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2019-08-29
Evidence for weak antilocalization-weak localization crossover and metal-insulator transition in CaCu$_{3}$Ru$_{4}$O$_{12}$ thin films
Artificial confinement of electrons by tailoring the layer thickness has turned out to be a powerful tool to harness control over competing phases in nano-layers of complex oxides. We investigate the effect of dimensionality on transport properties of $d$-electron based heavy-fermion metal CaCu$_{3}$Ru$_{4}$O$_{12}$. Transport behavior evolves from metallic to localized regime upon reducing thickness and a metal insulator transition is observed below 3 nm film thickness for which sheet resistance crosses $h/e^{2} \sim 25~$k$\Omega$, the quantum resistance in 2D. Magnetotransport study reveals a strong interplay between inelastic and spin-orbit scattering lengths upon reducing thickness, which results in weak antilocalization (WAL) to weak localization (WL) crossover in magnetoconductance.
1908.11128v2
2021-01-17
Surface-Wave Propagation on Non-Hermitian Metasurfaces with Extreme Anisotropy
Electromagnetic metasurfaces enable the advanced control of surface-wave propagation by spatially tailoring the local surface reactance. Interestingly, tailoring the surface resistance distribution in space provides new, largely unexplored degrees of freedom. Here, we show that suitable spatial modulations of the surface resistance between positive (i.e., loss) and negative (i.e., gain) values can induce peculiar dispersion effects, far beyond a mere compensation. Taking inspiration from the parity-time symmetry concept in quantum physics, we put forward and explore a class of non-Hermitian metasurfaces that may exhibit extreme anisotropy mainly induced by the gain-loss interplay. Via analytical modeling and full-wave numerical simulations, we illustrate the associated phenomenon of surface-wave canalization, explore nonlocal effects and possible departures from the ideal conditions, and address the feasibility of the required constitutive parameters. Our results suggest intriguing possibilities to dynamically reconfigure the surface-wave propagation, and are of potential interest for applications to imaging, sensing and communications.
2101.06641v1
2012-06-11
Multiorbital effects on the transport and the superconducting fluctuations in LiFeAs
The resistivity, Hall effect and transverse magnetoresistance (MR) have been measured in low residual resistivity single crystals of LiFeAs. A comparison with angle resolved photoemission spectroscopy and quantum oscillation data implies that four carrier bands unevenly contribute to the transport. However the scattering rates of the carriers all display the T^2 behavior expected for a Fermi liquid. Near Tc low field deviations of the MR with respect to a H^2 variation permit us to extract the superconducting fluctuation contribution to the conductivity. Though below Tc the anisotropy of superconductivity is rather small, the superconducting fluctuations display a quasi ideal two-dimensional behavior which persists up to 1.4 Tc. These results call for a refined theoretical understanding of the multiband behavior of superconductivity in this pnictide.
1206.2278v2
2015-04-27
Two types of nematicity in the phase diagram of the cuprate superconductor YBa$_2$Cu$_3$O$_y$
Nematicity has emerged as a key feature of cuprate superconductors, but its link to other fundamental properties such as superconductivity, charge order and the pseudogap remains unclear. Here we use measurements of transport anisotropy in YBa$_2$Cu$_3$O$_y$ to distinguish two types of nematicity. The first is associated with short-range charge-density-wave modulations in a doping region near $p = 0.12$. It is detected in the Nernst coefficient, but not in the resistivity. The second type prevails at lower doping, where there are spin modulations but no charge modulations. In this case, the onset of in-plane anisotropy - detected in both the Nernst coefficient and the resistivity - follows a line in the temperature-doping phase diagram that tracks the pseudogap energy. We discuss two possible scenarios for the latter nematicity.
1504.06972v3
2015-06-29
Magnetization and magneto-transport studies on Fe$_2$VAl$_{1-x}$Si$_x$
We report on magnetoresistance, Hall and magnetization measurements of Fe2VAl1-xSix Heusler compounds for x= 0.005, 0.015, 0.02. There is a systematic change in the temperature coefficient of resistance (TCR) from negative to positive as the Si composition is increased. The Hall co-efficient shows that the carriers are electron like and the carrier density increases with Si concentration. Resistance measurements under magnetic field indicate a decreasing behavior under the application of magnetic field at low temperature region (T< 60 K), suggesting the suppression of scattering by magnetic field. Temperature and field dependent magnetization measurements did not show any significant change apart from the fact that the presence of super paramagnetic (SPM) cluster and its ordering at low temperatures. Arrott plot analysis of magnetization versus field also indicates the magnetic ordering with applied field below 60 K.
1506.08516v1
2015-07-07
Two-dimensional superconductor-insulator quantum phase transitions in an electron-doped cuprate
We use ionic liquid-assisted electric field effect to tune the carrier density in an electron-doped cuprate ultrathin film and cause a two-dimensional superconductor-insulator transition (SIT). The low upper critical field in this system allows us to perform magnetic field (B)-induced SIT in the liquid-gated superconducting film. Finite-size scaling analysis indicates that SITs induced both by electric and magnetic field are quantum phase transitions and the transitions are governed by percolation effects - quantum mechanical in the former and classical in the latter case. Compared to the hole-doped cuprates, the SITs in electron-doped system occur at critical sheet resistances (Rc) much lower than the pair quantum resistance RQ=h/(2e)2=6.45 k{\Omega}, suggesting the possible existence of fermionic excitations at finite temperature at the insulating phase near SITs.
1507.01668v1
2015-07-07
S-wave Superconductivity in Optimally Doped SrTi$_{1-x}$Nb$_x$O$_3$ Unveiled by Electron Irradiation
We report on a study of electric resistivity and magnetic susceptibility measurements in electron irradiated SrTi$_{0.987}$Nb$_{0.013}$O$_3$ single crystals. Point-like defects, induced by electron irradiation, lead to an almost threefold enhancement of the residual resistivity, but barely affect the superconducting critical temperature ($T_c$). The pertinence of Anderson's theorem provides strong evidence for a s-wave superconducting order parameter. Stronger scattering leads to a reduction of the effective coherence length ($\xi$) and the deduced coherence length in the clean limit ($\xi_0$) is around the BCS coherence length ($\xi_{BCS}$). Combined with thermal conductivity data pointing to multiple nodeless gaps, the current results identify optimally doped SrTi$_{1-x}$Nb$_x$O$_3$ as a multi-band s-wave superconductor.
1507.01867v2
2015-07-15
Depinning of Trapped Magnetic Flux in Bulk Niobium SRF Cavities
Trapped magnetic flux is known to be a significant contribution to the residual resistance of superconducting radio frequency (SRF) cavities. The additional losses depend strongly if the vortices are depinned by the RF. The depinning is affected by the purity of the material, and the size of the pinning centers, as well as the cavity operation frequency. One may define a depinning frequency, above which significant depinning occurs. This publication presents a derivation of the depinning frequency from experimental data. We find a depinning frequency of 673 MHz for RRR 110 niobium. On this basis the currently used model is extended to describe the trapped flux sensitivity as function of residual resistance ratio (RRR) and operation frequency while also accounting for the pinning center size and the treatment history of the cavity. Moreover, the model offers an explanation for the significantly higher trapped flux sensitivity reported for nitrogen doped and 120 C baked cavities.
1507.04105v1
2016-09-08
Pressure-induced topological phase transition in polar semiconductor BiTeBr
We performed X-ray diffraction and electrical resistivity measurement up to pressures of 5 GPa and the first-principles calculations utilizing experimental structural parameters to investigate the pressure-induced topological phase transition in BiTeBr having a noncentrosymmetric layered structure (space group P3m1). The P3m1 structure remains stable up to pressures of 5 GPa; the ratio of lattice constants, c/a, has a minimum at pressures of 2.5 - 3 GPa. In the same range, the temperature dependence of resistivity changes from metallic to semiconducting at 3 GPa and has a plateau region between 50 and 150 K in the semiconducting state. Meanwhile, the pressure variation of band structure shows that the bulk band-gap energy closes at 2.9 GPa and re-opens at higher pressures. Furthermore, according to the Wilson loop analysis, the topological nature of electronic states in noncentrosymmetric BiTeBr at 0 and 5 GPa are explicitly revealed to be trivial and non-trivial, respectively. These results strongly suggest that pressure-induced topological phase transition in BiTeBr occurs at the pressures of 2.9 GPa.
1609.02274v1
2016-09-27
Anomalous Feedback and Negative Domain Wall Resistance
Magnetic induction can be regarded as a negative feedback effect, where the motive-force opposes the change of magnetic flux that generates the motive-force. In artificial electromagnetics emerging from spintronics, however, this is not necessarily the case. By studying the current-induced domain wall dynamics in a cylindrical nanowire, we show that the spin motive-force exerting on electrons can either oppose or support the applied current that drives the domain wall. The switching into the anomalous feedback regime occurs when the strength of the dissipative torque {\beta} is about twice the value of the Gilbert damping constant {\alpha}. The anomalous feedback manifests as a negative domain wall resistance, which has an analogy with the water turbine.
1609.08250v1
2018-07-19
General theory of topological Hall effect in systems with chiral spin textures
We present a consistent theory of the topological Hall effect (THE) in 2D magnetic systems with disordered array of chiral spin textures, such as magnetic skyrmions. We focus on the scattering regime when the mean-free path of itinerant electrons exceeds the spin texture size, and THE arises from the asymmetric carrier scattering on individual chiral spin textures. We calculate the resistivity tensor on the basis of the Boltzmann kinetic equation taking into account the asymmetric scattering on skyrmions via the collision integral. Our theory describes both the adiabatic regime, when THE arises from a spin Hall effect and the non-adiabatic scattering when THE is due to purely charge transverse currents. We analyze the dependence of THE resistivity on a chiral spin texture structure,as well as on material parameters. We discuss the crossover between spin and charge regimes of THE driven by the increase of skyrmion size, the features of THE due to the variation of the Fermi energy, and the exchange interaction strength; we comment on the sign and magnitude of THE
1807.07396v1
2018-12-21
Thermoelectric transport in two-dimensional topological insulator state based on HgTe quantum well
The thermoelectric response of HgTe quantum wells in the state of two-dimensional topological insulator (2D TI) has been studied experimentally. Ambipolar thermopower, typical for an electron-hole system, has been observed across the charge neutrality point, where the carrier type changes from electrons to holes according to the resistance measurements. The hole-type thermopower is much stronger than the electron-type one. The thermopower linearly increases with temperature. We present a theoretical model which accounts for both the edge and bulk contributions to the electrical conductivity and thermoelectric effect in a 2D TI, including the effects of edge to bulk leakage. The model, contrary to previous theoretical studies, demonstrates that the 2D TI is not expected to show anomalies of thermopower near the band conductivity threshold, which is consistent with our experimental results. Based on the experimental data and theoretical analysis, we conclude that the observed thermopower is mostly of the bulk origin, while the resistance is determined by both the edge and bulk transport.
1812.09226v1
2019-01-09
Crystal structures and the sign reversal Hall resistivity in iron-based superconductors Lix(C3H10N2)0.32FeSe (0.15<x<0.4)
We report the crystal structure, superconductivity and normal state properties of two iron-based materials, Li0.15(C3H10N2)0.32FeSe(P-4) and Lix(C3H10N2)0.32FeSe(P4/nmm, 0.25<x<0.4) with superconducting transition temperature from 40~46K. The determined crystal structures revealed a coupling between Li concentration and the oritation of 1,2-Diaminopropane molecules within the hyper expanded FeSe layers. Further fitting on resistivity in terms of the Lawence-Doniach model suggests the two superconductors belong to the quasi-two dimonsional system. With increasing temperature, a differences in crystal structures and doping levels. First principle calculations revealed the increase in FeSe layer diatance will restruct the Fermi surface and generate a new hole pocket around Gamma point in the Brillouin Zone. Our findings support that the increase in two dimensionalities will leads to a temperature induced Lifshitz transition in electron doped FeSe superconductors.
