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244
10.1021_acs.orglett.3c03142
C(=O)(OC)c1ccc2c(=O)n(Cc3ccccc3C#N)nnc2c1
5
5
[0.10963542 0.78515632 0.31482213 0.83671878]
[0.33028706 0.77656254 0.89365298 0.85000001]
1H NMR
400 MHz
CDCl3
8.81 (s, 1H), 8.41-8.40 (m, 2H), 7.73 (d, J = 8.4 Hz, 1H), 7.55 (t, J = 7.8 Hz, 1H), 7.43 (dd, J = 14.2, 7.4 Hz, 2H), 5.86 (s, 2H), 4.03 (s, 3H)
null
[('s', [], '1H', 8.81, 8.81), ('m', [], '2H', 8.41, 8.4), ('d', ['8.4Hz'], '1H', 7.73, 7.73), ('t', ['7.8Hz'], '1H', 7.55, 7.55), ('dd', ['14.2Hz', '7.4Hz'], '2H', 7.43, 7.43), ('s', [], '2H', 5.86, 5.86), ('s', [], '3H', 4.03, 4.03)]
12
9
12
10.1021_acs.orglett.3c03142
C(=O)(OC)c1ccc2c(=O)n(Cc3ccccc3C#N)nnc2c1
5
5
[0.10963542 0.78515632 0.31482213 0.83671878]
[0.33028706 0.77656254 0.89365298 0.85000001]
13C NMR
100 MHz
CDCl3
164.6, 154.4, 143.7, 138.4, 136.1, 132.95, 132.91, 132.4, 129.9, 128.7, 128.5, 125.5, 122.3, 116.9, 112.4, 52.9, 51.2
null
[(164.6, None, None), (154.4, None, None), (143.7, None, None), (138.4, None, None), (136.1, None, None), (132.95, None, None), (132.91, None, None), (132.4, None, None), (129.9, None, None), (128.7, None, None), (128.5, None, None), (125.5, None, None), (122.3, None, None), (116.9, None, None), (112.4, None, None), (5...
17
17
17
10.1021_acs.orglett.3c03142
COc1ccc2c(=O)n(Cc3ccccc3C#N)nnc2c1
6
6
[0.10846174 0.11562501 0.29963334 0.16484376]
[0.10438839 0.10996094 0.89365298 0.21601563]
1H NMR
400 MHz
CDCl3
8.25 (d, J = 8.8 Hz, 1H), 7.71 (dd, J = 7.8, 1.4 Hz, 1H), 7.55-7.51 (m, 2H), 7.42-7.38 (m, 2H), 7.35 (dd, J = 8.8, 2.4 Hz, 1H), 5.84 (s, 2H), 4.00 (s, 3H)
null
[('d', ['8.8Hz'], '1H', 8.25, 8.25), ('dd', ['7.8Hz', '1.4Hz'], '1H', 7.71, 7.71), ('m', [], '2H', 7.55, 7.51), ('m', [], '2H', 7.42, 7.38), ('dd', ['8.8Hz', '2.4Hz'], '1H', 7.35, 7.35), ('s', [], '2H', 5.84, 5.84), ('s', [], '3H', 4.0, 4.0)]
12
9
12
10.1021_acs.orglett.3c03142
COc1ccc2c(=O)n(Cc3ccccc3C#N)nnc2c1
6
6
[0.10846174 0.11562501 0.29963334 0.16484376]
[0.10438839 0.10996094 0.89365298 0.21601563]
13C NMR
100 MHz
CDCl3
164.7, 154.9, 146.2, 139.0, 133.0, 132.9, 128.5, 128.3, 126.7, 122.5, 117.0, 113.2, 112.3, 108.6, 56.1, 51.0
null
[(164.7, None, None), (154.9, None, None), (146.2, None, None), (139.0, None, None), (133.0, None, None), (132.9, None, None), (128.5, None, None), (128.3, None, None), (126.7, None, None), (122.5, None, None), (117.0, None, None), (113.2, None, None), (112.3, None, None), (108.6, None, None), (56.1, None, None), (51.0...
16
16
16
10.1021_acs.orglett.3c03142
c1(C#N)ccccc1Cn1nnc2ccc(F)cc2c1=O
6
6
[0.11101622 0.25351565 0.27505511 0.30390628]
[0.10507879 0.23183595 0.63848134 0.24394532]
1H NMR
600 MHz
CDCl3
8.23 (dd, J = 9.0, 4.8 Hz, 1H), 7.98 (dd, J = 7.8, 3.0 Hz, 1H), 7.72 (d, J = 7.8 Hz, 1H), 7.68-7.65 (m, 1H), 7.55 (t, J = 7.8 Hz, 1H), 7.44-7.41 (m, 2H), 5.85 (s, 2H)
null
[('dd', ['9.0Hz', '4.8Hz'], '1H', 8.23, 8.23), ('dd', ['7.8Hz', '3.0Hz'], '1H', 7.98, 7.98), ('d', ['7.8Hz'], '1H', 7.72, 7.72), ('m', [], '1H', 7.68, 7.65), ('t', ['7.8Hz'], '1H', 7.55, 7.55), ('m', [], '2H', 7.44, 7.41), ('s', [], '2H', 5.85, 5.85)]
9
8
9
10.1021_acs.orglett.3c03142
c1(C#N)ccccc1Cn1nnc2ccc(F)cc2c1=O
6
6
[0.11101622 0.25351565 0.27505511 0.30390628]
[0.10507879 0.23183595 0.63848134 0.24394532]
13C NMR
150 MHz
CDCl3
164.2 (JC-F= 257 Hz), 154.6, 141.2, 138.7, 133.1, 133.0, 131.8, 131.7, 128.8, 128.6, 123.9, 123.7, 122.0 (JC-F= 9 Hz), 117.0, 112.5, 110.6, 110.5, 51.1
null
[(164.2, None, 257.0), (154.6, None, None), (141.2, None, None), (138.7, None, None), (133.1, None, None), (133.0, None, None), (131.8, None, None), (131.7, None, None), (128.8, None, None), (128.6, None, None), (123.9, None, None), (123.7, None, None), (122.0, None, 9.0), (117.0, None, None), (112.5, None, None), (110...
15
15
18
10.1021_acs.orglett.3c03142
COc1ccc2nnn(Cc3ccccc3C#N)c(=O)c2c1
6
6
[0.11101622 0.39414065 0.30129029 0.44414065]
[0.10383607 0.38984376 0.89420532 0.49609379]
1H NMR
400 MHz
CDCl3
8.08 (dd, J = 8.8, 1.2 Hz, 1H), 7.71 (d, J = 8.0 Hz, 1H), 7.66 (s, 1H), 7.54-7.46 (m, 2H), 7.41-7.38 (m, 2H), 5.84 (s, 2H), 3.96 (s, 3H)
null
[('dd', ['8.8Hz', '1.2Hz'], '1H', 8.08, 8.08), ('d', ['8.0Hz'], '1H', 7.71, 7.71), ('s', [], '1H', 7.66, 7.66), ('m', [], '2H', 7.54, 7.46), ('m', [], '2H', 7.41, 7.38), ('s', [], '2H', 5.84, 5.84), ('s', [], '3H', 3.96, 3.96)]
12
9
12
10.1021_acs.orglett.3c03142
COc1ccc2nnn(Cc3ccccc3C#N)c(=O)c2c1
6
6
[0.11101622 0.39414065 0.30129029 0.44414065]
[0.10383607 0.38984376 0.89420532 0.49609379]
13C NMR
100 MHz
CDCl3
162.6, 155.3, 139.2, 139.0, 132.92, 132.88, 130.3, 128.5, 128.3, 125.0, 121.5, 117.0, 112.4, 104.2, 56.2, 51.0
null
[(162.6, None, None), (155.3, None, None), (139.2, None, None), (139.0, None, None), (132.92, None, None), (132.88, None, None), (130.3, None, None), (128.5, None, None), (128.3, None, None), (125.0, None, None), (121.5, None, None), (117.0, None, None), (112.4, None, None), (104.2, None, None), (56.2, None, None), (51...
16
16
16
10.1021_acs.orglett.3c03142
C(#N)c1ccccc1Cn1nnc2c(OC)cccc2c1=O
6
6
[0.11184469 0.53710941 0.26124712 0.60039065]
[0.27781671 0.53046879 0.89089138 0.6039063 ]
1H NMR
400 MHz
CDCl3
7.89 (d, J = 8.0 Hz, 1H), 7.76 (d, J = 7.6 Hz, 1H), 7.72-7.69 (m, 1H), 7.51 (t, J = 8.0 Hz, 1H), 7.40-7.36 (m, 3H), 5.85 (s, 2H), 4.11 (s, 3H)
null
[('d', ['8.0Hz'], '1H', 7.89, 7.89), ('d', ['7.6Hz'], '1H', 7.76, 7.76), ('m', [], '1H', 7.72, 7.69), ('t', ['8.0Hz'], '1H', 7.51, 7.51), ('m', [], '3H', 7.4, 7.36), ('s', [], '2H', 5.85, 5.85), ('s', [], '3H', 4.11, 4.11)]
12
9
12
10.1021_acs.orglett.3c03142
C(#N)c1ccccc1Cn1nnc2c(OC)cccc2c1=O
6
6
[0.11184469 0.53710941 0.26124712 0.60039065]
[0.27781671 0.53046879 0.89089138 0.6039063 ]
13C NMR
100 MHz
CDCl3
155.6, 155.0, 138.8, 134.5, 133.6, 132.9, 132.8, 128.4, 128.3, 120.9, 116.9, 115.9, 115.4, 112.4, 56.6, 51.1
null
[(155.6, None, None), (155.0, None, None), (138.8, None, None), (134.5, None, None), (133.6, None, None), (132.9, None, None), (132.8, None, None), (128.4, None, None), (128.3, None, None), (120.9, None, None), (116.9, None, None), (115.9, None, None), (115.4, None, None), (112.4, None, None), (56.6, None, None), (51.1...
16
16
16
10.1021_acs.orglett.3c03142
C(#N)c1ccccc1Cn1nnc2cccc(C)c2c1=O
6
6
[0.11101622 0.67656253 0.25710473 0.72578129]
[0.09444664 0.67031251 0.89144372 0.76093754]
1H NMR
600 MHz
CDCl3
8.00 (d, J = 8.4 Hz, 1H), 7.80 (t, J = 7.5 Hz, 1H), 7.71 (d, J = 7.8 Hz, 1H), 7.55-7.52 (m, 2H), 7.39 (t, J = 8.7 Hz, 2H), 5.80 (s, 2H), 2.89 (s, 3H)
null
[('d', ['8.4Hz'], '1H', 8.0, 8.0), ('t', ['7.5Hz'], '1H', 7.8, 7.8), ('d', ['7.8Hz'], '1H', 7.71, 7.71), ('m', [], '2H', 7.55, 7.52), ('t', ['8.7Hz'], '2H', 7.39, 7.39), ('s', [], '2H', 5.8, 5.8), ('s', [], '3H', 2.89, 2.89)]
12
9
12
10.1021_acs.orglett.3c03142
C(#N)c1ccccc1Cn1nnc2cccc(C)c2c1=O
6
6
[0.11101622 0.67656253 0.25710473 0.72578129]
[0.09444664 0.67031251 0.89144372 0.76093754]
13C NMR
150 MHz
CDCl3
155.9, 145.7, 140.3, 139.5, 134.7, 134.4, 133.1, 133.0, 128.4, 128.3, 126.7, 118.1, 117.1, 112.3, 50.9, 22.5
null
[(155.9, None, None), (145.7, None, None), (140.3, None, None), (139.5, None, None), (134.7, None, None), (134.4, None, None), (133.1, None, None), (133.0, None, None), (128.4, None, None), (128.3, None, None), (126.7, None, None), (118.1, None, None), (117.1, None, None), (112.3, None, None), (50.9, None, None), (22.5...
