task
stringclasses
5 values
input
stringlengths
89
339
canonicalization
### Instruction: Canonicalize the following SMILES string. C(C(N1C[C@H](c2ccccc2)OCC1)=O)CC(=O)N1CCOCC1 ### Response: O=C(CCC(=O)N1CCO[C@@H](c2ccccc2)C1)N1CCOCC1
functional_group
### Instruction: Does the molecule contain a aromatic_ring group? FC(F)COc1ccc(CN2CC[NH+](C[C@H]3CCOC3)CC2)cc1 ### Response: Yes
canonicalization
### Instruction: Canonicalize the following SMILES string. [C@@H]([S@@](Cc1ncc(Cl)n1C)=O)(C)C(Nc1cccc(C)c1C)=O ### Response: Cc1cccc(NC(=O)[C@@H](C)[S@](=O)Cc2ncc(Cl)n2C)c1C
canonicalization
### Instruction: Canonicalize the following SMILES string. n1c(SCC(Nc2cccc(c2)Cl)=O)n[nH]c1N/N=C/c1ccc(C)cc1 ### Response: Cc1ccc(/C=N/Nc2nc(SCC(=O)Nc3cccc(Cl)c3)n[nH]2)cc1
canonicalization
### Instruction: Canonicalize the following SMILES string. C1N(CCC(C)C1)C([C@H](S(=O)(=O)c1cc(ccc1C)C)C)=O ### Response: Cc1ccc(C)c(S(=O)(=O)[C@H](C)C(=O)N2CCC(C)CC2)c1
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? O=C1N[C@H](c2cccc(Oc3ccccc3)c2)Oc2ccccc21 ### Response: 0
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [4*]CC1CC1 Fragment 2: [1*]C(=O)c1ccccc1 ### Response: O=C(NC1CCN(C(=O)N[C@@H]2CC[NH+](CC3CC3)C2)CC1)c1ccccc1
ring_counting
### Instruction: Count the six-membered rings in the following molecule. CCn1nc(C(C)C)cc1C(=O)N1CCC[C@H](OCc2ccccn2)C1 ### Response: 2
canonicalization
### Instruction: Canonicalize the following SMILES string. CC(C)(NC([C@H](NC(NCCc1ccc(cc1)CC)=O)C)=O)C ### Response: CCc1ccc(CCNC(=O)N[C@H](C)C(=O)NC(C)(C)C)cc1
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [1*]C(=O)c1csc([14*])n1 Fragment 2: [14*]c1cc2ccccc2n1C ### Response: CSc1ccccc1NC(=O)c1csc(-c2cc3ccccc3n2C)n1
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? Nc1nnc(SCC(=O)Nc2ccccc2NC(=O)c2ccc(C(F)(F)F)cc2)s1 ### Response: 2
functional_group
### Instruction: Does the molecule contain a sulfonyl group? CCN(C(=O)C[NH2+][C@](C)(CO)C1CCCCC1)[C@@H]1CCS(=O)(=O)C1 ### Response: Yes
ring_counting
### Instruction: Count the five-membered rings in the following molecule. COC(=O)[C@@H]1CN(C(=O)c2cnns2)C[C@H]1C ### Response: 2
canonicalization
### Instruction: Canonicalize the following SMILES string. c1c(ccc(c1OC(=O)c1c(C)ccc(c1)S(=O)(C)=O)C)[N+](=O)[O-] ### Response: Cc1ccc([N+](=O)[O-])cc1OC(=O)c1cc(S(C)(=O)=O)ccc1C
ring_counting
### Instruction: Count the five-membered rings in the following molecule. CC[C@H]([NH2+]Cc1cn(-c2ccccc2)nn1)c1cnn(C)c1 ### Response: 2
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? Cn1nccc1C(=O)N1CCC(c2nnc(C[NH+](C)C)n2C2CC2)CC1 ### Response: 1
ring_counting
### Instruction: Count the five-membered rings in the following molecule. Cc1nc(SCC(=O)N(C)Cc2cnn(Cc3ccccc3)c2)c2c(C)c(C)sc2n1 ### Response: 2
ring_counting
### Instruction: Count the five-membered rings in the following molecule. CCCOc1ccc(N2CC[C@H](CO)C2)cc1 ### Response: 1
functional_group
### Instruction: Does the molecule contain a ketone group? Cc1ccccc1CCNC(=O)[C@@H](C)NC(=O)C1CCCC1 ### Response: No
functional_group
