFACTURER
Effects of Overexposure:INGESTION: HARMFUL IF SWALLOWED. INHALATION:
MAY CAUSE IRRITATION AND COUGHING AND MAY CAUSE MUCOUS MEMBRANE
IRRITATION. SKIN: MAY CAUSE IRRITATION AND MAY BE ABSORBED THROUGH
SKIN. PROLONGED AND/OR R EPEATED CONTACT MAY CAUSE DERMATITIS.
EYES: CONTACT CAUSES REDNESS, IRRITATION, AND PAIN.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS MAY BE
MORE SUSCEPTIBLE TO THIS MATERIAL.
======================= First Aid Measures =======================
First Aid:EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES. SEE MD. SKIN: RINSE WITH WATER FOR AT LEAST 15 MINUTES.
REMOVE ANY CONTAMINATED CLOTHING. IF IRRITATION DEVELOPS SEEK
MEDICAL AID. INGESTION: IF SWALLOWED, GIVE WATER TODILUTE. CALL
PHYSICIAN OR POISON CONTROL CENTER. INHALATION: IF INHALED, REMOVE
TO FRESH AIR. GIVE CPR IF NEEDED OR CALL MEDICAL HELP.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:CO2, WATER SPRAY, OR FOAM OR DRY CHEMICAL POWDER.
WATER SPRAY MAY BE USED TO COOL FIRE EXPOSED CONTAINER.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-
APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE
OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:TOXIC FUMES
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS,
PUT IN A CONTAINER FOR FUTURE DISPOSAL. WASH AND VENTILATE SPILL
SITE AFTER PICKUP IS COMPLET E.
Neutralizing Agent:NOT APPLICABLE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE-STORE IN A COOL,DRY PLACE.KEEP
TIGHTLY CLOSED.
Other Precautions:DO NOT RAISE DUST. AVOID CONTACT WITH EYES AND SKIN.
AVOID BREATHING DUST. WASH THOROUGHLY AFTER HANDLING MATERIAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE ONLY IN A CHEMICAL FUME HOOD OR WEAR A
NIOSH/ MSHA APPROVED SELF CONTAINED BREATHING APPARATUS.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:EYE WASH STATION, EMERGENCY SHOWER,
APPROPRIATE LABORATORY COAT TO COVER EXPOSED SKIN
Work Hygienic Practices:TOXIC. DO NOT PERMIT EATING, DRINKING OR
SMOKING NEAR THIS MATERIAL.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
Appearance and Odor:BROWN-RED POWDER
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:NONE KNOWN
Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE, CARBON
DIOXIDE AND SULFUR OXIDES
==================== Disposal Considerations ====================
Waste Disposal Methods:KEEP PENDING DISPOSAL INSTRUCTIONS. SUGGESTION:
DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN
A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
OBSERVE ALL LOCAL,STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:5R598, 5750/5760/5765/5790 DOCUCOLOR (SUPDAT)
CAGE:0E6G9
CAGE:0E6G9
CAGE:26921
============= Composition/Information on Ingredients =============
Ingred Name:BARIUM, CALCIUM, MAGNESIUM, STRONTIUM, ALUMINUM SILICATE
FLUX; (CU-ZN FERRITE POWDER)
CAS:66402-68-4
Fraction by Wt: >86%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:POLYESTER
CAS:128781-91-9
Fraction by Wt: >4.5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:YELLOW PIGMENT 37. % (WT): 0.2-0.4%
CAS:4531-49-1
Fraction by Wt: SEE ING
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SPILL PROC: USED TO REDUCE STATIC BUILDUP. RESIDUE CAN BE
REMOVED WITH SOAP AND COLD WATER. GARMENTS MAY BE (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4: WASHED OR DRY CLEANED AFTER REMOVAL OF LOOSE TONER.
RTECS #:9999999ZZ
Ingred Name:OTHER PROT EQUIP: TONER PROCESSING FACILITIES), GOGGS &
NIOSH APPRVD RESPS MAY BE REQD. FOR MORE INFO, CONT XEROX.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL,RAT) >5 G/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: MINIMAL RESPIRATORY TRACT
IRRITATION MAY OCCUR AS WITH EXPOSURE TO LARGE AMOUNTS OF ANY
NON-TOXIC DUST. ADDNL INFO: RESULTS OBTAINED FROM XEROX SPONSORED
CHRONIC TONER INHAL STUDY, DEMONSTRATED NO LUNG CHANGE IN RATS FOR
LOWEST (1MG/M3) EXPOS LEVEL (I.E. LEVEL MOST RELEVANT TO POTENTIAL
HUMAN (EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZ: EXPOS). A VERY SLIGHT DEGREE OF
FIBROSIS WAS NOTED IN 25% OF ANIMALS @ MIDDLE (4MG/M3) EXPOS LEVEL,
WHILE SLIGHT DEGREE OF FIBROSIS WAS NOTED IN ALL ANIMALS AT HIGHEST
(16MG/M3) EXPOS LEVEL. THESE FINDINGS ARE ATTRIBUTED TO
"LUNGOVERLOADING", GENERIC RESPONSE TO EXCESS AMTS OF ANY DUST
RETAINED IN (SUPDAT)
Medical Cond Aggravated by Exposure:NONE WHEN USED AS DESCRIBED BY
PRODUCT LITERATURE.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SKIN: WASH
WITH SOAP AND WATER. INHALATION: REMOVE FROM EXPOSURE. INGESTION:
DILUTE STOMACH CONTENTS WITH SEVERAL GLASSES OF WATER.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER, DRY CHEMICAL, CARBON DIOXIDE OR FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . AVOID INHALATION OF SMOKE.
Unusual Fire/Explosion Hazard:TONER IS A COMBUSTIBLE POWDER. LIKE MOST
ORGANIC MATERIALS IN POWDER FORM, IT CAN FORM EXPLOSIVE MIXTURES
WHEN DISPERSED IN AIR.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP/VACUUM SPILLED TONER & CAREFULLY
TRANSFER INTO SEALABLE WASTE CNTNR. SWEEP SLOWLY TO MINIMIZE
GENERATION OF DUST DURING CLEAN-UP. IF VACUUM IS USED, MOTOR MUST
BE RATED AS DUST TIGHT. A CONDU CTIVE HOSE BONDED TO MACHINE SHOULD
BE (ING 4)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE.
Other Precautions:AVOID PROLONGED INHALATION OF EXCESSIVE DUST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED WHEN USED AS INTENDED IN XEROX
EQUIPMENT. NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF
CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . FOR
USE OTHER THAN NORM CUSTOMER-OPERATING PROC(SUCH AS IN BULK (ING 6)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR TRADE NAME/PART NO: 40 YELLOW DEVELOPER. EFTS OF OVEREXP: LUNGS FOR
PRLNGD PERIOD. THIS STUDY WAS CONDUCTED USING SPEC TEST TONER TO
COMPLY W/EPA TESTING PROTOCOL. TEST TONER WAS 10 TIMES MORE RES
PIRABLE THAN COMMERCIALLY AVAIL XEROX TONER, & WOULD NOT BE
FUNCTIONALLY SUITABLE FOR XEROX EQUIPMENT.
================== Physical/Chemical Properties ==================
Solubility in Water:NOT KNOWN
Appearance and Odor:YELLOW POWDER/FAINT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:PRODUCTS OF COMBUSTION MAY BE TOXIC.
AVOID BREATHING SMOKE.
==================== Disposal Considerations ====================
Waste Disposal Methods:THIS MATL IS NOT HAZ WASTE ACCORDING TO FED REG
40 CFR 261 WHEN DISPOSED. STATE & LOCAL REQUIREMENTS HOWEVER, MAY
BE MORE RESTRICTIVE. CONSULT W/APPROP FED, STATE & LOC WASTE DISP
AUTH FOR ADDNL INFO. INCINERATE ONLY IN CLSD CONTAINER.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:KRYLON 2603 SPATTER PAINT
CAGE:07982
CAGE:07982
CAGE:54636
============= Composition/Information on Ingredients =============
Ingred Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 9%
OSHA PEL:1000 PPM
ACGIH TLV:SIMPLE ASPHYXIANT
Ingred Name:PROPANE, 2-METHYL-; (ISOBUTANE)
CAS:75-28-5
RTECS #:TZ4300000
Fraction by Wt: 11%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:VM&P NAPHTHA
CAS:8032-32-4
RTECS #:OI6180000
Fraction by Wt: 30%
OSHA PEL:300 PPM;400 STEL
ACGIH TLV:300 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: SKIN ABSORP: NO HAZ KNOWN.
INGEST: MAY BE HARMFUL IF SWALLOWED. INHAL: MAY BE HARMFUL IF
INHALED. LIQ/VAP CAN CAUSE IRRIT OF NOSE, THROAT & LUNGS.
SKIN/EYES: IRRIT. ING 1: MATL IS A SIMPLE ASPH YXIANT, SIGNS &
SYMPS OF OVEREXP INCL CYANOSIS, RESP DISTRESS HDCH, DIZZ, DROW,
UNCON & ASPHY. CAN (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: CAUSE CNS DEPRESS. ING 2: CAN CAUSE
CNS DEPRESS. SIGNS & SYMPS MAY INCL HDCH, DIZZ, NAUS, VOMIT, UNCON
& EVEN ASPHYXIATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST: DO NOT INDUCE VOMITING. CALL A PHYS IMMED. INHAL:
REMOVE TO FRESH AIR. SKIN: FLUSH W/WATER. IF IRRITATION PERSISTS,
CALL A PHYSICIAN. EYE: IMMED FLUSH WITH PLENTY OF WATER FOR AT
LEAST 15 MINU TES. CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:EXTREMELY FLAMM. CONTENTS UNDER PRESS;
EXPOS TO HIGH TEMP; MAY CAUSE BURST. AVOID RADIA, STOVES, DIRECT
SUNLIGHT/OTHER HEAT SOURCE. DO NOT PUNCT/INCIN (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. SOAK UP WITH
ABSORBENT MATERIAL AND REMOVE TO A CHEMICAL DISPOSAL AREA. PREVENT
ENTRY INTO NATURAL BODIES OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE AT TEMPERATURES OVER
120F. AVOID BREATHING VAP/MIST. AVOID CONT W/SKIN/EYES. USE
W/ADEQUATE VENTILATION.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MHA APPROVED RESPIRATORY PROTECTION
REQUIRED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL.
Ventilation:USE W/ADEQUATE VENTILATION.
Other Protective Equipment:SAFETY SHOES, HARD HATS AND SUITABLE
CLOTHING IS STANDARD PRACTICE IN MANY INDUSTRIAL OPERATIONS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXPLO HAZ: CONTAINER. DO NOT SPRAY NEAR OPEN FLAME.
================== Physical/Chemical Properties ==================
HCC:V3
Vapor Pres:50PSIG
Vapor Density:HVR/AIR
Spec Gravity:LTR/WATER
Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE
Solubility in Water:SLIGHT
Percent Volatiles by Volume:80
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CO, CO2.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL, STATE, AND
FEDERAL REQUIREMENTS. EMPTY CONTR: MAY CNTN EXPLOS VAPS. DO NOT
CUT, PUNCTURE/WELD ON/NEARBY. INCINERATION WILL CAUSE CONTAINER TO
BURST VIOLENTLY.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:FS 27038 BLACK S/G LATEX
CAGE:47695
CAGE:47695
============= Composition/Information on Ingredients =============
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: 2-5%
Other REC Limits:IPEL 0.1 MG/M3
OSHA PEL:SEE TABLE Z3
ACGIH TLV:0.1 MG/M3 RDUST;9293
Ingred Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
Fraction by Wt: 2-5%
Other REC Limits:PPG IPEL 3.5 MG/M3
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3
Ingred Name:DEIONIZED WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 60-65%
Other REC Limits:NONE SPECIFIED
Ingred Name:DIETHYLENE GLYCOL MONOPROPYL ETHER (SARA 313)
CAS:6881-94-3
Fraction by Wt: 2-5%
Other REC Limits:NONE SPECIFIED
Ingred Name:2,2,4 TRIMETHYL 1,3 PENTANEDIOL ISOBUTYRATE
CAS:25265-77-4
RTECS #:UF6000000
Fraction by Wt: 1-2%
Other REC Limits:NONE SPECIFIED
Ingred Name:BENZYL ALCOHOL
CAS:100-51-6
RTECS #:DN3150000
Fraction by Wt: 1-2%
Other REC Limits:NONE SPECIFIED
Ingred Name:FILM FORMERS, RESINS AND ADDITIVES
Fraction by Wt: 25-30%
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES
Health Hazards Acute and Chronic:INGEST: HARMFUL OR FATAL. EYE:
IRRITATION. SKIN: SLIGHT SKIN IRRITATION. INHAL: VAPOR/SPRAY MAY BE
HARMFUL IF INHALED. SANDING/GRINDING DUST MAY BE HARMFUL. CHRONIC
OVEREXPOS: INCREASED RISK OF CANCER IN LAB ANIMALS. DISABLING
INJURY (SILICOSIS). APPLIC OF PROD NOT EXPECTED TO GENERATE
DUST--LIMITED POTENTIAL HAZARD.
Explanation of Carcinogenicity:QUARTZ LISTED AS A COMPONENT OF AN
INGREDIENT IS LISTED AS CARCINOGENIC BY THE IARC.
Effects of Overexposure:REDNESS, ITCHING, BURNING SENSATION AND VISUAL
DISTURBANCES MAY INDICATE EXCESSIVE EYE CONTACT. DRYNESS, ITCHING,
CRACKING, BURNING, REDNESS, SWELLING ARE CONDITIONS ASSOCIATED WITH
EXCESSIVE SKIN CON TACT.
======================= First Aid Measures =======================
First Aid:INGESTION: DON'T INDUCE VOMITING. EYE: FLUSH EYES IMMEDIATELY
W/PLENTY OF WATER, 15 MIN. SKIN: FLUSH IMMEDIATELY W/PLENTY OF
WATER FOLLOWED BY WASHING W/SOAP & WATER. INHALATION: REMOVE TO
FRESH AIR.APPLY ARTIF RESPIRATION & OTHER SUPPORTIVE MEASURES AS
REQUIRED. OTHER: IF INGESTION, ANY TYPE OF OVEREXPOSURE/SYMPTOMS OF
OVEREXPOSURE OCCUR CONTACT POISON CONTROL CTR/EMERG RM/DR. HAVE
MSDS AVAIL.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Extinguishing Media:NFPA CLASS B EXTINGUISHERS (CO2, DRY CHEMICAL,
UNIVERSAL AQUEOUS FILM FORMING FOAM) TO EXTINGUISH NFPA CLASS IIIB
FIRE.
Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE. USE WATER
SPRAY (PREFER FOG NOZZLES) TO COOL CLOSED CNTNRS (PREVENT PRESS
BLDUP/AUTO IGNIT/EXPLOS W/HEAT). FIREMEN WEAR SCBA.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE OR BURST
(DUE TO BUILD-UP OF STEAM PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:PROVIDE MAXIMUM VENTILATION. ONLY PERSONNEL
BE PERMITTED IN THE AREA. REMOVE ALL SOURCES OF IGNITION. TAKE UP
SPILLED MAT'L W/SAWDUS T, VERMICULITE OR OTHER ABSORB & PLACE IN
CNTNR.
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T STORE ABOVE 120 F. STORE LRG
QUANTITIES IN BLDG DESIGNED & PROTECTED FOR STORAGE OF NFPA CLASS
IIIB COMBUSTIBLE LIQUIDS. PROTECT FROM FREEZING.
Other Precautions:IF THIS MATERIAL IS PART OF A MULTIPLE COMPONENT
SYSTEM, READ THE MATERIAL SAFETY DATA SHEETS FOR THE OTHER COMPNENT
OR COMPONENTS BEFORE BLENDING AS THE RESULTING MIXTURE MAY HAVE THE
HAZARDS OF ALL OF ITS PARTS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE VENTILATION IS INADEQUATE, USE A SUITABLE
RESPIRATOR.
Ventilation:PROVIDE GEN DILUTION/LOCAL EXHAUST VENT (VOL/PATTRN) TO
KEEP CONC OF INGRED BELOW LOWEST TLV/LEL/REMOVE DECOMP PRODUCTS.
Other Protective Equipment:WEAR PROTECTIVE CLOTHING CONSTRUCTED OF
NITRILE, NEOPRENE OR LATEX.
Work Hygienic Practices:CLEAN OR DISCARD CONTAMINATED CLOTHING AND
SHOES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:100 TO 244C
Vapor Pres:17.2
Vapor Density:> AIR
Spec Gravity:1.04
Evaporation Rate & Reference:32 (BU AC=100)
Solubility in Water:65.4%
Appearance and Odor:VISCOUS LIQUID W/ODOR CHARACTERISTIC OF CHEMCIAL
FAMILY & SOLVENTS LISTED.
Percent Volatiles by Volume:70.90
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG ALKALIES, STRONG MINERAL ACIDS OR STRONG
OXIDIZING AGENTS.
Hazardous Decomposition Products:HEAT OR WELDING, BRAZING, FLAME
CUTTING SURFACES COATED W/THIS PROD MAY PRODUCE FUMES INCLUDING:
CARBON MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE
WITH FEDERAL, STATE, PROVINCIAL AND LOCAL ENVIRONMENTAL CONTROL
REGULATIONS. EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF
THROUGH AN APPROVED WAS TE MANAGEMENT FACILITY.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:GANTREZ ES-225 POLYMER
CAGE:FO504
CAGE:FO504
CAGE:46575
============= Composition/Information on Ingredients =============
Ingred Name:MONOETHYL ESTER OF POLY(METHYL VINYL ETHER/MALEIC ACID)
CAS:25087-06-3
Ingred Name:ETHYL ALCOHOL (ETHANOL)
CAS:64-17-5
RTECS #:KQ6300000
Fraction by Wt: 50%
Other REC Limits:1900 MG/CUM
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9192
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RATS): >25,000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: IRRITATION OF MUCOUS
MEMBRANES, NOSE & THROAT, COUGHING & DIFFICULTY IN BREATHING. SKIN:
IRRITATION & DERMATITIS. EYES: IRRITATION, PAINFUL STINGING,
BURNING, WATERING, CONJUNCTIVITIES, OP AQUENESS OF CORNEA, &
POSSIBLY LEADING TO LOSS OF SLIGHT.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: IRRITATION OF MUCOUS MEMBRANES,
NOSE/THROAT/COUGHING & DIFFICULTY BREATHING. SKIN:
IRRITATION/DERMATITIS. EYES: IRRITATION, PAINFUL STINGING, BURNING,
WATERING, CONJUNCTIVITIS, OPAQUENESS OF CORNEA/POSSIBLY LEAING TO
LOSS OF SLIGHT. ANIMAL TESTING ON ANALOGOUS MATERIAL DEMONSTRATED
EXTREME EYE IRRITATION.
Medical Cond Aggravated by Exposure:DERMATITIS
======================= First Aid Measures =======================
First Aid:INGESTION: INDUCE VOMITING BY GIVING 2 GLASSES OF WATER.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL
PHYSICIAN. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPI RATION, PREFERABLY MOUTH-TO-MOUTH. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. CALL PHYSICIAN. SKIN: WASH W/SOAP & WATER.
EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES. CALL
PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:46.00F
Lower Limits:3.30%
Upper Limits:19.00%
Extinguishing Media:ALCOHOL FOAM, DRY CHEMICAL, CO2. WATER MAY BE
INEFFECTIVE, BUT SHOULD BE USED TO KEEP FIRE-EXPOSED CONTAINERS
COOL.
Fire Fighting Procedures:FIREFIGHTERS SHOULD USE SELF-CONTAINED
BREATHING APPARATUS & WEAR PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:MODERATE EXPLOSION HAZARD, WHEN EXPOSED
TO FLAMES DUE TO ETHANOL.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE SOURCES OF IGNITION. ABSORB W/EARTH,
SAND OR SIMILAR INERT MATERIAL & DISPOSE OF W/SOLID WASTE ACCORDING
TO FEDERAL, STATE, & LOCL REGULATIONS. FLUSH SPILL AREA W/WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP CONTAINER
& VAPORS AWAY FROM HEAT, SPARKS & FLAME. INSIDE STORAGE SHOULD BE
IN A STANDARD FLAMMABLE LIQUID STORAGE ROOM.
Other Precautions:WASH THOROUGHLY AFTER HANDLING. DON'T GET IN EYES.
AVOID BREATHING VAPOR. WASH EQUIPMENT W/STEAM/WARM WATER UNTIL
CLEAN. CHECK FOR FLAMMABLES W/AN EXPLOSION METER & CHECK THE OXYGEN
LEVEL W/AN OXYGEN METER. USE ADEQUATE VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH-APPROVED RESPIRATOR, WHERE TLV OR PEL MAY
BE EXCEEDED.
Ventilation:USE W/ADEQUATE VENTILATION
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. FOLLOW GOOD
INDUSTRIAL SAFETY PRACTICES BEFORE ENTERING EQUIPMENT.
Supplemental Safety and Health
90-DAY SUBCHRONIC INHALATION: BASIC HAIR SPRAY FORMULATIONS IN AEROSOL
FORM, CONTAINING 6% GANTREZ ES-225, FOR 4 HRS/DAY, 5 DAYS/WEEK.
CONCENTRATION OF PARTICULATES RANGED FROM 0.531 TO 6.59 MICROGRAM
S/LITER, NO TOXIC EFFECTS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:78.50C
Vapor Pres:40.00
Vapor Density:1.59
Spec Gravity:0.9830
Evaporation Rate & Reference:(BU AC = 1): 2.70
Solubility in Water:NOT SOLUBLE
Appearance and Odor:VISCOUS LIQUID W/ETHANOLIC ODOR
Percent Volatiles by Volume:50%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NITRIC & SULFURIC ACID, STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, IGNITION SOURCES, FLAME, & SPARKS
Hazardous Decomposition Products:CO, CO2
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF W/LIQUID WASTE ACCORDING TO FEDERAL,
STATE, & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:TT-E-2784
Preparer's Name:ONEY FLEMING
CAGE:JO954
CAGE:JO954
CAGE:39934
============= Composition/Information on Ingredients =============
Ingred Name:PROPYLENE GLYCOL
CAS:57-55-6
RTECS #:TY2000000
Fraction by Wt: 3.69%
Other REC Limits:NONE RECOMMENDED
Ingred Name:2,2,4-TRIMETHYL-1-3-PENTANEDIOL MONOISOBUTYRATE
CAS:25265-77-4
RTECS #:UF6000000
Fraction by Wt: 3.41%
Other REC Limits:NONE RECOMMENDED
Ingred Name:DIMETHYLAMINOETHANOL LOW VOC
CAS:108-01-0
RTECS #:KK6125000
Fraction by Wt: 0.21%
Other REC Limits:NONE RECOMMENDED
Ingred Name:2-N-OCTYL-4-ISOTHIAZOLIN-3-ONE
CAS:26530-20-1
Fraction by Wt: 0.18%
Other REC Limits:NONE RECOMMENDED
Ingred Name:NON HAZARDOUS INGREDIENTS
Fraction by Wt: 92.51%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT RELEVANT
ACGIH TLV:NOT RELEVANT
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CAN CAUSE IRRITATION OF RESPIRATORY
PASSAGES.
Effects of Overexposure:INHALATION OF VAPOR/MIST CAN CAUSE HEADACHES,
NAUSEA, IRRITATION OF NOSE/THROAT/LUNGS. EYES: CAN CAUSE SLIGHT
IRRITATION. CHRONIC SKIN CONTACT CAN CAUSE SLIGHT IRRITATION.
Medical Cond Aggravated by Exposure:PREEXISTING LUNG DISEASE MAY BE
AGGRAVATED BY EXPOSURE.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/LARGE AMTS WATER 15 MINUTES. CONSULT DR. IF
IRRITATION PERSISTS. SKIN: WASH AFFECTED AREA THOROUGHLY W/SOAP &
WATER. INGESTION: GIVE 2 GLASSES WATER. CONSULT DR.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:>212F,>100C
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:WEAR SCBA (PRESSURE DEMAND MSHA/NIOSH APPROVED
OR EQUIVALENT) & FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:MATERIAL CAN SPLATTER ABOVE 212F/100C.
POLYMER FILM CAN BURN.
================== Accidental Release Measures ==================
Spill Release Procedures:KEEP SPECTATORS AWAY. FLOOR MAY BE SLIPPERY.
USE CARE TO AVOID FALLING. CONTAIN W/INERT MAT'L (SAND/EARTH).
TRANSFER LIQ/SOLID DIKING MAT'L TO SEPARATE SUITABLE CONTAINERS FOR
RECOVERY/DISPOSAL.
Neutralizing Agent:NONE
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP FROM FREEZING. DO NOT TAKE
INTERNALLY. KEEP AWAY FROM CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:APPROVED MECHANICAL FILTER RESPIRATOR TO REMOVE
SOLID AIRBORNE PARTICLES OF OVER-SPRAY DURING SPRAY APPLICATION.
Ventilation:NORMAL, SUCH AS FAN.
Other Protective Equipment:EYEWASH STATION.
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212 TO 644F
Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C
Decomp Temp:Decomp Text:350F,177C
Vapor Pres:NONE
Vapor Density:>AIR
Spec Gravity:1.12
VOC Pounds/Gallon:191
pH:9 MAX
VOC Grams/Liter:1.59
Viscosity:77-95 KU
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:SLIGHT
Appearance and Odor:YELLOW LIQUID, SLIGHT ODOR
Percent Volatiles by Volume:60.6
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:ACRYLIC MONOMERS
==================== Disposal Considerations ====================
Waste Disposal Methods:KEEP SPILLS/CLEANING RUN-OFF OUT OF SEWERS &
OPEN BODIES OF WATER. CONSULT FEDERAL/STATE/LOCAL AUTHORITIES FOR
PROPER DISPOSAL PROCEDURES CONCERNING HEALTH & ENVIRONMENT.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:STAINLESS STEEL CLEANER AND POLISH
CAGE:5G570
CAGE:85884
CAGE:5G570
============= Composition/Information on Ingredients =============
Ingred Name:MINERAL SPIRITS (HEAVY NAPTHA)
CAS:64475-85-0
RTECS #:PY8240000
Fraction by Wt: 10%
ACGIH TLV:200
Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROETHANE) (SARA III)
CAS:71-55-6
RTECS #:KJ2975000
Fraction by Wt: 30%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:350 PPM
ACGIH TLV:350 PPM/450STEL;9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ozone Depleting Chemical:1
Ingred Name:ISOBUTANE (PROPELLANT)
CAS:75-28-5
RTECS #:TZ4300000
Fraction by Wt: 5%
ACGIH TLV:2300
Ingred Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 5%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT; 9192
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Effects of Overexposure:MAY CAUSE EYE OR SKIN IRRITATION. MAY CAUSE
STOMACH DISTRESS, NAUSEA OR VOMITING IF SWALLOWED. MAY CAUSE
BREATHING DIFFICULTIES,DIZZINESS,HEADACHE OR UNCONSCIOUSNESS.
======================= First Aid Measures =======================
First Aid:IF INHALED,IMMEDIATELY MOVE TO FRESH AIR.EYES:FLUSH WITH
WATER FOR 15 MINUTES. IF SWALLOWED,RINSE MOUTH,THEN DRINK ONE OR
TWO LARGE GLASSES OF WATER. DO NOT INDUCE VOMITING. SKIN:FLUSH WITH
WATER,THENWASH WITH SOAP AND WATER. IF IRRITATION OR DISCOMFORT
PERSISTS,CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:165F
Extinguishing Media:CARBON DIOXIDE,DRY CHEMICAL,FOAM
Fire Fighting Procedures:WATER MAY BE USED TO KEEP FIRE EXPOSED
CONTAINERS COOL BUT MAY BE INEFFECTIVE AS AN EXTINGUISHING AGENT.
Unusual Fire/Explosion Hazard:CONTENTS UNDER PRESSURE.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE.
AVOID BREATHING VAPORS AND REMOVE WITH INERT ABSORBENT.
======================Handling and Storage ======================
Other Precautions:UNMIXED PROPELLANT IS EXTREMELY FLAMMABLE. TO REDUCE
FLAMMABILITY,SHAKE WELL BEFORE USING.
============= Exposure Controls/Personal Protection =============
Ventilation:VENTILATE AS APPROPRIATE FOR AMOUNTS OF SPILL.
Supplemental Safety and Health
DO NOT STORE ABOVE 120F. KEEP AT ROOM TEMPERATURE AS EXPOSURE TO DIRECT
SUNLIGHT OR OTHER HEAT MAY CAUSE BURSTING. DO NOT PUNCTURE OR
INCINERATE. DO NOT SPRAY NEAR FIRE OR OPEN FLAME.
================== Physical/Chemical Properties ==================
Solubility in Water:NEGLIGIBLE
Appearance and Odor:AEROSOL.MILD HYDROCARBON ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT INCINERATE. CONSULT STATE AND LOCAL
AUTHORITIES FOR RESTRICTIONS ON DISPOSAL OF CHEMICAL WASTE.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:COBALT CHLORIDE: PRODUCT CODE 1670 OR 4532
Resp. Party Other MSDS Num.:C4928
CAGE:70829
CAGE:70829
============= Composition/Information on Ingredients =============
Ingred Name:COBALT(II) CHLORIDE
CAS:7646-79-9
RTECS #:GF9800000
Minumum % Wt:90.
Maxumum % Wt:100.
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL RAT LD50 = 80 MG/KG
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: CAUSES IRRITATION TO THE
RESPIRATORY TRACT, RESPIRATORY HYPERSENSITIVITY, ASTHMA. INHALATION
OF COBALT DUST AND FUMES IS ASSOCIATED WITH AN INCREASE INCIDENCE
OF LUNG DISEASE. INGESTION: T OXIC. MAY HAVE ACCUMULATIVE TOXIC
ACTION WHERE ELIMINATION CANNOT KEEP PACE WITH ABSORPTION. LARGE
AMOUNTS DEPRESS ERYTHROCYTE PRODUCTION. SKIN: CAUSES IRRITATION TO
SKIN. EYE CONTACT: CAUSES IRRITAT ION. CHRONIC EXPOSURE: REPEATED
ORAL ADMINISTRATION MAY PRODUCE GOITER AND REDUCED THYROID
ACTIVITY. PROLONGED OR REPEATED SKIN EXPOSURE MAY CAUSE DERMATITIS.
