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2016-10-18
Light emission, light detection and strain sensing with nanocrystalline graphene
Graphene is of increasing interest for optoelectronic applications exploiting light detection, light emission and light modulation. Intrinsically light matter interaction in graphene is of a broadband type. However by integrating graphene into optical micro cavities also narrow band light emitters and detectors have been demonstrated. The devices benefit from the transparency, conductivity and processability of the atomically thin material. To this end we explore in this work the feasibility of replacing graphene by nanocrystalline graphene, a material which can be grown on dielectric surfaces without catalyst by graphitization of polymeric films. We have studied the formation of nanocrystalline graphene on various substrates and under different graphitization conditions. The samples were characterized by resistance, optical transmission, Raman, X-ray photoelectron spectroscopy, atomic force microscopy and electron microscopy measurements. The conducting and transparent wafer-scale material with nanometer grain size was also patterned and integrated into devices for studying light-matter interaction. The measurements show that nanocrystalline graphene can be exploited as an incandescent emitter and bolometric detector similar to crystalline graphene. Moreover the material exhibits piezoresistive behavior which makes nanocrystalline graphene interesting for transparent strain sensors.
1610.05513v1
2017-02-01
Pore ordering in mesoporous matrices induced by different directing agents
Mesoporous silica particles of MCM-41 type were synthesized by sol-gel method from tetraethyl orthosilicate (TEOS) in 2-methoxyethanol and deionized water mixture in base conditions at room temperature. Ammonia or sodium hydroxides were used as catalysts and cetyl-trimethylammonium bromide (CTAB) and n-dodecyl-trimethylammonium bromide (DTAB) as structure directing agents. The porosities and the ordered structure have been analyzed using transmission and scanning electron microscopy, small angle neutron and X-ray diffraction, nitrogen adsorption, thermal analysis and FTIR spectroscopy. The samples consist of spherical particles of sub-micrometer size, with radially arranged pores. The comparison of the effect of the different surfactants and catalysts shows that by varying the surfactant type and their proportion, the pore sizes can be controlled. As compared to the commonly used ammonia catalyst, the use of NaOH as catalyst results in a much smaller porosity of the as-prepared materials. These materials are not resisting to the heat treatment at 700 C used for the template removal, and the ordered porous structure is completely lost.
1702.00366v1
2017-10-27
Materials considerations for forming the topological insulator phase in InAs/GaSb heterostructures
In an ideal InAs/GaSb bilayer of appropriate dimension in-plane electron and hole bands overlap and hybridize, and a topologically non-trivial, or quantum spin Hall (QSH) insulator, phase is predicted to exist. The in-plane dispersion's potential landscape, however, is subject to microscopic perturbations originating from material imperfections. In this work, the effect of disorder on the electronic structure of InAs/GaSb bilayers was studied by the temperature and magnetic field dependence of the resistance of a dual-gated heterostructures gate-tuned through the inverted to normal gap regimes. Conduction in the inverted (predicted topological) regime was qualitatively similar to behavior in a disordered two-dimensional system. The impact of charged impurities and interface roughness on the formation of topologically protected edge states and an insulating bulk was estimated. The experimental evidence and estimates of disorder in the potential landscape indicated the potential fluctuations in state-of-the-art films are sufficiently strong such that conduction in the predicted topological insulator (TI) regime was dominated by a symplectic metal phase rather than a TI phase. The implications are that future efforts must address disorder in this system and focus must be placed on the reduction of defects and disorder in these heterostructures if a TI regime is to be achieved.
1710.10095v1
2014-08-05
Emergent surface superconductivity of nanosized Dirac puddles in a topological insulator
Surfaces of three-dimensional topological insulators have emerged as one of the most remarkable states of condensed quantum matter1-5 where exotic electronic phases of Dirac particles should arise1,6-8. Here we report a discovery of surface superconductivity in a topological material (Sb2Te3) with resistive transition at a temperature of ~9 K induced through a minor tuning of growth chemistry that depletes bulk conduction channels. The depletion shifts Fermi energy towards the Dirac point as witnessed by about two orders of magnitude reduction of carrier density and by very large (~25,000 cm^2/Vs) carrier mobility. Direct evidence from scanning tunneling spectroscopy and from magnetic response show that the superconducting condensate forms in surface puddles at unprecedentedly higher temperatures, near 60 K and above. The new superconducting state we observe to emerge in puddles can be tuned by the topological material's parameters such as Fermi velocity and mean free path through band engineering; it could potentially become a hunting ground for Majorana modes6 and lead to a disruptive paradigm change9 in how quantum information is processed.
1408.1046v1
2019-07-31
Coexisting 1T/2H polymorphs, reentrant resistivity behavior, and charge distribution in MoS2-hBN 2D/2D composite thin films
In view of their immensely intriguing properties, two dimensional materials are being intensely researched in search of novel phenomena and diverse application interests, however, studies on the realization of nanocomposites in the application-worthy thin-film platform are rare. Here we have grown MoS2-hBN composite thin films on different substrates by the pulsed laser deposition technique and made comparative studies with the pristine MoS2 and hBN films. The Raman, XPS and HRTEM confirm the concomitant presence of both the 1T (conducting) and 2H (semiconducting) polymorphs of MoS2 in the composite film. Interestingly, a peculiar reentrant semiconductor-metal-insulator transition is seen in the composite film which is absent in the MoS2 film, and it correlates well with the signatures of phonon softening seen in temperature-dependent Raman spectroscopy. Furthermore, electrostatic force microscopy reveals the presence of three distinct regions (metallic, semiconducting, and insulating) in the composite film with differing contact potentials and enhanced propensity for charge transfer with respect to pristine MoS2. A triboelectric nanogenerator device containing biphasic composite film as an electron acceptor exhibits more than twofold (sixfold) enhancement in peak-to-peak output voltage as compared to the pristine MoS2 (hBN) film. These observations bring out the potential of nanocomposite thin films for unfolding emergent phenomena and technological applications.
1907.13522v1
2022-02-21
Towards fully two-dimensional spintronic devices
Within the field of spintronics major efforts are directed towards developing applications for spin-based transport devices made fully out of two-dimensional (2D) materials. In this work we present an experimental realization of a spin-valve device where the generation of the spin signal is exclusively attributed to the spin-dependent conductivity of the magnetic graphene resulting from the proximity of an interlayer antiferromagnet, CrSBr. We clearly demonstrate that the usage of the conventional 3D magnetic contacts, that are commonly air-sensitive and incompatible with practical technologies, can be fully avoided when graphene/CrSBr heterostructures are employed. Moreover, apart from providing exceptionally long spin relaxation length, the usage of graphene for both generation and transport of the spin allows to automatically avoid the conductivity mismatch between the source and the channel circuits that has to be considered when using conventional low-resistive contacts. Our results address a necessary step in the engineering of spintronic circuitry out of layered materials and precede further developments in the area of complex spin-logic devices. Moreover, we introduce a fabrication procedure where we designed and implemented a recipe for the preparation of electrodes via a damage-free technique that offers an immediate advantage in the fields of air-sensitive and delicate organic materials.
2202.09972v1
2016-03-10
Möbius Kondo Insulators
Heavy fermion materials have recently attracted attention for their potential to combine topological protection with strongly correlated electron physics. To date, the ideas of topological protection have been restricted to the heavy fermion or "Kondo" insulators with the simplest point-group symmetries. Here we argue that the presence of nonsymmorphic crystal symmetries in many heavy fermion materials opens up a new family of topologically protected heavy electron systems. Re-examination of archival resistivity measurements in nonsymmorphic heavy fermion insulators Ce$_3$Bi$_4$Pt$_3$ and CeNiSn reveals the presence of low temperature conductivity plateau, making them candidate members of the new class of material. We illustrate our ideas with a specific model for CeNiSn, showing how glide symmetries generate surface states with a novel Mobius braiding that can be detected by ARPES or non-local conductivity measurements. One of the interesting effects of strong correlation, is the development of partially localization or "Kondo breakdown" on the surfaces, which transforms Mobius surface states into quasi-one dimensional conductors, with the potential for novel electronic phase transitions.
1603.03435v4
2017-07-14
Mesoscale simulations of confined Nafion thin films
The morphology and transport properties of thin films of the ionomer Nafion, with thicknesses on the order of the bulk cluster size, have been investigated as a model system to explain the anomalous behaviour of catalyst/electrode-polymer interfaces in membrane-electrode assemblies. We have employed dissipative particle dynamics (DPD) to investigate the interaction of water and fluorocarbon chains with carbon and quartz as confining materials for a wide range of operational water contents and film thicknesses. We found confinement-induced clustering of water perpendicular to the thin film. Hydrophobic carbon forms a water depletion zone near the film interface, whereas hydrophilic quartz results in a zone with excess water. There are, on average, oscillating water-rich and fluorocarbon-rich regions, in agreement with experimental results from neutron reflectometry. Water diffusivity shows increasing directional anisotropy of up to 30% with decreasing film thickness, depending of the confining material. The percolation analysis revealed significant differences in water clustering and connectivity with the confining material. These findings indicate the fundamentally different nature of ionomer thin films, compared to membranes, and suggest explanations for increased ionic resistances observed in the catalyst layer.
1707.04604v3
2017-07-27
SRF Theory Developments from the Center for Bright Beams
We present theoretical studies of SRF materials from the Center for Bright Beams. First, we discuss the effects of disorder, inhomogeneities, and materials anisotropy on the maximum parallel surface field that a superconductor can sustain in an SRF cavity, using linear stability in conjunction with Ginzburg-Landau and Eilenberger theory. We connect our disorder mediated vortex nucleation model to current experimental developments of Nb$_3$Sn and other cavity materials. Second, we use time-dependent Ginzburg-Landau simulations to explore the role of inhomogeneities in nucleating vortices, and discuss the effects of trapped magnetic flux on the residual resistance of weakly- pinned Nb$_3$Sn cavities. Third, we present first-principles density-functional theory (DFT) calculations to uncover and characterize the key fundamental materials processes underlying the growth of Nb$_3$Sn. Our calculations give us key information about how, where, and when the observed tin-depletedregions form. Based on this we plan to develop new coating protocols to mitigate the formation of tin depleted regions.
1707.09025v1
2019-12-13
Strength, transformation toughening and fracture dynamics of rocksalt-structure Ti1-xAlxN (0 <= x <= 0.75) alloys
Ab initio-calculated ideal strength and toughness describe the upper limits for mechanical properties attainable in real systems and can, therefore, be used in selection criteria for materials design. We employ density-functional ab initio molecular dynamics (AIMD) to investigate the mechanical properties of defect-free rocksalt-structure (B1) TiN and B1 Ti1-xAlxN (x = 0.25, 0.5, 0.75) solid solutions subject to [001], [110], and [111] tensile deformation at room temperature. We determine the alloys' ideal strength and toughness, elastic responses, and ability to plastically deform up to fracture as a function of the Al content. Overall, TiN exhibits greater ideal moduli of resilience and tensile strengths than TiAlN solid solutions. Nevertheless, AIMD modelingshows that, irrespective of the strain direction, the binary compound systematically fractures by brittle cleavage at its yield point. The simulations also indicate that Ti0.5Al0.5N and Ti0.25Al0.75N solid solutions are inherently more resistant to fracture and possess much greater toughness than TiN, due to the activation of local structural transformations (primarily of B1 -> wurtzite type) beyond the elastic-response regime. In sharp contrast, TiAlN alloys with 25% Al exhibit similar brittleness as TiN. The results of this work are examples of the limitations of elasticity-based criteria for prediction of strength, brittleness, ductility, and toughness in materials able to undergo phase transitions with loading. Furthermore, comparing present and previous findings, we suggest a general principle for design of hard ceramic solid solutions that are thermodynamically inclined to dissipate extreme mechanical stresses via transformation toughening mechanisms.
1912.06367v2
2015-04-02
Thermoelectric Signal Enhancement by Reconciling the Spin Seebeck and Anomalous Nernst Effects in Ferromagnet/Non-magnet Multilayers
The utilization of ferromagnetic (FM) materials in thermoelectric devices allows one to have a simpler structure and/or independent control of electric and thermal conductivities, which may further remove obstacles for this technology to be realized. The thermoelectricity in FM/non-magnet (NM) heterostructures using an optical heating source is studied as a function of NM materials and a number of multilayers. It is observed that the overall thermoelectric signal in those structures which is contributed by spin Seebeck effect and anomalous Nernst effect (ANE) is enhanced by a proper selection of NM materials with a spin Hall angle that matches to the sign of the ANE. Moreover, by an increase of the number of multilayer, the thermoelectric voltage is enlarged further and the device resistance is reduced, simultaneously. The experimental observation of the improvement of thermoelectric properties may pave the way for the realization of magnetic-(or spin-) based thermoelectric devices.
