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2010-01-19
High-Resolution Spectroscopy of Extremely Metal-Poor Stars in the Least Evolved Galaxies: Leo IV
We present high-resolution Magellan/MIKE spectroscopy of the brightest star in the ultra-faint dwarf galaxy Leo IV. We measure an iron abundance of [Fe/H] = -3.2, adding to the rapidly growing sample of extremely metal-poor stars being identified in Milky Way satellite galaxies. The star is enhanced in the alpha elements Mg, Ca, and Ti by ~0.3 dex, very similar to the typical Milky Way halo abundance pattern. All of the light and iron-peak elements follow the trends established by extremely metal-poor halo stars, but the neutron-capture elements Ba and Sr are significantly underabundant. These results are quite similar to those found for stars in the ultra-faint dwarfs Ursa Major II, Coma Berenices, Bootes I, and Hercules, suggesting that the chemical evolution of the lowest luminosity galaxies may be universal. The abundance pattern we observe is consistent with predictions for nucleosynthesis from a Population III supernova explosion. The extremely low metallicity of this star also supports the idea that a significant fraction (>10%) of the stars in the faintest dwarfs have metallicities below [Fe/H] = -3.0.
1001.3137v2
2010-02-16
Electron-doping evolution of the low-energy spin excitations in the iron arsenide BaFe$_{2-x}$Ni$_{x}$As$_{2}$ superconductors
We use elastic and inelastic neutron scattering to systematically investigate the evolution of the low-energy spin excitations of the iron arsenide superconductor BaFe2-xNixAs2 as a function of nickel doping x. In the undoped state, BaFe2As2 exhibits a tetragonal-to-orthorhombic structural phase transition and simultaneously develops a collinear antiferromagnetic (AF) order below TN = 143 K. Upon electron-doping of x = 0.075 to induce bulk superconductivity with Tc = 12.3 K, the AF ordering temperature reduces to TN = 58 K.We show that the appearance of bulk superconductivity in BaFe1.925Ni0.075As2 coincides with a dispersive neutron spin resonance in the spin excitation spectra, and a reduction in the static ordered moment. For optimally doped BaFe1.9Ni0.1As2 (Tc = 20 K) and overdoped BaFe1.85Ni0.15As2 (Tc = 15 K) superconductors, the static AF long-range order is completely suppressed and the spin excitation spectra are dominated by a resonance and spin-gap at lower energies. We determine the electron-doping dependence of the neutron spin resonance and spin gap energies, and demonstrate that the three-dimensional nature of the resonance survives into the overdoped regime. If spin excitations are important for superconductivity, these results would suggest that the three-dimensional character of the electronic superconducting gaps are prevalent throughout the phase diagram, and may be critical for superconductivity in these materials.
1002.3133v2
2010-04-07
Iron oxide doped boron nitride nanotubes: structural and magnetic properties
A first-principles formalism is employed to investigate the interaction of iron oxide (FeO) with a boron nitride (BN) nanotube. The stable structure of the FeO-nanotube has Fe atoms binding N atoms, with bond length of roughly $\sim$2.1 \AA, and binding between O and B atoms, with bond length of 1.55 \AA. In case of small FeO concentrations, the total magnetic moment is (4$\mu_{Bohr}$) times the number of Fe atoms in the unit cell and it is energetically favorable to FeO units to aggregate rather than randomly bind to the tube. As a larger FeO concentration case, we study a BN nanotube fully covered by a single layer of FeO. We found that such a structure has square FeO lattice with Fe-O bond length of 2.11 \AA, similar to that of FeO bulk, and total magnetic moment of 3.94$\mu_{Bohr}$ per Fe atom. Consistently with experimental results, the FeO covered nanotube is a semi-half-metal which can become a half-metal if a small change in the Fermi level is induced. Such a structure may be important in the spintronics context.
1004.1151v2
2010-04-20
Terzan 5: an alternative interpretation for the split horizontal branch
We consider the horizontal branch (HB) of the Globular Cluster Terzan 5, recently shown to be split into two parts, the fainter one (delta M_K ~ 0.3mag) having a lower metallicity than the more luminous. Both features show that it contains at least two stellar populations. The separation in magnitude has been ascribed to an age difference of ~6 Gyr and interpreted as the result of an atypical evolutionary history for this cluster. We show that the observed HB morphology is also consistent with a model in which the bright HB is composed of second generation stars that are metal enriched and with a helium mass fraction larger (by delta Y ~ 0.07) than that of first generation stars populating the fainter part of the HB. Terzan 5 would therefore be anomalous, compared to most "normal" clusters hosting multiple populations, only because its second generation is strongly contaminated by supernova ejecta; the previously proposed prolonged period of star formation, however, is not required. The iron enrichment of the bright HB can be ascribed either to contamination from Type Ia supernova ejecta of the low-iron, helium rich, ejecta of the massive asympotic giant branch stars of the cluster, or to its mixing with gas, accreting on the cluster from the environment, that has been subject to fast metal enrichment due to its proximity with the galactic bulge. The model here proposed requires only a small age difference, of ~100Myr.
1004.3426v1
2010-04-26
A strong and broad iron line in the XMM-Newton spectrum of the new X-ray transient and black-hole candidate XTE J1652-453
We observed the new X-ray transient and black-hole candidate XTE J1652-453 simultaneously with XMM-Newton and the Rossi X-ray Timing Explorer (RXTE). The observation was done during the decay of the 2009 outburst, when XTE J1652-453 was in the hard-intermediate state. The spectrum shows a strong and broad iron emission line with an equivalent width of ~ 450 eV. The profile is consistent with that of a line being produced by reflection off the accretion disk, broadened by relativistic effects close to the black hole. The best-fitting inner radius of the accretion disk is ~ 4 gravitational radii. Assuming that the accretion disk is truncated at the radius of the innermost stable circular orbit, the black hole in XTE J1652-453 has a spin parameter of ~ 0.5. The power spectrum of the RXTE observation has an additional variability component above 50 Hz, which is typical for the hard-intermediate state. No coherent quasi-periodic oscillations at low frequency are apparent in the power spectrum, which may imply that we view the system at a rather low inclination angle.
1004.4442v2
2010-04-28
Are C-rich ultra iron poor stars also He-rich?
(abridged) The three most iron poor stars presently known ([Fe/H] equal to -5.96, -5.4 and -4.75) are carbon-rich, they are called C-Rich Ultra-Metal Poor Stars (CRUMPS). The origin of their peculiar surface abundances is not understood. We propose a synthetic view of the different models so far proposed to explain the peculiar abundances observed at the surface of the CRUMP stars. We deduce some expected trends based on nucleosynthetic arguments and look for signatures allowing to discriminate among models. We discuss the conditions for having CRUMP stars which are He-rich, i.e. with a mass fraction of helium greater than 0.30 and up to 0.60. We discuss the chemical composition of stars made of interstellar medium mixed with wind material of very metal poor massive stars, with wind plus supernova ejecta and with material extracted from the envelope of early AGB stars. Rotating and non-rotating models are considered. CRUMP stars formed from wind material of massive stars mixed with small amounts of pristine interstellar medium are He-rich (helium mass fraction between 0.30 and 0.60), Li-depleted and present low $^{12}$C/$^{13}$C ratios (inferior to 10 in number). Such He-rich stars, if discovered, would confirm that the most metal poor CRUMPs formed from essentially pure wind/envelope material. They would provide the most direct way to probe the nucleosynthetic outputs of the first generations of stars. We show that rotation is a key ingredient to explain the abundance patterns of CRUMPS stars.
1004.5024v1
2010-05-08
Non-Resonant X-ray Magnetic Scattering on Rare-Earth Iron Borates RFe$_3$(BO$_3$)$_4$
Hard x-ray scattering (HXS) experiments with a photon energy of 100keV were performed as a function of temperature and applied magnetic field on selected compounds of the RFe$_3$(BO$_3$)$_4$ family. The results show the presence of several unexpected diffraction features, in particular non-resonant magnetic reflections in the magnetically ordered phase, and structural reflections that violate the diffraction conditions for the low temperature phase $P3_121$ of the rare-earth iron borates. The temperature and field dependence of the magnetic superlattice reflections corroborate the magnetic structures of the borate compounds obtained by neutron diffraction. The detailed analysis of the intensity and scattering cross section of the magnetic reflection reveals details of the magnetic structure of these materials such as the spin domain structure of NdFe$_3$(BO$_3$)$_4$ and GdFe$_3$(BO$_3$)$_4$. Furthermore we find that the correlation length of the magnetic domains is around 100 \AA{} for all the compounds and that the Fe moments are rotated $53^\circ\pm3^\circ$ off from the hexagonal basal plane in GdFe$_3$(BO$_3$)$_4$
1005.1333v2
2010-05-13
Vacancy ordering and electronic structure of gamma-Fe2O3 (maghemite): a theoretical investigation
The crystal structure of the iron oxide gamma-Fe2O3 is usually reported in either the cubic system (space group P4332) with partial Fe vacancy disorder or in the tetragonal system (space group P41212) with full site ordering and c/a\approx 3. Using a supercell of the cubic structure, we obtain the spectrum of energies of all the ordered configurations which contribute to the partially disordered P4332 cubic structure. Our results show that the configuration with space group P41212 is indeed much more stable than the others, and that this stability arises from a favourable electrostatic contribution, as this configuration exhibits the maximum possible homogeneity in the distribution of iron cations and vacancies. Maghemite is therefore expected to be fully ordered in equilibrium, and deviations from this behaviour should be associated with metastable growth, extended anti-site defects and surface effects in the case of small nanoparticles. The confirmation of the ordered tetragonal structure allows us to investigate the electronic structure of the material using density functional theory (DFT) calculations. The inclusion of a Hubbard (DFT+U) correction allows the calculation of a band gap in good agreement with experiment. The value of the gap is dependent on the electron spin, which is the basis for the spin-filtering properties of maghemite.
1005.2370v1
2010-05-13
Competing order and nature of the pairing state in the iron pnictides
We show that the competition between magnetism and superconductivity can be used to determine the pairing state in the iron arsenides. To this end we demonstrate that the itinerant antiferromagnetic phase (AFM) and the unconventional $s^{+-}$ sign-changing superconducting state (SC) are near the borderline of microscopic coexistence and macroscopic phase separation, explaining the experimentally observed competition of both ordered states. In contrast, conventional $s^{++}$ pairing is not able to coexist with magnetism. Expanding the microscopic free energy of the system with competing orders around the multicritical point, we find that static magnetism plays the role of an intrinsic interband Josephson coupling, making the phase diagram sensitive to the symmetry of the Cooper pair wavefunction. We relate this result to the quasiparticle excitation spectrum and to the emergent SO$(5)$ symmetry of systems with particle-hole symmetry. Our results rely on the assumption that the same electrons that form the ordered moment contribute to the superconducting condensate and that the system is close to particle-hole symmetry. We also compare the suppression of SC in different regions of the FeAs phase diagram, showing that while in the underdoped side it is due to the competition with AFM, in the overdoped side it is related to the disappearance of pockets from the Fermi surface.
