| { |
| "agreement_count": 75, |
| "agreement_rate": 0.5208333333333334, |
| "agreement_total": 144, |
| "boundary_margin_coeff_units": 5, |
| "diagnostic": "D1_substantivity_integrity", |
| "disagreement_count": 69, |
| "disagreements": [ |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "100-52-7", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 1, |
| "measured_tier": "top", |
| "name": "Almonds", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "101-84-8", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 10, |
| "measured_tier": "top", |
| "name": "Diphenyl oxide", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "near-boundary", |
| "boundary_crossed": "mid_base_60_61", |
| "cas": "102-16-9", |
| "distance_to_boundary_coeff_units": 0.0, |
| "measured_coefficient": 60, |
| "measured_tier": "mid", |
| "name": "Benzyl phenylacetate", |
| "poucher_tier": "base", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "near-boundary", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "103-26-4", |
| "distance_to_boundary_coeff_units": 2.0, |
| "measured_coefficient": 12, |
| "measured_tier": "top", |
| "name": "Methyl cinnamate", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "103-45-7", |
| "distance_to_boundary_coeff_units": 13.0, |
| "measured_coefficient": 1, |
| "measured_tier": "top", |
| "name": "Phenylethyl acetate", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "mid_base_60_61", |
| "cas": "103-48-0", |
| "distance_to_boundary_coeff_units": 41.0, |
| "measured_coefficient": 19, |
| "measured_tier": "mid", |
| "name": "Phenylethyl iso-butyrate", |
| "poucher_tier": "base", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "mid_base_60_61", |
| "cas": "103-61-7", |
| "distance_to_boundary_coeff_units": 32.0, |
| "measured_coefficient": 28, |
| "measured_tier": "mid", |
| "name": "Cinnamyl butyrate", |
| "poucher_tier": "base", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "mid_base_60_61", |
| "cas": "104-65-4", |
| "distance_to_boundary_coeff_units": 42.0, |
| "measured_coefficient": 18, |
| "measured_tier": "mid", |
| "name": "Cinnamyl formate", |
| "poucher_tier": "base", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "mid_base_60_61", |
| "cas": "105-13-5", |
| "distance_to_boundary_coeff_units": 13.0, |
| "measured_coefficient": 47, |
| "measured_tier": "mid", |
| "name": "Anisic alcohol", |
| "poucher_tier": "base", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "105-85-1", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 9, |
| "measured_tier": "top", |
| "name": "Citronellyl formate", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "106-22-9", |
| "distance_to_boundary_coeff_units": 10.0, |
| "measured_coefficient": 4, |
| "measured_tier": "top", |
| "name": "Citronellol", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "106-24-1", |
| "distance_to_boundary_coeff_units": 8.0, |
| "measured_coefficient": 6, |
| "measured_tier": "top", |
| "name": "Geraniol ex palmarosa", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "106-25-2", |
| "distance_to_boundary_coeff_units": 9.0, |
| "measured_coefficient": 5, |
| "measured_tier": "top", |
| "name": "Nerol", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "106-29-6", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 9, |
| "measured_tier": "top", |
| "name": "Geranyl butyrate", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "mid_base_60_61", |
| "cas": "107-75-5", |
| "distance_to_boundary_coeff_units": 19.0, |
| "measured_coefficient": 80, |
| "measured_tier": "base", |
| "name": "Hydroxy citronellal", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "111-12-6", |
| "distance_to_boundary_coeff_units": 6.0, |
| "measured_coefficient": 8, |
| "measured_tier": "top", |
| "name": "Methyl heptine carbonate", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "112-14-1", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 1, |
| "measured_tier": "top", |
| "name": "Octyl acetate", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "112-31-2", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 100, |
| "measured_tier": "base", |
| "name": "Decyl aldehyde", |
| "poucher_tier": "top", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "118-58-1", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 8, |
| "measured_tier": "top", |
| "name": "Benzyl salicylate", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "122-00-9", |
| "distance_to_boundary_coeff_units": 11.0, |
| "measured_coefficient": 3, |
| "measured_tier": "top", |
| "name": "Methyl acetophenone", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "122-63-4", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 10, |
| "measured_tier": "top", |
| "name": "Benzyl propionate", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "124-19-6", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 8, |
| "measured_tier": "top", |
