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int64
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13.4k
1ldolmvvn
chemistry
redox-reactions
oxidation-number
<p>Sum of oxidation states of bromine in bromic acid and perbromic acid is ___________.</p>
[]
null
12
<p>The sum of the oxidation states of bromine in bromic acid (HBrO<sub>3</sub>) and perbromic acid (HBrO<sub>4</sub>) is +12.</p> <p>In bromic acid, the oxidation state of bromine is +5, while in perbromic acid, it is +7. The sum of the oxidation states of bromine in both compounds is (+5) + (+7) = +12.</p>
integer
jee-main-2023-online-1st-february-morning-shift
3,350
1lh29uyl4
chemistry
redox-reactions
oxidation-number
<p>In ammonium - phosphomolybdate, the oxidation state of Mo is + ___________</p>
[]
null
6
In ammonium phosphomolybdate, the compound typically found in the reagent used for the quantitative determination of phosphorus, the molybdenum (Mo) atom is in the +6 oxidation state.
integer
jee-main-2023-online-6th-april-morning-shift
3,353
jaoe38c1lsda2rjf
chemistry
redox-reactions
oxidation-number
<p>In the reaction of potassium dichromate, potassium chloride and sulfuric acid (conc.), the oxidation state of the chromium in the product is $$(+)$$ _________.</p>
[]
null
6
<p>$$\begin{aligned} & \mathrm{K}_2 \mathrm{Cr}_2 \mathrm{O}_7(\mathrm{~s})+4 \mathrm{KCl}(\mathrm{s})+6 \mathrm{H}_2 \mathrm{SO}_4 \text { (conc.) } \\ & \rightarrow 2 \mathrm{CrO}_2 \mathrm{Cl}_2(\mathrm{~g})+6 \mathrm{KHSO}_4+3 \mathrm{H}_2 \mathrm{O} \end{aligned}$$</p> <p>This reaction is called chromyl chloride t...
integer
jee-main-2024-online-31st-january-evening-shift
3,354
jaoe38c1lsfpnil4
chemistry
redox-reactions
oxidation-number
<p>The oxidation number of iron in the compound formed during brown ring test for NO$$_3^-$$ iron is ________.</p>
[]
null
1
<p>$$\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_5(\mathrm{NO})\right]^{2+} \text {, }$$</p> <p>Oxidation no. of $$\mathrm{Fe}=+1$$</p>
integer
jee-main-2024-online-29th-january-evening-shift
3,355
Nc3KC2d3VAtJyLmgZhERW
chemistry
redox-reactions
redox-titration
50 mL of 0.5 M oxalic acid is needed to neutralize 25 mL of sodium hydroxide solution. The amount of NaOH in 50 mL of the given sodium hydroxide solution is -
[{"identifier": "A", "content": "20 g "}, {"identifier": "B", "content": "4 g"}, {"identifier": "C", "content": "80 g"}, {"identifier": "D", "content": "10 g"}]
["B"]
null
<p>The reaction between sodium hydroxide (NaOH) and oxalic acid (H<sub>2</sub>C<sub>2</sub>O<sub>4</sub>) is as follows :</p> <p>$$ \text{H}_2\text{C}_2\text{O}_4 + 2\text{NaOH} \rightarrow \text{Na}_2\text{C}_2\text{O}_4 + 2\text{H}_2\text{O} $$</p> <p>We can see that 1 mole of oxalic acid ($\text{H}_2\text{C}_2\text{...
mcq
jee-main-2019-online-12th-january-morning-slot
3,356
fJgmdZRvqRLiiFd7mUjgy2xukevksjwi
chemistry
redox-reactions
redox-titration
While titrating dilute HCl solution with aqueous NaOH, which of the following will not be required?
[{"identifier": "A", "content": "Pipette and distilled water\n"}, {"identifier": "B", "content": "Clamp and phenolphthalein"}, {"identifier": "C", "content": "Burette and porcelain tile"}, {"identifier": "D", "content": "Bunsen burner and measuring cylinder"}]
["D"]
null
Bunsen Burner and measuring cylinder is not required for titration.
mcq
jee-main-2020-online-2nd-september-morning-slot
3,357
jR6G1U3lIXmR5hprc61klsc56n9
chemistry
redox-reactions
redox-titration
0.4 g mixture of NaOH, Na<sub>2</sub>CO<sub>3</sub> and some inert impurities was first titrated with $${N \over {10}}$$ HCl using phenolphthalein as an indicator, 17.5 mL of HCl was required at the end point. After this methyl orange was added and titrated. 1.5 mL of same HCl was required for the next end point. The w...
[]
null
4
<b>1<sup>st</sup> end point reaction :</b><br><br>$$NaOH + HCl\buildrel {} \over \longrightarrow NaCl + {H_2}O$$<br><br>$$nf = 1$$<br><br>$$NaC{O_3} + HCl\buildrel {} \over \longrightarrow NaHC{O_3}$$<br><br>$$nf = 1$$<br><br>Eq of HCl used $$ = {n_{NaOH}} \times 1 + {n_{N{a_2}C{O_3}}} \times 1$$<br><br>$$17.5 \times...
integer
jee-main-2021-online-25th-february-morning-slot
3,359
1ks1jhofn
chemistry
redox-reactions
redox-titration
10.0 mL of 0.05 M KMnO<sub>4</sub> solution was consumed in a titration with 10.0 mL of given oxalic acid dihydrate solution. The strength of given oxalic acid solution is _________ $$\times$$ 10<sup>$$-$$2</sup> g/L.<br/><br/>(Round off to the nearest integer)
[]
null
1575
n<sub>eq</sub> KMnO<sub>4</sub> = n<sub>eq</sub> H<sub>2</sub>C<sub>2</sub>O<sub>4</sub> . 2H<sub>2</sub>O<br><br>or, $${{10 \times 0.05} \over {1000}} \times 5 = {{10 \times M} \over {1000}} \times 2$$<br><br>$$\therefore$$ Conc. of oxalic acid solution = 0.125 M<br><br>= 0.125 $$\times$$ 125 g/L = 15.75 g/L<br><br>= ...
integer
jee-main-2021-online-27th-july-evening-shift
3,360
1l6rl5zgs
chemistry
redox-reactions
redox-titration
<p>A compound 'X' is a weak acid and it exhibits colour change at pH close to the equivalence point during neutralization of NaOH with $$\mathrm{CH}_{3} \mathrm{COOH}$$. Compound 'X' exists in ionized form in basic medium. The compound 'X' is</p>
[{"identifier": "A", "content": "methyl orange"}, {"identifier": "B", "content": "methyl red"}, {"identifier": "C", "content": "phenolphthalein"}, {"identifier": "D", "content": "erichrome Black T"}]
["C"]
null
Phenolphthalein is weak acid give colour in basic medium.
mcq
jee-main-2022-online-29th-july-evening-shift
3,363
1lduligif
chemistry
redox-reactions
redox-titration
<p>The density of a monobasic strong acid (Molar mass 24.2 g/mol) is 1.21 kg/L. The volume of its solution required for the complete neutralization of 25 mL of 0.24 M NaOH is __________ $$\times$$ 10$$^{-2}$$ mL (Nearest integer)</p>
[]
null
12
$$ \begin{aligned} & \text { millimole of } \mathrm{NaOH}=0.24 \times 25 \\\\ & \therefore \text { millimole of acid }=0.24 \times 25 \\\\ & \Rightarrow \text { mass of acid }=0.24 \times 25 \times 24.2 \mathrm{mg} \\\\ & \text { for pure acid, } \\\\ & \mathrm{V}=\frac{\mathrm{w}}{\mathrm{d}} ;(\mathrm{d}=1.21 \mathrm...
integer
jee-main-2023-online-25th-january-morning-shift
3,364
1lgvv7bnc
chemistry
redox-reactions
redox-titration
<p>In alkaline medium, the reduction of permanganate anion involves a gain of __________ electrons.</p>
[]
null
3
<p>In alkaline medium, the reduction of permanganate anion involves a gain of <strong>3 electrons</strong>.</p> <p>The balanced chemical equation for the reduction of permanganate anion in alkaline medium is:</p> $ \begin{equation} \ce{MnO4^{-}(aq) + 3 e^{-} + 2 H2O(l) -> MnO2(s) + 4 OH^{-}(aq)} \end{equation}$<p>In th...
integer
jee-main-2023-online-10th-april-evening-shift
3,365
1lgys8ty2
chemistry
redox-reactions
redox-titration
<p>Given below are two statements:</p> <p>Statement I : In redox titration, the indicators used are sensitive to change in $$\mathrm{pH}$$ of the solution.</p> <p>Statement II : In acid-base titration, the indicators used are sensitive to change in oxidation potential.</p> <p>In the light of the above statements, choos...
[{"identifier": "A", "content": "Both Statement I and Statement II are incorrect"}, {"identifier": "B", "content": "Statement I is correct but Statement II is incorrect"}, {"identifier": "C", "content": "Statement I is incorrect but Statement II is correct"}, {"identifier": "D", "content": "Both Statement I and Stateme...
["A"]
null
<p>The correct answer is Option A: Both Statement I and Statement II are incorrect.</p> <p>Explanation : </p> <p>In redox titrations, the indicators used are sensitive to a change in oxidation potential, not pH. A redox titration (also called an oxidation-reduction titration) can accurately determine the concentration ...
mcq
jee-main-2023-online-8th-april-evening-shift
3,366
lv0vyra5
chemistry
redox-reactions
redox-titration
<p>Only $$2 \mathrm{~mL}$$ of $$\mathrm{KMnO}_4$$ solution of unknown molarity is required to reach the end point of a titration of $$20 \mathrm{~mL}$$ of oxalic acid $$(2 \mathrm{M})$$ in acidic medium. The molarity of $$\mathrm{KMnO}_4$$ solution should be ________ M.</p>
[]
null
8
<p>$$\begin{aligned} & \mathrm{(M) \times(2) \times(5)=2 \times 20 \times 2} \\ & \mathrm{M=8} \end{aligned} $$</p>
integer
jee-main-2024-online-4th-april-morning-shift
3,367
BsaVZ1wbbWcIJLZwfg3rsa0w2w9jx56tijx
chemistry
redox-reactions
types-of-redox-reactions
An example of a disproportionation reaction is :
[{"identifier": "A", "content": "2NaBr + Cl<sub>2</sub> $$ \\to $$ 2NaCl + Br<sub>2</sub>"}, {"identifier": "B", "content": "2KMnO<sub>4</sub> $$ \\to $$ 2KMnO<sub>4</sub> + MnO<sub>2</sub> + O<sub>2</sub>\n(3) (4)\n"}, {"identifier": "C", "content": "2CuBr $$ \\to $$ CuBr<sub>2</sub> + Cu"}, {"identifier": "D", "cont...
