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2005-06-17
Theory of spin-polarized transport in ferromagnet-semiconductor structures: Unified description of ballistic and diffusive transport
A theory of spin-polarized electron transport in ferromagnet-semiconductor heterostructures, based on a unified semiclassical description of ballistic and diffusive transport in semiconductors, is outlined. The aim is to provide a framework for studying the interplay of spin relaxation and transport mechanism in spintronic devices. Transport inside the (nondegenerate) semiconductor is described in terms of a thermoballistic current, in which electrons move ballistically in the electric field arising from internal and external electrostatic potentials, and are thermalized at randomly distributed equilibration points. Spin relaxation is allowed to take place during the ballistic motion. For arbitrary potential profile and arbitrary values of the momentum and spin relaxation lengths, an integral equation for a spin transport function determining the spin polarization in the semiconductor is derived. For field-driven transport in a homogeneous semiconductor, the integral equation can be converted into a second-order differential equation that generalizes the spin drift-diffusion equation. The spin-polarization in ferromagnet semiconductor structures is obtained by matching the spin-resolved chemical potentials at the interfaces, with allowance for spin-selective interface resistances. Illustrative examples are considered.
0506441v1
2006-02-06
Non-collinear Magnetoelectronics
The electron transport properties of hybrid ferromagnetic|normal metal structures such as multilayers and spin valves depend on the relative orientation of the magnetization direction of the ferromagnetic elements. Whereas the contrast in the resistance for parallel and antiparallel magnetizations, the so-called Giant Magnetoresistance, is relatively well understood for quite some time, a coherent picture for non-collinear magnetoelectronic circuits and devices has evolved only recently. We review here such a theory for electron charge and spin transport with general magnetization directions that is based on the semiclassical concept of a vector spin accumulation. In conjunction with first-principles calculations of scattering matrices many phenomena, e.g. the current-induced spin-transfer torque, can be understood and predicted quantitatively for different material combinations.
0602151v1
2006-02-27
Relating supercooling and glass-like arrest of kinetics for phase separated systems: studies on doped CeFe$_2$ and (La,Pr,Ca)MnO$_3$
Coexisting ferromagnetic and antiferromagnetic phases over a range of temperature as well as magnetic field have been reported in many materials of current interest, showing disorder-broadened 1st order transitions. Anomalous history effects observed in magnetization and resistivity are being explained invoking the concepts of kinetic arrest akin to glass transitions. From magnetization measurements traversing novel paths in field-temperature space, we obtain the intriguing result that the regions of the sample which can be supercooled to lower temperatures undergo kinetic-arrest at higher temperatures, and vice versa. Our results are for two diverse systems viz. the inter-metallic doped CeFe$_2$ which has an antiferromagnetic ground state, and the oxide La-Pr-Ca-Mn-O which has a ferromagnetic ground state, indicating the possible universality of this effect of disorder on the widely encountered phenomenon of glass-like arrest of kinetics.
0602627v1
2006-06-09
The magnetotransport properties of La0.7Sr0.3MnO3/BaTiO3 superlattices grown by pulsed laser deposition technique
We have investigated the magnetotransport properties of La0.7Sr0.3MnO3/BaTiO3 superlattices, grown on SrTiO3 substrate by pulsed laser deposition technique, both with current-in-plane and current-perpendicular-to-the-plane directions. Several features indicate the presence of magnetic inhomogeneities at the interfaces which is independent of BaTiO3 layer thickness variation. First, the magnetic property in the superlattices decreases. Second, a hysteresis in magnetoresistance due to the relaxation of the resistive state is observed. Third, a threshold under an applied magnetic field in the magnetoresistance is seen. Such behaviors are in agreement with the phase separation scenario which could be the possible reason for these magnetic inhomogeneities at the interfaces. On the contrary, the magnetoresistance with the current-perpendicular-to-the-plane direction is mostly attributed to the tunneling effect along with the ordering of the spin at the interface. This study confirms the importance of the interfaces in superlattices that can be used to control novel physical properties in oxide materials.
0606232v1
2006-06-30
Synthesis of VO_2 Nanowire and Observation of the Metal-Insulator Transition
We have fabricated crystalline nanowires of VO_2 using a new synthetic method. A nanowire synthesized at 650^oC shows the semiconducting behavior and a nanowire at 670^oC exhibits the first-order metal-insulator transition which is not the one-dimensional property. The temperature coefficient of resistance in the semiconducting nanowire is 7.06 %/K at 300 K, which is higher than that of commercial bolometer.
0606793v1
2006-11-17
Evolution in Materio: Exploiting the Physics of Materials for Computation
We describe several techniques for using bulk matter for special purpose computation. In each case it is necessary to use an evolutionary algorithm to program the substrate on which the computation is to take place. In addition, the computation comes about as a result of nearest neighbour interactions at the nano- micro- and meso-scale. In our first example we describe evolving a saw-tooth oscillator in a CMOS substrate. In the second example we demonstrate the evolution of a tone discriminator by exploiting the physics of liquid crystals. In the third example we outline using a simulated magnetic quantum dot array and an evolutionary algorithm to develop a pattern matching circuit. Another example we describe exploits the micro-scale physics of charge density waves in crystal lattices. We show that vastly different resistance values can be achieved and controlled in local regions to essentially construct a programmable array of coupled micro-scale quasiperiodic oscillators. Lastly we show an example where evolutionary algorithms could be used to control density modulations, and therefore refractive index modulations, in a fluid for optical computing.
0611462v1
2006-12-23
Magnetic phase diagram of Ce2Fe17
Rare-earth-based permanent-magnet materials rich in iron have relatively low ferromagnetic ordering temperatures. This is believed to be due to the presence of antiferromagnetic exchange interactions, besides the ferromagnetic interactions responsible for the magnetic order. The magnetic properties of Ce2Fe17 are anomalous. Instead of ferromagnetic, it is antiferromagnetic, and instead of one ordering temperature, it shows two, at the Neel temperature TN ~ 208 K and at TT ~ 124 K. Ce2Fe17, doped by 0.5% Ta, also shows two ordering temperatures, one to an antiferromagnetic phase, at TN ~ 214 K, and one to a ferromagnetic phase, at T0 ~ 75 K. In order to clarify this behavior, single-crystalline samples were prepared by solution growth, and characterized by electron microscopy, single crystal x-ray diffraction, temperature-dependent specific heat, and magnetic field and temperature-dependent electrical resistivity and magnetization. From these measurements, magnetic H-T phase diagrams were determined for both Ta-doped Ce2Fe17 and undoped Ce2Fe17. These phase diagrams can be very well described in terms of a theory that gives magnetic phase diagrams of systems with competing antiferro- and ferromagnetism.
0612603v1
2006-05-06
Radiation enhancement and radiation suppression by a left-handed metamaterial
The perfect lens property of a dispersive and lossy left-handed metamaterial (LHM) disk is exploited to superimpose a source of electromagnetic radiation onto its mirror image, formed as a result of reflection from a perfect electric conductor (PEC) or a perfect magnetic conductor (PMC). The superposition of a vertical wire-dipole antenna with its PEC-image results in an increase of the radiation resistance of the antenna compared to that of an antenna emitting in free space. On the other hand, if the same antenna is coupled to a PMC-image it is shown that the result is the formation of a non-radiating configuration. The finite-difference time-domain (FDTD) analysis is performed and this allows a detailed characterization of the systems. It is shown that the non-radiating system allows relatively large amounts of electromagnetic energy to be stored in the LHM-disk and that is indicative of strong electromagnetic fields inside the material. This property is employed in a second-harmonic generation (SHG) process and the potential of a non-radiating configuration as an efficient nonlinear device is demonstrated.
0605055v1
2006-07-25
Superconductivity: coherent "tunnelling" by a dielectric array of charge-carriers
Superconduction manifests when a steady-state current flows through a material without an electric field being present. It is argued here that the absence of scattering of the charge-carriers, although absolutely necessary, is not sufficient to explain why an electric field is zero when a current flows between two contacts to a superconducting material. It is concluded that an electric field, and thus a resistance, must manifest unless (i) the charge-carriers form part of an array of dielectric charge centres, and (ii) the charge-carriers can increase their velocities without increasing their kinetic energies. A model is propoased which allows these requirements to manifest. The model is fitted to selected experimental results which have been published for low temperature metals, YBCO, and highly-doped p-type diamond. In each case a satisfactory description of the experimental results is demonstrated.
0607227v1
2005-04-05
Reduction of Magnetic Noise in Atom Chips by Material Optimization
We discuss the contribution of the material type in metal wires to the electromagnetic fluctuations in magnetic microtraps close to the surface of an atom chip. We show that significant reduction of the magnetic noise can be achieved by replacing the pure noble metal wires with their dilute alloys. The alloy composition provides an additional degree of freedom which enables a controlled reduction of both magnetic noise and resistivity if the atom chip is cooled. In addition, we provide a careful re-analysis of the magnetically induced trap loss observed by Yu-Ju Lin et al. [Phys. Rev. Lett. 92, 050404 (2004)] and find good agreement with an improved theory.
0504027v2
2007-04-20
Transport measurements across a tunable potential barrier in graphene
The peculiar nature of electron scattering in graphene is among many exciting theoretical predictions for the physical properties of this material. To investigate electron scattering properties in a graphene plane, we have created a gate-tunable potential barrier within a single-layer graphene sheet. We report measurements of electrical transport across this structure as the tunable barrier potential is swept through a range of heights. When the barrier is sufficiently strong to form a bipolar junctions (npn or pnp) within the graphene sheet, the resistance across the barrier sharply increases. We compare these results to predictions for both diffusive and ballistic transport, as the barrier rises on a length scale comparable to the mean free path. Finally, we show how a magnetic field modifies transport across the barrier.
0704.2626v2
2007-05-16
Ab initio estimate of temperature dependence of electrical conductivity in a model amorphous material: hydrogenated amorphous silicon
We present an ab initio calculation of the DC conductivity of amorphous silicon and hydrogenated amorphous silicon. The Kubo-Greenwood formula is used to obtain the DC conductivity, by thermal averaging over extended dynamical simulation. Its application to disordered solids is discussed. The conductivity is computed for a wide range of temperatures and doping is explored in a naive way by shifting the Fermi level. We observed the Meyer-Neldel rule for the electrical conductivity with E_MNR = 0.06 eV and a temperature coefficient of resistance, TCR ~ -2.0% K^-1 for a-Si:H. In general, experimental trends are reproduced by these calculations, and this suggests the possible utility of the approach for modeling carrier transport in other disordered systems.