CHRONIC EXPOSURE ASSOCIATED WITH KIDNEY, LIVER, HEART AND LUNG
DISEASE.
Explanation of Carcinogenicity:COBALT II CHLORIDE, CAS # 7646-79-9,
IARC 2B. COBALT AND ITS COMPOUNDS HAVE BEEN SHOWN TO CAUSE CANCER
IN LABORATORY ANIMALS.
Effects of Overexposure:INHALATION: COUGHING, SHORTNESS OF BREATH,
NAUSEA. INGESTION: ABDOMINAL PAIN, NAUSEA, VOMITING, FLUSHING OF
FACE AND EARS, MILD HYPOTENSION, RASH, RINGING IN EARS.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS OR EYE PROBLEMS, IMPAIRED LIVER, KIDNEY OR RESPIRATORY
FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS SUBSTANCE.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET
MEDICAL ATTENTION. INGESTION: INDUCE VOMITING IMMEDIATELY AS
DIRECTED BY MED ICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. GET MEDICAL ATTENTION. EYES: IMMEDIATELY FLUSH
WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING LIDS. GET
MEDICAL ATTENTION IMMEDIATELY. SKIN: WIPE OFF EXCESS THEN
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES. GET ATTENTION IMMEDIATELY.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE.
Fire Fighting Procedures:USE PROTECTIVE CLOTHING AND BREATHING
EQUIPMENT APPROPRIATE FOR SURROUNDING FIRE.
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSION HAZARD.
NOT CONSIDERED TO BE A FIRE HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. WEAR APPROPRIATE PERSONAL
PROTECTIVE EQUIPMENT. SPILLED: SWEEP UP & CONTAINERIZE FOR
RECLAIMATION OR DISPOSAL. VACUUMING OR WET SWEEPING MAY BE USED TO
MINIMIZE DUST DISPERSAL. CERCLA REQUIRES REPORTING SPILLS &
RELEASES TO SOIL, WATER AND AIR IN EXCESS OF REPORTABLE QUANTITIES.
THE TOLL FREE NUMBER FOR THE US COAST GUARD NATIONAL RESPONSE
CENTER IS 800-424-8802.
Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER,
STORED IN A DRY, COOL, WELL-VENTILATED AREA. PROTECT AGAINST
PHYSICAL DAMAGE. ISOLATE FROM INCOMPATIBLE SUBSTANCES. WASH HANDS
BEFORE EATING AND DO NOT EAT, DRINK O R SMOKE IN WORKPLACE.
Other Precautions:CONTAINERS OF THIS PRODUCT RETAIN PRODUCT RESIDUES
(DUSTS, SOLIDS); OBSERVE ALL WARNINGS AND PRECAUTIONS LISTED FOR
THE PRODUCT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:HALF-FACE HIGH EFFICIENCY RESPIRATOR MAY BE WORN
FOR UP TO 10 TIMES THE EXPOSURE LIMIT. A FULL-FACE HIGH EFFICIENCY
RESPIRATOR MAY BE WORN UP TO 50 TIMES THE EXPOSURE LIMIT. FOR
EMERGENCIES OR WHERE EXPSOURE LIMITS ARE NOT KNOWN, A
FULL-FACEPIECE, POSITIVE PRESSURE, AIR SUPPLIED RESPIRATOR MAY BE
USED.
Ventilation:LOCAL/GENERAL EXHAUST IS RECOMMENDED TO KEEP EMPLOYEE
EXPSOURES BELOW THE AIRBORNE EXPOSURE LIMITS.
Other Protective Equipment:MAINTAIN EYE WASH FOUNTAIN AND QUICK-DRENCH
FACILITIES IN WORK AREA. WEAR BODY-COVERING CLOTHING.
Work Hygienic Practices:WASH CLOTHING BEFORE REUSE. THOROUGHLY CLEAN
SHOES BEFORE REUSE.
Supplemental Safety and Health
WARNING: AIR-PURIFYING RESPIRATORS DO NOT PROTECT IN OXYGEN-DEFICIENT
ATMOSPHERE.
================== Physical/Chemical Properties ==================
HCC:N1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=110.C, 230.F
B.P. Text:LOSES 6H2O
Melt/Freeze Pt:=86.C, 186.8F
Vapor Pres:40 MM HG @ 770C
Spec Gravity:1.92
pH:4.6
Evaporation Rate & Reference:NO INFORMATION FOUND
Solubility in Water:APPRECIABLE
Appearance and Odor:ODORLESS, ROSE-RED CRYSTALS.
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, STRONG MINERAL ACIDS, TERT-BUTYL HYDROPREOXIDE,
POTASSIUM AND METAL HALIDES, SODIUM DISPERSIONS.
Stability Condition to Avoid:INCOMPATIBLES.
Hazardous Decomposition Products:EMITS TOXIC CHLORIDES AND POSSIBLY
COBALT FUMES WHEN HEATED TO DECOMPOSITION. COBALT OXIDE FUMES MAY
FORM IN FIRE.
Conditions to Avoid Polymerization:INCOMPATIBLES.
=================== Toxicological Information===================
Toxicological Information:ORAL RAT LD50: 80 MG/KG. INVESTIGATED AS A
TUMORIGEN, MUTAGEN, REPRODUCTIVE FACTOR. CARCINOGENICITY: COBALT
AND ITS COMPOUNDS HAVE BEEN SHOWN TO CAUSE CANCER IN LABORATORY
ANIMALS.
===================== Ecological Information =====================
Ecological:ENVIRONMENTAL FATE: NO INFORMATION FOUND. ENVIRONMENTAL
TOXICITY: NO INFORMATION FOUND.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE USED FOR RECOVERY OR
RECYCLING SHOULD BE MANAGED IN AN APPROPRIATE & APPROVED WASTE
DISPOSAL FACILITY. PROCESSING, USE OR CONTAMINATION OF THIS PRODUCT
MAY CHANGE THE WASTE MANAGEME NT OPTIONS. DISPOSE OF CONTAINER &
UNUSED CONTENTS IN ACCORDANCE WITH FEDERAL, STATE & LOCAL REQUIRE
MENTS.
=================== MSDS Transport Information ===================
Transport Information:NOT REGULATED.
===================== Regulatory Information =====================
SARA Title III Information:SECTIONS 302 TPQ & RQ: NOT LISTED. SECTION
313: NOT LISTED. SARA 311/312: ACUTE-YES, CHRONIC-YES, FIRE-NO,
PRESSURE-NO, REACTIVITY-NO.
Federal Regulatory Information:CERCLA:1(?). RCRA 261.33-NO, TSCA
8(D)-NO. CHEMICAL WEAPONS CONVENTION: NO. TSCA 12(B): NO, CDTA: NO.
State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:METAPHOSPHORIC ACID, PX1004
CAGE:0SK29
CAGE:0SK29
CAGE:63612
============= Composition/Information on Ingredients =============
Ingred Name:METAPHOSPHORIC ACID
CAS:37267-86-0
Ingred Name:METAPHOSPHORIC ACID, SODIUM SALT; (CONTAINS APPROX 65%
SODIUM METAPHOSPHATE AS STABILIZER)
CAS:10361-03-2
RTECS #:OY3750000
Fraction by Wt: 65%
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CAUSES BURNS (POSSIBLY SEVERE) ON
CONTACT WITH SKIN OR EYES. DUST INHALATION IRRITATING TO UPPER
RESPIRATORY TRACT AND MAY CAUSE LUNG DAMAGE. INGESTION CAUSES BURNS
TO DIGESTIVE TRACT.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:DATA NOT AVAILABLE.
======================= First Aid Measures =======================
First Aid:GET MED ASSISTANCE FOR ALL CASES OF OVEREXPOSURE! SKIN: IMMED
FLUSH THORO WITH LARGE AMOUNTS OF WATER. EYES: IMMED FLUSH THORO
WITH WATER FOR AT LEAST 15 MIN. INHAL: REMOVE TO FRESH AIR; GIVE
ARTF RES P IF BREATHING HAS STOPPED. INGEST: DO NOT INDUCE VOMIT;
IF CONSCIOUS, GIVE WATER FREELY AND GET MED ATTN.
===================== Fire Fighting Measures =====================
Flash Point:NOT COMBUSTIBLE
Extinguishing Media:WATER SPRAY TO COOL CONTAINERS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCES TOXIC
FUMES.
================== Accidental Release Measures ==================
Spill Release Procedures:TAKE UP AND CONTAINERIZE FOR PROPER DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTR TIGHTLY CLSD. STORE @
CONTROLLED ROOM TEMP AWAY FROM METALS. DO NOT BRTH DUST. DO NOT GET
IN EYES, ON SKIN/CLTHG. DO NOT TAKE INTERNALLY.
Other Precautions:RETAINED RESIDUES MAY MAKE EMPTY CONTAINERS
HAZARDOUS: USE CAUTION!
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED
FUME HOOD OR WITH ADEQUATE VENTILATION.
Other Protective Equipment:PROTECTIVE CLOTHING. EYEWASH & SAFETY
EQUIPMENT. DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
BP: SUBLIMES AT RED HEAT.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:SUPP DATA
Spec Gravity:2.2-2.5
Evaporation Rate & Reference:NEG
Solubility in Water:88
Appearance and Odor:CLEAR, COLORLESS SOLID, ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
BASES, METALS, CARBONATES,SULFIDES, CYANIDES.
Stability Condition to Avoid:REACTS WITH COMMON MTALS, IF HEATED OR ON
SOLN, TO PRODUCE HYDROGEN GAS WHICH FORMS FLAMMABLE MIXTURE WITH
AIR.
Hazardous Decomposition Products:PO*X, NA2O.
==================== Disposal Considerations ====================
Waste Disposal Methods:TO BE PERFORMED IN COMPLIANCE WITH ALL CURRENT
LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:CUPRIC SULFATE PENTAHYDRATE APPROX 99%, C7631
CAGE:21076
CAGE:21076
============= Composition/Information on Ingredients =============
Ingred Name:CUPRIC SULFATE PENTAHYDRATE
CAS:7758-99-8
RTECS #:GL8900000
= Wt:99.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED. MAY BE
HARMFUL IF INHALED. MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN.
CAUSES SEVERE EYE IRRITATION. CAUSES SKIN IRRITATION. MATERIAL IS
IRRITATING TO MUCOUS MEMBRANES AN D UPPER RESPIRATORY TRACT. MAY
CAUSE ALLERGIC SKIN REACTION. ABSORPTION INTO THE BODY LEADS TO THE
FORMATION OF METHEMOGLOBIN WHICH, IN SUFFICIENT CONCENTRATIONS,
CAUSES CYANOSIS. ONSET MAY BE DELAYED 2 TO 4 HOURS OR LONGER.
EXPOSURE CAN CAUSE DAMAGE TO THE EYES, GASTROINTESTINAL
DISTURBANCES. CHRONIC: POSSIBLE RISK OF CONGENITAL MALFORMATION IN
THE FETUS. MAY CAUSE REPRODUCTIVE DISORDERS. (EFFECT S OF
OVEREXPOSURE)
Effects of Overexposure:HEALTH HAZARDS: TARGET ORGANS: LIVER, KIDNEYS,
BLOOD. ADDITIONAL INFORMATION: CHRONIC COPPER POISONING IS TYPIFIED
BY HEPATIC CIRRHOSIS, BRAIN DAMAGE AND DEMYELINATION, KIDNEY
DEFECTS, AND COPPER DEPO SITION IN THE CORNEA AS EXEMPLIFIED BY
HUMANS WITH WILSON'S DISEASE. IT HAS ALSO BEEN REPORTED THAT COPPER
POISONING HAS LEAD TO HEMOLYTIC ANEMIA AND ACCELERATES
ARTERIOSCLEROSIS.
======================= First Aid Measures =======================
First Aid:SKIN: IMMEDIATELY WASH WITH SOAP AND COPIOUS AMOUNTS OF
WATER. EYES: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. INHALATION: REMOVE TO FRESH AIR. IF NOT
BREATHING, GIVE AR TIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. INGESTION: WASH OUT MOUTH WITH WATER PROVIDED PERSON
IS CONSCIOUS. CALL A PHYSICIAN. REMOVE AND WASH CONTAMINATED
CLOTHING PROMPTLY.
===================== Fire Fighting Measures =====================
Extinguishing Media:NON-COMBUSTIBLE. USE EXTINGUISHING MEDIA
APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH APPROVED RESPIRATOR, CHEMICAL
PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST.
VENTILATE AREA AND WASH SPILL S ITE AFTER MATERIAL PICKUP IS
COMPLETE.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT BREATHE DUST. DO NOT GET IN
EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE.
KEEP TIGHTLY CLOSED. STORE IN A COOL DRY PLACE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . WEAR OTHER PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
TOX INFO: KIDNEY, URETER, BLADDER (OTHER CHANGES); BLOOD (HEMORR, OTHER
HEMOLYSIS W/OR W/OUT ANEMIA); NUTRITIONAL & GROSS METABOLIC (WT
LOSS/DECRD WT GAIN). ONLY SELECTED REGISTRY OF TOX EFTS OF CHEM
SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN
RTECS FOR COMPLETE INFO.
================== Physical/Chemical Properties ==================
Vapor Pres:7.3 MM @ 25C
Spec Gravity:2.284
Appearance and Odor:BLUE CRYSTALS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CORRODES STEEL. FINELY POWDERED METALS.
Stability Condition to Avoid:HEAT. SENSITIVE TO AIR. EFFLORESCENT.
Hazardous Decomposition Products:TOXIC FUMES OF SULFUR OXIDES.
=================== Toxicological Information===================
Toxicological Information:RTECS #: GL8900000 - COPPER (II) SULFATE,
PENTAHYDRATE (1:1:5). TOXICITIY DATA: ORL-HMN LDLO: 1088 MG/KG;
IPRAA8 18, 807, 1965. UNR-MAN LDLO: 221 MG/KG; 85DCAI 2, 73, 1970.
ORL-RAT LD50: 300 MG/KG; 85 ARAE 2, 182, 1977. SKN-RAT LD50: >2
GM/KG; NNGADV 18, S161, 1993. IPR-RAT LD50: 18700 UG/KG; GISAAA 53
(4), 78, 1988. IPR-MUS LD50: 33 MG/KG; BCPCA6 14, 289, 1965.
IPR-MAM LD50: 7500 UG/KG; JANSAG 55, 337, 1982. TARGET ORGAN DATA:
AUTONOMIC NERV SYS (OTHER: PARASYMPATHOMIMETIC); BEHAVIORAL
(SOMNOLENCE, COMA); GI (CHANGES IN STRUCTURE/FUNC OF SALIVARY
GLANDS, HYPERMOTILITY, DIARR, NAUS/VOMIT); LIVE R (JAUN,
HEPATOCELLULAR); (SUP DAT)
===================== Ecological Information =====================
Ecological:DATA NOT YET AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTACT A LICENSED PROFESSIONAL WASTE DISPOSAL
SERVICE TO DISPOSE OF THIS MATERIAL. OBSERVE ALL FEDERAL, STATE AND
LOCAL ENVIRONMENTAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.
===================== Regulatory Information =====================
SARA Title III Information:THIS PRODUCT IS SUBJECT TO SARA SECTION 313
REPORTING REQUIREMENTS - COPPER COMPOUNDS.
Federal Regulatory Information:EUROPEAN INFO: CAUTION: SUBSTANCE NOT
YET FULLY TESTED. HARMFUL. R 22: HARMFUL IF SWALLOWED. R 36/38:
IRRITATING TO EYES & SKIN. S 22: DO NOT BREATHE DUST. REVIEWS,
STDS, & REGS: OEL=MAK. EPA FIFRA 19 88 PESTICIDE SUBJECT TO
REGISTRATION/RE-REGISTRATION FEREAC 54, 7740, 1989. OEL-ARAB
REPUBLIC OF EGYPT, OEL-DENMARK, OEL-GERMANY, OEL-THE PHILIPPINES,
OEL-POLAND, OEL-THAILAND: TWA 0.1 MG(CU)/M3 (FUME ) JAN 1993.
OEL-AUSTRALIA, OEL-BELGIUM, OEL-FINLAND, OEL-FRANCE, OEL-INDIA,
OEL-THE NETHERLANDS, OEL -SWEDEN, OEL-UNITED KINGDOM: TWA 0.2
MG(CU)/M3 (FUME) JAN 1993. (OTHER INFO)
State Regulatory Information:OTHER INFO: OEL-UNITED KINGDOM: TWA 1
MG(CU)/M3 JAN 1993. NOES 1983: HZD X5421; NIS 13; TNF 979; NOS 21;
TNE 10821; TFE 3606. NTP TOXICITY STUDIES, RPT# TOX-29, OCTOBER
1997.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:POLY ENAMEL INK, PE-113
Preparer's Name:BEBE ALI
CAGE:38065
CAGE:38065
============= Composition/Information on Ingredients =============
Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; (PETROLEUM
HYDROCARBON). LD50 (ORAL RAT): 8700 MG/KG
CAS:64742-47-8
RTECS #:OA5504000
Fraction by Wt: 15-40%
OSHA PEL:N/K
ACGIH TLV:25 PPM (MFR)
Ingred Name:STODDARD SOLVENT; (PETROLEUM DISTILLATES). LD50 (ORAL RAT):
10 ML/KG
CAS:8052-41-3
RTECS #:WJ8925000
Fraction by Wt: 1-7%
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Ingred Name:VOC 2.55 LBS/GAL (305 G/L)-3.86 LBS/GAL (462 G/L)
RTECS #:9999999VO
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN:POSS IRRIT & DEFAT DERM,
ESPECIALLY W/RPTD OR PRLNGD CONTACT. EYE:SEV IRRIT. INHAL:SOLV VAP
MAY CAUSE IRRIT TO UPPER RESP TRACT & LEAD TO CNS DEPRESS.
INGEST:WILL CAUSE IRRIT AND BURNING OF MOUTH . CHRONIC:SKIN:SOLV
MAY BE ABSORBED THRU INTACT SKIN AND EVENTUALLY CAUSE SYSTEMIC
POISONING &/OR (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:CNS DEPRESS. EYE:IRRIT & POSS CONJUNCT
UPON RPTD CNTCT. INHAL:SOLV VAP MAY CAUSE IRRIT TO NOSE, THROAT &
LUNGS & EVENTUALLY TO KIDNEY, LIVER & BLADDER EFTS. INGEST:WILL
CAUSE IRRIT & BURNING OF MOUTH, ABDOMINAL PAIN, CNS DEPRESS, &/OR
SYSTEMIC POISONING. NOTE:CNS DEPRESS IS CHARACTERIZED BY HDCH, DIZZ
(SUPDAT)
Medical Cond Aggravated by Exposure:SOME PRE-EXISTING MEDICAL
DISORDERS.
======================= First Aid Measures =======================
First Aid:EYES:WASH IMMED W/COPIOUS QTY OF INDUS EYE WASH/WATER FOR AT
LEAST 15 MIN & GET MED AID.SKIN:IMMED WASH AFFECTED AREAS W/INDUS
HAND CLEANER/SOAP & WATER. GET MED AID IF SYMPS PERSIST. REMOVE
CONTAM CL THG.INGEST:GIVE TWO GLASSES OF WATER TODRINK IF PATIENT
IS CONSCIOUS.DO NOT INDUCE VOM.GET MED AID IMMED. INHAL:MOVE
PATIENT TO FRESH AIR.RESTORE BRTHG IF NEC.KEEP PATIENT WARM & QUIET
& GET MED AID.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:102F,39C
Lower Limits:0.9%
Upper Limits:6.1%
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE,
UNIVERSAL-TYPE FOAM APPLIED BY MANUFACTURES' RECOMMENDED
TECHNIQUES.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
ISOLATE HAZ AREA. USE WATER SPRAY TO COOL FIRE-EXPOSED CNTNRS &
ALSO DISPERSE VAPS; RE-IGNITION IS POSSIBLE.
Unusual Fire/Explosion Hazard:VAPS ARE HEAVIER THAN AIR AND MAY TRAVEL
TO A SOURCE OF IGNIT AND SUBSEQUENTLY "FLASH BACK" TO THE SOURCE OF
PRODUCT DISCHARGE CAUSING FIRE OR EXPLOSION.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. STOP AND
CONTAIN DISCHARGE (IF WITHOUT RISK) BY CONSTRUCTING BARRIERS OR
APPLYING INERT SORBENT (EG. SAND, EARTH). PREVENT DISCHARGE FROM
ENTERING SEWERS OR WATER COURS ES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:GROUND AND BOND ALL EQUIPMENT AND
CONTAINERS TO PREVENT A POSSIBLE STATIC CHARGE BUILDUP. USE
SPARK-RESISTANT TOOLS.
Other Precautions:STORE IN A COOL, WELL-VENTILATED ENVIRONMENT. KEEP
AWAY FROM HEAT, SPARKS AND OTHER SOURCES OF IGNITION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL EXHAUST AND GENERAL VENTILATION AS REQUIRED, TO
MAINTAIN EMISSIONS AT A POINT OF USE BELOW THE TLV-TWA OR PEL.
Other Protective Equipment:FOOTWEAR, OTHER PROTECTIVE CLOTHING AS
REQUIRED.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
HLTH HAZ:NAUS, VOM, DROWS, ABDOM PAIN & INCOORD. SEV OVEREXPOS MAY LEAD
TO RESP FAIL, COMA, & POSS DEATH. OTHER CNS EFTS ARE ALSO POSS.
SENSIT:IN RARE CASE, PETROLEUM DISTILLATES (CAS 64742-47-8) & (C AS
8052-43-3) MAY SENSITIZE HEART MUSCLE CAUSING HEART ARRYTHMIA. EYE
PROT: & FACESHIELD .
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>280F,>138C
Vapor Density:4.5 (CAL)
Spec Gravity:0.93-1.30
Solubility in Water:NOT KNOWN
Appearance and Odor:LIQUID, VARIOUS COLOURS-MILD ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS AND BASES.
Stability Condition to Avoid:EXCESSIVE HEAT, IGNITION SOURCES (EG.
SPARKS, STATIC ELECTRIFICATION, FLAME, ETC.), STRONG BASES AND
OXIDIZERS.
Hazardous Decomposition Products:COMBUSTION...CARBON DIOXIDE & MONOXIDE
PLUS OTHER ORGANIC OR INORGANIC OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF WASTE OR PROPERLY CONTAINED, CONTAM
SOLIDS IN A APPROVED WASTE TREATMENT FACILITY WHERE PERMITTED UNDER
APPROP FEDERAL, PROVINCIAL, STATE AND LOCAL REGULATIONS. DO NOT
DISPOSE OF WASTES IN LOCAL SEWERS OR WITH NORMAL REFUSE.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SUPER METAL BASE,1111,1024/0866,75066
Kit Part:Y
Preparer's Name:W. FAUPEL
CAGE:67020
CAGE:0PX05
CAGE:67020
CAGE:NO786
============= Composition/Information on Ingredients =============
Ingred Name:BISPHENOL A-EPICHLOROHYDRIN COPOLYMER/DGEBA-EPOXY RESIN
CAS:25068-38-6
RTECS #:SL6475000
Fraction by Wt: 10 - 30%
Other REC Limits:NONE RECOMMENDED
Ingred Name:PHENOL,POLYMER WITH FORMALDEHYDE,GLYCIDYL ETHER/DGEBF-EPOXY
RESIN
CAS:28064-14-4
Fraction by Wt: 10 - 30%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SILICON DIOXIDE (AMORPHOUS)/MODIFIED SILICA
CAS:67762-90-7
Fraction by Wt: 1 - 5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:6 MG/M3
ACGIH TLV:10 MG/M3
Ingred Name:TALC (CONTAINING NO ASBESTOS)
CAS:14807-96-6
RTECS #:WW2710000
Fraction by Wt: 1 - 5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:20 MPPCF Z-3
ACGIH TLV:2 MG/M3 RDUST; 9596
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN.
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, RESPIRATORY &
GI TRACTS. ACUTE- EYES/SKIN:MAY CAUSE IRRITATION. MAY BE ABSORBED
THROUGH SKIN. INHALE:HIGH VAPOR/AEROSOL CONCENTRATIONS MAY CAUSE
RESPIRATORY IRRITATION. ORAL:M AY BE HARMFUL IF SWALLOWED. CHRONIC-
MAYCAUSE IRRITATION, SENSITIZATION & DERMATITIS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, SENSITIZATION, DERMATITIS
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS OR EYE PROBLEMS MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF
THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH
AIR. EYES:FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN.
SKIN:WASH WITH SOAP & WATER. ORAL:DO NOT INDUCE VOMITING. IF
CONSCIOUS, RINS E MOUTH WITH WATER & DRINK LARGE AMOUNTOF WATER.
SEEK MEDICAL ATTENTION. DO NOT GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:>230F,>110C
Extinguishing Media:WATER FOG, FOAM, DRY CHEMICAL/CARBON DIOXIDE. DON'T
USE DIRECT STREAM OF WATER.
Fire Fighting Procedures:DO NOT ENTER ANY ENCLOSED OR CONFINED AREA
WITHOUT PROPER PROTECTIVE EQUIPMENT AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:DECOMPOSITION PRODUCTS MAY BE HAZARDOUS.
================== Accidental Release Measures ==================
Spill Release Procedures:SCOOP UP EXCESS SPILLS. PICK-UP RESIDUE WITH
INERT ABSORBENT MATERIAL SUCH AS DIATOMACEOUS EARTH, SAND OR
VERMICULITE. SWEEP UP AND TRANSFER TO A CONTAINER FOR PROPER
DISPOSAL. CLEAN SPILL AREA WITH D ETERGENT AND WATER.
Neutralizing Agent:NOT RELEVANT
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY PLACE, AWAY FROM
INCOMPATIBLE MATERISLS. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:AVOID EYE AND SKIN CONTACT. DO NOT INGEST.
DECOMPOSITION AND COMBUSTION PRODUCTS MAY BE HAZARDOUS. EMPTY
CONTAINER RETAINS RESIDUE. FOLLOW LABEL INSTRUCTIONS. WHEN USING,
DO NOT EAT, DRINK OR SMOKE. W ASH HANDS THOROUGHLY AFTER HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS TO AN ACCEPTABLE LEVEL, A NIOSH-APPROVED DUST
RESPIRATOR MUST BE WORN.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
FUME OR DUST LEVELS AS LOW AS POSSIBLE.
Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASH FACILITIES
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING,
DRINKING/SMOKING.
Supplemental Safety and Health
KEY1:N1. KIT CONSISTS OF MODIFIED EPOXY RESIN (PNI A) AND MODIFIED
POLYAMINE (PNI B).
================== Physical/Chemical Properties ==================
HCC:V5
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:DECOMPOSES
Decomp Temp:Decomp Text:>392F,>200C
Spec Gravity:2.80
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:NEGLIGIBLE (<0.1%)
Appearance and Odor:DARK, GRAY PASTE WITH EPOXY ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG ALKALIS AND AMINES
Stability Condition to Avoid:EXCESSIVE HEAT (ABOVE 200C/392F)
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
SMOKE, GASES CONTAINING CARBON, HYDROGEN, OXYGEN
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS. CONTRACT WITH A LICENSED WASTE DISPOSAL
SERVICE.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:R-0001 DPD REAGENT 1
CAGE:EO526
CAGE:EO526
CAGE:89975
============= Composition/Information on Ingredients =============
Ingred Name:POTASSIUM PHOSPHATE (MONOBASIC) *94-4*
CAS:7778-77-0
Fraction by Wt: <10%
Ingred Name:SODIUM PHOSPHATE, DIBASIC, ANHYDROUS, DISODIUM PHOSPHATE
CAS:7558-79-4
RTECS #:WC4500000
Fraction by Wt: <10%
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:SODIUM HYDROXIDE, CAUSTIC SODA, LYE
CAS:1310-73-2
RTECS #:WB4900000
Fraction by Wt: <1%
Other REC Limits:2MG/M3 CEILING NIOSH
OSHA PEL:2 MG/CUM
ACGIH TLV:2 MG/CUM CEILING
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: <100%
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): 140-340 MG/KG (SEE SUP)
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES/SKIN: IRRITANT. INGESTION MAY
CAUSE GI IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, NAUSEA, DIARRHEA.
Medical Cond Aggravated by Exposure:EYE & SKIN CONDITIONS.
======================= First Aid Measures =======================
First Aid:EYES: IMMEDIATELY FLUSH W/WATER FOR 15 MINS. SKIN: WASH
THOROUGHLY W/SOAP & WATER. INGESTION: GIVE LARGE AMOUNTS OF WATER.
DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL, CO2, WATER SPRAY, FOAM.
Fire Fighting Procedures:WEAR SCBA (IN POSITIVE PRESSURE) & FULL
PROTECTIVE CLOTHING.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB W/VERMICULITE/OTHER INERT MATERIAL.
CONTAINERIZE FOR LATER DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY AREA. AVOID
DIRECT SUNLIGHT.
Other Precautions:AVOID CONTACT W/EYES, SKIN & CLOTHING. AVOID
BREATHING CHEMICAL.
============= Exposure Controls/Personal Protection =============
Other Protective Equipment:LAB COAT
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
ORAL LD50 INFORMATION IS FOR SODIUM HYDROXIDE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F
Vapor Pres:17
Vapor Density:0.64
Spec Gravity:1.24
pH:10
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR COLORLESS LIQUID W/NO ODOR
Percent Volatiles by Volume:68
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:EXTREME HEAT, TEMPS, DIRECT SUNLIGHT.
