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2018-10-04
Anisotropic electrical and thermal magnetotransport in the magnetic semimetal GdPtBi
The half-Heusler rare-earth intermetallic GdPtBi has recently gained attention due to peculiar magnetotransport phenomena that have been associated with the possible existence of Weyl fermions, thought to arise from the crossings of spin-split conduction and valence bands. On the other hand, similar magnetotransport ph...
1810.02300v3
2019-04-02
Spin pumping and spin torque in interfacial tailored Co2FeAl/\b{eta}-Ta layers
The Heusler ferromagnetic (FM) compound Co2FeAl interfaced with a high-spin orbit coupling non-magnetic (NM) layer is a promising candidate for energy efficient spin logic circuits. The circuit potential depends on the strength of angular momentum transfer across the FM/NM interface; hence, requiring low spin memory lo...
1904.01506v3
2019-04-10
Non-trivial topological valence bands of common diamond and zinc-blende semiconductors
The diamond and zinc-blende semiconductors are well-known and have been widely studied for decades. Yet, their electronic structure still surprises with unexpected topological properties of the valence bands. In this joint theoretical and experimental investigation we demonstrate for the benchmark compounds InSb and Ga...
1904.05063v1
2019-10-30
Magnon spectrum of the Weyl semimetal half-Heusler compound GdPtBi
The compound GdPtBi is known as a material where the non-trivial topology of electronic bands interplays with an antiferromagnetic order, which leads to the emergence of many interesting magnetotransport phenomena. Although the magnetic structure of the compound has previously been reliably determined, the magnetic int...
1910.13845v2
2014-06-03
Design and discovery of a novel Half-Heusler transparent hole conductor made of all-metallic heavy elements
Metallic conductors that are optically transparent represent a rare breed of generally contraindicated physical properties that are nevertheless critically needed for application where both functionalities are crucial. Such rare materials have traditionally been searched in the general chemical neighborhood of compound...
1406.0872v2
2014-06-26
Unusual weak magnetic exchange in two different structure types: YbPt$_2$Sn and YbPt$_2$In
We present the structural, magnetic, thermodynamic, and transport properties of the two new compounds YbPt$_2$Sn and YbPt$_2$In. X-ray powder diffraction shows that they crystallize in different structure types, the hexagonal ZrPt$_2$Al and the cubic Heusler type, respectively. Despite quite different lattice types, bo...
1406.6800v2
2018-08-16
Tunnel magneto-Seebeck effect
The interplay of charge, spin and heat transport is investigated in the fascinating research field of spin caloritronics, the marriage of spintronics and thermoelectrics. Here, many new spin-dependent thermal transport phenomena in magnetic nanostructures have been explored in the recent years. One of them is the tunne...
1808.05638v2
2019-02-20
On the inexistence of solitons in Einstein-Maxwell-scalar models
Three non-existence results are established for self-gravitating solitons in Einstein-Maxwell-scalar models, wherein the scalar field is, generically, non-minimally coupled to the Maxwell field via a scalar function $f(\Phi)$. Firstly, a trivial Maxwell field is considered, which yields a consistent truncation of the f...
1902.07721v3
2019-06-14
Stability of Long-lived Antiskyrmions in Mn-Pt-Sn Material
The lifetime of antiskyrmions at room temperature in a Mn-Pt-Sn tetragonal Heusler material has been calculated using an atomic scale representation including nearly a million spins. The evaluation of the pre-exponential factor in the Arrhenius rate expression for this large system is made possible by an implementation...
1906.06383v5
2022-02-04
Bipolar conduction asymmetries lead to ultra-high thermoelectric power factor
Low band gap thermoelectric materials suffer from bipolar effects at high temperatures, with increased electronic thermal conductivity and reduced Seebeck coefficient, leading to reduced power factor and low ZT figure of merit. In this work we show that the presence of strong transport asymmetries between the conductio...
2202.02128v1
2022-03-04
In-situ nitriding of Fe2VAl during laser surface remelting to manipulate microstructure and crystalline defects
Tailoring the physical properties of complex materials for targeted applications requires optimizing the microstructure and crystalline defects that influence electrical and thermal transport, and mechanical properties. Laser surface remelting can be used to modify the sub-surface microstructure of bulk materials and h...
2203.02209v1
2016-03-03
Room-temperature magnetic topological semimetal state in half-metallic Heusler Co$_2$TiX (X=Si, Ge, or Sn)
Topological semimetals (TSMs) including Weyl semimetals and nodal-line semimetals are expected to open the next frontier of condensed matter and materials science. Although the first inversion breaking Weyl semimetal was recently discovered in TaAs, its magnetic counterparts, i.e., the time-reversal breaking Weyl and n...
1603.01255v3
2016-12-10
Chaos and regularity in the doubly magic nucleus 208Pb
High resolution experiments have recently lead to a complete identification (energy, spin, and parity) of 151 nuclear levels up to an excitation Energy of Ex= 6.20 MeV in 208Pb. We present a thorough study of the fluctuation properties in the energy spectra of the unprecedented set of nuclear bound states. In a first a...
