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453c5decd89ab92a719af633b6cc95a74ed8fdb1
yet other ways to make triones start from
yet other ways to make triones start from a β-dione, and oxidise the carbon at the α position, between the two ketone groups. different methods include reaction with bromine to make a dibromide, and then reacting with acetaldehyde and hydrolysing. nitrogen oxides can also be used. another way is by reacting 2,4-pentand...
wikipedia
0c06cef41c0a6abb46f646dc296c77519902ded9
2,3,4-pentanetrione can be made by oxidizing 2,4-pentanedione with
2,3,4-pentanetrione can be made by oxidizing 2,4-pentanedione with selenium dioxide. ludwig wolff made the 2,3 oxime by reacting hydroxylamine with isonitrosoacetylacetone in cold, aqueous, concentrated solution.
wikipedia
74197990cd1ce74e1907326125a126a4d973ec8a
2,3,4-pentanetrione (or iupac name pentane-2,3,4-trione, triketopentane or dimethyl
2,3,4-pentanetrione (or iupac name pentane-2,3,4-trione, triketopentane or dimethyl triketone) is the simplest linear triketone, a ketone with three c=o groups. it is an organic molecule with formula ch cocococh.
wikipedia
b38c5adb93417f3ee8b336b1ce71d5186ebf9e4a
the 1967 all-ireland under-21 football championship was the
the 1967 all-ireland under-21 football championship was the fourth staging of the all-ireland under-21 football championship since its establishment by the gaelic athletic association in 1964. roscommon entered the championship as the defending champions, however, they were defeated by mayo in the connacht final. on 8 ...
wikipedia
a520d73f11f8fb40f444e91f70a87945ed0c827d
matthew kreuzer is a retired professional australian rules
matthew kreuzer is a retired professional australian rules footballer who played for the carlton football club in the australian football league (afl). he was selected first overall pick in the 2007 afl draft. he announced his retirement in september 2020.
wikipedia
c79e276595e197b0a41e7929a4b7b4d3a21333da
in the opening round of the 2020 afl
in the opening round of the 2020 afl season against richmond, kreuzer suffered a foot injury which initially ruled him out for three to four months, but he did not play again and announced his retirement, with immediate effect, on 10 september 2020. following his retirement, kreuzer was appointed ruck coach at carlton ...
wikipedia
2e3e562ce836784f57bd7bfb612f4f8f8df0adfd
in round 13, 2010, after 56 consecutive games
in round 13, 2010, after 56 consecutive games from debut, kreuzer ruptured his anterior cruciate ligament after landing awkwardly in a marking contest. he had a conventional knee reconstruction, and missed eleven months of football, returning to vfl football in may 2011 and to carlton in round 12, 2011. he played every...
wikipedia
aaad0a540bf372fedb516907bfc8904979daebc5
kreuzer played all twenty-three games in his second
kreuzer played all twenty-three games in his second season, again sharing ruck duties and spending some time in the forward-line, again scoring thirteen goals. he finished fifth in the john nicholls medal. kreuzer continued as one of the club's top two ruckmen in 2010, and he played his 50th afl game in round 7.
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14018fa1884ede1ad27af623d87f9530bf81baeb
kreuzer made his afl debut in round 3
kreuzer made his afl debut in round 3 of the 2008 season against essendon at the mcg on 5 april 2008, impressing on debut and scoring a goal with his first kick. he played largely as the second ruckman through the early part of the season. he earned a nab rising star nomination in his ninth game (against port adelaide)...
wikipedia
da7f675a173321f4a05a8a08c0e7412fa986c1ad
noted for possessing a level of agility and
noted for possessing a level of agility and endurance unusual for a player of his size, kreuzer was widely expected to be selected early in the 2007 afl draft. he was selected by carlton with its priority draft pick (no. 1 overall) in the draft; carlton received that draft pick only after losing its final round match a...
wikipedia
fbf19336950bdaa95ff249080036e499a20b0585
kreuzer played for st mary's greensborough junior football
kreuzer played for st mary's greensborough junior football club, part of the yarra junior football league, in melbourne's north as a junior, before moving to the northern knights to play under-18s football in the tac cup in 2006 and 2007. kreuzer established himself as both the team's no. 1 ruckman and as a key forward...
