pino-source-code / artifacts /three_diagnostics_v8 /diagnostic1_substantivity_integrity_finished_v8.json
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| "poucher_tier": "mid", | |
| "tier_step_distance": 1 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "wild", | |
| "boundary_crossed": "top_mid_14_15", | |
| "cas": "8007-75-8", | |
| "coefficient_tier_recomputed": "top", | |
| "distance_to_boundary_coeff_units": 8.0, | |
| "measured_coefficient": 6, | |
| "measured_tier": "top", | |
| "name": "Bergamot", | |
| "poucher_tier": "mid", | |
| "tier_step_distance": 1 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "wild", | |
| "boundary_crossed": null, | |
| "cas": "8008-45-5", | |
| "coefficient_tier_recomputed": "top", | |
| "distance_to_boundary_coeff_units": null, | |
| "measured_coefficient": 14, | |
| "measured_tier": "top", | |
| "name": "Nutmeg", | |
| "poucher_tier": "base", | |
| "tier_step_distance": 2 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "wild", | |
| "boundary_crossed": "top_mid_14_15", | |
| "cas": "8008-56-8", | |
| "coefficient_tier_recomputed": "top", | |
| "distance_to_boundary_coeff_units": 9.0, | |
| "measured_coefficient": 5, | |
| "measured_tier": "top", | |
| "name": "Lemon", | |
| "poucher_tier": "mid", | |
| "tier_step_distance": 1 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "wild", | |
| "boundary_crossed": "mid_base_60_61", | |
| "cas": "8014-09-3", | |
| "coefficient_tier_recomputed": "base", | |
| "distance_to_boundary_coeff_units": 39.0, | |
| "measured_coefficient": 100, | |
| "measured_tier": "base", | |
| "name": "Patchouli", | |
| "poucher_tier": "mid", | |
| "tier_step_distance": 1 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "wild", | |
| "boundary_crossed": "top_mid_14_15", | |
| "cas": "8014-17-3", | |
| "coefficient_tier_recomputed": "top", | |
| "distance_to_boundary_coeff_units": 6.0, | |
| "measured_coefficient": 8, | |
| "measured_tier": "top", | |
| "name": "Petitgrain, French", | |
| "poucher_tier": "mid", | |
| "tier_step_distance": 1 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "wild", | |
| "boundary_crossed": null, | |
| "cas": "8014-19-5", | |
| "coefficient_tier_recomputed": "top", | |
| "distance_to_boundary_coeff_units": null, | |
| "measured_coefficient": 14, | |
| "measured_tier": "top", | |
| "name": "Palmarosa", | |
| "poucher_tier": "base", | |
| "tier_step_distance": 2 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "near-boundary", | |
| "boundary_crossed": "mid_base_60_61", | |
| "cas": "8015-64-3", | |
| "coefficient_tier_recomputed": "mid", | |
| "distance_to_boundary_coeff_units": 2.0, | |
| "measured_coefficient": 58, | |
| "measured_tier": "mid", | |
| "name": "Angelica root", | |
| "poucher_tier": "base", | |
| "tier_step_distance": 1 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "wild", | |
| "boundary_crossed": null, | |
| "cas": "8015-73-4", | |
| "coefficient_tier_recomputed": "top", | |
| "distance_to_boundary_coeff_units": null, | |
| "measured_coefficient": 14, | |
| "measured_tier": "top", | |
| "name": "Basilic", | |
| "poucher_tier": "base", | |
| "tier_step_distance": 2 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "wild", | |
| "boundary_crossed": "mid_base_60_61", | |
| "cas": "8016-96-4", | |
| "coefficient_tier_recomputed": "base", | |
| "distance_to_boundary_coeff_units": 39.0, | |
| "measured_coefficient": 100, | |
| "measured_tier": "base", | |
| "name": "Vetivert", | |
| "poucher_tier": "mid", | |
| "tier_step_distance": 1 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "wild", | |
| "boundary_crossed": "mid_base_60_61", | |
| "cas": "8021-15-0", | |
| "coefficient_tier_recomputed": "mid", | |
| "distance_to_boundary_coeff_units": 8.0, | |
| "measured_coefficient": 52, | |
| "measured_tier": "mid", | |
| "name": "Opoponax oil", | |
| "poucher_tier": "base", | |
| "tier_step_distance": 1 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "near-boundary", | |
| "boundary_crossed": "top_mid_14_15", | |
| "cas": "8022-09-9", | |
| "coefficient_tier_recomputed": "top", | |
| "distance_to_boundary_coeff_units": 5.0, | |
| "measured_coefficient": 9, | |
| "measured_tier": "top", | |
| "name": "Spike lavender", | |
| "poucher_tier": "mid", | |
| "tier_step_distance": 1 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "wild", | |
| "boundary_crossed": null, | |
| "cas": "8022-62-6", | |
| "coefficient_tier_recomputed": "top", | |
| "distance_to_boundary_coeff_units": null, | |
| "measured_coefficient": 14, | |
| "measured_tier": "top", | |
| "name": "Reseda absolute", | |
| "poucher_tier": "base", | |
| "tier_step_distance": 2 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "near-boundary", | |
| "boundary_crossed": "top_mid_14_15", | |
| "cas": "8023-70-5", | |
| "coefficient_tier_recomputed": "top", | |
| "distance_to_boundary_coeff_units": 4.0, | |
| "measured_coefficient": 10, | |
| "measured_tier": "top", | |
| "name": "Ginger", | |
| "poucher_tier": "mid", | |
| "tier_step_distance": 1 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "near-boundary", | |
| "boundary_crossed": "top_mid_14_15", | |
| "cas": "8023-82-3", | |
| "coefficient_tier_recomputed": "top", | |
| "distance_to_boundary_coeff_units": 4.0, | |
| "measured_coefficient": 10, | |
| "measured_tier": "top", | |
