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2023-01-18
Paper-based Flexible Supercapacitors with drawn van der Waals materials
Two-dimensional (2D) materials are widely used in various applications due to their extraordinary properties. In particular, their electrochemical stability, low electrical resistance, and huge specific surface area make them very interesting active materials for supercapacitors. Herein, flexible, biodegradable, and low-cost supercapacitors are introduced in a very simple way based on hand-drawing pencil traces or -rubbing molybdenum disulfide (MoS2), titanium trisulfide (TiS3) and franckeite traces on the paper. Results demonstrate that pencil-drawn paper has higher capacitance performance (~6.39 F/g) among the suggested electrodes. Interestingly, the introduced MoS2/pencil, TiS3/pencil, and franckeite/pencil drawn paper electrodes reveal dramatic improvements with long cyclic life thanks to the occurrence of synergetic effects and higher available active cites within the heterostructures. Moreover, the assembled symmetric solid-state supercapacitors retain their performance even under applied bending, indicating their excellent potential for wearable/flexible applications.
2301.07759v1
2023-02-18
Magnetoresistance signature of two-dimensional electronic states in Co$_3$Sn$_2$S$_2$
Two-dimensional (2D) Dirac bands and flat bands are characteristics of a kagome lattice. However, experimental studies on their electrical transport are few, because three-dimensional (3D) bulk bands of kagome materials, consisting of stacked 2D kagome layers, dominate the transport. We report a magnetoresistance (MR) study of a kagome material, Co$_3$Sn$_2$S$_2$. Based on analysis of the temperature, magnetic field, and field angle dependence of the resistivity, we obtain a complete anatomy of MR. Besides a magnon MR, a chirality-dependent MR, and a chiral-anomaly-induced MR, the most intriguing feature is an orbital MR that scales only with the out-of-plane field, which strongly indicates its 2D nature. We attribute it to the Dirac band of the kagome lattice.
2302.09229v1
2023-03-01
Thermodynamic determination of the equilibrium first-order phase-transition line hidden by hysteresis in a phase diagram
Phase diagrams form the basis for the study of material science, and the profiles of phase-transition lines separating different thermodynamic phases include comprehensive information about thermodynamic quantities, such as latent heat. However, in some materials exhibiting field-induced first-order transitions (FOTs), the equilibrium phase-transition line is hidden by the hysteresis region associated with the FOT; thus, it cannot be directly determined from measurements of resistivity, magnetization, etc. Here, we demonstrate a thermodynamics-based method for determining the hidden equilibrium FOT line. This method is verified for the FOT between antiferromagnetic and ferrimagnetic states in magneto-electric compounds (Fe$_{0.95}$Zn$_{0.05}$)$_{2}$Mo$_{3}$O$_{8}$. The equilibrium FOT line determined based on the Clausius-Clapeyron equation exhibits a reasonable profile in terms of the third law of thermodynamics, and it shows marked differences from the midpoints of the hysteresis region. Our findings highlight that care should be taken for referring to the hysteresis midpoint line when discussing field-induced latent heat or magnetocaloric effects.
2303.00327v1
2023-03-21
Structure, physical properties, and magnetically tunable topological phases in topological semimetal EuCuBi
A single material achieving multiple topological phases can provide potential application for topological spintronics, whereas the candidate materials are very limited. Here, we report the structure, physical properties, and possible emergence of multiple topological phases in the newly discovered, air-stable EuCuBi single crystal. EuCuBi crystallizes in a hexagonal space group P63/mmc (No. 194) in ZrBeSi-type structure with an antiferromagnetic (AFM) ground state below TN = 11.2 K. There is a competition between AFM and ferromagnetic (FM) interactions below TN revealed by electrical resistivity and magnetic susceptibility measurements. With the increasing magnetic field, EuCuBi evolves from the AFM ground state with a small amount of FM component, going through two possible metamagnetic phases, finally reaches the field-induced FM phase. Based on the first-principles calculations, we demonstrate that the Dirac, Weyl, and possible mirror Chern insulator can be achieved in EuCuBi by tuning the temperature and applying magnetic field, making EuCuBi a promising candidate for exploring multiple topological phases.
2303.11894v1
2023-04-20
Magnetic behavior of cubic Dy4RhAl with respect to isostructural Dy4PtAl, revealing a novel 4f d-band interaction
We have investigated for the first time the magnetic behaviour of an intermetallic compound, Dy4RhAl, crystallizing in Gd4RhIn type cubic structure containing 3 sites for rare-earth (R), by several bulk measurements down to 1.8 K. This work is motivated by the fact that the isostructural Dy compound in the R4PtAl family surprisingly orders ferromagnetically unlike other members of this series, which order antiferromagnetically. The results reveal that the title compound undergoes antiferromagnetic order at about 18 K, similar to other heavy R members of R4RhAl family, unlike its Pt counterpart, indicating a subtle difference in the role of conduction electrons to decide magnetism of these compounds. Besides, spin-glass features coexisting with antiferromagnetic order could be observed, which could mean cluster antiferromagnetism. The electrical resistivity and magnetoresistance behaviours in the magnetically ordered state are typical of magnetic materials exhibiting antiferromagnetic gap. Features attributable to spin-reorientation as a function of temperature and magnetic field can be seen in the magnetization data.
2304.10122v1
2023-08-07
Oxide layer formation prevents deteriorating ion migration in thermoelectric Cu$_2$Se during operation in air
Cu$_2$Se is a mixed ionic-electronic conductor with outstanding thermoelectric performance originally envisioned for space missions. Applications were discontinued due to material instability, where elemental Cu grows at the electrode interfaces during operation in vacuum. Here, we show that when Cu$_2$Se is operating in air, formation of an oxide surface layer suppresses Cu$^+$ migration along the current direction. In operando X-ray scattering and electrical resistivity measurements quantify Cu$^+$ migration through refinement of atomic occupancies and phase composition analysis. Cu deposition can be prevented during operation in air, irrespective of a critical voltage, if the thermal gradient is applied along the current direction. Maximum entropy electron density analysis provides experimental evidence that Cu$^+$ migration pathways under thermal and electrical gradients differ substantially from equilibrium diffusion. The study establishes new promise for inexpensive sustainable Cu$_2$Se in thermoelectric applications, and it underscores the importance of atomistic insight into materials during thermoelectric operating conditions.
2308.03559v1
2023-09-01
Denture reinforcement via topology optimization
We present a computational design method that optimizes the reinforcement of dental prostheses and increases the durability and fracture resistance of dentures. Our approach optimally places reinforcement, which could be implemented by modern multi-material, three-dimensional printers. The study focuses on reducing deformation by identifying regions within the structure that require reinforcement (E-glass material). Our method is applied to a three-dimensional removable lower jaw dental prosthesis and aims to improve the living quality of denture patients and pretend fracture of dental reinforcement in clinical studies. To do this, we compare the deformation results of a non-reinforced denture and a reinforced denture that has two materials. The results indicate the maximum deformation is lower and node-based displacement distribution demonstrates that the average displacement distribution is much better in the reinforced denture.
2309.00396v1
2023-09-06
Magnetic order in the $S_{\mathrm{eff}}$ = 1/2 triangular-lattice compound NdCd$_3$P$_3$
We present and characterize a new member of the $R$Cd$_3$P$_3$ ($R$= rare earth) family of materials, NdCd$_3$P$_3$, which possesses Nd$^{3+}$ cations arranged on well-separated triangular lattice layers. Magnetic susceptibility and heat capacity measurements demonstrate a likely $S_{\mathrm{eff}}$ = 1/2 ground state, and also reveal the formation of long-range antiferromagnetic order at $T_{N} = 0.34$ K. Via measurements of magnetization, heat capacity, and electrical resistivity, we characterize the electronic properties of NdCd$_3$P$_3$ and compare results to density functional theory calculations.
2309.03332v1
2023-09-18
Ferroelectric Schottky diodes of CuInP$_2$S$_6$ nanosheet
Ferroelectricity in van der Waals (vdW) layered material has attracted a great deal of interest recently. CuInP$_2$S$_6$ (CIPS), the only vdW layered material whose ferroelectricity in the bulk was demonstrated by direct polarization measurements, was shown to remain ferroelectric down to a thickness of a few nanometers. However, its ferroelectric properties have just started to be explored in the context of potential device applications. We report here the preparation and measurements of metal-ferroelectric semiconductor-metal heterostructures using nanosheets of CIPS obtained by mechanical exfoliation. Four bias voltage and polarization dependent resistive states were observed in the current-voltage characteristics, which we attribute to the formation of ferroelectric Schottky diode, along with switching behavior.
2309.10045v1
2023-10-25
Super-resolution imaging reveals resistance to mass transfer in functionalized stationary phases
Chemical separations are costly in terms of energy, time, and money. Separation methods are optimized with inefficient trial-and-error approaches that lack insight into the molecular dynamics that lead to the success or failure of a separation and, hence, ways to improve the process. We perform super-resolution imaging of fluorescent analytes in four different commercial liquid chromatography materials. Surprisingly, we observe that chemical functionalization can block over fifty percent of the porous interior of the material, rendering it inaccessible to small molecule analytes. Only in situ imaging unveils the inaccessibility when compared to the industry-accepted ex situ characterization methods. Selectively removing some of the functionalization with solvent restores pore access without significantly altering the single-molecule kinetics that underlie the separation and agree with bulk chromatography measurements. Our molecular results determine that commercial stationary phases, marketed as fully porous, are over-functionalized and provide a new avenue to characterize and direct separation material design from the bottom-up.
2310.16266v1
2023-11-17
Fabrication of damage-free and/or contamination-free sub-um electrodes using PMMA masks
Quality of the electrical contacts and interfaces in various metal/semiconductor/insulator heterostructures is one of the pivotal aspects in both applied and fundamental research areas. For instance, non-optimal contact resistance can limit the overall efficiency of a certain developed technology and thus considerably narrow the range or fully block its practical application. On the other hand in fundamental research it is often the case that the manifestation of targeted phenomenon crucially depends on the level of contamination in the fabricated experimental samples. Here we offer a set of recipes that are aimed at contamination-free and damage-free fabrication of the devices, mostly developed for the two dimensional materials, but nevertheless applicable for a wider range of the systems, where the quality of the interfaces and/or non-invasiveness of the fabrication recipes are important. Our recipes are based on the preparation of the flexible PMMA membranes, with the help of which we can prepare residue-free or damage-free electrical connections to the studied material.
2311.10340v1
2023-11-20
Spontaneous supercrystal formation during a strain-engineered metal-insulator transition
Mott metal-insulator transitions possess electronic, magnetic, and structural degrees of freedom promising next generation energy-efficient electronics. We report a previously unknown, hierarchically ordered state during a Mott transition and demonstrate correlated switching of functional electronic properties. We elucidate in-situ formation of an intrinsic supercrystal in a Ca2RuO4 thin film. Machine learning-assisted X-ray nanodiffraction together with electron microscopy reveal multi-scale periodic domain formation at and below the film transition temperature (TFilm ~ 200-250 K) and a separate anisotropic spatial structure at and above TFilm. Local resistivity measurements imply an intrinsic coupling of the supercrystal orientation to the material's anisotropic conductivity. Our findings add an additional degree of complexity to the physical understanding of Mott transitions, opening opportunities for designing materials with tunable electronic properties.
2311.11842v1
2023-12-10
Characterization of Semiconducting Materials Using the Van der Pauw Method
Semiconductors are currently an active topic of study due to the endless range of applications in electronic hardware and computer engineering. In this experiment, the material properties (i.e. resistivity $\rho$, Hall coefficient $R_{H}$, and mobility $\mu$) of a doped GaAs sheet is described by utilizing Hall Effect and the Van der Pauw method with varying temperature $T$ and magnetic field values $B$. It is determined that the sample is an $n$-type semiconductor using the sign of $R_H$, which is measured to be $R_H = -2.9 \times 10^{-12} \pm 0.1 \times 10^{-14} ~ \text{m}^{3} \text{C}^{-1}$, at $T = 303 ~\text{K}$ and $B = 3.3 ~\text{kGs}$. Furthermore, the rate of change for the slope $R_H$ and $T$ is increasing along $B$ at the rate of $\Delta k/ \Delta B = \left(3.6 \pm 0.5 \right) \times 10^{-16} ~\text{m}^3 (\text{CK} \cdot \text{kGs})^{-1}$, meaning the charge accumulation caused by the current and Lorentz force is quadratic in $B$. It is also discovered that $\mu$, and therefore the electron drift velocity is reduced proportionally at higher $T$-values. This method provides a potential analogue in quantum scales with the Quantum Hall Effect and characterisation of quantum dots.
