page_content stringlengths 12 2.63M | metadata unknown |
|---|---|
- **14.1** Predict the transition metal-containing products of the following reactions:
- a. $[Mn(CO)_5]^- + H_2C = CH CH_2Cl \longrightarrow$ initial product $\xrightarrow{-CO}$ final product
- **b.** trans-Ir(CO)Cl(PPh<sub>3</sub>)<sub>2</sub> + CH<sub>3</sub>I $\longrightarrow$
- c. $Ir(PPh_3)_3Cl \xrightarrow{... | {
"Header 1": "14.4.2 Water Gas Reaction",
"Header 3": "**Problems**",
"token_count": 1220,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Identify **A** and **B**.
- **14.6** The reaction of V(CO)<sub>5</sub>(NO) with P(OCH<sub>3</sub>)<sub>3</sub> to give $V(CO)_4[P(OCH_3)_3](NO)$ has the rate law
$$\frac{-d[V(CO)_5(NO)]}{dt} = k_1 [V(CO)_5(NO)] + k_1 [V(CO)_5(NO)] + k_2 [V(CO)_5(NO)] + k_3 [V(CO)_5(NO)] + k_4 [V(CO)_5(NO)] + k_5 [V(CO)_5(NO)] + k_5... | {
"Header 1": "14.4.2 Water Gas Reaction",
"Header 3": "**Problems**",
"token_count": 1909,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
What was the general formula of the complexes used by Tolman?
- **b.** How was X defined?
- **c.** What types of ligands had high values of $\chi$ ?
- **d.** To what extent does this approach distinguish between the sigma donor and pi acceptor nature of the ligands studied?
- **14.11** The nickel(II) pincer complexes ... | {
"Header 1": "14.4.2 Water Gas Reaction",
"Header 3": "**Problems**",
"token_count": 1994,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Chem.*, **1987**, *26*, 1690.)
- 14.19 The complex I in the preceding problem can be synthesized from $Re(CO)_5Br$ and 2-bromoethanol in ethylene oxide solution with solid NaBr present. Suggest a mechanism for the formation of the carbene ligand.
- **14.20** BrCH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>Mn(CO)<sub>5<... | {
"Header 1": "14.4.2 Water Gas Reaction",
"Header 3": "**Problems**",
"token_count": 1867,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Addition of NaSCN to **II** replaces Cl with SCN to give a product **III** having the following <sup>1</sup>H NMR spectrum:
| <b>Chemical Shift</b> | Relative Area | Туре |
|-----------------------|---------------|---------------------------|
| 6.9–7.5 | 12 | Aromatic ... | {
"Header 1": "14.4.2 Water Gas Reaction",
"Header 3": "**Problems**",
"token_count": 1790,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Comparisons within main group chemistry have already been discussed in earlier chapters. These included the similarities and differences between borazine and benzene, the relative instability of silanes in comparison with alkanes, and differences in bonding in homonuclear and heteronuclear diatomic species, such as the... | {
"Header 1": "15.1 **[Main Group Parallels with Binary Carbonyl](#page-9-0) Complexes**",
"token_count": 1871,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
An important contribution to the understanding of parallels between organic and inorganic chemistry has been the concept of isolobal molecular fragments, described elaborately by Roald Hoffmann in his 1981 Nobel lecture.<sup>2</sup> Hoffmann defined molecular fragments to be isolobal
if the number, symmetry propertie... | {
"Header 1": "15.2 The Isolobal Analogy",
"token_count": 787,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Using Hoffmann's symbol $\leftarrow_0$ to designate groups as isolobal, we may write
$$CH_3 \stackrel{\longleftarrow}{\longleftarrow} ML_5 \qquad \stackrel{H}{\longleftarrow} C \stackrel{\longleftarrow}{\longleftarrow} L \stackrel{L}{\longleftarrow} M \stackrel{\longleftarrow}{\longleftarrow} L \stackrel{\longlefta... | {
"Header 1": "15.2 The Isolobal Analogy",
"token_count": 2315,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
These fragments are 2 electrons short of a filled-shell octet or 18-electron configuration, so they are electronically equivalent; each has two singly occupied hybrid orbitals at otherwise vacant sites. Absence of a third ligand similarly gives a pair of isolobal fragments, 5-electron CH and 15-electron $ML_3$ .
$$\... | {
"Header 1": "15.2 The Isolobal Analogy",
"token_count": 1377,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
The isolobal fragment concept can be extended to include charged species, ligands other than CO, and organometallic fragments not based on octahedral geometries. Some ways of extending the isolobal parallels are summarized as follows:
1. The isolobal definition may be extended to isoelectronic fragments having the sa... | {
"Header 1": "15.2.1 Extensions of the Analogy",
"token_count": 1841,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Propose examples of organometallic fragments isolobal with CH<sub>2</sub><sup>+</sup>.
Here we will limit ourselves to the ligand CO and first-row transition metals. Other ligands and metals may be used with equally valid results.
CH<sub>2</sub><sup>+</sup> is two ligands and 3 electrons short of its parent compoun... | {
"Header 1": "15.2.1 Extensions of the Analogy",
"Header 3": "**EXAMPLE 15.1**",
"token_count": 527,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
| Neutral hydrocarbons | CH <sub>4</sub> | CH <sub>3</sub> | CH <sub>2</sub> | СН | С |
|-------------------------------------------------------------------|---------------------|----------------------------|------... | {
"Header 1": "15.2.1 Extensions of the Analogy",
"Header 3": "**TABLE 15.3** Examples of Isolobal Fragments",
"token_count": 1026,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
The isolobal analogy can be extended to any molecular fragment having frontier orbitals of suitable size, shape, symmetry, and energy. Realization of these analogies inspires research by suggesting target molecules that can appear unorthodox on first inspection. For example, the 5-electron fragment CH is isolobal with ... | {
"Header 1": "15.2.2 Examples of Applications of the Analogy",
"token_count": 1114,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
CH<sub>3</sub> is isolobal with 17-electron $Zn(\eta^5-C_5Me_5)$ (extension 4 of the analogy).
