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2016-03-16
Robust Structural Identification via Polyhedral Template Matching
Successful scientific applications of large-scale molecular dynamics often rely on automated methods for identifying the local crystalline structure of condensed phases. Many existing methods for structural identification, such as Common Neighbour Analysis, rely on interatomic distances (or thresholds thereof) to class...
1603.05143v2
2016-03-25
ThFeAsN in Relation to Other Iron-Based Superconductors
The electronic structure, magnetic and structural properties of the superconductor ThFeAsN are discussed in relation to the Fe-pnictide and Fe-chalcogenide superconductors based on results of first principles calculations. The electronic structure is that of a high density of states semimetal. It shows approximately ne...
1603.07917v1
2016-03-30
The identification of the dominant donors in low temperature grown InPBi materials
Combined with magnetotransport measurements and first-principles calculations, we systematically investigated the effects of Bi incorporation on the electrical properties of the undoped InP1-xBix epilayers with 0<x<2.41%. The Hall-bar measurements reveal a dominant n-type conductivity of the InPBi samples. The electron...
1603.09015v1
2016-12-14
Modeling of cyclic creep in the finite strain range using a nested multiplicative split
A new phenomenological model of cyclic creep is proposed which is suitable for applications involving finite creep deformations of the material. The model accounts for the the effect of the transient increase of the creep strain rate upon the load reversal. In order to extend the applicability range of the model, the c...
1612.04620v1
2016-12-21
Quantum Griffiths phase inside the ferromagnetic phase of Ni$_{1-x}$V$_x$
We study by means of bulk and local probes the d-metal alloy Ni$_{1-x}$V$_x$ close to the quantum critical concentration, $x_c \approx 11.6\%$, where the ferromagnetic transition temperature vanishes. The magnetization-field curve in the ferromagnetic phase takes an anomalous power-law form with a nonuniversal exponent...
1612.07207v2
2016-12-23
Density functional theory study of vacancy induced magnetism in Li$_{3}$N
The effect of lithium vacancies in the hexagonal structure of $\alpha-$Li$_3$N, is studied within the framework of density functional theory. Vacancies ($\square$) substituting for lithium in $\alpha-$Li$_2$(Li$_{1-x}\square_x$)N are treated within the coherent potential approximation as alloy components. According to ...
1612.07981v2
2017-02-02
Low-Symmetry Two-Dimensional Materials for Electronic and Photonic Applications
In this review article, we discuss the synthesis, properties, and novel device applications of low-symmetry 2D materials, including black phosphorus and its arsenic alloys, compounds with black-phosphorus like structure such as the monochalcogenides of group IV elements like Ge and Sn, as well as the class of low-symme...
1702.00573v1
2017-02-03
Free energy calculation of mechanically unstable but dynamically stabilized bcc titanium
The phase diagram of numerous materials of technological importance features high-symmetry high-temperature phases that exhibit phonon instabilities. Leading examples include shape-memory alloys, as well as ferroelectric, refractory, and structural materials. The thermodynamics of these phases have proven challenging t...
1702.00911v1
2017-02-05
Atomic Order in Non-Equilibrium Silicon-Germanium-Tin Semiconductors
The precise knowledge of the atomic order in monocrystalline alloys is fundamental to understand and predict their physical properties. With this perspective, we utilized laser-assisted atom probe tomography to investigate the three-dimensional distribution of atoms in non-equilibrium epitaxial Sn-rich group IV SiGeSn ...
1702.01366v1
2017-02-17
Magnetic anisotropy in Permalloy: hidden quantum mechanical features
By means of relativistic, first principles calculations, we investigate the microscopic origin of the vanishingly low magnetic anisotropy of Permalloy, here proposed to be intrinsically related to the local symmetries of the alloy. It is shown that the local magnetic anisotropy of individual atoms in Permalloy can be s...
1702.05414v1
2017-02-22
Probing the role of carbon solubility in transition metal catalyzing Single-Walled Carbon Nanotubes growth
Metal catalysts supporting the growth of Single Wall Carbon Nanotubes display different carbon solubilities and chemical reactivities. In order to specifically assess the role of carbon solubility, we take advantage of the physical transparency of a tight binding model established for Ni-C alloys, to develop metal carb...
1702.06742v1
2017-02-23
Spin-Orbit Coupling of Conduction Electrons in Magnetization Switching
Strong magnetic field pulses associated with a relativistic electron bunch can imprint switching patterns in magnetic thin films that have uniaxial in-plane anisotropy. In experiments with Fe and FeCo alloy films the pattern shape reveals an additional torque acting on magnetization during the short (in the 100fs time ...
1702.07153v1
2017-06-06
The Vapor-Solid-Solid Growth of Ge Nanowires on Ge (110) by Molecular Beam Epitaxy
We demonstrate Au-assisted vapor-solid-solid (VSS) growth of Ge nanowires (NWs) by molecular beam epitaxy (MBE) at 220 {\deg}C, which is compatible with the temperature window for Si-based integrated circuit. Low temperature grown Ge NWs hold a smaller size, similar uniformity and better fit with Au tips in diameter, i...
