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} | ['gnd:4144934-4', 'gnd:4116614-0', 'gnd:4032524-6', 'gnd:4057803-3'] | ['Korruption', 'Strafverfolgung', 'Steuerrecht', 'Bestechung'] | ['jur'] | ['Technische Informationsbibliothek (TIB)'] | [['(isbn13)9783845292175', '(doi)10.5771/9783845292175', '(firstid)KXP:1663460914', '(ppn)1663460914']] | ['Nomos'] | [['Besteuerung', '(classificationName=bk, id=106413287)86.73 - Steuerrecht', '(classificationName=rvk)PP 3675', 'taxation procedure', '(classificationName=ssg)INTRECHT', 'Bestechung', '(classificationName=ddc)345.430233', 'criminal tax law', 'Korruption', 'prohibition', 'Strafrecht', 'investigations', 'Besteuerungsverfahren', '(classificationName=rvk)PP 4320', 'combat', '(classificationName=rvk)PH 3700', 'Mitteilungspflicht gem. § 4 Abs. 5 S. 1 Nr. 10 S. 2 EStG', 'Ermittlungen', 'taxation', 'Verfahren', 'Steuerrecht', '§ 4 Abs. 5 S. 1 Nr. 10 EStG', '(classificationName=linseach:mapping)jur', 'Steuerstrafrecht', 'white-collar crime', 'procedure', 'Wirtschaftskriminalität', 'bribery', 'Steuerhinterziehung', 'Bekämpfung', '(classificationName=bk, id=181572001)86.41 - Kriminologie', 'Kooperation Strafverfolgungs- und Finanzbehörden', 'Verbot', 'tax evasion', '(classificationName=ddc-dbn)340', 'criminal law', 'tax law', 'corruption', 'steuerliches Abzugsverbot', '(classificationName=rvk)PP 5645', 'Vorteilszuwendung']] | ['Korruptionsbekämpfung durch das Steuerrecht und Kooperation von Strafverfolgungs- und Finanzbehörden : rechtliche Möglichkeiten und "gelebte" Wirklichkeit, zugleich ein Beitrag zum Anwendungsbereich des § 4 Abs. 5 S. 1 Nr. 10 EStG'] | [['This thesis investigates how tax law can be used to fight corruption. The taxation procedure is particularly well-suited as a starting point for further criminal proceedings in cases involving corruption in the context of economic crime. However, the collaboration between law enforcement and tax authorities in this field is not without its difficulties, as it involves different areas of the law (tax law, criminal law, criminal tax law) and different types of proceedings (taxation proceedings, criminal investigations), whose interactions result in numerous problems. This work also finds that § 4 sec. 5 sentence 1 No. 10 of the EStG (Germany’s Income Tax Act) is insufficiently considered in practice. After analysing the norm and its various levels of impact (fiscal, general preventive and criminal tax law levels), the author concludes that the current rules have weaknesses that provoke avoidance behaviour among the tax authorities.', 'Die Arbeit untersucht die Einsatzmöglichkeiten des Steuerrechts zur Korruptionsbekämpfung. Gerade bei der Korruption im Kontext der Wirtschaftskriminalität bietet sich das Besteuerungsverfahren als Ausgangspunkt für weitere strafrechtliche Ermittlungen an. Das Zusammenwirken von Strafverfolgungs- und Finanzbehörden auf diesem Gebiet ist nicht unproblematisch, da hier unterschiedlichste Rechtsgebiete (Steuerrecht, Strafrecht, Steuerstrafrecht) und unterschiedliche Verfahrensarten (Besteuerungsverfahren, strafrechtliches Ermittlungsverfahren) zusammentreffen, deren Interdependenzen zu zahlreichen Problemen führen. § 4 Abs. 5 S. 1 Nr. 10 EStG erfährt in der Praxis nur unzureichende Beachtung. Nach einer Analyse der Norm mit ihren unterschiedlichen Wirkungsebenen (fiskalische, generalpräventive und steuerstrafrechtliche Ebene) gelangt der Autor zum Schluss, dass die bisherigen Regelungen Schwachstellen aufweisen und somit ein Vermeidungsverhalten auf Seiten der Finanzbehörden provozieren.']] | ['2019'] | ['http://id.loc.gov/vocabulary/iso639-1/de'] | ['commercial licence'] | [[{'@id': 'gnd:4144934-4'}, {'@id': 'gnd:4116614-0'}, {'@id': 'gnd:4032524-6'}, {'@id': 'gnd:4057803-3'}]] | ['gnd:1185410228', 'gnd:36154-9', 'gnd:4032524-6', 'gnd:4057803-3', 'gnd:4116614-0', 'gnd:4144934-4', 'https://www.tib.eu/de/suchen/id/TIBKAT%3A1663460914'] | ['Ermert, Alexander', 'Justus-Liebig-Universität Gießen', 'Korruption', 'Strafverfolgung', 'Steuerrecht', 'Bestechung'] | 12 |