16
16
16
10.1021_acs.orglett.3c03142
c1(C#N)ccccc1Cn1nnc2cc(F)c(F)cc2c1=O
6
6
[0.10825463 0.80078132 0.28140679 0.84921881]
[0.10217911 0.79531251 0.89144372 0.90000006]
1H NMR
600 MHz
CDCl3
8.11 (dd, J = 9.3, 8.1 Hz, 1H), 7.97 (dd, J = 9.3, 6.9 Hz, 1H), 7.72 (d, J = 6.6 Hz, 1H), 7.57-7.55 (m, 1H), 7.44-7.42 (m, 2H), 5.84 (s, 2H)
null
[('dd', ['9.3Hz', '8.1Hz'], '1H', 8.11, 8.11), ('dd', ['9.3Hz', '6.9Hz'], '1H', 7.97, 7.97), ('d', ['6.6Hz'], '1H', 7.72, 7.72), ('m', [], '1H', 7.57, 7.55), ('m', [], '2H', 7.44, 7.42), ('s', [], '2H', 5.84, 5.84)]
8
7
8
10.1021_acs.orglett.3c03142
c1(C#N)ccccc1Cn1nnc2cc(F)c(F)cc2c1=O
6
6
[0.10825463 0.80078132 0.28140679 0.84921881]
[0.10217911 0.79531251 0.89144372 0.90000006]
13C NMR
150 MHz
CDCl3
155.0 (JC-F= 262 Hz), 154.4 (JC-F= 262 Hz), 152.4 (JC-F= 14 Hz), 141.9 (JC-F= 10 Hz), 138.5, 133.2, 133.1, 128.9, 128.7, 117.8 (JC-F= 7 Hz), 116.9, 116.8, 116.7, 113.3, 113.2, 112.6, 51.3
null
[(155.0, None, 262.0), (154.4, None, 262.0), (152.4, None, 14.0), (141.9, None, 10.0), (138.5, None, None), (133.2, None, None), (133.1, None, None), (128.9, None, None), (128.7, None, None), (117.8, None, 7.0), (116.9, None, None), (116.8, None, None), (116.7, None, None), (113.3, None, None), (113.2, None, None), (11...
15
15
17
10.1021_acs.orglett.3c03142
C(#N)c1ccccc1Cn1nnc2cc(OC)c(OC)cc2c1=O
7
7
[0.1104639 0.11523438 0.30073797 0.16484376]
[0.10659766 0.10996094 0.89310064 0.21601563]
1H NMR
400 MHz
CDCl3
7.72 (d, J = 7.6 Hz, 1H), 7.63 (s, 1H), 7.55-7.50 (m, 2H), 7.40 (t, J = 7.0 Hz, 2H), 5.84 (s, 2H), 4.07 (s, 3H), 4.03 (s, 3H)
null
[('d', ['7.6Hz'], '1H', 7.72, 7.72), ('s', [], '1H', 7.63, 7.63), ('m', [], '2H', 7.55, 7.5), ('t', ['7.0Hz'], '2H', 7.4, 7.4), ('s', [], '2H', 5.84, 5.84), ('s', [], '3H', 4.07, 4.07), ('s', [], '3H', 4.03, 4.03)]
14
9
14
10.1021_acs.orglett.3c03142
C(#N)c1ccccc1Cn1nnc2cc(OC)c(OC)cc2c1=O
7
7
[0.1104639 0.11523438 0.30073797 0.16484376]
[0.10659766 0.10996094 0.89310064 0.21601563]
13C NMR
100 MHz
CDCl3
155.03, 155.01, 153.3, 140.7, 139.1, 132.96, 132.89, 128.5, 128.3, 117.1, 114.4, 112.4, 108.1, 103.6, 56.8, 56.7, 51.2
null
[(155.03, None, None), (155.01, None, None), (153.3, None, None), (140.7, None, None), (139.1, None, None), (132.96, None, None), (132.89, None, None), (128.5, None, None), (128.3, None, None), (117.1, None, None), (114.4, None, None), (112.4, None, None), (108.1, None, None), (103.6, None, None), (56.8, None, None), (...
17
17
17
10.1021_acs.orglett.3c03142
c1(C#N)ccccc1Cn1nnc2cc3c(cc2c1=O)OCO3
7
7
[0.11129238 0.25390627 0.29300549 0.30390628]
[0.10438839 0.23164063 0.76717179 0.24414064]
1H NMR
400 MHz
CDCl3
7.72 (d, J = 7.6 Hz, 1H), 7.61 (s, 1H), 7.53 (t, J = 7.6 Hz, 1H), 7.46 (s, 1H), 7.40 (t, J = 8.2 Hz, 2H), 6.22 (s, 2H), 5.82 (s, 2H)
null
[('d', ['7.6Hz'], '1H', 7.72, 7.72), ('s', [], '1H', 7.61, 7.61), ('t', ['7.6Hz'], '1H', 7.53, 7.53), ('s', [], '1H', 7.46, 7.46), ('t', ['8.2Hz'], '2H', 7.4, 7.4), ('s', [], '2H', 6.22, 6.22), ('s', [], '2H', 5.82, 5.82)]
10
8
10
10.1021_acs.orglett.3c03142
c1(C#N)ccccc1Cn1nnc2cc3c(cc2c1=O)OCO3
7
7
[0.11129238 0.25390627 0.29300549 0.30390628]
[0.10438839 0.23164063 0.76717179 0.24414064]
13C NMR
100 MHz
CDCl3
154.9, 153.5, 151.7, 142.2, 138.9, 133.0, 132.9, 128.6, 128.3, 117.0, 116.5, 112.4, 106.3, 103.0, 102.0, 51.1
null
[(154.9, None, None), (153.5, None, None), (151.7, None, None), (142.2, None, None), (138.9, None, None), (133.0, None, None), (132.9, None, None), (128.6, None, None), (128.3, None, None), (117.0, None, None), (116.5, None, None), (112.4, None, None), (106.3, None, None), (103.0, None, None), (102.0, None, None), (51....
16
16
16
10.1021_acs.orglett.3c03142
c1(C#N)ccccc1Cn1nnc2cc3ccccc3cc2c1=O
7
7
[0.11184469 0.37929689 0.29493861 0.4292969 ]
[0.10549303 0.3746094 0.89144372 0.47968754]
1H NMR
400 MHz
CDCl3
8.94 (s, 1H), 8.74 (s, 1H), 8.16 (dd, J = 14.4, 7.6 Hz, 2H), 7.78-7.72 (m, 3H), 7.54 (t, J = 7.6 Hz, 1H), 7.46-7.39 (m, 2H), 5.88 (s, 2H)
null
[('s', [], '1H', 8.94, 8.94), ('s', [], '1H', 8.74, 8.74), ('dd', ['14.4Hz', '7.6Hz'], '2H', 8.16, 8.16), ('m', [], '3H', 7.78, 7.72), ('t', ['7.6Hz'], '1H', 7.54, 7.54), ('m', [], '2H', 7.46, 7.39), ('s', [], '2H', 5.88, 5.88)]
12
11
12
10.1021_acs.orglett.3c03142
C(#N)c1cccc(Cl)c1Cn1nnc2ccccc2c1=O
7
7
[0.1090831 0.51484379 0.26538952 0.57109378]
[0.09223736 0.51484379 0.89310064 0.62031254]
1H NMR
600 MHz
CDCl3
8.34 (dd, J = 7.8, 1.2 Hz, 1H), 8.12 (d, J = 8.4 Hz, 1H), 7.94 (t, J = 8.1 Hz, 1H), 7.80 (t, J = 7.2 Hz, 1H), 7.67 (d, J = 7.8 Hz, 1H), 7.62 (d, J = 8.4 Hz, 1H), 7.41 (t, J = 8.1 Hz, 1H), 5.89 (s, 2H)
null
[('dd', ['7.8Hz', '1.2Hz'], '1H', 8.34, 8.34), ('d', ['8.4Hz'], '1H', 8.12, 8.12), ('t', ['8.1Hz'], '1H', 7.94, 7.94), ('t', ['7.2Hz'], '1H', 7.8, 7.8), ('d', ['7.8Hz'], '1H', 7.67, 7.67), ('d', ['8.4Hz'], '1H', 7.62, 7.62), ('t', ['8.1Hz'], '1H', 7.41, 7.41), ('s', [], '2H', 5.89, 5.89)]
9
8
9
10.1021_acs.orglett.3c03142
C(#N)c1cccc(Cl)c1Cn1nnc2ccccc2c1=O
7
7
[0.1090831 0.51484379 0.26538952 0.57109378]
[0.09223736 0.51484379 0.89310064 0.62031254]
13C NMR
150 MHz
CDCl3
155.3, 143.8, 136.1, 135.9, 135.0, 134.3, 132.6, 131.7, 129.9, 128.4, 125.2, 119.6, 116.7, 116.6, 49.5
null
[(155.3, None, None), (143.8, None, None), (136.1, None, None), (135.9, None, None), (135.0, None, None), (134.3, None, None), (132.6, None, None), (131.7, None, None), (129.9, None, None), (128.4, None, None), (125.2, None, None), (119.6, None, None), (116.7, None, None), (116.6, None, None), (49.5, None, None)]
15
15
15
10.1021_acs.orglett.3c03142
c1(C#N)ccc(F)cc1Cn1nnc2ccccc2c1=O
7
7
[0.11129238 0.65859376 0.266218 0.70859381]
[0.10369799 0.63671875 0.64179528 0.64921878]
1H NMR
600 MHz
CDCl3
8.37-8.36 (m, 1H), 8.22-8.20 (m, 1H), 8.01-7.98 (m, 1H), 7.86-7.83 (m, 1H), 7.74-7.72 (m, 1H), 7.13-7.10 (m, 2H), 5.84 (s, 2H)
null
[('m', [], '1H', 8.37, 8.36), ('m', [], '1H', 8.22, 8.2), ('m', [], '1H', 8.01, 7.98), ('m', [], '1H', 7.86, 7.83), ('m', [], '1H', 7.74, 7.72), ('m', [], '2H', 7.13, 7.1), ('s', [], '2H', 5.84, 5.84)]
9
8
9
10.1021_acs.orglett.3c03142
c1(C#N)ccc(F)cc1Cn1nnc2ccccc2c1=O
7
7
[0.11129238 0.65859376 0.266218 0.70859381]
[0.10369799 0.63671875 0.64179528 0.64921878]
13C NMR
150 MHz
CDCl3
165.0 (JC-F= 257 Hz), 155.3, 144.1, 142.5 (JC-F= 9 Hz), 135.5, 135.4, 135.3, 132.9, 128.6, 125.2, 119.7, 116.43, 116.37, 116.32, 116.28, 116.2, 108.5, 50.7
null
[(165.0, None, 257.0), (155.3, None, None), (144.1, None, None), (142.5, None, 9.0), (135.5, None, None), (135.4, None, None), (135.3, None, None), (132.9, None, None), (128.6, None, None), (125.2, None, None), (119.7, None, None), (116.43, None, None), (116.37, None, None), (116.32, None, None), (116.28, None, None), ...
15
15
18
10.1021_acs.orglett.3c03142
c1(C#N)ccc(Cl)cc1Cn1nnc2ccccc2c1=O
7
7
[0.11101622 0.79843756 0.2745028 0.84843753]
[0.28941541 0.79570315 0.89475756 0.85468754]
1H NMR
400 MHz
CDCl3
8.36 (d, J = 8.0 Hz, 1H), 8.21 (d, J = 8.4 Hz, 1H), 8.00 (t, J = 7.8 Hz, 1H), 7.84 (t, J = 7.6 Hz, 1H), 7.65 (d, J = 7.6 Hz, 1H), 7.41-7.38 (m, 2H), 5.82 (s, 2H)
null
[('d', ['8.0Hz'], '1H', 8.36, 8.36), ('d', ['8.4Hz'], '1H', 8.21, 8.21), ('t', ['7.8Hz'], '1H', 8.0, 8.0), ('t', ['7.6Hz'], '1H', 7.84, 7.84), ('d', ['7.6Hz'], '1H', 7.65, 7.65), ('m', [], '2H', 7.41, 7.38), ('s', [], '2H', 5.82, 5.82)]
9
8
9
10.1021_acs.orglett.3c03142
c1(C#N)ccc(Cl)cc1Cn1nnc2ccccc2c1=O
7
7
[0.11101622 0.79843756 0.2745028 0.84843753]
[0.28941541 0.79570315 0.89475756 0.85468754]
13C NMR
100 MHz
CDCl3
155.2, 144.0, 140.7, 139.7, 135.1, 134.0, 132.7, 129.0, 128.9, 128.5, 125.1, 119.6, 116.3, 110.8, 50.7
null
[(155.2, None, None), (144.0, None, None), (140.7, None, None), (139.7, None, None), (135.1, None, None), (134.0, None, None), (132.7, None, None), (129.0, None, None), (128.9, None, None), (128.5, None, None), (125.1, None, None), (119.6, None, None), (116.3, None, None), (110.8, None, None), (50.7, None, None)]
15
15
15
10.1021_acs.orglett.3c03142
COc1ccc(C#N)c(Cn2nnc3ccccc3c2=O)c1
8
8
[0.10659766 0.11328126 0.28969158 0.16269532]
[0.10494071 0.10996094 0.89365298 0.21601563]
1H NMR
500 MHz
CDCl3
8.37 (d, J = 8.5 Hz, 1H), 8.19 (d, J = 8.5 Hz, 1H), 7.97 (t, J = 8.5 Hz, 1H), 7.82 (t, J = 7.8 Hz, 1H), 7.64 (d, J = 9.5 Hz, 1H), 6.89-6.87 (m, 2H), 5.81 (s, 2H), 3.78 (s, 3H)
null
[('d', ['8.5Hz'], '1H', 8.37, 8.37), ('d', ['8.5Hz'], '1H', 8.19, 8.19), ('t', ['8.5Hz'], '1H', 7.97, 7.97), ('t', ['7.8Hz'], '1H', 7.82, 7.82), ('d', ['9.5Hz'], '1H', 7.64, 7.64), ('m', [], '2H', 6.89, 6.87), ('s', [], '2H', 5.81, 5.81), ('s', [], '3H', 3.78, 3.78)]
12
9
12
10.1021_acs.orglett.3c03142
COc1ccc(C#N)c(Cn2nnc3ccccc3c2=O)c1
8
8
[0.10659766 0.11328126 0.28969158 0.16269532]
[0.10494071 0.10996094 0.89365298 0.21601563]
13C NMR
125 MHz
CDCl3
162.8, 155.2, 144.0, 140.9, 134.9, 134.8, 132.6, 128.4, 125.1, 119.7, 117.4, 114.7, 113.7, 103.9, 55.6, 51.1
null
[(162.8, None, None), (155.2, None, None), (144.0, None, None), (140.9, None, None), (134.9, None, None), (134.8, None, None), (132.6, None, None), (128.4, None, None), (125.1, None, None), (119.7, None, None), (117.4, None, None), (114.7, None, None), (113.7, None, None), (103.9, None, None), (55.6, None, None), (51.1...
