answer
string
choices
dict
id
string
kind
string
lang
string
question
string
steps
list
subject
string
text
string
topic
string
The law of conservation of mass states matter is neither created nor destroyed in reactions.
null
che_0451
concept
en
What is the law of conservation of mass?
[ "Atoms rearrange only.", "Total mass stays fixed.", "Basis of balancing." ]
chemistry
Answer: Mass is conserved in reactions. Steps: 1. Atoms rearrange only. 2. Total mass stays fixed. 3. Basis of balancing.
stoichiometry
One mole of helium holds 6.022 x 10^23 atoms.
{ "A": "6.022 x 10^23", "B": "1.204 x 10^24", "C": "3.011 x 10^23", "D": "1.00 x 10^23" }
che_0452
multiple_choice
en
How many atoms are in 1.00 mol of helium?
[ "One mole means Avogadro's count.", "Value 6.022 x 10^23.", "Select option A." ]
chemistry
Answer: 6.022 x 10^23. Steps: 1. One mole means Avogadro's count. 2. Value 6.022 x 10^23. 3. Select option A. Answer: (A)
stoichiometry
The mass is 19.70 g, from 0.100 mol times 196.97 g/mol.
null
che_0453
worked_example
en
What mass is 0.100 mol of gold (M = 196.97 g/mol)?
[ "Write: m = 0.100 x 196.97.", "Multiply.", "m = 19.70 g." ]
chemistry
Answer: 19.70 g. Steps: 1. Write: m = 0.100 x 196.97. 2. Multiply. 3. m = 19.70 g.
stoichiometry
Relativní atomová hmotnost je průměrná hmotnost atomu vůči 1/12 uhlíku 12.
null
che_0454
concept
cs
Co je relativní atomová hmotnost?
[ "Průměr přes izotopy.", "Jednotka 1/12 12C.", "Bezrozměrné číslo." ]
chemistry
Answer: Průměrná hmotnost atomu. Steps: 1. Průměr přes izotopy. 2. Jednotka 1/12 12C. 3. Bezrozměrné číslo.
stoichiometry
There are 2.00 mol, from 8.00 g divided by 4.003 g/mol.
null
che_0455
worked_example
en
How many moles are in 8.00 g of helium (M = 4.003 g/mol)?
[ "Write: n = 8.00/4.003.", "Divide.", "n = 2.00 mol." ]
chemistry
Answer: 2.00 mol. Steps: 1. Write: n = 8.00/4.003. 2. Divide. 3. n = 2.00 mol.
stoichiometry
Sulfuric acid totals 98.08 g/mol from 2 H, 1 S, and 4 O.
{ "A": "49.04 g/mol", "B": "98.08 g/mol", "C": "114.08 g/mol", "D": "82.08 g/mol" }
che_0456
multiple_choice
en
What is the molar mass of H2SO4?
[ "2x1.008 + 32.06 + 4x16.00.", "Total 98.08.", "Select option B." ]
chemistry
Answer: 98.08 g/mol. Steps: 1. 2x1.008 + 32.06 + 4x16.00. 2. Total 98.08. 3. Select option B. Answer: (B)
stoichiometry
Formula mass is per formula unit in amu while molar mass is per mole in g/mol.
null
che_0457
concept
en
How do formula mass and molar mass differ?
[ "Formula mass: one unit, amu.", "Molar mass: one mole, g/mol.", "Numerically equal." ]
chemistry
Answer: Per unit versus per mole. Steps: 1. Formula mass: one unit, amu. 2. Molar mass: one mole, g/mol. 3. Numerically equal.
stoichiometry
The mass is 150.1 g, from 1.50 mol times 100.09 g/mol.
null
che_0458
worked_example
en
What mass is 1.50 mol of CaCO3 (M = 100.09 g/mol)?
[ "Write: m = 1.50 x 100.09.", "Multiply.", "m = 150.1 g." ]
chemistry
Answer: 150.1 g. Steps: 1. Write: m = 1.50 x 100.09. 2. Multiply. 3. m = 150.1 g.
stoichiometry
Je to 0,50 molu, protože 20 děleno 40,08 se rovná 0,50.
null
che_0459
worked_example
cs
Kolik molů je ve 20 g vápníku (M = 40,08 g/mol)?
[ "Napiš vzorec: n = 20/40,08.", "Vyděl.", "n = 0,50 mol." ]
chemistry
Answer: 0,50 mol. Steps: 1. Napiš vzorec: n = 20/40,08. 2. Vyděl. 3. n = 0,50 mol.
stoichiometry
The balanced equation is C3H8 + 5O2 -> 3CO2 + 4H2O.
{ "A": "1, 3, 3, 4", "B": "2, 5, 3, 4", "C": "1, 5, 3, 4", "D": "1, 5, 4, 3" }
che_0460
multiple_choice
en
What coefficients balance C3H8 + O2 -> CO2 + H2O?
[ "C: 3 CO2. H: 4 H2O.", "O: 5 O2.", "Select option C." ]
chemistry
Answer: 1, 5, 3, 4. Steps: 1. C: 3 CO2. H: 4 H2O. 2. O: 5 O2. 3. Select option C. Answer: (C)
stoichiometry
The stoichiometric map routes mass to moles, across the ratio, then back to mass.
null
che_0461
concept
en
What is the stoichiometric map?
[ "Mass to moles via M.", "Moles across via ratio.", "Moles to mass via M." ]
chemistry
Answer: Mass-mole-mole-mass route. Steps: 1. Mass to moles via M. 2. Moles across via ratio. 3. Mole to mass via M.
stoichiometry
Three moles of H2 are needed, from 2 mol NH3 times the 3/2 ratio.
null
che_0462
worked_example
en
How much H2 is needed to make 2.0 mol NH3 (N2 + 3H2 -> 2NH3)?
