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3b54cfbf7fdd8fc71d91ae95a3de81d6e0325809 | chalcogenidotetrelates encompass the most common minerals on earth, | chalcogenidotetrelates encompass the most common minerals on earth, and other terrestrial planets in the form of silicates and carbonates. feldspar, olivine, pyroxene and calcite are common. other chalcogenidotetrelate minerals containing sulfur and other elements are known. | wikipedia |
689ad4bfe31ccf23c165d3e34f425f3137d2a93f | the ortho -chalcogenidotetrelate anions (t is a tetrel | the ortho -chalcogenidotetrelate anions (t is a tetrel and e is a chalcogen) are tetrahedral in arrangement. a supertetrahedron can fuse 4 or 10 of these into a larger tetrahedral adamantane cluster eg. dimers that share a corner have formula, and sharing an edge yield. | wikipedia |
57816bee11b82d219146cdd0fe8dd93d58728571 | chalcogenidotetrelates are chemical compounds containing a group 14 | chalcogenidotetrelates are chemical compounds containing a group 14 element, known as a tetrel, and a group 16 element, known as a chalcogen. the group 14 elements are carbon, silicon, germanium, tin, lead and flerovium. flerovium compounds like this are unknown due to its short half-life. the group 16 elements are oxy... | wikipedia |
1f588761e35b7e6a1373eee56a0312dd1e3eed92 | hms standard was decommissioned in july 1945 after | hms standard was decommissioned in july 1945 after the end of the war in europe, subsequently the camp became a labour camp for polish refugees before becoming a forestry commission depot. the site of the camp was flooded with the creation of kielder water in 1980. | wikipedia |
3dcd60dcfef5fc5f3a52668f939d25a23026ad42 | during the three years hms standard was operational, | during the three years hms standard was operational, 842 men were assessed of whom 680 were classed as 'successes' because they were drafted to other duties within the navy with the average period at standard being four months. of those redrafted the records are incomplete but some performed well enough to be decorated... | wikipedia |
394ed2f3ee555451f2f44eb59ce8153c42623572 | prior to the second world war the ministry | prior to the second world war the ministry of labour had established a number of training centres for unemployed men, one of these was kielder camp. in 1941 the navy was growing increasingly concerned about the number of men suffering from behavioural problems, which prevented them from carrying out full duties. a vari... | wikipedia |
f36c813b0aac38fc469b3898d4e9c3559dc494d6 | carol marcel vadnais was a canadian professional ice | carol marcel vadnais was a canadian professional ice hockey defenceman who played 17 seasons in the national hockey league (nhl) from 1966–67 until 1982–83. vadnais won the stanley cup twice during his career, in 1968 with the montreal canadiens and again in 1972 with the boston bruins. | wikipedia |
05a40a70b5001b974a05f889a6f40edc46e44654 | vadnais joined the rangers' coaching staff as an | vadnais joined the rangers' coaching staff as an assistant for the 1983–84 and 1984–85 seasons. this was followed by one season as the head coach of the quebec major junior hockey league 's verdun junior canadiens, after which vadnais left hockey for good. | wikipedia |
e6c81de098ec433fab2245e8a7a20d3bd7dac6e5 | vadnais played 1,087 career nhl games, scoring 169 | vadnais played 1,087 career nhl games, scoring 169 goals and 418 assists for 587 points, as well as adding 1,813 penalty minutes. in his best statistical season (1974–75), he scored 18 goals and set career highs with 56 assists and 74 points. vadnais participated in six nhl all-star games and was a member of team canad... | wikipedia |
5e8b78e77188d7b08ec02e0d52e6b5aa89d2ca5e | vadnais was involved in the november 7, 1975 | vadnais was involved in the november 7, 1975 blockbuster trade that sent him along with star forward phil esposito to the new york rangers for jean ratelle and brad park. vadnais went on to play seven seasons for the rangers and one for the new jersey devils before retiring in 1983. along with wayne cashman of the brui... | wikipedia |
1deca6c93e242824fd556b6066de03638d913f85 | on february 23, 1972, vadnais was acquired by | on february 23, 1972, vadnais was acquired by the boston bruins in an attempt to bolster their blueline for a stanley cup run. the bruins outbid vadnais' old club, the canadiens, to secure his services. the move paid off and vadnais headed the bruins' second defence pairing behind bobby orr 's first unit, which helped ... | wikipedia |
53dac889fa8b2238dc983af226e4c832aa4ed1a7 | originally a forward, vadnais was shifted to defence | originally a forward, vadnais was shifted to defence in his final year of junior hockey with the montreal jr. canadiens. in his first nhl training camp, he made the montreal canadiens lineup for the 1966-67 season. while the canadiens were initially successful in not exposing vadnais to the 1967 expansion draft, he was... | wikipedia |