["C"]
null
In disproportionation reaction one element undergoes both oxidation and reduction. <picture><source media="(max-width: 320px)" srcset="https://res.cloudinary.com/dckxllbjy/image/upload/v1734263499/exam_images/tzgva0nvrqfrga5yabmj.webp"><img src="https://res.cloudinary.com/dckxllbjy/image/upload/v1734264671/exam_images/...
mcq
jee-main-2019-online-12th-april-morning-slot
3,368
1l6gqai21
chemistry
redox-reactions
types-of-redox-reactions
<p>Which of the given reactions is not an example of disproportionation reaction?</p>
[{"identifier": "A", "content": "$$2 \\mathrm{H}_{2} \\mathrm{O}_{2} \\rightarrow 2 \\mathrm{H}_{2} \\mathrm{O}+\\mathrm{O}_{2}$$"}, {"identifier": "B", "content": "$$2 \\mathrm{NO}_{2}+\\mathrm{H}_{2} \\mathrm{O} \\rightarrow \\mathrm{HNO}_{3}+\\mathrm{HNO}_{2}$$"}, {"identifier": "C", "content": "$$\\mathrm{MnO}_{4}^...
["C"]
null
$$ \begin{aligned} & 2 \mathrm{H}_2 \overset{-1}{\mathrm{O}_2} \longrightarrow 2 \mathrm{H}_2 \overset{2-}{\mathrm{O}}+\overset{0}{\mathrm{O}_2}: \text { Disproportionation } \\\\ & 2 \overset{+4}{\mathrm{NO}_2}+\mathrm{H}_2 \mathrm{O} \rightarrow \overset{+5}{\mathrm{HNO}_3}+\overset{+3}{\mathrm{HNO}_2} \text { : Disp...
mcq
jee-main-2022-online-26th-july-morning-shift
3,370
1lh27pci2
chemistry
redox-reactions
types-of-redox-reactions
<p>Which of the following options are correct for the reaction</p> <p>$$2\left[\mathrm{Au}(\mathrm{CN})_{2}\right]^{-}(\mathrm{aq})+\mathrm{Zn}(\mathrm{s}) \rightarrow 2 \mathrm{Au}(\mathrm{s})+\left[\mathrm{Zn}(\mathrm{CN})_{4}\right]^{2-}(\mathrm{aq})$$</p> <p>A. Redox reaction</p> <p>B. Displacement reaction</p> <p>...
[{"identifier": "A", "content": "A and B only"}, {"identifier": "B", "content": "C and D only"}, {"identifier": "C", "content": "A only"}, {"identifier": "D", "content": "A and D only"}]
["A"]
null
$2\left[\stackrel{+1}{\mathrm{Au}}(\mathrm{CN})_2\right]^{-}+\stackrel{0}{\mathrm{Z}} \mathrm{n}(\mathrm{s}) \longrightarrow 2 \stackrel{0}{\mathrm{Au}}+\left[\stackrel{+2}{\mathrm{Zn}}(\mathrm{CN})_4\right]^{-2}$<br/><br/>$\mathrm{Zn}$ displaced $\mathrm{Au}^{+}$<br/><br/> Reduction and Oxidation both are taking place...
mcq
jee-main-2023-online-6th-april-morning-shift
3,371
lsblv392
chemistry
redox-reactions
types-of-redox-reactions
Which of the following reactions are disproportionation reactions?<br/><br/> (A) $\mathrm{Cu}^{+} \rightarrow \mathrm{Cu}^{2+}+\mathrm{Cu}$<br/><br/> (B) $3 \mathrm{MnO}_4^{2-}+4 \mathrm{H}^{+} \longrightarrow 2 <br/><br/>\mathrm{MnO}_4^{-}+\mathrm{MnO}_2+2 \mathrm{H}_2 \mathrm{O}$<br/><br/> (C) $2 \mathrm{KMnO}_4 \lon...
[{"identifier": "A", "content": "(A), (B)"}, {"identifier": "B", "content": "(A), (D)"}, {"identifier": "C", "content": "(B), (C), (D)"}, {"identifier": "D", "content": "(A), (B), (C)"}]
["A"]
null
<p>A disproportionation reaction is a chemical reaction in which a single substance is simultaneously reduced and oxidized, forming two different products. To identify disproportionation reactions, one should look for a specified element in the reactant that gains electrons (reduction) and for the same element that los...
mcq
jee-main-2024-online-1st-february-morning-shift
3,372
1lsg8687o
chemistry
redox-reactions
types-of-redox-reactions
<p>Total number of species from the following which can undergo disproportionation reaction is ________.</p> <p>$$\mathrm{H}_2 \mathrm{O}_2, \mathrm{ClO}_3^{-}, \mathrm{P}_4, \mathrm{Cl}_2, \mathrm{Ag}, \mathrm{Cu}^{+1}, \mathrm{~F}_2, \mathrm{NO}_2, \mathrm{K}^{+}$$</p>
[]
null
6
<p>Intermediate oxidation state of element can undergo disproportionation.</p> <p>$$\mathrm{H}_2 \mathrm{O}_2, \mathrm{ClO}_3^{-}, \mathrm{P}_4, \mathrm{Cl}_2, \mathrm{Cu}^{+1}, \mathrm{NO}_2$$</p>
integer
jee-main-2024-online-30th-january-evening-shift
3,373
lvb29nmy
chemistry
redox-reactions
types-of-redox-reactions
<p>Match List I with List II.</p> <p><style type="text/css"> .tg {border-collapse:collapse;border-spacing:0;} .tg td{border-color:black;border-style:solid;border-width:1px;font-family:Arial, sans-serif;font-size:14px; overflow:hidden;padding:10px 5px;word-break:normal;} .tg th{border-color:black;border-style:solid;b...
[{"identifier": "A", "content": "(A)-(IV), (B)-(I), (C)-(II), (D)-(III)\n"}, {"identifier": "B", "content": "(A)-(I), (B)-(II), (C)-(III), (D)-(IV)\n"}, {"identifier": "C", "content": "(A)-(II), (B)-(III), (C)-(IV), (D)-(I)\n"}, {"identifier": "D", "content": "(A)-(III), (B)-(II), (C)-(I), (D)-(IV)"}]
["A"]
null
<p>(A) $$\stackrel{\circ}{\mathrm{N}}_2+\stackrel{\circ}{\mathrm{O}}_2 \longrightarrow 2 \mathrm{NO}_{(\mathrm{g})}$$</p> <p>Combination reaction</p> <p>(B) $$2 \mathrm{~Pb}\left(\mathrm{NO}_3\right)_{2(\mathrm{~s})} \longrightarrow 2 \mathrm{PbO}+4 \mathrm{NO}_2+\mathrm{O}_2$$</p> <p>Decomposition reaction</p> <p>(C) ...
mcq
jee-main-2024-online-6th-april-evening-shift
3,374
nZxFpwa9Fg4z9Ugm
chemistry
s-block-elements
compounds-of-alkali-metals
KO<sub>2</sub> (potassium super oxide) is used in oxygen cylinders in space and submarines because it :
[{"identifier": "A", "content": "absorbs CO<sub>2</sub> and increases O<sub>2</sub> content"}, {"identifier": "B", "content": "eliminates moisture"}, {"identifier": "C", "content": "absorbs CO<sub>2</sub>"}, {"identifier": "D", "content": "produces ozone"}]
["A"]
null
$$2K{O_2} + 2{H_2}O$$ <br><br>$$ \to 2KOH + {H_2}{O_2} + {O_2}$$ <br><br>$$K{O_2}$$ is used as an oxidising agent. It is used as air purifier in space capsules. Submarines and breathing masks as it <b>produces oxygen and removes carbon dioxide.</b>
mcq
aieee-2002
3,375
Qx01cNZKLz1oysG1
chemistry
s-block-elements
compounds-of-alkali-metals
Which of the following on thermal decomposition yields a basic as well as an acidic oxide?
[{"identifier": "A", "content": "NaNO<sub>3</sub>"}, {"identifier": "B", "content": "KClO<sub>3</sub>"}, {"identifier": "C", "content": "CaCO<sub>3</sub>"}, {"identifier": "D", "content": "NH<sub>4</sub>NO<sub>3</sub>"}]
["C"]
null
Calcium carbonate on thermal decomposition gives $$CaO$$ (Basic oxide) and $$C{O_2}$$ (Acidic oxide) <br><br>$$CaC{O_3}\buildrel \Delta \over \longrightarrow \mathop {\,\,\,\,\,CaO\,\,\,\,\,}\limits_{Basic\,\,oxide} + \,\,\mathop {\,\,\,\,C{O_2} \uparrow }\limits_{Acidic\,\,oxide} $$
mcq
aieee-2012
3,376
RLhIav4b1VFGw9o607ijK
chemistry
s-block-elements
compounds-of-alkali-metals
A metal on combustion in excess air forms X. X upon hydrolysis with water yields H<sub>2</sub>O<sub>2</sub> and O<sub>2</sub> along with another product. The metal is :
[{"identifier": "A", "content": "Rb"}, {"identifier": "B", "content": "Mg"}, {"identifier": "C", "content": "Na"}, {"identifier": "D", "content": "Li"}]
["A"]
null
K, Rb and Cs form super oxides on reaction with excess air. <br><br>Rb + O<sub>2</sub> $$ \to $$ RbO<sub>2</sub> <br><br>2RbO<sub>2</sub> + 2H<sub>2</sub>O $$ \to $$ 2RbOH + H<sub>2</sub>O<sub>2</sub> + O<sub>2</sub>$$ \uparrow $$
mcq
jee-main-2019-online-12th-january-morning-slot
3,377
lGXfO6lCgykyXQyZzz3rsa0w2w9jx0w6xqr
chemistry
s-block-elements
compounds-of-alkali-metals
A hydrated solid X on heating initially gives a monohydrated compound Y. Y upon heating above 373 K leads to an anhydrous white powder Z. X and Z, respectively, are :
[{"identifier": "A", "content": "Baking soda and dead burnt plaster.\n"}, {"identifier": "B", "content": "Washing soda and soda ash"}, {"identifier": "C", "content": "Washing soda and dead burnt plaster."}, {"identifier": "D", "content": "Baking soda and soda as. "}]
["B"]
null
<picture><source media="(max-width: 320px)" srcset="https://res.cloudinary.com/dckxllbjy/image/upload/v1734265619/exam_images/yfm0cybutkxeeu1xoxsp.webp"><source media="(max-width: 500px)" srcset="https://res.cloudinary.com/dckxllbjy/image/upload/v1734266416/exam_images/gkkkwg2olxhnuulsazmq.webp"><img src="https://res.c...
mcq
jee-main-2019-online-10th-april-evening-slot
3,378
1krq5w35n
chemistry
s-block-elements
compounds-of-alkali-metals
A s-block element (M) reacts with oxygen to form an oxide of the formula MO<sub>2</sub>. The oxide is pale yellow in colour and paramagnetic. The element (M) is :
[{"identifier": "A", "content": "Mg"}, {"identifier": "B", "content": "Na"}, {"identifier": "C", "content": "Ca"}, {"identifier": "D", "content": "K"}]
["D"]
null
<p>The element (M) is potassium (K). It reacts with O<sub>2</sub> to form KO<sub>2</sub>, which is paramagnetic in nature. All other elements form oxides or peroxides which are diamagnetic in nature.</p> <p><img src="https://app-content.cdn.examgoal.net/fly/@width/image/1l2pnip0g/cb7cf53d-8cbe-4afc-adbd-24047297f128/9e...
mcq
jee-main-2021-online-20th-july-morning-shift
3,380
1krx511ei
chemistry
s-block-elements
compounds-of-alkali-metals
Match List I with List II :<br/><br/><style type="text/css"> .tg {border-collapse:collapse;border-spacing:0;} .tg td{border-color:black;border-style:solid;border-width:1px;font-family:Arial, sans-serif;font-size:14px; overflow:hidden;padding:10px 5px;word-break:normal;} .tg th{border-color:black;border-style:solid;b...
