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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=2.177 mol and ...
M = 1.290 mol/L.
{ "id": "WUA_CHEM_25K_012001", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=2.41 mol, T=324 K, V=1.44 L,...
P ≈ 44.495 atm.
{ "id": "WUA_CHEM_25K_012002", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=3.74 mol, T=330 K, V=13.11 L...
P ≈ 7.725 atm.
{ "id": "WUA_CHEM_25K_012003", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.13 mol, T=276 K, V=16.11 L...
P ≈ 0.183 atm.
{ "id": "WUA_CHEM_25K_012004", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.314 mol and ...
M = 0.463 mol/L.
{ "id": "WUA_CHEM_25K_012005", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=105.06 g (M=58.44 ...
Limiting reagent: B. Moles of C formed = 1.4517 mol.
{ "id": "WUA_CHEM_25K_012006", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.22 mol, T=292 K, V=10.92 L...
P ≈ 9.260 atm.
{ "id": "WUA_CHEM_25K_012007", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 1.69e-12...
pH ≈ 11.77.
{ "id": "WUA_CHEM_25K_012008", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-67 kJ/mol, ΔS=2...
ΔG = -78.15 kJ/mol.
{ "id": "WUA_CHEM_25K_012009", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=90 kJ/mol, ΔS=-6...
ΔG = 115.79 kJ/mol.
{ "id": "WUA_CHEM_25K_012010", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.132 mol and ...
M = 0.127 mol/L.
{ "id": "WUA_CHEM_25K_012011", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=0.43 M, V1=5 m...
M2 = 0.005 M.
{ "id": "WUA_CHEM_25K_012012", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=131 kJ/mol, ΔS=6...
ΔG = 97.67 kJ/mol.
{ "id": "WUA_CHEM_25K_012013", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=37.35 g (M=58.44 g...
Limiting reagent: B. Moles of C formed = 0.2512 mol.
{ "id": "WUA_CHEM_25K_012014", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.91 M, V1=8 m...
M2 = 0.089 M.
{ "id": "WUA_CHEM_25K_012015", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 2.29e-10...
pH ≈ 9.64.
{ "id": "WUA_CHEM_25K_012016", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=46.07 g (M=18.02 g...
Limiting reagent: A. Moles of C formed = 2.5566 mol.
{ "id": "WUA_CHEM_25K_012017", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.000505...
pH ≈ 3.30.
{ "id": "WUA_CHEM_25K_012018", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.99 mol, T=275 K, V=18.43 L...
P ≈ 1.212 atm.
{ "id": "WUA_CHEM_25K_012019", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.562 mol and ...
M = 4.351 mol/L.
{ "id": "WUA_CHEM_25K_012020", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.837 mol and ...
M = 7.541 mol/L.
{ "id": "WUA_CHEM_25K_012021", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=72.13 g (M=44.01 g...
Limiting reagent: B. Moles of C formed = 1.5544 mol.
{ "id": "WUA_CHEM_25K_012022", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.94 M, V1=134...
M2 = 0.289 M.
{ "id": "WUA_CHEM_25K_012023", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=2.66 M, V1=188...
M2 = 1.553 M.
{ "id": "WUA_CHEM_25K_012024", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=1.71 mol, T=283 K, V=9.45 L,...
P ≈ 4.202 atm.
{ "id": "WUA_CHEM_25K_012025", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=66.62 g (M=32.0 g/...
Limiting reagent: B. Moles of C formed = 1.8932 mol.
{ "id": "WUA_CHEM_25K_012026", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=35 kJ/mol, ΔS=-2...
ΔG = 133.28 kJ/mol.
{ "id": "WUA_CHEM_25K_012027", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.69 M, V1=170...
M2 = 0.385 M.
{ "id": "WUA_CHEM_25K_012028", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 5.08e-06...
pH ≈ 5.29.
{ "id": "WUA_CHEM_25K_012029", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.97 M, V1=106...
M2 = 0.669 M.
{ "id": "WUA_CHEM_25K_012030", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=2.23 mol, T=278 K, V=43.01 L...
P ≈ 1.183 atm.
{ "id": "WUA_CHEM_25K_012031", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=1.44 mol, T=284 K, V=45.06 L...
P ≈ 0.745 atm.
{ "id": "WUA_CHEM_25K_012032", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=1.73 mol, T=269 K, V=1.9 L, ...
P ≈ 20.098 atm.
{ "id": "WUA_CHEM_25K_012033", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=86.47 g (M=32.0 g/...