$CH_2$ is isolobal with 16-electron $Ir(PPh_3)_2(CS)Cl$ (start with 16-electron $[Ir(CO)_4]^+$ from the parent octahedron, and substitute $PPh_3$ , $Cl^-$ , and CS, respectively, for CO, extension 2 of the analogy)... | {
"Header 1": "15.2.2 Examples of Applications of the Analogy",
"Header 3": "**EXAMPLE 15.2**",
"token_count": 223,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
The formation of metal-metal bonds was described using the isolobal analogy in Section 15.2. These bonds differ from others in the use of d orbitals on both atoms. In addition to the usual $\sigma$ and $\pi$ bonds, $\delta$ bonds are possible in transition-metal compounds. Furthermore, bridging by ligands and the... | {
"Header 1": "15.3 Metal-Metal Bonds",
"token_count": 798,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Transition metals may form single, double, triple, or quadruple bonds (or bonds of fractional order) with other metal atoms. How are quadruple bonds possible? In main group chemistry, atomic orbitals in general can interact in a $\sigma$ or $\pi$ fashion, with the highest possible bond order of 3 a combination of o... | {
"Header 1": "15.3 Metal-Metal Bonds",
"Header 3": "**Quadruple Bonds**",
"token_count": 1958,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
For example, removal of $\delta^*$ electrons on oxidation of Re<sub>2</sub>Cl<sub>4</sub>(PMe<sub>2</sub>Ph<sub>4</sub>)<sub>4</sub> gives only very slight shortening of the Re—Re distances, as shown in **Table 15.5**.<sup>16</sup>
A possible explanation for the small change in bond distance is that, with increasin... | {
"Header 1": "15.3 Metal-Metal Bonds",
"Header 3": "**Quadruple Bonds**",
"token_count": 442,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Can there be such a thing as a quintuple bond? Figure 15.8 shows five possible interactions between *d* orbitals, including two d interactions—so it is reasonable to propose a compound having bonding electron pairs in orbitals arising from all five. In 2005 Power reported a compound with "fivefold" bonding.17 This dime... | {
"Header 1": "15.3 Metal-Metal Bonds",
"Header 3": "**Quintuple Bonds**",
"token_count": 815,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Boron and hydrogen form many neutral and ionic species. For the purposes of illustrating parallels between these species and transition-metal clusters, we will first consider one category of these boranes, closo (Greek, "cagelike") boranes ( $B_nH_n^{2-}$ ). These consist of closed polyhedra with n corners and all tria... | {
"Header 1": "15.4 Cluster Compounds",
"Header 3": "**15.4.1 Boranes**",
"token_count": 1085,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
In all *closo* boranes, there is one more framework bonding pair than the number of corners in the polyhedron. One framework bonding pair occupies a totally symmetric orbital (like the $A_{1g}$ orbital in $B_6H_6^{2-}$ ), resulting from the overlap of atomic (or hybrid) orbitals at the center of the polyhedron. In a... | {
"Header 1": "15.4 Cluster Compounds",
"Header 3": "11 nonbonding or antibonding orbitals",
"token_count": 1218,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Consider $B_{11}H_{13}^{2-}$ with 33 + 13 + 2 = 48 valence electrons.
1. Each boron atom possesses at least one terminal hydrogen atom, and a B—H fragment contributes two electrons to framework bonding; one boron valence electron participates in the covalent bond to hydrogen. The framework contribution is $11 \tim... | {
"Header 1": "15.4 Cluster Compounds",
"Header 3": "**EXAMPLE 15.3**",
"token_count": 1405,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
The structures of boranes can be classified according to the following scheme:
*closo* boranes have the formula $B_n H_n^{2-}$ *nido* boranes are formally derived from $B_n H_n^{4-}$ ions
arachno boranes are formally derived from B<sub>n</sub>H<sub>n</sub><sup>6-</sup> ions hypho boranes are formally derived fro... | {
"Header 1": "15.4 Cluster Compounds",
"Header 3": "**A Method for Classifying Boranes**",
"token_count": 271,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Classify the following boranes by structural type.
$$B_{10}H_{14}$$
$$B_{10}H_{14} - 4 H^+ = B_{10}H_{10}{}^{4-}$$
The classification is *nido*.
$$B_2H_7$$
$$B_2H_7^- - 5 H^+ = B_2H_2^{6-}$$
The classification is *arachno*.
$$B_8H_1$$
$$B_8H_{16} - 8 H^+ = B_8H_8^{8-}$$
The classification is hypho.
**EXER... | {
"Header 1": "15.4 Cluster Compounds",
"Header 3": "**EXAMPLE 15.4**",
"token_count": 246,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
The electron-counting schemes can be extended to isoelectronic species such as the carboranes, also known as carbaboranes. The CH<sup>+</sup> unit is isoelectronic with BH; many compounds are known in which one or more BH groups have been replaced by CH<sup>+</sup> (or by C, which also has the same number of electrons ... | {
"Header 1": "15.4.2 Heteroboranes",
"token_count": 788,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Classify the following carboranes by structural type:
$$C_2B_9H_{12}^{-1}$$
$$C_2B_9H_{12}^- \longrightarrow B_{11}H_{14}^- \ B_{11}H_{14}^- - 3H^+ = B_{11}H_{11}^{4-}$$
The classification is *nido*.
$$C_2B_7H_{13}$$
$$\begin{array}{l} C_2B_7H_{13} \longrightarrow B_9H_{15} \\ B_9H_{15} - 6H^+ = B_9H_9{}^{6-} \... | {
"Header 1": "15.4.2 Heteroboranes",
"Header 3": "**EXAMPLE 15.5**",
"token_count": 465,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Classify the following heteroboranes by structural type:
$$SB_9H_{11}$$
$$SB_9H_{11} \longrightarrow B_{10}H_{14}$$
$B_{10}H_{14} - 4H^+ = B_{10}H_{10}^{4-}$
The classification is *nido*.
