text large_stringlengths 7 3.02k |
|---|
Mixtures of nanoparticles and polymer-like objects are encountered in many nanotechnological applications and biological systems. We study the behavior of grafted polymer layers decorated by nanoparticles that are attracted to the polymers using lattice gas based mean field theory and accompanying coarse-grained Brown... |
We employ simulations of model proteins to study folding on rugged energy landscapes. We construct ``first-passage'' networks as the system transitions from unfolded to native states. |
The magnitude of the relative permittivity of the ferroelectric nematic phase (NF) is under a lively scientific discussion since the phase was recently discovered. Dielectric spectroscopy measurements (DSM) give a huge value of relative permittivity, which depends on the cell thickness, but this is argued to result fr... |
Formation of recirculating wakes is a prominent feature of inertial flow around bluff bodies. Below the onset of vortex shedding in uniform unbounded flows, the fluid in the recirculating wake region moves on closed planar orbits. |
Many embryonic deformations during development are the global result of local cell shape changes and other local active cell sheet deformations. Morphogenesis does not only therefore rely on the ability of the tissue to produce these active deformations, but also on the ability to regulate them in such a way as to ove... |
Pathogens in droplets on fomites and aerosols go through extreme physiochemical conditions, such as confinement and osmotic stress, due to evaporation. Still, these droplets are the predominant transmission routes of many contagious diseases. |
A theory of electrical transport through molecular wires is used to estimate the electronic factor in the intramolecular electron transfer (ET) in porphyrin-nitrobenzene supermolecules, and to analyze its structure. The chosen molecules have complex donor and acceptor configurations, and relatively simple structure of... |
We report a detailed simulation study of the phase behavior of core softened system with attractive well. Different repulsive shoulder widthes and attractive well depthes are considered which allows to monitor the influence of repulsive and attractive forces on the phase diagram of the system. |
Using angle-resolved synchrotron-radiation photoemission spectroscopy we have determined the dispersion of the valence bands of BeTe(100) along $\Gamma X$, i.e. the [100] direction. The measurements are analyzed with the aid of a first-principles calculation of the BeTe bulk band structure as well as of the photoemiss... |
The nonlinear elastic properties of nematic liquid crystals have acquired new interest with the recent experimental observation of bulk modulated nematic phases which are composed by achiral molecules. We extend the Oseen-Zocher-Frank's elastic theory for nematic liquid crystals by including gradients of the nemat... |
Anion exchange membranes are used in alkaline fuel cells and offer a promising alternative to the more expensive proton exchange membrane fuel cells. However, hydroxide ion conductivity in anion exchange membranes is low, and the quest for membranes with superior ion conductivity, mechanical robustness, and chemical s... |
Disordered granular packings share many similarities with supercooled liquids, particu-larly in the rapid increase of structural relaxation time within a narrow range of temperature or packing fraction. However, it is unclear whether the dynamics of granular materials align with those of their corresponding thermal ha... |
The use of glass for pharmaceutical new applications such as high-technology drugs, requires the strictest container inertness. A common theme of paramount importance in glass container integrity preservation is the detailed mechanism driving the sudden failure due the crack propagation. |
We show in simulations that a rich variety of novel orderings such as pinwheel and star states can be realized for colloidal molecular crystal mixtures at rational ratios of the number of colloids to the number of minima from an underlying periodic substrate. These states can have multi-step melting transitions and al... |
The influence of confinement, due to flat parallel structureless walls, on phase separation in colloid-polymer mixtures, is investigated by means of grand-canonical Monte Carlo simulations. Ultra-thin films, with thicknesses between $D=3-10$ colloid diameters, are studied. |
Dense, stabilized, frictional particulate suspensions in a viscous liquid undergo increasingly strong continuous shear thickening (CST) as the solid packing fraction, $\phi$, increases above a critical volume fraction, and discontinuous shear thickening (DST) is observed for even higher packing fractions. Recent studi... |
The dynamics of granular media in the jammed, glassy region is described in terms of "modes", by applying a Principal Component Analysis (PCA) to the covariance matrix of the position of individual grains. We first demonstrate that this description is justified and gives sensible results in a regime of time/de... |