16
16
16
10.1021_acs.orglett.3c03142
c1(C#N)cc(Cl)ccc1Cn1nnc2ccccc2c1=O
8
8
[0.10901407 0.25468751 0.28416839 0.30390628]
[0.10438839 0.25019532 0.89475756 0.35625003]
1H NMR
500 MHz
CDCl3
8.36 (d, J = 7.5 Hz, 1H), 8.20 (d, J = 8.0 Hz, 1H), 7.99 (t, J = 8.3 Hz, 1H), 7.83 (t, J = 8.0 Hz, 1H), 7.69 (d, J = 2.0 Hz, 1H), 7.51 (dd, J = 8.5, 2.0 Hz, 1H), 7.41 (d, J = 8.5 Hz, 1H), 5.82 (s, 2H)
null
[('d', ['7.5Hz'], '1H', 8.36, 8.36), ('d', ['8.0Hz'], '1H', 8.2, 8.2), ('t', ['8.3Hz'], '1H', 7.99, 7.99), ('t', ['8.0Hz'], '1H', 7.83, 7.83), ('d', ['2.0Hz'], '1H', 7.69, 7.69), ('dd', ['8.5Hz', '2.0Hz'], '1H', 7.51, 7.51), ('d', ['8.5Hz'], '1H', 7.41, 7.41), ('s', [], '2H', 5.82, 5.82)]
9
8
9
10.1021_acs.orglett.3c03142
c1(C#N)cc(Cl)ccc1Cn1nnc2ccccc2c1=O
8
8
[0.10901407 0.25468751 0.28416839 0.30390628]
[0.10438839 0.25019532 0.89475756 0.35625003]
13C NMR
125 MHz
CDCl3
155.2, 144.0, 137.4, 135.1, 134.5, 133.3, 132.7, 132.5, 130.3, 128.5, 125.1, 119.7, 115.8, 114.1, 50.7
null
[(155.2, None, None), (144.0, None, None), (137.4, None, None), (135.1, None, None), (134.5, None, None), (133.3, None, None), (132.7, None, None), (132.5, None, None), (130.3, None, None), (128.5, None, None), (125.1, None, None), (119.7, None, None), (115.8, None, None), (114.1, None, None), (50.7, None, None)]
15
15
15
10.1021_acs.orglett.3c03142
c1(C#N)cc(F)ccc1Cn1nnc2ccccc2c1=O
8
8
[0.1077023 0.39414065 0.2861015 0.44335941]
[0.10273143 0.38984376 0.89420532 0.51250003]
1H NMR
600 MHz
CDCl3
8.36 (d, J = 8.4 Hz, 1H), 8.19 (d, J = 8.4 Hz, 1H), 7.98 (t, J = 7.8 Hz, 1H), 7.83 (t, J = 7.5 Hz, 1H), 7.49 (dd, J = 8.7, 5.1 Hz, 1H), 7.41 (dd, J = 7.8, 2.4 Hz, 1H), 7.27-7.25 (m, 1H), 5.82 (s, 2H)
null
[('d', ['8.4Hz'], '1H', 8.36, 8.36), ('d', ['8.4Hz'], '1H', 8.19, 8.19), ('t', ['7.8Hz'], '1H', 7.98, 7.98), ('t', ['7.5Hz'], '1H', 7.83, 7.83), ('dd', ['8.7Hz', '5.1Hz'], '1H', 7.49, 7.49), ('dd', ['7.8Hz', '2.4Hz'], '1H', 7.41, 7.41), ('m', [], '1H', 7.27, 7.25), ('s', [], '2H', 5.82, 5.82)]
9
8
9
10.1021_acs.orglett.3c03142
c1(C#N)cc(F)ccc1Cn1nnc2ccccc2c1=O
8
8
[0.1077023 0.39414065 0.2861015 0.44335941]
[0.10273143 0.38984376 0.89420532 0.51250003]
13C NMR
150 MHz
CDCl3
161.6 (JC-F= 250 Hz), 155.4, 144.2, 135.21, 135.17, 132.8, 131.3 (JC-F= 8 Hz), 128.6, 125.2, 120.8, 120.7, 119.9, 119.81, 119.77, 115.9, 114.2 (JC-F= 9 Hz), 108.5, 50.5
null
[(161.6, None, 250.0), (155.4, None, None), (144.2, None, None), (135.21, None, None), (135.17, None, None), (132.8, None, None), (131.3, None, 8.0), (128.6, None, None), (125.2, None, None), (120.8, None, None), (120.7, None, None), (119.9, None, None), (119.81, None, None), (119.77, None, None), (115.9, None, None), ...
15
15
18
10.1021_acs.orglett.3c03142
C(F)(F)(F)c1ccc(Cn2nnc3ccccc3c2=O)c(C#N)c1
8
8
[0.10963542 0.55117189 0.29272935 0.60039065]
[0.10549303 0.54570315 0.89144372 0.65156254]
1H NMR
700 MHz
CDCl3
8.36 (d, J = 7.7 Hz, 1H), 8.21 (d, J = 8.4 Hz, 1H), 8.00 (t, J = 8.4 Hz, 1H), 7.98 (s, 1H), 7.85 (t, J = 8.0 Hz, 1H), 7.78 (d, J = 8.4 Hz, 1H), 7.58 (d, J = 7.7 Hz, 1H), 5.90 (s, 2H)
null
[('d', ['7.7Hz'], '1H', 8.36, 8.36), ('d', ['8.4Hz'], '1H', 8.21, 8.21), ('t', ['8.4Hz'], '1H', 8.0, 8.0), ('s', [], '1H', 7.98, 7.98), ('t', ['8.0Hz'], '1H', 7.85, 7.85), ('d', ['8.4Hz'], '1H', 7.78, 7.78), ('d', ['7.7Hz'], '1H', 7.58, 7.58), ('s', [], '2H', 5.9, 5.9)]
9
8
9
10.1021_acs.orglett.3c03142
C(F)(F)(F)c1ccc(Cn2nnc3ccccc3c2=O)c(C#N)c1
8
8
[0.10963542 0.55117189 0.29272935 0.60039065]
[0.10549303 0.54570315 0.89144372 0.65156254]
13C NMR
175 MHz
CDCl3
155.4, 144.1, 142.9, 135.3, 132.9, 131.2 (JC-F= 34 Hz), 130.0 (JC-F= 4 Hz), 129.7 (JC-F= 3 Hz), 129.5, 128.6 125.2, 122.6 (JC-F= 271 Hz), 119.7, 115.7, 113.4, 50.9
null
[(155.4, None, None), (128.6, None, None), (144.1, None, None), (142.9, None, None), (135.3, None, None), (132.9, None, None), (131.2, None, 34.0), (130.0, None, 4.0), (129.7, None, 3.0), (129.5, None, None), (125.2, None, None), (122.6, None, 271.0), (119.7, None, None), (115.7, None, None), (113.4, None, None), (50.9...
16
16
16
10.1021_acs.orglett.3c03142
COC(=O)c1ccc(Cn2nnc3ccccc3c2=O)c(C#N)c1
8
8
[0.11129238 0.69140632 0.31758373 0.73984381]
[0.10273143 0.6667969 0.67382982 0.68007814]
1H NMR
500 MHz
CDCl3
8.38-8.35 (m, 2H), 8.21 (d, J = 8.5 Hz, 1H), 8.17 (dd, J = 8.3, 1.8 Hz, 1H), 8.00 (t, J = 7.8 Hz, 1H), 7.84 (t, J = 7.5 Hz, 1H), 7.48 (d, J = 8.5 Hz, 1H), 5.90 (s, 2H), 3.94 (s, 3H)
null
[('m', [], '2H', 8.38, 8.35), ('d', ['8.5Hz'], '1H', 8.21, 8.21), ('dd', ['8.3Hz', '1.8Hz'], '1H', 8.17, 8.17), ('t', ['7.8Hz'], '1H', 8.0, 8.0), ('t', ['7.5Hz'], '1H', 7.84, 7.84), ('d', ['8.5Hz'], '1H', 7.48, 7.48), ('s', [], '2H', 5.9, 5.9), ('s', [], '3H', 3.94, 3.94)]
12
9
12
10.1021_acs.orglett.3c03142
COC(=O)c1ccc(Cn2nnc3ccccc3c2=O)c(C#N)c1
8
8
[0.11129238 0.69140632 0.31758373 0.73984381]
[0.10273143 0.6667969 0.67382982 0.68007814]
13C NMR
125 MHz
CDCl3
164.6, 155.3, 144.0, 143.3, 135.2, 134.1, 133.7, 132.8, 130.5, 128.8, 128.5, 125.1, 119.6, 116.2, 112.7, 52.6, 50.9
null
[(164.6, None, None), (155.3, None, None), (144.0, None, None), (143.3, None, None), (135.2, None, None), (134.1, None, None), (133.7, None, None), (132.8, None, None), (130.5, None, None), (128.8, None, None), (128.5, None, None), (125.1, None, None), (119.6, None, None), (116.2, None, None), (112.7, None, None), (52....
17
17
17
10.1021_acs.orglett.3c03142
c1(OC(=O)c2ccccc2)ccc(Cn2nnc3ccccc3c2=O)c(C#N)c1
9
9
[0.11156854 0.29570314 0.29383398 0.34492188]
[0.10328375 0.27226564 0.67548678 0.28554689]
1H NMR
500 MHz
CDCl3
8.37 (d, J = 8.0 Hz, 1H), 8.20 (d, J = 8.0 Hz, 1H), 8.16 (d, J = 8.0 Hz, 2H), 7.98 (t, J = 7.8 Hz, 1H), 7.83 (t, J = 7.5 Hz, 1H), 7.65 (t, J = 7.3 Hz, 1H), 7.60 (s, 1H), 7.56 (d, J = 8.5, 1H), 7.51 (t, J = 7.8, 2H), 7.43 (d, J = 8.5 Hz, 1H), 5.87 (s, 2H)
null
[('d', ['8.0Hz'], '1H', 8.37, 8.37), ('d', ['8.0Hz'], '1H', 8.2, 8.2), ('d', ['8.0Hz'], '2H', 8.16, 8.16), ('t', ['7.8Hz'], '1H', 7.98, 7.98), ('t', ['7.5Hz'], '1H', 7.83, 7.83), ('t', ['7.3Hz'], '1H', 7.65, 7.65), ('s', [], '1H', 7.6, 7.6), ('d', "['8.5Hz']", '1H', 7.56, 7.56), ('t', "['7.8Hz']", '2H', 7.51, 7.51), ('...
14
11
14
10.1021_acs.orglett.3c03142
c1(OC(=O)c2ccccc2)ccc(Cn2nnc3ccccc3c2=O)c(C#N)c1
9
9
[0.11156854 0.29570314 0.29383398 0.34492188]
[0.10328375 0.27226564 0.67548678 0.28554689]
13C NMR
125 MHz
CDCl3
164.3, 155.4, 150.5, 144.1, 136.5, 135.2, 134.1, 132.8, 130.5, 130.2, 128.7, 128.6, 128.4, 126.9, 126.2, 125.2, 119.8, 116.3, 113.7, 50.6
null
[(164.3, None, None), (155.4, None, None), (150.5, None, None), (144.1, None, None), (136.5, None, None), (135.2, None, None), (134.1, None, None), (132.8, None, None), (130.5, None, None), (130.2, None, None), (128.7, None, None), (128.6, None, None), (128.4, None, None), (126.9, None, None), (126.2, None, None), (125...
