image imagewidth (px) 317 2.47k | query stringlengths 197 2.73k | label listlengths 1 1 |
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Material name: Mn-doped CsPbBr3
Morphology: nanocubes.
Synthesis procedure: not reported
Image description: HAADF-TEM (d), label 芒聙聹Mn/Pb 4/1芒聙聺; nearly all particles are nanocubes with D 芒聣聢 6.3 nm; scale bar 50 nm.
Measure temp: not reported
Question: What are the photoluminescence properties of this material? | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 芒聣聢488 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: CsPbBr1.5Cl1.5:Sr0.006 (Sr-0.1
Morphology: not reported
Synthesis procedure: 0.9024 mmol PbBr2, 0.6016 mmol PbCl2, 0.09024 mmol SrBr2脗路6H2O, 0.06016 mmol SrCl2, 6 mL OA, 6 mL OLA, 4 mL ODE, 2 mL Cs-oleate/NH4-oleate (prepared from 3 mmol Cs2CO3, 0.6 mmol (NH4)2CO3, 30 mL ODE, 3.6 mL OA, 120脗掳C vacuum, th... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 461 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 6.74 ns ; Lifetime Dopant_avg: not reported"
] | |
Material=CsPb0.95Co0.05I3 ; Morphology=nearly cubic nanocubes ; Procedure=PbI2 0.8 g + ODE 40 mL; Cs-oleate from Cs2CO3 0.4 g + OA 1.6 mL + ODE 40 mL, 120 脗掳C vacuum, N2 cycles, hold 100 脗掳C; OA 4 mL + OAm 4 mL ligands min storage at 4 脗掳C in dark 48 h, decant and final 4000 rpm 5 min redispersion in hexane 9.6 mL, sec... | [
"Bandgap: not reported ; PLQY total: 98.86% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 673 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material=CsPbBr3 ; Morphology=thickness of 2.8 nm ; Procedure=degassing 0.069 mg PbBr2 with 0.5 mL oleic acid, 0.5 mL oleylamine, and 5 mL octadecene at 120脗掳C for 20 min, then injecting 0.4 mL Cs-oleate (prepared from 0.16 g Cs2CO3, 0.5 mL oleic acid, 8 mL octadecene) at 25脗掳C, heating to 180脗掳C, and quenching. ; Micr... | [
"Bandgap: not reported ; PLQY total: 35.30% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 465 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs2NaInCl6: Sb3
Morphology: micrometer-sized octahedra
Synthesis procedure: InCl3 0.25 mmol, NaCl 0.25 mmol, SbCl3 0.0125 mmol, CsCl 0.5 mmol, HCl 4 mL Heat InCl3/NaCl/SbCl3 in HCl at 78 脗掳C 30 min with stirring; add CsCl; stir 20 min; cool, filter, ethanol-wash 脙聴3; dry under IR lamp
Image description: ... | [
"Bandgap: not reported ; PLQY total: 93% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 450 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Eu3+-doped CH3NH3PbBr3
Morphology: npl
Synthesis procedure: CH3NH3Br prepared from CH3NH3/ethanol (8 mL, 33 wt%) + ethanol 20 mL + HBr 3 mL; PbBr2 partly replaced by EuCl3 to achieve 30 mol%; DMF 1 mL, oleic acid , OAm 60 ?L. l 30 min; add 80 ?L product to 10 mL toluene; centrifuge 2脙聴 at 10 000 rpm for ... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: not reported ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs0.59Rb0.41Pb(Br/Cl)3
Morphology: nanocrystals.
Synthesis procedure: Cs octanoate and Rb octanoate in a 1:2 ratio (total 1 mL), and PbBr2/PbCl2 in DMF, with TOAB and DDAB as ligands. The mixed A-site precursor and B-site precursor were injected into ethanol at room temperature mixing purification via he... | [
"Bandgap: 2.68 eV. ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 461 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Ba(SCN)2-added CsPbBr3
Synthesis procedure: Cs-oleate from Cs2CO3 0.448 g + oleic acid 1.375 mL + octadecene 22 mL (vacuum 120 脗掳C 1 h; 140 脗掳C under N2 oleylamine 0.5 mL (vacuum 120 脗掳C 1 h; 140 脗掳C under N2 PbBr2 0.188 mmol and Ba(SCN)2 0.188 mmol each dissolved in octadecene 5 mL + oleic acid 0.5 mL +... | [
"Bandgap: 2.415 eV ; PLQY total: 74% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 522 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material=Mn2+:OAM2PbBr4 ; Morphology=microcrystals ; Procedure=Pb acetate (0.0758 g), Mn acetate (0.03 g), octadecene (5 mL), oleic acid (0.7 mL), oleylamine (0.27 mL), bromo(trimethyl)silane TMSBr (0.2 mL TMSBr (0.2 mL), keep 1 min, then cool to room temp load reagents into three-neck flask, vacuum 20 min at 100 脗掳C, ... | [
"Bandgap: not reported ; PLQY total: 16% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 405 nm ; PL Peak Dopant: 612芒聠聮619 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 110000.00 ns ; Lifetime Dopant_avg: 110000 ns"
] | |
Material name: Cu2+ doped CsPbCl3
Synthesis procedure: Cs2CO3 (0.0801 g), PbCl2 (0.0556 g), CuCl2 (0.0016 g), ODE (5 mL), OA (0.5 mL), OAm (0.5 mL), and TOP (0.5 mL) in toluene injected at 200脗掳C, quenched in ice-water purified by centrifugation and ethanol washing
Morphology: average lateral size 16.40 nm
Image descri... | [
"Bandgap: 3.01 eV ; PLQY total: 75% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 406 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 10.49 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs2NaBi0.95Mn0.1Cl6
Morphology: not reported
Synthesis procedure: placing 2 mmol CsCl, 0.1 mmol MnCl2, 0.95 mmol BiCl3, and 0.95 mmol NaCl in a 100 mL three-neck flask, adding 5 mL HCl, heating to 120 degrees Celsius with stirring for 60 minutes, followed by centrifugation at 6000 rpm for 5 minutes, wash... | [
"Bandgap: not reported ; PLQY total: 0.80% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 596 nm. ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: CsPbCl3 MnCl2 YbCl3
Morphology: average edge length of 8.3 脗卤 0.4 nm.