wikipedia
eb339abd6617ac18e1ee399c23d75e4f42076f81
matthew kreuzer (born 13 may 1989) is a
matthew kreuzer (born 13 may 1989) is a retired professional australian rules footballer who played for the carlton football club in the australian football league (afl). he was selected first overall pick in the 2007 afl draft. he announced his retirement in september 2020.
wikipedia
91fd9c180976e82aace9268401badc4a09378de4
the 1919–20 season was the 43rd scottish football
the 1919–20 season was the 43rd scottish football season in which dumbarton competed at national level, entering the scottish football league and the scottish cup. in addition dumbarton entered the dumbartonshire cup and the dumbartonshire charity cup.
wikipedia
238f7ef1ba6e815e08727f1c3cff74186be8fd2a
in addition robert carmichael, david finnie, val lawrence,
in addition robert carmichael, david finnie, val lawrence, john mcewan, james mcgregor, james mcintosh, james neil, william wilson and james young all played their final 'first xi' games in dumbarton colours.
wikipedia
135d1267acb0fdb8f96a68721879c3f41ba69561
with the resumption of the scottish cup, dumbarton
with the resumption of the scottish cup, dumbarton were perhaps unfortunate to come up against rangers in the first round. however they gave a good account of themselves, and lost a very close encounter by the only goal, after a 0-0 draw.
wikipedia
91fd9c180976e82aace9268401badc4a09378de4
the 1919–20 season was the 43rd scottish football
the 1919–20 season was the 43rd scottish football season in which dumbarton competed at national level, entering the scottish football league and the scottish cup. in addition dumbarton entered the dumbartonshire cup and the dumbartonshire charity cup.
wikipedia
c6303c99b67024413fb997818633629b6049060b
maclyn mccarty was an american geneticist, a research
maclyn mccarty was an american geneticist, a research scientist described in 2005 as "the last surviving member of a manhattan scientific team that overturned medical dogma in the 1940s and became the first to demonstrate that genes were made of dna." he had worked at rockefeller university "for more than 60 years." 19...
wikipedia
59c638e6bdd36765bc68bb8518ebdce262ee5f68
mccarty's scientific interests and energy had a counterpart
mccarty's scientific interests and energy had a counterpart in his rich personal life. along with his second wife, marjorie, mccarty had a wide circle of very close friends, both in the united states and abroad, who cherished his personal warmth, his low key, spare, and pragmatic character, his wit, and his wide-rangin...
wikipedia
80cf05ca648f291041a6ac617aa499c25c9368bc
in his later years, mccarty increasingly served as
in his later years, mccarty increasingly served as a statesman of the biomedical sciences. he served for 14 years as the physician-in-chief of the rockefeller university hospital, and as a trusted adviser and the vice president of the rockefeller university. outside the university, his leadership was sought by the new ...
wikipedia
babeff7871c37ba689accc368b9d06f81fcca4c7
in parallel, mccarty studied patients with rheumatic fever
in parallel, mccarty studied patients with rheumatic fever admitted to the rockefeller hospital as well as valuable specimen collections from military outbreaks of the disease during world war ii. he and his collaborators found that antibody responses to several streptococcal antigens were significantly higher in the g...
wikipedia
3fb7f047993f16cde57a4638e78bb60c29534eaf
together with his students and collaborators, over the
together with his students and collaborators, over the next 20 years, mccarty's work changed the understanding of the organism from a gram-positive streptococcus with a particular serological characteristic to one of the best characterized bacterial species. work on bacterial cell-wall anatomy and chemistry was just be...
wikipedia
cde12a7caad1e95a34cdbc79a034f2b899db9c1c
a 1946 retirement resulted in mccarty being asked
a 1946 retirement resulted in mccarty being asked to head a specialized 1922-established laboratory. this lab was the scientific home of rebecca lancefield, who developed a major classification system. his work, combined with hers, made it clear that conditions affecting the joints and the heart resulted from infection...
wikipedia
1517b9cfe7498560df4c07b77782cdda89a1a949
acceptance of the concept that "genes are dna"
acceptance of the concept that "genes are dna" was a slow process. skepticism and being ignored, at least in the new york research institutions abounded. there were challenges associated with research, which made it especially difficult to attract other investigators to pursue it. few people had the necessary expertise...