22
20
20
10.1021_acs.orglett.3c03142
O(c1ccc(Cn2nnc3ccccc3c2=O)c(C#N)c1)[Si](C)(C)C(C)(C)C
9
9
[0.11156854 0.45312504 0.33028706 0.50234376]
[0.10328375 0.42890626 0.80638649 0.44140629]
1H NMR
500 MHz
CDCl3
8.37 (d, J = 7.5 Hz, 1H), 8.19 (d, J = 8.5 Hz, 1H), 7.96 (t, J = 7.8 Hz, 1H), 7.81 (t, J = 7.5 Hz, 1H), 7.36 (d, J = 8.5 Hz, 1H), 7.12 (s, 1H), 6.99 (d, J = 11.0 Hz, 1H), 5.78 (s, 2H), 0.95 (s, 9H), 0.19 (s, 6H)
null
[('d', ['7.5Hz'], '1H', 8.37, 8.37), ('d', ['8.5Hz'], '1H', 8.19, 8.19), ('t', ['7.8Hz'], '1H', 7.96, 7.96), ('t', ['7.5Hz'], '1H', 7.81, 7.81), ('d', ['8.5Hz'], '1H', 7.36, 7.36), ('s', [], '1H', 7.12, 7.12), ('d', ['11.0Hz'], '1H', 6.99, 6.99), ('s', [], '2H', 5.78, 5.78), ('s', [], '9H', 0.95, 0.95), ('s', [], '6H',...
24
10
24
10.1021_acs.orglett.3c03142
O(c1ccc(Cn2nnc3ccccc3c2=O)c(C#N)c1)[Si](C)(C)C(C)(C)C
9
9
[0.11156854 0.45312504 0.33028706 0.50234376]
[0.10328375 0.42890626 0.80638649 0.44140629]
13C NMR
125 MHz
CDCl3
155.5, 155.3, 144.1, 135.0, 132.6, 131.4, 130.7, 128.4, 125.1, 123.9, 119.8, 116.9, 113.5, 50.5, 25.4, 18.0,-4.6
null
[(155.5, None, None), (155.3, None, None), (144.1, None, None), (135.0, None, None), (132.6, None, None), (131.4, None, None), (130.7, None, None), (128.4, None, None), (125.1, None, None), (123.9, None, None), (119.8, None, None), (116.9, None, None), (113.5, None, None), (50.5, None, None), (25.4, None, None), (18.0,...
21
18
17
10.1021_acs.orglett.3c03142
C(C)(C)(C)c1cc(Cn2nnc3ccccc3c2=O)c(C#N)c(C(C)(C)C)c1
9
9
[0.10956638 0.58828126 0.28030216 0.64375004]
[0.10328375 0.56875001 0.70034116 0.58203129]
1H NMR
500 MHz
CDCl3
8.39 (d, J = 8.0 Hz, 1H), 8.20 (d, J = 8.0 Hz, 1H), 7.97 (t, J = 7.8 Hz, 1H), 7.82 (t, J = 7.5 Hz, 1H), 7.45 (s, 1H), 7.18 (s, 1H), 5.89 (s, 2H), 1.56 (s, 9H), 1.22 (s, 9H)
null
[('d', ['8.0Hz'], '1H', 8.39, 8.39), ('d', ['8.0Hz'], '1H', 8.2, 8.2), ('t', ['7.8Hz'], '1H', 7.97, 7.97), ('t', ['7.5Hz'], '1H', 7.82, 7.82), ('s', [], '1H', 7.45, 7.45), ('s', [], '1H', 7.18, 7.18), ('s', [], '2H', 5.89, 5.89), ('s', [], '9H', 1.56, 1.56), ('s', [], '9H', 1.22, 1.22)]
26
9
26
10.1021_acs.orglett.3c03142
C(C)(C)(C)c1cc(Cn2nnc3ccccc3c2=O)c(C#N)c(C(C)(C)C)c1
9
9
[0.10956638 0.58828126 0.28030216 0.64375004]
[0.10328375 0.56875001 0.70034116 0.58203129]
13C NMR
125 MHz
CDCl3
156.0, 155.4, 154.3, 144.1, 140.8, 135.0, 132.6, 128.5, 125.3, 123.0, 122.8, 119.8, 118.4, 107.7, 51.6, 36.0, 35.3, 30.9, 30.2
null
[(156.0, None, None), (155.4, None, None), (154.3, None, None), (144.1, None, None), (140.8, None, None), (135.0, None, None), (132.6, None, None), (128.5, None, None), (125.3, None, None), (123.0, None, None), (122.8, None, None), (119.8, None, None), (118.4, None, None), (107.7, None, None), (51.6, None, None), (36.0...
23
19
19
10.1021_acs.orglett.3c03142
c1(C#N)cc2c(cc1Cn1nnc3ccccc3c1=O)OCO2
9
9
[0.11156854 0.73164067 0.28554919 0.78085943]
[0.30129029 0.72812506 0.89144372 0.78593753]
1H NMR
500 MHz
CDCl3
8.36 (d, J = 8.0 Hz, 1H), 8.19 (d, J = 8.5 Hz, 1H), 7.97 (t, J = 7.8 Hz, 1H), 7.82 (t, J = 7.8 Hz, 1H), 7.05 (s, 1H), 6.90 (s, 1H), 6.03 (s, 2H), 5.76 (s, 2H)
null
[('d', ['8.0Hz'], '1H', 8.36, 8.36), ('d', ['8.5Hz'], '1H', 8.19, 8.19), ('t', ['7.8Hz'], '1H', 7.97, 7.97), ('t', ['7.8Hz'], '1H', 7.82, 7.82), ('s', [], '1H', 7.05, 7.05), ('s', [], '1H', 6.9, 6.9), ('s', [], '2H', 6.03, 6.03), ('s', [], '2H', 5.76, 5.76)]
10
8
10
10.1021_acs.orglett.3c03142
c1(C#N)cc2c(cc1Cn1nnc3ccccc3c1=O)OCO2
9
9
[0.11156854 0.73164067 0.28554919 0.78085943]
[0.30129029 0.72812506 0.89144372 0.78593753]
13C NMR
125 MHz
CDCl3
155.4, 151.9, 147.7, 144.1, 135.4, 135.1, 132.7, 128.5, 125.2, 119.8, 117.3, 111.5, 109.2, 105.2, 102.6, 50.9
null
[(155.4, None, None), (151.9, None, None), (147.7, None, None), (144.1, None, None), (135.4, None, None), (135.1, None, None), (132.7, None, None), (128.5, None, None), (125.2, None, None), (119.8, None, None), (117.3, None, None), (111.5, None, None), (109.2, None, None), (105.2, None, None), (102.6, None, None), (50....
16
16
16
10.1021_acs.orglett.3c03142
c1(C#N)c(Cn2nnc3ccccc3c2=O)ccc2ccccc12
10
10
[0.11101622 0.11240235 0.28113062 0.16767579]
[0.10604534 0.10996094 0.89365298 0.21582033]
1H NMR
500 MHz
CDCl3
8.35 (d, J = 7.5 Hz, 1H), 8.30 (d, J = 8.5 Hz, 1H), 8.18 (d, J = 8.0 Hz, 1H), 8.00-7.94 (m, 2H), 7.87 (d, J = 8.0 Hz, 1H), 7.81 (t, J = 7.0 Hz, 1H), 7.70 (t, J = 8.0 Hz, 1H), 7.60 (t, J = 7.0 Hz, 1H), 7.52 (d, J = 8.5 Hz, 1H), 6.05 (s, 2H)
null
[('d', ['7.5Hz'], '1H', 8.35, 8.35), ('d', ['8.5Hz'], '1H', 8.3, 8.3), ('d', ['8.0Hz'], '1H', 8.18, 8.18), ('m', [], '2H', 8.0, 7.94), ('d', ['8.0Hz'], '1H', 7.87, 7.87), ('t', ['7.0Hz'], '1H', 7.81, 7.81), ('t', ['8.0Hz'], '1H', 7.7, 7.7), ('t', ['7.0Hz'], '1H', 7.6, 7.6), ('d', ['8.5Hz'], '1H', 7.52, 7.52), ('s', [],...
12
11
12
10.1021_acs.orglett.3c03142
c1(C#N)c(Cn2nnc3ccccc3c2=O)ccc2ccccc12
10
10
[0.11101622 0.11240235 0.28113062 0.16767579]
[0.10604534 0.10996094 0.89365298 0.21582033]
13C NMR
125 MHz
CDCl3
155.4, 144.1, 139.3, 135.1, 133.3, 132.7, 132.5, 132.2, 129.0, 128.5, 128.4, 127.7, 125.5, 125.2, 124.9, 119.8, 116.0, 110.1, 51.8
null
[(155.4, None, None), (144.1, None, None), (139.3, None, None), (135.1, None, None), (133.3, None, None), (132.7, None, None), (132.5, None, None), (132.2, None, None), (129.0, None, None), (128.5, None, None), (128.4, None, None), (127.7, None, None), (125.5, None, None), (125.2, None, None), (124.9, None, None), (119...
19
19
19
10.1021_acs.orglett.3c03142
COc1c(C#N)c(Cn2nnc3ccccc3c2=O)c(OC)c2ccccc12
10
10
[0.10963542 0.25859376 0.28692998 0.31953126]
[0.10714998 0.23164063 0.72685246 0.24414064]
1H NMR
500 MHz
CDCl3
8.39 (d, J = 8.5 Hz, 1H), 8.22 (d, J = 8.0 Hz, 1H), 8.14 (d, J = 8.0 Hz, 1H), 8.08 (d, J = 8.5 Hz, 1H), 7.94 (t, J = 7.8 Hz, 1H), 7.80 (t, J = 7.5 Hz, 1H), 7.68 (t, J = 7.8 Hz, 1H), 7.63 (t, J = 7.8 Hz, 1H), 5.94 (s, 2H), 4.23 (s, 3H), 3.95 (s, 3H)
null
[('d', ['8.5Hz'], '1H', 8.39, 8.39), ('d', ['8.0Hz'], '1H', 8.22, 8.22), ('d', ['8.0Hz'], '1H', 8.14, 8.14), ('d', ['8.5Hz'], '1H', 8.08, 8.08), ('t', ['7.8Hz'], '1H', 7.94, 7.94), ('t', ['7.5Hz'], '1H', 7.8, 7.8), ('t', ['7.8Hz'], '1H', 7.68, 7.68), ('t', ['7.8Hz'], '1H', 7.63, 7.63), ('s', [], '2H', 5.94, 5.94), ('s'...
16
11
16
10.1021_acs.orglett.3c03142
COc1c(C#N)c(Cn2nnc3ccccc3c2=O)c(OC)c2ccccc12
10
10
[0.10963542 0.25859376 0.28692998 0.31953126]
[0.10714998 0.23164063 0.72685246 0.24414064]
13C NMR
125 MHz
CDCl3
158.8, 155.4, 151.8, 143.9, 134.9, 132.4, 130.8, 129.6, 128.4, 128.3, 127.8, 125.2, 123.5, 122.8, 119.7, 115.3, 102.4, 63.2, 62.6, 46.7
null
[(158.8, None, None), (155.4, None, None), (151.8, None, None), (143.9, None, None), (134.9, None, None), (132.4, None, None), (130.8, None, None), (129.6, None, None), (128.4, None, None), (128.3, None, None), (127.8, None, None), (125.2, None, None), (123.5, None, None), (122.8, None, None), (119.7, None, None), (115...
