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values | r1_response stringlengths 346 4.41k ⌀ | r1_reasoning_content stringlengths 1.79k 67.6k ⌀ | extract_solution stringclasses 560
values | url stringclasses 55
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values | success bool 1
class | page_count int64 6 500 ⌀ | page_number int64 1 499 ⌀ | question_choices_solutions stringclasses 532
values | extracted_question stringclasses 607
values | extracted_answer_choices sequencelengths 1 16 ⌀ | matched_solution stringclasses 498
values | qa_validation_outputs bool 1
class | classifier_reasoning stringlengths 120 909 ⌀ | is_organic_chemistry bool 1
class | ms_id int64 0 3.95k | qwq_thinking_trajectory stringlengths 947 93.6k | qwq_attempt stringlengths 179 9.44k | qwq_response sequencelengths 12 16 | _majority_responses sequencelengths 8 8 | verified_qwq_response stringlengths 2.67k 105k | conversations listlengths 2 2 |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
"Explain the fact that trans-4-tert-butylcyclohexyl tosylate undergoes bimolecular elimination with (...TRUNCATED) | organic-chemistry-questions | "Let's analyze the problem step-by-step:\n\n---\n\n### The compound:\n**trans-4-tert-butylcyclohexyl(...TRUNCATED) | 1,060 | 4,851 | Organic Chemistry | "\n\nThe observed reactivity of trans-4-tert-butylcyclohexyl tosylate can be explained by considerin(...TRUNCATED) | "Okay, let's see. The question is about why trans-4-tert-butylcyclohexyl tosylate undergoes bimolecu(...TRUNCATED) | "This is a case of merged substitution–elimination reaction. During E2 elimination, the stereoelec(...TRUNCATED) | null | null | null | null | null | null | null | null | null | null | "The question pertains specifically to the mechanism of a reaction involving an organic compound (tr(...TRUNCATED) | true | 66 | "<think>\n\nOkay, let's try to tackle this question. The user is asking why trans-4-tert-butylcycloh(...TRUNCATED) | "The fact that trans-4-tert-butylcyclohexyl tosylate undergoes bimolecular elimination (E\\(_2\\)) w(...TRUNCATED) | ["<think>\n\nOkay, let's try to tackle this question. The user is asking why trans-4-tert-butylcyclo(...TRUNCATED) | ["<think>\n\nOkay, so I need to explain why trans-4-tert-butylcyclohexyl tosylate undergoes bimolecu(...TRUNCATED) | "<think>\n\nOkay, so I need to explain why trans-4-tert-butylcyclohexyl tosylate undergoes bimolecul(...TRUNCATED) | [{"from":"human","value":"Explain the fact that trans-4-tert-butylcyclohexyl tosylate undergoes bimo(...TRUNCATED) |
"The average O.P. of human blood is 7.7 atm at 40°C. Calculate, assuming molarity and molality be s(...TRUNCATED) | organic-chemistry-questions | "Given Data:\n- Average osmotic pressure (O.P.) of human blood, \\(\\pi = 7.7 \\text{ atm}\\)\n- Tem(...TRUNCATED) | 54,986 | 1,301 | Physical Chemistry | "\n\nGiven the average osmotic pressure (O.P.) of human blood is 7.7 atm at 40°C, we need to calcul(...TRUNCATED) | "Okay, so I need to solve this problem about the osmotic pressure of human blood and find out the co(...TRUNCATED) | null | null | null | null | null | null | null | null | null | null | null | "The question involves calculations related to the properties of a solution (human blood) and requir(...TRUNCATED) | true | 3,436 | "<think>\nOkay, let's tackle this problem step by step. The question is about calculating the molari(...TRUNCATED) | "(a) To calculate the molarity (M) of blood using the osmotic pressure formula: \n\\[\n\\pi = MRT \(...TRUNCATED) | ["<think>\nOkay, let's tackle this problem step by step. The question is about calculating the molar(...TRUNCATED) | ["<think>\nOkay, so I have this problem here about calculating the concentration of blood in molarit(...TRUNCATED) | "<think>\nOkay, so I have this problem here about calculating the concentration of blood and its fre(...TRUNCATED) | [{"from":"human","value":"The average O.P. of human blood is 7.7 atm at 40°C. Calculate, assuming m(...TRUNCATED) |