85ea56be0d5fbf0fa393f688565d786cc8ae6183 | carol marcel vadnais (september 25, 1945 – august | carol marcel vadnais (september 25, 1945 – august 31, 2014) was a canadian professional ice hockey defenceman who played 17 seasons in the national hockey league (nhl) from 1966–67 until 1982–83. vadnais won the stanley cup twice during his career, in 1968 with the montreal canadiens and again in 1972 with the boston b... | wikipedia |
684fd9e564c2407cf2d76745d64857065abd2b03 | configuration interaction (ci) is a post-hartree–fock linear variational | configuration interaction (ci) is a post-hartree–fock linear variational method for solving the nonrelativistic schrödinger equation within the born–oppenheimer approximation for a quantum chemical multi-electron system. mathematically, configuration simply describes the linear combination of slater determinants used f... | wikipedia |
803e59b4480adfa1b79a59fd88d6dc8c69b08f1d | configuration interaction (ci) is a post-hartree–fock linear variational | excitations. single excitations on their own do not mix with the hartree–fock determinant. these methods, cid and cisd, are in many standard programs. the davidson correction can be used to estimate a correction to the cisd energy to account for higher excitations. an important problem of truncated ci methods is their... | wikipedia |
1967d6b65def42f12d4ca4504169e4f7d6ee9f5c | the eigenvalues are the energies of the ground | the eigenvalues are the energies of the ground and some electronically excited states. by this it is possible to calculate energy differences (excitation energies) with ci methods. excitation energies of truncated ci methods are generally too high, because the excited states are not that well correlated as the ground s... | wikipedia |
f34b55c359ed8df25d89240bdeec01eeeadb898d | for nearly degenerate determinants which build the ground | for nearly degenerate determinants which build the ground state one should use the multi-configurational self-consistent field (mcscf) method because the hartree–fock determinant is qualitatively wrong and so are the ci wave functions and energies. | wikipedia |
df5bf1f2c20cb0b2599803b62d6e85e9436f2b13 | the solution of the ci procedure are some | the solution of the ci procedure are some eigenvalues e j {\displaystyle \mathbf {e} ^{j}} and their corresponding eigenvectors c i j {\displaystyle \mathbf {c} _{i}^{j}}. the eigenvalues are the energies of the ground and some electronically excited states. by this it is possible to calculate energy differences (excit... | wikipedia |
4a3126a5fb72a41fa78375fcb81bdbdf9d175aca | slater determinants are constructed from sets of orthonormal | slater determinants are constructed from sets of orthonormal spin orbitals, so that ⟨ Φ i s o | Φ j s o ⟩ = δ i j {\displaystyle \left\langle \phi _{i}^{so}|\phi _{j}^{so}\right\rangle =\delta _{ij}}, making s {\displaystyle \mathbb {s} } the identity matrix and simplifying the above matrix equation. | wikipedia |
62b279f5c4477a642bd5dc23e0e6d4df197438b7 | truncating the ci-space is important to save computational | truncating the ci-space is important to save computational time. for example, the method cid is limited to double excitations only. the method cisd is limited to single and double excitations. single excitations on their own do not mix with the hartree – fock determinant. these methods, cid and cisd, are in many standa... | wikipedia |
b23bda9d8a873428b7bb1a8efed4d5326a20904b | where Ψ is usually the electronic ground state | where Ψ is usually the electronic ground state of the system. if the expansion includes all possible csfs of the appropriate symmetry, then this is a full configuration interaction procedure which exactly solves the electronic schrödinger equation within the space spanned by the one-particle basis set. the first term i... | wikipedia |
64882525fc3bc0286d428fd7cc9d37a778852f28 | in contrast to the hartree–fock method, in order | in contrast to the hartree–fock method, in order to account for electron correlation, ci uses a variational wave function that is a linear combination of configuration state functions (csfs) built from spin orbitals (denoted by the superscript so), | wikipedia |
adb9e4c1b9a2f8867961ec56723751b0a0d4aad6 | configuration interaction (ci) is a post-hartree–fock linear variational | configuration interaction (ci) is a post-hartree–fock linear variational method for solving the nonrelativistic schrödinger equation within the born–oppenheimer approximation for a quantum chemical multi-electron system. mathematically, configuration simply describes the linear combination of slater determinants used f... | wikipedia |
d757bf69bcbed6c6dab2cb530150211d497cc021 | hae-young kee is a professor in the department | hae-young kee is a professor in the department of physics at the university of toronto and is a canada research chair in the theory of quantum materials. in 2018, she was elected as a fellow of the american physical society and in 2020 was made a theoretical physics distinguished fellow from asia pacific center. | wikipedia |
d757bf69bcbed6c6dab2cb530150211d497cc021 | hae-young kee is a professor in the department | hae-young kee is a professor in the department of physics at the university of toronto and is a canada research chair in the theory of quantum materials. in 2018, she was elected as a fellow of the american physical society and in 2020 was made a theoretical physics distinguished fellow from asia pacific center. | wikipedia |
