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Discovery of ferromagnetism with large magnetic anisotropy in ZrMnP and HfMnP: ZrMnP and HfMnP single crystals are grown by a self-flux growth technique and structural as well as temperature dependent magnetic and transport properties are studied. Both compounds have an orthorhombic crystal structure. ZrMnP and HfMnP...
cond-mat_mtrl-sci
Folding Energetics in Thin-Film Diaphragms: We perform experiments on thin-film diaphragms to show that the folding patterns of anisotropically compressed diaphragms are strikingly different from those of isotropically compressed ones. We then use a simple von Karman model to relate the overall features of these foldin...
cond-mat_mtrl-sci
Phase Stability in 3d-5d (NiPt and CuAu) and 3d-4d (NiPd and CuAg) Systems: We show the differences in the stability of 3d-5d (NiPt and CuAu) and 3d-4d (NiPd and CuAg) alloys arise mainly due to relativistic corrections. The magnetic properties of disordered NiPd and NiPt alloys also differ due to these corrections w...
cond-mat_mtrl-sci
Thermoelectric power factor of Bi-Sb-Te and Bi-Te-Se alloys and doping strategy: First-principles study: By performing first principles calculations combined with Boltzmann transport equations, we calculate the thermoelectric power factor (PF) of Bi-Sb-Te and Bi-Te-Se ternary alloys as a function of alloy composition...
cond-mat_mtrl-sci
Strain engineering of two-dimensional piezo-photocatalytic materials for hydrogen production: Low-dimensional transition metal dichalcogenides (TMDC) exhibit great photocatalytic performance and tunability. In this work, using first-principles simulations based on density functional theory (DFT), we demonstrate that ...
cond-mat_mtrl-sci
Room Temperature Magnetocaloric Effect in Ni-Mn-In: We have studied the effect of magnetic field on a non-stoichiometric Heusler alloy Ni$_{50}$Mn$_{35}$In$_{15}$ that undergoes a martensitic as well as a magnetic transition near room temperature. Temperature dependent magnetization measurements demonstrate the influen...
cond-mat_mtrl-sci
Strain-induced dynamic control over the population of quantum emitters in two-dimensional materials: The discovery of quantum emitters in two-dimensional materials has triggered a surge of research to assess their suitability for quantum photonics. While their microscopic origin is still the subject of intense studie...
cond-mat_mtrl-sci
Coercivity and random interfacial exchange coupling in CoPt/Co films: Hard-soft bilayers are analogous to prototype exchange-biased ferromagnetic -antiferromagnetic systems as the minor loop of the soft layer is biased by the hard and furthermore they offer bias layer tunability. In sputtered CoPt/Co hard-soft bilayers...
cond-mat_mtrl-sci
Thermodynamics of point defects and diffusion mechanisms in B2-ordered compounds: The point defect thermodynamics in a general family of binary compounds, including B2 compounds as a specific representative, are classified by way of two non-trivial energy parameters. The scheme is applied to published ab initio defec...
cond-mat_mtrl-sci
Tunable Optoelectronic Properties of Triply-Bonded Carbon Molecules with Linear and Graphyne Substructures: In this paper we present a detailed computational study of the electronic structure and optical properties of triply-bonded hydrocarbons with linear, and graphyne substructures, with the aim of identifying thei...
cond-mat_mtrl-sci
Nano-scale oxygen octahedral tilting in 0.90(Bi1/2Na1/2)TiO3-0.05(Bi1/2K1/2)TiO3-0.05BaTiO3 lead-free perovskite piezoelectric ceramics: The oxygen octahedral tilted domains in 0.90(Bi1/2Na1/2)TiO3-0.5(Bi1/2K1/2)TiO3-0.5BaTiO3 lead-free perovskite piezoelectric ceramic have been studied by transmission electron mic...
cond-mat_mtrl-sci
A Graphene-Carbon Nanotube Hybrid Material for Photovoltaic Applications: Large area graphene sheets grown by chemical vapor deposition can potentially be employed as a transparent electrode in photovoltaics if their sheet resistance can be significantly lowered, without any loss in transparency. Here, we report the fa...