1706.01605v1
2017-06-12
Blue-to-green single photons from InGaN/GaN dot-in-a-wire nanowire ordered arrays
Single-photon emitters (SPEs) are at the basis of many applications for quantum information management. Semiconductor-based SPEs are best suited for practical implementations because of high design flexibility, scalability and integration potential in practical devices. Single-photon emission from ordered arrays of InG...
1706.03601v1
2017-06-15
First order magneto-structural transition and magnetocaloric effect in MnNiGe$_{0.9}$Ga$_{0.1}$
The first order magneto-structural transition ($T_t\simeq95$ K) and magnetocaloric effect in MnNiGe$_{0.9}$Ga$_{0.1}$ are studied via powder x-ray diffraction and magnetization measurements. Temperature dependent x-ray diffraction measurements reveal that the magneto-structural transition remains incomplete down to 23 ...
1706.04740v1
2017-06-17
Optical readout of hydrogen storage in films of Au and Pd
For hydrogen sensor and storage applications, films of Au and Pd were (i) co-sputtered at different rates or (ii) deposited in a sequential layer-by-layer fashion on a cover glass. Peculiarities of hydrogen uptake and release were optically monitored using 1.3 micrometers wavelength light. Increase of optical transmiss...
1706.05517v1
2017-06-19
Spin Hall effect from hybridized 3$d$-4$p$ orbitals
Electrical manipulation of magnetization by spin-orbit torque (SOT) has shown promise for realizing reliable magnetic memories and oscillators. To date, the generation of transverse spin current and SOT, whether it is of spin Hall effect (SHE), Rashba-Edelstein effect or spin-momentum locking origin, relies primarily o...
1706.05846v1
2017-06-21
Compact arrangement for femtosecond laser induced generation of broadband hard x-ray pulses
We present a simple apparatus for femtosecond laser induced generation of X-rays. The apparatus consists of a vacuum chamber containing an off-axis parabolic focusing mirror, a reel system, a debris protection setup, a quartz window for the incoming laser beam, and an X-ray window. Before entering the vacuum chamber, t...
1706.06819v1
2017-06-23
Nearly Blinking-Free, High-Purity Single-Photon Emission by Colloidal InP/ZnSe Quantum Dots
Colloidal core/shell InP/ZnSe quantum dots (QDs), recently produced using an improved synthesis method, have a great potential in life-science applications as well as in integrated quantum photonics and quantum information processing as single-photon emitters. Single-particle spectroscopy of 10-nm QDs with 3.2-nm cores...
1706.07609v1
2017-06-28
Multiple scattering theory for heterogeneous elastic continua with strong property fluctuation: theoretical fundamentals and applications
In this work, the author developed a multiple scattering model for heterogeneous elastic continua with strong property fluctuation and obtained the exact solution to the dispersion equation derived from the Dyson equation under the first-order smoothing approximation. The model establishes accurate quantitative relatio...
1706.09137v1
2017-06-28
Super-Hydrophobic Stearic Acid Layer Formed on Anodized High Purified Magnesium for Improving Corrosion Resistance of Biodegradable Implants
Magnesium and its alloys are ideal candidates for biodegradable implants. However, they can dissolve too rapidly in the human body for most applications. In this research, high purified magnesium (HP-Mg) was coated with stearic acid in order to slow the corrosion rate of magnesium in simulated body fluid at 37{\deg}C. ...
1706.09508v1
2017-10-02
The multi-purpose three-axis spectrometer (TAS) MIRA at FRM II
The cold-neutron three-axis spectrometer MIRA is an instrument optimized for low-energy excitations. Its excellent intrinsic $Q$-resolution makes it ideal for studying incommensurate magnetic systems (elastic and inelastic). MIRA is at the forefront of using advanced neutron focusing optics such as elliptic guides, whi...
1710.00589v1
2017-09-08
Understanding deformation with high angular resolution electron backscatter diffraction (HR-EBSD)
High angular resolution electron backscatter diffraction (HR-EBSD) affords an increase in angular resolution, as compared to 'conventional' Hough transform based EBSD, of two orders of magnitude, enabling measurements of relative misorientations of 1E-4 rads (~ 0.006 {\deg}) and changes in (deviatoric) lattice strain w...
1710.00728v1
2017-10-02
Wegner estimate and disorder dependence for alloy-type Hamiltonians with bounded magnetic potential
We consider non-ergodic magnetic random Sch\"odinger operators with a bounded magnetic vector potential. We prove an optimal Wegner estimate valid at all energies. The proof is an adaptation of the arguments from [Kle13], combined with a recent quantitative unique continuation estimate for eigenfunctions of elliptic op...
1710.00899v3
2017-10-02
Band Topology and Dichroic Signature of Bismuth
Bismuth has been the key element in the discovery and development of topological insulator materials. Previous theoretical studies indicated that Bi is topologically trivial and it can transform into the topological phase by alloying with Sb. However, recent high-resolution angle-resolved photoemission spectroscopy (AR...