20f56bb8343db498fdbe4c89cd66166e6353cfac | christina curtis is an american scientist who is | christina curtis is an american scientist who is a professor of medicine, genetics and biomedical data science and an endowed scholar at stanford university where her research investigates the evolution of tumors. she is director of artificial intelligence and cancer genomics at stanford university school of medicine a... | wikipedia |
cf99f7268be084df76bfd639bd747118aab63575 | curtis uses computer simulations to understand genetic mutations | curtis uses computer simulations to understand genetic mutations in tumor samples. she believes that breast cancer tumors have genetic differences that respond differently to treatments. in 2019, she combined molecular analysis and historical clinical data to create the largest breast cancer cohort. in this cohort she ... | wikipedia |
d7fca5e382f0865ad4654848efce8bdc15a87c6d | curtis decided that she wanted to work on | curtis decided that she wanted to work on cancer treatments when she was a teenager. she was an undergraduate student at the university of california, los angeles and did a masters degree at heidelberg university. she moved to the university of southern california for graduate studies, where she earned both a master's ... | wikipedia |
20f56bb8343db498fdbe4c89cd66166e6353cfac | christina curtis is an american scientist who is | christina curtis is an american scientist who is a professor of medicine, genetics and biomedical data science and an endowed scholar at stanford university where her research investigates the evolution of tumors. she is director of artificial intelligence and cancer genomics at stanford university school of medicine a... | wikipedia |
6e42f7d1baf17a49bb0759b5ce8c03f1f9e43a6e | bradley w. schenck is an american artist and | bradley w. schenck is an american artist and game designer. schenck's art is widely recognized for its strong themes and rigorous structure applied to fantastic subjects that is reminiscent of the work of members of the pre-raphaelite brotherhood. his work has been strongly influenced by traditional celtic art and the ... | wikipedia |
e06acd25a2e3ac8ccb5e23620a224841643fb20f | schenck has retired from computer game graphics and | schenck has retired from computer game graphics and has decided to use the web as a medium for producing interactive books. his favored theme is presently retro-futuristic. this theme can be seen in much of his prior work as well, such as the scenes of the labyrinth of time that are placed in the future. his current pr... | wikipedia |
e3ab1bdbb055e05da18393793f3b525b6b24923c | schenck has gone on to do further computer | schenck has gone on to do further computer graphics work, including star trek: starfleet command iii, halls of the dead: faery tale adventure ii, dinotopia, i have no mouth, and i must scream, return to zork and spirit of excalibur. | wikipedia |
908861c077f052c84041fb87413d26cb556b19ab | schenck painted a mural for the children's area | schenck painted a mural for the children's area of the public library in thousand oaks, california. it features characters from many famous children's books done in schenck's distinctive style, wound into a single expansive composition which features images of children entering the piece at floor level. the unveiling o... | wikipedia |
87e1c387fe9feeb7a537bad1cf8f859f4c3f1b76 | after a number of successful projects schenck sought | after a number of successful projects schenck sought to work on a project over which he could have greater creative control. for this project, he returned to his role playing game roots on the computer with the labyrinth of time. he formed company terra nova development with veteran programmer michal todorovic. the gam... | wikipedia |
73d982407440acb58b8260228922d1dde1c971e5 | the introduction of the amiga provided an affordable | the introduction of the amiga provided an affordable computer platform with which schenck was able to express himself artistically. schenck used an amiga 500 to develop demos for the amiga killer demo contest. he won the contest for three years running, obtaining better hardware with which to work as well as opportunit... | wikipedia |
47982834b4a66546df337537626cf32cf1f1b5fa | schenck turned his hand to the making of | schenck turned his hand to the making of celtic harps for several years in the late 1980s. he learned the craft under the tutelage of jay witcher). his harps were known for their excellent sound and beautiful decoration, but schenck decided to leave the business as too much of the work was rote manufacturing that did n... | wikipedia |
17662d703f6cbefc497d2468688f62e07f90cae6 | the c64 was not the most crude computer | the c64 was not the most crude computer medium brad has worked with. the ibm-pc 's cga graphics were significantly less sophisticated, yet brad managed to create stunning images for this system for the game mind-roll by epyx. | wikipedia |