1504.00642v1
2018-07-02
Electron-electron interactions of the multi-Cooper-pairs in the 1D limit and their role in the formation of global phase coherence in quasi-one-dimensional superconducting nanowire arrays
Nanostructuring of superconducting materials to form dense arrays of thin parallel nanowires with significantly large transverse Josephson coupling has proven to be an effective way to increase the upper critical field of superconducting elements by as much as two orders of magnitude as compared to the corresponding bulk materials and, in addition, may cause considerable enhancements in their critical temperatures. Such materials have been realized in the linear pores of mesoporous substrates or exist intrinsically in the form of various quasi-1D crystalline materials. The transverse coupling between the superconducting nanowires is determined by the size-dependent coherence length E0. In order to obtain E0 over the Langer-Ambegaokar- McCumber-Halperin (LAMH) theory, extensive experimental fitting parameters have been required over the last 40 years. We propose a novel Monte Carlo algorithm for determining E0 of the multi-Cooper pair system in the 1D limit. The concepts of uncertainty principle, Pauli-limit, spin flip mechanism, electrostatic interaction, thermal perturbation and co-rotating of electrons are considered in the model. We use Pb nanowires as an example to monitor the size effect of E0 as a result of the modified electron-electron interaction without the need for experimental fitting parameters. We investigate how the coherence length determines the transverse coupling of nanowires in dense arrays. This determines whether or not a global phase-coherent state with zero resistance can be formed in such arrays. Our Monte Carlo results are in very good agreement with experimental data from various types of superconducting nanowire arrays
1807.00611v1
2018-07-30
Tunable Thermal Energy Transport across Diamond Membranes and Diamond-Si Interfaces by Nanoscale Graphoepitaxy
The development of electronic devices, especially those that involve heterogeneous integration of materials, has led to increased challenges in addressing their thermal operational-temperature demands. The heat flow in these systems is significantly influenced or even dominated by thermal boundary resistance at interface between dissimilar materials. However, controlling and tuning heat transport across an interface and in the adjacent materials has so far drawn limited attention. In this work, we grow chemical-vapor-deposited (CVD) diamond on silicon substrates by graphoepitaxy and experimentally demonstrate tunable thermal transport across diamond membranes and diamond-silicon interfaces. We observed the highest diamond-silicon thermal boundary conductance (TBC) measured to date and increased diamond thermal conductivity due to strong grain texturing in the diamond near the interface. Additionally, non-equilibrium molecular-dynamics (NEMD) simulations and a Landauer approach are used to understand the diamond-silicon TBC. These findings pave the way for tuning or increasing thermal conductance in heterogeneously integrated electronics that involve polycrystalline materials and will impact applications including electronics thermal management and diamond growth.
1807.11400v2
2019-10-28
Tailored Graphenic Structures Directly Grown on Titanium Oxide Boost the Interfacial Charge Transfer
The successful application of titanium oxide-graphene hybrids in the fields of photocatalysis, photovoltaics and photodetection strongly depends on the interfacial contact between both materials. The need to provide a good coupling between the enabling conductor and the photoactive phase prompted us to directly grow conducting graphenic structures on TiO2 crystals. We here report on the direct synthesis of tailored graphenic structures by using Plasma Assisted Chemical Vapour Deposition that present a clean junction with the prototypical titanium oxide (110) surface. Chemical analysis of the interface indicates chemical bonding between both materials. Photocurrent measurements under UV light illumination manifest that the charge transfer across the interface is efficient. Moreover, the influence of the synthesis atmosphere, gas precursor (C2H2) and diluents (Ar, O2), on the interface and on the structure of the as-grown graphenic material is assessed. The inclusion of O2 promotes vertical growth of partially oxidized carbon nanodots/rods with controllable height and density. The deposition with Ar results in continuous graphenic films with low resistivity (6.8x10-6 ohm x m). The synthesis protocols developed here are suitable to produce tailored carbon-semiconductor structures on a variety of practical substrates as thin films, pillars or nanoparticles.
1910.12667v1
2020-08-23
Nanofibril-mediated Fracture Resistance of Bone
Natural hard composites like human bone possess a combination of strength and toughness that exceeds that of their constituents and of many engineered composites. This augmentation is attributed to their complex hierarchical structure, spanning multiple length scales; in bone, characteristic dimensions range from nanoscale fibrils to microscale lamellae to mesoscale osteons and macroscale organs. The mechanical properties of bone have been studied, with the understanding that the isolated microstructure at micro- and nano-scales gives rise to superior strength compared to that of whole tissue, and the tissue possesses an amplified toughness relative to that of its nanoscale constituents. Nanoscale toughening mechanisms of bone are not adequately understood at sample dimensions that allow for isolating salient microstructural features, because of the challenge of performing fracture experiments on small-sized samples. We developed an in-situ three-point bend experimental methodology that probes site-specific fracture behavior of micron-sized specimens of hard material. Using this, we quantify crack initiation and growth toughness of human trabecular bone with sharp fatigue pre-cracks and blunt notches. Our findings indicate that bone with fatigue cracks is two times tougher than that with blunt cracks. In-situ data-correlated electron microscopy videos reveal this behavior arises from crack-bridging by nanoscale fibril structure. The results reveal a transition between fibril-bridging (~1 $\mu$m) and crack deflection/twist (~500 $\mu$m) as a function of length-scale, and quantitatively demonstrate hierarchy-induced toughening in a complex material. This versatile approach enables quantifying the relationship between toughness and microstructure in various complex material systems and provides direct insight for designing biomimetic composites.
2008.09955v1
2020-10-28
Statistical analysis of the material, geometrical and imperfection characteristics of structural stainless steels and members
Traditional member-based two-step design approaches included in current structural codes for steel structures, as well as more recent system-based direct-design alternatives, require building rigorous structural reliability frameworks for the calibration of partial coefficients (resistance factors) to achieve specified target reliability requirements. Key design parameters affecting the strength of structures and their random variations are generally modelled by nominal or characteristic values in design standards, which are combined with partial coefficients that need to be calibrated from measurements on real samples. While the statistical characterization of material and geometric properties of structural steels has been consolidated over the last decades, information about the characterization of structural stainless steels is virtually non-existent due to the limited pool of available data. Thus, this paper presents the basic ingredient for developing reliability frameworks for stainless steel structures and components by statistically characterizing the main random parameters affecting their strength through a comprehensive database collected from the literature. Based on the collected data, appropriate probabilistic models are proposed for geometric properties, material properties, imperfections and residual stresses of different stainless steel alloys and cross-section or product types. The data is equally applicable to member-based reliability analyses as described in existing codes and system-based analyses targeted at the direct-design of stainless steel structures by advanced analysis.
2010.14777v2
2020-11-03
Fully-Compensated Ferrimagnetic Spin Filter Materials within the Cr$\textit{M}\textit{N}$Al Equiatomic Quaternary Heusler Alloys
XX'YZ equiatomic quaternary Heusler alloys (EQHA's) containing Cr, Al, and select Group IVB elements ($\textit{M}$ = Ti, Zr, Hf) and Group VB elements ($\textit{N}$ = V, Nb, Ta) were studied using state-of-the-art density functional theory to determine their effectiveness in spintronic applications. Each alloy is classified based on their spin-dependent electronic structure as a half-metal, a spin gapless semiconductor, or a spin filter material. We predict several new fully-compensated ferrimagnetic spin filter materials with small electronic gaps and large exchange splitting allowing for robust spin polarization with small resistance. CrVZrAl, CrVHfAl, CrTiNbAl, and CrTiTaAl are identified as particularly robust spin filter candidates with an exchange splitting of $\sim 0.20$ eV. In particular, CrTiNbAl and CrTiTaAl have exceptionally small band gaps of $\sim 0.10$ eV. Moreover, in these compounds, a spin asymmetric electronic band gap is maintained in 2 of 3 possible atomic arrangements they can take, making the electronic properties less susceptible to random site disorder. In addition, hydrostatic stress is applied to a subset of the studied compounds in order to determine the stability and tunability of the various electronic phases. Specifically, we find the CrAlV$\textit{M}$ subfamily of compounds to be exceptionally sensitive to hydrostatic stress, yielding transitions between all spin-dependent electronic phases.
2011.01389v1
2020-12-02
Strain-induced anion ordering in perovskite oxyfluoride films
Anionic ordering is a promising route to engineer physical properties in functional heteroanionic materials. A central challenge in the study of anion-ordered compounds lies in developing robust synthetic strategies to control anion occupation and in understanding the resultant implications for electronic structure. Here, we show that epitaxial strain induces preferential occupation of F and O on the anion sites in perovskite oxyfluoride SrMnO2.5-dFg films grown on different substrates. Under compressive strain, F tends to take the apical-like sites, which was revealed by F and O K-edge linearly polarized x-ray absorption spectroscopy and density functional theory calculations, resulting in an enhanced c-axis expansion. Under tensile strain, F tends to take the equatorial-like sites, enabling the longer Mn-F bonds to lie within the plane. The anion ordered oxyfluoride films exhibit a significant orbital polarization of the 3d electrons, distinct F-site dependence to their valence band density of states, and an enhanced resistivity when F occupies the apical-like anion site compared to the equatorial-like site. By demonstrating a general strategy for inducing anion-site order in oxyfluoride perovskites, this work lays the foundation for future materials design and synthesis efforts that leverage this greater degree of atomic control to realize new polar or quasi-two-dimensional materials.
2012.01221v1
2021-02-06
Multiple charge density waves and superconductivity nucleation at antiphase domain walls in the nematic pnictide Ba$_{1-x}$Sr$_{x}$Ni$_{2}$As$_{2}$
How superconductivity interacts with charge or nematic order is one of the great unresolved issues at the center of research in quantum materials. Ba$_{1-x}$Sr$_{x}$Ni$_{2}$As$_{2}$ (BSNA) is a charge ordered pnictide superconductor recently shown to exhibit a six-fold enhancement of superconductivity due to nematic fluctuations near a quantum phase transition (at $x_c=0.7$). The superconductivity is, however, anomalous, with the resistive transition for $0.4 < x< x_c$ occurring at a higher temperature than the specific heat anomaly. Using x-ray scattering, we discovered a new charge density wave (CDW) in BSNA in this composition range. The CDW is commensurate with a period of two lattice parameters, and is distinct from the two CDWs previously reported in this material. We argue that the anomalous transport behavior arises from heterogeneous superconductivity nucleating at antiphase domain walls in this CDW. We also present new data on the incommensurate CDW, previously identified as being unidirectional, showing that is a rotationally symmetric, "4$Q$" state with $C_4$ symmetry. Our study establishes BSNA as a rare material containing three distinct CDWs, and an exciting testbed for studying coupling between CDW, nematic, and SC orders.
2102.03592v2
2021-04-29
Competing magnetic interactions and magnetoresistance anomalies in cubic intermetallic compounds, Gd4RhAl and Tb4RhAl, and enhanced magnetocaloric effect for the Tb case
We report complex magnetic, magnetoresistance (MR) and magnetocaloric properties of Gd4RhAl and Tb4RhAl forming in the Gd4RhIn type cubic structure. Though the synthesis of the compounds was reported long ago, to our knowledge, no attempt was made to investigate the properties of these compounds. The present results of ac and dc magnetization, electrical resistivity and heat-capacity measurements down to 1.8 K establish that these compounds undergo antiferromagnetic order initially, followed by complex spin-glass features with decreasing temperature. These characteristic temperatures are: For Gd case, TN is about 46K and TG is about 21 K, and for Tb, about 32 and 28 K respectively. Additionally, there are field induced magnetic effects, interestingly leading to non-monotonic variations in MR. There is a significant MR over a wide temperature range above TN, similar to the behavior of magnetocaloric effect (MCE) as measured by isothermal entropy change (DeltaS). An intriguing finding we made is that DeltaS at the onset of magnetic order is significantly larger for the Tb compound than that observed for the Gd analogue near its TN. On the basis of this observation in a cubic material, we raise a question whether aspherical nature of the 4f orbital can play a role to enhance MCE under favorable circumstances, a clue that could be useful to find materials for magnetocaloric applications.