[{"identifier": "A", "content": "(a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)"}, {"identifier": "B", "content": "(a)-(i), (b)-(iii), (c)-(ii), (d)-(iv)"}, {"identifier": "C", "content": "(a)-(iv), (b)-(ii), (c)-(iii), (d)-(i)"}, {"identifier": "D", "content": "(a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)"}]
["A"]
null
(a) CsI salt is poor water soluble due to it's low hydration energy<br><br>(b) NaHCO<sub>3</sub> is used in fire extinguisher<br><br>(c) K is most abundant element in cell fluid<br><br>(d) Li<sub>2</sub>CO<sub>3</sub> decomposes easily due to high covalent character caused by small size Li<sup>+</sup> cation.
mcq
jee-main-2021-online-25th-july-evening-shift
3,381
1ks1gxe6d
chemistry
s-block-elements
compounds-of-alkali-metals
Match List - I with List - II :<br/><br/><style type="text/css"> .tg {border-collapse:collapse;border-spacing:0;} .tg td{border-color:black;border-style:solid;border-width:1px;font-family:Arial, sans-serif;font-size:14px; overflow:hidden;padding:10px 5px;word-break:normal;} .tg th{border-color:black;border-style:sol...
[{"identifier": "A", "content": "(a) - (v), (b) - (i), (c) - (ii), (d) - (iv)"}, {"identifier": "B", "content": "(a) - (v), (b) - (ii), (c) - (iv), (d) - (i)"}, {"identifier": "C", "content": "(a) - (iv), (b) - (iii), (c) - (i), (d) - (ii)"}, {"identifier": "D", "content": "(a) - (v), (b) - (iii), (c) - (ii), (d) - (i)...
["D"]
null
Li makes alloy with Lead to make white metal bearings for motor engines<br><br>Liquid Na metal is used s coolant in fast breeder nuclear reactor<br><br>K is a very absorbent of CO<sub>2</sub><br><br>Cs is used in making photoelectric cell
mcq
jee-main-2021-online-27th-july-evening-shift
3,382
1ktfrglym
chemistry
s-block-elements
compounds-of-alkali-metals
Choose the correct statement from the following :
[{"identifier": "A", "content": "The standard enthalpy of formation for alkali metal bromides becomes less negative on descending the group."}, {"identifier": "B", "content": "The low solubility of CsI in water is due to its high lattice enthalpy."}, {"identifier": "C", "content": "Among the alkali metal halides, LiF i...
["C"]
null
a. Standard enthalpy of formation for alkali metal bromides becomes more negative on descending down the group.<br><br>b. In case of CsI, lattice energy is less, but Cs<sup>+</sup> is having less hydration enthalpy due to which it is less soluble in water.<br><br>c. For alkali metal fluorides, the solubility in water i...
mcq
jee-main-2021-online-27th-august-evening-shift
3,383
1l54ygmwk
chemistry
s-block-elements
compounds-of-alkali-metals
<p>Amongst baking soda, caustic soda and washing soda, carbonate anion is present in :</p>
[{"identifier": "A", "content": "washing soda only."}, {"identifier": "B", "content": "washing soda and caustic soda only."}, {"identifier": "C", "content": "washing soda and baking soda only."}, {"identifier": "D", "content": "baking soda, caustic soda and washing soda. "}]
["A"]
null
<p>Baking soda $$ \to $$ NaHCO<sub>3</sub></p> <p>Washing soda $$ \to $$ Na<sub>2</sub>CO<sub>3</sub>.10H<sub>2</sub>O</p> <p>Caustic soda $$ \to $$ NaOH </p> <p>$$\text{CO}^{-2}_{3} $$ ion is present only in washing soda.</p>
mcq
jee-main-2022-online-29th-june-evening-shift
3,384
1l5bd8vjo
chemistry
s-block-elements
compounds-of-alkali-metals
<p>Which one of the following compounds is used as a chemical in certain type of fire extinguishers?</p>
[{"identifier": "A", "content": "Baking soda"}, {"identifier": "B", "content": "Soda ash"}, {"identifier": "C", "content": "Washing soda"}, {"identifier": "D", "content": "Caustic soda"}]
["A"]
null
Baking soda $$\left(\mathrm{NaHCO}_{3}\right)$$ is used in certain type of fire extinguishers because it decomposes at high temperature to produce $$\mathrm{CO}_{2}$$ which extinguishes fire<br/><br/> $$ 2 \mathrm{NaHCO}_{3}(\mathrm{~s}) \stackrel{\Delta}{\longrightarrow} \mathrm{Na}_{2} \mathrm{CO}_{3}(\mathrm{~s})+\m...
mcq
jee-main-2022-online-24th-june-evening-shift
3,385
1l5w5wxgq
chemistry
s-block-elements
compounds-of-alkali-metals
<p>Correct statement about alkali metal oxides is :</p>
[{"identifier": "A", "content": "peroxides are colored."}, {"identifier": "B", "content": "superoxides are paramagnetic."}, {"identifier": "C", "content": "oxides are paramagnetic."}, {"identifier": "D", "content": "peroxides are both colored and paramagnetic."}]
["B"]
null
The peroxide and oxides of alkali metals are colourless when pure. <br/><br/> Superoxides are paramagnetic while peroxides are diamagnetic. Electronic configuration of $\mathrm{O}_{2}^{2-}$ (peroxide) <br/><br/> $\left(\sigma 1 s^{2}\right)\left(\sigma^{*} 1 s^{2}\right)\left(\sigma 2 s^{2}\right)\left(\sigma^{*} 2 s^{...
mcq
jee-main-2022-online-30th-june-morning-shift
3,386
1l6i51di1
chemistry
s-block-elements
compounds-of-alkali-metals
<p>Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R.</p> <p>Assertion A: $$\mathrm{LiF}$$ is sparingly soluble in water.</p> <p>Reason R: The ionic radius of $$\mathrm{Li}^{+}$$ ion is smallest among its group members, hence has least hydration enthalpy.</p> <p>In the...
[{"identifier": "A", "content": "Both A and R are true and R is the correct explanation of A."}, {"identifier": "B", "content": "Both A and R are true but R is NOT the correct explanation of A."}, {"identifier": "C", "content": "A is true but R is false."}, {"identifier": "D", "content": "A is false but R is true."}]
["C"]
null
LiF is sparingly soluble in water. <br/><br/> The low solubility of LiF in water is due to its high lattice enthalpy (Since $$\mathrm{Li}^{+}$$ and $$\mathrm{F}^{-}$$ are small in size). Also, due to small size of $$\mathrm{Li}^{+}$$, its hydration enthalpy is high. <br/><br/> Hence, Assertion is true but Reason is fal...
mcq
jee-main-2022-online-26th-july-evening-shift
3,387
1ldoi309o
chemistry
s-block-elements
compounds-of-alkali-metals
<p>Match List I with List II :</p> <p><style type="text/css"> .tg {border-collapse:collapse;border-spacing:0;} .tg td{border-color:black;border-style:solid;border-width:1px;font-family:Arial, sans-serif;font-size:14px; overflow:hidden;padding:10px 5px;word-break:normal;} .tg th{border-color:black;border-style:solid;...
[{"identifier": "A", "content": "(A) - III, (B) - IV, (C) - II, (D) - I"}, {"identifier": "B", "content": "(A) - III, (B) - II, (C) - IV, (D) - I"}, {"identifier": "C", "content": "(A) - II, (B) - IV, (C) - I, (D) - III"}, {"identifier": "D", "content": "(A) - I, (B) - IV, (C) - II, (D) - III"}]
["C"]
null
A : Slaked lime $\quad: \mathrm{Ca}(\mathrm{OH})_{2}$ <br/><br/>B : Dead burnt plaster $\quad$: $\mathrm{CaSO}_{4}$ <br/><br/>C : Caustic Soda $\quad$: $\mathrm{NaOH}$ <br/><br/>D : Washing Soda $\quad$: $\mathrm{Na}_{2} \mathrm{CO}_{3} \cdot 10 \mathrm{H}_{2} \mathrm{O}$
mcq
jee-main-2023-online-1st-february-morning-shift
3,389
ldqwpq9c
chemistry
s-block-elements
compounds-of-alkali-metals
Which of the following reaction is correct?
[{"identifier": "A", "content": "$4 \\mathrm{LiNO}_{3} \\stackrel{\\Delta}{\\longrightarrow} 2 \\mathrm{Li}_{2} \\mathrm{O}+4 \\mathrm{NO}_{2}+\\mathrm{O}_{2}$"}, {"identifier": "B", "content": "$2 \\mathrm{LiNO}_{3} \\longrightarrow 2 \\mathrm{Li}+2 \\mathrm{NO}_{2}+\\mathrm{O}_{2}$"}, {"identifier": "C", "content": "...
["A"]
null
<p>$$\mathrm{4LiNO_3}$$ $$\buildrel {\mathrm{Heat}} \over \longrightarrow $$ $$\mathrm{2Li_2O+4NO_2+O_2}$$</p> <p>$$\mathrm{LiNO_3}$$ on heating produces $$\mathrm{Li_2O,NO_2}$$ and $$\mathrm{O_2}$$</p>
mcq
jee-main-2023-online-30th-january-evening-shift
3,390
1ldr4kfao
chemistry
s-block-elements
compounds-of-alkali-metals
<p>Lithium aluminium hydride can be prepared from the reaction of :</p>
[{"identifier": "A", "content": "$$\\mathrm{LiCl}$$ and $$\\mathrm{Al_2H_6}$$"}, {"identifier": "B", "content": "$$\\mathrm{LiH}$$ and $$\\mathrm{Al}(\\mathrm{OH})_{3}$$"}, {"identifier": "C", "content": "$$\\mathrm{LiH}$$ and $$\\mathrm{Al}_{2} \\mathrm{Cl}_{6}$$"}, {"identifier": "D", "content": "$$\\mathrm{LiCl}, \\...