7ea808e6f7e942d2ad5ab71b45055852d4532d48 | he wrote several utility programs for the 64, | he wrote several utility programs for the 64, including software for selecting the appropriate strings for a celtic harp. he also experimented with computer graphics on this system, producing his earliest computer art. among his experiments were designs for software which would display graphically stunning banner pages... | wikipedia |
d92f25ae6e2870d031797c2910080beb2e25e118 | schenck's involvement with computers grew when he obtained | schenck's involvement with computers grew when he obtained a commodore 64. his involvement with the gaming community became very deep very quickly, and is displayed in various ways, including his emily patella comic for the new zork times of spring 1989. | wikipedia |
3cf7d63b69721299781d55785d7aac09eac18f7f | a major commercial project for schenck in the | a major commercial project for schenck in the mid-1980s was the layout, design, and art of the songbook cold iron, in which leslie fish sets rudyard kipling's poems to music. the book was published by off-centaur publications in 1983 and 1987. schenck also did art for the centaur pillow book, which contained erotic ill... | wikipedia |
92332333b984326de26bba48224e7ef9a4c16cda | morno used the company name cosmic frog productions, | morno used the company name cosmic frog productions, and advertised it beginning in 1975, for anyone wanting "fantasy and legendary illustration". he worked for pete kerestan as the artist for his company wee warriors; one of the company's wargames, dragonlord (1977), was designed by morno and thus co-production with c... | wikipedia |
0bfb4c0b32e4199a2b20b51607381ae533489404 | much of his work during this time was | much of his work during this time was sold at science fiction conventions and private auctions. among the most popular of his pieces were watercolors of line art originals. during this time, his pieces often presented moody scenes of stylized celts in dramatic landscapes, as opposed to his earlier compositions of fairl... | wikipedia |
8eefe309467bb4ebac3b972b70b97ba5f145e5af | this changed rapidly, however, as the work presented | this changed rapidly, however, as the work presented in the runestaff and various publications of the society for creative anachronism in the early 1980s attests. his control over form, particularly of people, had improved dramatically. during this time his command of further detail in his work grew with each piece pro... | wikipedia |
d10cc843944859e84ce8fb61cc8d25a263fe58bb | some of schenck's earliest published work can be | some of schenck's earliest published work can be found in the arduin role playing game book welcome to skull tower. schenck's early work can often be identified by his artist's signature "morno" or the sigil of the moon with an inscribed letter 'm.' all of the art in this volume was produced by schenck except for a cou... | wikipedia |
8f37369a67cf0faac335c7a04b27349c23874b75 | schenck began his work as an artist at | schenck began his work as an artist at an early age, as a result of moving out of his parents' home to live on his own at the age of 14. he had a strong network of friends that assisted him through his connections in the society for creative anachronism and the role playing game community. he also had a strong work eth... | wikipedia |
1ca6461aecd06419fb09f9e8e4787caf32d914c9 | schenck's art is widely recognized for its strong | schenck's art is widely recognized for its strong themes and rigorous structure applied to fantastic subjects that is reminiscent of the work of members of the pre-raphaelite brotherhood. his work has been strongly influenced by traditional celtic art and the art nouveau style. nonetheless, while his style contains ele... | wikipedia |
4822b047be6ff9fa2c79a23ea8bb3acc1705ca34 | the common lisp interface manager (clim) is a | the common lisp interface manager (clim) is a common lisp-based programming interface for creating user interfaces, i.e., graphical user interfaces (guis). it provides an application programming interface (api) to user interface facilities for the programming language lisp. it is a fully object-oriented programming use... | wikipedia |
bf975b8abbdef339a2ba289b285dcd576a2613a8 | a free software implementation of clim is named | a free software implementation of clim is named mcclim. it has several extensions to clim and has been used for several applications like climacs, an emacs -like editor. it also provides a mouse -sensitive lisp listener, a read–eval–print loop (repl) for common lisp. | wikipedia |
99260d3a791f66e08670aa4f4785813cb1f222c2 | ... you can check out common lisp interface | ... you can check out common lisp interface manager (clim). a descendant of the symbolics lisp machines gui framework, clim is powerful but complex. although many commercial common lisp implementations actually support it, it doesn't seem to have seen a lot of use. but in the past couple years, an open-source implement... | wikipedia |
497329b9d5ce17cc3d23ff29f0a03d763b8f10c5 | the common lisp interface manager (clim) is a | the common lisp interface manager (clim) is a common lisp -based programming interface for creating user interfaces, i.e., graphical user interfaces (guis). it provides an application programming interface (api) to user interface facilities for the programming language lisp. it is a fully object-oriented programming us... | wikipedia |