Synthesis procedure: treated with 0.125 ml 40 mM MnCl2 and 0.125 ml 40 mM YbCl3 in DMF, added to 3.5 ml of CsPbCl3 dispersion, incubated overnight at room temperature
Image description: (b) is the caption. the d-spacings are 0.28 nm an... | [
"Bandgap: not reported ; PLQY total: 1.60% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 410 nm ; PL Peak Dopant: 610 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 1.50 ns ; Lifetime Dopant_avg: 680000000 ns"
] | |
Material=C18H22Br4F6N2 ; Morphology=plate-like layered single crystal ; Procedure=heat mixture to 110 脗掳C to dissolve solids PbBr2 73 mg (AR 99.0%) dissolved in 48 wt% HBr at 0 脗掳C with stirring; add 2-(4-trifluoromethylphenyl)ethylamine 4-CF3-PEA 64 脦录L (98% wash with CH2Cl2 three times, dry at 60 脗掳C for 8 cool slowl... | [
"Bandgap: 2.88 eV ; PLQY total: 24.63% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 414 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 4.19 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Sb:Cs2InBr4I脗路H2O
Morphology: irregular aggregated crystals
Synthesis procedure: CsBr 2 mmol, In2O3 0.5 mmol, Sb2O3 0.005 mmol mix CsBr, In2O3, Sb2O3 with the HBr/HI mixture, load into a 10 mL Teflon-lined autoclave, heat 180 脗掳C for 7 h, slow-cool to room temperature over 10 h wash crystals three times ... | [
"Bandgap: not reported ; PLQY total: 30% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 597芒聙聯750 nm ; PL Peak Dopant: 597芒聙聯750 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 3110.00 ns ; Lifetime Dopant_avg: not reported"
] | |
Material=CsPbCl0.99Br2.01 ; Morphology=uniform tetragonal nanocubes ; Procedure=at room temperature, simultaneously inject 1 mL PbBr2/CsBr solution and 0.02 mL NiCl2 solution into 10 mL toluene under vigorous stirring in air PbBr2 0.4 mmol, CsBr 0.4 mmol, OA 1 mL, OLA 0.5 mL in DMF 10 mL (stir 30 脗掳C, 1 h); NiCl2 10 mm... | [
"Bandgap: not reported ; PLQY total: 89 脗卤 3% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 469 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Mn2+-doped Cs2AgInCl6
Synthesis procedure: silver acetate Ag(ac) 0.22 mmol, indium(III) acetate In(ac)3 0.25 mmol, manganese acetate Mn(ac)2 (amount to set Mn/In = 0.1), oleylamine (Olam) 0.5 mL, Cs-oleate solution 1 mL (0.5 M), diphenyl ether (DPE) 4 mL; benzoyl chloride (Bz-Cl) 200 脦录L (1.72 mmol) in D... | [
"Bandgap: not reported ; PLQY total: 10% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 620 nm ; PL Peak Dopant: 620 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Mn-doped FAPbBr3
Morphology: nearly cubic nanocrystals
Synthesis procedure: FABr, MnBr2, and PbBr2 together 0.05 mmol in 1 mL DMF; ligands 60 脦录L oleic acid and 20 脦录L oleylamine; antisolvent 6 mL chloroform; washing/redisperse with toluene. at room temperature, dissolve salts in DMF, add ligands, then i... | [
"Bandgap: not reported ; PLQY total: 70% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 526 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 33.60 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs2Na0.2Ag0.8InCl6
Morphology: average size 芒聣聢8.5 nm
Synthesis procedure: in a 100 mL three-neck flask add Cs2CO3, Na and Ag precursors in the stated Na/Ag ratio, In(OAc)3, OA, OLA, ODE; evacuate 30 min (rt); N2, heat to 100 脗掳C for 1 h; evacuate 1 h at 100 脗掳C; N2, heat to 180 脗掳C; inject TMS-Cl (600 ?... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: not reported ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: CsPbBr3
Morphology: not reported
Synthesis procedure: te 1.2 mL after 40 min PbBr2 0.2 g; PbBr2 0.2 g dissolved in ODE 5 mL at 190芒聙聯200 脗掳C for 10 min under air-free conditions quench reaction mixture in 10 脗掳C cold-water bath centrifuge at 15000 rpm for 15 min add OA 0.5 mL and OAm 0.5 mL, maintain 190... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: not reported ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material=CsPbCl3 ; Morphology=cubic ncs ; Procedure=Pb(CH3CO2)2脗路3H2O 0.2 mmol; CsCH3CO2 (1 M in ethanol) 0.28 mL; 1-octadecene (ODE) 5 mL; oleylamine (OLA) 0.5 mL; oleic acid (OA) 1.0 mL. centrifuge 3500 rpm 15 min, redisperse in cyclohexane; wash with ethyl acetate and centrifuge 3500 rpm 15 min (脙聴2); settle overnig... | [
"Bandgap: not reported ; PLQY total: 1.20% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 409 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 2.56 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs2ScCl5脗路H2O
Morphology: diameter 芒聣聢120 nm
Synthesis procedure: e at 芒聣聢3 脗掳C h?1 CsCl 2 mmol and ScCl3脗路6H2O 1 mmol (Cs:Sc = 2:1) are dissolved in 3 mL concentrated HCl, the clear solution is sealed in a 25 mL Teflon-lined stainless-steel autoclave, heated at 180 脗掳C for 12 h, then slowly cooled to ro... | [
"Bandgap: 3.87 eV ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: not reported ; PL Peak Dopant: 550 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material=(C6H18N2O2)Pb0.95Mn0.05Br4 ; Morphology=not reported ; Procedure=dissolve C6H16N2O2 (1 mmol) and PbBr2 (1 mmol) in 2 mL HBr at 60脗掳C with vigorous stirring for 1 h; add ethanol as antisolvent to precipitate; remove supernatant, wash repeatedly with ethanol; filter and dry under vacuum at 70脗掳C overnight. thoro... | [
"Bandgap: not reported ; PLQY total: 12.41% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 403 nm ; PL Peak Dopant: 640 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 15.75 ns ; Lifetime Dopant_avg: 1519000 ns"
] | |
Material name: Cs2ZrCl6
Synthesis procedure: CsCl 2 mmol (99.99%), ZrCl4 1 mmol (99.9%), HCl 5 mL (37% aqueous dissolve CsCl in HCl in a 25 mL Teflon-lined autoclave, add ZrCl4, stir to clear solution, seal and heat at 100 脗掳C for 12 h cool naturally to room temperature mix Cs2ZrCl6 powder with PDMS at mass ratio 1:2 i... | [
"Bandgap: 3.65 eV ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 438 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 12680.00 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Ag-doped Cs2NaBiCl6
Synthesis procedure: CsCl, NaCl, BiCl3, AgCl in stoichiometric ratio Cs:Na:Bi:Ag = 2:1:1:0.01芒聙聯0.1 solvothermal synthesis at 160 脗掳C for 24 h in HCl, washed with ethanol and dried
Morphology: cubic particles
Image description: figure (a) inset is the image caption scale bars 10 脦录m a... | [
"Bandgap: not reported ; PLQY total: 1% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 420 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs2ZrCl6:13%Bi3
Synthesis procedure: dissolve CsCl, Bi2O3/BiO1.5 and ZrCl4 in HCl, stir 30 min, transfer to 100 mL Teflon-lined autoclave, heat 180 脗掳C for 12 h Solvent/acid: HCl(aq, 37 wt%) 30 mL CsCl 6 mmol (99.9%), ZrCl4 2.61 mmol (99.9%), Bi2O3 (as BiO1.5) 0.39 mmol, giving 13 mol% Bi3+ wash three ti... | [
"Bandgap: not reported ; PLQY total: 15.50% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 435 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 12610.00 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Dy3+-doped Cs2NaInCl6: Sb3
Synthesis procedure: with 0.95 mmol dysprosium(III) acetate tetrahydrate added to the raw materials.
Morphology: average size about 10 nm.