1710.00908v1
2017-10-05
First-principles and model simulation of all-optical spin reversal
All-optical spin switching is a potential trailblazer for information storage and communication at an unprecedented fast rate and free of magnetic fields. However, the current wisdom is largely based on semiempirical models of effective magnetic fields and heat pulses, so it is difficult to provide high-speed design pr...
1710.01834v1
2017-10-05
Multi-scale Modeling of Plasticity Nearby Precipitates in Nanostructured Materials
Precipitation strengthening is one of the most effective methods to design alloys with the desired combination of strength and ductility. The main mechanism of strengthening is generally known to be the interaction between dislocations and precipitates. When a dislocation encounters a precipitate, it bends and therefor...
1710.02075v3
2017-10-10
Predictive design and experimental realization of InAs/GaAs superlattices with tailored thermal conductivity
We demonstrate an ab-initio predictive approach to computing the thermal conductivity ($\kappa$) of InAs/GaAs superlattices (SLs) of varying period, thickness, and composition. Our new experimental results illustrate how this method can yield good agreement with experiment when realistic composition profiles are used a...
1710.03449v1
2017-10-16
Carrier and Spin Coherent Dynamics in Strained Germanium-Tin Semiconductor on Silicon
Germanium-Tin is emerging as a material exhibiting excellent photonic properties. Here we demonstrate optical initialization and readout of spins in this intriguing group IV semiconductor alloy and report on spin quantum beats between Zeeman-split levels under an external magnetic field. Our optical experiments reveal ...
1710.05792v1
2017-10-17
Unified mechanism of the surface Fermi level pinning in III-As nanowires
Fermi level pinning at the oxidized (110) surfaces of III-As nanowires (GaAs, InAs, InGaAs, AlGaAs) is studied. Using scanning gradient Kelvin probe microscopy, we show that the Fermi level at oxidized cleavage surfaces of ternary Al$_{x}$Ga$_{1-x}$As (0$\le$x$\le$0.45) and Ga$_{x}$In$_{1-x}$As (0$\le$x$\le$1) alloys i...
1710.06227v2
2017-10-24
Thermal management and non-reciprocal control of phonon flow via optomechanics
Engineering phonon transport in physical systems is a subject of interest in the study of materials and plays a crucial role in controlling energy and heat transfer. Of particular interest are non-reciprocal phononic systems, which in direct analogy to electric diodes, provide a directional flow of energy. Here, we pro...
1710.08967v2
2017-10-27
Nanolayered diffusion couple technique for the reconsidering of the miscibility gap
Mysteries in binary phase diagram are still in existence, e.g., the case in Cu-Ni which is mutual miscible system, the question addressed that "Indirect experimental evidence indicates the presence of a miscibility gap in the fcc phase at a temperature somewhere between 450 and 923 K". Recently, author's group suggests...
1710.10125v1
2017-10-31
Formation of Nb-rich droplets in laser deposited Ni-matrix microstructures
Ni-rich $\gamma$ cells and Nb-rich eutectic droplets that form during laser power bed fusion solidification of Ni-Nb alloys are studied using experiments and simulations. Finite element simulations estimate the cooling rates in the melt pool and phase-field simulations predict the resulting cellular microstructures. Th...
1710.11525v3
2018-03-31
Ultra-low-field magneto-elastocaloric cooling in a multiferroic composite device
The advent of caloric materials for magnetocaloric, elastocaloric, and electrocaloric cooling is changing the landscape of solid state cooling technologies with potentials for high-efficiency and environmentally-friendly residential and commercial cooling as well as heating applications. Given that caloric materials ar...
1804.00196v1
2018-04-10
Microwave cavity tuned with liquid metal and its application to Electron Paramagnetic Resonance
This note presents a method to tune the resonant frequency $f_{0}$ of a rectangular microwave cavity. This is achieved using a liquid metal, GaInSn, to decrease the volume of the cavity. It is possible to shift $f_{0}$ by filling the cavity with this alloy, in order to reduce the relative distance between the internal ...
1804.03443v1
2018-03-16
Reliability Analysis of Polymeric Materials
Polymeric materials are widely used in many applications and are especially useful when combined with other polymers to make polymer composites. The appealing features of these materials come from their having comparable levels of strength and endurance to what one would find in metal alloys while being more lightweigh...
1804.04586v1
2018-04-16
Interpretation of some Yb-based valence-fluctuating crystals as approximants to a dodecagonal quasicrystal
The hexagonal ZrNiAl-type (space group: P-62m) and the tetragonal Mo2FeB2-type (space group: P4/mbm) structures, which are frequently formed in the same Yb-based alloys and exhibit physical properties related to valence-fluctuation, can be regarded as approximants of a hypothetical dodecagonal quasicrystal. Using Pd-Sn...
1804.05505v1
2018-04-16
Short-time dynamics in $s+is$-wave superconductor with incipient bands
Motivated by the recent observation of the time-reversal symmetry broken state in K-doped BaFe$_2$As$_2$ superconducting alloys, we theoretically study the collective modes and the short time dynamics of the superconducting state with $s+is$-wave order parameter using an effective four-band model with two hole and two ...