1901.02580v1
2019-01-18
Tuning electric charge scattering in YBCO single crystals via irradiation with MeV electrons
Irradiation with electrons is an efficient approach to inducing a large number of defects with a minimal impact on the material itself. Analysis of the energy transfer from an accelerated particle smashing into the crystal lattice shows that only electrons with MeV energies produce point defects in the form of interstitial ions and vacancies that form perfect scattering centers. Here, we investigate the changes in the resistive characteristics of YBCO single crystals from the 1-2-3 system after several steps of low-temperature irradiation with $0.5-2.5$\,MeV electrons and irradiation doses of up to $8.8\times10^{18}$\,cm$^{-2}$. The penetration depth of such electrons is much larger than the crystal thickness. We reveal that defects appearing in consequence of such electron irradiation not only increase the residual resistance, but they affect the phonon spectrum of the system and lower the superconducting transition temperature linearly with increase of the irradiation dose. Furthermore, the irradiation-induced defects are distributed non-uniformly, that manifests itself via a broadening of the superconducting transition. Interestingly, the excess conductivity remains almost unaffected after such electron irradiation.
1901.06293v1
2019-06-11
Characterisation of Li in the surface film of a corrosion resistant Mg-Li(-Al-Y-Zr) alloy
The surface film formed upon Mg-Li(-Al-Y-Zr) following aqueous immersion and air-exposure was investigated. This alloy (which contains 30.3 at. % Li) possesses a bcc crystal structure and has been reported as being corrosion resistant. It was determined that the principal components of the surface film were Li2CO3 and Mg(OH)2 as characterised by grazing incidence X-ray diffraction (GIXRD). The detection of hcp grains near the alloy surface was observed by GIXRD and selected area electron diffraction (SAED). The spatial distribution of Li and Mg in the surface film was characterised by electron energy loss spectroscopy (EELS) and the distribution of other major elements in the alloy was characterised by scanning transmission electron microscopy (STEM) and energy dispersive X-ray spectroscopy (EDXS). It was observed that Li was distributed throughout the alloy surface film and with an elevated concentration in the so-called outer layer.
1906.04508v1
2019-06-11
Electrical Switching of Tristate Antiferromagnetic Néel Order in $α$-Fe$_{2}$O$_{3}$ Epitaxial Films
The ability to manipulate antiferromagnetic (AF) moments is a key requirement for the emerging field of antiferromagnetic spintronics. Electrical switching of bi-state AF moments has been demonstrated in metallic AFs, CuMnAs and Mn$_2$Au. Recently, current-induced "saw-tooth" shaped Hall resistance was reported in Pt/NiO bilayers, while its mechanism is under debate. Here, we report the first demonstration of convincing, non-decaying, step-like electrical switching of tri-state N\'eel order in Pt/$\alpha$-Fe$_2$O$_3$ bilayers. Our experimental data, together with Monte-Carlo simulations, reveal the clear mechanism of the switching behavior of $\alpha$-Fe$_2$O$_3$ N\'eel order among three stable states. We also show that the observed "saw-tooth" Hall resistance is due to an artifact of Pt, not AF switching, while the signature of AF switching is step-like Hall signals. This demonstration of electrical control of magnetic moments in AF insulator (AFI) films will greatly expand the scope of AF spintronics by leveraging the large family of AFIs.
1906.04694v2
2019-10-01
Valley Hall Effect and Non-Local Resistance in Locally Gapped Graphene
We report on the emergence of bulk, valley-polarized currents in graphene-based devices, driven by spatially varying regions of broken sublattice symmetry, and revealed by non-local resistance ($R_\mathrm{NL}$) fingerprints. By using a combination of quantum transport formalisms, giving access to bulk properties as well as multi-terminal device responses, the presence of a non-uniform local bandgap is shown to give rise to valley-dependent scattering and a finite Fermi surface contribution to the valley Hall conductivity, related to characteristics of $R_\mathrm{NL}$. These features are robust against disorder and provide a plausible interpretation of controversial experiments in graphene/hBN superlattices. Our findings suggest both an alternative mechanism for the generation of valley Hall effect in graphene, and a route towards valley-dependent electron optics, by materials and device engineering.
1910.00489v2
2019-11-14
Free-standing silicon shadow masks for transmon qubit fabrication
Nanofabrication techniques for superconducting qubits rely on resist-based masks patterned by electron-beam or optical lithography. We have developed an alternative nanofabrication technique based on free-standing silicon shadow masks fabricated from silicon-on-insulator wafers. These silicon shadow masks not only eliminate organic residues associated with resist-based lithography, but also provide a pathway to better understand and control surface-dielectric losses in superconducting qubits by decoupling mask fabrication from substrate preparation. We have successfully fabricated aluminum 3D transmon superconducting qubits with these shadow masks and found coherence quality factors comparable to those fabricated with standard techniques.
1911.05924v2
2019-11-21
Experimental Realization of a Reconfigurable Electroacoustic Topological Insulator
A substantial challenge in guiding elastic waves is the presence of reflection and scattering at sharp edges, defects, and disorders. Recently, mechanical topological insulators have sought to overcome this challenge by supporting back-scattering resistant wave transmission. In this Letter, we propose and experimentally demonstrate the first \emph{reconfigurable electroacoustic} topological insulator exhibiting an analog to the quantum valley Hall effect (QVHE). Using programmable switches, this phononic structure allows for rapid reconfiguration of domain walls and thus the ability to control back-scattering resistant wave propagation along dynamic interfaces for phonons lying in static and finite-frequency regimes. Accordingly, a graphene-like Polyactic Acid (PLA) layer serves as the host medium, equipped with periodically arranged and bonded piezoelectric patches, resulting in two Dirac cones at the $K-$points. The PZT patches are then connected to negative capacitance external circuits to break inversion symmetry and create nontrivial topologically-protected bandgaps. As such, topologically protected interface waves are demonstrated numerically and validated experimentally for different predefined trajectories over a broad frequency range.
1911.09608v1
2020-01-07
Joule heating in the normal-superconductor phase transition in a magnetic field
Joule heating is a non-equilibrium dissipative process that occurs in a normal metal when an electric current flows, in an amount proportional to the metal's resistance. When it is induced by eddy currents resulting from a change in magnetic flux, it is also proportional to the rate at which the magnetic flux changes. Here we show that in the phase transformation between normal and superconducting states of a metal in a magnetic field, the total amount of Joule heating is determined by the thermodynamic properties of the system and is independent of the resistivity of the normal metal. We also show that Joule heating only occurs in the normal region of the material. The conventional theory of superconductivity however predicts that Joule heating occurs also in the superconducting region within a London penetration depth of the phase boundary. This implies that there is a problem with the conventional theory of superconductivity.
2001.07509v2
2020-05-05
Study of single crystalline SrAgSb and SrAuSb semimetals
Given renewed interest in the electronic properties of semimetallic compounds with varying degrees of spin orbit coupling we have grown single crystals of SrAgSb and SrAuSb, measured their temperature and field dependent electrical resistivity and magnetization and performed density functional theory (DFT) band structure calculations. Magnetization measurements are consistent with a diamagnetic host with a small amount of local moment bearing impurities. Although the residual resistivity ratio (RRR) for all samples studied was relatively low, ranging between 2.4 and 3.4, the compounds had non-saturating magnetoresistance (MR), reaching values of $\sim$ 17% and $\sim$ 70% at 4 K and 9 T for SrAgSb and SrAuSb respectively. Band structure calculations, using the experimentally determined Wyckoff positions for the Sr, Ag/Au, and Sb atoms, show that whereas SrAgSb is a topologically trivial, but compensated, semimetal; SrAuSb is a topologically non-trivial, Dirac semimetal.
2005.02323v1
2020-05-12
Large anisotropic topological Hall effect in a hexagonal non-collinear magnet Fe5Sn3
We report the observation of a large anisotropic topological Hall effect (THE) in the hexagonal non-collinear magnet Fe5Sn3 single crystals. It is found that the sign of the topological Hall resistivity is negative when a magnetic field H perpendicular to the bc-plane (H\perp bc-plane), however, it changes form negative to positive when H parallel to the c-axis (H\parallel c-axis). The value of topological Hall resistivity increased with the increasing temperature and reached approximately -2.12 \mu\Omega cm (H\perp bc-plane) and 0.5 \mu\Omega cm (H\parallel c-axis) at 350 K, respectively. Quantitative analyses of the measured data suggest that the observed anisotropic THE may originate from the opposite scalar spin chirality induced by the magnetic fields perpendicular and parallel to the c-axis, respectively.
2005.05709v1
2020-05-16
Defect Level Switching for Highly-Nonlinear and Hysteretic Electronic Devices
Nonlinear and hysteretic electrical devices are needed for applications from circuit protection to next-generation computing. Widely-studied devices for resistive switching are based on mass transport, such as the drift of ions in an electric field, and on collective phenomena, such as insulator-metal transitions. We ask whether the large photoconductive response known in many semiconductors can be stimulated in the dark and harnessed to design electrical devices. We design and test devices based on photoconductive CdS, and our results are consistent with the hypothesis that resistive switching arises from point defects that switch between deep- and shallow-donor configurations: defect level switching (DLS). This new electronic device design principle - photoconductivity without photons - leverages decades of research on photoconductivity and defect spectroscopy. It is easily generalized and will enable the rational design of new nonlinear, hysteretic devices for future electronics.
2005.07935v1
2020-06-04
Competition between ferromagnetic and antiferromagnetic states in Al8.5-xFe23Ge12.5+x (0<=x<=3)
Polycrystalline Al7+xFe23Ge14-x-type orthorhombic Al8.5-xFe23Ge12.5+x (0<=x<=3) compounds were studied by X-ray diffraction measurement, metallographic examination, and magnetization and electrical resistivity measurements. The lattice parameters show anisotropic x dependences, reflecting a lower symmetry of rather complex crystal structure. In the x=0 sample, a ferromagnetic (FM) transition occurs at the Curie temperature TC of 255 K, which is systematically reduced with increasing x and disappears at x=2.5 where an antiferromagnetic (AFM) ground state is realized. The Neel temperature TN seems to appear at x>=1, and grows to 143 K at x=3 with the increment of x. In the intermediate range of x (1<=x<=2), a FM to AFM phase transition occurs below TC. In the AFM phase, the electrical resistivity rho shows a Fermi surface instability characterized by the upturn of rho below approximately TN. The competition between the FM and AFM states would be ascribed to the anisotropic x dependences of Fe-Fe bond lengths.
2006.03152v1
2020-06-08
Anisotropic physical properties and large critical current density in KCa${_2}$Fe${_4}$As${_4}$F${_2}$ single crystal
We present a systematic study of electrical resistivity, Hall coefficient, magneto-optical imaging, magnetization, and STEM analyses of KCa${_2}$Fe${_4}$As${_4}$F${_2}$ single crystals. Sharp diamagnetic transition and magneto-optical imaging reveal homogeneity of single crystal and prominent Bean-like penetrations of vortices. Large anisotropy of electrical resistivity, with ${\rho _c / \rho _{ab}}$ > 100, and semiconductor-like ${\rho _c}$ suggest that the electronic state is quasi two-dimensional. Hall effect measurements indicate that KCa${_2}$Fe${_4}$As${_4}$F${_2}$ is a multiband system with holes as main carriers. Magnetization measurements reveal significantly larger J$_c$ compared with that in other iron-based superconductors with different values of J$_c$ depending on the direction of magnetic field. Origin of these J$_c$ characteristics is discussed based on microstructural observations using STEM. In addition, further enhancement of J$_c$ in KCa${_2}$Fe${_4}$As${_4}$F${_2}$ for future application is demonstrated in terms of heavy-ion irradiation.