["C"]
null
$$\mathrm{8LiH+Al_2Cl_6\to2LiAlH_4+6LiCl}$$
mcq
jee-main-2023-online-30th-january-morning-shift
3,391
1ldsdx85d
chemistry
s-block-elements
compounds-of-alkali-metals
<p>On heating, $$\mathrm{LiNO_3}$$ gives how many compounds among the following __________</p> <p>$$\mathrm{Li_2O,N_2,O_2,LiNO_2,NO_2}$$</p>
[]
null
3
<p>$$\mathrm{LiNO_3\buildrel \Delta \over \longrightarrow Li_2O+NO_2+O_2}$$</p>
integer
jee-main-2023-online-29th-january-evening-shift
3,392
1lgp305w1
chemistry
s-block-elements
compounds-of-alkali-metals
<p>Identify the correct order of standard enthalpy of formation of sodium halides :</p>
[{"identifier": "A", "content": "$$\\mathrm{NaI}<\\mathrm{NaBr}<\\mathrm{NaCl}<\\mathrm{NaF}$$"}, {"identifier": "B", "content": "$$\\mathrm{NaI}<\\mathrm{NaBr}<\\mathrm{NaF}<\\mathrm{NaCl}$$"}, {"identifier": "C", "content": "$$\\mathrm{NaF}<\\mathrm{NaCl}<\\mathrm{NaBr}<\\mathrm{NaI}$$"}, {"identifier": "D", "content...
["A"]
null
Lattice energy is directly proportional to the charges of the ions and inversely proportional to the sum of their radii: <br/><br/> Lattice energy ∝ (Q₁Q₂) / (r₁ + r₂) <br/><br/> As we move down the group, the size of the halide ions increases, resulting in a decrease in lattice energy. This leads to a decrease in the ...
mcq
jee-main-2023-online-13th-april-evening-shift
3,393
1lguzqkuf
chemistry
s-block-elements
compounds-of-alkali-metals
<p>Match List-I with List-II:</p> <p><style type="text/css"> .tg {border-collapse:collapse;border-spacing:0;} .tg td{border-color:black;border-style:solid;border-width:1px;font-family:Arial, sans-serif;font-size:14px; overflow:hidden;padding:10px 5px;word-break:normal;} .tg th{border-color:black;border-style:solid;b...
[{"identifier": "A", "content": "A-IV, B-III, C-I, D-II"}, {"identifier": "B", "content": "A-III, B-II, C-IV, D-I"}, {"identifier": "C", "content": "A-III, B-IV, C-II, D-I"}, {"identifier": "D", "content": "A-IV, B-I, C-III, D-II"}]
["B"]
null
<p>Let&#39;s consider each item in List-I and match it with an appropriate item from List-II:</p> <p>A. K (Potassium): Potassium ions are crucial for the operation of the sodium-potassium pump in nerve cells. So, A matches with III.</p> <p>B. KCl (Potassium Chloride): Potassium chloride is widely used in agriculture as...
mcq
jee-main-2023-online-11th-april-morning-shift
3,394
1lh321pgm
chemistry
s-block-elements
compounds-of-alkali-metals
<p>The product, which is not obtained during the electrolysis of brine solution is :</p>
[{"identifier": "A", "content": "NaOH"}, {"identifier": "B", "content": "Cl$$_2$$"}, {"identifier": "C", "content": "H$$_2$$"}, {"identifier": "D", "content": "HCl"}]
["D"]
null
<p>The electrolysis of brine, which is a solution of sodium chloride (NaCl) in water, involves the migration of ions towards electrodes. When an electric current is passed through the solution, positive sodium ions ($Na^+$) move towards the cathode (negative electrode), and negative chloride ions ($Cl^-$) move towards ...
mcq
jee-main-2023-online-6th-april-evening-shift
3,396
xmLplKAoWrSvtU2v
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
The metallic sodium disolves in liquid ammonia to form a deep blue coloured solution. The deep blue colour is due to formation of :
[{"identifier": "A", "content": "solvated electron, $$e(NH_3)^-_x$$"}, {"identifier": "B", "content": "solvated atomic sodium, Na(NH<sub>3</sub>)<sub>y</sub>"}, {"identifier": "C", "content": "(Na<sup>+</sup> + Na<sup>-</sup>)"}, {"identifier": "D", "content": "NaNH<sub>2</sub> + H<sub>2</sub>"}]
["A"]
null
The alkali metals dissolve in liquid ammonia without evolution of hydrogen. The metal loses electrons and combine with ammonia molecule. <br><br>$$M \to {M^ + }\,\,$$ (in liquid ammonia) $$\,\, + {E^ - }\,\,$$ (ammoniated) <br><br>$$\,\,M + (x + y)N{H_3}$$ <br><br>$$ \to {\left[ {M{{(N{H_3})}_x}} \right]^ + }\matho...
mcq
aieee-2002
3,398
8uVfBltXqgGofLA4
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
Based on lattice energy and other considerations which one of the following alkali metal chlorides is expected to have the highest melting point :
[{"identifier": "A", "content": "LiCl"}, {"identifier": "B", "content": "NaCl "}, {"identifier": "C", "content": "KCl"}, {"identifier": "D", "content": "RbCl"}]
["B"]
null
$$LiCl$$ has partly covalent character. Other halides are ionic in nature. Lattice energy decreases with increases of ionic radius of cation, anion being the same. Larger is the lattice energy, the higher will be $$m.$$ $$pt.$$ hence $$NaCl$$ will have highest lattice energy.
mcq
aieee-2005
3,399
1nwds6DFEkalJLKm
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
Which of the following atoms has the highest first ionization energy?
[{"identifier": "A", "content": "Na "}, {"identifier": "B", "content": "K"}, {"identifier": "C", "content": "Sc"}, {"identifier": "D", "content": "Rb"}]
["C"]
null
<p>The first ionization energy is the energy required to remove the most loosely held electron from an atom or a cation. It is measured in units of electron volts (eV) or kilojoules per mole (kJ/mol).</p> <p>Among the given options, Scandium (Sc) has the highest first ionization energy because it has the smallest atom...
mcq
jee-main-2016-offline
3,401
nMDPHAX75JenhSDN
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
The main oxides formed on combustion of Li, Na and K in excess of air are, respectively :
[{"identifier": "A", "content": "LiO<sub>2</sub>, Na<sub>2</sub>O<sub>2</sub> and K<sub>2</sub>O"}, {"identifier": "B", "content": "Li<sub>2</sub>O<sub>2</sub>, Na<sub>2</sub>O<sub>2</sub> and KO<sub>2</sub>"}, {"identifier": "C", "content": "Li<sub>2</sub>O, Na<sub>2</sub>O<sub>2</sub> and KO<sub>2</sub>"}, {"identifi...
["C"]
null
On heating with excess of air $$Li,$$ $$Na$$ and $$K$$ forms following oxides <br><br>$$4Li + {O_2}\,\,\buildrel \, \over \longrightarrow \,\,\mathop {2L{i_2}O\,\,\,\,\,\,\,\,\,\,}\limits_{Lithium\,\,\,\,monoxide} \,$$ <br><br>$$2Na + {O_2}\,\,\buildrel {575\,\,K} \over \longrightarrow \,\,\mathop {N{a_2}{O_2}\,\,\...
mcq
jee-main-2016-offline
3,402
TgDdM2mmeRLD5wAgr65Ee
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
The metal that forms nitride by reacting directly with N<sub>2</sub> of air, is :
[{"identifier": "A", "content": "K"}, {"identifier": "B", "content": "Li"}, {"identifier": "C", "content": "Rb"}, {"identifier": "D", "content": "Cs"}]
["B"]
null
Only Li react directly with N<sub>2</sub> out of alkali metals <br><br>6 Li + N<sub>2</sub> $$ \to $$ 2Li<sub>3</sub>N
mcq
jee-main-2019-online-9th-january-evening-slot
3,404
3fIvRcFOUr7RdzK3xtdhl
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
Sodium metal on dissolution in liquid ammonia gives a deep blue solution due to the formation of :
[{"identifier": "A", "content": "ammoniated electrons "}, {"identifier": "B", "content": "sodamide \n"}, {"identifier": "C", "content": "sodium-ammonia complex "}, {"identifier": "D", "content": "sodium ion-ammonia complex "}]
["A"]
null
Na + (x + y)NH<sub>3</sub>($$l$$) $$ \to $$ [Na(NH<sub>3</sub>)<sub>x</sub>]<sup>+</sup> + [e(NH<sub>3</sub>)<sub>y</sub>]<sup>-</sup> <br><br>[e(NH<sub>3</sub>)<sub>y</sub>]<sup>-</sup> is called solvated or ammoniated electron.
mcq
jee-main-2019-online-10th-january-evening-slot
3,405
8pFtw7Curi3b8lhQbQxiK
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
The correct order of hydration enthapies of alkali metal ions is :
[{"identifier": "A", "content": "Li<sup>+</sup> &gt; Na<sup>+</sup> &gt; Cs<sup>+</sup> &gt; Rb<sup>+</sup>"}, {"identifier": "B", "content": "Na<sup>+</sup> &gt; Li<sup>+</sup> &gt; K<sup>+</sup> &gt; Cs<sup>+</sup> &gt; Rb<sup>+</sup>"}, {"identifier": "C", "content": "Na<sup>+</sup> &gt; Li<sup>+</sup> &gt; K<sup>+<...
["D"]
null
Hydration energy/enthalpy $$ \propto $$ $${{ch\arg e} \over {size}}$$ <br><br>$$ \therefore $$ Smaller the size more is hydration energy. <br><br>Li<sup>+</sup> having minimum radius so maximum hydration energy. <br><br>Correct order is : <br><br>Li<sup>+</sup> &gt; Na<sup>+</sup> &gt; K<sup>+</sup> &gt; Rb<sup>+</sup>...
mcq
jee-main-2019-online-8th-april-morning-slot
3,406
Md7RnupcKQ9LHk4fmu3rsa0w2w9jx84cpe7
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
The INCORRECT statement is :
[{"identifier": "A", "content": "Lithium is least reactive with water among the alkali metals"}, {"identifier": "B", "content": "LiCl crystallises from aqueous solution as LiCl.2H<sub>2</sub>O"}, {"identifier": "C", "content": "Lithium is the strongest reducing agent among the alkali metals"}, {"identifier": "D", "cont...
["D"]
null
LiNO<sub>3</sub> $$\buildrel \Delta \over \longrightarrow $$ Li<sub>2</sub>O + NO<sub>2</sub> + O<sub>2</sub> <br><br>Ionic potential of Li is high that is why on thermal demoposition of nitrate form of Li will give oxide of Li and NO<sub>2</sub> and O<sub>2</sub>.
mcq
jee-main-2019-online-12th-april-evening-slot
3,407
S59yV4Qjk0ZGs6Qcydjgy2xukevm4nda
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
The metal mainly used in devising photoelectric cells is :
[{"identifier": "A", "content": "Na"}, {"identifier": "B", "content": "Rb"}, {"identifier": "C", "content": "Li"}, {"identifier": "D", "content": "Cs"}]
["D"]
null
Cs has least work function value because of less electronegativity thats why it is used in photoelectric cells.
mcq
jee-main-2020-online-2nd-september-morning-slot
3,409
kG3tUlNLd1J8H7qs8S1kmj7fogs
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
The correct order of conductivity of ions in water is :
[{"identifier": "A", "content": "K<sup>+</sup> &gt; Na<sup>+</sup> &gt; Cs<sup>+</sup> &gt; Rb<sup>+</sup>"}, {"identifier": "B", "content": "Cs<sup>+</sup> &gt; Rb<sup>+</sup> &gt; K<sup>+</sup> &gt; Na<sup>+</sup>"}, {"identifier": "C", "content": "Na<sup>+</sup> &gt; K<sup>+</sup> &gt; Rb<sup>+</sup> &gt; Cs<sup>+</...