21
21
20
10.1021_acs.orglett.3c03142
C(#N)c1sccc1Cn1nnc2ccccc2c1=O
10
10
[0.11101622 0.40937501 0.24799145 0.45937501]
[0.10328375 0.38671879 0.67272519 0.39921878]
1H NMR
500 MHz
CDCl3
8.37 (d, J = 7.5 Hz, 1H), 8.19 (d, J = 8.0 Hz, 1H), 7.97 (t, J = 7.8 Hz, 1H), 7.82 (t, J = 7.5 Hz, 1H), 7.53 (d, J = 5.0 Hz, 1H), 7.19 (d, J = 5.0 Hz, 1H), 5.77 (s, 2H)
null
[('d', ['7.5Hz'], '1H', 8.37, 8.37), ('d', ['8.0Hz'], '1H', 8.19, 8.19), ('t', ['7.8Hz'], '1H', 7.97, 7.97), ('t', ['7.5Hz'], '1H', 7.82, 7.82), ('d', ['5.0Hz'], '1H', 7.53, 7.53), ('d', ['5.0Hz'], '1H', 7.19, 7.19), ('s', [], '2H', 5.77, 5.77)]
8
7
8
10.1021_acs.orglett.3c03142
C(#N)c1sccc1Cn1nnc2ccccc2c1=O
10
10
[0.11101622 0.40937501 0.24799145 0.45937501]
[0.10328375 0.38671879 0.67272519 0.39921878]
13C NMR
125 MHz
CDCl3
155.2, 146.1, 144.1, 135.1, 132.7, 132.5, 128.5, 128.3, 125.1, 119.7, 112.9, 108.6, 47.1
null
[(155.2, None, None), (146.1, None, None), (144.1, None, None), (135.1, None, None), (132.7, None, None), (132.5, None, None), (128.5, None, None), (128.3, None, None), (125.1, None, None), (119.7, None, None), (112.9, None, None), (108.6, None, None), (47.1, None, None)]
13
13
13
10.1021_acs.orglett.3c03142
C(#N)c1ncccc1Cn1nnc2ccccc2c1=O
10
10
[0.11156854 0.53437504 0.25793321 0.58359377]
[0.10052215 0.53046879 0.89144372 0.63593754]
1H NMR
500 MHz
CDCl3
8.67 (d, J = 4.5 Hz, 1H), 8.36 (d, J = 7.5 Hz, 1H), 8.21 (d, J = 8.0 Hz, 1H), 8.00 (t, J = 7.8 Hz, 1H), 7.84 (t, J = 8.0 Hz, 2H), 7.48 (dd, J = 8.0, 5.0 Hz, 1H), 5.88 (s, 2H)
null
[('d', ['4.5Hz'], '1H', 8.67, 8.67), ('d', ['7.5Hz'], '1H', 8.36, 8.36), ('d', ['8.0Hz'], '1H', 8.21, 8.21), ('t', ['7.8Hz'], '1H', 8.0, 8.0), ('t', ['8.0Hz'], '2H', 7.84, 7.84), ('dd', ['8.0Hz', '5.0Hz'], '1H', 7.48, 7.48), ('s', [], '2H', 5.88, 5.88)]
9
8
9
10.1021_acs.orglett.3c03142
C(#N)c1ncccc1Cn1nnc2ccccc2c1=O
10
10
[0.11156854 0.53437504 0.25793321 0.58359377]
[0.10052215 0.53046879 0.89144372 0.63593754]
13C NMR
125 MHz
CDCl3
155.2, 150.1, 143.9, 136.8, 135.8, 135.2, 133.4, 132.8, 128.5, 126.7, 124.9, 119.5, 115.4, 49.7
null
[(155.2, None, None), (150.1, None, None), (143.9, None, None), (136.8, None, None), (135.8, None, None), (135.2, None, None), (133.4, None, None), (132.8, None, None), (128.5, None, None), (126.7, None, None), (124.9, None, None), (119.5, None, None), (115.4, None, None), (49.7, None, None)]
14
14
14
10.1021_acs.orglett.3c03142
C(#N)c1nc2ccccc2cc1Cn1nnc2ccccc2c1=O
10
10
[0.10935927 0.67421876 0.29134855 0.72421881]
[0.24522985 0.67070315 0.89144372 0.7285157 ]
1H NMR
400 MHz
CDCl3
8.36 (d, J = 7.6 Hz, 1H), 8.26 (s, 1H), 8.21 (d, J = 8.4 Hz, 1H), 8.16 (d, J = 8.8 Hz, 1H), 7.99 (t, J = 7.6 Hz, 1H), 7.85-7.79 (m, 3H), 7.66 (t, J = 7.6 Hz, 1H), 6.02 (s, 2H)
null
[('d', ['7.6Hz'], '1H', 8.36, 8.36), ('s', [], '1H', 8.26, 8.26), ('d', ['8.4Hz'], '1H', 8.21, 8.21), ('d', ['8.8Hz'], '1H', 8.16, 8.16), ('t', ['7.6Hz'], '1H', 7.99, 7.99), ('m', [], '3H', 7.85, 7.79), ('t', ['7.6Hz'], '1H', 7.66, 7.66), ('s', [], '2H', 6.02, 6.02)]
11
10
11
10.1021_acs.orglett.3c03142
C(#N)c1nc2ccccc2cc1Cn1nnc2ccccc2c1=O
10
10
[0.10935927 0.67421876 0.29134855 0.72421881]
[0.24522985 0.67070315 0.89144372 0.7285157 ]
13C NMR
100 MHz
CDCl3
155.2, 147.3, 143.9, 136.7, 135.1, 133.5, 132.7, 131.2, 130.2, 129.64, 129.57, 128.5, 128.2, 127.6, 125.1, 119.6, 115.8, 49.8
null
[(155.2, None, None), (147.3, None, None), (143.9, None, None), (136.7, None, None), (135.1, None, None), (133.5, None, None), (132.7, None, None), (131.2, None, None), (130.2, None, None), (129.64, None, None), (129.57, None, None), (128.5, None, None), (128.2, None, None), (127.6, None, None), (125.1, None, None), (1...
18
18
18
10.1021_acs.orglett.3c03142
C(#N)CCCn1nnc2ccccc2c1=O
10
10
[0.10984254 0.81484376 0.25959018 0.86484381]
[0.09113272 0.81093751 0.8953099 0.90156254]
1H NMR
600 MHz
CDCl3
8.33 (d, J = 8.4 Hz, 1H), 8.14 (d, J = 8.4 Hz, 1H), 7.95 (t, J = 7.8 Hz, 1H), 7.80 (t, J = 7.5 Hz, 1H), 4.59 (t, J = 6.6 Hz, 2H), 2.50 (t, J = 7.2 Hz, 2H), 2.28 (quint, J = 7.2 Hz, 2H)
null
[('d', ['8.4Hz'], '1H', 8.33, 8.33), ('d', ['8.4Hz'], '1H', 8.14, 8.14), ('t', ['7.8Hz'], '1H', 7.95, 7.95), ('t', ['7.5Hz'], '1H', 7.8, 7.8), ('t', ['6.6Hz'], '2H', 4.59, 4.59), ('t', ['7.2Hz'], '2H', 2.5, 2.5), ('p', ['7.2Hz'], '2H', 2.28, 2.28)]
10
7
10
10.1021_acs.orglett.3c03142
C(#N)CCCn1nnc2ccccc2c1=O
10
10
[0.10984254 0.81484376 0.25959018 0.86484381]
[0.09113272 0.81093751 0.8953099 0.90156254]
13C NMR
150 MHz
CDCl3
155.6, 144.1, 135.0, 132.6, 128.4, 125.0, 119.6, 118.5, 48.1, 24.8, 14.9
null
[(155.6, None, None), (144.1, None, None), (135.0, None, None), (132.6, None, None), (128.4, None, None), (125.0, None, None), (119.6, None, None), (118.5, None, None), (48.1, None, None), (24.8, None, None), (14.9, None, None)]
11
11
11
10.1021_acs.orglett.3c03142
C(#N)CCCCn1nnc2ccccc2c1=O
11
11
[0.10742615 0.13945314 0.27201737 0.18847658]
[0.28831078 0.13632813 0.89033904 0.19453126]
1H NMR
600 MHz
CDCl3
8.36 (d, J = 7.8 Hz, 1H), 8.17 (d, J = 7.8 Hz, 1H), 7.96 (t, J = 7.5 Hz, 1H), 7.82 (t, J = 7.5 Hz, 1H), 4.53 (t, J = 6.9 Hz, 2H), 2.46 (t, J = 7.2 Hz, 2H), 2.11 (quint, J = 7.5 Hz, 2H), 1.79 (quint, J = 7.5 Hz, 2H)
null
[('d', ['7.8Hz'], '1H', 8.36, 8.36), ('d', ['7.8Hz'], '1H', 8.17, 8.17), ('t', ['7.5Hz'], '1H', 7.96, 7.96), ('t', ['7.5Hz'], '1H', 7.82, 7.82), ('t', ['6.9Hz'], '2H', 4.53, 4.53), ('t', ['7.2Hz'], '2H', 2.46, 2.46), ('p', ['7.5Hz'], '2H', 2.11, 2.11), ('p', ['7.5Hz'], '2H', 1.79, 1.79)]
12
8
12
10.1021_acs.orglett.3c03142
C(#N)CCCCn1nnc2ccccc2c1=O
11
11
[0.10742615 0.13945314 0.27201737 0.18847658]
[0.28831078 0.13632813 0.89033904 0.19453126]
13C NMR
150 MHz
CDCl3
155.6, 144.2, 134.9, 132.5, 128.4, 125.1, 119.7, 119.1, 48.4, 27.8, 22.5, 16.7
null
[(155.6, None, None), (144.2, None, None), (134.9, None, None), (132.5, None, None), (128.4, None, None), (125.1, None, None), (119.7, None, None), (119.1, None, None), (48.4, None, None), (27.8, None, None), (22.5, None, None), (16.7, None, None)]
12
12
12
10.1021_acs.orglett.3c03142
O=c1c2ccccc2nc2n1Cc1ccccc1-2
11
11
[0.10991158 0.31933594 0.23142187 0.37675784]
[0.10494071 0.31914065 0.89144372 0.42421876]
1H NMR
700 MHz
CDCl3
8.38 (d, J = 9.1 Hz, 1H), 8.18 (d, J = 7.7 Hz, 1H), 7.83 (d, J = 7.7 Hz, 1H), 7.78 (t, J = 8.4 Hz, 1H), 7.65-7.63 (m, 2H), 7.58 (t, J = 8.1 Hz, 1H), 7.49 (t, J = 8.1 Hz, 1H), 5.15 (s, 2H)
null
[('d', ['9.1Hz'], '1H', 8.38, 8.38), ('d', ['7.7Hz'], '1H', 8.18, 8.18), ('d', ['7.7Hz'], '1H', 7.83, 7.83), ('t', ['8.4Hz'], '1H', 7.78, 7.78), ('m', [], '2H', 7.65, 7.63), ('t', ['8.1Hz'], '1H', 7.58, 7.58), ('t', ['8.1Hz'], '1H', 7.49, 7.49), ('s', [], '2H', 5.15, 5.15)]
10
9
10
10.1021_acs.orglett.3c03142
O=c1c2ccccc2nc2n1Cc1ccccc1-2
11
11
[0.10991158 0.31933594 0.23142187 0.37675784]
[0.10494071 0.31914065 0.89144372 0.42421876]
13C NMR
175 MHz
CDCl3
160.6, 154.9, 149.5, 139.6, 134.2, 132.7, 132.3, 128.9, 127.4, 126.5, 126.4, 123.52, 123.47, 120.6, 49.8
null
[(160.6, None, None), (154.9, None, None), (149.5, None, None), (139.6, None, None), (134.2, None, None), (132.7, None, None), (132.3, None, None), (128.9, None, None), (127.4, None, None), (126.5, None, None), (126.4, None, None), (123.52, None, None), (123.47, None, None), (120.6, None, None), (49.8, None, None)]
15
15
15
10.1021_acs.orglett.3c03142
O=c1c2ccc(Cl)cc2nc2n1Cc1ccccc1-2
11
11
[0.10721903 0.45976565 0.266218 0.51601564]
[0.09444664 0.45937501 0.89641458 0.56406252]
1H NMR
500 MHz
CDCl3
8.31 (d, J = 8.5 Hz, 1H), 8.17 (d, J = 8.0 Hz, 1H), 7.82 (s, 1H), 7.68-7.64 (m, 2H), 7.60 (t, J = 7.3 Hz, 1H), 7.44 (d, J = 8.5 Hz, 1H), 5.15 (s, 2H)
null
[('d', ['8.5Hz'], '1H', 8.31, 8.31), ('d', ['8.0Hz'], '1H', 8.17, 8.17), ('s', [], '1H', 7.82, 7.82), ('m', [], '2H', 7.68, 7.64), ('t', ['7.3Hz'], '1H', 7.6, 7.6), ('d', ['8.5Hz'], '1H', 7.44, 7.44), ('s', [], '2H', 5.15, 5.15)]
9
8
9
10.1021_acs.orglett.3c03142
O=c1c2ccc(Cl)cc2nc2n1Cc1ccccc1-2
11
11
[0.10721903 0.45976565 0.266218 0.51601564]
[0.09444664 0.45937501 0.89641458 0.56406252]
13C NMR
125 MHz
CDCl3
159.9, 156.0, 150.5, 140.4, 139.7, 132.6, 132.4, 128.9, 127.8, 126.92, 126.89, 123.7, 123.5, 119.0, 49.8
null
[(159.9, None, None), (156.0, None, None), (150.5, None, None), (140.4, None, None), (139.7, None, None), (132.6, None, None), (132.4, None, None), (128.9, None, None), (127.8, None, None), (126.92, None, None), (126.89, None, None), (123.7, None, None), (123.5, None, None), (119.0, None, None), (49.8, None, None)]
15
15
15
10.1021_acs.orglett.3c03142
O=c1c2ccc(C(F)(F)F)cc2nc2n1Cc1ccccc1-2
11
11
[0.10797847 0.59921877 0.25931401 0.65546879]
[0.09389432 0.59882817 0.89144372 0.70468756]
1H NMR
600 MHz
CDCl3
8.47 (d, J = 8.4 Hz, 1H), 8.17 (d, J = 7.8 Hz, 1H), 8.09 (s, 1H), 7.68-7.63 (m, 3H), 7.60 (t, J = 7.2 Hz, 1H), 5.16 (s, 2H)
null
[('d', ['8.4Hz'], '1H', 8.47, 8.47), ('d', ['7.8Hz'], '1H', 8.17, 8.17), ('s', [], '1H', 8.09, 8.09), ('m', [], '3H', 7.68, 7.63), ('t', ['7.2Hz'], '1H', 7.6, 7.6), ('s', [], '2H', 5.16, 5.16)]
9
8
9
10.1021_acs.orglett.3c03142
O=c1c2ccc(C(F)(F)F)cc2nc2n1Cc1ccccc1-2
11
11
[0.10797847 0.59921877 0.25931401 0.65546879]
[0.09389432 0.59882817 0.89144372 0.70468756]
13C NMR
150 MHz
CDCl3
159.8, 156.2, 149.6, 139.7, 135.8 (JC-F= 33 Hz), 132.8, 132.3, 129.1, 127.6, 126.2, 124.9 (JC-F= 4 Hz), 123.7, 123.54, 123.52 (JC-F= 271 Hz), 122.8, 122.2 (JC-F= 3 Hz), 49.9
null
[(159.8, None, None), (156.2, None, None), (149.6, None, None), (139.7, None, None), (135.8, None, 33.0), (132.8, None, None), (132.3, None, None), (129.1, None, None), (127.6, None, None), (126.2, None, None), (124.9, None, 4.0), (123.7, None, None), (123.54, None, None), (123.52, None, 271.0), (122.8, None, None), (1...