A recently introduced stochastic model for fluid flow can be made Galilean invariant by introducing a random shift of the computational grid before collisions. This grid shifting procedure accelerates momentum transfer between cells and leads to a collisional contribution to transport coefficients. |
Cholesteric liquid crystals with helicoidal molecular architecture are known for their ability to selectively reflect light with the wavelength that is determined by the periodicity of molecular orientations. Here we demonstrate that by using a cholesteric with oblique helicoidal(heliconical) structure, as opposed to ... |
We have produced loose packings of cohesionless, frictional spheres by sequential deposition of highly-spherical, monodisperse particles through a fluid. By varying the properties of the fluid and the particles, we have identified the Stokes number (St) - rather than the buoyancy of the particles in the fluid - as the... |
In this work we incorporate some real-system effects into the theory of orientational phase transitions under shear flow (M. E. Cates and S. T. Milner, Phys. |
Liquid marbles, which are droplets coated with a hydrophobic powder, were exposed to a uniform electric field. It was established that a threshold value of the electric field, 15 cgse, should be surmounted for deformation of liquid marbles. |
Precise measuring the deforming force and observation of the deformation dynamics along with difficulties of micro sample preparation are the main problems which make the micro-scale experiments difficult. Here we present a method for direct observation and measurements of mechanical parameters of elastic microfibrils... |
We present experimental results on the shape of arches that block the outlet of a two dimensional silo. For a range of outlet sizes, we measure some properties of the arches such as the number of particles involved, the span, the aspect ratio, and the angles between mutually stabilizing particles. |
This paper, in French, describes a series of completely different behaviours of the mechanics of granular matter, which are obtained experimentally using periodic forcing at different amplitude, frequency and orientation. It starts with the problem of granular dissipative gas which has been investigated in micro-gravi... |
Guided by experiments contrasting electrically accelerated recovery with natural healing, this study formulates a model to investigate the importance of electroactive differential growth and morphological changes in tissue repair. It underscores the clinical potential of leveraging electroactive differential growth fo... |
We study the buckling of an idealized, semiflexible filament along whose contour magnetic moments are placed. {We give analytic expressions for the critical stiffness of the filament below which it buckles due to the magnetic compression. |
We define a model microswimmer with a variable cycle time, thus allowing the possibility of phase locking driven by hydrodynamic interactions between swimmers. We find that, for extensile or contractile swimmers, phase locking does occur, with the relative phase of the two swimmers being, in general, close to 0 or pi,... |
The effects of contact-line pinning are well-known in macroscopic systems, but are only just beginning to be explored at the microscale in colloidal suspensions. We use digital holography to capture the fast three-dimensional dynamics of micrometer-sized ellipsoids breaching an oil-water interface. |
We present a framework to segregate the roles of elastic and non-elastic deformations in the examination of real-space experiments of solid-solid Martensitic transitions. The Martensitic transformation of a body-centred-tetragonal(BCT) to a body-centred-orthorhombic(BCO) crystal structure has been studied in a model s... |
The interaction between water and ions within droplets plays a key role in the chemical reactivity of atmospheric and man-made aerosols. Here we report direct computational evidence that in supercooled aqueous nanodroplets a lower density core of tetrahedrally coordinated water expels the cosmotropic ions to the dense... |
It is well known that, at a macroscopic level, the boundary condition for a viscous fluid at a solid wall is one of "no-slip". The liquid velocity field vanishes at a fixed solid boundary. |
Eshelby's theory is the foundation of composite mechanics, allowing calculation of the effective elastic moduli of composites from a knowledge of their microstructure. However it ignores interfacial stress and only applies to very dilute composites -- i.e. where any inclusions are widely spaced apart. |
A theory of the propagation of acoustic waves in a porous medium filled with superfluid solution is developed. The elastic coefficients in the system of equations are expressed in terms of physically measurable quantities. |
