task
stringclasses
5 values
input
stringlengths
89
339
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [14*]c1ncnc(S(=O)(=O)CC)c1N Fragment 2: [3*]OCC ### Response: CCOc1ncnc(S(=O)(=O)CC)c1N
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [5*]Nc1cn(C)c(=O)cc1C Fragment 2: [1*]C(=O)CS[11*] ### Response: Cc1cccc(NC(=O)CSCC(=O)Nc2cn(C)c(=O)cc2C)c1
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? Cc1cccnc1NC(=S)NC(=O)c1oc2ccccc2c1C ### Response: 1
ring_counting
### Instruction: Count the five-membered rings in the following molecule. C[C@H]([C@@H](C)c1ccc(Cl)cc1)N(C)C(=O)c1cc(C2CC2)[nH]n1 ### Response: 1
ring_counting
### Instruction: Count the six-membered rings in the following molecule. CC(C)CNC(=O)NCc1c(-n2cccc2)sc2c1CC[NH+](C)C2 ### Response: 1
functional_group
### Instruction: Does the molecule contain a amide group? O=C(Nc1ccc(F)cc1)N[C@H]1CCN(Cc2cnc(Cl)s2)C1 ### Response: Yes
canonicalization
### Instruction: Canonicalize the following SMILES string. C1CN(C[C@@H]([C@H](c2cccs2)[NH2+]CC)O1)C ### Response: CC[NH2+][C@@H](c1cccs1)[C@@H]1CN(C)CCO1
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? C[C@H]1CCCC[C@H]1NC(=O)[C@]1(C)Cn2c(cc3sccc32)C(=O)N1Cc1cccs1 ### Response: 1
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [9*]n1cc[nH+]c1CO Fragment 2: [8*]CCC(C)(C)O ### Response: CC(C)(O)CCn1cc[nH+]c1CO
ring_counting
### Instruction: Count the six-membered rings in the following molecule. Cc1nn(CC(C)C)c(C)c1CCC(=O)N(C)C[C@H]1COc2ccccc2O1 ### Response: 2
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? CC(=O)N1CCN(C(=O)[C@H](C)Cc2ccccc2)CC1 ### Response: 3
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? CO[C@@H]1CCCC[C@H]1NC(=O)N(C)CCN1CCN(c2ccccc2)CC1 ### Response: 2
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? NC(=O)CCN(C(=O)C1CCC1)c1ccc(F)cc1 ### Response: 3
canonicalization
### Instruction: Canonicalize the following SMILES string. COc1cc(cc(OC)c1)NC(=O)c1c2c(C)noc2nc(c1)-c1ccc(C)cc1 ### Response: COc1cc(NC(=O)c2cc(-c3ccc(C)cc3)nc3onc(C)c23)cc(OC)c1
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? Cc1ccc([C@]2(C)NC(=O)N(CC(=O)N(c3ccccc3)C(C)C)C2=O)cc1 ### Response: 3
functional_group
### Instruction: Does the molecule contain a ether group? C[C@H](CNC(=O)N[C@H]1C[C@@H]1C)N1CCc2ccccc21 ### Response: No
functional_group
### Instruction: Does the molecule contain a ether group? C[C@@H]1CN(C(=O)[C@@H](C)NC(=O)c2cccs2)C[C@H](C)O1 ### Response: Yes
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [14*]c1ccc(Br)o1 Fragment 2: [16*]c1ccc(F)c(F)c1 ### Response: [NH3+][C@H](Cc1ccc(F)c(F)c1)c1ccc(Br)o1
ring_counting
### Instruction: Count the six-membered rings in the following molecule. O=C(Nc1ccc(F)cc1OCC(F)F)NC1CCCC1 ### Response: 1
functional_group
### Instruction: Does the molecule contain a amide group? COCCn1nc(C)c(NC(=O)N2CCC[C@H]2c2cccc(C)c2)c1C ### Response: Yes
functional_group
### Instruction: Does the molecule contain a amine group? Cc1cc(C)cc(CNc2ccc(-n3ncn(C)c3=O)cc2)c1 ### Response: Yes
ring_counting