2006.04478v1
2020-06-12
Unraveling ferroelectric polarization and ionic contributions to electroresistance in epitaxial Hf0.5Zr0.5O2 tunnel junctions
Tunnel devices based on ferroelectric Hf0.5Zr0.5O2 (HZO) barriers hold great promises for emerging data storage and computing technologies. The resistance state of the device can be changed by a suitable writing voltage. However, the microscopic mechanisms leading to the resistance change are an intricate interplay between ferroelectric polarization controlled barrier properties and defect-related transport mechanisms. Here is shown the fundamental role of the microstructure of HZO films setting the balance between those contributions. The oxide film presents coherent or incoherent grain boundaries, associated to the existence of monoclinic and orthorhombic phases in HZO films, which are dictated by the mismatch with the substrates for epitaxial growth. These grain boundaries are the toggle that allows to obtain either large (up to 450 %) and fully reversible genuine polarization controlled electroresistance when only the orthorhombic phase is present or an irreversible and extremely large (1000-100000 %) electroresistance when both phases coexist.
2006.07093v1
2020-06-30
2D MoSe2 as a Promising Chemo-resistive Sensor for N2O Detection: A DFT Approach
We have investigated the impact of toxic N2O gas upon structural and electronic properties of 2D MoSe2 monolayer using DFT approach. In this work, as a result of N2O gas absorption, charge transfer, band gap and density of states (DOS) are changed and these parameters are extracted as electronic properties of 2D MoSe2 monolayer nano-gas sensor. Moreover, the band gap is tunable upon the N2O gas absorption for pristine and adsorbed MoSe2 in both Top Mo (Top Se) structures. Also, the spin up and down states in the DOS results considerable magnetic moment altering the magnetic property of the 2D MoSe2 monolayer. Later, the desorption property of the 2D MoSe2 monolayer towards the target N2O gas molecule at three different temperature are calculated. Thus, the paper concludes with outcomes of the structural and electronic properties aligning its behavior as a chemo-resistive nano-gas sensor and showing it as a potential applicant for sensing of toxic N2O gas molecule. The nature of toxic N2O gas molecule is not explored till date using 2D monolayer, thus, in this work it is estimated through simulated results and the experimental verification is awaited.
2006.16698v2
2020-07-09
Magnetoresistance scaling, disorder, `hot spots' and the origin of $T$-linear resistivity in BaFe$_2$(As$_{1-x}$P$_x$)$_2$
The scaling of $H$-linear magnetoresistance in field and temperature was measured in under-doped (x = 0.19) and optimally-doped (x=0.31)~BaFe$_2$(As$_{1-x}$P$_x$)$_2$. We analyze the data based on an orbital model in the presence of strongly anisotropic quasiparticle spectra and scattering time due to antiferromagnetism. The magnetoresistance is dominated by the properties of small regions of the Fermi surface called `hot spots' where antiferromagnetic excitations induce a large quasiparticle scattering rate. Approximate temperature-magnetic field scaling relations are derived and shown to be consistent with the experimental data. We argue that these results link the origin of linear-in-temperature resistivity to hot spots arising from an antiferromagnetic critical point, and magnetoresistance measurements provide a route to quantify this link.
2007.04970v1
2020-07-28
A Novel Compact Si-B-N Barrier on Mg-Li Alloys via Plasma Treatment
Mg-Li alloys have attracted much attention due to their superior properties. However, it is a great challenge to improve their inferior oxidation and corrosion resistance. We report a novel Si-B-N ceramic film deposited on the Mg-9.6Li alloy surface as an effective barrier against oxidation and corrosion. The films were deposited by using plasma enhanced chemical vapor deposition from a N2-B2H6-SiH4 gas mixtures, showing compact structure and adhesive attachment to the alloy surface. The barrier revealed excellent protection against oxidation in humid air for 500 days, and no observable changes were found in immersion test of the 3.5 wt.% NaCl solution for 10 min. The superior oxidation and corrosion resistance are attributed to the excellent material property of Si-B-N coatings with compact structure via plasma treatment. Moreover, it is found that moderate proportion of B_2 H_6 in the source gas mixture is beneficial to the protection of alloys, where the hydrogen release reaction nearly disappeared and no bubbles were generated on the surface in the immersion test.
2007.14170v1
2020-08-13
Resistivity saturation in Kondo insulators
Resistivities of heavy-fermion insulators typically saturate below a characteristic temperature $T^*$. For some, metallic surface states, potentially from a non-trivial bulk topology, are a likely source of residual conduction. Here, we establish an alternative mechanism: At low temperature, in addition to the charge gap, the scattering rate turns into a relevant energy scale, invalidating the semiclassical Boltzmann picture. Finite lifetimes of intrinsic carriers limit conduction, impose the existence of a crossover $T^*$, and control - now on par with the gap - the quantum regime emerging below it. We showcase the mechanism with realistic many-body simulations and elucidate how the saturation regime of the Kondo insulator Ce$_3$Bi$_4$Pt$_3$, for which residual conduction is a bulk property, evolves under external pressure and varying disorder. Using a phenomenological formula we derived for the quantum regime, we also unriddle the ill-understood bulk conductivity of SmB$_6$ - demonstrating that our mechanism is widely applicable to correlated narrow-gap semiconductors.
2008.05846v1
2020-08-21
Growth and anisotropy evaluation of NbBiCh$_3$ (Ch = S, Se) misfit-layered superconducting single crystals
NbBiCh$_3$ (Ch = S, Se) misfit-layered superconducting single crystals were successfully grown using a CsCl/KCl flux for the first time. The obtained crystals had a well-developed habit parallel to the c-plane with a typical width of 1-2 mm and thickness of 10-40 um. The superconducting transition temperatures with zero resistivity of NbBiS$_3$ single crystals obtained from the nominal composition of Nb0.9Bi1.2S3 was 0.31 K, and that value of the NbBiSe$_3$ single crystals grown from the stoichiometry composition (NbBiSe$_3$) was 2.3 K. Sharp decreases in electric resistivity and magnetic susceptibility at approximately 3 K suggested a possible superconducting transition temperature of NbBiSe$_3$. The normal-state anisotropy values of grown NbBiS$_3$ and NbBiSe$_3$ single crystals were 2.2-2.4 and 1.5-1.6, respectively.
2008.09322v1
2020-08-27
Core-structure and lattice resistance of twinning dislocations in fcc metals
Metals with fcc structure may exhibit deformation twinning under specific conditions, which is an interesting but somewhat elusive aspect of their deformation behavior. It is well acknowledged that the phenomenon occurs through the activities of twinning partial dislocations. However, the lack of a comprehensive understanding of their fundamental properties obstructs the development of detailed multiscale models of crystal plasticity in the fcc metals. Here we explore the core-structures and lattice friction of twinning partials through atomistically informed numerical modeling. To this end, we choose four fcc crystals with widely differing stacking fault energies. Using the semi-discrete variational Peierls Nabarro model, we compute the core-widths and Peierls stresses of edge and screw twinning dislocations. Apart from the conventional layer-by-layer model of twin nucleation, the recently proposed alternate-shear model has also been examined. In the latter case, a negative stable fault energy has been observed, which is large enough to overcome the Peierls barrier. This study also highlights the significance of incorporating the surface correction, the absence of which leads to an overestimation of the intrinsic lattice resistance of the twinning dislocations.
2008.11937v1
2020-10-11
Electrical properties of thermal oxide scales on pure iron in liquid lead-bismuth eutectic
The impedance behavior of pre-oxidized iron in liquid lead-bismuth eutectic (LBE) at 200 oC is studied using electrochemical impedance spectroscopy. The structures and resistance of oxide grown on iron oxidized in air at different temperatures and durations are compared. The results show that the resistance of the oxide film increases with increasing oxidizing temperature, due to the formation of a thicker scale and fewer defects. At the same temperature (600 oC), increasing the oxidation time can also reduce the defect concentration in the oxide film and improve the impedance of the oxide scale in LBE.
2010.05372v1
2020-10-14
Competing spin modulations in a magnetically frustrated semimetal EuCuSb
The competing magnetic ground states of the itinerant magnet EuCuSb, which has a hexagonal layered structure, were studied via magnetization, resistivity, and neutron diffraction measurements on single-crystal samples. EuCuSb has a three-dimensional semimetallic band structure as confirmed by band calculation and angle-resolved photoelectron spectroscopy, consistent with the nearly isotropic metallic conductivity in the paramagnetic state. However, below the antiferromagnetic transition temperature of TN1 (8.5 K), the resistivity, especially along the hexagonal axis, increases significantly. This implies the emergence of anisotropic magnetic ordering coupled to the conducting electrons. Neutron diffraction measurements show that the Eu spins, which order ferromagnetically within each layer, are collinearly modulated (up-up-down-down) along the hexagonal axis below TN1, followed by the partial emergence of helical spin modulation below TN2 (6 K). Based on the observation of anomalous magnetoresistance with hysteretic behavior, we discuss the competing nature of the ground state inherent in a frustrated Heisenberg-like spin system with a centrosymmetric structure.
2010.06841v1
2020-10-20
Strange metals as ersatz Fermi liquids
A long standing mystery of fundamental importance in correlated electron physics is to understand strange non-Fermi liquid metals that are seen in diverse quantum materials. A striking experimental feature of these metals is a resistivity that is linear in temperature ($T$). In this paper we ask what it takes to obtain such non-Fermi liquid physics down to zero temperature in a translation invariant metal. If in addition the full frequency ($\omega$) dependent conductivity satisfies $\omega/T$ scaling, we argue that the $T$-linear resistivity must come from the intrinsic physics of the low energy fixed point. Combining with earlier arguments that compressible translation invariant metals are `ersatz Fermi liquids' with an infinite number of emergent conserved quantities, we obtain powerful and practical conclusions. We show that there is necessarily a diverging susceptibility for an operator that is odd under inversion/time reversal symmetries, and has zero crystal momentum. We discuss a few other experimental consequences of our arguments, as well as potential loopholes which necessarily imply other exotic phenomena.
2010.10523v3
2020-11-06
Molecular Dynamic Study of Local Interfacial Thermal Resistance of Solid-Liquid and Solid-Solid Interfaces: Water and Nanotextured Surface
Degradation in performances of air conditioners and refrigerators is caused by a frost formation and adhesion on the surface. In the present study, by means of the classical molecular dynamics simulation, we investigate how and how much the nanotextured surface characteristics, such as surface wettability and geometry, influenced the interfacial thermal resistance (ITR) between the solid wall and the water/ice. The ITR of the interfacial region was comparable in both the water and the ice states. As the nanostructure gaps became narrower, the ITR of the interfacial region decreased. The local ITR had a weak negative correlation with the local H2O molecule density regardless of the phase of the H2O molecules. The local ITR decreased as the local density increased. The greater amount of the thermal energy was transferred through the material interface by means of the intermolecular interaction when more the H2O molecules were located in the proximity area, which was closer to the Pt solid wall than the first adsorption layer peak. When the H2O molecules were in the crystal form on the solid wall, the proximity molecules decreased, and then the local ITR significantly increased.
2011.03184v2
2020-11-10
Thickness induced metal to insulator charge transport and unusual hydrogen response in granular palladium nanofilms
This work reports a systematic study of the evolution of charge transport mechanism in granular ultra-thin films of palladium of thickness varying between 6nm and 2nm. While the films with thickness > 4nm exhibit metallic behaviour, that at 3nm thickness undergoes a metal-insulator transition at 19.5K. In contrast, the 2nm thick film remained insulating at all temperatures. with transport following Mott's variable range hopping. At room temperature, while the thicker film exhibit resistance decrease on H$_2$ exposure. the insulating film showed an anomalous initial resistance increase before switching to a subsequent decrease. The nanostructure dependent transport and the ensuing H$_2$ response is modeled on a percolation model, which also explores the relevance of film thickness as a macroscopic control parameter to engineer the desired system response in granular metal films.
2011.05123v1
2020-11-23
From hidden metal-insulator transition to Planckian-like dissipation by tuning disorder in a nickelate
Heavily oxygen deficient NdNiO$_3$ (NNO) films, which are insulating due to electron localization, contain pristine regions that undergo a hidden metal-insulator transition. Increasing oxygen content increases the connectivity of the metallic regions and the metal-insulator transition is first revealed, upon reaching the percolation threshold, by the presence of hysteresis. Only upon further oxygenation is the global metallic state (with a change in the resistivity slope) eventually achieved. It is shown that sufficient oxygenation leads to linear temperature dependence of resistivity in the metallic state, with a scattering rate directly proportional to temperature. Despite the known difficulties to establish the proportionality constant, the experiments are consistent with a relationship 1/$\tau$= $\alpha k_B T/\hbar$, with $\alpha$ not far from unity. These results could provide experimental support for recent theoretical predictions of disorder in a two-fluid model as a possible origin of Planckian dissipation.