2312.05744v1
2023-12-15
Smart sensing of the multifunctional properties of magnetron sputtered $MoS_2$ across the amorphous-crystalline transition
Molybdenum disulfide, $MoS_2$, is a next-generation semiconductor and is frequently integrated into emergent optoelectronic technologies based on two-dimensional materials. Here, we present a method that provides direct optical feedback on the thickness and crystallinity of sputter-deposited $MoS_2$ down to the few-layer regime. This smart sensing enables tracking the material's functional properties, such as excitonic response, sheet resistance, and hardness across the amorphous-crystalline transition. To illustrate the potential of such feedback-controlled fabrication, we realized $MoS_2$-based hyperbolic metamaterials (HMM) with controllable optical topological transitions and hardness.
2312.10180v2
2024-01-10
A Universal Scaling Law for Intrinsic Fracture Energy of Networks
Networks of interconnected materials permeate throughout nature, biology, and technology due to exceptional mechanical performance. Despite the importance of failure resistance in network design and utility, no existing physical model effectively links strand mechanics and connectivity to predict bulk fracture. Here, we reveal a universal scaling law that bridges these levels to predict the intrinsic fracture energy of diverse networks. Simulations and experiments demonstrate its remarkable applicability to a breadth of strand constitutive behaviors, topologies, dimensionalities, and length scales. We show that local strand rupture and nonlocal energy release contribute synergistically to the measured intrinsic fracture energy in networks. These effects coordinate such that the intrinsic fracture energy scales independent of the energy to rupture a strand; it instead depends on the strand rupture force, breaking length, and connectivity. Our scaling law establishes a physical basis for understanding network fracture and a framework for fabricating tough materials from networks across multiple length scales.
2401.05564v1
2024-01-23
Berezinskii-Kosterlitz-Thouless transition in rhenium nitride films
The quest to manipulate and understand superconductivity demands exploring diverse materials and unconventional behaviors. Here, we investigate the BKT transition in synthesized ReN$_x$ thin films, demonstrating their emergence as a compelling platform for studying this pivotal phenomenon. By systematically varying synthesis parameters, we achieve ReN$_x$ films exhibiting a BKT transition comparable or even surpassing the archetypal NbN$_x$ system. Detailed current-voltage measurements unlock the intrinsic parameters of the BKT transition, revealing the critical role of suppressed superconducting volume in pushing ReN$_x$ towards the two-dimensional limit. Utilizing this two-dimensional electron system, we employ Beasley-Mooij-Orlando (BMO) theory to extract the vortex unbinding transition temperature and superelectron density at the critical point. Further confirmation of the BKT transition is obtained through temperature-dependent resistivity, current-voltage, and magnetoresistance measurements. Our findings suggest that native disorder and inhomogeneity within ReN$_x$ thin films act to suppress long-range coherence, ultimately driving the system towards the BKT regime. This work establishes ReN$_x$ as a promising material for exploring BKT physics and paves the way for tailoring its properties for potential applications in superconducting devices.
2401.12628v1
2024-02-11
Cooperating Cracks in Two-Dimensional Crystals
The pattern development of multiple cracks in extremely anisotropic solids such as bilayer or multilayer two-dimensional (2D) crystals contains rich physics, which, however, remains largely unexplored. We studied crack interaction across neighboring 2D layers by transmission electron microscopy and molecular dynamics simulations. Parallel and anti-parallel ('En-Passant') cracks attract and repel each other in bilayer 2D crystals, respectively, in stark contrast to the behaviors of co-planar cracks. We show that the misfit between in-plane displacement fields around the crack tips results in non-uniform interlayer shear, which modifies the crack driving forces by creating an antisymmetric component of the stress intensity factor. The cross-layer interaction between cracks directly leads to material toughening, the strength of which increases with the shear stiffness and decreases with the crack spacings. Backed by the experimental findings and simulation results, a theory that marries the theory of linear elastic fracture mechanics and the shear-lag model is presented, which guides the unconventional approach to engineer fracture patterns and enhance material resistance to cracking.
2402.07088v1
2024-03-26
Microscale Morphology Driven Thermal Transport in Fiber Reinforced Polymer Composites
Fiber-reinforced polymer composite (FRPC) materials are used extensively in various industries, such as aerospace, automobiles, and electronics packaging, due to their remarkable specific strength and desirable properties, such as enhanced durability and corrosion resistance. The evolution of thermal properties in FRPCs is crucial for advancing thermal management systems, optimizing material performance, and enhancing energy efficiency across these diverse sectors. Despite significant research efforts to develop new materials with improved thermal properties and reduced thermal degradation, there is a lack of understanding of the thermal transport phenomena considering the influence of microscale reinforcement morphology in these composites. In the current study, we performed experimental investigations complemented by computations to determine the thermal transport properties and associated phenomena in epoxy and carbon fiber-reinforced epoxy composites. The experimental findings were utilized as input data for numerical analysis to examine the impact of fiber morphology and volume fraction in thermal transport phenomena. Our results revealed that composites incorporating non-circular fibers manifested higher thermal conductivity than traditional circular fibers in the transverse direction. This can be attributed to increased interconnected heat flow pathways facilitated by the increased surface area of non-circular fibers with the same cross-sectional areas, resulting in efficient heat transfer.
2403.17650v1
2024-04-24
Synthesis of layered gold tellurides AuSbTe and Au$_2$Te$_3$ and their semiconducting and metallic behavior
Previous studies on natural samples of pampaloite (AuSbTe) revealed the crystal structure of a potentially cleavable and/or exfoliable material, while studies on natural and synthetic montbrayite (Sb-containing Au$_2$Te$_3$) claimed various chemical compositions for this low symmetry compound. Few investigations of synthetic samples have been reported for both materials, leaving much of their chemical, thermal and electronic characteristics unknown. Here, we investigate the stability, electronic properties and synthesis of the gold antimony tellurides AuSbTe and Au$_{1.9}$Sb$_{0.46}$Te$_{2.64}$ (montbrayite). Differential thermal analysis and $\textit{in situ}$ powder x-ray diffraction revealed that AuSbTe is incongruently melting, while Au$_{1.9}$Sb$_{0.46}$Te$_{2.64}$ is congruently melting. Calculations of the band structures and four-point resistivity measurements showed that AuSbTe is a semiconductor and Au$_{1.9}$Sb$_{0.46}$Te$_{2.64}$ a metal. Various synthesis attempts confirmed the limited stable chemical composition of Au$_{1.9}$Sb$_{0.46}$Te$_{2.64}$, identified successful methods to synthesize both compounds, and highlighted the challenges associated with single crystal synthesis of AuSbTe.
2404.16239v1
2024-05-03
Piezoresistivity as an Order Parameter for Ferroaxial Transitions
Recent progress in the understanding of the collective behavior of electrons and ions have revealed new types of ferroic orders beyond ferroelectricity and ferromagnetism, such as the ferroaxial state. The latter retains only rotational symmetry around a single axis and reflection symmetry with respect to a single mirror plane, both of which are set by an emergent electric toroidal dipole moment. Due to this unusual symmetry-breaking pattern, it has been challenging to directly measure the ferroaxial order parameter, despite the increasing attention this state has drawn. Here, we show that off-diagonal components of the piezoresistivity tensor (i.e., the linear change in resistivity under strain) transform the same way as the ferroaxial moments, providing a direct probe of such order parameters. We identify two new proper ferroaxial materials through a materials database search, and use first-principles calculations to evaluate the piezoconductivity of the double-perovskite CaSnF$_6$, revealing its connection to ferroaxial order and to octahedral rotation modes.
2405.02149v1
2004-11-16
Upper Critical Fields up to 60T in Dirty Magnesium Diboride Thin Films
Upper critical fields of several magnesium diboride thin films were measured up to 28 T at the Grenoble High Magnetic Field Laboratory (GHMFL) in Grenoble and up to 60 T at the Laboratoire National des Champs Magnetiques Pulses (LNCMP) in Toulouse. The samples were prepared both by pulsed laser deposition (PLD) and hybrid physical chemical vapour deposition (HPCVD) technique; they have critical temperatures between 29 and 39 K and normal state resistivities between 5 and 250 μohmcm; one of them has been intentionally doped with carbon. The measured critical fields were exceptionally high; we obtained the record value of 52 T at 4.2 K in the parallel orientation. In contrast with the BCS predictions, no saturation in Hc2 at low temperature was observed. Furthermore, films with a wide range of resistivity values showed similar critical fields, suggesting that in a two band system resistivity and Hc2 are not trivially linked. The high Hc2 values seem to be related with the expanded c-axis. The structure of one of the samples was carefully investigated with X-ray diffraction at European Synchrotron Radiation Facility (ESRF) in Grenoble.
0411404v1
2008-07-22
Microphysical dissipation, turbulence and magnetic fields in hyper-accreting discs
Hyper-accreting discs occur in compact-object mergers and collapsars, and may power gamma-ray bursts (GRBs). We calculate the microscopic viscosity and resistivity of plasma in these discs, and discuss the implications for their global structure and evolution. In the neutrino-cooled innermost regions, the viscosity is provided mainly by mildly degenerate electrons, while the resistivity is modified from the Spitzer value due to the effects of both relativity and degeneracy. The plasma behaves as an almost ideal MHD fluid. Among the non-ideal MHD effects the Hall term is relatively the most important, while the magnetic Prandtl number, Pr (the ratio of viscosity to resistivity), is typically larger than unity: 10 < Pr < 6000. The outer radiatively inefficient regions also display high Pr. Numerical simulations of the magneto-rotational instability indicate that the saturation level and angular momentum transport efficiency may be greatly enhanced at high Pr. If this behaviour persists in the presence of a strong Hall effect we would expect that hyper-accreting discs should be strongly magnetised and highly variable. The expulsion of magnetic field that cannot be dissipated at small scales may also favour a magnetic outflow. We note the similaries between the Prandtl number in hyper-accreting discs and X-ray binary discs, which suggests that a comparison between late-time activity in GRBs and X-ray binary accretion states may be fruitful. Our results imply that the behavior of high Prandtl number MHD flows needs to be considered in studies of hyper-accreting discs.
0807.3547v2
2011-11-16
Optical tuning and ultrafast dynamics of high-temperature superconducting terahertz metamaterials
Through the integration of semiconductors or complex oxides into metal resonators, tunable metamaterials have been achieved by a change of environment using an external stimulus. Metals provide high conductivity to realize a strong resonant response in metamaterials; however, they contribute very little to the tunability. The complex conductivity in high-temperature superconducting films is highly sensitive to external perturbations, which provides new opportunities in achieving tunable metamaterials resulting directly from the resonant elements. Here we demonstrate ultrafast dynamical tuning of resonance in the terahertz (THz) frequency range in YBa_2Cu_3O_7-\delta (YBCO) split-ring resonator arrays excited by near-infrared femtosecond laser pulses. The photoexcitation breaks the superconducting Cooper pairs to create the quasiparticle state. This dramatically modifies the imaginary part of the complex conductivity and consequently the metamaterial resonance in an ultrafast timescale. We observed resonance switching accompanied with a wide range frequency tuning as a function of photoexcitation fluence, which also strongly depend on the nano-scale thickness of the superconducting films. All of our experimental results are well reproduced through calculations using an analytical model, which takes into account the SRR resistance and kinetic inductance contributed from the complex conductivity of YBCO films. The theoretical calculations reveal that the increasing SRR resistance upon increasing photoexcitation fluence is responsible for the reduction of resonance strength, and both the resistance and kinetic inductance contribute to the tuning of resonance frequency.