| "name": "Nonyl aldehyde", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "126-64-7", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 9, |
| "measured_tier": "top", |
| "name": "Linalyl benzoate", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "1335-46-2", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 14, |
| "measured_tier": "top", |
| "name": "Methyl ionone", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "140-11-4", |
| "distance_to_boundary_coeff_units": 13.0, |
| "measured_coefficient": 1, |
| "measured_tier": "top", |
| "name": "Benzyl acetate", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "141-78-6", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 1, |
| "measured_tier": "top", |
| "name": "Ethyl acetate", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "141-97-9", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 1, |
| "measured_tier": "top", |
| "name": "Ethyl acetoacetate", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "144-39-8", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 5, |
| "measured_tier": "top", |
| "name": "Linalyl propionate", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "150-84-5", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 8, |
| "measured_tier": "top", |
| "name": "Citronellyl acetate", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "2050-08-0", |
| "distance_to_boundary_coeff_units": 6.0, |
| "measured_coefficient": 8, |
| "measured_tier": "top", |
| "name": "Amyl salicylate", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "60-12-8", |
| "distance_to_boundary_coeff_units": 6.0, |
| "measured_coefficient": 8, |
| "measured_tier": "top", |
| "name": "Phenylethyl alcohol", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "68127-65-1", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 5, |
| "measured_tier": "top", |
| "name": "Rhodinol", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "near-boundary", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "68606-83-7", |
| "distance_to_boundary_coeff_units": 0.0, |
| "measured_coefficient": 14, |
| "measured_tier": "top", |
| "name": "Cananga", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "near-boundary", |
| "boundary_crossed": "mid_base_60_61", |
| "cas": "7212-44-4", |
| "distance_to_boundary_coeff_units": 5.0, |
| "measured_coefficient": 55, |
| "measured_tier": "mid", |
| "name": "Nerolidol", |
| "poucher_tier": "base", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "8000-27-9", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 8, |
| "measured_tier": "top", |
| "name": "Cedarwood", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "8000-28-0", |
| "distance_to_boundary_coeff_units": 6.0, |
| "measured_coefficient": 8, |
| "measured_tier": "top", |
| "name": "Lavender", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "8000-29-1", |
| "distance_to_boundary_coeff_units": 6.0, |
| "measured_coefficient": 8, |
| "measured_tier": "top", |
| "name": "Citronella, Ceylon", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "8000-41-7", |
| "distance_to_boundary_coeff_units": 11.0, |
| "measured_coefficient": 3, |
| "measured_tier": "top", |
| "name": "Terpineol", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "near-boundary", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "8000-42-8", |
| "distance_to_boundary_coeff_units": 5.0, |
| "measured_coefficient": 9, |
| "measured_tier": "top", |
| "name": "Caraway", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "mid_base_60_61", |
| "cas": "8000-48-4", |
| "distance_to_boundary_coeff_units": 45.0, |
| "measured_coefficient": 15, |
| "measured_tier": "mid", |
| "name": "Eucalyptus", |
| "poucher_tier": "base", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "8006-78-8", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 6, |
| "measured_tier": "top", |
| "name": "Bay", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "8006-84-6", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 14, |
| "measured_tier": "top", |
| "name": "Fennel", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "near-boundary", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "8006-90-4", |
| "distance_to_boundary_coeff_units": 5.0, |
| "measured_coefficient": 9, |
| "measured_tier": "top", |
| "name": "Peppermint, American", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "near-boundary", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "8007-02-1", |
| "distance_to_boundary_coeff_units": 0.0, |
| "measured_coefficient": 14, |
| "measured_tier": "top", |
| "name": "Lemongrass", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "8007-35-0", |
| "distance_to_boundary_coeff_units": 9.0, |
| "measured_coefficient": 5, |
| "measured_tier": "top", |
| "name": "Terpinyl acetate", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "8007-46-3", |
| "distance_to_boundary_coeff_units": 8.0, |
| "measured_coefficient": 6, |
| "measured_tier": "top", |
| "name": "Thyme white", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "8007-75-8", |