2fb9602d56e46aa19c70d4587a9d973b92a6e4e4 | choi dae-shik was a south korean footballer who | choi dae-shik was a south korean footballer who played as a midfielder for daewoo royals, lg cheetahs and oita trinita (japan). he was a participant at 1994 fifa world cup and 1994 asian games. he was also the manager of kyungmin information industrial technology high school football team. | wikipedia |
993e67c1f43428b2554030dca67de70a1df23183 | choi dae-shik (january 10, 1965 – march 27, | choi dae-shik (january 10, 1965 – march 27, 2024) was a south korean footballer who played as a midfielder for daewoo royals (south korea), lg cheetahs (south korea) and oita trinita (japan). he was a participant at 1994 fifa world cup and 1994 asian games. he was also the manager of kyungmin information industrial tec... | wikipedia |
9f2616af9f5e56873b4b932334fb0e9cad72dcd3 | in mathematics, a completely metrizable space (metrically topologically | in mathematics, a completely metrizable space (metrically topologically complete space) is a topological space (x, t) for which there exists at least one metric d on x such that (x, d) is a complete metric space and d induces the topology t. the term topologically complete space is employed by some authors as a synonym... | wikipedia |
6cf83a1793ec84224be717b56388aaa080fdf113 | this implies e. g. that every completely metrizable | this implies e. g. that every completely metrizable topological vector space is complete. indeed, a topological vector space is called complete iff its uniformity (induced by its topology and addition operation) is complete; the uniformity induced by a translation-invariant metric that induces the topology coincides wi... | wikipedia |
7892a9ea99521ad67b30a3f0b01ddf35920a5273 | however, no confusion can arise when talking about | however, no confusion can arise when talking about an abelian topological group or a topological vector space being completely metrizable: it can be proven that every abelian topological group (and thus also every topological vector space) that is completely metrizable as a topological space (i. e., admits a complete m... | wikipedia |
5d207e698daeb5e8a98103f7982e4d65172bd03e | when talking about spaces with more structure than | when talking about spaces with more structure than just topology, like topological groups, the natural meaning of the words “completely metrizable” would arguably be the existence of a complete metric that is also compatible with that extra structure, in addition to inducing its topology. for abelian topological groups... | wikipedia |
36f55fa1f96d9c11d9ca6e04339977ca27aca5ca | the distinction between a completely metrizable space and | the distinction between a completely metrizable space and a complete metric space lies in the words there exists at least one metric in the definition of completely metrizable space, which is not the same as there is given a metric (the latter would yield the definition of complete metric space). once we make the choic... | wikipedia |
9f2616af9f5e56873b4b932334fb0e9cad72dcd3 | in mathematics, a completely metrizable space (metrically topologically | in mathematics, a completely metrizable space (metrically topologically complete space) is a topological space (x, t) for which there exists at least one metric d on x such that (x, d) is a complete metric space and d induces the topology t. the term topologically complete space is employed by some authors as a synonym... | wikipedia |
0438304bc011451def9386de7f477b50f23d83c7 | in 2016, sanderson was appointed as a senior | in 2016, sanderson was appointed as a senior assistant coach at the collingwood football club under senior coach nathan buckley, overseeing forward line and ball movement. sanderson left the collingwood football club at the end of the 2021 season. | wikipedia |
336eb45557c7ad0c2d34968737dfe08fd22b9035 | after getting to within a goal of reaching | after getting to within a goal of reaching the afl grand final in 2012, the crows underachieved in the ensuing two years, finishing 11th and 10th respectively and therefore failing to make the finals. as a result, on 17 september 2014 (almost three years to the day since he was appointed) sanderson was sacked as senior... | wikipedia |
b95dbe2b86f61e2795c1bf2c5228dd89a84cf9b7 | on monday 19 september 2011, sanderson was appointed | on monday 19 september 2011, sanderson was appointed senior coach of the adelaide football club ahead of red hot favourite scott burns and premiership captain mark bickley. sanderson replaced caretaker senior coach mark bickley, who replaced neil craig after craig resigned in the middle of the 2011 season. | wikipedia |
795d25ee646e2392bc58e38b59e0fb1444095c96 | in 1995 sanderson moved to geelong and reinvented | in 1995 sanderson moved to geelong and reinvented himself as a half-back flanker, generating a lot of run out of defence. he had his best season in 2001, when he took out the carji greeves medal as well as earning international rules selection. | wikipedia |