Hazardous Decomposition Products:MAY EMIT TOXIC FUMES OF PHOSPHORUS
OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATION/OTHER METHOD IAW/FEDERAL, STATE &
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:210/220/226 COPPER/COPPER ALLOYS
CAGE:40518
CAGE:40518
============= Composition/Information on Ingredients =============
Ingred Name:ZINC OXIDE
CAS:1314-13-2
RTECS #:ZH4810000
Fraction by Wt: 4-14%
OSHA PEL:15MG/M3 TDUST/5 FUME
ACGIH TLV:10MG/M3 TDUST; 9293
Ingred Name:COPPER (DUST & MIST), BRONZE POWDER
CAS:7440-50-8
RTECS #:GL5325000
Fraction by Wt: BALANCE
Other REC Limits:1 MG(CU)/M3 (DUST)
OSHA PEL:0.1 MG(CU)/M3 (FUME)
ACGIH TLV:0.2 MG/M3 (FUME)
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:RESPIRATORY TRACT IRRITATION, METAL
FUME FEVER, EYE IRRITATION. LEAD INTOXICATION INCLUDING KIDNEY
DISEASE, ANEMIA, NERVOUS DISORDERS, REPRODUCTIVE EFFECTS, BIRTH
DEFECTS & KIDNEY CANCER. COPPER FUMES CAUSES METAL FUME FEVER,
SKIN/HAIR DISCOLORATION, KERATINIZATION OF HANDS/FEET SOLES, &
RESPIRATORY TRACT IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:METAL FUME FEVER SYMPTOMS: SWEET OR METTALLIC
TASTE IN MOUTH, DRYNESS & THROAT IRRITATION, COUGH, SHORTNESS OF
BREATH, CHEST PAIN, NAUSEA, VOMITING, WEAKNESS, FATIGUE,
MUSCLE/JOINT PAIN, CHILLS & SWEA TING. COPPER: SKIN/HAIR
DISCOLORATION. ZINC: BRONCHITIS OR PNEUMONIA & BLUISH TINT TO SKIN.
SEE SUPP.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/WATER. SKIN: VACUUM OFF EXCESS DUST. WASH
W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. METAL FUME FEVER
MAY BE TREATED SYMPTOMATICALLY. INGESTION: OBTAIN MEDICAL ATTENTION
IF LARGE Q UANTITIES HAVE BEEN INGESTED. OBTAIN MEDICAL ATTENTION
IN ALL CASES.
===================== Fire Fighting Measures =====================
Fire Fighting Procedures:SOLID MASSIVE FORM ISN'T COMBUSTIBLE. WEAR
SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. WHEN IN
DUST FORM USE DRY CHEMICAL/SAND.
Unusual Fire/Explosion Hazard:FIRE & EXPLOSION HAZARDS ARE MODERATE
WHEN MATERIAL IS IN THE FORM OF DUST & EXPOSED TO HEAT, FLAMES,
CHEMICAL REACTION OR IN CONTACT W/POWDERFUL OXIDIZERS.
================== Accidental Release Measures ==================
Spill Release Procedures:LARGE QUANTITIES OF DUST: VACUUM/WET SWEEP.
LIQUIDS W/SOLID METAL: EVACUATE AREA. ABSORB W/VERMICULATE/DRY
SAND/SIMILAR MATERIAL.
======================Handling and Storage ======================
Handling and Storage Precautions:GOOD HOUSEKEEPING MUST BE PRACTICED
DURING STORAGE, TRANSFER & USE. AVOID EXCESSIVE DUST ACCUMULATION.
Other Precautions:ALWAYS EVALUATE THE JOBS DONE ON THIS PRODUCT IN
ACCORDANCE W/OSHA, FEDERAL, STATE OR LOCAL STANDARDS. APPLY
RECOMMENDATIONS OF NFPA 49 FOR COPPER ALLOYS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/OSHA APPROVED RESPIRATORY PROTECTION
IF EXPOSURE EXCEEDS THE PEL/TLV LIMITS.
Ventilation:LOCAL EXHAUST/MECHANICAL (GENERAL): REQUIRED IF DUST/FUME
CREATED IN HANDLING OR WORKING ON THIS MATERIAL
Other Protective Equipment:GRINDING OPERATIONS MAY REQUIRED FACE
SHIELDS. MELTING/WELDING REQUIRE FACE SHIELDS W/SPECIALTY TINTED
GLASS.
Work Hygienic Practices:USE GOOD PERSONAL HYGIENE. WASH HANDS BEFORE
EATING/DRINKING/SMOKING/LEAVING WORK AFTER CONTACT W/METAL DUST OR
FUME.
Supplemental Safety and Health
UNDER NORMAL CONDITIONS THE SOLID ALLOY PRESENTS NO SIGNIFICANT HEALTH
HAZARDS. PROCESSSING OF THE ALLOY BY DUST/FUME PRODUCING OPERATION
(GRINDING/BUFFING/HEATING/WELDING) MAY RESULT IN POTENTIAL FOR
EXPOSURE TO AIRBORNE METAL PARTICULATES/FUME. ZINC: LOW IN
TOXICITY. SYMPTOMS GO AWAY IN 24-48 HRS & LEAVE NO EFFECTS.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text: 1500-2260F
Spec Gravity:7.4-9
Solubility in Water:INSOLUBLE
Appearance and Odor:SILVER OR YELLOW TO RED SOLID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, BASES & OXIDERS. MAY REACT VIOLENTLY W/WATER. MERCURY,
AMMONIA & ACETYLENE.
Stability Condition to Avoid:HEAT, FLAMES
Hazardous Decomposition Products:METAL FUME
==================== Disposal Considerations ====================
Waste Disposal Methods:MAXIMIZE PRODUCT RECOVERY FOR REUSE OR
RECYCLING. CONDITIONS MAY CAUSE THIS MATERIAL TO BECOME A SOLID
HAZARDOUS WASTE. SOLID WASTE LEACHATE TESTING MAY INDICATE THE NEED
FOR PROPERLY PERMITTED DISPOS AL IN ACCORDANCE W/FEDERAL, STATE, &
LOCAL LAWS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:DOWANOL DM SOLVENT
CAGE:86511
CAGE:86511
============= Composition/Information on Ingredients =============
Ingred Name:2-METHOXYETHANOL (EGME) (SARA III)
CAS:109-86-4
RTECS #:KL5775000
Fraction by Wt: 95%
OSHA PEL:S, 25 PPM
ACGIH TLV:S, 5 PPM; 9192
===================== Hazards Identification =====================
Effects of Overexposure:EYE IRRIT, LIVER,LUNG & KIDNEY DAMAGE.
======================= First Aid Measures =======================
First Aid:INHAL:RMV TO FRESH AIR. IF NOT BRTHNG GIVE CPR; IF BRTHNG
DIFF GIVE OXYGEN. EYE:IMMED FLUSH W/PLENTY OF WATER. SKIN:WASH
W/SOAP&WATER. RMV CONTAM CLTHG&SHOES. INGEST:INDUCE VOMIT. RPT
UNTIL VOMIT IS C LEAR. NOTHG BY MOUTH IF UNCONSC. GET MEDICAL ATTN.
===================== Fire Fighting Measures =====================
Flash Point:200F,93.3C(COC)
Extinguishing Media:WATER FOG, ALCOHOL FOAM, CARBON DIOXIDE,DRY
CHEMICAL.
Fire Fighting Procedures:WEAR SCBA & PROT CLTHNG
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB W/INERT MATL AND SHOVEL INTO CLOSED
DISPOSAL DRUM.FLUSH RESIDUE W/LG AMT OF WATER. DIKE TO RETAIN LG
SPILL. PICK UP W/PUMP/VAC AND PLACE IN DISPOSAL DRUM.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY AREA AWAY FROM
IGNIT SOURCES. AVOID SKIN & EYE CONTACT. DO NOT INHAL MIST OR
VAPOR. WASH THOROUGHLY AFTER HANDLING.
Other Precautions:NONE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESP IF REQUIRED. NOT
NORMALLY NEEDED.
Ventilation:MECHANICAL RECOMMENDED.
Other Protective Equipment:APRON, WORK CLTHG, EYE BATH
Supplemental Safety and Health
MSDS DATED 15 FEB 73. MSDS IS FM DOW CHEMICAL
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:381F,194C
Vapor Pres:0.2
Vapor Density:4.14
Spec Gravity:1.018
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR,COLORLESS LIQUID,SWEEPTISH ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIAL
Stability Condition to Avoid:NONE SPECIFIED BY MFG
Hazardous Decomposition Products:NONE SPECIFIED BY MFG.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINRATE I/A/W ALL LOCAL, STATE, FEDERAL
REGULATIONS
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:TURCO 3003-TWA
CAGE:61102
CAGE:61102
============= Composition/Information on Ingredients =============
Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL)
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: <5%
OSHA PEL:50 PPM, S
ACGIH TLV:25 PPM, S
Ingred Name:GLYCOLS, POLYETHYLENE, MONO(NONYLPHENYL) ETHER;
(NONYLPHENOXYPOLY (ETHYLENEOXY) ETHANOL)
CAS:9016-45-9
RTECS #:MD0900000
Fraction by Wt: <5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:PHOSPHORIC ACID (SARA III)
CAS:7664-38-2
RTECS #:TB6300000
Fraction by Wt: <5%
OSHA PEL:1 MG/M3; 3 STEL
ACGIH TLV:1 MG/M3; 3 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:NITRIC ACID (SARA III)
CAS:7697-37-2
RTECS #:QU5775000
Fraction by Wt: <5%
OSHA PEL:2 PPM; 4 STEL
ACGIH TLV:2 PPM; 4 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:BORATE (1-), TETRAFLUORO-, HYDROGEN; (FLUOBORIC ACID 47%)
(MFR'S CAS # 1687-11-0)
CAS:16872-11-0
RTECS #:ED2685000
Fraction by Wt: <5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPDAT: TO INDUCE VOMITING OR GIVE ANYTHING BY MOUTH TO
UNCON PERSON.
RTECS #:9999999ZZ
Ingred Name:SPILL PROC: APPRVD DRUMS FOR DISP. ABSORB REMAINING LIQ
ONTO INERT ABSORB & PLACE IN DOT-APPRVD DRUMS FOR DISP. (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8: WASH AREA W/WATER. COLLECT WASHINGS & PLACE IN
DOT-APPRVD DRUMS. COLLECTED WASHINGS MAY BE TREATED AS (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9: DESCRIBED & RELEASED TO SEWER IF LOCAL REGS PERMIT.
USE SOLUTION: AS FOR CONCENTRATATE, IF APPLICABLE.
RTECS #:9999999ZZ
Ingred Name:WASTE DISP METH: WASTE. (3) SM AMTS MAY BE DISSOLVED IN
WATER & TREATED AS DESCRIBED BELOW. CLARIFIED WATER MAY (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11: BE RELSD TO SEWER IF LOC REGS PERMIT. SPENT SOLN &
RINSES: DISPOSE PER (1) OR (2) OR PHOSPHATE (& (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12: FLUORIDES IF PRESENT) MAY BE REMOVED BY LIME
TREATMENT; HEAVY METALS (IF PRESENT) PRECIPITATED BY PH (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13: ADJUSTMENT TO 9.5-10.5; PH OF SEPARATED WATER
SHOULD THEN BE READJUSTED TO PH OF 7-8. CLARIFIED WATER (ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14: MAY BE RELEASED TO SEWER IF LOCAL REGULATIONS
PERMIT.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC: OPENINGS TO AVOID SPURTING. CLEAN EXTERIOR &
INTERIOR BY FLUSHING W/WATER. COLLECT FLUSHINGS FOR (ING 17)
RTECS #:9999999ZZ
Ingred Name:ING 16: DISPOSAL. USE PROTECTIVE EQUIPMENT FOR EYES, SKIN &
INHALATION.
RTECS #:9999999ZZ
Ingred Name:EYE PROT: & FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ
Ingred Name:OTHER PROT EQUIP:(E.G. VITON, PVC, ETC.). PROT SUIT NOT
NORM REQD BUT ADVISED IF NEC TO AVOID POSS SKIN CNTCT/EXPOSURES.
RTECS #:9999999ZZ
Ingred Name:HYGIENE PRACT: REUSE. DISCARD SHOES THAT BECOME
CONTAMINATED ON THE INTERIOR.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: CONTACT MAY CAUSE SEVERE
IRRITATION, POSS CHEMICAL BURNS, POSS TISSUE DAMAGE/DESTRUCTION,
POSS BLINDNESS. SKIN: CONTACT MAY CAUSE SEVERE IRRITATION, POSS
CHEMICAL BURNS, POSS TISSUE DAMAGE. INHA L: VAPORS:MODERATE TO
SEVERE IRRITATION. MIST:SEVERE IRRITATION MAY CAUSE DAMAGE TO UPPER
RESPIRATORY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: TRACT. INGEST: SEVERE IRRITATION,
POSS DAMAGE TO GASTROINTESTINAL TRACT. CHRONIC: ANIMALS STUDIES
HAVE CLEARLY SHOWN DOSE-RELATED ADVERSE EFFECTS TO CNS,
HEMATOPOIETIC TISSUES, BLOOD, KIDNEY S & LIVER ASSOCIATED
W/ADMINISTRATION OF 2-BUTOXYETHANOL. (EXTRACTED FROM DHHS (NIOSH)
PUBLICATION NO. 90-118) .
Medical Cond Aggravated by Exposure:NO KNOWN CHRONIC EFFECTS THAT
DIFFER FROM ACUTE EFFECTS.
======================= First Aid Measures =======================
First Aid:EYES: SPEED IS ESSNTL. IMMED BEGIN FLUSHING EYES W/LG VOLS OF
WATER. CONTINUE FOR 5 MIN. FOLLOW W/NORM SALINE FOR 30-60 MIN. HOLD
LIDS APART TO ASSURE CNTCT W/ALL SURFS. OBTAIN IMMED MED ATTN.
(SEND S OMEONE FOR MED ASSISTANCE AS SOON AS FLUSHING IS STARTED.)
SKIN: SPEED IS ESSNTL. FLUSH AFFECTED AREA W/LG VOLS OF WATER. WASH
W/SOAP & WATER. RINSE THORO. IF IRRIT IS EVIDENT OR BLISTERING
(SUPDAT)
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
ANY WATER RUNOFF MAY CONTAIN SOLUBLE CMPDS OF HEAVY METALS & SHOULD
NOT BE ALLOWED TO ENTER SEWER/WATERWAYS.
Unusual Fire/Explosion Hazard:CONTACT WITH REACTIVE METALS SUCH AS
ALUMINUM, MAGNESIUM, ETC., MAY LEAD TO GENERATION OF HYDROGEN GAS
IN EXPLOSIVE AMOUNTS.
================== Accidental Release Measures ==================
Spill Release Procedures:CONCENTRATE: CONFINE SPILL. STOP LEAK AT
SOURCE IF IT CAN BE DONE SAFELY. VENT AREA. NONESNTL PERS SHOULD
LEAVE AREA UNTIL CLEANUP IS COMPLETED. PUMP LIQ INTO DOT-APPRVD
DRUMS FOR DISP. ABSORB REMAINI NG LIQ ONTO INERT ABSORB & PLACE IN
DOT- (ING 8)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN DRY PROTECTED AREA.
Other Precautions:MIXING:CAREFULLY ADD TO WATER WHILE MIX, TAKING CARE
TO AVOID SPLASHING. USE APPROP SFTY EQUIP TO ELIM POSS OF SKIN/EYE
CNTCT. MAKE ADDNS TO IN-USE TANKS SLOWLY & CAUTIOUSLY. REPAIR &
MAINT OF CONTAMD EQUIP: RELIEVE ANY PRESS. COVER (ING 16
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOR MIST CONDITIONS, A NIOSH/MSHA APPROVED
RESPIRATOR FOR DUST & MISTS IS ADVISED. IF RESPIRATORS ARE USED, A
FORMAL TRAINING & SCREENING PROGRAM MUST BE INITIATED. SEE 29 CFR
1910.134.
Ventilation:MAINTAIN SUFFICIENT MECHANICAL VENTILATION TO KEEP VAPOR
CONCENTRATION BELOW TLV.
Other Protective Equipment:EMER EYE WASH & DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . BOOTS & APRON MADE OF ACID RESISTANT MATL (ING
19)
Work Hygienic Practices:WASH HANDS & FACE W/SOAP & WATER BEFORE SMKNG/
EATING. IMMED REMOVE ALL CONTAMD CLTHG. LAUNDER SEPARATELY BEFORE
(ING 20
Supplemental Safety and Health
PH: 1.5 (CONC). FIRST AID PROC: OCCURS, OBTAIN MED ATTN. INHAL: REMOVE
TO FRESH AIR. ADMIN OXYGEN IF BRTHG IS DFCLT. OBTAIN MED ATTN IF
IRRIT PERSISTS. INGEST: DO NOT INDUCE VOMIT EXCEPT ON ADVICE OF
COMPETENT MED PERS. IF CONSCIOUS, DILUTE BY GIVING LG VOLS OF
MILK/WATER. OBTAIN IMMED MED ATTN. NEVER ATTEMPT (ING 7)
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:212F,100C
Vapor Pres:25
Vapor Density:<1
Spec Gravity:1.06
pH:SUPDAT
Evaporation Rate & Reference:<1 (BUAC=1)
Solubility in Water:COMPLETE
Appearance and Odor:TRANSLUCENT LIQUID; ACID ODOR.
Percent Volatiles by Volume:85
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CONTACT WITH STRONG ALKALIES, REACTIVE METALS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC OXIDES OF CARBON.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS.
CONCENTRATE: (1) TRANSFER TO RECLAIMING CTR FOR RECYCLING/REUSE, IF
POSS. (2) TRANSFER TO LICENSED HAZ WASTE TREATMENT/DISP SITE FOR
DISPOSITION UNDER A PPLIC LOC, STATE & REGIONAL REGS AS HAZ(ING 11)
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SUPELPREME-HC KIT BASE-NEUTRALS MIX 2, 4890
Kit Part:Y
CAGE:54968
CAGE:54968
============= Composition/Information on Ingredients =============
Ingred Name:BENZENE, P-DICHLORO-; (1,4-DICHLOROBENZENE).
LD50:(ORAL,RAT)500 MG/KG
CAS:106-46-7
RTECS #:CZ4550000
Fraction by Wt: 0.2%
OSHA PEL:75 PPM
ACGIH TLV:10 PPM,A3 9394
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:TOLUENE,2,4-DINITRO-; (2,4-DINITROTOLUENE).
LD5O:ORAL(RAT)268 MG/KG
CAS:121-14-2
RTECS #:XT1575000
Fraction by Wt: 0.2%
OSHA PEL:1.5 MG/M3, S
ACGIH TLV:1.5 MG/M3, S
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:TOLUENE, 2,6-DINITRO-; (2,6-DINITROTOLUENE). LD50:(ORAL)RAT
177 MG/KG.
CAS:606-20-2
RTECS #:XT1925000
Fraction by Wt: 0.2%
OSHA PEL:1.5 MG/M3, S
ACGIH TLV:1.5 MG/M3, S
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:1,3-BUTADIENE, HEXACHLORO-;(HEXACHLORO-1, 3-BUTADIENE).
LD50:ORAL(RAT)90 MG/KG
CAS:87-68-3
RTECS #:EJ0700000
Fraction by Wt: 0.2%
OSHA PEL:0.02 PPM
ACGIH TLV:0.02 PPM,S
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:1,3-CYCLOPENTADIENE,1,2,3,4,5, 5-HEXACHLORO-;
(HEXACHLOROCYCLOPENTADIENE). LD50:ORAL(RAT)113 MG/KG
CAS:77-47-4
RTECS #:GY1225000
Fraction by Wt: 0.2%
OSHA PEL:0.01 PPM
ACGIH TLV:0.01 PPM
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:2-CYCLOHEXEN-1-ONE,3,5,5-TRIMETHYL-;(ISOPHORONE).
LD50:(ORAL,RAT)2330 MG/KG
CAS:78-59-1
RTECS #:GW7700000
Fraction by Wt: 0.2%
Other REC Limits:10 PPM (MFR)
OSHA PEL:25 PPM
ACGIH TLV:C 5 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:BENZENE, NITRO-;(NITROBENZENE). LD50:ORAL(RAT)640 MG/KG
CAS:98-95-3
RTECS #:DA6475000
Fraction by Wt: 0.2%
Other REC Limits:5 PPM (MFR)
OSHA PEL:1 PPM, S
ACGIH TLV:1 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:METHANE, DICHLORO-;(METHYLENE CHLORIDE). LD50:ORAL(RAT)2524
MG/KG
CAS:75-09-2
RTECS #:PA8050000
Fraction by Wt: 97%
Other REC Limits:100 PPM (MFR)
OSHA PEL:500 PPM, 1000 C
ACGIH TLV:50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:BENZENE,M-DICHLORO-; (1,3-DICHLOROBENZENE)
CAS:541-73-1
RTECS #:CZ4499000
Fraction by Wt: 0.2%
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:AZOBENZENE (99%); (DIAZENE, DIPHENYL-). LD50:ORAL(RAT)1000
MG/KG
CAS:103-33-3
RTECS #:CN1400000
Fraction by Wt: 0.2%
Ingred Name:BENZENE, 1,2,4-TRICHLORO-;(1,2,4-TRICHLOROBENZENE)
CAS:120-82-1
RTECS #:DC2100000
Fraction by Wt: 0.2%
OSHA PEL:5 PPM, C
ACGIH TLV:5 PPM, C
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:BENZENE, HEXACHLORO-;(HEXACHLOROBENZENE). LD50:ORAL(RAT)
10000 MG/KG
CAS:118-74-1
RTECS #:DA2975000
Fraction by Wt: 0.2%
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:ETHANE, HEXACHLORO-;(HEXACHLOROETHANE). LD50:ORAL(RAT) 6000
MG/KG
CAS:67-72-1
RTECS #:KI4025000
Fraction by Wt: 0.2%
Other REC Limits:10 PPM (MFR)
OSHA PEL:S, 1 PPM
ACGIH TLV:S, 1 PPM; A2, 9394
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:NAPHTHALENE, 2-CHLORO-; (2-CHLORONAPHTHALENE).
LD50:ORAL(RAT)2078 MG/KG
CAS:91-58-7
RTECS #:QJ2275000
Fraction by Wt: 0.2%
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:O-DICHLOROBENZENE (SARA III)
CAS:95-50-1
RTECS #:CZ4500000
Fraction by Wt: 0.2%
OSHA PEL:C 50 PPM
ACGIH TLV:S, 25PPM/50 STEL9394
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CAUSES CANCER. IRRITATES
EYE/SKIN/NAUS/DIZZ. SEVERAL CHRONIC INHAL STUDIES RPTD BY NIOSH
REVEALED THAT TEST ANIMALS EXPOS TO METHYLENE CHLORIDE CONC AS HIGH
AS 10,000PPM SHOWED SLIGHT LIVER/ KIDNEY CH ANGES. METHYLENE
CHLORIDE HAS BEEN SHOWN TO INCR RATE OF SPONT OCCURING MALIGNANT
TUMORS IN 1 STRAIN OF (EFTS OF OVEREXP
Explanation of Carcinogenicity:HEXACHLOROBENZENE:IARC GRP 2B, NTP GROUP
2. P-DICHLOROBENZENE:IARC GRP 2B, NTP GRP 2. HEXACHLOROBUTADIENE:
(SUPP DATA)
Effects of Overexposure:HLTH HAZ:MICE & BENIGN TUMORS IN RATS.
CHLOROCARBON MATLS HAVE PRDCD SENSIT OF MYOCARDIUM TO EPINEPHRINE
IN LAB ANIMALS & COULD HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS
(E.G., EPINEPHRINE) MAY BE CO NTRAINDICATED EXCEPT FOR
LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY EXPOS TO (SUPP
DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN: PROMPTLY WASH W/MILD SOAP & LARGE VOL OF H2O, CONT
PHYS. INHAL: IMMED MOVE TO FRESH AIR. GIVE O2 IF BRTHG IS LABORED.
IF BRTHG STOPS, GIVE ARTF RESP. CONTACT PHYS. INGEST: NEVER GIVE
ANYTHING BY MOUTH TO AN UNCON PERSON. NEVER TRY TOMAKE AN UNCON
PERSON VOMIT. GIVE SYRUP OF IPECAC. IMMED CONTACT PHYS. EYES:
CONTACT PHYS.
===================== Fire Fighting Measures =====================
Lower Limits:12.0%
Upper Limits:9.0%
Extinguishing Media:THIS MATERIAL IS NOT FLAMMABLE. DETERMINED BY
SUPPORTING FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT WHEN FIGHT A CHEMICAL FIRE.
Unusual Fire/Explosion Hazard:THE FOLLOWING TOXIC VAPORS ARE FORMED
WHEN THIS MATERIAL IS HEATED TO DECOMPOSITION: HCL, OXIDES OF
NITROGEN. PHOSGENE .
================== Accidental Release Measures ==================
Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. FLUSH WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER. KEEP
AWAY FROM OXIDIZERS. KEEP AWAY FROM BASES.
Other Precautions:AVOID EYE OR SKIN CONTACT. AVOID BREATHING VAPORS. NO
SMOKING IN AREA OF USE. DO NOT USE IN GEN VICINITY OF ARC WELD,
OPEN FLAMES OR HOT SURF. HEAT &/OR UV RADIATION MAY CAUSE FORMATION
OF HCL &/OR PH OSGENE .
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATORY PROTECTION.
Ventilation:USE ONLY IN EXHAUST HOOD.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN:ACGIH GROUP A2. METHYLENE CHLORIDE:IARC GROUP 2B, NTP
GROUP 2, ACGIH GROUP A2. EFTS OF OVEREXP: CHLOROCARBONS .
================== Physical/Chemical Properties ==================
HCC:T4
Boiling Pt:B.P. Text:104F,40C
Vapor Pres:350
Solubility in Water:1.3
Appearance and Odor:CLEAR LIQUID, CHLOROFORM-LIKE ODOR.
Percent Volatiles by Volume:97
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG BASES, OXIDIZING AGENTS, CHEMICAL ACTIVE METALS SUCH AS ALUMINUM
OR MAGNESIUM POWDERS.
Hazardous Decomposition Products:HCL, OXIDES OF NITROGEN. PHOSGENE .
==================== Disposal Considerations ====================
Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE, OR
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:140 3377,COLOR DEVLPR REPL,PROCESS E-4,PT B
CAGE:19139
CAGE:19139
============= Composition/Information on Ingredients =============
Ingred Name:T-BUTYLAMINE BORANE; CAS# 7337-45-3
RTECS #:EO3900000
Fraction by Wt: 100%
===================== Hazards Identification =====================
Effects of Overexposure:INHALE:CNS
STIMULATION,CONVULSIONS;EYE:IRRITNT;SKIN:IRRITNT,SOLN MAY BE
ABSORBED (TOXIC);INGEST:NO.
======================= First Aid Measures =======================
First Aid:INHALE:REMOVE TO FRESH AIR,GIVE CPR/O*2 IF NEED;EYES:FLUSH W
LG AMT H*2O FOR 15 MIN;SKIN:FLUSH W/LG AMTS H*2O;INGEST:RINSE
MOUTH;GET IMMEDIATE MEDICAL ATTENTION FOR OVEREXPOSURE OR
INGESTION.
===================== Fire Fighting Measures =====================
Extinguishing Media:FLAMMABLE SOLID:USE WATER SPRAY,CO*2, OR DRY
CHEMICAL
Fire Fighting Procedures:SELF-CNTND BRTHG APP./STAY UPWIND,AVOID DENSE
WHITE SMOKE
Unusual Fire/Explosion Hazard:BURNS W GREEN FLAME;DIBORANE GAS
LIBERATED BY ANHYDROUS ACIDS;AVOID OXIDANTS OR CONC ACIDS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE UNPROTECTED PERSONS.PROVIDE
VENTILLATION/ELIM DUST.SWEEP/SHOVEL MATERIAL INTO COVERED
CONTAINERS PENDING DISPOSAL.NOTE:FLAMMABLE SOLID-AVOID IGNITION
SOURCES.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED,LOW
FIRE RISK AREA.PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL
CONTACT.KEEP CONTAINERS TIGHTLY CLOSED.
Other Precautions:AVOID PROLONGED OR REPEATED CONTACT W CHEMICAL.REMOVE
& WASH CONTAMINATED CLOTHING.MAINTAIN STRICT HYGIENE.KEEP AWAY FROM
UNTRAINED PERSONNEL;AVOID HEAT,SPRARKS,OR OPEN FLAME.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOR EXCESSIVE DISPERSAL,IN AIR,WEAR DUST
RESPIRATOR.
Ventilation:MECHANICAL(GEN.)/LOCAL EXHAUST,AS NECESSARY;AVOID DUSTING
CO
Other Protective Equipment:NO SPECIAL REQUIREMENTS.
Supplemental Safety and Health
MSDS FROM MFG DATED 7/8/76. PART B OF FOUR PART PRODUCT, SAME NSN
STORAGE CODE BASED UPON MFG DESCRIPTION OF PRODUCT AS FLAMMABLE
SOLID. KEY1:F7.
================== Physical/Chemical Properties ==================
HCC:F8
Boiling Pt:B.P. Text:DECOMPOSES
Vapor Pres:0
Spec Gravity:0.87
Solubility in Water:APPRECIABLE
Appearance and Odor:WHITE CRYSTALLINE SOLID; AMINE ODOR.
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CONCENTRATED ACIDS CAUSE VIOLENT REACTION.
Stability Condition to Avoid:DUST GENERATING CONDITIONS;TEMP ABOVE
160F.
Hazardous Decomposition Products:FLAMMABLE-TOXIC DIBORANE OFF-GAS FROM
RX W ANHYDROUS ACIDS
==================== Disposal Considerations ====================
Waste Disposal Methods:KEEP IN COVERED CONTAINERS PENDING
DISPOSAL.HANDLE & DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE
INTERNATIONAL,FEDERAL,STATE,& LOCAL REGULATIONS.MFG SUGGESTS
NEUTRALIZE W SODIUM HYPOCHLORITE & FLUS H TO ACID FREE SEWER W
EXCESS WATER.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:F-10, CORROSION REMOVING COMPOUND
CAGE:55872
CAGE:55872
============= Composition/Information on Ingredients =============
Ingred Name:PHOSPHORIC ACID (SARA III)
CAS:7664-38-2
RTECS #:TB6300000
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG/M3/3 STEL
ACGIH TLV:1 MG/M3/3 STEL; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:>0.85 MG/L (RAT)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN: MAY INDUCE IRRITATION.