1111.3917v1
2012-05-14
A fully covariant mean-field dynamo closure for numerical 3+1 resistive GRMHD
The powerful high-energy phenomena typically encountered in astrophysics invariably involve physical engines, like neutron stars and black hole accretion disks, characterized by a combination of highly magnetized plasmas, strong gravitational fields, and relativistic motions. In recent years numerical schemes for General Relativistic MHD (GRMHD) have been developed to model the multidimensional dynamics of such systems, including the possibility of an evolving spacetime. Such schemes have been also extended beyond the ideal limit including the effects of resistivity, in an attempt to model dissipative physical processes acting on small scales (sub-grid effects) over the global dynamics. Along the same lines, magnetic fields could be amplified by the presence of turbulent dynamo processes, as often invoked to explain the high values of magnetization required in accretion disks and neutron stars. Here we present, for the first time, a further extension to include the possibility of a mean-field dynamo action within the framework of numerical 3+1 (resistive) GRMHD. A fully covariant dynamo closure is proposed, in analogy with the classical theory, assuming a simple alpha-effect in the comoving frame. Its implementation into a finite-difference scheme for GRMHD in dynamical spacetimes [the X-ECHO code: (Bucciantini and Del Zanna 2011)] is described, and a set of numerical test is presented and compared with analytical solutions wherever possible.
1205.2951v3
2013-01-31
An ageing study of resistive micromegas for the HL-LHC environment
Resistive-anode micromegas detectors are in development since several years, in an effort to solve the problem of sparks when working at high flux and high ionizing radiation like in the HL-LHC (up to ten times the luminosity of the LHC). They have been chosen as one of the technologies that will be part of the ATLAS New Small Wheel project (forward muon system). An ageing study is mandatory to assess their capabilities to handle the HL-LHC environment on a long-term period. A prototype has been exposed to several types of irradiation (X-rays, cold neutrons, $^{60}$Co gammas and alphas) above the equivalent charge produced at the detector in five HL-LHC running years without showing any degradation of the performances in terms of gain and energy resolution. This study has been completed with the characterization of the tracking performances in terms of efficiency and spatial resolution, verifying the compatibility of results obtained with both resistive micromegas detectors, irradiated and non-irradiated one.
1301.7648v1
2014-03-20
High Electron Mobility in Epitaxial Graphene on 4H-SiC(0001) via post-growth annealing under hydrogen
We investigate the magneto-transport properties of epitaxial graphene single-layer on 4H-SiC(0001), grown by atmospheric pressure graphitization in Ar, followed by H2 intercalation. We directly demonstrate the importance of saturating the Si dangling bonds at the graphene/SiC(0001) interface to achieve high carrier mobility. Upon successful Si dangling bonds elimination, carrier mobility increases from 3 000 cm^2/Vs to > 11 000 cm^2/Vs at 0.3 K. Additionally, graphene electron concentration tends to decrease from a few 10^12 cm^-2 to less than 10^12 cm^-2. For a typical large (30x280 um^2) Hall bar, we report the observation of the integer quantum Hall states at 0.3 K with well developed transversal resistance plateaus at Landau level fillings factors of nu = 2, 6, 10, 14.. 42 and Shubnikov de Haas oscillation of the longitudinal resistivity observed from about 1 T. In such a device, the Hall state quantization at nu=2, at 19 T and 0.3 K, can be very robust: the dissipation in electronic transport can stay very low, with the longitudinal resistivity lower than 5 mOhm, for measurement currents as high as 250 uA. This is very promising in the view of an application in metrology.
1403.5059v1
2015-02-16
(Li0.84Fe0.16)OHFe0.98Se superconductor: Ion-exchange synthesis of large single crystal and highly two-dimensional electron properties
A large and high-quality single crystal (Li0.84Fe0.16)OHFe0.98Se, the optimal superconductor of newly reported (Li1-xFex)OHFe1-ySe system, has been successfully synthesized via a hydrothermal ion-exchange technique. The superconducting transition temperature (Tc) of 42 K is determined by magnetic susceptibility and electric resistivity measurements, and the zero-temperature upper critical magnetic fields are evaluated as 79 and 313 Tesla for the field along the c-axis and the ab-plane, respectively. The ratio of out-of-plane to in-plane electric resistivity,\r{ho}c/\r{ho}ab, is found to increases with decreasing temperature and to reach a high value of 2500 at 50 K, with an evident kink occurring at a characteristic temperature T*=120 K. The negative in-plane Hall coefficient indicates that electron carriers dominate in the charge transport, and the hole contribution is significantly reduced as the temperature is lowered to approach T*. From T* down to Tc, we observe the linear temperature dependences of the in-plane electric resistivity and the magnetic susceptibility for the FeSe layers. Our findings thus reveal that the normal state of (Li0.84Fe0.16)OHFe0.98Se becomes highly two-dimensional and anomalous prior to the superconducting transition, providing a new insight into the mechanism of high-Tc superconductivity.
1502.04688v2
2015-09-29
Design, development and performance study of six-gap glass MRPC detectors
The Multigap Resistive Plate Chambers (MRPCs) are gas ionization detectors with multiple gas sub-gaps made of resistive electrodes. The high voltage (HV) is applied on the outer surfaces of outermost resistive plates only, while the interior plates are left electrically floating. The presence of multiple narrow sub--gaps with high electric field results in faster signals on the outer electrodes, thus improving the detector's time resolution. Due to their excellent performance and relatively low cost, the MRPC detector has found potential application in Time-of-Flight (TOF) systems. Here we present the design, fabrication, optimization of the operating parameters such as the HV, the gas mixture composition, and, performance of six--gap glass MRPC detectors of area 27cm $\times$ 27 cm, which are developed in order to find application as trigger detectors, in TOF measurement etc. The design has been optimized with unique spacers and blockers to ensure a proper gas flow through the narrow sub-gaps, which are 250 $\mu$m wide. The gas mixture consisting of R134A, Isobutane and SF$_{6}$, and the fraction of each constituting gases has been optimized after studying the MRPC performance for a set of different concentrations. The counting efficiency of the MRPC is about 95% at $17.9$ kV. At the same operating voltage, the time resolution, after correcting for the walk effect, is found to be about $219$ ps.
1509.08586v2
2017-02-21
Pressure induced half-collapsed-tetragonal phase in CaKFe$_4$As$_4$
We report the temperature-pressure phase diagram of CaKFe$_4$As$_4$ established using high pressure electrical resistivity, magnetization and high energy x-ray diffraction measurements up to 6 GPa. With increasing pressure, both resistivity and magnetization data show that the bulk superconducting transition of CaKFe$_4$As$_4$ is suppressed and then disappears at $p$ $\gtrsim$ 4 GPa. High pressure x-ray data clearly indicate a phase transition to a collapsed tetragonal phase in CaKFe$_4$As$_4$ under pressure that coincides with the abrupt loss of bulk superconductivity near 4 GPa. The x-ray data, combined with resistivity data, indicate that the collapsed tetragonal transition line is essentially vertical, occuring at 4.0(5) GPa for temperatures below 150 K. Band structure calculations also find a sudden transition to a collapsed tetragonal state near 4 GPa, as As-As bonding takes place across the Ca-layer. Bonding across the K-layer only occurs for $p$ $\geq$ 12 GPa. These findings demonstrate a new type of collapsed tetragonal phase in CaKFe$_4$As$_4$: a half-collapsed-tetragonal phase.
1702.06622v1
2016-06-30
Identification of a possible superconducting transition above room temperature in natural graphite crystals
Measuring with high precision the electrical resistance of highly ordered natural graphite samples from a Brazil mine, we have identified a transition at $\sim$350~K with $\sim$40~K transition width. The step-like change in temperature of the resistance, its magnetic irreversibility and time dependence after a field change, consistent with trapped flux and flux creep, and the partial magnetic flux expulsion obtained by magnetization measurements, suggest the existence of granular superconductivity below 350~K. The zero-field virgin state can only be reached again after zero field cooling the sample from above the transition. Paradoxically, the extraordinarily high transition temperature we found for this and several other graphite samples is the reason why this transition remained undetected so far. The existence of well ordered rhombohedral graphite phase in all measured samples has been proved by x-rays diffraction measurements, suggesting its interfaces with the Bernal phase as a possible origin for the high-temperature superconductivity, as theoretical studies predicted. The localization of granular superconductivity at these two dimensional interfaces prevents the observation of a zero resistance state or of a full Meissner state.
1606.09425v1
2022-02-04
Fabrication of Surface Ion Traps with Integrated Current Carrying Wires enabling High Magnetic Field Gradients
A major challenge for quantum computers is the scalable simultaneous execution of quantum gates. One approach to address this in trapped ion quantum computers is the implementation of quantum gates based on static magnetic field gradients and global microwave fields. In this paper, we present the fabrication of surface ion traps with integrated copper current carrying wires embedded inside the substrate below the ion trap electrodes, capable of generating high magnetic field gradients. The copper layer's measured sheet resistance of 1.12 m$\Omega$/sq at room temperature is sufficiently low to incorporate complex designs, without excessive power dissipation at high currents causing a thermal runaway. At a temperature of 40 K the sheet resistance drops to 20.9 $\mu\Omega$/sq giving a lower limit for the residual resistance ratio of 100. Continuous currents of 13 A can be applied, resulting in a simulated magnetic field gradient of 144 T/m at the ion position, which is 125 $\mu$m from the trap surface for the particular anti-parallel wire pair in our design.
2202.02313v2
2019-03-15
Hyper-Resistive Model of Ultra High Energy Cosmic Ray Acceleration by Magnetically Collimated Jets Created by Active Galactic Nuclei
This is the fourth in a series of companion papers showing that, when an efficient dynamo can be maintained by accretion disks around supermassive black holes in Active Galactic Nuclei (AGNs), it will lead to the formation of a powerful, magnetically-collimated helix that could explain both the observed jet/radiolobe structures on very large scales and ultimately the enormous power inferred from the observed ultra high energy cosmic rays (UHECRs) with energies > 10^19 eV. Many timescales are involved in this process. Our hyper-resistive magnetohydrodynamic (MHD) model provides a bridge between General Relativistic MHD simulations of dynamo formation, on the short accretion timescale, and observational evidence of magnetic collimation of large-scale jets on astrophysical timescales. Given the final magnetic structure, we apply hyper-resistive kinetic theory to show how instability causes slowly-evolving magnetically-collimated jets to become the most powerful relativistic accelerators in the Universe. The model yields nine observables in reasonable agreement with observations: the jet length, radiolobe radius and apparent opening angle as observed by synchrotron radiation; the synchrotron total power, synchrotron wavelengths and maximum electron energy (TeVs); and the maximum UHECR energy, the cosmic ray energy spectrum and the cosmic ray intensity on Earth.
1903.06839v2
2019-01-23
Josephson junctions and SQUIDs created by focused helium ion beam irradiation of YBa$_2$Cu$_3$O$_7$
By scanning with a $30\, \mathrm{keV}$ focused He ion beam (He-FIB) across YBa$_2$Cu$_3$O$_7$ (YBCO) thin film microbridges, we create Josephson barriers with critical current density $j_\mathrm{c}$ adjustable by irradiation dose $D$. The dependence $j_\mathrm{c} (D)$ yields an exponential decay. At $4.2\, \mathrm{K}$, a transition from flux-flow to Josephson behavior occurs when $j_\mathrm{c}$ decreases below $\approx 2\, \mathrm{MA/cm^2}$. The Josephson junctions exhibit current-voltage characteristics (IVCs) that are well described by the resistively and capacitively shunted junction model, without excess current for characteristic voltages $V_\mathrm{c} \lesssim 1\, \mathrm{mV}$. Devices on MgO and LSAT substrates show non-hysteretic IVCs, while devices on SrTiO$_3$ show a small hysteresis. For all junctions an approximate scaling $V_\mathrm{c} \propto j_\mathrm{c}^{1/2}$ is found. He-FIB irradiation with high dose produces barriers with $j_\mathrm{c}=0$ and high resistances of $10\, \mathrm{k\Omega} \ldots 1\, \mathrm{G\Omega}$. This provides the possibility to write highly resistive walls or areas into YBCO using a He-FIB. Transmission electron microscopy reveals an amorphous phase within the walls, whereas for lower doses the YBCO stays crystalline. We have also ``drawn'' superconducting quantum interference devices (SQUIDs) by using a He-FIB for definition of the SQUID hole and the junctions. The SQUIDs show high performance, with flux noise $< 500\, \mathrm{n \Phi_0/Hz^{1/2}}$ in the thermal white noise limit for a device with $19\, \mathrm{pH}$ inductance.