1fa6654b9bd557ad0b7a4c300ec3a57eded9ffc0 | originally from adelaide, south australia, sanderson moved from | originally from adelaide, south australia, sanderson moved from sturt to adelaide as one of their 10 concession picks. while at sturt he injured his right leg and had to learn to kick left footed, this subsequently became his primary kicking foot. he finally made his debut in 1992 but had limited opportunities and play... | wikipedia |
af7c59efeffbc855e878f4d3c62c5436695ca6c4 | giancarlo michele "carlo" corazzin is a canadian retired | giancarlo michele "carlo" corazzin is a canadian retired professional soccer player who played as a forward for winnipeg fury, vancouver 86ers, cambridge united, plymouth argyle, northampton town, oldham athletic and vancouver whitecaps at club level. at international level, he was capped 59 times for the canada nation... | wikipedia |
66b262167dbbc50605ba2c19db32f70097a020b0 | corazzin made his canada national team debut on | corazzin made his canada national team debut on june 1, 1994, in a 1–1 tie with morocco. corazzin scored the majority of his international goals between 1999–2000 and formed an effective striker partnership with paul peschisolido for canada over the years. in 2000, corazzin won the golden boot as top scorer of the conc... | wikipedia |
faf6b38343b71182264477e8c50c7fa00cfaff34 | in 2003, corazzin re-signed with vancouver whitecaps, where | in 2003, corazzin re-signed with vancouver whitecaps, where he scored 7 goals in a 13-game undefeated streak. corazzin played with the whitecaps for 3 years until he was released in 2006. | wikipedia |
8f2720eb35540a243b47c5960e562bcaf72b1634 | on july 28, 2000, after a successful concacaf | on july 28, 2000, after a successful concacaf gold cup with canada, corazzin signed with oldham athletic and scored 22 goals in 129 games over three seasons. his finest moment with oldham came in a match against wrexham when corazzin scored 4 in a 5–1 victory in 2001, finishing it off with his trademark celebration "th... | wikipedia |
cd12934a8371e506642477ff206dcc7ec1a826b8 | corazzin joined northampton town of the third division | corazzin joined northampton town of the third division on june 26, 1998, netting 32 goals in 89 games over two seasons. northampton town were relegated in 1999, but with corazzin's help, the club regained promotion in 2000. | wikipedia |
4df555da0c7a0d56b4ed2e0e3ede2d933dd76a3d | corazzin signed with cambridge united of the english | corazzin signed with cambridge united of the english second division (now known as league 1) on december 10, 1993, scoring 43 goals in 117 games over two-and-a-half seasons. in his final year with cambridge, the team was relegated, and on march 28, 1996, corazzin signed with plymouth argyle for a transfer fee of £ 150 ... | wikipedia |
82a5369785728d71048f21aa797c85ba29d1780e | corazzin began his career with winnipeg fury of | corazzin began his career with winnipeg fury of the canadian soccer league in 1992, scoring 10 goals in 24 games and helping the team win the csl championship. in 1993, corazzin signed with the vancouver whitecaps of the a-league (now known as the usl first division, where he finished second in the team's scoring chart... | wikipedia |
1fe18f6d3d08e84023692885097a06de67667d75 | giancarlo michele "carlo" corazzin (born december 25, 1971) | giancarlo michele "carlo" corazzin (born december 25, 1971) is a canadian retired professional soccer player who played as a forward for winnipeg fury, vancouver 86ers, cambridge united, plymouth argyle, northampton town, oldham athletic and vancouver whitecaps at club level. at international level, he was capped 59 ti... | wikipedia |
7e912e09ef1a962358911bf8af1288c242a84ff8 | cobalt-precorrin 5a hydrolase (ec 3.7.1.12), cbig (gene)) is | cobalt-precorrin 5a hydrolase (ec 3.7.1.12), cbig (gene)) is an enzyme with systematic name cobalt-precorrin 5a acylhydrolase. this enzyme catalyses the following chemical reaction this enzyme hydrolyses the ring a acetate delta-lactone of cobalt-precorrin-5a and releases a two-carbon fragment from the macrocyclic corr... | wikipedia |
1dfd494e06d24cab098923cfb0291f6ee94d961b | this enzyme hydrolyses the ring a acetate delta-lactone | this enzyme hydrolyses the ring a acetate delta-lactone of cobalt-precorrin-5a and releases a two-carbon fragment from the macrocyclic corrin ring as acetaldehyde. this is part of the biosynthetic pathway to cobalamin (vitamin b) in anaerobic bacteria such as salmonella typhimurium and bacillus megaterium. | wikipedia |
dbc9c49aeb77d00e3c06fe1215fb8bbe6c716052 | cobalt-precorrin 5a hydrolase (ec 3.7.1.12), cbig (gene)) is | cobalt-precorrin 5a hydrolase (ec 3.7.1.12), cbig (gene)) is an enzyme with systematic name cobalt-precorrin 5a acylhydrolase. this enzyme catalyses the following chemical reaction | wikipedia |
81642369bdc12b091551623a61b11d639c0256b4 | the chevrolet 153 cu in engine was an | the chevrolet 153 cu in engine was an inline-four engine designed in the early 1960s for use in the chevy ii. it is a four-cylinder variant of the turbo-thrift six-cylinder engine. after 1970, gm ceased production of the 153 engine in north america because of low demand, but the engine continued to be used in cars in o... | wikipedia |