1005.2437v3
2010-05-18
Spectral variability of the peculiar A-type supergiant 3Pup
Optical spectra of the peculiar supergiant 3Pup taken in 1997-2008 are used to analyze the spectral peculiarities and velocity field in its atmosphere. The profiles of strong FeII lines and of the lines of other iron-group ions have a specific shape: the wings are raised by emissions, whereas the core is sharpened by a depression. The latter feature becomes more pronounced with the increasing line strength, and the increasing wavelength. Line profiles are variable: the magnitude and sign of the absorption asymmetry, and the blue-to-red emission intensity ratios vary from one spectrum to another. The temporal Vr variations are minimal for the forbidden emissions and sharp shell cores of the absorption features of FeII(42), and other strong lines of iron-group ions. The average velocity for the above lines can be adopted as the systemic velocity: Vsys=28.5+/-0.5km/s. The weakest photospheric absorptions and photospheric MgII, SiII absorptions exhibit well-defined day-to-day velocity variations of up to 7km/s. Quantitative spectral classification yields the spectral type of A2.7+/-0.3 Ib. The equivalent widths and profiles of Hdelta and Hgamma, and the equivalent width of the OI7774A triplet yield an absolute magnitude estimate of Mv=-5.5+/-0.3mag, implying the heliocentric distance of 0.7kpc.
1005.3098v1
2010-05-18
A New Limit on the Distances of Nuclei UHECRs Sources
Recent evidence from the Pierre Auger Observatory suggests a transition, at 5 EeV-10EeV in the composition of Ultra High Energy Cosmic Rays (UHECRs), from protons to heavier nuclei such as iron. I consider here the implications of the heavier composition on the sources of UHECRs. The smaller magnetic rigidity implies that nuclei UHECRs are: (i) More easily accelerated (ii) Local, as they can diffuse only a few Mpc from their sources before disintegrating (iii) Isotropic, because large deflections in the extra galactic and the galactic magnetic fields erase the directional information. Uncertainties in the strength and structure of the the extra galactic magnetic field (EGMF) makes it difficult to estimate the overall effects. However, with typical reasonable parameters of a few nG and a coherence distance of a Mpc the distance a nuclei UHECR above the GZK energy traverses before photodisintegrating is only a few Mpc. In spite of the significantly weaker limits on the luminosity, Cen A is the only currently active potential source of nuclei UHECRs within this distance. The large deflections erases the directional anisotropy expected from a single source. If indeed the composition of above-GZK-UHECRs is iron and if the EGMF is not too small then Cen A is the dominant source of observed nuclei UHECRs above the GZK limit.
1005.3311v1
2010-05-19
Thermodynamic Limits on Magnetodynamos in Rocky Exoplanets
To ascertain whether magnetic dynamos operate in rocky exoplanets more massive or hotter than the Earth, we developed a parametric model of a differentiated rocky planet and its thermal evolution. Our model reproduces the established properties of Earth's interior and magnetic field at the present time. When applied to Venus, assuming that planet lacks plate tectonics and has a dehydrated mantle with an elevated viscosity, the model shows that the dynamo shuts down or never operated. Our model predicts that at a fixed planet mass, dynamo history is sensitive to core size, but not to the initial inventory of long-lived, heat-producing radionuclides. It predicts that rocky planets larger than 2.5 Earth masses will not develop inner cores because the temperature-pressure slope of the iron solidus becomes flatter than that of the core adiabat. Instead, iron "snow" will condense near or at the top of these cores, and the net transfer of latent heat upwards will suppress convection and a dynamo. More massive planets can have anemic dynamos due to core cooling, but only if they have mobile lids (plate tectonics). The lifetime of these dynamos is shorter with increasing planet mass but longer with higher surface temperature. Massive Venus-like planets with stagnant lids and more viscous mantles will lack dynamos altogether. We identify two alternative sources of magnetic fields on rocky planets: eddy currents induced in the hot or molten upper layers of planets on very short period orbits, and dynamos in the ionic conducting layers of "ocean" planets with ~10% mass in an upper mantle of water (ice).
1005.3523v1
2010-05-21
Observation of Lattice and Andreev Bound States of Vortices in Ba0.6K0.4Fe2As2 Single Crystals with Scanning Tunneling Microscopy/Spectroscopy
For a type-II superconductor, when the applied magnetic field is higher than the lower critical value Hc1, the magnetic flux will penetrate into the superconductor and form quantized vortices, which usually are arranged in an Abrikosov lattice. For the newly discovered iron pnictide superconductors, previous measurements have shown that, in electron-doped BaFe2As2, the vortices form a highly disordered structure. In addition, the density of states (DOS) within the vortex cores1 do not exhibit the Andreev bound states in conventional superconductors. In this Letter, we report the observation of a triangular vortex lattice and the Andreev bound states in hole-doped BaFe2As2 by using a low temperature scanning tunneling microscope (STM). Detailed study of the vortex cores reveals that the spectrum of the Andreev bound states inside the vortex core exhibits a distinct spatial evolution: at the center of the vortex core, it appears as a single peak at 0.5 mV below the Fermi-energy; away from the core center, it gradually evolves into two sub-peaks and they eventually fade out. The drastic differences between the vortex cores of the electron-doped and hole-doped counterparts are illusive to the pairing mechanism of the iron pnictide superconductors.
1005.4038v1
2010-05-25
The pairing state in KFe2As2 studied by measurements of the magnetic vortex lattice
Understanding the mechanism and symmetry of electron pairing in iron-based superconductors represents an important challenge in condensed matter physics [1-3]. The observation of magnetic flux lines - "vortices" - in a superconductor can contribute to this issue, because the spatial variation of magnetic field reflects the pairing. Unlike many other iron pnictides, our KFe2As2 crystals have very weak vortex pinning, allowing small-angle-neutron-scattering (SANS) observations of the intrinsic vortex lattice (VL). We observe nearly isotropic hexagonal packing of vortices, without VL-symmetry transitions up to high fields along the fourfold c-axis of the crystals, indicating rather small anisotropy of the superconducting properties around this axis. This rules out gap nodes parallel to the c-axis, and thus d-wave and also anisotropic s-wave pairing [2, 3]. The strong temperature-dependence of the intensity down to T<<Tc indicates either widely different full gaps on different Fermi surface sheets, or nodal lines perpendicular to the axis.
1005.4468v2
2010-06-11
Scaling of normal-state transport properties of 1111 iron-pnictide superconductors
We show that the zero field normal-state resistivity above Tc for various levels of electron doping-both for underdoped, optimally, and overdoped LaO1-xFxFeAs, i.e. (x=0.05-0.075 and 0.1-0.2) and underdoped SmO1-xFxFeAs (x=0.06- 0.1) members of the 1111-iron-pnictide superconductor family-can be scaled in a broad temperature range from 20 to 300 K onto a single universal curve. The scaling was performed using the energy scale Delta, the resistivity rho(Delta) and the residual resistivity rho0 as scaling parameters as well as applying a recently proposed model-independent scaling method (H. G. Luo, Y. H. Su, and T. Xiang, Phys. Rev. B 77, 014529 (2008)). The scaling parameters have been calculated and the compositional variation of Delta has been determined. The existence of a universal metallic rho(T) curve is interpreted as an indication of a single mechanism which dominates the scattering of the charge carriers in LaO1-xFxFeAs (x= 0.05 to 0.075 and 0.1 to 0.2) and SmO1-xFxFeAs (x = 0.06 to 0.1) .
1006.2350v2
2010-07-12
Magnetic order in orbital models of the iron pnictides
We examine the appearance of the experimentally-observed stripe spin-density-wave magnetic order in five different orbital models of the iron pnictide parent compounds. A restricted mean-field ansatz is used to determine the magnetic phase diagram of each model. Using the random phase approximation, we then check this phase diagram by evaluating the static spin susceptibility in the paramagnetic state close to the mean-field phase boundaries. The momenta for which the susceptibility is peaked indicate in an unbiased way the actual ordering vector of the nearby mean-field state. The dominant orbitally resolved contributions to the spin susceptibility are also examined to determine the origin of the magnetic instability. We find that the observed stripe magnetic order is possible in four of the models, but it is extremely sensitive to the degree of the nesting between the electron and hole Fermi pockets. In the more realistic five-orbital models, this order competes with a strong-coupling incommensurate state which appears to be controlled by details of the electronic structure below the Fermi energy. We conclude by discussing the implications of our work for the origin of the magnetic order in the pnictides.
1007.1949v2
2010-07-15
Spectroscopic survey of M--type asteroids
M-type asteroids, as defined in the Tholen taxonomy (Tholen, 1984), are medium albedo bodies supposed to have a metallic composition and to be the progenitors both of differentiated iron-nickel meteorites and enstatite chondrites. We carried out a spectroscopic survey in the visible and near infrared wavelength range (0.4-2.5 micron) of 30 asteroids chosen from the population of asteroids initially classified as Tholen M -types, aiming to investigate their surface composition. The data were obtained during several observing runs during the years 2004-2007 at the TNG, NTT, and IRTF telescopes. We computed the spectral slopes in several wavelength ranges for each observed asteroid, and we searched for diagnostic spectral features. We confirm a large variety of spectral behaviors for these objects as their spectra are extended into the near-infrared, including the identification of weak absorption bands, mainly of the 0.9 micron band tentatively attributed to orthopyroxene, and of the 0.43 micron band that may be associated to chlorites and Mg-rich serpentines or pyroxene minerals such us pigeonite or augite. A comparison with previously published data indicates that the surfaces of several asteroids belonging to the M-class may vary significantly. We attempt to constrain the asteroid surface compositions of our sample by looking for meteorite spectral analogues in the RELAB database and by modelling with geographical mixtures of selected meteorites/minerals. We confirm that iron meteorites, pallasites, and enstatite chondrites are the best matches to most objects in our sample, as suggested for M-type asteroids. The presence of subtle absorption features on several asteroids confirms that not all objects defined by the Tholen M-class have a pure metallic composition.