2104.14521v1
2021-10-12
Bridging the Band Gap: What Device Physicists Need to Know About Machine Learning
This article surveys the landscape of semiconductor materials and devices research for the acceleration of machine learning (ML) algorithms. We observe a disconnect between the semiconductor and device physics and engineering communities, and the digital logic and computer hardware architecture communities. The article first provides an overview of the principles of computational complexity and fundamental physical limits to computing and their relation to physical systems. The article then provides an introduction to ML by presenting three key components of ML systems: representation, evaluation, and optimisation. The article then discusses and provides examples of the application of emerging technologies from the demiconductor and device physics domains as solutions to computational problems, alongside a brief overview of emerging devices for computing applications. The article then reviews the landscape of ML accelerators, comparing fixed-function and reprogrammable digital logic with novel devices such as memristors, resistive memories, magnetic memories, and probabilistic bits. We observe broadly lower performance of ML accelerators based on novel devices and materials when compared to those based on digital complimentary metal-oxide semiconductor (CMOS) technology, particularly in the MNIST optical character recognition task, a common ML benchmark, and also highlight the lack of a trend of progress in approaches based on novel materials and devices. Lastly, the article proposes figures of merit for meaningful evaluation and comparison of different ML implementations in the hope of fostering a dialogue between the materials science, device physics, digital logic, and computer architecture communities by providing a common frame of reference for their work.
2110.05910v2
2021-11-15
In situ Bragg coherent X-ray diffraction imaging of corrosion in a Co-Fe alloy microcrystal
Corrosion is a major concern for many industries, as corrosive environments can induce structural and morphological changes that lead to material dissolution and accelerate material failure. The progression of corrosion depends on nanoscale morphology, stress, and defects present. Experimentally monitoring this complex interplay is challenging. Here we implement in situ Bragg coherent X-ray diffraction imaging (BCDI) to probe the dissolution of a Co-Fe alloy microcrystal exposed to hydrochloric acid (HCl). By measuring five Bragg reflections from a single isolated microcrystal at ambient conditions, we compare the full three-dimensional (3D) strain state before corrosion and the strain along the [111] direction throughout the corrosion process. We find that the strained surface layer of the crystal dissolves to leave a progressively less strained surface. Interestingly, the average strain closer to the centre of the crystal increases during the corrosion process. We determine the localised corrosion rate from BCDI data, revealing the preferential dissolution of facets more exposed to the acid stream, highlighting an experimental geometry effect. These results bring new perspectives to understanding the interplay between crystal strain, morphology, and corrosion; a prerequisite for the design of more corrosion-resistant materials.
2111.07903v5
2021-12-16
Observation and manipulation of a phase separated state in a charge density wave material
The 1T polytype of TaS$_\textrm{2}$ has been studied extensively as a strongly correlated system. As 1T-TaS$_\textrm{2}$ is thinned towards the 2D limit, its phase diagram shows significant deviations from that of the bulk material. Optoelectronic maps of ultrathin 1T-TaS$_\textrm{2}$ have indicated the presence of non-equilibrium charge density wave phases within the hysteresis region of the nearly commensurate (NC) to commensurate (C) transition. We perform scanning tunneling microscopy on exfoliated ultrathin flakes of 1T-TaS$_\textrm{2}$ within the NC-C hysteresis window, finding evidence that the observed non-equilibrium phases consist of intertwined, irregularly shaped NC-like and C-like domains. After applying lateral electrical signals to the sample we image changes in the geometric arrangement of the different regions. We use a phase separation model to explore the relationship between electronic inhomogeneity present in ultrathin 1T-TaS$_\textrm{2}$ and its bulk resistivity. These results demonstrate the role of phase competition morphologies in determining the properties of 2D materials.
2112.09240v1
2022-03-17
Quasi-static crack front deformations in cohesive materials
When a crack interacts with material heterogeneities, its front distorts and adopts complex tortuous configurations that are reminiscent of the energy barriers encountered during crack propagation. As such, the study of crack front deformations is key to rationalize the effective failure properties of micro-structured solids and interfaces. Yet, the impact of a localized dissipation in a finite region behind the crack front, called the process zone, has often been overlooked. In this work, we derive the equation ruling 3D coplanar crack propagation in heterogeneous cohesive materials where the opening of the crack is resisted by some traction in its wake. We show that the presence of a process zone results in two competing effects on the deformation of crack fronts: (i) it makes the front more compliant to small-wavelength perturbations, and (ii) it smooths out local fluctuations of strength and process zone size, from which emerge heterogeneities of fracture energy. Their respective influence on front deformations is shown to strongly impact the stability of perturbed crack fronts, as well as their stationary shapes when interacting with arrays of tough obstacles. Overall, our theory provides a unified framework to predict the variety of front profiles observed in experiments, even when the small-scale yielding hypothesis of linear elastic fracture mechanics breaks down.
2203.09317v2
2022-05-11
Reversible Tuning of Superconductivity in Ion-Gated NbN Ultrathin Films by Self-Encapsulation with a High-$κ$ Dielectric Layer
Ionic gating is a powerful technique for tuning the physical properties of a material via electric field-induced charge doping, but is prone to introduce extrinsic disorder and undesired electrochemical modifications in the gated material beyond pure electrostatics. Conversely, reversible, volatile and electrostatic modulation is pivotal in the reliable design and operation of novel device concepts enabled by the ultrahigh induced charge densities attainable via ionic gating. Here we demonstrate a simple and effective method to achieve reversible and volatile gating of surface-sensitive ultrathin niobium nitride films via controlled oxidation of their surface. The resulting niobium oxide encapsulation layer exhibits a capacitance comparable to that of non-encapsulated ionic transistors, withstands gate voltages beyond the electrochemical stability window of the gate electrolyte, and enables a fully-reversible tunability of both the normal-state resistivity and the superconducting transition temperature of the encapsulated films. Our approach should be transferable to other materials and device geometries where more standard encapsulation techniques are not readily applicable.
2205.05491v3
2022-06-07
Observation of surface superconductivity in a three-dimensional Dirac material
Superconductivity becomes more interesting when it encounters dimensional constraint or topology, because it is of importance for exploring exotic quantum phenomena or developing superconducting electronics. Here we report the coexistence of naturally formed surface superconducting state and three-dimensional topological Dirac state in single crystals of BaMg$_2$Bi$_2$. The electronic structure obtained from the first-principles calculations demonstrates that BaMg$_2$Bi$_2$ is an ideal Dirac material, in which the Dirac point is very close to the Fermi level and no other energy band crosses the Fermi level. Superconductivity up to 4.77 K can be observed under ambient pressure in the measurements of resistivity. The angle dependent magnetoresistance reveals the two-dimensional characteristic of superconductivity, indicating that superconductivity occurs on the surface of the sample and is absent in the bulk state. Our study not only provides BaMg$_2$Bi$_2$ as a suitable platform to study the interplay between superconductivity and topological Dirac state, but also indicates that MgBi-based materials may be a promising system for exploring new superconductors.
2206.03405v1
2022-10-03
Interwoven atypical quantum states in CeLiBi$_2$
We report the discovery of CeLiBi$_2$, the first example of a material in the tetragonal Ce$TX_2$ ($T$ = transition metal; $X$ = pnictogen) family wherein an alkali cation replaces the typical transition metal. Magnetic susceptibility and neutron powder diffraction measurements are consistent with a crystal-field $\Gamma_6$ ground state Kramers doublet that orders antiferromagnetically below $T_N = 3.4$ K with an incommensurate propagation wave vector ${\bf{k}} = (0, 0.0724(4), 0.5)$ that generates a nanometric modulation of the magnetic structure. The best model of the ordered state is an elliptical cycloid with Ce moments primarily residing in the $ab$ plane. This is highly unusual, as all other $\Gamma_6$ Ce$TX_2$ members order ferromagnetically. Further, we observe an atypical hard-axis metamagnetic transition at $2$ T in magnetostriction, magnetization, and resistivity measurements. CeLiBi$_2$ is a rare example of a highly conductive material with dominant skew scattering leading to a large anomalous Hall effect. Quantum oscillations with five frequencies arise in magnetostriction and magnetic susceptibility data to $T = 30$ K and $\mu_0H = 55$ T, which indicate small Fermi pockets of light carriers with effective masses as low as 0.07$m_e$. Density functional theory calculations indicate that square-net Dirac-like Bi$-p$ bands are responsible for these ultralight carriers. Together, our results show that CeLiBi$_2$ enables multiple atypical magnetic and electronic properties in a single clean material.
2210.01031v2
2022-11-27
Ionic Peltier Effect in Li-Ion Electrolytes
The coupled transport of charge and heat provide fundamental insights into the microscopic thermodynamics and kinetics of materials. We describe a sensitive ac differential resistance bridge that enables measurements of the temperature difference on two sides of a coin cell with a resolution of better than 10 uK. We use this temperature difference metrology to determine the ionic Peltier coefficients of symmetric Li-ion electrochemical cells as a function of Li salt concentration, solvent composition, electrode material, and temperature. The Peltier coefficients {\Pi} are negative, i.e., heat flows in the direction opposite to the drift of Li ions in the applied electric field, large, 30 kJ mol-1, and increase with increasing temperature at T > 300 K. The Peltier coefficient is approximately constant on time scales that span the characteristic time for mass diffusion across the thickness of the electrolyte, suggesting that heat of transport plays a minor role in comparison to the changes in partial molar entropy of Li at the interface between the electrode and electrolyte. Our work demonstrates a new platform for studying the non-equilibrium thermodynamics of electrochemical cells and provides a window into the transport properties of electrochemical materials through measurements of temperature differences and heat currents that complement traditional measurements of voltages and charge currents.
2211.14949v2
2023-03-28
A model for critical current effects in point-contact Andreev-reflection spectroscopy
It is well known that point-contact Andreev reflection spectroscopy provides reliable measurements of the energy gap(s) in a superconductor when the contact is in the ballistic or nearly-ballistic regime. However, especially when the mean free path of the material under study is small, obtaining ballistic contacts can be a major challenge. One of the signatures of a Maxwell contribution to the contact resistance is the presence of "dips" in the differential conductance, associated to the sudden appearance of a Maxwell term, in turn due to the attainment of the critical current of the material in the contact region. Here we show that, using a proper model for the $R(I)$ of the material under study, it is possible to fit the experimental curves (without the need of normalization) obtaining the correct values of the gap amplitudes even in the presence of such dips, as well as the temperature dependence of the critical current in the contact. We present a test of the procedure in the case of Andreev-reflection spectra in Mg$_{0.85}$Al$_{0.15}$B$_2$ single crystals.
2303.15968v2
2023-05-12
Striation lines in intermittent fatigue crack growth in an Al alloy
Fatigue failure of crystalline materials is a difficult problem in science and engineering, and recent results have shown that fatigue crack growth can occur in intermittent jumps which have fat-tailed distributions. As fatigue crack propagation is known to leave markings -- called striations -- on the fracture surface, the distances between these should also have fat-tailed distributions, if the crack propagation is intermittent. Here, we combine macroscale crack tip tracking in fatigue crack growth measurements of aluminum 5005 samples with \emph{post-mortem} scanning electron microscopy imaging of the striation lines. We introduce two different methods for extracting the striation line spacing from the images. What we find is a similar distribution of striation spacings as jump sizes using one of our methods, but the average striation spacing does not correlate with the crack growth rate. We conclude that we observe avalanche-like crack propagation, reflected in both the macroscale crack tip tracking as well as the analysis of the fracture surfaces. Our results show that the fracture surfaces can be used to study the intermittency of fatigue crack propagation and in development of crack-resistant materials. The advantages and disadvantages of the two methods introduced are discussed.
2305.07460v1
2023-07-07
Observation of the anomalous Hall effect in a layered polar semiconductor
Progress in magnetoelectric materials is hindered by apparently contradictory requirements for time-reversal symmetry broken and polar ferroelectric electronic structure in common ferromagnets and antiferromagnets. Alternative routes could be provided by recent discoveries of a time-reversal symmetry breaking anomalous Hall effect in noncollinear magnets and altermagnets, but hitherto reported bulk materials are not polar. Here, we report the observation of a spontaneous anomalous Hall effect in doped AgCrSe$_2$, a layered polar semiconductor with an antiferromagnetic coupling between Cr spins in adjacent layers. The anomalous Hall resistivity 3 $\mu\Omega$ cm is comparable to the largest observed in compensated magnetic systems to date, and is rapidly switched off when the angle of an applied magnetic field is rotated to $\sim 80^{\circ}$ from the crystalline $c$-axis. Our ionic gating experiments show that the anomalous Hall conductivity magnitude can be enhanced by modulating the $p$-type carrier density. We also present theoretical results that suggest the anomalous Hall effect is driven by Berry curvature due to noncollinear antiferromagnetic correlations among Cr spins, which are consistent with the previously suggested magnetic ordering in AgCrSe$_2$. Our results open the possibility to study the interplay of magnetic and ferroelectric-like responses in this fascinating class of materials.
