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chalcogenidotetrelates encompass the most common minerals on earth,
chalcogenidotetrelates encompass the most common minerals on earth, and other terrestrial planets in the form of silicates and carbonates. feldspar, olivine, pyroxene and calcite are common. other chalcogenidotetrelate minerals containing sulfur and other elements are known.
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689ad4bfe31ccf23c165d3e34f425f3137d2a93f
the ortho -chalcogenidotetrelate anions (t is a tetrel
the ortho -chalcogenidotetrelate anions (t is a tetrel and e is a chalcogen) are tetrahedral in arrangement. a supertetrahedron can fuse 4 or 10 of these into a larger tetrahedral adamantane cluster eg. dimers that share a corner have formula, and sharing an edge yield.
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57816bee11b82d219146cdd0fe8dd93d58728571
chalcogenidotetrelates are chemical compounds containing a group 14
chalcogenidotetrelates are chemical compounds containing a group 14 element, known as a tetrel, and a group 16 element, known as a chalcogen. the group 14 elements are carbon, silicon, germanium, tin, lead and flerovium. flerovium compounds like this are unknown due to its short half-life. the group 16 elements are oxy...
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1f588761e35b7e6a1373eee56a0312dd1e3eed92
hms standard was decommissioned in july 1945 after
hms standard was decommissioned in july 1945 after the end of the war in europe, subsequently the camp became a labour camp for polish refugees before becoming a forestry commission depot. the site of the camp was flooded with the creation of kielder water in 1980.
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3dcd60dcfef5fc5f3a52668f939d25a23026ad42
during the three years hms standard was operational,
during the three years hms standard was operational, 842 men were assessed of whom 680 were classed as 'successes' because they were drafted to other duties within the navy with the average period at standard being four months. of those redrafted the records are incomplete but some performed well enough to be decorated...
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394ed2f3ee555451f2f44eb59ce8153c42623572
prior to the second world war the ministry
prior to the second world war the ministry of labour had established a number of training centres for unemployed men, one of these was kielder camp. in 1941 the navy was growing increasingly concerned about the number of men suffering from behavioural problems, which prevented them from carrying out full duties. a vari...
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f36c813b0aac38fc469b3898d4e9c3559dc494d6
carol marcel vadnais was a canadian professional ice
carol marcel vadnais was a canadian professional ice hockey defenceman who played 17 seasons in the national hockey league (nhl) from 1966–67 until 1982–83. vadnais won the stanley cup twice during his career, in 1968 with the montreal canadiens and again in 1972 with the boston bruins.
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05a40a70b5001b974a05f889a6f40edc46e44654
vadnais joined the rangers' coaching staff as an
vadnais joined the rangers' coaching staff as an assistant for the 1983–84 and 1984–85 seasons. this was followed by one season as the head coach of the quebec major junior hockey league 's verdun junior canadiens, after which vadnais left hockey for good.
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e6c81de098ec433fab2245e8a7a20d3bd7dac6e5
vadnais played 1,087 career nhl games, scoring 169
vadnais played 1,087 career nhl games, scoring 169 goals and 418 assists for 587 points, as well as adding 1,813 penalty minutes. in his best statistical season (1974–75), he scored 18 goals and set career highs with 56 assists and 74 points. vadnais participated in six nhl all-star games and was a member of team canad...
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5e8b78e77188d7b08ec02e0d52e6b5aa89d2ca5e
vadnais was involved in the november 7, 1975
vadnais was involved in the november 7, 1975 blockbuster trade that sent him along with star forward phil esposito to the new york rangers for jean ratelle and brad park. vadnais went on to play seven seasons for the rangers and one for the new jersey devils before retiring in 1983. along with wayne cashman of the brui...
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1deca6c93e242824fd556b6066de03638d913f85
on february 23, 1972, vadnais was acquired by
on february 23, 1972, vadnais was acquired by the boston bruins in an attempt to bolster their blueline for a stanley cup run. the bruins outbid vadnais' old club, the canadiens, to secure his services. the move paid off and vadnais headed the bruins' second defence pairing behind bobby orr 's first unit, which helped ...
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53dac889fa8b2238dc983af226e4c832aa4ed1a7
originally a forward, vadnais was shifted to defence
originally a forward, vadnais was shifted to defence in his final year of junior hockey with the montreal jr. canadiens. in his first nhl training camp, he made the montreal canadiens lineup for the 1966-67 season. while the canadiens were initially successful in not exposing vadnais to the 1967 expansion draft, he was...