1901.08039v3
2023-02-14
The current unbalance in stacked REBCO tapes -- simulations based on a circuit grid model
Unlike low temperature superconducting cables, there is so far no perfect solution for REBCO coated conductors to form a fully transposed high current cable. Every REBCO cable concept must import a stack of tapes to achieve an operating current as high as tens of kiloamperes. The stacked REBCO tapes, no matter whether they are twisted or not, however, have a nature of non-transposing and therefore could result in current unbalance. In this manuscript, the current unbalance and the related electrical characteristics of a cable made of 40 stacked REBCO tapes are studied with an electrical circuit simulation. The differences in splice resistances and tape inductances that are both related to the non-transposed structure of a REBCO stack are considered. Results show that for a 40 cm long termination, a proper method to keep the contact resistivity between each tape and the copper termination around 1e-8 ohmm is crucial to totally avoid current unbalance lowering the cable performance. Surprisingly, the inter-tape current transfer is found to be able to further exacerbate local high current though it does make the overall distribution more balanced. The inductance difference induced current unbalance is only important if local defects exist at long REBCO tapes, which on the other hand can be cured by good inter-tape current transfer. For a fast-charging rate of 1 kA/s, the inter-tape contact resistivity should also be low to a level of 1e-8 ohmm to ensure a short current transfer length of around 1 m.
2302.06817v1
2024-04-25
Conductivity of lattice bosons at high temperatures
Quantum simulations are quickly becoming an indispensable tool for studying particle transport in correlated lattice models. One of the central topics in the study of transport is the bad-metal behavior, characterized by the direct current (dc) resistivity linear in temperature. In the fermionic Hubbard model, optical conductivity has been studied extensively, and a recent optical lattice experiment has demonstrated bad metal behavior in qualitative agreement with theory. Far less is known about transport in the bosonic Hubbard model. We investigate the conductivity in the Bose-Hubbard model, and focus on the regime of strong interactions and high-temperatures. We use numerically exact calculations for small lattice sizes. At weak tunneling, we find multiple peaks in the optical conductivity that stem from the Hubbard bands present in the many-body spectrum. This feature slowly washes out as the tunneling rate gets stronger. At high temperature, we identify a regime of $T$-linear resistivity, as expected. When the interactions are very strong, the leading inverse-temperature coefficient in conductivity is proportional to the tunneling amplitude. As the tunneling becomes stronger, this dependence takes quadratic form. At very strong coupling and half filling, we identify a separate linear resistivity regime at lower temperature, corresponding to the hard-core boson regime. Additionally, we unexpectedly observe that at half filling, in a big part of the phase diagram, conductivity is an increasing function of the coupling constant before it saturates at the hard-core-boson result. We explain this feature based on the analysis of the many-body energy spectrum and the contributions to conductivity of individual eigenstates of the system.
2404.16559v1
2004-10-22
Observation of double resistance anomalies and excessive resistance in mesoscopic superconducting Au$_{0.7}$In$_{0.3}$ rings with phase separation
We have measured mesoscopic superconducting Au$_{0.7}$In$_{0.3}$ rings prepared by e-beam lithography and sequential deposition of Au and In at room temperature followed by a standard lift-off procedure. In samples showing no Little-Parks resistance oscillations, highly unusual double resistance anomalies, two resistance peaks found near the onset of superconductivity, were observed. Although resistance anomaly featuring a single resistance peak has been seen in various mesoscopic superconducting samples, double resistance anomalies have never been observed previously. The dynamical resistance measurements suggest that there are two critical currents in these samples. In addition, the two resistance peaks were found to be suppressed at different magnetic fields. We attribute the observed double resistance anomalies to an underlying phase separation in which In-rich grains of intermetallic compound of AuIn precipitate in a uniform In-dilute matrix of Au$_{0.9}$In$_{0.1}$. The intrinsic superconducting transition temperature of the In-rich grains is substantially higher than that of the In-dilute matrix. The suppression of the conventional Little-Parks resistance oscillation is explained in the same picture by taking into consideration a strong variation in the $T_c$ of the In-rich grains. We also report the observation of an unusual magnetic-field-induced metallic state with its resistance higher than the normal-state resistance, referred to here as excessive resistance, and an h/2e resistance oscillation with the amplitude of oscillation depends extremely weakly on temperature.
0410567v2
2022-09-17
Superfunctional materials by ultra-severe plastic deformation
Superfunctional materials are defined as materials with specific properties being superior to the functions of engineering materials. Numerous studies introduced severe plastic deformation (SPD) as an effective process to improve the functional and mechanical properties of various metallic and non-metallic materials. Moreover, the concept of ultra-SPD - introducing shear strains over 1000 to reduce the thickness of sheared phases to levels comparable to atomic distances - was recently utilized to synthesize novel superfunctional materials. In this article, the application of ultra-SPD for controlling atomic diffusion and phase transformation and synthesizing new materials with superfunctional properties is discussed. The main properties achieved by ultra-SPD include: (i) high-temperature thermal stability in new immiscible age-hardenable aluminum alloys; (ii) room-temperature superplasticity for the first time in magnesium and aluminum alloys; (iii) high strength and high plasticity in nanograined intermetallics; (iv) low elastic modulus and high hardness in biocompatible binary and high-entropy alloys; (v) superconductivity and high strength in the Nb-Ti alloys; (vi) room-temperature hydrogen storage for the first time in magnesium alloys; and (vii) superior photocatalytic hydrogen production, oxygen production, and carbon dioxide conversion on high-entropy oxides and oxynitrides as a new family of photocatalysts.
2209.08295v3
2020-06-08
Data-driven topology design using a deep generative model
In this paper, we propose a sensitivity-free and multi-objective structural design methodology called data-driven topology design. It is schemed to obtain high-performance material distributions from initially given material distributions in a given design domain. Its basic idea is to iterate the following processes: (i) selecting material distributions from a dataset of material distributions according to eliteness, (ii) generating new material distributions using a deep generative model trained with the selected elite material distributions, and (iii) merging the generated material distributions with the dataset. Because of the nature of a deep generative model, the generated material distributions are diverse and inherit features of the training data, that is, the elite material distributions. Therefore, it is expected that some of the generated material distributions are superior to the current elite material distributions, and by merging the generated material distributions with the dataset, the performances of the newly selected elite material distributions are improved. The performances are further improved by iterating the above processes. The usefulness of data-driven topology design is demonstrated through numerical examples.
2006.04559v3
2024-04-03
Wenzhou TE: a first-principles calculated thermoelectric materials database
Since the implementation of the Materials Genome Project by the Obama administration in the United States, the development of various computational materials databases has fundamentally expanded the choices of industries such as materials and energy. In the field of thermoelectric materials, the thermoelectric figure of merit ZT quantifies the performance of the material. From the viewpoint of calculations for vast materials, the ZT values are not easily obtained due to their computational complexity. Here, we show how to build a database of thermoelectric materials based on first-principles calculations for the electronic and heat transport of materials. Firstly, the initial structures are classified according to the values of bandgap and other basic properties using the clustering algorithm K-means in machine learning, and high-throughput first principles calculations are carried out for narrow-bandgap semiconductors which exhibiting potential thermoelectric application. The present framework of calculations mainly includes deformation potential module, electrical transport performance module, mechanical and thermodynamic properties module. We have also set up a search webpage for the calculated database of thermoelectric materials, providing searching and viewing the related physical properties of materials. Our work may inspire the construction of more computational databases of first-principle thermoelectric materials and accelerate research progress in the field of thermoelectrics.
2404.02571v1
2023-12-13
The Milky Way shines in high-energy neutrinos
The most energetic astrophysical sources in the Milky Way, cosmic accelerators capable of producing high-energy cosmic rays, have resisted discovery for over a century. Up to now, astrophysicists sought these sources mainly by scouring the Galaxy for the gamma rays they are expected to emit. In 2023, the IceCube Neutrino Observatory discovered high-energy neutrinos from the Milky Way, inaugurating a telltale stream of evidence of cosmic-ray production and interaction in the Galaxy.
2312.08102v1
1998-10-21
Inverse Cascade of Primordial Magnetic Field in MHD Turbulence
The feature of the spectrum of primordial magnetic field is studied by using renormalization group analysis in magnetohydrodynamics. Taking account of the renormalized resistivity at the fixed point, we show that the scaling of the typical scale with time obeys $L(t) \sim t^{2/5}$ for random initial condition.
9810339v1
1999-06-10
Luttinger liquid behavior in single wall nanotubes
Transport properties of metallic single-wall nanotubes are examined based on the Luttinger liquid theory. Focusing on a nanotube transistor setup, the linear conductance is computed from the Kubo formula using perturbation theory in the lead-tube tunnel conductances. For sufficiently long nanotubes and high temperature, phonon backscattering should lead to an anomalous temperature dependence of the resistivity.
9906150v1
2002-01-07
Temperature-dependent $H_{c2}$ anisotropy in MgB$_2$ as inferred from measurements on polycrystals
We present data on temperature-dependent anisotropy of the upper critical field of MgB$_2$ obtained from the analysis of measurements on high purity, low resistivity polycrystals. The anisotropy decreases in a monotonic fashion with increase of temperature.
0201085v1
2003-05-29
Imaging the charge transport in arrays of CdSe nanocrystals
A novel method to image charge is used to measure the diffusion coefficient of electrons in films of CdSe nanocrystals at room temperature. This method makes possible the study of charge transport in films exhibiting high resistances or very small diffusion coefficients.
0305684v1
2003-06-03
Intrinsic tunneling or Joule heating?
It is shown that the `tunnelling spectra' reported by Yurgens et al. could be reproduced qualitatively and quantitatively using the experimental out-of-plane normal state resistance R(T) and assuming that the heating of the mesa, caused by the Joule dissipation, is the only reason for effects observed at high bias.
0306081v2
2004-10-09
Comment on cond-mat/0409228 "Microwave photoresponse in the 2D electron system caused by intra-Landau level transitions"
We provide an article-extract which points out that a microwave-induced modification in the resistance occurs at relatively "high" magnetic fields where the radiation is incapable of producing inter-Landau level excitations and, therefore, that the microwave radiation must be producing intra Landau level excitations as well.
0410227v1
2005-11-22
Quantum phase slip junctions
In this paper we demonstrate that, if it exists, coherent quantum phase slip is the exact dual to Josephson tunneling. We use the duality to predict kinetic capacitance and a sharp resonance in narrow wires. Biased resistively and driven at high frequency, quantum phase slip junctions should exhibit current plateaus of interest for a fundamental standard.
0511535v1
2003-04-13
Comment on "Phase Transition-Like Behavior in a Low-Pass Filter"
This is a reminder that an infinite series can be defined other than as the limit of a sequence of finite series. An example is provided in which a circuit element comprised of an infinite series of resistors has negative resistance.
0304051v1
2005-01-24
Nonlocal Gate Of Quantum Network Via Cavity Quantum Electrodynamics
We propose an experimentally feasible scheme to realize the nonlocal gate between two different quantum network nodes. With an entanglement-qubit (ebit) acts as a quantum channel, our scheme is resistive to actual environment noise and can get high fidelity in current cavity quantum electrodynamics (C-QED) system.
0501125v2
2008-03-16
Asymmetric exclusion processes with constrained dynamics
Asymmetric exclusion processes with locally reversible kinetic constraints are introduced to investigate the effect of non-conservative driving forces in athermal systems. At high density they generally exhibit rheological-like behavior, negative differential resistance, two-step structural relaxation, dynamical heterogeneity and, possibly, a jamming transition driven by the external field.