Image description: scale bar is 50 nm. (f) is the caption
Measurement temperature: not reported
What are the photoluminescence properties o... | [
"Bandgap: not reported ; PLQY total: 74.20% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: not reported ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 1465.00 ns ; Lifetime Dopant_avg: 8400000 ns"
] | |
Material name: Sr:CsPbI3
Morphology: size 15芒聙聯20 nm
Synthesis procedure: Cs2CO3, PbI2, SrI2 powders, octadecene (ODE), oleylamine (OLA), oleic acid (OA mixture of Cs2CO3, PbI2, and SrI2 with ODE, OLA, OA, sonicated under ambient atmosphere 40芒聙聯50% humidity, 20 脗卤 10 脗掳C reaction mixture turned from colorless to brown... | [
"Bandgap: not reported ; PLQY total: 90% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 690 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Mn2+-doped CsPbCl3
Morphology: nearly cubic nanocrystals
Synthesis procedure: Add PbCl2, MnCl2脗路4H2O, OAm, OA, ODE to a 25 mL three-neck flask; evacuate/refill N2 three times; heat 120 脗掳C for 30 min then to 165 脗掳C and 200 脗掳C for 10 min each; at 200 脗掳C inject additional OA 0.8 mL and OAm 0.8 mL to PbC... | [
"Bandgap: not reported ; PLQY total: 14% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 400 nm ; PL Peak Dopant: 600 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 1100000.00 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: (PPA)2PbBr4:60%Mn2
Morphology: sheet-like particles
Synthesis procedure: dissolve PPABr (0.4 mmol), PbBr2 (0.08 mmol), and MnBr2 (0.12 mmol) in DMF (2.5 mL) at room temperature under stirring ntrifuge 4000 rpm for 5 min PPABr 0.4 mmol; PbBr2 0.08 mmol; MnBr2 0.12 mmol; DMF 2.5 mL; toluene 10 mL. re-dispe... | [
"Bandgap: not reported ; PLQY total: 67% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 405 nm ; PL Peak Dopant: 600 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: 750000 ns"
] | |
Material name: CsMnCl3
Morphology: polycrystalline powders
Synthesis procedure: CsCl and MnCl2脗路4H2O dissolved in 4.0 mL HCl(aq), Cs:Mn feed molar ratio 1.5:1, loaded in 25 mL Teflon-lined autoclave, heated 180 脗掳C for 24 h, cooled to room temperature at 5 脗掳C h?? grinding the single crystals into powders crystals filt... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 655 nm ; PL Peak Dopant: 332, 355, 372, 420, 448 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 202000.00 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs2Na0.997Ag0.003Bi0.935Ho0.065Cl6
Morphology: micron-scale crystallites
Synthesis procedure: dissolve all salts in 5.0 mL HCl (37%) in a 25 mL Teflon autoclave; heat at 453 K (180 脗掳C) for 12 h; cool slowly to room temperature at 5 脗掳C h?1; wash precipitate with isopropanol 脙聴3 and ethanol sonication; d... | [
"Bandgap: not reported ; PLQY total: 87.45% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 620 nm ; PL Peak Dopant: 660 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: 2210 ns"
] | |
Material name: Eu3+-doped CH3NH3PbBr3
Synthesis procedure: CH3NH3Br from CH3NH3/ethanol (8 mL, 33 wt%) + ethanol 20 mL + HBr 3 mL; PbBr2 partly replaced by EuCl3 to 50 mol%; DMF 1 mL, oleic acid , OAm 60 ?L. solvothermal 120 脗掳C 30 min, cool 30 min; add 80 ?L product to 10 mL toluene; centrifuge 2脙聴 at 10 000 rpm for 1... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 412 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: CsMnCl3脗路2H2O.
Morphology: crystalline particle
Synthesis procedure: dissolve in 8 mL HCl (15 mL Teflon liner); 150 脗掳C, 24 h; cool; remove supernatant; wash with ethanol 脙聴3; dry 60 脗掳C, 12 h. CsCl 1 mmol; MnCl2 1 mmol; concentrated HCl 8 mL.
Image description: scale bar 1 脦录m. image caption: SEM (SE) m... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 640 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 150000.00 ns ; Lifetime Dopant_avg: 150000 ns"
] | |
Material name: CsBr:Ca2+,Eu2
Morphology: cube-like nanocrystals densely packed in a monolayer
Synthesis procedure: Cs-oleate precursor: Cs2CO3 0.5 g + oleic acid 2 mL + octadecene 40 mL; vacuum 120脗掳C 30 min; heat under N2 to 150脗掳C until clear; keep Cs-oleate at 100脗掳C before injection. CaBr2 161.53 mg (0.7308 mmol) +... | [
"Bandgap: not reported ; PLQY total: 23.30% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 440 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material=Cs3YCl6:1%Sb ; Morphology=uniform flower-shaped microcrystals ; Procedure=olve YCl3脗路6H2O 0.3 mmol and SbCl3 0.003 mmol in 1.5 mL MeOH CsCl 0.9 mmol (99.99%), YCl3脗路6H2O 0.3 mmol (99.99%), SbCl3 0.003 mmol (99.9%), methanol 7.5 mL (6 mL + 1.5 mL), ethanol 6 mL. dissolve CsCl 0.9 mmol in 6 mL MeOH under ultraso... | [
"Bandgap: 5.4 eV ; PLQY total: 93.50% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 550 nm ; PL Peak Dopant: 550 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 2370.00 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Ba(SCN)2-added CsPbBr3
Morphology: cubic
Synthesis procedure: Cs-oleate from Cs2CO3 0.448 g + oleic acid 1.375 mL + octadecene 22 mL (vacuum 120 脗掳C 1 h, then 140 脗掳C under N2 amine 0.5 mL (120 脗掳C vacuum 1 h, then 140 脗掳C under N2 PbBr2 0.188 mmol and Ba(SCN)2 0.188 mmol each dissolved in octadecene 5 m... | [
"Bandgap: 2.416 eV ; PLQY total: 75% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 521 nm ; PL Peak Dopant: 270芒聙聯480 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Eu2+-doped CsPbBr3
Morphology: not reported
Synthesis procedure: 0.083 mmol EuBr2 and 0.017 mmol PbBr2
Image description: (e) is caption. scale bar is 50 nm. TEM
Measure temp: not reported
Question: What are the photoluminescence properties of this material?