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85ea56be0d5fbf0fa393f688565d786cc8ae6183
carol marcel vadnais (september 25, 1945 – august
carol marcel vadnais (september 25, 1945 – august 31, 2014) was a canadian professional ice hockey defenceman who played 17 seasons in the national hockey league (nhl) from 1966–67 until 1982–83. vadnais won the stanley cup twice during his career, in 1968 with the montreal canadiens and again in 1972 with the boston b...
wikipedia
684fd9e564c2407cf2d76745d64857065abd2b03
configuration interaction (ci) is a post-hartree–fock linear variational
configuration interaction (ci) is a post-hartree–fock linear variational method for solving the nonrelativistic schrödinger equation within the born–oppenheimer approximation for a quantum chemical multi-electron system. mathematically, configuration simply describes the linear combination of slater determinants used f...
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803e59b4480adfa1b79a59fd88d6dc8c69b08f1d
configuration interaction (ci) is a post-hartree–fock linear variational
excitations. single excitations on their own do not mix with the hartree–fock determinant. these methods, cid and cisd, are in many standard programs. the davidson correction can be used to estimate a correction to the cisd energy to account for higher excitations. an important problem of truncated ci methods is their...
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1967d6b65def42f12d4ca4504169e4f7d6ee9f5c
the eigenvalues are the energies of the ground
the eigenvalues are the energies of the ground and some electronically excited states. by this it is possible to calculate energy differences (excitation energies) with ci methods. excitation energies of truncated ci methods are generally too high, because the excited states are not that well correlated as the ground s...
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f34b55c359ed8df25d89240bdeec01eeeadb898d
for nearly degenerate determinants which build the ground
for nearly degenerate determinants which build the ground state one should use the multi-configurational self-consistent field (mcscf) method because the hartree–fock determinant is qualitatively wrong and so are the ci wave functions and energies.
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df5bf1f2c20cb0b2599803b62d6e85e9436f2b13
the solution of the ci procedure are some
the solution of the ci procedure are some eigenvalues e j {\displaystyle \mathbf {e} ^{j}} and their corresponding eigenvectors c i j {\displaystyle \mathbf {c} _{i}^{j}}. the eigenvalues are the energies of the ground and some electronically excited states. by this it is possible to calculate energy differences (excit...
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4a3126a5fb72a41fa78375fcb81bdbdf9d175aca
slater determinants are constructed from sets of orthonormal
slater determinants are constructed from sets of orthonormal spin orbitals, so that ⟨ Φ i s o | Φ j s o ⟩ = δ i j {\displaystyle \left\langle \phi _{i}^{so}|\phi _{j}^{so}\right\rangle =\delta _{ij}}, making s {\displaystyle \mathbb {s} } the identity matrix and simplifying the above matrix equation.
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62b279f5c4477a642bd5dc23e0e6d4df197438b7
truncating the ci-space is important to save computational
truncating the ci-space is important to save computational time. for example, the method cid is limited to double excitations only. the method cisd is limited to single and double excitations. single excitations on their own do not mix with the hartree – fock determinant. these methods, cid and cisd, are in many standa...
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b23bda9d8a873428b7bb1a8efed4d5326a20904b
where Ψ is usually the electronic ground state
where Ψ is usually the electronic ground state of the system. if the expansion includes all possible csfs of the appropriate symmetry, then this is a full configuration interaction procedure which exactly solves the electronic schrödinger equation within the space spanned by the one-particle basis set. the first term i...
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64882525fc3bc0286d428fd7cc9d37a778852f28
in contrast to the hartree–fock method, in order
in contrast to the hartree–fock method, in order to account for electron correlation, ci uses a variational wave function that is a linear combination of configuration state functions (csfs) built from spin orbitals (denoted by the superscript so),
wikipedia
adb9e4c1b9a2f8867961ec56723751b0a0d4aad6
configuration interaction (ci) is a post-hartree–fock linear variational
configuration interaction (ci) is a post-hartree–fock linear variational method for solving the nonrelativistic schrödinger equation within the born–oppenheimer approximation for a quantum chemical multi-electron system. mathematically, configuration simply describes the linear combination of slater determinants used f...
wikipedia
d757bf69bcbed6c6dab2cb530150211d497cc021
hae-young kee is a professor in the department
hae-young kee is a professor in the department of physics at the university of toronto and is a canada research chair in the theory of quantum materials. in 2018, she was elected as a fellow of the american physical society and in 2020 was made a theoretical physics distinguished fellow from asia pacific center.
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d757bf69bcbed6c6dab2cb530150211d497cc021
hae-young kee is a professor in the department
hae-young kee is a professor in the department of physics at the university of toronto and is a canada research chair in the theory of quantum materials. in 2018, she was elected as a fellow of the american physical society and in 2020 was made a theoretical physics distinguished fellow from asia pacific center.