$CPB_{10}H_{11}$
$$CPB_{10}H_{11} \longrightarrow PB_{11}H_{12} \longrightarrow B_{12}H_{14}$$
$B_{12}H_{14} - 2H^{+} ... | {
"Header 1": "15.4.2 Heteroboranes",
"Header 3": "**EXAMPLE 15.6**",
"token_count": 331,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
The CH group of a carborane is isolobal with 15-electron fragments of an octahedron such as Co(CO)<sub>3</sub>. Similarly, BH, which has 4 valence electrons, is isolobal with 14-electron fragments such as Fe(CO)<sub>3</sub> and Co( $\eta^5$ -C<sub>5</sub>H<sub>5</sub>). These organometallic fragments have been found in... | {
"Header 1": "15.4.3 Metallaboranes and Metallacarboranes",
"token_count": 1583,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Classify the following metallaboranes by structural type:
$B_4H_6(CoCp)_2$
$$B_4H_6(CoCp)_2 \longrightarrow B_4H_6(BH)_2 = B_6H_8$$
$B_6H_8 - 2H^+ = B_6H_6^{2-}$
The classification is *closo*.
$B_3H_7[Fe(CO)_3]_2$
$$B_3H_7[Fe(CO)_3]_2 \longrightarrow B_3H_7[BH]_2 = B_5H_9$$
$$B_5H_9 - 4H^+ = B_5H_5^{4-}$$... | {
"Header 1": "15.4.3 Metallaboranes and Metallacarboranes",
"Header 3": "**EXAMPLE 15.7**",
"token_count": 250,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Many carbonyl clusters have structures similar to boranes. To what extent is the approach used to describe bonding in boranes applicable to bonding in carbonyl clusters and other clusters?
According to Wade, the valence electrons in a cluster can be assigned to framework and metal-ligand bonding.<sup>36</sup>
```
T... | {
"Header 1": "15.4.4 Carbonyl Clusters",
"token_count": 2046,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
a A capped *closo* cluster has a valence electron count equivalent to neutral B*n*H*n*. A capped *nido* cluster has the same electron
count as a *closo* cluster. b This complex has an electron count matching a *nido* structure, but it adapts the butterfl y structure expected for *arachno* . This is one of the many ... | {
"Header 1": "15.4.4 Carbonyl Clusters",
"token_count": 383,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Classify the following main-group clusters:
**a.** $Pb_5^{2-}$ : Total valence-electron count = 22 (including each of the 4 valence electrons per Pb, plus 2 electrons for the charge). Because n = 5, the total electron count = 4n + 2; the classification is *closo*. (See Table 15.11.)
- **b.** Sn9 <sup>4</sup>-: Tot... | {
"Header 1": "15.4.4 Carbonyl Clusters",
"Header 3": "**EXAMPLE 15.8**",
"token_count": 495,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Determine the number of framework electron pairs predicted by the *mno* rule for the following:
```
B12H12
2- (see Figure 15.15 )
```
*m* : This structure consists of a single polyhedron. *m* = 1
*n* : Each boron atom in the polyhedron is a vertex. *n* = 12
*o* : There are no bridges between polyhedra. *o* = 0 ... | {
"Header 1": "15.4.4 Carbonyl Clusters",
"Header 3": "**E X A M P L E 15 . 9**",
"token_count": 585,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Many compounds have been synthesized, often fortuitously, in which one or more atoms have been partially or completely encapsulated within metal clusters. The most common have been the carbon-centered clusters, also called carbide or carbido clusters, with carbon exhibiting coordination numbers and geometries not found... | {
"Header 1": "15.4.5 Carbon-Centered Clusters",
"token_count": 879,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
As we have seen, transition-metal clusters can adopt a wide variety of geometries and can involve metal–metal bonds of order as high as 5. Clusters may also include much larger polyhedra than shown so far in this chapter; polyhedra linked through vertices, edges, or faces; and extended three-dimensional arrays. Example... | {
"Header 1": "15.4.6 **[Additional Comments on Clusters](#page-10-0)**",
"token_count": 1975,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Wade, *Electron Defi cient Compounds* , Thomas Nelson & Sons, London, 1971.
- **26.** K. Wade, "Some Bonding Considerations," in B. F. G. Johnson, ed., *Transition Metal Clusters* , John Wiley & Sons, New York, 1980, p. 217.
- **27.** Z. Chen, R. B. King, *Chem. Rev.* , **2005** , *105* , 3613.
- **28.** K. Srinivasu, ... | {
"Header 1": "15.4.6 **[Additional Comments on Clusters](#page-10-0)**",
"token_count": 1172,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
A classic reference on parallels between main-group and organometallic chemistry is Roald Hoffmann's 1982 Nobel lecture, "Building Bridges between Inorganic and Organic Chemistry," in *Angew. Chem., Int. Ed.*, **1982**, *21*, 711–724, which describes in detail the isolobal analogy. Another very useful paper is John Ell... | {
"Header 1": "15.4.6 **[Additional Comments on Clusters](#page-10-0)**",
"Header 3": "**General References**",
"token_count": 513,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
- **15.1** Predict the following products:
- **a.** $Mn_2(CO)_{10} + Br_2 \longrightarrow$
- **b.** $HCCl_3 + excess [Co(CO)_4]^-$
- c. $Co_2(CO)_8 + (SCN)_2 \longrightarrow$
- **d.** $Co_2(CO)_8 + C_6H_5 C \equiv C C_6H_5$ (product has a single Co Co bond)
- e. $Mn_2(CO)_{10} + [(\eta^5 C_5H_5)Fe(CO)_2]_2 \longr... | {
"Header 1": "15.4.6 **[Additional Comments on Clusters](#page-10-0)**",
"Header 3": "**Problems**",
"token_count": 692,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
$$\begin{array}{cccccccccccccccccccccccccccccccccccc$$
$\begin{array}{cccccccccccccccccccccccccccccccccccc$
$(CO)_4$ $(CO)_4$ $(CO)_4$ $(CO)_4$ $(CO)_4$ $(CO)_4$ $(CO)_4$ $(CO)_4$ $(CO)_4$ $(CO)_4$ $(CO)_4$ $(CO)_4$ $(CO)_4$ $(CO)_4$ $(CO)_4$ $(CO)_4$ $(CO)_4$ $(CO)_4$ $(CO)_4$... | {
"Header 1": "15.4.6 **[Additional Comments on Clusters](#page-10-0)**",
"Header 3": "**Problems**",
"token_count": 2029,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Furthermore, analogs of the unstable CH<sub>5</sub><sup>+</sup>, CH<sub>6</sub><sup>2+</sup>, and CH<sub>7</sub><sup>3+</sup> ions can be prepared using AuPPh<sub>3</sub> instead of H. Predict the structures of the AuPPh<sub>3</sub> analogs of these ions, and suggest a reason for their stability. (Hint: see G. A. Olah,... | {
"Header 1": "15.4.6 **[Additional Comments on Clusters](#page-10-0)**",
"Header 3": "**Problems**",
"token_count": 2024,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Kaupp; S. Demeshko; R. Kempe, Z. Anorg. Allg. Chem., 2009, 635, 1149). Use the sketches in this reference to discuss the steric and electronic features of aminopyridinates, amidinates, and guanidinates that result in varying Cr-Cr bond lengths. How does the magnetic susceptibility measurement for the dichromium complex... | {
"Header 1": "15.4.6 **[Additional Comments on Clusters](#page-10-0)**",
"Header 3": "**Problems**",
"token_count": 1895,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
What differentiates the MoCp\* fragments leading to this spectral feature?
