publicationDate
stringlengths
1
2.79k
title
stringlengths
1
36.5k
abstract
stringlengths
1
37.3k
id
stringlengths
9
47
2017-05-16
The Structural Fate of Individual Multicomponent Metal-Oxide Nanoparticles in Polymer Nanoreactors
Multicomponent nanoparticles can be synthesized with either homogeneous or phase-segregated architectures depending on the synthesis conditions and elements incorporated. To understand the parameters that determine their structural fate, multicomponent metal-oxide nanoparticles consisting of combinations of Co, Ni, and...
1705.05760v2
2017-05-23
Stochastic Replica Voting Machine Prediction of Stable Cubic and Double Perovskite Materials and Binary Alloys
A machine learning approach that we term the `Stochastic Replica Voting Machine' (SRVM) algorithm is presented and applied to a binary and a 3-class classification problems in materials science. Here, we employ SRVM to predict candidate compounds capable of forming stable perovskites and double perovskites and further ...
1705.08491v5
2017-05-24
Transverse Magnetoresistance of Zn$_{0.9}$Co$_{0.1}$O:Al Thin Films
The transverse magnetoresistance of thin films of the Diluted Magnetic Semiconductor Zn$_{1-x}$Co$_{x}$O:Al on glass was studied for temperatures in the range of 5 to 100 K. Measurements were made on thin films grown by rf magnetron sputtering, with a thickness of approximately 200 nm. ZnO was alloyed with Co to a conc...
1705.08936v1
2017-05-25
Spin-wave spectroscopy on Dzyaloshinskii-Moriya interaction in room-temperature chiral magnets hosting skyrmions
Propagation character of spin wave was investigated for chiral magnets FeGe and Co-Zn-Mn alloys, which can host magnetic skyrmions near room temperature. On the basis of the frequency shift between counter-propagating spin waves, the magnitude and sign of Dzyaloshinskii-Moriya (DM) interaction were directly evaluated. ...
1705.09001v1
2017-05-30
Growth of bulk single-crystal MnP helimagnet and its structural and NMR characterization
Bulk single crystals of manganese phosphide (MnP) were grown from melt at 1 GPa and 1200 C by using a cubic-anvil, high-pressure, and high-temperature technique. The obtained black colored crystals exhibit a plate-like morphology, with flat surfaces and maximum dimensions up to 4 x 2 x 0.5 mm3. The orthorhombic crystal...
1705.10491v1
2017-05-30
Towards an ASM thesis for reflective sequential algorithms
Starting from Gurevich's thesis for sequential algorithms (the so-called "sequential ASM thesis"), we propose a characterization of the behaviour of sequential algorithms enriched with reflection. That is, we present a set of postulates which we conjecture capture the fundamental properties of reflective sequential alg...
1705.10708v1
2018-07-03
Hexagonal Sr0.6Ba0.4MnO3: Spin and Dipole Coupling via Local Structure
Hexagonal Sr0.6Ba0.4MnO3 (SBMO) follows P63/mmc symmetry where MnO6 octahedra are both face-shared (Mn2O9 bi-octahedra) and corner-shared via oxygen anion. It undergoes ferroelectric (FE) and antiferromagnetic (AFM) orderings close to the room temperature. Magnetic properties appear to be governed by intricate exchange...
1807.01303v2
2018-07-10
Evidence of the isoelectronic character of F doping in SmFeAsO(1-x)F(x): a first-principles investigation
We study the electronic structure of the SmFeAsO(1-x)F(x) alloy by means of first-principle calculations. We find that, contrary to common believe, F-doping does not change the charge balance between electrons and holes free-carriers in SmFeAsO(1-x)F(x). For energies within a narrow energy range across E_F, the effect ...
1807.03709v1
2018-07-13
Ab initio thermal conductivity of thermoelectric Mg$_3$Sb$_2$: evidence for dominant extrinsic effects
The lattice thermal conductivity of the candidate thermoelectric material Mg$_3$Sb$_2$ is studied from first principles, with the inclusion of anharmonic, isotope, and boundary scattering processes, and via an accurate solution of the Boltzmann equation. We find that the anomalously low observed conductivity is due to ...
1807.04981v3
2018-07-15
Thermoelectric Properties of (1-x)LaCoO$_{3.x}$La$_{0.7}$Sr$_{0.3}$MnO$_3$ Composite
We report the thermoelectric (TE) properties of (1-x)LaCoO3.xLa0.7Sr0.3MnO3 (0 < x < 0.10) composite in a temperature range 320-800 K. Addition of La0.7Sr0.3MnO3 to LaCoO3 in small amount (5 weight %) improves the overall Seebeck coefficient ({\alpha}) at higher temperatures. The electrical conductivity, however, decre...
1807.05563v1
2018-07-15
Tunable double-Weyl Fermion semimetal state in the SrSi$_2$ materials class
We discuss first-principles topological electronic structure of noncentrosymmetric SrSi$_2$ materials class based on the hybrid exchange-correlation functional. Topological phase diagram of SrSi$_2$ is mapped out as a function of the lattice constant with focus on the semimetal order. A tunable double-Weyl Fermion stat...