| "name": "Myrrh oil", | |
| "poucher_tier": "mid", | |
| "tier_step_distance": 1 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "wild", | |
| "boundary_crossed": null, | |
| "cas": "8023-87-6", | |
| "coefficient_tier_recomputed": "top", | |
| "distance_to_boundary_coeff_units": null, | |
| "measured_coefficient": 14, | |
| "measured_tier": "top", | |
| "name": "Mimosa absolute", | |
| "poucher_tier": "base", | |
| "tier_step_distance": 2 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "wild", | |
| "boundary_crossed": "mid_base_60_61", | |
| "cas": "8023-91-4", | |
| "coefficient_tier_recomputed": "mid", | |
| "distance_to_boundary_coeff_units": 8.0, | |
| "measured_coefficient": 52, | |
| "measured_tier": "mid", | |
| "name": "Galbanum resin", | |
| "poucher_tier": "base", | |
| "tier_step_distance": 1 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "near-boundary", | |
| "boundary_crossed": "mid_base_60_61", | |
| "cas": "83-54-5", | |
| "coefficient_tier_recomputed": "mid", | |
| "distance_to_boundary_coeff_units": 0.0, | |
| "measured_coefficient": 60, | |
| "measured_tier": "mid", | |
| "name": "Rhodinyl formate", | |
| "poucher_tier": "base", | |
| "tier_step_distance": 1 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "wild", | |
| "boundary_crossed": "mid_base_60_61", | |
| "cas": "9000-50-6", | |
| "coefficient_tier_recomputed": "base", | |
| "distance_to_boundary_coeff_units": 39.0, | |
| "measured_coefficient": 100, | |
| "measured_tier": "base", | |
| "name": "Oakmoss", | |
| "poucher_tier": "mid", | |
| "tier_step_distance": 1 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "wild", | |
| "boundary_crossed": "mid_base_60_61", | |
| "cas": "91-64-5", | |
| "coefficient_tier_recomputed": "base", | |
| "distance_to_boundary_coeff_units": 39.0, | |
| "measured_coefficient": 100, | |
| "measured_tier": "base", | |
| "name": "Coumarin", | |
| "poucher_tier": "mid", | |
| "tier_step_distance": 1 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "wild", | |
| "boundary_crossed": "mid_base_60_61", | |
| "cas": "91771-61-8", | |
| "coefficient_tier_recomputed": "mid", | |
| "distance_to_boundary_coeff_units": 42.0, | |
| "measured_coefficient": 18, | |
| "measured_tier": "mid", | |
| "name": "Citronella, Java", | |
| "poucher_tier": "base", | |
| "tier_step_distance": 1 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "wild", | |
| "boundary_crossed": null, | |
| "cas": "94-48-4", | |
| "coefficient_tier_recomputed": "top", | |
| "distance_to_boundary_coeff_units": null, | |
| "measured_coefficient": 4, | |
| "measured_tier": "top", | |
| "name": "Geranyl benzoate", | |
| "poucher_tier": "base", | |
| "tier_step_distance": 2 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "wild", | |
| "boundary_crossed": null, | |
| "cas": "94-59-7", | |
| "coefficient_tier_recomputed": "top", | |
| "distance_to_boundary_coeff_units": null, | |
| "measured_coefficient": 3, | |
| "measured_tier": "top", | |
| "name": "Sassafras", | |
| "poucher_tier": "base", | |
| "tier_step_distance": 2 | |
| }, | |
| { | |
| "agrees": false, | |
| "boundary_classification": "wild", | |
| "boundary_crossed": null, | |
| "cas": "98-86-2", | |
| "coefficient_tier_recomputed": "top", | |
| "distance_to_boundary_coeff_units": null, | |
| "measured_coefficient": 1, | |
| "measured_tier": "top", | |
| "name": "Acetophenone", | |
| "poucher_tier": "base", | |
| "tier_step_distance": 2 | |
| } | |
| ], | |
| "histogram": { | |
| "near-boundary": 12, | |
| "wild": 57 | |
| }, | |
| "histogram_by_pair": { | |
| "base->mid:wild": 5, | |
| "base->top:wild": 1, | |
| "mid->base:near-boundary": 4, | |
| "mid->base:wild": 8, | |
| "top->base:wild": 26, | |
| "top->mid:near-boundary": 8, | |
| "top->mid:wild": 17 | |
| }, | |
| "pimt_version": "v8", | |
| "verdict": { | |
| "measured_170_stands": true, | |
| "phase1_conclusion_survives": true, | |
| "phase1_recompute_reason": "Wild cases are mostly same-CAS source/construct disagreements or form mismatches in the auxiliary tier source, not measured-side join errors. The 170 measured coefficients remain the Phase 1 target.", | |
| "phase1_recomputed": false, | |
| "phase1_saved_best_baseline_r2": 0.24057748815493107, | |
| "phase1_saved_best_baseline_spearman_rho": 0.6130893034049266, | |
| "phase1_saved_best_structure_r2": 0.3990232662101132, | |
| "phase1_saved_best_structure_spearman_rho": 0.6633801733693918, | |
| "phase1_test_wild_non_join_cas": [ | |
| "106-29-6", | |
| "112-14-1", | |
| "118-58-1", | |
| "141-78-6", | |
| "141-97-9", | |
| "68127-65-1", | |
| "8000-29-1", | |
| "8000-41-7", | |
| "8008-45-5", | |
| "8014-09-3" | |
| ], | |
| "tier_fold_policy": "Do not fold disagreeing auxiliary tiers as substantivity supervision. Only near-boundary-consistent rows, and future join-corrected rows if any, may be folded with provenance poucher-tier; poucher-measured remains uncontaminated." | |
| }, | |
| "wild_case_causes": [ | |
| { | |
| "cas": "100-52-7", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 1 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Almonds, Benzaldehyde; tier row name: Almonds.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 1, | |
| "measured_tier": "top", | |