INGESTION: TOXIC. INHALATION: MAY CAUSE NASAL IRRITATION. EYES: MAY
CAUSE IRRITATION.
Explanation of Carcinogenicity:PRODUCT CONTAINS NO MATERIALS CURRENTLY
CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA.
Effects of Overexposure:SKIN: IRRITATION. INGESTION: TOXIC. INHALATION:
NASAL IRRITATION. EYES: IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHALATION: IN A CLOSED AREA OR PROLONGED USE, EMPLOY A
RESPIRATOR (OSHA). INGESTION: DRINK LARGE AMOUNTS OF WATER AND SEE
PHYSICIAN. SKIN: WASH WITH COLD WATER. EYES: WASH WITH COPIOUS
AMOUNTS OF WAT ER. IF IRRITATION PERSISTS, SEE A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:135F MIN (SPEC)
Extinguishing Media:NOT SPECIFIED BY MANUFACTURER
Fire Fighting Procedures:NOT SPECIFIED BY MANUFACTURER
Unusual Fire/Explosion Hazard:NOT SPECIFIED BY MANUFACTURER
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH WITH WATER OR DIKE WITH SAND, SAWDUST OR
VERMICULITE AND STORE IN NON-METAL CONTAINER FOR DISPOSAL.
Neutralizing Agent:NEUTRALIZING CHEMICALS INCLUDE LIME, SODA ASH
(SODIUM CARBONATE).
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN NON-METAL CONTAINERS IN COOL
DRY AREA WITH SOME VENTILATION.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN CLOSED AREA OR FOR PROLONGED USE, EMPLOY
NIOSH/OSHA RESPIRATOR.
Ventilation:LOCAL EXHAUST AND MECHANICAL (GENERAL) EXHAUST RECOMMENDED.
Other Protective Equipment:AVOID CONTACT WITH BODY OR CLOTHING BY USING
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING
PRODUCT. DO NOT EAT, DRINK OR SMOKE IN WORK AREA.
Supplemental Safety and Health
LD50 RABBIT=2740 MG/KG; FOR 75-80% TECHNICAL MATERIAL, TELO
HUMAN=100MG/M3. FOR GRADES ABOVE 75-80%, LC50=MORE THAN 0.85 MG/L.
================== Physical/Chemical Properties ==================
HCC:F6
Boiling Pt:B.P. Text:207F,97C
Vapor Pres:NONVOLATIL
Vapor Density:NONVOLATIL
Spec Gravity:1.17
Evaporation Rate & Reference:NONVOLATILE
Solubility in Water:100 %
Appearance and Odor:CLEAR WITH MILD ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID STRONG CAUSTICS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:UPON DECOMPOSITION PHOSPHORIC ACID
FUMES MAY BE RELEASED.
==================== Disposal Considerations ====================
Waste Disposal Methods:DEPOSIT ON SUITABLE LANDFILL. DISPOSE IN
ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:PAINTSTIK "H", BLUE
CAGE:94858
CAGE:94858
============= Composition/Information on Ingredients =============
Ingred Name:PHTHALIC ANHYDRIDE
CAS:85-44-9
RTECS #:TI3150000
Fraction by Wt: 15%
OSHA PEL:2 PPM
ACGIH TLV:1 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PHTHALIC ANHYDRIDE IS KNOWN TO BE A
PRIMARY IRRITANT TO THE MUCOUS MEMBRANES OF THE NOSE, UPPER
RESPIRATORY TRACT, EYES AND SKIN. IRRITANT EFFECTS ARE MORE SEVERE
ON MOIST SURFACES DUE TO FORMATION OF PHTHALIC ACID. PHTHALIC
ANHYDRIDE IN THE FORM OF VAPOR, FUME OR DUST IRRITATES THE EYES;IT
IS BOTH AN (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:IRRITANT AND SENSITIZER OF THE SKIN
AND RESPIRATORY TRACT.
Medical Cond Aggravated by Exposure:MAY PRODUCE OR AGGRAVATE ASTHMA,
BRONCHITIS OR EMPHYSEMA.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH W/WATER FOR AT LEAST 15 MINUTES, CALL MD.
SKIN:FLUSH W/PLENTY OF WATER. INHAL:IF LARGE AMOUNTS BREATHED IN,
REMOVE TO FRESH AIR. INGEST:GET MD IMMEDIATELY .
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:304F,151C
Lower Limits:1.7%
Upper Limits:10.4%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM OR WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . MOLTEN MATERIAL HYDROLYZES IN CONTACT WITH
WATER WHICH GENERATES STEAM.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP AND PLACE IN CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION.
Other Precautions:NONE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF CONCENTRATION EXCEEDS TLV, USE NIOSH/MSHA
APPROVED RESPIRATOR FOR ACID VAPORS.
Ventilation:LOCAL EXHAUST IF NECESSARY. MECHANICAL (GENERAL) ACCEPTABLE
FOR SMALL VOLUME.
Other Protective Equipment:NONE
Work Hygienic Practices:WASH AFTER USING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:N1
Solubility in Water:INSOLUBLE
Appearance and Odor:CYLINDRICAL STIK 3/8 INCH DIAMETER X 4-1/2 LONG.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, STRONG ALKALI.
Hazardous Decomposition Products:PHTHALIC ACID FUMES AND CO MAY BE
RELEASED IN A FIRE.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE OR DISPOSE OF IN AN APPROVED LANDFILL
WHICH COMPLIES WITH LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ENZYME #1
CAGE:ULANO
CAGE:53176
CAGE:ULANO
============= Composition/Information on Ingredients =============
Ingred Name:PROTEASE ENZYME
Fraction by Wt: 100%
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:N/K
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SEE SIGNS AND SYMPTOMS OF
OVEREXPOSURE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:DUST MAY CAUSE IRRITATION.SKIN:PROLONGED
OR REPEATED CONTACT MAY CAUSE IRRITATION.INGESTION:N/K
.INHALATION:MAY CAUSE IRRITATION OF UPPER RESPIRATORY TRACT.
Medical Cond Aggravated by Exposure:N/K
======================= First Aid Measures =======================
First Aid:EYES:FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15
MINUTES AND CONSULT PHYSICIAN IF IRRITATION IS PRESENT.SKIN:WASH
WITH SOAP AND WATER.INGESTION:CALL MD IMMEDIATELY .INHALATION:MOVE
SUBJE CT TO FRESH AIR.
===================== Fire Fighting Measures =====================
Extinguishing Media:CO*2,DRY CHEMICAL,WATER FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .USE WATER SPRAY TO COOL FIRE-EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:DUSTS MAY PRESENT AN EXPLOSION HAZARD IF
CONTACTED WITH SPARKS OR OTHER IGNITION SOURCES.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP AND PLACE INTO CONTAINERS FOR
DISCARD.
Neutralizing Agent:N/K
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL,DRY PLACE BELOW
70F,21.11C.FREEZING TEMPERATURES WILL NOT AFFECT ACTIVITY.AVOID
COPPER AND ALUMINUM STORAGE VESSELS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL & GENERAL VENTIL NEC TO KEEP AIR CONCENTRATION BELOW
LEVEL OF CONCERN .PROVIDE DUST FREE WORKROOM AIR.
Other Protective Equipment:WEAR APRON OF IMPERVIOUS MATERIAL.
Work Hygienic Practices:N/K
Supplemental Safety and Health
ROUTES OF ENTRY:INHAL .
================== Physical/Chemical Properties ==================
HCC:N1
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
pH:6.7
Solubility in Water:SOLUBLE
Appearance and Odor:WHITE POWDER,MILD INOFFENSIVE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID IGNITION SOURCES AND HIGH HEAT.
Hazardous Decomposition Products:N/K
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .LANDFILL ACCORDING TO
REGULATIONS.DO NOT REUSE CONTAINER.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:DURO AW 68 (FORMALLY DURO AW S-315)
CAGE:3T432
CAGE:3T432
CAGE:9V333
============= Composition/Information on Ingredients =============
Ingred Name:SOLVENT REFINED MINERAL OIL.
Fraction by Wt: 99%
ACGIH TLV:5 MG/CUM
Ingred Name:ADDITIVE (PROPRIETARY COMPOSITION)
Fraction by Wt: 1%
===================== Hazards Identification =====================
Effects of Overexposure:EYE: IRRITATION.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH WITH WATER 15 MINUTES. SKIN: WASH WITH SOAP AND
WATER. INHALATION: REMOVE FROM EXPOSURE. INGESTION: GIVE QUANTITIES
OF WATER,INDUCE VOMITING,GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:440F/226C (D92)
Extinguishing Media:DRY CHEM,CO*2;FOAM & WATER ARE EFFECTIVE BUT MAY
CAUSE FROTH
Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS
Unusual Fire/Explosion Hazard:MIST OR SPRAY MAY BE FLAMMABLE AT TEMPS
BELOW THE NORMAL FLASH POINT.
================== Accidental Release Measures ==================
Spill Release Procedures:SECURE SOURCES OF IGNITION,USE ABSORBENT
MATERIAL SUCH AS CLAY OR DIATOMACEOUS EARTH TO CLEAN UP SPILL.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM OPEN FLAMES
Other Precautions:OIL SOAKED CLOTHING SHOULD BE REMOVED AND LAUNDERED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESP DEVICE IN ACCORD WITH
EXPOSURE OF CONCERN.
Ventilation:GENERAL
Supplemental Safety and Health
VISCOSITY: 315 SUS 100F/37C.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>600F/315C
Vapor Pres:0.1
Vapor Density:>10
Spec Gravity:0.88
Evaporation Rate & Reference:>1 (ETHER)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:AMBER LIQUID - LUBE OIL ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS,ALKALIES & OXIDIZERS.
Hazardous Decomposition Products:CARBON MONOXIDE & TRACE OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:COMPLY WITH LOCAL,STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:MIL-C-22750E GRAY 16081 ACTIVATOR PART B
Kit Part:Y
Preparer's Name:DAVID SCHMETTERER
CAGE:DO165
CAGE:DO165
CAGE:5V430
============= Composition/Information on Ingredients =============
Ingred Name:TOLUENE (VAPOR PRESSURE 38 MM HG) THIS ITEM CONTAINS A
TRACE OF BENZENE. (SARA 313).
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 15%
Other REC Limits:NONE SPECIFIED
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:METHYL ETHYL KETONE (VAPOR PRESSURE 71.2 MM HG) (SARA 313).
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 25%
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM
ACGIH TLV:200 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:NONYLPHENOL (VAPOR PRESSURE 0.9 MM HG) CONTAINS A TRACE OF
PHENOL, CAS #108-95-2.
CAS:25154-52-3
RTECS #:SM5600000
Fraction by Wt: 10%
Other REC Limits:NONE SPECIFIED
Ingred Name:META XYLENE DIAMINE
CAS:1477-55-0
RTECS #:PF8970000
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
ACGIH TLV:0.1 MG/M3
Ingred Name:AMINE ADDUCT
CAS:68738-77-2
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
Ingred Name:CRYSTALLINE SILICA
CAS:14464-46-1
RTECS #:VV7325000
Fraction by Wt: <0.1%
Other REC Limits:NONE SPECIFIED
OSHA PEL:SEE TABLE Z3
ACGIH TLV:0.05 MG/M3 RDUST9293
Ingred Name:TITANIUM OXIDE CONTAINS 0-10% AMORPHOUS SILICA. CAS
#112926-00-8. CONTAINS 0-9% ALUMINUM HYDROXIDE CAS #21645-51-2.
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 10%
Other REC Limits:NONE SPECIFIED
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:SILICON DIOXIDE. THIS INGREDIENT MAY BE RELEASED BY
SANDING THE DRIED PAINT FILM. IN THIS CASE THE FOLLOWING DUST *
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: 30%
Other REC Limits:NONE SPECIFIED
OSHA PEL:SEE TABLE Z3
ACGIH TLV:0.1 MG/M3 RDUST;9293
Ingred Name:*WARNING APPLIES: PROLONGED OVER-EXPOSURE DUE TO INHALATION
MAY CAUSE DELAYED LUNG INJURY/DISEASE (SILICOSIS). ON THE**
RTECS #:9999999ZZ
Other REC Limits:NONE SPECIFIED
Ingred Name:**BASIS OF INITIAL EXPERIMENTAL TEST IN ANIMALS AND LIMITED
EPIDEMILOGICAL STUDIES IN HUMAN POPULATIONS, THE IARC HAS***
RTECS #:9999999ZZ
Other REC Limits:NONE SPECIFIED
Ingred Name:***CONCLUDED THAT THERE IS LIMITED EVIDANCE FOR THE
CARCINOGENICITY OF CRYSTALINE SILICA TO HUMANS.
RTECS #:9999999ZZ
Other REC Limits:NONE SPECIFIED
Ingred Name:VOC: 464 GPL.
RTECS #:9999999VO
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:ACUTE TOXICITY:
HEADACHE/DIZZINESS/NAUSEA/UNCONSCIOUSNESS. SEVERE EYE IRRITATION,
POSSIBLE PERMANENT DAMAGE. IRRIATED MUCOUS MEMBRANES. VOMITING DUE
TO INGESTION. DEFATTING AND DRYING OF THE SKIN. SEN SITIZATION
AFTER REPEATED CONTACT.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/CLEAN/LUKEWARM/LOW PRESSURE WATER 15 MIN, LIFT
LIDS. MED ATTEN. INHALE: MOVE TO FRESH AIR/PROVIDE OXYGEN IF BREATH
DIFF. ARTIF RSPRTN-NOT BREATHING. MED ATTEN. KEEP WARM/COMFORTABLE.
NEV ER GIVE AN UNCONSCIOUS PERSON LIQUIDS. INGEST: IMMED MED ATTEN.
ONLY INDUCE VOMITING ON INSTRUCT-DR. IF VOMIT OCCURS KEEP HEAD
BELOW HIPS-PREVENT ASPIRATION OF LIQUID INTO LUNGS. SKIN: FLUSH
W/WATER*
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:22.0F,-5.6C
Lower Limits:1.2
Extinguishing Media:FOAM, CARBON DIOXIDE, OR DRY CHEMICAL.
Fire Fighting Procedures:WATER USED TO KEEP EXPOSED CONTAINERS COOL/TO
KEEP FLAMMABLE STRUCTURES WET. DO NOT ENTER FIRE AREA W/O PROPER
PROTECTION-HAZARDOUS DECOMP PRODS PRESENT.
Unusual Fire/Explosion Hazard:WATER PRESSURE MAY SPREAD A FLAMMABLE
LIQUID FIRE. SEALED CONTAINERS MAY EXPLODE IF OVERHEATED.
================== Accidental Release Measures ==================
Spill Release Procedures:WARNING-FLAMMABLE! ELIMINATE ALL IGNITION
SOURCES. HANDLING EQUIPMENT MUST BE GROUNDED TO PREVENT SPARKING.
SOAK UP WITH AN ABSORBENT AND PLACE IN NON-LEAKING CONTAINERS. SEAL
TIGHTLY FOR PROPER DISPO SAL.
======================Handling and Storage ======================
Handling and Storage Precautions:TREAT AS HAZARD-FLAM MATERIAL.
APPLICABLE DOT REGS WHEN TRANSPORT MAT'L. HOT ORGANIC CHEMICAL
VAPORS/MISTS SUSCEPTIBLE TO SPONTANEOUS COMBUSTION **
Other Precautions:**WHEN MIXED W/AIR. IGNITION AT TEMPERATURES BELOW
THOSE PUBLISHED IN LITURATURE AS "AUTOIGNITION"/"IGNITION"
TEMPERATURES. IGNITION TEMPERATURES DECREASE W/INCREASING VAPOR
VOLUME/VAPOR/AIR CONTACT, ARE INFLUENCED BY PRESSURE CHANGES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IMPORTANT-MUST PROVIDE ADEQUATE VENTILATION TO
MAINTAIN VAPOR CONCENTRATIONS BELOW THE ESTABLISHED TLV LIMIT AS
GIVEN BY OSHA. IN MORE CONFINED AREAS A NIOSH-MSHA APPROVED
RESPIRATOR EQUIPPED WITH ORG ANIC VAPOR CARTRIDGE SHOULD BE WORN.
Ventilation:MUST PROVIDE ADEQUATE VENTILATION.
Other Protective Equipment:HAVE EYE BATH AND SAFETY SHOWER AVAILABLE.
Work Hygienic Practices:DO NOT REUSE CONTAMINATED CLOTHING OR SHOES.
Supplemental Safety and Health
*WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH W/SOAP/WATER. IF
IRRITATION PERSISTS GET MED ATTEN.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:174FTO567F
Vapor Density:>AIR
Spec Gravity:1.25
Viscosity:>200CST
Evaporation Rate & Reference:3.64 (X N-BUTYL ACETATE)
Solubility in Water:SLIGHT
Appearance and Odor:GRAY LIQUID, SOLVENT ODOR.
Percent Volatiles by Volume:56.4
Corrosion Rate:NOT CORR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MAY BE INCOMPATIBLE WITH OXIDIZING AGENTS AND STRONG ALKALIES.
Stability Condition to Avoid:AVOID HEAT/SPARKS/OPEN FLAME/OXIDIZING
AGENTS/STRONG ALKALIES.
Hazardous Decomposition Products:INCOMPLETE COMBUSTION FOR PRODUCTS
LIKE THIS MAY GENERATE HIGHLY POISONOUS CARBON MONOXIDE AND OTHER
TOXIC GASES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH CURRENT
LOCAL, STATE AND FEDERAL REGULATIONS. CONTACT AN APPROVED DISPOSAL
FACILITY.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:9E SYNTHETIC REDUCER
Preparer's Name:E. SOETARIK
CAGE:9D157
CAGE:9D157
============= Composition/Information on Ingredients =============
Ingred Name:SOLVENT NAPHTHA PETROLEUM, LIGHT ALIPHATIC; (SOLVENT
NAPHTHA (PETROLEUM))
CAS:64742-89-8
OSHA PEL:300 PPM;400 PPM STEL
ACGIH TLV:300 PPM
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE)
CAS:78-93-3
RTECS #:EL6475000
OSHA PEL:200 PPM;300 PPM STEL
ACGIH TLV:200 PPM;300 PPM STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:2-HEPTANONE; (METHYL AMYL KETONE)
CAS:110-43-0
RTECS #:MJ5075000
OSHA PEL:100 PPM
ACGIH TLV:50 PPM
Ingred Name:BUTYL ALCOHOL; (NORMAL BUTYL ALCOHOL)
CAS:71-36-3
RTECS #:EO1400000
OSHA PEL:100 PPM
ACGIH TLV:S, C 50 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ISOBUTYL ALCOHOL (SARA III)
CAS:78-83-1
RTECS #:NP9625000
OSHA PEL:100 PPM
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:VAPS MAY BE IRRIT TO NOSE/
THROAT/RESP TRACT. HIGH VAP CONC MAY CAUSE CNS DEPRESSION.
SKIN/EYES: BURNING SENS FROM VAP/LIQ. DERM, SENSIT. LIQ IS MILDLY
IRRIT TO SKIN. PRLNGD/RPTD CNTCT CAN RSLT IN DEFATTING & DRYING
WHICH MAY RSLT IN SKIN IRRIT & DERM. INGEST: TOX IF SWALLOWED. CAN
CAUSE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:BURNING SENS, VOMIT, DIARR, DROWS,
NAUS, DIZZ, HDCH/CONFUSION. INTENTIONAL ABUSE, MISUSE/MASSIVE EXPOS
MAY CAUSE MULTIPLE ORGAN DMG &/OR DEATH.CHRONIC:REPORTS HAVE ASSOC
RPTD/PRLNGD OCCUP OVE REXP TO SOLV W/PERM BRAIN & NERV SYS DMG.
INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS MAY BE HARMFUL OR
FATAL.
Medical Cond Aggravated by Exposure:ASTHMA AND SKIN ALLERGIES.
======================= First Aid Measures =======================
First Aid:EYE:IMMED FLUSH W/FRESH H2O FOR @ LST 15 MIN. SEEK MED AID.
SKIN:WASH W/SOAP & H2O, RINSE IMMED. SEEK MED AID. INHAL:MOVE
PERSON TO FRESH AIR; ARTF RESP IF NEC. SEEK MED ATTN. INGEST:DO NOT
INDUCE VOM IT. IF VOMIT OCCUS SPONTANEOUSLY, KEEP HEAD BELOW HIPS
TO PVNT ASPIR OF LIQ INTO LUNGS. SEEK MED ATTN. MD NOTE:IF MORE
THAN 2.0 ML/KG HAS BEEN INGEST & VOMIT HAS NOT OCCURED, EMESIS
(SUPP DATA)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:55.0F,12.8C
Lower Limits:1 %
Upper Limits:11 %
Extinguishing Media:WATER SPRAY, FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:BLANKET FLAME WITH ONE OF THE ABOVE. VAPS OF
COMBUST MAY BE IRRIT TO RESP TRACT. MAY CAUSE BRTHG DFCLTS. PVNT
HUMAN EXPOS TO FIRE, SMOKE, FUMES, ETC.(SUPP DATA)
Unusual Fire/Explosion Hazard:COOL HOT CNTNRS W/H2O TO PVNT RUPTURES.
KEEP MATL AWAY FROM HEAT/SPARKS/OPEN FLAMES. FLAMM FUMES MAY ACCUM
IN CONFINED AREA & SPARKS/OPEN FLAMES MAY IGNITE IT.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL TYPES OF IGNIT SOURCES. PROVIDE
SUFFICIENT VENT. PROTECT CLEAN-UP PERSON W/NIOSH/MSHA APPRVD CORP
RESP & GOGG. USE METAL CONTAINER MARKED "DO NOT REUSE". PUT MATL
INTO THIS CNTNR. USE VERMI CULITE/OTHER INERT ABSORB. KEEP AWAY
FROM SEWERS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:PROT AGAINST PHYSICAL DAMAGE TO
CONTAINERS AND SPILLAGE. STORE IN A COOL VENT AREA WITH SPRINKLER
SYSTEM. KEEP AWAY FROM HEAT. POST NO SMOKING SIGNS.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED DUST/MIST RESPIRATOR
(HIGH EFFICIENCY CARTRIDGES ADVISED) IF SPRAYING OR SANDING. USE
NIOSH/MSHA APPRVD ORG VAP CARTRIDGE RESP IF TLV FOR SOLV COMPONENTS
MAY BE EXCEEDED E. G. 8540 3M CORP RESP (NIOSH/MSHA APPROVED).
Ventilation:USE ONLY WITH ADEQUATE VENTILATION.
Other Protective Equipment:PROT CLTHG & CHANGE CONTAM CLTHG IMMED.
PROVIDE EMERGENCY SHOWERS & EYEWASH @ STATIONARY PAINT APPLICATION
FACILITIES.
Work Hygienic Practices:TRAIN EMPLOYEES ON ALL SPECIAL HANDLING PROC
BEFORE WORKING WITH THIS PRODUCT.
Supplemental Safety and Health
FIRE FIGHT PROC:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. FIRST
AID PROC:SHOULD BE INDUCED W/SUPERVISION. KEEP VICTIM'S HEAD BELOW
HIPS TO PVNT ASPIR. IF SYMP SUCH AS LOSS OF GAG REFLEXES,
CONVULSIONS/UNCONSCIOUSNESS OCCUR BEFORE EMESIS, GASTRIC LAVAGE
USING A CUFFED ENDOTRACHEAL TUBE SHOULD BE CONSIDERED.
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:175F,79C
Melt/Freeze Pt:M.P/F.P Text:<32F,<0C
Vapor Pres:8-124 @20C
Vapor Density:2.5-3.3
Spec Gravity:0.78
Evaporation Rate & Reference:0.82-3.6 (BUAC=1)
Solubility in Water:MODERATE
Appearance and Odor:WATER WHITE WITH CHARACTERISTIC ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:HEAT, SPARKS, AND OPEN FLAMES. DO NOT
ALLOW VAPORS TO ACCUMULATE.
Hazardous Decomposition Products:CO & UNIDENTIFIED ORG CMPNDS MAY BE
FORMED DURING COMBUSTION.
Conditions to Avoid Polymerization:EXTREME HEAT.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF ALL WASTES IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:MASTERSEAL 550 (FORMERLY RE039), PART B, 03652
Kit Part:Y
CAGE:FO873
CAGE:98898
CAGE:FO873
============= Composition/Information on Ingredients =============
Ingred Name:SILICATE, PORTLAND CEMENT; (PORTLAND CEMENT)
CAS:65997-15-1
RTECS #:VV8770000
Fraction by Wt: 25-45%
OSHA PEL:50 MPPCF
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (SILICA, CRYSTALLINE QUARTZ)
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: 60-80%
OSHA PEL:0.1 MG/M3 RDUST(MFR)
ACGIH TLV:0.1 MG/M3 RDUST
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: <5%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:NUISANCE DUST MAY CAUSE
TEMPORARY BUT REVERSIBLE RESP PROBS. EYES:ABRASIVE ACTION MAY CAUSE
DMG TO OUTER SURF. IN COMBINATION W/WATER, MAY CAUSE SEV IRRIT
W/CORNEAL INJURY. SKIN CONT:IN CO MBINATION W/WATER DERMAL EXPOS
MAY CAUSE SEV ALKALI BURNS. SKIN ABORPTION:DOES NOT ABSORB THRU
SKIN. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC
MONOGRAPHS, VOL 68, 1997:GRP 1. NTP 7TH ANNUAL RPT ON CARCINS,
1994:ANTIC TO BE CARCIN.
Effects of Overexposure:HLTH HAZ:INGEST:NOT LIKELY SOURCE OF ENTRY DUE
TO NATURE OF MATL. CHRONIC:MATLS ARE NOT KNOWN MUTAGENIC,
TERATOGENIC/REPRO HLTH HAZS. RPTD INHAL OF RESP SILICA IN EXCESS OF
TLV OVER EXTENDED PERIODS C AN RSLT IN IRREVERSIBLE FIBROSIS OF
LUNGS (SILICOSIS).
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE VICTIM FROM EXPOS. IF DFCLTY W/BRTHG, ADMIN
OXYG. IF BRTHG HAS STOPPED ADMIN ARTF RESP, PREF MOUTH-TO-MOUTH.
SEEK MED ATTN. EYES:FLUSH W/WATER, LIFTING UPPER & LOWER LIDS OCCAS
FOR AT LST15 MINS. SEEK MED ATTN. SKIN:REMOVE CONTAM CLTHG. WASH
THORO W/SOAP & WATER. IF IRRIT PERSISTS SEEK MED ATTN. WASH CONTAM
CLTHG BEFORE REUSE. INGEST:DO NOT INDUCE VOMIT; GIVE LG QTYS OF
(SUPP DATA)
===================== Fire Fighting Measures =====================
Extinguishing Media:USE EXTINGUISHING AGENT SUITABLE FOR TYPE OF
SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE KNOWN.
================== Accidental Release Measures ==================
Spill Release Procedures:NO SPECIAL PROCEDURES ARE REQUIRED FOR
CLEAN-UP OF SPILLS OR LEAKS OF THIS MATERIAL. SWEEP UP & RETURN FOR
REUSE OR DISCARD. LANDFILL AT AGENCY APPROVED WASTE-DISPOSAL
FACILITIES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVERAGE SHELF LIFE:REFER TO PRODUCT
DATA SHEET. STORE IN A COOL, DRY PLACE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH APPRVD RESP WHENEVER AIRBORNE CONCS
EXCEED TLV CEILINGS/TWA, USE NIOSH APPRVD RESPS EQUIPPED W/DUST
CARTRIDGE FOR LISTED HAZ. CONFINED SPACES, ROOMS/TANKS ARE AREAS
WHERE CONCERN FOR TLV'S IS ESP IMPORTANT. REFERENCE OSHA(SUPDAT)
Ventilation:VENT IS REC. AIR MOVEMENT MUST BE DESIGNED TO INSURE
TURNOVER AT ALL LOCATIONS IN WORK AREA TO AVOID BUILD UP OF(SUPDAT)
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
SHOWER . SELECTION OF SPECIFIC ITEMS SUCH AS BOOTS & APRONS (SUPP
DATA)
Work Hygienic Practices:DO NOT WEAR CONTACT LENSES WHEN WORKING W/THIS
MATERIAL.
Supplemental Safety and Health
FIRST AID PROC:WATER; GET IMMED MED ATTN. IF VOMIT OCCURS SPONT, KEEP
HEAD BELOW HIPS TO PVNT ASPIR OF LIQS INTO LUNGS. DO NOT GIVE
ANYTHING BY MOUTH TO AN UNCON PERS. RESP PROT:REG CFR 29 1910.134
FO R REC RESP PROT. VENT:AIRBORNE DUST CONCS. EYE PROT:FULL LGTH
FSHLD . OTHER PROT EQUIP:WILL DEPEND ON OPERATION.
================== Physical/Chemical Properties ==================
Solubility in Water:SLIGHT
Appearance and Odor:WHITE POWDER; ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS.
Stability Condition to Avoid:NOT SENSITIVE TO MECHANICAL IMPACT.