0705.2384v3
2007-07-08
Tensoresistive Effect in Single Crystal Microwires of Pbte Doped with Tl
Results of room temperature measurements of tensoresistive effect of thin single crystal microwires of Pb1-xTlxTe (x=0.0000 - 0.0025, d = 5 - 20 micrometers) obtained from the melted compound of corresponding composition by the filling of quartz capillary with the following crystallization of material are presented. For the samples corresponding to chemical composition with concentration of thallium x ~0,0025 an essential increase of tensoresistive effect (resistance changes for elastic elongations per unit length of a crystal) in comparison with nondoped samples is observed. Various mechanisms which can lead to observable anomalies, including resonance scattering are discussed. Obtained experimental results allow us to suppose that the observed peculiarities can be interpreted on the basis of model of an impurity band of Tl in PbTe.
0707.1124v1
2007-08-13
Orbital Ordering Structures in (Nd,Pr)0.5Sr0.5MnO3 Manganite Thin Films on Perovskite (011) Substrates
Structural study of orbital-ordered manganite thin films has been conducted using synchrotron radiation, and a ground state electronic phase diagram is made. The lattice parameters of four manganite thin films, Nd0.5Sr0.5MnO3 (NSMO) or Pr0.5Sr0.5MnO3 (PSMO) on (011) surfaces of SrTiO3 (STO) or [(LaAlO3){0.3}(SrAl0.5Ta0.5O3){0.7}] (LSAT), were measured as a function of temperature. The result shows, as expected based on previous knowledge of bulk materials, that the films' resistivity is closely related to their structures. Observed superlattice reflections indicate that NSMO thin films have an antiferro-orbital-ordered phase as their low-temperature phase while PSMO film on LSAT has a ferro-orbital-ordered phase, and that on STO has no orbital-ordered phase. A metallic ground state was observed only in films having a narrow region of A-site ion radius, while larger ions favor ferro-orbital-ordered structure and smaller ions stabilize antiferro-orbital-ordered structure. The key to the orbital-ordering transition in (011) film is found to be the in-plane displacement along [0-1 1] direction.
0708.1693v1
2007-08-16
The nanostructural origin of the ac conductance in dielectric granular metals: the case study of Co_20(ZrO_2)_80
We show which is the nanostructure required in granular Co20(ZrO2)80 thin films to produce an ac response such as the one that is universally observed in a very wide variety of dielectric materials. A bimodal size distribution of Co particles yields randomly competing conductance channels which allow both thermally assisted tunneling through small particles and capacitive conductance among larger particles that are further apart. A model consisting on a simple cubic random resistance-capacitor network describes quantitatively the experimental results as functions of temperature and frequency, and enables the determination of the microscopic parameters controlling the ac response of the samples.
0708.2140v1
2007-08-16
Spin-transfer torques in anti-ferromagnetic metals from first principles
In spite of the absence of a macroscopic magnetic moment, an anti-ferromagnet is spin-polarized on an atomic scale. The electric current passing through a conducting anti-ferromagnet is polarized as well, leading to spin-transfer torques when the order parameter is textured, such as in anti-ferromagnetic non-collinear spin valves and domain walls. We report a first principles study on the electronic transport properties of anti-ferromagnetic systems. The current-induced spin torques acting on the magnetic moments are comparable with those in conventional ferromagnetic materials, leading to measurable angular resistances and current-induced magnetization dynamics. In contrast to ferromagnets, spin torques in anti-ferromagnets are very nonlocal. The torques acting far away from the center of an anti-ferromagnetic domain wall should facilitate current-induced domain wall motion.
0708.2143v2
2007-12-11
Frequency- and electric-field-dependent conductivity of single-walled carbon nanotube networks of varying density
We present measurements of the frequency and electric field dependent conductivity of single walled carbon nanotube(SWCNT) networks of various densities. The ac conductivity as a function of frequency is consistent with the extended pair approximation model and increases with frequency above an onset frequency $\omega_0$ which varies over seven decades with a range of film thickness from sub-monolayer to 200 nm. The nonlinear electric field-dependent DC conductivity shows strong dependence on film thickness as well. Measurement of the electric field dependence of the resistance R(E) allows for the determination of a length scale $L_{E}$ possibly characterizing the distance between tube contacts, which is found to systematically decrease with increasing film thickness. The onset frequency $\omega_0$ of ac conductivity and the length scale $L_{E}$ of SWCNT networks are found to be correlated, and a physically reasonable empirical formula relating them has been proposed. Such studies will help the understanding of transport properties and benefit the applications of this material system.
0712.1733v3
2007-12-21
Kinks in the electronic specific heat
We find that the heat capacity of a strongly correlated metal presents striking changes with respect to Landau Fermi liquid theory. In contrast with normal metals, where the electronic specific heat is linear at low temperature (with a T^3 term as a leading correction), a dynamical mean-field study of the correlated Hubbard model reveals a clear kink in the temperature dependence, marking a rapid change from a low-temperature linear behavior and a second linear regime with a reduced slope. Experiments on LiV2O4 support our findings, implying that correlated materials are more resistive to cooling at low T than expected from the intermediate temperature behavior.
0712.3723v2
2008-01-07
Utility of transient testing to characterize thermal interface materials
This paper analyzes a transient method for the characterization of low-resistance thermal interfaces of microelectronic packages. The transient method can yield additional information about the package not available with traditional static methods at the cost of greater numerical complexity, hardware requirements, and sensitivity to noise. While the method is established for package-level thermal analysis of mounted and assembled parts, its ability to measure the relatively minor thermal impedance of thin thermal interface material (TIM) layers has not yet been fully studied. We combine the transient thermal test with displacement measurements of the bond line thickness to fully characterize the interface.
0801.1009v1
2008-03-05
Giant room temperature piezoresistance in a metal/silicon hybrid
Metal/semiconductor hybrids are artificially created structures presenting novel properties not exhibited by either of the component materials alone. Here we present a giant piezoresistance effect in a hybrid formed from silicon and aluminum. The maximum piezoresistive gage factor (GF) of 843, measured at room temperature, compares with a GF of -93 measured in the bulk homogeneous silicon. This piezoresistance boost is not due to the silicon/aluminum interface, but results from a stress induced anisotropy in the silicon conductivity that acts to switch current away from the highly conductive aluminum for uniaxial tensile strains. Its magnitude is shown, via the calculation of hybrid resistivity weighting functions, to depend only on the geometrical arrangement of the component parts of the hybrid.
0803.0655v1
2008-04-02
Physical properties of the new Uranium ternary compounds U3Bi4M3 (M=Ni, Rh)
We report the properties of two new isostructural compounds, U3Bi4Ni3 and U3Bi4Rh3. The first of these compounds is non-metallic, and the second is a nearly ferromagnetic metal, both as anticipated from their electron count relative to other U-based members of the larger 3-4-3 family. For U3Bi4Rh3, a logarithmic increase of C/T below 3 K, a resistivity proportional to T^4/3, and the recovery of Fermi-liquid behavior in both properties with applied fields greater than 3T, suggest that U3Bi4Rh3 may be a new example of a material displaying ferromagnetic quantum criticality.
0804.0393v1
2008-11-19
Intrinsic Response of Graphene Vapor Sensors
Graphene is a purely two-dimensional material that has extremely favorable chemical sensor properties. It is known, however, that conventional nanolithographic processing typically leaves a resist residue on the graphene surface, whose impact on the sensor characteristics of the system has not yet been determined. Here we show that the contamination layer both degrades the electronic properties of the graphene and masks graphene s intrinsic sensor responses. The contamination layer chemically dopes the graphene, enhances carrier scattering, and acts as an absorbent layer that concentrates analyte molecules at the graphene surface, thereby enhancing the sensor response. We demonstrate a cleaning process that verifiably removes the contamination on the device structure and allows the intrinsic chemical responses of graphene to be measured.
0811.3091v1
2009-03-19
Superconductivity at 17 K in (Fe2P2)(Sr4Sc2O6): a new superconducting layered pnictide oxide with a thick perovskite oxide layer
A new layered oxypnictide (Fe2P2)(Sr4Sc2O6) have been synthesized by solid-state reaction. This material has an alternating layer stacking structure of anti-fluorite Fe2P2 and perovskite-based Sr4Sc2O6 oxide layers. Space group of the material is P4/nmm and lattice constants a and c are 4.016 A and 15.543 A, respectively. The interlayer Fe-Fe distance corresponding to the c-axis length is the longest ever reported in the iron-based oxypnictide systems. In both magnetization and resistivity measurements, the present compound exhibited superconductivity below 17 K, which is much higher than that of LaFePO and the highest in arsenic-free iron-based oxypnictide systems under ambient pressure.
0903.3314v3
2009-05-27
Precision Cutting and Patterning of Graphene with Helium Ions
We report nanoscale patterning of graphene using a helium ion microscope configured for lithography. Helium ion lithography is a direct-write lithography process, comparable to conventional focused ion beam patterning, with no resist or other material contacting the sample surface. In the present application, graphene samples on Si/SiO2 substrates are cut using helium ions, with computer controlled alignment, patterning, and exposure. Once suitable beam doses are determined, sharp edge profiles and clean etching are obtained, with little evident damage or doping to the sample. This technique provides fast lithography compatible with graphene, with ~15 nm feature sizes.
0905.4407v2
2009-06-08
Tunneling electroresistance effect in ferroelectric tunnel junctions at the nanoscale
Stable and switchable polarization of ferroelectric materials opens a possibility to electrically control their functional behavior. A particularly promising approach is to employ ferroelectric tunnel junctions where the polarization reversal in a ferroelectric barrier changes the tunneling current across the junction. Here, we demonstrate the reproducible tunneling electroresistance effect using a combination of Piezoresponse Force Microscopy (PFM) and Conducting Atomic Force Microscopy (C-AFM) techniques on nanometer-thick epitaxial BaTiO3 single crystal thin films on SrRuO3 bottom electrodes. Correlation between ferroelectric and electronic transport properties is established by the direct nanoscale visualization and control of polarization and tunneling current in BaTiO3 films. The obtained results show a change in resistance by about two orders of magnitude upon polarization reversal on a lateral scale of 20 nm at room temperature. These results are promising for employing ferroelectric tunnel junctions in non-volatile memory and logic devices, not involving charge as a state variable.
0906.1521v1
2009-06-30
Electric field effects, Mott insulator, Surface patterning, Scanning tunneling microscopy, Transition metal chalcogenides
We report the first experimental evidence for a strong electromechanical coupling in the Mott insulator GaTa4Se8 allowing a highly reproducible nano-writing with a Scanning Tunneling Microscope (STM). The local electric field across the STM junction is observed to have a threshold value above which the clean (100) surface of GaTa4Se8 becomes mechanically instable: At voltage biases V > 1.1V the surface suddenly inflates and comes in contact with the STM tip, resulting in nanometer size craters. The formed pattern can be indestructibly "read" by STM at lower voltage bias, thus allowing a 5 Tdots/inch2 dense writing/reading at room temperature. The discovery of the electromechanical coupling in GaTa4Se8 might give new clues in the understanding of the Electric Pulse Induced Resistive Switching recently observed in this stoechiometric Mott insulator.