### Instruction: Count the six-membered rings in the following molecule. CC[NH+]1CCC[C@@H]1CNC(=O)N1CCC[C@H]([NH+](C)C)C1 ### Response: 1
ring_counting
### Instruction: Count the five-membered rings in the following molecule. O=C(NC[C@H](c1ccco1)N1CCc2ccccc2C1)Nc1ccc(F)cc1 ### Response: 1
ring_counting
### Instruction: Count the six-membered rings in the following molecule. Cc1ccc(-c2noc([C@H]3[C@H]4C[C@H]5[C@@H]3C(=O)O[C@H]5C4)n2)cc1S(=O)(=O)N1CCOCC1 ### Response: 2
canonicalization
### Instruction: Canonicalize the following SMILES string. C(N1CCN(C(c2cocc2)=O)CC1)c1ccc(-c2ccccc2)s1 ### Response: O=C(c1ccoc1)N1CCN(Cc2ccc(-c3ccccc3)s2)CC1
functional_group
### Instruction: Does the molecule contain a halide group? Cc1c(Cl)ccc2c1NC(=O)[C@@]21[C@@H]2C(=O)N(c3ccc(F)cc3)C(=O)[C@@H]2[C@@H]2CCC[NH+]21 ### Response: Yes
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? CC[NH+]1CCC(CNc2nc3ccc(C)cn3n2)CC1 ### Response: 2
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [6*]C(N)=O Fragment 2: [5*]Nc1sc(C)c(CC)c1[16*] ### Response: CCc1c(C)sc(NC(=O)c2cc(S(N)(=O)=O)c(Cl)cc2Cl)c1C(N)=O
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [5*]Nc1ncnn1C Fragment 2: [1*]C(=O)N[5*] ### Response: Cn1ncnc1NC(=O)NCCCC[NH+]1CCCC1
functional_group
### Instruction: Does the molecule contain a amide group? COc1cccc(C(=O)Nc2ccc3c(c2)CN(Cc2cccc(OC)c2OC)C(=O)[C@H](C)O3)c1 ### Response: Yes
functional_group
### Instruction: Does the molecule contain a amine group? CCOc1cccc2c1CC[C@H]2NC(=O)NCCC(F)(F)F ### Response: No
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [1*]C(=O)[C@H]1CC(=O)N([10*])C1 Fragment 2: [8*]C(C)C ### Response: CC(C)N1C[C@@H](C(=O)N2C[C@@H](O)[C@@H](O)C2)CC1=O
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [16*]c1ccc(C)nc1 Fragment 2: [1*]C(=O)C[8*] ### Response: Cc1ccc(OCC#CCNC(=O)Cc2c[nH]c3ccccc23)cn1
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? Cc1cccnc1C(=O)Nc1c(C#N)cnn1C ### Response: 1
functional_group
### Instruction: Does the molecule contain a ester group? Cc1ccc(-c2csc(NC(=O)CCSc3cc(C)ncn3)n2)cc1 ### Response: No
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? CC[NH2+]CC1=NC(=O)C2(CC2)C([O-])=N1 ### Response: 2
ring_counting
### Instruction: Count the five-membered rings in the following molecule. CC[C@@H](C)N(CC)C(=O)C[C@H]([NH3+])c1ccccc1 ### Response: 0
ring_counting
### Instruction: Count the six-membered rings in the following molecule. Cc1cc(C)c(NC(=O)C(=O)NC[C@H](O)C2CCOCC2)c(C)c1 ### Response: 2
functional_group
### Instruction: Does the molecule contain a sulfonyl group? Cc1cc(C)c(S(=O)(=O)NCC#CCOc2cccnc2)c(C)c1 ### Response: Yes
ring_counting
### Instruction: Count the five-membered rings in the following molecule. C[C@H]1CC(C(=O)NNc2ncnc3[nH]cnc23)C[C@H](C)O1 ### Response: 1
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? COC[C@H](C)NC(=O)[C@@H](C)NC(=O)c1ccc(C(C)(C)C)cc1 ### Response: 3
functional_group
