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Long-range hydrodynamics between colloidal particles or fibers is modelled by the Fluid Particle Model. Two methods are considered to impose the fluid boundary conditions at colloidal surfaces. |
We investigate numerically the irreversible aggregation of patchy spherical colloids on a flat substrate. We consider $n$-patch particles and characterize the dependence of the irreversible aggregation kinetics on $n$. |
In the last two years we have witnessed the exciting experimental discovery of soft matter with nontrivial quasiperiodic long-range order - a new form of matter termed a soft quasicrystal. Two groups have independently discovered such order in soft matter: Zeng et al. |
Although the stretching of polymers and biomolecules is important in numerous settings, their response when confined to two-dimensions is relatively poorly-studied. In this paper, we derive closed-form analytical expressions for the two-dimensional force-extension response of a freely-jointed chain under force control... |
Phase behavior of large three-dimensional complex plasma systems under microgravity conditions onboard the International Space Station is investigated. The neutral gas pressure is used as a control parameter to trigger phase changes. |
In viscous particulate liquids, such as suspensions and polymer solutions, the large-distance steady-state flow due to a local disturbance is commonly described in terms of hydrodynamic screening -- beyond a correlation length $\xi$ the response drops from that of the pure solvent, characterized by its viscosity $\eta_... |
We analyze the stress tensor and the gyration tensor of an unentangled polymer melt under flow by using a Rouse-type single chain model. We employ the bead-spring type single chain model, in which beads interact each other via nonlinear potentials such as the finite-extensible nonlinear elasticity (FENE) potential. |
Despite many attempts, ordered equilibrium microphases have yet to be obtained in experimental colloidal suspensions. The recent computation of the equilibrium phase diagram of a microscopic, particle-based microphase former [Zhuang et al., Phys. Rev. Lett. 116, 098301 (2016)] has nonetheless found such mesoscale asse... |
To better understand lipid membranes in living organisms, the study of intermolecular forces using the osmotic pressure technique applied to model lipid membranes has constituted the ground knowledge in the field of biophysics since four decades. However, the study of intermolecular forces in lipid systems other than ... |
The swelling equilibrium of Olympic gels, which are composed of entangled cyclic polymers, is studied by Monte Carlo Simulations. In contrast to chemically crosslinked polymer networks, we observe that Olympic gels made of chains with a \emph{larger} degree of polymerization, $N$, exhibit a \emph{smaller} equilibrium ... |
There is increasing evidence that entropy can induce microphase separation in binary fluid mixtures interacting through hard particle potentials. One such phase consists of alternating two dimensional liquid-like layers of rods and spheres. |
We review and compare the Born-Huang and the Lemaitre-Maloney's theories that lead to analytical expressions for elastic constants, accounting for affine and nonaffine deformations in a lattice. The Born-Huang method is based on Helmholtz energy while the Lemaitre-Maloney's formalism focus on Gibbs force. |
We identify configurational phases and structural transitions in a polymer nanotube composite by means of machine learning. We employ various unsupervised dimensionality reduction methods, conventional neural networks, as well as the confusion method, an unsupervised neural-network-based approach. |
We study a dynamical curvature instability caused by a local chemical modification of a phospholipid membrane. In our experiments, a basic solution is microinjected close to a giant unilamellar vesicle, which induces a local chemical modification of some lipids in the external monolayer of the membrane. |
The interfacial free energy is a central quantity in crystallization from the meta-stable melt. In suspensions of charged colloidal spheres, nucleation and growth kinetics can be accurately measured from optical experiments. |
We study theoretically the temporal evolution and the spatial structure of the interface between two polymer melts involving three different species (A, A* and B). The first melt is composed of two different polymer species A and A* which are fairly indifferent to one another (Flory parameter chi_AA* ~ 0). |
The flow of frictionless granular particles is studied with stress-controlled discrete element modeling simulations for systems varying in size from 300 to 100,000 particles. The volume fraction and shear stress ratio $\mu$ are relatively insensitive to system size fo a wide range of inertial numbers $I$. |