1007.2582v1
2010-07-16
High-Resolution X-ray Spectroscopy of the Interstellar Medium
The interstellar medium (ISM) has a multiphase structure characterized by gas, dust and molecules. The gas can be found in different charge states: neutral, low-ionized (warm) and high-ionized (hot). It is possible to probe the multiphase ISM through the observation of its absorption lines and edges in the X-ray spectra of background sources. We present a high-quality RGS spectrum of the low-mass X-ray binary GS 1826-238 with an unprecedent detailed treatment of the absorption features due to the dust and both the neutral and ionized gas of the ISM. We constrain the column density ratios within the different phases of the ISM and measure the abundances of elements such as O, Ne, Fe and Mg. We found significant deviations from the proto-Solar abundances: oxygen is over-abundant by a factor 1.23 +/- 0.05, neon 1.75 +/- 0.11, iron 1.37 +/- 0.17 and magnesium 2.45 +/- 0.35. The abundances are consistent with the measured metallicity gradient in our Galaxy: the ISM appears to be metal-rich in the inner regions. The spectrum also shows the presence of warm/hot ionized gas. The gas column has a total ionization degree less than 10%. We also show that dust plays an important role as expected from the position of GS 1826-238: most iron appears to be bound in dust grains, while 10-40% of oxygen consists of a mixture of dust and molecules.
1007.2796v1
2010-07-16
Crystal Symmetry and Magnetic Order in Iron Pnictides: a Tight Binding Wannier Function Analysis
To perform a local orbital analysis of electronic and magnetic interactions, we construct the Wannier functions (WFs) of the Fe $3d$ orbitals in the parent compound of the recently discovered iron pnictide superconductors, LaFeAsO, and a comparison material LaFePO. Comparing the WFs for the stripe antiferromagnetic order with those for no magnetic order, the difference is a significant spreading (``{\it de}localization'') of specifically the $d_{xy}$ and $d_{xz}$ (but not $d_{yz}$) WFs, where parallel Fe spins lie along the $x$ direction. The WF basis gives a tight-binding representation of the first principles, density functional based Fe-derived bands. Comparing hopping parameters, it is found that changes due to stripe antiferromagnetism, even if it is weak, enables more isotropic hopping involving spin-majority electrons in the Fe $3d_{xz}$ (but not the $3d_{yz}$) orbital. This change, counterintuitively, actually reinforces electronic anisotropy. Further insight is gained by comparing the WFs of LaFeAsO and LaFePO, identifying how the difference in WFs is related to the difference in hopping integrals and showing how the pnictide atom is influential in forming the stripe antiferromagnetism. Kinetic energy considerations suggest that orbital fluctuation, in addition to spin fluctuation, may contribute to the decrease in observed ordered moment compared to the calculated values.
1007.2878v1
2010-07-21
Pseudogap of Superconducting correlation origin in iron-pnictide superconductor Ba0.6+δK0.4-δFe2As2
Pseudogap (PG), a phenomenon of opening of gap like features above superconducting (SC) transition temperature (Tc), has been universally observed in the high-Tc cuprates (HTC) (1,2), some heavy fermion superconductors (3), and iron pnictides (4-7). Here, we report the observation of PG behavior in optical conductivity in an underdoped Ba0.6+{\delta}K0.4-{\delta}Fe2As2 (Tconset =36 K) single crystal far above Tc, up to 100 K (~ 3Tc). Unique scale separation in Ba0.6+{\delta}K0.4-{\delta}Fe2As2 compound - magnetic and SC correlation energy scales being widely separated - enabled us to establish that the PG structures observed in the range of 50 cm-1 - 150 cm-1 in optical conductivity is caused by the SC correlation and the magnetic correlation origin is ruled out. Theoretical calculations, based on the preformed Cooper pair model (8), provided an excellent description to the temperature evolution of the optical conductivity data from below to above Tc.
1007.3617v1
2010-07-29
Dissimilarities between the electronic structure of chemically doped and chemically pressurized iron pnictides from an angle-resolved photoemission spectroscopy study
We have studied the electronic structure of EuFe2As2-xPx using high resolution angle-resolved photoemission spectroscopy. Upon substituting As with the isovalent P, which leads to a chemical pressure and to superconductivity, we observe a non-rigid-band like change of the electronic structure along the center of the Brillouin zone (BZ): an orbital and kz dependent increase or decrease in the size of the hole pockets near the Gamma - Z line. On the other hand, the diameter of the Fermi surface cylinders at the BZ corner forming electron pockets, hardly changes. This is in stark contrast to p and n-type doped iron pnictides where, on the basis of ARPES experiments, a more rigid-band like behavior has been proposed. These findings indicate that there are different ways in which the nesting conditions can be reduced causing the destabilization of the antiferromagnetic order and the appearance of the superconducting dome.
1007.5205v1
2010-07-29
Spectral analysis for the iron-based superconductors: Anisotropic spin fluctuations and fully gapped s^{\pm}-wave superconductivity
Spin fluctuations are considered to be one of the candidates that drive a sign-reversed s^{\pm} superconducting state in the iron pnictides. In the magnetic scenario, whether the spin fluctuation spectrum exhibits certain unique fine structures is an interesting aspect for theoretical study in order to understand experimental observations. We investigate the detailed momentum dependence of the short-range spin fluctuations using a 2-orbital model in the self-consistent fluctuation exchange approximation and find that a common feature of those fluctuations that are capable of inducing a fully gapped s^{\pm} state is the momentum anisotropy with lengthened span along the direction transverse to the antiferromagnetic momentum transfer. Performing a qualitative analysis based on the orbital character and the deviation from perfect nesting of the electronic structure for the 2-orbital and a more complete 5-orbital model, we gain the insight that this type of anisotropic spin fluctuations favor superconductivity due to their enhancement of intra-orbital, but inter-band, pair scattering processes. The momentum anisotropy leads to elliptically shaped magnetic responses which have been observed in inelastic neutron scattering measurements. Meanwhile, our detailed study on the magnetic and the electronic spectrum shows that the dispersion of the magnetic resonance mode in the nearly isotropic s^{\pm} superconducting state exhibits anisotropic propagating behavior in an upward pattern and the coupling of the resonance mode to fermions leads to a dip feature in the spectral function.
1007.5321v3
2010-09-22
3D MHD simulations of subsurface convection in OB stars
During their main sequence evolution, massive stars can develop convective regions very close to their surface. These regions are caused by an opacity peak associated with iron ionization. Cantiello et al. (2009) found a possible connection between the presence of sub-photospheric convective motions and small scale stochastic velocities in the photosphere of early-type stars. This supports a physical mechanism where microturbulence is caused by waves that are triggered by subsurface convection zones. They further suggest that clumping in the inner parts of the winds of OB stars could be related to subsurface convection, and that the convective layers may also be responsible for stochastic excitation of non-radial pulsations. Furthermore, magnetic fields produced in the iron convection zone could appear at the surface of such massive stars. Therefore subsurface convection could be responsible for the occurrence of observable phenomena such as line profile variability and discrete absorption components. These phenomena have been observed for decades, but still evade a clear theoretical explanation. Here we present preliminary results from 3D MHD simulations of such subsurface convection.
1009.4462v1
2010-10-05
Renormalization group flow, competing phases, and the structure of superconducting gap in multi-band models of Iron based superconductors
We perform an analytical renormalization group (RG) study to address the role of Coulomb repulsion, the competition between extended s-wave superconducting order (s+-) and the spin-density wave (SDW) order and the angular dependence of the superconducting gap in multi-pocket models of Iron based superconductors. Previous analytic RG studies considered a toy model of one hole and one electron pocket. We consider more realistic models of two electron pockets and either two or three hole pockets, and also incorporate the angular dependence of interaction. We neglect for simplicity one of the two hole pockets centered at k=0, which is less nested with electron pockets, i.e., consider 3-pocket and 4-pocket models. In a toy 2-pocket model, SDW order always wins over s+- order at perfect nesting, and s+- order only appears at a finite doping, and only if RG flow extends long enough to overcome intra-pocket Coulomb repulsion. For multi-pocket models, we find two new effects. First, there always exists an attractive component of the interaction in s+- channel, such that the system necessary becomes a superconductor once it overcomes the competition from the SDW state. Second, in 3-pocket case (but not in 4-pocket case), there are situations when s+- order wins over SDW order even for perfect nesting, suggesting that SDW order is not a necessary pre-condition for the s+- order. Our results are in good agreement with recent numerical functional RG studies by Thomale et al. [arXiv:1002.3599]
1010.0984v3
2010-10-08
Parity-odd multipoles, magnetic charges and chirality in haematite (alfa-Fe2O3)
Collinear and canted magnetic motifs in haematite were investigated by Kokubun et al. (2008) using x-ray Bragg diffraction magnified at the iron K-edge, and analyses of observations led to various potentially interesting conclusions. We demonstrate that the reported analyses for both non-resonant and resonant magnetic diffraction at low energies near the absorption K-edge are not appropriate. In its place, we apply a radically different formulation, thoroughly tried and tested, that incorporates all magnetic contributions to resonant x-ray diffraction allowed by the established chemical and magnetic structures. Essential to a correct formulation of diffraction by a magnetic crystal with resonant ions at sites that are not centres of inversion symmetry are parity-odd atomic multipoles, time-even (polar) and time-odd (magneto-electric), that arise from enhancement by the electric-dipole (E1) - electric-quadrupole (E2) event. Analyses of azimuthal-angle scans on two space-group forbidden reflections, hexagonal (0, 0, 3)h and (0, 0, 9)h, collected by Kokubun et al. above and below the Morin temperature (TM = 250K), allow us to obtain good estimates of contributing polar and magneto-electric multipoles, including the iron anapole. We show, beyond reasonable doubt, that available data are inconsistent with parity-even events only (E1-E1 and E2- E2). For future experiments, we show that chiral states of haematite couple to circular polarization and differentiate E1-E2 and E2-E2 events, while the collinear motif supports magnetic charges.
1010.1686v3
2010-11-02
Electron transport and anisotropy of the upper critical magnetic field in a Ba0.68K0.32Fe2As2 single crystals
Early work on the iron-arsenide compounds supported the view, that a reduced dimensionality might be a necessary prerequisite for high-Tc superconductivity. Later, however, it was found that the zero-temperature upper critical magnetic field, Hc2(0), for the 122 iron pnictides is in fact rather isotropic. Here, we report measurements of the temperature dependence of the electrical resistivity, \Gamma(T), in Ba0.5K0.5Fe2As2 and Ba0.68K0.32Fe2As2 single crystals in zero magnetic field and for Ba0.68K0.32Fe2As2 as well in static and pulsed magnetic fields up to 60 T. We find that the resistivity of both compounds in zero field is well described by an exponential term due to inter-sheet umklapp electron-phonon scattering between light electrons around the M point to heavy hole sheets at the \Gamma point in reciprocal space. From our data, we construct an H-T phase diagram for the inter-plane (H || c) and in-plane (H || ab) directions for Ba0.68K0.32Fe2As2. Contrary to published data for underdoped 122 FeAs compounds, we find that Hc2(T) is in fact anisotropic in optimally doped samples down to low temperatures. The anisotropy parameter, {\gamma} = Habc2/Hcc2, is about 2.2 at Tc. For both field orientations we find a concave curvature of the Hc2 lines with decreasing anisotropy and saturation towards lower temperature. Taking into account Pauli spin paramagnetism we perfectly can describe Hc2(T) and its anisotropy.