["B"]
null
As the size of gaseous ion decreases, it get more hydrated in water and hence, the size of aqueous ion increases. When this bulky ion move in solution, it experience greater resistance and hence lower conductivity.
mcq
jee-main-2021-online-17th-march-morning-shift
3,412
1krz1p5wh
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
Given below are two statements : One is labelled as Assertion A and the other labelled as Reason R.<br/><br/>Assertion A : Lithium halides are some what covalent in nature.<br/><br/>Reason R : Lithium posses high polarisation capability.<br/><br/>In the light of the above statements, choose the most appropriate answer ...
[{"identifier": "A", "content": "A is true but R is false"}, {"identifier": "B", "content": "A is false but R is true"}, {"identifier": "C", "content": "Both A and R are true but R is NOT the correct explanation of A"}, {"identifier": "D", "content": "Both A and R are true and R is the correct explanation of A"}]
["D"]
null
Lithium due to small size has very high polarization capability and thus increases covalent nature of Halides.
mcq
jee-main-2021-online-27th-july-morning-shift
3,413
1ktjvo52s
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). <br/><br/>Assertion (A) : Lithium salts are hydrated.<br/><br/>Reason (R) : Lithium has higher polarising power than other alkali metal group members.<br/><br/>In the light of the above statements, choose the most...
[{"identifier": "A", "content": "Both (A) and (R) are correct but (R) is not the correct explanation of (A)"}, {"identifier": "B", "content": "(A) is correct but (R) is not correct."}, {"identifier": "C", "content": "(A) is not correct but (R) is correct."}, {"identifier": "D", "content": "Both (A) and (R) are correct ...
["A"]
null
Lithium salts are hydrated due to high hydration energy of Li<sup>+</sup><br><br>Li<sup>+</sup> due to smallest size in IA group has highest polarizing power.
mcq
jee-main-2021-online-31st-august-evening-shift
3,414
1l548jryc
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
<p>Arrange the following in the decreasing order of their covalent character :</p> <p>(A) LiCl</p> <p>(B) NaCl</p> <p>(C) KCl</p> <p>(D) CsCl</p> <p>Choose the most appropriate answer from the options given below :</p>
[{"identifier": "A", "content": "(A) > (C) > (B) > (D)"}, {"identifier": "B", "content": "(B) > (A) > (C) > (D)"}, {"identifier": "C", "content": "(A) > (B) > (C) > (D)"}, {"identifier": "D", "content": "(A) > (B) > (D) > (C)"}]
["C"]
null
Covalent character $$ \propto $$ polarising power of cation<br/><br/> Correct decreasing order of covalent character<br/><br/> LiCl > NaCl > KCl > CsCl
mcq
jee-main-2022-online-29th-june-morning-shift
3,415
1l549ceo4
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
<p>Match List-I with List-II</p> <p><style type="text/css"> .tg {border-collapse:collapse;border-spacing:0;} .tg td{border-color:black;border-style:solid;border-width:1px;font-family:Arial, sans-serif;font-size:14px; overflow:hidden;padding:10px 5px;word-break:normal;} .tg th{border-color:black;border-style:solid;bo...
[{"identifier": "A", "content": "(A)-(I), (B)-(II), (C)-(III), (D)-(IV)"}, {"identifier": "B", "content": "(A)-(III), (B)-(II), (C)-(I), (D)-(IV)"}, {"identifier": "C", "content": "(A)-(III), (B)-(I), (C)-(II), (D)-(IV)"}, {"identifier": "D", "content": "(A)-(IV), (B)-(II), (C)-(I), (D)-(III)"}]
["A"]
null
<img src="https://app-content.cdn.examgoal.net/fly/@width/image/1l5itvxgl/85123a1a-1c60-4f89-ae17-a908bdc5c880/af37e550-023d-11ed-82d2-afb4f8196e66/file-1l5itvxgm.png?format=png" data-orsrc="https://app-content.cdn.examgoal.net/image/1l5itvxgl/85123a1a-1c60-4f89-ae17-a908bdc5c880/af37e550-023d-11ed-82d2-afb4f8196e66/fi...
mcq
jee-main-2022-online-29th-june-morning-shift
3,416
1l5bd7ybh
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
<p>In the industrial production of which of the following, molecular hydrogen is obtained as a byproduct?</p>
[{"identifier": "A", "content": "NaOH"}, {"identifier": "B", "content": "NaCl"}, {"identifier": "C", "content": "Na metal"}, {"identifier": "D", "content": "Na<sub>2</sub>CO<sub>3</sub>"}]
["A"]
null
Molecular hydrogen is produced as a byproduct in the industrial production of $$\mathrm{NaOH}$$ by electrolysis of aq $$\mathrm{NaCl}$$ solution<br/><br/> $$ \mathrm{NaCl} \rightarrow \mathrm{Na}^{+}+\mathrm{Cl}^{-} $$<br/><br/> $$ \begin{aligned} & \mathrm{H}_{2} \mathrm{O} \rightleftharpoons \mathrm{H^{+}}+\mathrm{OH...
mcq
jee-main-2022-online-24th-june-evening-shift
3,417
1l5c6ksxr
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
<p>Which of the following statements are correct?</p> <p>(A) Both LiCl and MgCl<sub>2</sub> are soluble in ethanol.</p> <p>(B) The oxides Li<sub>2</sub>O and MgO combine with excess of oxygen to give superoxide.</p> <p>(C) LiF is less soluble in water than other alkali metal fluorides.</p> <p>(D) Li<sub>2</sub>O is mor...
[{"identifier": "A", "content": "(A) and (C) only"}, {"identifier": "B", "content": "(A), (C) and (D) only"}, {"identifier": "C", "content": "(B) and (C) only"}, {"identifier": "D", "content": "(A) and (D) only"}]
["A"]
null
(A) Both LiCl and MgCl<sub>2</sub> are soluble in ethanol<br/><br/> (B) Li and Mg do not form superoxide<br/><br/> (C) LiF has high lattice energy<br/><br/> (D) Li<sub>2</sub>O is least soluble in water than another alkali metal oxides
mcq
jee-main-2022-online-24th-june-morning-shift
3,418
1l6e18lqx
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
<p>Choose the correct order of density of the alkali metals :</p>
[{"identifier": "A", "content": "Li < K < Na < Rb < Cs"}, {"identifier": "B", "content": "Li < Na < K < Rb < Cs"}, {"identifier": "C", "content": "Cs < Rb < K < Na < Li"}, {"identifier": "D", "content": "Li < Na < K < Cs < Rb"}]
["A"]
null
The increasing order of density of alkali metals as <br/><br/> $$ \underset{0.53}{\mathrm{Li}}<\underset{0.86}{\mathrm{~K}}<\underset{0.97}{\mathrm{Na}}<\underset{1.53}{\mathrm{Rb}}<\underset{1.87}{\mathrm{Cs}} \quad\text { (in } \mathrm{g}{/ \mathrm{dm}^{3} \text { ) }} $$ <br/><br/> ' $\mathrm{K}$ ' metal has less de...
mcq
jee-main-2022-online-25th-july-morning-shift
3,419
1l6mcnw4r
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
<p>Which of the following statement is <b>incorrect</b>?</p>
[{"identifier": "A", "content": "Low solubility of LiF in water is due to its small hydration enthalpy."}, {"identifier": "B", "content": "$$\\mathrm{KO}_{2}$$ is paramagnetic."}, {"identifier": "C", "content": "Solution of sodium in liquid ammonia is conducting in nature."}, {"identifier": "D", "content": "Sodium meta...
["A"]
null
Low solubility of LiF in water is due to the fact that though $\mathrm{Li}^{+}$ is having high hydration enthalpy but it has higher lattice enthalpy when present in LiF. Due to higher lattice enthalpy its solubility is less.
mcq
jee-main-2022-online-28th-july-morning-shift
3,420
ldo9ucsk
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
The number of alkali metal(s), from $\mathrm{Li}, \mathrm{K}, \mathrm{Cs}$, Rb having ionization enthalpy greater than $400 \mathrm{~kJ}$ $\mathrm{mol}^{-1}$ and forming stable super oxide is _____________.
[]
null
2
<img src="https://app-content.cdn.examgoal.net/fly/@width/image/1lecssgjd/16d9b562-4c48-4482-adcb-e3b645d7f48b/a41a5a90-b11a-11ed-8d19-c1418e0c6b67/file-1lecssgje.png?format=png" data-orsrc="https://app-content.cdn.examgoal.net/image/1lecssgjd/16d9b562-4c48-4482-adcb-e3b645d7f48b/a41a5a90-b11a-11ed-8d19-c1418e0c6b67/fi...
integer
jee-main-2023-online-31st-january-evening-shift
3,421
1ldu04kqa
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
<p>Which one among the following metals is the weakest reducing agent?</p>
[{"identifier": "A", "content": "K"}, {"identifier": "B", "content": "Na"}, {"identifier": "C", "content": "Li"}, {"identifier": "D", "content": "Rb"}]
["B"]
null
Sodium has the lowest oxidation potential in alkali metals. Hence it is the weakest reducing agent among alkali metals.
mcq
jee-main-2023-online-25th-january-evening-shift
3,422
1ldu1d2x5
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
<p>Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R</p> <p>Assertion A : The alkali metals and their salts impart characteristic colour to reducing flame.</p> <p>Reason R : Alkali metals can be detected using flame tests.</p> <p>In the light of the above statements, c...
[{"identifier": "A", "content": "A is not correct but R is correct"}, {"identifier": "B", "content": "A is correct but R is not correct"}, {"identifier": "C", "content": "Both A and R are correct and R is the correct explanation of A"}, {"identifier": "D", "content": "Both A and R are correct but R is NOT the correct e...
["A"]
null
Assertion is not correct because alkali metals and their salts impart characteristic colour to oxidising part of flame and not reducing part of flame. Reason is correct because all alkali metals can be detected by their flame tests.
mcq
jee-main-2023-online-25th-january-evening-shift
3,423
1ldwv6nx1
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
<p>Identify the correct statements about alkali metals.</p> <p>A. The order of standard reduction potential (M$$^+$$ | M) for alkali metal ions is Na &gt; Rb &gt; Li.</p> <p>B. CsI is highly soluble in water.</p> <p>C. Lithium carbonate is highly stable to heat.</p> <p>D. Potassium dissolved in concentrated liquid am...
[{"identifier": "A", "content": "C and E only"}, {"identifier": "B", "content": "A and E only"}, {"identifier": "C", "content": "A, B, D only"}, {"identifier": "D", "content": "A, B and E only"}]
["B"]
null
A. The order of standard reduction potential (M<sup>+</sup> | M) for alkali metal ions is Na > Rb > Li. This statement is correct. The standard reduction potential generally increases as we move down the group from Li to Cs so order should be Cs > Rb > K > Na > Li but here Na and K are exception, Na has highest standar...
mcq
jee-main-2023-online-24th-january-evening-shift
3,424
1lgrk21qp
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
<p>The density of alkali metals is in the order :</p>
[{"identifier": "A", "content": "$$\\mathrm{Na}<\\mathrm{K}<\\mathrm{Cs}<\\mathrm{Rb}$$"}, {"identifier": "B", "content": "$$\\mathrm{K}<\\mathrm{Na}<\\mathrm{Rb}<\\mathrm{Cs}$$"}, {"identifier": "C", "content": "$$\\mathrm{K}<\\mathrm{Cs}<\\mathrm{Na}<\\mathrm{Rb}$$"}, {"identifier": "D", "content": "$$\\mathrm{Na}<\\...