### Instruction: Does the molecule contain a ether group? Cc1nc(-c2ccc(Cl)cc2)sc1C(=O)NC1=C[C@@H]2N=CC=C2C=C1 ### Response: No
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? CC(C)c1nnc(NC(=O)c2cc(S(=O)(=O)N(C)C)ccc2N2CCOCC2)s1 ### Response: 3
functional_group
### Instruction: Does the molecule contain a ether group? CN(C[C@H]1CC[NH+](C)C1)C(=O)CCl ### Response: No
ring_counting
### Instruction: Count the five-membered rings in the following molecule. Cc1cccc(NC(=O)N[C@@H]2COc3ccccc3C2)c1C ### Response: 0
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? COCc1nc(C)c(C(=O)N[C@H]2CCCc3ccc(F)cc32)s1 ### Response: 1
functional_group
### Instruction: Does the molecule contain a ether group? CCc1cc(OCc2cccc(C)n2)c(C(=O)[O-])s1 ### Response: Yes
ring_counting
### Instruction: Count the six-membered rings in the following molecule. CC(=O)N1CCCN(C(=O)NCCCc2nc3ccccc3s2)CC1 ### Response: 1
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? CC(C)(C)OC(=O)N1CC[C@H](c2nc(Cc3ccc(F)cc3)no2)C1 ### Response: 3
ring_counting
### Instruction: Count the five-membered rings in the following molecule. CC[C@@H]1CO[C@H](C)CN1[C@H](C[NH3+])CC(=O)NC(C)C ### Response: 0
functional_group
### Instruction: Does the molecule contain a ketone group? Cc1cccc([C@H](O)C[C@@H]2CCCCC[NH2+]2)c1 ### Response: No
canonicalization
### Instruction: Canonicalize the following SMILES string. c1n(C)nc(c1CCC(NCC1CCN(c2cc[nH+]cc2)CC1)=O)C ### Response: Cc1nn(C)cc1CCC(=O)NCC1CCN(c2cc[nH+]cc2)CC1
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [6*]C(=O)N/N=C/c1cc(Br)ccc1O Fragment 2: [3*]OCC ### Response: CCOc1ccc(C2=C[C@H](C(=O)N/N=C/c3cc(Br)ccc3O)N=N2)cc1OC
ring_counting
### Instruction: Count the six-membered rings in the following molecule. COc1cc(NC(=O)[C@H](C)Sc2ccccc2Cl)cc(OC)c1 ### Response: 2
functional_group
### Instruction: Does the molecule contain a aldehyde group? O=C(CCSc1ccccn1)Nc1ccc(OC(F)F)c(Cl)c1 ### Response: No
canonicalization
### Instruction: Canonicalize the following SMILES string. C1CNC([C@H]1NC(=O)c1nc(oc1)COc1cc2nc(sc2cc1)C)=O ### Response: Cc1nc2cc(OCc3nc(C(=O)N[C@H]4CCNC4=O)co3)ccc2s1
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? O=C(NC[C@@H]1Cc2ccccc21)Nc1ccc2c(c1)COC2 ### Response: 1
canonicalization
### Instruction: Canonicalize the following SMILES string. CC(OC(=O)[C@@H]1[NH+](C(C)C)CCC1)C ### Response: CC(C)OC(=O)[C@H]1CCC[NH+]1C(C)C
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? CN(C(=O)Nc1ccc([N+](=O)[O-])c(Cl)c1)[C@H]1CCCc2c1cnn2C ### Response: 1
canonicalization
### Instruction: Canonicalize the following SMILES string. C1CN(S(=O)(c2ccc(F)cc2)=O)CCN1Cc1oc2cc(Cl)ccc2n1 ### Response: O=S(=O)(c1ccc(F)cc1)N1CCN(Cc2nc3ccc(Cl)cc3o2)CC1
functional_group
### Instruction: Does the molecule contain a amide group? COc1ccc(CC/N=C/[C@H]2C(=O)N(c3nc4ccccc4s3)N=C2C(F)(F)F)cc1 ### Response: Yes
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? CC1(C)CN(c2ccc(CC#N)cc2)C1=O ### Response: 2
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? O=C(COc1ccccc1)NC[C@@H]1Cc2cc(-c3cnccn3)ccc2O1 ### Response: 2
