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Complete the following reactions and select the major products by considering the steric hindrance, and the stability of the products.
2-ethyl-2,6-dimethylcyclohexan-1-one + ethyl acrylate (t-BuOK) ---> A
1-nitropropane + (KOH, (E)-but-2-enenitrile, H2O) ---> B | {
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A benzene ring has a carboxylic acid a carbaldehyde and a cyano group all meta to one another. Ortho to the carboxylic acid are a hydroxyl and a dimethyl amino and para to the carboxylic acid is a methoxy group. The methoxy and the alcohol are also both ortho to the nitrile. What is the correct IUPAC name for this mole... | {
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A spin-half particle is in a linear superposition 0.5|\uparrow\rangle+sqrt(3)/2|\downarrow\rangle of its spin-up and spin-down states. If |\uparrow\rangle and |\downarrow\rangle are the eigenstates of \sigma{z} , then what is the expectation value up to one decimal place, of the operator 10\sigma{z}+5\sigma_{x} ? Here,... | {
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"β |Οβ© = 0.5|ββ© + β3/2|ββ©\n\nβ β¨Ο_zβ© = |0.5|Β² - |β3/2|Β² = 0.25 - 0.75 = -0.5\n\nβ Ο_x|ββ© = |ββ©, Ο_x|ββ© = |ββ©\n\nβ β¨Ο_xβ© = (0.5β¨β| + β3/2β¨β|)Ο_x(0.5|ββ© + β3/2|ββ©)\n = 0.5β3/2β¨β|ββ© + 0.5β3/2β¨β|ββ© = 0.5β3/2 + 0.5β3/2 = β3/2 β 0.866\n\nβ β¨10Ο_z + 5Ο_xβ© = 10(-0.5) + 5(0.866) = -5 + 4.33 = -0.67 β -0.7\n\nANSWER: A"
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There has been an outbreak of an viral infectious disease in your city. You have been asked to design a molecular diagnostic kit for quick detection of this retrovirus. How would you go about designing this kit? | {
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"β A: ELISA β β (Ag-Ab) β β
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0.5
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Identify compound E in the following reaction scheme.
Compound A, when reacted with HCN, produces compound B.
Compound B, upon reduction with H2 in the presence of Pd, forms compound C.
Compound C, upon reaction with HNO2, forms compound D.
Compound D, upon elimination of an inert gas, forms compound E.
Hints:
a) Compo... | {
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"β A: 1750 cmβ»ΒΉ β C=O β \nβ A + HCN β B: C=O β CN β \nB + Hβ/Pd β C: CN β NHβ β \nC + HNOβ β D: NHβ β NββΊ β \nD β E + inert gas: NββΊ β Nββ β \n\nβ A + ylide β 1,2-dimethyl-4-(propan-2-ylidene)cyclopentane β Wittig β C=O β C=C β \nβ΄ A = cyclopentanone derivative β \n\nβ A: C=O β 1750 cmβ»ΒΉ β \nβ E: 1715 cmβ»ΒΉ ... | [
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A methanol solution of (R)-(+)-Limonene is stirred with Pd/C under a Hydrogen atmosphere. After 1 equivalent of hydrogen is consumed, product 1 is isolated as the major product.
1 is treated with 3-chloroperbenzoic acid, forming product 2.
Product 2 is treated with sodium methoxide, forming product 3.
Product 3 is t... | {
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"β (R)-(+)-Limonene β CββHββ β
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You come across an algorithm that gives the following output (written as input -> output):
AGG -> 115
TGCTGA -> 176
What value does ACAGTGACC give? | {
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ChIP-seq on a PFA-fixed sample with an antibody to the IKAROS transcription factor in human B cells followed by next-generation sequencing and standard quality control, alignment and peak-calling steps produced ChIP peaks that disappeared when PFA+DSG fixation was used. Where are we most likely to find such disappearin... | {
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Congratulations, you just landed your dream job at one of the top structural biology labs at Stanford University in California. Without further ado, the Principal Investigator explains that the priority of the moment is to produce in E. coli BL21 then purify as quickly as possible the Human P53 protein.
The amino acid... | {
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reaction of solid A with 8 equivalents of gas B forms bright red product C.
When C reacts with 2 equivalents of gas D, it produces the extremely hazardous product E.
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t1-wingdings-gpqa-kimi-k2-instruct
Wingdings GPQA eval of Kimi-K2-Instruct. pass@1: 0%, compliance: 47.5%
Dataset Info
- Rows: 10
- Columns: 14
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| question | Value('large_string') | No description provided |
| answer | Value('large_string') | No description provided |
| choices | {'label': List(Value('string')), 'text': List(Value('null'))} | No description provided |
| answer_key | Value('large_string') | No description provided |
| task_source | Value('large_string') | No description provided |
| id | Value('large_string') | No description provided |
| formatted_prompt | List({'content': Value('string'), 'role': Value('string')}) | No description provided |
| prompt_variant | Value('large_string') | No description provided |
| response | List(Value('string')) | No description provided |
| formatted_prompt__metadata | List({'endpoint_type': Value('string'), 'litellm_function': Value('string'), 'model': Value('string'), 'raw_prompt': List({'content': Value('string'), 'role': Value('string')}), 'raw_system_prompt': Value('null'), 'request_payload': Value('string')}) | No description provided |
| response__metadata | List({'cost': Value('float64'), 'finish_reason': Value('string'), 'input_tokens': Value('int64'), 'model': Value('string'), 'output_tokens': Value('int64'), 'raw_response': Value('string')}) | No description provided |
| eval_result | List(Value('bool')) | No description provided |
| eval_result__metadata | List({'choice_labels': List(Value('string')), 'confidence': Value('float64'), 'correct_answer': Value('string'), 'extracted_answer': Value('string'), 'extractor': Value('string'), 'full_span': Value('string'), 'line_index': Value('int64'), 'pattern_used': Value('string')}) | No description provided |
| wingdings_compliance | List(Value('float64')) | No description provided |
Generation Parameters
{
"script_name": "wingdings_compliance/academic_eval.py",
"model": "moonshotai/Kimi-K2-Instruct-0905",
"description": "Wingdings GPQA eval of Kimi-K2-Instruct. pass@1: 0%, compliance: 47.5%",
"hyperparameters": {},
"input_datasets": []
}
Usage
from datasets import load_dataset
dataset = load_dataset("reasoning-degeneration-dev/t1-wingdings-gpqa-kimi-k2-instruct", split="train")
print(f"Loaded {len(dataset)} rows")
This dataset is tracked in reasoning-degeneration-dev/PROJECT-MANIFEST
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