[ "Ratio H2:NH3 = 3:2.", "Multiply: 2.0 x 3/2.", "H2 = 3.0 mol." ]
chemistry
Answer: 3.0 mol. Steps: 1. Ratio H2:NH3 = 3:2. 2. Multiply: 2.0 x 3/2. 3. H2 = 3.0 mol.
stoichiometry
Hydrogen limits because 3 mol H2 pairs with only 1 mol N2, leaving N2 over.
{ "A": "H2 limits", "B": "N2 limits", "C": "Neither limits", "D": "Both limit" }
che_0463
multiple_choice
en
With 3 mol N2 and 3 mol H2 for N2 + 3H2 -> 2NH3, what limits?
[ "3 H2 needs 1 N2.", "N2 is in excess.", "Select option A." ]
chemistry
Answer: H2 limits. Steps: 1. 3 H2 needs 1 N2. 2. N2 is in excess. 3. Select option A. Answer: (A)
stoichiometry
Nadbytek reaktantu je množství zbývající po spotřebování limitujícího reaktantu.
null
che_0464
concept
cs
Co je nadbytek reaktantu?
[ "Více, než reakce spotřebuje.", "Zbude po reakci.", "Opak limitujícího reaktantu." ]
chemistry
Answer: Nespotřebovaný zbytek. Steps: 1. Více, než reakce spotřebuje. 2. Zbude po reakci. 3. Opak limitujícího reaktantu.
stoichiometry
Excess N2 left is 0.333 mol, from 1.00 minus 0.667 mol consumed.
null
che_0465
worked_example
en
1.00 mol N2 reacts with 2.00 mol H2 (N2 + 3H2 -> 2NH3). How much N2 remains?
[ "H2 limits: needs 2.00/3 = 0.667 N2.", "Subtract: 1.00 - 0.667.", "N2 left = 0.333 mol." ]
chemistry
Answer: 0.333 mol. Steps: 1. H2 limits: needs 2.00/3 = 0.667 N2. 2. Subtract: 1.00 - 0.667. 3. N2 left = 0.333 mol.
stoichiometry
The molarity is 0.40 M, from 0.200 mol divided by 0.500 L.
{ "A": "0.10 M", "B": "0.40 M", "C": "1.00 M", "D": "2.50 M" }
che_0466
multiple_choice
en
What is the molarity of 0.200 mol in 0.500 L?
[ "Write: M = 0.200/0.500.", "Divide: 0.40.", "Select option B." ]
chemistry
Answer: 0.40 M. Steps: 1. Write: M = 0.200/0.500. 2. Divide: 0.40. 3. Select option B. Answer: (B)
stoichiometry
The volume is 0.200 L, from 0.100 mol divided by 0.500 M.
null
che_0467
worked_example
en
What volume of 0.500 M solution holds 0.100 mol?
[ "Write: V = n/M.", "Substitute: 0.100/0.500.", "V = 0.200 L." ]
chemistry
Answer: 0.200 L. Steps: 1. Write: V = n/M. 2. Substitute: 0.100/0.500. 3. V = 0.200 L.
stoichiometry
Koncentrace je 0,2 M, protože 0,3 děleno 1,5 se rovná 0,2.
null
che_0468
worked_example
cs
Jaká je koncentrace 0,3 molu v 1,5 l?
[ "Napiš vzorec: M = 0,3/1,5.", "Vyděl.", "M = 0,2 mol/l." ]
chemistry
Answer: 0,2 M. Steps: 1. Napiš vzorec: M = 0,3/1,5. 2. Vyděl. 3. M = 0,2 mol/l.
stoichiometry
The volume is 67.2 L, from 3.00 mol times 22.414 L/mol.
{ "A": "22.4 L", "B": "44.8 L", "C": "33.6 L", "D": "67.2 L" }
che_0469
multiple_choice
en
What volume does 3.00 mol of gas occupy at STP?
[ "Multiply: 3.00 x 22.414.", "Result 67.2 L.", "Select option D." ]
chemistry
Answer: 67.2 L. Steps: 1. Multiply: 3.00 x 22.414. 2. Result 67.2 L. 3. Select option D. Answer: (D)
stoichiometry
Arrhenius acids release H+ and bases release OH- in water.
null
che_0470
concept
en
What is the Arrhenius definition?
[ "Acid gives H+ in water.", "Base gives OH- in water.", "Limited to aqueous solutions." ]
chemistry
Answer: H+ versus OH- in water. Steps: 1. Acid gives H+ in water. 2. Base gives OH- in water. 3. Limited to aqueous solutions.
acids_bases
An Arrhenius base yields hydroxide ions in water.
{ "A": "H+", "B": "Electrons", "C": "OH-", "D": "Salts" }
che_0471
multiple_choice
en
What does an Arrhenius base produce in water?
[ "Recall OH- release.", "Eliminate H+, electrons, salts.", "Select option C." ]
chemistry
Answer: OH-. Steps: 1. Recall OH- release. 2. Eliminate H+, electrons, salts. 3. Select option C. Answer: (C)
acids_bases
The pH is 3.70, from -log(2.0 x 10^-4).
null
che_0472
worked_example
en
Compute the pH of 2.0 x 10^-4 M HCl.
[ "[H+] = 2.0 x 10^-4 M.", "pH = -log(2.0 x 10^-4).", "pH = 3.70." ]
chemistry
Answer: 3.70. Steps: 1. [H+] = 2.0 x 10^-4 M. 2. pH = -log(2.0 x 10^-4). 3. pH = 3.70.
acids_bases
Arrheniova kyselina uvolňuje ve vodě ionty H+.
null
che_0473
concept
cs
Co je Arrheniova kyselina?
[ "Uvolňuje H+ ve vodě.", "Příklad: HCl.", "Platí jen ve vodném prostředí." ]
chemistry
Answer: Zdroj H+ ve vodě. Steps: 1. Uvolňuje H+ ve vodě. 2. Příklad: HCl. 3. Platí jen ve vodném prostředí.
acids_bases
Hydrofluoric acid ionizes only partly, so it is weak.