0906.5473v1
2009-11-30
Kondo-like behaviors in magnetic and thermal properties of single crystal Tm5Si2Ge2
We grew the single crystal of stoichiometric Tm5Si2.0Ge2.0 using a Bridgeman method and performed XRD, EDS, magnetization, ac and dc magnetic susceptibilities, specific heat, electrical resistivity and XPS experiments. It crystallizes in orthorhombic Sm5Ge4-type structure. The mean valence of Tm ions in Tm5Si2.0Ge2.0 is almost trivalent. The 4f states is split by the crystalline electric field. The ground state exhibits the long range antiferromagnetic order with the ferromagnetically coupled magnetic moments in the ac plane below 8.01 K, while the exited states exhibit the reduction of magnetic moment and magnetic entropy and -log T-behaviors observed in Kondo materials.
0911.5640v1
2009-12-05
Theory and Simulation of Spin Transport in Antiferromagnetic Semiconductors: Application to MnTe
We study in this paper the parallel spin current in an antiferromagnetic semiconductor thin film where we take into account the interaction between itinerant spins and lattice spins. The spin model is an anisotropic Heisenberg model. We use here the Boltzmann's equation with numerical data on cluster distribution obtained by Monte Carlo simulations and cluster-construction algorithms. We study the cases of degenerate and non-degenerate semiconductors. The spin resistivity in both cases is shown to depend on the temperature with a broad maximum at the transition temperature of the lattice spin system. The shape of the maximum depends on the spin anisotropy and on the magnetic field. It shows however no sharp peak in contrast to ferromagnetic materials. Our method is applied to MnTe. Comparison to experimental data is given.
0912.0989v4
2010-05-14
Effect of phonon dispersion on thermal conduction across Si/Ge interfaces
We report finite-volume simulations of the phonon Boltzmann transport equation (BTE) for heat conduction across the heterogeneous interfaces in SiGe superlattices. The diffuse mismatch model incorporating phonon dispersion and polarization is implemented over a wide range of Knudsen numbers. The results indicate that the thermal conductivity of a Si/Ge superlattice is much lower than that of the constitutive bulk materials for superlattice periods in the submicron regime. We report results for effective thermal conductivity of various material volume fractions and superlattice periods. Details of the non-equilibrium energy exchange between optical and acoustic phonons that originate from the mismatch of phonon spectra in silicon and germanium are delineated for the first time. Conditions are identified for which this effect can produce significantly more thermal resistance than that due to boundary scattering of phonons.
1005.2578v1
2010-07-22
Anisotropic weakly localized transport in nitrogen-doped ultrananocrystalline diamond films
We establish the dominant effect of anisotropic weak localization (WL) in three dimensions associated with a propagative Fermi surface, on the conductivity correction in heavily nitrogen doped ultrananocrystalline diamond (UNCD) films based on magneto-resistance studies at low temperatures. Also, low temperature electrical conductivity can show weakly localized transport in 3D combined with the effect of electron-electron interactions in these materials, which is remarkably different from the conductivity in 2DWL or strong localization regime. The corresponding dephasing time of electronic wavefunctions in these systems described as ~ T^-p with p < 1, follows a relatively weak temperature dependence compared to the generally expected nature for bulk dirty metals having $p \geq 1$. The temperature dependence of Hall (electron) mobility together with an enhanced electron density has been used to interpret the unusual magneto-transport features and show delocalized electronic transport in these n-type UNCD films, which can be described as low-dimensional superlattice structures.
1007.3918v2
2010-09-01
Anomalous scattering in superconducting indium-doped tin telluride
Results of resistivity, Hall effect, magnetoresistance, susceptibility and heat capacity measurements are presented for single crystals of indium-doped tin telluride with compositions Sn$_{.988-x}$In$_x$Te where $0 \leq x \leq 8.4 %$, along with microstructural analysis based on transmission electron microscopy. For small indium concentrations, $x \leq 0.9 %$ the material does not superconduct above 0.3 K, and the transport properties are consistent with simple metallic behavior. For $x \geq 2.7 %$ the material exhibits anomalous low temperature scattering and for $x \geq 6.1 %$ bulk superconductivity is observed with critical temperatures close to 2 K. Intermediate indium concentrations $2.7% \leq x \leq 3.8%$ do not exhibit bulk superconductivity above 0.7 K. Susceptibility data indicate the absence of magnetic impurities, while magnetoresistance data are inconsistent with localization effects, leading to the conclusion that indium-doped SnTe is a candidate charge Kondo system, similar to thallium-doped PbTe.
1009.0090v1
2010-09-06
Understanding adhesion at as-deposited interfaces from ab initio thermodynamics of deposition growth: thin-film alumina on titanium carbide
We investigate the chemical composition and adhesion of chemical vapour deposited thin-film alumina on TiC using and extending a recently proposed nonequilibrium method of ab initio thermodynamics of deposition growth (AIT-DG) [Rohrer J and Hyldgaard P 2010 Phys. Rev. B 82 045415]. A previous study of this system [Rohrer J, Ruberto C and Hyldgaard P 2010 J. Phys.: Condens. Matter 22 015004] found that use of equilibrium thermodynamics leads to predictions of a non-binding TiC/alumina interface, despite the industrial use as a wear-resistant coating. This discrepancy between equilibrium theory and experiment is resolved by the AIT-DG method which predicts interfaces with strong adhesion. The AIT-DG method combines density functional theory calculations, rate-equation modelling of the pressure evolution of the deposition environment and thermochemical data. The AIT-DG method was previously used to predict prevalent terminations of growing or as-deposited surfaces of binary materials. Here we extent the method to predict surface and interface compositions of growing or as-deposited thin films on a substrate and find that inclusion of the nonequilibrium deposition environment has important implications for the nature of buried interfaces.
1009.1027v1
2010-09-07
Phase coherent transport in SrTiO3/LaAlO3 interfaces
The two dimensional electron gas formed between the two band insulators SrTiO3 and LaAlO3 exhibits a variety of interesting physical properties which make it an appealing material for use in future spintronics and/or quantum computing devices. For this kind of applications electrons have to retain their phase memory for sufficiently long times or length. Using a mesoscopic size device we were able to extract the phase coherence length, and its temperature variation. We find the dephasing rate to have a power law dependence on temperature. The power depends on the temperature range studied and sheet resistance as expected from dephasing due to strong electron-electron interactions.
1009.1273v1
2010-10-11
Restoring the electrical conductivity of graphene oxide films by UV light induced oxygen desorption
We report a chemical free method for the reduction of graphene oxide (GO) thin films. It was observed how for GO films annealed in air the oxygen species desorb from the GO surface upon exposure to UV light and how the surface resistivity of such deoxygenated GO films decreases with increasing the exposure to the UV light. The obtained results open a clean as well as easy route for the integration of GO based materials into optoelectronic devices.
1010.2108v4
2010-11-12
Memory effects in complex materials and nanoscale systems
Memory effects are ubiquitous in nature and are particularly relevant at the nanoscale where the dynamical properties of electrons and ions strongly depend on the history of the system, at least within certain time scales. We review here the memory properties of various materials and systems which appear most strikingly in their non-trivial time-dependent resistive, capacitative and inductive characteristics. We describe these characteristics within the framework of memristors, memcapacitors and meminductors, namely memory circuit elements whose properties depend on the history and state of the system. We examine basic issues related to such systems and critically report on both theoretical and experimental progress in understanding their functionalities. We also discuss possible applications of memory effects in various areas of science and technology ranging from digital to analog electronics, biologically-inspired circuits, and learning. We finally discuss future research opportunities in the field.
1011.3053v1
2010-12-13
The split-ring Josephson resonator as an artificial atom
Using the resistive-shunted-junction model we show that a split-ring Josephson oscillator or radio-frequency SQUID in the hysteretic regime is similar to an atomic system. It has a number of stationary states that we characterize. Applying a short magnetic pulse we switch the system from one state to another. These states can be detected via the reflection of a small amplitude signal forming the base of a new spectroscopy.
1012.2833v1
2010-12-23
Memristive Systems Analysis of 3-Terminal Devices
Memristive systems were proposed in 1976 by Leon Chua and Sung Mo Kang as a model for 2-terminal passive nonlinear dynamical systems which exhibit memory effects. Such systems were originally shown to be relevant to the modeling of action potentials in neurons in regards to the Hodgkin-Huxley model and, more recently, to the modeling of thin film materials such as TiO2-x proposed for non-volatile resistive memory. However, over the past 50 years a variety of 3-terminal non-passive dynamical devices have also been shown to exhibit memory effects similar to that predicted by the memristive system model. This article extends the original memristive systems framework to incorporate 3-terminal, non-passive devices and explains the applicability of such dynamic systems models to 1) the Widrow-Hoff memistor, 2) floating gate memory cells, and 3) nano-ionic FETs. Keywords-memristive systems, memistor, transconductance, synaptic transistor, non-linear dynamic systems
1012.5124v1
2011-01-14
Ni-Mn-Ga films in the austenite and the martensite structures at room temperature: Uniaxial texturation and epitaxial growth
Ni-Mn-Ga films in the austenite and the martensite structures at room temperature have been obtained using the DC magnetron sputtering technique. Two elaboration processes were studied. A first batch of samples was deposited using a resist sacrificial layer in order to release the film from the substrate before vacuum annealing. This process leads to polycrystalline films with a strong (022) fiber texture. The martensitic phase transformation of such polycrystalline freestanding films has been studied by optical and scanning electron microscopy. A second batch of samples was grown epitaxially on (100)MgO substrates using different deposition temperatures. The texture has been analyzed with four-circle X-ray diffraction. Epitaxial films crystallized both in the austenite and the martensite structures at room temperature have been studied.
1101.2811v1
2011-01-31
Yielding and irreversible deformation below the microscale: Surface effects and non-mean-field plastic avalanches
Nanoindentation techniques recently developed to measure the mechanical response of crystals under external loading conditions reveal new phenomena upon decreasing sample size below the microscale. At small length scales, material resistance to irreversible deformation depends on sample morphology. Here we study the mechanisms of yield and plastic flow in inherently small crystals under uniaxial compression. Discrete structural rearrangements emerge as series of abrupt discontinuities in stress-strain curves. We obtain the theoretical dependence of the yield stress on system size and geometry and elucidate the statistical properties of plastic deformation at such scales. Our results show that the absence of dislocation storage leads to crucial effects on the statistics of plastic events, ultimately affecting the universal scaling behavior observed at larger scales.