1804.05662v1
2018-04-19
On the mechanical properties of novamene: a fully atomistic molecular dynamics and DFT investigation
We have investigated through fully atomistic reactive molecular dynamics and DFT simulations, the mechanical properties and fracture dynamics of novamene, a new 3D carbon allotrope structure recently proposed. Our results showed that novamene is an anisotropic structure with relation to tensile deformation. Although no...
1804.07215v1
2018-04-20
Polaronic transport and thermoelectricity in Fe$_{1-x}$Co$_x$Sb$_2$S$_4$ ($x$ = 0, 0.1, and 0.2)
We report a study of Co-doped berthierite Fe$_{1-x}$Co$_x$Sb$_2$S$_4$ ($x$ = 0, 0.1, and 0.2). The alloy series of Fe$_{1-x}$Co$_x$Sb$_2$S$_4$ crystallize in an orthorhombic structure with the Pnma space group, similar to FeSb$_2$, and show semiconducting behavior. The large discrepancy between activation energy for co...
1804.07776v1
2018-04-23
Phase Field Modeling of Galvanic Corrosion
A phase field (PF) based electrochemical model is presented for simulation of galvanic corrosion. Distributions of electrolyte potential and current density on anode and cathode surfaces are obtained by coupling the phase field variable with electrochemistry. Evolution of surface recession is naturally obtained by solv...
1804.08517v1
2018-04-25
Topological semimetals in the SnTe material class: Nodal lines and Weyl points
We theoretically show that IV-VI semiconducting compounds with low-temperature rhombohedral crystal structure represent a new potential platform for topological semimetals. By means of minimal $\mathbf{k}\cdot\mathbf{p}$ models we find that the two-step structural symmetry reduction of the high-temperature rocksalt cry...
1804.09574v3
2019-03-01
Strain control of the Neel vector in Mn-based antiferromagnets
Control of the Neel vector in antiferromagnetic materials is one of the challenges preventing their use as active device components. Several methods have been investigated such as exchange bias, electric current, and spin injection, but little is known about strain-mediated anisotropy. This study of the antiferromagnet...
1903.00413v1
2019-03-06
Coercivity enhancement of selective laser sintered NdFeB magnets by grain boundary infiltration
Laser powder bed fusion is a well-established additive manufacturing method that can be used for the production of net-shaped Nd-Fe-B sintered magnets. However, low coercivity has been one of the drawbacks in the laser powder bed fusion processed Nd-Fe-B magnets. In this work, we have demonstrated that the grain bounda...
1903.02233v1
2019-03-07
Fe-Sn nanocrystalline films for flexible magnetic sensors with high thermal stability
The interplay of magnetism and spin-orbit coupling on an Fe kagome lattice in Fe3Sn2 crystal produces a unique band structure leading to an order of magnitude larger anomalous Hall effect than in conventional ferromagnetic metals. In this work, we demonstrate that Fe-Sn nanocrystalline films also exhibit a large anomal...
1903.02689v1
2019-03-08
MFM and FORC+ study of switching mechanism in Co$_{25}$Pd$_{75}$ films
Recent research on CoPd alloys with perpendicular magnetic anisotropy (PMA) has suggested that they might be useful as the pinning layer in CoFeB/MgO-based perpendicular magnetic tunnel junctions (pMTJ's) for various spintronic applications such as spin-torque transfer random access memory (STT-RAM). We have previously...
1903.03568v2
2019-03-11
High Field Anomalies of Equilibrium and Ultrafast Magnetism in Rare-Earth-Transition Metal Ferrimagnets
Magneto-optical spectroscopy in fields up to 30 Tesla reveals anomalies in the equilibrium and ultrafast magnetic properties of the ferrimagnetic rare-earth-transition metal alloy TbFeCo. In particular, in the vicinity of the magnetization compensation temperature, each of the magnetizations of the antiferromagneticall...
1903.04293v1
2019-03-14
Maximum Supercooling Studies in Ti39.5Zr39.5Ni21 and Zr80Pt20 - Connecting Liquid Structure and the Nucleation Barrier
Almost three quarters of a century ago, Charles Frank proposed that the deep supercooling observed in metallic liquids is due to icosahedral short-range order (ISRO), which is incompatible with the long-range order of crystal phases. Some evidence in support of this hypothesis has been published previously. However, th...
1903.06072v1
2019-03-22
Al$_{5+α}$Si$_{5+δ}$N$_{12}$, a new Nitride compound
We report on the synthesis of new nitride-based compound by using annealing of AlN heteroepitaxial layers under a Si-atmosphere at temperatures between 1350$^\circ$C and 1550$^\circ$C. The structure and stoichiometry of this compound are investigated by high-resolution scanning transmission electron microscopy (HRSTEM)...
1903.09400v1
2019-03-26
Axial GaAs/Ga(As,Bi) Nanowire Heterostructures
Bi-containing III-V semiconductors constitute an exciting class of metastable compounds with wide-ranging potential optoelectronic and electronic applications. However, the growth of III-V-Bi alloys requires group-III-rich growth conditions, which pose severe challenges for planar growth. In this work, we exploit the n...