Retrieved similar samples (KG neighbors, top-... | [
"Bandgap: not reported ; PLQY total: 73% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 501 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 5.13 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs2(Ag/Na)InCl6:1.0% Cu
Synthesis procedure: CsCl 2 mmol; AgCl 0.6 mmol; NaCl 0.4 mmol; CuCl 0.2 mmol (nominal feed for Cu+); In(CH3CO2)3 1 mmol; HCl (aq) 10 mL. 25 mL Teflon-lined autoclave Load CsCl (2 mmol), AgCl (0.6 mmol), NaCl (0.4 mmol), CuCl (0.2 mmol), and In(CH3CO2)3 (1 mmol) with 10 mL HCl int... | [
"Bandgap: not reported ; PLQY total: 62.6 % 脗卤 0.6 % ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 605 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 3900.00 ns ; Lifetime Dopant_avg: not reported"
] | |
Material=CsPbClxBr3?x ; Morphology=uniform tetragonal nanocubes ; Procedure=at room temperature, simultaneously inject 1 mL PbBr2/CsBr solution and 0.04 mL NiCl2 solution into 10 mL toluene under vigorous stirring in air PbBr2 0.4 mmol, CsBr 0.4 mmol, OA 1 mL, OLA 0.5 mL in DMF 10 mL (stir 30 脗掳C, 1 h); NiCl2 10 mmol i... | [
"Bandgap: not reported ; PLQY total: 78 脗卤 3% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 455 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: (CEA)2PbBr4:Mn2+ 0.02
Morphology: sheet-like 2d crystals (platelets
Synthesis procedure: CEABr 0.2 mmol + PbBr2 0.1 mmol in DMF 1 mL at 80 C for 1 h; slowly add into toluene 10 mL to precipitate; centrifuge 5000 rpm 5 min; wash with diethyl ether 3脙聴; vacuum-dry at 60 C overnight. CEABr salt (CEA 7 mL + ... | [
"Bandgap: not reported ; PLQY total: 47.01% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 415 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: CsPbxMn1?xCl3
Morphology: cubic qds
Synthesis procedure: Pb(CH3COO)2 and MnCl2, total 2 mmol, mixed in 1-octadecene (ODE) 20 mL + oleic acid (OA) 3 mL + oleylamine (OAm) 3 mL. Dissolve Pb(CH3COO)2 and MnCl2 in ODE/OA/OAm at 70 脗掳C for 1 h (stirring redisperse precipitate in hexane CsOAc 0.9426 g + OA 3 m... | [
"Bandgap: not reported ; PLQY total: 52.47% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 405芒聙聯424 nm ; PL Peak Dopant: 595芒聙聯611 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material=Cs3CdBr5 ; Morphology=bulk crystals ; Procedure=Cs2CO3 3 mmol, (CH3COO)2Cd脗路2H2O 1 mmol, Sb2O3 0 mmol, HBr (40 wt%) 5 mL. Add precursors and HBr to a Teflon autoclave; heat at 160 脗掳C for 4 h; cool to room temperature; wash the solids with ethanol three times; dry at 70 脗掳C for 4 h. ; Micrograph=Scale bar: 2 ?... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 430 nm ; PL Peak Dopant: 430 nm, 665 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs4PbBr6-0.75
Synthesis procedure: inject Cs-oleate 0.8 mL, 5 s, quench with PbBr2 0.076 mmol + ZnBr2 0.057 mmol + ODE 10 mL + OLA 1 mL + OA 1 mL; 120 脗掳C vacuum 1 h 芒聠聮 180 脗掳C N2 Cs
Morphology: quasi-hexagonal 16.6 脗卤 2.2 nm
Image description: scale bar 50 nm. TEM d is TEM image
Measurement temperature... | [
"Bandgap: not reported ; PLQY total: 77.50% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 518 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 28.65 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs2AgInCl6
Synthesis procedure: suspension cooled to room temperature InCl3 0.25 mmol and AgCl 0.25 mmol dissolved in 37 wt% HCl 2 mL at 80 脗掳C, magnetic stirring 30 min; CsCl 0.50 mmol added, mixture kept at 80 脗掳C for 20 min to form Cs2AgInCl6 precipitate powder dried in a centrifugation 6000 rpm 3 min... | [
"Bandgap: 芒聣聢3.24 eV ; PLQY total: 0.40% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: not reported ; PL Peak Dopant: 400芒聙聯700 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Ni-doped CsPbBr3
Synthesis procedure: 0 脗掳C for ~20 min to dissolve CsBr 0.4 mmol (reported as 0.085 mg), PbBr2 0.4 mmol (147 mg), OAm 200 ?L, OA 500 ?L, DMF 5.0 mL; NiBr2 stock 10 mmol (2.18 g in 10 mL DMF) added to reach Ni:Pb = 2:1; antisolvent isopropyl alcohol 10.0 mL. Heat CsBr, PbBr2, OAm, OA in D... | [
"Bandgap: not reported ; PLQY total: 64% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 535 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Sm3+-doped Cs2K0.5Rb0.5(In0.95Sb0.05)Cl6
Morphology: cubic ncs
Synthesis procedure: CsOAc 0.1247 g; KOAc 0.225 mmol; RbOAc 0.225 mmol; In(OAc)3 0.072 g (0.25 mmol); Sb(OAc)3 0.0747 g (0.25 mmol); Sm(OAc)3脗路H2O (amount not reported); oleic acid 2.8 mL; oleylamine 0.7 mL; octadecene 10 mL; TMS芒聙聯Cl 0.4 mL.... | [
"Bandgap: not reported ; PLQY total: 75% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: not reported ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: CsPbBr3
Morphology: cubic nanocrystals.
Synthesis procedure: Dissolve CsBr (0.8 mmol) and PbBr2 (0.8 mmol) in DMF (40 mL) under stirring 20 min; add OA (2 mL) and OAm (1 mL); heat at 60 脗掳C for 1 h to improve solubility CsBr 0.8 mmol; PbBr2 0.8 mmol; DMF 40 mL; oleic acid (OA) 2 mL; oleylamine (OAm) 1 mL... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 520 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 2.55 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: 5% Mn:CsPbI3
Morphology: cubic ncs
Synthesis procedure: Cs-oleate芒聙聰Cs2CO3 0.407 g + OA 1.5 mL + ODE 20 mL NC precursor芒聙聰PbI2 0.087 g (0.188 mmol) + MnI2 0.01 g + OAm 0.5 mL + OA 0.5 mL + ODE 5 mL Ar; raise to 160 脗掳C; inject Cs-oleate; 1 min growth; ice quench 120 脗掳C 30 min Ar; raise to 160 脗掳C; injec... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 679 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 16.00 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Mn??-doped 脦卤-CsPbI3
Synthesis procedure: Cs-oleate: Cs2CO3 0.39 g + oleic acid 2.0 mL + ODE 18 mL, 120 脗掳C vacuum 1 h, then 150 脗掳C under N2 until clear, cooled 60 脗掳C. PbI2 0.4 mmol + Mn(Ac)2 with Mn/Pb feeding ratio 40% in ODE 10 mL, 120 脗掳C vacuum 1 h; inject oleylamine 1.0 mL, oleic a OLA-HI: oleyla... | [
"Bandgap: not reported ; PLQY total: 95% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 682 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 11.50 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs2InBr5H2O
Morphology: plate-like microcrystals
Synthesis procedure: dissolve CsBr in 5 mL HBr/H3PO4, InBr3 in 2 mL same mix, stir 80 脗掳C; mix, seal, heat 80 脗掳C 2 h; wash ethanol 3脙聴, vacuum-dry 50 脗掳C CsBr 1.0 mmol, InBr3 0.5 mmol; Acids/solvent: 9 mL HBr (48%) + 1 mL H3PO4 (85%), hydrohalic acid:H3PO... | [
"Bandgap: not reported ; PLQY total: 28.10% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 365 nm ; PL Peak Dopant: 630 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material=Cs4SnBr6 ; Morphology=cuboid crystal particles ; Procedure=CsBr 4 mmol; SnF2 1 mmol; NH4Br 2 mmol; H2O 200 脦录L. add CsBr, SnF2, and NH4Br to a ball-milling jar with water; wet ball-mill at 600 rpm for 2 h in ambient atmosphere; dry the solid at 60 脗掳C to remove water collect powders. ; Micrograph=scale bar 2 脦... | [
"Bandgap: not reported ; PLQY total: 62.80% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: not reported ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 741.00 ns ; Lifetime Dopant_avg: not reported"
] | |
Material=CsPbBr3 ; Morphology=uniform spherical nanocrystals ; Procedure=, boron oxide (B2O3, 99.9%), zinc oxide (ZnO, 99%), caesium carbonate (Cs2CO3, 99%), lead bromide (PbBr2, 99%), and sodium bromide (NaBr, 99.9% with Cs2CO3 (9.31 mol%), PbBr2 (5.84 mol%), and NaBr (2.76 mol%), fully ground and placed in an alumina... | [