1612.03260v1
2019-05-24
A first-principles investigation of Topological Phase Transition in face-centred cubic LiMgBi
Topological Insulators (TI) exhibit robust spin-locked dissipationless Fermion transport along the surface states. In the current study, we use \textit{first-principles} calculations to investigate a Topological Phase Transition (TPT) in a Half-Heusler (HH) compound LiMgBi driven by a Volume Expansive Pressure (VEP) wh...
1905.10103v2
2019-09-04
Exploring Disorder in the Spin Gapless Semiconductor Mn$_2$CoAl
Since the prediction of spin-gapless semiconducting behaviour in the Heusler compound Mn$_2$CoAl, evidence of spin-gapless behaviour in thin films has typically been inferred from magnetotransport measurements. The spin gapless state is however fragile, and further, band structure calculations indicate that even a smal...
1909.02153v1
2019-12-13
Shallow impurity band in ZrNiSn
ZrNiSn and related half Heusler compounds are candidate materials for efficient thermoelectric energy conversion with a reported thermoelectric figure-of-merit of n-type ZrNiSn exceeding unity. Progress on p-type materials has been more limited, which has been attributed to the presence of an impurity band, possibly re...
1912.06539v1
2019-12-20
Defect charging and resonant levels in half-Heusler Nb$_{1-x}$Ti$_x$FeSb
We report $^{93}$Nb and $^{121}$Sb NMR and $^{57}$Fe M\"{o}ssbauer studies combined with DFT calculations of Nb$_{1-x}$Ti$_x$FeSb ($0\leqslant x \leqslant0.3$), one of the most promising thermoelectric systems for applications above 1000 K. These studies provide local information about defects and electronic configurat...
1912.09643v3
2020-03-18
Neutron diffraction and symmetry analysis of the martensitic transformation in Co-doped Ni$_2$MnGa
Martensitic transformations are strain driven displacive transitions governing the mechanical and physical properties in intermetallic materials. This is the case in Ni$_2$MnGa, where the martensite transition is at the heart of the striking magnetic shape memory and magneto-caloric properties. Interestingly, the marte...
2003.08261v1
2020-07-27
Role of magnetic exchange interactions in chiral-type Hall effects of epitaxial Mn$_{x}$PtSn films
Tetragonal Mn-based Heusler compounds feature rich exchange interactions and exotic topological magnetic textures, such as antiskyrmions, complimented by the chiral-type Hall effects. This makes the material class interesting for device applications. We report the relation of the magnetic exchange interactions to the t...
2007.13412v1
2021-01-22
Structural and transport properties of 4f electron doped Y1-x(Dy)xPdBi topological semi-metallic thin films
We report the effect of 4f electron doping on structural, electrical and magneto-transport properties of Dy doped half Heusler Y1-x(Dy)xPdBi (x =0, 0.2, 0.5, 1) thin films grown by pulsed laser deposition. The Dy doping leads to lattice contraction which increases from 0% for the parent x =0 sample to approx 1.3% for x...
2101.09185v2
2021-01-29
Room-temperature antiskyrmions and sawtooth surface textures in a noncentrosymmetric magnet with $S_4$ symmetry
Topological spin textures have attracted much attention both for fundamental physics and spintronics applications. Among them, antiskyrmions possess a unique spin configuration with Bloch-type and N\'eel-type domain walls due to anisotropic Dzyaloshinskii-Moriya interaction (DMI) in the noncentrosymmetric crystal struc...
2101.12359v1
2021-02-25
Unidirectional magnetoresistance and spin-orbit torque in NiMnSb
Spin-dependent transport phenomena due to relativistic spin-orbit coupling and broken space-inversion symmetry are often difficult to interpret microscopically, in particular when occurring at surfaces or interfaces. Here we present a theoretical and experimental study of spin-orbit torque and unidirectional magnetores...
2102.12838v1
2021-10-11
Absolute calibration of the latent heat of transition using differential thermal analysis
We describe a simple and accurate differential thermal analysis set up to measure the latent heat of solid state materials undergoing abrupt phase transitions in the temperature range from 77 K to above room temperature. We report a numerical technique for the absolute calibration of the latent heat of the transition, ...
2110.05046v1
2021-11-20
Skyrmionics in correlated oxides
While chiral magnets, metal-based magnetic multilayers, or Heusler compounds have been considered as the material workhorses in the field of skyrmionics, oxides are now emerging as promising alternatives, as they host special correlations between the spin-orbital-charge-lattice degrees of freedom and/or coupled ferroic...
2111.10562v2
2021-11-28
CoFeVSb: A Promising Candidate for Spin Valve and Thermoelectric Applications
We report a combined theoretical and experimental study of a novel quaternary Heusler system CoFeVSb from the view point of room temperature spintronics and thermoelectric applications. It crystallizes in cubic structure with small DO$_3$-type disorder. The presence of disorder is confirmed by room temperature synchrot...