wikipedia
cdfe893038b95dcc9b39d0f1aab6d57feba523b8
macleod, over a number of years of research,
macleod, over a number of years of research, had resolved several thorny technical issues, so that by the time mccarty arrived at the rockefeller university, avery's team had paved the way for mccarty. their progress over the next three years is described in mccarty's memoir the transforming principle, written in the e...
wikipedia
1b7cda159a86c99120737ff967712d23ceb809d4
as an undergraduate at stanford university, he began
as an undergraduate at stanford university, he began his studies in the nascent field of biochemistry, working with james murray luck on protein turnover in the liver. he "graduated in 1933 from stanford, where he majored in biochemistry" and then "went on to earn his medical degree at johns hopkins university in 1937....
wikipedia
5c83fd38bf11a3de1787083179e9dc87124c791c
mccarty devoted his life as a physician-scientist to
mccarty devoted his life as a physician-scientist to studying infectious disease organisms, and was best known for his part in the monumental discovery that dna, rather than protein, constituted the chemical nature of a gene. uncovering the molecular secret of the gene in question — that for the capsular polysaccharide...
wikipedia
218b41e70971eb6c74f13037deb748958557473a
maclyn mccarty (june 9, 1911 – january 2,
maclyn mccarty (june 9, 1911 – january 2, 2005) was an american geneticist, a research scientist described in 2005 as "the last surviving member of a manhattan scientific team that overturned medical dogma in the 1940s and became the first to demonstrate that genes were made of dna." he had worked at rockefeller univer...
wikipedia
44d4680c7b25a1247201602dbf0920cd91dfb27f
the 1933–34 nhl season was the 17th season
the 1933–34 nhl season was the 17th season of the national hockey league (nhl). nine teams each played 48 games. the chicago black hawks were the stanley cup winners as they beat the detroit red wings three games to one.
wikipedia
9c571471e5965d54068165920047518df4bd3d3f
the chicago black hawks beat the detroit red
the chicago black hawks beat the detroit red wings three games to one with the fourth game going into double overtime. after regulation time in the fourth game, black hawks star goaltender and two-time vezina trophy winner, charlie gardiner, left the game because he wasn't feeling well. he died two months later of a br...
wikipedia
78bc353c63d11fd394aa5deea99b8aa3b9194299
the game itself was proposed by walter gilhooley,
the game itself was proposed by walter gilhooley, the sports editor of the journal in montreal. this proposal became a reality on january 24, 1934, in a meeting of the nhl's board of governors in 1934. the game was held at maple leaf gardens in toronto, during which bailey's #6 uniform was retired by the leafs. it was ...
wikipedia
d68c4268a604c1463b39ea2034395a3437709776
on february 14, 1934, the first nhl all-star
on february 14, 1934, the first nhl all-star game, albeit an unofficial one, was held to benefit toronto maple leafs forward ace bailey, who suffered a career-ending injury. on december 12, 1933, near the end of the second period of a game between the leafs and the boston bruins in the boston garden, bailey was hit fro...
wikipedia
d3dfd26d902f0956de2dd2716be9d68fac455575
a major trade was a swap of goaltenders
a major trade was a swap of goaltenders as lorne chabot was traded to the montreal canadiens for george hainsworth. the canadiens also loaned wilf cude to detroit and he led thered wings to first place. chabot did not do badly either, leading the canadian division in goaltending, helping the goal-strapped canadiens to ...
wikipedia
3acc047012b0dc6c7b6938cce36472e9930ddd6f
the ottawa senators, having enough problems, now had
the ottawa senators, having enough problems, now had to deal with holdout cooney weiland. he was sold to detroit, strengthening the red wings. the senators continued to lose, but won a few games when they signed an amateur named max kaminsky to centre the roche brothers desse and earl. a defenceman, ralph "scotty" bowm...
wikipedia
564f871b5c9211ad7b7e6f9dfe4c7d074e58a268
the new york americans introduce new sweaters. the
the new york americans introduce new sweaters. the team's home uniform uses the word 'americans' across the front with white stars over a blue area around the shoulders with red and white stripes below the wording. the road uniform is white with a shield logo. there are sleeves and shoulders are blue with a horizontal ...
wikipedia
44d4680c7b25a1247201602dbf0920cd91dfb27f
the 1933–34 nhl season was the 17th season
the 1933–34 nhl season was the 17th season of the national hockey league (nhl). nine teams each played 48 games. the chicago black hawks were the stanley cup winners as they beat the detroit red wings three games to one.