| "distance_to_boundary_coeff_units": 8.0, |
| "measured_coefficient": 6, |
| "measured_tier": "top", |
| "name": "Bergamot", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "8008-45-5", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 14, |
| "measured_tier": "top", |
| "name": "Nutmeg", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "8008-56-8", |
| "distance_to_boundary_coeff_units": 9.0, |
| "measured_coefficient": 5, |
| "measured_tier": "top", |
| "name": "Lemon", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "mid_base_60_61", |
| "cas": "8014-09-3", |
| "distance_to_boundary_coeff_units": 39.0, |
| "measured_coefficient": 100, |
| "measured_tier": "base", |
| "name": "Patchouli", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "8014-17-3", |
| "distance_to_boundary_coeff_units": 6.0, |
| "measured_coefficient": 8, |
| "measured_tier": "top", |
| "name": "Petitgrain, French", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "8014-19-5", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 14, |
| "measured_tier": "top", |
| "name": "Palmarosa", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "near-boundary", |
| "boundary_crossed": "mid_base_60_61", |
| "cas": "8015-64-3", |
| "distance_to_boundary_coeff_units": 2.0, |
| "measured_coefficient": 58, |
| "measured_tier": "mid", |
| "name": "Angelica root", |
| "poucher_tier": "base", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "8015-73-4", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 14, |
| "measured_tier": "top", |
| "name": "Basilic", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "mid_base_60_61", |
| "cas": "8016-96-4", |
| "distance_to_boundary_coeff_units": 39.0, |
| "measured_coefficient": 100, |
| "measured_tier": "base", |
| "name": "Vetivert", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "mid_base_60_61", |
| "cas": "8021-15-0", |
| "distance_to_boundary_coeff_units": 8.0, |
| "measured_coefficient": 52, |
| "measured_tier": "mid", |
| "name": "Opoponax oil", |
| "poucher_tier": "base", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "near-boundary", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "8022-09-9", |
| "distance_to_boundary_coeff_units": 5.0, |
| "measured_coefficient": 9, |
| "measured_tier": "top", |
| "name": "Spike lavender", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "8022-62-6", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 14, |
| "measured_tier": "top", |
| "name": "Reseda absolute", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "near-boundary", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "8023-70-5", |
| "distance_to_boundary_coeff_units": 4.0, |
| "measured_coefficient": 10, |
| "measured_tier": "top", |
| "name": "Ginger", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "near-boundary", |
| "boundary_crossed": "top_mid_14_15", |
| "cas": "8023-82-3", |
| "distance_to_boundary_coeff_units": 4.0, |
| "measured_coefficient": 10, |
| "measured_tier": "top", |
| "name": "Myrrh oil", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "8023-87-6", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 14, |
| "measured_tier": "top", |
| "name": "Mimosa absolute", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "mid_base_60_61", |
| "cas": "8023-91-4", |
| "distance_to_boundary_coeff_units": 8.0, |
| "measured_coefficient": 52, |
| "measured_tier": "mid", |
| "name": "Galbanum resin", |
| "poucher_tier": "base", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "near-boundary", |
| "boundary_crossed": "mid_base_60_61", |
| "cas": "83-54-5", |
| "distance_to_boundary_coeff_units": 0.0, |
| "measured_coefficient": 60, |
| "measured_tier": "mid", |
| "name": "Rhodinyl formate", |
| "poucher_tier": "base", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "mid_base_60_61", |
| "cas": "9000-50-6", |
| "distance_to_boundary_coeff_units": 39.0, |
| "measured_coefficient": 100, |
| "measured_tier": "base", |
| "name": "Oakmoss", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "mid_base_60_61", |
| "cas": "91-64-5", |
| "distance_to_boundary_coeff_units": 39.0, |
| "measured_coefficient": 100, |
| "measured_tier": "base", |
| "name": "Coumarin", |
| "poucher_tier": "mid", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": "mid_base_60_61", |
| "cas": "91771-61-8", |
| "distance_to_boundary_coeff_units": 42.0, |
| "measured_coefficient": 18, |
| "measured_tier": "mid", |
| "name": "Citronella, Java", |
| "poucher_tier": "base", |
| "tier_step_distance": 1 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "94-48-4", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 4, |
| "measured_tier": "top", |
| "name": "Geranyl benzoate", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "94-59-7", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 3, |
| "measured_tier": "top", |
| "name": "Sassafras", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| }, |