1011.0698v1
2011-01-18
Microturbulent velocity from stellar spectra: a comparison between different approaches (Research Note)
Context --- The classical method to infer microturbulent velocity in stellar spectra requires that the abundances of the iron lines are not correlated with the observed equivalent widths. An alternative method, requiring the use of the expected line strength, is often used to by-pass the risk of spurious slopes due to the correlation between the errors in abundance and equivalent width. Aims --- To compare the two methods and identify pros and cons and applicability to the typical practical cases. Methods --- I performed a test with a grid of synthetic spectra, including instrumental broadening and Poissonian noise. For all these spectra, microturbulent velocity has been derived by using the two approaches and compared with the original value with which the synthetic spectra have been generated. Results --- The two methods provide similar results for spectra with SNR$ > 70, while for lower SNR both approaches underestimate the true microturbulent velocity, depending of the SNR and the possible selection of the lines based on the equivalent width errors. Basically, the values inferred by using the observed equivalent widths better agree with those of the synthetic spectra. In fact, the method based on the expected line strength is not totally free from a bias that can heavily affect the determination of microturbulent velocity. Finally, I recommend to use the classical approach (based on the observed equivalent widths) to infer this parameter. In cases of full spectroscopical determination of all the atmospherical parameters, the difference between the two approaches is reduced, leading to an absolute difference in the derived iron abundances of less than 0.1 dex.
1101.3426v1
2011-01-24
Distinct Fermi Surface Topology and Nodeless Superconducting Gap in (Tl0.58Rb0.42)Fe1.72Se2 Superconductor
High resolution angle-resolved photoemission measurements have been carried out to study the electronic structure and superconducting gap of the (Tl$_{0.58}$Rb$_{0.42}$)Fe$_{1.72}$Se$_2$ superconductor with a T$_c$=32 K. The Fermi surface topology consists of two electron-like Fermi surface sheets around $\Gamma$ point which is distinct from that in all other iron-based compounds reported so far. The Fermi surface around the M point shows a nearly isotropic superconducting gap of $\sim$12 meV. The large Fermi surface near the $\Gamma$ point also shows a nearly isotropic superconducting gap of $\sim$15 meV while no superconducting gap opening is clearly observed for the inner tiny Fermi surface. Our observed new Fermi surface topology and its associated superconducting gap will provide key insights and constraints in understanding superconductivity mechanism in the iron-based superconductors.
1101.4556v1
2011-02-10
An effective quantum parameter for strongly correlated metallic ferromagnets
The correlated motion of electrons in multi-orbital metallic ferromagnets is investigated in terms of a realistic Hubbard model with {\cal N}-fold orbital degeneracy and arbitrary intra- and inter-orbital Coulomb interactions U and J using a Goldstone-mode-preserving non-perturbative scheme. An effective quantum parameter '\hbar'=\frac{U^2+({\cal N}-1)J^2}{(U+({\cal N}-1)J)^2} is obtained which determines, in analogy with 1/S for quantum spin systems and 1/N for the N-orbital Hubbard model, the strength of correlation-induced quantum corrections to magnetic excitations. The rapid suppression of this quantum parameter with Hund's coupling J, especially for large {\cal N}, provides fundamental insight into the phenomenon of strong stabilization of metallic ferromagnetism by orbital degeneracy and Hund's coupling. This approach is illustrated for the case of ferromagnetic iron and the half metallic Heusler alloy Co_2 Mn Si. For realistic values for iron, the calculated spin stiffness and Curie temperature values obtained are in quantitative agreement with measurements. Significantly, the contribution of long wavelength modes is shown to yield a nearly ~25% reduction in the calculated Curie temperature. Finally, an outline is presented for extending the approach to generic multi-band metallic ferromagnets including realistic band-structure features of non-degenerate orbitals and inter-orbital hopping as obtained from LDA calculations.
1102.2115v1
2011-03-05
Physics and measurements of magnetic materials
Magnetic materials, both hard and soft, are used extensively in several components of particle accelerators. Magnetically soft iron-nickel alloys are used as shields for the vacuum chambers of accelerator injection and extraction septa; Fe-based material is widely employed for cores of accelerator and experiment magnets; soft spinel ferrites are used in collimators to damp trapped modes; innovative materials such as amorphous or nanocrystalline core materials are envisaged in transformers for high-frequency polyphase resonant convertors for application to the International Linear Collider (ILC). In the field of fusion, for induction cores of the linac of heavy-ion inertial fusion energy accelerators, based on induction accelerators requiring some 107 kg of magnetic materials, nanocrystalline materials would show the best performance in terms of core losses for magnetization rates as high as 105 T/s to 107 T/s. After a review of the magnetic properties of materials and the different types of magnetic behaviour, this paper deals with metallurgical aspects of magnetism. The influence of the metallurgy and metalworking processes of materials on their microstructure and magnetic properties is studied for different categories of soft magnetic materials relevant for accelerator technology. Their metallurgy is extensively treated. Innovative materials such as iron powder core materials, amorphous and nanocrystalline materials are also studied. A section considers the measurement, both destructive and non-destructive, of magnetic properties. Finally, a section discusses magnetic lag effects.
1103.1069v1
2011-03-22
Dipolar Interactions between Iron-Oxide Nanoparticles in Frozen Ferrofluids and Ferronematics
We present a detailed study of the magnetic behavior of iron-oxide (gamma-Fe2O3 and Fe3O4) nanoparticles constituents of ferrofluids (FF's) with average particle sizes <d> = 2.5 and 10 nm. The particles were dispersed in the frozen liquid carrier (pure FF) and in a frozen lyotropic liquid crystalline matrix in the nematic phase or ferronematic (FN) (ferrolyomesophase). Both FF and FN phases displayed superparamagnetic (SPM) behaviour at room temperature, with blocking temperatures T_B ~ 10 and 100 K for <d> = 2.5 and 10 nm, respectively. Dynamic ac susceptibility measurements showed a thermally activated N\'eel-Brown dependence of the blocking temperature with applied frequency. Our results show that dipolar interactions are small, but non-negligible, as compared to the single-particle energy barriers from magnetic anisotropy. From the fit of ac susceptibility we calculated the effective magnetic anisotropy constant K_{eff} for 2.5 nm maghemite particles. Although interparticle interactions present in highly diluted samples do not appreciably modify the dynamic magnetic behavior of isolated particles, the calculated magnetic anisotropy were abut one order of magnitude larger that the bulk materials, suggesting the existence of large surface anisotropy. Using the thermally activated model to fit the dynamic data yielded effective energy barriers Ea = 3.5x10^{-21} J. From these data, we obtained K_{eff} = 422 kJ/m^3 for the single-particle effective magnetic anisotropy.
1103.4403v1
2011-04-04
X-ray Spectroscopy of MXB 1728-34 with XMM-Newton
We have analysed an XMM-Newton observation of the low mass X-ray binary and atoll source MXB 1728-34. The source was in a low luminosity state during the XMM-Newton observation, corresponding to a bolometric X-ray luminosity of 5*10E36 d^2 erg/s, where d is the distance in units of 5.1 kpc. The 1-11 keV X-ray spectrum of the source, obtained combining data from all the five instruments on-board XMM-Newton, is well fitted by a Comptonized continuum. Evident residuals are present at 6-7 keV which are ascribed to the presence of a broad iron emission line. This feature can be equally well fitted by a relativistically smeared line or by a self-consistent, relativistically smeared, reflection model. Under the hypothesis that the iron line is produced by reflection from the inner accretion disk, we can infer important information on the physical parameters of the system, such as the inner disk radius, Rin = 25-100 km, and the inclination of the system, 44{\deg} < i < 60{\deg}.
1104.0566v1
2011-04-22
Non-LTE line formation for Fe I and Fe II in the atmospheres of A-F type stars
Non-local thermodynamical equilibrium (non-LTE) line formation for neutral and singly-ionized iron is considered through a range of spectral types when the effective temperature varies from 6500 K up to 8500 K, the gravity from log g = 4 down to log g = 3, and the metallicity is solar one. The non-LTE calculations were performed with a comprehensive model atom for iron which was treated in our earlier paper (Mashonkina et al. 2011, A&A, 528, A87). The departures from LTE lead to systematically depleted total absorption in the Fe I lines and positive abundance corrections, in qualitative agreement with the Rentzsch-Holm (1996, A&A, 312, 966) study. However, our predicted magnitude of the non-LTE effects is significantly smaller compared to the previous results due to the use of rather complete model atom of Fe I. The non-LTE abundance corrections do not exceed 0.1 dex for the dwarf models and 0.20 dex for the giant ones. Non-LTE leads to strengthening the Fe II lines, however, the effect is small, such that the abundance correction is at the level of -0.01 to -0.03 dex over the whole range of stellar parameters being considered. No firm conclusion can be drawn with respect to whether or not the Fe I/Fe II ionization equilibrium is fulfilled in the atmosphere of the Sun and Procyon due to uncertainty in available gf-values for visible lines of Fe I and Fe II.
1104.4403v1
2011-05-11
Doping-induced vertical line nodes in the superconducting gap of the iron arsenide K-Ba122 from directional thermal conductivity
The thermal conductivity k of the iron-arsenide superconductor K-Ba122 was measured down to 50 mK in a magnetic field up to 15 T, for a heat current parallel and perpendicular to the tetragonal c axis. In the range from optimal doping (x ~ 0.4) down to x = 0.16, there is no residual linear term in k(T) at T = 0, showing that there are no nodes in the superconducting gap anywhere on the Fermi surface. Upon crossing below x = 0.16, a large residual linear term suddenly appears, signaling the onset of nodes in the superconducting gap, most likely vertical line nodes running along the c axis. We discuss two scenarios: 1) accidental nodes in an s-wave gap, resulting from a strong modulation of the gap around the Fermi surface, in which minima deepen rapidly with underdoping; 2) a phase transition from a nodeless s-wave state to a d-wave state, in which nodes are imposed by symmetry.