Limiting reagent: B. Moles of C formed = 0.1839 mol.
{ "id": "WUA_CHEM_25K_012034", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.0135 m...
pH ≈ 1.87.
{ "id": "WUA_CHEM_25K_012035", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=80.66 g (M=98.08 g...
Limiting reagent: A. Moles of C formed = 0.8224 mol.
{ "id": "WUA_CHEM_25K_012036", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=26.53 g (M=58.44 g...
Limiting reagent: A. Moles of C formed = 0.4540 mol.
{ "id": "WUA_CHEM_25K_012037", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.073 mol and ...
M = 0.026 mol/L.
{ "id": "WUA_CHEM_25K_012038", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=2.72 M, V1=52 ...
M2 = 1.373 M.
{ "id": "WUA_CHEM_25K_012039", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.507 mol and ...
M = 10.538 mol/L.
{ "id": "WUA_CHEM_25K_012040", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.66 M, V1=64 ...
M2 = 0.345 M.
{ "id": "WUA_CHEM_25K_012041", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=42.19 g (M=18.02 g...
Limiting reagent: A. Moles of C formed = 2.3413 mol.
{ "id": "WUA_CHEM_25K_012042", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=2.419 mol and ...
M = 1.131 mol/L.
{ "id": "WUA_CHEM_25K_012043", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.182 mol and ...
M = 0.595 mol/L.
{ "id": "WUA_CHEM_25K_012044", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.0959 m...
pH ≈ 1.02.
{ "id": "WUA_CHEM_25K_012045", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=64.6 g (M=44.01 g/...
Limiting reagent: B. Moles of C formed = 0.8767 mol.
{ "id": "WUA_CHEM_25K_012046", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=29.63 g (M=18.02 g...
Limiting reagent: B. Moles of C formed = 1.3142 mol.
{ "id": "WUA_CHEM_25K_012047", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=113.5 g (M=32.0 g/...
Limiting reagent: A. Moles of C formed = 3.5469 mol.
{ "id": "WUA_CHEM_25K_012048", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.199 mol and ...
M = 0.358 mol/L.
{ "id": "WUA_CHEM_25K_012049", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.788 mol and ...
M = 1.100 mol/L.
{ "id": "WUA_CHEM_25K_012050", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=36.41 g (M=44.01 g...
Limiting reagent: A. Moles of C formed = 0.8273 mol.
{ "id": "WUA_CHEM_25K_012051", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=68.57 g (M=32.0 g/...
Limiting reagent: B. Moles of C formed = 1.7097 mol.
{ "id": "WUA_CHEM_25K_012052", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=21.77 g (M=18.02 g...
Limiting reagent: A. Moles of C formed = 1.2081 mol.
{ "id": "WUA_CHEM_25K_012053", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.83 M, V1=112...
M2 = 0.401 M.
{ "id": "WUA_CHEM_25K_012054", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.94 mol, T=254 K, V=2.41 L,...
P ≈ 42.723 atm.
{ "id": "WUA_CHEM_25K_012055", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=140 kJ/mol, ΔS=2...
ΔG = 59.13 kJ/mol.
{ "id": "WUA_CHEM_25K_012056", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=110.79 g (M=32.0 g...
Limiting reagent: B. Moles of C formed = 1.2191 mol.
{ "id": "WUA_CHEM_25K_012057", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.87 M, V1=249...
M2 = 0.678 M.
{ "id": "WUA_CHEM_25K_012058", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=38.37 g (M=44.01 g...
Limiting reagent: B. Moles of C formed = 0.8357 mol.
{ "id": "WUA_CHEM_25K_012059", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=2.52 M, V1=185...
M2 = 0.658 M.
{ "id": "WUA_CHEM_25K_012060", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=0.73 M, V1=211...
M2 = 0.255 M.
{ "id": "WUA_CHEM_25K_012061", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=0.21 M, V1=139...
M2 = 0.031 M.
{ "id": "WUA_CHEM_25K_012062", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.263 mol and ...
M = 2.979 mol/L.
{ "id": "WUA_CHEM_25K_012063", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 1.19e-09...
pH ≈ 8.92.
{ "id": "WUA_CHEM_25K_012064", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=2.31 mol, T=308 K, V=24.42 L...
P ≈ 2.391 atm.
{ "id": "WUA_CHEM_25K_012065", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.231 mol and ...
M = 0.805 mol/L.
{ "id": "WUA_CHEM_25K_012066", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.19 M, V1=200...
M2 = 0.407 M.
