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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=65 kJ/mol, ΔS=-2...
ΔG = 184.08 kJ/mol.
{ "id": "WUA_CHEM_25K_016901", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.47 mol, T=293 K, V=33.71 L...
P ≈ 0.335 atm.
{ "id": "WUA_CHEM_25K_016902", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.09 mol, T=262 K, V=48.12 L...
P ≈ 1.827 atm.
{ "id": "WUA_CHEM_25K_016903", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=184 kJ/mol, ΔS=1...
ΔG = 60.92 kJ/mol.
{ "id": "WUA_CHEM_25K_016904", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.25 mol, T=265 K, V=12.94 L...
P ≈ 0.420 atm.
{ "id": "WUA_CHEM_25K_016905", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.298 mol and ...
M = 1.155 mol/L.
{ "id": "WUA_CHEM_25K_016906", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=170 kJ/mol, ΔS=2...
ΔG = 103.21 kJ/mol.
{ "id": "WUA_CHEM_25K_016907", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=3.21 mol, T=327 K, V=12.17 L...
P ≈ 7.077 atm.
{ "id": "WUA_CHEM_25K_016908", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=2.008 mol and ...
M = 0.930 mol/L.
{ "id": "WUA_CHEM_25K_016909", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=2.47 M, V1=214...
M2 = 0.698 M.
{ "id": "WUA_CHEM_25K_016910", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=1.22 mol, T=322 K, V=17.72 L...
P ≈ 1.819 atm.
{ "id": "WUA_CHEM_25K_016911", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=92.39 g (M=18.02 g...
Limiting reagent: A. Moles of C formed = 5.1271 mol.
{ "id": "WUA_CHEM_25K_016912", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 4.65e-11...
pH ≈ 10.33.
{ "id": "WUA_CHEM_25K_016913", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 1.43e-09...
pH ≈ 8.84.
{ "id": "WUA_CHEM_25K_016914", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.56 M, V1=9 m...
M2 = 0.079 M.
{ "id": "WUA_CHEM_25K_016915", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.00031 ...
pH ≈ 3.51.
{ "id": "WUA_CHEM_25K_016916", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=25 kJ/mol, ΔS=-1...
ΔG = 109.26 kJ/mol.
{ "id": "WUA_CHEM_25K_016917", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.03 mol, T=327 K, V=15.82 L...
P ≈ 6.835 atm.
{ "id": "WUA_CHEM_25K_016918", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=17.98 g (M=18.02 g...
Limiting reagent: A. Moles of C formed = 0.9978 mol.
{ "id": "WUA_CHEM_25K_016919", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=42.43 g (M=58.44 g...
Limiting reagent: A. Moles of C formed = 0.7260 mol.
{ "id": "WUA_CHEM_25K_016920", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=3.83 mol, T=275 K, V=36.05 L...
P ≈ 2.397 atm.
{ "id": "WUA_CHEM_25K_016921", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=2.416 mol and ...
M = 1.487 mol/L.
{ "id": "WUA_CHEM_25K_016922", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=41.39 g (M=32.0 g/...
Limiting reagent: A. Moles of C formed = 1.2934 mol.
{ "id": "WUA_CHEM_25K_016923", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.484 mol and ...
M = 0.595 mol/L.
{ "id": "WUA_CHEM_25K_016924", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-172 kJ/mol, ΔS=...
ΔG = -391.74 kJ/mol.
{ "id": "WUA_CHEM_25K_016925", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 2.42e-06...
pH ≈ 5.62.
{ "id": "WUA_CHEM_25K_016926", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.058 mol and ...
M = 0.029 mol/L.
{ "id": "WUA_CHEM_25K_016927", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=0.23 M, V1=109...
M2 = 0.031 M.
{ "id": "WUA_CHEM_25K_016928", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.00151 ...
pH ≈ 2.82.
{ "id": "WUA_CHEM_25K_016929", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=2.7 mol, T=276 K, V=14.17 L,...
P ≈ 4.315 atm.
{ "id": "WUA_CHEM_25K_016930", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.822 mol and ...
M = 1.272 mol/L.
{ "id": "WUA_CHEM_25K_016931", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 1.63e-10...
pH ≈ 9.79.
{ "id": "WUA_CHEM_25K_016932", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.0154 m...
pH ≈ 1.81.
{ "id": "WUA_CHEM_25K_016933", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=2.46 M, V1=79 ...
M2 = 0.319 M.
{ "id": "WUA_CHEM_25K_016934", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-36 kJ/mol, ΔS=-...
ΔG = 101.02 kJ/mol.
{ "id": "WUA_CHEM_25K_016935", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=82 kJ/mol, ΔS=19...
ΔG = -0.74 kJ/mol.
{ "id": "WUA_CHEM_25K_016936", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-189 kJ/mol, ΔS=...
ΔG = -230.11 kJ/mol.
{ "id": "WUA_CHEM_25K_016937", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.186 mol and ...
M = 0.608 mol/L.