1105.2232v2
2011-05-21
Specific Heat Discontinuity, deltaC, at Tc in BaFe2(As0.7P0.3)2 - Consistent with Unconventional Superconductivity
We report the specific heat discontinuity, deltaC/Tc, at Tc = 28.2 K of a collage of single crystals of BaFe2(As0.7P0.3)2 and compare the measured value of 38.5 mJ/molK**2 with other iron pnictide and iron chalcogenide (FePn/Ch) superconductors. This value agrees well with the trend established by Bud'ko, Ni and Canfield who found that deltaC/Tc ~ a*Tc**2 for 14 examples of doped Ba1-xKxFe2As2 and BaFe2-xTMxAs2, where the transition metal TM=Co and Ni. We extend their analysis to include all the FePn/Ch superconductors for which deltaC/Tc is currently known and find deltaC/Tc ~ a*Tc**1.9 and a=0.083 mJ/molK**4. A comparison with the elemental superconductors with Tc>1 K and with A-15 superconductors shows that, contrary to the FePn/Ch superconductors, electron-phonon-coupled conventional superconductors exhibit a significantly different dependence of deltaC on Tc, namely deltaC/Tc ~ Tc**0.9. However deltaC/gamma*Tc appears to be comparable in all three classes (FePn/Ch, elemental and A-15) of superconductors with, e. g., deltaC/gamma*Tc=2.4 for BaFe2(As0.7P0.3)2. A discussion of the possible implications of these phenomenological comparisons for the unconventional superconductivity believed to exist in the FePn/Ch is given.
1105.4289v1
2011-06-03
Iron-based n-type electron-induced ferromagnetic semiconductor
Carrier-induced ferromagnetic semiconductors (FMSs) have been intensively studied for decades as they have novel functionalities that cannot be achieved with conventional metallic materials. These include the ability to control magnetism by electrical gating or light irradiation, while fully inheriting the advantages of semiconductor materials such as band engineering. Prototype FMSs such as (In,Mn)As or (Ga,Mn)As, however, are always p-type, making it difficult to be used in real spin devices. This is because manganese (Mn) atoms in those materials work as local magnetic moments and acceptors that provide holes for carrier-mediated ferromagnetism. Here we show that by introducing iron (Fe) into InAs, it is possible to fabricate a new FMS with the ability to control ferromagnetism by both Fe and independent carrier doping. Despite the general belief that the tetrahedral Fe-As bonding is antiferromagnetic, we demonstrate that (In,Fe)As doped with electrons behaves as an n-type electron-induced FMS, a missing piece of semiconductor spintronics for decades. This achievement opens the way to realise novel spin-devices such as spin light-emitting diodes or spin field-effect transistors, as well as helps understand the mechanism of carrier-mediated ferromagnetism in FMSs.
1106.0561v3
2011-06-06
Correlation of conductivity and angle integrated valence band photoemission characteristics in single crystal iron perovskites for 300 K < T < 800 K: Comparison of surface and bulk sensitive methods
A single crystal monolith of La0.9Sr0.1FeO3 and thin pulsed laser deposited film of La0.8Sr0.2Fe0.8Ni0.2O3 were subject to angle integrated valence band photoemission spectroscopy in ultra high vacuum and conductivity experiments in ambient air at temperatures from 300 K to 800 K. Except for several sputtering and annealing cycles, the specimen were not prepared in-situ.. Peculiar changes in the temperature dependent, bulk representative conductivity profile as a result of reversible phase transitions, and irreversible chemical changes are semi-quantitatively reflected by the intensity variation in the more surface representative valence band spectra near the Fermi energy. X-ray photoelectron diffraction images reflect the symmetry as expected from bulk iron perovskites. The correlation of spectral details in the valence band photoemission spectra (VB PES) and details of the conductivity during temperature variation suggest that valuable information on electronic structure and transport properties of complex materials may be obtained without in-situ preparation.
1106.1034v1
2011-06-15
No X-Ray Excess from the HESS J1741-302 Region except a New Intermediate Polar Candidate
With the Suzaku satellite, we observed an unidentified TeV gamma-ray source HESS J1741$-$302 and its surroundings. No diffuse or point-like X-ray sources are detected from the bright southern emission peak of HESS J1741$-$302. From its neighborhood, we found a new intermediate polar candidate at the position of $(\alpha, \delta)_{\rm J2000.0} = (\timeform{17h40m35.6s}, \timeform{-30D14m16s})$, which is designated as Suzaku J174035.6$-$301416. The spectrum of Suzaku J174035.6$-$301416 exhibits emission lines at the energy of 6.4, 6.7 and 7.0 keV, which can be assigned as the K$\alpha$ lines from neutral, He-like and H-like iron, respectively. A coherent pulsation is found at a period of 432.1 $\pm$ 0.1 s. The pulse profile is quasi-sinusoidal in the hard X-ray band (4$-$8 keV), but is more complicated in the soft X-ray band (1$-$3 keV). The moderate period of pulsation, the energy flux, and the presence of the iron K$\alpha$ lines indicate that Suzaku J174035.6$-$301416 is likely an intermediate polar, a subclass of magnetized white dwarf binaries (cataclysmic variables). Based on these discoveries, we give some implications on the origin of GCDX and brief comments on HESS J1741$-$302 and PSR B1737$-$30.
1106.2861v1
2011-06-15
Electronic identification of the actual parental phase of KxFe2-ySe2 superconductor and its intrinsic mesoscopic phase separation
While the parent compounds of the cuprate high temperature superconductors (high-Tc's) are Mott insulators, the iron-pnictide high-Tc's are in the vicinity of a metallic spin density wave (SDW) state, which highlights the difference between these two families. However, insulating parent compounds were identified for the newly discovered KxFe2-ySe2. This raises an intriguing question as to whether the iron-based high-Tc's could be viewed as doped Mott insulators like the cuprates. Here we report angle-resolved photoemission spectroscopy (ARPES) evidence of two insulating and one semiconducting phases of KxFe2-ySe2, and the mesoscopic phase separation between the superconducting/semiconducting phase and the insulating phases. The insulating phases are characterized by the depletion of electronic states over a 0.5 eV window below the chemical potential, giving a compelling evidence for the presence of Mott-like physics. The charging effects and the absence of band folding in the superconducting/semiconducting phase further prove that the static magnetic and vacancy orders are not related to the superconductivity. Instead, the electronic structure of the superconducting phase is much closer to the semiconducting phase, indicating the superconductivity is likely developed by doping the semiconducting phase rather than the insulating phases.
1106.3026v1
2011-06-19
Iron Based Superconductors: Pnictides versus Chalcogenides
We present a brief review of the present day situation with studies of high-temperature superconductivity in iron pnictides and chalcogenides. Recent discovery of superconductivity with T_c > 30 K in A_xFe_{2-x/2}Se_2 (A=K,Cs,Tl,...) represents the major new step in the development of new concepts in the physics of Fe - based high-temperature superconductors. We compare LDA and ARPES data on the band structure and Fermi surfaces of novel superconductors and those of the previously studied FeAs superconductors, especially isostructural 122 - superconductors like BaFe_2As_2. It appears that electronic structure of new superconductors is rather different from that of FeAs 122 - systems. In particular, no nesting properties of electron and hole - like Fermi surfaces is observed, casting doubts on most popular theoretical schemes of Cooper pairing for these systems. The discovery of Fe vacancies ordering and antiferromagnetic (AFM) ordering at pretty high temperatures (T_N> 500 K), much exceeding superconducting T_c makes these systems unique antiferromagnetic superconductors with highest T_N observed up to now. We discuss the role of both vacancies and AFM ordering in transformations of band structure and Fermi surfaces, as well as their importance for superconductivity. In particular, we show that system remains metallic with unfolded Fermi surfaces quite similar to that in paramagnetic state. Superconducting transition temperature T_c of new superconductors is discussed within the general picture of superconductivity in multiple band systems. It is demonstrated that both in FeAs - superconductors and in new FeSe - systems the value of T_c correlates with the value of the total density of states (DOS) at the Fermi level.
1106.3707v1
2011-06-24
Unprecedented anisotropic metallic state in BaFe2As2 revealed by optical spectroscopy
An ordered phase showing remarkable electronic anisotropy in proximity to the superconducting phase is now a hot issue in the field of high-transition-temperature superconductivity. As in the case of copper oxides, superconductivity in iron arsenides competes or coexists with such an ordered phase. Undoped and underdoped iron arsenides have a magnetostructural ordered phase exhibiting stripe-like antiferromagnetic spin order accompanied by an orthorhombic lattice distortion; both the spin order and lattice distortion break the tetragonal symmetry of crystals of these compounds. In this ordered state, anisotropy of in-plane electrical resistivity is anomalous and difficult to attribute simply to the spin order and/or the lattice distortion. Here, we present the anisotropic optical spectra measured on detwinned BaFe2As2 crystals with light polarization parallel to the Fe planes. Pronounced anisotropy is observed in the spectra, persisting up to an unexpectedly high photon energy of about 2 eV. Such anisotropy arises from an anisotropic energy gap opening below and slightly above the onset of the order. Detailed analysis of the optical spectra reveals an unprecedented electronic state in the ordered phase.
1106.4967v1
2011-06-27
Silicon and Oxygen Abundances in Planet-Host Stars
The positive correlation between planet detection rate and host star iron abundance lends strong support to the core accretion theory of planet formation. However, iron is not the most significant mass contributor to the cores of giant planets. Since giant planet cores are thought to grow from silicate grains with icy mantles, the likelihood of gas giant formation should depend heavily on the oxygen and silicon abundance of the planet formation environment. Here we compare the silicon and oxygen abundances of a set of 76 planet hosts and a control sample of 80 metal-rich stars without any known giant planets. Our new, independent analysis was conducted using high resolution, high signal-to-noise data obtained at McDonald Observatory. Because we do not wish to simply reproduce the known planet-metallicity correlation, we have devised a statistical method for matching the underlying [Fe/H] distributions of our two sets of stars. We find a 99% probability that planet detection rate depends on the silicon abundance of the host star, over and above the observed planet-metallicity correlation. We do not detect any such correlation for oxygen. Our results would thus seem to suggest that grain nucleation, rather than subsequent icy mantle growth, is the important limiting factor in forming giant planets via core accretion. Based on our results and interpretation, we predict that planet detection should correlate with host star abundance for refractory elements responsible for grain nucleation and that no such trends should exist for the most abundant volatile elements responsible for icy mantle growth.
1106.5509v1
2011-06-28
Pressure-induced isostructural phase transition and correlation of FeAs coordination with the superconducting properties of 111-type Na1-xFeAs
The effect of pressure on the crystalline structure and superconducting transition temperature (Tc) of the 111-type Na1-xFeAs system using in situ high pressure synchrotron x-ray powder diffraction and diamond anvil cell techniques is studied. A pressure-induced tetragonal to tetragonal isostructural phase transition was found. The systematic evolution of the FeAs4 tetrahedron as a function of pressure based on Rietveld refinements on the powder x-ray diffraction patterns was obtained. The non-monotonic Tc(P) behavior of Na1-xFeAs is found to correlate with the anomalies of the distance between the anion (As) and the iron layer as well as the bond angle between As-Fe-As for the two tetragonal phases. This behavior provides the key structural information in understanding the origin of the pressure dependence of Tc for 111-type iron pnictide superconductors. A pressure-induced structural phase transition is also observed at 20 GPa.