2111.14081v1
2022-04-19
Thermoelectric properties of Fe$_{2}$VAl at high temperature region: A combined experimental and theoretical study
Heusler type compounds have long been recognized as potential thermoelectric (TE) materials. Here, the experimentally observed TE properties of Fe$_{2}$VAl are understood through electronic structure calculations in the temperature range of $300-800$ K. The observed value of $S$ is $\sim-$138 $\mu$V/K at 300 K. Then, t...
2204.08654v1
2022-08-24
The type-I antiferromagnetic Weyl semimetal InMnTi$_2$
Topological materials have been a main focus of studies in the past decade due to their protected properties that can be exploited for the fabrication of new devices. Among them, Weyl semimetals are a class of topological semimetals with non-trivial linear band crossing close to the Fermi level. The existence of such c...
2208.11412v3
2023-01-03
Ab-initio study of phononic thermal conduction in ScAgC half-Heusler
We present a first-principles lattice calculations to comprehend the thermal expansion $\alpha(T)$ and lattice thermal conductivity $\kappa_{ph}$ of ScAgC. The obtained positive frequencies of phonon dispersion shows the dynamical stability of ScAgC in FCC structure. The estimated $\alpha(T)$ from quasi-harmonic approx...
2301.01029v1
2023-01-19
Ab initio comparison of spin-transport properties in MgO-spaced ferrimagnetic tunnel junctions based on Mn$_3$Ga and Mn$_3$Al
We report on first-principles spin-polarised quantum transport calculations (from NEGF+DFT) in MgO-spaced magnetic tunnel junctions (MTJs) based on two different Mn-based Heusler ferrimagnetic metals, namely Mn$_3$Al and Mn$_3$Ga in their tetragonal DO$_{22}$ phase. The former is a fully compensated half-metallic ferri...
2301.08300v1
2023-02-13
The impact of an interactive visualization and simulation tool on learning quantum physics: Results of an eye-tracking study
Employing scientific practices to obtain and use information is one of the central facets of next generation science standards. Especially in quantum technology education, the ability to employ such practices is an essential skill to foster both academic success and technological development. In order to help educators...
2302.06286v1
2023-08-20
A Framework for Curriculum Transformation in Quantum Information Science and Technology Education
The field of Quantum Information Science and Technology (QIST) is booming. Due to this, many new educational courses and university programs are needed in order to prepare a workforce for the developing industry. Owing to its specialist nature, teaching approaches in this field can suffer with being disconnected from t...
2308.10371v2
1994-10-19
Ab initio simulations of liquid NaSn alloys: Zintl anions and network formation
Using the Car-Parrinello technique, ab initio molecular dynamics simulations are performed for liquid NaSn alloys in five different compositions (20, 40, 50, 57 and 80 % sodium). The obtained structure factors agree well with the data from neutron scattering experiments. The measured prepeak in the structure factor is ...
9410074v1
1995-08-25
Relaxation of Thermoremanent Magnetization in Different Magnetic Phases Of Fe-rich $\mbox{$γ$}$-FeNiCr Alloys
The time decay of the thermoremanent magnetization(TRM) of the $\mbox{Fe}_{80-\mbox{x}}\mbox{Ni}_{\mbox{x}}\mbox{Cr}_{20}$ ($14\leq \mbox{x} \leq 30$) alloys has been measured for four different magnetic phases within the fcc $\mbox{$\gamma$}$-phase using a SQUID magnetometer. In the spin-glass phase(SG)(X=19) very dis...
9508116v1
1995-09-27
Numerical Studies on the Magnetism of Fe-Ni-Mn Alloys in the Invar Region
By means of self-consistent semi-empirical LCAO calculations we study the itinerant magnetism of (Fe_{0.65}Ni_{0.35})_{1-y} Mn_y alloys for y between 0 and 0.22 at T=0 K, neglecting only the transverse spin components. We find that the magnetic behaviour is quite complicated on a local scale. In addition to ferromagnet...
9509167v1
1996-03-07
Droplet Free Energy Functional for the Morphology of Martensites
Martensites are metastable phases, possessing a characteristic morphology, usually formed during a fast quench accross a structural transition. We attempt to understand these morphological features using a coarsegrained free energy functional ${\cal F}[\epsilon ; \Phi]$ which contains, in addition to the usual strain f...
9603049v1
1996-09-25
Surface Critical Behavior of Binary Alloys and Antiferromagnets: Dependence of the Universality Class on Surface Orientation
The surface critical behavior of semi-infinite (a) binary alloys with a continuous order-disorder transition and (b) Ising antiferromagnets in the presence of a magnetic field is considered. In contrast to ferromagnets, the surface universality class of these systems depends on the orientation of the surface with r...
9609245v2
1996-12-17
Kondo disorder: a possible route towards non-Fermi liquid behavior
We present a general model of disorder in Kondo alloys that, under certain conditions, leads to non-Fermi liquid behavior. The central underlying idea is the presence of a distribution of local Kondo temperature scales. If this distribution is broad enough, such that there are sites with arbitrarily low Kondo temperatu...