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20f56bb8343db498fdbe4c89cd66166e6353cfac
christina curtis is an american scientist who is
christina curtis is an american scientist who is a professor of medicine, genetics and biomedical data science and an endowed scholar at stanford university where her research investigates the evolution of tumors. she is director of artificial intelligence and cancer genomics at stanford university school of medicine a...
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cf99f7268be084df76bfd639bd747118aab63575
curtis uses computer simulations to understand genetic mutations
curtis uses computer simulations to understand genetic mutations in tumor samples. she believes that breast cancer tumors have genetic differences that respond differently to treatments. in 2019, she combined molecular analysis and historical clinical data to create the largest breast cancer cohort. in this cohort she ...
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d7fca5e382f0865ad4654848efce8bdc15a87c6d
curtis decided that she wanted to work on
curtis decided that she wanted to work on cancer treatments when she was a teenager. she was an undergraduate student at the university of california, los angeles and did a masters degree at heidelberg university. she moved to the university of southern california for graduate studies, where she earned both a master's ...
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20f56bb8343db498fdbe4c89cd66166e6353cfac
christina curtis is an american scientist who is
christina curtis is an american scientist who is a professor of medicine, genetics and biomedical data science and an endowed scholar at stanford university where her research investigates the evolution of tumors. she is director of artificial intelligence and cancer genomics at stanford university school of medicine a...
wikipedia
6e42f7d1baf17a49bb0759b5ce8c03f1f9e43a6e
bradley w. schenck is an american artist and
bradley w. schenck is an american artist and game designer. schenck's art is widely recognized for its strong themes and rigorous structure applied to fantastic subjects that is reminiscent of the work of members of the pre-raphaelite brotherhood. his work has been strongly influenced by traditional celtic art and the ...
wikipedia
e06acd25a2e3ac8ccb5e23620a224841643fb20f
schenck has retired from computer game graphics and
schenck has retired from computer game graphics and has decided to use the web as a medium for producing interactive books. his favored theme is presently retro-futuristic. this theme can be seen in much of his prior work as well, such as the scenes of the labyrinth of time that are placed in the future. his current pr...
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e3ab1bdbb055e05da18393793f3b525b6b24923c
schenck has gone on to do further computer
schenck has gone on to do further computer graphics work, including star trek: starfleet command iii, halls of the dead: faery tale adventure ii, dinotopia, i have no mouth, and i must scream, return to zork and spirit of excalibur.
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908861c077f052c84041fb87413d26cb556b19ab
schenck painted a mural for the children's area
schenck painted a mural for the children's area of the public library in thousand oaks, california. it features characters from many famous children's books done in schenck's distinctive style, wound into a single expansive composition which features images of children entering the piece at floor level. the unveiling o...
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87e1c387fe9feeb7a537bad1cf8f859f4c3f1b76
after a number of successful projects schenck sought
after a number of successful projects schenck sought to work on a project over which he could have greater creative control. for this project, he returned to his role playing game roots on the computer with the labyrinth of time. he formed company terra nova development with veteran programmer michal todorovic. the gam...
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73d982407440acb58b8260228922d1dde1c971e5
the introduction of the amiga provided an affordable
the introduction of the amiga provided an affordable computer platform with which schenck was able to express himself artistically. schenck used an amiga 500 to develop demos for the amiga killer demo contest. he won the contest for three years running, obtaining better hardware with which to work as well as opportunit...
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47982834b4a66546df337537626cf32cf1f1b5fa
schenck turned his hand to the making of
schenck turned his hand to the making of celtic harps for several years in the late 1980s. he learned the craft under the tutelage of jay witcher). his harps were known for their excellent sound and beautiful decoration, but schenck decided to leave the business as too much of the work was rote manufacturing that did n...
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17662d703f6cbefc497d2468688f62e07f90cae6
the c64 was not the most crude computer
the c64 was not the most crude computer medium brad has worked with. the ibm-pc 's cga graphics were significantly less sophisticated, yet brad managed to create stunning images for this system for the game mind-roll by epyx.
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7ea808e6f7e942d2ad5ab71b45055852d4532d48
he wrote several utility programs for the 64,
he wrote several utility programs for the 64, including software for selecting the appropriate strings for a celtic harp. he also experimented with computer graphics on this system, producing his earliest computer art. among his experiments were designs for software which would display graphically stunning banner pages...
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d92f25ae6e2870d031797c2910080beb2e25e118
schenck's involvement with computers grew when he obtained
schenck's involvement with computers grew when he obtained a commodore 64. his involvement with the gaming community became very deep very quickly, and is displayed in various ways, including his emily patella comic for the new zork times of spring 1989.