| "name": "Almonds", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "101-84-8", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 10 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Diphenyl oxide; tier row name: Diphenyl oxide.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 10, | |
| "measured_tier": "top", | |
| "name": "Diphenyl oxide", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "103-45-7", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 1 maps to top; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Phenylethyl acetate; tier row name: Phenylethyl acetate.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 1, | |
| "measured_tier": "top", | |
| "name": "Phenylethyl acetate", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "103-48-0", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 19 maps to mid; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Phenylethyl iso-butyrate; tier row name: Phenylethyl iso-butyrate.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 19, | |
| "measured_tier": "mid", | |
| "name": "Phenylethyl iso-butyrate", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "103-61-7", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 28 maps to mid; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Cinnamyl butyrate; tier row name: Cinnamyl butyrate.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 28, | |
| "measured_tier": "mid", | |
| "name": "Cinnamyl butyrate", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "104-65-4", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 18 maps to mid; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Cinnamyl formate; tier row name: Cinnamyl formate.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 18, | |
| "measured_tier": "mid", | |
| "name": "Cinnamyl formate", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "105-13-5", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 47 maps to mid; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Anisic alcohol; tier row name: Anisic alcohol.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 47, | |
| "measured_tier": "mid", | |
| "name": "Anisic alcohol", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "105-85-1", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 9 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Citronellyl formate; tier row name: Citronellyl formate.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 9, | |
| "measured_tier": "top", | |
| "name": "Citronellyl formate", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "106-22-9", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 4 maps to top; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Citronellol; tier row name: Citronellol.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 4, | |
| "measured_tier": "top", | |
| "name": "Citronellol", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "106-24-1", | |
| "cause": "join-error", | |
| "evidence": [ | |
| "Measured coefficient 6 maps to top; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Geraniol ex palmarosa, Geraniol, Java; tier row name: Geraniol ex palmarosa.", | |
| "Measured extraction has an intra-CAS coefficient conflict, so identity/name aggregation must be manually corrected before folding this row." | |
| ], | |
| "measured_coefficient": 6, | |
| "measured_tier": "top", | |
| "name": "Geraniol ex palmarosa", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "106-25-2", | |
| "cause": "join-error", | |
| "evidence": [ | |
| "Measured coefficient 5 maps to top; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Nerol, Neroli bigarade, Neroli, Italian; tier row name: Nerol.", | |
| "Measured extraction has an intra-CAS coefficient conflict, so identity/name aggregation must be manually corrected before folding this row." | |
| ], | |
| "measured_coefficient": 5, | |
| "measured_tier": "top", | |
| "name": "Nerol", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "106-29-6", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 9 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Geranyl butyrate; tier row name: Geranyl butyrate.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 9, | |
| "measured_tier": "top", | |
| "name": "Geranyl butyrate", | |
| "phase1_scaffold_test_member": true, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "107-75-5", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 80 maps to base; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Hydroxy citronellal; tier row name: Hydroxy citronellal.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 80, | |
| "measured_tier": "base", | |
| "name": "Hydroxy citronellal", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "111-12-6", | |
| "cause": "join-error", | |
| "evidence": [ | |
| "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Methyl heptine carbonate, Methyl octine carbonate; tier row name: Methyl heptine carbonate.", | |
| "Measured extraction has an intra-CAS coefficient conflict, so identity/name aggregation must be manually corrected before folding this row." | |
| ], | |
| "measured_coefficient": 8, | |
| "measured_tier": "top", | |
| "name": "Methyl heptine carbonate", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "112-14-1", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 1 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Octyl acetate; tier row name: Octyl acetate.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 1, | |