- 15.30 The reaction of [Fe(η<sup>6</sup>-arene)]<sup>2+</sup> and Tl<sub>2</sub>[nido-7,8-C<sub>2</sub>B<sub>9</sub>H<sub>11</sub>] results in arene displacement and formation of [1-(η<sup>6</sup>-arene)-closo-1,2,3-FeC<sub>2</sub>B<sub>9</sub>... | {
"Header 1": "15.4.6 **[Additional Comments on Clusters](#page-10-0)**",
"Header 3": "**Problems**",
"token_count": 2005,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
A, 2002, 106, 5600.)
- 15.38 Construct the ions $Re_2Cl_8^{2-}$ and $Os_2Cl_8^{2-}$ (see Figure 15.7), and calculate and display their molecular orbitals. Compare these orbitals with Figure 15.8, focusing on the metal-metal bonds and on d-orbital interactions with the ligands, and classify orbitals involved in meta... | {
"Header 1": "15.4.6 **[Additional Comments on Clusters](#page-10-0)**",
"Header 3": "**Problems**",
"token_count": 881,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
2.1
$$E = R_H \left(\frac{1}{2^2} - \frac{1}{3^2}\right) = R_H \left(\frac{5}{36}\right) = 2.179 \times 10^{-18} \,\mathrm{J}\left(\frac{5}{36}\right) = 3.026 \times 10^{-19} \,\mathrm{J}$$
= $1.097 \times 10^7 \,\mathrm{m}^{-1} \left(\frac{5}{36}\right) = 1.524 \times 10^6 \,\mathrm{m}^{-1} \times \frac{\mathrm{m}}... | {
"Header 1": "Answers to Exercises",
"Header 3": "**Chapter 2**",
"token_count": 1977,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
**3.1** POF3 : The octet rule results in single PiF and PiO bonds; formal charge arguments result in a double bond for P"O . The actual distance is 143 pm, considerably shorter than a regular PiO bond (164 pm).
$$\begin{array}{cccccccccccccccccccccccccccccccccccc$$
SOF<sub>4</sub>: This is a distorted trigonal bipy... | {
"Header 1": "Answers to Exercises",
"Header 3": "**Chapter 3**",
"token_count": 1385,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
**4.1** $S_2$ is made up of $C_2$ followed by $\sigma_{\perp}$ , which is shown in the figure below to be the same as *i*.
$S_1$ is made up of $C_1$ followed by $\sigma_{\perp}$ , which is shown in the figure below to be the same as $\sigma$ .
... | {
"Header 1": "Answers to Exercises",
"Header 3": "**Chapter 4**",
"token_count": 1772,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
**4.4 a.**
$$\begin{bmatrix} 5 & 1 & 3 \\ 4 & 2 & 2 \\ 1 & 2 & 3 \end{bmatrix} \times \begin{bmatrix} 2 & 1 & 1 \\ 1 & 2 & 3 \\ 5 & 4 & 3 \end{bmatrix}$$
$$= \begin{bmatrix} (5 \times 2) + (1 \times 1) + (3 \times 5) & (5 \times 1) + (1 \times 2) + (3 \times 4) & (5 \times 1) + (1 \times 3) + (3 \times 3) \\ (4 \ti... | {
"Header 1": "Answers to Exercises",
"Header 3": "**Chapter 4**",
"token_count": 702,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
$$x' = \text{new } x = x$$
$y' = \text{new } y = y$
$z' = \text{new } z = z$
$$\begin{bmatrix} 1 & 0 & 0 \\ 0 & 1 & 0 \\ 0 & 0 & 1 \end{bmatrix} = \text{transformation matrix for } E$$
In matrix notation,
$$\begin{bmatrix} x' \\ y' \\ z' \end{bmatrix} = \begin{bmatrix} 1 & 0 & 0 \\ 0 & 1 & 0 \\ 0 & 0 & 1 \end{b... | {
"Header 1": "Answers to Exercises",
"Header 3": "**4.5** E: The new coordinates are",
"token_count": 1275,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
$$D_{2h}$$
$E$ $C_2(z)$ $C_2(y)$ $C_2(x)$ $i$ $\sigma(xy)$ $\sigma(xz)$ $\sigma(yz)$ $\Gamma$ 18 0 0 -2 0 6 2 0
This reduces to: $3 A_g + 3 B_{1g} + 2 B_{2g} + B_{3g} + A_u + 2 B_{1u} + 3 B_{2u} + 3 B_{3u}$
Translational modes (matching x, y, and z): $B_{1u} + B_{2u} + B_{3u}$
Rotational modes ... | {
"Header 1": "Answers to Exercises",
"Header 3": "The reducible representation ( $D_{2h}$ symmetry) is:",
"token_count": 265,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
| $T_d$ | E | 8C <sub>3</sub> | $3C_{2}$ | 6S <sub>4</sub> | $6\sigma_d$ |
|------------|---|-----------------|----------|-----------------|-------------|
| $\Gamma_1$ | 4 | 1 | 0 | 0 | 2 |
| $A_1$ | 1 | 1 | 1 | 1 | 1 |
... | {
"Header 1": "Answers to Exercises",
"Header 3": "**4.10 a.** $\\Gamma_1 = A_1 + T_2$ :",
"token_count": 1939,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
With 4 atoms in the molecule, 3N = 12, so there are 3N degrees of freedom in the ammonia molecule.