0803.2287v2
2010-04-05
Superconducting plasmonics and extraordinary transmission
Negative dielectric constant and dominant kinetic resistance make superconductors an intriguing plasmonic media. Here we report on the first study of one of the most important and disputed manifestations of plasmonics, the effect of extraordinary transmission through an array of sub-wavelength holes, using a perforated film of high-temperature superconductor.
1004.0729v1
2010-05-03
Construction of a Digital Hadron Calorimeter
The DHCAL collaboration is assembling a large scale prototype Digital Hadron Calorimeter (DHCAL). The calorimeter utilizes Resistive Plate Chambers (RPCs) as active medium and features of the order of 400,000 1 \times 1 cm2 pads with binary (or digital) electronic readout. The purpose of the prototype is to provide detailed measurements of hadronic showers and to prove the concept of a DHCAL with RPCs as active elements.
1005.0410v1
2010-07-16
Indications of room-temperature superconductivity at a metal-PZT interface
We report the observation of an exceptionally large room-temperature electrical conductivity in silver and aluminum layers deposited on a lead zirconate titanate (PZT) substrate. The surface resistance of the silver-coated samples also shows a sharp change near 313 K. The results are strongly suggestive of a superconductive interfacial layer, and have been interpreted in the framework of Bose-Einstein condensation of bipolarons as the suggested mechanism for high-temperature superconductivity in cuprates.
1007.2736v1
2010-07-18
Test Beam Results Using an RPC Semi-Digital HCAL
We report on the development of an GRPCs (Glass Resistive Plate chambers) Semi- Digital hadron calorimeter for the future International Linear Collider (ILC).Two types of GRPCs (small and 1m2) were tested in PS beam at CERN. Detector performances are presented here in terms of efficiency, pad multiplicity, homogeneity and stability in time.
1007.3009v3
2011-12-14
Superconductivity in Single-Crystal YIn3
We measure the superconducting transition of YIn$_3$ by resistivity, susceptibility, and specific heat. Despite using high-quality single-crystal samples, the transitions detected by the three techniques are shifted from each other in temperature, suggesting a region of filamentary superconductivity. We discuss the possible implications for filamentary superconductivity in unconventional superconductors.
1112.3083v1
2013-03-05
Unusual suppression of superconductivity in YNi2B2C under neutron irradiation
The behavior of electrical resistivity rho(T), temperature of superconducting transition Tc, and upper critical field Hc2(T) of polycrystalline YNi2B2C after irradiation with thermal neutron and subsequent high-temperature isochronous annealings in the temperature range Tann = 100 - 1000C has been studied.
1303.0929v1
2015-01-11
Resistance of a Rotating-Moving Brane with Background Fields Against Collapse
Using the boundary state formalism we investigate the effect of tachyon condensation process on a rotating and moving D$p$-brane with various background fields in the bosonic string theory. The rotation and motion are inside the brane volume. We demonstrate that some specific rotations and/or motions can preserve the brane from instability and collapse.
1501.02453v1
2017-02-12
Optimal doping of the diode current interrupters
An analytical solution to the problem of decreasing the energy losses $\Omega$ in diode current interrupters during recovery of the blocking ability by optimizing dopant distribution $N(x)$ over structure thickness has been obtained. It was found the distribution $N(x)$ close to optimal one that decreases $\Omega$ by 30-55% compared with standard interrupters with uniformly doped high-resistivity layers.
1702.03496v1
2016-03-24
A note on "achieving security, robust cheating resistance, and high-efficiency for outsourcing large matrix multiplication computation to a malicious cloud"
We show that the Lei et al.'s scheme [Information Sciences, 280 (2014), 205-217] fails, because the verifying equation does not hold over the infinite field R. For the field R, the computational errors should be considered seriously. We also remark that the incurred communication cost in the scheme could be overtake the computational gain, which makes it somewhat artificial.
1603.07399v1
2020-06-07
Asymmetric Jet launching
In resistive and viscous magnetohydrodynamical (MHD) simulations we obtain axial jets launched from the innermost magnetosphere of a star-disk system. We found that in a part of the parameter space continuous asymmetric jets, which are propagating in opposite directions, are launched. We compare the speed of propagation and rotation of obtained jets with recent observational results.
2006.04083v1
2021-12-30
Two Instances of Interpretable Neural Network for Universal Approximations
This paper proposes two bottom-up interpretable neural network (NN) constructions for universal approximation, namely Triangularly-constructed NN (TNN) and Semi-Quantized Activation NN (SQANN). Further notable properties are (1) resistance to catastrophic forgetting (2) existence of proof for arbitrarily high accuracies (3) the ability to identify samples that are out-of-distribution through interpretable activation "fingerprints".
2112.15026v2
2022-02-20
High-throughput computational screening of nanoporous materials in targeted applications
Due to their chemical and structural diversity, nanoporous materials can be used in a wide variety of applications, including fluid separation, gas storage, heterogeneous catalysis, drug delivery, etc. Given the large and rapidly increasing number of known nanoporous materials, and the even bigger number of hypothetical structures, computational screening is an efficient method to find the current best-performing materials and to guide the design of future materials. This review highlights the potential of high-throughput computational screenings in various applications. The achievements and the challenges associated to the screening of several material properties are discussed to give a broader perspective on the future of the field.
2202.09886v2
2020-08-29
High-throughput Design of Magnetic Materials
Materials design based on density functional theory (DFT) calculations is an emergent field of great potential to accelerate the development and employment of novel materials. Magnetic materials play an essential role in green energy applications as they provide efficient ways of harvesting, converting, and utilizing energy. In this review, after a brief introduction to the major functionalities of magnetic materials, we demonstrated the fundamental properties which can be tackled via high-throughput DFT calculations, with a particular focus on the current challenges and feasible solutions. Successful case studies are summarized on several classes of magnetic materials, followed by bird-view perspectives for the future.
2008.12907v1
2021-02-03
High-throughput discovery of novel cubic crystal materials using deep generative neural networks
High-throughput screening has become one of the major strategies for the discovery of novel functional materials. However, its effectiveness is severely limited by the lack of quantity and diversity of known materials deposited in the current materials repositories such as ICSD and OQMD. Recent progress in machine learning and especially deep learning have enabled a generative strategy that learns implicit chemical rules for creating chemically valid hypothetical materials with new compositions and structures. However, current materials generative models have difficulty in generating structurally diverse, chemically valid, and stable materials. Here we propose CubicGAN, a generative adversarial network (GAN) based deep neural network model for large scale generation of novel cubic crystal structures. When trained on 375,749 ternary crystal materials from the OQMD database, we show that our model is able to not only rediscover most of the currently known cubic materials but also generate hypothetical materials of new structure prototypes. A total of 506 such new materials (all of them are either ternary or quarternary) have been verified by DFT based phonon dispersion stability check, several of which have been found to potentially have exceptional functional properties. Considering the importance of cubic materials in wide applications such as solar cells and lithium batteries, our GAN model provides a promising approach to significantly expand the current repository of materials, enabling the discovery of new functional materials via screening. The new crystal structures finally verified by DFT are freely accessible at our Carolina Materials Database http://www.carolinamatdb.org.
2102.01880v2
2020-08-25
Cathode Materials for Lithium Ion Batteries (LIBs): A Review on Materials related aspects towards High Energy Density LIBs
This article reviews the development of cathode materials for secondary lithium ion batteries since its inception with the introduction of lithium cobalt oxide in early 1980s. The time has passed and numerous cathode materials are designed and developed to realize not only the enhanced capacity but also the power density simultaneously. However, there are numerous challenges such as the cyclic stability of cathode materials, their structural and thermal stability, higher operating voltage together with high ionic and electronic conductivity for efficient ion and charge transport during charging and discharging. This article will cover the development of materials in chronological order classifying as the lithium ion cathode materials in different generations. The ternary oxides such as LiTMOx (TM=Transition Metal) are considered as the first generation materials, whereas modified ternary and quaternary oxide systems are considered as the second generation materials. The current i.e. third generation includes complex oxide systems with higher lithium content such as Li2TMSiO4 aiming for higher energy density. Further, developments are heading towards lithium metal based batteries with a possibility for very high energy densities.
2008.10896v2
1999-11-15
Comparison of the Transport Mechanism in Underdoped High Temperature Superconductors and in Spin Ladders
Recently, the normal state resistivity of high temperature superconductors (in particular in La2-xSrxCuO4 single crystals) has been studied extensively in the region below Tc by suppressing the superconducting state in high magnetic fields. In the present work we report on the normal state resistance of underdoped La2-xSrxCuO4 thin films under epitaxial strain, measured far below Tc by applying pulsed fields up to 60 T. We will compare the transport measurements on these high temperature superconductors with transport data reported for the Sr2.5Ca11.5Cu24O41 spin ladder compound. This comparison leads to an interpretation of the data in terms of the recently proposed 1D quantum transport model and the charge-stripe models.
9911217v1
2007-11-13
High-resolution intracellular recordings using a real-time computational model of the electrode
Intracellular recordings of neuronal membrane potential are a central tool in neurophysiology. In many situations, especially in vivo, the traditional limitation of such recordings is the high electrode resistance, which may cause significant measurement errors. We introduce a computer-aided technique, Active Electrode Compensation (AEC), based on a digital model of the electrode interfaced in real time with the electrophysiological setup. The characteristics of this model are first estimated using white noise current injection. The electrode and membrane contribution are digitally separated, and the recording is then made by online subtraction of the electrode contribution. Tests comparing AEC to other techniques demonstrate that it yields recordings with improved accuracy. It enables high-frequency recordings in demanding conditions, such as injection of conductance noise in dynamic-clamp mode, not feasible with a single high resistance electrode until now. AEC should be particularly useful to characterize fast phenomena in neurons, in vivo and in vitro.
0711.2075v1
2010-08-19
Josephson Coupling and Fiske Dynamics in Ferromagnetic Tunnel Junctions
We report on the fabrication of Nb/AlO_x/Pd_{0.82}Ni_{0.18}/Nb superconductor/insulator/ferromagnetic metal/superconductor (SIFS) Josephson junctions with high critical current densities, large normal resistance times area products, high quality factors, and very good spatial uniformity. For these junctions a transition from 0- to \pi-coupling is observed for a thickness d_F ~ 6 nm of the ferromagnetic Pd_{0.82}Ni_{0.18} interlayer. The magnetic field dependence of the \pi-coupled junctions demonstrates good spatial homogeneity of the tunneling barrier and ferromagnetic interlayer. Magnetic characterization shows that the Pd_{0.82}Ni_{0.18} has an out-of-plane anisotropy and large saturation magnetization, indicating negligible dead layers at the interfaces. A careful analysis of Fiske modes provides information on the junction quality factor and the relevant damping mechanisms up to about 400 GHz. Whereas losses due to quasiparticle tunneling dominate at low frequencies, the damping is dominated by the finite surface resistance of the junction electrodes at high frequencies. High quality factors of up to 30 around 200 GHz have been achieved. Our analysis shows that the fabricated junctions are promising for applications in superconducting quantum circuits or quantum tunneling experiments.
1008.3341v1
2010-09-02
Superconducting and Structural Transitions in the β-Pyrochlore Oxide KOs2O6 under High Pressure
Rattling-induced superconductivity in the {\beta}-pyrochlore oxide KOs2O6 is investigated under high pressure up to 5 GPa. Resistivity measurements in a high-quality single crystal reveal a gradual decrease in the superconducting transition temperature Tc from 9.7 K at 1.0 GPa to 6.5 K at 3.5 GPa, followed by a sudden drop to 3.3 K at 3.6 GPa. Powder X-ray diffraction experiments show a structural transition from cubic to monoclinic or triclinic at a similar pressure. The sudden drop in Tc is ascribed to this structural tran-sition, by which an enhancement in Tc due to a strong electron-rattler interaction present in the low-pressure cubic phase is abrogated as the rattling of the K ion is completely suppressed or weakened in the high-pressure phase of reduced symmetry. In addition, we find two anomalies in the temperature dependence of resistivity in the low-pressure phase, which may be due to subtle changes in rattling vibration.