16
16
17
10.1021_acs.orglett.3c03142
C(=O)(OC)c1ccc2c(=O)n3c(nc2c1)-c1ccccc1C3
11
11
[0.10742615 0.73984381 0.28941541 0.79609379]
[0.10549303 0.73906253 0.89089138 0.84453128]
1H NMR
700 MHz
CDCl3
8.48 (s, 1H), 8.41 (d, J = 8.4 Hz, 1H), 8.18 (d, J = 7.7 Hz, 1H), 8.08 (d, J = 9.1 Hz, 1H), 7.67-7.63 (m, 2H), 7.59 (t, J = 7.4 Hz, 1H), 5.15 (s, 2H), 3.99 (s, 3H)
null
[('s', [], '1H', 8.48, 8.48), ('d', ['8.4Hz'], '1H', 8.41, 8.41), ('d', ['7.7Hz'], '1H', 8.18, 8.18), ('d', ['9.1Hz'], '1H', 8.08, 8.08), ('m', [], '2H', 7.67, 7.63), ('t', ['7.4Hz'], '1H', 7.59, 7.59), ('s', [], '2H', 5.15, 5.15), ('s', [], '3H', 3.99, 3.99)]
12
9
12
10.1021_acs.orglett.3c03142
C(=O)(OC)c1ccc2c(=O)n3c(nc2c1)-c1ccccc1C3
11
11
[0.10742615 0.73984381 0.28941541 0.79609379]
[0.10549303 0.73906253 0.89089138 0.84453128]
13C NMR
175 MHz
CDCl3
166.1, 160.1, 155.6, 149.4, 139.6, 135.3, 132.6, 132.4, 129.3, 129.0, 126.8, 126.3, 123.7, 123.5, 52.6, 49.8
null
[(166.1, None, None), (160.1, None, None), (155.6, None, None), (149.4, None, None), (139.6, None, None), (135.3, None, None), (132.6, None, None), (132.4, None, None), (129.3, None, None), (129.0, None, None), (126.8, None, None), (126.3, None, None), (123.7, None, None), (123.5, None, None), (52.6, None, None), (49.8...
17
17
16
10.1021_acs.orglett.3c03142
COc1ccc2c(=O)n3c(nc2c1)-c1ccccc1C3
12
12
[0.10963542 0.11845704 0.2689796 0.17568361]
[0.28416839 0.11015625 0.89144372 0.18359377]
1H NMR
600 MHz
CDCl3
8.27 (d, J = 9.0 Hz, 1H), 8.16 (d, J = 7.2 Hz, 1H), 7.64-7.56 (m, 3H), 7.21 (s, 1H), 7.07 (d, J = 7.8 Hz, 1H), 5.13 (s, 2H), 3.95 (s, 3H)
null
[('d', ['9.0Hz'], '1H', 8.27, 8.27), ('d', ['7.2Hz'], '1H', 8.16, 8.16), ('m', [], '3H', 7.64, 7.56), ('s', [], '1H', 7.21, 7.21), ('d', ['7.8Hz'], '1H', 7.07, 7.07), ('s', [], '2H', 5.13, 5.13), ('s', [], '3H', 3.95, 3.95)]
12
9
12
10.1021_acs.orglett.3c03142
COc1ccc2c(=O)n3c(nc2c1)-c1ccccc1C3
12
12
[0.10963542 0.11845704 0.2689796 0.17568361]
[0.28416839 0.11015625 0.89144372 0.18359377]
13C NMR
150 MHz
CDCl3
164.6, 160.3, 155.6, 151.9, 139.8, 132.7, 132.3, 128.9, 127.9, 123.5, 123.4, 116.5, 114.2, 108.1, 55.7, 49.7
null
[(164.6, None, None), (160.3, None, None), (155.6, None, None), (151.9, None, None), (139.8, None, None), (132.7, None, None), (132.3, None, None), (128.9, None, None), (127.9, None, None), (123.5, None, None), (123.4, None, None), (116.5, None, None), (114.2, None, None), (108.1, None, None), (55.7, None, None), (49.7...
16
16
16
10.1021_acs.orglett.3c03142
O=c1c2cc(F)ccc2nc2n1Cc1ccccc1-2
12
12
[0.1090831 0.25039064 0.25682858 0.30664062]
[0.10935927 0.25000002 0.89365298 0.35546879]
1H NMR
600 MHz
CDCl3
8.15 (d, J = 7.8 Hz, 1H), 8.00 (dd, J = 8.4, 3.0 Hz, 1H), 7.82 (dd, J = 9.0, 4.8 Hz, 1H), 7.66-7.62 (m, 2H), 7.58 (t, J = 7.2 Hz, 1H), 7.50 (td, J = 8.4, 3.0 Hz, 1H), 5.14 (s, 2H)
null
[('d', ['7.8Hz'], '1H', 8.15, 8.15), ('dd', ['8.4Hz', '3.0Hz'], '1H', 8.0, 8.0), ('dd', ['9.0Hz', '4.8Hz'], '1H', 7.82, 7.82), ('m', [], '2H', 7.66, 7.62), ('t', ['7.2Hz'], '1H', 7.58, 7.58), ('td', ['8.4Hz', '3.0Hz'], '1H', 7.5, 7.5), ('s', [], '2H', 5.14, 5.14)]
9
8
9
10.1021_acs.orglett.3c03142
O=c1c2cc(F)ccc2nc2n1Cc1ccccc1-2
12
12
[0.1090831 0.25039064 0.25682858 0.30664062]
[0.10935927 0.25000002 0.89365298 0.35546879]
13C NMR
150 MHz
CDCl3
160.6 (JC-F= 246 Hz), 159.9, 154.4, 146.2, 139.4, 132.5, 132.4, 129.7 (JC-F= 8 Hz), 128.9, 123.5, 123.4, 122.8, 122.7, 121.8 (JC-F= 8 Hz), 111.5, 111.4, 49.8
null
[(160.6, None, 246.0), (159.9, None, None), (154.4, None, None), (146.2, None, None), (139.4, None, None), (132.5, None, None), (132.4, None, None), (129.7, None, 8.0), (128.9, None, None), (123.5, None, None), (123.4, None, None), (122.8, None, None), (122.7, None, None), (121.8, None, 8.0), (111.5, None, None), (111....
15
15
17
10.1021_acs.orglett.3c03142
COc1ccc2nc3n(c(=O)c2c1)Cc1ccccc1-3
12
12
[0.10963542 0.39609377 0.27671208 0.45312504]
[0.29300549 0.3902344 0.89144372 0.46445315]
1H NMR
600 MHz
CDCl3
8.16 (d, J = 7.2 Hz, 1H), 7.78-7.76 (m, 2H), 7.63 (d, J = 4.8 Hz, 2H), 7.59-7.56 (m, 1H), 7.40 (dd, J = 9.0, 3.0 Hz, 1H), 5.17 (s, 2H), 3.95 (s, 3H)
null
[('d', ['7.2Hz'], '1H', 8.16, 8.16), ('m', [], '2H', 7.78, 7.76), ('d', ['4.8Hz'], '2H', 7.63, 7.63), ('m', [], '1H', 7.59, 7.56), ('dd', ['9.0Hz', '3.0Hz'], '1H', 7.4, 7.4), ('s', [], '2H', 5.17, 5.17), ('s', [], '3H', 3.95, 3.95)]
12
9
12
10.1021_acs.orglett.3c03142
COc1ccc2nc3n(c(=O)c2c1)Cc1ccccc1-3
12
12
[0.10963542 0.39609377 0.27671208 0.45312504]
[0.29300549 0.3902344 0.89144372 0.46445315]
13C NMR
150 MHz
CDCl3
160.5, 158.2, 153.1, 144.1, 139.2, 132.9, 131.9, 129.0, 128.9, 124.5, 123.5, 123.2, 121.4, 106.1, 55.9, 49.8
null
[(160.5, None, None), (158.2, None, None), (153.1, None, None), (144.1, None, None), (139.2, None, None), (132.9, None, None), (131.9, None, None), (129.0, None, None), (128.9, None, None), (124.5, None, None), (123.5, None, None), (123.2, None, None), (121.4, None, None), (106.1, None, None), (55.9, None, None), (49.8...
16
16
16
10.1021_acs.orglett.3c03142
O(C)c1cccc2c(=O)n3c(nc12)-c1ccccc1C3
12
12
[0.10887598 0.53554689 0.23418346 0.59882817]
[0.24854379 0.53046879 0.89144372 0.6039063 ]
1H NMR
600 MHz
CDCl3
8.30 (d, J = 7.8 Hz, 1H), 7.98 (dd, J = 7.8, 1.2 Hz, 1H), 7.63-7.62 (m, 2H), 7.58-7.56 (m, 1H), 7.44 (t, J = 8.1 Hz, 1H), 7.26 (d, J = 7.8 Hz, 1H), 5.17 (s, 2H), 4.07 (s, 3H)
null
[('d', ['7.8Hz'], '1H', 8.3, 8.3), ('dd', ['7.8Hz', '1.2Hz'], '1H', 7.98, 7.98), ('m', [], '2H', 7.63, 7.62), ('m', [], '1H', 7.58, 7.56), ('t', ['8.1Hz'], '1H', 7.44, 7.44), ('d', ['7.8Hz'], '1H', 7.26, 7.26), ('s', [], '2H', 5.17, 5.17), ('s', [], '3H', 4.07, 4.07)]
12
9
12
10.1021_acs.orglett.3c03142
O(C)c1cccc2c(=O)n3c(nc12)-c1ccccc1C3
12
12
[0.10887598 0.53554689 0.23418346 0.59882817]
[0.24854379 0.53046879 0.89144372 0.6039063 ]
13C NMR
150 MHz
CDCl3
160.5, 154.5, 154.4, 140.1, 139.6, 132.8, 132.2, 128.7, 126.6, 124.1, 123.3, 121.7, 117.9, 114.1, 56.4, 49.8
null
[(160.5, None, None), (154.5, None, None), (154.4, None, None), (140.1, None, None), (139.6, None, None), (132.8, None, None), (132.2, None, None), (128.7, None, None), (126.6, None, None), (124.1, None, None), (123.3, None, None), (121.7, None, None), (117.9, None, None), (114.1, None, None), (56.4, None, None), (49.8...