{ "id": "WUA_CHEM_25K_016938", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 8.21e-08...
pH ≈ 7.09.
{ "id": "WUA_CHEM_25K_016939", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.44 mol, T=308 K, V=28.61 L...
P ≈ 3.922 atm.
{ "id": "WUA_CHEM_25K_016940", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.0104 m...
pH ≈ 1.98.
{ "id": "WUA_CHEM_25K_016941", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=0.95 M, V1=181...
M2 = 0.242 M.
{ "id": "WUA_CHEM_25K_016942", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-11 kJ/mol, ΔS=2...
ΔG = -106.27 kJ/mol.
{ "id": "WUA_CHEM_25K_016943", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=238 kJ/mol, ΔS=8...
ΔG = 190.37 kJ/mol.
{ "id": "WUA_CHEM_25K_016944", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=83.65 g (M=58.44 g...
Limiting reagent: A. Moles of C formed = 1.4314 mol.
{ "id": "WUA_CHEM_25K_016945", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=1.61 mol, T=265 K, V=11.04 L...
P ≈ 3.171 atm.
{ "id": "WUA_CHEM_25K_016946", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.13 mol, T=286 K, V=27.96 L...
P ≈ 0.109 atm.
{ "id": "WUA_CHEM_25K_016947", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=100.03 g (M=18.02 ...
Limiting reagent: B. Moles of C formed = 3.1709 mol.
{ "id": "WUA_CHEM_25K_016948", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=2.81 mol, T=343 K, V=25.94 L...
P ≈ 3.049 atm.
{ "id": "WUA_CHEM_25K_016949", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 6.66e-06...
pH ≈ 5.18.
{ "id": "WUA_CHEM_25K_016950", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=0.61 M, V1=228...
M2 = 0.404 M.
{ "id": "WUA_CHEM_25K_016951", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=66.62 g (M=32.0 g/...
Limiting reagent: B. Moles of C formed = 0.4315 mol.
{ "id": "WUA_CHEM_25K_016952", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=34 kJ/mol, ΔS=28...
ΔG = -140.78 kJ/mol.
{ "id": "WUA_CHEM_25K_016953", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.998 mol and ...
M = 0.370 mol/L.
{ "id": "WUA_CHEM_25K_016954", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=-249 kJ/mol, ΔS=...
ΔG = -372.80 kJ/mol.
{ "id": "WUA_CHEM_25K_016955", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 4.91e-05...
pH ≈ 4.31.
{ "id": "WUA_CHEM_25K_016956", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.24 mol, T=264 K, V=42.35 L...
P ≈ 0.123 atm.
{ "id": "WUA_CHEM_25K_016957", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.000369...
pH ≈ 3.43.
{ "id": "WUA_CHEM_25K_016958", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 1.6e-05 ...
pH ≈ 4.80.
{ "id": "WUA_CHEM_25K_016959", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=160 kJ/mol, ΔS=-...
ΔG = 200.82 kJ/mol.
{ "id": "WUA_CHEM_25K_016960", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.32 M, V1=180...
M2 = 0.326 M.
{ "id": "WUA_CHEM_25K_016961", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.00157 ...
pH ≈ 2.80.
{ "id": "WUA_CHEM_25K_016962", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.518 mol and ...
M = 0.750 mol/L.
{ "id": "WUA_CHEM_25K_016963", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.84 mol, T=281 K, V=22.22 L...
P ≈ 5.023 atm.
{ "id": "WUA_CHEM_25K_016964", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=169 kJ/mol, ΔS=1...
ΔG = 85.95 kJ/mol.
{ "id": "WUA_CHEM_25K_016965", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 8.36e-12...
pH ≈ 11.08.
{ "id": "WUA_CHEM_25K_016966", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.321 mol and ...
M = 1.326 mol/L.
{ "id": "WUA_CHEM_25K_016967", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=0.93 M, V1=248...
M2 = 0.804 M.
{ "id": "WUA_CHEM_25K_016968", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.96 M, V1=47 ...
M2 = 0.970 M.
{ "id": "WUA_CHEM_25K_016969", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=17.78 g (M=58.44 g...
Limiting reagent: A. Moles of C formed = 0.3042 mol.
{ "id": "WUA_CHEM_25K_016970", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 0.0772 m...
pH ≈ 1.11.
{ "id": "WUA_CHEM_25K_016971", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 5.01e-13...
pH ≈ 12.30.
{ "id": "WUA_CHEM_25K_016972", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.97 mol, T=318 K, V=14.94 L...
P ≈ 8.681 atm.
{ "id": "WUA_CHEM_25K_016973", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=0.5 M, V1=233 ...
M2 = 0.202 M.
{ "id": "WUA_CHEM_25K_016974", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=2.72 mol, T=253 K, V=2.07 L,...
P ≈ 27.279 atm.
{ "id": "WUA_CHEM_25K_016975", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=2.69 M, V1=42 ...
M2 = 0.448 M.
{ "id": "WUA_CHEM_25K_016976", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=1.2 mol, T=284 K, V=20.41 L,...