1903.11039v2
2019-03-27
Traveling Waves Induced by Sweeping Flows on Solidification Interfaces
Solidification of alloys in a thermal gradient usually involves the generation of flows by thermal or thermosolutal convection. We experimentally study their effects on the dynamics of a solidification interface by inducing a controlled sweeping flow in a directional solidification device. Flow is induced in the sample...
1903.11333v1
2019-03-27
The effect of the electric field on the nucleation of the nanometer periodic structure of adatoms in GaAs semiconductor under the action of laser irradiation
In the paper, the effect of the electric field on the conditions of formation and on the period of the surface superlattice of adatoms in $n$-GaAs semiconductor is investigated. It is established that in GaAs semiconductor, an increase in the electric field strength, depending on the direction, leads to an increase or ...
1903.11601v1
2019-05-02
Anomalous spin Hall angle of a metallic ferromagnet determined by a multiterminal spin injection/detection device
We report on the determination of the anomalous spin Hall angle in the ferromagnetic metal alloy cobalt-iron (Co$_{25}$Fe$_{75}$, CoFe). This is accomplished by measuring the spin injection/detection efficiency in a multiterminal device with nanowires of platinum (Pt) and CoFe deposited onto the magnetic insulator yttr...
1905.00663v1
2019-05-02
Aging and rejuvenation during elastostatic loading of amorphous alloys
Using molecular dynamics simulations, we investigate the effect of uniaxial elastostatic compression on the potential energy, structural relaxation, and mechanical properties of binary glasses. We consider the three-dimensional Kob-Andersen binary mixture, which was initially cooled from the liquid state to the glass p...
1905.00761v1
2019-05-03
Phase transitions in titanium with an analytic bond-order potential
Titanium is the base material for a number of technologically important alloys for energy conversion and structural applications. Atomic-scale studies of Ti-based metals employing first-principles methods, such as density functional theory, are limited to ensembles of a few hundred atoms. To perform large-scale and/or ...
1905.01197v1
2019-05-04
Tuning the Hysteresis of a Metal-Insulator Transition via Lattice Compatibility
Structural phase transitions serve as the basis for many functional applications including shape memory alloys (SMAs), switches based on metal-insulator transitions (MITs), etc. In such materials, lattice incompatibility between phases often results in a thermal hysteresis, which is intimately tied to degradation of re...
1905.01398v1
2019-05-09
Driving upside-down in a circular track
In this article, we point out an interesting solution for the dynamics of a racecar in a banked circular track with banking angle well over 90o. We call this track configuration an Inverted Track, at which a racecar can drive partially upside-down. We show an experimental setup where we made a toy car to circulate upsi...
1905.03825v1
2019-05-10
Solute drag and dynamic phase transformations in moving grain boundaries
A discrete model and the regular solution approximation are applied to describe the effect of grain boundary motion on grain boundary phase transformations in a binary alloy. The model predicts all thermodynamic properties of the grain boundary and the solute drag force, and permits a broad exploration of the parameter...
1905.04126v1
2019-05-10
Exploration of Gibbs-Laguerre tessellations for three-dimensional stochastic modeling
Random tessellations are well suited for probabilistic modeling of three-dimensional (3D) grain microstructures of polycrystalline materials. The present paper is focused on so-called Gibbs-Laguerre tessellations, in which the generators of the Laguerre tessellation form a Gibbs point process. The goal is to construct ...
1905.04252v2
2019-05-14
Tuning topology in thin films of topological insulators by strain gradients
We theoretically show that the coupling of inhomogeneous strains to the Dirac fermions of three-dimensional topological insulators (3DTI) in thin film geometries results in the occurrence of phase transitions between topologically distinct insulating phases. By means of minimal k dot p models for strong 3DTI in the Bi ...
1905.06189v1
2019-05-17
Diffusion in binary mixtures: an analysis of the dependence on the thermodynamic factor
We study the diffusion process in binary mixtures using transition probabilities that depend on a mean-field potential. This approach reproduces the Darken equation, a relationship between the intrinsic and the tracer diffusion coefficients, $D_A$ and $D_A^*$, through the thermodynamic factor $\Phi$ (a function of the ...
1905.07249v1
2019-05-17
Superconductivity in the $η$-carbide-type oxides Zr4Rh2Ox
We report on the synthesis and the superconductivity of Zr$_4$Rh$_2$O$_{x}$ ($x$ = 0.4, 0.5, 0.6, 0.7, 1.0). These compounds crystallize in the $\eta$-carbide structure, which is a filled version of the complex intermetallic Ti$_2$Ni structure. We find that in the system Zr$_4$Rh$_2$O$_{x}$, already a small amount ($x$...
1905.07402v1
2019-05-23
Near-infrared optical properties and proposed phase-change usefulness of transition metal disulfides
The development of photonic integrated circuits would benefit from a wider selection of materials that can strongly-control near-infrared (NIR) light. Transition metal dichalcogenides (TMDs) have been explored extensively for visible spectrum opto-electronics, but the NIR properties of these layered materials have been...