["B"]
null
<p>Alkali metals are part of Group 1 on the periodic table and include lithium (Li), sodium (Na), potassium (K), rubidium (Rb), and cesium (Cs). As you move down the group, the atomic radius increases due to the addition of energy levels (shells). While you might think that the increased atomic mass would correspond to...
mcq
jee-main-2023-online-12th-april-morning-shift
3,425
1lgyrlw06
chemistry
s-block-elements
physiochemical-trends-in-alkali-metals
<p>Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R.</p> <p>Assertion A : Sodium is about 30 times as abundant as potassium in the oceans.</p> <p>Reason R : Potassium is bigger in size than sodium.</p> <p>In the light of the above statements, choose the correct answer...
[{"identifier": "A", "content": "Both A and R are true but R is NOT the correct explanation of A"}, {"identifier": "B", "content": "A is false but R is true"}, {"identifier": "C", "content": "Both A and R are true and R is the correct explanation of A"}, {"identifier": "D", "content": "A is true but R is false"}]
["C"]
null
Due to bigger size of potassium, it forms more efficient lattices as compared to sodium with silicates.<br/><br/> The abundance of sodium in ocean is more due to the more soluble nature of salt of sodium as compared to potassium salts.
mcq
jee-main-2023-online-8th-april-evening-shift
3,427
m7DFC0V1q3ppedgi
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
A metal M readily forms its sulphate MSO<sub>4</sub>, which is water-soluble. It forms its oxide MO which becomes inert on heating. It forms an insoluble hydroxide M(OH)<sub>2</sub> which is soluble in NaOH solution. The M is :
[{"identifier": "A", "content": "Mg"}, {"identifier": "B", "content": "Ba"}, {"identifier": "C", "content": "Ca"}, {"identifier": "D", "content": "Be"}]
["D"]
null
Sulphate of alkaline earth metal are sparingly soluble or almost not soluble in water whereas $$BeS{O_4}$$ is soluble in water due to high degree of solvation. $$Be{\left( {OH} \right)_2}$$ is insoluble in water but soluble in $$NaOH.$$ <br><br>$$BeO + 2NaOH\,\,$$ $$ \to \,\,N{a_2}Be{O_2} + {H_2}O$$
mcq
aieee-2002
3,428
CkTPci39C0Xfl6Cj
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
One mole of magnesium nitride on the reaction with an excess of water gives :
[{"identifier": "A", "content": "one mole of ammonia"}, {"identifier": "B", "content": "two moles of nitric acid "}, {"identifier": "C", "content": "two moles of ammonia "}, {"identifier": "D", "content": "one mole of nitric acid "}]
["C"]
null
$$M{g_3}{N_2} + 6{H_2}O\,\,\rightleftharpoons\,\,3Mg{\left( {OH} \right)_2} + 2N{H_3}$$
mcq
aieee-2004
3,430
K4eHcbFTKpsFqwfS
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
The metal that cannot be obtained by electrolysis of an aqueous solution of its salts is :
[{"identifier": "A", "content": "Cu"}, {"identifier": "B", "content": "Cr"}, {"identifier": "C", "content": "Ag"}, {"identifier": "D", "content": "Ca"}]
["D"]
null
On electrolysis of aqueous solution of $$s$$-block elements $${H_2}$$ gas discharge at cathode. <br><br>At cathode: $${H_2}O + {e^ - } \to {1 \over 2}{H_2} + O{H^ - }$$
mcq
jee-main-2014-offline
3,431
NXhbC551v5SSKO0F
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
Which one of the following alkaline earth metal sulphates has its hydration enthalpy greater than its lattice enthalpy?
[{"identifier": "A", "content": "BeSO<sub>4</sub>"}, {"identifier": "B", "content": "BaSO<sub>4</sub>"}, {"identifier": "C", "content": "SrSO<sub>4</sub>"}, {"identifier": "D", "content": "CaSO<sub>4</sub>"}]
["A"]
null
In alkaline earth metals, ionic size increases down the group. The lattice energy remains constant because sulphate ion is so large, so that small change in cationic size does not make any difference. On moving down the group the degree of hydration of metal ions decreases very much leading to decrease in solubility. ...
mcq
jee-main-2015-offline
3,432
6b7YOR8lcPINC5urSqZaJ
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
The correct order of the solubility of alkaline-earth metal sulphates in water is :
[{"identifier": "A", "content": "Mg &lt; Ca &lt; Sr &lt; Ba"}, {"identifier": "B", "content": "Mg &lt; Sr &lt; Ca &lt; Ba"}, {"identifier": "C", "content": "Mg &gt; Sr &gt; Ca &gt; Ba"}, {"identifier": "D", "content": "Mg &gt; Ca &gt; Sr &gt; Ba"}]
["D"]
null
The solubility of the sulphates in water decreases down the group. Mg > Ca > Sr > Ba. MgSO<sub>4</sub> is soluble, but CaSO<sub>4</sub> is sparingly soluble, and the sulphates of Sr, Ba and Ra are virtually insoluble. The significantly high solubility of MgSO4 is due to the high enthalpy of solvation of the smaller Mg...
mcq
jee-main-2016-online-9th-april-morning-slot
3,433
7OQbAyzGvzLVaGmi
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
Both lithium and magnesium display several similar properties due to the diagonal relationship; however, the one which is incorrect, is :
[{"identifier": "A", "content": "both form soluble bicarbonates"}, {"identifier": "B", "content": "both from nitrides\n"}, {"identifier": "C", "content": "nitrates of both Li and Mg yield NO<sub>2</sub> and O<sub>2</sub> on heating "}, {"identifier": "D", "content": "both form basic carbonates "}]
["D"]
null
Mg can form basic carbonate like <br><br>3MgCO<sub>3</sub> . Mg(OH)<sub>2</sub> . 3H<sub>2</sub>O <br><br>While Li can not.
mcq
jee-main-2017-offline
3,434
g3MNTjqnsbi5rUXXP13rsa0w2w9jwvclt5n
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
The alloy used in the construction of aircrafts is :
[{"identifier": "A", "content": "Mg \u2013 Zn"}, {"identifier": "B", "content": "Mg \u2013 Al "}, {"identifier": "C", "content": "Mg \u2013 Mn"}, {"identifier": "D", "content": "Mg \u2013 Sn"}]
["B"]
null
An alloy of Mg and Al called magnalium is used in manufacturing of aircraft due to its light weight and high strength.
mcq
jee-main-2019-online-10th-april-morning-slot
3,436
UDmTrfxCRp1DXrXcHTbww
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
The metal used for marking X–ray tube window is :
[{"identifier": "A", "content": "Ca"}, {"identifier": "B", "content": "Na"}, {"identifier": "C", "content": "Mg"}, {"identifier": "D", "content": "Be"}]
["D"]
null
''Be'' Metal is used in x-ray window is due to transparent to x-rays.
mcq
jee-main-2019-online-10th-january-morning-slot
3,438
x8nHejYs6ywrEWJdhB3Ja
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
The alkaline earth metal nitrate that does not crystallise with water molecules, is :
[{"identifier": "A", "content": "Mg(NO<sub>3</sub>)<sub>2</sub>"}, {"identifier": "B", "content": "Sr(NO<sub>3</sub>)<sub>2</sub>"}, {"identifier": "C", "content": "Ca(NO<sub>3</sub>)<sub>2</sub>"}, {"identifier": "D", "content": "Ba(NO<sub>3</sub>)<sub>2</sub>"}]
["D"]
null
When central atom size is smaller then more water molecule will crystallize. Ba(NO<sub>3</sub>)<sub>2</sub> does not ctystallize with water as size of Ba<sup>+2</sup> ion is very large.
mcq
jee-main-2019-online-9th-january-morning-slot
3,439
UZbRl56uOuvlI5bb6ojgy2xukey6nndt
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
Two elements A and B have similar chemical properties. They don’t form solid hydrogencarbonates, but react with nitrogen to form nitrides. A and B, respectively, are :
[{"identifier": "A", "content": "Li and Mg"}, {"identifier": "B", "content": "Cs and Ba"}, {"identifier": "C", "content": "Na and Rb"}, {"identifier": "D", "content": "Na and Ca"}]
["A"]
null
Solid hydrogencarbonates are not formed by lithium and magnesium. <br><br>– 6Li + N<sub>2</sub> $$ \to $$ 2Li<sub>3</sub>N <br><br>– 3Mg + N<sub>2</sub> $$ \to $$ Mg<sub>3</sub>N<sub>2</sub>
mcq
jee-main-2020-online-2nd-september-evening-slot
3,440
IHQJW0f6JG7mifzSAIjgy2xukfcedvk5
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
An alkaline earth metal ‘M’ readily forms water soluble sulphate and water insoluble hydroxide. Its oxide MO is very stable to heat and does not have rock-salt structure. M is :
[{"identifier": "A", "content": "Ca"}, {"identifier": "B", "content": "Mg"}, {"identifier": "C", "content": "Sr"}, {"identifier": "D", "content": "Be"}]
["D"]
null
BeSO<sub>4</sub> is water soluble. <br>Be(OH)<sub>2</sub> is water insoluble. <br>BeO is stable to heat.
mcq
jee-main-2020-online-4th-september-evening-slot
3,441
WsmnVOe6nwSecTM36Ujgy2xukftdeo7z
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
Among the sulphates of alkaline earth metals, the solubilities of BeSO<sub>4</sub> and MgSO<sub>4</sub> in water, respectively, are :
[{"identifier": "A", "content": "poor and poor"}, {"identifier": "B", "content": "poor and high"}, {"identifier": "C", "content": "high and poor"}, {"identifier": "D", "content": "high and high"}]
["D"]
null
Order of solubility of sulphate of Alkaline earth metals <br><br>BeSO<sub>4</sub> &gt; MgSO<sub>4</sub> &gt; CaSO<sub>4</sub> &gt; SrSO<sub>4</sub> &gt; BaSO<sub>4</sub> <br><br>The greater hydration enthalpies of Be<sup>2+</sup> and Mg<sup>2+</sup> ions dominate over their lattice enthalpies and therefore their su...
mcq
jee-main-2020-online-6th-september-morning-slot
3,442
FBEC1Yigj9F7SXOolx1kmhtmrch
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
Given below are two statements :<br/><br/>Statement I : Both CaCl<sub>2</sub> . 6H<sub>2</sub>O and MgCl<sub>2</sub> . 8H<sub>2</sub>O undergo dehydration on heating.<br/><br/>Statement II : BeO is amphoteric whereas the oxides of other elements in the same group are acidic.<br/><br/>In the light of the above statement...