2307.03541v1
2023-08-23
Plastic deformation mechanisms during nanoindentation of W, Mo, V body-centered cubic single crystals and their corresponding W-Mo, W-V equiatomic random solid solutions
Deformation plasticity mechanisms in alloys and compounds may unveil the material capacity towards optimal mechanical properties. We conduct a series of molecular dynamics (MD) simulations to investigate plasticity mechanisms due to nanoindentation in pure tungsten, molybdenum and vanadium body-centered cubic single crystals, as well as the also body-centered cubic, equiatomic, random solid solutions (RSS) of tungsten--molybdenum and tungsten--vanadium alloys. Our analysis focuses on a thorough, side-by-side comparison of dynamic deformation processes, defect nucleation, and evolution, along with corresponding stress--strain curves. We also check the surface morphology of indented samples through atomic shear strain mapping. As expected, the presence of Mo and V atoms in W matrices introduces lattice strain and distortion, increasing material resistance to deformation and slowing down dislocation mobility of dislocation loops with a Burgers vector of 1/2 $\langle 111 \rangle$. Our side-by-side comparison displays a remarkable suppression of the plastic zone size in equiatomic W--V RSS, but not in equiatomic W--Mo RSS alloys, displaying a clear prediction for optimal hardening response equiatomic W--V RSS alloys. If the small-depth nanoindentation plastic response is indicative of overall mechanical performance, it is possible to conceive a novel MD-based pathway towards material design for mechanical applications in complex, multi-component alloys.
2308.12206v1
2023-09-08
Intralayer Negative Poisson's Ratio in Two-Dimensional Black Arsenic by Strain Engineering
Negative Poisson's ratio as the anomalous characteristic generally exists in artificial architectures, such as re-entrant and honeycomb structures. The structures with negative Poisson's ratio have attracted intensive attention due to their unique auxetic effect and many promising applications in shear resistant and energy absorption fields. However, experimental observation of negative Poisson's ratio in natural materials barely happened, although various two-dimensional layered materials are predicted in theory. Herein, we report the anisotropic Raman response and the intrinsic intralayer negative Poisson's ratio of two-dimensional natural black arsenic (b-As) via strain engineering strategy. The results were evident by the detailed Raman spectrum of b-As under uniaxial strain together with density functional theory calculations. It is found that b-As was softer along the armchair than zigzag direction. The anisotropic mechanical features and van der Waals interactions play essential roles in strain-dependent Raman shifts and negative Poisson's ratio in the natural b-As along zigzag direction. This work may shed a light on the mechanical properties and potential applications of two-dimensional puckered materials.
2309.04058v1
2023-10-04
Three-Sensor 2ω Method with Multi-directional Layout: A General Methodology for Measuring Thermal Conductivity of Solid Materials
Anisotropic thermal transport plays a key role in both theoretical study and engineering practice of heat transfer, but accurately measuring anisotropic thermal conductivity remains a significant challenge. To address this issue, we propose the three-sensor 2{\omega} method in this study, which is capable of accurately measuring the isotropic or anisotropic thermal conductivity of solid materials. In this method, several three-sensor groups following the design guidelines are fabricated upon the sample along different characteristic directions, and each group consists of three parallel metal sensors with unequal widths and distances optimally designed based on sensitivity analysis. Among the three sensors, the outer two serve as AC heaters and the middle one as a DC detector. The 2{\omega} voltage signals across the detector in each three-sensor group are measured, and then the data are processed by the proposed Intersection Method to derive the thermal conductivities along directions of interest. The application of the detector's 2{\omega} instead of the heater's 3{\omega} voltage signals eliminates the errors introduced by the uncertainties of thermal resistance in superficial structures (metal layer, insulation layer, interface, etc.). Meanwhile, by replacing the fitting algorithm with the Intersection Method, the local optimum trap of multivariate fitting is avoided. To verify the accuracy and reliability, four typical monocrystalline semiconductors, i.e., Si, GaN, AlN, and {\beta -Ga _2 O _3}, are measured, and the results are consistent with the literature. This method will provide a comprehensive and versatile solution for the thermal conductivity measurements of solid materials.
2310.02846v1
2023-10-25
Non-Destructive Imaging of Breakdown Process in Ferroelectric Capacitors Using \textit{In-situ} Laser-Based Photoemission Electron Microscopy
HfO$_2$-based ferroelectrics are one of the most actively developed functional materials for memory devices. However, in HfO$_2$-based ferroelectric devices, dielectric breakdown is a main failure mechanism during repeated polarization switching. Elucidation of the breakdown process may broaden the scope of applications for the ferroelectric HfO$_2$. Here, we report direct observations of a breakdown process in HfO$_2$-based ferroelectric capacitors, by \textit{in-situ} laser-based photoemission electron microscopy (laser-PEEM). We have not only clearly visualized the hard dielectric breakdown (HDB) spot, but also observed the regions responsible for the soft dielectric breakdown (SDB) which is a precursor phenomenon to HDB. It was found that the low-resistance region formed after SDB is wider than the conduction path formed after HDB. Furthermore, our spectromicroscopic analysis revealed that the photoelectron spectrum after SDB shows an enhancement in intensity without spectral-shape modulation, interpreted that the initially existed defects are increased. In the HDB spot, however, an additional shoulder structure was observed. These results provide spectroscopic evidence that the electronic states responsible for the conduction path after SDB are different from those after HDB. Through this work, we propose this microscopic approach as a versatile tool for studying buried materials as they are, accelerating the development of material engineering for advanced electronic devices.
2310.16275v1
2023-11-16
Properties of Nb\_xTi\_{(1-x)}N thin films deposited on 300 mm silicon wafers for upscaling superconducting digital circuits
Scaling superconducting digital circuits requires fundamental changes in the current material set and fabrication process. The transition to 300 mm wafers and the implementation of advanced lithography are instrumental in facilitating mature CMOS processes, ensuring uniformity, and optimizing the yield. This study explores the properties of NbxTi(1-x)N films fabricated by magnetron DC sputtering on 300 mm Si wafers. As a promising alternative to traditional Nb in device manufacturing, NbxTi(1-x)N offers numerous advantages, including enhanced stability and scalability to smaller dimensions, in both processing and design. As a ternary material, NbxTi(1-x)N allows engineering material parameters by changing deposition conditions. The engineered properties can be used to modulate device parameters through the stack and mitigate failure modes. We report characterization of NbxTi(1-x)N films at less than 2% thickness variability, 2.4% Tc variability and 3% composition variability. The films material properties such as resistivity (140-375 {\Omega}cm) and critical temperature Tc (4.6 K - 14.1 K) are correlated with stoichiometry and morphology of the films. Our results highlight the significant influence of deposition conditions on crystallographic texture along the films and its correlation with Tc.
2311.09772v2
2024-03-18
Primary Defect Production in Doped Iron Grain Boundaries during Low Energy Collision Cascades
This study explores the intricate interactions between grain boundaries (GBs) and irradiation-induced defects in nanocrystalline iron, highlighting the role of dopants like copper. Utilizing molecular dynamics simulations, the research delineates how GB properties, such as GB energy and defect formation energies, influence the formation and evolution of defects in low energy collision cascades. It reveals that GBs not only augment defect production but also show a marked preference for interstitials over vacancies, a behavior significantly modulated by the cascade's proximity to the GB. The presence of dopants is shown to alter GB properties, affecting both the rate and type of defect production, thereby underscoring the complex interplay between GB characteristics, dopant elements, and defect dynamics. Moreover, the investigation uncovers that the structural characteristics of GBs play a crucial role in cascade evolution and defect generation, with certain GB configurations undergoing reconfiguration in response to cascades. For instance, the reconfiguration of one pure Fe twist GB suggests that GB geometry can significantly influence defect generation mechanisms. These findings point to the potential of GB engineering in developing materials with enhanced radiation tolerance, advocating for a nuanced approach to material design. By tailoring GB properties and selectively introducing dopant elements, materials can be optimized to exhibit superior resistance to radiation-induced damage, offering insights for applications in nuclear reactors and other radiation-prone environments.
2403.12257v1
2024-05-21
Engineering band structures of two-dimensional materials with remote moire ferroelectricity
The stacking order and twist angle provide abundant opportunities for engineering band structures of two-dimensional materials, including the formation of moire bands, flat bands, and topologically nontrivial bands. The inversion symmetry breaking in rhombohedral-stacked transitional metal dichalcogenides (TMDCs) endows them with an interfacial ferroelectricity associated with an out-of-plane electric polarization. By utilizing twist angle as a knob to construct rhombohedral-stacked TMDCs, antiferroelectric domain networks with alternating out-of-plane polarization can be generated. Here, we demonstrate that such spatially periodic ferroelectric polarizations in parallel-stacked twisted WSe2 can imprint their moire potential onto a remote bilayer graphene. This remote moire potential gives rise to pronounced satellite resistance peaks besides the charge-neutrality point in graphene, which are tunable by the twist angle of WSe2. Our observations of ferroelectric hysteresis at finite displacement fields suggest the moire is delivered by a long-range electrostatic potential. The constructed superlattices by moire ferroelectricity represent a highly flexible approach, as they involve the separation of the moire construction layer from the electronic transport layer. This remote moire is identified as a weak potential and can coexist with conventional moire. Our results offer a comprehensive strategy for engineering band structures and properties of two-dimensional materials by utilizing moire ferroelectricity.
2405.12811v1
1996-07-08
Dynamic Conductance in Quantum Hall Systems
In the framework of the edge-channel picture and the scattering approach to conduction, we discuss the low frequency admittance of quantized Hall samples up to second order in frequency. The first-order term gives the leading order phase-shift between current and voltage and is associated with the displacement current. It is determined by the emittance which is a capacitance in a capacitive arrangement of edge channels but which is inductive-like if edge channels predominate which transmit charge between different reservoirs. The second-order term is associated with the charge relaxation. We apply our results to a Corbino disc and to two- and four-terminal quantum Hall bars, and we discuss the symmetry properties of the current response. In particular, we calculate the longitudinal resistance and the Hall resistance as a function of frequency.
9607051v1
1997-02-12
Kondo Effect in High-T_c Cuprates
We study the Kondo effect due to the nonmagnetic impurity, e.g., Zn, in high-T_c cuprates based on the spin-change separated state. In the optimal or overdoped case with the Kondo screening, the residual resistivity is dominated by the spinons while the T-dependent part determined by the holons. This gives $\rho(T) = { {4 \hbar} /{e^2}} { { n_{imp.}} /{(1-x)}} + {{\alpha T} / x}$ (x: hole concentration,$n_{imp.}$: impurity concentration, $\alpha$: constant ), which is in agreement with experiments. In the underdoped region with the pseudo spin gap, an SU(2) formulation predicts that the holon phase shift is related to the formation of the local spin moment, and hence the residual resistivity is given by $\rho_{res.} = { {4 \hbar} /{ e^2}} { { n_{imp.}}/{x}} $, which is also consistent with the experiments. The magnetic impurity case, e.g., Ni, is also discussed.
9702103v2
1999-03-11
Anisotropic States of Two-Dimensional Electron Systems in High Landau Levels: Effect of an In-Plane Magnetic Field
We report the observation of an acute sensitivity of the anisotropic longitudinal resistivity of two-dimensional electron systems in half-filled high Landau levels to the magnitude and orientation of an in-plane magnetic field. In the third and higher Landau levels, at filling fractions nu=9/2, 11/2, etc., the in-plane field can lead to a striking interchange of the "hard" and "easy" transport directions. In the second Landau level the normally isotropic resistivity and the weak nu=5/2 quantized Hall state are destroyed by a large in-plane field and the transport becomes highly anisotropic.
9903196v2
1999-06-23
Micro-Raman and resistance measurements of epitaxial La0.7Sr0.3MnO3 films
The Channel-Spark method was used for deposition of highly oriented ferromagnetic La0.7Sr0.3MnO3 films on NdGaO3 substrates. It was found that additional oxygen decreases the film quality suppressing the Curie temperature and metal-insulator transition below the room temperature. To achieve the best quality of the films the samples were either annealed in high vacuum at deposition temperature or even deposited in argon atmosphere with no oxygen annealing. For such films the resistive measurements showed a metallic behaviour in the interval 10-300 K in accordance with the high Curie point (Tc 350 K). Micro-Raman analysis indicate that the La0.7Sr0.3MnO3 films are well ordered, while some outgrowths show stoichiometrical deviations.