functional_group
### Instruction: Does the molecule contain a ketone group? CCCOc1cccc(C(=O)C2=C([O-])C(=O)N(c3nc4ccc(C)cc4s3)[C@@H]2c2ccncc2)c1 ### Response: Yes
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? O=S(=O)(N[C@@H]1CCCOc2ccc(F)cc21)c1ccc2c(c1)OCCCO2 ### Response: 0
functional_group
### Instruction: Does the molecule contain a aromatic_ring group? Cc1cccc(/C=C(\C[NH2+]C(C)C)C(C)C)c1 ### Response: Yes
functional_group
### Instruction: Does the molecule contain a ether group? Nc1ccc(Oc2cncnc2)nc1 ### Response: Yes
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [16*]c1ccccc1C Fragment 2: [5*]N1CCC[C@H]1[13*] ### Response: Cc1ccccc1[C@@H]1CCCN1C(=O)c1cc(C#N)cs1
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? C[C@H]1CC[C@@H](CO)C[NH+]1Cc1ccn(Cc2ccccc2)c1 ### Response: 1
functional_group
### Instruction: Does the molecule contain a aldehyde group? CCn1c(N2CCC[C@@H](C(=O)NC3CCCC3)C2)[nH+]c2ccccc21 ### Response: No
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [4*]Cc1ccccc1 Fragment 2: [1*]C(=O)C[4*] ### Response: O=C(CSc1nc(-c2ccc(Cl)cc2)n[nH]1)N1CCN(Cc2ccccc2)CC1
functional_group
### Instruction: Does the molecule contain a hydroxyl group? CS[C@H]1CC[C@H](NC(=O)c2ccc(N3CCNC3=O)cc2)C1 ### Response: No
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? COc1ccc(CN2CCO[C@H]3CC[C@@H](OC)C[C@@H]32)cc1SC ### Response: 1
ring_counting
### Instruction: Count the six-membered rings in the following molecule. Cc1nc(C)c([C@H](C)[NH+](C)Cc2cc3c(cc2O)OCO3)s1 ### Response: 1
canonicalization
### Instruction: Canonicalize the following SMILES string. C1CN(C(=O)O1)c1ccc([C@H](N[C@@H]2C(=O)N(C3CCCCC3)CC2)C)cc1 ### Response: C[C@@H](N[C@H]1CCN(C2CCCCC2)C1=O)c1ccc(N2CCOC2=O)cc1
functional_group
### Instruction: Does the molecule contain a aromatic_ring group? O=C(COc1ccc2ccccc2c1)Nc1ccc(SC(F)F)cc1 ### Response: Yes
canonicalization
### Instruction: Canonicalize the following SMILES string. c12ccccc2=[NH+]C(SCc2ccccn2)[NH+]=1 ### Response: c1ccc(CSC2[NH+]=c3ccccc3=[NH+]2)nc1
functional_group
### Instruction: Does the molecule contain a ester group? O=C(COc1ccc(Cl)c(Cl)c1)N1CCN(c2ccc(F)cc2)CC1 ### Response: No
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [8*]C[C@H]1C(=O)N2CCC[C@@H]2c2nc([14*])nn21 Fragment 2: [16*]c1ccccc1 ### Response: O=C1[C@H](Cc2nc3ccccc3o2)n2nc(-c3ccccc3)nc2[C@H]2CCCN12
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [15*][C@@H]1CC[C@@H](C[NH3+])[C@H]([15*])C1 Fragment 2: [11*]Sc1ccncc1 ### Response: CCC(C)(C)[C@@H]1CC[C@@H](C[NH3+])[C@H](Sc2ccncc2)C1
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [16*]c1cc(C)c(C)cc1C=O Fragment 2: [3*]OS(=O)(=O)c1c[nH]c2nccc(Cl)c12 ### Response: Cc1cc(C=O)c(OS(=O)(=O)c2c[nH]c3nccc(Cl)c23)cc1C
ring_counting
### Instruction: Count the five-membered rings in the following molecule. CCOc1ccccc1NC(=O)c1c(Cl)cnn1C ### Response: 1
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [5*]NC[C@@H]1COC2(CCCCC2)O1 Fragment 2: [3*]OCC ### Response: CCOc1ccc(CC(=O)NC[C@@H]2COC3(CCCCC3)O2)cc1