We study in this work steady laminar flows in a low density granular gas modelled as a system of identical smooth hard spheres that collide inelastically. The system is excited by shear and temperature sources at the boundaries, which consist of two infinite parallel walls. |
We present a comprehensive investigation of polymer diffusion in the semidilute regime by fluorescence correlation spectroscopy (FCS) and dynamic light scattering (DLS). Using single-labeled polystyrene chains, FCS leads to the self-diffusion coefficient while DLS gives the cooperative diffusion coefficient for exactl... |
We report on the direct observation of an oscillating atomic current in a one-dimensional array of Josephson junctions realized with an atomic Bose-Einstein condensate. The array is created by a laser standing-wave, with the condensates trapped in the valleys of the periodic potential and weakly coupled by the inter-w... |
The two-dimensional pressure driven flow of non-Newtonian power-law fluids in self-affine fracture channels at finite Reynolds number is calculated. The channels have constant mean aperture and two values $\zeta$=0.5 and 0.8 of the Hurst exponent are considered. |
Colloidal dispersions of Laponite platelets are known to age slowly from viscous sols to colloidal glasses. We follow this aging process by monitoring the diffusion of probe particles embedded in the sample via dynamic light scattering. |
The observed magnetic tunability of light transmission through a ferrofluid can be effectively understood in terms of the inter-particle interaction that can be estimated from the magnetic and rheological properties of these fluids. The present study reports complementary magnetic and rheological measurements of aqueo... |
Electro-osmosis (EO) is a powerful tool to manipulate liquids in micro and nanofluidic systems. While EO has been studied extensively at liquid-solid interfaces, the case of liquid-vapor interfaces, found e.g. in foam films and bubbles, remains to be explored. |
We demonstrate that the configurational temperature formalism can be derived from the classical hypervirial theorem, and introduce a hierarchy of hyperconfigurational temperature definitions, which are particularly well suited for experimental studies. We then use these analytical tools to probe the electrostatic inte... |
Motivated by the centering of biological objects in large cells, we study the generic properties of centering forces inside a ball (or a volume of spherical topology) in $n$ dimensions. We consider two scenarios : autonomous centering (in which distance information is integrated from the agent perspective) and non-aut... |
We present a model improving the two-angle model for interphase chromatin (E2A model). This model takes into account the cylindrical shape of the histone octamers, the H1 histones in front of the nucleosomes and the vertical distance $d$ between the in and outgoing DNA strands. |
The fragility, that controls the temperature-dependent viscous properties of liquids as the glass transition is approached, in various glass-forming liquids with different atomic interactions and densities is investigated by molecular dynamic simulations. We show the landscape of fragility in purely repulsive systems ... |
Gene therapy is a promising tool for the treatment of various cancers but is hindered by the physico-chemical properties of siRNA and needs a suitable vector for the delivery of siRNA to the target tissue. Bile acid-based block copolymers offers certain advantages for the loading and delivery of siRNA since they can e... |
The separation of colloidal particles based solely on their surface properties is a highly challenging task. This study demonstrates that diffusiophoresis and diffusioosmosis enable the continuous separation of carboxylate polystyrene particles with similar sizes and zeta potentials but distinct surface concentrations... |
We use lattice Boltzmann simulations of the Beris--Edwards formulation of nematodynamics to probe the response of a nematic liquid crystal with conflicting anchoring at the boundaries under shear and Poiseuille flow. The geometry we focus on is that of the hybrid aligned nematic (HAN) cell, common in devices. |
Chemical structure has been long recognized to greatly influence polymer glass formation, but a general molecular theory that predicts how chemical structure determines the properties of glass-forming polymers has been slow to develop. While the generalized entropy theory (GET) explains the influence of various molecu... |
Kirigami tessellations, regular planar patterns formed by cutting flat, thin sheets, have attracted recent scientific interest for their rich geometries, surprising material properties and promise for technologies. Here we pose and solve the inverse problem of designing the number, size, and orientation of cuts that a... |