1807.05585v1
2018-07-15
Accessible computational materials design with high fidelity and high throughput
Despite multiple successful applications of high-throughput computational materials design from first principles, there is a number of factors that inhibit its future adoption. Of particular importance are limited ability to provide high fidelity in a reliable manner and limited accessibility to non-expert users. We pr...
1807.05623v1
2018-07-24
Impact of magnetic moment and anisotropy of Co$_\textrm{1-x}$Fe$_\textrm{x}$ thin films on the magnetic proximity effect of Pt
We present a systematic study of the magnetic proximity effect in Pt, depending on the magnetic moment and anisotropy of adjacent metallic ferromagnets. Element-selective x-ray resonant magnetic reflectivity measurements at the Pt absorption edge (11565$\,$eV) are carried out to investigate the spin polarization of Pt ...
1807.09032v2
2018-07-24
Thermodynamics and kinetics of nucleation in binary solutions
A new approach that is a combination of classical thermodynamics and macroscopic kinetics is offered for studying the nucleation kinetics in condensed binary solutions. The theory covers the separation of liquid and solid solutions proceeding along the nucleation mechanism, as well as liquid-solid transformations, e.g....
1807.09293v1
2018-07-25
Properties of dislocation lines in crystals with strong atomic-scale disorder
We use a discrete dislocation dynamics (DDD) approach to study the motion of a dislocation under strong stochastic forces that may cause bending and roughening of the dislocation line on scales that are comparable to the dislocation core radius. In such situations, which may be relevant in high entropy alloys (HEA) exh...
1807.09512v1
2018-07-25
Engineering strain relaxation of GeSn epilayers on Ge/Si(001) substrates
A mechanism of controlling the degree of strain relaxation in GeSn epilayers, grown by molecular beam epitaxy on Ge/Si(001) substrates, is reported in this work. It is demonstrated that by suitably controlling the thickness and the growth recipe of the underlying Ge buffer layer, both fully-strained and highly-relaxed ...
1807.09718v1
2018-10-02
Spin-dependent (inverse) spin Hall effect in Co$_{60}$Fe$_{20}$B$_{20}$
In ferromagnetic metals, the interconversion of spin and charge currents via the spin Hall effect and its inverse can depend on the angle between the ferromagnets magnetization and the spin current polarization direction. Here, such a spin-dependent (inverse) spin Hall effect is found in the ferromagnetic alloy Co$_{60...
1810.01227v3
2018-10-02
Enhancement of the density of states at the Fermi level due to oxygen atoms in noble metals
The interaction of oxygen with noble metals such as silver has been an important topic of research for many decades. Here, we show occurrence of a peak in the density of states (DOS) at the Fermi level ($E_F$) when oxygen atoms occupy disordered substitutional positions in noble metals such as Ag, Au or Ag-Au alloy. Th...
1810.01454v2
2018-09-30
General Synthetic Route Towards Highly Dispersed Metal Clusters Enabled by Poly(ionic liquid)s
The capability to synthesize a broad spectrum of metal clusters (MCs) with their size controllable in a subnanometer scale presents an enticing prospect for exploring nanosize-dependent properties. Here we report an innovative design of a capping agent from a polytriazolium poly(ionic liquid) (PIL) in a vesicular form ...
1810.01507v1
2018-10-04
Thermal conductivity of strong coupling V$_{1-x}$Ti$_x$ superconductors in the Mott-Ioffe-Regel limit
We report an enhancement of thermal conductivity ($\kappa$) below the superconducting transition temperature ($T_C$) in the high carrier density $\beta$-V$_{1-x}$Ti$_x$ alloys. We find that the point defects generated when Ti is added to V reduce the electron mean free path down to the inter-atomic distances and make t...
1810.02083v1
2018-10-06
Possible origin of $β$-relaxation in amorphous metal alloys from atomic-mass differences of the constituents
We employ an atomic-scale theory within the framework of nonaffine lattice dynamics to uncover the origin of the Johari-Goldstein (JG) $\beta$-relaxation in metallic glasses (MGs). Combining simulation and experimental data with our theoretical approach, we reveal that the large mass asymmetry between the elements in a...
1810.02967v1
2018-10-15
Three-dimensional in situ characterization of phase transformation induced austenite grain refinement in nickel-titanium
Near-field and far-field high-energy diffraction microscopy and microcomputed tomography X-ray techniques were used to study a bulk single crystal nickel-titanium shape memory alloy sample subjected to thermal cycling under a constant applied load. Three-dimensional in situ reconstructions of the austenite microstructu...
1810.06141v2
2018-10-15
Space partitioning of exchange-correlation functionals with the projector augmented-wave method
We implement a Becke fuzzy cells type space partitioning scheme for the purposes of exchange-correlation within the GPAW projector augmented-wave method based density functional theory code. Space partitioning is needed in the situation where one needs to treat different parts of a combined system with different exchan...
1810.06491v1
2018-10-24
Properties of selected structural and flat flexible cabling materials for low temperature applications
We present measurements of the low temperature thermal conductivity for materials useful in the construction of cryogenic supports for scientific instrumentation and in the fabrication of flat flexible cryogenic cabling. The materials we measure have relatively low thermal conductivity. We present a method for measurin...