1905.09740v1
2019-05-27
Nanoscale spatially resolved mapping of uranium enrichment in actinide-bearing materials
Spatially resolved analysis of uranium isotopes in small volumes of actinide-bearing materials is critical for a variety of technical disciplines, including earth and planetary sciences, environmental monitoring, bioremediation, and the nuclear fuel cycle. However, achieving sub-nanometer scale spatial resolution for s...
1905.10932v1
2019-05-27
Microstructural Inelastic Fingerprints And Data-Rich Predictions of Plasticity and Damage in Solids
Inelastic mechanical responses in solids, such as plasticity, damage and crack initiation, are typically modeled in constitutive ways that display microstructural and loading dependence. Nevertheless, {linear} elasticity at infinitesimal deformations is used for microstructural properties. We demonstrate a framework th...
1905.11289v3
2019-05-29
Convex Integration Solutions for the Geometrically Non-linear Two-Well Problem with Higher Sobolev Regularity
In this article we discuss higher Sobolev regularity of convex integration solutions for the geometrically non-linear two-well problem. More precisely, we construct solutions to the differential inclusion $\nabla u\in K$ subject to suitable affine boundary conditions for $ u$ with $$ K:= SO(2)\left[\begin{array}{ ccc }...
1905.12521v1
2019-05-29
Strain engineering in Ge/GeSn core/shell nanowires
Strain engineering in Sn-rich group IV semiconductors is a key enabling factor to exploit the direct band gap at mid-infrared wavelengths. Here, we investigate the effect of strain on the growth of GeSn alloys in a Ge/GeSn core/shell nanowire geometry. Incorporation of Sn content in the 10-20 at.% range is achieved wit...
1905.12671v1
2019-05-31
Investigation of the electroplastic effect using nanoindentation
A promising approach to deform metallic-intermetallic composite materials is the application of electric current pulses during the deformation process to achieve a lower yield strength and enhanced elongation to fracture. This is known as the electroplastic effect. We developed a novel setup to study the electroplastic...
1905.13518v1
2019-08-03
A Critical Review on the Electromigration Effect, the Electroplastic Effect, and Perspectives on the Effects of Electric Current Upon Alloy Phase Stability
The electronic interconnections in the state-of-the-art integrated circuit manufacturing have been scaled down to the micron or sub-micron scale. This results in a dramatic increase in the current density passing through interconnections, which means that the electromigration (EM) effect plays a significant role in the...
1908.01170v1
2019-08-16
Non-Trivial Topological Phase in the Sn_{1-x}In_xTe Superconductor
Whereas SnTe is a inverted band gap topological crystalline insulator, the topological phase of the alloy Sn_{1-x}In_xTe, a topological superconductor candidate, has not been clearly studied so far. Our calculations show that the Sn_{1-x}In_xTe band gap reduces by increasing the In content, becoming a metal for x>0.1. ...
1908.05967v1
2019-08-25
New 3D and 2D Octacarbon C8 and isoelectronic B4N4 having peculiar mechanic and magnetic properties. First-principles identifications
Cohesive energies, energy-volume equations of states EOS, electron localization ELF maps, elastic constants, and band structures are reported for original octacarbon C8 three dimensional 3D and two-dimensional 2D chemical systems based on density functional theory calculations. Specifically, tetragonal C8 is identified...
1908.09265v1
2019-08-26
New thermodynamic constraints on internal, thermal and magnetic states of terrestrial-like Super-Earths
Ascertaining rocky exoplanets dynamic evolution requires better understanding of key internal thermophysical processes that shaped their geological surfaces, heat fluxes, volatiles and atmospheric content. New high-pressure experiments on iron and silicates compressible, melting and transport properties are providing n...
1908.09871v1
2019-08-30
Efficient Pourbaix diagrams of many-element compounds
Pourbaix diagrams have long been an essential tool for determining the phase stability of solids and their associated ionic species under electrochemical conditions. In recent years, Pourbaix diagrams have been used for applications ranging from corrosion-resistance alloy design to electrocatalysis, and the data from w...
1909.00035v1
2019-09-03
Defects in Cd3As2 Epilayers Via Molecular Beam Epitaxy and Strategies for Reducing Them
Molecular beam epitaxy offers an exciting avenue for investigating the behavior of topological semimetal Cd3As2, by providing routes for doping, alloying, strain engineering, and heterostructure formation. To date, however, minimal exploration has been devoted to the impact of defects that are incorporated into epilaye...
1909.01450v1
2019-09-05
Spin-orbit related power-law dependence of the diffusive conductivity on the carrier density in disordered Rashba two-dimensional electron systems
By using the momentum-space Lanczos recursive method which considers rigorously all multiple-scattering events, we unveil that the non-perturbative disorder effect has dramatic impact on the charge transport of a two-dimensional electron system with Rashba spin-orbit coupling in the low-density region. Our simulations ...
1909.02186v3
2019-08-21
Computational Screening of Current Collectors for Enabling Anode-free Lithium Metal Batteries
Lithium metal cells are key towards achieving high specific energy and energy density for electrification of transportation and aviation. Anode-free cells are the limiting case of lithium metal cells involving no excess lithium and the highest possible specific energy. In addition, anode-free cells are easier, cheaper ...