[{"identifier": "A", "content": "Both statement I and statement II are false"}, {"identifier": "B", "content": "Statement I is false but statement II is true"}, {"identifier": "C", "content": "Statement I is true but statement II is false"}, {"identifier": "D", "content": "Both statement I and statement II are true"}]
["A"]
null
CaCl<sub>2</sub>.6H<sub>2</sub>O $$\buildrel \Delta \over \longrightarrow $$ CaCl<sub>2</sub> + 6H<sub>2</sub>O<br><br> MgCl<sub>2</sub>.6H<sub>2</sub>O $$\buildrel \Delta \over \longrightarrow $$ MgCl(OH) + H<sub>2</sub>O<br><br> Among alkaline earth metal BeO is amphoteric &amp; rest are basic oxide
mcq
jee-main-2021-online-16th-march-morning-shift
3,443
6BsBWGWetlGz7d3oGa1kmki64va
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
The set of elements that differ in mutual relationship from those of the other sets is :
[{"identifier": "A", "content": "Li - Na"}, {"identifier": "B", "content": "Be - Al"}, {"identifier": "C", "content": "B - Si"}, {"identifier": "D", "content": "Li - Mg"}]
["A"]
null
<img src="https://res.cloudinary.com/dckxllbjy/image/upload/v1734264651/exam_images/f8e0ml2oibv52mp4tpzq.webp" style="max-width: 100%;height: auto;display: block;margin: 0 auto;" loading="lazy" alt="JEE Main 2021 (Online) 17th March Evening Shift Chemistry - s-Block Elements Question 78 English Explanation"><br> Li–Mg,...
mcq
jee-main-2021-online-17th-march-evening-shift
3,444
1krussbkk
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
Given below are two statements :<br/><br/>Statement I : None of the alkaline earth metal hydroxides dissolve in alkali.<br/><br/>Statement II : Solubility of alkaline earth metal hydroxides in water increases down the group. <br/><br/>In the light of the above statements, choose the most appropriate answer from the opt...
[{"identifier": "A", "content": "Statement I is correct but Statement II is incorrect."}, {"identifier": "B", "content": "Statement I is incorrect but Statement II is correct."}, {"identifier": "C", "content": "Statement I and Statement II both are incorrect."}, {"identifier": "D", "content": "Statement I and Statement...
["B"]
null
Statement - I is incorrect<br><br>Be(OH)<sub>2</sub> dissolve in alkali due to it's amphoteric nature.<br><br>Statement - II is correct<br><br>Solubility of alkaline earth metal hydroxide in water increases down the group due to rapid decreases in lattice energy as compared to hydration energy.
mcq
jee-main-2021-online-25th-july-morning-shift
3,447
1l58dt92f
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
<p>The correct order of melting point is :</p>
[{"identifier": "A", "content": "Be > Mg > Ca > Sr"}, {"identifier": "B", "content": "Sr > Ca > Mg > Be"}, {"identifier": "C", "content": "Be > Ca > Mg > Sr"}, {"identifier": "D", "content": "Be > Ca > Sr > Mg"}]
["D"]
null
$$\begin{array}{ll}\text {Element } & \text { M.P. } \\ \mathrm{Be} & 1560 \mathrm{~K} \\ \mathrm{Mg} & 924 \mathrm{~K} \\ \mathrm{Ca} & 1124 \mathrm{~K} \\ \mathrm{Sr} & 1062 \, \text{K}\end{array}$$
mcq
jee-main-2022-online-26th-june-morning-shift
3,448
1l5alvkoc
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
<p>Which one of the following alkaline earth metal ions has the highest ionic mobility in its aqueous solution?</p>
[{"identifier": "A", "content": "Be<sup>2+</sup>"}, {"identifier": "B", "content": "Mg<sup>2+</sup>"}, {"identifier": "C", "content": "Ca<sup>2+</sup>"}, {"identifier": "D", "content": "Sr<sup>2+</sup>"}]
["D"]
null
In aqueous solution, the ionic mobility is inversely proportional to the charge density on the ion. Hence Sr<sup>2+</sup> has highest ionic mobility in water.
mcq
jee-main-2022-online-25th-june-morning-shift
3,450
1l6f6uoab
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
<p>The correct order of density is :</p>
[{"identifier": "A", "content": "Be > Mg > Ca > Sr"}, {"identifier": "B", "content": "Sr > Ca > Mg > Be"}, {"identifier": "C", "content": "Sr > Be > Mg > Ca"}, {"identifier": "D", "content": "Be > Sr > Mg > Ca"}]
["C"]
null
Density of $$\mathrm{Sr}=2.63 \mathrm{~g} / \mathrm{cm}^{3}$$ <br/><br/> Density of $$\mathrm{Be}=1.84 \mathrm{~g} / \mathrm{cm}^{3}$$ <br/><br/> Density of $$\mathrm{Mg}=1.74 \mathrm{~g} / \mathrm{cm}^{3}$$ <br/><br/> Density of $$\mathrm{Ca}=1.55 \mathrm{~g} / \mathrm{cm}^{3}$$
mcq
jee-main-2022-online-25th-july-evening-shift
3,451
1l6i4sc3n
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
<p>The metal that has very low melting point and its periodic position is closer to a metalloid is :</p>
[{"identifier": "A", "content": "Al"}, {"identifier": "B", "content": "Ga"}, {"identifier": "C", "content": "Se"}, {"identifier": "D", "content": "In"}]
["B"]
null
Among the given elements, Gallium has the lowest melting point, Gallium is also close to a metalloid
mcq
jee-main-2022-online-26th-july-evening-shift
3,452
1l6kpeypx
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
<p>An element A of group 1 shows similarity to an element B belonging to group 2. If A has maximum hydration enthalpy in group 1 then B is :</p>
[{"identifier": "A", "content": "Mg"}, {"identifier": "B", "content": "Be"}, {"identifier": "C", "content": "Ca"}, {"identifier": "D", "content": "Sr"}]
["A"]
null
<img src="https://app-content.cdn.examgoal.net/fly/@width/image/1l7oihc9m/bdf7ed88-de80-4efb-bbfd-4b02aa3446d5/37c09ba0-2cf6-11ed-a627-29822045a51b/file-1l7oihc9n.png?format=png" data-orsrc="https://app-content.cdn.examgoal.net/image/1l7oihc9m/bdf7ed88-de80-4efb-bbfd-4b02aa3446d5/37c09ba0-2cf6-11ed-a627-29822045a51b/fi...
mcq
jee-main-2022-online-27th-july-evening-shift
3,453
1l6nuhhdy
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
<p>The correct decreasing order for metallic character is :</p>
[{"identifier": "A", "content": "Na > Mg > Be > Si > P"}, {"identifier": "B", "content": "P > Si > Be > Mg > Na"}, {"identifier": "C", "content": "Si > P > Be > Na > Mg"}, {"identifier": "D", "content": "Be > Na > Mg > Si > P"}]
["A"]
null
Metallic character increases top to bottom in group and decreases left to right in a period. <br/><br/> $\mathrm{Mg}$ is from second group it will be less metallic than $\mathrm{Na}$. Be comes above $\mathrm{Mg}$ hence less metallic than Mg. Si is more metallic than phosphorous.
mcq
jee-main-2022-online-28th-july-evening-shift
3,454
1l6nuyuiq
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
<p>Statement I : An alloy of lithium and magnesium is used to make aircraft plates.</p> <p>Statement II : The magnesium ions are important for cell-membrane integrity.</p> <p>In the light the above statements, choose the correct answer from the options given below :</p>
[{"identifier": "A", "content": "Both Statement I and Statement II are true"}, {"identifier": "B", "content": "Both Statement I and Statement II are false"}, {"identifier": "C", "content": "Statement I is true but Statement II is false"}, {"identifier": "D", "content": "Statement I is false but Statement II is true"}]
["B"]
null
Alloy of Li and Mg is used to make armour plates and not aircraft plates.<br/><br/> Calcium plays important roles in neuromuscular function, interneuronal transmission and cell membrane integrity .
mcq
jee-main-2022-online-28th-july-evening-shift
3,455
ldo8cwum
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
The element playing significant role in neuromuscular function and interneuronal transmission is :
[{"identifier": "A", "content": "Be"}, {"identifier": "B", "content": "$\\mathrm{Ca}$"}, {"identifier": "C", "content": "$\\mathrm{Mg}$"}, {"identifier": "D", "content": "$\\mathrm{Li}$"}]
["B"]
null
Calcium plays important role in neuromuscular function, interneuronal transmission, cell membrane etc.
mcq
jee-main-2023-online-31st-january-evening-shift
3,456
1ldoj5w8f
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
<p>Choose the correct statement(s) :</p> <p>A. Beryllium oxide is purely acidic in nature.</p> <p>B. Beryllium carbonate is kept in the atmosphere of $$\mathrm{CO_2}$$.</p> <p>C. Beryllium sulphate is readily soluble in water.</p> <p>D. Beryllium shows anomalous behaviour.</p> <p>Choose the correct answer from the opti...
[{"identifier": "A", "content": "A only"}, {"identifier": "B", "content": "B, C and D only"}, {"identifier": "C", "content": "A, B and C only"}, {"identifier": "D", "content": "A and B only"}]
["B"]
null
<p>A. Beryllium oxide is amphoteric in nature. </p> <p> B. Beryllium carbonate is kept in the atmosphere of CO<sub>2</sub> because it is thermally less stable. </p> <p> C. Beryllium sulphate is readily soluble in water due to high degree of hydration. </p> <p> D. Beryllium shows anomalous behaviour due to small size...
mcq
jee-main-2023-online-1st-february-morning-shift
3,457
ldqwnz40
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
Chlorides of which metal are soluble in organic solvents :
[{"identifier": "A", "content": "K"}, {"identifier": "B", "content": "Be"}, {"identifier": "C", "content": "Ca"}, {"identifier": "D", "content": "Mg"}]
["B"]
null
<p>$$\mathrm{BeCl_2}$$ is a covalent molecule</p> <p>So, it is soluble in organic solvents, rest are ionic compounds.</p>
mcq
jee-main-2023-online-30th-january-evening-shift
3,458
1ldr4n6j4
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
<p>The alkaline earth metal sulphate(s) which are readily soluble in water is/are :</p> <p>A. $$\mathrm{BeSO}_{4}$$</p> <p>B. $$\mathrm{MgSO}_{4}$$</p> <p>C. $$\mathrm{CaSO}_{4}$$</p> <p>D. $$\mathrm{SrSO}_{4}$$</p> <p>E. $$\mathrm{BaSO}_{4}$$</p> <p>Choose the correct answer from the options given below :</p>
[{"identifier": "A", "content": "A and B"}, {"identifier": "B", "content": "B and C"}, {"identifier": "C", "content": "B only"}, {"identifier": "D", "content": "A only"}]
["A"]
null
<p>BeSO$$_4$$ and MgSO$$_4$$ are readily soluble in water.</p>
mcq
jee-main-2023-online-30th-january-morning-shift
3,459
1ldsr0jvc
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
<p>The correct order of hydration enthalpies is</p> <p>(A) K$$^+$$</p> <p>(B) Rb$$^+$$</p> <p>(C) Mg$$^{2+}$$</p> <p>(D) Cs$$^+$$</p> <p>(E) Ca$$^{2+}$$</p> <p>Choose the correct answer from the options given below :</p>
[{"identifier": "A", "content": "E > C > A > B > D"}, {"identifier": "B", "content": "C > A > E > B > D"}, {"identifier": "C", "content": "C > E > A > D > B"}, {"identifier": "D", "content": "C > E > A > B > D"}]
["D"]
null
Hydration enthalpy $\propto$ charge density <br/><br/>Charge density means $${{Magnitude\,of\,Charge} \over {Ionic\,Radius}}$$. <br/><br/> $\therefore$ The correct order of charge density is <br/><br/> $$ \mathrm{Mg}^{2+}>\mathrm{Ca}^{2+}>\mathrm{K}^{+}>\mathrm{Rb}^{+}>\mathrm{Cs}^{+} $$ <br/><br/> $\therefore$ The or...