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3cf7d63b69721299781d55785d7aac09eac18f7f
a major commercial project for schenck in the
a major commercial project for schenck in the mid-1980s was the layout, design, and art of the songbook cold iron, in which leslie fish sets rudyard kipling's poems to music. the book was published by off-centaur publications in 1983 and 1987. schenck also did art for the centaur pillow book, which contained erotic ill...
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92332333b984326de26bba48224e7ef9a4c16cda
morno used the company name cosmic frog productions,
morno used the company name cosmic frog productions, and advertised it beginning in 1975, for anyone wanting "fantasy and legendary illustration". he worked for pete kerestan as the artist for his company wee warriors; one of the company's wargames, dragonlord (1977), was designed by morno and thus co-production with c...
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0bfb4c0b32e4199a2b20b51607381ae533489404
much of his work during this time was
much of his work during this time was sold at science fiction conventions and private auctions. among the most popular of his pieces were watercolors of line art originals. during this time, his pieces often presented moody scenes of stylized celts in dramatic landscapes, as opposed to his earlier compositions of fairl...
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8eefe309467bb4ebac3b972b70b97ba5f145e5af
this changed rapidly, however, as the work presented
this changed rapidly, however, as the work presented in the runestaff and various publications of the society for creative anachronism in the early 1980s attests. his control over form, particularly of people, had improved dramatically. during this time his command of further detail in his work grew with each piece pro...
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d10cc843944859e84ce8fb61cc8d25a263fe58bb
some of schenck's earliest published work can be
some of schenck's earliest published work can be found in the arduin role playing game book welcome to skull tower. schenck's early work can often be identified by his artist's signature "morno" or the sigil of the moon with an inscribed letter 'm.' all of the art in this volume was produced by schenck except for a cou...
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8f37369a67cf0faac335c7a04b27349c23874b75
schenck began his work as an artist at
schenck began his work as an artist at an early age, as a result of moving out of his parents' home to live on his own at the age of 14. he had a strong network of friends that assisted him through his connections in the society for creative anachronism and the role playing game community. he also had a strong work eth...
wikipedia
1ca6461aecd06419fb09f9e8e4787caf32d914c9
schenck's art is widely recognized for its strong
schenck's art is widely recognized for its strong themes and rigorous structure applied to fantastic subjects that is reminiscent of the work of members of the pre-raphaelite brotherhood. his work has been strongly influenced by traditional celtic art and the art nouveau style. nonetheless, while his style contains ele...
wikipedia
4822b047be6ff9fa2c79a23ea8bb3acc1705ca34
the common lisp interface manager (clim) is a
the common lisp interface manager (clim) is a common lisp-based programming interface for creating user interfaces, i.e., graphical user interfaces (guis). it provides an application programming interface (api) to user interface facilities for the programming language lisp. it is a fully object-oriented programming use...
wikipedia
bf975b8abbdef339a2ba289b285dcd576a2613a8
a free software implementation of clim is named
a free software implementation of clim is named mcclim. it has several extensions to clim and has been used for several applications like climacs, an emacs -like editor. it also provides a mouse -sensitive lisp listener, a read–eval–print loop (repl) for common lisp.
wikipedia
99260d3a791f66e08670aa4f4785813cb1f222c2
... you can check out common lisp interface
... you can check out common lisp interface manager (clim). a descendant of the symbolics lisp machines gui framework, clim is powerful but complex. although many commercial common lisp implementations actually support it, it doesn't seem to have seen a lot of use. but in the past couple years, an open-source implement...
wikipedia
497329b9d5ce17cc3d23ff29f0a03d763b8f10c5
the common lisp interface manager (clim) is a
the common lisp interface manager (clim) is a common lisp -based programming interface for creating user interfaces, i.e., graphical user interfaces (guis). it provides an application programming interface (api) to user interface facilities for the programming language lisp. it is a fully object-oriented programming us...
wikipedia
2fb9602d56e46aa19c70d4587a9d973b92a6e4e4
choi dae-shik was a south korean footballer who
choi dae-shik was a south korean footballer who played as a midfielder for daewoo royals, lg cheetahs and oita trinita (japan). he was a participant at 1994 fifa world cup and 1994 asian games. he was also the manager of kyungmin information industrial technology high school football team.
wikipedia
993e67c1f43428b2554030dca67de70a1df23183
choi dae-shik (january 10, 1965 – march 27,
choi dae-shik (january 10, 1965 – march 27, 2024) was a south korean footballer who played as a midfielder for daewoo royals (south korea), lg cheetahs (south korea) and oita trinita (japan). he was a participant at 1994 fifa world cup and 1994 asian games. he was also the manager of kyungmin information industrial tec...