### Instruction: Does the molecule contain a phenol group? Cc1nc(C)c(C(=O)N(C)Cc2ccc(F)c(F)c2)o1 ### Response: No
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? CC[C@@H](CSC)N(C)C(=O)NC1CCC(OC(C)C)CC1 ### Response: 4
canonicalization
### Instruction: Canonicalize the following SMILES string. OCC[C@H](CNc1nn2c(ccc(C)c2)n1)CC ### Response: CC[C@H](CCO)CNc1nc2ccc(C)cn2n1
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [1*]C(=O)[C@H]1CC(=O)N([10*])C1 Fragment 2: [5*]NCC1CCN([5*])CC1 ### Response: COC(=O)N1CCC(CNC(=O)[C@H]2CC(=O)N(c3ccc(C)c(C)c3)C2)CC1
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [5*]N1CCC([15*])CC1 Fragment 2: [1*]C(=O)C([1*])=O ### Response: O=C(NCCC1CCN(c2cc[nH+]cc2)CC1)C(=O)Nc1cccc(F)c1
canonicalization
### Instruction: Canonicalize the following SMILES string. CN(C)c1sc2cc3c(c(C)c(C(=O)OCC)o3)cc2n1 ### Response: CCOC(=O)c1oc2cc3sc(N(C)C)nc3cc2c1C
canonicalization
### Instruction: Canonicalize the following SMILES string. c1c(c(ccc1)O)CCC(=O)NCCc1nnc(o1)-c1ccccc1 ### Response: O=C(CCc1ccccc1O)NCCc1nnc(-c2ccccc2)o1
functional_group
### Instruction: Does the molecule contain a sulfonyl group? CC[NH+]1CC[C@H](N(C)CC(=O)N(C(C)C)C(C)C)[C@H](C)C1 ### Response: No
canonicalization
### Instruction: Canonicalize the following SMILES string. c1c2C(N(Cc3ccco3)[C@@H](c3cc(ccc3)Br)Nc2ccc1)=O ### Response: O=C1c2ccccc2N[C@H](c2cccc(Br)c2)N1Cc1ccco1
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [5*]NC(C)C Fragment 2: [1*]C(=O)c1cccc(S(=O)(=O)[C@@H]2CCS(=O)(=O)C2)c1 ### Response: CC(C)NC(=O)c1cccc(S(=O)(=O)[C@@H]2CCS(=O)(=O)C2)c1
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [5*]Nc1cccc([16*])c1 Fragment 2: [5*]NS(=O)(=O)C[8*] ### Response: CC[C@@H](C)NS(=O)(=O)Cc1cccc(NC(=O)[C@H]2CCOC2)c1
ring_counting
### Instruction: Count the six-membered rings in the following molecule. CCCOc1ccc([C@H]2c3c(oc4ccc(C)cc4c3=O)C(=O)N2c2ncccn2)cc1OCC ### Response: 4
ring_counting
### Instruction: Count the six-membered rings in the following molecule. O=C(CCc1nc(-c2ccc(Cl)cc2)no1)OC[C@H]1CCCO1 ### Response: 1
functional_group
### Instruction: Does the molecule contain a phenol group? Nc1c(C(=O)Nc2ccc(Cl)cc2)c2ccccc2n1C(=O)c1ccc(F)cc1 ### Response: No
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? COc1cc(C(=S)N2CCCC2)cc(Cl)c1O ### Response: 1
functional_group
### Instruction: Does the molecule contain a aromatic_ring group? O=C(NCc1cccs1)C1(c2cccc(Cl)c2)CCC1 ### Response: Yes
ring_counting
### Instruction: Count the five-membered rings in the following molecule. O=c1[nH]c(CSc2nncs2)nc2ccc(Cl)cc12 ### Response: 1
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [1*]C(=O)[C@H]1C=C(C[8*])N=N1 Fragment 2: [5*]N1CCCC[C@@H]1[13*] ### Response: CC(C)c1nccn1CC1=C[C@H](C(=O)N2CCCC[C@@H]2c2cccnc2)N=N1
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [16*]c1cc(/N=C\c2cc([N+](=O)[O-])ccc2[O-])c(C)cc1O Fragment 2: [8*]C(C)C ### Response: Cc1cc(O)c(C(C)C)cc1/N=C\c1cc([N+](=O)[O-])ccc1[O-]
functional_group