cond-mat_mtrl-sci
Nonvolatile Electric-Field Control of Inversion Symmetry: In condensed-matter systems, competition between ground states at phase boundaries can lead to significant changes in material properties under external stimuli, particularly when these ground states have different crystal symmetries. A key scientific and techno...
cond-mat_mtrl-sci
Bulk-sensitive photoemission spectroscopy of A_2FeMoO_6 double perovskites (A=Sr, Ba): Electronic structures of Sr_2FeMoO_6 (SFMO) and Ba_2FeMoO_6 (BFMO) double perovskites have been investigated using the Fe 2p->3d resonant photoemission spectroscopy (PES) and the Cooper minimum in the Mo 4d photoionization cross se...
cond-mat_mtrl-sci
Thermal Conductivity and Phonon Transport in Suspended Few-Layer Hexagonal Boron Nitride: The thermal conductivity of suspended few-layer hexagonal boron nitride (h-BN) was measured using a micro-bridge device with built-in resistance thermometers. Based on the measured thermal resistance values of 11-12 atomic layer...
cond-mat_mtrl-sci
Comparison of exact-exchange calculations for solids in current-spin-density- and spin-density-functional theory: The relative merits of current-spin-density- and spin-density-functional theory are investigated for solids treated within the exact-exchange-only approximation. Spin-orbit splittings and orbital magnetic...
cond-mat_mtrl-sci
The roles of adhesion, internal heat generation and elevated temperatures in normally loaded, sliding rough surfaces: The thermal effects of plastic and frictional heat generation and elevated temperature were examined along with the role of adhesion in the context of galling wear, using a representative crystal plas...
cond-mat_mtrl-sci
Multiscale Kinetic Monte-Carlo for Simulating Epitaxial Growth: We present a fast Monte-Carlo algorithm for simulating epitaxial surface growth, based on the continuous-time Monte-Carlo algorithm of Bortz, Kalos and Lebowitz. When simulating realistic growth regimes, much computational time is consumed by the relativel...
cond-mat_mtrl-sci
Undercooling growth and magnetic characterization of ferromagnetic shape memory alloy Ni2FeGa single crystals: Ni2FeGa single crystals have been grown in undercooling conditions provided by a glass-purification method. It has been found that trace amounts of gamma phase embededin the single crystalline matrix prefere...
cond-mat_mtrl-sci
Effect of edge vacancies on localized states in semi-infinite zigzag graphene sheet: The effect of vacancies on the robustness of zero-energy edge electronic states in zigzag-type graphene layer is studied at different concentrations and distributions of defects. All calculations are performed by using the Green's fu...
cond-mat_mtrl-sci
Ba(Zn,Co)2As2: a II-II-V Diluted Ferromagnetic Semiconductor with N-type Carriers: Diluted ferromagnetic semiconductors (DMSs) that combine the properties of semiconductors with ferromagnetism have potential application in spin-sensitive electronics (spintronics) devices. The search for DMS materials exploded after t...
cond-mat_mtrl-sci
High-throughput search for triplet point defects with narrow emission lines in 2D materials: We employ a first-principles computational workflow to screen for optically accessible, high-spin point defects in wide band gap two-dimensional (2D) crystals. Starting from an initial set of 5388 point defects, comprising bo...
cond-mat_mtrl-sci
Ab initio vibrational free energies including anharmonicity for multicomponent alloys: A density-functional-theory based approach to efficiently compute numerically exact vibrational free energies - including anharmonicity - for chemically complex multicomponent alloys is developed. It is based on a combination of th...
cond-mat_mtrl-sci
Imaging Antiferromagnetic Domains in Nickel-oxide Thin Films by Magneto-optical Voigt Effect: Recent demonstrations of electrical detection and manipulation of antiferromagnets (AFMs) have opened new opportunities towards robust and ultrafast spintronics devices. However, it is difficult to establish the connection b...