9906348v1
1999-07-19
Quantum Theory of Quantum-Hall Smectics
We propose a quantum stripe (smectic) coupled-Luttinger-liquid model for the anisotropic states which occur in two-dimensional electron systems with high-index partial Landau level filling, $\nu^{*} = \nu - \lbrack\nu\rbrack$. Perturbative renormalization group calculations establish that interaction terms neglected in this model are relevant - probably driving the system into an anisotropic Wigner crystal---but for $0.4 \lesssim \nu^{*} \lesssim 0.6$ only below temperatures which are outside of the experimentally accessible range. We argue that the Hall conductance of the ground state flows toward $\lbrack\nu\rbrack e^{2}/h$ and $(\lbrack\nu\rbrack + 1) e^{2}/h$ respectively, on the low and high filling factor sides of this range, consistent with recent observations. A semiclassical theory of smectic state transport properties, which incorporates Luttinger liquid effects in the evaluation of scattering amplitudes, accounts for the magnitude of the dissipative resistivities at $\nu^{*}=1/2$, for their $\nu^{*}$-dependence, and for the observation of non-linearities of opposite sign in easy and hard direction resistivities.
9907278v1
1999-10-14
Electrical Noise From Phase Separation In Pr2/3Ca1/3MnO3 Single Crystal
Low frequency electrical noise measurements have been used to probe the electronic state of the perovskite-type manganese oxide Pr2/3Ca1/3MnO3 versus temperature and in the vicinity of the field-induced transition from the insulating, charge-ordered state (I-CO) to the metallic, ferromagnetic state (M-F). At high temperature we have observed a high level of the excess noise with mainly a gaussian distribution of the resistance fluctuations, and the associated power spectral density has a standard 1/f dependence. However, in the hysteretic region, where the electrical resistance depends dramatically on the sample history, we have observed a huge non-gaussian noise characterized by two level fluctuator-like switching (TLS) in the time domain. We discuss the origin of the noise in terms of percolative behavior of the conductivity. We speculate that the dominant fluctuators are manganese clusters switching between the M-F and the I-CO phases.
9910204v1
1999-12-20
Oxygen isotope effects in high-quality thin films of manganites: Quantitative constraints on the physics of manganites
Oxygen isotope effects on the transport properties have been studied in high-quality epitaxial thin films of La_{0.75}Ca_{0.25}MnO_{3} and Nd_{0.7}Sr_{0.3}MnO_{3}. In the paramagnetic state, the resistivity can be well fitted by \rho (T) = (A/\sqrt{T})\exp(E_{\rho}/k_{B}T) with the parameters A and E_{a} depending strongly on the oxygen isotope mass. The resistivity below 80 K almost perfectly follows \rho = \rho_{o}+ B\omega_{s}/\sinh^{2}(\hbar\omega_{s}/2k_{B}T) with \hbar\omega_{s}/k_{B} \sim 100 K. Both \rho_{o} and B increase by about 15(3)% upon raplacing $^{16}$O by $^{18}$O. The results provide quantitative constraints on the basic physics of manganites.
9912355v1
2000-05-03
The doping dependence of T* - what is the real high-Tc phase diagram?
Underdoped high-Tc superconductors are frequently characterised by a temperature, T*, below which the normal-state pseudogap opens. Two different "phase diagrams" based on the doping (p) dependence of T* are currently considered: one where T* falls to zero at a critical doping state and the other where T* merges with Tc in the overdoped region. By examining the temperature dependence of the NMR Knight shift and relaxation rate, entropy, resistivity, infrared conductivity, Raman scattering, ARPES and tunnelling data it is concluded that the second scenario is not at all supported. Neither can one distinguish a small and a large pseudogap as is often done. T* is an energy scale which falls abruptly to zero at p=0.19.
0005063v2
2000-07-13
Exclusion of quantum coherence as the origin of the 2D metallic state in high-mobility silicon inversion layers
The temperature and density dependence of the phase coherence time $\tau_\phi$ in high-mobility silicon inversion layers was determined from the magnetoresistivity due to weak localization. The upper temperature limit for single-electron quantum interference effects was delineated by comparing $\tau_\phi$ with the momentum relaxation time $\tau$. A comparison between the density dependence of the borders for quantum interference effects and the strong resistivity drop reveals that theses effects are not related to each other. As the strong resistivity drop occurs in the Drude regime, the apparent metallic behavior can not be caused by quantum coherent effects.
0007230v3
2001-02-22
Magnetoresistivity and Complete $H_{c2}(T)$ in $MgB_2$
Detailed magneto-transport data on dense wires of $MgB_2$ are reported for applied magnetic fields up to 18 T. The temperature and field dependencies of the electrical resistivity are consistent with $MgB_2$ behaving like a simple metal and following a generalized form of Kohler's rule. In addition, given the generally high $T_c$ values and narrow resistive transition widths associated with $MgB_2$ synthesized in this manner, combined with applied magnetic fields of up to 18 T, an accurate and complete $H_{c2}(T)$ curve could be determined. This curve agrees well with curves determined from lower field measurements on sintered pellets and wires of $MgB_2$. $H_{c2}(T)$ is linear in $T$ over a wide range of temperature (7 K $\le~T~\le$ 32 K) and has an upward curvature for $T$ close to $T_c$. These features are similar to other high $\kappa$, clean limit, boron-bearing intermetallics: $YNi_2B_2C$ and $LuNi_2B_2C$.
0102413v2
2001-08-17
Entropy of vortex cores on the border of the superconductor-to-insulator transition in an underdoped cuprate
We present a study of Nernst effect in underdoped $La_{2-x}Sr_xCuO_4$ in magnetic fields as high as 28T. At high fields, a sizeable Nernst signal was found to persist in presence of a field-induced non-metallic resistivity. By simultaneously measuring resistivity and the Nernst coefficient, we extract the entropy of vortex cores in the vicinity of this field-induced superconductor-insulator transition. Moreover, the temperature dependence of the thermo-electric Hall angle provides strong constraints on the possible origins of the finite Nernst signal above $T_c$, as recently discovered by Xu et al.
0108277v2
2002-03-07
Pseudogap and Conduction Dimensionalities in High-T_c Superconductors
The nature of normal state charge-carriers' dynamics and the transition in conduction and gap dimensionalities between 2D and 3D for YBa_2 Cu_3 O_{7-delta} and Bi_2 Sr_2 Ca_{1-x} Y_x Cu_2 O_8 high-T_c superconductors were described by computing and fitting the resistivity curves, rho(T,delta,x). These were carried out by utilizing the 2D and 3D Fermi liquid (FL) and ionization energy (E_I) based resistivity models coupled with charge-spin (CS) separation based t-J model [Phys. Rev. B 64, 104516 (2001)]. rho(T,delta,x) curves of Y123 and Bi2212 samples indicate the beginning of the transition of conduction and gap from 2D to 3D with reduction in oxygen content (7-delta) and Ca^{2+} (1-x) as such, c-axis pseudogap could be a different phenomenon from superconductor and spin gaps. These models also indicate that the recent MgB_2 superconductor is at least not Y123 or Bi2212 type.
0203164v8
2002-03-07
The Onset of Anisotropic Transport of Two-Dimensional Electrons in High Landau Levels: An Isotropic-to-Nematic Liquid Crystal Phase Transition?
The recently discovered anisotropy of the longitudinal resistance of two-dimensional electrons near half filling of high Landau levels is found to persist to much higher temperatures T when a large in-plane magnetic field B|| is applied. Under these conditions we find that the longitudinal resistivity scales quasi-linearly with B||/T. These observations support the notion that the onset of anisotropy at B||=0 does not reflect the spontaneous development of charge density modulations but may instead signal an isotropic-to-nematic liquid crystal phase transition.
0203174v1
2003-05-21
Magnetoresistive response of a high mobility 2DES under electromagnetic wave excitation
Oscillations of the resistance observed under electromagnetic wave excitation in the high mobility GaAs/AlGaAs 2DES are examined as a function of the radiation frequency and the power, utilizing an empirical lineshape based on exponentially damped sinusoids. The fit-analysis indicates the resistance oscillation frequency, F, increases with the radiation frequency, n, at the rate dF/dn = 2.37 mTesla/GHz; the damping parameter, a, is approximately independent of n at constant power; and the amplitude, A, of the oscillations grows slowly with the incident power, at a constant temperature and frequency. The lineshape appears to provide a good description of the data.
0305507v2
2003-07-15
Bolometric technique for high-resolution broadband microwave spectroscopy of ultra-low-loss samples
A novel low temperature bolometric method has been devised and implemented for high-precision measurements of the microwave surface resistance of small single-crystal platelet samples having very low absorption, as a continuous function of frequency. The key to the success of this non-resonant method is the in-situ use of a normal metal reference sample that calibrates the absolute rf field strength. The sample temperature can be controlled independently of the 1.2 K liquid helium bath, allowing for measurements of the temperature evolution of the absorption. However, the instrument's sensitivity decreases at higher temperatures, placing a limit on the useful temperature range. Using this method, the minimum detectable power at 1.3 K is 1.5 pW, corresponding to a surface resistance sensitivity of $\approx$1 $\mu\Omega$ for a typical 1 mm$\times$1 mm platelet sample.
0307340v1
2003-09-26
Metastable Resistance Anisotropy Orientation of Two-Dimensional Electrons in High Landau Levels
In half-filled high Landau levels, two-dimensional electron systems possess collective phases which exhibit a strongly anisotropic resistivity tensor. A weak, but as yet unknown, rotational symmetry-breaking potential native to the host semiconductor structure is necessary to orient these phases in macroscopic samples. Making use of the known external symmetry-breaking effect of an in-plane magnetic field, we find that the native potential can have two orthogonal local minima. It is possible to initialize the system in the higher minimum and then observe its relaxation toward equilibrium.
0309625v2
2003-12-31
Single-electron transistors in electromagnetic environments
The current-voltage (I-V) characteristics of single-electron transistors (SETs) have been measured in various electromagnetic environments. Some SETs were biased with one-dimensional arrays of dc superconducting quantum interference devices (SQUIDs). The purpose was to provide the SETs with a magnetic-field-tunable environment in the superconducting state, and a high-impedance environment in the normal state. The comparison of SETs with SQUID arrays and those without arrays in the normal state confirmed that the effective charging energy of SETs in the normal state becomes larger in the high-impedance environment, as expected theoretically. In SETs with SQUID arrays in the superconducting state, as the zero-bias resistance of the SQUID arrays was increased to be much larger than the quantum resistance R_K = h/e^2 = 26 kohm, a sharp Coulomb blockade was induced, and the current modulation by the gate-induced charge was changed from e periodic to 2e periodic at a bias point 0<|V|<2D_0/e, where D_0 is the superconducting energy gap. The author discusses the Coulomb blockade and its dependence on the gate-induced charge in terms of the single Josephson junction with gate-tunable junction capacitance.
0312726v2
2004-08-19
Charge dynamics of Ca_{2-x}Na_{x}CuO_{2}Cl_{2} as a correlated electron system with the ideal tetragonal lattice
We report the reflectivity and the resistivity measurement of Ca_{2-x}Na_{x}CuO_{2}Cl_{2} (CNCOC), which has a single-CuO2-plane lattice with no orthorhombic distortion. The doping dependence of the in-plane optical conductivity spectra for CNCOC is qualitatively the same to those of other cuprates, but a slight difference between CNCOC and LSCO, i.e., the absence of the 1.5 eV peak in CNCOC, can be attributed to the smaller charge-stripe instability in CNCOC. The temperature dependence of the optical onductivity spectra of CNCOC has been analyzed both by the two-component model (Drude+Lorentzian) and by the one-component model (extended-Drude analysis). The latter analysis gives a universal trend of the scattering rate Gamma(omega) with doping. It was also found that Gamma(omega) shows a saturation behavior at high frequencies, whose origin is the same as that of resistivity saturation at high temperatures.
0408423v1
2004-11-17
Spin-fluctuation dominated electrical transport of Ni3Al at high pressure
We present the first study of a magnetic quantum phase transition in the itinerant-electron ferromagnet Ni3Al at high pressures. Electrical resistivity measurements in a diamond anvil cell at hydrostatic pressures up to 100 kbar and temperatures as low as 50 mK indicate that the Curie temperature collapses towards absolute zero at a critical pressure pc=82(2) kbar. Over wide ranges in pressure and temperature, both in the ferromagnetic and paramagnetic states, the temperature variation of the resistivity is found to deviate from the conventional Fermi-liquid form. We consider the extent to which this deviation can be understood in terms of a mean-field model of enhanced spin fluctuations on the border of ferromagnetism in three dimensions.
