text
stringlengths
2
2.33k
source
stringclasses
826 values
mass : fundamental property indicating amount of matter
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
matter : anything that occupies space and has mass
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
meter (m) : standard metric and SI unit of length; 1 m = approximately 1.094 yards
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
microscopic domain : realm of things that are much too small to be sensed directly
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
milliliter (mL) : 1/1,000 of a liter; equal to 1 cm3
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
mixture : matter that can be separated into its components by physical means
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
molecule : bonded collection of two or more atoms of the same or different elements
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
physical change : change in the state or properties of matter that does not involve a change in its chemical composition
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
physical property : characteristic of matter that is not associated with any change in its chemical composition
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
plasma : gaseous state of matter containing a large number of electrically charged atoms and/or molecules
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
precision : how closely a measurement matches the same measurement when repeated
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
pure substance : homogeneous substance that has a constant composition
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
rounding : procedure used to ensure that calculated results properly reflect the uncertainty in the measurements used in the calculation
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
scientific method : path of discovery that leads from question and observation to law or hypothesis to theory, combined with experimental verification of the hypothesis and any necessary modification of the theory
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
second (s) : SI unit of time
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
SI units (International System of Units) : standards fixed by international agreement in the International System of Units (Le Système International d’Unités)
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
significant figures : (also, significant digits) all of the measured digits in a determination, including the uncertain last digit
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
solid : state of matter that is rigid, has a definite shape, and has a fairly constant volume
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
symbolic domain : specialized language used to represent components of the macroscopic and microscopic domains, such as chemical symbols, chemical formulas, chemical equations, graphs, drawings, and calculations
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
temperature : intensive property representing the hotness or coldness of matter
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
theory : well-substantiated, comprehensive, testable explanation of a particular aspect of nature
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
uncertainty : estimate of amount by which measurement differs from true value
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
unit : standard of comparison for measurements
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
unit conversion factor : ratio of equivalent quantities expressed with different units; used to convert from one unit to a different unit
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
volume : amount of space occupied by an object
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
weight : force that gravity exerts on an object
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-key-terms
Chemistry deals with the composition, structure, and properties of matter, and the ways by which various forms of matter may be interconverted. Thus, it occupies a central place in the study and practice of science and technology. Chemists use the scientific method to perform experiments, pose hypotheses, and formulate...
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-summary
Matter is anything that occupies space and has mass. The basic building block of matter is the atom, the smallest unit of an element that can enter into combinations with atoms of the same or other elements. In many substances, atoms are combined into molecules. On earth, matter commonly exists in three states: solids,...
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-summary
All substances have distinct physical and chemical properties, and may undergo physical or chemical changes. Physical properties, such as hardness and boiling point, and physical changes, such as melting or freezing, do not involve a change in the composition of matter. Chemical properties, such flammability and acidit...
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-summary
Measurable properties fall into one of two categories. Extensive properties depend on the amount of matter present, for example, the mass of gold. Intensive properties do not depend on the amount of matter present, for example, the density of gold. Heat is an example of an extensive property, and temperature is an exam...
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-summary
Measurements provide quantitative information that is critical in studying and practicing chemistry. Each measurement has an amount, a unit for comparison, and an uncertainty. Measurements can be represented in either decimal or scientific notation. Scientists primarily use SI (International System) units such as meter...
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-summary
Quantities can be defined or measured. Measured quantities have an associated uncertainty that is represented by the number of significant figures in the quantity’s number. The uncertainty of a calculated quantity depends on the uncertainties in the quantities used in the calculation and is reflected in how the value...
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-summary
Measurements are made using a variety of units. It is often useful or necessary to convert a measured quantity from one unit into another. These conversions are accomplished using unit conversion factors, which are derived by simple applications of a mathematical approach called the factor-label method or dimensional a...
https://openstax.org/books/chemistry-atoms-first-2e/pages/1-summary
average mass = ∑ i ( fractional abundance × isotopic mass ) i average mass = ∑ i ( fractional abundance × isotopic mass ) i
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-equations
alpha particle (α particle) : positively charged particle consisting of two protons and two neutrons
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
anion : negatively charged atom or molecule (contains more electrons than protons)
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
atomic mass : average mass of atoms of an element, expressed in amu
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
atomic mass unit (amu) : (also, unified atomic mass unit, u, or Dalton, Da) unit of mass equal to112112of the mass of a12C atom
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
atomic number (Z) : number of protons in the nucleus of an atom
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
cation : positively charged atom or molecule (contains fewer electrons than protons)
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
chemical symbol : one-, two-, or three-letter abbreviation used to represent an element or its atoms
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
Dalton (Da) : alternative unit equivalent to the atomic mass unit
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
Dalton’s atomic theory : set of postulates that established the fundamental properties of atoms
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
electron : negatively charged, subatomic particle of relatively low mass located outside the nucleus
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
empirical formula : formula showing the composition of a compound given as the simplest whole-number ratio of atoms
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
fundamental unit of charge : (also called the elementary charge) equals the magnitude of the charge of an electron (e) with e = 1.602××10−19C
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
ion : electrically charged atom or molecule (contains unequal numbers of protons and electrons)
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
isomers : compounds with the same chemical formula but different structures
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
isotopes : atoms that contain the same number of protons but different numbers of neutrons
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
law of constant composition : (also, law of definite proportions) all samples of a pure compound contain the same elements in the same proportions by mass
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
law of definite proportions : (also, law of constant composition) all samples of a pure compound contain the same elements in the same proportions by mass
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
law of multiple proportions : when two elements react to form more than one compound, a fixed mass of one element will react with masses of the other element in a ratio of small whole numbers
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
mass number (A) : sum of the numbers of neutrons and protons in the nucleus of an atom
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
molecular formula : formula indicating the composition of a molecule of a compound and giving the actual number of atoms of each element in a molecule of the compound.