cond-mat_mtrl-sci
The role of the catalytic particle temperature gradient for SWNT growth from small particles: The Vapour-Liquid-Solid (VLS) model, which often includes a temperature gradient (TG) across the catalytic metal particle, is often used to describe the nucleation and growth of carbon nanostructures. Although the TG may be ...
cond-mat_mtrl-sci
Giant optical anisotropy in cylindrical self-assembled InAs/GaAs quantum rings: Using a single-particle atomistic pseudopotential method followed by a many-particle configuration interaction method, we investigate the geometry, electronic structure and optical transitions of a self-assembled InAs/GaAs quantum ring (Q...
cond-mat_mtrl-sci
Quantum Phase Transitions in Ba(1-x)CaxFe12O19: The ground state of BaFe12O19 (BFO) is controversial as three different quantum states, namely quantum paraelectric, frustrated antiferroelectric and quantum electric dipole liquid (QEDL), have been proposed. We have investigated the quantum critical behavior of BFO as a ...
cond-mat_mtrl-sci
Toy nanoindentation model and incipient plasticity: A toy model of two dimensional nanoindentation in finite crystals is proposed. The crystal is described by periodized discrete elasticity whereas the indenter is a rigid strain field of triangular shape representing a hard knife-like indenter. Analysis of the model sh...
cond-mat_mtrl-sci
NMR in magnetic molecular rings and clusters (I): In the last years there has been a great interest in magnetic systems formed by a cluster of transition metal ions covalently bonded via superexchange bridges, embedded in a large organic molecule. Following the synthesis and the structural and magnetic characterization...
cond-mat_mtrl-sci
Morphology of supported polymer electrolyte ultra-thin films: a numerical study: Morphology of polymer electrolytes membranes (PEM), e.g., Nafion, inside PEM fuel cell catalyst layers has significant impact on the electrochemical activity and transport phenomena that determine cell performance. In those regions, Nafi...
cond-mat_mtrl-sci
Third order perturbed modified Heisenberg Hamiltonian of fcc structured ferromagnetic films with seventy spin layers: Magnetic properties of fcc structured ferromagnetic films with the number of spin layers up to seventy was described using third order perturbed Heisenberg Hamiltonian. The variation of magnetic easy ...
cond-mat_mtrl-sci
Local structural ordering determines the mechanical damage tolerance of amorphous grain boundary complexions: Amorphous grain boundary complexions act as toughening features within a microstructure because they can absorb dislocations more efficiently than traditional grain boundaries. This toughening effect should b...
cond-mat_mtrl-sci
Segregation-induced phase transformations in grain boundaries: Phase transformations in metallic grain boundaries (GBs) present significant fundamental interest in the context of thermodynamics of low-dimensional physical systems. We report on atomistic computer simulations of the Cu-Ag system that provide direct evide...
cond-mat_mtrl-sci
The growth of ZnO crystals from the melt: The peculiar properties of zinc oxide (ZnO) make this material interesting for very different applications like light emitting diodes, lasers, and piezoelectric transducers. Most of these applications are based on epitaxial ZnO layers grown on suitable substrates, preferably bu...
cond-mat_mtrl-sci
Complete mapping of magnetic anisotropy for prototype Ising van der Waals FePS$_3$: Several Ising-type magnetic van der Waals (vdW) materials exhibit stable magnetic ground states. Despite these clear experimental demonstrations, a complete theoretical and microscopic understanding of their magnetic anisotropy is sti...
cond-mat_mtrl-sci
Spin Angular Momentum Transfer and Plasmogalvanic Phenomena: We introduce the continuity equation for the electromagnetic spin angular momentum (SAM) in matter and discuss the torque associated with the SAM transfer in terms of effective spin forces acting in a material. In plasmonic metal, these spin forces result in ...
cond-mat_mtrl-sci
Anomalous Hall effect in a two-dimensional electron gas with spin-orbit interaction: We discuss the mechanism of anomalous Hall effect related to the contribution of electron states below the Fermi surface (induced by the Berry phase in momentum space). Our main calculations are made within a model of two-dimensional...