{ "id": "WUA_CHEM_25K_012067", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=16.55 g (M=98.08 g...
Limiting reagent: A. Moles of C formed = 0.1687 mol.
{ "id": "WUA_CHEM_25K_012068", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=10.69 g (M=98.08 g...
Limiting reagent: A. Moles of C formed = 0.1090 mol.
{ "id": "WUA_CHEM_25K_012069", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.17 mol, T=305 K, V=1.81 L,...
P ≈ 2.351 atm.
{ "id": "WUA_CHEM_25K_012070", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=2.428 mol and ...
M = 0.997 mol/L.
{ "id": "WUA_CHEM_25K_012071", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=67 kJ/mol, ΔS=-1...
ΔG = 138.00 kJ/mol.
{ "id": "WUA_CHEM_25K_012072", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=30.52 g (M=58.44 g...
Limiting reagent: A. Moles of C formed = 0.5222 mol.
{ "id": "WUA_CHEM_25K_012073", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.79 mol, T=348 K, V=36.64 L...
P ≈ 3.733 atm.
{ "id": "WUA_CHEM_25K_012074", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 2.21e-13...
pH ≈ 12.66.
{ "id": "WUA_CHEM_25K_012075", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=146 kJ/mol, ΔS=3...
ΔG = 118.56 kJ/mol.
{ "id": "WUA_CHEM_25K_012076", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.0137 m...
pH ≈ 1.86.
{ "id": "WUA_CHEM_25K_012077", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 1.77e-09...
pH ≈ 8.75.
{ "id": "WUA_CHEM_25K_012078", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=3.82 mol, T=293 K, V=11.65 L...
P ≈ 7.884 atm.
{ "id": "WUA_CHEM_25K_012079", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 3.32e-11...
pH ≈ 10.48.
{ "id": "WUA_CHEM_25K_012080", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-110 kJ/mol, ΔS=...
ΔG = -247.01 kJ/mol.
{ "id": "WUA_CHEM_25K_012081", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=2.2 M, V1=242 ...
M2 = 1.787 M.
{ "id": "WUA_CHEM_25K_012082", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-182 kJ/mol, ΔS=...
ΔG = -213.64 kJ/mol.
{ "id": "WUA_CHEM_25K_012083", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-198 kJ/mol, ΔS=...
ΔG = -137.52 kJ/mol.
{ "id": "WUA_CHEM_25K_012084", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=2.47 mol, T=343 K, V=22.98 L...
P ≈ 3.025 atm.
{ "id": "WUA_CHEM_25K_012085", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=116 kJ/mol, ΔS=2...
ΔG = -21.98 kJ/mol.
{ "id": "WUA_CHEM_25K_012086", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=59.08 g (M=18.02 g...
Limiting reagent: A. Moles of C formed = 3.2786 mol.
{ "id": "WUA_CHEM_25K_012087", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 2.51e-05...
pH ≈ 4.60.
{ "id": "WUA_CHEM_25K_012088", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=2.05 mol, T=261 K, V=42.31 L...
P ≈ 1.038 atm.
{ "id": "WUA_CHEM_25K_012089", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-213 kJ/mol, ΔS=...
ΔG = -268.91 kJ/mol.
{ "id": "WUA_CHEM_25K_012090", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 4.48e-13...
pH ≈ 12.35.
{ "id": "WUA_CHEM_25K_012091", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.226 mol and ...
M = 0.469 mol/L.
{ "id": "WUA_CHEM_25K_012092", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=82.41 g (M=98.08 g...
Limiting reagent: A. Moles of C formed = 0.8402 mol.
{ "id": "WUA_CHEM_25K_012093", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.000536...
pH ≈ 3.27.
{ "id": "WUA_CHEM_25K_012094", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=101 kJ/mol, ΔS=1...
ΔG = -0.14 kJ/mol.
{ "id": "WUA_CHEM_25K_012095", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=246 kJ/mol, ΔS=-...
ΔG = 340.60 kJ/mol.
{ "id": "WUA_CHEM_25K_012096", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 8.56e-13...
pH ≈ 12.07.
{ "id": "WUA_CHEM_25K_012097", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.46 M, V1=8 m...
M2 = 0.025 M.
{ "id": "WUA_CHEM_25K_012098", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 2.02e-09...
pH ≈ 8.69.
{ "id": "WUA_CHEM_25K_012099", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.783 mol and ...
M = 0.900 mol/L.
{ "id": "WUA_CHEM_25K_012100", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
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