Hazardous Decomposition Products:NONE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DOES NOT CONTAIN HAZARDOUS CHEMICALS AS DEFINED
IN 40 CFR 260. HANDLE DISPOSAL OF WASTE MATERIAL IN MANNER WHICH
COMPLIES W/LOCAL, STATE, PROVINCE & FEDERAL REGULATIONS. LANDFILL
AGENCY APPROVED WASTE -DISPOSAL FACILITIES.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:LACQUER ACRYLIC GRAY 16440 ID 794620
Preparer's Name:W.A. ELLISON
CAGE:FO127
CAGE:FO127
CAGE:61196
============= Composition/Information on Ingredients =============
Ingred Name:CYCLOHEXANONE (SARA III)
CAS:108-94-1
RTECS #:GW1050000
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 25 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
CAS:78-93-3
RTECS #:EL6475000
OSHA PEL:200 PPM/300 STEL
ACGIH TLV:200 PPM/300STEL 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
CAS:67-63-0
RTECS #:NT8050000
OSHA PEL:400 PPM/500 STEL
ACGIH TLV:400 PPM/500STEL;9192
Ingred Name:VOC. ORGANIC CMPD 5.0 LB/GL LESS WATER & NPRS* 600 G/L LESS
WATER VOC 16.2 LB/GAL SOLIDS 1944 G/L SOLIDS CALCULATED.
RTECS #:9999999VO
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SWALLOWING: CAN CAUSE GASTROINTESTINAL
IRR/NAUSEA/VOMIT. ASPIRATION OF MAT'L MAYCAUSE CHEM PNEUMONITIS.
INHALATION: NOSE/THROAT IRRITA. HIGH CONCENTRATION MAY CAUSE
CENTRAL NERVOUS SYSTEM DEPRESSION CHAR BY
HEADACHES/DIZZINESS/NAUSEA/CONFUSION. EYE: MAY CAUSE EYE IRRITA.
SKIN: MAY CAUSE DEFATTING AND IRRITATION.
Explanation of Carcinogenicity:TITANIUM DIOXIDE IS NOT LISTED AS A
POTENTIAL CARCINOGEN BY THE NTP, IARC, OSHA OR ACGIH.
Effects of Overexposure:REPORTS HAVE ASSOCIATED PROLONGED AND REPEATED
OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND
NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING AND INHALINGTHE CONTENTS MAY BE HARMFUL OR
FATAL.REPEATED OVEREXPOSURE TO TOLUENE MAY CAUSE LIVER DAMAGE.
======================= First Aid Measures =======================
First Aid:SWALLOWING: DO NOT INDUCE VOMITING/GET MED ATTN. INHALATION:
REMOVE TO FRESH AIRIF BREATHING HAS STOPPED GIVE CPR. GET MED ATTN.
EYE: FLUSH W/WATER FOR 15 MIN LIFTING UPPER/LOWER LIDS. GET MED
ATTN. SKIN: REMOVE CONTAMINATED CLOTHING.WASH AFFECTED AREA.
OBTAIN MED ATTN IF IRR'N PERSISTS. TREATMENT REQ FOR OVER-
EXPOSURE S/B DIRECTED AT THE CONTROL OF SYMPTOMS AND THE CLINICAL
CONDITIONS.
===================== Fire Fighting Measures =====================
Flash Point:24F -4.44C
Extinguishing Media:USE NFPA CLASS B FIRE EXTINGUISHERS. POLYMER FOAM
IS PREFERRED FOR LARGE FIRES.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. WATER
TO COOL CONT TO PREVENT POSSIBLE AUTO-IGNITION OR EXPLOSION. IF
WATER IS USED, FOG NOZZLES ARE PREFERABLE.
Unusual Fire/Explosion Hazard:DURING EMERGENCY CONDITIONS, OVEREXPOSURE
TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZ. SYMPTOMS MAY NOT
BE IMMED APPARENT. GET MED ATTN. WARNING-FLAMMABLE!
================== Accidental Release Measures ==================
Spill Release Procedures:ELIM ALL IGNITION SOURCES. DIKE/CONTAIN SPILL
WITHINERT MAT'L. TRANSFER LIQ'S/ABSORBENT DIKING MAT'LIN COVERED
METAL CONT'S FOR RECOVERY/DISPOSAL. USEONLY NON-SPARKING TOOLS.
PREVENT CONTAM OF SEWERS/ STREAMS/GROUNDWATER W/SPILLED MAT'L/USED
ABSORBENT
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 95F. STORE LARGE
QUANTITIES IN COMPLIANCE WITH OSHA 29CFR1910.106.
Other Precautions:DO NOT REUSE EMPTY CONTAINER. DO NOT TAKE INTERNALLY.
CONTAINER SHOULD BE GROUNDED AND BONDED TO THE RECEIVING
CONTAINER. DO NOT WELD/BRAZE OR CUT CONT'R.NEVER USE PRESSURE TO
EMPTY. DRUM IS NOTA PRESSURE VESSEL. CLOSE AFTER EA USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WELL VENTILATED AREA-RESP NOT REQ. RESTRICTED
VENT-NIOSH CHEMICAL CARTRIDGE MAY BE REQ. IF SPRAYING, MECH
PREFILTER MAY BE REQ. IF TLF ARE EXCEEDED, USE A PROP FITTED
NIOSH/MSHA RESP W/APPROP PROTECTI ON FACTOR. SEE OSHA 29 CFR
1910.134.
Ventilation:PROVIDE DILUTION/LOCAL EXHAUST VENTILATION TO KEEP CONCEN-
TRATIONS OF HAZARDOUS INGRID BELOW EXPOSURE LIMITS STATED.
Other Protective Equipment:NOT LIKELY TO BE NEEDED.
Work Hygienic Practices:WASH WITH SOAP AND WATER HANDS/FACE THROUGHLY
BEFORE EATING OR DRINKING.
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:175F 314F
Vapor Density:>AIR
Evaporation Rate & Reference:SLOWER THAN ETHER.
Percent Volatiles by Volume:69
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT AND SOURCES OF
IGNITION.
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE AND CARBON
DIOXIDE.
Conditions to Avoid Polymerization:KEEP AWAY FROM HEAT, SPARKS AND
FLAME.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE ONLY IN EPA PERMITTED FACILITY.
DISPOSEONLY IAW FED/STATE/LOCAL REGS. DO NOT INCINERATE CLOSED
CONTAINERS. OBSERVE PRECAUTIONS FOR DIS- POSAL OF FLAMMABLE
MAT'S. CONTAMINATED ABSORBENT MAY BE DISPOSED IN A HAZARDOUS
WASTE LANDFILL.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:FLAT GREEN, PAINT, OIL BASE
CAGE:33200
CAGE:33200
============= Composition/Information on Ingredients =============
Ingred Name:PIGMENTS
Fraction by Wt: 65.0%
Ingred Name:ALKYD RESIN
Fraction by Wt: 7.0%
Ingred Name:PETROLEUM DISTILLATES (NAPHTHA OR RUBBER SOLVENT)
CAS:8002-05-9
RTECS #:SE7449000
Fraction by Wt: 28.0%
OSHA PEL:400 PPM
ACGIH TLV:400 PPM; 8990
===================== Hazards Identification =====================
Effects of Overexposure:EYES:SEVERE IRRITATION SKIN:DRYING.
INH;(EXCESSIVE) HEADACHE,LDIZZINESS, NAUSEA.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH W/WATER. SKIN: WASH W/MILD SOAP & WATER & APPLY
SKIN CREME. INHALATION:REMOVE TO FRESH AIR & CALL PHYSCIAN.APPLY
ARTIFICIAL RESPIRATION IF NECESSARY.
===================== Fire Fighting Measures =====================
Flash Point:102F (SETA)
Lower Limits:0.8
Upper Limits:5.0
Extinguishing Media:FOAM, CO*2, CRY CHEMICAL
Fire Fighting Procedures:TREAT AS A CLASS B FIRE
Unusual Fire/Explosion Hazard:VAPORS MAY FORM EXPLOSIVE MIXTURES W/AIR.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR A RESPIRATOR. FLUSH W/WATER INTO
RETAINING AREA OR CONTAINER. AVOID EXPOSURE TO SPARKS, FIRE OR HOT
METAL SURFACES.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, & OPEN
FLAMES. USE W/ADEQUATE VENTILATION. AVOID PROLONGED OR REPEATED
SKIN CONTACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SELF-CONTAINED, APPROVED RESPIRATOR IF TLV IS
EXCEEDED.
Ventilation:USE LOCAL EXHAUST.
Other Protective Equipment:EYE BATH & SAFETY SHOWER.
Supplemental Safety and Health
VAPOR PRESSURE: <80.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:315F
Vapor Density:4.90
Spec Gravity:1.5600
Evaporation Rate & Reference:0.1 (N-BUAC)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:GREEN OPAQUE LIQUID, PETROLEUM DISTILLATE ODOR.
Percent Volatiles by Volume:64.0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:EXCESSIVE HEAT, SPARKS, & OEPN FLAMES
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD CARBON
MONOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:LANDFILL OR INCINERATION IF IN ACCORDANCE TO
FED., STATE & LOCAL CODES.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:3M BRAND ACTIVATOR
CAGE:76381
CAGE:76381
DIV
CAGE:1BY21
============= Composition/Information on Ingredients =============
Ingred Name:MAGNESIUM ACETATE (WT% RANGE 80-90%)
CAS:142-72-3
RTECS #:AI5600000
Fraction by Wt: 10%.
Ingred Name:ETHYLENE THIOUREA/SILVER COMPLEX (WT% RANGE 1-5%
Fraction by Wt: 5%
Ingred Name:ETHYLENE THIOUREA (SARA III)
CAS:96-45-7
RTECS #:NI9625000
Fraction by Wt: 0.2%
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 85%
Ingred Name:ACETIC ACID (SARA III)
CAS:64-19-7
RTECS #:AF1225000
Fraction by Wt: <1.0%
Other REC Limits:NONE SPECIFIED
OSHA PEL:10 PPM
ACGIH TLV:10 PPM/15 STEL; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Health Hazards Acute and Chronic:IRRITATION.ETHYLENE THIOUREA PROBABLE
HUMAN CARCINOGEN, NO HUMAN EVIDENCE.
Effects of Overexposure:EYE:IRRT.SKN:NONE EXPECTED.INHL:NONE,INGEST;
REPTD EXPOSURE HAS CAUSED CANCER,BIRTH DEF IN LAB ANMLS
Medical Cond Aggravated by Exposure:NONE KNOWN
======================= First Aid Measures =======================
First Aid:INHAL:RMV TO FRESH AIR. IF NOT BRTHNG GIVE CPR; IF BRTHNG
DIFF GIVE OXYGEN. EYE:IMMED FLUSH W/PLENTY OF WATER. SKIN:WASH
W/SOAP&WATER. RMV CONTAM CLTHG&SHOES. INGEST:INDUCE VOMIT. RPT
UNTIL VOMIT IS C LEAR. NOTHG BY MOUTH IF UNCONSC. GET MEDICAL ATTN.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.
================== Accidental Release Measures ==================
Spill Release Procedures:CAREFULLY OBSERVE PRECAUTIONS FROM OTHER
SECTIONS. COLLECT SPILLED MATERIAL. FLUSH AA WITH LARGE AMOUNTS OF
WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:PROTECT FROM FREEZING.
Other Precautions:AVOID EYE,SKN CONTACT. DO NOT INHALE OR INGEST. WASH
AFTER HANDLING.
============= Exposure Controls/Personal Protection =============
Ventilation:GEN MECHANICAL
Other Protective Equipment:NONE
Supplemental Safety and Health
UPDATE PER 3M MSDS DOC#10-3571-6 DATED 1NOV85. 3M ID# IS 78-9020-0080-7
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:215F
Spec Gravity:1.03
pH:4.7-5.
Evaporation Rate & Reference:1.0 (WATER=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR SOLUTION, VINEGAR ODOR. PH=4.7-5.3
Percent Volatiles by Volume:>85
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:NEUTRALIZE ACID WITH SODIUM HYDROXIDE OR
POTASSIUM HYDROXIDE. REMOVAL OF SILVER BY A CONVENTIONAL SILVER
REMOVAL PROCEDURE. SLOWLY DISCHARGE SOLUTION TO DRAIN WITH EXCESS
WATER. OR, SEND TO NEAREST HA ZARDOUS WASTE MANAGEMENT FACILITY FOR
DISPOSAL.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:TIN SILVER SOLDER
CAGE:52329
CAGE:52329
============= Composition/Information on Ingredients =============
Ingred Name:TIN
CAS:7440-31-5
RTECS #:XP7320000
Fraction by Wt: 94-99%
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3
Ingred Name:SILVER (SARA III)
CAS:7440-22-4
RTECS #:VW3500000
Fraction by Wt: 1-6%
OSHA PEL:0.01 MG/M3
ACGIH TLV:0.1 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL: MAY CAUSE IRRITATION OF THE
RESPIRATORY TRACT. SKIN CONTACT: MAY CAUSE SOME IRRITATION. EYE
CONTACT: MAY IRRITATE. INGEST: NO DOCUMENTED EFFECTS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE FROM EXPOSURE AND CONSULT MD. SKIN: WASH
AFFECTED AREAS WITH SOAP & WATER. EYES: FLUSH WITH WATER FOR AT
LEAST 15 MINUTES. INGEST: CONSULT MD.
===================== Fire Fighting Measures =====================
Lower Limits:SUPDAT
Extinguishing Media:DRY SAND OR OTHER INERT MATERIAL. DO NOT USE CLASS
"A", "B", OR "C" EXTINGUISHERS OR HALOGENATED AGENTS.
Fire Fighting Procedures:WEAR NIOSH/SHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:WHEN HEATED OR IN CONTACT WITH ACID CAN
EMIT TOXIC FUMES.
================== Accidental Release Measures ==================
MSHA APPROVED RESPIRATOR.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE AVOIDING
CONTACT WITH HEAT AND ACIDS.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED SUPPLIED AIR RESPIRATOR
IN CONFINED OR ENCLOSED SPACES IF NEEDED.
Ventilation:LOCAL EXHAUST, MINIMUM FACE VELOCITY OF 60 F.P.M.
Other Protective Equipment:CHEMICAL RESISTANT APRON TO AVOID PROLONGED
OR REPEATED SKIN CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
BP: SN-4118F,2270C; AG-4014F,2212C. LEL: 220 OZ/1000 FT3.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:SUPP DATA
Melt/Freeze Pt:M.P/F.P Text:430F,221C
Spec Gravity:7.1 (WATER=1)
Solubility in Water:NONE
Appearance and Odor:GRAY AND ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, SULFUR, CHLORINE, SODIUM AND POTASSIUM PEROXIDE.
Stability Condition to Avoid:OPEN FLAMES.
Hazardous Decomposition Products:REACTION WITH STRONG ACIDS CAN PRODUCE
TOXIC ORGANIC OR INORGANIC TIN COMPOUNDS.
==================== Disposal Considerations ====================
Waste Disposal Methods:PUT IN CLOSED CONTAINER FOR DISPOSAL. DISPOSAL
MUST COMPLY WITH FEDERAL, STATE OR LOCAL WASTE DISPOSAL LAWS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:IMCOR A-102,83169
Preparer's Name:LEWIS J. HICKS
CAGE:NO311
CAGE:0MB12
CAGE:NO311
CAGE:1AP98
============= Composition/Information on Ingredients =============
Ingred Name:5-CHLORO-2-METHYL-4-ISOTHIOAZOLIN-3-ONE
CAS:26172-55-4
RTECS #:NX8156850
Other REC Limits:NONE RECOMMENDED
Ingred Name:COPPER (II) NITRATE, TRIHYDRATE/CUPRIC NITRATE
CAS:10031-43-3
RTECS #:GL7875000
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3 (CU)
ACGIH TLV:1 MG/M3 (CU)
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) IS 3,810 MG/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY
& GI TRACTS. ACUTE- CORROSIVE. MAY CAUSE SEVERE EYE & SKIN
IRRITATION, IRREVERSIBLE EYE DAMAGE. MAY CAUSE SKIN SENSITIZATION.
HARMFUL IF INGESTED. INHALATION CAUS ES NOSE & THROAT IRRITATION.
CHRONIC- UNKNOWN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:ABDOMINAL PAIN, NAUSEA, RASHES, SEVERE
IRRITATION, EYE DAMAGE, SKIN SENSITIZATION, COUGH, TEARING
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE
MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:MOVE TO FRESH
AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:IMMEDIATELY FLUSH WITH
WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. SKIN:WASH WITH SOAP &
WATER. ORAL:IF CONSCIOUS, DRINK TWO GLASSES OF WATER.SEEK
IMMEDIATE MEDICAL ATTENTION. IF VOMITING OCCURS, KEEP HEAD BELOW
HIPS. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NON-COMBUSTIBLE
Lower Limits:NOT RELEVANT
Upper Limits:NOT RELEVANT
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS. HAZARDOUS DECOMPOSITION
PRODUCTS MAY BE FORMED. PRODUCT IS NOT COMBUSTIBLE.
Unusual Fire/Explosion Hazard:EMITS TOXIC AND CORROSIVE GASES.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. VENTILATE AREA.
STOP FLOW OF MATERIAL. CONTAIN/ABSORB SPILLS WITH DRY SAND, EARTH,
VERMICULITE. TRANSFER TO SUITABLE CONTAINER FOR RECOVERY/DISPOSAL.
DO NOT DISCHARGE TO SEW ERS OR WATERWAYS.
Neutralizing Agent:NOT RELEVANT
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN VENTILATED AREA. KEEP OUT OF
REACH OF CHILDREN. KEEP CONTAINER CLOSED WHEN NOT IN USE.
Other Precautions:CORROSIVE. READ AND FOLLOW ALL LABEL DIRECTIONS AND
PRECAUTIONS. WASH THOROUGHLY AFTER HANDLING. AVOID CONTACT WITH
EYES AND SKIN. DO NOT INGEST. USE IN VENTILATED AREA. AVOID
BREATHIN VAPOR OR MIST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS TO AN ACCEPTABLE LEVEL, A NIOSH-APPROVED RESPIRATOR
MUST BE WORN. A PROGRAM SHOULD BE INSTITUTED TO ASSURE COMPLIANCE
WITH OSHA STANDARD29 CFR 1910.134.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP MIST/FUME
LEVELS AS LOW AS POSSIBLE.
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, UNIFORM
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
EPA REGISTRATION NUMBER: 707-133-17866
================== Physical/Chemical Properties ==================
HCC:C2
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:212F,100C
Spec Gravity:1.02
pH:4
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:PALE YELLOW TO GREEN LIQUID - MILD AROMATIC ODOR
Percent Volatiles by Volume:95
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:MAY FORM CARBON MONOXIDE, CARBON
DIOXIDE, OXIDES OF SULFUR, HYDROGEN CHLORIDE GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT/DISPOSAL IS SUBJECT TO
FEDERAL, STATE/LOCAL REGULATIONS. CONTRACT WITH A LICENSED CHEMICAL
DISPOSAL AGENCY. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNING E VEN AFTER CONTAINER IS EMPTIED.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:METHYL ALCOHOL
Resp. Party Other MSDS Num.:MM360
Preparer's Name:MICHAEL RASZEJA
CAGE:6V042
CAGE:6V042
Contract Num:MDA414-99-A-0001-0144
CAGE:33089
Contract Num:MDA414-99-P-4383
CAGE:4A560
Contract Num:MDA414-99-A-0024-0020
CAGE:63759
Contract Num:MDA414-99-A-0024-0034
CAGE:63759
============= Composition/Information on Ingredients =============
Ingred Name:METHYL ALCOHOL
CAS:67-56-1
RTECS #:PC1400000
Minumum % Wt:90.
Maxumum % Wt:100.
OSHA PEL:260 MG/M3;200 PPM
ACGIH TLV:262 MG/M3;200 PPM
ACGIH STEL:328 MG/M3;250 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL-RAT LD50: 5628 MG/KG
Health Hazards Acute and Chronic:INGESTION: HARMFUL AND MAY BE FATAL IF
SWALLOWED. CANNOT BE MADE NON-POISONIOUS. EYES: IRRITATION.
INHALATION: MAY BE FATAL IF INHALED. SKIN: PROLONGED CONTACT MAY
CAUSE DERMITITIS.
Effects of Overexposure:INGESTION: HEADACHE, NAUSEA, VOMITING,
GASTROINTESTIONAL IRRITATION, CENTRAL NERVOUS SYSTEM DEPRESSION,
HEARING LOSS, BLINDNESS AND PERHAPS DEATH. EYES: CORNEAL DAMAGE.
INHALATION: NARCOSIS, RESPIRATO RY FAILURE, LOW BLOOD PRESSURE,
CENTRAL NERVOUS SYSTEM DISORDER, DROWSINESS, HEADACHE, NAUSEA,
VOMITING. SKIN: DERMITITIS.
======================= First Aid Measures =======================
First Aid:INGESTION: IF SWALLOWED, IF CONSCIOUS,GIVE 1-2 GLASSES OF
WATER TO DRINK, INDUCE VOMITING & CALL PHYSICIAN IMMEDIATELY. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION: REMOVE
TO FRE SH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN IMMEDIATELY.
EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING
LIDS OCCASIO NALLY. GET MEDICAL ATTENTION. SKIN: FLUSH WITH WATER
FOR 15 MINUTES, THEN WASH WITH MILD SOAP & WATER. *FOR ALL ROUTES:
KEEP PATIENT WARM & COVER EYES TO EXCLUDE LIGHT.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:=12.C, 53.6F
Autoignition Temp:=463.C, 865.4F
Lower Limits:6.0
Upper Limits:36
Extinguishing Media:CARBON DIOXIDE (CO2); DRY CHEMICAL (ABC); ALCOHOL
TYPE FOAM-WATER MAY BE INEFFECTIVE. FLUSH SPILL AREA WITH WATER
SPRAY.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE
EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. MOVE CONTAINERS FROM
FIRE AREA IF IT CAN BE DONE WIT HOUT RISK.USE WATER SPRAY TO COOL
FIRE EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:VAPORS MAY FOLLOW ALONG SURFACES TO A
DISTANT IGNITION SOURCES AND FLASH BACK. CLOSED CONTAINERS EXPOSED
TO HEAT MAY EXPLODE. CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE.
BURNS WITH A CLEAR, ALMOST I NVISIBLE FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. USE WATER
SPRAY TO REDUCE VAPORS. USE ABSORBENT MATERIALS TO SOAK UP
SPILLS(SAND,EATH OR VERMICULITE). CAREFULLY SWEEP UP & PLACE IN
CONTAINER FOR DISPOSAL. SPILLS IN C RITICAL AREAS CAN BE DILUTED
WITH WATER TO REDUCE FIRE HAZARD DURING CLEAN-UP. DO NOT FLUSH TO
SEWER, DRAIN OR WATERWAYS. WASH SPILL AREA WITH SOAP & WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED
AREA AWAY FROM STRONG OXIDIZERS & FIRE HAZARDS. AVOID CONTACT WITH
EYES SKIN & CLOTHING. WASH THOROUGHLY AFTER HANDLING. REMOVE &
WASH CONTAMINATED CLOTHING. KEE P CONTAINER TIGHTLY CLOSED WHEN NOT
IN USE.
Other Precautions:KEEP AWAY FROM HAT, SPARKS, FLAME. USE
EXPLOSIVE-PROOF ELECTRICAL FIXTURES. CONTAINERS SHOULD BE
ELECTRICALLY GROUNDED/BONDED DURING MATERIAL TRANSFER TO PREVENT
STATIC SPARK. AVOID BREATHING VAPORS. USE WITH ADEQUATE
VENTILATION. DO NOT WEAR CONTACT LENSES WHEN WORKING WITH
CHEMICALS. KEEP OT OF RE ACH OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NEEDED IN NORMAL LABORATORY HANDLING. IF
MISTY CONDITIONS PREVAIL, WORK IN VENTILATION HOOD OR WEAR A
NIOSH/MSHA APPROVED RESPIRATOR AIR-SUPPLIED OR SELF-CONTAINED
BREATHING APPARATUS.
Ventilation:LOCAL:RECOMMENDED. MECHANICAL:YES. OTHER:ADEQUATE TO
MAINTAIN BELOW EXPOSURE LIMIT.
EXTINGUISHER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE AND WASH
CONTAMINATED CLOTHING.
Supplemental Safety and Health
WARD'S P/N: 39W0296; SCHOOL SPECIALTY P/N: S75833. NASCO P/N: KM00010M.
================== Physical/Chemical Properties ==================
HCC:F5
Boiling Pt:=65.C, 149.F
Melt/Freeze Pt:=-98.C, -144.4F
Vapor Pres:96MM
Vapor Density:1.11
Spec Gravity:0.79
Evaporation Rate & Reference:4.6
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR,COLORLESS LIQUID; PUNGENT ODOR.
Percent Volatiles by Volume:100%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS, ZINC, ALUMINUM AND MAGNESIUM.
Stability Condition to Avoid:SPARKS, EXCESSIVE HEAT, SOURCES OF
IGNITION, OPEN FLAMES, STATIC DISCHARGE.
Hazardous Decomposition Products:TOXIC GASES OF CARBON DIOXIDE AND/OR
CARBON MONOXIDE, FORMALDEHYDE.
=================== Toxicological Information===================
Toxicological Information:THRESHOLD LIMITED VALUE: STEL 250 PPM, 328
MG/M3. (ACGIH 1992-93). TOXICITY DATA: ORL-RAT LD50: 5628 MG/KG.
===================== Ecological Information =====================
Ecological:NO DATA PROVIDED BY RESPONSIBLE PARTY.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO FEDERAL, STATE OR LOCAL LAWS. THESE DISPOSAL GUIDE LINES ARE
INTENDED FOR CATALOG-SIZE QUANTITIES ONLY. DISPOSE OF IN ACCORDANCE
WITH FEDERAL, STATE , AND LOCAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:DOT: METHYL ALCOHOL, 3, UN1230, PGII.
===================== Regulatory Information =====================
SARA Title III Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Federal Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:BARIUM HYDROXIDE,OCTAHYDRATE
Preparer's Name:ALEXANDER A. PICCIRILLI
CAGE:EO227
CAGE:EO227
CAGE:63759
============= Composition/Information on Ingredients =============
Ingred Name:BARIUM HYDROXIDE OCTAHYDRATE
CAS:12230-71-6
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG BA/M3
ACGIH TLV:10 MG BA/M3
===================== Hazards Identification =====================
LD50 LC50 Mixture:LDL0 (ORAL RAT) IS 335 MG/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, RESPIRATORY
AND GASTROINTESTINAL TRACTS. ACUTE- POISON AND CORROSIVE.
EYE/SKIN:MAY CAUSE IRRITATION, BURNS. INHALE:IRRITANT TO MUCOUS
MEMBRANES. POISONING MAY AFFECT THE HEART , LUNGS, CNS AND
RESPIRATORY SYSTEM. ORAL:MAY CAUSE VIOLENT DIARRHEA, ABDOMINAL
PAIN, SALIVATION. CHRONIC- DERMATITIS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, WEAKNESS, FATIGUE, HEADACHE,
ABDOMINAL PAIN, EXCESSIVE SALIVATION, NAUSEA, VOMITING, VIOLENT
DIARRHEA, SORE THROAT, SHORTNESS OF BREATH, BURNS, DERMATITIS
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS OR IMPAIRED CNS OR RESPIRATORY FUNCTION MAY
BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:CALL A DOCTOR IF SYMPTOMS PERSIST. EYE/SKIN:FLUSH WITH WATER
FOR 15 MINUTES. HOLD EYELIDS OPEN. INHALED:REMOVE TO FRESH AIR.
PROVIDE CPR/OXYGEN IF NEEDED. ORAL:IF CONSCIOUS, DRINK 1-2 GLASSES
OF WATER OR MILK & INDUCE VOMITING. CALL A PHYSICIAN/POISON
CONTROL CENTER IMMEDIATELY. NEVER GIVE FLUID OR INDUCE VOMITING IF
PATIENT IS UNCONSCIOUS OR HAS CONVULSIONS.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS. FORMS HAZARDOUS DUSTS/FUMES.
SEE 1990 EMERGENCY RESPONSE GUIDEBOOK, GUIDE NO 59.
Unusual Fire/Explosion Hazard:FORMS HAZARDOUS DUSTS/FUMES.
================== Accidental Release Measures ==================
Spill Release Procedures:RECLAIM AS MUCH AS POSSIBLE. WEAR SUITABLE
PROTECTIVE CLOTHING. AVOID MAKING DUST. SWEEP UP AND PLACE IN A
SUITABLE CONTAINER FOR LATER DISPOSAL. WASH SPILL SITE WELL WITH
SOAP AND WATER AFTER PICK UP IS COMPLETE.
Neutralizing Agent:WEAK ACID
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, VENTILATED PLACE
AWAY FROM INCOMPATIBLE MATERIALS. ABSORBS CARBON DIOXIDE FROM AIR.
KEEP CONTAINER TIGHTLY CLOSED.
Other Precautions:POISON AND CORROSIVE. AVOID CREATING DUST. DO NOT GET
IN EYES, ON SKIN OR ON CLOTHING. AVOID INHALATION OF DUST OR FUME.
KEEP OUT OF REACH OF CHILDREN. OBEY HAZARD WARNING LABEL. FOR
LABORATORY USE ON LY. NOT FOR DRUG, FOOD OR HOUSEHOLD USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED IN NORMAL LABORATORY
HANDLING. IF DUSTY CONDITIONS PREVAIL, WORK IN A FUME HOOD OR WEAR
A NIOSH-APPROVED DUST RESPIRATOR OR DUST MASK. IN EMERGENCY, WEAR
NIOSH-APPROVED SELF-CONT AINED BREATHING APPARATUS.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION.
