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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 1.28e-05...
pH ≈ 4.89.
{ "id": "WUA_CHEM_25K_013001", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-140 kJ/mol, ΔS=...
ΔG = -182.72 kJ/mol.
{ "id": "WUA_CHEM_25K_013002", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=38.0 g (M=58.44 g/...
Limiting reagent: A. Moles of C formed = 0.6502 mol.
{ "id": "WUA_CHEM_25K_013003", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.69 mol, T=257 K, V=22.39 L...
P ≈ 4.417 atm.
{ "id": "WUA_CHEM_25K_013004", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.99 mol, T=273 K, V=16.1 L,...
P ≈ 1.377 atm.
{ "id": "WUA_CHEM_25K_013005", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=65.59 g (M=18.02 g...
Limiting reagent: A. Moles of C formed = 3.6398 mol.
{ "id": "WUA_CHEM_25K_013006", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=34.73 g (M=44.01 g...
Limiting reagent: A. Moles of C formed = 0.7891 mol.
{ "id": "WUA_CHEM_25K_013007", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=196 kJ/mol, ΔS=-...
ΔG = 234.74 kJ/mol.
{ "id": "WUA_CHEM_25K_013008", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.36 mol and V...
M = 0.651 mol/L.
{ "id": "WUA_CHEM_25K_013009", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=43.57 g (M=18.02 g...
Limiting reagent: A. Moles of C formed = 2.4179 mol.
{ "id": "WUA_CHEM_25K_013010", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.49 mol, T=297 K, V=29.59 L...
P ≈ 3.698 atm.
{ "id": "WUA_CHEM_25K_013011", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.993 mol and ...
M = 1.129 mol/L.
{ "id": "WUA_CHEM_25K_013012", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.89 M, V1=126...
M2 = 0.612 M.
{ "id": "WUA_CHEM_25K_013013", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-164 kJ/mol, ΔS=...
ΔG = -260.15 kJ/mol.
{ "id": "WUA_CHEM_25K_013014", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=70.65 g (M=18.02 g...
Limiting reagent: B. Moles of C formed = 0.8267 mol.
{ "id": "WUA_CHEM_25K_013015", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=2.86 mol, T=317 K, V=48.62 L...
P ≈ 1.530 atm.
{ "id": "WUA_CHEM_25K_013016", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.288 mol and ...
M = 0.205 mol/L.
{ "id": "WUA_CHEM_25K_013017", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 1.94e-05...
pH ≈ 4.71.
{ "id": "WUA_CHEM_25K_013018", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.276 mol and ...
M = 0.622 mol/L.
{ "id": "WUA_CHEM_25K_013019", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.0405 m...
pH ≈ 1.39.
{ "id": "WUA_CHEM_25K_013020", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.51 M, V1=245...
M2 = 0.433 M.
{ "id": "WUA_CHEM_25K_013021", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.52 M, V1=137...
M2 = 1.326 M.
{ "id": "WUA_CHEM_25K_013022", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=1.45 mol, T=321 K, V=24.58 L...
P ≈ 1.554 atm.
{ "id": "WUA_CHEM_25K_013023", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=2.41 M, V1=52 ...
M2 = 0.237 M.
{ "id": "WUA_CHEM_25K_013024", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-94 kJ/mol, ΔS=-...
ΔG = -53.88 kJ/mol.
{ "id": "WUA_CHEM_25K_013025", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.00447 ...
pH ≈ 2.35.
{ "id": "WUA_CHEM_25K_013026", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=81.96 g (M=32.0 g/...
Limiting reagent: B. Moles of C formed = 2.0692 mol.
{ "id": "WUA_CHEM_25K_013027", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=64 kJ/mol, ΔS=-2...
ΔG = 269.32 kJ/mol.
{ "id": "WUA_CHEM_25K_013028", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=227 kJ/mol, ΔS=1...
ΔG = 188.31 kJ/mol.
{ "id": "WUA_CHEM_25K_013029", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.853 mol and ...
M = 0.670 mol/L.
{ "id": "WUA_CHEM_25K_013030", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-203 kJ/mol, ΔS=...
ΔG = -292.79 kJ/mol.
{ "id": "WUA_CHEM_25K_013031", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.61 mol, T=298 K, V=2.37 L,...
P ≈ 47.565 atm.
{ "id": "WUA_CHEM_25K_013032", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.905 mol and ...
M = 4.415 mol/L.
{ "id": "WUA_CHEM_25K_013033", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=166 kJ/mol, ΔS=-...