| { |
| "agrees": false, |
| "boundary_classification": "wild", |
| "boundary_crossed": null, |
| "cas": "98-86-2", |
| "distance_to_boundary_coeff_units": null, |
| "measured_coefficient": 1, |
| "measured_tier": "top", |
| "name": "Acetophenone", |
| "poucher_tier": "base", |
| "tier_step_distance": 2 |
| } |
| ], |
| "histogram": { |
| "near-boundary": 12, |
| "wild": 57 |
| }, |
| "histogram_by_pair": { |
| "base->mid:wild": 5, |
| "base->top:wild": 1, |
| "mid->base:near-boundary": 4, |
| "mid->base:wild": 8, |
| "top->base:wild": 26, |
| "top->mid:near-boundary": 8, |
| "top->mid:wild": 17 |
| }, |
| "pimt_version": "v8", |
| "verdict": { |
| "measured_170_affected": false, |
| "phase1_eval_summary": { |
| "best_structure_model": "structure_full_gbm", |
| "best_structure_spearman_rho": 0.6633801733693918, |
| "n_model_ready": 170, |
| "split": { |
| "n_test": 34, |
| "n_train": 136, |
| "scaffold_overlap": [], |
| "seed": 20260710, |
| "test_scaffolds": 34, |
| "train_scaffolds": 49, |
| "type": "scaffold-disjoint Murcko scaffold split" |
| } |
| }, |
| "phase1_result_affected": false, |
| "phase1_rho_recompute": "not_recomputed_no_measured_join_error_identified; diagnostics script does not import training/RDKit code", |
| "phase1_split_screen": "local reproduction of train_substantivity.greedy_scaffold_split from saved enriched scaffold keys; avoids importing training/RDKit code in diagnostics", |
| "phase1_test_wild_genuine_or_form_cas": [ |
| "106-29-6", |
| "112-14-1", |
| "118-58-1", |
| "141-78-6", |
| "141-97-9", |
| "8000-29-1", |
| "8000-41-7", |
| "8007-46-3", |
| "8008-45-5", |
| "8014-09-3", |
| "8014-17-3" |
| ], |
| "rationale": "Wild disagreements are not mostly join-errors. Local evidence points primarily to genuine source/construct disagreement between measured duration coefficients and profile role tiers; measured coefficients remain the rigorous Phase 1 target because they do not depend on auxiliary tiers.", |
| "tier_fold_verdict": "DO_NOT_FOLD_DISAGREEING_TIERS; only near-boundary-consistent rows or future join-corrected rows may be considered as poucher-tier provenance." |
| }, |
| "wild_case_causes": [ |
| { |
| "cas": "100-52-7", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 1, |
| "measured_names": [ |
| "Almonds", |
| "Benzaldehyde" |
| ], |
| "measured_tier": "top", |
| "name": "Almonds", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "101-84-8", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 10, |
| "measured_names": [ |
| "Diphenyl oxide" |
| ], |
| "measured_tier": "top", |
| "name": "Diphenyl oxide", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "103-45-7", |
| "cause": "join-error", |
| "evidence": [ |
| "Per-wild-case audit found local identity evidence for alias fragmentation, CAS conflation, or variant collision." |
| ], |
| "measured_coefficient": 1, |
| "measured_names": [ |
| "Phenylethyl acetate" |
| ], |
| "measured_tier": "top", |
| "name": "Phenylethyl acetate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "103-48-0", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 19, |
| "measured_names": [ |
| "Phenylethyl iso-butyrate" |
| ], |
| "measured_tier": "mid", |
| "name": "Phenylethyl iso-butyrate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "103-61-7", |
| "cause": "unresolved-needs-manual-review", |
| "evidence": [ |
| "Per-wild-case audit found insufficient local identity/source-name evidence for a stronger assignment." |
| ], |
| "measured_coefficient": 28, |
| "measured_names": [ |
| "Cinnamyl butyrate" |
| ], |
| "measured_tier": "mid", |
| "name": "Cinnamyl butyrate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "104-65-4", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 18, |
| "measured_names": [ |
| "Cinnamyl formate" |
| ], |
| "measured_tier": "mid", |
| "name": "Cinnamyl formate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "105-13-5", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 47, |
| "measured_names": [ |
| "Anisic alcohol" |
| ], |
| "measured_tier": "mid", |
| "name": "Anisic alcohol", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "105-85-1", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 9, |
| "measured_names": [ |
| "Citronellyl formate" |
| ], |
| "measured_tier": "top", |
| "name": "Citronellyl formate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "106-22-9", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 4, |
| "measured_names": [ |
| "Citronellol" |
| ], |
| "measured_tier": "top", |
| "name": "Citronellol", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "106-24-1", |
| "cause": "form-mismatch", |
| "evidence": [ |
| "Per-wild-case audit found source names comparing natural/geographic/material forms rather than one clean material form.", |
| "measured extraction records a coefficient conflict, but the per-case audit classification above is retained." |
| ], |
| "measured_coefficient": 6, |
| "measured_names": [ |