1810.10187v3
2019-01-01
Machine learning materials physics: Integrable deep neural networks enable scale bridging by learning free energy functions
The free energy of a system is central to many material models. Although free energy data is not generally found directly, its derivatives can be observed or calculated. In this work, we present an Integrable Deep Neural Network (IDNN) that can be trained to derivative data, then analytically integrated to recover an a...
1901.00081v3
2019-01-10
The universal emergence of self-affine roughness from deformation
Most natural and man-made surfaces appear to be rough on many length scales. There is presently no unifying theory of the origin of roughness or the self-affine nature of surface topography. One likely contributor to the formation of roughness is deformation, which underlies many processes that shape surfaces such as m...
1901.03236v1
2019-01-17
Machine Learning for Novel Thermal-Materials Discovery: Early Successes, Opportunities, and Challenges
High-throughput computational and experimental design of materials aided by machine learning have become an increasingly important field in material science. This area of research has emerged in leaps and bounds in the thermal sciences, in part due to the advances in computational and experimental methods in obtaining ...
1901.05801v1
2019-01-20
Influence of morphological instability on grain boundary trajectory during directional solidification
The interplay between the diffusion-controlled dynamics of a solidification front and the trajectory of a grain boundary groove at the solid-liquid interface is studied by means of thin-sample directional solidification experiments of a transparent alloy, and by numerical simulations with the phase-field method in two ...
1901.06705v1
2019-01-22
Semiconducting nature and thermal transport studies of ZrTe3
We report electrical and thermal transport properties of polycrystalline ZrTe3. The polycrystalline sample shows semiconducting behavior in contrast to the established semi-metallic character of the compound. However the charge density wave (CDW) transition remains intact and its clear signatures are observed in therma...
1901.07286v1
2019-01-26
Atomic-scale factors that control the rate capability of nanostructured amorphous Si for high-energy-density batteries
Nanostructured Si is the most promising high-capacity anode material to substantially increase the energy density of Li-ion batteries. Among the remaining challenges is its low rate capability as compared to conventional materials. To understand better what controls the diffusion of Li in the amorphous Li-Si alloy, we ...
1901.09272v1
2019-01-28
Effect of Bi Substitution on Thermoelectric Properties of SbSe2-based Layered Compounds NdO$_{0.8}$F$_{0.2}$Sb$_{1-x}$Bi$_x$Se$_2$
Although SbSe2-based layered compounds have been predicted to be high-performance thermoelectric materials and topological materials, most of these compounds obtained experimentally have been insulators so far. Here, we present the effect of Bi substitution on the thermoelectric properties of SbSe2-based layered compou...
1901.09909v1
2019-01-29
Interdiffusion in Group IV Semiconductor Material Systems: Applications, Research Methods and Discoveries
Group IV semiconductor alloys and heterostructures such as SiGe, GeSn, Ge/Si and SiGe:C have been widely used and under extensive research for applications in major microelectronic and photonic devices. In the growth and processing of these materials, nanometer scale interdiffusion happens that are generally undesirabl...
1901.10105v2
2019-04-05
Two- and three-electron bubbles in Al$_{x}$Ga$_{1-x}$As/Al$_{0.24}$Ga$_{0.76}$As quantum wells
We report on transport signatures of eight distinct bubble phases in the $N=3$ Landau level of a Al$_{x}$Ga$_{1-x}$As/Al$_{0.24}$Ga$_{0.76}$As quantum well with $x = 0.0015$. These phases occur near partial filling factors $\nu^\star \approx 0.2\,(0.8)$ and $\nu^\star \approx 0.3\,(0.7)$ and have $M = 2$ and $M = 3$ el...
1904.03159v1
2019-04-08
On the depth resolution of transmission Kikuchi diffraction (TKD) analysis
In this paper, we have analysed the depth resolution that can be achieved by on-axis transmission Kikuchi diffraction (TKD) using a Zr-Nb alloy. The results indicate that the signals contributing to detectable Kikuchi bands originate from a depth of approximately the mean free path of thermal diffuse scattering (lambda...
1904.04140v1
2019-04-09
Structurally driven asymmetric miscibility in the phase diagram of W-Ti
Phase diagrams for multi-component systems represent crucial information for understanding and designing materials but are very time consuming to assess experimentally. Computational modeling plays an increasingly important role in this regard but has been largely focused on systems with matching lattice structures and...
1904.04814v1
2019-04-10
Tuning the glass-forming ability of metallic glasses through energetic frustration
The design of multi-functional BMGs is limited by the lack of a quantitative understanding of the variables that control the glass-forming ability (GFA) of alloys. Both geometric frustration (e.g. differences in atomic radii) and energetic frustration (e.g. differences in the cohesive energies of the atomic species) co...
1904.05407v1
2019-04-11
Forescattered electron imaging of nanoparticles in a scanning electron microscopy
In this study, we have used a Zr-Nb alloy containing well-defined nano-precipitates as a model material in which to study imaging contrast inversions (atomic number or diffraction contrast) observed with the forescattered electron imaging system, ARGUSTM, in a scanning electron microscope (SEM) when imaging a thin foil...