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} | ['gnd:4015110-4', 'gnd:4228491-0', 'gnd:4052258-1', 'gnd:4226351-7'] | ['Erbrecht', 'Schenkung', 'Unentgeltliche Verfügung', 'Erblasser'] | ['jur'] | ['Technische Informationsbibliothek (TIB)'] | [['(firstid)KXP:1664603948', '(ppn)1664603948', '(doi)10.5771/9783845299211', '(isbn13)9783845299211']] | ['Nomos'] | [['Spende', 'Unentgeltlichkeit', 'Pflichtteilsergänzung', 'unentgeltliche Verfügung', 'Pflichtteil', 'renunciation of inheritance', '(classificationName=rvk)PD 8108', '(classificationName=ddc-dbn)340', '(classificationName=ssg)INTRECHT', 'law of succession', '(classificationName=bk, id=106413414)86.23 - Erbrecht', 'compulsory portion', 'augmented compulsory portion', 'Erbrecht', '(classificationName=linseach:mapping)jur', 'Verfügung', 'Stiftungsgeschäft unter Lebenden', 'Erbverzicht', 'Zuwendung unter Ehegatten', '(classificationName=ddc)346.43052', 'Schenkung', 'Zustiftung']] | ['Die Schenkung und die unentgeltliche Verfügung im Erbrecht'] | [['By examining donations and free disposition in the context of inheritance law, this work is dedicated to a central theme of inheritance law, which is of particular importance in judicial, notarial and legal practice. Using an interpretation of the terms in the law of obligations, it discusses the understanding of donations and free disposition in the standards of inheritance law (§§ 2287 et seq., 2325 et seq. of the German Civil Code and §§ 2113 paragraph 2, 2205 sentence 3 of the German Civil Code) in detail. By looking at selected constellations, it identifies the similarities and differences between the terms in the context of the respective inheritance law standards. Finally, and for the first time in such clarity, the work investigates the reasons for the differences between §§ 2287 et seq., 2325 et seq. of the German Civil Code on the one hand and §§ 2113 paragraph 2, 2205 sentence 3 of the German Civil Code on the other. Furthermore, it reveals the trends in jurisprudence and presents legal policy proposals.', 'Mit der Untersuchung von Schenkung und unentgeltlicher Verfügung im erbrechtlichen Kontext widmet sich die Arbeit einem zentralen Thema des Erbrechts, dem in der gerichtlichen, notariellen und anwaltlichen Praxis besondere Bedeutung zukommt. Ausgehend von der Auslegung der Begriffe im Schuldrecht wird das Verständnis von Schenkung und unentgeltlicher Verfügung in den nachlassschützenden Normen des Erbrechts (§§ 2287 f., 2325 ff. BGB sowie § §§ 2113 Absatz 2, 2205 Satz 3 BGB) im Einzelnen erörtert. Anhand einer Betrachtung ausgewählter Sachverhalte werden die Gemeinsamkeiten und Unterschiede der erbrechtlichen Unentgeltlichkeitsbegriffe herausgearbeitet. Schließlich eruiert die Arbeit erstmals in dieser Klarheit den Grund für die Unterschiede zwischen den §§ 2287 f., 2325 ff. BGB einerseits und den §§ 2113 Absatz 2, 2205 Satz 3 BGB andererseits in Bezug auf Tatbestand und Rechtsfolge, zeigt außerdem die Tendenzen der Rechtsprechung auf und unterbreitet rechtspolitische Vorschläge.']] | ['2019'] | ['http://id.loc.gov/vocabulary/iso639-1/de'] | ['commercial licence'] | [[{'@id': 'gnd:4015110-4'}, {'@id': 'gnd:4228491-0'}, {'@id': 'gnd:4052258-1'}, {'@id': 'gnd:4226351-7'}]] | ['gnd:1185714227', 'gnd:4011882-4', 'gnd:4015110-4', 'gnd:4052258-1', 'gnd:4226351-7', 'gnd:4228491-0', 'gnd:7409-3', 'https://www.tib.eu/de/suchen/id/TIBKAT%3A1664603948'] | ['Höfling, Lisa-Marie', 'Deutschland', 'Erbrecht', 'Schenkung', 'Unentgeltliche Verfügung', 'Erblasser', 'Ruhr-Universität Bochum'] | 12 |