1102.0019v2
2011-05-11
Linear magnetoresistance in commercial n-type silicon due to inhomogeneous doping
Free electron theory tells us that resistivity is independent of magnetic field. In fact, most observations match the semiclassical prediction of a magnetoresistance that is quadratic at low fields before saturating. However, a non-saturating linear magnetoresistance has been observed in exotic semiconductors such as silver chalcogenides, lightly-doped InSb, N-doped InAs, MnAs-GaAs composites, PrFeAsO, and epitaxial graphene. Here we report the observation of a large linear magnetoresistance in the ohmic regime in commonplace commercial n-type silicon wafer. It is well-described by a classical model of spatially fluctuating donor densities, and may be amplified by altering the aspect ratio of the sample to enhance current-jetting: increasing the width tenfold increased the magnetoresistance at 8 T from 445 % to 4707 % at 35 K. This physical picture may well offer insights into the large magnetoresistances recently observed in n-type and p-type Si in the non-ohmic regime.
1105.2174v1
2011-05-27
Development of correlated quasiparticle conductance peak as molecule-linked gold nanoparticle films transition from Mott-insulator to metal phases
We have studied conductance ($\it{g}$) of butanedithiol-linked gold nanoparticle films across a percolation insulator-to-metal transition. As the transition proceeds, electrons become itinerant (i.e. Coulomb charging and kinetic effects are both significant), and films exhibit a previously unobserved zero-bias conductance peak (ZBCP). The peak is much more pronounced and easily observed using electromigration-induced break junction (BJ) contacts rather than macroscopic 4-probe electrodes. We attribute this ZBCP to quantum correlations amongst electrons, in view of other temperature- ($\it{T}$-) and magnetic ($\it{B}$-) dependent measurements as well as predictions of the Hubbard model and dynamic mean field theory in this transition regime. Metallic film resistances ($\it{R}$'s) increase linearly with $\it{T}$, but with suggested scattering lengths that, anomalously, are shorter than inter-atomic distances. Similar so-called "bad-metallic" behaviour has been observed in several studies of correlated systems, and is still being understood. We find here that the anomalous $\it{R}$ behaviours are associated with the ZBCP. This system can serve as a new test bed for studying correlated electrons and points to a nano building-block strategy for fashioning novel correlated materials.
1105.5647v1
2011-07-31
Observation of Quantized Hall Effect and Shubnikov-de Hass Oscillations in Highly Doped Bi2Se3: Evidence for Layered Transport of Bulk Carriers
Bi2Se3 is an important semiconductor thermoelectric material and a prototype topological insulator. Here we report observation of Shubnikov-de Hass (SdH) oscillations accompanied by quantized Hall resistances (Rxy) in highly-doped n-type Bi2Se3 with bulk carrier concentrations of few 10^19 cm^-3. Measurements under tilted magnetic fields show that the magnetotransport is 2D-like, where only the c-axis component of the magnetic field controls the Landau level formation. The quantized step size in 1/Rxy is found to scale with the sample thickness, and average ~e2/h per quintuple layer (QL). We show that the observed magnetotransport features do not come from the sample surface, but arise from the bulk of the sample acting as many parallel 2D electron systems to give a multilayered quantum Hall effect. Besides revealing a new electronic property of Bi2Se3, our finding also has important implications for electronic transport studies of topological insulator materials.
1108.0204v2
2011-08-30
Linear magnetoresistivity in the ternary AM2B2 and A3Rh8B6 phases (A = Ca, Sr; M = Rh, Ir)
We studied the magnetoresistivity of the AM2B2 and A3Rh8B6 (A = Ca, Sr; M = Rh, Ir) compounds within the ranges 1.8<=T<=300 K and 0<=H<=50 kOe. The zero-field resistivity {\rho}0(T) is metallic and follows closely the Bloch-Gr\"uneisen description. A positive, nonsaturating, and dominantly linear-in-H magnetoresistivity was observed in all samples, including the ones with a superconducting ground state. Such {\Delta}{\rho}T(H)/{\rho}T(0), reaching 1200% in favorable cases, was found to be much stronger for the AM2B2 compounds and to decrease with temperature as well as when Ca is replaced by Sr, or Rh is replaced by Ir. Finally, the general features of the observed magnetoresistivity will be discussed in terms of the Abrikosov model for the linear magnetoresistivity in inhomogeneous materials.
1108.5803v1
2011-09-22
Microscopic model for the ferroelectric field effect in oxide heterostructures
A microscopic model Hamiltonian for the ferroelectric field effect is introduced for the study of oxide heterostructures with ferroelectric components. The long-range Coulomb interaction is incorporated as an electrostatic potential, solved self-consistently together with the charge distribution. A generic double-exchange system is used as the conducting channel, epitaxially attached to the ferroelectric gate. The observed ferroelectric screening effect, namely the charge accumulation/depletion near the interface, is shown to drive interfacial phase transitions that give rise to robust magnetoelectric responses and bipolar resistive switching, in qualitative agreement with previous density functional theory calculations. The model can be easily adapted to other materials by modifying the Hamiltonian of the conducting channel, and it is useful in simulating ferroelectric field effect devices particularly those involving strongly correlated electronic components where ab-initio techniques are difficult to apply.
1109.4791v1
2011-10-09
Optimizing the Bi_(2-x)Sb_(x)Te_(3-y)Se_(y) solid solutions to approach the intrinsic topological insulator regime
To optimize the bulk-insulating behavior in the topological insulator materials having the tetradymite structure, we have synthesized and characterized single-crystal samples of Bi_(2-x)Sb_(x)Te_(3-y)Se_(y) (BSTS) solid solution at various compositions. We have elucidated that there are a series of "intrinsic" compositions where the acceptors and donors compensate each other and present a maximally bulk-insulating behavior. At such compositions, the resistivity can become as large as several Ohmcm at low temperature and one can infer the role of the surface-transport channel in the non-linear Hall effect. In particular, the composition of Bi1.5Sb0.5Te1.7Se1.3 achieves the lowest bulk carrier density and appears to be best suited for surface transport studies.
1110.1788v1
2011-10-24
Ni(111)|Graphene|h-BN Junctions as Ideal Spin Injectors
Deposition of graphene on top of hexagonal boron nitride (h-BN) was very recently demonstrated while graphene is now routinely grown on Ni. Because the in-plane lattice constants of graphite, h-BN, graphite-like BC2N and of the close-packed surfaces of Co, Ni and Cu match almost perfectly, it should be possible to prepare ideal interfaces between these materials which are respectively, a semimetal, insulator, semiconductor, ferromagnetic and nonmagnetic metals. Using parameter-free energy minimization and electronic transport calculations, we show how h-BN can be combined with the perfect spin filtering property of Ni|graphite and Co|graphite interfaces to make perfect tunnel junctions or ideal spin injectors (SI) with any desired resistance-area product.
1110.5291v1
2011-11-30
Synthesis, Characterization, and Finite Size Effects on Electrical Transport of Nanoribbons of the Charge-Density Wave Conductor NbSe3
NbSe3 exhibits remarkable anisotropy in most of its physical properties and has been a model system for studies of quasi-one-dimensional charge-density-wave (CDW) phenomena. Herein, we report the synthesis, characterization, and electrical transport of single-crystalline NbSe3 nanoribbons by a facile one-step vapour transport process involving the transport of selenium powder onto a niobium foil substrate. Our investigations aid the understanding of the CDW nature of NbSe3 and the growth process of the material. They also indicate that NbSe3 nanoribbons have enhanced CDW properties compared to those of the bulk phase due to size confinement effects, thus expanding the search for new mesoscopic phenomena at the nanoscale level. Single nanoribbon measurements on the electrical resistance as a function of temperature show charge-density wave transitions at 59 K and 141 K. We also demonstrate significant enhancement in the depinning effect and sliding regimes mainly attributed to finite size effects.
1112.0039v1
2012-04-02
Phase Stability, Structures and Properties of the (Bi2)m(Bi2Te3)n Natural Superlattices
The phase stability of the (Bi2)m(Bi2Te3)n natural superlattices has been investigated through the low temperature solid state synthesis of a number of new binary BixTe1-x compositions. Powder X-ray diffraction revealed that an infinitely adaptive series forms for 0.44 < x < 0.70, while an unusual 2-phase region with continuously changing compositions is observed for 0.41 < x < 0.43. For x > 0.70, mixtures of elemental Bi and an almost constant composition (Bi2)m(Bi2Te3)n phase are observed. Rietveld analysis of synchrotron X-ray powder diffraction data collected on Bi2Te (m = 2, n = 1) revealed substantial interchange of Bi and Te between the Bi2 and Bi2Te3 blocks, demonstrating that the block compositions are variable. All investigated phase pure compositions are degenerate semiconductors with low residual resistivity ratios and moderate positive magnetoresistances (R/R0 = 1.05 in 9 T). The maximum Seebeck coefficient is +80 muV K-1 for x = 0.63, leading to an estimated thermoelectric figure of merit, zT = 0.2 at 250 K.
1204.0356v1
2012-05-16
Spin transport and spin dephasing in zinc oxide
The wide bandgap semiconductor ZnO is interesting for spintronic applications because of its small spin-orbit coupling implying a large spin coherence length. Utilizing vertical spin valve devices with ferromagnetic electrodes (TiN/Co/ZnO/Ni/Au), we study the spin-polarized transport across ZnO in all-electrical experiments. The measured magnetoresistance agrees well with the prediction of a two spin channel model with spin-dependent interface resistance. Fitting the data yields spin diffusion lengths of 10.8nm (2K), 10.7nm (10K), and 6.2nm (200K) in ZnO, corresponding to spin lifetimes of 2.6ns (2K), 2.0ns (10K), and 31ps (200K).
1205.3666v3
2012-05-28
Visualizing Landau levels of Dirac electrons in a one dimensional potential
Using scanning tunneling spectroscopy we have measured the response of Dirac electrons in a magnetic field to the presence of a well-defined smoothly varying 1D periodic potential. We find that the lower index Landau level energies reliably trace the potential variations, while the higher index levels appear surprisingly homogeneous. Modeling the effects of the periodic potential on the Landau level spectra, we show that the Landau level behavior encodes information on the spatial extent of the wavefunctions. The lower index maps reveal Landau level stripes, which would act as traps for chiral one-dimensional modes. Our findings have important implications for transport and magneto-resistance measurements in Dirac materials with engineered potential landscapes.
