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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.27 mol, T=319 K, V=13.47 L...
P ≈ 8.298 atm.
{ "id": "WUA_CHEM_25K_015801", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.94 mol, T=269 K, V=37.75 L...
P ≈ 0.550 atm.
{ "id": "WUA_CHEM_25K_015802", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=2.15 mol, T=312 K, V=17.36 L...
P ≈ 3.171 atm.
{ "id": "WUA_CHEM_25K_015803", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=2.73 M, V1=134...
M2 = 0.835 M.
{ "id": "WUA_CHEM_25K_015804", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 4.65e-12...
pH ≈ 11.33.
{ "id": "WUA_CHEM_25K_015805", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.000216...
pH ≈ 3.67.
{ "id": "WUA_CHEM_25K_015806", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=2.74 mol, T=302 K, V=17.59 L...
P ≈ 3.860 atm.
{ "id": "WUA_CHEM_25K_015807", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.24 mol, T=337 K, V=15.26 L...
P ≈ 0.435 atm.
{ "id": "WUA_CHEM_25K_015808", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.49 mol, T=254 K, V=17.89 L...
P ≈ 0.571 atm.
{ "id": "WUA_CHEM_25K_015809", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=12.03 g (M=32.0 g/...
Limiting reagent: A. Moles of C formed = 0.3759 mol.
{ "id": "WUA_CHEM_25K_015810", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=160 kJ/mol, ΔS=-...
ΔG = 353.44 kJ/mol.
{ "id": "WUA_CHEM_25K_015811", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.0153 m...
pH ≈ 1.82.
{ "id": "WUA_CHEM_25K_015812", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=2.39 M, V1=77 ...
M2 = 0.227 M.
{ "id": "WUA_CHEM_25K_015813", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=106 kJ/mol, ΔS=1...
ΔG = 62.91 kJ/mol.
{ "id": "WUA_CHEM_25K_015814", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.71 M, V1=164...
M2 = 1.095 M.
{ "id": "WUA_CHEM_25K_015815", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.482 mol and ...
M = 0.211 mol/L.
{ "id": "WUA_CHEM_25K_015816", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=0.3 M, V1=135 ...
M2 = 0.238 M.
{ "id": "WUA_CHEM_25K_015817", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=118.84 g (M=58.44 ...
Limiting reagent: B. Moles of C formed = 1.6372 mol.
{ "id": "WUA_CHEM_25K_015818", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.256 mol and ...
M = 0.087 mol/L.
{ "id": "WUA_CHEM_25K_015819", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 1.09e-06...
pH ≈ 5.96.
{ "id": "WUA_CHEM_25K_015820", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=182 kJ/mol, ΔS=-...
ΔG = 253.26 kJ/mol.
{ "id": "WUA_CHEM_25K_015821", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=43.78 g (M=58.44 g...
Limiting reagent: A. Moles of C formed = 0.7491 mol.
{ "id": "WUA_CHEM_25K_015822", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=3.24 mol, T=341 K, V=49.45 L...
P ≈ 1.833 atm.
{ "id": "WUA_CHEM_25K_015823", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-90 kJ/mol, ΔS=-...
ΔG = -42.34 kJ/mol.
{ "id": "WUA_CHEM_25K_015824", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=2.18 M, V1=149...
M2 = 0.931 M.
{ "id": "WUA_CHEM_25K_015825", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=110.78 g (M=18.02 ...
Limiting reagent: B. Moles of C formed = 1.5453 mol.
{ "id": "WUA_CHEM_25K_015826", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=54.04 g (M=98.08 g...
Limiting reagent: A. Moles of C formed = 0.5510 mol.
{ "id": "WUA_CHEM_25K_015827", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 2.02e-12...
pH ≈ 11.69.
{ "id": "WUA_CHEM_25K_015828", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=1.82 mol, T=263 K, V=6.36 L,...
P ≈ 6.176 atm.
{ "id": "WUA_CHEM_25K_015829", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.72 mol, T=286 K, V=22.24 L...
P ≈ 0.760 atm.
{ "id": "WUA_CHEM_25K_015830", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-67 kJ/mol, ΔS=6...
ΔG = -111.99 kJ/mol.
{ "id": "WUA_CHEM_25K_015831", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=78.08 g (M=32.0 g/...
Limiting reagent: A. Moles of C formed = 2.4400 mol.
{ "id": "WUA_CHEM_25K_015832", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=2.34 mol, T=285 K, V=5.83 L,...
P ≈ 9.387 atm.