0411451v1
2004-12-27
Fiske steps studied with flux-flow resistance oscillation in a narrow stack of Bi2Sr2CaCu2O8+d junctions
We have experimentally investigated the fluxon dynamics in a narrow Bi2Sr2CaCu2O8+d stack with junction length L~1.8 um. As an evidence of high-frequency excitation by a collective cavity mode, under an (in-plane) external magnetic field, the current-voltage characteristics show prominent Fiske steps with the corresponding resonance frequencies of 75-305 GHz. Further study of flux-flow resistance oscillation with various c-axis currents clarifies the correlation with Fiske steps by distinguishing two different regions i.e., static flux-flow region at low bias current level and dynamic Fiske step region at high bias current level.
0412690v3
2005-03-07
Quantum Hall Effect at 40 kelvin: Evidence of MacroscopicQuantization in the Extreme Soft Limit
Evidence of both fractional and integer quantum hall effects (QHE) in three dimensional bulk replica opal (250nm diameter) structures of non-crystalline carbon are presented. In a remarkably soft quantum limit of ~ 40K temperature and about one tesla of magnetic field clear hall steps, such as n= 2/3, 4/5, 1 and others were observed to be coordinated with the minima of longitudinal magneto-resistance. This behavior is indicative of macroscopic quantum phenomenon associated with electronic condensation into a strongly correlated quantum liquid (QL). For other systems, such as very high mobility, two-dimensional, electron (hole)-gas or (TDEG) these effects typically arise under high magnetic fields (B) and at low temperatures (T), i.e., in the extreme quantum limit (B/T>1). Currently, QHE is applied as calibration benchmark, international resistance standard, and a characterization technique for semiconductor heterostructures. We believe that applications can be widespread if the devices and the operating conditions were more accessible.
0503166v1
2005-04-01
On the origin of multiple ordered phases in PrFe4P12
The nature of multiple electronic orders in skutterudite PrFe_4P_{12} is discussed on the basis of a model with antiferro-quadrupole (AFQ) interaction of \Gamma_3 symmetry. The high-field phase can be reproduced qualitatively provided (i) ferro-type interactions are introduced between the dipoles as well as between the octupoles of localized f-electrons, and (ii) separation is vanishingly small between the \Gamma_1-\Gamma_4^{(1)} crystalline electric field (CEF) levels. The high-field phase can have either the same ordering vector q=(1,0,0) as in the low-field phase, or a different one q=0 depending on the parameters. In the latter case, distortion of the crystal perpendicular to the (111) axis is predicted. The corresponding anomaly in elastic constants should also appear. The electrical resistivity is calculated with account of scattering within the CEF quasi-quartet. It is found that the resistivity as a function of the direction of magnetic field shows a sharp maximum around the (111) axis at low temperatures because of the level crossing.
0504014v2
2005-04-27
Influence of a Parallel Magnetic Field on Microwave Photoconductivity in a High-Mobility 2D Electron System
We have studied experimentally the influence of a parallel magnetic field ($B_{//}$) on microwave-induced resistance oscillations (MIRO) and zero-resistance states (ZRS) previously discovered in a high-mobility 2D electron system. We have observed a strong suppression of MIRO/ZRS by a modest $B_{//}\sim 0.5$ T. In Hall bar samples, magnetoplasmon resonance (MPR) has also been observed concurrently with the MIRO/ZRS. In contrast to the suppression of MIRO/ZRS, the MPR peak is found to be enhanced by $B_{//}$. These findings have not been addressed by current models proposed to explain the microwave-induced effects.
0504715v1
2005-05-25
Anisotropy, disorder, and superconductivity in CeCu2Si2 under high pressure
Resistivity measurements were carried out up to 8 GPa on single crystal and polycrystalline samples of CeCu2Si2 from differing sources in the homogeneity range. The anisotropic response to current direction and small uniaxial stresses was explored, taking advantage of the quasi-hydrostatic environment of the Bridgman anvil cell. It was found that both the superconducting transition temperature Tc and the normal state properties are very sensitive to uniaxial stress, which leads to a shift of the valence instability pressure Pv and a small but significant change in Tc for different orientations with respect to the tetragonal c-axis. Coexistence of superconductivity and residual resistivity close to the Ioffe-Regel limit around 5 GPa provides a compelling argument for the existence of a valence-fluctuation mediated pairing interaction at high pressure in CeCu2Si2.
0505613v1
2005-07-06
Magnetoresistance and spin polarization in the insulating regime of a Si two-dimensional electron system
We have studied the magnetoresistance in a high-mobility Si inversion layer down to low electron concentrations at which the longitudinal resistivity $\rho_{xx}$ has an activated temperature dependence. The angle of the magnetic field was controlled so as to study the orbital effect proportional to the perpendicular component $B_\perp$ for various total strengths $B_{\rm tot}$. A dip in $\rho_{xx}$, which corresponds to the Landau level filling factor of $\nu=4$, survives even for high resistivity of $\rho_{xx} \sim 10^8 \Omega$ at $T= 150 {\rm mK}$. The linear $B_{\rm tot}$-dependence of the value of $B_\perp$ at the dip for low $B_{\rm tot}$ indicates that a ferromagnetic instability does not occur even in the far insulating regime.
0507136v1
2006-05-22
Radiation-induced magnetoresistance oscillations in two-dimensional electron systems under bichromatic irradiation
We analyze the magnetoresistance $R_{xx}$ oscillations in high-mobility two-dimensional electron systems induced by the combined driving of two radiation fields of frequency $\omega_1$ and $\omega_2$, based on the balance-equation approach to magnetotransport for high-carrier-density systems in Faraday geometry. It is shown that under bichromatic irradiation of $\omega_2\sim 1.5 \omega_1$, most of the characterstic peak-valley pairs in the curve of $R_{xx}$ versus magnetic field in the case of monochromatic irradiation of either $\omega_1$ or $\omega_2$ disappear, except the one around $\omega_1/\omega_c\sim 2$ or $\omega_2/\omega_c\sim 3$. $R_{xx}$ oscillations show up mainly as new peak-valley structures around other positions related to multiple photon processes of mixing frequencies $\omega_1+\omega_2$, $\omega_2-\omega_1$, etc. Many minima of these resistance peak-valley pairs can descend down to negative with enhancing radiation strength, indicating the possible bichromaticzero-resistance states.
0605521v1
2006-06-19
Metallic State in Cubic FeGe beyond its Quantum Phase Transition
We report on results of electrical resistivity and structural investigations on the cubic modification of FeGe under high pressure. The long-wavelength helical order ($T_C=280$ K) is suppressed at a critical pressure $p_c\approx 19$ GPa. An anomaly in the resistivity data at $T_X(p)$ and strong deviations from a Fermi-liquid behavior in a wide pressure range above $p_c$ suggest that the suppression of $T_C$ disagrees with the standard notion of a quantum critical phase transition. The metallic ground state persisting at high pressure can be described by band-structure calculations if structural disorder due to zero-point motion is included. Discontinuous changes in the pressure dependence of the shortest Fe-Ge interatomic distance occurring close to the $T_C(p)$ phase line could be interpreted as a symmetry-conserving transition of first order.
0606493v1
2007-03-23
Giant asymmetry of the longitudinal magnetoresistance in high-mobility two-dimensional electron gas on a cylindrical surface
A giant asymmetry in the magnetoresistance was revealed in high-mobility, two-dimensional electron gas on a cylindrical surface. The longitudinal resistance along the magnetic-field gradient impressed by the surface curvature was found to vanish if measured along one of the edges of the curved Hall bar. If the external magnetic field is reversed, then the longitudinal resistance vanishes at the opposite edge of the Hall bar. This asymmetry is analyzed quantitatively in terms of the Landauer-Buettiker formalism.
0703623v1
2006-12-17
A New GEM-like Imaging Detector with Electrodes Coated with Resistive Layers
We have developed and tested several prototypes of GEM-like detectors with electrodes coated with resistive layers: CuO or CrO. These detectors can operate stably at gains close to 10E5 and they are very robust. We discovered that the cathodes of these detectors could be coated by CsI layers and in such a way the detectors gain high efficiency for the UV photons. We also demonstrated that such detectors can operate stably in the cascade mode and high overall gains (~10E6) are reachable. This opens applications in several areas, for example in RICH or in noble liquid TPCs. Results from the first applications of these devices for UV photon detection at room and cryogenic temperatures are given.
0612166v1
1997-02-07
The Landauer Resistance and Band Spectra for the Counting Quantum Turing Machine
The generalized counting quantum Turing machine (GCQTM) is a machine which, for any N, enumerates the first $2^{N}$ integers in succession as binary strings. The generalization consists of associating a potential with read-1 steps only. The Landauer Resistance (LR) and band spectra were determined for the tight binding Hamiltonians associated with the GCQTM for energies both above and below the potential height. For parameters and potentials in the electron region, the LR fluctuates rapidly between very high and very low values as a function of momentum. The rapidity and extent of the fluctuations increases rapidly with increasing N. For N=18, the largest value considered, the LR shows good transmission probability as a function of momentum with numerous holes of very high LR values present. This is true for energies above and below the potential height. It is suggested that the main features of the LR can be explained by coherent superposition of the component waves reflected from or transmitted through the $2^{N-1}$ potentials in the distribution. If this explanation is correct, it provides a dramatic illustration of the effects of quantum nonlocality.
9702021v1
2008-06-17
Structural transition and anisotropic properties of single crystalline SrFe2As2
Plate-like single crystals of SrFe2As2 as large as 3x3x0.5 mm3 have been grown out of Sn flux. The SrFe2As2 single crystals show a structural phase transition from a high temperature tetragonal phase to a low temperature orthorhombic phase at To = 198 K, and do not show any sign of superconductivity down to 1.8 K. The structural transition is accompanied by an anomaly in the electrical resistivity, Hall resistivity, specific heat, and the anisotropic magnetic susceptibility. In an intermediate temperature range from 198 K to 160 K, single crystal X-ray diffraction suggests a coexistence of the high-temperature tetragonal and the low-temperature orthorhombic phases.
0806.2711v1
2008-08-29
On collisions driven negative energy waves and Weibel instability of a relativistic electron beam in a quasi-neutral plasma
A new quasi-neutral model describing the Weibel instability of a high-current relativistic beam propagating through a resistive plasma is developed. It treats beam electrons as kinetic particles, and ambient plasma as a non-relativistic fluid. For a finite-temperature beam, a new class of negative energy magneto-sound waves is identified, which can possess negative energy. Their growth due to collisional dissipation in the cold return current destabilizes the beam-plasma system even for high beam temperatures. We perform detailed two- and three-dimensional particle-in-cell (PIC) simulations of the thermal beam and collisional plasma. It is shown that in three dimensions, the Weibel instability persists even for physically collisionless background plasma. The anomalous plasma resistivity is then caused by the two-stream instability.
0808.4078v2
2008-10-05
Anisotropic magnetic and superconducting properties of pure and Co-doped CaFe$_2$As$_2$ single crystals
We report anisotropic dc magnetic susceptibility $\chi(T)$, electrical resistivity $\rho(T)$, and heat capacity $C(T)$ measurements on the single crystals of CaFe$_{2-x}$Co$_x$As$_2$ for $x$ = 0 and 0.06. Large sized single crystals were grown by the high temperature solution method with Sn as the solvent. For the pure compound with $x$ = 0, a high temperature transition at 170 K is observed which is attributed to a combined spin density wave (SDW) ordering and a structural phase transition. On the other hand, for the Co-doped samples for $x$ = 0.06, the SDW transition is suppressed while superconductivity is observed at $\simeq$17 K. The superconducting transition has been confirmed from the magnetization and electrical resistivity studies. The $^{57}$Fe M\"ossbauer spectrum in CaFe$_2$As$_2$ indicates that the SDW ordering is incommensurate. In the Co-doped sample, a prominent paramagnetic line at 4.2 K is observed indicating a weakening of the SDW state.