1904.05660v1
2019-04-24
An atomistic view of grain boundary diffusion
This paper presents an overview of recent computer simulations of grain boundary (GB) diffusion focusing on atomistic understanding of diffusion mechanisms. At low temperatures when GB structure is ordered, diffusion is mediated by point defects inducing collective jumps of several atoms forming a chain. At high temper...
1904.10756v1
2019-04-26
Blueprint for deterministic all-optical switching of magnetization
We resolve a significant controversy about how to understand and engineer single-shot all-optical switching of magnetization in ferrimagnets using femto- or picosecond-long heat pulses. By realistically modelling a generic ferrimagnet as two coupled macrospins, we comprehensively show that the net magnetization can be ...
1904.11977v1
2019-06-19
Giant and Linear Magnetoresistance in Liquid Metals at Ambient Temperature
Disorder-induced magnetoresistance has been reported in a range of solid metals and semiconductors, however, the underlying physical mechanism is still under debate because it is difficult to experimentally control. Liquid metals, due to lack of long-range order, offers an ideal model system where many forms of disorde...
1907.01462v1
2019-07-04
Dynamics of the magnetoelastic phase transition and adiabatic temperature change in Mn1.3Fe0.7P0.5Si0.55
The adiabatic temperature change DTad of a Mn1.3Fe0.7P0.5Si0.55 Fe2P-type alloy was measured under different magnetic field-sweep rates from 0.93 Ts-1 to 2870 Ts-1. We find a field-sweep-rate independent magnetocaloric effect due to a partial alignment of magnetic moments in the paramagnetic region overlapping with the...
1907.02307v1
2019-07-06
Proof of the feasibility of a nanocell-based wide-range optical magnetometer
We present an experimental scheme performing scalar magnetometry based on the fitting of Rb D$_2$ line spectra recorded by derivative selective reflection spectroscopy from an optical nanometric-thick cell. To demonstrate its efficiency, the magnetometer is used to measure the inhomogeneous magnetic field produced by a...
1907.03106v1
2019-07-10
Temperature dependence of magnetic resonance in ferrimagnetic GdFeCo alloys
We provide a macroscopic theory and experimental results for magnetic resonances of antiferromagnetically-coupled ferrimagnets. Our theory, which interpolates the dynamics of antiferromagnets and ferromagnets smoothly, can describe ferrimagnetic resonances across the angular momentum compensation point. We also present...
1907.04540v1
2019-07-11
Structural properties of Co$_{2}$TiSi films on GaAs(001)
Co$_{2}$TiSi films were grown by molecular beam epitaxy on GaAs(001) and analyzed using reflection high-energy electron diffraction, and electron microscopy. In addition, X-ray diffraction was combined with lattice parameter calculations by density functional theory comparing the \textit{L$2_1$} and \textit{B}2 structu...
1907.05238v1
2019-07-19
A Koopmans-compliant screened exchange potential with correct asymptotic behavior for semiconductors
The performance of density functional theory depends largely on the approximation applied for the exchange functional. We propose here a novel screened exchange potential for semiconductors, with parameters based on the physical properties of the underlying microscopic screening and obeying the requirements for proper ...
1907.08404v5
2019-07-25
Stainless Steel Surface Structure and Initial Oxidation at Nanometric and Atomic Scales
The durability of passivable metals and alloys is often limited by the stability of the surface oxide film, the passive film, providing self-protection against corrosion in aggressive environments. Improving this stability requires to develop a deeper understanding of the surface structure and initial surface reactivit...
1907.10911v1
2019-07-25
Multipolar order and excitations in rare-earth boride Kondo systems
We review the cubic rare-earth boride series which displays diverse electronic states like localized 4f electron multiplets split by the crystal electric field (CEF), itinerant heavy-fermion quasiparticle bands of the Kondo lattice as well as gapped Kondo insulator or mixed-valent semiconductor states. Fairly exotic st...
1907.10967v1
2019-07-27
High CO2-tolerance oxygen permeation dual-phase membranes Ce0.9Pr0.1O2-δ-Pr0.6Sr0.4Fe0.8Al0.2O3-δ
High stability and oxygen permeability are two prominent requirements for the oxygen transport membrane candidates used as industrialization. Herein, we report several composite membranes based on xwt.%Ce0.9Pr0.1O2(CPO)-(100-x)wt.%Pr0.6Sr0.4Fe0.8Al0.2O3(PSFAO) (x = 50, 60 and 75) prepared via a modified Pechini method....
1907.11923v1
2019-07-27
Microwave derived monoclinic Ba1-xSnxNb2O6 materials as an alternative of ITO
Microwave synthesis was optimized for preparing novel monoclinic Tin-doped Barium Niobate ceramics (Ba1-xSnxNb2O6; x= 0.0, 0.01, 0.05, 0.1, 0.2, 0.3) BSN. The intensity of monoclinic phase formation was observed to decrease on increasing tin as dopant indicating decreased crystallinity. Strained crystalline phase was o...
1907.11946v1
2019-07-31
Carrier free long-range magnetism in Mo doped one quintuple layer Bi2Te3 and Sb2Te3
One of the keys to the realization of Quantum Anomalous Hall effect (QAHE) is long range ferromagnetism, which is only experimentally realized in Cr or V doped (Bi,Sb)2Te3 system. Both elements are 3d transition metals and 4d transition metals are found to be ineffective to produce long range ferromagnetism in Bi2Se3. ...