9612160v1
1997-03-10
Kinetics of Joint Ordering and Decomposition in Binary Alloys
We study phase segregation in a model alloy undergoing both ordering and decomposition, using computer simulations of Kawasaki exchange dynamics on a square lattice. Following a quench into the miscibility gap we observe an early stage in which ordering develops while the composition remains almost uniform. Then decomp...
9703094v1
1997-04-02
Effect of the vacancy interaction on the antiphase domain growth process in a two dimensional binary alloy
The influence of diffusing vacancies on the antiphase domain growth process in a binary alloy is studied by Monte Carlo simulations. The system is modelled by means of a Blume-Emery-Griffiths hamiltonian with a biquadratic coupling parameter K controlling the microscopic interactions between vacancies. We obtain that, ...
9704013v1
1997-07-29
Spin-Orbit-Induced Magnetic Anisotropy for Impurities in Metallic Samples II. Finite Size Dependence in the Kondo Resistivity
The electrical resistivity including the Kondo resistivity increase at low temperature is calculated for thin films of dilute magnetic alloys. Assuming that in the non-magnetic host the spin-orbit interaction is strong like in Au and Cu, the magnetic impurities have a surface anisotropy calculated in part I. That aniso...
9707299v1
1997-07-31
Surface critical behavior of bcc binary alloys
The surface critical behavior of bcc binary alloys undergoing a continuous B2-A2 order-disorder transition is investigated in the mean-field (MF) approximation. Our main aim is to provide clear evidence for the fact that surfaces which break the two-sublattice symmetry generically display the critical behavior of the N...
9707345v1
1997-09-10
Thermal and Mechanical Properties of some FCC Transition Metals and their Binary Alloys
The temperature dependence of thermodynamic and mechanical properties of six fcc transition metals (Ni, Cu, Ag, Au, Pt, Rh) and the alloying behavior of Ag-Au and Cu-Ni are studied using molecular dynamics (MD). The structures are described at elevated temperatures by the force fields developed by Sutton and co-workers...
9709114v1
1997-10-08
Theory for the electromigration wind force in dilute alloys
A multiple scattering formulation for the electromigration wind force on atoms in dilute alloys is developed. The theory describes electromigration via a vacancy mechanism. The method is used to calculate the wind valence for electromigration in various host metals having a close-packed lattice structure, namely alumin...
9710072v1
1997-10-13
Non-Fermi liquid behavior and Griffiths phase in {\it f}-electron compounds
We study the interplay among disorder, RKKY and Kondo interactions in {\it f}-electron alloys. We argue that the non-Fermi liquid behavior observed in these systems is due to the existence of a Griffiths phase close to a quantum critical point. The existence of this phase provides a unified picture of a large class of ...
9710123v2
1998-02-19
Ferroelectric effects in PZT
First-principles calculations are performed to investigate alloying and ferroelectric effects in lead zirconate titanate (PZT) with high Ti composition. We find that the main effect of alloying in the paraelectric phase of PZT is the existence of two sets of B-O bonds, i.e., shorter Ti-O bonds vs. longer Zr-O bonds. On...
9802209v1
1998-03-13
The Electromigration Force in Metallic Bulk
The voltage induced driving force on a migrating atom in a metallic system is discussed in the perspective of the Hellmann-Feynman force concept, local screening concepts and the linear-response approach. Since the force operator is well defined in quantum mechanics it appears to be only confusing to refer to the Hellm...
9803172v1
1998-06-07
Volume changes in binary alloy ordering, a binary classical density functional theory approach
The chemical ordering transition in a binary alloy is examined using classical density functional theory for a binary mixture. The ordered lattice is assumed to be obtained from the disordered lattice by a volume change only, as in L1_2 ordering from an face centered cubic chemically disordered crystal. Using the simpl...
9806093v1
1998-07-15
Exactly solvable toy models of unconventional magnetic alloys: Bethe Ansatz versus Renormalization Group method
We propose toy models of unconventional magnetic alloys, in which the density of band states, $\rho(\epsilon)$, and hybridization, $t(\epsilon)$, are energy dependent; it is assumed, however, that $t^2(\epsilon)\propto\rho^{-1}(\epsilon)$, and hence an effective electron-impurity coupling $\Gamma(\epsilon)=\rho(\epsilo...
9807231v2
1998-10-28
Theory of Doping and Defects in III-V Nitrides
Doping problems in GaN and in AlGaN alloys are addressed on the basis of state-of-the-art first-principles calculations. For n-type doping we find that nitrogen vacancies are too high in energy to be incorporated during growth, but silicon and oxygen readily form donors. The properties of oxygen, including DX-center fo...
9810385v1
1999-02-10
Non-Fermi Liquid Behavior in a Disordered Kondo Alloy Model
We study a mean-field model of a Kondo alloy using numerical techniques and analytic approximations. In this model, randomly distributed magnetic impurities interact with a band of conduction electrons and have a residual RKKY coupling of strength $J$. This system has a quantum critical point at $J=J_{c} \sim T_{K}^0$,...