0810.0848v2
2008-11-17
Possible superconductivity above 25 K in single crystalline Co-doped BaFe$_{2}$As$_{2}$
We present superconducting properties of single crystalline Ba(Fe$_{0.9}$Co$_{0.1}$)$_{2}$As$_{2}$ by measuring magnetization, resistivity, upper critical field, Hall coefficient, and magneto-optical images. The magnetization measurements reveal fish-tail hysteresis loop at high temperatures and relatively high critical current density above $J_{c}=10^{5}$ A/cm$^{2}$ at low temperatures. Upper critical field determined by resistive transition is anisotropic with anisotropic parameter $\sim$ 3.5. Hall effect measurements indicate that Ba(Fe$_{0.9}$Co$_{0.1}$)$_{2}$As$_{2}$ is a multiband system and the mobility of electron is dominant. The magneto-optical imaging reveals prominent Bean-like penetration of vortices although there is a slight inhomogeneity in a sample. Moreover, we find a distinct superconductivity above 25 K, which leads us to speculate that higher transition temperature can be realized by fine tuning Co-doping level.
0811.2621v1
2008-12-05
High-T_c superconductivity induced by doping rare earth elements into CaFeAsF
We have successfully synthesized the fluoride-arsenide compounds Ca$_{1-x}$RE$_x$FeAsF (RE=Nd, Pr; x=0, 0.6). The x-ray powder diffraction confirmed that the main phases of our samples are Ca$_{1-x}$RE$_x$FeAsF with the ZrCuSiAs structure. By measuring resistivity, superconductivity was observed at 57.4 K in Nd-doped and 52.8 K in Pr-doped samples with x=0.6. Bulk superconductivity was also proved by the DC magnetization measurements in both samples. Hall effect measurements revealed hole-like charge carriers in the parent compound CaFeAsF with a clear resistivity anomaly below 118 K, while the Hall coefficient $R_H$ in the normal state is negative for the superconducting samples Ca$_{0.4}$Nd$_{0.6}$FeAsF and Ca$_{0.4}$Pr$_{0.6}$FeAsF. This indicates that the rare earth element doping introduces electrons into CaFeAsF which induces the high temperature superconductivity.
0812.1192v1
2009-01-14
AC Josephson effect in the long voltage-biased SINIS junction
Theory of non-stationary coherent effects is developed for superconductor-normal-superconductor (SNS) structures with relatively strong normal scattering on S/N interfaces (interface resistance is large compared to intrinsic resistance of N metal). Analitical expressions are found for the time-dependent anomalous Green functions induced in the N region under the fixed-voltage-bias. The amplitude of the current oscillations is determined in non-equilibrium conditions. Non-stationary correction to the distribution function is calculated in high-temperature limit and found to be slowly decreasing with the temperature, leading to the dominance of the second-harmonic term in the Josepshon current at high temperatures and low voltage.
0901.1966v2
2009-03-04
Observation of a non-Ohmic Hall resistivity above the critical temperature in the high-temperature superconductor YBa$_{2}$Cu$_{3}$O$_{7-δ}$
Investigations of the resistivity and the Hall effect as a function of electric field and temperature in the normal state and upper part of the superconducting transition of an optimally doped, very thin film of YBa$_{2}$Cu$_{3}$O$_{7-\delta}$ are reported. Using a fast pulsed-current technique allowed to reduce the self-heating of the sample and to reach electric fields up to 1 kV/cm. An intrinsic non-Ohmic behavior of the Hall conductivity above the critical temperature that appears to originate from two different, partially counteracting effects is revealed. The major contribution stems from the suppression of Aslamazov-Larkin superconducting fluctuations in high electric fields.
0903.0725v1
2009-04-17
EuFe$_2$As$_2$ under high pressure: an antiferromagnetic bulk superconductor
We report the ac magnetic susceptibility $\chi_{ac}$ and resistivity $\rho$ measurements of EuFe$_2$As$_2$ under high pressure $P$. By observing nearly 100% superconducting shielding and zero resistivity at $P$ = 28 kbar, we establish that $P$-induced superconductivity occurs at $T_c \sim$~30 K in EuFe$_2$As$_2$. $\rho$ shows an anomalous nearly linear temperature dependence from room temperature down to $T_c$ at the same $P$. $\chi_{ac}$ indicates that an antiferromagnetic order of Eu$^{2+}$ moments with $T_N \sim$~20 K persists in the superconducting phase. The temperature dependence of the upper critical field is also determined.
0904.2618v2
2009-06-29
Spontaneous non-steady magnetic reconnection within the solar environment
This work presents a 2.5-dimensional simulation study of the instability of current-sheets located in a medium with a strong density variation along the current layer. The initial force-free configuration is observed to undergo a two-stage evolution consisting of an abrupt regime transition from a slow to a fast reconnection process leading the system to a final chaotic configuration. Yet, the onset of the fast phase is not determined by the presence of any anomalous enhancement in plasma's local resistivity, but rather is the result of a new mechanism discovered in Lapenta (2008)* and captured only when sufficient resolution is present. Hence, the effects of the global resistivity, the global viscosity and the plasma beta on the overall dynamics are considered. This mechanism allowing the transition from slow to fast reconnection provides a simple but effective model of several processes taking place within the solar atmosphere from the high chromosphere up to the low corona. In fact, the understanding of a spontaneous transition to a self-feeding fast reconnection regime as well as its macroscopic evolution is the first and fundamental step to produce realistic models of all those phenomena requiring fast (and high power) triggering events (* Lapenta G. 2008, Phys. Rev. Lett., 100, 235001).
0906.5382v1
2009-07-17
Performances of linseed oil-free bakelite RPC prototypes with cosmic ray muons
A comparative study has been performed on Resistive Plate Chambers (RPC) made of two different grades of bakelite paper laminates, produced and commercially available in India. The chambers, operated in the streamer mode using argon, tetrafluroethane and isobutane in 34:59:7 mixing ratio, are tested for the efficiency and the stability with cosmic rays. A particular grade of bakelite (P-120, NEMA LI-1989 Grade XXX), used for high voltage insulation in humid conditions, was found to give satisfactory performance with stable efficiency of > 96% continuously for more than 130 days. A thin coating of silicone fluid on the inner surfaces of the bakelite RPC is found to be necessary for operation of the detector.
0907.2976v1
2009-10-21
"Bad Metal" Conductivity of Hard Core Bosons
Two dimensional hard core bosons suffer strong scattering in the high temperature resistive state at half filling. The dynamical conductivity is calculated using non perturbative tools such as continued fractions, series expansions and exact diagonalization. We find a large temperature range with linearly increasing resistivity and broad dynamical conductivity, signaling a breakdown of Boltzmann-Drude quasiparticle transport theory. At zero temperature, a high frequency peak in the dynamical conductivity appears above a "Higgs mass" gap, and corresponds to order parameter magnitude fluctuations. We discuss the apparent similarity between conductivity of hard core bosons and phenomenological characteristics of cuprates, including the universal scaling of Homes et. al. (Nature 430, 539 (2004)).
0910.4158v2
2009-12-16
Distributed control of reactive power flow in a radial distribution circuit with high photovoltaic penetration
We show how distributed control of reactive power can serve to regulate voltage and minimize resistive losses in a distribution circuit that includes a significant level of photovoltaic (PV) generation. To demonstrate the technique, we consider a radial distribution circuit with a single branch consisting of sequentially-arranged residential-scale loads that consume both real and reactive power. In parallel, some loads also have PV generation capability. We postulate that the inverters associated with each PV system are also capable of limited reactive power generation or consumption, and we seek to find the optimal dispatch of each inverter's reactive power to both maintain the voltage within an acceptable range and minimize the resistive losses over the entire circuit. We assume the complex impedance of the distribution circuit links and the instantaneous load and PV generation at each load are known. We compare the results of the optimal dispatch with a suboptimal local scheme that does not require any communication. On our model distribution circuit, we illustrate the feasibility of high levels of PV penetration and a significant (20% or higher) reduction in losses.
0912.3281v1
2010-03-26
Strong carrier-scattering in iron-pnictide superconductors with highest Tc obtained from charge transport experiments
Characteristic normal-state charge transport is found in the oxygen-deficient iron-arsenides LnFeAsO1-y (Ln: La and Nd) with the highest Tc's among known Fe-based superconductors. The effect of "doping" in this system is mainly on the carrier scattering, quite distinct from that in high-Tc cuprates. In the superconducting regime of the La system with maximum Tc = 28 K, the low-temperature resistivity is dominated by a T^2 term. On the other hand, in the Nd system with Tc higher than 40 K, the carriers are subject to stronger scattering showing T-linear resistivity and small magnetoresistance. Such strong scattering appears crucial for high-Tc superconductivity in the iron-based system.
1003.5039v1
2010-04-14
Electron-hole coexistence in disordered graphene probed by high-field magneto-transport
We report on magneto-transport measurement in disordered graphene under pulsed magnetic field of up to 57T. For large electron or hole doping, the system displays the expected anomalous Integer Quantum Hall Effect (IQHE) specific to graphene up to filling factor $\nu=2$. In the close vicinity of the charge neutrality point, the system breaks up into co-existing puddles of holes and electrons, leading to a vanishing Hall and finite longitudinal resistance with no hint of divergence at very high magnetic field. Large resistance fluctuations are observed near the Dirac point. They are interpreted as the the natural consequence of the presence of electron and hole puddles. The magnetic field at which the amplitude of the fluctuations are the largest is directly linked to the mean size of the puddles.
1004.2356v1
2010-05-30
Loss-resistant state teleportation and entanglement swapping using a quantum-dot spin in an optical microcavity
We present a scheme for efficient state teleportation and entanglement swapping using a single quantum-dot spin in an optical microcavity based on giant circular birefringence. State teleportation or entanglement swapping is heralded by the sequential detection of two photons, and is finished after the spin measurement. The spin-cavity unit works as a complete Bell-state analyzer with a built-in spin memory allowing loss-resistant repeater operation. This device can work in both the weak coupling and the strong coupling regime, but high efficiencies and high fidelities are only achievable when the side leakage and cavity loss is low. We assess the feasibility of this device, and show it can be implemented with current technology. We also propose a spin manipulation method using single photons, which could be used to preserve the spin coherence via spin echo techniques.
1005.5545v2
2010-09-28
Vortex Phase Diagram of Layered Superconductor Cu0.03TaS2 for H || c
The magnetization and anisotropic electrical transport properties have been measured in high quality Cu0.03TaS2 single crystal. A pronounced peak effect has been observed, indicating that the high quality and homogeneity are vital to peak effect. A kink has been observed in the magnetic field H dependence of the in-plane resistivity {\rho}ab for H || c, which corresponds to a transition from activated to diffusive behavior of vortex liquid phase. In the diffusive regime of the vortex liquid phase, the in-plane resistivity {\rho}ab shows {\rho}ab $\propto$ H0.3 relation, which does not follow the Bardeen-Stephen law for free flux flow. Finally, a simplified vortex phase diagram of Cu0.03TaS2 for H || c is given.
1009.5449v2
2010-11-27
Performance of Glass Resistive Plate Chambers for a high granularity semi-digital calorimeter
A new design of highly granular hadronic calorimeter using Glass Resistive Plate Chambers (GRPCs) with embedded electronics has been proposed for the future International Linear Collider (ILC) experiments. It features a 2-bit threshold semi-digital read-out. Several GRPC prototypes with their electronics have been successfully built and tested in pion beams. The design of these detectors is presented along with the test results on efficiency, pad multiplicity, stability and reproducibility.
1011.5969v2
2010-12-13
Self-consistent calculation of the single particle scattering rate in high $Tc$ cuprates
The linear temperature dependence of the resistivity above the optimal doping is a longstanding problem in the field of high temperature superconductivity in cuprates. In this paper, we investigate the effect of gauge fluctuations on the momentum relaxation time and the transport scattering rate within the slave boson method. We use a more general slave treatment to resolve the ambiguity of decomposing the Heisenberg exchange term. We conclude that this term should be decomposed only in the Cooper channel. This results in the spinon mass inversely proportional to the doping. It is showed that solving the equation for the transport scattering rate self-consistently, we find a crossover temperature above which we obtain the linear temperature dependence of the electrical resistivity as well as the single particle scattering rate. It is also shown that this linear temperature dependence of the scattering rate in the pseudogap region explains the existence of the Fermi arcs with a length that linearly varies with temperature.
1012.2764v1
2011-03-17
Quantum-Classical Crossover and Apparent Metal-Insulator Transition in a Weakly Interacting 2D Fermi Liquid
We report the observation of a parallel magnetic field induced metal-insulator transition (MIT) in a high-mobility two-dimensional electron gas (2DEG) for which spin and localization physics most likely play no major role. The high-mobility metallic phase at low field is consistent with the established Fermi liquid transport theory including phonon scattering, whereas the insulating phase at higher field shows a large negative temperature dependence at resistances much smaller than the quantum of resistance, $h/e^2$. We argue that this observation is a direct manifestation of a quantum-classical crossover arising predominantly from the magneto-orbital coupling between the finite width of the 2DEG and the in-plane magnetic field.