The formation of patterns and exotic nonequilibrium steady states in active-fluid systems continues to pose challenging problems -- theoretical, numerical, and experimental -- for statistical physicists and fluid dynamicists. We combine theoretical ideas from statistical mechanics and fluid mechanics to uncover a new ... |
The formation of domains via phase transitions is ubiquitous across physical systems from metallic alloys to biomolecular condensates in cells. We show that when the boundaries between such domains are forced to move, for example by external electrical fields or concentration gradients, this motion internally generate... |
We formulate and apply a continuum model that incorporates elasticity, yield stress, plasticity and viscous drag. It is motivated by the two-dimensional foam rheology experiments of Debregeas et al. |
We develop a continuum elastic approach to examining the bending mechanics of semiflexible filaments with a local internal degree of freedom that couples to the bending modulus. We apply this model to study the nonlinear mechanics of a double stranded DNA oligomer (shorter than its thermal persistence length) whose fr... |
Protein aggregation is of great importance in biology, e.g., in amyloid fibrillation. The aggregation processes that occur at the cellular scale must be highly stochastic in nature because of the statistical number fluctuations that arise on account of the small system size at the cellular scale. |
Chiral active fluids break both time-reversal and parity symmetry, leading to exotic transport phenomena unobservable in ordinary passive fluids. We develop a generalized Green-Kubo relation for the anomalous lift experienced by a passive tracer suspended in a two-dimensional chiral active fluid subjected to an applie... |
We investigated experimentally the magneto-optical and dielectric properties of magnetic-nanoparticle-doped nematic liquid crystals (ferronematics). Our studies focus on the effect of the very small orienting bias magnetic field $B_{bias}$, and that of the nematic director pretilt at the boundary surfaces in our syste... |
The adsorption of flexible and highly charged polyelectrolytes onto oppositely charged planar surfaces is investigated by means of Monte Carlo simulations. The effect of image forces stemming from the dielectric discontinuity at the substrate interface is considered. |
Multivalent particles competing for binding on the same surface can exhibit switch-like behaviour, depending on the concentration of receptors on the surface. When the receptor concentration is low, energy dominates the free energy of binding, and particles having a small number of strongly-binding ligands preferentia... |
We investigate the origin of the deviations from the classical Darcy law by numerical simulation of the Navier-Stokes equations in two-dimensional disordered porous media. We apply the Forchheimer equation as a phenomenological model to correlate the variations of the friction factor for different porosities and flow ... |
Patchy colloidal model with three and four equivalent patches, confined in the attractive random porous media, undergo re-entrant gas-liquid phase separation with the possibility for the liquid phase density to approach zero. This unusual behavior is caused by an interplay between strong fluid-fluid bonding interactio... |
Linkages are mechanical devices constructed from rigid bars and freely rotating joints studied both for their utility in engineering and as mathematical idealizations in a number of physical systems. Recently, there has been a resurgence of interest in designing linkages to perform certain tasks from the physics commu... |
In a granular gas experiment of magnetized particles confined in a thin layer, the rate of dissipative collisions is tuned by adjusting the amplitude of an external magnetic field. The velocity statistics are analyzed using the dynamic and static structure factors of transverse velocity modes. |
Although known that single domain proteins fold and unfold by parallel pathways, demonstration of this expectation has been difficult to establish in experiments. Unfolding rate, $k_\mathrm{u}(f)$, as a function of force $f$, obtained in single molecule pulling experiments on src SH3 domain, exhibits upward curvature ... |
The term "fragility" describes the rate at which viscosity grows when a supercooled liquid approaches its putative glass transition temperature. The field of glassy materials is actively searching for a structural origin that governs this dynamical slowing down in the supercooled liquid, which occurs without a... |
Efficient and non-invasive techniques of cargo delivery to biological cells are the focus of biomedical research because of their great potential importance for targeted drug therapy. Therefore, much effort is being made to study the characteristics of using nano-based biocompatible materials as systems that can facil... |