| "measured_tier": "top", | |
| "name": "Octyl acetate", | |
| "phase1_scaffold_test_member": true, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "112-31-2", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 100 maps to base; auxiliary Poucher profile tier is top.", | |
| "Measured source names: Decyl aldehyde; tier row name: Decyl aldehyde.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 100, | |
| "measured_tier": "base", | |
| "name": "Decyl aldehyde", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "top" | |
| }, | |
| { | |
| "cas": "118-58-1", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Benzyl salicylate; tier row name: Benzyl salicylate.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 8, | |
| "measured_tier": "top", | |
| "name": "Benzyl salicylate", | |
| "phase1_scaffold_test_member": true, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "122-00-9", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 3 maps to top; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Methyl acetophenone; tier row name: Methyl acetophenone.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 3, | |
| "measured_tier": "top", | |
| "name": "Methyl acetophenone", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "122-63-4", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 10 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Benzyl propionate; tier row name: Benzyl propionate.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 10, | |
| "measured_tier": "top", | |
| "name": "Benzyl propionate", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "124-19-6", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Nonyl aldehyde; tier row name: Nonyl aldehyde.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 8, | |
| "measured_tier": "top", | |
| "name": "Nonyl aldehyde", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "126-64-7", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 9 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Linalyl benzoate; tier row name: Linalyl benzoate.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 9, | |
| "measured_tier": "top", | |
| "name": "Linalyl benzoate", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "1335-46-2", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 14 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Methyl ionone; tier row name: Methyl ionone.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 14, | |
| "measured_tier": "top", | |
| "name": "Methyl ionone", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "140-11-4", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 1 maps to top; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Benzyl acetate; tier row name: Benzyl acetate.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 1, | |
| "measured_tier": "top", | |
| "name": "Benzyl acetate", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "141-78-6", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 1 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Ethyl acetate; tier row name: Ethyl acetate.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 1, | |
| "measured_tier": "top", | |
| "name": "Ethyl acetate", | |
| "phase1_scaffold_test_member": true, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "141-97-9", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 1 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Ethyl acetoacetate; tier row name: Ethyl acetoacetate.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 1, | |
| "measured_tier": "top", | |
| "name": "Ethyl acetoacetate", | |
| "phase1_scaffold_test_member": true, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "144-39-8", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 5 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Linalyl propionate; tier row name: Linalyl propionate.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 5, | |
| "measured_tier": "top", | |
| "name": "Linalyl propionate", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "150-84-5", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Citronellyl acetate; tier row name: Citronellyl acetate.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 8, | |
| "measured_tier": "top", | |
| "name": "Citronellyl acetate", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "2050-08-0", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Amyl salicylate; tier row name: Amyl salicylate.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 8, | |
| "measured_tier": "top", | |
| "name": "Amyl salicylate", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "60-12-8", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Phenylethyl alcohol; tier row name: Phenylethyl alcohol.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 8, | |
| "measured_tier": "top", | |
| "name": "Phenylethyl alcohol", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "68127-65-1", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 5 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Rhodinol; tier row name: Rhodinol.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 5, | |
| "measured_tier": "top", | |
| "name": "Rhodinol", | |
| "phase1_scaffold_test_member": true, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "8000-27-9", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Cedarwood; tier row name: Cedarwood.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 8, | |