9902139v2
1999-03-03
Theory of magnetoresistance in films of dilute magnetic alloys
Earlier a magnetic anisotropy for magnetic impurities nearby the surface of non-magnetic host was proposed in order to explain the size dependence of the Kondo effect in dilute magnetic alloys. Recently Giordano has measured the magnetoresistance of dilute Au(Fe) films for different thicknesses well above the Kondo tem...
9903054v2
1999-05-14
Magnetic hysteresis in the Cu-Al-Mn intermetallic alloy: experiments and modeling
We study isothermal magnetization processes in the Cu-Al-Mn intermetallic alloy. Hysteresis is observed at temperatures below the spin-freezing of the system. The characteristics of the hysteresis cycles as a function of temperature and Mn content (magnetic element) are obtained. At low temperature (5 K) a change from ...
9905204v1
1999-06-18
Spinodal decomposition of an ABv model alloy: Patterns at unstable surfaces
We develop mean-field kinetic equations for a lattice gas model of a binary alloy with vacancies (ABv model) in which diffusion takes place by a vacancy mechanism. These equations are applied to the study of phase separation of finite portions of an unstable mixture immersed in a stable vapor. Due to a larger mobility ...
9906301v1
1999-08-09
Magnetic anisotropy, first-order-like metamagnetic transitions and large negative magnetoresistance in the single crystal of Gd$_{2}$PdSi$_3$
Electrical resistivity ($\rho$), magnetoresistance (MR), magnetization, thermopower and Hall effect measurements on the single crystal Gd$_{2}$PdSi$_3$, crystallizing in an AlB$_2$-derived hexagonal structure are reported. The well-defined minimum in $\rho$ at a temperature above N\'eel temperature (T$_N$= 21 K) and la...
9908128v1
1999-08-25
The virtual crystal approximation revisited: Application to dielectric and piezoelectric properties of perovskites
We present an approach to the implementation of the virtual crystal approximation (VCA) for the study of properties of solid solutions in the context of density-functional methods. Our approach can easily be applied to any type of pseudopotential, and also has the advantage that it can be used to obtain estimates of th...
9908364v1
1999-11-18
Local structure of In_(0.5)Ga_(0.5)As from joint high-resolution and differential pair distribution function analysis
High resolution total and indium differential atomic pair distribution functions (PDFs) for In_(0.5)Ga_(0.5)As alloys have been obtained by high energy and anomalous x-ray diffraction experiments, respectively. The first peak in the total PDF is resolved as a doublet due to the presence of two distinct bond lengths, In...
9911293v1
2000-01-10
Connection between charge transfer and alloying core-level shifts based on density-functional calculations
The measurement of alloying core-level binding energy (CLBE) shifts has been used to give a precise meaning to the fundamental concept of charge transfer. Here, ab-initio density-functional calculations for the intermetallic compound MgAu are used to investigate models which try to make a connection between the core le...
0001099v1
2000-01-12
Incommensurate and Commensurate Antiferromagnetic Spin Fluctuations in Cr and Cr Alloys from Ab Initio Dynamical Spin Susceptibility Calculations
A scheme for making ab-initio calculations of the dynamic paramagnetic spin susceptibilities of solids at finite temperatures is described. It is based on Time-Dependent Density Functional Theory and employs an electronic multiple scattering formalism. Incommensurate and commensurate anti-ferromagnetic spin fluctuation...
0001160v1
2000-04-06
Peculiarities of structural changes in Pd and Pd-alloys
It has been discovered that kinetics of structural changes in Pd and Pd-alloys under the influence of dissolved hydrogen seems to be non-trivial. As a rule, structural changes in these systems include correlation changes of co-existing phases concentration and the defect structure character. These changes have the stag...
0004097v1
2000-05-08
Fermi Surface Properties of Low Concentration Ce$_{x}$La$_{1-x}$B$_{6}$: dHvA
The de Haas-van Alphen effect is used to study angular dependent extremal areas of the Fermi Surfaces (FS) and effective masses of Ce$_{x}$La$_{1-x}$B$% _{6}$ alloys for $x$ between 0 and 0.05. The FS of these alloys was previously observed to be spin polarized at low Ce concentration ($x$ = 0.05). This work gives the ...
0005147v1
2000-05-24
An anomalous alloy: Y_x Si_{1-x}
We study via density functional-based molecular dynamics the structural and dynamical properties of the rare earth silicon amorphous alloy Y_xSi_{1-x} for x=0.093 and x=0.156. The Si network forms cavities in which a Y^{3+} cation is entrapped. Its electrons are transferred to the Si network and are located in the dang...
0005411v1
2000-05-28
Details of disorder matter in 2D d-wave superconductors
We demonstrate that discrepancies between predicted low-energy quasiparticle properties in disordered 2D d-wave superconductors occur because of the unanticipated importance of disorder model details and normal-state particle-hole symmetry. This conclusion follows from numerically exact evaluations of the quasiparticle...
0005487v1
2000-06-16
Spin fluctuations in nearly magnetic metals from ab-initio dynamical spin susceptibility calculations:application to Pd and Cr95V5
We describe our theoretical formalism and computational scheme for making ab-initio calculations of the dynamic paramagnetic spin susceptibilities of metals and alloys at finite temperatures. Its basis is Time-Dependent Density Functional Theory within an electronic multiple scattering, imaginary time Green function fo...