"I had a mug of hot coffee cool too rapidly for my liking the other day, which made me wonder what w(...TRUNCATED) | stackexchange-physics | "Interesting question! Let's systematically compare the **per-unit-area heat loss rate** (including (...TRUNCATED) | 31,982 | 8,346 | null | null | null | null | null | null | null | null | null | null | null | null | null | null | null | null | 1,998 | "<think>\nOkay, the user wants to know which part of an open-top ceramic mug (top, side walls, or ba(...TRUNCATED) | "The open top of the ceramic mug is the **greatest contributor to heat loss per unit area**, driven (...TRUNCATED) | ["<think>\nOkay, the user wants to know which part of an open-top ceramic mug (top, side walls, or b(...TRUNCATED) | ["<think>\nOkay, so I need to figure out whether the main heat loss from a coffee mug happens throug(...TRUNCATED) | "<think>\n\nOkay, so I need to figure out which part of the coffee mug—top, sides, or bottom—con(...TRUNCATED) | [{"from":"human","value":"I had a mug of hot coffee cool too rapidly for my liking the other day, wh(...TRUNCATED) |
"The four 2s electrons provide the non-bonded lone pairs located one on each N atom. Therefore, in t(...TRUNCATED) | organic-chemistry-questions | "In the nitrogen molecule (N₂), the four 2s electrons (two from each nitrogen atom's 2s orbital) o(...TRUNCATED) | 5,310 | 1,646 | null | null | null | null | "https://blogmedia.testbook.com/kmat-kerala/wp-content/uploads/2023/06/organic-chemistry-by-jonathan(...TRUNCATED) | organic-chemistry-by-jonathan-clayden-nick-greeves-stuart-warren-z-lib.org_-847123c1.pdf | true | 500 | 121 | "QUESTION: \"What is the total number of electrons contributed by nitrogen atoms in a nitrogen molec(...TRUNCATED) | "\"What are the two types of pairs that the four 2s electrons represent in the context of nitrogen m(...TRUNCATED) | ["\"bonded pairs and lone pairs\"","\"lone pairs and inner pairs\"","\"bonded pairs and unbonded pai(...TRUNCATED) | "lone pairs and inner pairs" | true | "The question specifically discusses electron configurations involving nitrogen atoms, which is a to(...TRUNCATED) | true | 331 | "<think>\n\nAlright, the user is asking about the roles of the four 2s electrons in nitrogen molecul(...TRUNCATED) | "The four 2s electrons in the nitrogen molecule (N₂) contribute to **bonding pairs** and **non-bon(...TRUNCATED) | ["<think>\n\nAlright, the user is asking about the roles of the four 2s electrons in nitrogen molecu(...TRUNCATED) | ["<think>\n\nOkay, let's tackle this question. The user is asking about the four 2s electrons in nit(...TRUNCATED) | "<think>\nOkay, let me think about this question. The user is asking about the four 2s electrons in (...TRUNCATED) | [{"from":"human","value":"The four 2s electrons provide the non-bonded lone pairs located one on eac(...TRUNCATED) |
"This is inspired by a recent post on why a free electron can't absorb a photon, though my question (...TRUNCATED) | stackexchange-physics | "This is a great and deep question! Let's break it down carefully because it touches on the foundati(...TRUNCATED) | 30,476 | 9,120 | null | null | null | null | null | null | null | null | null | null | null | null | null | null | null | null | 1,904 | "<think>\nOkay, so the user is asking about why certain particles can't exist, especially in the con(...TRUNCATED) | "The question of why certain particles cannot exist, such as a free electron absorbing a photon, hin(...TRUNCATED) | ["<think>\nOkay, so the user is asking about why certain particles can't exist, especially in the co(...TRUNCATED) | ["<think>\nOkay, so I've been thinking a lot about this question. Let me try to break it down step b(...TRUNCATED) | "<think>\nOkay, so I've been thinking a lot about this question. Let me try to break it down step by(...TRUNCATED) | [{"from":"human","value":"This is inspired by a recent post on why a free electron can't absorb a ph(...TRUNCATED) |