| "measured_tier": "top", | |
| "name": "Cedarwood", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "8000-28-0", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Lavender; tier row name: Lavender.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 8, | |
| "measured_tier": "top", | |
| "name": "Lavender", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "8000-29-1", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Citronella, Ceylon; tier row name: Citronella, Ceylon.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 8, | |
| "measured_tier": "top", | |
| "name": "Citronella, Ceylon", | |
| "phase1_scaffold_test_member": true, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "8000-41-7", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 3 maps to top; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Terpineol; tier row name: Terpineol.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 3, | |
| "measured_tier": "top", | |
| "name": "Terpineol", | |
| "phase1_scaffold_test_member": true, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "8000-48-4", | |
| "cause": "join-error", | |
| "evidence": [ | |
| "Measured coefficient 15 maps to mid; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Eucalyptus, Eucalyptus citriodora; tier row name: Eucalyptus.", | |
| "Measured extraction has an intra-CAS coefficient conflict, so identity/name aggregation must be manually corrected before folding this row." | |
| ], | |
| "measured_coefficient": 15, | |
| "measured_tier": "mid", | |
| "name": "Eucalyptus", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "8006-78-8", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 6 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Bay; tier row name: Bay.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 6, | |
| "measured_tier": "top", | |
| "name": "Bay", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "8006-84-6", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 14 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Fennel; tier row name: Fennel.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 14, | |
| "measured_tier": "top", | |
| "name": "Fennel", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "8007-35-0", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 5 maps to top; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Terpinyl acetate; tier row name: Terpinyl acetate.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 5, | |
| "measured_tier": "top", | |
| "name": "Terpinyl acetate", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "8007-46-3", | |
| "cause": "join-error", | |
| "evidence": [ | |
| "Measured coefficient 6 maps to top; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Thyme red, Thyme white; tier row name: Thyme white.", | |
| "Measured extraction has an intra-CAS coefficient conflict, so identity/name aggregation must be manually corrected before folding this row." | |
| ], | |
| "measured_coefficient": 6, | |
| "measured_tier": "top", | |
| "name": "Thyme white", | |
| "phase1_scaffold_test_member": true, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "8007-75-8", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 6 maps to top; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Bergamot; tier row name: Bergamot.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 6, | |
| "measured_tier": "top", | |
| "name": "Bergamot", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "8008-45-5", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 14 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Nutmeg; tier row name: Nutmeg.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 14, | |
| "measured_tier": "top", | |
| "name": "Nutmeg", | |
| "phase1_scaffold_test_member": true, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "8008-56-8", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 5 maps to top; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Lemon; tier row name: Lemon.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 5, | |
| "measured_tier": "top", | |
| "name": "Lemon", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "8014-09-3", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 100 maps to base; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Patchouli; tier row name: Patchouli.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 100, | |
| "measured_tier": "base", | |
| "name": "Patchouli", | |
| "phase1_scaffold_test_member": true, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "8014-17-3", | |
| "cause": "join-error", | |
| "evidence": [ | |
| "Measured coefficient 8 maps to top; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Petitgrain para, Petitgrain, French; tier row name: Petitgrain, French.", | |
| "Measured extraction has an intra-CAS coefficient conflict, so identity/name aggregation must be manually corrected before folding this row." | |
| ], | |
| "measured_coefficient": 8, | |
| "measured_tier": "top", | |
| "name": "Petitgrain, French", | |
| "phase1_scaffold_test_member": true, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "8014-19-5", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 14 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Palmarosa; tier row name: Palmarosa.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 14, | |