2011.11535v2
2020-11-26
All-MOCVD-Grown Gallium Nitride Diodes with Ultra-Low Resistance Tunnel Junctions
We carefully investigate three important effects including postgrowth activation annealing, delta ({\delta}) dose and p+-GaN layer thickness and experimentally demonstrate their influence on the electrical properties of GaN p-n homojunction diodes with a tunnel junction (TJ)-based p-contact. The p-n diodes and TJ structures were monolithically grown by metalorganic chemical vapor deposition (MOCVD) in a single growth step. By optimizing the annealing time and temperature for magnesium (Mg) activation and introducing {\delta}-doses for both donors and acceptors at TJ interfaces, a significant improvement in electrical properties is achieved. For the continuously-grown, all-MOCVD GaN homojunction TJs, ultra-low forward voltage penalties of 158 mV and 490 mV are obtained at current densities of 20 A/cm2 and 100 A/cm2, respectively. The p-n diode with an engineered TJ shows a record-low normalized differential resistance of 1.6 x 10-4 {\Omega}-cm2 at 5 kA/cm2.
2011.13431v1
2020-12-29
Efficient partitioning of surface Green's function: toward ab initio contact resistance study
In this work, we propose an efficient computational scheme for first-principle quantum transport simulations to evaluate the open-boundary conditions. Its partitioning differentiates from conventional methods in that the contact self-energy matrices are constructed on smaller building blocks, principal layers (PL), while conventionally it was restricted to have the same lateral dimensions of the adjoining atoms in a channel region. Here, we obtain the properties of bulk electrodes through non-equilibrium Green's function (NEGF) approach with significant improvements in the computational efficiency without sacrificing the accuracy of results. To exemplify the merits of the proposed method we investigate the carrier density dependency of contact resistances in silicon nanowire devices connected to bulk metallic contacts.
2012.14903v1
2020-12-30
Anomalous thermal transport and violation of Wiedemann-Franz law in the critical regime of a charge density wave transition
ErTe$_3$ is studied as a model system to explore thermal transport in a layered charge density wave (CDW) material. We present data from thermal diffusivity, resistivity, and specific heat measurements: There is a sharp decrease in thermal conductivity both parallel and perpendicular to the primary CDW at the CDW transition temperature. At the same time, the resistivity changes more gradually. Correspondingly, while well above and below $T_c$, a consistent description of the thermal transport applies with essentially independent electron and phonon contributions (estimated using the Wiedemann Franz law), in the critical regime no such description is possible; the observed behavior corresponds to a strongly coupled electron-phonon critical `soup.'
2012.15048v1
2021-02-05
A Colossal Electroresistance response, accompanied by metal-insulator transition, in a mixed-valent vanadate
Colossal electroresistance (CER) in manganites, i.e., a large change in electrical resistance under the influence of either an applied electric field or an applied electric current, has often been described as complimentary to the colossal magnetoresistance (CMR) effect. Mixed valent vanadates with active t2g and empty eg orbitals, unlike manganites, have not naturally been discussed in this context, as double exchange based CMR is not realizable in them. However, presence of coupled spin and orbital degrees of freedom, metal-insulator transition (MIT) accompanied by orbital order-disorder transition, etc., anyway make the vanadates an exciting group of materials. Here we probe a Fe-doped hollandite lead vanadate PbFe1.75V4.25O11 (PFVO), which exhibits a clear MIT as a function of temperature. Most importantly, a giant fall in the resistivity, indicative of a CER, as well as a systematic shift in the MIT towards higher temperature are observed as a function of applied electric current. Detailed structural, magnetic, thermodynamic and transport studies point towards a complex interplay between orbital order/disorder effect, MIT and double exchange in this system.
2102.03128v1
2021-02-02
Fabrication of astronomical x-ray reflection gratings using thermally activated selective topography equilibration
Thermally activated selective topography equilibration (TASTE) enables the creation of 3D structures in resist using grayscale electron-beam lithography followed by a thermal treatment to induce a selective polymer reflow. A blazed grating topography can be created by reflowing repeating staircase patterns in resist into wedge-like structures. Motivated by astronomical applications, such patterns with periodicities 840 nm and 400 nm have been fabricated in 130 nm-thick PMMA using TASTE to provide a base for X-ray reflection gratings. A path forward to integrate this alternative blazing technique into grating fabrication recipes is discussed.
2102.12359v1
2021-03-04
Uncovering Thermal and Electrical Properties of Sb2Te3/GeTe Superlattice Films
Superlattice-like phase change memory (SL-PCM) promises lower switching current than conventional PCM based on Ge2Sb2Te5 (GST). However, a fundamental understanding of SL-PCM requires detailed characterization of the interfaces within such a SL. Here, we explore the electrical and thermal transport of SLs with deposited Sb2Te3 and GeTe alternating layers of various thicknesses. We find up to ~4X reduction of the effective cross-plane thermal conductivity of the SL stack (as-deposited polycrystalline) compared to polycrystalline GST (as-deposited amorphous and later annealed) due to the thermal interface resistances within the SL. Thermal measurements with varying periods of our SLs show a signature of phonon coherence with a transition from wave-like to particle-like phonon transport, further described by our modeling. Electrical resistivity measurements of such SLs reveal strong anisotropy (~2000X) between the in-plane and cross-plane directions due to the weakly interacting van der Waals gaps. This work uncovers electro-thermal transport in SLs based on Sb2Te3 and GeTe, for improved design of low-power PCM.
2103.02867v3
2021-04-01
Unconventional satellite resistance peaks in moiré superlattice of h-BN/ AB-stacked tetralayer-graphene heterostructure
Most studies on moir\'e superlattices formed from a stack of h-BN and graphene have focused on single layer graphene; graphene with multiple layers is less understood. Here, we show that a moir\'e superlattice of multilayer graphene shows new features arising from the anisotropic Fermi surface affected by the superlattice structure. The moir\'e superlattice of a h-BN/AB-stacked tetralayer graphene heterostructure exhibited resistivity peaks showing a complicated dependence on the perpendicular electric field. The peaks were not due to secondary Dirac cones forming, but rather opening of the energy gap due to folding of the anisotropic Fermi surface. In addition, superlattice peaks resulted from mixing of light- and heavy-mass bilayer-like bands via the superlattice potential. The gaps did not open on the boundary of the superlattice Brillouin zone, but rather opened inside it, which reflected the anisotropy of the Fermi surface of multilayer graphene.
2104.00261v1
2021-07-07
Structural and WAL analysis of Topological single-crystal SnSb2Te4
Here, we report successful single crystal growth of SnSb2Te4 using the self-flux method. Unidirectional crystal growth is confirmed through X Ray Diffraction (XRD) pattern taken on mechanically cleaved crystal flake while the rietveld refined Powder XRD (PXRD) pattern confirms the phase purity of the grown crystal. Scanning Electron Microscopy (SEM) image and Energy Dispersive X-Ray analysis (EDAX) confirm crystalline morphology and exact stoichiometry of constituent elements. Vibrational Modes observed in Raman spectra also confirm the formation of the SnSb2Te4 phase. DC resistivity measurements confirm the metallic character of the grown crystal. Magneto-transport measurements up to 5T show a nonsaturating low magneto-resistance percentage. V type cusp and Hikami Larkin Nagaoka (HLN) fitting at lower field confirms the Weak Anti-localization (WAL) effect in SnSb2Te4. Density Functional Theory (DFT) calculations were showing topological non-trivial electronic band structure. It is the first-ever report on MR study and WAL analysis of SnSb2Te4 single crystal.
2107.03014v1
2021-07-13
First-principles study of the crystal structure, electronic structure, and transport properties of NiTe$_2$ under pressure
Recent experiments showed the distinct observations on the transition metal ditelluride NiTe$_2$ under pressure: one reported a superconducting phase transition at 12 GPa, whereas another observed a sign reversal of Hall resistivity at 16 GPa without the appearance of superconductivity. To clarify the controversial experimental phenomena, we have carried out first-principles electronic structure calculations on the compressed NiTe$_2$ with structure searching and optimization. Our calculations show that the pressure can transform NiTe$_2$ from a layered P-3m1 phase to a cubic Pa-3 phase at $\sim$10 GPa. Meanwhile, both the P-3m1 and Pa-3 phases possess nontrivial topological properties. The calculated superconducting $T_c$'s for these two phases based on the electron-phonon coupling theory both approach 0 K. Further magnetic transport calculations reveal that the sign of Hall resistance for the Pa-3 phase is sensitive to the pressure and the charge doping, in contrast to the case of the P-3m1 phase. Our theoretical predictions on the compressed NiTe$_2$ wait for careful experimental examinations.
2107.05922v1
2021-07-14
A fast-converging scheme for the Phonon Boltzmann equation with dual relaxation times
Callaway's dual relaxation times model, which takes into account the normal and resistive scatterings of phonon, is used to describe the heat conduction in materials like graphene. For steady-state problems, the Callaway model is usually solved by the conventional iterative scheme (CIS), which is efficient in the ballistic regime, but inefficient in the diffusive/hydrodynamic regime. In this paper, a general synthetic iterative scheme (GSIS) is proposed to expedite the convergence to steady-state solutions. First, macroscopic synthetic equations are designed to guide the evolution of equilibrium distribution functions for normal and resistive scatterings, so that fast convergence can be achieved even in the diffusive/hydrodynamic regime. Second, the Fourier stability analysis is conducted to find the convergence rate for both CIS and GSIS, which rigorously proves the efficiency of GSIS over CIS. Finally, several numerical simulations are carried out to demonstrate the accuracy and efficiency of GSIS, where up to three orders of magnitude of convergence acceleration is achieved.
2107.06688v1
2021-07-26
Statistical analysis of spin switching in coupled spin-crossover molecules
We study the switching behavior of two spin-crossover molecules residing in a nanojunction device consisting of two closely spaced gold electrodes. The spin states are monitored through a real-time measurement of the resistance of the junction. A statistical analysis of the resistance values, the occupation probabilities, and the lifetimes of the respective spin states shows that the two spin-crossover molecules are coupled to each other. We extract the parameters for a minimal model describing the two coupled spin-crossover molecules. Finally, we use the time dependence of factorial cumulants to demonstrate that the measured data indicates the presence of interactions between the two spin-crossover molecules.
2107.11935v1
2021-09-29
Physical and one-dimensional properties of single crystalline La$_{5}$AgPb$_{3}$
We report here the properties of single crystals of La$_{5}$AgPb$_{3}$, which is a member of the $R_5MX_3$ ($R$ = rare earth, $M$ = transition metal or main group element, $X$ = Pb, Sn, Sb, In, Bi) family of chain-like compounds. Measurements of the electrical resistivity, specific heat and magnetic susceptibility are compared to the results of density functional calculations, finding that La$_{5}$AgPb$_{3}$ is a non-magnetic metal with moderate correlations. The analysis of the electrical resistivity and specific heat measurements highlight the importance of lattice vibrations in the material, while the calculated electron density suggests the presence of localized La and well-hybridized Ag atoms that extend along the c-axis in the La$_{5}$AgPb$_{3}$ structure. The temperature dependence of the magnetic susceptibility is consistent with a possible one-dimensional character of La$_{5}$AgPb$_{3}$, where the strength of correlations is much weaker than in one-dimensional conductors that have been previously reported.