0006268v1
2000-06-26
Computer simulation of the microstructure and rheology of semi-solid alloys under shear
The rheological behavior of metallic alloys containing both solid and liquid phases is investigated in the low solid fraction range (<50%). This behavior depends on both the solid fraction and the shear rate. The concept of Effective Volume Fraction (EVF) is used to decorrelate the influence of these two parameters. At...
0006405v1
2000-07-18
Shape-induced magnetic anisotropy in dilute magnetic alloys
We extend the theory of the surface-induced magnetic anisotropy to mesoscopic samples with arbitrary geometry. The shape-induced anisotropy of impurity spins in small brick-shaped grains of dilute magnetic alloys is studied in detail. The surface-induced blocking of a magnetic-impurity spin is shown to be very sensitiv...
0007294v1
2000-08-31
Ab Initio Molecular Dynamics Simulation of Liquid Ga_xAs_{1-x} Alloys
We report the results of ab initio molecular dynamics simulations of liquid Ga_xAs_{1-x} alloys at five different concentrations, at a temperature of 1600 K, just above the melting point of GaAs. The liquid is predicted to be metallic at all concentrations between x = 0.2 and x = 0.8, with a weak resistivity maximum ne...
0008467v1
2000-10-27
Dynamics of mesoscopic precipitate lattices in phase separating alloys under external load
We investigate, via three-dimensional atomistic computer simulations, phase separation in an alloy under external load. A regular two-dimensional array of cylindrical precipitates, forming a mesoscopic precipitate lattice, evolves in the case of applied tensile stress by the movement of mesoscopic lattice defects. A st...
0010439v1
2000-11-20
Exchange Effects in the Invar Hardening: $Fe_{0.65}Ni_{0.35}$ as a test case
An increase of the critical resolved shear stress of Invar alloys (Invar hardening) with a lowering temperature is explained. The effect is caused by a growth of the exchange interaction between dangling $d$-electron states of dislocation cores and paramagnetic obstacles (e.g., Ni atoms in FeNi alloys) which occurs bel...
0011325v1
2000-11-29
Spontaneous alloying in binary metal microclusters - A molecular dynamics study -
Microcanonical molecular dynamics study of the spontaneous alloying(SA), which is a manifestation of fast atomic diffusion in a nano-sized metal cluster, is done in terms of a simple two dimensional binary Morse model. Important features observed by Yasuda and Mori are well reproduced in our simulation. The temperature...
0011481v2
2000-12-20
Glassy Spin Dynamics in Non-Fermi-Liquid UCu_{5-x}Pd_x, x = 1.0 and 1.5
Local f-electron spin dynamics in the non-Fermi-liquid heavy-fermion alloys UCu_{5-x}Pd_x, x = 1.0 and 1.5, have been studied using muon spin-lattice relaxation. The sample-averaged asymmetry function Gbar(t) indicates strongly inhomogeneous spin fluctuations, and exhibits the scaling Gbar(t,H) = Gbar(t/H^\gamma) expec...
0012389v2
2000-12-28
Hybridization Mechanism for Cohesion of Cd-based Quasicrystals
Cohesion mechanism of cubic approximant crystals of newly discovered binary quasicrystals, Cd$_6$M (M=Yb and Ca), are studied theoretically. It is found that stabilization due to alloying is obtained if M is an element with low-lying unoccupied $d$ states. This leads to conclusion that the cohesion of the Cd-based comp...
0012485v3
2001-02-26
Transformation Kinetics on Mechanical Alloying
We propose and develop a model as an attempt to describe the local mechanism of mechanical alloying. This model is based on the observation of global parameters, such as the volumes of the various phases present in the material, and their transformations during the process. The model is applied to milled Fe-Cu and Fe-N...
0102465v3
2001-03-13
Monte Carlo simulation of subsurface ordering kinetics in an fcc-alloy model
Within the atom-vacancy exchange mechanism in a nearest-neighbor interaction model we investigate the kinetics of surface-induced ordering processes close to the (001) surface of an fcc A_3B-alloy. After a sudden quench into the ordered phase with a final temperature above the ordering spinodal, T_f > T_sp, the early t...
0103271v2
2001-03-29
Evolution of Nanoporosity in Dealloying
Dealloying is a common corrosion process during which an alloy is "parted" by the selective dissolution of the electrochemically more active elements. This process results in the formation of a nanoporous sponge composed almost entirely of the more noble alloy constituents . Even though this morphology evolution proble...
0103615v1
2001-04-27
Effects of C, Cu and Be substitutions in superconducting MgB2
Density functional calculations are used to investigate the effects of partial substitutional alloying of the B site in MgB2 with C and Be alone and combined with alloying of the Mg site with Cu. The effect of such substitutions on the electronic structure, electron phonon coupling and superconductivity are discussed. ...