wikipedia
10a972dde666cf7d4e15160ea50877cb237334d6
mechanical vapor recompression (mvr) is an energy recovery
mechanical vapor recompression (mvr) is an energy recovery process which can be used to recycle waste heat to improve efficiency. typically, the compressed vapor is fed back to help heat the mother liquor in order to produce more vapor or steam.
wikipedia
c1c3008b0fa3b864fb351260fe48ace3f6aee100
"in the ordinary way this would have created
"in the ordinary way this would have created much noise and clouds of steam, but with the condensing set in action it was all absorbed with the ease with which snow would melt in a furnace! the engine was as silent as an electric locomotive and the only faint noises were due to slight pounding of the rods and a small b...
wikipedia
d571a46ab2baa2e80ef81d1f5673b9ea455af0d6
mvr was successfully tested in a locomotive under
mvr was successfully tested in a locomotive under the name of " the anderson system ". testing found that it almost completely eliminated steam ejection, as well as greatly reduced operating noise. an harold holcroft, organiser of the tests wrote the following:
wikipedia
10a972dde666cf7d4e15160ea50877cb237334d6
mechanical vapor recompression (mvr) is an energy recovery
mechanical vapor recompression (mvr) is an energy recovery process which can be used to recycle waste heat to improve efficiency. typically, the compressed vapor is fed back to help heat the mother liquor in order to produce more vapor or steam.
wikipedia
8679dd40f03465329927c9381b5ddf5c890bf370
yao kouassi scored the game-winning goal for air
yao kouassi scored the game-winning goal for air force central on 17 may 2014, as the club came from 0−1 down to win 2−1. on 31 may, he scored air force's second goal in their 2−0 win over sisaket f.c. on 21 june, he brought his team back from a goal down, scoring a hat-trick to defeat chainat hornbill 3−1 in the 19th ...
wikipedia
1841213423f797feda37423a0de29a25f99e12ff
hermann scored 16 goals for air force central
hermann scored 16 goals for air force central in 2013 as the club were promoted back to the thai premier league. on 9 march 2014, he made his debut in the premier league and scored a consolation goal as air force were defeated 5−1 by police united.
wikipedia
98980d2f8bb70889811097f2eda39488b9b4e01f
kouassi yao hermann (born 26 january 1990), known
kouassi yao hermann (born 26 january 1990), known as yao hermann kouassi and hermann yao kouassi, is an ivorian footballer who plays for angthong in the thai league 3 as a forward.
wikipedia
0e57e71830ae4960d6424722c0a42cd2be60faed
fellon made his debut in the 2020 fim
fellon made his debut in the 2020 fim cev moto3 junior world championship with junior team 0,0 estrella galicia. he did not start the season well, in the two races in portugal, he did not score any points, and in the first race in jerez, he retired due to a crash. but from the second jerez race onwards, until the last ...
wikipedia
84520a8c55b5b34bd85038ebfd1c326a87d6b60e
during the 2019 season, lorenzo fellon participated in
during the 2019 season, lorenzo fellon participated in the 2019 red bull motogp rookies cup. his season was good, he finished all twelve races of the championship in the points. his best result was a fourth place finish in the last race of the season at aragón. he finished the season fifth in the standings collecting 1...
wikipedia
1a96a71625210e5fc4fe22b644f65e28feb6034d
after retiring from baseball deegan worked as a
after retiring from baseball deegan worked as a commercial photographer in miami, north carolina, and new jersey. she also worked for the western electric corporation in kearney, new jersey. she served as a coach for a semi-professional women's softball team for 22 years (1958–79) and as a coach at middlesex county col...
wikipedia
027be339215b1e736a9c7d790dbeb6a90c1c6ebf
in 1944, the brooklyn dodgers brought deegan and
in 1944, the brooklyn dodgers brought deegan and two other women players to the team's spring training camp at bear mountain, new york. she was given permission to travel with the team from manager leo durocher but was not allowed to step on the field. however, after retrieving a foul ball during an exhibition game, on...
wikipedia
fd325590960c581822cebfafb9417c29326f3881
as a pitcher, she gave up the winning
as a pitcher, she gave up the winning run to the racine belles in the final game of the 1946 shaughnessy series but had a lifetime earned run average of 2.36. her career batting average was.260.