cond-mat_mtrl-sci
Local Structural Evidence for Strong Electronic Correlations in LiRh$_2$O$_4$ Spinel: The local structure of the spinel LiRh$_2$O$_4$ has been studied using atomic pair distribution function (PDF) analysis of powder x-ray diffraction data. This measurement is sensitive to the presence of short Rh-Rh bonds that form d...
cond-mat_mtrl-sci
Hybrid-functional and quasi-particle calculations of band structures of Mg2Si, Mg2Ge, and Mg2Sn: We perform hybrid functional and quasi-particle band structure calculations with spin-orbit interaction to investigate the band structures of Mg2Si, Mg2Ge, and Mg2Sn. For all Mg2X materials, where X = Si, Ge, and Sn, the ...
cond-mat_mtrl-sci
Scaling of alloy interfacial properties under compositional strain: Complex morphologies and microstructures that emerge during materials growth and solidification are often determined by both equilibrium and kinetic properties of the interface and their crystalline anisotropies. However limited knowledge is available ...
cond-mat_mtrl-sci
Computer simulations of defects in perovskite KNbO3 crystals: An ab initio LMTO approach and semi-empirical quantum chemical INDO method have been used for supercell calculations of basic point defects - F-type centers and hole polarons bound to cation vacancy - in partly covalent perovskite KNbO3. We predict the exist...
cond-mat_mtrl-sci
Disclinations in the geometric theory of defects: In the geometric theory of defects, media with a spin structure, for example, ferromagnet, is considered as a manifold with given Riemann--Cartan geometry. We consider the case with the Euclidean metric corresponding to the absence of elastic deformations but with nontr...
cond-mat_mtrl-sci
Nanostructured Immunosensors. Application to the detection of Progesterone: A novel nanostructured electrochemical immunsensor for the determination of progesterone is reported. The approach combines the properties of gold nanoparticles with the use of a graphite-Teflon composite electrode matrix, into which gold nan...
cond-mat_mtrl-sci
Fabrication of diamond diffraction gratings for experiments with intense hard x-rays: The demands on optical components to tolerate high radiation dose and manipulate hard x-ray beams that can fit the experiment requirements, are constantly increasing due to the advancements in the available x-ray sources. Here we ha...
cond-mat_mtrl-sci
Room temperature Epitaxial Stabilization of a Tetragonal Phase in ARuO3 (A=Ca,Sr) Thin Films: We demonstrate that SrRuO3 and CaRuO3 thin films undergo a room temperature structural phase transition driven by the substrate imposed epitaxial biaxial strain. As tensile strain increases, ARuO3 (A=Ca, Sr) films transform ...
cond-mat_mtrl-sci
Graphene oxyhydride catalysts in view of spin radical chemistry: The article discusses carbocatalysis provided with amorphous carbons. The discussion is conducted from the standpoint of the spin chemistry of graphene molecules, in the framework of which the amorphous carbocatalysts are a conglomerate of graphene-oxynit...
cond-mat_mtrl-sci
Observation of Magnetopiezoelectric Effect in Antiferromagnetic Metal EuMnBi2: We have experimentally studied a magnetopiezoelectric effect predicted recently for magnetic metals with low crystal symmetries. In EuMnBi2 with antiferromagnetic Mn moments at 77 K, dynamic displacements emerge along the $a$ direction upo...
cond-mat_mtrl-sci
Structural defects induced by Fe-ion implantation in TiO2: X-ray photoelectron spectroscopy (XPS) and resonant x-ray emission spectroscopy (RXES) measurements of pellet and thin film forms of TiO$_2$ with implanted Fe ions are presented and discussed. The findings indicate that Fe-implantation in a TiO$_2$ pellet sampl...
cond-mat_mtrl-sci
Dynamic friction force in a carbon peapod oscillator: We investigate a new generation of fullerene nano-oscillators: a single-walled carbon nanotube with one buckyball inside with an operating frequency in the tens-of-gigahertz range. A quantitative characterization of energy dissipation channels in the peapod pair has...