1205.6230v2
2012-07-14
Topological phase transition induced by random substitution
The transition from topologically nontrivial to a trivial state is studied by first-principles calculations on bulk zinc-blende type (Hg$_{1-x}$Zn$_x$)(Te$_{1-x}$S$_x$) disordered alloy series. The random chemical disorder was treated by means of the Coherent Potential Approximation. We found that although the phase transition occurs at the strongest disorder regime (${x\approx 0.5}$), it is still manifested by well-defined Bloch states forming a clear Dirac cone at the Fermi energy of the bulk disordered material. The computed residual resistivity tensor confirm the topologically-nontrivial state of the HgTe-rich (${x<0.5}$), and the trivial state of the ZnS-rich alloy series (${x>0.5}$) by exhibiting the quantized behavior of the off-diagonal spin-projected component, independently on the concentration $x$.
1207.3463v1
2012-07-23
Superconducting and thermoelectric properties of new layered Superconductor Bi4O4S3
Polycrystalline sample of the new layered superconductor Bi4O4S3 is successfully synthesized by solid-state reaction method by using Bi, S and Bi2O3 powders with one step reaction. The superconducting transition temperature (Tconset=4.5 K), the zero resistance transition temperature (Tc0=4.07 K) and the diamagnetic transition temperature (4.02 K at H=10 Oe) were confirmed by electrical transport and magnetic measurements. Also, our results indicate a typical type II-superconductor behavior. In addition, a large thermoelectric effect was observed with a dimensionless thermoelectric figure of merit (ZT) of about 0.03 at 300K, indicating Bi4O4S3 can be a potential thermoelectric material.
1207.5395v1
2012-09-13
Topological-Metal to Band-Insulator Transition in (Bi1-xInx)2Se3 Thin Films
By combining transport and photo emission measurements on (Bi1-xInx)2Se3 thin films, we report that this system transforms from a topologically non-trivial metal into a topologically trivial band insulator through three quantum phase transitions. At x = 3-7%, there is a transition from a topologically non-trivial metal to a trivial metal. At x = 15%, the metal becomes a variable-range-hopping insulator. Finally, above x = 25%, the system becomes a true band insulator with its resistance immeasurably large even at room temperature. This material provides a new venue to investigate topologically tunable physics and devices with seamless gating/tunneling insulators.
1209.2840v1
2012-11-01
Spin Hall Magnetoresistance Induced by a Non-Equilibrium Proximity Effect
We report anisotropic magnetoresistance in Pt|Y3Fe5O12 bilayers. In spite of Y3Fe5O12 being a very good electrical insulator, the resistance of the Pt layer reflects its magnetization direction. The effect persists even when a Cu layer is inserted between Pt and Y3Fe5O12, excluding the contribution of induced equilibrium magnetization at the interface. Instead, we show that the effect originates from concerted actions of the direct and inverse spin Hall effects and therefore call it "spin Hall magnetoresistance."
1211.0098v1
2012-11-07
Tuning the thermoelectric properties of SrTiO3 by controlled oxygen doping
We report the thermoelectric properties (Seebeck coefficient, thermal conductivity, and electrical resistivity) of lightly doped single crystals of (001)-oriented SrTiO3 (STO). Hall effect measurements show that electron doping around 10^-5 carriers per unit cell can be achieved by vacuum annealing of the crystals under carefully controlled conditions. The steep density of states near the Fermi energy of STO at this doping level (confirmed by ab initio calculations) retains an unusually large Seebeck coefficient, in spite of an increase in the electronic conductivity by several orders of magnitude. This effect, combined with a decrease in thermal conductivity due to vacancy disorder scattering makes intrinsic doping in STO (and other materials) an alternative strategy to optimize its thermoelectric figure of merit.
1211.1615v1
2012-12-21
Multigap RPC for PET: development and optimisation of the detector design
Transforming the resistive plate chambers from charged-particle into gamma-quanta detectors opens the way towards their application as a basic element of a hybrid imaging system, which combines positron emission tomography (PET) with magnetic resonance imaging (MRI) in a single device and provides non- and minimally- invasive quantitative methods for diagnostics. To this end, we performed detailed investigations encompassing the whole chain from the annihilation of the positron in the body, through the conversion of the created photons into electrons and to the optimization of the electron yield in the gas. GEANT4 based simulations of the efficiency of the RPC photon detectors with different converter materials and geometry were conducted for optimization of the detector design. The results justify the selection of a sandwich-type gas-insulator-converter design, with Bi or Pb as converter materials.
1212.5551v1
2013-02-18
Comparative Measurements of Inverse Spin Hall and Magnetoresistance in YIG|Pt and YIG|Ta
We report on a comparative study of spin Hall related effects and magnetoresistance in YIG|Pt and YIG|Ta bilayers. These combined measurements allow to estimate the characteristic transport parameters of both Pt and Ta layers juxtaposed to YIG: the spin mixing conductance $G_{\uparrow \downarrow}$ at the YIG$|$normal metal interface, the spin Hall angle $\Theta_{SH}$, and the spin diffusion length $\lambda_{sd}$ in the normal metal. The inverse spin Hall voltages generated in Pt and Ta by the pure spin current pumped from YIG excited at resonance confirm the opposite signs of spin Hall angles in these two materials. Moreover, from the dependence of the inverse spin Hall voltage on the Ta thickness, we extract the spin diffusion length in Ta, found to be $\lambda_{sd}^\text{Ta}=1.8\pm0.7$ nm. Both the YIG|Pt and YIG|Ta systems display a similar variation of resistance upon magnetic field orientation, which can be explained in the recently developed framework of spin Hall magnetoresistance.
1302.4416v1
2013-02-20
Anomalous metallic state above the upper critical field of the conventional three-dimensional superconductor AgSnSe2 with strong intrinsic disorder
We report superconducting properties of AgSnSe2 which is a conventional type-II superconductor in the very dirty limit due to intrinsically strong electron scatterings. While this material is an isotropic three-dimensional (3D) superconductor with a not-so-short coherence length where strong vortex fluctuations are NOT expected, we found that the magnetic-field-induced resistive transition at fixed temperatures becomes increasingly broader toward zero temperature and, surprisingly, that this broadened transition is taking place largely ABOVE the upper critical field determined thermodynamically from the specific heat. This result points to the existence of an anomalous metallic state possibly caused by quantum phase fluctuations in a strongly-disordered 3D superconductor.
1302.4787v1
2013-03-06
Li$_2$RhO$_3$: A spin-glassy relativistic Mott insulator
Motivated by the rich interplay among electronic correlation, spin-orbit coupling (SOC), crystal-field splitting, and geometric frustrations in the honeycomb-like lattice, we systematically investigated the electronic and magnetic properties of Li$_2$RhO$_3$. The material is semiconducting with a narrow band gap of $\Delta\sim$78 meV, and its temperature dependence of resistivity conforms to 3D variable range hopping mechanism. No long-range magnetic ordering was found down to 0.5 K, due to the geometric frustrations. Instead, single atomic spin-glass behavior below the spin-freezing temperature ($\sim$6 K) was observed and its spin dynamics obeys the universal critical slowing down scaling law. First principle calculations suggested it to be a relativistic Mott insulator mediated by both electronic correlation and SOC. With moderate strength of electronic correlation and SOC, our results shed new light to the research of Heisenberg-Kitaev model in realistic materials.
1303.1235v2
2013-06-13
Combinatorial search of superconductivity in Fe-B composition spreads
We have fabricated Fe-B thin film composition spreads in search of possible superconducting phases following a theoretical prediction by Kolmogorov et al.^1 Co-sputtering was used to deposit spreads covering a large compositional region of the Fe-B binary phase diagram. A trace of superconducting phase was found in the nanocrystalline part of the spread, where the film undergoes a metal to insulator transition as a function of composition in a region with the average composition of FeB_2. The resistance drop occurs at 4K, and a diamagnetic signal has also been detected at the same temperature. The superconductivity is suppressible in the magnetic field up to 2 Tesla.
1306.3024v1
2013-07-16
Correlating toughness and roughness in ductile fracture
Three dimensional calculations of ductile crack growth under mode I plane strain, small scale yielding conditions are carried out using an elastic-viscoplastic constitutive relation for a progres- sively cavitating plastic solid with two populations of void nucleating second phase particles. Full field solutions are obtained for three dimensional material microstructures characterized by ran- dom distributions of void nucleating particles. Crack growth resistance curves and fracture surface roughness statistics are calculated using standard procedures. The range of void nucleating particle volume fractions considered give rise to values of toughness, JIC, that vary by a factor of four. For all volume fractions considered, the computed fracture surfaces are self-affine over a size range of about two orders of magnitude with a roughness exponent of 0.54 $\pm$ 0.03. For small void nucleating particle volume fractions, the mean large particle spacing serves as a single dominant length scale. In this regime, the correlation length of the fracture surface corresponding to the cut-off of the self-affine behavior is found to be linearly related to JIC thus quantitatively correlating toughness and fracture surface roughness.
1307.4413v1
2013-08-30
A linear nonequilibrium thermodynamics approach to optimization of thermoelectric devices
Improvement of thermoelectric systems in terms of performance and range of applications relies on progress in materials science and optimization of device operation. In this chapter, we focuse on optimization by taking into account the interaction of the system with its environment. For this purpose, we consider the illustrative case of a thermoelectric generator coupled to two temperature baths via heat exchangers characterized by a thermal resistance, and we analyze its working conditions. Our main message is that both electrical and thermal impedance matching conditions must be met for optimal device performance. Our analysis is fundamentally based on linear nonequilibrium thermodynamics using the force-flux formalism. An outlook on mesoscopic systems is also given.
1308.6735v1
2013-09-24
Efficient Gate-tunable light-emitting device made of defective boron nitride nanotubes: from ultraviolet to the visible
Boron nitride is a promising material for nanotechnology applications due to its two-dimensional graphene-like, insulating, and highly-resistant structure. Recently it has received a lot of attention as a substrate to grow and isolate graphene as well as for its intrinsic UV lasing response. Similar to carbon, one-dimensional boron nitride nanotubes (BNNTs) have been theoretically predicted and later synthesised. Here we use first principles simulations to unambiguously demonstrate that i) BN nanotubes inherit the highly efficient UV luminescence of hexagonal BN; ii) the application of an external perpendicular field closes the electronic gap keeping the UV lasing with lower yield; iii) defects in BNNTS are responsible for tunable light emission from the UV to the visible controlled by a transverse electric field (TEF). Our present findings pave the road towards optoelectronic applications of BN-nanotube-based devices that are simple to implement because they do not require any special doping or complex growth.