{ "A": "HCl", "B": "HF", "C": "HNO3", "D": "HBr" }
che_0474
multiple_choice
en
Which of these is a weak acid?
[ "Strong: HCl, HNO3, HBr.", "HF is famously weak.", "Select option B." ]
chemistry
Answer: HF. Steps: 1. Strong: HCl, HNO3, HBr. 2. HF is famously weak. 3. Select option B. Answer: (B)
acids_bases
Percent ionization is dissociated acid over initial concentration times 100.
null
che_0475
concept
en
What is percent ionization?
[ "Divide [H+] by initial C.", "Multiply by 100.", "Higher means stronger acid." ]
chemistry
Answer: Share of acid dissociated. Steps: 1. Divide [H+] by initial C. 2. Multiply by 100. 3. Higher means stronger acid.
acids_bases
Percent ionization is 1.34%, from 1.34 x 10^-3 divided by 0.10.
null
che_0476
worked_example
en
0.10 M acetic acid gives [H+] = 1.34 x 10^-3 M. Compute percent ionization.
[ "Divide: 1.34 x 10^-3 / 0.10 = 0.0134.", "Multiply by 100.", "Ionization = 1.34%." ]
chemistry
Answer: 1.34%. Steps: 1. Divide: 1.34 x 10^-3 / 0.10 = 0.0134. 2. Multiply by 100. 3. Ionization = 1.34%.
acids_bases
The first dissociation dominates pH because later Ka values are tiny.
null
che_0477
concept
en
Why does the first step dominate polyprotic pH?
[ "Ka1 far exceeds Ka2.", "First H+ dwarfs the rest.", "Approximate with Ka1 only." ]
chemistry
Answer: Ka1 dwarfs later steps. Steps: 1. Ka1 far exceeds Ka2. 2. First H+ dwarfs the rest. 3. Approximate with Ka1 only.
acids_bases
Ka2 of carbonic acid is far smaller than Ka1, so the second proton is very weak.
{ "A": "Large", "B": "Equal to Ka1", "C": "Strong", "D": "Much smaller than Ka1" }
che_0478
multiple_choice
en
How does Ka2 of H2CO3 compare to Ka1?
[ "Second proton harder to lose.", "Ka2 << Ka1.", "Select option D." ]
chemistry
Answer: Much smaller than Ka1. Steps: 1. Second proton harder to lose. 2. Ka2 << Ka1. 3. Select option D. Answer: (D)
acids_bases
pH je 1,70, protože -log(0,02) = 1,70.
null
che_0479
worked_example
cs
Vypočítej pH roztoku 0,02 M HCl.
[ "HCl disociuje plně.", "pH = -log(0,02).", "pH = 1,70." ]
chemistry
Answer: 1,70. Steps: 1. HCl disociuje plně. 2. pH = -log(0,02). 3. pH = 1,70.
acids_bases
The leveling effect caps acid strength in water at H3O+.
null
che_0480
concept
en
What is the leveling effect of water?
[ "Strong acids protonate water.", "All become H3O+.", "No stronger acid survives." ]
chemistry
Answer: Water caps strength at H3O+. Steps: 1. Strong acids protonate water. 2. All become H3O+. 3. No stronger acid survives.
acids_bases
Hydronium is the strongest acid that can exist in water.
{ "A": "H3O+", "B": "HCl", "C": "H2SO4", "D": "CH3COOH" }
che_0481
multiple_choice
en
What is the strongest acid in water?
[ "Stronger acids level to H3O+.", "H3O+ is the cap.", "Select option A." ]
chemistry
Answer: H3O+. Steps: 1. Stronger acids level to H3O+. 2. H3O+ is the cap. 3. Select option A. Answer: (A)
acids_bases
The base-to-acid ratio is 10:1, since log(ratio) = 5.76 - 4.76 = 1.
null
che_0482
worked_example
en
An acetate buffer (pKa = 4.76) has pH 5.76. Find the base/acid ratio.
[ "Write: 5.76 = 4.76 + log(ratio).", "log(ratio) = 1.", "Ratio = 10:1." ]
chemistry
Answer: 10:1. Steps: 1. Write: 5.76 = 4.76 + log(ratio). 2. log(ratio) = 1. 3. Ratio = 10:1.
acids_bases
Buffer capacity is the amount of acid or base a buffer absorbs before pH shifts sharply.
null
che_0483
concept
en
What is buffer capacity?
[ "Depends on concentrations.", "Higher means tougher buffer.", "Exhausted when a partner runs out." ]
chemistry
Answer: Absorbable acid/base amount. Steps: 1. Depends on concentrations. 2. Higher means tougher buffer. 3. Exhausted when a partner runs out.
acids_bases
Disociační konstanta Ka vyjadřuje sílu kyseliny v rovnováze.
null
che_0484
concept
cs
Co je disociační konstanta?
[ "Rovnováha disociace.", "Větší Ka = silnější kyselina.", "pKa = -log Ka." ]
chemistry
Answer: Konstanta síly kyseliny. Steps: 1. Rovnováha disociace. 2. Větší Ka = silnější kyselina. 3. pKa = -log Ka.
acids_bases
Back-titration handles slow or insoluble analytes by reacting excess reagent first.
{ "A": "Strong-strong only", "B": "Slow or insoluble analytes", "C": "Gases only", "D": "Never used" }
che_0485
multiple_choice
en
When is back-titration used?
[ "Direct endpoint unclear.", "Excess reagent added first.", "Select option B." ]
chemistry
Answer: Slow or insoluble analytes. Steps: 1. Direct endpoint unclear. 2. Excess reagent added first. 3. Select option B. Answer: (B)
acids_bases
There are 7.50 mmol, from 15.0 mL times 0.500 M.
null
che_0486
worked_example
en
How many millimoles are in 15.0 mL of 0.500 M base?