1106.5640v1
2011-06-30
Suzaku Observation of the Intermediate Polar V1223 Sagittarii
We report on the Suzaku observation of the intermediate polar V1223 Sagittarii. Using a multi-temperature plasma emission model with its reflection from a cold matter, we obtained the shock temperature to be 37.9^{+5.1}_{-4.6} keV. This constrains the mass and the radius of the white dwarf (WD) in the ranges 0.82^{+0.05}_{-0.06} solar masses and (6.9+/-0.4)x10^8 cm, respectively, with the aid of a WD mass-radius relation. The solid angle of the reflector viewed from the post-shock plasma was measured to be Omega/2pi = 0.91+/-0.26. A fluorescent iron Kalpha emission line is detected, whose central energy is discovered to be modulated with the WD rotation for the first time in magnetic-CVs. Detailed spectral analysis indicates that the line comprises of a stable 6.4 keV component and a red-shifted component, the latter of which appears only around the rotational intensity-minimum phase. The equivalent width (EW) of the former stable component ~80 eV together with the measured Omega indicates the major reflector is the WD surface, and the shock height is not more than 7% of the WD radius. Comparing this limitation to the height predicted by the Aizu model (1973), we estimated the fractional area onto which the accretion occurs to be < 7x10^{-3}$ of the WD radius, which is the most severe constraint in non-eclipsing IPs. The red-shifted iron line component, on the other hand, can be interpreted as emanating from the pre-shock accretion flow via fluorescence. Its EW (28^{+44}_{-13} eV) and the central energy (6.30_{-0.05}^{+0.07} keV) at the intensity-minimum phase are consistent with this interpretation.
1106.6111v1
2011-08-09
Magnetic spots on hot massive stars
Hot luminous stars show a variety of phenomena in their photospheres and winds which still lack clear physical explanation. Among these phenomena are photospheric turbulence, line profile variability (LPV), non-thermal emission, non-radial pulsations, discrete absorption components (DACs) and wind clumping. Cantiello et al. (2009) argued that a convection zone close to the stellar surface could be responsible for some of these phenomena. This convective zone is caused by a peak in the opacity associated with iron-group elements and is referred to as the "iron convection zone" (FeCZ). Assuming dynamo action producing magnetic fields at equipartition in the FeCZ, we investigate the occurrence of subsurface magnetism in OB stars. Then we study the surface emergence of these magnetic fields and discuss possible observational signatures of magnetic spots. Simple estimates are made using the subsurface properties of massive stars, as calculated in 1D stellar evolution models. We find that magnetic fields of sufficient amplitude to affect the wind could emerge at the surface via magnetic buoyancy. While at this stage it is difficult to predict the geometry of these features, we show that magnetic spots of size comparable to the local pressure scale height can manifest themselves as hot, bright spots. Localized magnetic fields could be widespread in those early type stars that have subsurface convection. This type of surface magnetism could be responsible for photometric variability and play a role in X-ray emission and wind clumping.
1108.2030v1
2011-08-23
Fine-Grid Calculations for Stellar Electron and Positron Capture Rates on Fe-Isotopes
The acquisition of precise and reliable nuclear data is a prerequisite to success for stellar evolution and nucleosynthesis studies. Core-collapse simulators find it challenging to generate an explosion from the collapse of the core of massive stars. It is believed that a better understanding of the microphysics of core-collapse can lead to successful results. The weak interaction processes are able to trigger the collapse and control the lepton-to-baryon ratio ($Y_{e}$) of the core material. It is suggested that the temporal variation of $Y_{e}$ within the core of a massive star has a pivotal role to play in the stellar evolution and a fine-tuning of this parameter at various stages of presupernova evolution is the key to generate an explosion. During the presupernova evolution of massive stars, isotopes of iron, mainly $^{54,55,56}$Fe, are considered to be key players in controlling $Y_{e}$ ratio via electron capture on these nuclide. Recently an improved microscopic calculation of weak interaction mediated rates for iron isotopes was introduced using the proton-neutron quasiparticle random phase approximation (pn-QRPA) theory. The pn-QRPA theory allows a microscopic \textit{state-by-state} calculation of stellar capture rates which greatly increases the reliability of calculated rates. The results were suggestive of some fine-tuning of the $Y_{e}$ ratio during various phases of stellar evolution. Here we present for the first time the fine-grid calculation of the electron and positron capture rates on $^{54,55,56}$Fe. Core-collapse simulators may find this calculation suitable for interpolation purposes and for necessary incorporation in the stellar evolution codes.
1108.4569v1
2011-10-09
Preemptive nematic order, pseudogap, and orbital order in the iron pnictides
Starting from a microscopic itinerant model, we derive and analyze the effective low-energy model for collective magnetic excitations in the iron pnictides. We show that the stripe magnetic order is generally preempted by an Ising-nematic order which breaks $C_{4}$ lattice symmetry but preserves O(3) spin-rotational symmetry. This leads to a rich phase diagram as function of doping, pressure, and elastic moduli, displaying split magnetic and nematic tri-critical points. The nematic transition may instantly bring the system to the verge of a magnetic transition, or it may occur first, being followed by a magnetic transition at a lower temperature. In the latter case, the preemptive nematic transition is accompanied by either a jump or a rapid increase of the magnetic correlation length, triggering a pseudogap behavior associated with magnetic precursors. Furthermore, due to the distinct orbital character of each Fermi pocket, the nematic transition also induces orbital order. We compare our results to various experiments, showing that they correctly address the changes in the character of the magneto-structural transition across the phase diagrams of different compounds, as well as the relationship between the orthorhombic and magnetic order parameters.
1110.1893v2
2011-11-08
Two Populations of X-ray Pulsars Produced by Two Types of Supernovae
Two types of supernova are thought to produce the overwhelming majority of neutron stars in the Universe. The first type, iron-core collapse supernovae, occurs when a high-mass star develops a degenerate iron core that exceeds the Chandrasekhar limit. The second type, electron-capture supernovae, is associated with the collapse of a lower-mass oxygen-neon-magnesium core as it loses pressure support owing to the sudden capture of electrons by neon and/or magnesium nuclei. It has hitherto been impossible to identify the two distinct families of neutron stars produced in these formation channels. Here we report that a large, well-known class of neutron-star-hosting X-ray pulsars is actually composed of two distinct sub-populations with different characteristic spin periods, orbital periods and orbital eccentricities. This class, the Be/X-ray binaries, contains neutron stars that accrete material from a more massive companion star. The two sub-populations are most probably associated with the two distinct types of neutron-star-forming supernovae, with electron-capture supernovae preferentially producing system with short spin period, short orbital periods and low eccentricity. Intriguingly, the split between the two sub-populations is clearest in the distribution of the logarithm of spin period, a result that had not been predicted and which still remains to be explained.
1111.2051v1
2011-11-22
Microstructural magnetic phases in superconducting FeTe0.65Se0.35
In this paper, we address a number of outstanding issues concerning the nature and the role of magnetic inhomogenities in the iron chalcogenide system FeTe1-xSex and their correlation with superconductivity in this system. We report morphology of superconducting single crystals of FeTe0.65Se0.35 studied with transmission electron microscopy, high angle annular dark field scanning transmission electron microscopy and their magnetic and superconducting properties characterized with magnetization, specific heat and magnetic resonance spectroscopy. Our data demonstrate a presence of nanometre scale hexagonal regions coexisting with tetragonal host lattice, a chemical disorder demonstrating non homogeneous distribution of host atoms in the crystal lattice, as well as hundreds-of-nanometres-long iron-deficient bands. From magnetic data and ferromagnetic resonance temperature dependence, we attribute magnetic phases in Fe-Te-Se to Fe3O4 inclusions and to hexagonal symmetry nanometre scale regions with structure of Fe7Se8 type. Our results suggest that nonhomogeneous distribution of host atoms might be an intrinsic feature of superconducting Fe-Te-Se chalcogenides and we find a surprising correlation indicating that faster grown crystal of inferior crystallographic properties is a better superconductor.
1111.5176v2
2011-11-27
Evolution of structural properties of iron oxide nano particles during temperature treatment from 250°C - 900°C: X-ray diffraction and Fe K-shell pre-edge X-ray absorption study
Iron oxide nano particles with nominal Fe2O3 stoichiometry were synthesized by a wet, soft chemical method with the heat treatment temperatures from 250{\deg}C to 900{\deg}C in air. The variation in the structural properties of the nano particles with the heat treatment temperature was studied by X-ray diffraction and Fe K shell X-ray absorption study. X-ray diffractograms show that at lower annealing temperatures nano particle comprises both maghemite and hematite phases. With increasing temperature, the remainder of the maghemite phase transformed completely to hematite. Profile analysis of the leading Bragg reflections reveals that the average crystallite size increases from 50 nm to 150 nm with increasing temperature. The mean primary particle size decreased from 105 nm to 90 nm with increasing heat treatment temperature. The X-ray diffraction results are paralleled by systematic changes in the pre-edge structure of the Fe K-edge X-ray absorption spectra, in particular by a gradual decrease of the t2g/eg peak height ratio of the two leading pre-edge resonances, confirming oxidation of the Fe from Fe2+ towards Fe3+. Transmission electron microscopy (TEM) on the samples treated at temperatures as high as 900{\deg}C showed particles with prismatic morphology along with the formation of stacking fault like defects. High resolution TEM with selected area electron diffraction (SAED) of samples heat treated above 350{\deg}C showed that the nano particles have well developed lattice fringes corresponding to that of (110) plane of hematite.
1111.6204v1
2011-11-29
A J-band detection of the donor star in the dwarf nova OY Carinae, and an optical detection of its `iron curtain'
Purely photometric models can be used to determine the binary parameters of eclipsing cataclysmic variables with a high degree of precision. However, the photometric method relies on a number of assumptions, and to date there have been very few independent checks of this method in the literature. We present time-resolved spectroscopy of the P=90.9 min eclipsing cataclysmic variable OY Carinae obtained with X-shooter on the VLT, in which we detect the donor star from K I lines in the J-band. We measure the radial velocity amplitude of the donor star K2 = 470.0 +/- 2.7 km/s, consistent with predictions based upon the photometric method (470 +/- 7 km/s). Additionally, the spectra obtained in the UVB arm of X-shooter show a series of Fe I and Fe II lines with a phase and velocity consistent with an origin in the accretion disc. This is the first unambiguous detection at optical wavelengths of the `iron curtain' of disc material which has been previously reported to veil the white dwarf in this system. The velocities of these lines do not track the white dwarf, reflecting a distortion of the outer disc that we see also in Doppler images. This is evidence for considerable radial motion in the outer disk, at up to 90 km/s towards and away from the white dwarf.