0104548v1
2001-05-03
Magnetic phase separation in ordered alloys
We present a lattice model to study the equilibrium phase diagram of ordered alloys with one magnetic component that exhibits a low temperature phase separation between paramagnetic and ferromagnetic phases. The model is constructed from the experimental facts observed in Cu$_{3-x}$AlMn$_{x}$ and it includes coupling b...
0105055v1
2001-06-03
Ferromagnetic transition in a double-exchange system with alloy disorder
We study ferromagnetic transition in three-dimensional double-exchange model containing impurities. The influence of both spin fluctuations and impurity potential on conduction electrons is described in coherent potential approximation. In the framework of thermodynamic approach we construct Landau functional for the s...
0106032v1
2001-07-12
Augmented space recursion for partially disordered systems
Off-stoichiometric alloys exhibit partial disorder, in the sense that only some of the sublattices of the stoichiometric ordered alloy become disordered. This paper puts forward a generalization of the augmented space recursion (ASR) (introduced earlier by one of us (Mookerjee et al 1997(*))) for systems with many atom...
0107245v1
2001-11-09
Growth and Properties of Quaternary Alloy Magnetic Semiconductor (InGaMn)As
We have studied growth and properties of quaternary alloy magnetic semiconductor (InGaMn)As grown both on GaAs substrates and on InP substrates by low-temperature molecular-beam epitaxy (LT-MBE). (InGaMn)As thin films were ferromagnetic below ~30 K, exhibiting strong magneto-optical effect. The lattice constant of [(In...
0111163v1
2001-11-21
Structural and Superconducting Transitions in Mg_{1-x}Al_{x}B_2
From systematic ab initio calculations of the alloy system Mg_{1-x}Al_{x}B_2, we find a strong tendency for the formation of a superstructure characterized by Al-rich layers. We also present a simple model, based on calculated energies and an estimate of the configurational entropy, which suggests that the alloy has tw...
0111392v3
2002-01-08
Anisotropic, Fermi-Surface-Induced Variation in T_c in MgB_2 Alloys
Using coherent-potential to describe disorder, Gaspari-Gyorffy approach to evaluate electron-phonon coupling, and Allen-Dynes equation to calculate T_c, we show that in Mg_{1-x}M_{x}B_{2} (M = Al,Li or Zn) alloys (i) the way T_c changes depends on the location of the added/modified k-resolved states on the Fermi surfac...
0201093v1
2002-01-08
Effects of Disorder in Mg_{1-x}Ta_{x}B_2 Alloys using Coherent-Potential Approximation
Using Korringa-Kohn-Rostoker coherent-potential approximation in the atomic-sphere approximation (KKR-ASA CPA) method for taking into account the effects of disorder, Gaspari-Gyorffy formalism for calculating the electron-phonon coupling constant $\lambda$, and Allen-Dynes equation for calculating T_c, we have studied ...
0201094v2
2002-02-26
First-order transition between a small-gap semiconductor and a ferromagnetic metal in the isoelectronic alloys FeSi$_{1-x}$Ge$_x$
The contrasting groundstates of isoelectronic and isostructural FeSi and FeGe can be explained within an extended local density approximation scheme (LDA+U) by an appropriate choice of the onsite Coulomb repulsion, $U$ on the Fe-sites. A minimal two-band model with interband interactions allows us to obtain a phase dia...
0202474v1
2002-03-18
Above-Room-Temperature Ferromagnetism in GaSb/Mn Digital Alloys
Digital alloys of GaSb/Mn have been fabricated by molecular beam epitaxy. Transmission electron micrographs showed good crystal quality with individual Mn-containing layers well resolved; no evidence of 3D MnSb precipitates was seen in as-grown samples. All samples studied exhibited ferromagnetism with temperature depe...
0203361v1
2002-05-23
Instability and decomposition on the surface of strained alloy films
A continuum dynamical model is developed to determine the morphological and compositional instabilities on the free surface of heteroepitaxial alloy films in the absence of growth. We use linear stability analysis to study the early nonequilibrium processes of surface evolution, and calculate the stability conditions a...
0205493v1
2002-05-27
Microscopical derivation of Ginzburg-Landau-type functionals for alloys and their application to studies of antiphase and interphase boundaries
The earlier-described cluster methods are used to generalize the Ginzburg-Landau gradient expansion for the free energy of an inhomogeneous alloy to the case of not small values of order parameters and variations of composition. The results obtained reveale a number of important differences with the expressions used in...
0205573v3
2002-06-26
Comparative Study of Dense Bulk MgB$_2$ Materials Prepared by Different Methods
We report on the results of a comparative investigation of highly dense bulk MgB$_2$ samples prepared by three methods: (i) hot deformation; (ii) high pressure sintering; and (iii) mechanical alloying of Mg and B powders with subsequent hot compaction. All types of samples were studied by ac-susceptibility, dc-magnetiz...
0206513v1
2002-09-24
The pseudo-binary mercury chalcogenide alloy HgSe0.7S0.3 at high pressure: a mechanism of the zinc blende/cinnabar reconstructive phase transition
The structure of the pseudo-binary mercury chalcogenide alloy HgSe0.7S0.3 has been studied by means of X-ray and neutron powder diffraction at pressures up to 8.5 GPa. A phase transition from the cubic zinc blende structure to the hexagonal cinnabar structure was observed at P ~ 1 GPa. A phenomenological model of this ...