wikipedia
474b6f2b9a46c8de4de4db793eed3498791b977a
deegan joined a chicago fastpitch softball team for
deegan joined a chicago fastpitch softball team for the american softball association national tournament in 1943. she was soon signed by the league to play for the rockford peaches. she played for the peaches until midway through the 1947 season, when she was traded to the kenosha comets, beginning a four-year stretch...
wikipedia
7bfe84e514cd8058dbff85ce459b20f34e439540
deegan was one of 25 players who made
deegan was one of 25 players who made the all-american girls professional baseball league clubs hailed from new york city and state, including muriel bevis, gloria cordes, nancy mudge, betty trezza and margaret wigiser. born in bensonhurst, brooklyn, she was a star athlete at abraham lincoln high school and in 1935 was...
wikipedia
31f3049afca253a47f15b6924d179bdf876de96d
mildred eleanor deegan (december 11, 1919 – july
mildred eleanor deegan (december 11, 1919 – july 21, 2002) was an american pitcher, outfielder and second basewoman who played ten seasons in the all-american girls professional baseball league, from 1943 to 1952.
wikipedia
a9d69e2438bead6b6091d5e29e3e30602dce8326
1781 van biesbroeck is a vesta asteroid from
1781 van biesbroeck is a vesta asteroid from the inner regions of the asteroid belt, approximately 8.5 kilometers in diameter. it was discovered on 17 october 1906, by german astronomer august kopff at heidelberg observatory in southern germany. it was named after astronomer george van biesbroeck.
wikipedia
1f805fbeae1dc4ab5966c1325076560181214212
in 1961, he published the van biesbroeck's star
in 1961, he published the van biesbroeck's star catalog of low-mass, low-luminosity stars. the mountain van biesbroeck near the mcdonald observatory, the lunar crater van biesbroeck, and most notably the red dwarf van biesbroeck's star, were also named in his honour. (there are very few stars named after people). the g...
wikipedia
685e1da9a8161f5fff7b9789d9f6dc3f21c32db3
this minor planet was named after renowned belgian–born
this minor planet was named after renowned belgian–born observational astronomer george van biesbroeck, who naturalized as u.s. citizens in 1922. he specialized in the observation of double stars, variable stars, comets and asteroids, of which he discovered sixteen at the u.s. yerkes observatory in williams bay, wiscon...
wikipedia
e703b5b1fdd5448309d6a494991668f1da24e639
according to the survey carried out by nasa's
according to the survey carried out by nasa's wide-field infrared survey explorer with its subsequent neowise mission, van biesbroeck measures 8.5 kilometers in diameter, and its surface has an albedo of 0.203. a generic absolute magnitude -to-diameter conversion gives an inferred diameter between 8 and 14 kilometers, ...
wikipedia
986d97a6f3d547f49c38d81e37deaaa75d745a37
van biesbroeck orbits the sun in the inner
van biesbroeck orbits the sun in the inner main-belt at a distance of 2.1–2.7 au once every 3 years and 9 months (1,354 days). its orbit has an eccentricity of 0.11 and an inclination of 7 ° with respect to the ecliptic. it is not known whether the member of the vesta family of asteroids is in fact a v / j-type, or if ...
wikipedia
0d9cee394e3121c899fc297646b5ab2b1221aee1
1781 van biesbroeck (prov. designation: a906 ub) is
1781 van biesbroeck (prov. designation: a906 ub) is a vesta asteroid from the inner regions of the asteroid belt, approximately 8.5 kilometers in diameter. it was discovered on 17 october 1906, by german astronomer august kopff at heidelberg observatory in southern germany. it was named after astronomer george van bies...
wikipedia
5165aa8d4c54eea54f3ec6d2f8b79c3d2c722b93
melody a. swartz is a professor and vice
melody a. swartz is a professor and vice dean for faculty affairs at the university of chicago who pioneered research in engineering complex tissues. her most cited work "capturing complex 3d tissue physiology in vitro" has been cited over 1784 times. her research is focused on understanding the role of the lymphatic s...
wikipedia
3c3a8ebcfa056f2adde2b01a1b5456279d13f7ff
swartz is on many journals' editorial boards. she
swartz is on many journals' editorial boards. she has served on the editorial board of angiogenesis, a journal covering topics on cellular and molecular mechanisms (2011–present). swartz is also on the editorial boards of cancer immunology research (2013–present) and biomechanics and modeling in mechanobiology (2015–pr...