mcq
jee-main-2023-online-29th-january-morning-shift
3,460
1ldu0yi9x
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
<p>Which of the following represents the correct order of metallic character of the given elements?</p>
[{"identifier": "A", "content": "K < Mg < Be < Si"}, {"identifier": "B", "content": "Si < Be < Mg < K"}, {"identifier": "C", "content": "Be < Si < Mg < K"}, {"identifier": "D", "content": "Be < Si < K < Mg"}]
["B"]
null
Metallic character of an element is directly proportional to its electropositivity. Of the given elements silicon is least electro positive and potassium is most electropositive whereas beryllium and magnesium have intermediate values in the increasing order. Therefore, correct order of metallic character is $\mathrm{S...
mcq
jee-main-2023-online-25th-january-evening-shift
3,461
1ldwum0sy
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
<p>Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R</p> <p>Assertion A : Beryllium has less negative value of reduction potential compared to the other alkaline earth metals.</p> <p>Reason R : Beryllium has large hydration energy due to small size of Be$$^{2+}$$ but r...
[{"identifier": "A", "content": "Both A and R are correct but R is NOT the correct explanation of A"}, {"identifier": "B", "content": "Both A and R are correct and R is the correct explanation of A"}, {"identifier": "C", "content": "A is correct but R is not correct"}, {"identifier": "D", "content": "A is not correct ...
["B"]
null
The most appropriate answer is Both A and R are correct and R is the correct explanation of A. <br/><br/> <b>Assertion A</b> states that beryllium has a less negative value of reduction potential compared to the other alkaline earth metals. This assertion is correct, as beryllium has higher ionization energy and a smal...
mcq
jee-main-2023-online-24th-january-evening-shift
3,462
lgnzloa4
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
Given below are two statements : One is labelled as Assertion A and the other is labelled as Reason R : <br/><br/> <b>Assertion (A)</b> : $\mathrm{BeCl}_{2}$ and $\mathrm{MgCl}_{2}$ produce characteristic flame<br/><br/> <b>Reason (R)</b> : The excitation energy is high in $\mathrm{BeCl}_{2}$ and $\mathrm{MgCl}_{2}$ <b...
[{"identifier": "A", "content": "$\\mathrm{(A)}$ is true but $(\\mathrm{R})$ is false"}, {"identifier": "B", "content": "Both (A) and $(\\mathrm{R})$ are true and $(\\mathrm{R})$ is the correct explanation of $(A)$"}, {"identifier": "C", "content": "(A) is false but (R) is true\n"}, {"identifier": "D", "content": "Both...
["C"]
null
BeCl<sub>2</sub> and MgCl<sub>2</sub> do not produce characteristic flame because excitation energy is high in BeCl<sub>2</sub> and MgCl<sub>2</sub>. Hence, the correct answer is option (C).
mcq
jee-main-2023-online-15th-april-morning-shift
3,463
1lgvtszte
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
<p>The correct order of metallic character is :</p>
[{"identifier": "A", "content": "K > Be > Ca"}, {"identifier": "B", "content": "Ca > K > Be"}, {"identifier": "C", "content": "K > Ca > Be"}, {"identifier": "D", "content": "Be > Ca > K"}]
["C"]
null
<p>As you move from top to bottom in a group (vertical column) on the periodic table, the metallic character increases. This is because elements at the bottom of a group have more electron shells than those at the top. These extra shells shield the outermost electrons from the pull of the nucleus, which makes it easier...
mcq
jee-main-2023-online-10th-april-evening-shift
3,464
1lh32h679
chemistry
s-block-elements
physiochemical-trends-in-alkaline-earth-metals
<p>Ion having highest hydration enthalpy among the given alkaline earth metal ions is :</p>
[{"identifier": "A", "content": "$$\\mathrm{Sr}^{2+}$$"}, {"identifier": "B", "content": "$$\\mathrm{Ca}^{2+}$$"}, {"identifier": "C", "content": "$$\\mathrm{Be}^{2+}$$"}, {"identifier": "D", "content": "$$\\mathrm{Ba}^{2+}$$"}]
["C"]
null
<p>Hydration enthalpy is the amount of energy released when one mole of gaseous ions is completely surrounded by water molecules. The process is exothermic, hence the enthalpy change is negative. </p> <p>Generally, smaller ions and ions with higher charge have larger hydration enthalpies due to the stronger attraction ...
mcq
jee-main-2023-online-6th-april-evening-shift
3,466
K8VVFHuXtvdFkmGb
chemistry
solid-state
close-packing-in-crystals
In a compound atoms of element Y from ccp lattice and those of element X occupy 2/3rd of tetrahedral voids. The formula of the compound will be :
[{"identifier": "A", "content": "X<sub>4</sub>Y<sub>3</sub>"}, {"identifier": "B", "content": "X<sub>2</sub>Y<sub>3</sub>"}, {"identifier": "C", "content": "X<sub>2</sub>Y"}, {"identifier": "D", "content": "X<sub>3</sub>Y<sub>4</sub>"}]
["A"]
null
From the given data, we have <br><br>Number of $$Y$$ atoms in a unit cell <br><br>$$=4$$ <br><br>Number of $$X$$ atoms in a unit cell <br><br>$$ = 8 \times {2 \over 3} = {{16} \over 3}$$ <br><br>From the above we get the formula of the compound <br><br>as $${X_{16/3}}{Y_4}\,\,$$ or $${X_4}{Y_3}$$
mcq
aieee-2008
3,467
6xBm9SOvpviBC90u
chemistry
solid-state
close-packing-in-crystals
Percentages of free space in cubic close packed structure and in body centred packed structure are respectively :
[{"identifier": "A", "content": "30% and 26%"}, {"identifier": "B", "content": "26% and 32%"}, {"identifier": "C", "content": "32% and 48%"}, {"identifier": "D", "content": "48% and 26%"}]
["B"]
null
Packing fraction is defined as the ratio of the volume of the unit cell that is occupied by the spheres to the volume of the unit cell. <br><br>P.F. for cpp and bcc are $$0.74$$ and $$0.68$$ respectively. <br><br>So, the free space in ccp and bcc are $$26\% $$ &amp; $$32\% $$ respectively.
mcq
aieee-2010
3,468
ya2QzB4oEpOwCfOkCxVnd
chemistry
solid-state
close-packing-in-crystals
A compound of formula A<sub>2</sub>B<sub>3</sub> has the hcp lattice. Which atom forms the hcp lattice and what fraction of tetrahedral voids is occupied by the other atoms :
[{"identifier": "A", "content": "hcp lattice - A, $${1 \\over 3}$$ Tetrahedral voids-B"}, {"identifier": "B", "content": "hcp lattice - B, $${1 \\over 3}$$ Tetrahedral voids - A"}, {"identifier": "C", "content": "hcp lattice - A, $${2 \\over 3}$$ Tetrahedral voids - B"}, {"identifier": "D", "content": "hcp lattice - B,...
["B"]
null
A<sub>2</sub>B<sub>3</sub><sub></sub> has HCP lattice <br><br>If A form HCP, <br>then $${{{3^{th}}} \over 4}$$ of THV must occupied by B to form A<sub>2</sub>B<sub>3</sub> <br><br>If B form HCP, then $${{{1^{th}}} \over 3}$$ of THV must occupied by A to form A<sub>2</sub>B<sub>3</sub>
mcq
jee-main-2019-online-10th-january-evening-slot
3,469
dVbe1ckEgS640O96lN1kmiv0k0d
chemistry
solid-state
close-packing-in-crystals
Ga (atomic mass 70 u) crystallizes in a hexagonal close packed structure. The total number of voids in 0.581 g of Ga is __________ $$\times$$ 10<sup>21</sup>. (Round off to the Nearest Integer). [Given : N<sub>A</sub> = 6.023 $$\times$$ 10<sub>23</sub>]
[]
null
15
For HCP structure Z = 6<br><br>Tetrahedral Void = (Z $$\times$$ 2) = 12<br><br>Octahedral Void = [Z $$\times$$ 1] = 6<br><br>No. of void per unit cell = 18<br><br>No. of unit cell = $$\left( {{{0.581 \times {N_A}} \over {70 \times 6}}} \right)$$<br><br>No. of void = $$\left( {{{0.581 \times 6.023 \times {{10}^{23}}} \o...
integer
jee-main-2021-online-16th-march-evening-shift
3,470
FdsRW5NnnN48Z4EMOp1kmlniank
chemistry
solid-state
close-packing-in-crystals
In a binary compound, atoms of element A form a hcp structure and those of element M occupy 2/3 of the tetrahedral voids of the hcp structure. The formula of the binary compound is :
[{"identifier": "A", "content": "M<sub>2</sub>A<sub>3</sub>"}, {"identifier": "B", "content": "M<sub>4</sub>A<sub>3</sub>"}, {"identifier": "C", "content": "M<sub>4</sub>A"}, {"identifier": "D", "content": "MA<sub>3</sub>"}]
["B"]
null
In HCP unit cell,<br><br>Z = 6 so A = 6<br><br>Also we know, in HCP<br><br>Tetrahedral voids = 2Z = 12<br><br>$$ \therefore $$ No. of M = $${2 \over 3}$$ [TV] = $${2 \over 3}$$ $$\times$$ 12 = 8<br><br>$$ \therefore $$ Formula = M<sub>8</sub>A<sub>6</sub> = M<sub>4</sub>A<sub>3</sub>
mcq
jee-main-2021-online-18th-march-morning-shift
3,471
1ktjyki76
chemistry
solid-state
close-packing-in-crystals
The empirical formula for a compound with a cubic close packed arrangement of anions and with cations occupying all the octahedral sites in A<sub>x</sub>B. The value of x is _____________. (Integer answer)
[]
null
1
Anions forms CCP or FCC(A<sup>$$-$$</sup>) = 4A<sup>$$-$$</sup> per unit cell Cations occupy all octahedral voids (B<sup>+</sup>) = 4B<sup>+</sup> per unit cell<br><br>cell formula $$\to$$ A<sub>4</sub>B<sub>4</sub><br><br>Empirical formula $$\to$$ AB $$\to$$ (x = 1)
integer
jee-main-2021-online-31st-august-evening-shift
3,472