P ≈ 1.370 atm.
{ "id": "WUA_CHEM_25K_016977", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.47 mol, T=339 K, V=7.63 L,...
P ≈ 1.714 atm.
{ "id": "WUA_CHEM_25K_016978", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.166 mol and ...
M = 0.426 mol/L.
{ "id": "WUA_CHEM_25K_016979", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.53 mol, T=265 K, V=35.69 L...
P ≈ 2.760 atm.
{ "id": "WUA_CHEM_25K_016980", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.475 mol and ...
M = 0.598 mol/L.
{ "id": "WUA_CHEM_25K_016981", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
{ "max_tokens_hint": 220, "style_contract": "concise_formal" }
{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.36 mol, T=284 K, V=11.29 L...
P ≈ 0.743 atm.
{ "id": "WUA_CHEM_25K_016982", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=0.9 mol, T=255 K, V=24.73 L,...
P ≈ 0.762 atm.
{ "id": "WUA_CHEM_25K_016983", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tags"...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=0.776 mol and ...
M = 0.565 mol/L.
{ "id": "WUA_CHEM_25K_016984", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=3.21 mol, T=341 K, V=43.88 L...
P ≈ 2.047 atm.
{ "id": "WUA_CHEM_25K_016985", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=23.77 g (M=44.01 g...
Limiting reagent: A. Moles of C formed = 0.5401 mol.
{ "id": "WUA_CHEM_25K_016986", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=167 kJ/mol, ΔS=2...
ΔG = 32.86 kJ/mol.
{ "id": "WUA_CHEM_25K_016987", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=1.4 mol, T=289 K, V=28.14 L,...
P ≈ 1.180 atm.
{ "id": "WUA_CHEM_25K_016988", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute pH = -log10([H+]). Given [H+] = 4.04e-05...
pH ≈ 4.39.
{ "id": "WUA_CHEM_25K_016989", "domain": "master_scholars_academics", "subdomain": "chemistry_math::acid_base", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=35.7 g (M=32.0 g/m...
Limiting reagent: A. Moles of C formed = 1.1156 mol.
{ "id": "WUA_CHEM_25K_016990", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=1.96 mol, T=331 K, V=13.05 L...
P ≈ 4.079 atm.
{ "id": "WUA_CHEM_25K_016991", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=4.15 mol, T=305 K, V=46.16 L...
P ≈ 2.250 atm.
{ "id": "WUA_CHEM_25K_016992", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "t...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Use PV=nRT. Given n=3.62 mol, T=302 K, V=33.8 L,...
P ≈ 2.654 atm.
{ "id": "WUA_CHEM_25K_016993", "domain": "master_scholars_academics", "subdomain": "chemistry_math::gas_laws", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "tag...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=215 kJ/mol, ΔS=1...
ΔG = 207.74 kJ/mol.
{ "id": "WUA_CHEM_25K_016994", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0"...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute molarity M = n/V. Given n=1.049 mol and ...
M = 0.550 mol/L.
{ "id": "WUA_CHEM_25K_016995", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=113.47 g (M=58.44 ...
Limiting reagent: A. Moles of C formed = 1.9416 mol.
{ "id": "WUA_CHEM_25K_016996", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=113.61 g (M=18.02 ...
Limiting reagent: B. Moles of C formed = 0.1416 mol.
{ "id": "WUA_CHEM_25K_016997", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "...
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Compute ΔG = ΔH - TΔS. Given ΔH=44 kJ/mol, ΔS=17...
ΔG = -43.26 kJ/mol.
{ "id": "WUA_CHEM_25K_016998", "domain": "master_scholars_academics", "subdomain": "chemistry_math::thermodynamics", "task": "quantitative_reasoning", "difficulty": "core", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", ...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Dilution: M1*V1 = M2*V2. Given M1=1.64 M, V1=220...
M2 = 0.490 M.
{ "id": "WUA_CHEM_25K_016999", "domain": "master_scholars_academics", "subdomain": "chemistry_math::solutions", "task": "quantitative_reasoning", "difficulty": "archon", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0", "ta...
[ { "source_title": "Self-contained in prompt", "source_url": "", "evidence_type": "self_contained", "accessed_at_utc": "2026-01-04T05:02:58" } ]
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{ "messages": [ { "role": "system", "content": "You are WithinUsAI Master Scholars Chemistry Quantitative Reasoning. Use the formula provided. Show minimal steps and give the final answer with units." }, { "role": "user", "content": "Reaction: A + 2B → C. mass(A)=32.56 g (M=58.44 g...
Limiting reagent: A. Moles of C formed = 0.5572 mol.
{ "id": "WUA_CHEM_25K_017000", "domain": "master_scholars_academics", "subdomain": "chemistry_math::stoichiometry", "task": "quantitative_reasoning", "difficulty": "advanced", "truth_mode": "self_contained_math", "wrapper": "minimal_chain", "created_utc": "2026-01-04T05:02:58", "license": "cc-by-4.0",...
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