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, PROTECTIVE
CLOTHING AND/OR UNIFORM
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:T3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:1436F -H2O
Melt/Freeze Pt:M.P/F.P Text:172F,78C
Vapor Pres:NEGLIGIBLE
Vapor Density:10.9
Spec Gravity:2.18
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:SLIGHT
Appearance and Odor:WHITE POWDER, CRYSTALS OR GRANULES - ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, CHLORINATED RUBBER, METALS
Stability Condition to Avoid:EXCESSIVE HEAT
Hazardous Decomposition Products:MAY FORM ACRID SMOKE AND IRRITATING
FUMES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS. MAY BE DISPOSED OF IN AN APPROVED CHEMICAL
LANDFILL OR CONTRACT WITH A LICENSED WASTE DISPOSAL SERVICE.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:RED DECK ENAMEL ALKYD
CAGE:47695
CAGE:47695
============= Composition/Information on Ingredients =============
Ingred Name:TALC (CONTAINING ASBESTOS)
CAS:14807-96-6
RTECS #:MW2700000
Fraction by Wt: 5-10% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.2 FIBERS/CC
ACGIH TLV:0.2 FIBERS/CC; 9394
Ingred Name:ZINC OXIDE
CAS:1314-13-2
RTECS #:ZH4810000
Fraction by Wt: 5-10% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10MG/M3 TDUST; 9394
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: 5-10% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG/M3 RDUST; Z-3
ACGIH TLV:0.1 MG/M3 RDUST;9394
Ingred Name:IRON OXIDE
CAS:1309-37-1
RTECS #:NO7400000
Fraction by Wt: 10-15% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG/M3 (FE)
ACGIH TLV:5MG(FE)/M3FUME,B2;94
Ingred Name:IRON OXIDE
CAS:51274-00-1
Fraction by Wt: 2-5% %
Other REC Limits:NONE RECOMMENDED
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 10-15% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9394
Ingred Name:PETROLEUM HYDROCARBON,
CAS:64742-47-8
RTECS #:OA5504000
Fraction by Wt: 5-10% %
Other REC Limits:NONE RECOMMENDED
Ingred Name:NAPHTHA, SOLVENT-REFINED HEAVY
CAS:64741-92-0
Fraction by Wt: 10-15% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3 (OIL MIST)
ACGIH TLV:5 MG/M3 (OIL MIST)
Ingred Name:PETROLEUM HYDROCARBON,
CAS:64742-47-8
RTECS #:OA5504000
Fraction by Wt: 5-10% %
Other REC Limits:NONE RECOMMENDED
Ingred Name:FILM FORMERS, RESINS, & ADDITIVES
Fraction by Wt: 25-30% %
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT GIVEN FOR PRODUCT AS A WHOLE
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:HARMFUL OR FATAL IF SWALLOWED. CAUSES
SEVERE EYE IRRITATION. MAY CAUSE MODERATE SKIN IRRITATION.
INHALATION MAY CAUSE RESPIRATORY TRACT IRRITATION AND PERMANENT
BRAIN AND NERVOUS SYSTEM DAMAGE. LONG-T ERM EXPOSURE TO CRYSTALLINE
SILICA MAY LEAD TO SILICOSIS OR CANCER.
Explanation of Carcinogenicity:IARC STATES THAT THER IS SUFFICIENT
EVIDENCE OF CARCINOGENITY OF CRYSTALLINE SILICA IN EXPERIMENTAL
ANIMALS.
Effects of Overexposure:EYE IRRITATION, SKIN IRRITATION, UPPER
RESPIRATORY TRACT IRRITATION, BRAIN DAMAGE, NERVOUS SYSTEM DAMAGE,
LUNG DAMAGE, EYES WATERING, HEADACHES, NAUSES, DIZZINESS, LOSS OF
COORDINTATION, VISUAL DISTUR BANCES.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN AND/OR
RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS
PRODUCT.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS
OPEN. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING.
WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL
ATTENTION. IN HALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. GET
MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:105F,41C
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, UNIVERSAL FILM
FORMING FOAM
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE SOURCES OF IGNITION. EVACUATE AREA.
WEAR PROPER PERSONAL PROTECTIVE EQUIPMENT. CONTAIN SPILL. STOP LEAK
IF CAN DO SO WITHOUT RISK. ABSORB LIQUID WITH SUITABLE ABSORBENT
MATERIAL. COLLECT FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 120F. STORE LARGE
QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA
CLASS II COMBUSTIBLE LIQUIDS.
Other Precautions:CONTAINERS SHOULD BE GROUNDED WHEN POURING. AVOID
FREE FALL OF LIQUIDS IN EXCESS OF A FEW INCHES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXOSURES BELOW PEL (TLV), USE NIOSH/MSHA APPROVED RESPIRATOR AS PER
CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS AND NIOSH RESPIRATOR
SELECTION.
Ventilation:LOCAL EXHAUST AND MECHANICAL (GENERAL) VENTILATION TO
MAINTAIN EXPOSURE LEVELS.
Other Protective Equipment:PROTECTIVE CLOTHING AS REQUIRED TO AVOID
SKIN CONTACT. AN EMERGENCY EYE WASH STATION AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:280F,138C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:NOT GIVEN
Vapor Density:> 1
Spec Gravity:> 1
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:NEGLIGIBLE
Appearance and Odor:VISCOUS LIQUID WITH AN ODOR CHARACTERISTIC OF THE
SOLVENTS
Percent Volatiles by Volume:50 %
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ALKALIS, STRONG MINERAL ACIDS
Stability Condition to Avoid:HEAT, OPEN FLAME, SPARKS
Hazardous Decomposition Products:CARBON MONOXIDE, OXIDES OF NITROGEN,
ZINC OXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: BAKELITE PREFORMS/POWDERS/PELLETS, 811-123
Cage: 94174
=======================================================
Contractor Summary
=======================================================
Cage: 94174
=======================================================
Ingredients
=======================================================
Cas: 100-97-0
RTECS #: MN4725000
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
% Wt: 36
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 1332-58-7
RTECS #: GF1670500
% Wt: 8-12
OSHA PEL: 2 MG/M3 TDUST
ACGIH TLV: 2 MG/M3 TDUST
------------------------------
Cas: 1332-69-0
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
% Wt: 2-6
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 57-11-4
RTECS #: WI2800000
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 557-05-1
RTECS #: ZH5200000
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 9003-35-4
% Wt: 50-56
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:VAPS EVOLVED DURING POLYMERIZATION/DECOMP MAY CAUSE
IRRIT TO EYES, LUNGS & SKIN. 1. PHENOL-CAS 108-95-2-OSHA PEL 5 PPM -
ACGIH TLV/TWA 5 PPM, TLV/STEL 10 PPM HIGHLY TOX - MAY CAUSE KIDNEY, LIVER
/HEART DMG. RPTD TO BE TUMOR PROMOTER. FORMALDEHYDE - CAS 50-00-0-OSHA PEL 3
PPM - ACGIH TLV/TWA 1 PPM,(EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ:TLV/STEL 2 PPM IRRITANT - TO
EYES, LUNGS & SKIN. HAS BEEN SHOWN TO CAUSE CANCER IN LAB ANIMALS, LISTED
AS IARC CARCIN. NATIONAL CANCER INSTITUTE STUDY FINDS LITTLE EVID TO CONNECT
FORMALDEHYD E EXPOS W/CANCER IN HUMANS. AMMONIA - CAS 7664-41-7- OSHA PEL 50
PPM - ACGIH TLV/TWA 25 PPM, TLV/STEL 35 PPM IRRITANT - TO EYES,MUC MEMB &
RESPIRATORY TRACT.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYES:IMMED FLUSH W/COPIOUS AMTS OF WATER FOR AT LST 15 MINS. GET MED
ATTN. SKIN:WASH THOROUGHLY WITH SOAP & WATER. INHAL:USE W/ADEQ VENT. IF
BRTHG IS AFFECTED, REMOVE TO FRESH AIR. IF BRTHG STOPS, APP LY MOUTH TO MOUTH
RESUSCITATION. GET MED ATTN. INGEST:DO NOT INDUCE VOMITING. DILUTE BY
DRINKING LARGE QUANTITIES OF WATER. IF VOMITING OCCURS, ADMINISTER MORE
WATER. GET MED ATTN.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: SMALL/LARGE SPILL:VACUUM OR SWEEP WITH SWEEPING
COMPOUND, SAWDUST OR SAND. AVOID GENERATING DUST. VACUUM WITH EXPLOSION-PROOF
MOTORS ARE RECOMMENDED.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: BURY OR INCINERATE IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
Handling And Storage Precautions: KEEP CONTAINER CLOSED TO AVOID CONTAMINATION.
STORE IN COOL, DRY PLACE.
Other Precautions: PREVENT ACCUMULATIONS OF DUST RAISED DURING PROCESSING. USE
ADEQUATE VENTILATION.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Lower Limits: NONE
Upper Limits: 0.030 OZ/FT3
Extinguishing Media: WATER, FOAM, DRY CHEMICAL, CARBON DIOXIDE.
Fire Fighting Procedures: NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N). AVOID
INHAL OF GASES. ORG DUST/AIR MIXS ARE HIGHLY FLAM(EXPLO). AVOID DUST
ACCUM/DUST-LADEN ATM & SOURCES OF IGNIT.
Unusual Fire/Explosion Hazard: NOT KNOWN.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH APPROVED RESPIRATORS RECOMMENDED IF TLV ARE
EXCEEDED.
Ventilation: USE LOC EXHAUST TO REMOVE DUST & VAPS EVOLVED DURING USE. USE
GEN VENT AS DUST COLLECTION SYS. POINT SOURCE EXHAUST RECOMMENDED, AND USE
EXPLOSION-PROOF MOTORS
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: OBSERVE GOOD HOUSEKEEPING PRACTICES. PRACTICE GOOD
HYGIENE & MAINTAIN A CLEAN WORK ENVIRONMENT.
Supplemental Safety and Health: HAZARDOUS DECOMPOSITION PRODUCTS: FORMALDEHYDE
AS WELL AS WATER VAPOR, CARBON MONOXIDE & CARBON DIOXIDE ARE EVOLVED.
BREATHING OF FUMES CAN BE HARMFUL.
=======================================================
Physical/Chemical Properties
=======================================================
Spec Gravity: 1.32-2.20
Evaporation Rate & Reference: NOT KNOWN
Solubility in Water: NEGLIGIBLE
Appearance and Odor: GRANULAR, NODULAR, PELLENT OR BRIQUET; SLIGHT PHENOL ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: AVOID DUST BUILDUP IN STORAGE AND MANUFACTURING AREAS.
Hazardous Decomposition Products: VAPS EVOLVED DURING POLYMERIZATION MAY
CONTAIN PHENOL, FORMALDEHYDE & AMMONIA. DURING PROCESSING OF PHENOLICS,
MELAMINE-PHENOLICS & HEXAMETHYLENETETRAMINE, SM AMTS OF AMMONIA, PHENOL, &
(SUPDAT)
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: BAKELITE PREFORMS/POWDERS/PELLETS, 811-123
Cage: 94174
Company Name: LECO CORPORATION
Street: 3000 LAKEVIEW AVE.
Zipcode: 49085-2396
Label Required IND: Y
Date Of Label Review: 12/24/1996
Status Code: C
Label Date: 12/24/1996
Origination Code: G
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE:VAPORS MAY IRRITATE EYES, LUNGS AND
SKIN. CHRONIC:NONE SPECIFIED BY MANUFACTURER.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:841 4393 FLEXICOLOR DEVELOPER REPLENISHER LORR, PART C
Kit Part:Y
CAGE:19139
CAGE:19139
CAGE:5K871
============= Composition/Information on Ingredients =============
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 50-55%
Other REC Limits:NONE RECOMMENDED
Ingred Name:4-(N-ETHYL-N-2-HYDROXYETHYL)-2-METHYLPHENYLENEDIAMINE
SULFATE
CAS:25646-77-9
RTECS #:KJ6477000
Fraction by Wt: 40-45%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM BISULFITE (SASA III) (CERCLA)
CAS:7631-90-5
RTECS #:VZ2000000
Fraction by Wt: < 1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT MALE): 25-50 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CONTAINS
4-(N-ETHYL-N-2-HYDROXYETHYL)-2-METHYLPHENYLENEDIAMINE SULFATE. MAY
CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA. CAN CAUSE IRRITATION TO
RESPIRATORY TRACT. CAUSES EYE IRRITATION. CAUSES SKIN IRRI TATION.
MAY CAUSE ALLERGIC SKIN REACTION. HARMFUL IF SWALLOWED. MAY CAUSE
KIDNEY DAMAGE BASED ON ANIMAL DATA.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:KIDNEY DAMAGE, EYE IRRITATION, SKIN IRRITATION,
ALLERFIC SKIN REACTION, GI TRACT IRRITATION, RESPIRATORY TRACT
IRRITATION.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS OR HYPERSENSITIVE
INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING.
======================= First Aid Measures =======================
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES: WASH OUT IMEEDIATELY WITH
WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH
SOAP AND WATER . GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: INDUCE VOMITING AS DIRECTED BY MEDICAL PERSONNEL. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL PHYSICIAN OR
POISON CONTROL ASAP.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL
FOAM
Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR SELF CONTAINED
BREATHING APPARATUS AND FULL PROTECTIVE GEAR. COOL TANKS AND
CONTAINERS EXPOSED TO FIRE WITH WATER.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY PRODUCE
HAZARDOUS DECOMPOSTION PRODUCTS.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER IF ALLOWABLE WITH LARGE AMOUNTS
OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT
MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN
SURFACE TO REMOVE RESIDUA L CONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT WITH EYES, SKIN AND
CLOTHING. AVOID BREATHING VAPOR. USE WITH ADEQUATE VENTILATION.
WASH THOROUGHLY AFTER HANDLING.
Other Precautions:THE ROUTINE USE OF A NONALKALINE (ACID) TYPE OF HAND
CLEANER AND REGULAR CLEANING OF WORKING SURFACES WILL HELP MINIMIZE
THE POSSIBILITY OF A SKIN REACTION. KEEP FROM CONTACT WITH
OXIDIZING MATERIALS. KEEP AWAY FROM HEAT. KEEP CAN CLOSED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED
RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: ACID GAS. IF RESPIRATORS
ARE USED, A PROGRAM SH OULD BE INSTITUTED.
Ventilation:GOOD GENERAL VENTILATION, TYPICALLY 10 AIR CHANGES PER
HOUR, SHOULD BE USED. RATES SHOULD MATCH CONDITIONS.
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO
PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. KEY1:C1.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:>212F,>100C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Decomp Temp:Decomp Text:338F,170C
Vapor Pres:18
Vapor Density:0.6
Spec Gravity:1.167
pH:2.1
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:COMPLETE
Appearance and Odor:YELLOW - DARK YELLOW LIQUID, STRONG SULFUR DIOXIDE
ODOR
Percent Volatiles by Volume:50-60%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG BASES
Stability Condition to Avoid:AVOID TEMPERATURES ABOVE 158F.
Hazardous Decomposition Products:NITROGEN OXIDES, SULFUR DIOXIDE,CARBON
DIOXIDE, CARBON MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE OR LOCAL LAWS. DISPOSE OF IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:METERPAK #103
CAGE:LO289
CAGE:0SL71
CAGE:LO289
============= Composition/Information on Ingredients =============
Ingred Name:NONE CONSIDERED HAZARDOUS
Other REC Limits:NA
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PRODUCT SOLD IN WATER SOLUBLE POUCH.
DIRECT CONTACT W/POWDER UNLIKELY UNDER NORMAL USE. SKIN: MAY CAUSE
IRRITATION, REDNESS. EYES: MAY CAUSE IRRITATION, STINGING.
INHALATION: MAY IRRITATE RESPIRATORY TRACT CAUSING COUGHING.
INGESTION: CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING
& DIARRHEA.
Effects of Overexposure:SEE HEALTH HAZARDS ABOVE.
Medical Cond Aggravated by Exposure:NONE KNOWN
======================= First Aid Measures =======================
First Aid:SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER 15 MINUTES,
HOLDING EYELIDS OPEN. SEEK MEDICAL ATTN. INHALATION: REMOVE TO
FRESH AIR. SEEK MEDICAL ATTN IF SYMPTOMS PERSIST. INGESTION: DRINK
1-2 GLASSES WATER TO DILUTE. SEEK MEDICAL ATTN.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR POSITIVE PRESSURE SCBA & PROPER
PROTECTIVE CLOTHING SHOULD BE WORN IN FIGHTING FIRES INVOLVING ANY
CHEMICAL SUBSTANCES.
Unusual Fire/Explosion Hazard:WATER SOLUTIONS OF PRODUCT MAY GENERATE
HYDROGEN GAS IN CONTACT W/ALUMINUM & ZINC.
================== Accidental Release Measures ==================
Spill Release Procedures:SPRINKLE W/SWEEPING COMPOUND TO REDUCE DUSTING
WHILE SWEEPING UP.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY & WELL-VENTILATED
AREA.
Other Precautions:WASH THOROUGHLY AFTER HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR IF DUSTING LIKELY.
Ventilation:LOCAL EXHAUST: STANDARD ROOM VENTILATION. MECHANICAL
(GENERAL): NOT NORMALLY REQUIRED.
Other Protective Equipment:NOT NORMALLY REQUIRED.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:NA
Melt/Freeze Pt:M.P/F.P Text:NA
Vapor Pres:NA
Vapor Density:NA
Spec Gravity:0.46
Evaporation Rate & Reference:NA
Solubility in Water:COMPLETE
Appearance and Odor:WHITE POWDER, LOW ODOR, PACKAGED IN WATER SOLUBLE
POUCH.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NK
Hazardous Decomposition Products:MAY EMIT TOXIC FUMES OF SOX, NA20 &
OXIDES OF CARBON IF HEATED TO DECOMPOSITION.
==================== Disposal Considerations ====================
Waste Disposal Methods:IN ACCORDANCE W/FEDERAL, STATE, LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:METHICILLIN SUSCEPTIBILITY TEST DISCS
CAGE:06531
CAGE:05545
CAGE:06531
CAGE:15481
============= Composition/Information on Ingredients =============
Ingred Name:SUSCEPTIBILITY TEST DISCS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Explanation of Carcinogenicity:NONE
===================== Fire Fighting Measures =====================
Extinguishing Media:USE ANY EXTINGUISHING MEDIA
================== Accidental Release Measures ==================
Spill Release Procedures:MAY BE SWEPT UP.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT REQUIRED UNDER NORMAL PRODUCT USAGE
Ventilation:NOT REQUIRED UNDER NORMAL PRODUCT USAGE
Other Protective Equipment:NOT REQUIRED UNDER NORMAL PRODUCT USAGE
Work Hygienic Practices:USE GOOD PERSONAL HYGIENE PRACTICES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Solubility in Water:INSOLUBLE
Appearance and Odor:PAPER DISCS OF VARIABLE COLOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF W/NORMAL LAB TRASH. FOLLOW ALL
FEDERAL, STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:601-87 2844-1109 COMPONENT A, 13-141
CAGE:9V982
CAGE:9V982
============= Composition/Information on Ingredients =============
Ingred Name:EPOXY RESIN ERL-2795; (EPOXY RESIN). VP:0.03 @ 77 C
CAS:25068-38-6
RTECS #:KD4380000
Fraction by Wt: 65%
Ingred Name:SUPER HI-FLASH NAPHTHA
CAS:64742-95-6
Fraction by Wt: 15%
Ingred Name:HYDROPHOBIC PRECIPITATED SILICA
CAS:67762-90-7
Fraction by Wt: 6%
Ingred Name:MAGNETITE; (IRON OXIDE MAGNETITE)
CAS:1309-38-2
RTECS #:OM4800000
Fraction by Wt: 12%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INGEST: GI DISTRESS INCLUDING
NAUSEA/VOMIT/ DIARR. ASPIR OF MATL INTO LUNGS CAN CAUSE CHEM
PNEUMONITIS WHICH CAN BE FATAL. INHAL: MAY CAUSE THROAT IRRIT. MAY
CAUSE NERV SYS DEPRESSION CHARAC BY: HDCH,DIZZ, NAUSEA, STAG
GAIT, CONFUSION, UNCON. REPORTS HAVE ASSOC RPTD & PRLNG OCCUP
OVEREXP TO SOLV (SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: W/PERMANENT BRAIN & NERV SYS DAMAGE.
INTENTIONAL MISUSE BY DELIBERATELY CONC & INHALING CONTENTS MAY BE
HARMFUL/FATAL. EYES: MAY CAUSE SEVERE IRRIT, REDNESS, TEARING,
BLURRED VISION. SKIN: P ROLONGED OR REPEATED CONTACT CAN CAUSE
MODERATE IRRITATION, DEFATTING DERMATITIS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. RESTORE BRTHG. TREAT
SYMPTOMATICALLY. CONSULT MD. EYES: FLUSH IMMED W/LRG AMTS OF H2O
FOR AT LEAST 15 MIN. TAKE TO MD FOR MEDICAL TREATMENT. SKIN: WASH
AFFECTED AREAS WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING.
CONSULT A PHYSICIAN IF IRRITATION PERSITS. INGEST: DO NOT INDUCE
VOMITING. CONSULT PHYSICIAN OR POISON CONTROL CENTER IMMED. TREAT
SYMPTOMATICALLY.
===================== Fire Fighting Measures =====================
Flash Point:106F,41C
Lower Limits:0.9 %
Extinguishing Media:FOAM, CO2 OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE SOURCES OF IGNITION AND PROVIDE
VENTILATION. LARGE SPILLS MAY BE SCOOPED UP WITH NONSPARKING TOOLS.
PROVIDE RESPIRATORY PROTECTION IF REQUIRED. SMALL QUANTITIES MAY BE
PICKED UP WITH ABSORBENT MATERIAL. SEE DISPOSAL PRECAUTIONS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:CLOSED CNTNRS MAY EXPLODE WHEN EXPOS
TO EXTREME HEAT. STORE AWAY FROM HIGH TEMPS, SPARKS & FLAMES. AVOID
PRLNGD SKIN CNTCT. DO NOT BREATHE SPRAY MIST.
Other Precautions:GROUND CONTAINERS WHILE POURING AND LIMIT FREE FALL
TO A FEW INCHES TO PVNT STATIC SPARKS. AVOID SPONTANEOUS COMBUST OF
CONTAM RAGS & OTHER EASILY IGNIT ORGANIC ACCUMULATIONS BY IMMED
IMMERSION IN H2O . EMPTIES CNTNRS MAY RETAIN (SUPP DATA)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:PROVIDE ADEQUATE VENTILATION. IF TLV OF THE
PRODUCTS IS EXCEEDED, A NIOSH/MSHA JOINTLY APPROVED SCBA WITH A
FULL FACEPIECE OPERATED IN PRESSURE DEMAND OR OTHER POSITIVE
PRESSURE MODE IS ADVISED.
Ventilation:PROVIDE SUFFICIENT MECHANICAL AND/OR LOCAL EXHAUST
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV.
Other Protective Equipment:TO PREVENT PROLONGED SKIN CONTACT, WEAR
IMPERVIOUS CLTHG & BOOTS. EYEWASH FACILITY, EMERGENCY SHOWER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
OTHER PREC: HAZARDOUS PROPERTIES. DO NOT CUT, PUNCTURE OR WELD ON OR
NEAR THE CONTAINER. STORE LARGE QUANTITIES ONLY IN BUILDINGS
DESIGNED TO COMPLY WITH OSHA 1910.106.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:306F,152C
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:20
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
UNKNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY PRODUCE NOXIOUS FUMES WHEN HEATED
TO DECOMPOSITION, AS IN WELDING. FUMES MAY CONTAIN CO, NOX.
==================== Disposal Considerations ====================
Waste Disposal Methods:PLACE IN CLOSED CONTAINERS. SEE OTHER
PRECAUTIONS. INCINERATE (FIRST OPEN CLOSED CONTAINERS) OR USE
SECURE LANDFILL IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:N-1200SCK
CAGE:SANCO
CAGE:SANYE
CAGE:SANCO
============= Composition/Information on Ingredients =============
Ingred Name:CADMIUM (SARA 313) (CERCLA)
CAS:7440-43-9
RTECS #:EU9800000
OSHA PEL:0.2 MG/M3 DUST; Z-2
ACGIH TLV:0.01 MG/M3 DUST
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:POTASSIUM HYDROXIDE; (KOH(POTASSIUM HYDROXIDE))
CAS:1310-58-3
RTECS #:TT2100000
OSHA PEL:0.2 MG/M3 DUST; Z-2
ACGIH TLV:0.01 MG/M3 DUST
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:SODIUM HYDROXIDE; (NAOH (SODIUM HYDROXIDE))
CAS:1310-73-2
RTECS #:WB4900000
OSHA PEL:N/K
ACGIH TLV:N/K
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:SKIN IRRITATION BY ELECTROLYTE.
CHRONIC:NONE LISTED BY MANUFACTURER.
Explanation of Carcinogenicity:CADMIUM:IARC MONOGRAPHS ON EVAL OF
CARCIN RISK OF CHEMS TO MAN, VOL 58, PG 119, 1993:GROUP 1. NTP 7TH
ANNUAL (SUPDAT)
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:SKIN BURN.
======================= First Aid Measures =======================
First Aid:WASH OUT ELECTROLYTE WITH WATER. INGEST:CALL MD IMMEDIATELY .
INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) .
EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR MINIMUM OF 15 M INUTES,
SEEK ASSISTANCE FROM MD .SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER.
CALL MD .
===================== Fire Fighting Measures =====================
Extinguishing Media:NOT APPLICABLE. MEDIA SUITABLE FOR SURROUNDING FIRE
.
Fire Fighting Procedures:NOT APPLICABLE. USE NIOSH/MSHA APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERE IS NO FLAMEABLE OR EXPLOSIVE
MATERIAL USED IN THE BATTERY.
================== Accidental Release Measures ==================
Spill Release Procedures:WASH OUT RELEASED OR SPILLED ELECTROLYTE WITH
WATER OR NEUTRALIZE ELECTROLYTE WITH BORIC ACID.
Neutralizing Agent:BORIC ACID.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT PUT IN A FIRE. HANDLE THE
PRODUCT GENTLY.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE
SHOWER .
Work Hygienic Practices:NOTHING IN PARTICULAR.
Supplemental Safety and Health
EXPLAN OF CARCIN:RPT ON CARCINS, 1994:ANTIC TO BE CARCIN. HUMAN:LUNG,
PROSTATE, RENAL SYS EFTS.
================== Physical/Chemical Properties ==================
Evaporation Rate & Reference:NOT KNOWN
Appearance and Odor:A CYLINDRICAL METAL CAN WITH PVC SHRINKING TUBE.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NOT APPLICABLE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NOT APPLICABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGUALTIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:GASOLINE, REGULAR LEADED, UNBRANDED, P 1635
Preparer's Name:PATNESKY
CAGE:82250
CAGE:82250
============= Composition/Information on Ingredients =============
Ingred Name:GASOLINE
CAS:8006-61-9
RTECS #:LX3300000
Fraction by Wt: 90-95%
OSHA PEL:300 PPM
ACGIH TLV:300 PPM/500STEL;9495
Ingred Name:BENZENE (SARA 313) (CERCLA)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: 0-5%
OSHA PEL:SEE 1910.1028
ACGIH TLV:10 PPM; A2; 9495
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:SUPDAT:EXPLOSION HAZ. CNTNRS MAY EXPLODE IN HEAT OF FIRE.
IRRIT/TOX SUBSTANCES MAY BE EMITTED UPON THERMAL DECOMP.
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP:HIGH PRESS SKIN INJECTIONS ARE SERIOUS MED
EMERGENCIES. INJURY MAY NOT APPEAR SERIOUS AT FIRST; (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4:W/IN A FEW HRS, TISS WILL BECOME SWOLLEN, DISCOLORED
& EXTREMELY PAINFUL (SEE NOTES TO MD). EYE:MAY CAUSE (ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5:SLIGHT TRANSIENT IRRIT. INHAL:MAY CAUSE RESP TRACT
IRRIT. EXPOS MAY CAUSE CNS SYMPS SIMILAR TO THOSE (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6:LISTED UNDER "INGEST" (SEE INGEST SECTION). MAY ALSO
CAUSE ANEMIA & IRREG HEART RHYTHM. RPTD/PRLNGD EXPOS (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7:MAY CAUSE BEHAVIORAL CHANGES.
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC:SHOULD BE HELD AWAY FROM EYEBALL TO ENSURE
THOROUGH RINSING. GET MED ATTN IF IRRIT PERSISTS. (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:INHAL:REMOVE AFFECTED PERS FROM SOURCE OF EXPOS. IF
NOT BRTHG, INSTITUTE CPR. IF BRTHG IS DIFF, GIVE (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:OXYGEN. GET MED ATTN. NOTES TO MD. IN CASE OF
INGEST, GASTRIC LAVAGE W/ACTIVATED CHARCOAL CAN BE USED (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11:PROMPTLY TO PVNT ABSORPTION. CONSIDERATION SHOULD BE
GIVEN TO USE OF INTRATRACHEAL TUBE, TO PVNT ASPIR. (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:INDIVIDUALS INTOXICATED BY GASOLINE SHOULD BE
HOSPITALIZED IMMED, W/ACUTE & CONTINUING ATTENTION TO (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13:NEUROLOGIC & CARDIOPULMONARY FUNCTION. POS PRES VENT
MAY BE NEC. AFTER INITIAL EPISODE, INDIVIDUALS (ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14:SHOULD BE FOLLOWED FOR CHANGES IN BLOOD VARIABLES &
DELAYED APPEAR OF PULM EDEMA & CHEM PNEUM. SUCH (ING 16)
RTECS #:9999999ZZ
Ingred Name:ING 15:PATIENTS SHOULD BE FOLLOWED FOR SEVERAL DAYS/WEEKS
FOR DELAYED EFTS, INCL BONE MARROW TOX, HEPATIC & (ING 17)
RTECS #:9999999ZZ
Ingred Name:ING 16:RENAL IMPAIRMENT. INDIVIDUALS W/CHRONIC PULM DISEASE
WILL BE MORE SERIOUSLY IMPAIRED, & RECOVERY FROM (ING 18)
RTECS #:9999999ZZ
Ingred Name:ING 17:INHAL EXPOS MAY BE COMPLICATED. IN CASE OF SKIN
INJECTION, PROMPT DEBRIDEMENT OF THE WOUND IS NECESSARY (ING 19)
RTECS #:9999999ZZ
Ingred Name:ING 18:TO MINIMIZE NECROSIS AND TISSUE LOSS.