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} | ['gnd:4113549-0', 'gnd:4070300-9', 'gnd:4279394-4'] | ['Deponie', 'Festbettreaktor', 'Sickerwasserbehandlung'] | ['cet'] | [['gnd:1138205567', 'gnd:1061626717']] | [['(ppn)1665091304', '(doi)10.15480/882.2247', '(isbn13)9783942768238', '(firstid)KXP:1665091304']] | [''] | [['(classificationName=linseach:mapping)bau', '(classificationName=ddc)620: Ingenieurwissenschaften', '(classificationName=ddc)500: Naturwissenschaften', '(classificationName=bk, id=106418831)58.53 - Abfallwirtschaft', '(classificationName=ddc)570: Biowissenschaften, Biologie', '(classificationName=ddc-dbn)624', '(classificationName=linseach:mapping)cet', '(classificationName=bk, id=106421069)56.35 - Siedlungswasserwirtschaft, industrielle Wasserwirtschaft']] | ['High-rate nitrification of membrane-filtrated saline landfill leachate using fixed-bed biofilm reactors'] | [['Landfill leachates containing high ammonia concentrations cannot be treated satisfactorily using reverse osmosis (RO) systems alone. In this work, leachate nitrification using aerated packed bed reactors was investigated to solve the problem of insufficient ammonia rejection faced by the multi-stage high pressure membrane system (comprising of RO and nanofiltration (NF) operations) treating the leachate at the Ihlenberg landfill site. Nitrification efficiencies greater than 97% were achieved with the NF permeate of RO retentate of raw leachate (having 16 g/L Cl-, 45 mS/cm) at loading rates of about 1100 g NH4+-N/(m3∙d) at 25°C. Based on the findings, a half-technical scale plant was conceptualised and commissioned at the Ihlenberg landfill site.', 'Alleine durch Umkehrosmose (UO) kann hochammoniumhaltigen Deponiesickerwässer nicht ausreichend behandelt werden. Die mehrstufige Hochdruckmembrananlage (inklusiv UO und Nanofiltration (NF) Verfahren) für die Sickerwasseraufbereitung in Deponie Ihlenberg ergibt sich ein unzureichender Ammoniumrückhalt. In dieser Arbeit wurde die Nitrifikation in belüfteten Festbettreaktoren untersucht, um dieses Problem zu lösen. Mit dem NF-Permeat des UO-Retentats des Rohsickerwassers (mit 16 g/L Cl-, 45 mS/cm) wurden Nitrifikationseffizienzen über 97% bei Volumenbelastungsraten von ca. 1100 g NH4+-N/(m3∙d) bei 25°C erreicht. Basierend der Ergebnisse wurde eine Anlage im halb-technischen Maßstab am Deponie Ihlenberg konzeptioniert und in Betrieb genommen.']] | ['2018'] | ['http://id.loc.gov/vocabulary/iso639-1/en'] | ['open access'] | [[{'@id': 'gnd:4113549-0'}, {'@id': 'gnd:4070300-9'}, {'@id': 'gnd:4279394-4'}]] | ['gnd:1061626717', 'gnd:1112763473', 'gnd:1132203899', 'gnd:1138205567', 'gnd:1143062434', 'gnd:4070300-9', 'gnd:4113549-0', 'gnd:4279394-4', 'https://www.tib.eu/de/suchen/id/TIBKAT%3A1665091304'] | ['Otterpohl, Ralf', 'Technische Universität Hamburg', 'Technische Universität Hamburg, Institut für Abwasserwirtschaft und Gewässerschutz', 'Ernst, Mathias', 'Ramaswami, Sreenivasan', 'Deponie', 'Festbettreaktor', 'Sickerwasserbehandlung'] | 4 |
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} | ['gnd:4034864-7', 'gnd:4114333-4'] | ['Lebensführung', 'Kunst'] | ['phi'] | ['Technische Informationsbibliothek (TIB)'] | [['(doi)10.5771/9783956505324', '(ppn)1665962917', '(isbn13)9783956505324', '(firstid)KXP:1665962917']] | ['Ergon Verlag'] | [['(classificationName=rvk)CC 6900', 'Kunst', 'Ästhetik', 'Erfahrung', '(classificationName=bk, id=10641433X)20.06 - Kunstphilosophie, Kunsttheorie', '(classificationName=linseach:mapping)phi', '(classificationName=bk, id=106403044)08.41 - Ästhetik', 'art', 'Selbst', 'Kunst und Leben', '(classificationName=ddc-dbn)100', 'Konstellation', 'Walter Benjamin', 'Verbindlichkeit', 'Theodor W. Adorno', 'Autonomie', 'aesthetics', 'Martin Heidegger', 'art