wikipedia
6639e1f181866d2822be811aaa8c5d04f65e300d
swartz' most cited article "capturing complex 3d tissue
swartz' most cited article "capturing complex 3d tissue physiology in vitro" was published in march 2006. she talks about creating 3d tissue models in the vitro software. discussing some design principles for recreating the interwoven set of both biochemical and mechanical cousin the cellular microenvironment and imple...
wikipedia
b4a63c49e4d40d6fe358d0efee964ee038a6de94
in 2014 swartz took over a part time
in 2014 swartz took over a part time role in the École polytechnique fédérale de lausanne as she began to transition to working in the university of chicago 's ben may department of cancer research and the pritzker school of molecular engineering, of which she jointly became a professor of both. swartz is a member of m...
wikipedia
a659efdfd71a144f7593ebb82901828ebb2c4745
swartz began her career working at northwestern university
swartz began her career working at northwestern university in evanston, illinois, from 1999 to 2004 as an assistant professor in the chemical, biomedical and bioengineering departments. she served various roles in the École polytechnique fédérale de lausanne from 2003 to 2016. first as an assistant professor in the ins...
wikipedia
1a208568472bdedc2cf58dbcff932373bec56de3
swartz was born in illinois. she earned her
swartz was born in illinois. she earned her undergraduate degree in chemical engineering at johns hopkins university (1991) and her phd in chemical engineering at massachusetts institute of technology (1998). she did her postdoctoral work in the pulmonary division at harvard medical school.
wikipedia
ed711fd3f68b9e9c6547f116098fd7d5b04c8df8
melody a. swartz (born april 1969) is a
melody a. swartz (born april 1969) is a professor and vice dean for faculty affairs at the university of chicago who pioneered research in engineering complex tissues. her most cited work "capturing complex 3d tissue physiology in vitro" has been cited over 1784 times. her research is focused on understanding the role ...
wikipedia
0a89fab65cd1fc67657c074efac2f8430d81e167
lindsay j. whaley is a professor of linguistics
lindsay j. whaley is a professor of linguistics and classics at dartmouth college he received his bachelor's degree with honors from calvin college in 1988. he went on to the state university of new york, where he earned his master's degree (1990) and phd (1993).
wikipedia
3d9c58adc1736026c2563a3cac132d4ff1d47ddd
michael joseph keating is a canadian former professional
michael joseph keating is a canadian former professional ice hockey left winger who played in one national hockey league game for the new york rangers during the 1977–78 season, on january 29, 1978, against the los angeles kings. the rest of his career, which lasted from 1977 to 1980, was spent in the minor leagues. as...
wikipedia
548415e35e940a364cbe1787fb028e02fbcf8c3a
michael joseph keating (born january 21, 1957) is
michael joseph keating (born january 21, 1957) is a canadian former professional ice hockey left winger who played in one national hockey league game for the new york rangers during the 1977–78 season, on january 29, 1978, against the los angeles kings. the rest of his career, which lasted from 1977 to 1980, was spent ...
wikipedia
c27bacf2a0d070bc5ddb6c7c5352f299031e173e
the mexico women's national cricket team, nicknamed the
the mexico women's national cricket team, nicknamed the jaguars, represents the country of mexico in women's cricket matches. in april 2018, the international cricket council (icc) granted full women's twenty20 international (wt20i) status to all its members. therefore, all twenty20 matches played between mexico women ...
wikipedia
6d4999eecf320c6ac8b695d7e645f5ecf2fd6c29
mexico's first wt20i matches were contested as part
mexico's first wt20i matches were contested as part of the south american women's championships in august 2018 against brazil, chile and peru however peru's matches were not classified as wt20is as not all of their players met the icc residency requirements. mexico lost four matches and won two to finish third on the t...
wikipedia
9de4f7648ba1d4d608bff4cd83e4994597c6337e
in april 2018, the international cricket council (icc)
in april 2018, the international cricket council (icc) granted full women's twenty20 international (wt20i) status to all its members. therefore, all twenty20 matches played between mexico women and another international side after 1 july 2018 have the full wt20i status.
wikipedia
a296fb26d6a272414d7f7185d116f458f40bbaae
methyl chloroformate is a chemical compound with the
methyl chloroformate is a chemical compound with the chemical formula cl−c(=o)−o−ch3. it is the methyl ester of chloroformic acid. it is an oily colorless liquid, although aged samples appear yellow. it is also known for its pungent odor.
wikipedia
e7be2bc1a1bae523930f4f3e6457ddbc1a187457
methyl chloroformate forms highly flammable vapour-air mixtures. the
methyl chloroformate forms highly flammable vapour-air mixtures. the compound has a flash point of 10 °c. methyl chloroformate, if heated, releases phosgene. it produces hydrogen chloride upon contact with water. it will cause skin damage if in contact with skin.