5862c5769b031d43f2e9a86de6d3847b269967aa | gm produced a variant of the 153 for | gm produced a variant of the 153 for use in industrial and marine applications, with the mexican version's larger 4-inch (101.6 mm) bore and a longer 3.6-inch (91.4 mm) stroke. the resulting 3.0 l (181 cu in) engine, branded the vortec 3000, was never installed in passenger cars. the vortec 3000 was manufactured in mex... | wikipedia |
056196596f4c67dc8a971de52bd725e981474d4b | gm de argentina designed its own 110 cu | gm de argentina designed its own 110 cu in (1,797 cc) variant of the engine called the chevrolet 110. the smaller displacement was achieved by using the 3 + 9 ⁄ 16 in (90.5 mm) bore of the 194 cu in straight-six and a unique, short 2 + 1 ⁄ 2 in (63.5 mm) stroke. the engine was designed for use in the locally-built opel... | wikipedia |
cfb2d0af1cdc3b516d5557fda0828b70d788ac21 | this engine was a mainstay for gmsa, who | this engine was a mainstay for gmsa, who built it in its aloes plant (on the northern edge of port elizabeth) for installation in a wide range of cars. two smaller displacement versions of this engine were also built there: a 2,319 cc (141.5 cu in) variant using the 153's bore and the brazilian 151 cu in engine's 3-inc... | wikipedia |
5d29766cd9ff2f8413d4c02796289f3b64a69976 | the 153 engine was used by gm do | the 153 engine was used by gm do brasil in its first locally-made car, the 1968 chevrolet opala. in 1973, the brazilian engineers redesigned the engine in order to quell vibrations, decreasing the stroke to 3 inches (76 mm) and increasing the connecting rod lengths to 6 inches (150 mm). to keep the power output similar... | wikipedia |
8ee4c8f18e0fb7ff144ee02bfb26a7d1d9107623 | in the chevy ii the engine was branded | in the chevy ii the engine was branded as the super-thrift 153, while in the 1964 chevy van, it was called the high torque 153. peak power and torque were 90 hp (67 kw) at 4,000 rpm and 152 lb⋅ft (206 n⋅m) at 2,400 rpm. | wikipedia |
c5540a15896578a59625f348b6cb5bb4010411f6 | the 153 cu in engine had a 3 | the 153 cu in engine had a 3 + 7 ⁄ 8 -inch (98 mm) bore and 3 + 1 ⁄ 4 -inch (82.6 mm) stroke, with two overhead valves per cylinder actuated by pushrods and a 1-3-4-2 firing order. the chevy ii 's 194 cu in six-cylinder used a 3 + 9 ⁄ 16 -inch (90.5 mm) bore, which by 1964 was enlarged to match the 153 four-cylinder's ... | wikipedia |
b57dee817a2278ff6b655acd42d7dbf2c1e7690e | the compact chevrolet corvair was introduced in 1960 | the compact chevrolet corvair was introduced in 1960 to compete with the ford falcon and plymouth valiant, but was handily outsold by its competitors. fearing the corvair's more radical engineering (featuring a rear-mounted air-cooled flat-six engine) was not appealing to consumers, gm hastily approved the design of a ... | wikipedia |
d7817e2492190032dc9f59c6b0231e71afd0fbd9 | the chevrolet 153 cu in engine was an | the chevrolet 153 cu in engine was an inline-four engine designed in the early 1960s for use in the chevy ii. it is a four-cylinder variant of the turbo-thrift six-cylinder engine. after 1970, gm ceased production of the 153 engine in north america because of low demand (and the inline-six was thereafter made the base ... | wikipedia |
3bc79fed3f24e5fa2166b18c44343ca6c9226e5a | "chō" is a song recorded by japanese singer | "chō" is a song recorded by japanese singer shizuka kudo for her eleventh studio album, doing. it was released through pony canyon as the album's second and last single on march 21, 1996. the song featured on tv commercials for the takano yuri beauty clinic. the b-side, "melody", served as ending theme to the 1996 ax t... | wikipedia |
390d9395683fded27b660fe5d41f2f02b79fcd43 | the single's coupling song, "melody", written by aeri | the single's coupling song, "melody", written by aeri and hideya nagazaki, was originally intended to be released as the a-side, but as the song started coming together, it was decided that the showier "chō" would be made into a single instead. | wikipedia |
25ff6760dd56413c01c4e1d860f65160ecf03a14 | "chō" was co-written by kudo, under the pseudonym | "chō" was co-written by kudo, under the pseudonym aeri, the checkers 's naoyuki fujii and akihisa matsūra. it is written in the key of a minor. kudo's vocals span two octaves; from a to e ♭ in modal voice, and a in head voice. during the recording, kudo suggested a few changes to the melody to fujii, who chiefly worked... | wikipedia |
4ce32e78f6f242356f1024d385550433739abb9a | " chō " (蝶 ( ちょう ), lit. | " chō " (蝶 ( ちょう ), lit. "butterfly") is a song recorded by japanese singer shizuka kudo for her eleventh studio album, doing. it was released through pony canyon as the album's second and last single on march 21, 1996. the song featured on tv commercials for the takano yuri beauty clinic. the b-side, "melody", served ... | wikipedia |
36f5ef3cc62d58475f2f5e7c887c2ec104b1040d | in chemistry, a chalcogen bond (chb) is an | in chemistry, a chalcogen bond (chb) is an attractive interaction in the family of σ-hole interactions, along with halogen bonds. electrostatic, charge-transfer (ct) and dispersion terms have been identified as contributing to this type of interaction. in terms of ct contribution, this family of attractive interactions... | wikipedia |