2109.14716v1
2021-10-20
Anomalous Hall effect from gapped nodal line in Co2FeGe Heusler compound
Full Heusler compounds with Cobalt as a primary element show anomalous transport properties owing to the Weyl fermions and broken time-reversal symmetry. We present here the study of anomalous Hall effect (AHE) in Co2FeGe Heusler compound. The experiment reveals anomalous Hall conductivity (AHC) 100 S/cm at room temperature with an intrinsic contribution of 78 S/cm . The analysis of anomalous Hall resistivity suggests the scattering independent intrinsic mechanism dominates the overall behaviour of anomalous Hall resistivity. The first principles calculation reveals that the Berry curvature originated by gapped nodal line near EF is the main source of AHE in Co2FeGe Heusler compound. The theoretically calculated AHC is in agreement with the experiment.
2110.10677v1
2021-11-06
GdV6Sn6: a Multi-carrier Metal with Non-magnetic 3d-electron Kagome Bands and 4f-electron Magnetism
Electronic properties of the single crystal of GdV6Sn6, where non-magnetic V-kagome layers are separated by magnetic Gd-triangular lattice, are investigated. GdV6Sn6 exhibits unique magnetotransport properties at low-temperature such as non-linear Hall resistivity and increase of resistance R in magnetic field H as R ~ H^0.75 up to 56 T with Shubnikov-De Haas oscillations. Investigation of the non-magnetic analogue YV6Sn6 and the first principles calculations reveal these properties are relevant to the bands arising from the V-kagome layer. A magnetic transition at 5 K in GdV6Sn6 modifies the transport properties, pointing to a coupling between Gd-spins on the triangular lattice and carriers in the V-kagome layer.
2111.03806v1
2021-11-14
Modelling photothermal induced resonance microscopy: the role of interface thermal resistances
Infrared (IR) nanospectroscopy by photothermal induced resonance (PTIR) is a novel experimental technique that combines the nanoscale resolution granted by atomic force microscopy (AFM) and the chemical labelling made possible by IR absorption spectroscopy. While the technique has developed enormously over the last decade from an experimental point of view, the theoretical modelling of the signal still varies significantly throughout the literature and misses a solid benchmark. Here, we report an analysis focused on the electromagnetic and thermal simulations of a PTIR experiment. Thanks to a control experiment where the signal is acquired as a function of the thickness of a polymer film and for different tip geometries, we find clear evidence that the interface thermal resistances play a key role in the determination of the measured signal and should therefore always be accounted for by any quantitative modelling.
2111.07303v1
2021-12-01
Immobilization of the rare earth fraction in lanthanide phosphates LnPO4. Radiation and hydrolytic resistance of the matrix
Radiation and hydrolytic resistance of Eu0.054Gd0.014Y0.05La0.111Ce0.2515Pr0.094Nd0.3665Sm0.059PO4 with monazite structure has been studied. The powders were obtained by deposition from solutions. Ceramic specimens with relative density ~97% were obtained by Spark Plasma Sintering (heating rate Vh = 50 {\deg}C/min, sintering temperature Ts = 1070 {\deg}C, sintering time ts = 18 min). Irradiation by accelerated electrons up to dose of 10^9 Ge was found not to result in a destruction of the target phase. After the irradiation, an increasing of the leaching rate by an order of magnitude (up to ~10^{-8} g/(cm2*day)) and a reduction of the mechanical properties by 32% as compared to the non-irradiated ceramic specimen were observed.
2112.00844v1
2021-12-24
Measured potential profile in a quantum anomalous Hall system suggests bulk-dominated current flow
Ideally, quantum anomalous Hall systems should display zero longitudinal resistance. Yet in experimental quantum anomalous Hall systems elevated temperature can make the longitudinal resistance finite, indicating dissipative flow of electrons. Here, we show that the measured potentials at multiple locations within a device at elevated temperature are well-described by solution of Laplace's equation, assuming spatially-uniform conductivity, suggesting non-equilibrium current flows through the two-dimensional bulk. Extrapolation suggests that at even lower temperatures current may still flow primarily through the bulk rather than, as had been assumed, through edge modes. An argument for bulk current flow previously applied to quantum Hall systems supports this picture.
2112.13123v3
2022-01-24
Nonconventional Quantized Hall Resistances Obtained with $ν= 2$ Equilibration in Epitaxial Graphene $p-n$ Junctions
We have demonstrated the millimeter-scale fabrication of monolayer epitaxial graphene $p-n$ junction devices using simple ultraviolet photolithography, thereby significantly reducing device processing time compared to that of electron beam lithography typically used for obtaining sharp junctions. This work presents measurements yielding nonconventional, fractional multiples of the typical quantized Hall resistance at $\nu=2$ ($R_H\approx 12906 {\Omega}$) that take the form: $\frac{a}{b}R_H$. Here, $a$ and $b$ have been observed to take on values such 1, 2, 3, and 5 to form various coefficients of $R_H$. Additionally, we provide a framework for exploring future device configurations using the LTspice circuit simulator as a guide to understand the abundance of available fractions one may be able to measure. These results support the potential for drastically simplifying device processing time and may be used for many other two-dimensional materials.
2201.09791v1
2022-03-11
Toward accurate polarization estimation in nanoscopic systems
The nanoscopic characterization of ferroelectric thin films is crucial from their device application point of view. Standard characterization techniques are based on detecting the nanoscopic charge compensation current (switching current) caused by the polarization reversal in the ferroelectric. Owing to various surface and bulk limited mechanisms, leakage currents commonly appear during such measurements, which are frequently subtracted using the device I-V characteristic by employing positive-up-negative-down (PUND) measurement scheme. By performing nanoscopic switching current measurements on a commonly used ferroelectric, BiFeO3, we show that such characterization methods may be prone to large errors in the polarization estimation on ferro-resistive samples, due to current background subtraction issues. Especially, when ferro-resistive behavior is associated with the polarization reversal of the ferroelectric thin film, background current subtraction is not accurate due to the mismatch of the I-V characteristics for the two polarization states. We show instead that removing the background current by an asymmetric least squares subtraction method, though not perfect, gives a much better estimation of the ferroelectric properties of the sample under study.
2203.06157v1
2022-05-11
Self-heating Effect in Silicon-Photomultipliers
The main effect of radiation damage in a Silicon-Photolumtiplier (SiPM) is a dramatic increase in the dark current. The power dissipated, if not properly cooled, heats the SiPM, whose performance parameters depend on temperature. Heating studies were performed with a KETEK SiPM, glued on an Al$_2$O$_3$ substrate, which is either directly connected to the temperature-controlled chuck of a probe station, or through layers of material with well-known thermal resistance. The SiPM is illuminated by a LED operated in DC-mode. The SiPM current is measured and used to determine the steady-state temperature as a function of power dissipated in the multiplication region of the SiPM and thermal resistance, as well as the time dependencies for heating and cooling. This information can be used to correct the parameters determined for radiation-damaged SiPM for the effects of self-heating. The method can also be employed for packaged SiPMs with unknown thermal contact to a heat sink. The results presented in this paper are preliminary.
2205.05504v2
2022-05-31
A Novel Readout Scheme for Muon Tomography Application in Material Identification
This work reports a cost-effective, multi-parameter readout and data-acquisition system for a muon scattering tomography system based on Resistive Plate Chambers (RPCs). Initial test measurements with a prototype Resistive Plate Chamber were performed using a low-cost FPGA coupled to the NINO ASIC for the event selection and handling data. The Time over-Threshold (TOT) property of NINO ASICs has been used to achieve better position information and achieve precise tracking capability. In our test setup, we try to build an imaging setup using a single RPC and lead block, which covers some areas of RPC. A glass RPC of dimension 30cm x 30cm, filled with a gas mixture of 95% Freon and 5% Isobutane, equipped with two orthogonal panels of readout strips of width 3 cm and pitch 3.2 cm, has been operated.
2205.15966v1
2022-06-04
How to recognize the universal aspects of Mott criticality?
In this paper we critically discuss several examples of two-dimensional electronic systems displaying interaction-driven metal-insulator transitions of the Mott (or Wigner--Mott) type, including dilute two-dimension electron gases (2DEG) in semiconductors, Mott organic materials, as well as the recently discovered transition-metal dichalcogenide (TMD) moir\'e bilayers. Remarkably similar behavior is found in all these systems, which is starting to paint a robust picture of Mott criticality. Most notable, on the metallic side a resistivity maximum is observed whose temperature scale vanishes at the transition. We compare the available experimental data on these systems to three existing theoretical scenarios: spinon theory, Dynamical Mean Field Theory (DMFT) and percolation theory. We show that the DMFT and percolation pictures for Mott criticality can be distinguished by studying the origins of the resistivity maxima using an analysis of the dielectric response.
2206.02055v2
2022-06-28
Negative Differential Resistance in Spin-Crossover Molecular Devices
We demonstrate, based on low-temperature scanning tunneling microscopy (STM) and spectroscopy, a pronounced negative differential resistance (NDR) in spin-crossover (SCO) molecular devices, where a Fe$^{\text{II}}$ SCO molecule is deposited on surfaces. The STM measurements reveal that the NDR is robust with respect to substrate materials, temperature, and the number of SCO layers. This indicates that the NDR is intrinsically related to the electronic structure of the SCO molecule. Experimental results are supported by density functional theory (DFT) with non-equilibrium Green's functions (NEGF) calculations and a generic theoretical model. While the DFT+NEGF calculations reproduce NDR for a special atomically-sharp STM tip, the effect is attributed to the energy-dependent tip density of states rather than the molecule itself. We, therefore, propose a Coulomb blockade model involving three molecular orbitals with very different spatial localization as suggested by the molecular electronic structure.
2206.13767v2
2022-07-26
Understanding the Mechanism of the Performance Improvement in Nitrogen-doped Niobium Superconducting Radio Frequency Cavity
Niobium superconducting radiofrequency cavities enable applications in modern accelerators and quantum computers. However, the surface resistance significantly deteriorates the cavities performance. Nitrogen doping surface treatment can consistently increase cavity performance by reducing surface resistance, but the improvement mechanism is not fully understood. Herein, we employed transmission electron microscopy and spectroscopy to uncover the structural and chemical differences of the Nb-air interface between the non-doped and nitrogen-doped cavities. The results indicate that nitrogen doping passivates the Nb surface by introducing a compressive strain close to the Nb/air interface, which impedes the oxygen diffusion and hydrogen atoms and reduces surface oxide thickness.
2207.13171v1
2022-08-31
Possible origin of extremely large magnetoresistance in the topological insulator CaBi2 single crystal
CaBi2 has been experimentally found to be a superconductor with a transition temperature of 2 K and identified as a topological insulator via spin- and angle-resolved photoemission spectroscopy, which makes it a possible platform to study the interplay between superconductivity and topology. But the detailed transport properties for CaBi2 single crystal remain unexplored in experiments. Here, we systematically studied the magneto-transport properties of CaBi2 single crystal grown by a flux method. CaBi2 shows a magnetic-field-induced upturn behavior with a plateau in resistivity at low temperature. An extremely large and non-saturating magnetoresistance up to ~15000% at 3 K and 12 T was achieved. The possible reason for the magnetic field and temperature dependence of resistivity and extremely large magnetoresistance at low temperature was discussed by adopting the Kohler's scaling law, which can be understood by the compensation effect confirmed by the Hall Effect measurement.
2208.14595v1
2022-09-16
Ferroelectricity and resistive switching in BaTiO$_3$ thin films with liquid electrolyte top contact for bioelectronic devices
We investigate ferroelectric- and resistive switching behavior in 18-nm-thick epitaxial BaTiO$_3$ (BTO) films in a model electrolyte-ferroelectric-semiconductor (EFS) configuration. The system is explored for its potential as a ferroelectric microelectrode in bioelectronics. The BTO films are grown by pulsed laser deposition (PLD) on semiconducting Nb-doped (0.5 wt\%) SrTiO$_{3}$ (Nb:STO) single crystal substrates. The ferroelectric properties of the bare BTO films are demonstrated by piezoresponse force microscopy (PFM) measurements. Cyclic voltammetry (CV) measurements in EFS configuration, with phosphate buffered saline (PBS) acting as the liquid electrolyte top contact, indicate characteristic ferroelectric switching peaks in the bipolar current-voltage loop. The ferroelectric nature of the observed switching peaks is confirmed by analyzing the current response of the EFS devices to unipolar voltage signals. Moreover, electrochemical impedance spectroscopy (EIS) measurements indicate bipolar resisitive switching behavior of the EFS devices, which is controlled by the remanent polarization state of the BTO layer. Our results represent a constitutive step towards the realization of neuroprosthetic implants and hybrid neurocomputational systems based on ferroelectric microelectrodes.