1309.6117v1
2013-10-11
Dropping the Ball: The effect of anisotropic granular materials on ejecta and impact crater shape
In this fluid dynamics video, we present an experimental investigation of the shape of impact craters in granular materials. Complex crater shapes, including polygons, have been observed in many terrestrial planets as well as moons and asteroids. We release spherical projectiles from different heights above a granular bed (sand). The experiments demonstrate two different techniques to create non-circular impact craters, which we measure by digitizing the final crater topography. In the first method, we create trenches in the sand to mimic fault lines or valleys on a planetary target. During impact, ejecta move faster in the direction of the trenches, creating nearly elliptical craters with the major axis running parallel to the trench. Larger trenches lead to more oblong craters. In the second method, a hose beneath the surface of the sand injects nitrogen gas. The pressure of the gas counters the hydrostatic pressure of the sand, greatly reducing static friction between grains above the injection point, without disturbing the surface. The affected sand has lower resistance to impact, creating a knob in the otherwise circular crater rim.
1310.3290v1
2013-10-20
Impurity effects in Cu$_2$O
The doping of wide gap semiconductors is an interesting problem both from the scientific and technological point of view. A well known example of this problem is the doping of Cu$_2$O. The only element which has produced an order of magnitude increase in the conductivity of Cu$_2$O bulk samples is chlorine, as previously reported by us and others. However the solar cells produced with this material do not show any improvement in performances because of the reduction in the minority carrier diffusion length. In this paper we investigate the effect of other impurities in order to check their possible use as dopants and to assess their effects on the minority carrier diffusion length. Seven impurities have been introduced by evaporation on the starting copper sheet before the oxidation used to produce Cu$_2$O: chromium (Cr), iron (Fe), silver (Ag), silicon (Si), sodium (Na), sulfur (S) and phosphorus (P). The experiments show that a 20 ppm of concentration of these dopants does not give any relevant effect neither on the resistivity, nor on the mobility. The effect on minority carrier diffusion length is also negligible except for sodium which produces a slight degradation of the samples.
1310.5341v1
2013-11-07
Magnetic domain and magnetic resistance phase transition in strongly correlated electronic material of perovskites junction
The junction magnetoresistivity and domain phase transition were studied between ZnO and La0.4Gd0.1Sr0.5CoO3 thin films grown on LaAlO3 (100) substrates epitaxially by pulse laser deposit. The ferromagnetic transformation into phase-separated (two phase) state was displayed below Tc~127 and has observed that the lattice change discontinuously in the doped cobalt perovskites La0.4Gd0.1Sr0.5CoO3. The Ginzburg-Landau phase field is introduced to deduce antiferroelectric domain structure in LGSCO thin film. On the basis of the domain structures, the phase boundary of thin film is strongly dependent on the combination of electric-mechanical coupling. The phase transformation into phase separated state occurs below Tc~127-128K, and have displayed that the lattice constants change discontinuously at the transformation. The positive MR of ZnO/LGSCO heterojunction exhibited the MIT behavior at 0.2 T is 4.86%, at 0.5 T is 6.05% for approximately 140K.
1311.1650v1
2013-11-17
First-principle study of octahedral tilting and Ferroelectric like transition in metallic LiOsO3
The octahedral tilting and ferroelectric-like structural transition of LiOsO3 metallic perovskite [Nature Materials 12, 1024 (2013)] was examined using first-principles density-functional theory. In LiOsO3, a-a-a- octahedral titling mode is responsible for the cubic to rhombohedral structural transition, which is stable phase at room temperature. At low temperatures, a non-centrosymmetric transition to a rhombohedra phase was realized due to zone center phonon softening. The phase transition behavior of LiOsO3 can be explained fully by density functional calculations and phonon calculations. The electronic structure and Fermi surface changes due to the electron lattice coupling effect are also presented. The carrier density of state across the phase transition is associated with the resistivity, heat capacity, and susceptibility.
1311.4139v1
2014-02-24
Experimental realization of a semiconducting full Heusler compound: Fe2TiSi
Single-phase films of the full Heusler compound Fe2TiSi have been prepared by magnetron sputtering. The compound is found to be a semiconductor with a gap of 0.4eV. The electrical resistivity has a logarithmic temperature dependence up to room temperature due to Kondo scattering of a dilute free electron gas off superparamagnetic impurities. The origin of the electron gas is extrinsic due to disorder or off-stoichiometry. Density functional theory calculations of the electronic structure are in excellent agreement with electron energy loss, optical, and x-ray absorption experiments. Fe2TiSi may find applications as a thermoelectric material.
1402.5755v1
2014-03-12
Magnetoresistance of double layer hybrid system in tilted magnetic field
Magnetoresistance and Hall coefficient of a graphene layer are investigated in the presence of a tilted magnetic field. We consider the graphene layer is assembled by either another graphene layer or a two-dimensional electron gas (2DEG) and an interlayer electron-electron interaction is modeled within Random Phase Approximation. Our calculated magnetoresistances show different interlayer screening effects between decoupled graphene-graphene and graphene-2DEG systems. We also analyze the dependence of dielectric materials as well as the distance between layers on magnetoresistances. The angle dependence of the Hall coefficient is studied and we show that a quite large Hall resistivity occurs in the graphene layer.
1403.2857v2
2014-03-28
Doping nature of native defects in 1T-TiSe2
The transition metal dichalcogenide 1T-TiSe2 is a quasi two-dimensional layered material with a charge density wave (CDW) transition temperature of TCDW 200 K. Self-doping effects for crystals grown at different temperatures introduce structural defects, modify the temperature dependent resistivity and strongly perturbate the CDW phase. Here we study the structural and doping nature of such native defects combining scanning tunneling microscopy/spectroscopy and ab initio calculations. The dominant native single atom dopants we identify in our single crystals are intercalated Ti atoms, Se vacancies and Se substitutions by residual iodine and oxygen.
1403.7339v2
2014-04-08
Modulation of pure spin currents with a ferromagnetic insulator
We propose and demonstrate spin manipulation by magnetically controlled modulation of pure spin currents in cobalt/copper lateral spin valves, fabricated on top of the magnetic insulator Y$_3$Fe$_5$O$_{12}$ (YIG). The direction of the YIG magnetization can be controlled by a small magnetic field. We observe a clear modulation of the non-local resistance as a function of the orientation of the YIG magnetization with respect to the polarization of the spin current. Such a modulation can only be explained by assuming a finite spin-mixing conductance at the Cu/YIG interface, as it follows from the solution of the spin-diffusion equation. These results open a new path towards the development of spin logics.
1404.2311v2
2014-04-10
Tunable chiral spin texture in magnetic domain-walls
Magnetic domain-walls (DWs) with a preferred chirality exhibit very efficient current-driven motion. Since structural inversion asymmetry (SIA) is required for their stability, the observation of chiral domain walls in highly symmetric Pt/Co/Pt is intriguing. Here, we tune the layer asymmetry in this system and observe, by current-assisted DW depinning experiments, a small chiral field which sensitively changes. Moreover, we convincingly link the observed efficiency of DW motion to the DW texture, using DW resistance as a direct probe for the internal orientation of the DW under the influence of in-plane fields. The very delicate effect of capping layer thickness on the chiral field allows for its accurate control, which is important in designing novel materials for optimal spin-orbit-torque-driven DW motion.
1404.2945v1
2014-04-17
Extreme thermopower anisotropy and interchain transport in the quasi-one-dimensional metal Li(0.9)Mo(6)O(17)
Thermopower and electrical resistivity measurements transverse to the conducting chains of the quasi-one-dimensional metal Li(0.9)Mo(6)O(17) are reported in the temperature range 5 K <= T <= 500 K. For T>= 400 K the interchain transport is determined by thermal excitation of charge carriers from a valence band ~ 0.14 eV below the Fermi level, giving rise to a large, p-type thermopower that coincides with a small, n-type thermopower along the chains. This dichotomy -- semiconductor-like in one direction and metallic in a mutually perpendicular direction -- gives rise to substantial transverse thermoelectric (TE) effects and a transverse TE figure of merit among the largest known for a single compound.
1404.4576v3
2014-05-15
Damage nucleation from repeated dislocation absorption at a grain boundary
Damage nucleation from repeated dislocation absorption at a grain boundary is simulated with molecular dynamics. At the grain boundary-dislocation intersection site, atomic shuffling events determine how the free volume brought by the incoming dislocation is accommodated. This process in turn determines the crack nucleation mechanism, as well as the critical strain and number of dislocations that can be absorbed before cracking. Slower strain rates promote earlier crack nucleation and a damage nucleation mode where cracking is preceded by dislocation emission. The simulation methodology presented here can be used to probe other types of boundaries as well, although multiple thermodynamically equivalent starting configurations are required to quantify the damage resistance of a given grain boundary.
1405.3974v2
2014-06-04
Magnetic-Field Induced Semimetal in Topological Crystalline Insulator Thin Films
We investigate electromagnetic properties of a topological crystalline insulator (TCI) thin film under external electromagnetic fields. The TCI thin film is a topological insulator indexed by the mirror-Chern number. It is demonstrated that the gap closes together with the emergence of a pair of gapless cones carrying opposite chirarities by applying in-plane magnetic field. A pair of gapless points have opposite vortex numbers. This is a reminiscence of a pair of Weyl cones in 3D Weyl semimetal. We thus present an a magnetic-field induced semimetal-semiconductor transition in 2D material. This is a giant-magnetoresistance, where resistivity is controlled by magnetic field. Perpendicular electric field is found to shift the gapless points and also renormalize the Fermi velocity in the direction of the in-plane magnetic field.
1406.1009v2
2014-06-05
Magnetotransport in ferromagnetic Mn5Ge3, Mn5Ge3C0.8, and Mn5Si3C0.8 thin films
The electrical resistivity, anisotropic magnetoresistance (AMR), and anomalous Hall effect of ferromagnetic Mn5Ge3, Mn5Ge3C0.8, and Mn5Si3C0.8 thin films has been investigated. The data show a behavior characteristic for a ferromagnetic metal, with a linear increase of the anomalous Hall coefficient with Curie temperature. While for ferromagnetic Mn5Si3C0.8 the normal Hall coefficient R0 and the AMR ratio are independent of temperature, these parameters strongly increase with temperature for the germanide films. This difference is attributed to the different hybridization of electronic states in the materials due different lattice parameters and different atomic configurations (Ge vs. Si metalloid). The concomitant sign change of R0 and the AMR ratio with temperature observed for the germanide films is discussed in a two-current model indicating an electron-like minority-spin transport at low temperatures.