"Although both stereoisomers yield 4-tert-butylcyclohexene as the only alkene, they do so at quite d(...TRUNCATED) | organic-chemistry-questions | "The dehydrobromination of **trans-4-tert-butylcyclohexyl bromide** results in the formation of **4-(...TRUNCATED) | 52,774 | 1,698 | null | null | null | null | "https://yustikaforict.wordpress.com/wp-content/uploads/2012/12/organic_chemistry_4th_ed_-_francis_a(...TRUNCATED) | organic_chemistry_4th_ed_-_francis_a-_carey-291.pdf | true | 500 | 225 | "QUESTION: What is the rate of reaction for the cis isomer of 4-tert-butylcyclohexyl bromide compare(...TRUNCATED) | What is the result of dehydrobromination of trans-4-tert-butylcyclohexyl bromide? | [
"\"Rapid\"",
"\"Slow\"",
"\"No reaction\"",
"\"Only trans-alkene formed\""
] | Slow | true | "The question pertains to the behavior of stereoisomers in organic reactions, specifically the proce(...TRUNCATED) | true | 3,298 | "<think>\nOkay, so the user is asking about the result of dehydrobromination of trans-4-tert-butylcy(...TRUNCATED) | "The dehydrobromination of **trans-4-tert-butylcyclohexyl bromide** still yields **4-tert-butylcyclo(...TRUNCATED) | ["<think>\nOkay, so the user is asking about the result of dehydrobromination of trans-4-tert-butylc(...TRUNCATED) | ["<think>\nOkay, so the question is about the dehydrobromination of trans-4-tert-butylcyclohexyl bro(...TRUNCATED) | "<think>\n\nOkay, so the user is asking about the result of dehydrobromination of trans-4-tert-butyl(...TRUNCATED) | [{"from":"human","value":"Although both stereoisomers yield 4-tert-butylcyclohexene as the only alke(...TRUNCATED) |
"If a nitro-compound dissolved in concentrated sulphuric acid is subjected to electrolytic reduction(...TRUNCATED) | organic-chemistry-questions | "**Question:** \nWhen a nitro-compound is dissolved in concentrated sulphuric acid and subjected to(...TRUNCATED) | 34,852 | 2,647 | null | null | null | null | https://library.sciencemadness.org/library/books/the_practical_methods_of_organic_chemistry.pdf | the_practical_methods_of_organic_chemistry.pdf | true | 372 | 209 | "QUESTION: What is the yield of the crystals separating out after cooling the two water solutions an(...TRUNCATED) | "What does electrolytic reduction of aromatic nitro-compounds achieve when a nitro-compound is disso(...TRUNCATED) | ["\"The nitro-group is reduced to the amido-group, and a hydroxyl group enters the para position\"",(...TRUNCATED) | The nitro-group is reduced to the amido-group, and a hydroxyl group enters the para position | true | "The question pertains to organic chemistry as it discusses the chemical transformation of a nitro c(...TRUNCATED) | true | 2,178 | "<think>\n\nOkay, so I need to explain what the electrolytic reduction of aromatic nitro-compounds i(...TRUNCATED) | "The electrolytic reduction of nitroaromatic compounds in concentrated sulfuric acid achieves two pr(...TRUNCATED) | ["<think>\n\nOkay, so I need to explain what the electrolytic reduction of aromatic nitro-compounds (...TRUNCATED) | ["<think>\n\nOkay, so I need to understand what happens when a nitro compound dissolved in concentra(...TRUNCATED) | "<think>\n\nOkay, let's tackle this question about the electrolytic reduction of aromatic nitro-comp(...TRUNCATED) | [{"from":"human","value":"If a nitro-compound dissolved in concentrated sulphuric acid is subjected (...TRUNCATED) |