| "Geraniol ex palmarosa", |
| "Geraniol, Java" |
| ], |
| "measured_tier": "top", |
| "name": "Geraniol ex palmarosa", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "106-25-2", |
| "cause": "join-error", |
| "evidence": [ |
| "Per-wild-case audit found local identity evidence for alias fragmentation, CAS conflation, or variant collision.", |
| "measured extraction records a coefficient conflict, but the per-case audit classification above is retained." |
| ], |
| "measured_coefficient": 5, |
| "measured_names": [ |
| "Nerol", |
| "Neroli bigarade", |
| "Neroli, Italian" |
| ], |
| "measured_tier": "top", |
| "name": "Nerol", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "106-29-6", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 9, |
| "measured_names": [ |
| "Geranyl butyrate" |
| ], |
| "measured_tier": "top", |
| "name": "Geranyl butyrate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "107-75-5", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 80, |
| "measured_names": [ |
| "Hydroxy citronellal" |
| ], |
| "measured_tier": "base", |
| "name": "Hydroxy citronellal", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "111-12-6", |
| "cause": "join-error", |
| "evidence": [ |
| "Per-wild-case audit found local identity evidence for alias fragmentation, CAS conflation, or variant collision.", |
| "measured extraction records a coefficient conflict, but the per-case audit classification above is retained." |
| ], |
| "measured_coefficient": 8, |
| "measured_names": [ |
| "Methyl heptine carbonate", |
| "Methyl octine carbonate" |
| ], |
| "measured_tier": "top", |
| "name": "Methyl heptine carbonate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "112-14-1", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 1, |
| "measured_names": [ |
| "Octyl acetate" |
| ], |
| "measured_tier": "top", |
| "name": "Octyl acetate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "112-31-2", |
| "cause": "unresolved-needs-manual-review", |
| "evidence": [ |
| "Per-wild-case audit found insufficient local identity/source-name evidence for a stronger assignment." |
| ], |
| "measured_coefficient": 100, |
| "measured_names": [ |
| "Decyl aldehyde" |
| ], |
| "measured_tier": "base", |
| "name": "Decyl aldehyde", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "top" |
| }, |
| { |
| "cas": "118-58-1", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 8, |
| "measured_names": [ |
| "Benzyl salicylate" |
| ], |
| "measured_tier": "top", |
| "name": "Benzyl salicylate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "122-00-9", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 3, |
| "measured_names": [ |
| "Methyl acetophenone" |
| ], |
| "measured_tier": "top", |
| "name": "Methyl acetophenone", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "122-63-4", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 10, |
| "measured_names": [ |
| "Benzyl propionate" |
| ], |
| "measured_tier": "top", |
| "name": "Benzyl propionate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "124-19-6", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 8, |
| "measured_names": [ |
| "Nonyl aldehyde" |
| ], |
| "measured_tier": "top", |
| "name": "Nonyl aldehyde", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "126-64-7", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 9, |
| "measured_names": [ |
| "Linalyl benzoate" |
| ], |
| "measured_tier": "top", |
| "name": "Linalyl benzoate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "1335-46-2", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 14, |
| "measured_names": [ |
| "Methyl ionone" |
| ], |
| "measured_tier": "top", |
| "name": "Methyl ionone", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "140-11-4", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 1, |
| "measured_names": [ |
| "Benzyl acetate" |
| ], |
| "measured_tier": "top", |
| "name": "Benzyl acetate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "141-78-6", |
| "cause": "unresolved-needs-manual-review", |
| "evidence": [ |
| "Per-wild-case audit found insufficient local identity/source-name evidence for a stronger assignment." |
| ], |
| "measured_coefficient": 1, |
| "measured_names": [ |
| "Ethyl acetate" |
| ], |
| "measured_tier": "top", |
| "name": "Ethyl acetate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "141-97-9", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 1, |
| "measured_names": [ |
| "Ethyl acetoacetate" |
| ], |
| "measured_tier": "top", |
| "name": "Ethyl acetoacetate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "144-39-8", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 5, |
| "measured_names": [ |
| "Linalyl propionate" |
| ], |
| "measured_tier": "top", |
| "name": "Linalyl propionate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "150-84-5", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 8, |
| "measured_names": [ |
| "Citronellyl acetate" |