Pattern formation of a thin layer of vertically agitated wet granular matter is investigated experimentally. Rotating spirals with three arms, which correspond to the kinks between regions with different colliding phases, are the dominating pattern. |
As an extension of the former study on 2-dimensional systems, we simulate phase behavior of polymer-grafted colloidal particles in 3 dimensions by molecular Monte Carlo technique in the canonical ensemble. We use a spherically symmetric square-step repulsive interaction potential, which has been obtained using self-co... |
We investigate the theoretical nonlinear response, Hessian stability, and possible wrinkling behaviour of a voltage-activated dielectric plate immersed in a tank filled with silicone oil. Fixed rigid electrodes are placed on the top and bottom of the tank, and an electric field is generated by a potential difference b... |
Metal--organic frameworks (MOFs), which possess a high degree of crystallinity and a large surface area with tunable inorganic nodes and organic linkers, exhibit high stimuli-responsiveness and molecular adsorption selectivity that enable various applications. The adsorption in MOFs changes the crystalline structure a... |
Glassy dynamics in a dense system of active particles with self-propulsion force $f_0$ and persistence time $\tau_p$ are crucial for many biological processes. Recent studies have shown that, unlike relaxation dynamics, dynamic heterogeneity (DH) in active glasses exhibits nontrivial behavior. |
Active matter systems being in a non-equilibrium state, exhibit complex behaviors such as self-organization and giving rise to emergent phenomena. There are many examples of active particles with biological origins, including bacteria and spermatozoa, or with artificial origins, such as self-propelled swimmers and Jan... |
We present coarse-grained simulation results for enhanced ion diffusion in a charged nanopore grafted with ionomer sidechains. The pore surface is hydrophobic and its diameter is varied from 2.0 nm to 3.7 nm. |
We present an extension of the multiparticle collision dynamics method for flows with complex interfaces, including supramolecular near-contact interactions mimicking the effect of surfactants. The new method is demonstrated for the case of |
Different advanced bridge function closures are utilized to investigate the structural and thermodynamic properties of dense Yukawa one-component plasma liquids within the framework of integral equation theory. The isomorph-based empirically modified hypernetted-chain, the variational modified hypernetted-chain, the R... |
We investigate the spatial dependence of the density of vibrated granular beds, using simulations based on a hybrid Monte Carlo algorithm. We find that the initial consolidation is typically inhmogeneous, both in the presence of a constant shaking intensity and when the granular bed is submitted to `annealed shaking&#... |
Field theories for complex systems traditionally focus on collective behaviors emerging from simple, reciprocal pairwise interaction rules. However, many natural and artificial systems exhibit behaviors driven by microscopic decision-making processes that introduce both nonreciprocity and many-body interactions, chall... |
We describe direct imaging measurements of a colloidal sphere's diffusion between two parallel surfaces. The dynamics of this deceptively simple hydrodynamically coupled system have proved difficult to analyze. |
The dynamics of multiple domain formation caused by the modulation instability of two-component Bose-Einstein condensates in an axially symmetric trap are studied by numerically integrating the coupled Gross-Pitaevskii equations. The modulation instability induced by the intercomponent mean-field coupling occurs in th... |
Many biological systems form colonies at high density. Passive granular systems will be jammed at such densities, yet for the survival of biological systems it is crucial that they are dynamic. |
An ideal nanofabrication method should allow the organization of nanoparticles and molecules with nanometric positional precision, stoichiometric control and well-defined orientation. The DNA origami technique has evolved into a highly versatile bottom-up nanofabrication methodology that fulfils almost all of these fe... |
Chemotactic interactions are ubiquitous in nature and can lead to nonreciprocal and complex emergent behavior in multibody systems. Here we show how chemotactic signaling between microscale oil droplets of different chemistries in micellar surfactant solutions can result in predator-prey-like chasing interactions. |