1009.0355v1
2010-09-03
Test beam studies for a highly granular GRPC Semi-Digital HCAL
The Particle Flow Analysis approach retained for the future ILC detectors requires high granularity and compact particle energy deposition. A Glass Resistive Plate Chamber based Semi-Digital calorimeter can offer both at a low price for the hadronic section. This paper presents some recent developments and results near test beam in the use of Glass Resistive Plate Chamber with embedded front-end electronics to build a prototype based on this principle. All the critical parameters such as the spatial and angular uniformity of the response as well as the noise level have been measured on small chambers and found to be appropriate. Small semi-conductive chambers allowing for high rates and a large chamber have also been tested.
1009.0719v1
2016-10-19
Gossamer bulk high-temperature superconductivity in FeSe
The cuprates and iron-based high-temperature superconductors share many common features: layered strongly anisotropic crystal structure, strong electronic correlations, interplay between different types of electronic ordering, the intrinsic spatial inhomogeneity due to doping. The understanding of complex interplay between these factors is crucial for a directed search of new high-temperature superconductors. Here we show the appearance of inhomogeneous gossamer superconductivity in bulk FeSe compound at ambient pressure and at temperature 5 times higher than its zero-resistance $T_c$. This discovery helps to understand numerous remarkable superconducting properties of FeSe. We also find and prove a general property: if inhomogeneous superconductivity in a anisotropic conductor first appears in the form of isolated superconducting islands, it reduces electric resistivity anisotropically with maximal effect along the least conducting axis. This gives a simple and very general tool to detect inhomogeneous superconductivity in anisotropic compounds, which is critically important to study the onset of high-temperature superconductivity.
1610.06117v1
2016-12-09
Graphenic Carbon-Silicon Contacts for Reliability Improvement of Metal-Silicon Junctions
Contact resistance and thermal degradation of metal-silicon contacts are challenges in nanoscale CMOS as well as in power device applications. Titanium silicide (TiSi) contacts are commonly used metal-silicon contacts, but are known to diffuse into the active region under high current stress. In this paper we show that a graphenic carbon (C) contact deposited on n-type silicon (C-Si) by CVD, has the same low Schottky barrier height of 0.45 eV as TiSi, but a much improved reliability against high current stress. The C-Si contact is over 100 million times more stable against high current stress pulses than the conventionally used TiSi junction. The C-Si contact properties even show promise to establish an ultra-low, high temperature stable contact resistance. The finding has important consequences for the enhancement of reliability in power devices as well as in Schottky-diodes and electrical contacts to silicon in general.
1612.06362v1
2018-10-05
Superconducting proximity effect in epitaxial Al-InAs heterostructures
Semiconductor-based Josephson junctions provide a platform for studying proximity effect due to the possibility of tuning junction properties by gate voltage and large-scale fabrication of complex Josephson circuits. Recently Josephson junctions using InAs weak link with epitaxial aluminum contact have improved the product of normal resistance and critical current, $I_cR_N$, in addition to fabrication process reliability. Here we study similar devices with epitaxial contact and find large supercurrent and substantial product of $I_cR_N$ in our junctions. However we find a striking difference when we compare these samples with higher mobility samples in terms of product of excess current and normal resistance, $I_{ex}R_N$. The excess current is negligible in lower mobility devices while it is substantial and independent of gate voltage and junction length in high mobility samples. This indicates that even though both sample types have epitaxial contacts only the high-mobility one has a high transparency interface. In the high mobility short junctions, we observe values of $I_cR_N/\Delta \sim 2.2$ and $I_{ex}R_N/\Delta \sim 1.5$ in semiconductor weak links.
1810.02514v4
2019-07-23
High-Chern-Number and High-Temperature Quantum Hall Effect without Landau Levels
The quantum Hall effect (QHE) with quantized Hall resistance of h/{\nu}e2 starts the research on topological quantum states and lays the foundation of topology in physics. Afterwards, Haldane proposed the QHE without Landau levels, showing nonzero Chern number |C|=1, which has been experimentally observed at relatively low temperatures. For emerging physics and low-power-consumption electronics, the key issues are how to increase the working temperature and realize high Chern numbers (C>1). Here, we report the experimental discovery of high-Chern-number QHE (C=2) without Landau levels and C=1 Chern insulator state displaying nearly quantized Hall resistance plateau above the N\'eel temperature in MnBi2Te4 devices. Our observations provide a new perspective on topological matter and open new avenues for exploration of exotic topological quantum states and topological phase transitions at higher temperatures.
1907.09947v4
2021-01-08
Superconductivity at ~70 K in Tin Hydride SnHx under High Pressure
Various tin hydrides SnHx (x = 4, 8, 12, 14) have been theoretically predicted to be stable at high pressures and to show high-critical-temperature superconductivity with Tc ranging from about 70 to 100 K. However, experimental verifications for any of these phases are still lacking to date. Here, we report on the in-situ synthesis, electrical resistance, and synchrotron x-ray diffraction measurements of SnHx at ~ 200 GPa. The main phase of the obtained sample can be indexed with the monoclinic C2/m SnH12 via comparison with the theoretical structural modes. A sudden drop of resistance and the systematic downward shift under external magnetic fields signals the occurrence of superconductivity in SnHx at Tc = ~ 70 K with an upper critical field u0Hc2(0) = ~ 11.2 T, which is relatively low in comparison with other reported high-Tc superhydrides. Various characteristic superconducting parameters are estimated based on the BCS theory.
2101.02846v1
2021-07-20
Performance of a fast timing micro-pattern gaseous detector for future collider experiments
The fast timing MPGD is a micro-pattern gaseous detector conceived for achieving sub-nanosecond time resolution while maintaining the ability to instrument large areas in high-rate environments; applications of such technology are perspected in high-energy physics experiments at future colliders and medical diagnostics with time-of-flight methods. This work shows the systematic studies carried on an FTM prototype on the performance of GEM foils coated with resistive DLC films, whose development is essential for the FTM operation. The resistive foil performance has been tested with several gas mixtures and compared with the results obtained on conductive foils. The results show that the performance of the FTM is presently limited by the technology of manufacturing of DLC-coated GEM foils, with high gains reachable exclusively in isobuthane-based mixtures.
2107.09439v1
2021-10-27
Robust genuine high-dimensional steering with many measurements
Quantum systems of high dimensions are attracting a lot of attention because they feature interesting properties when it comes to observing entanglement or other forms of correlations. In particular, their improved resistance to noise is favourable for experiments in quantum communication or quantum cryptography. However, witnessing this high-dimensional nature remains challenging, especially when the assumptions on the parties involved are weak, typically when one of them is considered as a black box. In this context, the concept of genuine high-dimensional steering has been recently introduced and experimentally demonstrated [Phys. Rev. Lett. 126, 200404 (2021)]; it allows for a one-sided device-independent certification of the dimension of a bipartite shared state by only using two measurements. Here I overcome this limitation by developing, for more than two measurements, universal bounds on the incompatibility robustness, turned into meaningful dimension certificates. Interestingly, even though the resulting bounds are quite loose, they still often offer an increased resistance to noise and could then be advantageously employed in experiments.
2110.14435v2
2022-03-10
Large output voltage to magnetic flux change in nanoSQUIDs based on direct-write Focused Ion Beam Induced Deposition technique
NanoSQUIDs are quantum sensors that excel in detecting a small change in magnetic flux with high sensitivity and high spatial resolution. Here, we employ resist-free direct-write Ga+ Focused Ion Beam Induced Deposition (FIBID) techniques to grow W-C nanoSQUIDs, and we investigate their electrical response to changes in the magnetic flux. Remarkably, FIBID allows the fast ($3~\mathrm{nm}$) growth of $700~\mathrm{nm}\times 300~\mathrm{nm}$ Dayem-bridge nanoSQUIDs based on narrow nanowires ($50~\mathrm{nm}$ wide) that act as Josephson junctions. The observed transfer coefficient (output voltage to magnetic flux change) is very high (up to $1301~\mathrm{\mu V/\Phi_0}$), which correlates with the high resistivity of W-C in the normal state. We discuss here the potential of this approach to reduce the active area of the nanoSQUIDs to gain spatial resolution as well as their integration on cantilevers for scanning-SQUID applications.
2203.05278v1
2008-08-07
Thermal strain-induced enhancement of electromagnetic properties in SiC-MgB2 composites
Strain engineering has been used to modify materials properties in ferroelectric, superconducting, and ferromagnetic thin films. The advantage of strain engineering is that it can achieve unexpected enhancement in certain properties, such as an increase in ferroelectric critical temperature, Tc, by 300 to 500K, with a minimum detrimental effect on the intrinsic properties of the material. The strain engineering has been largely applied to the materials in thin film form, where the strain is generated as a result of lattice mismatch between the substrate and component film or between layers in multilayer structures. Here, we report the observation of residual thermal stress/strain in dense SiC-MgB2 superconductor composites prepared by a diffusion method. We demonstrate that the thermal strain caused by the different thermal expansion coefficients between the MgB2 and SiC phases is responsible for the significant improvement in the critical current density, Jc, the irreversibility field, Hirr, and the upper critical field, Hc2, in the SiC-MgB2 composite where the carbon substitution level is low. In contrast to the common practice of improving the Jc and Hc2 of MgB2 through chemical substitution, by taking advantage of residual thermal strains we are able to design a composite, which shows only a small drop in Tc and little increase in resistivity, but a significant improvement over the Jc and Hc2 of MgB2. The present findings open up a new direction for manipulation of materials properties through strain engineering for materials in various forms.
0808.1136v1
2008-08-26
Thermoelectric Effects in Anisotropic Systems: Measurement and Applications
The Harman method for measuring the thermal conductivity of a sample using the Peltier effect, may also be used to determine the dimensionless figure of merit from just two electrical resistance measurements. We consider a modified version of the Harman method where the current contacts are much smaller than the contact faces of the sample. We calculate the voltage and temperature distributions in a rectangular sample of a material having anisotropy in all of its transport coefficients. The thermoelectric anisotropy has important consequences in the form of thermoelectric eddy currents and the Bridgman effect. We prove that in the limit of a very thin sample of arbitrary shape, there exist van der Pauw formulae relating particular linear combinations of the potential and temperature differences between points on the edges of the sample. We show that the Harman figure of merit can be radically different from the intrinsic figures of merit of the material, and can often be substantially enhanced. By defining an effective figure of merit in terms of the rate of entropy production, we show that the increase in the Harman figure of merit does indicate an improvement in the thermoelectric performance of an anisotropic sample having small current contacts. However, we also prove that in the case of a material with tetragonal symmetry, the effective figure of merit is always bounded from above by the largest intrinsic figure of merit of the material.
0808.3526v1
2015-02-27
Electrically Tunable Band Gap in Antiferromagnetic Mott Insulator Sr2IrO4
The electronic band gap in conventional semiconductor materials, such as silicon, is fixed by the material's crystal structure and chemical composition. The gap defines the material's transport and optical properties and is of great importance for performance of semiconductor devices like diodes, transistors and lasers. The ability to tune its value would allow enhanced functionality and flexibility of future electronic and optical devices. Recently, an electrically tunable band gap was realized in a 2D material - electronically gated bilayer graphene [1-3]. Here we demonstrate the realization of an electrically tunable band gap in a 3D antiferromagnetic Mott insulator Sr2IrO4. Using nano-scale contacts between a sharpened Cu tip and a single crystal of Sr2IrO4, we apply a variable external electric field up to a few MV/m and demonstrate a continuous reduction in the band gap of Sr2IrO4 by as much as 16%. We further demonstrate the feasibility of reversible resistive switching and electrically tunable anisotropic magnetoresistance,which provide evidence of correlations between electronic transport, magnetic order, and orbital states in this 5d oxide. Our findings suggest a promising path towards band gap engineering in 5d transition-metal oxides that could potentially lead to appealing technical solutions for next-generation electronic devices.