and life', '(classificationName=ddc)170.44']] | ['Kunst und Leben : eine kritische Auseinandersetzung mit Adorno, Benjamin und Heidegger'] | [['The book aims to disclose the relevance of art for life. Through a critical examination of the art theories of Heidegger, Adorno and Benjamin, who embed their consideration of art in their own systems of thought, the book opens up the systematical connection between art and life from an immanent perspective both to life and to art. Starting from the individual man and from the individual artwork, man is defined as the conscious process of self-realization that freely shapes his own life in a world of normative practices and the artwork is defined as an autonomous experience-form. Consequently, the analysis shows that the aesthetic experience, that makes the artwork as experience-form, is distinguished by an immanent normativity that suspends all other normativities. This causes a ‘sublation’ of the validity of the normative structures of the world and confronted the viewer with the task of self-realization.', 'Das Buch verfolgt das Ziel, die Relevanz der Kunst für das Leben zu erschließen. In kritischer Auseinandersetzung mit Adorno, Benjamin und Heidegger, die ihre Kunstbetrachtung in ihren Denksystemen einbetten, erschließt das Buch den systematischen Zusammenhang zwischen Kunst und Leben aus einer Perspektive, die sowohl dem Leben als auch der Kunst immanent ist. Vom einzelnen Menschen und vom einzelnen Kunstwerk ausgehend wird der Mensch als der bewusste Selbstwerdungsprozess, der sein je eigenes Leben in einer Welt von verbindlichen Praktiken frei gestaltet, und das Kunstwerk als autonome Erfahrungsgestalt definiert. Daraufhin zeigt die Analyse, dass die ästhetische Erfahrung, die das Kunstwerk als Erfahrungsgestalt ausmacht, durch eine immanente Verbindlichkeit ausgezeichnet ist, die all anderen Verbindlichkeiten suspendiert. Dies bewirkt eine Aufhebung der Gültigkeit der verbindlichen Weltstrukturen und stellt der Betrachter immer wieder auf Neues vor der Aufgabe der Selbstwerdung.']] | ['2019'] | ['http://id.loc.gov/vocabulary/iso639-1/de'] | ['commercial licence'] | [[{'@id': 'gnd:4034864-7'}, {'@id': 'gnd:4114333-4'}]] | ['gnd:118500775', 'gnd:118509039', 'gnd:118547798', 'gnd:1185584951', 'gnd:4034864-7', 'gnd:4114333-4', 'https://www.tib.eu/de/suchen/id/TIBKAT%3A1665962917'] | ['Adorno, Theodor W. 1903-1969', 'Benjamin, Walter 1892-1940', 'Heidegger, Martin 1889-1976', 'Caruso, Giovanna', 'Lebensführung', 'Kunst'] | 21 |
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} | ['gnd:4016899-2', 'gnd:4070102-5'] | ['Fertigung', 'Controlling'] | ['oek'] | ['Technische Informationsbibliothek (TIB)'] | [['(doi)10.5771/9783845298399', '(isbn13)9783845298399', '(firstid)HEB:449659267', '(ppn)1667200275']] | ['Nomos'] | [['controlling', 'Industrie 4.0', 'logistics', 'Maschinenbau', 'Flexible Preissysteme', 'Arbeit', 'Produktion', 'production controlling', '(classificationName=ddc-dbn)650', 'Echtzeitdaten', '(classificationName=linseach:mapping)tec', '(classificationName=ddc)658.4013', 'production', 'Controlling', 'planning', 'production management', '(classificationName=rvk)QP 361', '(classificationName=bk, id=106403729)85.35 - Fertigung', 'Produktionsmanagement', '(classificationName=loksys-fbw)oek 7890', 'Produktionscontrolling', '(classificationName=ddc)658.514', 'Digitalisierung', '(classificationName=linseach:mapping)oek', 'corporate management', 'Logistik', 'Unternehmenssteuerung', '(classificationName=rvk)QP 505', 'Planung']] | ['Produktionscontrolling im Kontext von Industrie 4.0 : Auswirkung von Echtzeitdaten auf die Effektivität und Effizienz der Planungs-, Steuerungs- und Kontrollunterstützung des Produktionsmanagements'] | [['The last few years have played host to a discussion