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Create SCHEMA.md

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+ # CarbonOps Dataset Schema
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+
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+ ## 1) grid-intensity/
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+ CSV/Parquet with columns:
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+ - `timestamp` (UTC, ISO8601)
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+ - `region` (string, snake_case)
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+ - `intensity_gco2_per_kwh` (float, >=0)
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+ - `source` (enum: `uk_national_grid`, `entsoe`, `custom_csv`)
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+ - `source_url` (string, optional)
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+ - `updated_at` (UTC)
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+
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+ Constraints:
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+ - `timestamp` monotonically increasing within region
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+ - one row per 30 min (GB) or configured resolution
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+ - missing data → `NaN`, never `-1`
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+
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+ ## 2) ci-samples/
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+ - `job_id` (string), `repo` (string), `duration_s` (float), `artifact_mb` (float), `runner_type` (enum), `timestamp_start` (UTC).