wikipedia
9f2616af9f5e56873b4b932334fb0e9cad72dcd3
in mathematics, a completely metrizable space (metrically topologically
in mathematics, a completely metrizable space (metrically topologically complete space) is a topological space (x, t) for which there exists at least one metric d on x such that (x, d) is a complete metric space and d induces the topology t. the term topologically complete space is employed by some authors as a synonym...
wikipedia
6cf83a1793ec84224be717b56388aaa080fdf113
this implies e. g. that every completely metrizable
this implies e. g. that every completely metrizable topological vector space is complete. indeed, a topological vector space is called complete iff its uniformity (induced by its topology and addition operation) is complete; the uniformity induced by a translation-invariant metric that induces the topology coincides wi...
wikipedia
7892a9ea99521ad67b30a3f0b01ddf35920a5273
however, no confusion can arise when talking about
however, no confusion can arise when talking about an abelian topological group or a topological vector space being completely metrizable: it can be proven that every abelian topological group (and thus also every topological vector space) that is completely metrizable as a topological space (i. e., admits a complete m...
wikipedia
5d207e698daeb5e8a98103f7982e4d65172bd03e
when talking about spaces with more structure than
when talking about spaces with more structure than just topology, like topological groups, the natural meaning of the words “completely metrizable” would arguably be the existence of a complete metric that is also compatible with that extra structure, in addition to inducing its topology. for abelian topological groups...
wikipedia
36f55fa1f96d9c11d9ca6e04339977ca27aca5ca
the distinction between a completely metrizable space and
the distinction between a completely metrizable space and a complete metric space lies in the words there exists at least one metric in the definition of completely metrizable space, which is not the same as there is given a metric (the latter would yield the definition of complete metric space). once we make the choic...
wikipedia
9f2616af9f5e56873b4b932334fb0e9cad72dcd3
in mathematics, a completely metrizable space (metrically topologically
in mathematics, a completely metrizable space (metrically topologically complete space) is a topological space (x, t) for which there exists at least one metric d on x such that (x, d) is a complete metric space and d induces the topology t. the term topologically complete space is employed by some authors as a synonym...
wikipedia
0438304bc011451def9386de7f477b50f23d83c7
in 2016, sanderson was appointed as a senior
in 2016, sanderson was appointed as a senior assistant coach at the collingwood football club under senior coach nathan buckley, overseeing forward line and ball movement. sanderson left the collingwood football club at the end of the 2021 season.
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336eb45557c7ad0c2d34968737dfe08fd22b9035
after getting to within a goal of reaching
after getting to within a goal of reaching the afl grand final in 2012, the crows underachieved in the ensuing two years, finishing 11th and 10th respectively and therefore failing to make the finals. as a result, on 17 september 2014 (almost three years to the day since he was appointed) sanderson was sacked as senior...
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b95dbe2b86f61e2795c1bf2c5228dd89a84cf9b7
on monday 19 september 2011, sanderson was appointed
on monday 19 september 2011, sanderson was appointed senior coach of the adelaide football club ahead of red hot favourite scott burns and premiership captain mark bickley. sanderson replaced caretaker senior coach mark bickley, who replaced neil craig after craig resigned in the middle of the 2011 season.
wikipedia
795d25ee646e2392bc58e38b59e0fb1444095c96
in 1995 sanderson moved to geelong and reinvented
in 1995 sanderson moved to geelong and reinvented himself as a half-back flanker, generating a lot of run out of defence. he had his best season in 2001, when he took out the carji greeves medal as well as earning international rules selection.
wikipedia
1fa6654b9bd557ad0b7a4c300ec3a57eded9ffc0
originally from adelaide, south australia, sanderson moved from
originally from adelaide, south australia, sanderson moved from sturt to adelaide as one of their 10 concession picks. while at sturt he injured his right leg and had to learn to kick left footed, this subsequently became his primary kicking foot. he finally made his debut in 1992 but had limited opportunities and play...
wikipedia
af7c59efeffbc855e878f4d3c62c5436695ca6c4
giancarlo michele "carlo" corazzin is a canadian retired
giancarlo michele "carlo" corazzin is a canadian retired professional soccer player who played as a forward for winnipeg fury, vancouver 86ers, cambridge united, plymouth argyle, northampton town, oldham athletic and vancouver whitecaps at club level. at international level, he was capped 59 times for the canada nation...
wikipedia
66b262167dbbc50605ba2c19db32f70097a020b0
corazzin made his canada national team debut on
corazzin made his canada national team debut on june 1, 1994, in a 1–1 tie with morocco. corazzin scored the majority of his international goals between 1999–2000 and formed an effective striker partnership with paul peschisolido for canada over the years. in 2000, corazzin won the golden boot as top scorer of the conc...