RTECS #:9999999ZZ
Ingred Name:SPILL PROC:LRG SPILLS:DIKE FAR AHEAD OF SPILL FOR LATER
DISPOSAL. NOTIFICATION:ANY SPILL/RELS/SUBSTANTIAL THREAT(ING 21)
RTECS #:9999999ZZ
Ingred Name:ING 20:OF RELEASE, OF THIS MATL TO NAVIGABLE H*2O
(VIRTUALLY ANY SURF H*2O) SUFFICIENT TO CAUSE A VISIBLE SHEEN (ING
22)
RTECS #:9999999ZZ
Ingred Name:ING 21:UPON THE H*2O MUST BE RPTD IMMED TO NATIONAL
RESPONSE CENTER (800/424-8802), AS REQ BY U.S. FED LAW. (ING 23)
RTECS #:9999999ZZ
Ingred Name:ING 22:FAILURE TO REPORT MAY RESULT IN SUBSTANTIAL CIVIL
AND CRIMINAL PENALTIES.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:DANGER! HARMFUL/FATAL IF SWALLOWED.
ASPIR HAZ. VAP MAY BE HARMFUL. LONG-TERM EXPOS TO VAP HAS CAUSED
CANCER IN SOME LAB ANIMALS. MAY BE IRRIT TO SKIN, EYES & RESP
TRACT. EXTREMELY FLAMM LIQ. VAP MAY E XPLODE. INGEST:MODERATELY
TOX. ASPIRATION INTO LUNGS MAY CAUSE HARMFUL CNS EFTS. EFTS MAY
INCL (EFTS OF OVEREXP)
Explanation of Carcinogenicity:BENZENE: IARC MONO, SUPP VOL 7, PG 120,
1987: GROUP 1: NTP 7TH ANNUAL RPT ON CARCINS, 1994: KNOWN TO BE
CARCINOGENS.
Effects of Overexposure:HLTH HAZ:EXCITATION, EUPHORIA, HDCH, DIZZ,
DROW, BLURRED VISION, FATIGUE, TREMORS, CONVS, LOSS OF
CONSCIOUSNESS, COMA, RESP ARREST & DEATH. SKIN:PRACTICALLY NON-TOX.
SLIGHTLY IRRIT. RPTD/PRLNG CNTCT M AY RSLT IN DEFAT, REDNESS,
ITCHING INFLAMM, CRACKING & POSS SECONDARY INFECTION. HIGH PRESS
SKIN INJECTIONS. (ING 4)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:DO NOT INDUCE VOMIT BECAUSE OF DANGER OF ASPIRATING
LIQ INTO LUNGS. GET IMMED MED ATTN. IF SPONT VOMIT OCCURS, MONITOR
FOR BRTHG DIFFICULTY. SKIN:REMOVE CONTAMD CLTHG IMMED. WASH AREA OF
CNTCT THORO W/SOAP & H*2O. GET MED ATTN IF IRRIT PERSISTS. HIGH
PRESS SKIN INJECTIONS ARE SERIOUS MED EMER. GET IMMED MED ATTN.
EYE:FLUSH IMMED W/LRG AMT OF WATER FOR AT LEAST 15 MIN. EYELIDS
(ING 9)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:-35F,-37C
Lower Limits:1.4%
Upper Limits:7.6%
Extinguishing Media:USE DRY CHEMICAL, FOAM OR CARBON DIOXIDE TO
EXTINGUISH FIRE.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . H*2O
MAY BE INEFT BUT SHOULD BE USED TO COOL FIRE-EXPOS CNTNRS,
STRUCTURES & TO PROT PERS. IF LEAK (SUPDAT)
Unusual Fire/Explosion Hazard:DANGEROUS WHEN EXPOS TO HEAT/FLAME. VAPS
FORM FLAMM/EXPLO MIX W/AIR AT ROOM TEMP. VAP/GAS MAY SPREAD TO
DISTANT IGNIT SOURCES & FLASH BACK. VAPS MAY (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:NO FLARES, SMOKING/FLAMES IN HAZ AREA. STOP
LEAK IF YOU CAN DO IT W/OUT RISK. USE WATER SPRAY TO REDUCE VAPS.
SMALL SPILLS:TAKE UP W/SAND/OTHER NONCOMBUSTIBLE ABSORB MATL/OTHER
SORBENT KNOWN TO BE COM PATIBLE, THEN FLUSH AREA W/H*2O. (ING 20)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS IN
COOL, DRY, ISOLATED, WELL-VENTILATED AREA AWAY FROM HEAT, SOURCES
OF IGNITION AND INCOMPATIBLES.
Other Precautions:GROUND LINES & EQUIP USED DURING TRANSFER TO REDUCE
POSSIBLILITY OF STATIC SPARK-INITIATED FIRE/EXPLOSION. EMPTY CNTNRS
MAY CNTN TOX. FLAMM/COMBUST/EXPLO RESIDUE/VAPS. FOR MORE SPECIFIC
INFORMATION CO NTACT NEHC .
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED EQUIPMENT WHEN AIRBORNE
EXPOSURE LIMITS ARE EXCEEDED. NIOSH APPROVED BREATHING EQUIPMENT
MUST BE AVAILABLE FOR NON-ROUTINE AND EMERGENCY USE. VENTILATION
MAY BE USED TO CONTROL OR R EDUCE AIRBORNE CONCENTRATIONS.
Ventilation:VENTILATION MAY BE USED TO CONTROL OR REDUCE AIRBORNE
CONCENTRATIONS.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . PROTECTIVE CLOTHING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
% VOLAT:100.0 @ 437F. FIRE FIGHT PROC:/SPILL HAS NOT IGNITED, VENT AREA
& USE WATER SPRAY TO DISPERSE GAS/VAP & TO PROTECT PERS ATTEMPTING
TO STOP A LEAK. USE H*2O TO FLUSH SPILLS AWAY FROM SOURCES OF
IGNIT. DO NOT FLUSH DOWN PUBLIC SEWERS. EXPLO HAZ:CONC IN CONFINED
AREAS. RUNOFF TO SEWER MAY CAUSE FIRE OR (ING 3)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:55.4F,13.0C
Vapor Pres:760 @ 100F
Vapor Density:1.2 AS VAP
Spec Gravity:0.72-0.74 @ 60F
Evaporation Rate & Reference:>1 (WATER = 1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR LIQUID WITH A STRONG HYDROCARBON ODOR.
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZERS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:COMBUSTION MAY PRODUCE CO, CO*2 AND
REACTIVE HYDROCARBONS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS . FOR MORE SPECIFIC INFORMATION CONTACT
NEHC .
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:GR-941
CAGE:29057
CAGE:81349
CAGE:29057
============= Composition/Information on Ingredients =============
Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT
===================== Hazards Identification =====================
Effects of Overexposure:IRRITATING TO ALL PARTS OF RESPIRATORY
TRACT.BOTH LIQUID STYRENE AND VAPOR CAN BE EXTREMELY IRRITATI
======================= First Aid Measures =======================
First Aid:INHALATION:MOVE SUBJECT TO FRESH AIR,KEEP WARM,GIVE OXYGEN OR
ARTIFICIAL RESP. AS REQUIRED.SKIN CONTACT:WASH W/SOAP &
WATER.EYES:FLUSH PROMPTLY WITH COPIOUS AMOUNTS OF WATER FOR 15
MINUTES AND CONSULT PHYS.INGESTION:CONSULT MD. PROMPTLY.
===================== Fire Fighting Measures =====================
Flash Point:PMCC 90F 32.1C
Lower Limits:1.1
Upper Limits:6.1
Extinguishing Media:DRY POWDER,FOAM,CARBON DIOXIDE
Fire Fighting Procedures:EXTINGUISH FLAME FROM PERIMETER INWARD TOWARD
MAIN BODY OF F
Unusual Fire/Explosion Hazard:POLYESTERS UNDERGO EXOTHERMIC
POLYMERIZATION.IF A CLOSED DRUM IS CAUGHT IN A FIRE VIOLENT RUPTURE
MA
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE SATURATED CLOTHING AND WASH AFFECTED
AREAS WITH SOAP & WATER.REMOVE SOURCES OF IGNITION (FLAMES,HOT
SURFACES,ELECTRICAL STATIC,FRICTION SPARKS).VENTILATE AREA.USE
MEASURES OUTLINED IN SECTION V III.ABSORB WITH INERT MATERIAL(E.G.
VERMICULITE)
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AND HANDLE AS NATIONAL FIRE
PROTECTIVE ASSOC.CLASS 1-C FLAMMABLE LIQUID.STORE BELOW 27C (80F)
IN A CLOSED CONTAINER AND DRY AREA TO AVOID SPOI
Other Precautions:IN BULK STORAGE,CHECK BY THE FORMATION OF
POLYMER.GROUND ALL CONNECTIONS,ETC.WHEN USING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:UP TO 100PPM-NONE 100 PPM AND ABOVE-SELF
CONTAINED APPARATUS
Ventilation:YES-LOCAL AND MECHANICAL TO COMPLY TO SEC. II AND IV.
Other Protective Equipment:PROTECTIVE CLOTHING TO MINIMIZE SKIN
CONTACT.SAFETY SHOWERS
Supplemental Safety and Health
IRRITATING TO ALL PARTS OF RESPIRATORY TRACT.BOTH LIQUID STYRENE AND
VAPOR CAN BE EXTREMELY IRRITATING TO EYES.LIQUID CONTACT WITH SKIN
MAY CAUSE MODERATE IRRITATION.
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:>150F>65C
Vapor Pres:5.2
Vapor Density:3.6
Spec Gravity:1.1
Solubility in Water:INSOLUBLE
Appearance and Odor:VISCOUS LIQUID WITH SHARP ODOR (STYRENE)
Percent Volatiles by Volume:35
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS,PEROXIDES AND OTHER OXIDIZING AGENTS.
Stability Condition to Avoid:SUNLIGHT,OPEN FLAMES, CONTAMINATION AND
PROLONG STORAGE ABOV
Hazardous Decomposition Products:CARBON MONOXIDE AND DIOXIDE,LOW
MOLECULAR WGT.HYDROCARBONS A
Conditions to Avoid Polymerization:SUNLIGHT,OPEN FLAMES,CONTAMINATION
AND PROLONGED STORAGE AB
==================== Disposal Considerations ====================
Waste Disposal Methods:RESIN MIXED WITH PEROXIDE INITATORS BEFORE
SPILL,SHOULD BE MIXED WITH INERT FILLER AND REMOVE TO OPEN
AREA.ALLOW TIME TO GEL CURE.USE SANITARY LANDFILL OR
INCINERATION.DO NOT INCINERATE CLOSED CONTAIN ERS.DISPOSAL MUST BE
CARRIED OUT IN ACCORDANCE WIT
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SYLGARD 184
CAGE:5D028
CAGE:5D028
CAGE:71984
============= Composition/Information on Ingredients =============
Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT
===================== Hazards Identification =====================
Effects of Overexposure:MAY CAUS DISCOMFORT TO EYES
======================= First Aid Measures =======================
First Aid:FLUSH WITH WATER.
===================== Fire Fighting Measures =====================
Flash Point:>250F,121C OC
Extinguishing Media:CARBON DIOXIDE OR FOAM
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:WIPE UP WITH ABSORBENT MATERIAL/CLOTH
W/SOLVENT
======================Handling and Storage ======================
Handling and Storage Precautions:NONE
Other Precautions:NONE
============= Exposure Controls/Personal Protection =============
Ventilation:MECHANICAL
Other Protective Equipment:AS REQUIRED
Supplemental Safety and Health
2-COMPONENT VIT "NO HAZARDOUS MATERIALS PRESENT."
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:>300F,148C
Vapor Pres:5.0
Spec Gravity:>1.0
Percent Volatiles by Volume:<5.0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:SILICONE DIOXIDE,CARBON DIOXIDE OR
TRACES NONBURNABLE PROD
==================== Disposal Considerations ====================
Waste Disposal Methods:LANDFILL
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:TSP CLEANER, 670
CAGE:SYNKO
CAGE:SYNKO
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM CARBONATE(2:1)
CAS:497-19-8
RTECS #:VZ4050000
Ingred Name:PHOSPHORIC ACID, TRISODIUM SALT; (TRI SODIUM PHOSPHATE, MFR
CAS #: 10124-58-8)
CAS:7601-54-9
RTECS #:TC9490000
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL: INHALATION OF VAPOR OR MIST CAN
CAUSE THE FOLLOWING: HEADACHE, NAUSEA, IRRITATION OF NOSE, THROAT,
AND LUNGS. EYE: DIRECT CONTACT WITH MATERIAL CAN CAUSE THE
FOLLOWING: SLIGHT IRRITATION. SKIN: DIRECT CONTACT W/MATERIAL CAN
CAUSE THE FOLLOWING: SLIGHT SKIN IRRITATION.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL: MOVE TO FRESH AIR. EYE: FLUSH WITH LARGE AMOUNT OF
WATER FOR AT LEAST 15 MINUTES. CONSULT A PHYSICIAN IF IRRITATION
PERSISTS. SKIN: WASH AFFECTED AREAS WITH SOAP AND WATER. CONSULT A
PHYSICIAN IF IRRITATION PERSISTS. INGEST: GIVE 2 GLASSES OF WATER
TO DRINK. CONSULT A PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCON PERSON.
===================== Fire Fighting Measures =====================
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL IGNITION SOURCES, ABSORB WITH
ABSORBENT, SWEEP UP OR SCOOP UP, VENTILATE EXPOSED AREAS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP FROM HEAT AND OPEN FLAMES. USE
ADEQUATE VENTILATION.
Other Precautions:AVOID REPEATED BREATHING OF VAPORS OR SKIN CONTACT.
USE NIOSH/MSHA APPROVED AIR SUPPLIED RESCUE EQUIPMENT IN ENCLOSED
AREAS. IN CASE OF FIRE COOL EXPOSED CONTAINERS WITH WATER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AVOID BREATHING VAPORS. USE W/ADEQUATE
VENTILATION. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:USE W/ADEQUATE VENTILATION.
Other Protective Equipment:USE FULL LENGTH CLOTHING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:SOLID
Spec Gravity:6.83
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:HIGH TEMPERATURES OR FLAME.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD
ACRYLIC MONOMERS, CARBON MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:TRIMAL (34033)
CAGE:HO105
CAGE:HO105
============= Composition/Information on Ingredients =============
Ingred Name:TRIBASIC LEAD MALEATE
Fraction by Wt: 100%
ACGIH TLV:0.05 MG/CUM MFR
===================== Hazards Identification =====================
Effects of Overexposure:TIREDNESS,DECREASED APPETITE, METALIC TASTE AND
INTERMITTENT STOMACH CRAMP. SEE SUP DATA.
======================= First Aid Measures =======================
First Aid:ABNORMAL INGESTION: INDUCE VOMITING. USE SYRUP OF INPECAC -
ONE OUNCE FOLLOWED BY EIGHT OUNCES OF WATER. CALL PHYSICIAN
IMMEDIATELY. SKIN: WASH W/SOAP AND WATER. CALL MD. INH: REMOVE TO
FRESH AIR.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER FOG, FOAM, CO*2, & DRY CHEMICALS
Fire Fighting Procedures:ISOLATE MATERIAL FROM ALL IGNITION SOURCES.
Unusual Fire/Explosion Hazard:USE NON-METALIC SCOOP. EQUIPMENT & HOPPER
MUST BE GROUNDED
================== Accidental Release Measures ==================
MATERIAL POSSIBLE TO CONTAINER. CLEAN FLOOR & OTHER SURFACES BY
VACUUMING; DO NOT USE COMPRESSED AIR FOR CLEANING
============= Exposure Controls/Personal Protection =============
Supplemental Safety and Health
OVEREXPOS: MUSCLE WEAK,HDCH,POSSIBLE CONVULSION & DEATH. KIDNEY DAMAGE
MAY OCCUR W/OUT SYMPTOMS. LEAD CROSSES THE PLACENTA; FETAL EXPOSURE
SHOULD NOT EXCEED 30UG/100G BLOOD (HEW GUIDELINE).
================== Physical/Chemical Properties ==================
Spec Gravity:6.3
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE ACCD TO MFR.
Stability Condition to Avoid:KEEP DUST ACCUMULATION TO A MINIMUM.
Hazardous Decomposition Products:ON IGNITION, OXIDES OF LEAD MAY BE
VOLATILIZED.
Conditions to Avoid Polymerization:TEMPERATURES GREATER THAN 400F, 204
==================== Disposal Considerations ====================
Waste Disposal Methods:MFR RECOMMENDS KEEPING WASTE RAGS IN A LABLED
SAFETY CONTAINER- DO NOT INCINERATE. WASTE DISPOSAL METHOD MUST BE
IAW FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:DIESEL FUEL NO 2, 4152
CAGE:15445
CAGE:15445
============= Composition/Information on Ingredients =============
Ingred Name:PETROLEUM MID-DISTILLATE; (DIESEL FUEL, NO. 2)
CAS:68476-34-6
Fraction by Wt: 100%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPDAT:PRLNGD/RPTD INHAL EXPOS TO HIGH CONCS OF SOME PETRO
DISTIL HAVE CAUSED LIVER TUMORS IN MICE & KIDNEY DMG &(ING 3)
RTECS #:9999999ZZ
Ingred Name:ING 2:TUMORS IN MALE RATS. HOWEVER, KIDNEY EFTS WERE NOT
SEEN IN SIMILAR STUDIES INVOLVING FEMALE RATS, GUINEA (ING 4)
RTECS #:9999999ZZ
Ingred Name:ING 3:PIGS, DOGS/MONKEYS. PRESENT STUDIES INDICATE KIDNEY
EFTS WILL ONLY OCCUR IN MALE RATS. ALSO, HUMAN STUDIES (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4:DO NOT INDICATE THIS PECULIAR SENSITIVITY FOR KIDNEY
DMG & STUDIES RPTD IN 1992 SHOWED THIS PARTICULAR TYPE(ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5:OF RAT KIDNEY DMG IS NOT USEFUL IN PREDICTING HUMAN
HLTH HAZ. SIGNIFICANCE OF LIVER TUMORS IN MICE EXPOS TO(ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6:HIGH DOSES OF CHEMS IS HIGHLY SPECULATIVE & PROBABLY
NOT GOOD INDICATOR FOR PREDICTING POTNTL HUMAN CARCIN (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7:HAZ. MOUSE SKIN PAINTING STUDIES HAVE SHOWN PETRO
MIDDLE DIST (BOILING RANGE 100-700F;NAPHTHA, JET FUEL, (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8:DIESEL FUEL, KEROSENE, ETC) CAN CAUSE SKIN CANCER
WHEN REPEATEDLY APPLIED & NEVER WASHED FROM ANIMAL'S (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:SKIN. RELATIVE SIGNIFICANCE OF THIS TO HUMAN HLTH IS
UNCERTAIN SINCE PETRO DIST WERE NOT WASHED FROM SKIN (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:& RSLTG SKIN EFTS(IRRIT, CELL DMG, ETC.) MAY PLAY
ROLE IN TUMORIGENIC RESPONSE. FEW STUDIES HAVE SHOWN (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11:WASHING ANIMAL'S SKIN W/SOAP & WATER BETWEEN
TREATMENTS GREATLY REDUCES CARCIN EFT OF SOME PETRO OILS. (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:OTHER LAB STUDIES INDICATE MIDDLE DISTIL CAUSED SKIN
TUMORS BY PROMOTING, RATHER THAN INITIATING, (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13:FORMATION OF TUMORS, SO EFT IS PROBABLY DOSE-RELATED
& LOW LEV EXPOS SHOULD NOT BE CARCIN. STUDIES IN (ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14:MICE & RATS HAVE SHOWN THAT CHRONIC EXPOS (8HRS/DAY,
7DAYS/WK, 24 MONTHS) TO UNFILTERED DIESEL EXHAUST (ING 16)
RTECS #:9999999ZZ
Ingred Name:ING 15:PRDCED TUMORS OF LUNGS & ALSO LYMPHOMAS. ON BASIS OF
THESE STUDIES, NIOSH REC WHOLE DIESEL EXHAUST BE (ING 17)
RTECS #:9999999ZZ
Ingred Name:ING 16:REGARDED AS POTENTIAL CARCIN.
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC:ADMIN. TO PREPARE ACTIVATED CHARCOAL MIX,
SUSPEND 50 GRAMS ACTIVATED CHARCOAL IN 400 ML WATER & (ING 19)
RTECS #:9999999ZZ
Ingred Name:ING 18:MIX THORO. ADMIN 5 ML/KG, OR 350 ML FOR AN AVERAGE
ADULT.
RTECS #:9999999ZZ
Ingred Name:SPILL PROC:& POWER TOOLS. IF EQUIP IS USED FOR SPILL
CLEANUP, IT MUST BE EXPLO PROOF & SUITABLE FOR FLAM LIQ & (ING 21)
RTECS #:9999999ZZ
Ingred Name:ING 20:VAP. NOTE:VAPS RELEASED FROM SPILL MAY CREATE EXPLO
ATM. DIKE SPILL. PVNT MATL FROM ENTERING SEWERS, (ING 22)
RTECS #:9999999ZZ
Ingred Name:ING 21:WATERWAYS, OR LOW AREAS. SOAK UP WITH SAWDUST, SAND,
OIL DRY/OTHER ABSORBENT MATERIAL.
RTECS #:9999999ZZ
Ingred Name:WASTE DISP METH:DRAINED, PROPERLY BUNGED, & PROMPTLY
SHIPPED TO SUPPLIER/DRUM RECONDITIONER. ALL OTHER CNTNRS (ING 24)
RTECS #:9999999ZZ
Ingred Name:ING 23:SHOULD BE DISPOSED OF IN AN ENVIRONMENTALLY SAFE
MANNER.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC:(LIQUID AND/OR VAPORS) AND MAY EXPLODE IN HEAT
OF FIRE.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) 2 ML/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:PROD MAY CAUSE IRRIT TO EYES,
NOSE, THROAT, LUNGS, & SKIN AFTER PRLNGD/RPTD EXPOS. EXTREME
OVEREXP/ASPIR INTO LUNGS MAY CAUSE DMG/DEATH. OVEREXP MAY CAUSE
WEAK, HDCH, NAUS, CONFUSN, BLURRED VISI ON, DROW, & OTHER NERV SYS
EFTS; GREATER OVEREXP MAY CAUSE DIZZ, SLURRED SPEECH, FLUSHED FACE,
UNCON, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:& CONVL. COMBUST PRODS:CO IS GAS THAT
CAN RSLT FROM INCOMPLETE COMBUST OF HYDROCARB, FROM DETOXIFICATION
OF SOME CHEMS LIKE METHYLENE CHLORIDE, TOBACCO SMOKE, & EVEN FROM
NATL BODY PROCESSES. CO BINDS TIGHTLY TO HEMOGLOBIN & INTERFERES
W/OXYG TRANSPORT TO BODY TISS. OVEREXP CAN CAUSE HDCH, NAUS, NERV
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
BRTHG IS DFCLT, GIVE OXYG. CALL MD. SKIN:WASH THORO W/SOAP & WATER.
IF IRRIT DEVELOPS & PERSISTS, CONSULT MD. EYE:IMMED FLUSH W/PLENTY
OF WA TER FOR @ LST 15 MINS. CALL MD. INGEST:DO NOT INDUCE VOMIT.
IMMED GIVE 2 GLASSES OF WATER. NEVER GIVE ANYTHING BY MOUTH TO
UNCON PERSON. CALL MD. NOTES TO PHYS:ACTIVATED CHARCOAL MIX MAY BE
(ING 18)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:130F,54C
Lower Limits:0.4%
Upper Limits:6%
Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CO*2.
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . USE
WATER TO KEEP FIRE-EXPOS CNTNRS COOL. IF LEAK/SPILL HAS NOT
IGNITED, USE WATER SPRAY TO DISPERSE VAPS & (SUPDAT)
Unusual Fire/Explosion Hazard:VAP FORMS EXPLO MIX W/AIR. VAPS/GASES MAY
TRAVEL CONSIDERABLE DIST TO IGNIT SOURCE & FLASH BACK. PRODS OF
COMBUST MAY CONTAIN CO, CO*2 & OTHER TOX (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:SAFEGUARDS (PERS):NOTE:REVIEW FIRE FIGHT
MEASURES & HNDLG (PERS) SECTION BEFORE PROCEEDING W/CLEAN-UP. USE
APPROP PERSONAL PROT EQUIP DURING CLEAN-UP. REMOVE SOURCE OF HEAT,
SPKS, FLAME, IMPACT, FRICT ION & ELEC INCL INTERNAL COMBUST ENGINES
(ING 20)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN WELL VENTILATED PLACE. KEEP
CNTNR TIGHTLY CLSD. STORE I/A/W NATL FIRE PROT ASSOC REC. STORE
AWAY FROM HEAT, SPARKS & FLAMES, OXIDIZERS.
Other Precautions:AVOID BRTHG VAPS/MIST. GROUND CNTNR WHEN POURING.
KEEP AWAY FROM HEAT, SPKS & FLAMES. CLOSE CNTNRS AFTER EACH USE. DO
NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, GRIND/DRILL ON/NEAR
FULL/EMPTY CNTNR. EM PTY CNTNR RETAINS RESIDUE (ING 25)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SELECT APPROPRIATE NIOSH APPRVD RESPIRATORY
PROTECTION WHEN NEEDED TO AVOID INHALATION OF MIST/VAPORS AND TO
MAINTIAN EXPOSURES BELOW ACCEPTABLE LIMITS.
Ventilation:USE ONLY WITH ADEQUATE VENTILATION. KEEP CONTAINER CLOSED.
Other Protective Equipment:COVERALLS IF SPLASHING IS PROBABLE. ANSI
APPRVD EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:LAUNDER CONTAMD CLTHG BEFORE REUSE. WASH HANDS
THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
FIRE PROC:TO PROVIDE PROT FOR PERS ATTEMPTING TO STOP LEAK. WATER SPRAY
MAY BE USED TO FLUSH SPILLS AWAY FROM EXPOS. EXPLO HAZ:MATLS. DO
NOT ENTER ENCLOSED/CONFINED SPACE W/OUT PROPER PROT EQUIP INCL
NIOSH APPRVD RESP PROT. EFTS OF OVEREXP:SYS DEPRESS, COMA, & DEATH.
TOX INFO:ANIMAL STUDIES HAVE SHOWN THAT (ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>350F,>177C
Vapor Pres:1 @ 68F
Vapor Density:>1
Spec Gravity:0.84-0.88 @60F
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:INSOLUBLE
Appearance and Odor:RED OR UNDYED (CLEAR OR STRAW-COLORED) LIQUID,
AROMATIC ODOR.
Percent Volatiles by Volume:NIL
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE OR CAN REACT WITH STRONG OXIDIZERS.
Stability Condition to Avoid:AVOID HEAT, SPARKS, AND FLAME.
Hazardous Decomposition Products:INCOMPLETE COMBUSTION MAY PRODUCE
CARBON MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:TREATMENT, STOR, TRANSPORTATION, & DISP MUST BE
I/A/W APPLIC FED, ST/PROVINCIAL, & LOC REGS. DO NOT FLUSH TO SURF
WATER/SANIT SEWER SYS. BY ITSELF, LIQ IS EXPECTED TO BE RCRA
IGNITABLE HAZ WASTE. CNTN R DISP:EMTPY DRUMS SHOULD BE
COMPLETELY(ING 23)
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:BRAYCOTE 610 (MIL-G-10924)
Preparer's Name:KAREL WRIGHT
CAGE:98308
DIV
CAGE:2R128
CAGE:98308
============= Composition/Information on Ingredients =============
Ingred Name:NON-HAZARDOUS INGREDIENTS (AS DESCRIBED BY MFR)
Fraction by Wt: 100%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE MODERATE IRRITATION TO EYES,
AND SLIGHT IRRITATIONTO SKIN. MAY CAUSE G/I IRRITATION.
MISTS/VAPORS UNLIKELY THROUGH CUSTOMARY HANDLING OR USE OF THIS
PRODUCT.
Explanation of Carcinogenicity:MANUFACTURER GAVE NO INFORMATION ABOUT
CARCINOGENICITY. HMIS DOES NOT EXPECT IT TO BE CARCINOGENIC.
Effects of Overexposure:EYE:IRRITATION, REDNESS, & TEARING.
SKIN:IRRITATION, DEFATTING, DERMATITIS, IF INJECTED IT CAN CAUSE
NECROSIS, & TISSUE DAMAGE. INGESTION:GASTROINTESTINAL IRRITATION,
NAUSEA, VOMITING, & DIARRHEA. INH ALATION:IRRITATION.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS MAY BE
AGGRAVATED.
======================= First Aid Measures =======================
First Aid:IF IRRITATION PERSISTS OR IS SEVERE, GET MEDICAL ATTENTION.
EYE:FLUSH W/WATER TO 15 MIN. SKIN:WASH W/SOAP & WATER. REMOVE
CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. INHALED:REMOVE FROM
EXPOSURE. AI D OR RESTORE BREATHING AS NEEDED. INGESTED:DO NOT
INDUCE VOMITING (ASPIRATION HAZARD). GIVE 1/2 PINT OF MILK OR WATER
TO DRINK. IF VOMITING, KEEP HEAD BELOW HIPS. GET IMMEDIATE MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:>200F,>93C
Extinguishing Media:DRY CHEMICAL, CO2, WATER FOG, & FOAM.
Fire Fighting Procedures:DON'T ENTER CONFINED FIRE SPACE W/OUT A NIOSH
APPROVED SELF-CONTAINED BREATHING APPARATUS. USE WATER AS FOG OR
SPRAY TO COOL FIRE EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:DON'T USE DIRECT STREAM OF WATER; WILL
FLOAT, & RE-IGNITE ON SURFACE OF WATER. WATER/FOAM MAY CAUSE
FROTHING WHICH CAN BE VIOLENT, IF SPRAYED INTO CONTAINER.
================== Accidental Release Measures ==================
Spill Release Procedures:SCOOP UP EXCESS GREASE. CLEAN AREA
W/APPROPRIATE CLEANER. STORE IN CLOSED METAL CONTAINER UNTIL
DISPOSAL.