cond-mat_mtrl-sci
The structure of amorphous two-dimensional materials: Elemental monolayer amorphous carbon versus binary monolayer amorphous boron nitride: The structure of amorphous materials has been debated since the 1930's as a binary question: amorphous materials are either Zachariasen continuous random networks (Z-CRNs) or Z-C...
cond-mat_mtrl-sci
The decoupled DFT-$\frac{1}{2}$ method for defect excitation energies: The DFT-$\frac{1}{2}$ method is a band gap correction with GW precision at a DFT computational cost. The method was also extended to correct the gap between defect levels, allowing for the calculation of optical transitions. However, this method fai...
cond-mat_mtrl-sci
Direct-written polymer field-effect transistors operating at 20 MHz: Printed polymer electronics has held for long the promise of revolutionizing technology by delivering distributed, flexible, lightweight and cost-effective applications for wearables, healthcare, diagnostic, automation and portable devices. While impr...
cond-mat_mtrl-sci
Magnetic spin excitations in Mn doped GaAs : A model study: We provide a quantitative theoretical model study of the dynamical magnetic properties of optimally annealed Ga$_{1-x}$Mn$_x$As. This model has already been shown to reproduce accurately the Curie temperatures for Ga$_{1-x}$Mn$_x$As. Here we show that the calc...
cond-mat_mtrl-sci
Superintermolecular orbitals in the C$_{60}$/pentacene complex: We report a group of unusually big molecular orbitals in the C60/pentacene complex. Our first-principles density functional calculation shows that these orbitals are very delocalized and cover both C60 and pentacene, which we call superintermolecular orbit...
cond-mat_mtrl-sci
Elastic and magnetic effects on the infrared phonon spectra of MnF2: We measured the temperature dependent infrared reflectivity spectra of MnF2 between 4 K and room temperature. We show that the phonon spectrum undergoes a strong renormalization at TN. The ab-initio calculation we performed on this compound accurately...
cond-mat_mtrl-sci
An Efficient DFT Solver for Nanoscale Simulations and Beyond: We present the One-orbital Ensemble Self-Consistent Field (OE-SCF) method, an {alternative} orbital-free DFT solver that extends the applicability of DFT to system sizes beyond the nanoscale while retaining the accuracy required to be predictive. OE-SCF is a...
cond-mat_mtrl-sci
Topological surface states of Bi2Se3 with the coexistence of Se vacancies: Although topological surface states are known to be robust against non-magnetic surface perturbations, their band dispersions and spatial distributions are still sensitive to the surface defects. Take Bi2Se3 as an example, we demonstrated that...
cond-mat_mtrl-sci
Langevin spin dynamics based on ab initio calculations: numerical schemes and applications: A method is proposed to study the finite-temperature behaviour of small magnetic clusters based on solving the stochastic Landau-Lifshitz-Gilbert equations, where the effective magnetic field is calculated directly during the ...
cond-mat_mtrl-sci
Electric-field control of magnetic domain wall motion and local magnetization reversal: Spintronic devices currently rely on magnetic switching or controlled motion of domain walls by an external magnetic field or spin-polarized current. Achieving the same degree of magnetic controllability using an electric field ha...
cond-mat_mtrl-sci
The Robustness of Cluster Expansion: Assessing the Roles of Relaxation and Numerical Error: Cluster expansion (CE) is effective in modeling the stability of metallic alloys, but sometimes cluster expansions fail. Failures are often attributed to atomic relaxation in the DFT-calculated data, but there is no metric for...
cond-mat_mtrl-sci
2D-MoS2 with Narrowest Excitonic Linewidths Grown by Flow-Less Direct Heating of Bulk Powders: Developing techniques for high-quality synthesis of mono and few-layered 2D materials with lowered complexity and cost continues to remain an important goal, both for accelerating fundamental research and for applications d...
cond-mat_mtrl-sci
Topological semimetal phases in a family of monolayer X3YZ6 (X=Nb,Ta, Y=Si,Ge,Sn, Z=S,Se,Te) with abundant nodal lines and nodes: The electronic and topological properties of single-layer X3YZ6 (X=Nb,Ta, Y=Si,Ge,Sn, Z=S,Se,Te) materials have been studied with the aid of first principles calculations. This kind of mat...