2209.08020v1
2022-09-21
Colossal Spontaneous Hall Effect and Emergent Magnetism in KTaO$_3$ Two-Dimensional Electron Gases
There has been intense recent interest in the two-dimensional electron gases (2DEGs) that form at the surfaces and interfaces of KTaO$_3$ (KTO), with the discovery of superconductivity at temperatures significantly higher than those of similar 2DEGs based on SrTiO$_3$ (STO). Here we demonstrate that KTO 2DEGs fabricated under conditions that suppress the superconductivity show a large spontaneous Hall effect at low temperatures. The transverse response is asymmetric in an applied perpendicular magnetic field and becomes hysteretic at millikelvin temperatures. The hysteresis is due to long range magnetic order arising from local Ta$^{4+}$ moments. However, the most striking features of the data are the asymmetry of the transverse response and the large spontaneous transverse resistance at zero field, which can be a significant fraction of the longitudinal resistance and depends on crystal orientation. Both effects are due to the presence of a dominant contribution to the transverse response that is symmetric in perpendicular field, suggesting that its origin is topological in nature. We argue that this contribution arises from Berry curvature dipoles coupled with nonequilibrium conditions induced by the measuring current.
2209.10534v2
2022-09-30
Remote Surface Optical Phonon Scattering in Ferroelectric Ba$_{0.6}$Sr$_{0.4}$TiO$_{3}$ Gated Graphene
We report the effect of remote surface optical (RSO) phonon scattering on carrier mobility in monolayer graphene gated by ferroelectric oxide. We fabricate monolayer graphene transistors back-gated by epitaxial (001) Ba$_{0.6}$Sr$_{0.4}$TiO$_{3}$ films, with field effect mobility up to 23,000 cm$^{2}$V$^{-1}$s$^{-1}$ achieved. Switching the ferroelectric polarization induces nonvolatile modulation of resistance and quantum Hall effect in graphene at low temperatures. Ellipsometry spectroscopy studies reveal four pairs of optical phonon modes in Ba$_{0.6}$Sr$_{0.4}$TiO$_{3}$, from which we extract the RSO phonon frequencies. The temperature dependence of resistivity in graphene can be well accounted for by considering the scattering from the intrinsic longitudinal acoustic phonon and the RSO phonon, with the latter dominated by the mode at 35.8 meV. Our study reveals the room temperature mobility limit of ferroelectric-gated graphene transistors imposed by RSO phonon scattering.
2209.15527v1
2022-10-06
Kinetically Decoupled Electrical and Structural Phase Transitions in VO2
Vanadium dioxide (VO2) has drawn significant attention for its near room temperature insulator to metal transition and associated structural phase transition. The underlying Physics behind the temperature induced insulator to metal and concomitant structural phase transition in VO2 is yet to be fully understood. We have investigated the kinetics of the above phase transition behaviors of VO2 with the help of resistivity measurements and Raman spectroscopy. Resistance thermal hysteresis scaling and relaxation measurements across the temperature induced insulator to metal transition reveal the unusual behaviour of this first-order phase transition, whereas Raman relaxation measurements show that the temperature induced structural phase transition in VO2 follows usual behaviour and is consistent with mean field prediction. At higher temperature sweeping rates decoupling of insulator to metal transition and structural phase transition have been confirmed. The observed anomalous first order phase transition behavior in VO2 is attributed to the unconventional quasi particle dynamics, i.e. significantly lowered electronic thermal conductivity across insulator to metal transition, which is confirmed by ultrafast optical pump-probe time domain thermoreflectance measurements.
2210.02691v1
2022-11-06
Triclinic BiFeO3: A room-temperature multiferroic phase with enhanced magnetism and resistivity
The magnetic and transport properties of BiFeO3/La2NiMnO6 (BFO/LNMO) composite have been investigated both experimentally and theoretically. Unlike the normal rhombohedral (R3c) phase, BFO in the composites is crystallized in the triclinic phase (P1). Interestingly, the composites demonstrate a significant enhancement in the magnetization, magnetoelectric coupling and show higher resistivity than that of the regular BFO (R3c). As LNMO has its Curie temperature at 280 K, the room temperature and above room temperature magnetic contribution in the composites is expected to be from the triclinic BFO phase. Experimentally observed enhancement in magnetization is validated using classical Monte Carlo simulation and density functional theory (DFT) calculations. The calculations reveal higher magnetic moments in triclinic BFO as compared to the rhombohedral BFO. Overall, this study reveals triclinic BFO as the promising room temperature multiferroic phase which is helpful to optimize the multiferroicity of BFO and achieve wider applications in future.
2211.03123v3
2022-11-11
Synthesis and physical properties of uranium thin-film hydrides UH2 and \b{eta}-UH3
Formation of thin uranium hydrides films, UH2 and \b{eta}-UH3, synthesized by a reactive dc sputtering of uranium metal, was explored using variable deposition conditions. Obtained stable oxygen-free hydride films were studied by a variety of methods, both in situ (photoelectron spectroscopy - XPS), and ex-situ (x-ray diffraction - XRD, transmission electron microscopy - TEM), electrical resistivity, and magnetometry). Both types of hydrides are ferromagnetic, the Curie temperatures of UH2 and \b{eta}-UH3 are approx. 120 and 170 K, respectively. Ferromagnetism in the thin films is robust and does not depend on structure details while electrical resistivity data reflect disorder in both types of hydrides.
2211.06144v1
2023-01-03
Supercurrent in Bi$_4$Te$_3$ Topological Material-Based Three-Terminal Junctions
In an in-situ prepared three-terminal Josephson junction based on the topological insulator Bi$_4$Te$_3$ and the superconductor Nb the transport properties are studied. The differential resistance maps as a function of two bias currents reveal extended areas of Josephson supercurrent including coupling effects between adjacent superconducting electrodes. The observed dynamics for the coupling of the junctions is interpreted using a numerical simulation of a similar geometry based on a resistively and capacitively shunted Josephson junction model. The temperature dependency indicates that the device behaves similar to prior experiments with single Josephson junctions comprising topological insulators weak links. Irradiating radio frequencies to the junction we find a spectrum of integer Shapiro steps and an additional fractional step, which is interpreted by a skewed current-phase relationship. In a perpendicular magnetic field we observe Fraunhofer-like interference patterns of the switching currents.
2301.01115v1
2023-01-06
Berry curvature induced valley Hall effect in non-encapsulated hBN/Bilayer graphene heterostructure aligned with near-zero twist angle
Valley Hall effect has been observed in asymmetric single-layer and bilayer graphene systems. In single-layer graphene systems, asymmetry is introduced by aligning graphene with hexagonal boron nitride (hBN) with a near-zero twist angle, breaking the sub-lattice symmetry. Although a similar approach has been used in bilayer graphene to break the layer symmetry and thereby observe the valley Hall effect, the bilayer graphene was sandwiched with hBN on both sides in those studies. This study looks at a much simpler, non-encapsulated structure where hBN is present only at the top of graphene. The crystallographic axes of both hBN and bilayer graphene are aligned. A clear signature of the valley Hall effect through non-local resistance measurement ($R_{\rm{NL}}$) was observed. The observed non-local resistance could be manipulated by applying a displacement field across the heterostructure. Furthermore, the electronic band structure and Berry curvature calculations validate the experimental observations.
2301.02358v2
2023-01-29
Anisotropic magnetic and magnetotransport properties in morphologically distinct Nd0.6Sr0.4MnO3 thin films
We investigate the magnetic and magnetotransport properties of nanostructured Nd0.6Sr0.4MnO3 (NSMO) thin films grown on (100) oriented SrTiO3 (STO) substrates. The thin films fabricated using the pulsed laser deposition technique have been found to possess two distinct surface morphologies: granular and nano rod type. Magnetization measurements have revealed that the films with rod-type morphology exhibit improved in-plane magnetic anisotropy. Magnetotransport studies have revealed that the granular thin films display a characteristic butterfly-shaped low-field magneto-resistive (LFMR) behavior. Furthermore, we investigate the anisotropic magneto-resistive (AMR) phenomenon in the samples and we find that morphology greatly affects AMR. Thin films with rod-type morphology show an enhanced AMR %. Such morphology dependent tunability in magnetoresistance properties over a wide temperature range is potentially interesting for developing oxide-based sensors and devices.
2301.12406v1
2023-02-10
Electrical characterization of the azimuthal anisotropy of $(\mathrm{Ni}_x\mathrm{Co}_{1-x})\mathrm{B}$-based ferromagnetic nanotubes
We report on the structural, electric and magnetic properties of $(\mathrm{Ni}_x\mathrm{Co}_{1-x})\mathrm{B}$ ferromagnetic nanotubes, displaying azimuthal magnetization. The tubes are fabricated using electroless plating in polycarbonate porous templates, with lengths several tens of micrometers, diameters from 100nm to 500nm and wall thicknesses from 10nm to 80nm. The resistivity is $\sim 1.5\times10^{-6}\mathrm{\Omega/m}$, and the anisotropic magnetoresistance~(AMR) of 0.2-0.3%, one order of magnitude larger~(resp. smaller) than in the bulk material, which we attribute to the resistance at grain boundaries. We determined the azimuthal anisotropy field from M(H) AMR loops of single tubes contacted electrically. Its magnitude is around 10mT, and tends to increase with the tube wall thickness, as well as the Co content. However, surprisingly it does not dependent much on the diameter nor on the curvature.
2302.05246v1
2023-02-14
Microscopic mechanism of tunable thermal conductivity in carbon nanotube-geopolymer nanocomposites
Geopolymer has been considered as a green and low-carbon material with great potential application due to its simple synthesis process, environmental protection, excellent mechanical properties, good chemical resistance and durability. In this work, the molecular dynamics simulation is employed to investigate the effect of the size, content and distribution of carbon nanotubes on the thermal conductivity of geopolymer nanocomposites, and the microscopic mechanism is analyzed by the phonon density of states, phonon participation ratio and spectral thermal conductivity, etc. The results show that there is a significant size effect in geopolymer nanocomposites system due to the carbon nanotubes. In addition, when the content of carbon nanotubes is 16.5%, the thermal conductivity in carbon nanotubes vertical axial direction (4.85 W/(mk)) increases 125.6% compared with the system without carbon nanotubes (2.15 W/(mk)). However, the thermal conductivity in carbon nanotubes vertical axial direction (1.25 W/(mk)) decreases 41.9%, which is mainly due to the interfacial thermal resistance and phonon scattering at the interfaces. The above results provide theoretical guidance for the tunable thermal conductivity in carbon nanotube-geopolymer nanocomposites.
2302.07195v1
2023-02-18
Fractional Marcus-Hush-Chidsey-Yakopcic current-voltage model for redox-based resistive memory devices
We propose a circuit-level model combining the Marcus-Hush-Chidsey electron current equation and the Yakopcic equation for the state variable for describing resistive switching memory devices of the structure metal-ionic conductor-metal. We extend the dynamics of the state variable originally described by a first-order time derivative by introducing a fractional derivative with an arbitrary order between zero and one. We show that the extended model fits with great fidelity the current-voltage characteristic data obtained on a Si electrochemical metallization memory device with Ag-Cu alloy.
2302.09407v2
2023-03-01
Electronic Transport Studies of Ag-doped Bi2Se3 Topological Insulator
The structural, magnetotransport, and angle-resolved photoemission spectroscopy (ARPES) of Ag-doped Bi2Se3 single crystals are presented. Temperature dependent resistivity exhibits metallic behavior with a slope change above 200 K for Ag-doped Bi2Se3. The magnetoresistance shows positive quadratic dependence at low fields satisfying Kohler's rule. Hall resistivity measurement shows that electrons are dominant charge carriers. Furthermore, these results agree well with the ARPES spectra observed at T = 20 K, where the Fermi level lies inside the bulk conduction band. The Dirac point of the topological surface states is shifted toward higher binding energy (~ 0.12 eV) for Ag-doped samples as compared to pristine Bi2Se3.