- **d.** All the vibrational modes are IR active (all have x, y, or z symmetry).
- **4.13** Taking only the C—O stretching modes for Mn(CO)<sub>5</sub> Cl (only the vectors between the C and O atoms):
| OC- |... | {
"Header 1": "Answers to Exercises",
"Header 3": "**4.10 a.** $\\Gamma_1 = A_1 + T_2$ :",
"token_count": 819,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
- **5.2** In Figure 5.3 , (a), s\* is s*u* , s is s*g* , p\* is p*g* , p is p*u* , d\* is d*u* , and d is d*g* .
- **5.3** Bonding in the OH- ion.
The energy match of the H 1 *s* and the O 2 *p* orbitals is fairly good, but that of the H 1s with the O 2 *s... | {
"Header 1": "Answers to Exercises",
"Header 3": "**Chapter 5**",
"token_count": 208,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
5.5 Group orbital 1: Every operation in the $D_{2h}$ point group transforms the orbital into one identical to the original, so the character for each operation is 1, matching the top $(A_g)$ row in the character table.
Group orbital 2: Each operation that transforms this orbital int... | {
"Header 1": "Answers to Exercises",
"Header 3": "**5.4** $H_3^+$ energy levels.",
"token_count": 633,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
**5.9** Using $H_b$ as defined in the Figure 5.29 coordinate system:
| Original Orbital | Е | $C_3$ | $C_3^2$ | $\sigma_{v(a)}$ | $\sigma_{v(b)}$ | $\sigma_{v(c)}$ |
|------------------------|-------|-------|---------|-----------------|-----------------|-----------------|
| ... | {
"Header 1": "Answers to Exercises",
"Header 3": "**5.8** BeH<sub>2</sub> molecular orbitals.",
"token_count": 2030,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
5.12 SOCl<sub>2</sub> has only a mirror plane and belongs to group $C_s$ . Using s orbitals on O and the two Cls, we can obtain the reducible representation and its irreducible components shown in the table.
| $C_s$ | Е | $\sigma_h$ | | |
|-------|---|------------|-------... | {
"Header 1": "Answers to Exercises",
"Header 3": "**5.8** BeH<sub>2</sub> molecular orbitals.",
"token_count": 254,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
**6.1** $pK_{\text{ion}} = 34.4 \text{ (Table 6.2)}$ $K_{\text{ion}} = [\text{CH}_3\text{CHN}^+][\text{CH}_2\text{CN}^-] = 10^{-34.4}$
Because $[CH_3CHN^+] = [CH_2CN^-]$ : $[CH_3CHN^+]^2 = 10^{-34.4}$
$$[CH_3CHN^+] = 10^{-17.2} = 6.3 \times 10^{-18} \, mol \, L^{-1}$$
- 6.2 If $C_6H_6$ is the stronger Brøn... | {
"Header 1": "Answers to Exercises",
"Header 3": "Chapter 6",
"token_count": 2034,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Therefore,
$$\chi = \frac{> 10.1 + 2.3}{2} > 6.2 \quad \eta = \frac{> 10.1 - 2.3}{2} > 3.9$$
**c.** $H_2O$ has I = 12.6 and A = -6.4. Therefore,
$$\chi = \frac{12.6 + (-6.4)}{2} = 3.1 \quad \eta = \frac{12.6 - (-6.4)}{2} = 9.5$$
NH<sub>3</sub> has I = 10.7 and A = -5.6. Therefore,
$$\chi = \frac{10.7 + (-5.... | {
"Header 1": "Answers to Exercises",
"Header 3": "Chapter 6",
"token_count": 1191,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
- 7.1 a. Atom or ion in the center of the cell = 1
8 atoms or ions at the corners of the cell, each ½ within the cell = 1 Total = 2 atoms or ions per unit cell
- **b.** Eight atoms at the corners of the cell, four of which are $\frac{1}{12}$ $\left(\frac{1}{2} \times \frac{1}{6}\right)$ in the cell and four of whic... | {
"Header 1": "Answers to Exercises",
"Header 3": "**Chapter 7**",
"token_count": 2009,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
$$HNO_2 \xrightarrow{0.996} NO$$
$$nE^{0} = (-1)(0.996 \text{ V}) = -0.996 \text{ V}$$
NO is 0.996 V lower than HNO<sub>2</sub>.