concerning the potential of digitisation in industrial production under the term ‘Industry 4.0’. The starting point of Industry 4.0 is the digitally networked factory. In this scenario, all production-relevant processes are recorded in real time. From a controlling perspective, the availability of real-time data provides new opportunities for data processing. As Industry 4.0 essentially addresses production and production processes, this especially applies to production controlling. In this context, the question arises of how real-time data affect the effectiveness and efficiency of production controlling. This study tackles this question, developing a method with which not only the effectiveness and efficiency of production controlling in general but also the effect of real-time data on the effectiveness and efficiency of production controlling in particular can be studied.', 'In den letzten Jahren wird unter dem Begriff „Industrie 4.0“ diskutiert, welche Potenziale die Digitalisierung für die industrielle Produktion bereithält. Den Ausgangspunkt von Industrie 4.0 bildet dabei zunächst die digital vernetzte Fabrik. In diesem Szenario werden produktionsrelevante Vorgänge in Echtzeit erfasst. Aus Sicht des Controllings ergeben sich durch die Verfügbarkeit von Echtzeitdaten neue Möglichkeiten für die Datenverarbeitung. Da Industrie 4.0 im Wesentlichen die Produktion adressiert, gilt dies insbesondere für das Produktionscontrolling. In diesem Zusammenhang stellt sich die Frage, wie sich Echtzeitdaten auf die Effektivität und Effizienz des Produktionscontrollings auswirken. Diese Frage wird in der Arbeit aufgegriffen und eine Methode entwickelt, mit der die Effektivität und Effizienz des Produktionscontrollings im Allgemeinen und die Auswirkung von Echtzeitdaten auf die Effektivität und Effizienz des Produktionscontrollings im Speziellen untersucht werden können.']] | ['2019'] | ['http://id.loc.gov/vocabulary/iso639-1/de'] | ['commercial licence'] | [[{'@id': 'gnd:4016899-2'}, {'@id': 'gnd:4070102-5'}]] | ['gnd:1130408167', 'gnd:36186-0', 'gnd:4016899-2', 'gnd:4070102-5', 'https://www.tib.eu/de/suchen/id/TIBKAT%3A1667200275'] | ['Sejdić, Goran', 'Universität Stuttgart', 'Fertigung', 'Controlling'] | 19 |
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} | ['gnd:4033151-9', 'gnd:4072885-7', 'gnd:4204241-0', 'gnd:4063213-1', 'gnd:4152415-9'] | ['Kriegsverbrechen', 'Versöhnung', 'Internationale Politik', 'Entschuldigung', 'Völkerrechtliches Verbrechen'] | ['sow'] | ['Technische Informationsbibliothek (TIB)'] | [['(firstid)KXP:1667801406', '(ppn)1667801406', '(isbn13)9783845261614', '(doi)10.5771/9783845261614']] | ['Nomos'] | [['(classificationName=ddc-dbn)300', 'Geschichte', '(classificationName=linseach:mapping)sow', 'Versöhnung', 'collective apologies', 'human rights', 'apologies', 'international relations', 'rite', '(classificationName=ddc)327', '(classificationName=rvk)AP 14150', 'Ritus', 'Internationale Beziehungen', '(classificationName=bk, id=10642047X)89.90 - Außenpolitik, Internationale Politik', 'apology research', 'Ritual', 'discourse', 'ritual', 'apology performance', 'Entschuldigungen', 'reconciliation', 'rituals', 'Festival', 'Diskurs']] | ['Dramas of reconciliation : a performance approach to the analysis of political apologies in international relations'] | [['Political apologies have been described as modern political rites. However, the scholarship has failed so far to take the ritualistic elements in apologies seriously. This book addresses this lacuna. Contrary to linguistic approaches that locate the transformative power of apologies in correct wording, this book grounds the force of apologies in ritual performances. Drawing on ritual theory the book reveals how apology performances bear characteristics of rites of