### Instruction: Does the molecule contain a thiol group? CC(C)[C@@H]1C[C@@](c2ccccc2)([C@@H](C[NH3+])CO)CCO1 ### Response: No
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? Cc1ccc2[nH]c(C(=O)[O-])c(NC(=O)[C@H]3C[C@H]3c3ccccc3)c2c1 ### Response: 1
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? Cc1ccncc1NC(=O)N[C@@H]1C[C@@H]1C1CCCCC1 ### Response: 1
ring_counting
### Instruction: Count the five-membered rings in the following molecule. CC[C@H]1CCC[C@H]([C@H](O)[C@@](C)(CC)[NH+]2CCCCC2)C1 ### Response: 0
functional_group
### Instruction: Does the molecule contain a ether group? COc1ccccc1NC(=O)CSc1nnc(C)c(=O)n1N ### Response: Yes
functional_group
### Instruction: Does the molecule contain a ester group? CCn1c(SCC(=O)N2CCCC[C@@H]2C)nnc1-c1ccncc1 ### Response: No
ring_counting
### Instruction: Count the six-membered rings in the following molecule. O=C(CC[C@@H]1CCC[NH+](Cc2cccc3cccnc23)C1)N1CCCC1 ### Response: 3
functional_group
### Instruction: Does the molecule contain a nitrile group? Cc1ccccc1CC[NH+]1CCC[C@@H](C[NH3+])C1 ### Response: No
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [1*]C(=O)N1CCOCC1 Fragment 2: [1*]C(=O)[C@@H]([8*])CC ### Response: CC[C@@H](C(=O)N1CCN(C(=O)N2CCOCC2)CC1)n1cccn1
canonicalization
### Instruction: Canonicalize the following SMILES string. c1ccc(cc1C(C)(C)C(=O)NC[C@@](O)(C)c1ccc(cc1)F)Cl ### Response: CC(C)(C(=O)NC[C@](C)(O)c1ccc(F)cc1)c1cccc(Cl)c1
canonicalization
### Instruction: Canonicalize the following SMILES string. c1c2c(ccc1)-c1nc(=O)[nH]nc1C2=O ### Response: O=C1c2ccccc2-c2nc(=O)[nH]nc21
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [5*]N1CCN([5*])CC1 Fragment 2: [16*]c1cc(=O)oc2cc(C)c(C)cc12 ### Response: COc1ccccc1N1CCN(C(=O)Cc2cc(=O)oc3cc(C)c(C)cc23)CC1
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? OCC1(CN2CC[NH+]3CCCC[C@@H]3C2)CCCCCC1 ### Response: 1
canonicalization
### Instruction: Canonicalize the following SMILES string. c1cccc(S[C@H](C(=O)Nc2sc3c(n2)cccc3)C)c1 ### Response: C[C@H](Sc1ccccc1)C(=O)Nc1nc2ccccc2s1
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? COc1ccc(NC(=O)c2ccco2)cc1NC(=O)c1ccc(Cl)cc1Cl ### Response: 1
ring_counting
### Instruction: Count the six-membered rings in the following molecule. O=C(CCNC(=O)c1ccc(O)c(Cl)c1)Nc1ccncc1 ### Response: 2
functional_group
### Instruction: Does the molecule contain a halide group? CCC[C@@H](Cl)[C@@H](C)c1ccncc1 ### Response: Yes
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? CCCCS(=O)(=O)N1CCN(c2ncccn2)CC1 ### Response: 4
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [4*][C@H]([8*])C(C)C Fragment 2: [5*]NS(=O)(=O)c1ccc2c(c1)CCC2 ### Response: COc1ccc([C@@H](NS(=O)(=O)c2ccc3c(c2)CCC3)C(C)C)cc1
ring_counting
### Instruction: Count the five-membered rings in the following molecule. CC(C)(C)[C@@H](CS)C[NH+]1CCN(c2ccccc2Cl)CC1 ### Response: 0
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [8*]CCCC Fragment 2: [3*]O[C@H]1CCCC[C@H]1CC ### Response: CCCCn1nc(C(=O)O[C@H]2CCCC[C@H]2CC)ccc1=O
chain_length
### Instruction: What is the length of the longest acyclic carbon chain in the molecule? COc1ccccc1[C@@H](O)[C@H]1CCOC2(CCOCC2)C1 ### Response: 1
ring_counting