The dynamics of flexible polymer molecules are often assumed to be governed by hydrodynamics of the solvent. However there is considerable evidence that internal dissipation of a polymer contributes as well. |
We study the effect of fluids on the angle of repose and the segregation of granular matter poured into a silo. The experiments are conducted in two regimes where: |
We investigate the stability and geometrically non-linear dynamics of slender rods made of a linear isotropic poroelastic material. Dimensional reduction leads to the evolution equation for the shape of the poroelastica where, in addition to the usual terms for the bending of an elastic rod, we find a term that arises... |
We study the energy structure and the transfer of an extra electron or hole along periodic polymers made of $N$ monomers, with a repetition unit made of $P$ monomers, using a Tight-Binding wire model, where a site is a monomer (e.g., in DNA, a base pair), for $P$ even, and deal with two categories of such polymers: mad... |
Area per molecule in a DPPC-Cholesterol bilayers depends non-linearly on the cholesterol concentration. Using flexible strings model of lipid membranes we calculate area per molecule in DPPC-Cholesterol mixtures in the biologically relevant concentrations range. |
We extend the Cahn-Landau-de Gennes mean field theory of binary mixtures to understand the wetting thermodynamics of a three phase system, that is in contact with an external surface which prefers one of the phases. We model the system using a phenomenological free energy having three minima corresponding to low, inte... |
The dielectric response of supercooled liquids is phenomenologically modeled by a set of Asymmetric Double Wells (ADW), where each ADW contains a dynamical heterogeneity of $N_{corr}$ molecules. We find that the linear macroscopic susceptibility $\chi_1$ does not depend on $N_{corr}$ contrary to all higher order susce... |
When the time-reversal and parity symmetries in a fluid are broken, transverse transport coefficients can arise in response to perturbations, an example being odd viscosity. We refer to these systems as odd fluids. |
Liquid Crystalline Elastomers (LCEs) are active materials that are of interest due to their programmable response to various external stimuli such as light and heat. When exposed to these stimuli, the anisotropy in the response of the material is governed by the nematic director, which is a continuum parameter that is... |
We report on the response of a yield stress material, namely a colloidal gel made of attractive carbon black particles, submitted to large amplitude oscillatory shear stress (LAOStress). At a constant stress amplitude well below its apparent yield stress, the gel displays fatigue and progressively turns from an elasti... |
We analyze several continuum models of polymers: worm-like chains, ribbons and Fourier knots. We show that the torsion of worm-like chains diverges and conclude that such chains can not be described by the Frenet-Serret (FS) equation of space curves. |
The structural dynamics of ice in the freezing - thawing process has been studied in the context of the concept of two-phase water. It was previously shown that water is a two-phase system consisting of free and bound (liquid crystal) fractions. |
We report the statistical properties of spherical steel particles rolling on an inclined surface being driven by an oscillating wall. Strong dissipation occurs due to collisions between the particles and rolling and can be tuned by changing the number density. |
It is demonstrated that the Lindemann's criterion of melting can be formulated for two-dimensional classical solids using statistical mechanics arguments. With this formulation the expressions for the melting temperature are equivalent in three and two dimensions. |
The force field of optical tweezers is commonly assumed to be conservative, neglecting the complex action of the scattering force. Using a novel method that extracts local forces from trajectories of an optically trapped particle, we measure the three dimensional force field experienced by a Rayleigh particle with 10 ... |
To mimic the motion of biological swimmers in bodily fluids, a novel experimental system of micellar solubilization driven active droplets in a visco-elastic polymeric solution is presented. The visco-elastic nature of the medium, characterized by the Deborah number (De), is tuned by varying the surfactant (fuel) and ... |
We review recent progress in the theoretical description of anisotropic hard colloidal particles. The shapes considered range from rods and dumbbells to rounded cubes, polyhedra and to biaxial particles with arbitrary shape. |
Disks of two sizes are confined to a long and narrow channel. The axis and the plane of the channel are horizontal. |