743c8b31160606ff5d0c02543d1956c7fab40243 | chalcogen bonding in catalysis has been used to | chalcogen bonding in catalysis has been used to pre-orient substrate, allowing for asymmetric/stereoselective catalysis on the preferred conformation of the substrate. examples include an asymmetric acyl transfer on an enantiomeric mixture catalyzed by a chiral isothiourea. the acyl group is first transfer on to the ch... | wikipedia |
b83206d5b30652dcbb7b4ffbca8a7cb8083d8002 | the conformational preference can be derived from various | the conformational preference can be derived from various classes of intramolecular chalcogen bonding, including 1,4, 1,5, and 1,6 os interactions, 1,4 and 1,5 ns interactions, and saromatic interactions. each class of these interactions is made up of large classes of drugs in which chalcogen bonding has resulted in up... | wikipedia |
6f994079a2cafb3b819905d18026bfbe12be72ea | drug design is a broad umbrella which includes | drug design is a broad umbrella which includes molecular design to vary biologically relevant characteristics. with regard to weak interactions, the design is aimed at tuning ligand docking/binding of drugs to biologically relevant molecules or proteins and associated biological effects from various binding modes. the ... | wikipedia |
c29067d8ec4487b2200ace3b1f6648bd6d8d17ea | a wide range of applications have been proposed | a wide range of applications have been proposed for designing chalcogen bonds into systems where weak interactions are crucial. this can include areas dependent on specific recognition or molecules, sort of a lock and key model, as seen in drug design, sensing, and highly selective catalysis. additional applications ar... | wikipedia |
d7a727543ce869b94be3ef3cc068caf6e2448adb | a means of comparing the chalcogen-chalcogen bonding forces | a means of comparing the chalcogen-chalcogen bonding forces with h-bonding is to compare the effect of various solvent environments on the chalcogen-chalcogen bond. this has been done on a series of molecules featuring a chalcogen-chalcogen intramolecular bond in one conformation (closed) and exposed to solvent interac... | wikipedia |
95f6a32dec485a63d257d103477568efdc225ff2 | due to a chalcogen's ability to function as | due to a chalcogen's ability to function as an electron donor, many systems will balance between hydrogen bonding with the chalcogen as a donor or chalcogen bonding. this balance can be observed in a series of self-bonding intermolecular interactions between various substituted chalcogens. in cases with hard chalcogen ... | wikipedia |
aa33c293e0450d501d4c838ac793ae91921970ac | both electrostatic mapping and molecular orbital explanation for | both electrostatic mapping and molecular orbital explanation for chalcogen bonding result in a predicted directionality for the bonding interaction. in a hydrogen or halogen bond, the electrophilic region/σ* orbital are located opposite the σ bond, forming a single σ-hole. optimal hydrogen or halogen bonds thus are lin... | wikipedia |
fc0c0374a2f0ba442b7f57ab235e4e1ae2e280d3 | another method used to evaluate chalcogen bonding specifically | another method used to evaluate chalcogen bonding specifically and a wide range of bonding generally is natural bond orbital (nbo) analysis. nbo analysis distinguishes between covalent, lewis-type bonding interactions and non-covalent, non-lewis bonding interaction. the chalcogen bond will be evaluated based on the nat... | wikipedia |
44c9c3634dc4ba2d6f890f277446a03c0082453a | any electron donor can donate electrons into the | any electron donor can donate electrons into the σ-hole of a bonded chalcogen, including halogen anions, amines, and π electrons (such as benzene). similar to halogen bonding, chalcogen bonding can occur between two chalcogens, resulting in a chalcogen-chalcogen bond. non-covalent interactions are well characterized by... | wikipedia |
06ddac349e2e4729cb39e0aff04647cfcef3660b | given the dual ability of chalcogens to serve | given the dual ability of chalcogens to serve as donor and acceptor molecules for σ-hole interactions, a geometric schematic has been generated to distinguish between the differing bonding character. the σ* orbital is exactly opposite the σ bonds to a chalcogen bond. it is the region between the σ-holes in which the lo... | wikipedia |
ce503702102bb092c4ca8cfa4df581df89cc54ea | chalcogen bonding is comparable to other forms of | chalcogen bonding is comparable to other forms of σ-hole interactions. however, the specific contributions to this interaction are still a matter of debate. the contributing forces can be broken down into dispersion / van der waals interactions, electrostatic interactions, and orbital mixing (ct) interactions. these co... | wikipedia |
cbd8fbd8a6987747f2a29e46e9e4267d9ac18ea6 | in chemistry, a chalcogen bond (chb) is an | in chemistry, a chalcogen bond (chb) is an attractive interaction in the family of σ-hole interactions, along with halogen bonds. electrostatic, charge-transfer (ct) and dispersion terms have been identified as contributing to this type of interaction. in terms of ct contribution, this family of attractive interactions... | wikipedia |
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