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
neutron : uncharged, subatomic particle located in the nucleus
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
nucleus : massive, positively charged center of an atom made up of protons and neutrons
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
proton : positively charged, subatomic particle located in the nucleus
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
spatial isomers : compounds in which the relative orientations of the atoms in space differ
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
structural formula : shows the atoms in a molecule and how they are connected
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
structural isomer : one of two substances that have the same molecular formula but different physical and chemical properties because their atoms are bonded differently
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
unified atomic mass unit (u) : alternative unit equivalent to the atomic mass unit
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-key-terms
The ancient Greeks proposed that matter consists of extremely small particles called atoms. Dalton postulated that each element has a characteristic type of atom that differs in properties from atoms of all other elements, and that atoms of different elements can combine in fixed, small, whole-number ratios to form com...
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-summary
Although no one has actually seen the inside of an atom, experiments have demonstrated much about atomic structure. Thomson’s cathode ray tube showed that atoms contain small, negatively charged particles called electrons. Millikan discovered that there is a fundamental electric charge—the charge of an electron. Ru...
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-summary
An atom consists of a small, positively charged nucleus surrounded by electrons. The nucleus contains protons and neutrons; its diameter is about 100,000 times smaller than that of the atom. The mass of one atom is usually expressed in atomic mass units (amu), which is referred to as the atomic mass. An amu is defined ...
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-summary
Protons are relatively heavy particles with a charge of 1+ and a mass of 1.0073 amu. Neutrons are relatively heavy particles with no charge and a mass of 1.0087 amu. Electrons are light particles with a charge of 1− and a mass of 0.00055 amu. The number of protons in the nucleus is called the atomic number (Z) and is...
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-summary
Isotopes of an element are atoms with the same atomic number but different mass numbers; isotopes of an element, therefore, differ from each other only in the number of neutrons within the nucleus. When a naturally occurring element is composed of several isotopes, the atomic mass of the element represents the average ...
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-summary
A molecular formula uses chemical symbols and subscripts to indicate the exact numbers of different atoms in a molecule or compound. An empirical formula gives the simplest, whole-number ratio of atoms in a compound. A structural formula indicates the bonding arrangement of the atoms in the molecule. Ball-and-stick and...
https://openstax.org/books/chemistry-atoms-first-2e/pages/2-summary
c = λν
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-equations
E = h ν = h c λ , E = h ν = h c λ , where h = 6.626 × × 10 −34 J s
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-equations
1 λ = R ∞ ( 1 n 1 2 − 1 n 2 2 ) 1 λ = R ∞ ( 1 n 1 2 − 1 n 2 2 )
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-equations
E n = − k Z 2 n 2 , n = 1 , 2 , 3 , … E n = − k Z 2 n 2 , n = 1 , 2 , 3 , …
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-equations
Δ E = k Z 2 ( 1 n 1 2 − 1 n 2 2 ) Δ E = k Z 2 ( 1 n 1 2 − 1 n 2 2 )
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-equations
r = n 2 Z a 0 r = n 2 Z a 0
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-equations
actinide : inner transition metal in the bottom of the bottom two rows of the periodic table
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
alkali metal : element in group 1
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
alkaline earth metal : element in group 2
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
amplitude : extent of the displacement caused by a wave
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
atomic orbital : mathematical function that describes the behavior of an electron in an atom (also called the wavefunction)
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
Aufbau principle : procedure in which the electron configuration of the elements is determined by “building” them in order of atomic numbers, adding one proton to the nucleus and one electron to the proper subshell at a time
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
blackbody : idealized perfect absorber of all incident electromagnetic radiation; such bodies emit electromagnetic radiation in characteristic continuous spectra called blackbody radiation
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
Bohr’s model of the hydrogen atom : structural model in which an electron moves around the nucleus only in circular orbits, each with a specific allowed radius
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
chalcogen : element in group 16
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
continuous spectrum : electromagnetic radiation given off in an unbroken series of wavelengths (e.g., white light from the sun)
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
core electron : electron in an atom that occupies the orbitals of the inner shells
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
covalent bond : attractive force between the nuclei of a molecule’s atoms and pairs of electrons between the atoms
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
covalent compound : (also, molecular compound) composed of molecules formed by atoms of two or more different elements
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
covalent radius : one-half the distance between the nuclei of two identical atoms when they are joined by a covalent bond
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
dorbital : region of space with high electron density that is either four lobed or contains a dumbbell and torus shape; describes orbitals withl= 2.
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
degenerate orbitals : orbitals that have the same energy
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
effective nuclear charge : charge that leads to the Coulomb force exerted by the nucleus on an electron, calculated as the nuclear charge minus shielding
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
electromagnetic radiation : energy transmitted by waves that have an electric-field component and a magnetic-field component
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
electromagnetic spectrum : range of energies that electromagnetic radiation can comprise, including radio, microwaves, infrared, visible, ultraviolet, X-rays, and gamma rays
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
electron affinity : energy change associated with addition of an electron to a gaseous atom or ion
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
electron configuration : listing that identifies the electron occupancy of an atom’s shells and subshells
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
electron density : a measure of the probability of locating an electron in a particular region of space, it is equal to the squared absolute value of the wave functionψ
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
endothermic : processes that increase the energy of an atom and involve the absorption of light
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
excited state : state having an energy greater than the ground-state energy
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
exothermic : processes that decrease the energy of an atom and involve the emission of light
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
forbital : multilobed region of space with high electron density, describes orbitals withl= 3
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms
frequency (ν) : number of wave cycles (peaks or troughs) that pass a specified point in space per unit time
https://openstax.org/books/chemistry-atoms-first-2e/pages/3-key-terms