wikipedia
faf6b38343b71182264477e8c50c7fa00cfaff34
in 2003, corazzin re-signed with vancouver whitecaps, where
in 2003, corazzin re-signed with vancouver whitecaps, where he scored 7 goals in a 13-game undefeated streak. corazzin played with the whitecaps for 3 years until he was released in 2006.
wikipedia
8f2720eb35540a243b47c5960e562bcaf72b1634
on july 28, 2000, after a successful concacaf
on july 28, 2000, after a successful concacaf gold cup with canada, corazzin signed with oldham athletic and scored 22 goals in 129 games over three seasons. his finest moment with oldham came in a match against wrexham when corazzin scored 4 in a 5–1 victory in 2001, finishing it off with his trademark celebration "th...
wikipedia
cd12934a8371e506642477ff206dcc7ec1a826b8
corazzin joined northampton town of the third division
corazzin joined northampton town of the third division on june 26, 1998, netting 32 goals in 89 games over two seasons. northampton town were relegated in 1999, but with corazzin's help, the club regained promotion in 2000.
wikipedia
4df555da0c7a0d56b4ed2e0e3ede2d933dd76a3d
corazzin signed with cambridge united of the english
corazzin signed with cambridge united of the english second division (now known as league 1) on december 10, 1993, scoring 43 goals in 117 games over two-and-a-half seasons. in his final year with cambridge, the team was relegated, and on march 28, 1996, corazzin signed with plymouth argyle for a transfer fee of £ 150 ...
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82a5369785728d71048f21aa797c85ba29d1780e
corazzin began his career with winnipeg fury of
corazzin began his career with winnipeg fury of the canadian soccer league in 1992, scoring 10 goals in 24 games and helping the team win the csl championship. in 1993, corazzin signed with the vancouver whitecaps of the a-league (now known as the usl first division, where he finished second in the team's scoring chart...
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1fe18f6d3d08e84023692885097a06de67667d75
giancarlo michele "carlo" corazzin (born december 25, 1971)
giancarlo michele "carlo" corazzin (born december 25, 1971) is a canadian retired professional soccer player who played as a forward for winnipeg fury, vancouver 86ers, cambridge united, plymouth argyle, northampton town, oldham athletic and vancouver whitecaps at club level. at international level, he was capped 59 ti...
wikipedia
7e912e09ef1a962358911bf8af1288c242a84ff8
cobalt-precorrin 5a hydrolase (ec 3.7.1.12), cbig (gene)) is
cobalt-precorrin 5a hydrolase (ec 3.7.1.12), cbig (gene)) is an enzyme with systematic name cobalt-precorrin 5a acylhydrolase. this enzyme catalyses the following chemical reaction this enzyme hydrolyses the ring a acetate delta-lactone of cobalt-precorrin-5a and releases a two-carbon fragment from the macrocyclic corr...
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1dfd494e06d24cab098923cfb0291f6ee94d961b
this enzyme hydrolyses the ring a acetate delta-lactone
this enzyme hydrolyses the ring a acetate delta-lactone of cobalt-precorrin-5a and releases a two-carbon fragment from the macrocyclic corrin ring as acetaldehyde. this is part of the biosynthetic pathway to cobalamin (vitamin b) in anaerobic bacteria such as salmonella typhimurium and bacillus megaterium.
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dbc9c49aeb77d00e3c06fe1215fb8bbe6c716052
cobalt-precorrin 5a hydrolase (ec 3.7.1.12), cbig (gene)) is
cobalt-precorrin 5a hydrolase (ec 3.7.1.12), cbig (gene)) is an enzyme with systematic name cobalt-precorrin 5a acylhydrolase. this enzyme catalyses the following chemical reaction
wikipedia
81642369bdc12b091551623a61b11d639c0256b4
the chevrolet 153 cu in engine was an
the chevrolet 153 cu in engine was an inline-four engine designed in the early 1960s for use in the chevy ii. it is a four-cylinder variant of the turbo-thrift six-cylinder engine. after 1970, gm ceased production of the 153 engine in north america because of low demand, but the engine continued to be used in cars in o...
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5862c5769b031d43f2e9a86de6d3847b269967aa
gm produced a variant of the 153 for
gm produced a variant of the 153 for use in industrial and marine applications, with the mexican version's larger 4-inch (101.6 mm) bore and a longer 3.6-inch (91.4 mm) stroke. the resulting 3.0 l (181 cu in) engine, branded the vortec 3000, was never installed in passenger cars. the vortec 3000 was manufactured in mex...
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056196596f4c67dc8a971de52bd725e981474d4b
gm de argentina designed its own 110 cu
gm de argentina designed its own 110 cu in (1,797 cc) variant of the engine called the chevrolet 110. the smaller displacement was achieved by using the 3 + 9 ⁄ 16 in (90.5 mm) bore of the 194 cu in straight-six and a unique, short 2 + 1 ⁄ 2 in (63.5 mm) stroke. the engine was designed for use in the locally-built opel...