canonicalization
### Instruction: Canonicalize the following SMILES string. N1(CC[NH+](CC1)CC(NC1[C@H]([NH+]=c2cc(C)ccc=12)C(OC)=O)=O)c1c(cccc1)F ### Response: COC(=O)[C@H]1[NH+]=c2cc(C)ccc2=C1NC(=O)C[NH+]1CCN(c2ccccc2F)CC1
functional_group
### Instruction: Does the molecule contain a thiol group? C[C@H]1CN(S(=O)(=O)c2ccc(C(=O)N(Cc3c(F)cccc3F)C3CCCC3)cc2)C[C@H](C)O1 ### Response: No
functional_group
### Instruction: Does the molecule contain a amide group? Cc1ccc(NC(=O)Cn2nc3ccc(SC(C)(C)C)nn3c2=O)cc1C ### Response: Yes
functional_group
### Instruction: Does the molecule contain a aromatic_ring group? C[NH+](C)CC(C)(C)CN1CCN(c2nc(-c3ccccc3)no2)CC1 ### Response: Yes
canonicalization
### Instruction: Canonicalize the following SMILES string. C(C[C@H](C)C[NH2+]Cc1ncc(-c2ccccc2)s1)O ### Response: C[C@@H](CCO)C[NH2+]Cc1ncc(-c2ccccc2)s1
canonicalization
### Instruction: Canonicalize the following SMILES string. C(NC(C(Nc1c(cc(F)cc1)Cl)=O)=O)CC ### Response: CCCNC(=O)C(=O)Nc1ccc(F)cc1Cl
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? O=Cc1cc2c(Cl)cncc2s1 ### Response: 1
ring_counting
### Instruction: Count the five-membered rings in the following molecule. O=C(Cc1cccc2cccnc12)N(C1CC1)[C@H]1CCS(=O)(=O)C1 ### Response: 1
functional_group
### Instruction: Does the molecule contain a aromatic_ring group? C[C@H]1CCN(C(=O)NC2CC[NH+](CCc3ccncc3)CC2)C[C@H]1O ### Response: No
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [14*]c1nc(C)c([14*])s1 Fragment 2: [4*]CCC[8*] ### Response: Cc1nnc(CCC[NH+](C)[C@H](C)c2sc(C(C)C)nc2C)o1
canonicalization
### Instruction: Canonicalize the following SMILES string. c1(c(OC)ccc(S(=O)(N(C)C)=O)c1)NC(c1c(c(Cl)c(Cl)cn1)Cl)=O ### Response: COc1ccc(S(=O)(=O)N(C)C)cc1NC(=O)c1ncc(Cl)c(Cl)c1Cl
ring_counting
### Instruction: Count the six-membered rings in the following molecule. CCNC(=O)c1ccc(C)c(NC(=O)[C@H]2COc3cc(OC)ccc3C2)c1 ### Response: 3
ring_counting
### Instruction: Count the six-membered rings in the following molecule. Cc1ccc([C@H](C)N(C)C(=O)[C@H](C)c2ccsc2)cc1 ### Response: 1
functional_group
### Instruction: Does the molecule contain a amide group? C[C@H](c1ccc(NC(=O)c2c(O)cccc2O)cc1)N1CCOCC1 ### Response: Yes
functional_group
### Instruction: Does the molecule contain a halide group? CC[NH+](C)Cc1cccc(CNC(=O)NC2CC[NH+](C3CC3)CC2)c1 ### Response: No
ring_counting
### Instruction: Count the five-membered rings in the following molecule. Cc1cc(C)c([N+](=O)[O-])c(C)c1C(=O)Nc1cnn(C[C@H]2CCCO2)c1 ### Response: 2
ring_counting
### Instruction: Count the six-membered rings in the following molecule. CC(C)C[NH2+]C[C@@]1(C[NH+]2CCC(C)(C)C2)CCCOC1 ### Response: 1
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? Cc1ccc2c(c1)NC(=O)c1cccnc1N2 ### Response: 1
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [5*]N(C)[C@H]1CCCc2ccccc21 Fragment 2: [16*]c1ccccc1F ### Response: CN(C(=O)CSc1nnc(-c2ccccc2F)n1C)[C@H]1CCCc2ccccc21
functional_group
### Instruction: Does the molecule contain a aromatic_ring group? C[C@@H]1C(=O)NCC(=O)N1C[C@@H]1CN(C)CCO1 ### Response: No
canonicalization