Many cellular organelles are membrane-bound structures with complex membrane composition and shape. Their shapes have been observed to depend on the metabolic state of the organelle, and the mechanisms that couple biochemical pathways and membrane shape are still actively investigated. |
Shear stress is an important physical factor that regulates proliferation, migration and morphogenesis. In particular, the homeostasis of blood vessels is dependent on shear stress. |
We study the two-dimensional domain morphology of twisted nematic liquid crystals during their phase-ordering kinetics [R. A. L. Almeida, Phys. Rev. Lett. 131 (2023) 268101], which is a physical candidate to self-generate critical clusters in the percolation universality class. Here we present experimental evidence th... |
To describe many-particle systems suspended in incompressible low-Reynolds-number fluids, effective hydrodynamic interactions can be introduced. Here, we consider particles embedded in elastic media. |
Molecular Dynamics simulations of water molecules in nanometre sized cylindrical channels connecting two reservoirs show that the permeation of water is very sensitive to the channel radius and to electric polarization of the embedding material. At threshold, the permeation is {\emph{intermittent}} on a nanosecond tim... |
The functionality of adhesives relies on their response under the application of a load. Yet, it has remained a challenge to quantitatively relate the macroscopic dynamics of peeling to the dissipative processes inside the adhesive layer. |
We study a generic model for quorum-sensing bacteria in circular confinement. Every bacterium produces signaling molecules, the local concentration of which triggers a response when a certain threshold is reached. |
Self-propelled Brownian particles show rich out-of-equilibrium physics, for instance, the motility-induced phase separation (MIPS). While decades of studying the structure of liquids have established a deep understanding of passive systems, not much is known about correlations in active suspensions. |
Demixing of binary liquids is a ubiquitous transition, which is explained using a well-established thermodynamic formalism that requires equality of intensive thermodynamics parameters across the phase boundaries. Demixing transitions also occur when binary fluid mixtures are driven away from equilibrium, for example,... |
We investigate the mechanical response of packings of purely repulsive, frictionless disks to quasistatic deformations. The deformations include simple shear strain at constant packing fraction and at constant pressure, "polydispersity" strain (in which we change the particle size distribution) at constant pac... |
In this paper, we present the study of magnetorheological properties of magnetic fluids containing Co0.9Ni0.1 nanocluster that have been measured as a function of both magnetic field and temperature. Co-rich nanoclusters were synthesized by conventional homogeneous nucleation in liquid polyol. |
The dynamics of a quasi two-dimensional isotropic droplet in a cholesteric liquid crystal medium under symmetric shear flow is studied by lattice Boltzmann simulations. We consider a geometry in which the flow direction is along the axis of the cholesteric, as this setup exhibits a significant viscoelastic response to... |
We use a one dimensional symmetric exclusion model to study pressure and osmosis driven flows through molecular-sized channels, such as biological membrane channels and zeolite pores. Analytic expressions are found for the steady-state flow which show rich nonlinear behavior. |
Lipid bilayer membranes are the fundamental biological barriers that permit life. <br>The bilayer dynamics largely participates in orchestrating cellular workings and is characterized by substantial stability together with extreme plasticity that allows controlled morphological/topological changes. |
We propose a simple system of optically driven colloids that convert light into heat and move in response to self- and collectively- generated thermal gradients. We show that the system exhibits self-organization into a moving comet-like swarm and characterize the structure and response of the swarm to a light intensi... |
We provide a comprehensive presentation of the Hierarchical Reference Theory (HRT) in the smooth cut-off formulation. A simple and self-consistent derivation of the hierarchy of differential equations is supplemented by a comparison with the known sharp cut-off HRT. |
Boehmite, an aluminum oxide hydroxide $\gamma$-AlO(OH), is broadly used in the form of particulate dispersions in industrial applications, e.g., for the fabrication of ceramics and catalyst supports or as a binder for extrusion processes. Under acidic conditions, colloidal boehmite dispersions at rest form gels, i.e.,... |