The Frost diagram point for $HNO_2$ is (3, 4.36 V).
$$N_2O_4 \xrightarrow{1.07} HNO_2$$
$$nE^{0} = (-1)(1.07 \text{ V}) = -1.07 \text{ V}$$
$HNO_2$ is 1.07 V lower than $N_2... | {
"Header 1": "Answers to Exercises",
"Header 3": "**Chapter 7**",
"token_count": 1958,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
$$E^{0} = 1.11 + (-0.646) = 0.464 \text{ V for } 2NH_{4}^{+} + 2NO_{3}^{-} \longrightarrow 2N_{2}O + 4H_{2}O.$$
$$\Delta G^{\circ} = -nFE^{\circ} = -(8 \text{ moles e}^{-})(96485 \frac{\text{C}}{\text{mol e}^{-}})(0.464 \text{ V}) = -360 \text{ kJ}$$
On the basis of its positive potential and $\Delta G^{o}$ < 0... | {
"Header 1": "Answers to Exercises",
"Header 3": "**Chapter 7**",
"token_count": 413,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
**9.1** a. Triamminetrichlorochromium(III)
**b.** Dichloroethylenediamineplatinum(II)
**c.** Bis(oxalato)platinate(II) or bis(oxalato)platinate(2-)
**d.** Pentaaquabromochromium(III) or pentaaquabromochromium(2+)
e. Tetrachloroethylenediaminecuprate(II) or tetrachloroethylenediaminecuprate(2-)
**f.** Tetrahyd... | {
"Header 1": "Answers to Exercises",
"Header 3": "**Chapter 9**",
"token_count": 311,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
M<aa><bb><cd>M<aa><bc><bd>M<ac><ad><bb><bd>M<ab><cd>M<ab><cd>M<ab><cd>Ab><cd>M<ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab><cd>Ab>... | {
"Header 1": "Answers to Exercises",
"Header 3": "9.3 Ma<sub>2</sub>b<sub>2</sub>cd has eight isomers, including two pairs of enantiomers, according to the method of Section 9.3.4.",
"token_count": 1305,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
7.6 This can be analyzed more easily if it is flipped over, rotating about a horizontal axis in the plane of the paper. The result on the right can be checked for the two rings on the lower front as they relate to the ring across the back. One is $\Lambda$ and one is $\Delta$ :
![]... | {
"Header 1": "Answers to Exercises",
"Header 3": "9.5 This is a $\\Lambda$ configuration:",
"token_count": 396,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
- 10.1 Nitrogen has three electrons in the 2*p* levels, with $m_l = -1$ , 0, +1 and all with $m_s = +\frac{1}{2}$ . $M_S = \frac{1}{2} + \frac{1}{2} + \frac{1}{2} = \frac{3}{2}$ , $M_L = -1 + 0 + 1 = 0$ , so $S = \frac{3}{2}$ and L = 0.
- 10.2 S = n/2, with n the number of unpaired electrons. $4 S(S + 1) = 4(n/2... | {
"Header 1": "Answers to Exercises",
"Header 3": "Chapter 10",
"token_count": 2012,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
| $D_{4h}$ | Е | $2C_4$ | $C_2$ | $2C_2'$ | $2C_2$ " | i | $2S_4$ | $\sigma_h$ | $2\sigma_v$ | $2\sigma_d$ | |
|------------------|---|-------------|-------|---------|----------|---|--------|------------|-------------|-------------|-------------------|
| $\Gamma_{p_{y}}$ | 4 | 0<br>0<br... | {
"Header 1": "Answers to Exercises",
"Header 3": "Chapter 10",
"token_count": 1108,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
$$d_{z^2}, d_{x^2-y^2}$$
total for 2, 3, 4, 5 = 0
$d_{xz}, d_{yz}$ total for 2, 3, 4, 5 = $2e_{\pi}$
$d_{xy}$ total for 2, 3, 4, 5 = $4e_{\pi}$
Ligand $\pi^*$ orbitals increase by $2e_{\pi}$ each.
**10.12** See Table 10.5 for the complete high-spin and low-spin configurations. ... | {
"Header 1": "Answers to Exercises",
"Header 3": "**b.** Adding p :",
"token_count": 982,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
| | | | $M_S$ | |
|-------|----|-----------------------------------------------------... | {
"Header 1": "Answers to Exercises",
"Header 3": "11.1 Microstate table for $d^2$ .",
"token_count": 1985,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
The excited state $t_{2g}{}^3 e_g{}^3$ is subject to Jahn–Teller distortion; consequently, as in the $d^1$ complex $[{\rm Ti}({\rm H}_2{\rm O})_6]^{3+}$ , the absorption band is split.
- 11.8 First assigning transitions, which are to the left of the crossover point of ${}^4A_2$ and ${}^4T_1$ :
$$^4T_1 \longri... | {
"Header 1": "Answers to Exercises",
"Header 3": "11.1 Microstate table for $d^2$ .",
"token_count": 511,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
$$ML_{5}X + Y \xrightarrow[k_{-1}]{k_{1}} ML_{5}XY$$
$$ML_{5}XY \xrightarrow{k_{2}} ML_{5}Y + X$$
Applying the stationary-state approach to ML<sub>5</sub>XY,
$$\frac{d [ML_5XY]}{dt} = k_1 [ML_5X][Y] - k_{-1}[ML_5XY] - k_2[ML_5XY] = 0$$
and [ML<sub>5</sub>XY] =
$$\frac{k_1[\text{ML}_5X][Y]}{k_{-1} + k_2}$$
Fro... | {
"Header 1": "Answers to Exercises",
"Header 3": "Chapter 12",
"token_count": 1559,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
13.1
| | | Met | hod A | Met | hod B |
|----|-----------------------------------------------|-------------------|----------------|--------------|----------------|
| a. | $[Fe(CO)_4]^{2-}$ | Fe <sup>2-... | {
"Header 1": "Answers to Exercises",
"Header 3": "Chapter 13",
"token_count": 1638,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
| M(CO)4 | (M = Ni, Pd) | M | 10 |
|---------------------|------------------------|-----------|----------|
| | | 4 CO | 8<br>18 |
| M(CO)5 | (M = Fe, Ru, Os) | M | 8 |
| | ... | {
"Header 1": "Answers to Exercises",
"Header 3": "Chapter 13",
"token_count": 1003,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
1-Node group orbitals.
13.10
| | | Meth | od A | Meth | nod B |
|----|----------------------------------------------------... | {
"Header 1": "Answers to Exercises",
"Header 3": "**13.9** 2-Node group orbitals.",
"token_count": 1074,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
- **14.1** The *cis* product is one with the labeled CO *cis* to CH<sub>3</sub>. The reverse of Mechanism 1 removes the acetyl <sup>13</sup>CO from the molecule completely, which means that the product should have no <sup>13</sup>CO label at all.