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cfb2d0af1cdc3b516d5557fda0828b70d788ac21
this engine was a mainstay for gmsa, who
this engine was a mainstay for gmsa, who built it in its aloes plant (on the northern edge of port elizabeth) for installation in a wide range of cars. two smaller displacement versions of this engine were also built there: a 2,319 cc (141.5 cu in) variant using the 153's bore and the brazilian 151 cu in engine's 3-inc...
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5d29766cd9ff2f8413d4c02796289f3b64a69976
the 153 engine was used by gm do
the 153 engine was used by gm do brasil in its first locally-made car, the 1968 chevrolet opala. in 1973, the brazilian engineers redesigned the engine in order to quell vibrations, decreasing the stroke to 3 inches (76 mm) and increasing the connecting rod lengths to 6 inches (150 mm). to keep the power output similar...
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8ee4c8f18e0fb7ff144ee02bfb26a7d1d9107623
in the chevy ii the engine was branded
in the chevy ii the engine was branded as the super-thrift 153, while in the 1964 chevy van, it was called the high torque 153. peak power and torque were 90 hp (67 kw) at 4,000 rpm and 152 lb⋅ft (206 n⋅m) at 2,400 rpm.
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c5540a15896578a59625f348b6cb5bb4010411f6
the 153 cu in engine had a 3
the 153 cu in engine had a 3 + 7 ⁄ 8 -inch (98 mm) bore and 3 + 1 ⁄ 4 -inch (82.6 mm) stroke, with two overhead valves per cylinder actuated by pushrods and a 1-3-4-2 firing order. the chevy ii 's 194 cu in six-cylinder used a 3 + 9 ⁄ 16 -inch (90.5 mm) bore, which by 1964 was enlarged to match the 153 four-cylinder's ...
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b57dee817a2278ff6b655acd42d7dbf2c1e7690e
the compact chevrolet corvair was introduced in 1960
the compact chevrolet corvair was introduced in 1960 to compete with the ford falcon and plymouth valiant, but was handily outsold by its competitors. fearing the corvair's more radical engineering (featuring a rear-mounted air-cooled flat-six engine) was not appealing to consumers, gm hastily approved the design of a ...
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d7817e2492190032dc9f59c6b0231e71afd0fbd9
the chevrolet 153 cu in engine was an
the chevrolet 153 cu in engine was an inline-four engine designed in the early 1960s for use in the chevy ii. it is a four-cylinder variant of the turbo-thrift six-cylinder engine. after 1970, gm ceased production of the 153 engine in north america because of low demand (and the inline-six was thereafter made the base ...
wikipedia
3bc79fed3f24e5fa2166b18c44343ca6c9226e5a
"chō" is a song recorded by japanese singer
"chō" is a song recorded by japanese singer shizuka kudo for her eleventh studio album, doing. it was released through pony canyon as the album's second and last single on march 21, 1996. the song featured on tv commercials for the takano yuri beauty clinic. the b-side, "melody", served as ending theme to the 1996 ax t...
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390d9395683fded27b660fe5d41f2f02b79fcd43
the single's coupling song, "melody", written by aeri
the single's coupling song, "melody", written by aeri and hideya nagazaki, was originally intended to be released as the a-side, but as the song started coming together, it was decided that the showier "chō" would be made into a single instead.
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25ff6760dd56413c01c4e1d860f65160ecf03a14
"chō" was co-written by kudo, under the pseudonym
"chō" was co-written by kudo, under the pseudonym aeri, the checkers 's naoyuki fujii and akihisa matsūra. it is written in the key of a minor. kudo's vocals span two octaves; from a to e ♭ in modal voice, and a in head voice. during the recording, kudo suggested a few changes to the melody to fujii, who chiefly worked...
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4ce32e78f6f242356f1024d385550433739abb9a
" chō " (蝶 ( ちょう ), lit.
" chō " (蝶 ( ちょう ), lit. "butterfly") is a song recorded by japanese singer shizuka kudo for her eleventh studio album, doing. it was released through pony canyon as the album's second and last single on march 21, 1996. the song featured on tv commercials for the takano yuri beauty clinic. the b-side, "melody", served ...
wikipedia
36f5ef3cc62d58475f2f5e7c887c2ec104b1040d
in chemistry, a chalcogen bond (chb) is an
in chemistry, a chalcogen bond (chb) is an attractive interaction in the family of σ-hole interactions, along with halogen bonds. electrostatic, charge-transfer (ct) and dispersion terms have been identified as contributing to this type of interaction. in terms of ct contribution, this family of attractive interactions...
wikipedia
743c8b31160606ff5d0c02543d1956c7fab40243
chalcogen bonding in catalysis has been used to
chalcogen bonding in catalysis has been used to pre-orient substrate, allowing for asymmetric/stereoselective catalysis on the preferred conformation of the substrate. examples include an asymmetric acyl transfer on an enantiomeric mixture catalyzed by a chiral isothiourea. the acyl group is first transfer on to the ch...