1406.1442v1
2014-07-16
Mesoscale Imperfections in MoS2 Atomic Layers Grown by Vapor Transport Technique
The success of isolating small flakes of atomically thin layers through mechanical exfoliation has triggered enormous research interest in graphene and other two-dimensional materials. For device applications, however, controlled large-area synthesis of highly crystalline monolayers with a low density of electronically active defects is imperative. Here, we demonstrate the electrical imaging of dendritic ad-layers and grain boundaries in monolayer molybdenum disulfide (MoS2) grown by vapor transport technique using microwave impedance microscopy. The micrometer-sized precipitates in our films, which appear as a second layer of MoS2 in conventional height and optical measurements, show 2 orders of magnitude higher conductivity than that of the single layer. The zigzag grain boundaries, on the other hand, are shown to be more resistive than the crystalline grains, consistent with previous studies. Our ability to map the local electrical properties in a rapid and nondestructive manner is highly desirable for optimizing the growth process of large-scale MoS2 atomic layers.
1407.4188v1
2014-07-30
Synthesis and transport properties of ternary type-I Si clathrate K8Al7Si39
A ternary type-I Si clathrate, K8AlxSi46-x, which is a candidate functional material composed of abundant non-toxic elements, was synthesized and its transport properties were investigated at temperatures ranging from 10 to 320 K. The synthesized compound is confirmed to be the ternary type-I Si clathrate K8Al7Si39 with a lattice parameter of a = 10.442 A using neutron powder diffractometry and inductively coupled plasma optical emission spectrometry. Electrical resistivity and Hall coefficient measurements revealed that K8Al7Si39 is a metal with electrons as the dominant carriers at a density of approximately 1x10^27 /m3. The value of Seebeck coefficient for K8Al7Si39 is negative and its absolute value increases with the temperature. The temperature dependence of the thermal conductivity is similar to that for a crystalline solid. The dimensionless figure of merit is approximately 0.01 at 300 K, which is comparable to that for other ternary Si clathrates.
1407.7911v2
2014-08-30
Chemical Pressure effect at the boundary of Mott insulator and itinerant electron limit of Spinel Vanadates
The chemical pressure effect on the structural, transport, magnetic and electronic properties (by measuring X-ray photoemission spectroscopy) of ZnV2O4 has been investigated by doping Mn and Co on the Zinc site of ZnV2O4. With Mn doping the V-V distance increases and with Co doping it decreases. The resistivity and thermoelectric power data indicate that as the V-V distance decreases the system moves towards Quantum Phase Transition. The transport data also indicate that the conduction is due to the small polaron hopping. The chemical pressure shows the non-monotonous behaviour of charge gap and activation energy. The XPS study also supports the observation that with decrease of the V-V separation the system moves towards Quantum Phase Transition. On the other hand when Ti is doped on the V-site of ZnV2O4 the metal-metal distance decreases and at the same time the TN also increases.
1409.0106v1
2014-12-23
Temperature controlled motion of an antiferromagnet-ferromagnet interface within a dopant-graded FeRh epilayer
Chemically ordered B2 FeRh exhibits a remarkable antiferromagnetic-ferromagnetic phase transition that is first order. It thus shows phase coexistence, usually by proceeding though nucleation at random defect sites followed by propagation of phase boundary domain walls. The transition occurs at a temperature that can be varied by doping other metals onto the Rh site. We have taken advantage of this to yield control over the transition process by preparing an epilayer with oppositely directed doping gradients of Pd and Ir throughout its height, yielding a gradual transition that occurs between 350~K and 500~K. As the sample is heated, a horizontal antiferromagnetic-ferromagnetic phase boundary domain wall moves gradually up through the layer, its position controlled by the temperature. This mobile magnetic domain wall affects the magnetisation and resistivity of the layer in a way that can be controlled, and hence exploited, for novel device applications.
1412.7346v1
2015-01-21
Efficient Linear Scaling Approach for Computing the Kubo Hall Conductivity
We report an order-N approach to compute the Kubo Hall conductivity for disorderd two-dimensional systems reaching tens of millions of orbitals, and realistic values of the applied external magnetic fields (as low as a few Tesla). A time-evolution scheme is employed to evaluate the Hall conductivity $\sigma_{xy}$ using a wavepacket propagation method and a continued fraction expansion for the computation of diagonal and off-diagonal matrix elements of the Green functions. The validity of the method is demonstrated by comparison of results with brute-force diagonalization of the Kubo formula, using (disordered) graphene as system of study. This approach to mesoscopic system sizes is opening an unprecedented perspective for so-called reverse engineering in which the available experimental transport data are used to get a deeper understanding of the microscopic structure of the samples. Besides, this will not only allow addressing subtle issues in terms of resistance standardization of large scale materials (such as wafer scale polycrystalline graphene), but will also enable the discovery of new quantum transport phenomena in complex two-dimensional materials, out of reach with classical methods.
1501.05100v2
2015-01-26
Raman scattering investigation of large positive magnetoresistance material WTe$_2$
We have performed polarized Raman scattering measurements on WTe$_2$, for which an extremely large positive magnetoresistance has been reported recently. We observe 5 A$_1$ phonon modes and 2 A$_2$ phonon modes out of 33 Raman active modes, with frequencies in good accordance with first-principles calculations. The angular dependence of the intensity of the peaks observed is consistent with the Raman tensors of the $C_{2v}$ point group symmetry attributed to WTe$_2$. Although the phonon spectra suggest neither strong electron-phonon nor spin-phonon coupling, the intensity of the A$_1$ phonon mode at 160.6 cm$^{-1}$ shows an unconventional decrease with temperature decreasing, for which the origin remains unclear.
1501.06321v3
2015-02-17
Superconducting Dome and Crossover to an Insulating State in [Tl4]Tl1-xSnxTe3
The structural, superconducting, and electronic phase diagram of [Tl4]Tl1-xSnxTe3 is reported. Magnetization and specific heat measurements show bulk superconductivity exists for 0 < x < 0.4. Resistivity measurements indicate a crossover from a metallic state for low dopings to a doped insulator at x = 1. Universally, there is a large non-Debye specific heat contribution, characterized by an Einstein temperature of {\theta}E ~ 35 K. Density functional theory calculations predict x = 0 to be a topological metal, while x = 1 is a topological crystalline insulator. The disappearance of superconductivity correlates with the transition between these distinct topological states.
1502.05059v2
2015-02-24
Room temperature magnetodielectric studies on Mn doped LaGaO3
The polycrystalline samples of LaGa1-xMnxO3 (0<x<0.3) has been prepared by solid state reaction route. The phase purity of these samples has been confirmed by powder x-ray diffraction experiments carried out on BL-12 at Indus-2 synchrotron radiation source. The sample with x=0.2 shows significant change in the value of capacitance with the application of magnetic field. The observed results were understood by systematically analyzing magneto-capacitance (MC), magneto resistance (MR) and dielectric loss as a function of frequency. Our results and analysis suggests that the observed magneto dielectric (MD) coupling may be due to the MR effect of Maxwell-Wagner type and/or field induced dipolar relaxation. Further it is observed that the oxygen stoichiometry plays a very crucial role in observed MD coupling.
1502.06887v2
2015-03-18
Atomically Thin Resonant Tunnel Diodes built from Synthetic van der Waals Heterostructures
Vertical integration of two-dimensional van der Waals materials is predicted to lead to novel electronic and optical properties not found in the constituent layers. Here, we present the direct synthesis of two unique, atomically thin, multi-junction heterostructures by combining graphene with the monolayer transition-metal dichalocogenides: MoS2, MoSe2, and WSe2.The realization of MoS2-WSe2-Graphene and WSe2-MoSe2-Graphene heterostructures leads toresonant tunneling in an atomically thin stack with spectrally narrow room temperature negative differential resistance characteristics.
1503.05592v1
2015-09-17
Microwave Loss Reduction in Cryogenically Cooled Conductors
Measurements of microwave attenuation at room temperature and 4.2 K have been performed on some conductors commonly used in receiver input circuits. The reduction in loss on cooling is substantial, particularly for copper and plated gold, both of which showed a factor of 3 loss reduction. Copper passivated with benzotriazole shows the same loss as without passivation. The residual resistivity ratio between room temperature and 4.2 K, deduced from the measurements using the classical skin effect formula, was smaller than the measured DC value to a degree consistent with conduction in the extreme anomalous skin effect regime at cryogenic temperatures. The measurements were made in the 5-10 GHz range. The materials tested were: aluminum alloys 1100-T6 and 6061-O, C101 copper, benzotriazole treated C101 copper, and brass plated with electroformed copper, Pur-A-Gold 125-Au soft gold, and BDT200 bright gold.
1509.05273v1
2015-09-17
Symmetry constraints on the elastoresistivity tensor
The elastoresistivity tensor $m_{ij,kl}$ characterizes changes in a material's resistivity due to strain. As a fourth-rank tensor, elastoresistivity can be a uniquely useful probe of the symmetries and character of the electronic state of a solid. We present a symmetry analysis of $m_{ij,kl}$ (both in the presence and absence of a magnetic field) based on the crystalline point group, focusing for pedagogic purposes on the $D_{4h}$ point group (of relevance to several materials of current interest). We also discuss the relation between $m_{ij,kl}$ and various thermodynamic susceptibilities, particularly where they are sensitive to critical fluctuations proximate to a critical point at which a point group symmetry is spontaneously broken.
1509.05462v1
2015-10-19
Structure, Energy, and Thermal Transport Properties of Si-SiO$_2$ Nanostructures using an Ab initio based Parameterization of a Charge-Optimized Many-Body Forcefield
In an effort to extend the reach of current ab initio calculations to simulations requiring millions of configurations for complex systems such as heterostructures, we have parameterized the third-generation Charge Optimized Many-Body (COMB3) potential using solely ab initio total energies, forces, and stress tensors as input. The quality and the predictive power of the new forcefield is assessed by computing properties including the cohesive energy and density of SiO$_2$ polymorphs, surface energies of alpha-quartz, and phonon densities of states of crystalline and amorphous phases of SiO$_2$. Comparison with data from experiments, ab initio calculations, and molecular dynamics simulations using published forcefields including BKS (van Beest, Kramer, and van Santen), ReaxFF, and COMB2 demonstrate an overall improvement of the new parameterization. The computed temperature dependence of the thermal conductivity of crystalline alpha-quartz and the Kapitza resistance of the interface between crystalline Si(001) and amorphous silica are in excellent agreement with experiment, setting the stage for simulations of complex nanoscale heterostructures.