cond-mat_mtrl-sci
Electronic structure of above-room-temperature van der Waals ferromagnet Fe$_3$GaTe$_2$: Fe$_3$GaTe$_2$, a recently discovered van der Waals ferromagnet, demonstrates intrinsic ferromagnetism above room temperature, necessitating a comprehensive investigation of the microscopic origins of its high Curie temperature (...
cond-mat_mtrl-sci
Harmonic vibrational excitations in graded elastic networks: transition from phonons to gradons: We have identified a new type of transition from extended to localized vibrational states in one-dimensional graded elastic chains of coupled harmonic oscillators, in which the vibrating masses or nearest-coupling force c...
cond-mat_mtrl-sci
Switching ferromagnetic spins by an ultrafast laser pulse: Emergence of giant optical spin-orbit torque: Faster magnetic recording technology is indispensable to massive data storage and big data sciences. {All-optical spin switching offers a possible solution}, but at present it is limited to a handful of expensive ...
cond-mat_mtrl-sci
Graphene Nanoribbon based T Junctions: Graphene nanoribbons (GNRs) based T junctions were designed and studied in this paper. These junctions were made up of shoulders (zigzag GNRs) joined with stems (armchair GNRs). We demonstrated the intrinsic transport properties and effective boron (or nitrogen) doping of the junc...
cond-mat_mtrl-sci
Anisotropic Gilbert damping in perovskite La$_{0.7}$Sr$_{0.3}$MnO$_{3}$ thin film: The viscous Gilbert damping parameter governing magnetization dynamics is of primary importance for various spintronics applications. Although, the damping constant is believed to be anisotropic by theories. It is commonly treated as a...
cond-mat_mtrl-sci
Structure and dynamics of the fullerene polymer Li4 C60 studied with neutron scattering: The two-dimensional polymer structure and lattice dynamics of the superionic conductor Li4 C60 are investigated by neutron diffraction and spectroscopy. The peculiar bonding architecture of this compound is definitely confirmed t...
cond-mat_mtrl-sci
Direct dry transfer of chemical vapor deposition graphene to polymeric substrates: We demonstrate the direct dry transfer of large area Chemical Vapor Deposition graphene to several polymers (low density polyethylene, high density polyethylene, polystyrene, polylactide acid and poly(vinylidenefluoride-co-trifluoroeth...
cond-mat_mtrl-sci
Tantalum STJ for Photon Counting Detectors: Superconducting Tunnel Junctions (STJ's) are currently being developed as photon detectors for a wide range of applications. Interest comes from their ability to cumulate photon counting with chromaticity (i.e. energy resolution) from the near infrared (2 $\mu$m) to the X-ray...
cond-mat_mtrl-sci
Discovery of Weyl nodal lines in a single-layer ferromagnet: Two-dimensional (2D) materials have attracted great attention and spurred rapid development in both fundamental research and device applications. The search for exotic physical properties, such as magnetic and topological order, in 2D materials could enable t...
cond-mat_mtrl-sci
Optimizing Floquet engineering for non-equilibrium steady states with gradient-based methods: Non-equilibrium steady states are created when a periodically driven quantum system is also incoherently interacting with an environment -- as it is the case in most realistic situations. The notion of Floquet engineering re...
cond-mat_mtrl-sci
Tuning carrier density and phase transitions in oxide semiconductors using focused ion beams: We demonstrate spatial modification of the optical properties of thin-film metal oxides, zinc oxide and vanadium dioxide as representatives, using a commercial focused ion beam (FIB) system. Using a Ga+ FIB and thermal annea...
cond-mat_mtrl-sci
High-order harmonic generation in solid $\rm \bf C_{60}$: High harmonic generation (HHG) has unleashed the power of strong laser physics in solids. Here we investigate HHG from a large system, solid C$_{60}$, with 240 valence electrons engaging harmonic generation at each crystal momentum, the first of this kind. We em...