In this paper we report on bubble growth rates and on the statistics of bubble topology for the coarsening of a dry foam contained in the narrow gap between two hemispheres. By contrast with coarsening in flat space, where six-sided bubbles neither grow nor shrink, we observe that six sided bubbles grow with time at a... |
We study the deformation of a fluctuating crystalline sheet confined between two flat rigid walls as a simple model for layered solids where bonds among atoms {\it within} the same layer are much stronger than those {\it between} layers. When subjected to sufficiently high loads in an appropriate geometry, these solid... |
Colloidal glasses form from hard spheres, nearly hard spheres, ellipsoids and platelets or their attractive variants have been studied in detail. Complementing and checking theoretical approaches and simulations, the many different types of model systems have significantly advanced our understanding of the glass trans... |
According to excess-entropy scaling, dynamic properties of liquids like viscosity and diffusion coefficient are determined by the entropy. This link between dynamics and thermodynamics is increasingly studied and of interest also for industrial applications, but hampered by the challenge of calculating entropy efficie... |
Mesoscale behavior of polymers is frequently described by universal laws. This physical property motivates us to propose a new modeling concept, grouping polymers into classes with a common long-wavelength representation. |
The effects of an externally applied one-dimensional periodic potential on the freezing/melting behaviour of two-dimensional systems of colloidal particles with a short-range attractive interaction are studied using Monte Carlo simulations. In such systems, incommensuration results when the periodicity of the external... |
We examined the kinetics of the transformation from the lamellar (LAM) to the hexagonally packed cylinder (HEX) phase for the triblock copolymer, polystyrene-b-poly (ethylene-co-butylene)-b-polystyrene (SEBS) in dibutyl phthalate (DBP), a selective solvent for polystyrene (PS), using time-resolved small angle x-ray sca... |
Elliptic shear applied to a homeotropically oriented nematic above the electric bend Freedericks transition (FT) generates slow precession of the director. The character of the accompanying nonlinear waves changes from diffusive phase waves to dispersive ones exhibiting spirals and spatio-temporal chaos as the FT is a... |
Although fully elastic when static, granular media become transiently elastic when being slowly sheared -- during which both the elastic energy and stress relax. Starting from this observation, we cogently derive the framework for granular hydrodynamics, a set of differential equations consistent with general principl... |
A variety of complex fluids under shear exhibit complex spatio-temporal behaviour, including what is now termed rheological chaos, at moderate values of the shear rate. Such chaos associated with rheological response occurs in regimes where the Reynolds number is very small. |
The lattice thermal conductivity of graphene is evaluated using a microscopic model that takes into account the lattice's discrete nature and the phonon dispersion relation within the Brillouin zone. The Boltzmann transport equation is solved iteratively within the framework of three-phonon interactions without ta... |
The material properties of polycrystals are strongly affected by the evolution and coarsening of their internal grain structures. Yet, studying this process is challenging due to the complex interactions within grain boundary networks. |
The ability to navigate in complex, inhomogeneous environments is fundamental to survival at all length scales, giving rise to the rapid development of various subfields in bio-locomotion such as the well established concept of chemotaxis. In this work, we extend this existing notion of taxis to rotating environments ... |
We demonstrate a novel technique for the measurement of the charge carried by a colloidal particle. The technique uses the phenomenon of the resonance of a particle held in an optical tweezers trap and driven by a sinusoidal electric field. |
We study the joint probability distribution of normal and tangential frictional forces in jammed granular media, $P_{\mu}(f_t, f_n)$, for various friction coefficient $\mu$, especially when $\mu = \infty$. A universal scaling law is found to collapse the data for $\mu=0$ to $\infty$ demonstrating a link between force ... |
Protein corona formation and nanoparticle aggregation have been heavily discussed over the last years since the lack of fine-mapping of these two combined effects has hindered the targeted delivery evolution and the personalized nanomedicine development. We present a multi-technique approach that combines Dynamic Ligh... |
Multiscale simulation methods have been developed based on the local stress sampling strategy and applied to three flow problems with different difficulty levels: (a) general flow problems of simple fluids, |