{ "id": "WUA_CHEM_25K_015833", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-136 kJ/mol, ΔS=...
ΔG = -216.63 kJ/mol.
{ "id": "WUA_CHEM_25K_015834", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=2.488 mol and ...
M = 1.882 mol/L.
{ "id": "WUA_CHEM_25K_015835", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 5.69e-05...
pH ≈ 4.24.
{ "id": "WUA_CHEM_25K_015836", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=3.06 mol, T=337 K, V=8.18 L,...
P ≈ 10.345 atm.
{ "id": "WUA_CHEM_25K_015837", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.804 mol and ...
M = 2.301 mol/L.
{ "id": "WUA_CHEM_25K_015838", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=2.33 mol and V...
M = 0.926 mol/L.
{ "id": "WUA_CHEM_25K_015839", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=0.44 M, V1=67 ...
M2 = 0.030 M.
{ "id": "WUA_CHEM_25K_015840", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.0359 m...
pH ≈ 1.44.
{ "id": "WUA_CHEM_25K_015841", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=182 kJ/mol, ΔS=2...
ΔG = 44.19 kJ/mol.
{ "id": "WUA_CHEM_25K_015842", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=30.57 g (M=58.44 g...
Limiting reagent: A. Moles of C formed = 0.5231 mol.
{ "id": "WUA_CHEM_25K_015843", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.78 M, V1=163...
M2 = 0.689 M.
{ "id": "WUA_CHEM_25K_015844", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=81.45 g (M=58.44 g...
Limiting reagent: A. Moles of C formed = 1.3937 mol.
{ "id": "WUA_CHEM_25K_015845", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.029 mol and ...
M = 3.500 mol/L.
{ "id": "WUA_CHEM_25K_015846", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=111.82 g (M=32.0 g...
Limiting reagent: B. Moles of C formed = 2.0793 mol.
{ "id": "WUA_CHEM_25K_015847", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=2.47 M, V1=11 ...
M2 = 0.162 M.
{ "id": "WUA_CHEM_25K_015848", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=2.02 M, V1=23 ...
M2 = 0.099 M.
{ "id": "WUA_CHEM_25K_015849", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-135 kJ/mol, ΔS=...
ΔG = -209.77 kJ/mol.
{ "id": "WUA_CHEM_25K_015850", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.0325 m...
pH ≈ 1.49.
{ "id": "WUA_CHEM_25K_015851", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 1.32e-12...
pH ≈ 11.88.
{ "id": "WUA_CHEM_25K_015852", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.76 M, V1=107...
M2 = 0.369 M.
{ "id": "WUA_CHEM_25K_015853", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=0.61 M, V1=233...
M2 = 0.154 M.
{ "id": "WUA_CHEM_25K_015854", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=240 kJ/mol, ΔS=-...
ΔG = 272.05 kJ/mol.
{ "id": "WUA_CHEM_25K_015855", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.82 mol, T=282 K, V=6.78 L,...
P ≈ 2.799 atm.
{ "id": "WUA_CHEM_25K_015856", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.692 mol and ...
M = 2.244 mol/L.
{ "id": "WUA_CHEM_25K_015857", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.106 mol and ...
M = 0.883 mol/L.
{ "id": "WUA_CHEM_25K_015858", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=2.59 mol, T=320 K, V=9.38 L,...
P ≈ 7.250 atm.
{ "id": "WUA_CHEM_25K_015859", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=15.16 g (M=18.02 g...
Limiting reagent: A. Moles of C formed = 0.8413 mol.
{ "id": "WUA_CHEM_25K_015860", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=77.53 g (M=44.01 g...
Limiting reagent: A. Moles of C formed = 1.7616 mol.
{ "id": "WUA_CHEM_25K_015861", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=39.17 g (M=58.44 g...
Limiting reagent: A. Moles of C formed = 0.6703 mol.
{ "id": "WUA_CHEM_25K_015862", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-61 kJ/mol, ΔS=2...
ΔG = -205.70 kJ/mol.
{ "id": "WUA_CHEM_25K_015863", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 2.66e-05...
pH ≈ 4.58.
{ "id": "WUA_CHEM_25K_015864", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.11 mol, T=349 K, V=19.33 L...
P ≈ 0.163 atm.
{ "id": "WUA_CHEM_25K_015865", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 2.11e-12...
pH ≈ 11.68.
{ "id": "WUA_CHEM_25K_015866", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.5 M, V1=174 ...
M2 = 0.284 M.