1907.13282v1
2019-10-01
Skyrmions in CeFeB Amorphous Nanodisks
Rare earth Fe B permanent magnets are usually used because of their excellent magnetic performance at room temperature. The high price of these elements pushes some researchers to find new alternatives. From rare earth elements cerium (Ce) is considered as the most abundant and cheap, therefore, the interest was focuse...
1910.00302v1
2019-10-07
Built-in electric field induces polarization rotation in bilayer BiFeO3/(Ba,Sr)TiO3 thin films
The crystal structure of BiFeO3/BaxSr1-xTiO3 (BFO/BST) heterostructures with x = 0.2, 0.6 and 0.8, grown on single-crystal MgO (001) substrate was investigated by x-ray diffraction and Raman spectroscopy in order to determine the influence of mismatch-induced strains and spontaneous polarization in BST buffer layers on...
1910.02681v1
2019-10-09
Effective medium approach in the renormalization group theory of phase transitions
An effective medium approach similar to the coherent potential approximation (CPA) in the theory of disordered alloys and to the DMFT has been extended to the renormalization group equations in the local potential approximation (LPA). Non-universal characteristics of the second order phase transitions such as the criti...
1910.05123v1
2019-10-15
Spontaneous photo-generated carrier separation of SnO/BiOX (X=Cl, Br, I) bilayer under visible light irradiation for water splitting
Alloying in 2D materials plays a more and more important role due to wide range bandgap tunability and integrating the advantages of HER and OER. Here, the novel bilayers of SnO/BiOX (X= Cl, Br and I) bilayer are constructed to integrate the advantages of narrow bandgap and separating photo-generated carriers. The band...
1910.06543v1
2019-10-04
Mechanical modeling of superelastic tensegrity braces for earthquake-proof structures
This paper presents a novel application of tensegrity systems as lightweight and noninvasive braces for seismically resistant structures. The analyzed braces consist of D-bar systems equipped with shape memory alloy cables with superelastic response. These structures are able to markedly amplify the applied longitudina...
1910.07080v1
2019-10-16
The Carbon State in Dilute Germanium Carbides
Conduction and valence band states for the highly mismatched alloy (HMA) Ge:C are projected onto Ge crystal states, Ge vacancy states, and Ge/C atomic orbitals, revealing that substitutional carbon not only creates a direct bandgap, but the new conduction band is optically active. Overlap integrals of the new Ge:C cond...
1910.07258v1
2019-10-17
Substoichiometric ultrathin zirconia films cause strong metal-support interaction
The strong metal-support interaction (SMSI) leads to substantial changes of the properties of an oxide-supported catalyst after annealing under reducing conditions. The common explanation is the formation of heavily reduced, ultrathin oxide films covering metal particles. This is typically encountered for reducible oxi...
1910.07798v1
2019-10-17
Robust cluster expansion of multicomponent systems using structured sparsity
Identifying a suitable set of descriptors for modeling physical systems often utilizes either deep physical insights or statistical methods such as compressed sensing. In statistical learning, a class of methods known as structured sparsity regularization seeks to combine both physics- and statistics-based approaches. ...
1910.08086v1
2019-10-23
Numerical and Experimental Investigation of Electro-Vortex Flow in a Cylindrical Container
In a cylindrical container filled with an eutectic GaInSn alloy, an electro-vortex flow (EVF) is generated by the interaction of a non-uniform current with its own magnetic field. In this paper, we investigate the EVF phenomenon numerically and experimentally. Ultrasound Doppler Velocimetry (UDV) is applied to measure ...
1910.10454v1
2019-10-28
Delta-doped \b{eta}-Ga2O3 thin films and \b{eta}-(Al0.26Ga0.74)2O3/\b{eta}-Ga2O3 heterostructures grown by metalorganic vapor-phase epitaxy
We report on silicon delta doping of metalorganic vapor-phase epitaxy-grown \b{eta}-Ga2O3 thin films using silane precursor. Delta-doped \b{eta}-Ga2O3 epitaxial films are characterized using capacitance-voltage profiling and secondary-ion mass spectroscopy. Electron sheet charge density in the range of 2.9e12 cm-2 to 8...
1910.12432v2
2012-09-05
Metallic spin-glasses beyond mean-field: An approach to the impurity-concentration dependence of the freezing temperature
A relation between the freezing temperature ($T^{}_{\rm g}$) and the exchange couplings ($J^{}_{ij}$) in metallic spin-glasses is derived, taking the spin-correlations ($G^{}_{ij}$) into account. This approach does not involve a disorder-average. The expansion of the correlations to first order in $J^{}_{ij}/T^{}_{\rm ...
1209.0926v7
2012-09-05
First-principles study of elastic properties of Cr-Al-N
The elastic properties of paramagnetic cubic B1 (c-) Cr1-xAlxN ternary alloys are studied using stress-strain and energy-strain methods within the framework of Density Functional Theory (DFT). A strong compositional dependence of the elastic properties is predicted. Young's modulus, E, and shear modulus, G, exhibit the...