0209548v2
2002-09-30
Magnetotransport properties of a polarization-doped three-dimensional electron slab
We present evidence of strong Shubnikov-de-Haas magnetoresistance oscillations in a polarization-doped degenerate three-dimensional electron slab in an Al$_{x}$Ga$_{1-x}$N semiconductor system. The degenerate free carriers are generated by a novel technique by grading a polar alloy semiconductor with spatially changing...
0209664v2
2002-10-14
Ferromagnetism and Metal-Insulator Transition in the Disordered Hubbard Model
A detailed study of the paramagnetic to ferromagnetic phase transition in the one-band Hubbard model in the presence of binary alloy disorder is presented. The influence of the disorder (with concentration $x$ and $1-x$ of the two alloy ions) on the Curie temperature $T_{c}$ is found to depend strongly on electron dens...
0210296v1
2002-11-14
Synthesis and Properties of YbB2
We report temperature and field dependent measurements of the magnetic susceptibility, specific heat and resistivity of sintered YbB2 pellets, prepared via two distinct reaction routes, utilizing different temperatures, pressures and sintering times. Sample behavior is affected by the preparation procedure, as a conseq...
0211288v1
2002-11-18
Optimizing thermal transport in the Falicov-Kimball model: binary-alloy picture
We analyze the thermal transport properties of the Falicov-Kimball model concentrating on locating regions of parameter space where the thermoelectric figure-of-merit ZT is large. We focus on high temperature for power generation applications and low temperature for cooling applications. We constrain the static particl...
0211385v1
2002-12-18
Coexistence of ferro- and antiferromagnetic order in Mn-doped Ni$_2$MnGa
Ni-Mn-Ga is interesting as a prototype of a magnetic shape-memory alloy showing large magnetic field induced strains. We present here results for the magnetic ordering of Mn-rich Ni-Mn-Ga alloys based on both experiments and theory. Experimental trends for the composition dependence of the magnetization are measured by...
0212442v1
2003-02-03
Bonding in MgSi and AlMgSi Compounds Relevant to AlMgSi Alloys
The bonding and stability of MgSi and AlMgSi compounds relevant to AlMgSi alloys is investigated with the use of (L)APW+(lo) DFT calculations. We show that the $\beta$ and $\beta''$ phases found in the precipitation sequence are characterised by the presence of covalent bonds between Si-Si nearest neighbour pairs and c...
0302027v1
2003-02-05
Using bond-length dependent transferable force constants to predict vibrational entropies in Au-Cu, Au-Pd, and Cu-Pd alloys
A model is tested to rapidly evaluate the vibrational properties of alloys with site disorder. It is shown that length-dependent transferable force constants exist, and can be used to accurately predict the vibrational entropy of substitutionally ordered and disordered structures in Au-Cu, Au-Pd, and Cu-Pd. For each re...
0302109v1
2003-04-17
The three-dimensional Anderson model of localization with binary random potential
We study the three-dimensional two-band Anderson model of localization and compare our results to experimental results for amorphous metallic alloys (AMA). Using the transfer-matrix method, we identify and characterize the metal-insulator transitions as functions of Fermi level position, band broadening due to disorder...
0304390v1
2003-04-24
Room Temperature Electrochemical Synthesis of Hg-1212 Superconducting Thin Films
In the present investigation, the novel two-step electrochemical process of room temperature synthesis of Hg-1212 superconducting films has been developed and reported first time. Electrochemical parameters were optimized by studying cyclic voltammetry (CV), linear sweep voltammetry (LSV) and chronoamperometry (CA) for...
0304566v1
2003-07-01
Growth and properties of ferromagnetic In(1-x)Mn(x)Sb alloys
We discuss a new narrow-gap ferromagnetic (FM) semiconductor alloy, In(1-x)Mn(x)Sb, and its growth by low-temperature molecular-beam epitaxy. The magnetic properties were investigated by direct magnetization measurements, electrical transport, magnetic circular dichroism, and the magneto-optical Kerr effect. These data...
0307032v1
2003-07-09
Frequency Dependence of Magnetoelectric Interactions in Layered Structures of Ferromagnetic Alloys and Piezoelectric Oxides
Magnetoelectric (ME) interactions in layered structures of magnetostrictive and piezoelectric phases are mediated by mechanical deformation. Here we discuss the frequency dependence of ME coupling in bilayers and trilayers of Permendur, a ferromagnetic alloy, and lead zirconate titanate. Data on ME voltage coefficient ...
0307208v1
2003-07-29
Vibrational properties of phonons in random binary alloys: An augmented space recursive technique in the k-representation
We present here an augmented space recursive technique in the k-representation which include diagonal, off-diagonal and the environmental disorder explicitly : an analytic, translationally invariant, multiple scattering theory for phonons in random binary alloys.We propose the augmented space recursion (ASR) as a compu...
0307697v2