cond-mat_mtrl-sci
Controlling the Electrical Properties of Undoped and Ta-doped TiO2 Polycrystalline Films via Ultra-Fast Annealing Treatments: We present a study on the crystallization process of undoped and Ta doped TiO2 amorphous thin films. In particular, the effect of ultra-fast annealing treatments in environments characterized ...
cond-mat_mtrl-sci
Oxidation tuning of ferroic transitions in Gd$_2$C monolayer: Tuning of ferroic phases provides great opportunities for material functionalities, especially in two-dimensional materials. Here, a $4f$ rare-earth carbide Gd$_2$C monolayer is predicted to be ferromagnetic metal with large magnetization, inherited from its...
cond-mat_mtrl-sci
Nonthermal effects in solids after swift heavy ion impact: This contribution is a brief introduction to nonthermal effects related to modifications of the interatomic potential upon ultrafast excitation of the electronic system of solids, primarily focusing on the swift heavy ion track problem. We clarify the differenc...
cond-mat_mtrl-sci
Ab initio study of proton-exchanged LiNbO3(I): Structural, thermodynamic, dielectric, and optical properties: Using first principles calculations, we study the ground-state structure of bulk proton-exchanged lithium niobate, which is also called hydrogen niobate and is widely used in waveguides. Thermodynamics helps ...
cond-mat_mtrl-sci
Spin-orbit Hamiltonian for organic crystals from first principles electronic structure and Wannier functions: Spin-orbit coupling in organic crystals is responsible for many spin-relaxation phenomena, going from spin diffusion to intersystem crossing. With the goal of constructing effective spin-orbit Hamiltonians to...
cond-mat_mtrl-sci
Moulding flexural waves in elastic plates lying atop a Faqir's bed of nails: Platonic crystals (PCs) are the elastic plate analogue of the photonic crystals widely used in optics, and are thin structured elastic plates along which flexural waves cannot propagate within certain stop band frequency intervals. The pract...
cond-mat_mtrl-sci
Prediction of grain boundary structure and energy by machine learning: Grain boundaries dramatically affect the properties of polycrystalline materials because of differences in atomic configuration. To fully understand the relationship between grain boundaries and materials properties, systematic studies of the grain ...
cond-mat_mtrl-sci
Cooperative gas adsorption without a phase transition in metal-organic frameworks: Cooperative adsorption of gases by porous frameworks permits more efficient uptake and removal than does the more usual non-cooperative (Langmuir-type) adsorption. Cooperativity, signaled by a step-like isotherm, is usually attributed ...
cond-mat_mtrl-sci
Characterization and control of ZnGeN2 cation lattice ordering: ZnGeN2 and other heterovalent ternary semiconductors have important potential applications in optoelectronics, but ordering of the cation sublattice, which can affect the band gap, lattice parameters, and phonons, is not yet well understood. Here the effec...
cond-mat_mtrl-sci
Superheating and solid-liquid phase coexistence in nanoparticles with non-melting surfaces: We present a phenomenological model of melting in nanoparticles with facets that are only partially wet by their liquid phase. We show that in this model, as the solid nanoparticle seeks to avoid coexistence with the liquid, t...
cond-mat_mtrl-sci
Giant optical birefringence of semiconductor nanowire metamaterials: Semiconductor nanowires exhibit large polarization anisotropy for the absorption and emission of light, making them ideal building blocks for novel photonic metamaterials. Here, we demonstrate that a high density of aligned nanowires exhibits giant op...
cond-mat_mtrl-sci
Imaging the stick-slip peeling of an adhesive tape under a constant load: Using a high speed camera, we study the peeling dynamics of an adhesive tape under a constant load with a special focus on the so-called stick-slip regime of the peeling. It is the first time that the very fast motion of the peeling point is imag...
cond-mat_mtrl-sci
Glancing-Incidence Focussed Ion Beam Milling: A Coherent X-ray Diffraction Study of 3D Nano-scale Lattice Strains and Crystal Defects: This study presents a detailed examination of the lattice distortions introduced by glancing incidence Focussed Ion Beam (FIB) milling. Using non-destructive multi-reflection Bragg co...