1502.07982v1
2016-11-28
Synthesis of low-moment CrVTiAl: a potential room temperature spin filter
The efficient production of spin-polarized currents at room temperature is fundamental to the advancement of spintronics. Spin-filter materials --- semiconductors with unequal band gaps for each spin channel --- can generate spin-polarized current without the need for spin-polarized contacts. In addition, a spin-filter material with zero magnetic moment would have the advantage of not producing strong fringing fields that would interfere with neighboring electronic components and limit the volume density of devices. The quaternary Heusler compound CrVTiAl has been predicted to be a zero-moment spin-filter material with a Curie temperature in excess of 1000 K. In this work, CrVTiAl has been synthesized with a lattice constant of $a = 6.15 \AA$. Magnetization measurements reveal an exceptionally low moment of $\mu = 2.3 \times 10^{-3} \mu_B/f.u.$ at a field of $\mu_0 H = 2 T$, that is independent of temperature between T = 10 K and 400 K, consistent with the predicted zero-moment ferrimagnetism. Transport measurements reveal a combination of metallic and semiconducting components to the resistivity. Combining a zero-moment spin-filter material with nonmagnetic electrodes would lead to an essentially nonmagnetic spin injector. These results suggest that CrVTiAl is a promising candidate for further research in the field of spintronics.
1611.09307v3
2016-10-19
Lattice of infinite bending-resistant fibers
This article present the double-periodical lattice made of infinite elastic fibers that withstand bending and tension. The model describes the elastic properties of flat periodic structure. With this model the behavior of a two-dimensional array of infinite fibers is simulated. The material that contains a row of broken fibers is considered. These broken fibers form the failure in the material that shapes like a long straight crack. The lattice is tensioned in the direction, which is orthogonal to the direction of straight crack. The conditions of fracture of this lattice are investigated. The closed form expression for the stress in the first unbroken fiber and the expression for fracture toughness are given. These values are the functions of mechanical parameters of lattice and tensions in both families of fibers. The closed form solution demonstrates a notable behavior of the material. Namely, the fracture behavior of two-dimensional lattice is cardinally depends upon the pre-stress in the material in the direction, parallel to crack direction. If the tension in fibers that parallel to the crack direction exists, it stabilizes the crack growth and makes the load distribution in the unbroken fibers more even. The two-dimensional lattice behaves in the presence of tension in both directions similarly to the plane elastic media. The finite length crack assumes the shape of the elongated elliptic split. Another behavior of lattice occurs if the fibers, parallel to crack direction, are unstressed. The character of stress concentration near the crack differs. The load distribution at the crack tip varies considerably. The first unbroken fiber carries higher load. The crack is lens-shaped and the crack borders form at the tip the finite angle.
1612.00274v1
2017-06-20
Coulomb drag in topological materials
Dirac fermions are at the forefront of modern condensed matter physics research. They are known to occur in materials as diverse as graphene, topological insulators, and transition metal dichalcogenides, while closely related Weyl fermions have been discovered in other materials. They have been predicted to lend themselves to a variety of technological applications, while the recent prediction and discovery of the quantized anomalous Hall effect of massive Dirac fermions is regarded as a potential gateway towards low-energy electronics. Some materials hosting Dirac fermions are natural platforms for interlayer coherence effects such as Coulomb drag and exciton condensation. The top and bottom surfaces of a thin topological insulator film provide such a prototype system. Here we describe recent insights into Coulomb drag between two layers of Dirac fermions relying primarily on topological insulator films as a minimal model. We consider both non-magnetic topological insulators, hosting massless Dirac fermions, and magnetic topological insulators, in which the fermions are massive. We discuss in general terms the dynamics of the thin-film spin density matrix, outlining numerical results and approximate analytical expressions where appropriate for the drag resistivity \r{ho}D at low temperatures and low electron densities. In magnetic topological insulators with out-of-plane magnetizations in both the active and passive layers we analyze the role of the anomalous Hall effect in Coulomb drag.
1706.07291v2
2019-02-11
Large area photoelectrodes based on hybrids of CNT fibres and ALD grown TiO2
Hybridisation is a powerful strategy towards the next generation of multifunctional materials for environmental and sustainable energy applications. Here, we report a new inorganic nanocarbon hybrid material prepared with atomically controlled deposition of a monocrystalline TiO2 layer that conformally coats a macroscopic carbon nanotube (CNT) fiber. Through X-ray diffraction, Raman spectroscopy and photoemission spectroscopy we detect the formation of a covalent Ti-O-C bond at the TiO2/CNT interface and a residual strain of approximately 0.7-2 \%, which is tensile in TiO2 and compressive in the CNT. It arises after deposition of the amorphous oxide onto the CNT surface previously functionalized by the oxygen plasma used in ALD. These features are observed in samples of different TiO2 thickness, in the range from 10 to 80 nm. Ultraviolet photoemission spectroscopy on a 20 nm-thick TiO2 coated sample gives a work function of 4.27 eV, between that of TiO2 (4.23 eV) and the CNT fiber (4.41 eV), and the presence of new interband gap states that shift the valence band maximum to 1.05 eV below the Fermi level. Photoelectrochemical measurements demonstrate electron transfer from TiO2 to the CNT fiber network under UV irradiation. Electrochemical impedance spectroscopy measurements reveal a low resistance for charge transfer and transport, as well as a large capacitance. Our results point to the fact that these hybrids, in which each phase has nanometric thickness and the current collector is integrated into the material, are very different from conventional electrodes and can provide a number of superior properties.
1902.04137v1
2020-09-15
Correlated electron metal properties of the honeycomb ruthenate Na$_2$RuO$_3$
We report the synthesis and characterisation of polycrystalline Na$_2$RuO$_3$, a layered material in which the Ru$^{4+}$ ($4d^4$ configuration) form a honeycomb lattice. The optimal synthesis condition was found to produce a nearly ordered Na$_2$RuO$_3$ ($C2/c$ phase), as assessed from the refinement of the time-of-flight neutron powder diffraction. Magnetic susceptibility measurements reveal a large temperature-independent Pauli paramagnetism ($\chi_0 \sim 1.42(2)\times10^{-3}$ emu/mol Oe) with no evidence of magnetic ordering down to 1.5 K, and with an absence of dynamic magnetic correlations, as evidenced by neutron scattering spectroscopy. The intrinsic susceptibility ($\chi_0$) together with the Sommerfeld coeficient of $\gamma=11.7(2)$ mJ/Ru mol K$^2$ estimated from heat capacity measurements, gives an enhanced Wilson ratio of $R_W\approx8.9(1)$, suggesting that magnetic correlations may be present in this material. While transport measurements on pressed pellets show nonmetallic behaviour, photoemission spectrocopy indicate a small but finite density of states at the Fermi energy, suggesting that the bulk material is metallic. Except for resistivity measurements, which may have been compromised by near surface and interface effects, all other probes indicate that Na$_2$RuO$_3$ is a moderately correlated electron metal. Our results thus stand in contrast to earlier reports that Na$_2$RuO$_3$ is an antiferromagnetic insulator at low temperatures.
2009.07105v1
2019-04-08
Ideal isotropic auxetic networks from random networks
Auxetic materials are characterized by a negative Poisson's ratio, $\mathrm{\nu}$. As the Poisson's ratio becomes negative and approaches the lower isotropic mechanical limit of $\mathrm{\nu = -1}$, materials show enhanced resistance to impact and shear, making them suitable for applications ranging from robotics to impact mitigation. Past experimental efforts aimed at reaching the $\mathrm{\nu = -1}$ limit have resulted in highly anisotropic materials, which show a negative Poisson's ratio only when subjected to deformations along specific directions. Isotropic designs have only attained moderately auxetic behavior, or have led to structures that cannot be manufactured in 3D. Here, we present a design strategy to create isotropic structures from disordered networks that leads to Poisson's ratios as low as $\mathrm{\nu = -0.98}$. The materials conceived through this approach are successfully fabricated in the laboratory and behave as predicted. The Poisson's ratio $\mathrm{\nu}$ is found to depend on network structure and bond strengths; this sheds light on the structural motifs that lead to auxetic behavior. The ideas introduced here can be generalized to 3D, a wide range of materials, and a spectrum of length scales, thereby providing a general platform that could impact technology.
1904.04359v1
2019-08-22
Size dependent yield hardness induced by surface energy
Size dependent hardness has long been reported in nanosized indentations, however the corresponding explanation is still in exploration. In this paper, we examine the influence of surface energy on the hardness of materials under spherical indentation. To evaluate the ability of materials to resist indentation, a yield hardness is defined here as the contact pressure at the inception of material yield. It is found that this defined hardness is an intrinsic material property depending only on the yield strength and Poisson ratio in conventional continuum mechanics. Then, the impact of surface energy on the yield hardness is analyzed through finite element simulations. By using the dimensional analysis, the dependences of the yield hardness and critical indent depth at yield initiation on surface energy have been achieved. When the yield strength is comparable to the ratio of surface energy density to indenter radius, surface energy will alter the yield hardness and the critical indent depth. As the size of indenter decreases to nanoscale, both the yield hardness and the indent depth will increase significantly. This study provides a possible clarification to the size dependence of hardness and a potential approach to measure the yield strength and surface energy of solids through nanosized indentations.
1908.08175v1
2020-07-25
Industrial manufacturing and characterization of multiscale CFRP laminates made from prepregs containing graphene-related materials
The introduction of graphene-related materials (GRMs) in carbon fibre-reinforced polymers (CFRP) has been proved to enhance their mechanical and electrical properties. However, methodologies to produce the 3-phase materials (multiscale composites) at an industrial scale and in an efficient manner are still lacking. In this paper, multiscale CFRP composites containing different GRMs have been manufactured following standard procedures currently used in the aerospace industry with the aim to evaluate its potential application. Graphite nanoplateletelets (GNPs), in situ exfoliated graphene oxide (GO) and reduced graphene oxide (rGO) have been dispersed into an epoxy resin to subsequently impregnate aeronautical grade carbon fibre tape. The resulting prepregs have been used for manufacturing laminates by hand lay-up and autoclave curing at 180 {\deg}C. Abroad characterization campaign has been carried out to understand the behaviour of the different multiscale laminates manufactured. The degree of cure, glass transition temperature and degradation temperature have been evaluated by thermal evolution techniques. Similarly, their mechanical properties (tensile, flexural, in-plane shear, interlaminar shear and mode I interlaminar fracture toughness) have been analysed together with their electrical conductivity. The manufacturing process resulted appropriated for producing three-phase laminates and their quality was as good as in conventional CFRPs. The addition ofGOand rGO resulted in an enhancement of the in-plane shear properties and delamination resistance while the addition ofGNPimproved the electrical conductivity.
2007.12902v1
2021-04-06
Phase Change Memory by GeSbTe Electrodeposition in Crossbar Arrays
Phase change memories (PCM) is an emerging type of non-volatile memory that has shown a strong presence in the data-storage market. This technology has recently attracted significant research interest in the development of non-Von Neumann computing architectures such as in-memory and neuromorphic computing. Research in these areas has been primarily motivated by the scalability potential of phase change materials and their compatibility with industrial nanofabrication processes. In this work, we are presenting our development of crossbar phase change memory arrays through the electrodeposition of GeSbTe (GST). We show that GST can be electrodeposited in microfabricated TiN crossbar arrays using a scalable process. Our phase switching test of the electrodeposited materials have shown that a SET/RESET resistance ratio of 2-3 orders of magnitude is achievable with a switching endurance of around 80 cycles. These results represent the first phase switching of electrodeposited GeSbTe in microfabricated crossbar arrays. Our work paves the way towards developing large memory arrays involving electrodeposited materials for passive selectors and phase switching devices. It also opens opportunities for developing a variety of different electronic devices using electrodeposited materials.
2104.02340v2
2021-07-29
Magnetic frustration in a van der Waals metal CeSiI
The realization of magnetic frustration in a metallic van der Waals (vdW) coupled material has been sought as a promising platform to explore novel phenomena both in bulk matter and in exfoliated devices. However, a suitable material platform has been lacking so far. Here, we demonstrate that CeSiI hosts itinerant electrons coexisting with exotic magnetism. In CeSiI, the magnetic cerium atoms form a triangular bilayer structure sandwiched by van der Waals stacked iodine layers. From resistivity and magnetometry measurements, we confirm the coexistence of itinerant electrons with magnetism with dominant antiferromagnetic exchange between the strongly Ising-like Ce moments below 7 K. Neutron diffraction directly confirms magnetic order with an incommensurate propagation vector k ~ (0.28, 0, 0.19) at 1.6 K, which points to the importance of further neighbor magnetic interactions in this system. The presence of a two-step magnetic-field-induced phase transition along c axis further suggests magnetic frustration in the ground state. Our findings provide a novel material platform hosting a coexistence of itinerant electron and frustrated magnetism in a vdW system, where exotic phenomena arising from rich interplay between spin, charge and lattice in low dimension can be explored.