[ "Write: mmol = 15.0 x 0.500.", "Multiply.", "mmol = 7.50." ]
chemistry
Answer: 7.50 mmol. Steps: 1. Write: mmol = 15.0 x 0.500. 2. Multiply. 3. mmol = 7.50.
acids_bases
[H+] je 1 x 10^-4 M, protože 10 na -4 odpovídá pH 4.
null
che_0487
worked_example
cs
Roztok má pH 4. Vypočítej [H+].
[ "Napiš vzorec: [H+] = 10^(-4).", "Dosaď.", "[H+] = 1 x 10^-4 M." ]
chemistry
Answer: 1 x 10^-4 M. Steps: 1. Napiš vzorec: [H+] = 10^(-4). 2. Dosaď. 3. [H+] = 1 x 10^-4 M.
acids_bases
The solution is basic because Kb of NH3 exceeds Ka of HCN.
{ "A": "Acidic", "B": "Neutral", "C": "Basic", "D": "Cannot tell" }
che_0488
multiple_choice
en
Is NH4CN solution acidic or basic (Kb NH3 = 1.8e-5, Ka HCN = 6.2e-10)?
[ "Compare Ka and Kb.", "Kb larger means basic.", "Select option C." ]
chemistry
Answer: Basic. Steps: 1. Compare Ka and Kb. 2. Kb larger means basic. 3. Select option C. Answer: (C)
acids_bases
Alkali metals always take oxidation state +1 in compounds.
null
che_0489
concept
en
What oxidation state do alkali metals take?
[ "Group 1 loses one electron.", "State is +1 always.", "Example: Na in NaCl." ]
chemistry
Answer: +1 always. Steps: 1. Group 1 loses one electron. 2. State is +1 always. 3. Example: Na in NaCl.
redox
Sodium is +1 in sodium peroxide, as in all its compounds.
{ "A": "+1", "B": "-1", "C": "0", "D": "+2" }
che_0490
multiple_choice
en
What is the oxidation state of Na in Na2O2?
[ "Alkali metals are +1.", "Applies here too.", "Select option A." ]
chemistry
Answer: +1. Steps: 1. Alkali metals are +1. 2. Applies here too. 3. Select option A. Answer: (A)
redox
Chlorine is +5, since Cl + 3(-2) = -1 gives Cl = +5.
null
che_0491
worked_example
en
Find the oxidation number of Cl in ClO3-.
[ "Assign O -2.", "Equation: Cl - 6 = -1.", "Cl = +5." ]
chemistry
Answer: +5. Steps: 1. Assign O -2. 2. Equation: Cl - 6 = -1. 3. Cl = +5.
redox
Oxidace kovů vzduchem je jejich samovolná reakce s kyslíkem.
null
che_0492
concept
cs
Co je oxidace kovů vzduchem?
[ "Kov odevzdá elektrony.", "Kyslík se redukuje.", "Vznikají oxidy, např. rez." ]
chemistry
Answer: Tvorba oxidů na kovu. Steps: 1. Kov odevzdá elektrony. 2. Kyslík se redukuje. 3. Vznikají oxidy, např. rez.
redox
Iron drops from +3 to 0, so it is reduced.
{ "A": "Carbon", "B": "Iron", "C": "Oxygen", "D": "CO" }
che_0493
multiple_choice
en
In Fe2O3 + 3CO -> 2Fe + 3CO2, what is reduced?
[ "Fe goes +3 to 0.", "That is reduction.", "Select option B." ]
chemistry
Answer: Iron. Steps: 1. Fe goes +3 to 0. 2. That is reduction. 3. Select option B. Answer: (B)
redox
The balanced ionic equation is Zn + 2Ag+ -> Zn2+ + 2Ag.
null
che_0494
worked_example
en
Balance: Zn + Ag+ -> Zn2+ + Ag.
[ "Zn loses 2 e-.", "Need 2 Ag+ to gain them.", "Result: Zn + 2Ag+ -> Zn2+ + 2Ag." ]
chemistry
Answer: Zn + 2Ag+ -> Zn2+ + 2Ag. Steps: 1. Zn loses 2 e-. 2. Need 2 Ag+ to gain them. 3. Result: Zn + 2Ag+ -> Zn2+ + 2Ag.
redox
The oxidation number method tracks electron loss and gain to find coefficients.
null
che_0495
concept
en
What is the oxidation number method?
[ "Assign all oxidation states.", "Find changes up and down.", "Scale to equalize electrons." ]
chemistry
Answer: Balance via electron changes. Steps: 1. Assign all oxidation states. 2. Find changes up and down. 3. Scale to equalize electrons.
redox
Six electrons are lost as sulfur rises from -2 to +4.
null
che_0496
worked_example
en
How many electrons are lost in H2S -> SO2 (S: -2 to +4)?
[ "Change: -2 to +4.", "Difference = 6 up.", "Electrons lost = 6." ]
chemistry
Answer: 6 electrons. Steps: 1. Change: -2 to +4. 2. Difference = 6 up. 3. Electrons lost = 6.
redox
Sodium metal donates electrons eagerly, making it a strong reducing agent.
{ "A": "Na", "B": "Cl2", "C": "O2", "D": "F2" }
che_0497
multiple_choice
en
Which is the best reducing agent?
[ "Reducers donate electrons.", "Alkali metal Na tops list.", "Select option A." ]
chemistry
Answer: Na. Steps: 1. Reducers donate electrons. 2. Alkali metal Na tops list. 3. Select option A. Answer: (A)
redox
Železo má oxidační číslo +2, protože Fe + (-2) = 0.
null
che_0498
worked_example
cs
Urči oxidační číslo železa v FeO.
[ "Přiřaď O -2.", "Rovnice: Fe - 2 = 0.", "Fe = +2." ]
chemistry
Answer: +2. Steps: 1. Přiřaď O -2. 2. Rovnice: Fe - 2 = 0. 3. Fe = +2.
redox
Corrosion cells pair anodic metal dissolving with cathodic oxygen reduction.
null
che_0499
concept
en
What is a corrosion cell?