| "measured_tier": "top", | |
| "name": "Palmarosa", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "8015-73-4", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 14 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Basilic; tier row name: Basilic.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 14, | |
| "measured_tier": "top", | |
| "name": "Basilic", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "8016-96-4", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 100 maps to base; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Vetivert; tier row name: Vetivert.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 100, | |
| "measured_tier": "base", | |
| "name": "Vetivert", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "8021-15-0", | |
| "cause": "join-error", | |
| "evidence": [ | |
| "Measured coefficient 52 maps to mid; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Opoponax oil, Opoponax resin; tier row name: Opoponax oil.", | |
| "Measured extraction has an intra-CAS coefficient conflict, so identity/name aggregation must be manually corrected before folding this row." | |
| ], | |
| "measured_coefficient": 52, | |
| "measured_tier": "mid", | |
| "name": "Opoponax oil", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "8022-62-6", | |
| "cause": "form-mismatch", | |
| "evidence": [ | |
| "Measured coefficient 14 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Reseda absolute; tier row name: Reseda absolute.", | |
| "The measured/tier evidence names a natural, source-geographic, or material-form variant rather than one clean isolate." | |
| ], | |
| "measured_coefficient": 14, | |
| "measured_tier": "top", | |
| "name": "Reseda absolute", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "8023-87-6", | |
| "cause": "form-mismatch", | |
| "evidence": [ | |
| "Measured coefficient 14 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Mimosa absolute; tier row name: Mimosa absolute.", | |
| "The measured/tier evidence names a natural, source-geographic, or material-form variant rather than one clean isolate." | |
| ], | |
| "measured_coefficient": 14, | |
| "measured_tier": "top", | |
| "name": "Mimosa absolute", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "8023-91-4", | |
| "cause": "join-error", | |
| "evidence": [ | |
| "Measured coefficient 52 maps to mid; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Galbanum oil, Galbanum resin; tier row name: Galbanum resin.", | |
| "Measured extraction has an intra-CAS coefficient conflict, so identity/name aggregation must be manually corrected before folding this row." | |
| ], | |
| "measured_coefficient": 52, | |
| "measured_tier": "mid", | |
| "name": "Galbanum resin", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "9000-50-6", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 100 maps to base; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Oakmoss; tier row name: Oakmoss.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 100, | |
| "measured_tier": "base", | |
| "name": "Oakmoss", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "91-64-5", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 100 maps to base; auxiliary Poucher profile tier is mid.", | |
| "Measured source names: Coumarin; tier row name: Coumarin.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 100, | |
| "measured_tier": "base", | |
| "name": "Coumarin", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "mid" | |
| }, | |
| { | |
| "cas": "91771-61-8", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 18 maps to mid; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Citronella, Java; tier row name: Citronella, Java.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 18, | |
| "measured_tier": "mid", | |
| "name": "Citronella, Java", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "94-48-4", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 4 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Geranyl benzoate; tier row name: Geranyl benzoate.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 4, | |
| "measured_tier": "top", | |
| "name": "Geranyl benzoate", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "94-59-7", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 3 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Sassafras; tier row name: Sassafras.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 3, | |
| "measured_tier": "top", | |
| "name": "Sassafras", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| }, | |
| { | |
| "cas": "98-86-2", | |
| "cause": "genuine-source-disagreement", | |
| "evidence": [ | |
| "Measured coefficient 1 maps to top; auxiliary Poucher profile tier is base.", | |
| "Measured source names: Acetophenone; tier row name: Acetophenone.", | |
| "Both sides are keyed to the same CAS and no local name evidence points to a different material; treat as source/construct disagreement, not a measured-coefficient failure." | |
| ], | |
| "measured_coefficient": 1, | |
| "measured_tier": "top", | |
| "name": "Acetophenone", | |
| "phase1_scaffold_test_member": false, | |
| "poucher_tier": "base" | |
| } | |
| ], | |
| "wild_cause_counts": { | |
| "form-mismatch": 2, | |
| "genuine-source-disagreement": 47, | |
| "join-error": 8 | |
| } | |
| } | |