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methyl chloroformate hydrolyzes in water to form methanol,
methyl chloroformate hydrolyzes in water to form methanol, hydrochloric acid, and carbon dioxide. this decomposition happens violently in the presence of steam, causing foaming. the compound decomposes in heat, which can liberate hydrogen chloride, phosgene, chlorine, or other toxic gases.
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edaf0c489488fab491883247554fc7cd64496e19
methyl chloroformate is a chemical compound with the
methyl chloroformate is a chemical compound with the chemical formula cl−c(=o)−o−ch. it is the methyl ester of chloroformic acid. it is an oily colorless liquid, although aged samples appear yellow. it is also known for its pungent odor.
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6050ce9071d226317ea6e50035088cb4c40f44bb
1887–88 was the third season for st. mary's
1887–88 was the third season for st. mary's young men's association football club based in southampton in southern england. the club entered, and won, the hampshire junior cup in its inaugural year, thus laying the foundation for success over the next two decades.
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by the end of the season, match reports
by the end of the season, match reports were also referring to the club as "the saints"; the first known record of this was on the day of the initial hampshire junior cup final when the southampton times reported: "the saints journeyed to cowes on saturday to decide the return match with the town club." this nickname c...
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s. mary's football club – we are glad
s. mary's football club – we are glad to record a great triumph for the above club, which has now, by following up its many victories won the much coveted "cup" for the year. we cordially congratulate them on their success.
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there is no record of how many of
there is no record of how many of the football club members confirmed their membership of the young men's association and it seems that the church and parish were happy for the football club to continue under the banner of "st. mary's", with canon wilberforce continuing as club president until he left the parish in 189...
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that st. mary's church of england young men's
that st. mary's church of england young men's association should, in future, consist only of members who are either active workers in some branch of the parochial organization, or regular attendants at one of the bible classes. for the purpose of effectively carrying this out, it was resolved to make a fresh enrolment ...
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the club had originally been founded by members
the club had originally been founded by members of the st. mary's young men's association in 1885 and the members were expected to be practicing members of the church of england, and participate in bible classes and teach in sunday school. the recruitment of players such as george carter, who had been signed for his ab...
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as recorded in the hampshire f.a. handbook, at
as recorded in the hampshire f.a. handbook, at the start of the season the club were registered as st. mary's young men's association fc. by the end of the season, however, all match reports had dropped references to the "young men's association" and the club were recorded as simply st. mary's football club.
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the final match of the season was played
the final match of the season was played at the antelope ground on 14 april 1888 against woolston works who had won the inaugural hampshire senior cup. the clubs had decided that they should compete to decide which was southampton's top club. the home side were victorious by three goals to nil; the bournemouth guardian...
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st. mary's continued to play friendly matches throughout
st. mary's continued to play friendly matches throughout the season, although reports are not available for many of these. for example, there were two matches against cowes on the isle of wight, including an away victory a week before the initial hampshire junior cup match.
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the replay was played two weeks later, again
the replay was played two weeks later, again at the county ground in front of a crowd of "over 500 people, exclusive of the ladies who, bless 'em, are admitted free." st. mary's took a 2–0 lead through mcdonald and warn (after some "pretty passing") before the harriers pulled one back. the report in the southampton tim...
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the southampton times estimated the crowd for the
the southampton times estimated the crowd for the final at approximately 600, despite the "threatening" weather. st. mary's fell behind early in the game and were 2–0 down at half-time but fought back to draw level at 2–2, with goals from warn and ned bromley who unleashed a "splendid shot" with three minutes left to p...
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the final was played on 10 march 1888
the final was played on 10 march 1888 at the county ground against southampton harriers, another strong local side who played their home matches on southampton common, having been founded as the temperance amateur athletic association, but changed their name in 1885. many of the harriers players had "transferred" from ...