We have developed a new model to describe FRET efficiency (E FRET) between freely-diffusing membrane probes in phase-separated bilayers (Finite Phase-separation FRET, or FP-FRET), that in principle applies to any system where phase domain dimensions are larger than ~Ro . Here we use Monte Carlo techniques to simulate ... |
We present a comprehensive study of water drops sliding down chemically heterogeneous surfaces formed by a periodic pattern of alternating hydrophobic and hydrophilic stripes. Drops are found to undergo a stick-slip motion whose average speed is an order of magnitude smaller than that measured on a homogeneous surface... |
Flow transport in confined spaces is ubiquitous in technological processes, ranging from separation and purification of pharmaceutical ingredients by microporous membranes and drug delivery in biomedical treatment to chemical and biomass conversion in catalyst-packed reactors and carbon dioxide sequestration. In this ... |
Nonlinear extensional flows are common in polymer processing but remain challenging theoretically because dramatic stretching of chains deforms the entanglement network far from equilibrium. Here, we present coarse-grained simulations of extensional flows in entangled polymer melts for Rouse-Weissenberg numbers $Wi_R=... |
The complex interactions underlying collective motion in biological systems give rise to emergent behaviours such as flocking, sorting, and cooperative transport. These dynamics often involve species with different motilities coordinating movement to optimize navigation and survival. |
I consider the ordering of dilute platelet additives when incorporated into an end-grafted polymer brush. The competition between wetting interactions and the anisotropic stress environment of the interior of the brush causes these platelet additives to either remain suspended at the outer edge of the brush laying fla... |
We have used ultracold atoms to characterize the magnetic field near the surface of copper conductors at room temperature carrying currents between 0.045 A and 2 A. In addition to the usual circular field we find an additional, 1000 - 10000 times smaller longitudinal field. The field changes its strength periodically ... |
We measure shear response in packings of glass beads by pulling a thin, rough, metal plate vertically through a bed of volume fraction phi, which is set, before the plate is pulled, in the range 0.575 to 0.628. The yield stress is velocity independent over 4 decades and increases exponentially with phi, with a transit... |
To evaluate the role of common substrates in the transmission of respiratory viruses, uniformly distributed microdroplets of artificial saliva were generated using an advanced inkjet printing technology to replicate the aerosol droplets, and subsequently deposited on five substrates, including glass, PTFE, stainless st... |
We study pairs of interacting self-avoiding walks on the 3d simple cubic lattice. They have a common origin and are allowed to overlap only at the same monomer position along the chain. |
In living cells, intrinsically disordered proteins (IDPs), such as FUS and DDX4, undergo phase separation, forming biomolecular condensates. Using molecular dynamics simulations, we investigate their behavior in their respective homogenous droplets. |
We use polydispersity in size as a control parameter to explore certain aspects of melting and freezing transitions in a system of Lennard-Jones spheres. Both analytical theory and computer simulations are employed to establish a potentially interesting relationship between observed terminal polydispersity in Lennard-... |
The elastic interactions between objects embedded in a nematic liquid crystal are usually caused by the average distorsion-rather than by the fluctuations-of the nematic orientational field. We argue that for sufficiently small particles, the nematic-mediated interaction originates purely from the fluctuations of the ... |
We suggest a simple method for measuring the temperature of ultra-cold gases made of fermions. We show that by using a two-photon Raman probe, it is possible to obtain lineshapes which reveal properties of the degenerate sample, notably its temperature $T$. |
The last half century of research into the structure, dynamics, and thermodynamics of simple liquids has revealed a number of approximate universalities. This paper argues that simple liquids' reduced-coordinate constant-potential-energy hypersurfaces constitute a quasiuniversal family of compact Riemannian manifo... |
The reflection of neutrons from a helium surface has been observed for the first time. The 4He surface is smoother in the superfluid state at 1.54 K than in the case of the normal liquid at 2.3 K. In the superfluid state we also observe a surface layer ~200 Angstroms thick which has a subtly different neutron scatteri... |