16
16
16
10.1021_acs.orglett.3c03142
Cc1cccc2nc3n(c(=O)c12)Cc1ccccc1-3
12
12
[0.10935927 0.67187507 0.23473578 0.72812506]
[0.10162679 0.67031251 0.89144372 0.77578126]
1H NMR
600 MHz
CDCl3
8.18 (d, J = 7.8 Hz, 1H), 7.68 (d, J = 7.8 Hz, 1H), 7.64-7.63 (m, 2H), 7.62 (d, J = 8.4 Hz, 1H), 7.60-7.57(m, 1H), 7.25 (d, J = 7.8 Hz, 1H), 5.12 (s, 2H), 2.96 (s, 3H)
null
[('d', ['7.8Hz'], '1H', 8.18, 8.18), ('d', ['7.8Hz'], '1H', 7.68, 7.68), ('m', [], '2H', 7.64, 7.63), ('d', ['8.4Hz'], '1H', 7.62, 7.62), ('m', [], '1H', 7.6, 7.57), ('d', ['7.8Hz'], '1H', 7.25, 7.25), ('s', [], '2H', 5.12, 5.12), ('s', [], '3H', 2.96, 2.96)]
12
9
12
10.1021_acs.orglett.3c03142
Cc1cccc2nc3n(c(=O)c12)Cc1ccccc1-3
12
12
[0.10935927 0.67187507 0.23473578 0.72812506]
[0.10162679 0.67031251 0.89144372 0.77578126]
13C NMR
150 MHz
CDCl3
161.4, 154.6, 151.2, 141.2, 139.7, 133.3, 132.8, 132.2, 129.2, 128.8, 125.7, 123.5, 119.1, 49.8, 23.1
null
[(161.4, None, None), (154.6, None, None), (151.2, None, None), (141.2, None, None), (139.7, None, None), (133.3, None, None), (132.8, None, None), (132.2, None, None), (129.2, None, None), (128.8, None, None), (125.7, None, None), (123.5, None, None), (119.1, None, None), (49.8, None, None), (23.1, None, None)]
16
16
15
10.1021_acs.orglett.3c03142
O=c1c2cc(F)c(F)cc2nc2n1Cc1ccccc1-2
12
12
[0.10825463 0.81093751 0.25627624 0.86718757]
[0.09996983 0.81093751 0.89144372 0.90156254]
1H NMR
600 MHz
CDCl3
8.15 (d, J = 7.8 Hz, 1H), 8.12 (d, J = 9.6 Hz, 1H), 7.69-7.64 (m, 2H), 7.62-7.58 (m, 2H), 5.15 (s, 2H)
null
[('d', ['7.8Hz'], '1H', 8.15, 8.15), ('d', ['9.6Hz'], '1H', 8.12, 8.12), ('m', [], '2H', 7.69, 7.64), ('m', [], '2H', 7.62, 7.58), ('s', [], '2H', 5.15, 5.15)]
8
7
8
10.1021_acs.orglett.3c03142
O=c1c2cc(F)c(F)cc2nc2n1Cc1ccccc1-2
12
12
[0.10825463 0.81093751 0.25627624 0.86718757]
[0.09996983 0.81093751 0.89144372 0.90156254]
13C NMR
150 MHz
CDCl3
159.3, 154.8 (JC-F= 256 Hz), 154.7 (JC-F= 263 Hz), 150.2 (JC-F= 14 Hz), 148.5 (JC-F= 14 Hz), 147.4 (JC-F= 11 Hz), 139.5, 132.7, 132.3, 129.1, 123.6, 123.5, 117.5 (JC-F= 6 Hz), 115.2, 115.1, 113.9, 113.8, 49.9
null
[(159.3, None, None), (154.8, None, 256.0), (154.7, None, 263.0), (150.2, None, 14.0), (148.5, None, 14.0), (147.4, None, 11.0), (139.5, None, None), (132.7, None, None), (132.3, None, None), (129.1, None, None), (123.6, None, None), (123.5, None, None), (117.5, None, 6.0), (115.2, None, None), (115.1, None, None), (11...
15
15
18
10.1021_acs.orglett.3c03142
O(C)c1cc2nc3n(c(=O)c2cc1OC)Cc1ccccc1-3
13
13
[0.11074007 0.14609375 0.27008423 0.20429688]
[0.11930102 0.21328126 0.64897544 0.22539064]
1H NMR
600 MHz
CDCl3
8.14 (s, 1H), 7.69-7.57 (m, 4H), 7.23 (s, 1H), 5.14 (s, 2H), 4.02 (s, 6H)
null
[('s', [], '1H', 8.14, 8.14), ('m', [], '4H', 7.69, 7.57), ('s', [], '1H', 7.23, 7.23), ('s', [], '2H', 5.14, 5.14), ('s', [], '6H', 4.02, 4.02)]
14
9
14
10.1021_acs.orglett.3c03142
O(C)c1cc2nc3n(c(=O)c2cc1OC)Cc1ccccc1-3
13
13
[0.11074007 0.14609375 0.27008423 0.20429688]
[0.11930102 0.21328126 0.64897544 0.22539064]
13C NMR
150 MHz
CDCl3
160.0, 154.9, 153.9, 148.8, 145.7, 139.4, 132.9, 131.9, 128.8, 123.5, 123.0, 113.9, 107.9, 105.5, 56.32, 56.29, 49.8
null
[(160.0, None, None), (154.9, None, None), (153.9, None, None), (148.8, None, None), (145.7, None, None), (139.4, None, None), (132.9, None, None), (131.9, None, None), (128.8, None, None), (123.5, None, None), (123.0, None, None), (113.9, None, None), (107.9, None, None), (105.5, None, None), (56.32, None, None), (56....
17
17
17
10.1021_acs.orglett.3c03142
O=c1c2cc3c(cc2nc2n1Cc1ccccc1-2)OCO3
13
13
[0.10970447 0.26171877 0.26097098 0.31796877]
[0.27726439 0.26093751 0.89144372 0.33515626]
1H NMR
700 MHz
CDCl3
8.11 (d, J = 7.7 Hz, 1H), 7.67 (s, 1H), 7.61 (d, J = 4.2 Hz, 2H), 7.57-7.54 (m, 1H), 7.17 (s, 1H), 6.12 (s, 2H), 5.11 (s, 2H)
null
[('d', ['7.7Hz'], '1H', 8.11, 8.11), ('s', [], '1H', 7.67, 7.67), ('d', ['4.2Hz'], '2H', 7.61, 7.61), ('m', [], '1H', 7.57, 7.54), ('s', [], '1H', 7.17, 7.17), ('s', [], '2H', 6.12, 6.12), ('s', [], '2H', 5.11, 5.11)]
10
8
10
10.1021_acs.orglett.3c03142
O=c1c2cc3c(cc2nc2n1Cc1ccccc1-2)OCO3
13
13
[0.10970447 0.26171877 0.26097098 0.31796877]
[0.27726439 0.26093751 0.89144372 0.33515626]
13C NMR
175 MHz
CDCl3
159.9, 153.9, 153.4, 147.4, 147.2, 139.4, 132.7, 131.9, 128.8, 123.4, 123.2, 115.5, 105.8, 103.4, 102.2, 49.7
null
[(159.9, None, None), (153.9, None, None), (153.4, None, None), (147.4, None, None), (147.2, None, None), (139.4, None, None), (132.7, None, None), (131.9, None, None), (128.8, None, None), (123.4, None, None), (123.2, None, None), (115.5, None, None), (105.8, None, None), (103.4, None, None), (102.2, None, None), (49....
16
16
16
10.1021_acs.orglett.3c03142
O=c1c2cc3ccccc3cc2nc2n1Cc1ccccc1-2
13
13
[0.11129238 0.40742188 0.26815112 0.46445315]
[0.09389432 0.40078126 0.8925483 0.50625001]
1H NMR
500 MHz
CDCl3
8.97 (s, 1H), 8.30 (s, 1H), 8.21 (d, J = 7.2 Hz, 1H), 8.07 (d, J = 8.4 Hz, 1H), 8.00 (d, J = 8.4 Hz, 1H), 7.66-7.59 (m, 4H), 7.54-7.51 (m, 1H), 5.18 (s, 2H)
null
[('s', [], '1H', 8.97, 8.97), ('s', [], '1H', 8.3, 8.3), ('d', ['7.2Hz'], '1H', 8.21, 8.21), ('d', ['8.4Hz'], '1H', 8.07, 8.07), ('d', ['8.4Hz'], '1H', 8.0, 8.0), ('m', [], '4H', 7.66, 7.59), ('m', [], '1H', 7.54, 7.51), ('s', [], '2H', 5.18, 5.18)]
12
11
12
10.1021_acs.orglett.3c03142
O=c1c2cc3ccccc3cc2nc2n1Cc1ccccc1-2
13
13
[0.11129238 0.40742188 0.26815112 0.46445315]
[0.09389432 0.40078126 0.8925483 0.50625001]
13C NMR
125 MHz
CDCl3
161.1, 154.2, 144.7, 139.7, 136.7, 132.8, 132.4, 131.3, 129.3, 128.9, 128.4, 127.9, 126.2, 125.1, 123.6, 123.5, 119.7, 49.6
null
[(161.1, None, None), (154.2, None, None), (144.7, None, None), (139.7, None, None), (136.7, None, None), (132.8, None, None), (132.4, None, None), (131.3, None, None), (129.3, None, None), (128.9, None, None), (128.4, None, None), (127.9, None, None), (126.2, None, None), (125.1, None, None), (123.6, None, None), (123...
19
19
18
10.1021_acs.orglett.3c03142
O=c1c2ccccc2nc2n1Cc1c(Cl)cccc1-2
13
13
[0.10963542 0.54453127 0.23998283 0.59609376]
[0.10328375 0.54062502 0.89365298 0.63125001]
1H NMR
500 MHz
CDCl3
8.40 (d, J = 8.0 Hz, 1H), 8.08 (d, J = 7.5 Hz, 1H), 7.84-7.79 (m, 2H), 7.61 (d, J = 8.0 Hz, 1H), 7.57 (d, J = 7.5 Hz, 1H), 7.52 (d, J = 7.8 Hz, 1H), 5.16 (s, 2H)
null
[('d', ['8.0Hz'], '1H', 8.4, 8.4), ('d', ['7.5Hz'], '1H', 8.08, 8.08), ('m', [], '2H', 7.84, 7.79), ('d', ['8.0Hz'], '1H', 7.61, 7.61), ('d', ['7.5Hz'], '1H', 7.57, 7.57), ('d', ['7.8Hz'], '1H', 7.52, 7.52), ('s', [], '2H', 5.16, 5.16)]
9
8
9
10.1021_acs.orglett.3c03142
O=c1c2ccccc2nc2n1Cc1c(Cl)cccc1-2
13
13
[0.10963542 0.54453127 0.23998283 0.59609376]
[0.10328375 0.54062502 0.89365298 0.63125001]
13C NMR
125 MHz
CDCl3
160.4, 154.2, 149.3, 138.0, 134.6, 134.4, 132.1, 130.6, 130.0, 127.5, 126.8, 126.6, 121.8, 120.7, 49.3
null
[(160.4, None, None), (154.2, None, None), (149.3, None, None), (138.0, None, None), (134.6, None, None), (134.4, None, None), (132.1, None, None), (130.6, None, None), (130.0, None, None), (127.5, None, None), (126.8, None, None), (126.6, None, None), (121.8, None, None), (120.7, None, None), (49.3, None, None)]
15
15
15
10.1021_acs.orglett.3c03142
O=c1c2ccccc2nc2n1Cc1cc(F)ccc1-2
13
13
[0.11004967 0.66875003 0.25033882 0.71875007]
[0.10217911 0.66562506 0.89199596 0.77109381]
1H NMR
600 MHz
CDCl3
8.37 (d, J = 8.4 Hz, 1H), 8.16 (dd, J = 8.4, 4.8 Hz, 1H), 7.81-7.77 (m, 2H), 7.51-7.48 (m, 1H), 7.31 (d, J = 7.8 Hz, 1H), 7.29 (td, J = 8.7, 1.8 Hz, 1H), 5.14 (s, 2H)
null
[('d', ['8.4Hz'], '1H', 8.37, 8.37), ('dd', ['8.4Hz', '4.8Hz'], '1H', 8.16, 8.16), ('m', [], '2H', 7.81, 7.77), ('m', [], '1H', 7.51, 7.48), ('d', ['7.8Hz'], '1H', 7.31, 7.31), ('td', ['8.7Hz', '1.8Hz'], '1H', 7.29, 7.29), ('s', [], '2H', 5.14, 5.14)]
9
8
9
10.1021_acs.orglett.3c03142
O=c1c2ccccc2nc2n1Cc1cc(F)ccc1-2
13
13
[0.11004967 0.66875003 0.25033882 0.71875007]
[0.10217911 0.66562506 0.89199596 0.77109381]
13C NMR
150 MHz
CDCl3
165.5 (JC-F= 252 Hz), 160.5, 153.9, 149.4, 141.9 (JC-F= 10 Hz), 134.3, 128.8, 127.3, 126.5, 125.6 (JC-F= 10 Hz), 120.4, 116.9 (JC-F= 24 Hz), 110.9 (JC-F= 24 Hz), 49.5
null
[(165.5, None, 252.0), (160.5, None, None), (153.9, None, None), (149.4, None, None), (141.9, None, 10.0), (134.3, None, None), (128.8, None, None), (127.3, None, None), (126.5, None, None), (125.6, None, 10.0), (120.4, None, None), (116.9, None, 24.0), (110.9, None, 24.0), (49.5, None, None)]
15
15
14
10.1021_acs.orglett.3c03142
O=c1c2ccccc2nc2n1Cc1cc(Cl)ccc1-2
13
13
[0.10853078 0.81171879 0.26594183 0.86328132]
[0.09113272 0.80625006 0.89089138 0.89687501]
1H NMR
500 MHz
CDCl3
8.39 (d, J = 8.0 Hz, 1H), 8.12 (d, J = 8.0 Hz, 1H), 7.83-7.78 (m, 2H), 7.64 (s, 1H), 7.58 (d, J = 8.5 Hz, 1H), 7.51 (t, J = 7.5 Hz, 1H), 5.15 (s, 2H)
null
[('d', ['8.0Hz'], '1H', 8.39, 8.39), ('d', ['8.0Hz'], '1H', 8.12, 8.12), ('m', [], '2H', 7.83, 7.78), ('s', [], '1H', 7.64, 7.64), ('d', ['8.5Hz'], '1H', 7.58, 7.58), ('t', ['7.5Hz'], '1H', 7.51, 7.51), ('s', [], '2H', 5.15, 5.15)]
9
8
9
10.1021_acs.orglett.3c03142
O=c1c2ccccc2nc2n1Cc1cc(Cl)ccc1-2
13
13
[0.10853078 0.81171879 0.26594183 0.86328132]
[0.09113272 0.80625006 0.89089138 0.89687501]
13C NMR
125 MHz
CDCl3
160.5, 153.9, 149.3, 141.1, 138.7, 134.4, 131.3, 129.7, 126.7, 126.5, 124.6, 123.9, 120.5, 49.4
null
[(160.5, None, None), (153.9, None, None), (149.3, None, None), (141.1, None, None), (138.7, None, None), (134.4, None, None), (131.3, None, None), (129.7, None, None), (126.7, None, None), (126.5, None, None), (124.6, None, None), (123.9, None, None), (120.5, None, None), (49.4, None, None)]
15
15
14
10.1021_acs.orglett.3c03142
COc1ccc2c(c1)Cn1c-2nc2ccccc2c1=O
14
14
[0.10915214 0.11484375 0.2874823 0.16621094]
[0.10494071 0.11015625 0.89144372 0.21640625]
1H NMR
500 MHz
CDCl3
8.37 (d, J = 8.0 Hz, 1H), 8.10 (d, J = 8.0 Hz, 1H), 7.80-7.75 (m, 2H), 7.47 (t, J = 7.0 Hz, 1H), 7.12-7.10 (m, 2H), 5.11 (s, 2H), 3.93 (s, 3H)
null
[('d', ['8.0Hz'], '1H', 8.37, 8.37), ('d', ['8.0Hz'], '1H', 8.1, 8.1), ('m', [], '2H', 7.8, 7.75), ('t', ['7.0Hz'], '1H', 7.47, 7.47), ('m', [], '2H', 7.12, 7.1), ('s', [], '2H', 5.11, 5.11), ('s', [], '3H', 3.93, 3.93)]
12
9
12
10.1021_acs.orglett.3c03142
COc1ccc2c(c1)Cn1c-2nc2ccccc2c1=O
14
14
[0.10915214 0.11484375 0.2874823 0.16621094]
[0.10494071 0.11015625 0.89144372 0.21640625]
13C NMR
125 MHz
CDCl3
163.5, 160.7, 154.9, 149.7, 141.9, 134.2, 127.1, 126.5, 125.9, 125.0, 124.8, 120.2, 116.0, 107.9, 55.7, 49.6
null
[(163.5, None, None), (160.7, None, None), (154.9, None, None), (149.7, None, None), (141.9, None, None), (134.2, None, None), (127.1, None, None), (126.5, None, None), (125.9, None, None), (125.0, None, None), (124.8, None, None), (120.2, None, None), (116.0, None, None), (107.9, None, None), (55.7, None, None), (49.6...