ΔG = 203.78 kJ/mol.
{ "id": "WUA_CHEM_25K_013034", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=2.236 mol and ...
M = 0.930 mol/L.
{ "id": "WUA_CHEM_25K_013035", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=92.81 g (M=58.44 g...
Limiting reagent: A. Moles of C formed = 1.5881 mol.
{ "id": "WUA_CHEM_25K_013036", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.00342 ...
pH ≈ 2.47.
{ "id": "WUA_CHEM_25K_013037", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.0148 m...
pH ≈ 1.83.
{ "id": "WUA_CHEM_25K_013038", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.00105 ...
pH ≈ 2.98.
{ "id": "WUA_CHEM_25K_013039", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.69 mol, T=309 K, V=19.08 L...
P ≈ 6.233 atm.
{ "id": "WUA_CHEM_25K_013040", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-192 kJ/mol, ΔS=...
ΔG = -196.86 kJ/mol.
{ "id": "WUA_CHEM_25K_013041", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=19 kJ/mol, ΔS=-1...
ΔG = 61.52 kJ/mol.
{ "id": "WUA_CHEM_25K_013042", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=2.23 mol, T=285 K, V=24.89 L...
P ≈ 2.095 atm.
{ "id": "WUA_CHEM_25K_013043", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 6.74e-07...
pH ≈ 6.17.
{ "id": "WUA_CHEM_25K_013044", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.32 M, V1=165...
M2 = 0.927 M.
{ "id": "WUA_CHEM_25K_013045", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 2.93e-07...
pH ≈ 6.53.
{ "id": "WUA_CHEM_25K_013046", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-130 kJ/mol, ΔS=...
ΔG = -40.76 kJ/mol.
{ "id": "WUA_CHEM_25K_013047", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-149 kJ/mol, ΔS=...
ΔG = 0.80 kJ/mol.
{ "id": "WUA_CHEM_25K_013048", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.054 mol and ...
M = 0.024 mol/L.
{ "id": "WUA_CHEM_25K_013049", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=68.39 g (M=44.01 g...
Limiting reagent: B. Moles of C formed = 0.4405 mol.
{ "id": "WUA_CHEM_25K_013050", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=240 kJ/mol, ΔS=-...
ΔG = 353.07 kJ/mol.
{ "id": "WUA_CHEM_25K_013051", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.01 M, V1=41 ...
M2 = 0.083 M.
{ "id": "WUA_CHEM_25K_013052", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=122 kJ/mol, ΔS=2...
ΔG = -59.92 kJ/mol.
{ "id": "WUA_CHEM_25K_013053", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=4 kJ/mol, ΔS=74 ...
ΔG = -43.66 kJ/mol.
{ "id": "WUA_CHEM_25K_013054", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=2.95 M, V1=188...
M2 = 1.153 M.
{ "id": "WUA_CHEM_25K_013055", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 8.71e-11...
pH ≈ 10.06.
{ "id": "WUA_CHEM_25K_013056", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=62.37 g (M=98.08 g...
Limiting reagent: A. Moles of C formed = 0.6359 mol.
{ "id": "WUA_CHEM_25K_013057", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.0335 m...
pH ≈ 1.47.
{ "id": "WUA_CHEM_25K_013058", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 1.63e-10...
pH ≈ 9.79.
{ "id": "WUA_CHEM_25K_013059", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-23 kJ/mol, ΔS=2...
ΔG = -163.30 kJ/mol.
{ "id": "WUA_CHEM_25K_013060", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 7.03e-12...
pH ≈ 11.15.
{ "id": "WUA_CHEM_25K_013061", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-188 kJ/mol, ΔS=...
ΔG = -141.52 kJ/mol.
{ "id": "WUA_CHEM_25K_013062", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=2.79 M, V1=222...
M2 = 0.965 M.
{ "id": "WUA_CHEM_25K_013063", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.63 M, V1=52 ...
M2 = 0.315 M.
{ "id": "WUA_CHEM_25K_013064", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=117.53 g (M=32.0 g...
Limiting reagent: B. Moles of C formed = 1.4018 mol.
{ "id": "WUA_CHEM_25K_013065", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=34.56 g (M=58.44 g...
Limiting reagent: A. Moles of C formed = 0.5914 mol.
{ "id": "WUA_CHEM_25K_013066", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 6.49e-10...
pH ≈ 9.19.
{ "id": "WUA_CHEM_25K_013067", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=1.81 mol, T=328 K, V=12.63 L...