1909.02404v1
2019-09-05
Effect of Oxygen on Hydrogen Diffusivity in hcp-Zirconium
Zirconium and its alloys are extensively used as cladding material in nuclear reactors. They are vulnerable to hydrogen degradation under the harsh service conditions of the reactors, which necessitates continuous monitoring for the hydride concentration. The presence of hydride denuded zones in the latter stages of th...
1909.02486v1
2019-09-09
Weak anti-localization in spin-orbit coupled lattice systems
The quantum correction to electrical conductivity is studied on the basis of two-dimensional Wolff Hamiltonian, which is an effective model for a spin-orbit coupled (SOC) lattice system. It is shown that weak anti-localization (WAL) arises in SOC lattices, although its mechanism and properties are different from the co...
1909.03757v1
2019-09-11
MOVPE-grown Si-doped \b{eta}-(Al0.26Ga0.74)2O3 thin films and heterostructures
We report on n-type degenerate doping in MOVPE grown \b{eta}-(Al0.26Ga0.74)2O3 epitaxial thin films and modulation doping in \b{eta}-(Al0.26Ga0.74)2O3/\b{eta}-Ga2O3 heterostructure. Alloy composition is confirmed using HRXRD measurements. Carrier concentration in the thin films is proportional to the silane molar flow....
1909.04855v1
2019-09-13
Transport properties of doped permalloy via ab-initio calculations: effect of the host disorder
Transport properties of permalloy doped with V, Co, Pt, and Au are explored via ab-initio calculations. The Kubo-Bastin formula is evaluated within the fully relativistic Korringa-Kohn-Rostoker Green function formalism. Finite temperature effects are treated by means of the alloy analogy model. It is shown that the fac...
1909.06066v3
2019-09-14
Data-driven approach for synchrotron X-ray Laue microdiffraction scan analysis
We propose a novel data-driven approach for analyzing synchrotron Laue X-ray microdiffraction scans based on machine learning algorithms. The basic architecture and major components of the method are formulated mathematically. We demonstrate it through typical examples including polycrystalline BaTiO$_3$, multiphase tr...
1909.06572v1
2019-09-14
Derived Crystal Structure of Martensitic Materials by Solid-Solid Phase Transformation
We propose a mathematical description of crystal structure: underlying translational periodicity together with the distinct atomic positions up to the symmetry operations in the unit cell. It is consistent with the international table of crystallography. By the Cauchy-Born hypothesis, such a description can be integrat...
1909.06574v1
2019-09-21
Basal dislocation/precipitate interactions in Mg-Al alloys: an atomistic investigation
The interaction between edge basal dislocations and $\beta$-Mg$_{17}$Al$_{12}$ precipitates was studied using atomistic simulations. A strategy was developed to insert a lozenge-shaped Mg$_{17}$Al$_{12}$ precipitate with Burgers orientation relationship within the Mg matrix in an atomistic model ensuring that the matri...
1909.09760v1
2019-09-24
Review on Generalized Dynamics of Soft-Matter Quasicrystals and Its Applications
This article provides a detailed review on the generalized dynamics of soft-matter quasicrystals developed recent years. Comparing to solid quasicrystals consisted mainly with metallic alloys, soft-matter quasicrystals have been observed in liquid crystals, polymers, colloids, nanoparticles, and surfactants, which indi...
1909.10676v2
2019-09-24
An analytical relation between Weibull's and Basquin's laws for smooth and notched specimens and application to constant amplitude fatigue
Starting from the classical definition of stress-life Wohler curve in the form of Basquin's law, an analytical procedure for the calibration of the four parameters Wohler curve (Weibull's law) for a plain specimen is proposed. The obtained parameters are then adjusted by means of an additional slope factor preserving t...
1909.10741v1
2019-09-25
Magneto-optic and transverse transport properties of non-collinear antiferromagnets
Previous studies on the anomalous Hall effect in coplanar non-collinear antiferromagnets are revisited and extended to magneto-optic properties, namely magneto-optic Kerr effect (MOKE) and X-ray magnetic dichroism (XMCD). Starting from group-theoretical considerations the shape of the frequency-dependent conductivity t...
1909.11375v1
2019-11-30
Structural relaxation in amorphous materials under cyclic tension-compression loading
The process of structural relaxation in disordered solids subjected to repeated tension-compression loading is studied using molecular dynamics simulations. The binary glass is prepared by rapid cooling well below the glass transition temperature and then periodically strained at constant volume. We find that the amorp...
1912.00221v1
2019-12-10
Oxygen Incorporation in the MBE growth of ScxGa1-xN and ScxAl1-xN
Secondary-ion Mass Spectrometry (SIMS) is used to determine impurity concentrations of carbon and oxygen in two scandium containing nitride semiconductor multilayer heterostructures: ScxGa1-xN/GaN and ScxAl1-xN/AlN grown by molecular beam epitaxy (MBE). In the ScxGa1-xN/GaN heterostructure grown in metal rich condition...