"Bandgap: not reported ; PLQY total: 37.60% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: not reported ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 72.39 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Fe3+-doped CsPbBr3/SiO2
Morphology: grains forming porous aggregates
Synthesis procedure: repeatedly until supernatant is clear disperse 100 mg PNCs/SNPs in 10 mL ethanol; add FeBr3 (10 mg); ultrasonicate 30 min; wash with ethanol and centrifuge 3000 rpm 10 min repeatedly until supernatant is clear; vacu... | [
"Bandgap: 2.19 eV ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: not reported ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 11.37 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cu2+-doped CsPbBr3
Morphology: cubic
Synthesis procedure: Cs-oleate precursor: Cs2CO3 0.16 g + oleic acid 2.5 mL + octadecene 6 mL; heat 120 脗掳C 30 min; raise to 150 脗掳C under N2 until Cs2CO3 fully dissolved PbBr2 0.188 mmol + oleylamine 1 mL + oleic acid 1 mL + octadecene 5 mL in 100 mL 4-neck flask Cs+... | [
"Bandgap: not reported ; PLQY total: 89% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 521.5 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 28.42 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Rb4CdCl6:0.1Mn2
Synthesis procedure: in a 25 mL Teflon-lined autoclave add RbCl 4 mmol, CdO and Mn(CH3COO)2 as Cd2+/Mn2+ sources with total divalent cation amount 1 mmol and Mn2+ molar fraction x = 0.1, plus HCl(aq) 3 mL and DMF 3 mL; heat at 150 脗掳C for 2 h, then cool to room temperature at 2 脗掳C h?1; w... | [
"Bandgap: not reported ; PLQY total: 88% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 580 nm ; PL Peak Dopant: 580 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Sb3+-doped CsPb2Br5/CsPbBr3
Synthesis procedure: 0.1 mmol Cs-oleate, 0.18 mmol PbBr2, 0.02 mmol SbBr3, 0.5 mL oleic acid, 0.5 mL oleylamine, 2 mL DMF, and 0.2 mL HBr. PbBr2, SbBr3 and Cs-oleate dissolved in OA and OAm, DMF as solvent, HBr added dropwise under stirring at room temperature, mixture injecte... | [
"Bandgap: not reported ; PLQY total: 2.70% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 527 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 4.85 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cr3+-doped Cs4SnBr6?xFx
Morphology: not reported
Synthesis procedure: CsBr 4 mmol, SnF2 1 mmol, NH4Br 2 mmol, CrF3 0.1 mmol, deionized H2O 60 脦录L. milled 30 min at 600 rpm, dried 60 min at 60 脗掳C in vacuum milled again 30 min at 600 rpm Precursors loaded in milling jar
Image description: scale bar 6 脦录m.... | [
"Bandgap: not reported ; PLQY total: 56.30% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 525 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 780.00 ns ; Lifetime Dopant_avg: 780 ns"
] | |
Material name: CsPbBr3
Synthesis procedure: 0.188 mmol PbBr2, 5 mL octadecene, 0.5 mL oleic acid, and 0.5 mL oleylamine are added into a four-neck flask and dried under vacuum for 30 min at 150 degrees Celsius. 0.45 mL Cs-oleate solution is injected centrifugation at 10000 rpm for 20 min redispersed in 30 mL t quenched... | [
"Bandgap: not reported ; PLQY total: 38% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 518 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 19.30 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs2NaInCl6: Sb3
Synthesis procedure: Sb-oleate precursor: Sb(CH3COO)3 0.5 mmol + oleic acid 20 mL, 120 脗掳C, 40 min, N2 Cs2CO3 0.3 mmol, CH3COONa 0.3 mmol, In(CH3COO)3 0.285 mmol, Sb-oleate 0.18 mL, 1-octadecene 10 mL, oleic acid 2 mL, oleylamine 0.5 mL; heat 110 脗掳C, 30 min, N2 until clear; inject trioct... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 453 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 17.10 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Mn2+-doped CsPbCl3
Morphology: cubic nanocrystals.
Synthesis procedure: Cs-oleate 0.4 mL swiftly injected (Cs-oleate: Cs2CO3 0.22 g + OA 0.65 mL + ODE 10 mL, 150 脗掳C, clear solution Mn precursor mixture: MnCl2 0.045 g + PbCl2 0.0459 g + TOP 1 mL + OA 1.5 mL + OLA 1.5 mL + ODE 5 mL; 110 脗掳C, vacuum, 20 mi... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 600 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 2.30 ns ; Lifetime Dopant_avg: 1800000 ns"
] | |
Material name: (TMEDA)3(Sb0.5Bi0.5)2Cl12脗路H2O
Morphology: faceted sc
Synthesis procedure: TMEDA 500 ?L; SbCl3 + BiCl3 total 1 mmol with Sb/(Sb+Bi)=0.5; HCl (36.8%) 2 mL mix TMEDA/SbCl3/BiCl3/HCl; heat 90 脗掳C with stirring to clear solution; cool to RT; store 5 脗掳C 24 h 芒聠聮
Image description: scale bar 1.0 mm. SEM capti... | [
"Bandgap: not reported ; PLQY total: 38% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 605 nm ; PL Peak Dopant: 595 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: 2830000 ns"
] | |
Material=Cs2AgInCl6 ; Morphology=average size ~12.4 nm ; Procedure=load reagents in 100 mL three-neck flask; vacuum 30 min at room temp; fill N2, heat to 100 脗掳C (10 脗掳C min?1) for 1 h; vacuum again 1 h at 100 脗掳C; refill N2, heat to 180 脗掳C; swiftly inject TMS-Cl at 180 脗掳C Cs2CO3 163 mg, Ag(ac) 84 mg, In(ac)3 160 mg,... | [
"Bandgap: not reported ; PLQY total: 1.5% 脗卤 0.5% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 570 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Sb:Cs2InCl5脗路H2O
Morphology: inhomogeneous block-like crystals
Synthesis procedure: mix CsCl, In2O3, Sb2O3 with HCl, load into a 10 mL Teflon-lined autoclave, heat 180 脗掳C for 7 h, slow-cool to room temperature over 10 h CsCl 2 mmol, In2O3 0.5 mmol, Sb2O3 0.005 mmol; solvent/acid: HCl 5 mL (37% aqueous t... | [
"Bandgap: not reported ; PLQY total: 28% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 597芒聙聯750 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 2430.00 ns ; Lifetime Dopant_avg: not reported"
] | |
Material=Cs2AgInCl6:Cr3+,Er3 ; Morphology=aggregated irregular faceted microcrystals ; Procedure=heat powder in air at 300 脗掳C for 1 h, then cool to room temperature AgCl 0.5 mmol; InCl3 0.5 mmol; CrCl3脗路6H2O 0.5 mmol (Cr/In precursor ratio 100%); ErCl3脗路6H2O 0.75 mmol (Er/In precursor ratio 150%); n 5 mL HCl at 80 脗掳C... | [
"Bandgap: not reported ; PLQY total: 57.50% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: not reported ; PL Peak Dopant: 1540 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 16810000.00 ns ; Lifetime Dopant_avg: 16810000 ns"
] | |
Material name: Cs2ZrCl6:Bi
Synthesis procedure: Zr(CO3)2 300 mg; Bi(OAc)3 3.4 mg; 1-octadecene (ODE) 10 mL; CH3COOH 325 脦录L; CsOAc 136 mg; oleic acid (OA) 2.8 mL; oleylamine (OLA) 615 脦录L; trimethylchlorosilane (TMSCl) 400 脦录L Combine Zr(CO3)2 (300 mg), Bi(OAc)3 (3.4 mg), ODE (10 mL), and CH3COOH (325 脦录L); heat until ... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 449 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material=Mn2+-doped Cs2AgInCl6 ; Morphology=cubic ncs ; Procedure=silver acetate Ag(ac) 0.22 mmol, indium(III) acetate In(ac)3 0.25 mmol, manganese acetate Mn(ac)2 (amount to set Mn/In = 0.3), oleylamine (Olam) 0.5 mL, Cs-oleate solution 1 mL (0.5 M), diphenyl ether (DPE) 4 mL; benzoyl chloride (Bz-Cl) 200 脦录L (1.72 mm... | [
"Bandgap: not reported ; PLQY total: 7 脗卤 3% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 620 nm ; PL Peak Dopant: 620 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: CsPbBr3
Morphology: nanocubes.