[ "Anode: metal oxidizes.", "Cathode: O2 reduces.", "Moisture conducts ions." ]
chemistry
Answer: Anode-cathode rust pair. Steps: 1. Anode: metal oxidizes. 2. Cathode: O2 reduces. 3. Moisture conducts ions.
redox
Paint blocks air and water from reaching the iron surface.
{ "A": "Oxidizes Fe faster", "B": "Adds salt", "C": "Blocks air and water", "D": "Heats the metal" }
che_0500
multiple_choice
en
How does painting prevent rust?
[ "Rust needs O2 and H2O.", "Paint seals them out.", "Select option C." ]
chemistry
Answer: Blocks air and water. Steps: 1. Rust needs O2 and H2O. 2. Paint seals them out. 3. Select option C. Answer: (C)
redox
The balanced equation is 2Al + 6HCl -> 2AlCl3 + 3H2.
null
che_0501
worked_example
en
Balance: Al + HCl -> AlCl3 + H2.
[ "Balance Cl and Al with 2 AlCl3, 6 HCl, 2 Al.", "Check H: 6 each side with 3 H2.", "Result: 2Al + 6HCl -> 2AlCl3 + 3H2." ]
chemistry
Answer: 2Al + 6HCl -> 2AlCl3 + 3H2. Steps: 1. Balance Cl and Al with 2 AlCl3, 6 HCl, 2 Al. 2. Check H: 6 each side with 3 H2. 3. Result: 2Al + 6HCl -> 2AlCl3 + 3H2.
redox
Redoxní pár tvoří oxidovaná a redukovaná forma téže látky.
null
che_0502
concept
cs
Co je redoxní pár?
[ "Dvě formy jedné látky.", "Liší se o elektrony.", "Příklad: Fe3+/Fe2+." ]
chemistry
Answer: Oxidovaná a redukovaná forma. Steps: 1. Dvě formy jedné látky. 2. Liší se o elektrony. 3. Příklad: Fe3+/Fe2+.
redox
Carbon is +4, since C + 2(-2) = 0 gives C = +4.
{ "A": "-4", "B": "0", "C": "+2", "D": "+4" }
che_0503
multiple_choice
en
What is the oxidation state of carbon in CO2?
[ "Assign O -2.", "Solve: C - 4 = 0.", "C = +4; select D." ]
chemistry
Answer: +4. Steps: 1. Assign O -2. 2. Solve: C - 4 = 0. 3. C = +4; select D. Answer: (D)
redox
Hydrogen peroxide disproportionates into water and oxygen: 2H2O2 -> 2H2O + O2.
null
che_0504
concept
en
How does hydrogen peroxide disproportionate?
[ "O is -1 in H2O2.", "Part goes to -2 in water.", "Part goes to 0 in O2." ]
chemistry
Answer: 2H2O2 -> 2H2O + O2. Steps: 1. O is -1 in H2O2. 2. Part goes to -2 in water. 3. Part goes to 0 in O2.
redox
Vyčíslená rovnice je 6Li + N2 -> 2Li3N.
null
che_0505
worked_example
cs
Vyčísli: Li + N2 -> Li3N.
[ "Dusík: 2 Li3N a 1 N2.", "Lithium: 6 Li.", "Výsledek: 6Li + N2 -> 2Li3N." ]
chemistry
Answer: 6Li + N2 -> 2Li3N. Steps: 1. Dusík: 2 Li3N a 1 N2. 2. Lithium: 6 Li. 3. Výsledek: 6Li + N2 -> 2Li3N.
redox
Oxygen with fluorine is +2, since O + 2(-1) = 0.
{ "A": "-2", "B": "+2", "C": "0", "D": "-1" }
che_0506
multiple_choice
en
What is oxygen's oxidation state in OF2?
[ "F is -1 each.", "Solve: O - 2 = 0.", "O = +2; select B." ]
chemistry
Answer: +2. Steps: 1. F is -1 each. 2. Solve: O - 2 = 0. 3. O = +2; select B. Answer: (B)
redox
One electron is lost as Fe2+ becomes Fe3+.
null
che_0507
worked_example
en
How many electrons are lost in Fe2+ -> Fe3+?
[ "Change: +2 to +3.", "Difference = 1 up.", "Electrons lost = 1." ]
chemistry
Answer: 1 electron. Steps: 1. Change: +2 to +3. 2. Difference = 1 up. 3. Electrons lost = 1.
redox
Open systems exchange matter and energy; closed systems exchange energy only.
null
che_0508
concept
en
How do open and closed systems differ?
[ "Open: matter crosses.", "Closed: only energy crosses.", "Isolated: neither crosses." ]
chemistry
Answer: Matter exchange versus energy only. Steps: 1. Open: matter crosses. 2. Closed: only energy crosses. 3. Isolated: neither crosses.
thermochemistry
A closed system exchanges energy but not matter.
{ "A": "Matter only", "B": "Energy only", "C": "Neither", "D": "Both freely" }
che_0509
multiple_choice
en
What does a closed system exchange?
[ "Matter sealed inside.", "Heat and work pass.", "Select option B." ]
chemistry
Answer: Energy only. Steps: 1. Matter sealed inside. 2. Heat and work pass. 3. Select option B. Answer: (B)
thermochemistry
The internal energy change is -150 J, from -300 plus +150 J.
null
che_0510
worked_example
en
A system releases 300 J of heat while 150 J of work is done on it. Find ΔU.
[ "Write: ΔU = -300 + 150.", "Add.", "ΔU = -150 J." ]
chemistry
Answer: -150 J. Steps: 1. Write: ΔU = -300 + 150. 2. Add. 3. ΔU = -150 J.
thermochemistry
Vnitřní energie je součet kinetické a potenciální energie částic soustavy.
null
che_0511
concept
cs
Co je vnitřní energie?