1912.04495v1
2019-12-17
Decorated dislocations against phonon propagation for thermal management
The impact of decorated dislocations on the effective thermal conductivity of GaN is investigated by means of equilibrium molecular dynamics simulations via the Green-Kubo approach. The formation of "nanowires" by a few atoms of In in the core of dislocations in wurtzite GaN is found to affect the thermal properties of...
1912.07923v1
2019-12-27
Ultra-sensitive hybrid diamond nanothermometer
Nitrogen-vacancy (NV) centers in diamond are promising quantum sensors for their long spin coherence time under ambient conditions. However, their spin resonances are relatively insensitive to non-magnetic parameters such as temperature. A magnetic-nanoparticle-nanodiamond hybrid thermometer, where the temperature chan...
1912.12097v1
2020-02-11
The role of delocalized chemical bonding in square-net-based topological semimetals
Principles that predict reactions or properties of materials define the discipline of chemistry. In this work we derive chemical rules, based on atomic distances and chemical bond character, which predict topological materials in compounds that feature the structural motif of a square-net. Using these rules we identify...
2002.04611v1
2020-02-13
Stabilized Interfacial Ferromagnetism and Enhanced Magnetoelectric Properties of Ultrathin FeRh Films Capped with Heavy Transition Metal Ta
Thin FeRh film was extensively studied recently, and an emergent substrate- and capping-dependent interfacial ferromagnetism (FM) was widely observed in experiments. However, the voltage modulation of this interfacial ferromagnetism is barely studied, which would have profound applications in antiferromagnetic (AFM) Fe...
2002.05621v1
2020-02-14
Effects of intrinsic defects and alloying with Fe on the half-metallicity of Co$_2$MnSi
The electronic structure and half-metallic gap of Co$_{2}$MnSi in the presence of crystallographic defects, partial Fe substitution for Mn, and thermal spin fluctuations are studied using the coherent potential approximation and the disordered local moment method. In the presence of 5\% Co or Mn vacancies the Fermi lev...
2002.06173v1
2020-02-25
Symmetry protection and giant Fermi arcs from multifold fermions in binary, ternary, and quaternary compounds
Higher-fold chiral fermions that go beyond two-fold Weyl fermions have recently been reported in crystalline systems. Here, we focus on such excitations in several binary, ternary and quaternary alloys/compounds with CoGe, BiSbPt and KMgBO3 as the representative examples that belong to the crystal space group (SG) 198....
2002.11145v2
2020-02-25
Low-temperature formation of platinum silicides on polycrystalline silicon
Phase formation and transitions in platinum silicide films on polycrystalline Si in the process of Pt magnetron sputtering and heat treatments at different temperatures are studied using X-ray photoelectron spectroscopy, high-resolution transmission electron microscopy and X-ray diffractometry. Phases of amorphous and ...
2002.11189v2
2020-02-26
Effect of He on the Order-Disorder Transition in Ni3Al under Irradiation
The order-disorder transition in Ni-Al alloys under irradiation represents an interplay between various re-ordering processes and disordering due to thermal spikes generated by incident high energy particles. Typically, ordering in enabled by diffusion of thermally-generated vacancies, and can only take place at temper...
2002.11659v1
2020-03-02
Low field transport calculations in 2-dimensional electron gas in $\mathrm{β\mbox{-}(Al_{x}Ga_{1-x})_{2}O_{3}/Ga_{2}O_{3}}$ heterostructures
$\mathrm{\beta}$-Gallium oxide ($\mathrm{\beta\mbox{-}Ga_{2}O_{3}}$) is an emerging widebandgap semiconductor for potential application in power and RF electronics applications. Initial theoretical calculation on a 2-dimensional electron gas (2DEG) in $\mathrm{\beta\mbox{-}(Al_{x}Ga_{1-x})_{2}O_{3}/Ga_{2}O_{3}}$ hetero...
2003.00959v1
2020-03-05
On the shear-affected zone of shear bands in bulk metallic glasses
Notched bars of bulk metallic glasses, Pd$_{40}$Ni$_{40}$P$_{20}$ and Zr$_{52.5}$Cu$_{17.9}$Ni$_{14.6}$Al$_{10}$Ti$_{5}$, were deformed under 3-point bending conditions, resulting in the formation of shear bands before failure. The immediate environment of shear bands was investigated in detail using fluctuation electr...
2003.02565v1
2020-03-11
Three-dimensional needle network model for dendritic growth with fluid flow
We present a first implementation of the Dendritic Needle Network (DNN) model for dendritic crystal growth in three dimensions including convective transport in the melt. The numerical solving of the Navier-Stokes equations is performed with finite differences and is validated by comparison with a classical benchmark i...
2003.05248v2
2020-03-11
Comparing mesoscopic models for dendritic growth
We present a quantitative benchmark of multiscale models for dendritic growth simulations. We focus on approaches based on phase-field, dendritic needle network, and grain envelope dynamics. As a first step, we focus on isothermal growth of an equiaxed grain in a supersaturated liquid in three dimensions. A quantitativ...
2003.05250v2