1209.0955v1
2012-09-06
Thermodynamic Comparison and the Ideal Glass Transition of A Monatomic Systems Modeled as an Antiferromagnetic Ising Model on Husimi and Cubic Recursive Lattices of the Same Coordination Number
Two kinds of recursive lattices with the same coordination number but different unit cells (2-D square and 3-D cube) are constructed and the antiferromagnetic Ising model is solved exactly on them to study the stable and metastable states. The Ising model with multi-particle interactions is designed to represent a mona...
1209.2090v2
2012-09-13
The spin Hall effect as a probe of nonlinear spin fluctuations
The spin Hall effect and its inverse play key roles in spintronic devices since they allow conversion of charge currents to and from spin currents. The conversion efficiency strongly depends on material details, such as the electronic band structure and the nature of impurities. Here we show an anomaly in the inverse s...
1209.2799v1
2012-09-13
Origin of the Superior Conductivity of Perovskite Ba(Sr)SnO3
ASnO3 (A=Ba, Sr) are unique perovskite oxides in that they have superior electron conductivity despite their wide optical band gaps. Using first-principles band structure calculations, we show that the small electron effective masses, thus, good electron conductivity of ASnO3 can be attributed to the large size of Sn i...
1209.2845v3
2012-09-20
A Response Embedded Atom Method of Interatomic Potentials
The embedded atom method (EAM) potentials are probably the most widely used interatomic potentials for metals and alloys. However, the EAM potentials impose three constraints on elastic constants that are inconsistent with experiments. At a more subtle (but more important) level, the EAM potentials often incorrectly de...
1209.4568v1
2012-09-22
Origin of perpendicular magneto-crystalline anisotropy in L10-FeNi under tetragonal distortion
We investigated the origin of perpendicular magneto-crystalline anisotropy (MCA) in L10 ordered FeNi alloy using first-principles density-functional calculations. We found that the perpendicular MCA of L10-FeNi arises predominantly from the constituent Fe atoms, which is consistent with recent measurements of the aniso...
1209.5003v2
2012-09-23
Existence, Uniqueness and Anisotropic-Decay-Caused Lifshitz Tails of the Integrated Density of Surface States for Random Surface Models
The current paper is devoted to the study of existence, uniqueness and Lifshitz tails of the integrated density of surface states (IDSS) for Schr\"{o}dinger operators with alloy type random surface potentials. We prove the existence and uniqueness of the IDSS for negative energies, which is defined as the thermodynamic...
1209.5092v1
2012-09-24
Coherent reaction of Fermi superfluid on correlated disorder
Motivated by the disparity between the experimentally observed properties of superfluid 3He in aerogel and predictions of the Abrikosov and Gorkov theory of superconducting alloys we consider effect of correlated pair-breaking impurities on the temperature dependence of the square of magnitude of the average order para...
1209.5172v2
2012-09-26
Topological electronic structure and Weyl semimetal in the TlBiSe$_2$ class of semiconductors
We present an analysis of bulk and surface electronic structures of thallium based ternary III-V-VI$_2$ series of compounds TlMQ$_2$, where M=Bi or Sb and Q=S, Se or Te, using the ab initio density functional theory framework. Based on parity analysis and (111) surface electronic structure, we predict TlSbSe$_2$, TlSbT...
1209.5896v1
2014-06-01
Parameters of microdiffusion in f.c.c.-Ni-Mo solid solutions
The time evolution of diffuse X-ray scattering intensities conditioned by the short-range order (SRO) in Ni-Mo solid solutions is investigated. As shown, the transition from a quenched (nonequilibrium) state to the equilibrium one is accompanied by the complex time reorganization of various SRO types. Computer simulati...
1406.0144v1
2014-06-01
Microscopic approach to the evaluation of diffusion coefficients for substitutional f.c.c. solid solutions
The microscopic theory of atomic diffusion kinetics is used for f.c.c. substitutional solid solutions. Within this approach, the short-range order relaxation is due to the atomic migration. Experimental data on the time dependence of radiation diffuse scattering are used for the determination of microscopic characteris...
1406.0145v1
2014-06-03
Muon spin rotation and relaxation in Pr$_{1-x}$Nd$_x$Os$_4$Sb$_{12}$: Paramagnetic states
Positive-muon ($\mu^+$) Knight shifts have been measured in the paramagnetic states of Pr$_{1-x}$Nd$_x$Os$_4$Sb$_{12}$ alloys, where $x =$ 0, 0.25, 0.45, 0.50, 0.55, 0.75, and 1.00. In Pr-substituted NdOs$_4$Sb$_{12}$ ($x \le$ 0.75), but not in NdOs$_4$Sb$_{12}$, Clogston-Jaccarino plots of $\mu^+$ Knight shift~$K$ ver...
1406.0903v1
2014-06-06
Convective nonlocal Cahn-Hilliard equations with reaction terms
We introduce and analyze the nonlocal variants of two Cahn-Hilliard type equations with reaction terms. The first one is the so-called Cahn-Hilliard-Oono equation which models, for instance, pattern formation in diblock-copolymers as well as in binary alloys with induced reaction and type-I superconductors. The second ...