### Instruction: Count the five-membered rings in the following molecule. CCC[NH2+][C@H](c1ccc(OCC)cc1Br)[C@@H]1COCCO1 ### Response: 0
ring_counting
### Instruction: Count the five-membered rings in the following molecule. CC[NH2+][C@H]1CCN(c2cccnc2)[C@H](C)[C@@H]1C ### Response: 0
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [14*]c1ccccn1 Fragment 2: [9*]n1cc(C)cn1 ### Response: Cc1cnn([C@@H]2CCCN(C(=O)CCCc3ccccn3)C2)c1
functional_group
### Instruction: Does the molecule contain a carboxyl group? C[NH2+][C@@H](C)c1cc(F)ccc1OCc1ccc(Br)cc1F ### Response: No
ring_counting
### Instruction: Count the six-membered rings in the following molecule. CCc1cnc(CCNC(=O)/C=C/c2cc3ccccc3o2)s1 ### Response: 1
canonicalization
### Instruction: Canonicalize the following SMILES string. C1[C@]2(C(O[C@H](C)C2)=O)C(O[C@]1(c1nc(NCC=C)sc1)C)=O ### Response: C=CCNc1nc([C@@]2(C)C[C@@]3(C[C@@H](C)OC3=O)C(=O)O2)cs1
canonicalization
### Instruction: Canonicalize the following SMILES string. C[NH+](C)[C@@H]1CC[C@H](C1)NC(NNC(c1cn(c2c1cccc2)C)=O)=O ### Response: Cn1cc(C(=O)NNC(=O)N[C@@H]2CC[C@@H]([NH+](C)C)C2)c2ccccc21
functional_group
### Instruction: Does the molecule contain a sulfonyl group? Cc1nccn1-c1cncc(NCCCS(=O)(=O)c2ccccc2)n1 ### Response: Yes
functional_group
### Instruction: Does the molecule contain a amide group? Cc1ccc(/C=C/C(=O)NCC2CCC(C(=O)[O-])CC2)s1 ### Response: Yes
functional_group
### Instruction: Does the molecule contain a nitrile group? CCN1CCN(C(=O)[C@H]2[C@@H]3C[C@H]4[C@H](OC(=O)[C@H]42)[C@H]3Cl)CC1 ### Response: No
fragment_assembly
### Instruction: Assemble these two molecular fragments into a single molecule. Fragment 1: [5*]N1C[C@H](C)C[C@H]([NH3+])C1 Fragment 2: [12*]S(=O)(=O)c1ccc(F)c([N+](=O)[O-])c1 ### Response: C[C@@H]1C[C@H]([NH3+])CN(S(=O)(=O)c2ccc(F)c([N+](=O)[O-])c2)C1
ring_counting
### Instruction: Count the six-membered rings in the following molecule. C[C@H]([NH2+][C@@H]1CCSc2ccc(F)cc21)c1ccoc1 ### Response: 2
ring_counting
### Instruction: Count the five-membered rings in the following molecule. COc1ccc(-n2ccc(CNC(=O)c3cc(Cl)ccc3[N+](=O)[O-])n2)cc1 ### Response: 1
canonicalization
### Instruction: Canonicalize the following SMILES string. c1c(c(Cl)c[nH+]c1)NC[C@@]1(C)OCCC1 ### Response: C[C@@]1(CNc2cc[nH+]cc2Cl)CCCO1
canonicalization
### Instruction: Canonicalize the following SMILES string. c1c(c(CNC(N(C)Cc2ccc(O)cc2)=O)ccc1)C[NH+](C)C ### Response: CN(Cc1ccc(O)cc1)C(=O)NCc1ccccc1C[NH+](C)C
functional_group
### Instruction: Does the molecule contain a amine group? Cc1ccc(CSc2nnc(N/N=C/c3ccc(F)cc3)n2N)cc1 ### Response: Yes
canonicalization
### Instruction: Canonicalize the following SMILES string. c1c2c(nc(n(C)c2[O-])=S)cc(C(NC[C@H](S(N)(=O)=O)C)=O)c1 ### Response: C[C@H](CNC(=O)c1ccc2c([O-])n(C)c(=S)nc2c1)S(N)(=O)=O
functional_group
### Instruction: Does the molecule contain a halide group? C[C@@H](NC(=O)c1ccccc1F)c1nnc(SCC(=O)Nc2c(F)cccc2F)n1C ### Response: Yes