[ "Energie částic soustavy.", "Mění se teplem a prací.", "ΔU = q + w." ]
chemistry
Answer: Energie částic soustavy. Steps: 1. Energie částic soustavy. 2. Mění se teplem a prací. 3. ΔU = q + w.
thermochemistry
Heat leaving the system is negative by convention.
{ "A": "Negative", "B": "Positive", "C": "Zero", "D": "Infinite" }
che_0512
multiple_choice
en
What sign does released heat (q) have?
[ "System loses energy.", "Loss is negative.", "Select option A." ]
chemistry
Answer: Negative. Steps: 1. System loses energy. 2. Loss is negative. 3. Select option A. Answer: (A)
thermochemistry
The water releases 62.8 kJ, from 250 x 4.184 x (-60) J.
null
che_0513
worked_example
en
250 g of water cools from 90 C to 30 C. Find q.
[ "ΔT = 30 - 90 = -60 C.", "q = 250 x 4.184 x (-60).", "q = -62,760 J = -62.8 kJ." ]
chemistry
Answer: -62.8 kJ. Steps: 1. ΔT = 30 - 90 = -60 C. 2. q = 250 x 4.184 x (-60). 3. q = -62,760 J = -62.8 kJ.
thermochemistry
Thermal equilibrium means no net heat flow because temperatures are equal.
null
che_0514
concept
en
What is thermal equilibrium?
[ "Bodies in contact.", "Temperatures equalize.", "Net heat flow stops." ]
chemistry
Answer: Equal temperatures, no flow. Steps: 1. Bodies in contact. 2. Temperatures equalize. 3. Net heat flow stops.
thermochemistry
The final temperature is 50 C, the average of 80 and 20.
null
che_0515
worked_example
en
100 g of water at 80 C mixes with 100 g at 20 C. Find the final T.
[ "Equal masses and material.", "Average: (80 + 20)/2.", "T = 50 C." ]
chemistry
Answer: 50 C. Steps: 1. Equal masses and material. 2. Average: (80 + 20)/2. 3. T = 50 C.
thermochemistry
Heat scales with mass, so doubling mass doubles q for the same ΔT.
{ "A": "Halves q", "B": "No change", "C": "Doubles q", "D": "Quadruples q" }
che_0516
multiple_choice
en
Doubling mass with the same ΔT does what to q?
[ "q = m c ΔT.", "m doubles, rest fixed.", "Select option C." ]
chemistry
Answer: Doubles q. Steps: 1. q = m c ΔT. 2. m doubles, rest fixed. 3. Select option C. Answer: (C)
thermochemistry
Potřebné teplo je 12 552 J, protože 300 x 4,184 x 10 se rovná 12 552.
null
che_0517
worked_example
cs
Kolik tepla ohřeje 300 g vody o 10 °C?
[ "Napiš vzorec: q = 300 x 4,184 x 10.", "Vynásob.", "q = 12 552 J." ]
chemistry
Answer: 12 552 J. Steps: 1. Napiš vzorec: q = 300 x 4,184 x 10. 2. Vynásob. 3. q = 12 552 J.
thermochemistry
Molar heat capacity is the heat to warm one mole by one degree.
null
che_0518
concept
en
What is molar heat capacity?
[ "Per mole basis.", "Times ΔT gives q.", "Water is 75.4 J/molC." ]
chemistry
Answer: Heat per mole per degree. Steps: 1. Per mole basis. 2. Times ΔT gives q. 3. Water is 75.4 J/molC.
thermochemistry
Molar heat capacity uses joules per mole per degree.
{ "A": "J/mol C", "B": "J/g only", "C": "kJ/L", "D": "mol/J" }
che_0519
multiple_choice
en
What are molar heat capacity units?
[ "Energy per mole per degree.", "That is J/mol C.", "Select option A." ]
chemistry
Answer: J/mol C. Steps: 1. Energy per mole per degree. 2. That is J/mol C. 3. Select option A. Answer: (A)
thermochemistry
The ΔH is -110.5 kJ, from -393.5 minus -283.0 kJ.
null
che_0520
worked_example
en
Given C+O2->CO2 (-393.5) and CO+1/2O2->CO2 (-283.0 kJ), find C+1/2O2->CO.
[ "Subtract second from first.", "-393.5 - (-283.0).", "ΔH = -110.5 kJ." ]
chemistry
Answer: -110.5 kJ. Steps: 1. Subtract second from first. 2. -393.5 - (-283.0). 3. ΔH = -110.5 kJ.
thermochemistry
Slučovací teplo je teplo vzniku 1 molu sloučeniny z prvků.
null
che_0521
concept
cs
Co je slučovací teplo?
[ "Vznik 1 molu z prvků.", "Standardní stavy.", "Příklad: voda -285,8 kJ/mol." ]
chemistry
Answer: Teplo vzniku z prvků. Steps: 1. Vznik 1 molu z prvků. 2. Standardní stavy. 3. Příklad: voda -285,8 kJ/mol.
thermochemistry
Aqueous H+ is the reference with ΔHf of zero.
{ "A": "100 kJ/mol", "B": "0 kJ/mol", "C": "-50 kJ/mol", "D": "285.8 kJ/mol" }
che_0522
multiple_choice
en
What is ΔHf of H+(aq)?
[ "Reference ion defined zero.", "All ions relative to it.", "Select option B." ]
chemistry
Answer: 0 kJ/mol. Steps: 1. Reference ion defined zero. 2. All ions relative to it. 3. Select option B. Answer: (B)
thermochemistry
ΔS universe is +20 J/K, so the process is spontaneous.
null
che_0523
worked_example
en
ΔS sys = +50 J/K and ΔS surr = -30 J/K. Compute ΔS universe.
[ "Write: ΔS = 50 + (-30).", "Add.", "ΔS = +20 J/K, spontaneous." ]
chemistry
Answer: +20 J/K. Steps: 1. Write: ΔS = 50 + (-30). 2. Add. 3. ΔS = +20 J/K, spontaneous.
thermochemistry
Druhý zákon říká, že entropie izolované soustavy samovolně roste.
null
che_0524
concept
cs
Co je druhý termodynamický zákon?