2107.13810v1
2022-03-31
Catapulting of topological defects through elasticity bands in active nematics
Active materials are those in which individual, uncoordinated local stresses drive the material out of equilibrium on a global scale. Examples of such assemblies can be seen across scales from schools of fish to the cellular cytoskeleton and underpin many important biological processes. Synthetic experiments that recapitulate the essential features of such active systems have been the object of study for decades as their simple rules allow us to elucidate the physical underpinnings of collective motion. One system of particular interest has been active nematic liquid crystals (LCs). Because of their well understood passive physics, LCs provide a rich platform to interrogate the effects of active stress. The flows and steady state structures that emerge in an active LCs have been understood to result from a competition between nematic elasticity and the local activity. However most investigations of such phenomena consider only the magnitude of the elastic resistance and not its peculiarities. Here we investigate a nematic liquid crystal and selectively change the ratio of the material's splay and bend elasticities. We show that increases in the nematic's bend elasticity specifically drives the material into an exotic steady state where elongated regions of acute bend distortion or "elasticity bands" dominate the structure and dynamics. We show that these bands strongly influence defect dynamics, including the rapid motion or "catapulting" along the disintegration of one of these bands thus converting bend distortion into defect transport. Thus, we report a novel dynamical state resultant from the competition between nematic elasticity and active stress.
2204.00113v1
2023-09-15
Emergence of partially disordered antiferromagnetism and isothermal magnetization plateau due to geometrical frustration in a metallic compound, Er2RhSi3
Partially disordered antiferro (PDA) magnetism (in which one of the three magnetic ions in a triangular network remains magnetically disordered), has been known commonly among geometrically frustrated insulating materials. The one-third plateau in isothermal magnetization (M) of such materials has been of great theoretical interest. Here, we report these properties in a AlB2-structure derived metallic material, Er2RhSi3 in which Er sublattice has triangular networks. The presence of a well-defined lamda anomaly in the temperature (T) dependence of heat capacity and its magnetic-field (H) dependence, and the loss of spin-disorder contribution in electrical resistivity (rho) confirm antiferromagnetic order below (TN=) 5 K. On the other hand, the separation of zero-field-cooled and field-cooled dc magnetic susceptibility (chi) curves, decay of isothermal remnant magnetization and the frequency dependence of real and imaginary components of ac chi suggest the onset of spin-glass freezing concomitant with the antiferromagnetic order. In addition, interestingly, we observe one-third plateau in M(H) below 20 kOe for T less than TN. The change in rho as a function of H at a given temperature well below TN is also revealing, with this compound exhibiting a plateau below 20 kOe, with complexities at higher fields. Therefore, this compound serves as a prototype for theoretical understanding of transport behavior across one-third plateau due to PDA magnetism in a metal without any interference from the 4f delocalization phenomena.
2309.08176v1
2023-10-18
Moire synaptic transistor for homogeneous-architecture reservoir computing
Reservoir computing has been considered as a promising intelligent computing paradigm for effectively processing complex temporal information. Exploiting tunable and reproducible dynamics in the single electronic device have been desired to implement the reservoir and the readout layer of reservoir computing system. Two-dimensional moire material, with an artificial lattice constant many times larger than the atomic length scale, is one type of most studied artificial quantum materials in community of material science and condensed-matter physics over the past years. These materials are featured with gate-tunable periodic potential and electronic correlation, thus varying the electric field allows the electrons in the moire potential per unit cell to exhibit distinct and reproducible dynamics, showing great promise in robust reservoir computing. Here, we report that a moire synaptic transistor can be used to implement the reservoir computing system with a homogeneous reservoir-readout architecture. The synaptic transistor is fabricated based on a h-BN/bilayer graphene/h-BN moire heterostructure, exhibiting ferroelectricity-like hysteretic gate voltage dependence of resistance. Varying the magnitude of the gate voltage enables the moire transistor to be switched between long-term memory and short-term memory with nonlinear dynamics. By employing the short- and long-term memory as the reservoir nodes and weights of the readout layer, respectively, we construct a full-moire physical neural network and demonstrate that the classification accuracy of 90.8% can be achieved for the MNIST handwritten digit database. Our work would pave the way towards the development of neuromorphic computing based on the moire materials.
2310.11743v1
2024-05-06
Band structure engineering using a moiré polar substrate
Applying long wavelength periodic potentials on quantum materials has recently been demonstrated to be a promising pathway for engineering novel quantum phases of matter. Here, we utilize twisted bilayer boron nitride (BN) as a moir\'e substrate for band structure engineering. Small-angle-twisted bilayer BN is endowed with periodically arranged up and down polar domains, which imprints a periodic electrostatic potential on a target two-dimensional (2D) material placed on top. As a proof of concept, we use Bernal bilayer graphene as the target material. The resulting modulation of the band structure appears as superlattice resistance peaks, tunable by varying the twist angle, and Hofstadter butterfly physics under a magnetic field. Additionally, we demonstrate the tunability of the moir\'e potential by altering the dielectric thickness underneath the twisted BN. Finally, we find that near-60{\deg}-twisted bilayer BN provides a unique platform for studying the moir\'e structural effect without the contribution from electrostatic moir\'e potentials. Tunable moir\'e polar substrates may serve as versatile platforms to engineer the electronic, optical, and mechanical properties of 2D materials and van der Waals heterostructures.
2405.03761v1
2001-11-01
To the problem of electron-phonon interaction and "d-wave pairing" in high-Tc oxides
It is supported a recent proposal by Maksimov that electron-phonon interaction (EPI) (Gruneisen-Bloch formulae) determines the linearity of temperature dependence of resistivity for both HTSC-cuprates and most of metals at T near above 0.2 of their characteristic Debye temperature (normal state for HTSC). However, it is emphasized here that in this T-region the resistivity is not proportional to T but is only linear in T. This fact indicates to T-independent contribution to normal-state resistivity in HTSC-cuprates (magnetic contribution, in our treatment) which behavior, in its turn, indicates to possible magnetic (SDW-like) phase transition before SC transition in HTSC-system. SDW-gap (measured as pseudogap with d-wave symmetry, in our treatment) is formed at the symmetrical parts of the Fermi surface above Tc and persists in SC state. The magnitude of SDW-gap is essentially larger than that for SC-gap. So, SDW formed can mimic d-wave symmetry of the order parameter measured below Tc (which is now attributed to d-wave pairing). On the other hand, since the Gruneisen-Bloch curve appears to be (in approach used) a geometric locus for the Tc(onset)(H) (as in LTSC) this fact evidents about EPI-nature (BCS) of SC transition (s-wave) in high-Tc oxides. The proposal to increase Tc using above (SDW/CDW/SC) model (and possible realization) is presented.
0111015v1
2004-05-31
Transport Properties in the "Strange Metal Phase" of High Tc Cuprates: Spin-Charge Gauge Theory Versus Experiments
The SU(2)xU(1) Chern-Simons spin-charge gauge approach developed earlier to describe the transport properties of the cuprate superconductors in the ``pseudogap'' regime, in particular, the metal-insulator crossover of the in-plane resistivity, is generalized to the ``strange metal'' phase at higher temperature/doping. The short-range antiferromagnetic order and the gauge field fluctuations, which were the key ingredients in the theory for the pseudogap phase, also play an important role in the present case. The main difference between these two phases is caused by the existence of an underlying statistical $\pi$-flux lattice for charge carriers in the former case, whereas the background flux is absent in the latter case. The Fermi surface then changes from small ``arcs'' in the pseudogap to a rather large closed line in the strange metal phase. As a consequence the celebrated linear in T dependence of the in-plane and out-of-plane resistivity is shown explicitly to recover. The doping concentration and temperature dependence of theoretically calculated in-plane and out-of-plane resistivity, spin-relaxation rate and AC conductivity are compared with experimental data, showing good agreement.
0405704v2
2007-05-03
Mean-Field Magnetohydrodynamics of Accretion Disks
We consider the accretion process in a disk with magnetic fields that are dragged in from the interstellar medium by gravitational collapse. Two diffusive processes are at work in the system: (1) "viscous" torques exerted by turbulent and magnetic stresses, and (2) "resistive" redistribution of mass with respect to the magnetic flux arising from the imperfect conduction of current. In steady state, self-consistency between the two rates of drift requires that a relationship exists between the coefficients of turbulent viscosity and turbulent resistivity. Ignoring any interactions with a stellar magnetosphere, we solve the steady-state equations for a magnetized disk under the gravitational attraction of a mass point and threaded by an amount of magnetic flux consistent with calculations of magnetized gravitational collapse in star formation. Our model mean-field equations have an exact analytical solution that corresponds to magnetically diluted Keplerian rotation about the central mass point. The solution yields the strength of the magnetic field and the surface density as functions of radial position in the disk and their connection with the departure from pure Keplerian rotation in representative cases. We compare the predictions of the theory with the available observations concerning T Tauri stars, FU Orionis stars, and low- and high-mass protostars. Finally, we speculate on the physical causes for high and low states of the accretion disks that surround young stellar objects. One of the more important results of this study is the physical derivation of analytic expressions for the turbulent viscosity and turbulent resistivity.
0705.0421v1
2008-08-27
The quantum critical point in CeRhIn_5: a resistivity study
The pressure--temperature phase diagram of CeRhIn_5 has been studied under high magnetic field by resistivity measurements. Clear signatures of a quantum critical point has been found at a critical pressure of p_c = 2.5 GPa. The field induced magnetic state in the superconducting state is stable up to the highest field. At p_c the antiferromagnetic ground-state under high magnetic field collapses very rapidly. Clear signatures of p_c are the strong enhancement of the resistivity in the normal state and of the inelastic scattering term. No clear T2 temperature dependence could be found for pressures above T_c. From the analysis of the upper critical field within a strong coupling model we present the pressure dependence of the coupling parameter lambda and the gyromagnetic ratio g. No signatures of a spatially modulated order parameter could be evidenced. A detailed comparison with the magnetic field--temperature phase diagram of CeCoIn_5 is given. The comparison between CeRhIn_5 and CeCoIn_5 points out the importance to take into account the field dependence of the effective mass in the calculation of the superconducting upper critical field H_c2. It suggests also that when the magnetic critical field H_(0) becomes lower than H_c2 (0)$, the persistence of a superconducting pseudo-gap may stick the antiferromagnetism to H_c2 (0).
0808.3687v1
2009-07-13
Enhanced Critical parameters of nano-Carbon doped MgB2 Superconductor
The high field magnetization and magneto transport measurements are carried out to determine the critical superconducting parameters of MgB2-xCx system. The synthesized samples are pure phase and the lattice parameters evaluation is carried out using the Rietveld refinement. The R-T(H) measurements are done up to a field of 140 kOe. The upper critical field values, Hc2 are obtained from this data based upon the criterion of 90% of normal resistivity i.e. Hc2=H at which Rho=90%Rho; where RhoN is the normal resistivity i.e., resistivity at about 40 K in our case. The Werthamer-Helfand-Hohenberg (WHH) prediction of Hc(0) underestimates the critical field value even below than the field up to which measurement is carried out. After this the model, the Ginzburg Landau theory (GL equation) is applied to the R-T(H) data which not only calculates the Hc2(0) value but also determines the dependence of Hc2 on temperature in the low temperature high field region. The estimated Hc(0)=157.2 kOe for pure MgB2 is profoundly enhanced to 297.5 kOe for the x=0.15 sample in MgB2-xCx series. Magnetization measurements are done up to 120 kOe at different temperatures and the other parameters like irreversibility field, Hirr and critical current density Jc(H) are also calculated. The nano carbon doping results in substantial enhancement of critical parameters like Hc2, Hirr and Jc(H) in comparison to the pure MgB2 sample.
0907.2129v2