1111.6775v1
2011-12-08
Influence of high permeability disks in an axisymmetric model of the Cadarache dynamo experiment
Numerical simulations of the kinematic induction equation are performed on a model configuration of the Cadarache von-K\'arm\'an-Sodium dynamo experiment. The effect of a localized axisymmetric distribution of relative permeability {\mu} that represents soft iron material within the conducting fluid flow is investigated. The critical magnetic Reynolds number Rm^c for dynamo action of the first non-axisymmetric mode roughly scales like Rm^c({\mu})-Rm^c({\mu}->infinity) ~ {\mu}^(-1/2) i.e. the threshold decreases as {\mu} increases. This scaling law suggests a skin effect mechanism in the soft iron disks. More important with regard to the Cadarache dynamo experiment, we observe a purely toroidal axisymmetric mode localized in the high permeability disks which becomes dominant for large {\mu}. In this limit, the toroidal mode is close to the onset of dynamo action with a (negative) growth-rate that is rather independent of the magnetic Reynolds number. We qualitatively explain this effect by paramagnetic pumping at the fluid/disk interface and propose a simplified model that quantitatively reproduces numerical results. The crucial role of the high permeability disks for the mode selection in the Cadarache dynamo experiment cannot be inferred from computations using idealized pseudo-vacuum boundary conditions (H x n = 0).
1112.1780v2
2011-12-20
Spin Dynamics of a J1-J2-K Model for the Paramagnetic Phase of Iron Pnictides
We study the finite-temperature spin dynamics of the paramagnetic phase of iron pnictides within an antiferromagnetic J_1-J_2 Heisenberg model on a square lattice with a biquadratic coupling $-K (S_i \cdot S_j)^2$ between the nearest-neighbor spins. Our focus is on the paramagnetic phase in the parameter regime of this J_1-J_2-K model where the ground state is a (\pi,0) collinear antiferromagnet. We treat the biquadratic interaction via a Hubbard-Stratonovich decomposition, and study the resulting effective quadratic-coupling model using both modified spin wave and Schwinger boson mean-field theories; the results for the spin dynamics derived from the two methods are very similar. We show that the spectral weight of dynamical structure factor S(q,\omega) is peaked at ellipses in the momentum space at low excitation energies. With increasing energy, the elliptic features expand towards the zone boundary, and gradually split into two parts, forming a pattern around (\pi,\pi). Finally, the spectral weight is anisotropic, being larger along the major axis of the ellipse than along its minor axis. These characteristics of the dynamical structure factor are consistent with the recent measurements of the inelastic neutron scattering spectra on BaFe_2As_2 and SrFe_2As_2.
1112.4785v3
2012-01-16
Universal heat conduction in the iron-arsenide superconductor KFe2As2 : Evidence of a d-wave state
The thermal conductivity of the iron-arsenide superconductor KFe2As2 was measured down to 50 mK for a heat current parallel and perpendicular to the tetragonal c-axis. A residual linear term (RLT) at T=0 is observed for both current directions, confirming the presence of nodes in the superconducting gap. Our value of the RLT in the plane is equal to that reported by Dong et al. [Phys. Rev. Lett. 104, 087005 (2010)] for a sample whose residual resistivity was ten times larger. This independence of the RLT on impurity scattering is the signature of universal heat transport, a property of superconducting states with symmetry-imposed line nodes. This argues against an s-wave state with accidental nodes. It favors instead a d-wave state, an assignment consistent with five additional properties: the magnitude of the critical scattering rate for suppressing Tc to zero; the magnitude of the RLT, and its dependence on current direction and on magnetic field; the temperature dependence of the thermal conductivity.
1201.3376v3
2012-01-26
Very fast photometric and X-ray observations of the intermediate polar V2069 Cygni (RX J2123.7+4217)
We present fast timing photometric observations of the intermediate polar V2069 Cygni (RX J2123.7+4217) using the Optical Timing Analyzer (OPTIMA) at the 1.3 m telescope of Skinakas Observatory. The optical (450-950 nm) light curve of V2069 Cygni was measured with sub-second resolution for the first time during July 2009 and revealed a double-peaked pulsation with a period of 743.38 +0.25. A similar double-peaked modulation was found in the simultaneous Swift satellite observations. We suggest that this period represents the spin of the white dwarf accretor. Moreover, we present the results from a detailed analysis of the XMM-Newton observation that also shows a double-peaked modulation, however shifted in phase, with 742.35 +0.23 s period. The X-ray spectra obtained from the XMM-Newton EPIC (European Photon Imaging Camera) instruments were modelled by a plasma emission and a soft black body component with a partial covering photo-electric absorption model with covering fraction of 0.65. An additional Gaussian emission line at 6.385 keV with an equivalent width of 243 eV is required to account for fluorescent emission from neutral iron. The iron fluorescence (~6.4 keV) and FeXXVI lines (~6.95 keV) are clearly resolved in the EPIC spectra. In the Porb-Pspin diagram of IPs, V2069 Cyg shows a low spin to orbit ratio of ~0.0276 in comparison with ~0.1 for other intermediate polars.
1201.5629v1
2012-02-14
Nernst effect of iron pnictide and cuprate superconductors: signatures of spin density wave and stripe order
The Nernst effect has recently proven a sensitive probe for detecting unusual normal state properties of unconventional superconductors. In particular, it may sensitively detect Fermi surface reconstructions which are connected to a charge or spin density wave (SDW) ordered state, and even fluctuating forms of such a state. Here we summarize recent results for the Nernst effect of the iron pnictide superconductor $\rm LaO_{1-x}F_xFeAs$, whose ground state evolves upon doping from an itinerant SDW to a superconducting state, and the cuprate superconductor $\rm La_{1.8-x}Eu_{0.2}Sr_xCuO_4$ which exhibits static stripe order as a ground state competing with the superconductivity. In $\rm LaO_{1-x}F_xFeAs$, the SDW order leads to a huge Nernst response, which allows to detect even fluctuating SDW precursors at superconducting doping levels where long range SDW order is suppressed. This is in contrast to the impact of stripe order on the normal state Nernst effect in $\rm La_{1.8-x}Eu_{0.2}Sr_xCuO_4$. Here, though signatures of the stripe order are detectable in the temperature dependence of the Nernst coefficient, its overall temperature dependence is very similar to that of $\rm La_{2-x}Sr_xCuO_4$, where stripe order is absent. The anomalies which are induced by the stripe order are very subtle and the enhancement of the Nernst response due to static stripe order in $\rm La_{1.8-x}Eu_{0.2}Sr_xCuO_4$ as compared to that of the pseudogap phase in $\rm La_{2-x}Sr_xCuO_4$, if any, is very small.
1202.2959v1
2012-04-04
A New Disintegrative Capture Theory for the Origin of the Moon
The object that resulted in the creation of the Moon started in the same orbital path as Earth around the Sun, but at Earth's L4. This proto-Moon (PM) was 4 times less massive than the usual Giant Impact (GI) object "Theia" and was captured into Earth orbit. It had a 32% Iron-Nickel-Sulfur core supporting a dynamo, which explains magnetized lunar rocks. Following capture, it was torn apart by tidal forces and its core of iron plastered itself, with some of its rock mantle, on the surface of Earth at a very flat angle (producing the "Late Veneer"). After tidal stripping, the remaining PM rock was driven away from Earth to about 3.8 times Earth's radius and formed into what is now the Moon. The GI theory has several troubles: The violent collision melts the entire Earth, contrary to geological evidence. The Moon itself also has to condense out of the vapor cloud generated in the collision, but there is evidence that the Moon was not condensed out of vapor. In the new theory, the Moon as we know it may be only 3.8 - 3.9 billion years old, not 4.56 as usually assumed. That is the age of the PM. The minerals in the Moon would be about as old as the Earth, but would have been re-arranged in the capture and temporary disintegration process. If the Moon is as young as suggested, its origin would coincide with the beginning of life on Earth, which is unexplained in the GI theory. The manuscript asks, "Was the Moon Turned Inside-Out" and the answer is "Essentially, Yes."
1204.0980v2
2012-05-02
Negative thermal expansion and antiferromagnetism in the actinide oxypnictide NpFeAsO
A neptunium analogue of the LaFeAsO tetragonal layered compound has been synthesized and characterized by a variety of experimental techniques. The occurrence of long-range magnetic order below a critical temperature T_N = 57 K is suggested by anomalies in the temperature-dependent magnetic susceptibility, electrical resistivity, Hall coefficient, and specific heat curves. Below T_N, powder neutron diffraction measurements reveal an antiferromagnetic structure of the Np sublattice, with an ordered magnetic moment of 1.70(0.07) \mu_B aligned along the crystallographic c-axis. No magnetic order has been observed on the Fe sublattice, setting an upper limit of about 0.3 \mu_B for the ordered magnetic moment on the iron. High resolution x-ray powder diffraction measurements exclude the occurrence of lattice transformations down to 5 K, in sharp contrast to the observation of a tetragonal-to-orthorhombic distortion in the rare-earth analogues, which has been associated with the stabilization of a spin density wave on the iron sublattice. Instead, a significant expansion of the NpFeAsO lattice parameters is observed with decreasing temperature below T_N, corresponding to a relative volume change of about 0.2% and to an invar behavior between 5 and 20 K. First-principle electronic structure calculations based on the local-spin density plus Coulomb interaction and the local density plus Hubbard-I approximations provide results in good agreement with the experimental findings.
1205.0438v1
2012-05-14
The Central Engine Structure of 3C120: Evidence for a Retrograde Black Hole or a Refilling Accretion Disk
The broad-line radio galaxy 3C120 is a powerful source of both X-ray and radio emission including superluminal jet outflows. We report on our reanalysis of 160 ks of Suzaku data taken in 2006, previously examined by Kataoka et al. (2007). Spectral fits to the XIS and HXD/PIN data over a range of 0.7-45 keV reveal a well-defined iron K line complex with a narrow Ka core and relativistically broadened features consistent with emission from the inner regions of the accretion disk. Furthermore, the inner region of the disk appears to be truncated with an inner radius of r_in = 11.7^{+3.5}_{-5.2} r_g. If we assume that fluorescent iron line features terminate at the inner-most stable circular orbit (ISCO), we measure a black hole spin of a < -0.1 at a 90% confidence level. A rapidly spinning prograde black hole (a > 0.8) can be ruled out at the 99% confidence level. Alternatively, the disk may be truncated well outside of the ISCO of a rapid prograde hole. The most compelling scenario is the possibility that the inner regions of the disk were destroyed/ejected by catastrophic instabilities just prior to the time these observations were made.