transitions. This book lays down the ritual features that enwrap apologies, demonstrates how apologizing agents activate sacred symbols in apology ceremonies, and how rites as a distinct mode of social communication may create extra-ordinary moments of transition. Based on a discourse analytical methodology, the study analyses several apology performances for historic crimes and discloses the potentials and the limits of rituals of apologies.', 'Politische Entschuldigungen gelten als modernes politisches Bußritual. Bis heute hat sich die Forschung jedoch nicht dem Ritualhaften in den Darbietungen politischer Entschuldigungshandlungen ernsthaft gewidmet. Dieses Buch schafft Abhilfe. Im Gegensatz zu sprach-analytischen Ansätzen, die die positive Wirkung von Entschuldigungen in ihrer sprachlichen Gestalt verorten, fundiert dieses Buch die Wirkmächtigkeit von politischen Entschuldigungen im Ritus selbst. Bezugnehmend auf die Ritualforschung demonstriert dieses Buch, welche übergangsrituellen Bezüge sich in politischen Entschuldigungen zeigen, wie repräsentative Akteure sakrale Symbole in Entschuldigungszeremonien aktivieren und wie durch Riten außergewöhnliche Momente der Versöhnung geschaffen werden. Basierend auf einer diskursanalytischen Methodik werden erfolgreiche und misslingende Entschuldigungshandlungen einer dichten empirischen Analyse unterzogen und die Potenziale und Grenzen ritualhafter Darbietungen präsentiert.']] | ['2019'] | ['http://id.loc.gov/vocabulary/iso639-1/en'] | ['commercial licence'] | [[{'@id': 'gnd:4033151-9'}, {'@id': 'gnd:4072885-7'}, {'@id': 'gnd:4204241-0'}, {'@id': 'gnd:4063213-1'}, {'@id': 'gnd:4152415-9'}]] | ['gnd:1042976996', 'gnd:4033151-9', 'gnd:4063213-1', 'gnd:4072885-7', 'gnd:4152415-9', 'gnd:4204241-0', 'https://www.tib.eu/de/suchen/id/TIBKAT%3A1667801406'] | ['Horelt, Michel-André', 'Kriegsverbrechen', 'Versöhnung', 'Internationale Politik', 'Entschuldigung', 'Völkerrechtliches Verbrechen'] | 25 |
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"Durch die Entdeckung von Kohlenstoffnanostrukturen (1D, 2D Strukturen) im vergangenen Jahrhundert begann in den darauffolgenden Jahren ein Wettlauf zur Verwendung dieses neuen Werkstofftyps mit herausragenden physikalischen Eigenschaften. Aufgrund der geometrischen Beschr\u00e4nkung von 1D und 2D Kohlenstoffstrukturen wurden um die Jahrtausendwende verschiedenste erstellungstechniken entwickelt, um 3D Kohlenstoffstrukturen zu synthetisieren, welche auch als Kohlenstoffsch\u00e4ume bezeichnet werden. Diese bieten auf Basis deren Morphologie gegen\u00fcber den bisherigen Strukturen entscheidende Vorteile, womit sich potentiell neue Anwendungsgebiete im Bereich der Energiespeichersysteme und Katalysatoren ergeben. Dabei beeinflussen insbesondere die Wachstumsmechanismen der Kohlenstoffstrukturen die sp\u00e4teren Eigenschaften. Im Zuge dessen entstehen in der Ausbildung der Kohlenstoffanordnung im hexagonalen Gitter immer wieder Defekte, welche die elektrischen und mechanischen Eigenschaften der Struktur verringern. Diese Defekte k\u00f6nnen durch Ausheilungsprozesse wie eine Hochtemperaturbehandlung verringert werden. Neben Defekten, wurde auch gezeigt, dass die Anzahl der Kohlenstofflagen die Eigenschaften ma\u00dfgeblich beeinflussen. Diese Arbeit befasst sich mit der Analyse des Wachstumsmechanismus der 3D Kohlenstoffstruktur Aerographit. Dieser Kohlenstoffschaum weist eine tetrapodischen Morphologie auf und zeichnet sich durch dessen hohe mechanische und elektrische Eigenschaften bei einer geringen Dichte von bis ~ 2 mg/cm\u00b3 aus. Im Zuge dessen wird vor allem der Einfluss des Wachstumsmechanismus auf die Eigenschaften beziehungsweise die kontrollierte Ver\u00e4nderung der Eigenschaften wie zum Beispiel der elektrischen Leitf\u00e4higkeit