P ≈ 3.857 atm.
{ "id": "WUA_CHEM_25K_013068", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=160 kJ/mol, ΔS=-...
ΔG = 255.81 kJ/mol.
{ "id": "WUA_CHEM_25K_013069", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=48.21 g (M=98.08 g...
Limiting reagent: A. Moles of C formed = 0.4915 mol.
{ "id": "WUA_CHEM_25K_013070", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-112 kJ/mol, ΔS=...
ΔG = -225.02 kJ/mol.
{ "id": "WUA_CHEM_25K_013071", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.787 mol and ...
M = 0.341 mol/L.
{ "id": "WUA_CHEM_25K_013072", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=2.275 mol and ...
M = 1.301 mol/L.
{ "id": "WUA_CHEM_25K_013073", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.323 mol and ...
M = 0.509 mol/L.
{ "id": "WUA_CHEM_25K_013074", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 4.99e-10...
pH ≈ 9.30.
{ "id": "WUA_CHEM_25K_013075", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=2.27 M, V1=165...
M2 = 0.620 M.
{ "id": "WUA_CHEM_25K_013076", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-187 kJ/mol, ΔS=...
ΔG = -115.17 kJ/mol.
{ "id": "WUA_CHEM_25K_013077", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.00905 ...
pH ≈ 2.04.
{ "id": "WUA_CHEM_25K_013078", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=3.96 mol, T=291 K, V=1.43 L,...
P ≈ 66.125 atm.
{ "id": "WUA_CHEM_25K_013079", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.38 M, V1=198...
M2 = 0.311 M.
{ "id": "WUA_CHEM_25K_013080", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 6.41e-06...
pH ≈ 5.19.
{ "id": "WUA_CHEM_25K_013081", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=2.018 mol and ...
M = 4.946 mol/L.
{ "id": "WUA_CHEM_25K_013082", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=19.78 g (M=44.01 g...
Limiting reagent: A. Moles of C formed = 0.4494 mol.
{ "id": "WUA_CHEM_25K_013083", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=18.78 g (M=32.0 g/...
Limiting reagent: A. Moles of C formed = 0.5869 mol.
{ "id": "WUA_CHEM_25K_013084", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-53 kJ/mol, ΔS=2...
ΔG = -72.24 kJ/mol.
{ "id": "WUA_CHEM_25K_013085", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=0.27 M, V1=94 ...
M2 = 0.112 M.
{ "id": "WUA_CHEM_25K_013086", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.2 mol, T=287 K, V=20.76 L,...
P ≈ 4.765 atm.
{ "id": "WUA_CHEM_25K_013087", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=175 kJ/mol, ΔS=8...
ΔG = 144.20 kJ/mol.
{ "id": "WUA_CHEM_25K_013088", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.341 mol and ...
M = 0.320 mol/L.
{ "id": "WUA_CHEM_25K_013089", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=49.39 g (M=98.08 g...
Limiting reagent: A. Moles of C formed = 0.5036 mol.
{ "id": "WUA_CHEM_25K_013090", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=92.17 g (M=98.08 g...
Limiting reagent: B. Moles of C formed = 0.6181 mol.
{ "id": "WUA_CHEM_25K_013091", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-100 kJ/mol, ΔS=...
ΔG = -147.87 kJ/mol.
{ "id": "WUA_CHEM_25K_013092", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.17 M, V1=140...
M2 = 0.398 M.
{ "id": "WUA_CHEM_25K_013093", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.05 mol, T=350 K, V=47.41 L...
P ≈ 2.453 atm.
{ "id": "WUA_CHEM_25K_013094", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags"...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.934 mol and ...
M = 0.507 mol/L.
{ "id": "WUA_CHEM_25K_013095", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=2.2 mol, T=346 K, V=28.76 L,...
P ≈ 2.172 atm.
{ "id": "WUA_CHEM_25K_013096", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=11.98 g (M=18.02 g...
Limiting reagent: A. Moles of C formed = 0.6648 mol.
{ "id": "WUA_CHEM_25K_013097", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=2.219 mol and ...
M = 1.412 mol/L.
{ "id": "WUA_CHEM_25K_013098", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=1.08 mol, T=287 K, V=15.06 L...
P ≈ 1.689 atm.
{ "id": "WUA_CHEM_25K_013099", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-29 kJ/mol, ΔS=2...
ΔG = -120.61 kJ/mol.
{ "id": "WUA_CHEM_25K_013100", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
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