Hydrogels have had a profound impact in the fields of tissue engineering, drug delivery, and materials science as a whole. Due to the network architecture of these materials, imbibement with water often results in uniform swelling and isotropic expansion which scales with the degree of cross-linking. |
The probability of finding a spherical "hole" of a given radius $r$ contains crucial structural information about many-body systems. Such hole statistics, including the void conditional nearest-neighbor probability functions $G_V(r)$, have been well studied for hard-sphere fluids in $d$-dimensional Euclidean s... |
We provide an exact mapping between the density functional of a binary mixture and that of the effective one-component fluid in the limit of infinite asymmetry. The fluid of parallel hard cubes is thus mapped onto that of parallel adhesive hard cubes. |
A paradigm proposed recently by Boal et al. (A.K. Boal et al., Nature 404, 746-748, 2000) deals with the possibility to use inorganic nanoparticles as building blocks for the design and fabrication of colloidal and supracolloidal assemblies. It is anticipated that these constructs could be made of different shapes, pa... |
Cardiac myocytes are the fundamental cells composing the heart muscle. The propagation of electric signals and chemical quantities through them is responsible for their nonlinear contraction and dilatation. |
Models of active nematics in biological systems normally require complexity arising from the hydrodynamics involved at the microscopic level as well as the viscoelastic nature of the system. Here we show that a minimal, space-independent, model based on the temporal alignment of active and polymeric particles provides... |
The effect of edge on wetting and layering transitions of a three-dimensional spin-1/2 Ising model is investigated, in the presence of longitudinal and surface magnetic fields, using mean field (MF) theory and Monte Carlo (MC) simulations. For T=0, the ground state phase diagram shows that there exist only three allow... |
Photoactive nematic elastomers are soft rubbery solids that undergo deformation when illuminated. They are made by incorporating photoactive molecules like azobenzene into nematic liquid crystal elastomers. |
A self-consistent variational theory for globules based on the uniform expansion method is presented. This method, first introduced by Edwards and Singh to estimate the size of a self-avoiding chain, is restricted to a good solvent regime, where two-body repulsion leads to chain swelling. |
Recent experiments and theoretical studies strongly indicate that water exhibits a liquid-liquid phase transition (LLPT) in the supercooled domain. An open question is how the LLPT of water can affect the properties of aqueous solutions. |
We discuss thermal and active fluctuations of a compressible bilayer vesicle by using the results of hydrodynamic theory for vesicles. Coupled Langevin equations for the membrane deformation and the density fields are employed to calculate the power spectral density matrix of membrane fluctuations. |
We report the simultaneous softening and compaction of a confined dense granular pack in acoustic resonance experiments. Elastic softening is manifested by a reduction of the shear-wave speed, as the wave amplitude increases beyond some threshold. |
Light provides a powerful means of controlling physical behavior of materials but is rarely used to power and guide active matter systems. We demonstrate optical control of liquid crystalline topological solitons dubbed "skyrmions", which recently emerged as highly reconfigurable inanimate active particles cap... |
Understanding the mechanical response and failure of solids is of obvious importance in their use as structural materials. The nature of plastic deformation leading to yielding of amorphous solids has been vigorously pursued in recent years. |
Walls in discrete element method simulations of granular flows are sometimes modeled as a closely packed monolayer of fixed particles, resulting in a rough wall rather than a geometrically smooth wall. An implicit assumption is that the resulting rough wall differs from a smooth wall only locally at the particle scale... |
Dynamic Monte Carlo simulations are used to study coupled transport (co-transport) through sub-nanometer-diameter pores. In this classic Hodgkin-Keynes mechanism, an ion species uses the large flux of an abundant ion species to move against its concentration gradient. |
A non-perturbative theory is presented which allows to calculate the solvation free energy of polarizable ions near a water-vapor and water-oil interfaces. The theory predicts that larger halogen anions are adsorbed at the interface, while the alkali metal cations are repelled from it. |
Subsets and Splits
No community queries yet
The top public SQL queries from the community will appear here once available.