- 14.2 The product distribution for the reaction of cis-CH<sub>3</sub>Mn(... | {
"Header 1": "Answers to Exercises",
"Header 3": "Chapter 14",
"token_count": 609,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
For example,
14.7
$$CH_3$$
$CH_3$ $CH_3$ $CH_3$ $CH_3$ $CH_3$ $CH_3$ $CH_3$ $CH_3$ $CH_4$ $CH_5$ $C_2H_5$ $C_2H_5$ $C_2H_5$ $C_2H_5$ $C_2H_5$ $C_2H_5$ $C_2H_5$ $C_2H_5$ $C_2H_5$ $C_2H_5$ $C_2H_5$ $C_2H_5$ $C_2H_5$ $C_2H_5$ $C_2H_5$ $C_2H_5$ $C_2H_5$ $C_2H_5$ $C_... | {
"Header 1": "Answers to Exercises",
"Header 3": "**b.** Metathesis between propene and cyclopentene:",
"token_count": 2036,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
- 15.1 There are many possible answers. Examples include the following:
- $(\eta^5-C_5H_5)Fe(CO)$ a. Re(CO)<sub>4</sub>
- $[(\eta^5 C_5 H_5) Co]^{2-}$ **b.** $Pt(CO)_3$
- $[(\eta^5 C_5 H_5) Mn(CO)_2]^- (\eta^6 C_6 H_6) Mn(CO)_2$ c. Re(CO)<sub>5</sub>
- 15.2 **a.** This is a 15-electron species with three vacant positi... | {
"Header 1": "Answers to Exercises",
"Header 3": "**Chapter 15**",
"token_count": 1516,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
| $A_1$ | 1 | 1 | 1 | z |
|-------|---|----|----|----------------------|
| $A_2$ | 1 | 1 | -1 | $R_z$ |
| E | 2 | -1 | 0 | $(x, y), (R_x, R_y)$ |
| $C_s$ | E | $\sigma_h$ | | |
|-------|---|------------|---------------|---------------------|
... | {
"Header 1": "1. Groups of Low Symmetry",
"token_count": 280,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
| $C_2$ | E | $C_2$ | | |
|-------|---|-------|------------------|---------------------|
| A | 1 | 1 | $z, R_z$ | $x^2, y^2, z^2, xy$ |
| В | 1 | -1 | $x, y, R_x, R_y$ | yz, xz |
| $C_3$ | E | $C_3$ | $C_3^{\ 2}... | {
"Header 1": "2. $C_{nr}$ , $C_{nvr}$ and $C_{nh}$ Groups $C_n$ Groups",
"token_count": 2006,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
ight.$ | | (yz, xz) |
| $E_2$ | $\begin{cases} 1 \\ 1 \end{cases}$ | -i | $-1 \\ -1$ | 1<br>1 | -1<br>-1 | -i $i$ | -i | $\left. egin{array}{c} -i \\ i \end{array} ight\}$ | | $(x^2-y^2,xy)$ |
| $E_3$ | $\begin{cases} ... | {
"Header 1": "2. $C_{nr}$ , $C_{nvr}$ and $C_{nh}$ Groups $C_n$ Groups",
"token_count": 231,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
| $C_{2\nu}$ | E | $C_2$ | $\sigma_{v}(xz)$ | $\sigma_{v}'(yz)$ | | |
|------------|---|-------|------------------|-------------------|-----------------------------|-----------------|
| $A_1$ | 1 | 1 | 1 | 1 | $z$ $R_z$ $x, R_y$ $y, R_x... | {
"Header 1": "C<sub>nv</sub> Groups",
"token_count": 1184,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
| $C_{2h}$ | E | $C_2$ | i | $\sigma_h$ | | |
|----------|---|-------|----|------------|---------------------|------------------------------|
| $A_g$ | 1 | 1 | 1 | 1 | $R_z$ | $x^2$ , $y^2$ , $z^2$ , $xy$ |
| $B_g$ | 1 | -1 | 1 | -1... | {
"Header 1": "C<sub>nh</sub> Groups",
"token_count": 2032,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
| $D_2$ | E | $C_2(z)$ | | | | |
|-------|---|----------|----|----|----------|--------------------------------------|
| A | 1 | 1 | 1 | 1 | | $x^2$ , $y^2$ , $z^2$ |
| $B_1$ | 1 | 1 | -1 | -1 | $z, R_z$ | $x^{2}, y^{2}, z^{2... | {
"Header 1": "$D_n$ Groups",
"token_count": 1173,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
| $D_{2d}$ | E | $2S_4$ | $C_2$ | $2C_2$ | $2\sigma_d$ | | |
|----------|---|---------|-------|--------|-------------|----------------------|------------------|
| $A_1$ | | 1 | | | | | $x^2 + y^2, z^2$ |
| $A_2$ | 1 | 1<b... | {
"Header 1": "$D_{nd}$ Groups",
"token_count": 2176,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
| $D_{2h}$ | E | $C_2(z)$ | $C_2(y)$ | $C_2(x)$ | i | $\sigma(xy)$ | $\sigma(xz)$ | $\sigma(yz)$ | | |
|----------|---|----------|----------|----------|----|--------------|--------------|--------------|----------------------------|-----------------|
| $A_g$ | 1 | 1 ... | {
"Header 1": "D<sub>nh</sub> Groups",
"token_count": 4149,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
| $C_{\infty y}$ | E | 2C ∞ <sup>φ</sup> | <br>$\infty \sigma_{v}$ | | |
|-----------------------|---|-------------------|-------------------------|----------------------|------------------|
| $A_1 \equiv \Sigma^+$ | 1 | 1 | <br>1 | z ... | {
"Header 1": "4. Linear Groups",
"token_count": 885,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
| $S_4$ | E | $S_4$ | $C_2$ | $S_4^{\ 3}$ | | |
|-------|------------------------------------|-----------|----------|---------------|----------------------|--------------------|
| A | 1 | 1 | 1... | {
"Header 1": "5. $S_{2n}$ Groups",
"token_count": 1054,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
| T | E | 4C <sub>3</sub> | $4C_3^{\ 2}$ | $3C_2$ | | |
|---|------------------------------------|-----------------|---------------------------|----------------|------------------------------|-------------... | {
"Header 1": "6. Tetrahedral, Octahedral, and Icosahedral Groups",
"token_count": 3249,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
| A | trans effect and, 461 | Ammonium nitrate, 288 |