2303.00296v1
2023-02-21
Electronic Transport in the Silicon Carbide Semiconductor in Phase 3C
In this work we study, theoretically, electronic mobility of the silicon carbide semiconductor in the 3C phase, named 3C-SiC. 3C-SiC has shown great potential for applications in extreme conditions. Thus, the study of the electronic mobility of this semiconductor is of great interest. In this work were theoretically deduced: drift velocity, displacement and mobility of the charge carriers in the n-type doped 3C-SiC semiconductor, subjected to a constant electric field. The dependence of these transport properties as a function of the intensity of the electric field and temperature was analyzed. For this, a differential equation of motion was used with a source term (low intensity electric fields) and a term of resistance to movement (electrical resistance).
2303.09457v1
2023-03-19
The fluidic memristor: collective phenomena in elastohydrodynamic networks
Fluid flow networks are ubiquitous and can be found in a broad range of contexts, from human-made systems such as water supply networks to living systems like animal and plant vasculature. In many cases, the elements forming these networks exhibit a highly non-linear pressure-flow relationship. Although we understand how these elements work individually, their collective behavior remains poorly understood. In this work, we combine experiments, theory, and numerical simulations to understand the main mechanisms underlying the collective behavior of soft flow networks with elements that exhibit negative differential resistance. Strikingly, our theoretical analysis and experiments reveal that a minimal network of nonlinear resistors, which we have termed a `fluidic memristor', displays history-dependent resistance. This new class of element can be understood as a collection of hysteresis loops that allows this fluidic system to store information. Our work provides insights that may inform new applications of fluid flow networks in soft materials science, biomedical settings, and soft robotics, and may also motivate new understanding of the flow networks involved in animal and plant physiology.
2303.10777v1
2023-03-20
Engineering Higher-Order Dirac and Weyl Semimetallic phase in 3D Topolectrical Circuits
We propose a 3D topolectrical (TE) network that can be tuned to realize various higher-order topological gapless and chiral phases. We first study a higher-order Dirac semimetal phase that exhibits a hinge-like Fermi arc linking the Dirac points. This circuit can be extended to host highly tunable first- and second-order Weyl semimetal phases by introducing a non-reciprocal resistive coupling in the x-y plane that breaks time reversal symmetry. The first- and second-order Weyl points are connected by zero-admittance surface and hinge states, respectively. We also study the emergence of first- and second-order chiral modes induced by resistive couplings between similar nodes in the z-direction. These modes respectively occur in the midgap of the surface and hinge admittance bands in our circuit model without the need for any external magnetic field.
2303.10911v2
2023-03-20
Electronic and magnetic properties of Lu and LuH$_2$
Clarifying the electronic and magnetic properties of lutetium, lutetium dihydride, and lutetium oxide is very helpful to understand the emergent phenomena in lutetium-based compounds (such as room-temperature superconductivity). However, this kind of study is still scarce at present. Here, we report on the electronic and magnetic properties of lutetium metals, lutetium dihydride powders, and lutetium oxide powders. Crystal structures and chemical compositions of these samples were characterized by X-ray diffraction and X-ray photoemission spectroscopy, respectively. Electrical transport measurements show that the resistance of lutetium has a linear behavior depending on temperature, whereas the resistance of lutetium dihydride powders is independent of temperature. More interestingly, paramagnetism-ferromagnetism-spin glass transitions were observed at near 240 and 200 K, respectively, in lutetium metals. Our work uncovered the complex magnetic properties of Lu-based compounds.
2303.11063v2
2023-04-22
A Deep Neural Network Deployment Based on Resistive Memory Accelerator Simulation
The objective of this study is to illustrate the process of training a Deep Neural Network (DNN) within a Resistive RAM (ReRAM) Crossbar-based simulation environment using CrossSim, an Application Programming Interface (API) developed for this purpose. The CrossSim API is designed to simulate neural networks while taking into account factors that may affect the accuracy of solutions during training on non-linear and noisy ReRAM devices. ReRAM-based neural cores that serve as memory accelerators for digital cores on a chip can significantly reduce energy consumption by minimizing data transfers between the processor and SRAM and DRAM. CrossSim employs lookup tables obtained from experimentally derived datasets of real fabricated ReRAM devices to digitally reproduce noisy weight updates to the neural network. The CrossSim directory comprises eight device configurations that operate at different temperatures and are made of various materials. This study aims to analyse the results of training a Neural Network on the Breast Cancer Wisconsin (Diagnostic) dataset using CrossSim, plotting the innercore weight updates and average training and validation loss to investigate the outcomes of all the devices.
2304.11337v1
2023-05-16
The kinetic theory of ultra-subsonic fermion systems and applications to flat band magic angle twisted bilayer graphene
The only kinematically-allowed phonon-scattering events for bands of subsonic fermions ($v_F < v_p$) are interband transitions, leading to different low-$T$ transport physics than in the typical supersonic case. We apply a kinetic theory of phonon-limited transport to a generic two-band system of subsonic fermions, deriving formulae for relaxation times and resistivity that are accurate in the limit of close bands and small $v_F/v_p$. We predict regimes of $\rho \propto T$, $\rho \propto T^2$, and perfect conductivity. Our theory predicts linear-in-$T$ resistivity down to a crossover temperature that is suppressed from its supersonic analogue by a factor of $v_F/v_p$, offering a new explanation for low-$T$ "strange metal" behavior observed in flat band systems.
2305.09120v1
2023-05-31
Supercurrent through a single transverse mode in nanowire Josephson junctions
Hybrid superconductor-semiconductor materials are fueling research in mesoscopic physics and quantum technology. Recently demonstrated smooth $\beta$-Sn superconductor shells, due to the increased induced gap, are expanding the available parameter space to new regimes. Fabricated on quasiballistic InSb nanowires, with careful control over the hybrid interface, Sn shells yield critical current-normal resistance products exceeding temperature by at least an order of magnitude even when nanowire resistance is of order 10k$\Omega$. In this regime Cooper pairs travel through a purely 1D quantum wire for at least part of their trajectory. Here, we focus on the evolution of supercurrent in magnetic field parallel to the nanowire. Long decay up to fields of 1T is observed. At the same time, the decay for higher occupied subbands is notably faster in some devices but not in others. We analyze this using a tight-binding numerical model that includes the Zeeman, orbital and spin-orbit effects. When the first subband is spin polarized, we observe a dramatic suppression of supercurrent, which is also confirmed by the model and suggests an absence of significant triplet supercurrent generation.
2306.00146v1
2023-06-26
Origin of magnetic ordering in half-Heusler RuMnGa
The half-Heusler alloy RuMnGa having valence electron count (VEC) 18 has recently been theoretically proposed to exhibit compensated ferrimagnetic (CFiM) character instead of the expected nonmagnetic ground state. On the other hand, a preliminary experimental study proposed ferromagnetic (FM) ordering. As no half-Heusler system with VEC 18 is known to exhibit magnetic ordering, we have investigated the details of crystal structure and magnetic properties of RuMnGa using a combination of experimental tools, viz., x-ray and neutron diffraction techniques, dc and ac susceptibility, isothermal magnetisation, heat capacity, resistivity and neutron depolarisation measurements. Rietveld refinements of x-ray and neutron diffraction data suggest single phase nature of the compound with elemental composition RuMn$_{0.86}$Ga$_{1.14}$. We have shown that the system exhibits FM-type ordering owing to the inherent presence of this minor off-stoichiometry, showing very low magnetic moment. The system also exhibits reentrant canonical spin-glass behaviour, which is rarely observed in half-Heusler alloys. The temperature coefficient of resistivity changes its sign from negative to positive and further to negative as the temperature decreases.
2306.14836v1
2023-07-02
Giant coercivity, resistivity upturn, and anomalous Hall effect in ferrimagnetic FeTb
Despite the blooming interest, the transition-metal rare-earth ferrimagnets have not been comprehensively understood in terms of their coercivity and transport properties. Here, we report a systematic study of the magnetic and transport properties of ferrimagnetic FeTb alloy by varying the layer thickness and temperature. The FeTb is tuned from the Tb-dominated regime to the Fe-dominated regime via the layer thickness, without varying the composition. The coercivity closely follows the $1/\cos\theta_H$ scaling (where $\theta_H$ is the polar angle of the external magnetic field) and increases quasi-exponentially upon cooling (exceeding 90 kOe at low temperatures), revealing that the nature of the coercivity is the thermally-assisted domain wall depinning field. The resistivity exhibits a quasi-linear upturn upon cooling possibly due to thermal vibrations of the structure factor of the amorphous alloy. The existing scaling laws of the anomalous Hall effect in the literature break down for the amorphous FeTb that are either Fe- or Tb-dominated. These findings should advance the understanding of the transition-metal-rare-earth ferrimagnets and the associated ferrimagnetic phenomena in spintronics.
2307.00475v1
2023-07-19
Observation of large intrinsic anomalous Hall conductivity in polycrystalline Mn$_3$Sn films
We report the observation of anomalous Hall effect in Mn$_3$Sn polycrystalline thin films deposited on Pt coated Al$_2$O$_3$ substrate with a large anomalous Hall conductivity of 65($\Omega$cm)$^{-1}$ at 3K. The Hall and magnetic measurements show a very small hysteresis owing to a weak ferromagnetic moment in this material. The longitudinal resistivity decreases sufficiently for the thin films as compared to the polycrystalline bulk sample used as the target for the film deposition. The anomalous Hall resistivity and conductivity decreases almost linearly with the increase in the temperature. A negative magnetoresistance is observed for all the measured temperatures with the negative decrease in the magnitude with the increase in temperature.
2307.09808v1
2023-10-27
A diamond anvil microassembly for Joule heating and electrical measurements up to 150 GPa and 4000 K
When diamond anvil cell (DAC) sample chambers are outfitted with both thermal insulation and electrodes, two cutting-edge experimental methods are enabled: Joule heating with spectroradiometric temperature measurement, and electrical resistance measurements of samples heated to thousands of kelvin. The accuracy of temperature and resistance measurements, however, often suffers from poor control of the shape and location of the sample, electrodes, and thermal insulation. Here, we present a recipe for the reproducible and precise fabrication of DAC sample, electrodes, and thermal insulation using a three-layer microassembly. The microassembly contains two potassium chloride thermal insulation layers, four electrical leads, a sample, and a buttressing layer made of polycrystalline alumina. The sample, innermost electrodes, and buttress layer are fabricated by focused-ion-beam milling. Three iron samples are presented as proof of concept. Each is successfully compressed and pulsed Joule heated while maintaining a four-point probe configuration. The highest pressure-temperature condition achieved is $\sim 150$ GPa and $\sim 4000$ K.
2310.18176v1
2023-11-02
Disentangling transport mechanisms in a correlated oxide by photoinduced charge injection
We present a novel heterostructured approach to disentangle the mechanism of electrical transport of the strongly correlated PrNiO3, by placing the nickelate under the photoconductor CdS. This enables the injection of carriers into PrNiO3 in a controlled way, which can be used to interrogate its intrinsic transport mechanism. We find a non-volatile resistance decrease when illuminating the system at temperatures below the PrNiO3 metal-insulator transition. The photoinduced change becomes more volatile as the temperature increases. These data help understand the intrinsic transport properties of the nickelate-CdS bilayer. Together with data from a bare PrNiO3 film, we find that the transport mechanism includes a combination of mechanisms including both thermal activation and variable range hopping. At low temperatures without photoinduced carriers the transport is governed by hopping, while at higher temperatures and intense illumination the activation mechanism becomes relevant. This work shows a new way to optically control the low-temperature resistance of PrNiO3.