"A bottle of oleum is labelled as 109%. Which of the following statement is/are correct for this ole(...TRUNCATED) | organic-chemistry-questions | "Given: Oleum is labelled as 109%. We need to analyze the given statements (a), (b), (c), and (d).\n(...TRUNCATED) | 44,399 | 6,234 | Physical Chemistry | "\n\nTo determine the correct statements about the 109% oleum sample, we analyze each option as foll(...TRUNCATED) | "Okay, so I need to figure out which statements about the 109% oleum sample are correct. Let's start(...TRUNCATED) | null | null | null | null | null | null | null | null | null | null | null | "The question pertains to the chemistry of oleum, which is a solution containing sulfur trioxide, a (...TRUNCATED) | true | 2,774 | "<think>\nOkay, let me try to work through this problem step by step. The question is about an oleum(...TRUNCATED) | "The correct answers are (a) and (d). Here's the detailed reasoning:\n\n### Analysis of Each Option:(...TRUNCATED) | ["<think>\nOkay, let me try to work through this problem step by step. The question is about an oleu(...TRUNCATED) | ["<think>\nOkay, let's see. The question is about oleum labeled as 109%. I need to figure out which (...TRUNCATED) | "<think>\nOkay, so there's this problem about an oleum sample labeled as 109%, and I need to figure (...TRUNCATED) | [{"from":"human","value":"A bottle of oleum is labelled as 109%. Which of the following statement is(...TRUNCATED) |
"Would appreciate any help -- I appears to be getting my right-hand and left-hand mixed.\nLet's the (...TRUNCATED) | stackexchange-physics | "Let's carefully analyze your problem step-by-step, clarify the vector directions, and resolve the c(...TRUNCATED) | 14,788 | 8,698 | null | null | null | null | null | null | null | null | null | null | null | null | null | null | null | null | 924 | "<think>\nOkay, let's see. The user is trying to figure out the direction of the friction force on a(...TRUNCATED) | "To resolve your confusion about the direction of friction force and rotation vectors, let's systema(...TRUNCATED) | ["<think>\nOkay, let's see. The user is trying to figure out the direction of the friction force on (...TRUNCATED) | ["<think>\nOkay, let's tackle this problem step by step. The user is confused about the rotation dir(...TRUNCATED) | "<think>\nOkay, so I need to figure out the direction of the angular velocity and how it affects the(...TRUNCATED) | [{"from":"human","value":"Would appreciate any help -- I appears to be getting my right-hand and lef(...TRUNCATED) |
"A number of complex metal hydrides such as lithium aluminium hydride (LiAlH4, abbreviated to LAH) a(...TRUNCATED) | organic-chemistry-questions | "The key point to consider regarding the transfer of hydride from complex metal hydrides like lithiu(...TRUNCATED) | 25,527 | 1,282 | null | null | null | null | "https://scholarsbasics.wordpress.com/wp-content/uploads/2018/03/essentials-of-organic-chemistry-dew(...TRUNCATED) | essentials-of-organic-chemistry-dewick-paul-m-srg.pdf | true | 500 | 221 | "QUESTION: What is the expected outcome of the reaction of a Grignard reagent with the epoxide elect(...TRUNCATED) | What must be considered regarding the transfer of hydride from complex metal hydrides? | [
"NO CHOICES AVAILABLE"
] | "The complex metal hydride never actually produces hydride as a nucleophile, but the aluminium hydri(...TRUNCATED) | true | "The question is focused on complex metal hydrides and their behavior in organic reactions, specific(...TRUNCATED) | true | 1,595 | "<think>\nOkay, let's tackle this question. The user is asking what must be considered regarding the(...TRUNCATED) | "When considering the transfer of hydride from complex metal hydrides such as LiAlH₄ (LAH) or NaBH(...TRUNCATED) | ["<think>\nOkay, let's tackle this question. The user is asking what must be considered regarding th(...TRUNCATED) | ["<think>\n\nOkay, let's see. I need to answer what must be considered regarding the transfer of hyd(...TRUNCATED) | "<think>\nOkay, let's tackle this question. The user wants to know what must be considered regarding(...TRUNCATED) | [{"from":"human","value":"A number of complex metal hydrides such as lithium aluminium hydride (LiAl(...TRUNCATED) |
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