Synthesis procedure: Cs-oleate (Cs2CO3 0.814 g + ODE 30.0 mL + OA 2.5 mL reaction芒聙聰PbBr2 0.138 g, CdBr2 0 g, OAm 1.0 mL, OA 1.0 mL, ODE 10.0 mL; antisolvent ethyl acetate 20.0 mL; hexane 10.0 mL. 5 s 芒聠聮 ethyl acetate purification (7000 rpm 10 min) 芒聠聮 redisperse in hexane... | [
"Bandgap: not reported ; PLQY total: 73% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 516 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs4Cd0.75Mn0.25Bi2Cl12
Morphology: faceted single crystals
Synthesis procedure: CsCl 4 mmol, CdCl2 0.75 mmol, MnCl2 0.25 mmol, BiCl3 2 mmol in HCl 10 mL. hydrothermal芒聙聰mix salts in HCl, heat 180 脗掳C for 12 h, cool to room temperature (acidic atmosphere
Image description: scale bar 100 脦录m SEM sublabels ... | [
"Bandgap: not reported ; PLQY total: 84.10% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 590 nm ; PL Peak Dopant: 590 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 469100.00 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs2SnCl6
Morphology: anisotropic growth into truncated octahedral microcrystals (>10 ?m
Synthesis procedure: CsCl 2 mmol (0.34 g), SnCl2脗路2H2O 1 mmol (0.23 g) dissolved in 5 mL HCl (36芒聙聯38% precipitate multiple times with methanol and acetone; dry ~12 h in a vacuum oven at 50 脗掳C transfer the clear mixt... | [
"Bandgap: not reported ; PLQY total: 7% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 440 nm ; PL Peak Dopant: 438 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 1.67 ns ; Lifetime Dopant_avg: not reported"
] | |
Material=KBr/CsPbI3-xBrx ; Morphology=hexagonal nanocrystals ; Procedure=cesium carbonate (Cs2CO3), lead bromide (PbBr2), lead iodide (PbI2), trioctylphosphine oxide (TOPO), oleic acid (OA), dodecyl dimethylammonium bromide (DDAB), and potassium bromide (KBr Cs-OA was rapidly added for nucleation and growth for 5 min, ... | [
"Bandgap: not reported ; PLQY total: 100% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 636 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 26.78 ns ; Lifetime Dopant_avg: not reported"
] | |
Material=Tb3+-doped Cs2NaInCl6 ; Morphology=cubic ncs ~11 nm ; Procedure=0.4 mmol In(OAc)3, 0.4 mmol Na(OAc), 0.4 mmol Cs(OAc), 10 mL octadecene, 1.5 mL oleylamine, 1.5 mL oleic acid, 0.64 mmol Tb(OAc)3脗路nH2O, heated to 105?脗掳C, evacuated for 80 min, raised to 190?脗掳C under N2, injected 0.8 mL TMSCl at 180?脗掳C, quenche... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 544 nm ; PL Peak Dopant: 490, 583, 622 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 62000.00 ns ; Lifetime Dopant_avg: not reported"
] | |
Material=Mn2+-doped Cs芒聙聯Pb芒聙聯Cl ; Morphology=芒聣聢55.5 nm ; Procedure=Cs-OA precursor: Cs2CO3 2.25 g + oleic acid 21.5 mL in 50 mL three-neck flask, 130 脗掳C 1 h, N2 10 min Cs-OA precursor 1.2 mL + n-hexane 80.0 mL + oleic acid 40.0 mL in 250 mL three-neck flask, degas 5 min, N2 5 min PbCl2 0.204 mmol + MnCl2脗路4H2O 0.036... | [
"Bandgap: not reported ; PLQY total: 77.30% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 405 nm ; PL Peak Dopant: 607 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 0.77 ns ; Lifetime Dopant_avg: 1068000 ns"
] | |
Material name: CPB-1.8Eu Eu3+-doped CsPbBr3
Synthesis procedure: glass batch molar composition 75% (B2O3-SiO2-ZnO-Al2O3-MgO)-25% (Cs2CO3-PbBr2-NaBr)-1.8% Eu2O3; B2O3, SiO2, ZnO, Al2O3, MgO, PbBr2, NaBr, Cs2CO3, Eu2O3 powders fully mixed, melted at 1250 脗掳C for 10 min in air (heating rate 10 脗掳C/min annealed at 400 脗掳C ... | [
"Bandgap: 2.400 eV ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 528 nm ; PL Peak Dopant: 577, 590, 612, 651, and 700 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs2NaIn0.75Bi0.25Cl6:Mn
Morphology: nanocubes.
Synthesis procedure: Cs(OAc) 0.65 mmol, Na(OAc) 0.45 mmol, In(OAc)3 0.75 mmol, Bi(OAc)3 0.25 mmol, Mn(OAc)2 0.14 mmol dissolved in 2.8 mL oleic acid, 0.7 mL oleylamine, 10 mL octadecene; heated at 110脗掳C under vacuum for 60 min. At 168脗掳C, inject 0.4 mL TMSC... | [
"Bandgap: not reported ; PLQY total: 54.28% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: not reported ; PL Peak Dopant: 583芒聙聯614 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: 6000000 ns"
] | |
Material name: CsPb(Br0.8Cl0.2)3
Morphology: cubic-shaped
Synthesis procedure: Hot Cs-oleate precursor (1 mL, prepared by reacting 0.407 g Cs2CO3 and 1.74 mL oleic acid in 18 mL octadecene FeCl2 (x mmol, x = 0 ate precursor (1 mL, prepared by reacting 0.407 g Cs2CO3 and 1.74 mL oleic acid in 18 mL octadecene at 150脗掳C)... | [
"Bandgap: not reported ; PLQY total: 43% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 519 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 47.00 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: (4-tert-butylbenzylamine)2PbBr4:8.4%Mn2
Morphology: irregular platelet-like crystal
Synthesis procedure: not reported
Image description: SEM image of a single polycrystal; white rectangle indicates EDS-mapping region.