|------------------------------------------------------|------------------------------------------|---------------------------------------------|
| Abel, E. W., 534, 574, 614... | {
"Header 1": "[Index](#page-10-0)",
"token_count": 1904,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
A., 259<br>Argon, 301–302 |
| defined, 170, 171, 184 | bond length, 60 | Aromatic amines, 181 |
| hard and soft, 201–209 | coordinate system for, 152 | Aromatic rings, 3 ... | {
"Header 1": "[Index](#page-10-0)",
"token_count": 1871,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
J., [398 ,](#page-412-0) [433 ,](#page-447-0) [434](#page-448-0) Balmer equation, [11](#page-25-0) Band gap, [230](#page-244-0) Band structure, crystalline solids, [229 – 236](#page-243-0) Band theory, [230 – 231](#page-244-0) Barbier, [477](#page-491-0) Bardeen, J., [237](#page-251-0) Barium, [263](#page-277-0)... | {
"Header 1": "[Index](#page-10-0)",
"token_count": 1613,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
W., [313](#page-327-0) Blomstrand's chain theory, [313 – 314](#page-327-0) Bochman, M., [8 ,](#page-22-0) [309 ,](#page-323-0) [534](#page-548-0) Body-centered cubic crystal, [217 – 218](#page-231-0) B(OH)3, planar, [87](#page-101-0) Bohr atom, [11 – 14](#page-25-0) Bohr, N., [5 ,](#page-19-0) [11](#page-25-0) B... | {
"Header 1": "[Index](#page-10-0)",
"token_count": 2751,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
P. C., 566 | Carbide complexes, 281 – 282 , 518 – 519 | |
| Bravais lattices, 216 | Carbide ligands, 513 , 518 – 519 | CB, 208 – 209 |
| BrF3. See Bromine trifl uoride (BrF3)... | {
"Header 1": "[Index](#page-10-0)",
"token_count": 1365,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
See Reaction mechanisms |
| C—N bond lengths, 48 | Carbon-oxygen electronegativity, 137 – 138 | Chemistry, subfi elds, 4 |
Chiral counterions[, 335](#page-349-0) Chiral fullerenes, [279](#page-293-0) Chiral isomers, [322 ,](#page-336-0) [323 ,](#page-337-0) [335](... | {
"Header 1": "[Index](#page-10-0)",
"token_count": 1838,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
G., [353](#page-367-0) Constitutional isomers, [331 – 334](#page-345-0) Cooper, L., [237](#page-251-0) Cooper pairs, [237 – 238](#page-251-0) Coordinate covalent bonds, [184](#page-198-0) Coordinated ligands, reactions of, [468 – 470](#page-482-0) Coordination chemistry, [313](#page-327-0) bonding, [357 – 402](#... | {
"Header 1": "[Index](#page-10-0)",
"token_count": 1719,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
J., [261](#page-275-0) Cr(CO)6, [483 – 484](#page-497-0) Cristobalite[, 241](#page-255-0) Critical temperature[, 237](#page-251-0) Crown ethers, [262 ,](#page-276-0) [263](#page-277-0) Cryptands, [261 ,](#page-275-0) [262](#page-276-0) Crystal fi eld stabilization energy (CFSE), [364](#page-378-0) Crystal fi eld... | {
"Header 1": "[Index](#page-10-0)",
"token_count": 1910,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
See O <sub>2</sub> | acidity and, 182 |
| Cyclopentadienyl (Cp) complexes, 502–503, | Dioxygenyl, 293 | atomic size and, 60-61 |
| 508-509 ... | {
"Header 1": "[Index](#page-10-0)",
"token_count": 1320,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
M., 374, 398 | evidence for, 357–363 |
| Deprotonation reactions, 178 | | ligand field theory, 363, 365–382 |
| Desnity functional theory (DFT), 396 ... | {
"Header 1": "[Index](#page-10-0)",
"token_count": 1962,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
N., 242 , 244 , 246 , 258 , |
| transition-metal ions, 396 | Fluxional behavior, 341 | 260 , 269 , 270 , 283 , 285 , 289 , 293 , 309 , |
| of transition-metal ions, 376 – 377 | Formal charge, 47 – 49 ... | {
"Header 1": "[Index](#page-10-0)",
"token_count": 2033,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
C., 581 | Hydroxide ion, 172 – 173 |
| bond length, 60 | Hoffmann, R., 131 , 230, 581–588 | Hypervalent atoms, 46 |
| H2Te | Hole formalism, 429 ... | {
"Header 1": "[Index](#page-10-0)",
"token_count": 1185,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
K., 170 |
| HCN, 87 | Hydrochloric acid, 5 , 296 | Inner-sphere reaction, 462 – 466 |
| HCP, 56 | Hydrofl uoric acid, 174 , 296 , 297 | Inorganic chemistry ... | {
"Header 1": "[Index](#page-10-0)",
"token_count": 1783,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
A., 111 | molecular orbitals for octahedral |
| electron affi nity and, 206 | Kinetic chelate effect, 452 | complexes, 365 – 371 |
| electronegativity and atomic siz... | {
"Header 1": "[Index](#page-10-0)",
"token_count": 1080,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
See Linear combinations of atomic | hydride complexes, 495 – 496 |
| hydrate, 331 – 332 | orbitals (LCAO) | modifi cation of, 550 – 555 |
| ionization, 332 ... | {
"Header 1": "[Index](#page-10-0)",
"token_count": 1558,
"source_pdf": "datasets/websources/biochem/inorganic-chemistry-g-l-miessler-2014.pdf"
} |
Subsets and Splits
No community queries yet
The top public SQL queries from the community will appear here once available.