1103.3496v2
2011-05-05
Pairing Fluctuations and Anomalous Transport Above the BCS-BEC Crossover in the Two Dimensional Attractive Hubbard Model
A Fermi liquid with weak attractive interaction undergoes a BCS transition to a superconductor with reducing temperature. With increasing interaction strength, the thermal transition is progressively modified as the high temperature `metallic' phase develops a pseudogap due to pairing fluctuations and the resistivity above T_c shows insulating behaviour. The crossover to insulating character occurs much before the system can be considered to be in the BEC regime of preformed fermion pairs. We use a new Monte Carlo tool to map out the BCS-BEC crossover in the attractive Hubbard model on large two dimensional lattices and explicitly compute the resistivity to demonstrate how the metal to superconductor (MS) thermal transition at weak coupling crosses over to an insulator to superconductor (IS) transition at intermediate coupling. Our high resolution access to the single particle and optical spectrum at finite temperature allows us to completely describe the transport crossover in this longstanding problem.
1105.1156v1
2011-11-28
Evolution of a metastable phase with a magnetic phase coexistence phenomenon and its unusual sensitivity to magnetic field cycling in the alloys Tb5-xLuxSi3 (x <= 0.7)
Recently, we reported an anomalous enhancement of the positive magnetoresistance beyond a critical magnetic field in Tb5Si3 in the magnetically ordered state, attributable to 'inverse metamagnetism'. This results in unusual magnetic hysteresis loops for the pressurized specimens, which are relevant to the topic of 'electronic phase separation'. In this paper, we report the influence of small substitutions of Lu for Tb, to show the evolution of these magnetic anomalies. We find that, at low temperatures, the high-field high-resistivity phase could be partially stabilized on returning the magnetic field to zero in many of these Lu substituted alloys, as measured through the electrical resistivity ({\rho}). Also, the relative fractions of this phase and the virgin phase appear to be controlled by a small tuning of the composition and temperature. Interestingly, at 1.8 K a sudden 'switch-over' of the value of {\rho} for this mixed phase to that for the virgin phase for some compositions is observed at low fields after a few field cycles, indicating metastability of this mixed phase.
1111.6368v1
2012-10-09
Interdependence of Electric Discharge and The Magnetorotational Instability in Protoplanetary Disks
We study how the magnetorotational instability (MRI) in protoplanetary disks is affected by the electric discharge caused by the electric field in the resistive MHD. We have performed three-dimensional shearing box simulations with various values of plasma beta and electrical breakdown models. We find the self-sustainment of the MRI in spite of the high resistivity. The instability gives rise to the large electric field that causes the electrical breakdown, and the breakdown maintains the high ionization degree required for the instability. The condition for this self-sustained MRI is set by the balance between the energy supply from the shearing motion and the energy consumed by the Ohmic dissipation. We apply the condition to various disk models and study where the active, self-sustained, and dead zones of MRI are. In the fiducial minimum-mass solar nebula (MMSN) model, the newly-found sustained zone occupies only the limited volume of the disk. In the late-phase gas-depleted disk models, however, the sustained zone occupies larger volume of the disk.
1210.2508v2
2012-12-18
Microwave properties of superconducting atomic-layer deposited TiN films
We have grown superconducting TiN films by atomic layer deposition with thicknesses ranging from 6 to 89 nm. This deposition method allows us to tune the resistivity and critical temperature by controlling the film thickness. The microwave properties are measured, using a coplanar-waveguide resonator, and we find internal quality factors above a million, high sheet inductances (5.2-620 pH), and pulse response times up to 100 \mu s. The high normal state resistivity of the films (> 100 \mu\Omega cm) affects the superconducting state and thereby the electrodynamic response. The microwave response is modeled using a quasiparticle density of states modified with an effective pair-breaker,consistently describing the measured temperature dependence of the quality factor and the resonant frequency.
1212.4434v1
2013-04-22
Persistent non-metallic behavior in Sr2IrO4 and Sr3Ir2O7 at high pressures
Iridium-based 5d transition-metal oxides are attractive candidates for the study of correlated electronic states due to the interplay of enhanced crystal-field, Coulomb and spin-orbit interaction energies. At ambient pressure, these conditions promote a novel Jeff = 1/2 Mott insulating state, characterized by a gap of the order of ~0.1 eV. We present high-pressure electrical resistivity measurements of single crystals of Sr2IrO4 and Sr3Ir2O7. While no indications of a pressure-induced metallic state up to 55 GPa were found in Sr2IrO4, a strong decrease of the gap energy and of the resistance of Sr3Ir2O7 between ambient pressure and 104 GPa confirm that this compound is in the proximity of a metal-insulator transition.
1304.5864v2
2013-08-28
Normal-state charge dynamics in doped BaFe2As2: Roles of doping and necessary ingredients for superconductivity
We carried out a comparative study of the in-plane resistivity and optical spectrum of doped BaFe2As2 and investigated the doping evolution of the charge dynamics. For BaFe2As2, charge dynamics is incoherent at high temperatures. Electron (Co) and isovalent (P) doping into BaFe2As2 increase coherence of the system and transform the incoherent charge dynamics into highly coherent one. On the other hand, charge dynamics remains incoherent for hole (K) doping. It is found in common with any type of doping that superconductivity with high transition temperature emerges when the normal-state charge dynamics maintains incoherence and when the resistivity associated with the coherent channel exhibits dominant temperature-linear dependence.
1308.6133v1
2014-04-07
Crystal structure and physical properties of EuPtIn$_{4}$ intermetallic antiferromagnet
We report the synthesis of EuPtIn$_{4}$ single crystalline platelets by the In-flux technique. This compound crystallizes in the orthorhombic Cmcm structure with lattice parameters $a=4.542(1)$ \AA, $b=16.955(2)$ \AA$\,$ and $c=7.389(1)$ \AA. Measurements of magnetic susceptibility, heat capacity, electrical resistivity, and electron spin resonance (ESR) reveal that EuPtIn$_{4}$ is a metallic Curie-Weiss paramagnet at high temperatures and presents antiferromagnetic (AFM) ordering below $T_{N}=13.3$ K. In addition, we observe a successive anomaly at $T^{*} = 12.6$ K and a spin-flop transition at $H_{c} \sim 2.5$ T applied along the $ac$-plane. In the paramagnetic state, a single Eu$^{2+}$ Dysonian ESR line with a Korringa relaxation rate of $b = 4.1(2)$ Oe/K is observed. Interestingly, even at high temperatures, both ESR linewidth and electrical resistivity reveal a similar anisotropy. We discuss a possible common microscopic origin for the observed anisotropy in these physical quantities likely associated with an anisotropic magnetic interaction between Eu$^{2+}$ 4$f$ electrons mediated by conduction electrons.
1404.1660v1
2014-04-14
High temperature superconducting FeSe films on SrTiO3 substrates
Interface enhanced superconductivity at two dimensional limit has become one of most intriguing research directions in condensed matter physics. Here, we report the superconducting properties of ultra-thin FeSe films with the thickness of one unit cell (1-UC) grown on conductive and insulating SrTiO3 (STO) substrates. For the 1-UC FeSe on conductive STO substrate (Nb-STO), the magnetization versus temperature (M-T) measurement shows a diamagnetic signal at 85 K, suggesting the possibility of superconductivity appears at this high temperature. For the FeSe films on insulating STO substrate, systematic transport measurements were carried out and the sheet resistance of FeSe films exhibits Arrhenius TAFF behavior with a crossover from a single-vortex pinning region to a collective creep region. More intriguing, sign reversal of Hall resistance with temperature is observed, demonstrating a crossover from hole conduction to electron conduction above Tc in 1-UC FeSe films.
1404.3464v2
2014-04-16
Magnetic Ordering at Anomalously High Temperatures in Dy at Extreme Pressures: a New Kondo-Lattice State?
In an attempt to destabilize the magnetic state of the heavy lanthanides Dy and Gd, extreme pressures were applied in an electrical resistivity measurement to 157 GPa over the temperature range 5 - 295 K. The magnetic ordering temperature $T_{\text{o}}$ and spin-disorder resistance $R_{sd}$ of Dy, as well as the superconducting pair-breaking effect $\Delta T_{c}$ in Y(1 at.\% Dy), are found to track each other in a highly non-monotonic fashion as a function of pressure, all three increasing sharply above 73 GPa, the critical pressure for a 6\% volume collapse in Dy. At 157 GPa $T_{\text{o}}$ is estimated to reach temperatures in the range 370 - 500 K, the highest magnetic ordering temperature of any lanthanide. In contrast, $T_{\text{o}% }(P)$ for Gd shows no such sharp increase to 105 GPa. Taken together, these results suggest that pressures greater than 73 GPa transform Dy from a conventional magnetic lanthanide into a Kondo lattice system with an anomalously high magnetic ordering temperature.
1404.4256v3
2014-05-14
Theory of universal incoherent metallic transport
In an incoherent metal, transport is controlled by the collective diffusion of energy and charge rather than by quasiparticle or momentum relaxation. We explore the possibility of a universal bound $D \gtrsim \hbar v_F^2/(k_B T)$ on the underlying diffusion constants in an incoherent metal. Such a bound is loosely motivated by results from holographic duality, the uncertainty principle and from measurements of diffusion in strongly interacting non-metallic systems. Metals close to saturating this bound are shown to have a linear in temperature resistivity with an underlying dissipative timescale matching that recently deduced from experimental data on a wide range of metals. This bound may be responsible for the ubiquitous appearance of high temperature regimes in metals with $T$-linear resistivity, motivating direct probes of diffusive processes and measurements of charge susceptibilities.
1405.3651v3
2014-05-14
Linear Resistivity from Non-Abelian Black Holes
Starting with the holographic p-wave superconductor, we show how to obtain a finite DC conductivity through a non-abelian gauge transformation. The translational symmetry is preserved. We obtain phenomenological similarities with high temperature cuprate superconductors. Our results suggest that a lattice or impurities are not essential to produce a finite DC resistivity with a linear temperature dependence. An analogous field theory calculation for free fermions, presented in the appendix, indicates our results may be a special feature of strong interactions.
1405.3714v4
2014-06-10
Nonlinear transport and noise thermometry in quasi-classical ballistic point contacts
We study nonlinear transport and non-equilibrium current noise in quasi-classical point contacts (PCs) defined in a low-density high-quality two-dimensional electron system in GaAs. At not too high bias voltages $V$ across the PC the noise temperature is determined by a Joule heat power and almost independent on the PC resistance that can be associated with a self-heating of the electronic system. This commonly accepted scenario breaks down at increasing $V$, where we observe extra noise accompanied by a strong decrease of the PC's differential resistance. The spectral density of the extra noise is roughly proportional to the nonlinear current contribution in the PC $\delta S\approx2F^*|e\delta I|\sim V^2$ with the effective Fano factor $F^*<1$, indicating that a random scattering process is involved. A small perpendicular magnetic field is found to suppress both $\delta I$ and $\delta S$. Our observations are consistent with a concept of a drag-like mechanism of the nonlinear transport mediated by electron-electron scattering in the leads of quasi-classical PCs.
1406.2481v2
2014-12-11
Transition-Metal Substitutions in Iron Chalcogenides
The $ab$-plane resistivity and Hall effect are studied in Fe$_{1-y}$M$_y$Te$_{0.65}$Se$_{0.35}$ single crystals doped with two transition metal elements, M = Co or Ni, over a wide doping range, $0 \leq y \leq 0.2$. The superconducting transition temperature, $T_{c}$, reaches zero for Co at $y \simeq 0.14$ and for Ni at $y \simeq 0.032$, while the resistivity at the $T_{c}$ onset increases weakly with Co doping, and strongly with Ni doping. The Hall coefficient $R_H$, positive for $y$ = 0, remains so at high temperatures for all $y$, while it changes sign to negative at low $T$ for $y > 0.135$ (Co) and $y > 0.06$ (Ni). The analysis based on a two band model suggests that at high $T$ residual hole pockets survive the doping, but holes get localized upon the lowering of $T$, so that the effect of the electron doping on the transport becomes evident. The suppression of the $T_c$ by Co impurity is related to electron doping, while in case of the Ni impurity strong electron localization most likely contributes to fast decrease of the $T_c$.
1412.3599v1