Measure temp: RT
Question: What are the photoluminescence properties of this material? | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 芒聣聢410 nm ; PL Peak Dopant: 芒聣聢630 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 19.80 ns ; Lifetime Dopant_avg: 432970 ns"
] | |
Material=CPB-1.8Eu Eu3+-doped CsPbBr3 ; Morphology=average nc size 芒聣聢9.8 nm ; Procedure=glass batch molar composition 75% (B2O3-SiO2-ZnO-Al2O3-MgO)-25% (Cs2CO3-PbBr2-NaBr)-1.8% Eu2O3; B2O3, SiO2, ZnO, Al2O3, MgO, PbBr2, NaBr, Cs2CO3, Eu2O3 powders fully mixed, melted at 1250 脗掳C for 10 min in air (heating rate 10 脗掳C/... | [
"Bandgap: 2.400 eV ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 528 nm ; PL Peak Dopant: 577, 590, 612, 651, and 700 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: CsPbBr3
Synthesis procedure: Cs-OA: Cs2CO3 0.16 g (0.49 mmol) + OA 2.0 mL + ODE 6 mL, 120 脗掳C 30 min N2, 150 脗掳C 5 min; PbBr2 0.07 g + ODE 5 mL, 120 脗掳C 30 min N2; add OAm 1 mL, OA 1 mL; transfer to Teflon autoclave; inject Cs-OA 0.4 mL, HBr 0 脦录L; 140 脗掳C 30 min; cool to RT; centrifuge 8500 rpm 4 min; w... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 511 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: 0.5% Ni-doped CsPbCl3
Morphology: monodisperse cubic ncs
Synthesis procedure: synthesis芒聙聰PbCl2 0.188 mmol, OA 1 mL, OLAm 1 mL, ODE 5 mL; add NiCl2 in the stoichiometric amount for 0.5% Ni; degas 120 脗掳C 1 h (vacuum), switch to Ar; raise to 180 脗掳C Cs-oleate precursor芒聙聰Cs2CO3 400 mg, OA 1.5 mL, ODE 20 m... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 364.7 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: CsPbBr3:10 mol%Zn(SCN)2
Morphology: monodisperse quasi-cubic particles
Synthesis procedure: PbBr2 0.188 mmol 脙聴0.9 and Zn(SCN)2 0.188 mmol 脙聴0.1 dissolved in octadecene 5 mL, oleic acid 0.5 mL, oleylamine 0.5 mL; dry at 120脗掳C under vacuum, then heat to 150脗掳C under N2. Cs-oleate precursor: Cs2CO3 0.163 ... | [
"Bandgap: 2.47 eV. ; PLQY total: 84% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 516.2 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Bi-doped Cs2Ag(In0.829Tb0.171)Cl6
Morphology: average size 12.9 nm
Synthesis procedure: mix 0.36 mmol AgNO3, 0.30 mmol InCl3, 0.0036 mmol BiCl3, 0.06 mmol Tb(NO3)3脗路5H2O, 14 mL ODE, 1 mL OA, 1 mL OLA, and 0.28 mL HCl in a 50 mL flask, degas under vacuum at 120脗掳C for 1 h, heat to 260脗掳C under N2, inject ... | [
"Bandgap: not reported ; PLQY total: 9.20% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 570 nm ; PL Peak Dopant: 495, 545, 587, 622 nm. ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 577.90 ns ; Lifetime Dopant_avg: 7600 ns"
] | |
Material=Cs2NaBiCl6 (CNBC ; Morphology=micron-sized polyhedral crystals ; Procedure=CsCl, NaCl, BiCl3 mixed in stoichiometric 2:1:1 molar ratio, dissolved in HCl solution, heated at 160 脗掳C for 24 h under solvothermal conditions product washed with ethanol and dried ; Micrograph=figure (b) is the image caption scale ba... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: not reported ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: CsPb(BrI)3
Morphology: from 9.5 to 21 nm.
Synthesis procedure: PbI2 (0.15 g), PbBr2 (0.08 g), oleic acid (2 mL), oleylamine (2 mL), and 1-octadecene (10 mL) were added to a three-necked bottle and dried under vacuum at 120脗掳C until PbX2 was completely dissolved. mixture solution was then heated to 175脗掳C... | [
"Bandgap: not reported ; PLQY total: 21.40% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 635 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 66.21 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs2NaGdCl6:1% Sb3+, 3% Sm3
Morphology: polyhedral microcrystals
Synthesis procedure: Mix CsCl, NaCl, Sb2O3, SmCl3脗路6H2O, and GdCl3脗路6H2O in 3 mL HCl; transfer to a 20 mL Teflon-lined autoclave; heat at 180 脗掳C for 12 h; cool slowly to room temperature CsCl 2 mmol; NaCl 1 mmol; Sb2O3 0.005 mmol (gives 1% ... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 460 nm ; PL Peak Dopant: 567, 605, 655, 711 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: 990 ns"
] | |
Material name: Cs2K0.5Rb0.5(In0.95Sb0.05)Cl6
Morphology: quasi-cubic ncs
Synthesis procedure: CsOAc 0.1247 g, NaOAc replaced by KOAc 0.225 mmol and RbOAc 0.225 mmol, In(OAc)3 0.144 g oleic acid (OA) 2.8 mL, oleylamine (OLA) 0.7 mL, 1-octadecene (ODE) 10 mL r 1 h load reagents in a three-neck flask; evacuate at 110 脗掳C ... | [
"Bandgap: not reported ; PLQY total: 45.01% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 520 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs3Zn0.5Cl5:0.5Sb3
Synthesis procedure: CsCl, ZnCl2, SbCl3 in DMF to give Cs3Zn0.5Cl5:0.5Sb3 Dissolve in DMF; stir 12 h at room temperature in air; centrifuge; wash ethanol (脙聴3); dry 50 脗掳C 12 h.
Morphology: uniform rods ~2 脦录m.