1510.05416v1
2015-11-07
Anomalous magneto-elastic and charge doping effects in thallium-doped BaFe2As2
Within the BaFe2As2 crystal lattice, we partially substitute thallium for barium and report the effects of interlayer coupling in Ba1-xTlxFe2As2 crystals. We demonstrate the unusual effects of magneto-elastic coupling and charge doping in this iron-arsenide material, whereby Neel temperature rises with small x, and then falls with additional x. Specifically, we find that Neel and structural transitions in BaFe2As2 (TN =Ts= 133 K) increase for x=0.05 (TN = 138 K, Ts = 140 K) from magnetization, heat capacity, resistivity, and neutron diffraction measurements. Evidence from single crystal X-ray diffraction and first principles calculations attributes the stronger magnetism in x=0.05 to magneto-elastic coupling related to the shorter intraplanar Fe-Fe bond distance. With further thallium substitution, the transition temperatures decrease for x = 0.09 (TN = Ts = 131 K), and this is due to charge doping. We illustrate that small changes related to 3d transition-metal state can have profound effects on magnetism.
1511.02400v1
2015-11-24
Transport and thermodynamic properties under anharmonic motion in type-I Ba8Ga16Sn30 clathrate
Anharmonic guest atom oscillation has direct connection to the thermal transport and thermo- electric behavior of type-I Ba8Ga16Sn30 clathrates. This behavior can be observed through several physical properties, with for example the heat capacity providing a measure of the overall excita- tion level structure. Localized anharmonic excitations also influence the low-temperature resistivity, as we show in this paper. By combining heat capacity, transport measurements and our previous NMR relaxation results, we address the distribution of local oscillators in this material, as well as the shape of the confining potential and the excitation energies for Ba(2) ions in the cages. We also compare to the soft-potential model and other models used for similar systems. The results show good agreement between the previously deduced anharmonic rattler potential and experimental data.
1511.07594v1
2015-11-28
Extremely large magnetoresistance in few-layer graphene/boron-nitride heterostructures
Understanding magnetoresistance, the change in electrical resistance upon an external magnetic field, at the atomic level is of great interest both fundamentally and technologically. Graphene and other two-dimensional layered materials provide an unprecedented opportunity to explore magnetoresistance at its nascent stage of structural formation. Here, we report an extremely large local magnetoresistance of ~ 2,000% at 400 K and a non-local magnetoresistance of > 90,000% in 9 T at 300 K in few-layer graphene/boron-nitride heterostructures. The local magnetoresistance is understood to arise from large differential transport parameters, such as the carrier mobility, across various layers of few-layer graphene upon a normal magnetic field, whereas the non-local magnetoresistance is due to the magnetic field induced Ettingshausen-Nernst effect. Non-local magnetoresistance suggests the possibility of a graphene based gate tunable thermal switch. In addition, our results demonstrate that graphene heterostructures may be promising for magnetic field sensing applications.
1511.08867v1
2015-12-22
Large-signal model of the bilayer graphene field-effect transistor targeting radio-frequency applications: theory versus experiment
Bilayer graphene is a promising material for radio-frequency transistors because its energy gap might result in a better current saturation than the monolayer graphene. Because the great deal of interest in this technology, especially for flexible radio-frequency applications, gaining control of it requires the formulation of appropriate models for the drain current, charge and capacitance. In this work we have developed them for a dual-gated bilayer graphene field-effect transistor. A drift-diffusion mechanism for the carrier transport has been considered coupled with an appropriate field-effect model taking into account the electronic properties of the bilayer graphene. Extrinsic resistances have been included considering the formation of a Schottky barrier at the metal-bilayer graphene interface. The proposed model has been benchmarked against experimental prototype transistors, discussing the main figures of merit targeting radio-frequency applications.
1512.07159v1
2016-01-21
Saturation of ion irradiation effects in Cr2AlC
Cr2AlC materials were irradiated with 7 MeV Xe26+ ions and 500 keV He2+ ions at room temperature. A structural transition with an increased c lattice parameter and a decreased a lattice parameter occurs after irradiation to doses above 1 dpa. Nevertheless, the modified structure is stable up to the dose of 5.2 dpa without obvious lattice disorder. The three samples irradiated to doses above 1 dpa have comparable lattice parameters and hardness values, suggesting a saturation of irradiation effects in Cr2AlC. The structural transition and irradiation effects saturation are ascribed to irradiation-induced antisite defects (CrAl and AlCr) and C interstitials, which is supported by the calculations of the formation energies of various defects in Cr2AlC. The irradiation-induced antisite defects and C interstitials may be critical to understand the excellent resistance to irradiation-induced amorphization of MAX phases.
1601.05514v1
2016-02-02
Fast synthesis of Fe1.1Se1-xTex superconductors in a self-heating and furnace-free way
A fast and furnace-free method of combustion synthesis is employed for the first time to synthesize iron-based superconductors. Using this method, Fe1.1Se1-xTex (0<=x<=1) samples can be prepared from self-sustained reactions of element powders in only tens of seconds. The obtained Fe1.1Se1-xTex samples show clear zero resistivity and corresponding magnetic susceptibility drop at around 10-14 K. The Fe1.1Se0.33Te0.67 sample shows the highest onset Tc of about 14 K, and its upper critical field is estimated to be approximately 54 T. Compared with conventional solid state reaction for preparing polycrystalline FeSe samples, combustion synthesis exhibits much-reduced time and energy consumption, but offers comparable superconducting properties. It is expected that the combustion synthesis method is available for preparing plenty of iron-based superconductors, and in this direction further related work is in progress.
1602.00880v1
2016-02-11
A multiscale model of distributed fracture and permeability in solids in all-round compression
We present a microstructural model of permeability in fractured solids, where the fractures are described in terms of recursive families of parallel, equidistant cohesive faults. Faults originate upon the attainment of a tensile or shear resistance in the undamaged material. Secondary faults may form in a hierarchical orga- nization, creating a complex network of connected fractures that modify the permeability of the solid. The undamaged solid may possess initial porosity and permeability. The particular geometry of the superposed micro-faults lends itself to an explicit analytical quantification of the porosity and permeability of the dam- aged material. The approach is particularly appealing as a means of modeling low permeability oil and gas reservoirs stimulated by hydraulic fracturing.
1602.03801v2
2016-04-04
Universal scaling for the spin-electricity conversion on surface states of topological insulators
We have investigated spin-electricity conversion on surface states of bulk-insulating topological insulator (TI) materials using a spin pumping technique. The sample structure is Ni-Fe|Cu|TI trilayers, in which magnetic proximity effects on the TI surfaces are negligibly small owing to the inserted Cu layer. Voltage signals produced by the spin-electricity conversion are clearly observed, and enhanced with decreasing temperature in line with the dominated surface transport at lower temperatures. The efficiency of the spin-electricity conversion is greater for TI samples with higher resistivity of bulk states and longer mean free path of surface states, consistent with the surface spin-electricity conversion.
1604.00751v1
2016-04-06
Enhanced Thermoelectric Power and Electronic Correlations in RuSe$_2$
We report the electronic structure, electric and thermal transport properties of Ru$_{1-x}$Ir$_{x}$Se$_2$ ($x \leq 0.2$). RuSe$_2$ is a semiconductor that crystallizes in a cubic pyrite unit cell. The Seebeck coefficient of RuSe$_2$ exceeds -200 $\mu$V/K around 730 K. Ir substitution results in the suppression of the resistivity and the Seebeck coefficient, suggesting the removal of the peaks in density of states near the Fermi level. Ru$_{0.8}$Ir$_{0.2}$Se$_{2}$ shows a semiconductor-metal crossover at about 30 K. The magnetic field restores the semiconducting behavior. Our results indicate the importance of the electronic correlations in enhanced thermoelectricity of RuSb$_{2}$.
1604.01755v1
2016-04-12
EPW: Electron-phonon coupling, transport and superconducting properties using maximally localized Wannier functions
The EPW (Electron-Phonon coupling using Wannier functions) software is a Fortran90 code that uses density-functional perturbation theory and maximally localized Wannier functions for computing electron-phonon couplings and related properties in solids accurately and efficiently. The EPW v4 program can be used to compute electron and phonon self-energies, linewidths, electron-phonon scattering rates, electron-phonon coupling strengths, transport spectral functions, electronic velocities, resistivity, anisotropic superconducting gaps and spectral functions within the Migdal-Eliashberg theory. The code now supports spin-orbit coupling, time-reversal symmetry in non-centrosymmetric crystals, polar materials, and $\mathbf{k}$ and $\mathbf{q}$-point parallelization. Considerable effort was dedicated to optimization and parallelization, achieving almost a ten times speedup with respect to previous releases. A computer test farm was implemented to ensure stability and portability of the code on the most popular compilers and architectures. Since April 2016, version 4 of the EPW code is fully integrated in and distributed with the Quantum ESPRESSO package, and can be downloaded through QE-forge at http://qe-forge.org/gf/project/q-e.
1604.03525v2
2016-05-09
A non-volatile memory based on nonlinear magnetoelectric effects
The magnetoelectric effects in multiferroics have a great potential in creating next-generation memory devices. We conceive a new concept of non-volatile memories based on a type of nonlinear magnetoelectric effects showing a butterfly-shaped hysteresis loop. The principle is to utilize the states of the magnetoelectric coefficient, instead of magnetization, electric polarization or resistance, to store binary information. Our experiments in a device made of the PMN-PT/Terfenol-D multiferroic heterostructure clearly demonstrate that the sign of the magnetoelectric coefficient can be repeatedly switched between positive and negative by applying electric fields, confirming the feasibility of this principle. This kind of non-volatile memory has outstanding practical virtues such as simple structure, easy operations in writing and reading, low power, fast speed, and diverse materials available.
1605.02505v1
2016-05-17
Pressure-induced gap closing and metallization of MoSe$_{2}$ and MoTe$_{2}$
Layered molybdenum dichalchogenides are semiconductors whose gap is controlled by delicate interlayer interactions. The gap tends to drop together with the interlayer distance, suggesting collapse and metallization under pressure. We predict, based on first principles calculations, that layered semiconductors 2H$_c$-MoSe$_2$ and 2H$_c$-MoTe$_2$ should undergo metallization at pressures between 28 and 40 GPa (MoSe$_2$) and 13 and 19 GPa (MoTe$_2$). Unlike MoS$_2$ where a 2H$_c$ $\to$ 2H$_a$ layer sliding transition is known to take place, these two materials appear to preserve the original 2H$_c$ layered structure at least up to 100 GPa and to increasingly resist lubric layer sliding under pressure. Similar to metallized MoS$_2$ they are predicted to exhibit a low density of states at the Fermi level, and presumably very modest superconducting temperatures if any. We also study the $\beta$-MoTe$_2$ structure, metastable with a higher enthalpy than 2H$_c$-MoTe$_2$. Despite its ready semimetallic and (weakly) superconducting character already at zero pressure, metallicity is not expected to increase dramatically with pressure.
1605.05111v1