16
16
16
10.1021_acs.orglett.3c03142
O=c1c2ccccc2nc2n1Cc1ccc(Cl)cc1-2
14
14
[0.10963542 0.25351565 0.2504769 0.30664062]
[0.10355991 0.23164063 0.49681141 0.24394532]
1H NMR
600 MHz
CDCl3
8.39 (dd, J = 8.1, 0.9 Hz, 1H), 8.19 (d, J = 1.8 Hz, 1H), 7.85-7.80 (m, 2H), 7.62-7.57 (m, 2H), 7.54-7.51 (m, 1H), 5.15 (s, 2H)
null
[('dd', ['8.1Hz', '0.9Hz'], '1H', 8.39, 8.39), ('d', ['1.8Hz'], '1H', 8.19, 8.19), ('m', [], '2H', 7.85, 7.8), ('m', [], '2H', 7.62, 7.57), ('m', [], '1H', 7.54, 7.51), ('s', [], '2H', 5.15, 5.15)]
9
8
9
10.1021_acs.orglett.3c03142
O=c1c2ccccc2nc2n1Cc1ccc(Cl)cc1-2
14
14
[0.10963542 0.25351565 0.2504769 0.30664062]
[0.10355991 0.23164063 0.49681141 0.24394532]
13C NMR
150 MHz
CDCl3
160.5, 153.8, 149.3, 137.8, 135.4, 134.5, 134.4, 132.5, 127.6, 126.8, 126.6, 124.8, 123.7, 120.7, 49.5
null
[(160.5, None, None), (153.8, None, None), (149.3, None, None), (137.8, None, None), (135.4, None, None), (134.5, None, None), (134.4, None, None), (132.5, None, None), (127.6, None, None), (126.8, None, None), (126.6, None, None), (124.8, None, None), (123.7, None, None), (120.7, None, None), (49.5, None, None)]
15
15
15
10.1021_acs.orglett.3c03142
O=c1c2ccccc2nc2n1Cc1ccc(F)cc1-2
14
14
[0.10970447 0.37792972 0.25158153 0.43125002]
[0.10328375 0.3746094 0.89199596 0.48007815]
1H NMR
600 MHz
CDCl3
8.36 (dd, J = 8.1, 0.9 Hz, 1H), 7.84-7.77 (m, 3H), 7.59 (dd, J = 8.4, 4.2 Hz, 1H), 7.52-7.49 (m, 1H), 7.34 (td, J = 8.7, 2.4 Hz, 1H), 5.12 (s, 2H)
null
[('dd', ['8.1Hz', '0.9Hz'], '1H', 8.36, 8.36), ('m', [], '3H', 7.84, 7.77), ('dd', ['8.4Hz', '4.2Hz'], '1H', 7.59, 7.59), ('m', [], '1H', 7.52, 7.49), ('td', ['8.7Hz', '2.4Hz'], '1H', 7.34, 7.34), ('s', [], '2H', 5.12, 5.12)]
9
8
9
10.1021_acs.orglett.3c03142
O=c1c2ccccc2nc2n1Cc1ccc(F)cc1-2
14
14
[0.10970447 0.37792972 0.25158153 0.43125002]
[0.10328375 0.3746094 0.89199596 0.48007815]
13C NMR
150 MHz
CDCl3
163.2 (JC-F = 247 Hz), 160.5, 154.0 (JC-F = 4 Hz), 149.3, 135.1, 134.8 (JC-F = 9 Hz), 134.3, 127.5, 126.7, 126.5, 125.0 (JC-F = 9 Hz), 120.6, 120.0, 119.8, 110.3, 110.2, 49.4
null
[(163.2, None, 247.0), (160.5, None, None), (154.0, None, 4.0), (149.3, None, None), (135.1, None, None), (134.8, None, 9.0), (134.3, None, None), (127.5, None, None), (126.7, None, None), (126.5, None, None), (125.0, None, 9.0), (120.6, None, None), (120.0, None, None), (119.8, None, None), (110.3, None, None), (110.2...
15
15
17
10.1021_acs.orglett.3c03142
O=c1c2ccccc2nc2n1Cc1ccc(C(F)(F)F)cc1-2
14
14
[0.1090831 0.52578126 0.26318024 0.58203129]
[0.10328375 0.51484379 0.89144372 0.62187503]
1H NMR
700 MHz
CDCl3
8.47 (s, 1H), 8.39 (d, J = 7.7 Hz, 1H), 7.91 (d, J = 7.7 Hz, 1H), 7.85-7.80 (m, 2H), 7.79 (d, J = 7.7 Hz, 1H), 7.54-7.52 (m, 1H), 5.23 (s, 2H)
null
[('s', [], '1H', 8.47, 8.47), ('d', ['7.7Hz'], '1H', 8.39, 8.39), ('d', ['7.7Hz'], '1H', 7.91, 7.91), ('m', [], '2H', 7.85, 7.8), ('d', ['7.7Hz'], '1H', 7.79, 7.79), ('m', [], '1H', 7.54, 7.52), ('s', [], '2H', 5.23, 5.23)]
9
8
9
10.1021_acs.orglett.3c03142
O=c1c2ccccc2nc2n1Cc1ccc(C(F)(F)F)cc1-2
14
14
[0.1090831 0.52578126 0.26318024 0.58203129]
[0.10328375 0.51484379 0.89144372 0.62187503]
13C NMR
175 MHz
CDCl3
160.3, 153.5, 149.1, 142.8, 134.5, 133.6, 131.8 (JC-F= 33 Hz), 128.9 (JC-F= 4 Hz), 127.6, 126.9, 126.5 (JC-F= 8 Hz), 124.2, 123.5 (JC-F= 271 Hz), 120.8 (JC-F= 7 Hz), 120.6, 49.8
null
[(160.3, None, None), (153.5, None, None), (149.1, None, None), (142.8, None, None), (134.5, None, None), (133.6, None, None), (131.8, None, 33.0), (128.9, None, 4.0), (127.6, None, None), (126.9, None, None), (126.5, None, 8.0), (124.2, None, None), (123.5, None, 271.0), (120.8, None, 7.0), (120.6, None, None), (49.8,...
16
16
16
10.1021_acs.orglett.3c03142
C(=O)(OC)c1ccc2c(c1)-c1nc3ccccc3c(=O)n1C2
14
14
[0.10659766 0.65625 0.28223527 0.71250006]
[0.10494071 0.65507815 0.89586224 0.7605469 ]
1H NMR
700 MHz
DMSO-d6
8.54 (s, 1H), 8.27 (dd, J = 8.1, 1.8 Hz, 1H), 8.24 (dd, J = 7.7, 1.4 Hz, 1H), 7.94 (d, J = 8.4 Hz, 1H), 7.87 (td, J = 7.4, 1.4 Hz, 1H), 7.83 (d, J = 8.4 Hz, 1H), 7.58-7.55 (m, 1H), 5.25 (s, 2H), 3.93 (s, 3H)
null
[('s', [], '1H', 8.54, 8.54), ('dd', ['8.1Hz', '1.8Hz'], '1H', 8.27, 8.27), ('dd', ['7.7Hz', '1.4Hz'], '1H', 8.24, 8.24), ('d', ['8.4Hz'], '1H', 7.94, 7.94), ('td', ['7.4Hz', '1.4Hz'], '1H', 7.87, 7.87), ('d', ['8.4Hz'], '1H', 7.83, 7.83), ('m', [], '1H', 7.58, 7.55), ('s', [], '2H', 5.25, 5.25), ('s', [], '3H', 3.93, ...
12
9
12
10.1021_acs.orglett.3c03142
C(=O)(OC)c1ccc2c(c1)-c1nc3ccccc3c(=O)n1C2
14
14
[0.10659766 0.65625 0.28223527 0.71250006]
[0.10494071 0.65507815 0.89586224 0.7605469 ]
13C NMR
175 MHz
DMSO-d6
165.6, 159.6, 154.4, 149.1, 145.6, 134.6, 133.1, 132.9, 130.4, 127.5, 126.8, 126.1, 125.1, 123.4, 120.7, 52.8, 50.4
null
[(165.6, None, None), (159.6, None, None), (154.4, None, None), (149.1, None, None), (145.6, None, None), (134.6, None, None), (133.1, None, None), (132.9, None, None), (130.4, None, None), (127.5, None, None), (126.8, None, None), (126.1, None, None), (125.1, None, None), (123.4, None, None), (120.7, None, None), (52....
17
17
17
10.1021_acs.orglett.3c03142
c1(C(C)(C)C)ccc2c(c1)-c1nc3ccccc3c(=O)n1C2
14
14
[0.11101622 0.79765628 0.25848553 0.85234378]
[0.27615977 0.79453131 0.89144372 0.85390626]
1H NMR
500 MHz
CDCl3
8.40 (d, J = 8.0 Hz, 1H), 8.21 (s, 1H), 7.85 (d, J = 8.5 Hz, 1H), 7.80 (t, J = 7.5 Hz, 1H), 7.72 (d, J = 8.0 Hz, 1H), 7.59 (d, J = 8.0 Hz, 1H), 7.50 (t, J = 7.5 Hz, 1H), 5.13 (s, 2H), 1.43 (s, 9H)
null
[('d', ['8.0Hz'], '1H', 8.4, 8.4), ('s', [], '1H', 8.21, 8.21), ('d', ['8.5Hz'], '1H', 7.85, 7.85), ('t', ['7.5Hz'], '1H', 7.8, 7.8), ('d', ['8.0Hz'], '1H', 7.72, 7.72), ('d', ['8.0Hz'], '1H', 7.59, 7.59), ('t', ['7.5Hz'], '1H', 7.5, 7.5), ('s', [], '2H', 5.13, 5.13), ('s', [], '9H', 1.43, 1.43)]
18
9
18