1406.1684v2
2014-06-16
The role of stoichiometric vacancy periodicity in pressure-induced amorphization of the Ga2SeTe2 semiconductor alloy
We observe that pressure-induced amorphization of Ga2SeTe2 (a III-VI semiconductor) is directly influenced by the periodicity of its intrinsic defect structures. Specimens with periodic and semi-periodic two-dimensional vacancy structures become amorphous around 10-11 GPa in contrast to those with aperiodic structures,...
1406.3923v1
2014-06-17
Theory of a quodon gas. With application to precipitation kinetics in solids under irradiation
Rate theory of the radiation-induced precipitation in solids is modified with account of non-equilibrium fluctuations driven by the gas of lattice solitons (a.k.a. quodons) produced by irradiation. According to quantitative estimations, a steady-state density of the quodon gas under sufficiently intense irradiation can...
1406.4314v1
2014-06-20
Anomalous Hall Effect in Ge(1-x-y)Pb(x)Mn(y)Te Composite System
The purpose of this study was to investigate the magnetotransport properties of the Ge(0.743)Pb(0.183)Mn(0.074)Te mixed crystal. The results of magnetization measurements indicated that the compound is a spin-glass-like diluted magnetic semiconductor with critical temperature TSG = 97.5 K. Nanoclusters in the sample ar...
1406.5294v1
2014-06-23
Theoretical study of the thermoelectric properties of SiGe nanotubes
The thermoelectric properties of two typical SiGe nanotubes are investigated using a combination of density functional theory, Boltzmann transport theory, and molecular dynamics simulations. Unlike carbon nanotubes, these SiGe nanotubes tend to have gear-like geometry, and both the (6, 6) and (10, 0) tubes are semicond...
1406.5832v1
2018-02-01
Laser induced breakdown spectroscopy for multielement analysis of powder materials utilized in additive technologies
Powder materials utilized in additive technologies were quantitatively analyzed by laser induced breakdown spectroscopy for the first time. Laser induced breakdown spectroscopy mapping of loose metal powder attached to the double-sided adhesive tape provided high reproducibility of measurements even for powder mixtures...
1802.00236v1
2018-02-10
Constructing first-principles phase diagrams of amorphous LixSi using machine-learning-assisted sampling with an evolutionary algorithm
The atomistic modeling of amorphous materials requires structure sizes and sampling statistics that are challenging to achieve with first-principles methods. Here, we propose a methodology to speed up the sampling of amorphous and disordered materials using a combination of a genetic algorithm and a specialized machine...
1802.03548v1
2018-02-14
Limit Theorems for the Alloy-type Random Energy Model
In this paper, we consider limit laws for the model, which is a generalisation of the random energy model (REM) to the case when the energy levels have the mixture distribution. More precisely, the distribution of the energy levels is assumed to be a mixture of two normal distributions, one of which is standard normal,...
1802.05071v1
2018-02-13
From mean-field localized magnetism to itinerant spin fluctuations in the "Non-metallic metal" - FeCrAs
FeCrAs displays an unusual electrical response that is neither metallic in character nor divergent at low temperatures, as expected for an insulating response, and therefore it has been termed a "nonmetal-metal". We carried out neutron scattering experiments on powder and single crystal samples to study the magnetic dy...
1802.05271v2
2018-02-15
Covariance Function Pre-Training with m-Kernels for Accelerated Bayesian Optimisation
The paper presents a novel approach to direct covariance function learning for Bayesian optimisation, with particular emphasis on experimental design problems where an existing corpus of condensed knowledge is present. The method presented borrows techniques from reproducing kernel Banach space theory (specifically m-k...
1802.05370v2
2018-02-15
High Dimensional Bayesian Optimization Using Dropout
Scaling Bayesian optimization to high dimensions is challenging task as the global optimization of high-dimensional acquisition function can be expensive and often infeasible. Existing methods depend either on limited active variables or the additive form of the objective function. We propose a new method for high-dime...
1802.05400v1
2018-02-15
Damping's effect on the magnetodynamics of spin Hall nano-oscillators
We study the impact of spin wave damping ($\alpha$) on the auto-oscillation properties of nano-constriction based spin Hall nano-oscillators (SHNOs). The SHNOs are based on a 5 nm Pt layer interfaced to a 5 nm Py$_{100-x-y}$Pt$_{x}$Ag$_{y}$ magnetic layer, where the Pt and Ag contents are co-varied to keep the saturati...
1802.05548v1
2018-02-21
Influence of surface stoichiometry and quantum confinement on the electronic structure of small diameter InxGa1-xAs nanowires
Electronic structures for InxGa1-xAs nanowires with [100], [110], and [111] orientations and critical dimensions of approximately 2 nm are treated within the framework of density functional theory. Explicit band structures are calculated and properties relevant to nanoelectronic design are extracted including band gaps...
1802.07848v1
2018-02-21
Work of a multi-cathode counter in a single electron counting mode
We describe a work of a multi-cathode counter of the developed design in a single electron counting mode with a cathode made of aluminum alloy. The results of the calibration of the counter are presented. The coefficient of gas amplification was found from the calibration spectra. The electric fields and operation of t...