Image description: Scale bar: 2 脦录m. SEM e is the image caption 芒聙聹SEM of C... | [
"Bandgap: not reported ; PLQY total: 23.67% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 573 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs2AgInCl6:Sm
Morphology: irregular agglomerated
Synthesis procedure: Sm(CH3COO)3脗路6H2O 0.20 mmol together with InCl3 0.25 mmol and AgCl 0.25 mmol in 37 wt% HCl 2 mL at 80 脗掳C, stirring 30 min; then CsCl 0.50 mmol added, 80 脗掳C for 20 min, followed by ethanol washing (centrifugation 6000 rpm 3 min, three... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: not reported ; PL Peak Dopant: 芒聣聢567 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: 4330000 ns"
] | |
Material name: Pb??-alloyed Cs?ZnBr
Synthesis procedure: heat mixture to 120 脗掳C under N? with stirring 1 h; raise to 140 脗掳C and hold 10 min; inject Bz-Br rapidly; after 5 min quench in ice芒聙聯water bath; centrifuge 10 000 rpm 6 min, wash with cyclohexane (4 mL), centrifuge 10 000 rpm 6 min, redisperse in cyclohexane (... | [
"Bandgap: not reported ; PLQY total: 82.90% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 433 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 66.70 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: (PbBr2+TOAB)-treated CsPbBr3
Morphology: cubic qds
Synthesis procedure: prepare solution with PbBr2 0.11 mmol + TOAB 0.20 mmol in toluene 100 ?L add passivation solution (100芒聙聯500 ?L; 300 ?L yields
Image description: TEM HRTEM (d-spacing 0.41 nm scale bars: main 20 nm insets 5 nm. b is TEM of (PbBr2+TOA... | [
"Bandgap: not reported ; PLQY total: 96.60% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 513 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 77.47 ns ; Lifetime Dopant_avg: not reported"
] | |
Material=Mn-doped CsPbBr3 ; Morphology=scale bar: 50 nm. ; Procedure=In a 50 mL three-neck flask add PbBr2, Mn(OAc)2, HBr, OA (0.7 mL), OAm (0.7 mL), and ODE (5 mL); degas at 140 脗掳C for 1 h, purge with N2; inject additional OA (0.7 mL) and OAm (0.7 mL); heat to 200 脗掳C for 1 h; swiftly inject 0.4 mL Cs-oleate at 200 脗... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 490 nm ; PL Peak Dopant: 616 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: 261000 ns"
] | |
Material name: Cs4MnBi2Cl12:5%Yb3
Morphology: micro-grained powder
Synthesis procedure: dissolve Bi2O3, Yb2O3 and MnCl2 in HCl at room temperature with vigorous stirring; add CsCl to precipitate; stir 20 min; filter; wash once with ethanol Bi2O3 0.95 mmol, Yb2O3 0.05 mmol, MnCl2 1.00 mmol, CsCl 4.00 mmol, HCl 10 mL, et... | [
"Bandgap: not reported ; PLQY total: 0.95%. ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 580 nm ; PL Peak Dopant: 1000 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Cs2HfCl6:0.5%Te
Morphology: particle dimension tens of micrometers
Synthesis procedure: CsCl 2 mmol (99.99%), HfCl4 1 mmol (99.9%), TeCl4 amount adjusted for 0.5 mol% Te4+ relative to Hf4+ (99.99%), concentrated HCl 4.0 mL (37 wt% all solids and HCl mixed in 25 mL Teflon-lined autoclave, heated 180 脗掳C 1... | [
"Bandgap: not reported ; PLQY total: 95.26% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 575 nm ; PL Peak Dopant: 575 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 2310000.00 ns ; Lifetime Dopant_avg: 1300000 ns"
] | |
Material name: Cs2NaInCl6:30% Sb3+, 45% Sm3
Synthesis procedure: Cesium acetate 0.65 mmol; sodium acetate 0.35 mmol; indium acetate hydrate 0.125 mmol; Sb-oleate 1.8 mL; samarium acetate hexahydrate 0.225 mmol; OA 2.8 mL; OAm 0.7 mL; ODE 10 mL; TOP 0.3 mL; chlorotrimethylsilane 0.4 mL. OA 15 mL; N2, 150 脗掳C, 1 h. Antim... | [
"Bandgap: not reported ; PLQY total: 35.80% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 458芒聙聯460 nm ; PL Peak Dopant: 565, 602, 650, 710 nm. ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 1000.76 ns ; Lifetime Dopant_avg: 8660000 ns"
] | |
Material name: Cu2+-doped CsPb2Br5/CsPbBr3
Morphology: irregular shape
Synthesis procedure: CsBr, PbBr2, CuBr2 in DMSO, oleylamine and oleic acid ligands, ethanol as antisolvent, Pb/Cu molar ratio = 5:1
Image description: not reported
Measure temp: not reported
Question: What are the photoluminescence properties of thi... | [
"Bandgap: not reported ; PLQY total: 100% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: not reported ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 19.46 ns ; Lifetime Dopant_avg: not reported"
] | |
Material name: CsPb0.975Co0.025I3
Synthesis procedure: Cs-oleate prepared as above from Cs2CO3 0.4 g + OA 1.6 mL + ODE 40 mL (120 脗掳C vacuum, N2 purge cycles, keep 100 脗掳C under N2 CsPbI3: PbI2 0.8 g + ODE 40 mL mple: MeOAc antisolvent 1:3, centrifuge 8000 rpm 5 min, redispersion in hexane 9.6 mL, second MeOAc precipit... | [
"Bandgap: not reported ; PLQY total: 96.21% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 680 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: 15%Sb3+:(NH4)2SnCl6
Morphology: microcrystals
Synthesis procedure: NH4Cl 2 mmol; SnCl4脗路5H2O 1 mmol; Sb2O3 stock made by dissolving Sb2O3 0.05 mmol in HCl 1 mL; for 15% feed add 500 脦录L of the Sb-precursor solution; HCl (aq) 2 mL added to each liner. load NH4Cl, SnCl4脗路5H2O, and the measured volume of Sb... | [
"Bandgap: not reported ; PLQY total: 58% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 590 nm ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] | |
Material name: Mn:PEA2PbCl3.2Br0.8.
Synthesis procedure: PbBr2 0.08 mmol, MnBr2 0.24 mmol, HBr (43%) 100 ?L to clarity at room temperature; add PEABr 0.20 mmol (solid) to form Mn:PEA2PbBr4; add trace HCl (43%) and shake 3 min to obtain Mn:PEA2PbCl3.2Br0.8. UV 365 nm, 6 W, continuous illumination for 3 h at room tempera... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 417 nm ; PL Peak Dopant: 600 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: 1370000 ns"
] | |
Material name: Cs2NaInCl6:2.5%Sb
Synthesis procedure: InCl3 + SbCl3 total 0.45 mmol with Sb/(Sb+In)=0.025, ODE 14 mL, OA 1.5 mL, OAm 1.5 mL, HCl 0.35 mL in 100 mL three-neck flask. Degas 110 脗掳C 1 h, then 260 脗掳C under N2, inject Cs/Na-oleate 1 mL, react 30 s, quench ice bath. Cs/Na-oleate stock: Cs2CO3 1.628 g, CH3COO... | [
"Bandgap: not reported ; PLQY total: 22% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: not reported ; PL Peak Dopant: not reported ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: 1023.87 ns ; Lifetime Dopant_avg: not reported"
] | |
Material=CsPbBr3@GdF3:Eu3 ; Morphology=diameter ~400 nm ; Procedure=with deionized water and ethanol place Gd(OH)CO3:Eu3+ precursor 0.042 g in small crucible inside larger crucible containing KHF2 0.5 g; heat in HF atmosphere to 400 脗掳C at 2 脗掳C脗路min?1; hold 2 h under vacuum to dissolve PbBr2 and remove water in 100 mL... | [
"Bandgap: not reported ; PLQY total: 24.34% ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 525 nm ; PL Peak Dopant: 598 nm, 618芒聙聯633 nm, 660 nm, and 713 nm. ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported... | |
Material name: Mn2+-doped CsPb(Br/Cl)3
Morphology: cubic ncs
Synthesis procedure: cursor together with 0.1 mL MnCl2 solution into 10 mL toluene under vigorous stirring but co-inject 0.5 mL CsPbBr3 precursor together with 0.1 mL MnCl2 solution into 10 mL toluene under vigorous stirring PbAc2 0.4 mmol, Cs2CO3 0.4 mmol, H... | [
"Bandgap: not reported ; PLQY total: not reported ; PLQY Exciton: not reported ; PLQY Dopant: not reported ; PL Peak Exciton: 450 nm ; PL Peak Dopant: 600 nm ; Exciton FWHM: not reported ; Dopant FWHM: not reported ; Lifetime Exciton_avg: not reported ; Lifetime Dopant_avg: not reported"
] |
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