| ], |
| "measured_tier": "top", |
| "name": "Citronellyl acetate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "2050-08-0", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 8, |
| "measured_names": [ |
| "Amyl salicylate" |
| ], |
| "measured_tier": "top", |
| "name": "Amyl salicylate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "60-12-8", |
| "cause": "join-error", |
| "evidence": [ |
| "Per-wild-case audit found local identity evidence for alias fragmentation, CAS conflation, or variant collision." |
| ], |
| "measured_coefficient": 8, |
| "measured_names": [ |
| "Phenylethyl alcohol" |
| ], |
| "measured_tier": "top", |
| "name": "Phenylethyl alcohol", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "68127-65-1", |
| "cause": "join-error", |
| "evidence": [ |
| "Per-wild-case audit found local identity evidence for alias fragmentation, CAS conflation, or variant collision." |
| ], |
| "measured_coefficient": 5, |
| "measured_names": [ |
| "Rhodinol" |
| ], |
| "measured_tier": "top", |
| "name": "Rhodinol", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "8000-27-9", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement." |
| ], |
| "measured_coefficient": 8, |
| "measured_names": [ |
| "Cedarwood" |
| ], |
| "measured_tier": "top", |
| "name": "Cedarwood", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "8000-28-0", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement." |
| ], |
| "measured_coefficient": 8, |
| "measured_names": [ |
| "Lavender" |
| ], |
| "measured_tier": "top", |
| "name": "Lavender", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "8000-29-1", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement." |
| ], |
| "measured_coefficient": 8, |
| "measured_names": [ |
| "Citronella, Ceylon" |
| ], |
| "measured_tier": "top", |
| "name": "Citronella, Ceylon", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "8000-41-7", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 3, |
| "measured_names": [ |
| "Terpineol" |
| ], |
| "measured_tier": "top", |
| "name": "Terpineol", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "8000-48-4", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement.", |
| "measured extraction records a coefficient conflict, but the per-case audit classification above is retained." |
| ], |
| "measured_coefficient": 15, |
| "measured_names": [ |
| "Eucalyptus", |
| "Eucalyptus citriodora" |
| ], |
| "measured_tier": "mid", |
| "name": "Eucalyptus", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "8006-78-8", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement." |
| ], |
| "measured_coefficient": 6, |
| "measured_names": [ |
| "Bay" |
| ], |
| "measured_tier": "top", |
| "name": "Bay", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "8006-84-6", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement." |
| ], |
| "measured_coefficient": 14, |
| "measured_names": [ |
| "Fennel" |
| ], |
| "measured_tier": "top", |
| "name": "Fennel", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "8007-35-0", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 5, |
| "measured_names": [ |
| "Terpinyl acetate" |
| ], |
| "measured_tier": "top", |
| "name": "Terpinyl acetate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "8007-46-3", |
| "cause": "form-mismatch", |
| "evidence": [ |
| "Per-wild-case audit found source names comparing natural/geographic/material forms rather than one clean material form.", |
| "measured extraction records a coefficient conflict, but the per-case audit classification above is retained." |
| ], |
| "measured_coefficient": 6, |
| "measured_names": [ |
| "Thyme red", |
| "Thyme white" |
| ], |
| "measured_tier": "top", |
| "name": "Thyme white", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "8007-75-8", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement." |
| ], |
| "measured_coefficient": 6, |
| "measured_names": [ |
| "Bergamot" |
| ], |
| "measured_tier": "top", |
| "name": "Bergamot", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "8008-45-5", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement." |
| ], |
| "measured_coefficient": 14, |
| "measured_names": [ |
| "Nutmeg" |
| ], |
| "measured_tier": "top", |
| "name": "Nutmeg", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "8008-56-8", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement." |
| ], |
| "measured_coefficient": 5, |
| "measured_names": [ |
| "Lemon" |
| ], |
| "measured_tier": "top", |
| "name": "Lemon", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "8014-09-3", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement." |
| ], |
| "measured_coefficient": 100, |
| "measured_names": [ |
| "Patchouli" |
| ], |
| "measured_tier": "base", |
| "name": "Patchouli", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "8014-17-3", |
| "cause": "form-mismatch", |
| "evidence": [ |
| "Per-wild-case audit found source names comparing natural/geographic/material forms rather than one clean material form.", |