[ "Entropie vesmíru roste.", "Samovolné děje ji zvyšují.", "Teplo neteče samo do teplejšího." ]
chemistry
Answer: Entropie roste. Steps: 1. Entropie vesmíru roste. 2. Samovolné děje ji zvyšují. 3. Teplo neteče samo do teplejšího.
thermochemistry
Absolute zero is 0 K, the unreachable minimum temperature.
{ "A": "0 C", "B": "-100 C", "C": "273 K", "D": "0 K" }
che_0525
multiple_choice
en
What is absolute zero?
[ "Kelvin scale starts there.", "Equals -273.15 C.", "Select option D." ]
chemistry
Answer: 0 K. Steps: 1. Kelvin scale starts there. 2. Equals -273.15 C. 3. Select option D. Answer: (D)
thermochemistry
Boiling needs 38.6 kJ, from 1.00 mol times 38.6 kJ/mol.
null
che_0526
worked_example
en
How much heat boils 46.1 g of ethanol (ΔHvap = 38.6 kJ/mol, M = 46.07 g/mol)?
[ "Moles = 46.1/46.07 = 1.00.", "Multiply: 1.00 x 38.6.", "Heat = 38.6 kJ." ]
chemistry
Answer: 38.6 kJ. Steps: 1. Moles = 46.1/46.07 = 1.00. 2. Multiply: 1.00 x 38.6. 3. Heat = 38.6 kJ.
thermochemistry
Haloalkane class counts carbons on the halogen-bearing carbon: one is primary, three is tertiary.
null
che_0527
concept
en
How are alkyl halides classified?
[ "Count carbons on C-X carbon.", "1 primary, 2 secondary, 3 tertiary.", "Reactivity rises with class in SN1." ]
chemistry
Answer: Primary, secondary, tertiary. Steps: 1. Count carbons on C-X carbon. 2. 1 primary, 2 secondary, 3 tertiary. 3. Reactivity rises with class in SN1.
organic_naming
(CH3)3CBr has three carbons on the C-Br carbon, so it is tertiary.
{ "A": "Primary", "B": "Secondary", "C": "Tertiary", "D": "Aryl" }
che_0528
multiple_choice
en
How is (CH3)3CBr classified?
[ "Count carbons on C-Br: three.", "Three means tertiary.", "Select option C." ]
chemistry
Answer: Tertiary. Steps: 1. Count carbons on C-Br: three. 2. Three means tertiary. 3. Select option C. Answer: (C)
organic_naming
The name is 2-bromopropane: bromine on carbon 2 of three.
null
che_0529
worked_example
en
Name CH3CHBrCH3.
[ "Count 3 carbons.", "Br on carbon 2.", "Name: 2-bromopropane." ]
chemistry
Answer: 2-bromopropane. Steps: 1. Count 3 carbons. 2. Br on carbon 2. 3. Name: 2-bromopropane.
organic_naming
Primární alkohol má -OH na uhlíku s jedním dalším uhlíkem.
null
che_0530
concept
cs
Co je primární alkohol?
[ "-OH na koncovém uhlíku.", "Jeden sousední uhlík.", "Příklad: ethanol." ]
chemistry
Answer: -OH na primárním uhlíku. Steps: 1. -OH na koncovém uhlíku. 2. Jeden sousední uhlík. 3. Příklad: ethanol.
organic_naming
The -OH sits on a carbon with one neighbor, so it is primary.
{ "A": "Primary", "B": "Secondary", "C": "Tertiary", "D": "Phenol" }
che_0531
multiple_choice
en
How is CH3CH2CH2OH classified?
[ "C-OH has one carbon neighbor.", "One neighbor means primary.", "Select option A." ]
chemistry
Answer: Primary. Steps: 1. C-OH has one carbon neighbor. 2. One neighbor means primary. 3. Select option A. Answer: (A)
organic_naming
Alkenes number the chain to give the double bond the lowest locant.
null
che_0532
concept
en
How are alkenes numbered?
[ "Find the double bond.", "Number from nearer end.", "Locant goes before -ene." ]
chemistry
Answer: Lowest locant for C=C. Steps: 1. Find the double bond. 2. Number from nearer end. 3. Locant goes before -ene.
organic_naming
The name is but-2-ene: double bond starting at carbon 2.
null
che_0533
worked_example
en
Name CH3CH=CHCH3.
[ "Count 4 carbons.", "Double bond at carbon 2.", "Name: but-2-ene." ]
chemistry
Answer: But-2-ene. Steps: 1. Count 4 carbons. 2. Double bond at carbon 2. 3. Name: but-2-ene.
organic_naming
Cis-trans isomers differ in substituent sides across a rigid double bond.
null
che_0534
concept
en
What is cis-trans isomerism?
[ "Double bond blocks rotation.", "Same side is cis.", "Opposite side is trans." ]
chemistry
Answer: Sides across C=C. Steps: 1. Double bond blocks rotation. 2. Same side is cis. 3. Opposite side is trans.
organic_naming
Cis means both methyl groups sit on the same side of the bond.
{ "A": "Opposite sides", "B": "Same side", "C": "No stereochemistry", "D": "Ring form" }
che_0535
multiple_choice
en
What does cis-2-butene look like?
[ "Cis means same side.", "Both CH3 together.", "Select option B." ]
chemistry
Answer: Same side. Steps: 1. Cis means same side. 2. Both CH3 together. 3. Select option B. Answer: (B)
organic_naming
CH2=CH2 je ethen.
null
che_0536
worked_example
cs
Pojmenuj sloučeninu CH2=CH2.
[ "Dva uhlíky.", "Dvojná vazba = -en.", "Název: ethen." ]
chemistry
Answer: Ethen. Steps: 1. Dva uhlíky. 2. Dvojná vazba = -en. 3. Název: ethen.
organic_naming
Alkynes use the -yne suffix with the lowest locant for the triple bond.
null
che_0537
concept
en
How are alkynes named?