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b83206d5b30652dcbb7b4ffbca8a7cb8083d8002
the conformational preference can be derived from various
the conformational preference can be derived from various classes of intramolecular chalcogen bonding, including 1,4, 1,5, and 1,6 os interactions, 1,4 and 1,5 ns interactions, and saromatic interactions. each class of these interactions is made up of large classes of drugs in which chalcogen bonding has resulted in up...
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6f994079a2cafb3b819905d18026bfbe12be72ea
drug design is a broad umbrella which includes
drug design is a broad umbrella which includes molecular design to vary biologically relevant characteristics. with regard to weak interactions, the design is aimed at tuning ligand docking/binding of drugs to biologically relevant molecules or proteins and associated biological effects from various binding modes. the ...
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c29067d8ec4487b2200ace3b1f6648bd6d8d17ea
a wide range of applications have been proposed
a wide range of applications have been proposed for designing chalcogen bonds into systems where weak interactions are crucial. this can include areas dependent on specific recognition or molecules, sort of a lock and key model, as seen in drug design, sensing, and highly selective catalysis. additional applications ar...
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d7a727543ce869b94be3ef3cc068caf6e2448adb
a means of comparing the chalcogen-chalcogen bonding forces
a means of comparing the chalcogen-chalcogen bonding forces with h-bonding is to compare the effect of various solvent environments on the chalcogen-chalcogen bond. this has been done on a series of molecules featuring a chalcogen-chalcogen intramolecular bond in one conformation (closed) and exposed to solvent interac...
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95f6a32dec485a63d257d103477568efdc225ff2
due to a chalcogen's ability to function as
due to a chalcogen's ability to function as an electron donor, many systems will balance between hydrogen bonding with the chalcogen as a donor or chalcogen bonding. this balance can be observed in a series of self-bonding intermolecular interactions between various substituted chalcogens. in cases with hard chalcogen ...
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aa33c293e0450d501d4c838ac793ae91921970ac
both electrostatic mapping and molecular orbital explanation for
both electrostatic mapping and molecular orbital explanation for chalcogen bonding result in a predicted directionality for the bonding interaction. in a hydrogen or halogen bond, the electrophilic region/σ* orbital are located opposite the σ bond, forming a single σ-hole. optimal hydrogen or halogen bonds thus are lin...
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fc0c0374a2f0ba442b7f57ab235e4e1ae2e280d3
another method used to evaluate chalcogen bonding specifically
another method used to evaluate chalcogen bonding specifically and a wide range of bonding generally is natural bond orbital (nbo) analysis. nbo analysis distinguishes between covalent, lewis-type bonding interactions and non-covalent, non-lewis bonding interaction. the chalcogen bond will be evaluated based on the nat...
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44c9c3634dc4ba2d6f890f277446a03c0082453a
any electron donor can donate electrons into the
any electron donor can donate electrons into the σ-hole of a bonded chalcogen, including halogen anions, amines, and π electrons (such as benzene). similar to halogen bonding, chalcogen bonding can occur between two chalcogens, resulting in a chalcogen-chalcogen bond. non-covalent interactions are well characterized by...
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06ddac349e2e4729cb39e0aff04647cfcef3660b
given the dual ability of chalcogens to serve
given the dual ability of chalcogens to serve as donor and acceptor molecules for σ-hole interactions, a geometric schematic has been generated to distinguish between the differing bonding character. the σ* orbital is exactly opposite the σ bonds to a chalcogen bond. it is the region between the σ-holes in which the lo...
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ce503702102bb092c4ca8cfa4df581df89cc54ea
chalcogen bonding is comparable to other forms of
chalcogen bonding is comparable to other forms of σ-hole interactions. however, the specific contributions to this interaction are still a matter of debate. the contributing forces can be broken down into dispersion / van der waals interactions, electrostatic interactions, and orbital mixing (ct) interactions. these co...
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cbd8fbd8a6987747f2a29e46e9e4267d9ac18ea6
in chemistry, a chalcogen bond (chb) is an
in chemistry, a chalcogen bond (chb) is an attractive interaction in the family of σ-hole interactions, along with halogen bonds. electrostatic, charge-transfer (ct) and dispersion terms have been identified as contributing to this type of interaction. in terms of ct contribution, this family of attractive interactions...
wikipedia