2311.00904v1
2023-11-13
Metallic conductivity on Na-deficient structural domain walls in the spin-orbit Mott insulator Na$_2$IrO$_3$
Honeycomb Na$_2$IrO$_3$ is a prototype spin-orbit Mott insulator and Kitaev magnet. We report a combined structural and electrical resistivity study of Na$_2$IrO$_3$ single crystals. Laue back-scattering diffraction indicates twinning with $\pm 120^\circ$ rotation around the $c^*$-axis while scanning electron microscopy displays nanothin lines parallel to all three b-axis orientations of twin domains. Energy dispersive x-ray analysis line-scans across such domain walls indicate no change of the Ir signal intensity, i.e. intact honeycomb layers, while the Na intensity is reduced down to $\sim 2/3$ of its original value at the domain walls, implying significant hole doping. Utilizing focused-ion-beam micro-sectioning, the temperature dependence of the electrical resistance of individual domain walls is studied. It demonstrates the tuning through the metal-insulator transition into a correlated-metal ground state by increasing hole doping.
2311.07275v1
2023-11-30
Electrical resistance associated with the scattering of optically oriented electrons in n-GaAs
In a bulk GaAs crystal, an unusual magnetoresistance effect, which takes place when a spin-polarized current flows through the sample, was detected. Under conditions of optical pumping of electron spins, an external magnetic field directed along the electric current and perpendicular to the oriented spins decreases the resistance of the material. The phenomenon is due to the spin-dependent scattering of electrons by neutral donors. It was found that the sign of the magnetoresistance does not depend on the sign of the exciting light circular polarization, the effect is even with respect to the sign of the spin polarization of the carriers, which indicates a correlation between the spins of optically oriented free electrons and electrons localized on donors.
2311.18713v1
2023-12-01
Comparative study of Kondo effect in Vanadium dichalcogenides VX$_2$ (X=Se & Te)
We report on the electrical transport, magnetotransport, and magnetic properties studies on the transition metal dichalcogenides VSe$_2$ and VTe$_2$ and draw a comprehensive comparison between them. We observe Kondo effect in both systems induced by the exchange interaction between localized moments and conduction electrons at low temperature, resulting into resistance upturn at 6 K for VSe$_2$ and 17 K for VTe$_2$. From the field dependent resistance measurements we find that the data is fitted best with modified Hamann equation corrected by the quantum Brillouin function for VSe$_2$, while the data is fitted best with modified Hamann equation corrected by the classical Langevin function for VTe$_2$. Interestingly, we observe a contrasting magnetoresistance (MR) property between these systems across the Kondo temperature. That means, negative MR is found in both systems in the Kondo state. In the normal state MR is positive for VSe$_2$, while it is negligible for VTe$_2$. In addition, both systems show weak ferromagnetism at low temperature due to intercalated V atoms.
2312.09258v1
2023-12-28
Memristive behavior of functionalized graphene quantum dot and polyaniline nanocomposites
Zero-dimensional graphene quantum dots (GQD) dispersed in conducting polymer matrix display a striking range of optical, mechanical, and thermoelectric properties which can be utilized to design next-generation sensors and low-cost thermoelectric. This exotic electrical property in GQDs is achieved by exploiting the concentration of the GQDs and by tailoring the functionalization of the GQDs. However, despite extensive investigation, the nonlinear resistivity behavior leading to memristive like characteristic has not been explored much. Here, we report electrical characterisation of nitrogen functionalized GQD (NGQD) embedded in a polyaniline (PANI) matrix. We observe a strong dependence of the resistance on current and voltage history, the magnitude of which depends on the NGQD concentration and temperature. We explain this memristive property using a phenomenological model of the alignment of PANI rods with a corresponding charge accumulation arising from the NGQD on its surface. The NGQD-PANI system is unique in its ability to matrix offers a unique pathway to design neuromorphic logic and synaptic architectures with crucial advantages over existing systems.
2312.16759v1
2024-01-04
Anomalous upper critical field in the quasicrystal superconductor Ta$_{1.6}$Te
Superconductivity in quasicrystals poses a new challenge in condensed matter physics. We measured the resistance and ac magnetic susceptibility of a Ta$_{1.6}$Te dodecagonal quasicrystal, which is superconducting below $T_c \sim$ 1 K. We show that the upper critical field increases linearly with a large slope of $-$4.4 T/K with decreasing temperature down to 0.04 K, with no tendency to level off. The extrapolated zero-temperature critical field exceeds the Pauli limit by a factor of 2.3. We also observed flux-flow resistance with thermally activated behavior and an irreversibility field that is distinct from the upper critical field. We discuss these peculiarities in terms of the nonuniform superconducting gap and spin--orbit interaction in quasicrystal structures.
2401.02079v1
2024-01-07
Advancing Noise-Resilient Twist Angle Characterization in Bilayer Graphene through Raman Spectroscopy via GAN-CNN Modeling
In this study, we introduce an innovative methodology for robust twist angle identification in bilayer graphene using Raman spectroscopy, featuring the integration of generative adversarial network and convolutional neural network (GAN-CNN). Our proposed approach showcases remarkable resistance to noise interference, particularly in ultra-low Signal-to-Noise Ratio (SNR) conditions. We demonstrate the GAN-CNN model's robust learning capability, even when SNR reaches minimal levels. The model's exceptional noise resilience negates the necessity for preprocessing steps, facilitating accurate classification, and substantially reducing computational expenses. Empirical results reveal the model's prowess, achieving heightened accuracy in twist angle identification. Specifically, our GAN-CNN model achieves a test accuracy exceeding 99.9% and a recall accuracy of 99.9%, relying on an augmented dataset containing 4209 spectra. This work not only contributes to the evolution of noise-resistant spectral analysis methodologies but also provides crucial insights into the application of advanced deep learning techniques for bilayer graphene characterization through Raman spectroscopy. The findings presented herein have broader implications for enhancing the precision and efficiency of material characterization methodologies, laying the foundation for future advancements in the field.
2401.03371v1
2024-01-10
Superconductivity in Ternary Zirconium Telluride Zr6MTe2 with 3d Transition Metals
We report the synthesis, electronic properties, and electronic states of Zr6MTe2 (M = Cr, Mn, Fe, and Co), which is isostructural to a recently discovered superconductor family Sc6MTe2. Based on the electrical resistivity and heat capacity data measured at low temperatures, Zr6FeTe2 is found to show bulk superconductivity below Tc = 0.76 K. Zr6CoTe2 also exhibited zero resistivity due to superconductivity below 0.13 K. In contrast, Zr6+dMn1-dTe2 does not show superconductivity but instead exhibits strong magnetism, which most likely prevents the formation of superconductivity in this material. The electronic properties and electronic states of Zr6MTe2 are discussed in comparison with those of Sc6MTe2.
2401.04870v1
2024-01-25
Non-zero crossing current-voltage characteristics of interface-type resistive switching devices
A number of memristive devices, mainly ReRAMs, have been reported to exhibit a unique non-zero crossing hysteresis attributed to the interplay of resistive and not yet fully understood `capacitive', and `inductive' effects. This work exploits a kinetic simulation model based on the stochastic cloud-in-a-cell method to capture these effects. The model, applied to Au/BiFeO$_{3}$/Pt/Ti interface-type devices, incorporates vacancy transport and capacitive contributions. The resulting nonlinear response, characterized by hysteresis, is analyzed in detail, providing an in-depth physical understanding of the virtual effects. Capacitive effects are modeled across different layers, revealing their significant role in shaping the non-zero crossing hysteresis behavior. Results from kinetic simulations demonstrate the impact of frequency-dependent impedance on the non-zero crossing phenomenon. This model provides insights into the effects of various device material properties, such as Schottky barrier height, device area and oxide layer on the non-zero crossing point.
2401.14507v1
2024-01-27
Electronic structure and physical properties of candidate topological material GdAgGe
We grew needle-shaped single crystals of GdAgGe, which crystallizes in a noncentrosymmetric hexagonal crystal structure with space group P$\overline{6}$2$m$ (189). The magnetic susceptibility data for $H \perp c$ reveal two pronounced antiferromagnetic transitions at $T_{N1}$ = 20 K and $T_{N2}$ = 14.5 K. The magnetic susceptibility anomalies are less prominent for $H \parallel c$. The transition at $T_{N1}$ is accompanied by a pronounced heat capacity anomaly confirming the bulk nature of the magnetic transition. Below $T_{N1}$, the electrical resistivity data follows a $T^{3/2}$ dependence. In the magnetically ordered state, GdAgGe shows positive transverse magnetoresistance, which increases with decreasing temperature and increasing field, reaching a value of $\sim$ 27% at 9 T and 10 K. The Hall resistivity data and electronic band structure calculations suggest that both the hole and electron charge carriers contribute to the transport properties. The electronic band structure displays linear band crossings near the Fermi level. The calculations reveal that GdAgGe has a nodal line with drumhead surface states coupled with a nonzero Berry phase, making it a nontrivial nodal-line semimetal.
2401.15464v1
2024-02-29
First-principles electron-phonon interactions and electronic transport in large-angle twisted bilayer graphene
Twisted bilayer graphene (tBLG) has emerged as an exciting platform for novel condensed matter physics. However, electron-phonon ($e$-ph) interactions in tBLG and their effects on electronic transport are not completely understood. Here we show first-principles calculations of $e$-ph interactions and resistivity in commensurate tBLG with large twist angles of 13.2 and 21.8 degrees. These calculations overcome key technical barriers, including large unit cells of up to 76 atoms, Brillouin-zone folding of the $e$-ph interactions, and unstable lattice vibrations due to the AA-stacked domains. We show that $e$-ph interactions due to layer-breathing (LB) phonons enhance intervalley scattering in large-angle tBLG. This interaction effectively couples the two layers, which are otherwise electronically decoupled at such large twist angles. As a result, the phonon-limited resistivity in tBLG deviates from the temperature-linear trend characteristic of monolayer graphene and tBLG near the magic angle. Taken together, our work quantifies $e$-ph interactions and scattering mechanisms in tBLG, revealing subtle interlayer coupling effects at large twist angles.
2402.19453v1
2024-03-04
Tuning charge density wave of kagome metal ScV6Sn6
Compounds with a kagome lattice exhibit intriguing properties and the charge density wave (CDW) adds an additional layer of interest to research on them. In this study, we investigate the temperature and magnetic field dependent electrical properties under a chemical substitution and hydrostatic pressure of ScV6Sn6, a non-magnetic charge density wave (CDW) compound. Substituting 5 % Cr at the V site or applying 1.5 GPa of pressure shifts the CDW to 50 K from 92 K. This shift is attributed to the movement of the imaginary phonon band, as revealed by the phonon dispersion relation. The longitudinal and Hall resistivities respond differently under these stimuli. The magnetoresistance (MR) maintains its quasilinear behavior under pressure, but it becomes quadratic after Cr substitution. The anomalous Hall-like behavior of the parent compound persists up to the respective CDW transition under pressure, after which it sharply declines. In contrast, the longitudinal and Hall resistivities of Cr substituted compounds follow a two-band model and originates from the multi carrier effect. These results clearly highlight the role of phonon contributions in the CDW transition and call for further investigation into the origin of the anomalous Hall-like behavior in the parent compound.
2403.02463v1
2024-03-05
A Reduced-Order Resistive Force Model for Robotic Foot-Mud Interactions
Legged robots are well-suited for broad exploration tasks in complex environments with yielding terrain. Understanding robotic foot-terrain interactions is critical for safe locomotion and walking efficiency for legged robots. This paper presents a reduced-order resistive-force model for robotic-foot/mud interactions. We focus on vertical robot locomotion on mud and propose a visco-elasto-plastic analog to model the foot/mud interaction forces. Dynamic behaviors such as mud visco-elasticity, withdrawing cohesive suction, and yielding are explicitly discussed with the proposed model. Besides comparing with dry/wet granular materials, mud intrusion experiments are conducted to validate the force model. The dependency of the model parameter on water content and foot velocity is also studied to reveal in-depth model properties under various conditions. The proposed force model potentially provides an enabling tool for legged robot locomotion and control on muddy terrain.
2403.02617v1