Neutralizing Agent:MFR GAVE NO INFORMATION ON MSDS.
======================Handling and Storage ======================
Handling and Storage Precautions:MAINTAIN AMBIENT TEMPERATURES. KEEP
CONTAINER TIGHTLY CLOSED. DON'T STORE NEAR HEAT, FLAME, & STRONG
OXIDANTS. MAINTAIN ADEQUATE VENTILATION.
Other Precautions:AVOID BREATHING VAPORS, MISTS, & FUMES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NORMALLY REQUIRED.
Ventilation:VENTILATION:NOT NORMALLY REQUIRED. LOCAL EXHAUST:IN
ADDITION TO GENERAL VENTILATION MAY BE USED.
Other Protective Equipment:NORMAL WORK CLOTHING
Work Hygienic Practices:DO NOT WEAR CONTAMINATED CLOTHING. LAUNDER
BEFORE REUSE OR DISCARD.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:V6
NRC/State Lic Num:NONE
Boiling Pt:B.P. Text:>450F,>232C
Vapor Density:>1
Spec Gravity:<1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BROWN GREASE W/SLIGHT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, OPEN FLAME.
Hazardous Decomposition Products:A COMPLEX MIXTURE OF AIRBORNE, SOLID,
LIQUID PARTICULATE, GASES, CO, OXIDES OF ZINC, CALCIUM, & VARIOUS
HYDROCARBONS.
==================== Disposal Considerations ====================
Waste Disposal Methods:ALL RECOVERED MATERIAL SHOULD BE PACKAGED,
LABELLED, TRANSPORTED, & DISPOSED OF IN ACCORDANCE W/LOCAL, STATE,
& FEDERAL REGULATIONS REGARDING HEALTH, AIR, & WATER POLLUTION. IF
PERMITTED, MAY BE DEPOS ITED IN AN APPROVED LANDFILL.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:PERCHLOROETHYLENE
CAGE:1B635
CAGE:1B635
============= Composition/Information on Ingredients =============
Ingred Name:PERCHLOROETHYLENE (TETRACHLOROETHYLENE) (SARA III)
CAS:127-18-4
RTECS #:KX3850000
Fraction by Wt: 100%
OSHA PEL:100 PPM
ACGIH TLV:25PPM/100,A3 STEL;94
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SEE SIGNS & SYMPTOMS OF OVEREXPOSURE.
Explanation of Carcinogenicity:PERCHLOROETHYLENE HAS BEEN PROPOSED FOR
ADDITION IN THE 5TH ANNUAL REPORT ON CARCINOGEN BY NTP.
Effects of Overexposure:EYES:MILDLY IRRITATING;SKIN:BURNING
SENSATION,MILDLY IRRITATING.MAY CAUSE SLIGHT DERMATITIS & DEFATTING
OF
SKIN;INHALATION:LIGHT-HEADEDNESS,DIZZINESS,HEADACHE,VERTIGO,DROWSIN
ESS,NARCOSIS,UNCONSCIOUSNE SS & EVEN DEATH;INGESTION:UNLIKELY
ROUTE.INGESTION OF SMALL QUANTITIES IS NOT LIKELY TO BE TOXIC.
Medical Cond Aggravated by Exposure:NONE NOTED.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH WITH WATER FOR 15 MINUTES;SKIN:REMOVE CONTAMINATED
CLOTHING & FLUSH EXPOSED AREAS WITH WATER FOR 5 TO 15
MINUTES;INHALATION:REMOVE TO FRESH AIR.GIVE CPR/OXYGEN IF
NEEDED;INGESTION:DO NOT IN DUCE VOMITING.SEE DOCTOR.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:1256F
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR SCBA.
Unusual Fire/Explosion Hazard:HIGH INTENSITY HEAT SOURCE WILL CAUSE
FORMATION OF HCL. VAPORS ARE HEAVIER THAN AIR AND WILL COLLECT IN
LOW AREAS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA,VENTILATE,AVOID BREATHING
VAPORS.WEAR SCBA & PROTECTIVE CLOTHING.ABSORB IN INERT MATERIAL &
TRANSFER TO APPROPRIATE DISPOSAL CONTAINER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
PLACE.KEEP CONTAINERS CLOSED. PREVENT MOISTURE FROM ENTERING
STORAGE AREA.
Other Precautions:NO SMOKING IN PRESENCE OF AIR.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED WHEN USED WITH ADEQUATE
VENTILATION.
Ventilation:MECHANICAL (GENERAL) TO KEEP UNDER TLV.
Other Protective Equipment:PROTECTIVE HEADGEAR AND APRON WHEN SPLASHING
IS A PROBLEM.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.REMOVE AND
LAUNDER CONTAMINATED CLOTHING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:T4
Boiling Pt:B.P. Text:250F(121C)
Vapor Pres:13
Vapor Density:5.8
Spec Gravity:1.6
Evaporation Rate & Reference:0.09 (ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS,CLEAR LIQUID. MILDLY SWEET ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES,OXIDIZING MATERIALS.
Stability Condition to Avoid:HEAT,SPARKS,OPEN FLAMES.
Hazardous Decomposition Products:HCL,PHOSGENE (SMALL AMOUNTS)
==================== Disposal Considerations ====================
Waste Disposal Methods:RECOVERED LIQUIDS MAY BE SENT TO A LICENSED
RECLAIMER OR INCINERATED.CONTAMINATED ABSORBENT MATERIAL MUST BE
DISPOSED OF IN A PERMITTED WASTE MANAGEMENT FACILITY.CONSULT
FEDERAL,STATE OR LOCAL DISPOSA L AUTHORITIES FOR APPROVED
PROCEDURES.
| 0 | eyes_protection_not_mandatory |
===================== Product Identification =====================
Product ID:STOPYT LIQUID 62A
CAGE:64972
CAGE:64972
============= Composition/Information on Ingredients =============
Ingred Name:ALPHA-ALUMINA; (ALUMINUM OXIDE), (EPA LISTS ONLY FIBROUS
FORMS) (SARA III)
CAS:1344-28-1
RTECS #:BD1200000
OSHA PEL:10 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:YITTRIUM OXIDE
CAS:1314-36-9
RTECS #:ZG3850000
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Ingred Name:ISOPROPYL ALCOHOL; (ISOPROPANOL) (SARA III). FL
PT:53F,11.7C. FL PT METH:COC. LEL:2% UEL:12%.
CAS:67-63-0
RTECS #:NT8050000
OSHA PEL:400 PPM;500 PPM STEL
ACGIH TLV:400 PPM;500 PPM STEL
Ingred Name:DI-SEC-OCTYL PHTHALATE; (DI-2-ETHYLHEXYL-PHTHALATE) (SARA
III). FL PT:425F,218C. FL PT METH:COC. LEL:0.3%.
CAS:117-81-7
RTECS #:TI0350000
OSHA PEL:5 MG/M3;10 STEL
ACGIH TLV:5 MG/M3
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:METHYL ISOBUTYL KETONE (MIBK) (SARA III). FLASH POINT:
73F,22.8C. FLASH POINT METHOD: TCC.
CAS:108-10-1
RTECS #:SA9275000
OSHA PEL:50 PPM; 75 PPM STEL
ACGIH TLV:50 PPM; 75 PPM STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHAL:ALUMINA IRRITS RESP TRACT.
EMPHASEMA HAS BEEN REPORTED W/YITTRIUM OXIDE INHAL. BRTHG
DI(2-ETHYLHEXYL) PHTHALATE, IPA & MIBK CAN CAUSE NAUS, IRRIT, DIZZ
& HDCHS. IPA & MIBK AT HIGH AIR LEVELS MAYCAUSE UNCON. SKIN:DEFAT
& IRRIT - IPA & MIBK CAN BE ABSORBED THRU SKIN. EYE:STRONG IRRIT,
DMG POSS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:DI(2-ETHYLHEXYL) PHTHALATE:GP 2B (IARC
SUP7,P56,'87, LIVER CARCIN IN LAB ANMLS), ANTIC TO BE CARCIN (NTP
6TH... (SUPDAT)
Effects of Overexposure:HLTH HAZ:(DUE TO IPA). INGEST:SWALLOWING SM
AMTS (100 ML) OF IPA CAN BE FATAL. INGESTING LESSER AMTS CAN LEAD
TO NAUS, VOMIT, BLEEDING, CNS DEPRESS & PULM DMG. SWALLOWING MIBK
CUASES IRRIT & BURNING S ENSATION. DI(2-ETHYLHEXYL) PHTHALATE
CAUSES GI UPSETS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR. RESTORE & SUPPORT BREATHING AS
REQUIRED. GET IMMEDIATE MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED
CLOTHING. WASH EXPOSED SKIN W/SOAP & WATER. GET MEDICAL ATTENTION
IF IRRIT ATION PERSISTS. EYE:FLUSH, INCLUDING UNDER EYELIDS,
W/RUNNING WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGEST:GET MEDICAL ATTENTION IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:SEE INGS
Lower Limits:SEE INGS
Upper Limits:SEE INGS
Extinguishing Media:DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:MIBK IS A DANGEROUS FIRE HAZARD &
MODERATE EXPLOSION HAZARD WHEN EXPOSED TO HEAT OR FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:NOTIFY SAFETY PERSONNEL. REMOVE ALL SOURCES OF
IGNITION. CONTAIN SPILL W/ABSORBANT MATERIAL. THOSE INVOLVED IN
CLEAN-UP SHOULD WEAR PROTECTIVE EQUIPMENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:MAINTAIN GOOD HOUSEKEEPING & STORAGE
AWAY FROM HOT SURFS, HEAT, FLAME & OXIDIZING AGENTS. AVOID
PRLNG/RPTD CONTACT W/LIQ & BRTHG MIST/VAPORS.
Other Precautions:DO NOT EAT/SMOKE IN AREAS WHERE THIS MATL IS
USED/STORED. DO NOT INGEST. PREPLACEMENT & ANNUAL PHYSICAL EXAMS
ARE REC IN AREAS OF EXCESS EXPOS W/ATTN TO POSS PERIPHERAL
NEUROPATHIES & RESP SYSTEMS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE AN APPROPRIATE NIOSH/MSHA APPROVED
RESPIRATOR IF AIRBORNE MIST/FUME/VAPOR CONCENTRATIONS EXCEED THE
APPROPRIATE PEL OR TLV. ALL APPROPRIATE REQUIREMENTS SET FORTH IN
29 CFR 1910.134 SHOULD BE MET.
Ventilation:PROVIDE SUFFICIENT GEN & LOC EXHST VENT TO MAINTAIN AIR
CONCS OF VAPS BELOW PEL & TLV. IF SUCH VENT IS UNAVAIL (SUPDAT)
Other Protective Equipment:EYEWASH FOUNTAINS SHOULD BE READILY
AVAILABLE TO AREAS OF USE & HANDLING.
Work Hygienic Practices:CONT LENSES POSE A SPECIAL HAZ; SOFT LENSES MAY
ABSORB & ALL LENSES CONCENTRATE IRRITS. WASH EXPOSED SKIN AREAS
(SUPDAT)
Supplemental Safety and Health
SPEC GRAV:0.8-0.92 (H*2O=1). VENT:USE NIOSH/MSHA APPROVED RESPIRATORS
AS SPECIFIED ABOVE. HYGIENE PRACT:AFTER HANDLING. CARCIN COMMENTS:
ANNUAL REPORT, 1991 .
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>180F,>82C
Vapor Pres:1.3-33
Vapor Density:2.07-13.5
Spec Gravity:SUPP DATA
Evaporation Rate & Reference:1.6-2.6 (VOLATILES)
Solubility in Water:INSOLUBLE
Appearance and Odor:OFF-WHITE LIQUID; ALCOHOL & KETONE ODOR.
Percent Volatiles by Volume:44-60
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS; POTASSIUM T-BUTOXIDE & OTHER STRONG OXIDIZERS.
Stability Condition to Avoid:HEAT & FLAME.
Hazardous Decomposition Products:CO, CO*2.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF I/A/W ALL APPLICABLE FEDERAL, STATE &
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ELMERS FILL'N FINISH WOOD FILLER-TAN, E837
CAGE:07982
CAGE:86142
CAGE:07982
============= Composition/Information on Ingredients =============
Ingred Name:MAGNESIUM CARBONATE (MGCO3)
CAS:546-93-0
RTECS #:OM2470000
Fraction by Wt: 1-5%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:LIMESTONE
CAS:1317-65-3
RTECS #:EV9580000
Fraction by Wt: 30-50%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:KAOLIN
CAS:1332-58-7
RTECS #:GF1670500
Fraction by Wt: 1-5%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:2 MG/M3 TDUST
Ingred Name:TALC
CAS:14807-96-6
RTECS #:WW2710000
Fraction by Wt: 5-10%
OSHA PEL:20 MPPCF Z-3
ACGIH TLV:2 MG/M3 RDUST
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: SKIN ABSORPTION: NOT TOX
DERMALLY WHEN TESTED AS DESCRIBED IN 16 CFR PART 1500.3 (C) (1) &
(2). INGEST: NOT TOX ORALLY WHEN TESTED AS DESCRIBED IN 16 CFR PART
1500.3 (C) (1) & (2). INHAL: NOT E XPECTED TO BE HARMFUL UNDER NORM
CNDTNSOF USE. HOWEVER, IF ALLOWED TO BECOME AIRBORNE, MAY CAUSE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: IRRIT OF NOSE, THROAT & LUNGS. NOT
TOX BY INHAL WHEN TESTED AS DESCRIBED IN 16 CFR PART 1500.3 (C) (1)
& (2). SKIN CONT: NOT AN IRRITANT WHEN TESTED AS DESCRIBED IN 16
CFR PART 1500.41. EYES : NOT AN IRRITANT WHEN TESTED AS DESCRIBED
IN 16 CFR PART 1500.42. LIMESTONE/TALC: CAN CAUSE LUNG DAMAGE.
Medical Cond Aggravated by Exposure:LIMESTONE/TALC: PREEXISTING
RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE.
======================= First Aid Measures =======================
First Aid:INGESTION: IF ACCIDENTLY SWALLOWED, DILUTE BY DRINKING LARGE
QUANTITIES OF WATER. IMMEDIATELY CONTACT POISON CONTROL CENTER OR
HOSPITAL EMERGENCY ROOM FOR ANY OTHER ADDITIONAL TREATMENT
DIRECTIONS. IN HALATION: REMOVE TO FRESH AIR. EYES: IMMEDIATELY
FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CALL MD IF
IRRITATION PERSISTS. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. SEE
MD .
===================== Fire Fighting Measures =====================
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . WATER SHOULD BE USED TO KEEP FIRE-EXPOSED CONTAINERS
COOL.
Unusual Fire/Explosion Hazard:WILL NOT BURN UNLESS WATER HAS
EVAPORATED.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP (SCOOP) UP AND REMOVE TO A CHEMICAL
DISPOSAL AREA. PREVENT ENTRY INTO NATURAL BODIES OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP FROM FREEZING. STORE IN A COOL,
DRY PLACE. KEEP CONTAINERS TIGHTLY CLOSED. AVOID PROLONGED OR
REPEATED BREATHING OF VAPOR.
Other Precautions:HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND
SAFETY PRACTICES. THESE PRACTICES INCLUDE AVOIDING UNNECESSARY
EXPOSURE AND REMOVAL OF THE MATERIAL FROM EYES, SKIN AND CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:IF AIRBORNE CONTAMINANTS ARE GENERATED WHEN MATL IS
HEATED/HANDLED, SUFFICIENT VENT IN VOL & AIR FLOW PATTERNS (SUP
DAT)
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
VENT: SHOULD BE PROVIDED TO KEEP AIR CONTAMINANT CONCENTRATION LEVELS
BELOW ACCEPTABLE CRITERIA.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F,100C
Vapor Pres:17.5 @ 20C
Vapor Density:<1
Spec Gravity:0.84
pH:9.6
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:DISPERSIBLE
Appearance and Odor:TAN PASTE WITH MILD ACRYLIC ODOR.
Percent Volatiles by Volume:27
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN TO BORDEN.
Stability Condition to Avoid:NORMALLY STABLE AS DEFINED IN NFPA
704-12(4-3.1).
Hazardous Decomposition Products:OXIDES OF CARBON.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL, STATE, AND
FEDERAL REQUIREMENTS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:2-CYANOETHYL N,N-DIISOPROPYLCHLORO- (SUPP D
CAGE:60928
CAGE:60928
============= Composition/Information on Ingredients =============
Ingred Name:2-CYANOETHYL N,N-DIISOPROPYLCHLORO- PHOSPHORAMIDITE
CAS:89992-70-1
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED, INHALED
OR ABSORBED THRU SKIN. MATL IS EXTREMELY DESTRUCT TO TISS OF MUC
MEMB & UPPER RESP TRACT, EYES & SKIN. INHAL MAY BE FATAL AS A RSLT
OF SPASM, INFLAMM & EDEMA OF LA RYNX & BRONCHI, CHEMICAL
PNEUMONITIS & PULM EDEMA. SYMPS OF EXPOS MAY INCL BURNING
SENSATION, COUGHING,(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:WHEEZING, LARYNGITIS, SHORTNESS OF
BREATH, HEADACHE, NAUSEA & VOMITING.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES/SKIN:IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR AT
LEAST 15 MINS WHILE REMOVING CONTAMINATED CLOTHING & SHOES. ASSURE
ADEQUATE FLUSHING OF EYES BY SEPARATING EYELIDS W/FINGERS. DISCARD
CONT AMINATED CLOTHING & SHOES. INHAL:REMOVETO FRESH AIR. IF NOT
BREATHING, GIVE ARTF RESP. IF BRTHG IS DIFFICULT, GIVE OXYGEN.
INGEST:WASH OUT MOUTH W/WATER PROVIDED PERSON IS CONSCIOUS. CALL
MD.
===================== Fire Fighting Measures =====================
Flash Point:>230F,>110C
Extinguishing Media:WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . PREVENT CONTACT W/SKIN & EYES. USE WATER
SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:MAY EXPLODE WHEN HEATED. EMITS TOXIC
FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVAC AREA. SHUT OFF ALL SOURCES OF IGNIT. WEAR
W/DRY-LIME, SAND OR SODA ASH. PLACE IN COVERED CONTR USING
NON-SPARKING TOOLS & TRANSPORT OUT DOORS. VENT AREA & WASH SPILL
SITE AFTER (SUP DAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:FREEZE. HANDLE & STORE UNDER NITROGEN.
KEEP AWAY FROM COMBUSTIBLE MATERIALS, HEAT, SPARKS & OPEN FLAME.
MOISTURE SENSITIVE. KEEP TIGHTLY CLOSED.
Other Precautions:CORROSIVE. DO NOT BREATHE VAPOR. DO NOT GET IN EYES,
ON SKIN OR ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER & EYE
BATH.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MFRS TRADE NAME/PART NO:PHOSPHORAMIDITE, 30230-9. HAZ DECOMP PROD:OF
PHOSPHORUS OXIDES &/OR PHOSPHINE. SPILL PROC:MATERIAL PICKUP IS
COMPLETE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>217F,>103C
Spec Gravity:1.061
Appearance and Odor:CLEAR TO SLIGHTLY HAZY COLORLESS LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG BASES & ALCOHOLS.
Stability Condition to Avoid:HEAT-SENSITIVE. READILY HYDROLYZED.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
NITROGEN OXIDES & HYDROGEN CHLORIDE GAS. THERMAL DECOMP MAY PRDCE
TOX FUMES (SUP DAT)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL W/A COMBUSTIBLE
SOLVENT & BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN AFTERBURNER
& SCRUBBER. OBSERVE ALL FEDERAL, STATE & LOCAL ENVIRONMENTAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SS26620, SODIUM HYDROXIDE SOLUTION 0.02N TO 2N
Resp. Party Other MSDS Num.:REV: #4
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM HYDROXIDE
CAS:1310-73-2
RTECS #:WB4900000
Minumum % Wt:.08
Maxumum % Wt:8.
OSHA PEL:2 MG/M3
ACGIH TLV:NONE ESTABLISHED
ACGIH STEL:C2 MG/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:99.
Maxumum % Wt:99.6
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL, RAT LD50: 90 ML/KG.
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: CAUSES BURNS. MAY CAUSE CHEMICAL
CONJUNCTIVITIS & CORNEAL DAMAGE. SKIN: CAUSES BURNS. MAY CAUSE
DEEP, PENETRATING ULCERS. MAY CAUSE RASH, COLD & CLAMMY SKIN WITH
CYANOSIS OR PALE COLOR. INGESTION : MAY CAUSE SEVERE & PERMANENT
DAMAGE TO THE DIGESTIVE TRACT. CAUSES GASTROINTESTINAL TRACT BURNS.
MAY CAUSE PERFORATION OF THE DIGESTIVE TRACT. CAUSES SEVERE PAIN,
NAUSEA, VOMITING, DIARRHEA & SHOCK. MAY CAUSE SYSTEMIC EFFECTS.
INHALATION: IRRITATION MAY LEAD TO CHEMICAL PNEUMONITIS & PULMONARY
EDEMA. CAUSES SEVERE IRRITATION OF UPPER RESPIRATORY TRACT WITH
COUGHING, BURNS, POSSIBLE SYSTEMIC EFFE CTS. (SEE OTHER)
Explanation of Carcinogenicity:SODIUM HYDROXIDE: NOT LISTED BY ACGIH,
IARC, NIOSH, NTP OR OSHA. WATER: NOT LISTED BY ACGIH, IARC, NIOSH,
NTP OR OSHA.
Effects of Overexposure:EYE: CAUSES EYE BURNS. MAY CAUSE CHEMICAL
CONJUNCTIVITIS AND CORNEAL DAMAGE. SKIN: CAUSES SKIN BURNS. MAY
CAUSE DEEP, PENETRATING ULCERS OF THE SKIN. MAY CAUSE SKIN RASH (IN
MILDER CASES). AND COLD AN D CLAMMY SKIN WITH CYANOSIS OR PALE
COLOR. INGESTION: MAY CAUSE SEVERE AND PERMANENT DAMAGE TO THE
DIGESTIVE TRACT. CAUSES GASTROINTESTINAL TRACT BURNS. MAY CAUSE
PERFORATION OF THE DIGESTIVE TRACT. C AUSES SEVERE PAIN, NAUSEA,
VOMITING, DIARRHEA, AND SHOCK. MAY CAUSE SYSTEMIC EFFECTS.
INHALATION: IRRITATION MAY LEAD TO CHEMICAL PNEUMONITIS AND
PULMONARY EDEMA. CAUSES SEVERE IRRITATION OF UPPER RES PIRATORY
TRACT WITH COUGHING, BURNS,
Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY MANUFACTURER
======================= First Aid Measures =======================
First Aid:EYES: GET MEDICAL AID IMMEDIATELY. DO NOT ALLOW VICTIM TO RUB
OR KEEP EYES CLOSED. EXTENSIVE IRRIGATION (AT LEAST 30 MINUTES).
SKIN: GET MEDICAL AID IMMEDIATELY. IMMEDIATELY FLUSH SKIN WITH
PLENTY OF SOAP AND WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE REUSE.
DISCARD CONTAMINATED CLOTHING IN A MANNER WHICH LIMITS FURTHER
EXPOSURE. INGESTION: D O NOT INDUCE VOMITING. IF VICTIM IS
CONSCIOUS AND ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL AID
IMMEDIATELY. INHALATION: GET MEDICAL AID IMMEDIATELY. REMOVE FROM
EXPOSURE.
===================== Fire Fighting Measures =====================
Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE,
OR WATER SPRAY. FOR LARGE FIRES, USE DRY CHEMICAL, CARBON DIOXIDE,
ALCOHOL-RESISTANT FOAM, OR WATER SPRAY.
Fire Fighting Procedures:DO NOT GET WATER INSIDE CONTAINERS. COOL
CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE
IS OUT. WEAR NIOSH/MSHA-APPROVED SCBA AND FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:DURING A FIRE, IRRITATING AND HIGHLY
TOXIC GASES MAY BE GENERATED BY THERMAL DECOMPOSITION. VAPOR MAY BE
HEAVIER THAN AIR. CONTACT WITH METALS MAY EVOLVE HIGHLY FLAMMABLE
HYDROGEN GAS. NON-COMBUSTIBL E.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB SPILL WITH INERT MATERIAL, (E.G., DRY
SAND OR EARTH), THEN PLACE INTO A CHEMICAL WASTE CONTAINER. AVOID
RUNOFF INTO STORM SEWERS AND DITCHES WHICH LEAD TO WATERWAYS. CLEAN
UP SPILLS IMMEDIATELY , OBSERVING PRECAUTIONS IN THE PROTECTIVE
EQUIPMENT SECTION. PROVIDE VENTILATION.
Neutralizing Agent:NO DATA PROVIDED BY MANUFACTURER DLA-HMIS: DILUTE
ACID SOLUTION.
======================Handling and Storage ======================
Handling and Storage Precautions:WASH THOROUGHLY AFTER HANDLING. USE
ONLY IN A WELL VENTILATED AREA. DO NOT BREATHE DUST, VAPOR, MIST,
OR GAS. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. KEEP CONTAINER
TIGHTLY CLOSED. DO NOT INGEST OR INHALE. DISCARD CONTAMINATED
SHOES. STORAGE: KEEP CONTAINER CLOSED WHEN NOT IN USE.
Other Precautions:STORE IN A COOL, DRY WELL-VENTILATED AREA AWAY FROM
INCOMPATIBLE SUBSTANCES. KEEP WAY FROM STRONG ACIDS. KEEP AWAY FROM
METALS. KEEP AWAY FROM FLAMMABLE LIQUIDS. KEEP AWAY FROM ORGANIC
HALOGENS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A RESPIRATORY PROTECTION PROGRAM THAT MEETS
OSHA'S 29 CFR :1910.134 AND ANSI Z88.2 REQUIREMENTS OR EUROPEAN
STANDARD EN 149 MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS
WARRANT A RESPIRATOR'S USE.
Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS
LOW.
Other Protective Equipment:WEAR APPROPRIATE PROTECTIVE CLOTHING TO
PREVENT SKIN EXPOSURE. FACILITIES STORING OR UTILIZING THIS
MATERIAL SHOULD BE EQUIPPED WITH AN EYEWASH FACILITY AND A SAFETY
SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING
Supplemental Safety and Health
SYNONYMS: CAUSTIC SODA: SODA LYE: SODIUM HYDRATE.
================== Physical/Chemical Properties ==================
HCC:B1
Boiling Pt:=100.C, 212.F
Melt/Freeze Pt:=0.C, 32.F
Vapor Pres:14 MM HG
Vapor Density:1.0
Spec Gravity:1.0
pH:ALKALINE
Viscosity:1 (ETHER=1)
Solubility in Water:COMPLETELY SOLUBLE IN WAT
Appearance and Odor:CLEAR LIQUID NO ODOR REPORTED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
INCOMPATIBILITIES WITH OTHER MATERIALS: STRONG BASES, STRONG OXIDIZING
AGENTS, STRONG REDUCING AGENTS, METALS.
Stability Condition to Avoid:INCOMPATIBLE MATERIALS, ACIDS.
Hazardous Decomposition Products:TOXIC FUMES OF SODIUM OXIDE, SODIUM
PEROXIDE FUMES.
=================== Toxicological Information===================
Toxicological Information:EPIDEMIOLOGY: NO INFORMATION FOUND.
TERATOGENICITY: NO INFORMATION FOUND. REPRODUCTIVE EFFECTS: NO
INFORMATION FOUND. NEUROTOXICITY: NO INFORMATION FOUND.
MUTAGENICITY: NO INFORMATION FOUND. OTHER STU DIES: SEE ACTUAL
ENTRY IN RTECS FOR COMPLETE INFORMATION.
===================== Ecological Information =====================
Ecological:ECOTOXICITY: NOT AVAILABLE. ENVIRONMENTAL FATE: NOT
AVAILABLE. PHYSICAL/CHEMICAL: NOT AVAILABLE. OTHER: NOT AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:US DOT: SHIPPING NAME: SODIUM HYDROXIDE,
SOLUTION. HAZARD CLASS: 8. UN NUMBER: UN1824. PACKING GROUP: II.
CANADIAN TDG: SHIPPING NAME: SODIUM HYDROXIDE, SOLUTION. HAZARD
CLASS: 8 (9.2). UN NUMBER: UN1 824.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ): CAS# 1310-73-2, FINAL RQ:
1000 LBS 9454 KG). SECTION 302 (TPQ): NONE OF THE CHEMICALS IN THIS
PRODUCT HAVE A TPQ. SARA CODES: 1310-73-2, ACUTE, REACTIVE. SECTION
313: NO CHEMICALS AR E REPORTABLE UNDER SECTION 313.
Federal Regulatory Information:TSCA: CAS 1310-73-2 IS LISTED ON THE
TSCA INVENTORY. CAS 7732-18-5 IS LISTED ON THE TSCA INVENTORY.
CHEMICAL TEST RULES: NONE OF THE CHEMICALS IN THIS PRODUCT ARE
UNDER A CHEMICAL TEST RULE. HEALTH & SAFETY REPORTING LIST: NONE
OF THE CHEMICALS IN THIS PRODUCT ARE ON THE HEALTH & SAFETY
REPORTING LIST. SECTION 12B: NONE OF THE CHEMICALS IN THIS PRODUCT
ARE LISTED UNDER 12B. TSCA SIGNIFIGANT NEW US E RULE: NONE OF THE
CHEMICALS IN THIS PRODUCT HAVE A SNUR UNDER TSCA. CLEAN AIR ACT:
THIS PRODUCT DO ES NOT CONTAIN ANY HAZARDOUS AIR POLLUTANTS, CLASS
1 0R 2 OZONE DEPLETORS.
State Regulatory Information:SODIUM HYDROXIDE CAN BE FOUND ON THE
FOLLOWING STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY,
FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. CALIFORNIA NO
SIGNIFIGANT REISK LEVEL: NONE OF THE CH EMICALS IN THIS PRODUCT ARE
LISTED.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
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