[ "Find the triple bond.", "Lowest locant applies.", "Suffix is -yne." ]
chemistry
Answer: Lowest locant plus -yne. Steps: 1. Find the triple bond. 2. Lowest locant applies. 3. Suffix is -yne.
organic_naming
HC triple CH with two carbons is ethyne.
{ "A": "Ethene", "B": "Ethane", "C": "Benzene", "D": "Ethyne" }
che_0538
multiple_choice
en
What is the name of HC≡CH?
[ "Two carbons present.", "Triple bond gives -yne.", "Select option D." ]
chemistry
Answer: Ethyne. Steps: 1. Two carbons present. 2. Triple bond gives -yne. 3. Select option D. Answer: (D)
organic_naming
The name is propyne: three carbons with a triple bond.
null
che_0539
worked_example
en
Name CH3C≡CH.
[ "Count 3 carbons.", "Triple bond gives -yne.", "Name: propyne." ]
chemistry
Answer: Propyne. Steps: 1. Count 3 carbons. 2. Triple bond gives -yne. 3. Name: propyne.
organic_naming
Phenyl is the C6H5- group used as a substituent name.
null
che_0540
concept
en
What does phenyl mean in naming?
[ "Benzene minus one H.", "Attaches as substituent.", "Example: phenylamine." ]
chemistry
Answer: C6H5- substituent. Steps: 1. Benzene minus one H. 2. Attaches as substituent. 3. Example: phenylamine.
organic_naming
Fenyl je skupina C6H5- odvozená od benzenu.
null
che_0541
concept
cs
Co je fenyl?
[ "Benzen bez jednoho H.", "Substituent v názvech.", "Příklad: fenylamin." ]
chemistry
Answer: Skupina C6H5-. Steps: 1. Benzen bez jednoho H. 2. Substituent v názvech. 3. Příklad: fenylamin.
organic_naming
The C6H5- fragment is called phenyl.
{ "A": "Phenyl", "B": "Benzyl", "C": "Methyl", "D": "Ethyl" }
che_0542
multiple_choice
en
What is the C6H5- group called?
[ "Benzene ring fragment.", "Named phenyl.", "Select option A." ]
chemistry
Answer: Phenyl. Steps: 1. Benzene ring fragment. 2. Named phenyl. 3. Select option A. Answer: (A)
organic_naming
The name is butanoic acid: four carbons ending in -COOH.
null
che_0543
worked_example
en
Name CH3CH2CH2COOH.
[ "Count 4 carbons.", "-COOH gives -oic acid.", "Name: butanoic acid." ]
chemistry
Answer: Butanoic acid. Steps: 1. Count 4 carbons. 2. -COOH gives -oic acid. 3. Name: butanoic acid.
organic_naming
C6H6 je benzen.
null
che_0544
worked_example
cs
Pojmenuj sloučeninu C6H6.
[ "Šestičlenný kruh.", "Aromatické elektrony.", "Název: benzen." ]
chemistry
Answer: Benzen. Steps: 1. Šestičlenný kruh. 2. Aromatické elektrony. 3. Název: benzen.
organic_naming
Ethers name the smaller group as alkoxy on the larger chain.
null
che_0545
concept
en
How are ethers named systematically?
[ "Smaller part is alkoxy.", "Larger part is parent.", "Example: methoxyethane." ]
chemistry
Answer: Alkoxy plus parent. Steps: 1. Smaller part is alkoxy. 2. Larger part is parent. 3. Example: methoxyethane.
organic_naming
Nucleophilic substitution swaps a leaving group for a nucleophile.
null
che_0546
concept
en
What is nucleophilic substitution?
[ "Nucleophile attacks carbon.", "Leaving group departs.", "SN1 or SN2 pathway." ]
chemistry
Answer: Nu replaces leaving group. Steps: 1. Nucleophile attacks carbon. 2. Leaving group departs. 3. SN1 or SN2 pathway.
organic_mechanisms
SN2 rate depends on both substrate and nucleophile concentrations.
{ "A": "k[RX] only", "B": "k[RX][Nu]", "C": "k[Nu] only", "D": "k always" }
che_0547
multiple_choice
en
What is the SN2 rate law?
[ "One step with both.", "Rate = k[RX][Nu].", "Select option B." ]
chemistry
Answer: k[RX][Nu]. Steps: 1. One step with both. 2. Rate = k[RX][Nu]. 3. Select option B. Answer: (B)
organic_mechanisms
The SN2 rate triples to 3x because rate scales with [Nu].
null
che_0548
worked_example
en
SN2 rate = k[RX][Nu]. What happens if [Nu] triples?
[ "Write: rate = k[RX] x 3[Nu].", "Factor: 3 x k[RX][Nu].", "Rate becomes 3x." ]
chemistry
Answer: Rate triples. Steps: 1. Write: rate = k[RX] x 3[Nu]. 2. Factor: 3 x k[RX][Nu]. 3. Rate becomes 3x.
organic_mechanisms
Nukleofilní substituce nahradí odstupující skupinu nukleofilem.
null
che_0549
concept
cs
Co je nukleofilní substituce?
[ "Nukleofil napadne uhlík.", "Skupina odstoupí.", "Mechanismus SN1 nebo SN2." ]
chemistry
Answer: Náhrada skupiny nukleofilem. Steps: 1. Nukleofil napadne uhlík. 2. Skupina odstoupí. 3. Mechanismus SN1 nebo SN2.
organic_mechanisms
Polar aprotic solvents free nucleophiles and speed SN2.
null
che_0550
concept
en
Which solvents favor SN2?
[ "Nucleophile must stay free.", "Aprotic avoids H-bond cage.", "Examples: acetone, DMSO." ]
chemistry
Answer: Polar aprotic solvents. Steps: 1. Nucleophile must stay free. 2. Aprotic avoids H-bond cage. 3. Examples: acetone, DMSO.
organic_mechanisms