cond-mat_mtrl-sci
Hybrid exchange-correlation functional for accurate prediction of the electronic and structural properties of ferroelectric oxides: Using a linear combination of atomic orbitals approach, we report a systematic comparison of various Density Functional Theory (DFT) and hybrid exchange-correlation functionals for the p...
cond-mat_mtrl-sci
Modelling the Nonlinear Response of Fibre-reinforced Bending Fluidic Actuators: Soft actuators are receiving increasing attention from the engineering community, not only in research but even for industrial applications. Among soft actuators, fibre-reinforced Bending Fluidic Actuators (BFAs) became very popular thank...
cond-mat_mtrl-sci
Spatially Heterogeneous Dynamics in a Metallic Glass Forming Liquid Imaged by Electron Correlation Microscopy: Supercooled liquids exhibit spatial heterogeneity in the dynamics of their fluctuating atomic arrangements. The length and time scales of the heterogeneous dynamics are central to the glass transition and in...
cond-mat_mtrl-sci
Gigahertz Dielectric Polarization of Single-atom Niobium Substituted in Graphitic layers: We have synthesized two Nb@C composites with an order of magnitude difference in the density of single-atom niobium substituted into graphitic layers. The concentration and sites of single-atom Nb are identified using aberration...
cond-mat_mtrl-sci
Failure time in the fiber-bundle model with thermal noise and disorder: The average time for the onset of macroscopic fractures is analytically and numerically investigated in the fiber-bundle model with quenched disorder and thermal noise under a constant load. We find an implicit exact expression for the failure time...
cond-mat_mtrl-sci
Electron-hole versus exciton delocalization in conjugated polymers: the role of topology: There is currently a great need for solid state lasers that emit in the infrared. Whether or not conjugated polymers that emit in the IR can be synthesized is an interesting theoretical challenge. We show that the requirement fo...
cond-mat_mtrl-sci
Structural Transitions at Ionic Liquids Interfaces: Recent advances in experimental and computational techniques have allowed for an accurate description of the adsorption of ionic liquids on metallic electrodes. It is now well established that they adopt a multi-layered structure, and that the composition of the layer...
cond-mat_mtrl-sci
First principles calculations of the interface properties of amorphous-Al2O3/MoS2 under non-strain and biaxial strain conditions: Al2O3 is a potential dielectric material for metal-oxide-semiconductor (MOS) devices. Al2O3 films deposited on semiconductors usually exhibit amorphous due to lattice mismatch. Compared to...
cond-mat_mtrl-sci
Magneto-transport and magneto-optical properties of ferromagnetic (III,Mn)V semicondcutors: a review: Rapid developments in material research of metallic ferromagnetic (III,Mn)V semiconductors over the past few years have brought a much better understanding of these complex materials. We review here some of the main ...
cond-mat_mtrl-sci
Theory of structural response to macroscopic electric fields in ferroelectric systems: We have developed and implemented a formalism for computing the structural response of a periodic insulating system to a homogeneous static electric field within density-functional perturbation theory (DFPT). We consider the thermo...
cond-mat_mtrl-sci
Anomalies in non-stoichiometric uranium dioxide induced by pseudo-phase transition of point defects: A uniform distribution of point defects in an otherwise perfect crystallographic structure usually describes a unique pseudo phase of that state of a non-stoichiometric material. With off-stoichiometric uranium dioxid...
cond-mat_mtrl-sci
Theory of self-diffusion in GaAs: Ab initio molecular dynamics simulations are employed to investigate the dominant migration mechanism of the gallium vacancy in gaas as well as to assess its free energy of formation and the rate constant of gallium self-diffusion. our analysis suggests that the vacancy migrates by sec...
cond-mat_mtrl-sci
Superconductivity in intercalated buckled two-dimensional materials: KGe$_2$: Germanene has emerged as a novel two-dimensional material with various interesting properties and applications. Here we report the possibility of superconductivity in a stable potassium intercalated germanene compound, KGe$_2$, with a trans...
cond-mat_mtrl-sci