untersucht. Dabei kann durch eine gezielte Prozessf\u00fchrung, w\u00e4hrend der Synthese IV von Aerographit in der chemischen Gasphasenabscheidung, die Wandst\u00e4rke der Tetrapoden gezielt variiert werden. Wobei durch eine nachgeschaltete Temperaturbehandlung von Aerographit, in Abh\u00e4ngigkeit der Temperatur und deren Haltezeit, kommt es zu einer schrittweisen Steigerung der elektrischen Leitf\u00e4higkeit. Weiterhin wird in dieser Arbeit eine Variation der Morphologie und des herstellungsprozesses f\u00fcr 3D Kohlenstoffsch\u00e4ume untersucht. Dabei liegt das Hauptaugenmerk auf eine anwendungsbezogene Morphologie und eines vergleichsweise vereinfachten Herstellungsprozesses der neu entwickelten Kohlenstoffstruktur. Der dabei entwickelte Kohlenstoffschaum weist eine globulare Morphologie auf und wird auf Basis eines keramischen Grundk\u00f6rpers hergestellt. Durch dieses Herstellungsverfahren lassen sich unter Verwendung von thermodynamischen Berechnungen katalytisch aktive Materialien dem keramischen Grundk\u00f6rper zuf\u00fcgen, welche gezielt nach dem CVD Prozess in dem gebildeten Kohlenstoffschaum verbleiben. Dabei kann diese Methode zu einem beliebig vielf\u00e4ltigen Anwendungsspektrum im Bereich der Katalysatoren f\u00fchren."
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Due to the geometric restriction of 1D and 2D carbon structures, a variety of manufacturing techniques have been developed around of the millennium to synthesise 3D carbon structures, which are also referred to as carbon aerogels or carbon foams. Based on their morphology, these structures offer decisive advantages over the existing structures and thus potentially new fields of application arise in the field of energy storage systems and catalysts. The growth mechanism of carbon structures has a property-defining influence on their properties. During their growth, carbon atoms arrange in ideal hexagonal lattices, which can also lead to defects that adversely affect the properties. These defects can be reduced by annealing processes such as a high-temperature treatment. Besides to defects, it was also shown that the number of carbon layers significantly affect the properties. This work concerned with the analysis of the growth mechanism of the 3D carbon structure Aerographite. This carbon foam has a tetrapodal morphology and is distinguished by its high mechanical and electrical properties at a density down to ~2 mg/cm3. Here, the influence of the growth mechanism via ex-situ studies and the tailoring of the properties such as electrical conductivity is investigated. The wall thickness of the tetrapods can be specifically varied by means of a targeted process control during the synthesis of Aerographite in the CVD process. A stepwise increase in the electrical conductivity occurs because of a subsequent temperature treatment of Aerographite, as a function of the temperature and its VI holding time. Additionally, the healing of Aerographite by a thermal treatment and the influence of the graphitisation on the properties of Aerographite is in focus in this work. Furthermore, this study aims a variation of the morphology and the manufacturing process for 3D carbon foams and the identification of possible applications. The focus here is on an application-related morphology and a comparatively simplified manufacturing process of the carbon structure. The developed carbon foam has a hierarchical globular morphology and is produced based on a porous ceramic template. Based on thermodynamic calculations, a wide range of catalytically active materials can be added to the green body, which are remains after the CVD process. Finally, a carbon foam with incorporated catalysts can be used for several applications.', 'Durch die Entdeckung von Kohlenstoffnanostrukturen (1D, 2D Strukturen) im vergangenen Jahrhundert begann in den darauffolgenden Jahren ein Wettlauf zur Verwendung dieses neuen Werkstofftyps mit herausragenden physikalischen Eigenschaften. Aufgrund der geometrischen Beschränkung von 1D und 2D Kohlenstoffstrukturen wurden um die Jahrtausendwende verschiedenste erstellungstechniken entwickelt, um 3D Kohlenstoffstrukturen zu synthetisieren, welche auch als Kohlenstoffschäume bezeichnet werden. Diese bieten auf Basis deren Morphologie gegenüber den bisherigen Strukturen entscheidende Vorteile, womit sich potentiell neue Anwendungsgebiete im Bereich der Energiespeichersysteme und Katalysatoren ergeben. Dabei beeinflussen insbesondere die Wachstumsmechanismen der Kohlenstoffstrukturen die späteren Eigenschaften. Im Zuge dessen entstehen in der Ausbildung der Kohlenstoffanordnung im hexagonalen Gitter immer wieder Defekte, welche die elektrischen und mechanischen Eigenschaften der Struktur verringern. Diese Defekte können durch Ausheilungsprozesse wie eine Hochtemperaturbehandlung verringert werden. Neben Defekten, wurde auch gezeigt, dass die Anzahl der Kohlenstofflagen die Eigenschaften maßgeblich beeinflussen. Diese Arbeit befasst sich mit der Analyse des Wachstumsmechanismus der 3D Kohlenstoffstruktur Aerographit. Dieser Kohlenstoffschaum weist eine tetrapodischen Morphologie auf und zeichnet sich durch dessen hohe mechanische und elektrische Eigenschaften bei einer geringen Dichte von bis ~ 2 mg/cm³ aus. Im Zuge dessen wird vor allem der Einfluss des Wachstumsmechanismus auf die Eigenschaften beziehungsweise die kontrollierte Veränderung der Eigenschaften wie zum Beispiel der elektrischen Leitfähigkeit untersucht. Dabei kann durch eine gezielte Prozessführung, während der Synthese IV von Aerographit in der chemischen Gasphasenabscheidung, die Wandstärke der Tetrapoden gezielt variiert werden. Wobei durch eine nachgeschaltete Temperaturbehandlung von Aerographit, in Abhängigkeit der Temperatur und deren Haltezeit, kommt es zu einer schrittweisen Steigerung der elektrischen Leitfähigkeit. Weiterhin wird in dieser Arbeit eine Variation der Morphologie und des herstellungsprozesses für 3D Kohlenstoffschäume untersucht. Dabei liegt das Hauptaugenmerk auf eine anwendungsbezogene Morphologie und eines vergleichsweise vereinfachten Herstellungsprozesses der neu entwickelten Kohlenstoffstruktur. Der dabei entwickelte Kohlenstoffschaum weist eine globulare Morphologie auf und wird auf Basis eines keramischen Grundkörpers hergestellt. Durch dieses Herstellungsverfahren lassen sich unter Verwendung von thermodynamischen Berechnungen katalytisch aktive Materialien dem keramischen Grundkörper zufügen, welche gezielt nach dem CVD Prozess in dem gebildeten Kohlenstoffschaum verbleiben. Dabei kann diese Methode zu einem beliebig vielfältigen Anwendungsspektrum im Bereich der Katalysatoren führen.']] | ['2019'] | ['http://id.loc.gov/vocabulary/iso639-1/en'] | ['open access'] | [[{'@id': 'gnd:4064180-6'}, {'@id': 'gnd:4062670-2'}, {'@id': 'gnd:4204530-7'}, {'@id': 'gnd:4009846-1'}, {'@id': 'gnd:4720368-7'}, {'@id': 'gnd:1148987150'}, {'@id': 'gnd:4064115-6'}]] | ['gnd:1112763473', 'gnd:113167281X', 'gnd:1138222542', 'gnd:1148987150', 'gnd:1168842336', 'gnd:120262258', 'gnd:122770129', 'gnd:4009846-1', 'gnd:4062670-2', 'gnd:4064115-6', 'gnd:4064180-6', 'gnd:4204530-7', 'gnd:4720368-7', 'https://www.tib.eu/de/suchen/id/TIBKAT%3A1668927896'] | ['Technische Universität Hamburg', 'Huber, Patrick', 'Technische Universität Hamburg, Institut für Kunststoffe und Verbundwerkstoffe', 'Aerographit', 'Marx, Janik', 'Fiedler, Bodo', 'Adelung, Rainer', 'CVD-Verfahren', 'Verbundwerkstoff', 'Wachstum', 'Wärmebehandlung', 'Nanostruktur', 'Materialcharakterisierung'] | 7 |
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