### Instruction: Canonicalize the following SMILES string. c1cc(ccc1NS(c1ccc(cc1)OC)(=O)=O)-c1c[nH+]c2CCCn21 ### Response: COc1ccc(S(=O)(=O)Nc2ccc(-c3c[nH+]c4n3CCC4)cc2)cc1
ring_counting
### Instruction: Count the five-membered rings in the following molecule. CCOC(=O)[C@H]1CCCN(C(=O)c2ccco2)C1 ### Response: 1
canonicalization
### Instruction: Canonicalize the following SMILES string. c1ccc(-c2csc(n2)NC(=O)[C@H](CS(=O)(C)=O)C)c(F)c1 ### Response: C[C@@H](CS(C)(=O)=O)C(=O)Nc1nc(-c2ccccc2F)cs1
functional_group
### Instruction: Does the molecule contain a sulfonyl group? Cc1noc2nc(-c3ccccc3F)cc(C(=O)N(C)[C@@H](C)c3cccs3)c12 ### Response: No
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [4*][C@@H]([8*])CC(=O)OC Fragment 2: [16*]c1ccccc1 ### Response: CCn1nc(C)c(NC(=O)N[C@H](CC(=O)OC)c2ccccc2)c1C
functional_group
### Instruction: Does the molecule contain a sulfonyl group? Cc1ccc(CCCCC(=O)Nc2cn(C)c(=O)cc2C)cc1 ### Response: No
canonicalization
### Instruction: Canonicalize the following SMILES string. N1(C(=O)/C(=C/c2c([N+](=O)[O-])cccc2)C#N)CCCC1 ### Response: N#C/C(=C\c1ccccc1[N+](=O)[O-])C(=O)N1CCCC1
functional_group
### Instruction: Does the molecule contain a ether group? COc1ncc(CNc2ccc(-n3ccnc3C)cc2)cn1 ### Response: Yes
functional_group
### Instruction: Does the molecule contain a ether group? COCCNc1ncccc1-c1nc(-c2ccc(OC)cc2)no1 ### Response: Yes
canonicalization
### Instruction: Canonicalize the following SMILES string. C([C@H](c1noc([C@@H]2CCCN(C2)C(C2CCCC2)=O)n1)C)C ### Response: CC[C@@H](C)c1noc([C@@H]2CCCN(C(=O)C3CCCC3)C2)n1
ring_counting
### Instruction: Count the six-membered rings in the following molecule. Cc1ccc(C(=O)C(=O)Nc2cncc(-c3nnc([S-])n3C)c2)cc1 ### Response: 2
canonicalization
### Instruction: Canonicalize the following SMILES string. C(O[C@H](C)C(Nc1c(n(ccc1)Cc1ccccc1)=O)=O)C ### Response: CCO[C@H](C)C(=O)Nc1cccn(Cc2ccccc2)c1=O
ring_counting
### Instruction: Count the five-membered rings in the following molecule. C[C@H](CCN1CCOCC1)[NH2+][C@H]1CCc2cc(Br)ccc2C1 ### Response: 0
ring_counting
### Instruction: Count the six-membered rings in the following molecule. CC[C@@H]([NH2+]Cc1cccc(NC(=O)[C@@H]2CCCO2)c1)c1cccs1 ### Response: 1
canonicalization
### Instruction: Canonicalize the following SMILES string. C(C(N(C)C)=O)Sc1scc(-c2ccc(C)cc2)n1 ### Response: Cc1ccc(-c2csc(SCC(=O)N(C)C)n2)cc1
canonicalization
### Instruction: Canonicalize the following SMILES string. n1(C(C)(C)C)c2c([nH]/c1=N\C(c1onc(C)c1)=O)cccc2 ### Response: Cc1cc(C(=O)/N=c2\[nH]c3ccccc3n2C(C)(C)C)on1
ring_counting
### Instruction: Count the five-membered rings in the following molecule. Cc1noc(CN2CCOC[C@@H]2C2CC2)n1 ### Response: 1
ring_counting
### Instruction: Count the five-membered rings in the following molecule. O=C(c1ccc(=O)n(-c2ccccc2)n1)N1C[C@H]2CCC[C@@H]2C1 ### Response: 2
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [5*]N1C[C@@H]([15*])CC[C@@H]1C Fragment 2: [6*]C(N)=O ### Response: C[C@H]1CC[C@H](C(N)=O)CN1C(=O)/C=C/c1ccc(Br)o1