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the semi-final draw gave st. mary's a match
the semi-final draw gave st. mary's a match against the bournemouth arabs and was played at the county ground on 18 february 1888. the "arabs" were a strong side and took the lead, after which carter and muir in defence ("certainly the best on the field" according to the southampton times) prevented them from playing o...
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in the next round, the saints received another
in the next round, the saints received another home draw against lymington; the pirates already had a fixture on the date of the match (21 january 1888), so the match was played on the pitch behind the anchor hotel, redbridge, four miles from the town centre. the match was won 4–0, but some of the saints' fans misbehav...
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as the common was not suitable for a
as the common was not suitable for a cup-tie, the st. mary's committee secured the use of the antelope ground, " by kind permission of the pirates ". the pirates were a rugby club who shared the ground with a football team from woolston works. the antelope ground, which stood on the east side of st mary's road between ...
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this problem did not arise with the first
this problem did not arise with the first round match, when the club were drawn to play at totton who had only been formed the year before but had the use of a field within the grounds of a private estate at south testwood park. the report on the match published in the southampton times complemented the hosts on their ...
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in september, the hampshire f.a. announced the creation
in september, the hampshire f.a. announced the creation of two cup tournaments, the hampshire senior cup and the hampshire junior cup; st. mary's y.m.a. entered into the latter competition. the trophy was a silver cup provided by charles baring young, the member of parliament for christchurch.
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in april 1887, the south hants & dorset
in april 1887, the south hants & dorset f.a. was dissolved to be replaced by two separate county associations. the newly formed hampshire football association held its first meeting on 20 april at the spartan club in southampton high street when st. mary's were represented by messrs. varley and bromley.
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the players continued to wear white shorts, black
the players continued to wear white shorts, black knee-length socks and "white tunics" with a red sash worn diagonally. a photograph taken after their victory in the hampshire junior cup in march 1888 shows the sashes worn from either shoulder in a rather haphazard fashion.
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canon basil wilberforce continued as the president of
canon basil wilberforce continued as the president of the club, although this was an honorary position, with dr. bencraft, a "highly-active" member of the committee, acting as "de facto" president. wilberforce left the parish of st. mary's in 1894, after which bencraft became the official club president. george muir, a...
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the most significant new arrival was george carter:
the most significant new arrival was george carter: carter was employed as an engraver by the ordnance survey and in 1887 he was posted to their offices in southampton. speaking in 1999, carter's daughter-in-law, nellie carter, said that carter was "not at all happy" about being posted to southampton and that carter ma...
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the 1887–88 season saw the st. mary's club
the 1887–88 season saw the st. mary's club start to evolve from a church youth club side playing friendly matches on the local common into the dominant team in southampton, who would play in front of paying crowds. two years after being founded, the club began to embrace professionalism and move away from its roots, gr...
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39dc32729242e6d5ca57325a135f8759b7e38049
1887–88 was the third season for st. mary's
1887–88 was the third season for st. mary's young men's association football club (st. mary's y.m.a.) based in southampton in southern england. the club entered, and won, the hampshire junior cup in its inaugural year, thus laying the foundation for success over the next two decades.
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the 1970–71 season was paris saint-germain's 1st season
the 1970–71 season was paris saint-germain's 1st season in existence. psg mainly played their home league games at the stade jean-bouin in paris, but occasionally at the stade municipal georges lefèvre in saint-germain-en-laye as well, registering an average attendance of 3,018 spectators per match. the club was presid...
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paris fc contributed with the financial backing, while
paris fc contributed with the financial backing, while stade saint-germain provided the sporting infrastructure, from the division 2 status to the camp des loges training center, as well as the manager pierre phelipon and most of the players, including bernard guignedoux, michel prost and camille choquier. in addition ...
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20,000 people backed the project and paris saint-germain
20,000 people backed the project and paris saint-germain were formed on june 17, 1970. pierre-Étienne guyot was elected the club's first president a few days later. for the first time in french football history, the fans had financially contributed in the making of a club. the merger was made official following the cre...
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in the summer of 1970, an ambitious group
in the summer of 1970, an ambitious group of businessmen decided to create a major team in the french capital. guy crescent and pierre-Étienne guyot chose to merge their virtual side, paris fc, created in 1969, with stade saint-germain of henri patrelle after the team from saint-germain-en-laye, 15km west of paris and ...
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