{ "id": "WUA_CHEM_25K_015867", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.22 mol, T=284 K, V=6.4 L, ...
P ≈ 15.366 atm.
{ "id": "WUA_CHEM_25K_015868", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-142 kJ/mol, ΔS=...
ΔG = -250.09 kJ/mol.
{ "id": "WUA_CHEM_25K_015869", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=77 kJ/mol, ΔS=-2...
ΔG = 178.62 kJ/mol.
{ "id": "WUA_CHEM_25K_015870", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 6.14e-13...
pH ≈ 12.21.
{ "id": "WUA_CHEM_25K_015871", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=3.44 mol, T=315 K, V=5.75 L,...
P ≈ 15.464 atm.
{ "id": "WUA_CHEM_25K_015872", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.207 mol and ...
M = 0.272 mol/L.
{ "id": "WUA_CHEM_25K_015873", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.691 mol and ...
M = 4.558 mol/L.
{ "id": "WUA_CHEM_25K_015874", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=37.85 g (M=32.0 g/...
Limiting reagent: A. Moles of C formed = 1.1828 mol.
{ "id": "WUA_CHEM_25K_015875", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=117 kJ/mol, ΔS=-...
ΔG = 256.73 kJ/mol.
{ "id": "WUA_CHEM_25K_015876", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=2.0 M, V1=9 mL...
M2 = 0.121 M.
{ "id": "WUA_CHEM_25K_015877", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-116 kJ/mol, ΔS=...
ΔG = -52.83 kJ/mol.
{ "id": "WUA_CHEM_25K_015878", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=2.59 mol, T=304 K, V=39.32 L...
P ≈ 1.643 atm.
{ "id": "WUA_CHEM_25K_015879", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=0.38 M, V1=131...
M2 = 0.343 M.
{ "id": "WUA_CHEM_25K_015880", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=2.046 mol and ...
M = 1.804 mol/L.
{ "id": "WUA_CHEM_25K_015881", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=1.35 mol, T=253 K, V=36.45 L...
P ≈ 0.769 atm.
{ "id": "WUA_CHEM_25K_015882", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 2.03e-13...
pH ≈ 12.69.
{ "id": "WUA_CHEM_25K_015883", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.27 M, V1=216...
M2 = 1.016 M.
{ "id": "WUA_CHEM_25K_015884", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.29 mol, T=250 K, V=44.13 L...
P ≈ 0.135 atm.
{ "id": "WUA_CHEM_25K_015885", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.27 mol, T=278 K, V=19.74 L...
P ≈ 4.934 atm.
{ "id": "WUA_CHEM_25K_015886", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-197 kJ/mol, ΔS=...
ΔG = -147.80 kJ/mol.
{ "id": "WUA_CHEM_25K_015887", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.49 mol, T=307 K, V=14.94 L...
P ≈ 0.826 atm.
{ "id": "WUA_CHEM_25K_015888", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 2.34e-08...
pH ≈ 7.63.
{ "id": "WUA_CHEM_25K_015889", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=20.73 g (M=32.0 g/...
Limiting reagent: A. Moles of C formed = 0.6478 mol.
{ "id": "WUA_CHEM_25K_015890", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=2.31 mol and V...
M = 1.083 mol/L.
{ "id": "WUA_CHEM_25K_015891", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=2.54 mol, T=321 K, V=36.93 L...
P ≈ 1.812 atm.
{ "id": "WUA_CHEM_25K_015892", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.04 M, V1=22 ...
M2 = 0.037 M.
{ "id": "WUA_CHEM_25K_015893", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 7.68e-08...
pH ≈ 7.11.
{ "id": "WUA_CHEM_25K_015894", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=178 kJ/mol, ΔS=-...
ΔG = 196.94 kJ/mol.
{ "id": "WUA_CHEM_25K_015895", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=35.35 g (M=18.02 g...
Limiting reagent: B. Moles of C formed = 0.9645 mol.
{ "id": "WUA_CHEM_25K_015896", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=1.37 mol, T=259 K, V=27.89 L...
P ≈ 1.044 atm.
{ "id": "WUA_CHEM_25K_015897", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.28 mol, T=289 K, V=20.8 L,...
P ≈ 4.880 atm.
{ "id": "WUA_CHEM_25K_015898", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.636 mol and ...
M = 0.987 mol/L.
{ "id": "WUA_CHEM_25K_015899", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.549 mol and ...
M = 1.376 mol/L.
{ "id": "WUA_CHEM_25K_015900", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
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