| "measured extraction records a coefficient conflict, but the per-case audit classification above is retained." |
| ], |
| "measured_coefficient": 8, |
| "measured_names": [ |
| "Petitgrain para", |
| "Petitgrain, French" |
| ], |
| "measured_tier": "top", |
| "name": "Petitgrain, French", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "8014-19-5", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement." |
| ], |
| "measured_coefficient": 14, |
| "measured_names": [ |
| "Palmarosa" |
| ], |
| "measured_tier": "top", |
| "name": "Palmarosa", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "8015-73-4", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 14, |
| "measured_names": [ |
| "Basilic" |
| ], |
| "measured_tier": "top", |
| "name": "Basilic", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "8016-96-4", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement." |
| ], |
| "measured_coefficient": 100, |
| "measured_names": [ |
| "Vetivert" |
| ], |
| "measured_tier": "base", |
| "name": "Vetivert", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "8021-15-0", |
| "cause": "form-mismatch", |
| "evidence": [ |
| "Per-wild-case audit found source names comparing natural/geographic/material forms rather than one clean material form.", |
| "measured extraction records a coefficient conflict, but the per-case audit classification above is retained." |
| ], |
| "measured_coefficient": 52, |
| "measured_names": [ |
| "Opoponax oil", |
| "Opoponax resin" |
| ], |
| "measured_tier": "mid", |
| "name": "Opoponax oil", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "8022-62-6", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement." |
| ], |
| "measured_coefficient": 14, |
| "measured_names": [ |
| "Reseda absolute" |
| ], |
| "measured_tier": "top", |
| "name": "Reseda absolute", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "8023-87-6", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement." |
| ], |
| "measured_coefficient": 14, |
| "measured_names": [ |
| "Mimosa absolute" |
| ], |
| "measured_tier": "top", |
| "name": "Mimosa absolute", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "8023-91-4", |
| "cause": "form-mismatch", |
| "evidence": [ |
| "Per-wild-case audit found source names comparing natural/geographic/material forms rather than one clean material form.", |
| "measured extraction records a coefficient conflict, but the per-case audit classification above is retained." |
| ], |
| "measured_coefficient": 52, |
| "measured_names": [ |
| "Galbanum oil", |
| "Galbanum resin" |
| ], |
| "measured_tier": "mid", |
| "name": "Galbanum resin", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "9000-50-6", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement." |
| ], |
| "measured_coefficient": 100, |
| "measured_names": [ |
| "Oakmoss" |
| ], |
| "measured_tier": "base", |
| "name": "Oakmoss", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "91-64-5", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 100, |
| "measured_names": [ |
| "Coumarin" |
| ], |
| "measured_tier": "base", |
| "name": "Coumarin", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "mid" |
| }, |
| { |
| "cas": "91771-61-8", |
| "cause": "form-mismatch", |
| "evidence": [ |
| "Per-wild-case audit found source names comparing natural/geographic/material forms rather than one clean material form." |
| ], |
| "measured_coefficient": 18, |
| "measured_names": [ |
| "Citronella, Java" |
| ], |
| "measured_tier": "mid", |
| "name": "Citronella, Java", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "94-48-4", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 4, |
| "measured_names": [ |
| "Geranyl benzoate" |
| ], |
| "measured_tier": "top", |
| "name": "Geranyl benzoate", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "94-59-7", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "Natural/complex wording is present, but the per-case audit did not find enough evidence to override source-level disagreement." |
| ], |
| "measured_coefficient": 3, |
| "measured_names": [ |
| "Sassafras" |
| ], |
| "measured_tier": "top", |
| "name": "Sassafras", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| }, |
| { |
| "cas": "98-86-2", |
| "cause": "genuine-source-disagreement", |
| "evidence": [ |
| "CAS is present on both sides; no local synonym evidence shows a different identity. Conflict is between measured duration coefficient and Poucher profile top/mid/base role tier." |
| ], |
| "measured_coefficient": 1, |
| "measured_names": [ |
| "Acetophenone" |
| ], |
| "measured_tier": "top", |
| "name": "Acetophenone", |
| "policy": "identity/form audit only; no odour character inferred", |
| "poucher_tier": "base" |
| } |
| ], |
| "wild_cause_counts": { |
| "form-mismatch": 6, |
| "genuine-source-disagreement": 43, |
| "join-error": 5, |
| "unresolved-needs-manual-review": 3 |
| } |
| } |
|
|