1802.07879v2
2018-02-22
Thermally driven anomalous Hall effect transitions in FeRh
Materials exhibiting controllable magnetic phase transitions are currently in demand for many spintronics applications. Here we investigate from first principles the electronic structure and intrinsic anomalous Hall, spin Hall and anomalous Nernst response properties of the FeRh metallic alloy which undergoes a thermal...
1802.08208v1
2018-02-26
Simulation of Thin-TFETs Using Transition Metal Dichalcogenides: Effect of Material Parameters, Gate Dielectric on Electrostatic Device Performance
In recent years, a lot of scientific research effort has been put forth for the investigation of Transition Metal Dichalcogenides (TMDC) and other Two Dimensional (2D) materials like Graphene, Boron Nitride. Theoretical investigation on the physical aspects of these materials has revealed a whole new range of exciting ...
1802.09140v1
2018-08-03
Influence of the AlN interlayer thickness on the photovoltaic properties of In-rich AlInN on Si heterojunctions deposited by RF sputtering
We report the influence of the AlN interlayer thickness (0-15 nm) on the photovoltaic properties of Al0.37In0.63N on Si heterojunction solar cells deposited by radio frequency sputtering. The poor junction band alignment and the presence of a 2-3 nm thick amorphous layer at the interface mitigates the response in devic...
1808.01117v1
2018-08-06
Short Note on Superconductivity at Ambient Temperature and Pressure in Silver Embedded Gold Nano-particles: A Goldsmith job ahead
Very recent observation of superconductivity in both transport (resistance versus temperature) and magnetization (Zero field cooled) at around 235 K has obviously raised many eyebrows. The experimental fraternity in particular is more thrilled. Although the results presented in the paper are clean and both transport an...
1808.01797v2
2018-08-04
Probing multipulse laser ablation by means of self-mixing interferometry
In this work, self-mixing interferometry (SMI) is implemented inline to a laser microdrilling system to monitor the machining process by probing the ablation-induced plume. An analytical model based on the Sedov-Taylor blast wave equation is developed for the expansion of the process plume under multiple-pulse laser pe...
1808.02015v2
2018-08-16
Superconductivity in the Bi/Ni bilayer
Motivated by the recent observations of possible p-wave superconductivity in the bismuth-nickel (Bi/Ni) bilayer, we explore theoretically the possibilities of realizing p-wave superconductivity in this bilayer. We begin with a literature survey on this system and related materials which have similar superconducting tra...
1808.05333v2
2018-08-22
Polarization properties of wurtzite III nitride indicate the principle of polarization engineering
The spontaneous and piezoelectric polarizations of III-nitrides considerably affect the operation of various III-nitride-based devices. We report an ab initio study of the spontaneous polarization (SP) and piezoelectric (PZ) constants of the III-nitride binary and ternary alloys with the hexagonal reference structure. ...
1808.07211v4
2018-08-27
Theoretical approach to the ductile fracture of polycrystalline solids
It is shown here that fracture after a brief plastic strain, typically of a few percents, is a necessary consequence of the polycrystalline nature of the materials. The polycrystal undergoing plastic deformation is modeled as a flowing continuum of random deformable polyhedra, representing the grains, which fill the sp...
1808.08670v1
2018-08-27
Sign Reversal and Tunability of Exchange Bias in Nanoscale AuFe Alloy Film: A New Material for Spintronic Application
We report here sign reversal and tunability of exchange bias in AuFe cosputtered films of thickness about 63 nm. As deposited film exhibits exchange bias effect at room temperature without external triggering field and its magnitude increases gradually with decrease in temperature down to 5 K. Upon irradiation with 100...
1808.08694v1
2018-08-29
Synthesizing Cu-Sn nanowires alloy in highly-ordered Aluminum Oxide templates by using electrodeposition method
In this research a novel and simple electrochemical method is developed in order to facilitate the large-scale production of nanowires. The proposed electrochemical technique shows versatile controllability over chemical composition and crystalline structure of Cu-Sn nanowires. Another important factor, which could be ...
1808.09838v1
2018-08-30
Interfacial Energy of Copper Clusters in Fe-Si-B-Nb-Cu alloys
Using a combination of numerical simulations and atom-probe tomography experiments, we determine the interfacial energy of Cu nanocrystals precipitated within the amorphous matrix of FINEMET (molar composition Fe72.89Si16.21B6.90Nb3Cu1). Specifically, we use the Langer-Schwartz model implemented in the software Thermoc...
1808.10525v3
2018-08-31
Renormalizations in unconventional superconducting states of Ce$_{1-x}$Yb$_{x}$CoIn$_{5}$
We have measured the superconducting penetration depth~$\Lambda(T)$ in the heavy-fermion/intermediate-valent superconducting alloy series~Ce$_{1-x}$Yb$_x$CoIn$_5$ using transverse-field muon spin relaxation, to study the effect of intermediate-valent Yb doping on Fermi-liquid renormalization. From $\Lambda(T)$ we deter...
1808.10606v2
2018-12-05
Quantum mechanics basis of quality control in hard metals
Non-destructive and reliable quality control methods are a key aspect to designing, developing and manufacturing new materials for industrial applications and new technologies. The measurement of the magnetic saturation is one of such methods and it is conventionally employed in the cemented carbides industry. We prese...
1812.01960v1