We experimentally study the motion of a colloidal particle, translated back and forth within a viscoelastic, i.e. non-Markovian bath. The particle starts in equilibrium before the forward motion, but only partially relaxes at the turning point. |
The charge distribution at the interface between two electrolytes is studied for the case of non-vanishing ion fluxes. The analysis is an extension of the established Verwey-Niessen theory to non-equilibrium situations. |
Polymers that extend covalently in two dimensions have attracted recent attention as a means of combining the mechanical strength and in-plane energy conduction of conventional two-dimensional (2D) materials with the low densities, synthetic processability, and organic composition of their one-dimensional counterparts.... |
Many models for complex phenomena use a model for strongly-interacting elements on a small scale to generate larger-scale simulations of some aspects of experimental realizations. These models may be agent-based (as in the case of discrete element method models for granular flow) or based on pattern-forming systems of... |
Discrete particle simulations are used to study the shear rheology of dense, stabilized, frictional particulate suspensions in a viscous liquid, toward development of a constitutive model for steady shear flows at arbitrary stress. These suspensions undergo increasingly strong continuous shear thickening (CST) as soli... |
We consider a fully directed self-avoiding walk model on a cubic lattice to mimic the conformations of an infinitely long confined flexible polymer chain; and the confinement condition is achieved by two parallel athermal plates. The confined polymer system is under good solvent condition and we revisit this problem t... |
We report molecular dynamics simulation results for two-component fluid mixtures of Gaussian-core particles, focusing on how tracer diffusivities and static pair correlations depend on temperature, particle concentration, and composition. At low particle concentrations, these systems behave like simple atomic mixtures... |
We report a first-principle study of the electronic and conduction properties of a quadruple-helix guanine wire (G4-wire), a DNA-derivative, with inner potassium ions. The analysis of the electronic structure highlights the presence of energy manifolds that are equivalent to the bands of (semi)conducting materials, an... |
In a contact density chain-growth study we investigate the solubility-temperature pseudo-phase diagram of a lattice polymer in a cavity with an attractive surface. In addition to the main phases of adsorbed and desorbed conformations we find numerous subphases of collapsed and expanded structures. |
Topological mechanical metamaterials have demonstrated exotic and robust mechanical properties which led to promising engineering applications. One of such properties is the focusing of stress at the interface connecting domains of topological Maxwell lattices of opposite topological polarizations, which protects the ... |
Based on renormalization group concepts and explicit mean field calculations we study the universal contribution to the effective force and torque acting on an ellipsoidal colloidal particle which is dissolved in a critical fluid and is close to a homogeneous planar substrate. At the same closest distance between the ... |
We study the hydrodynamics of a freely-standing smectic-A film in the isothermal, incompressible limit theoretically by analyzing the linearized hydrodynamic equations of motion with proper boundary conditions. The dynamic properties for the system can be obtained from the response functions for the free surfaces. |
A lattice model with soft repulsion followed by attraction is developed for a monolayer of hybrid core-shell particles self-assembling at an interface. The model is solved exactly in one dimension. |
In a recent article (Forterre, PRL, 2001), we have reported a new instability observed in rapid granular flows down inclined planes that leads to the spontaneous formation of longitudinal vortices. From the experimental observations, we have proposed an instability mechanism based on the coupling between the flow and ... |
Directed paths have been used extensively in the scientific literature as a model of a linear polymer. Such paths models in particular the conformational entropy of a linear polymer and the effects it has on the free energy. |
The curvature dependence of the surface tension is related to the excess equimolar radius of liquid drops, i.e., the deviation of the equimolar radius from that defined with the macroscopic capillarity approximation. Based on the Tolman [J. Chem. Phys. 17, 333 (1949)] approach and its interpretation by Nijmeijer et al... |
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