1205.3175v1
2012-05-21
Impact of the 2 Fe unit cell on the electronic structure measured by ARPES in iron pnictides
In all iron pnictides, the positions of the ligand alternatively above and below the Fe plane create 2 inequivalent Fe sites. This results in 10 Fe 3d bands in the electronic structure. However, they do not all have the same status for an ARPES experiment. There are interference effects between the 2 Fe that modulate strongly the intensity of the bands and that can even switch their parity. We give a simple description of these effects, notably showing that ARPES polarization selection rules in these systems cannot be applied by reference to a single Fe ion. We show that ARPES data for the electron pockets in Ba(Fe0.92Co0.08)2As2 are in excellent agreement with this model. We observe both the total suppression of some bands and the parity switching of some other bands. Once these effects are properly taken into account, the structure of the electron pockets, as measured by ARPES, becomes very clear and simple. By combining ARPES measurements in different experimental configurations, we clearly isolate each band forming one of the electron pockets. We identify a deep electron band along one ellipse axis with the dxy orbital and a shallow electron band along the perpendicular axis with the dxz/dyz orbitals, in good agreement with band structure calculations. We show that the electron pockets are warped as a function of kz as expected theoretically, but that they are much smaller than predicted by the calculation.
1205.4513v1
2012-05-27
Neutron-Diffraction Measurements of an Antiferromagnetic Semiconducting Phase in the Vicinity of the High-Temperature Superconducting State of K$_x$Fe$_{2-y}$Se$_2$
The recently discovered K-Fe-Se high temperature superconductor has caused heated debate regarding the nature of its parent compound. Transport, angle-resolved photoemission spectroscopy, and STM measurements have suggested that its parent compound could be insulating, semiconducting or even metallic [M. H. Fang, H.-D. Wang, C.-H. Dong, Z.-J. Li, C.-M. Feng, J. Chen, and H. Q. Yuan, Europhys. Lett. 94, 27009 (2011); F. Chen et al. Phys. Rev. X 1, 021020 (2011); and W. Li et al.,Phys. Rev. Lett. 109, 057003 (2012)]. Because the magnetic ground states associated with these different phases have not yet been identified and the relationship between magnetism and superconductivity is not fully understood, the real parent compound of this system remains elusive. Here, we report neutron-diffraction experiments that reveal a semiconducting antiferromagnetic (AFM) phase with rhombus iron vacancy order. The magnetic order of the semiconducting phase is the same as the stripe AFM order of the iron pnictide parent compounds. Moreover, while the root5*root5 block AFM phase coexists with superconductivity, the stripe AFM order is suppressed by it. This leads us to conjecture that the new semiconducting magnetic ordered phase is the true parent phase of this superconductor.
1205.5992v2
2012-05-30
The silicate model and carbon rich model of CoRoT-7b, Kepler-9d and Kepler-10b
Possible bulk compositions of the super-Earth exoplanets, CoRoT-7b, Kepler-9d, and Kepler-10b are investigated by applying a commonly used silicate and a non-standard carbon model. Their internal structures are deduced using the suitable equation of state of the materials. The degeneracy problems of their compositions can be partly overcome, based on the fact that all three planets are extremely close to their host stars. By analyzing the numerical results, we conclude: 1) The iron core of CoRoT-7b is not more than 27% of its total mass within 1 $\sigma$ mass-radius error bars, so an Earth-like composition is less likely, but its carbon rich model can be compatible with an Earth-like core/mantle mass fraction; 2) Kepler-10b is more likely with a Mercury-like composition, its old age implies that its high iron content may be a result of strong solar wind or giant impact; 3) the transiting-only super-Earth Kepler-9d is also discussed. Combining its possible composition with the formation theory, we can place some constraints on its mass and bulk composition.
1205.6554v2
2012-06-18
Impact of Dynamic Orbital Correlations on Magnetic Excitations in the Normal State of Iron-Based Superconductors
We show here that orbital degrees of freedom produce a distinct signature in the magnetic excitation spectrum of iron-based superconductors above the magnetic ordering temperature. Because $d_{xz}$ and $d_{yz}$ orbitals are strongly connected with the Fermi surface topology, the nature of magnetic excitations can be modified significantly due to the presence of either static or fluctuating orbital correlations. Within a five-orbital itinerant model, we show that static orbital order generally leads to an enhancement of commensurate magnetic excitations even when the original Fermi surface lacks nesting at $(\pi,0)$ or $(0,\pi)$. When long-range orbital order is absent, Gaussian fluctuations beyond the standard random-phase approximation (RPA) capture the effects of fluctuating orbital correlations on the magnetic excitations. We find that commensurate magnetic excitations can also be enhanced if the orbital correlations are strong. Our results offer a natural explanation for the incommensurate-to-commensurate transformation observed in a recent neutron scattering measurement (Z. Xu, et. al., arXiv:1201.4404), and we propose that this unusual transformation is an important signature to distinguish orbital from spin physics in the normal state of the pnictides. Implications for the magnetic and superconducting states are discussed.
1206.4095v2
2012-06-29
Laser spectroscopy of finite size and covering effects in magnetite nanoparticles
The experiments on the impact of the size of magnetite clusters on various magnetic properties (magnetic moment, Curie temperature, blocking temperature etc.) have been carried out. The methods of magnetic separation, centrifuging of water suspensions of biocompatible iron oxide nanoparticles (NPs) allow producing fractions with diameter of nanoparticles in the range of 4{\div}22 nm. The size of NPs are controlled by the methods of dynamic light scattering (DLS), transmission electron microscopy (TEM) and atomic force microscopy (AFM). For the first time the DLS method is applied in real time to control the size during the process of the separation of the NPs in aqueous suspensions. The changes of the size of NPs cause a shift in the Curie temperature and in the changes in the specific magnetic properties of the iron NPs. The experimental data is interpreted on the basis of Monte Carlo simulations for the classical Heisenberg model with different bulk and surface magnetic moments. It is demonstrated experimentally and by theoretical modeling that magnetic properties of magnetite NPs are determined not only by their sizes, but also by the their surface spin states, while both growing and falling dependences of the magnetic moment (per Fe3O4 formula unit) being possible, depending on the number of magnetic atoms in the nanoparticle. Both NPs clean and covered with a bioresorbable layer clusters have been investigated.
1206.6985v5
2012-07-03
Two-dome structure in electron-doped iron arsenide superconductors
Iron arsenide superconductors based on the material LaFeAsO1-xFx are characterized by a two-dimensional Fermi surface (FS) consisting of hole and electron pockets yielding structural and antiferromagnetic transitions at x = 0. Electron doping by substituting O2- with F- suppresses these transitions and gives rise to superconductivity with a maximum Tc = 26 K at x = 0.1. However, the over-doped region cannot be accessed due to the poor solubility of F- above x = 0.2. Here we overcome this problem by doping LaFeAsO with hydrogen. We report the phase diagram of LaFeAsO1-xHx (x < 0.53) and, in addition to the conventional superconducting dome seen in LaFeAsO1-xFx, we find a second dome in the range 0.21 < x < 0.53, with a maximum Tc of 36 K at x = 0.3. Density functional theory calculations reveal that the three Fe 3d bands (xy, yz, zx) become degenerate at x = 0.36, whereas the FS nesting is weakened monotonically with x. These results imply that the band degeneracy has an important role to induce high Tc.
1207.0583v2
2012-07-13
The nature of the multi-wavelength emission of 3C 111
We attempt to determine the nature of the high energy emission of the radio galaxy 3C 111, by distinguishing between the effects of the thermal and non-thermal processes. We study the X-ray spectrum of 3C 111 between 0.4 keV and 200 keV, and its spectral energy distribution, using data from the Suzaku satellite combined with INTEGRAL, Swift/BAT data, and Fermi/LAT data. We then model the overall spectral energy distribution including radio and infrared data. The combined Suzaku, Swift and INTEGRAL data are represented by an absorbed exponentially cut-off power-law with reflection from neutral material with a photon index Gamma = 1.68+-0.03, a high-energy cut-off Ecut = 227+143-67 keV, a reflection component with R = 0.7+-0.3 and a Gaussian component to account for the iron emission-line at 6.4 keV with an equivalent width of EW = 85+-11 eV. The X-ray spectrum appears dominated by thermal, Seyfert-like processes, but there are also indications of non-thermal processes. The radio to gamma-ray spectral energy distribution can be fit with a single-zone synchrotron-self Compton model, with no need for an additional thermal component. We suggest a hybrid scenario to explain the broad-band emission, including a thermal component (iron line, reflection) that dominates in the X-ray regime and a non-thermal one to explain the spectral energy distribution.
1207.3308v2
2012-07-16
Searching for Massive Outflows in Holmberg IX X-1 and NGC 1313 X-1: The Iron K Band
We have analysed all the good quality XMM-Newton data publicly available for the bright ULXs Holmberg IX X-1 and NGC 1313 X-1, with the aim of searching for discrete emission or absorption features in the Fe K band that could provide observational evidence for the massive outflows predicted if these sources are accreting at substantially super-Eddington rates. We do not find statistically compelling evidence for any atomic lines, and the limits that are obtained have interesting consequences. Any features in the immediate Fe K energy band (6-7 keV) must have equivalent widths weaker than ~30 eV for Holmberg IX X-1, and weaker than ~50 eV for NGC 1313 X-1 (at 99 per cent confidence). In comparison to the sub-Eddington outflows observed in GRS 1915+105, which imprint iron absorption features with equivalent widths of ~30 eV, the limits obtained here appear quite stringent, particularly when Holmberg IX X-1 and NGC 1313 X-1 must be expelling at least 5-10 times as much material if they host black holes of similar masses. The difficulty in reconciling these observational limits with the presence of strong line-of-sight outflows suggests that either these sources are not launching such outflows, or that they must be directed away from our viewing angle.
1207.3839v1
2012-08-01
Coronae above accretion disks around black holes: The effect of Compton cooling
The geometry of the accretion flow around stellar mass and supermassive black holes depends on the accretion rate. Broad iron emission lines originating from the irradiation of cool matter can indicate that there is an inner disk below a hot coronal flow.These emission lines have been detected in X-ray binaries. Observations with the Chandra X-ray Observatory, XMM Newton and Suzaku have confirmed the presence of these emission lines also in a large fraction of Seyfert-1 active galactic nuclei (AGN). We investigate the accretion flow geometry for which broad iron emission lines can arise in hard and soft spectral state. We study an ADAF-type coronal flow, where the ions are viscously heated and electrons receive their heat only by collisions from the ions and are Compton cooled by photons from an underlying cool disk. For a strong mass flow in the disk and the resulting strong Compton cooling only a very weak coronal flow is possible. This limitation allows the formation of ADAF-type coronae above weak inner disks in the hard state, but almost rules them out in the soft state. The observed hard X-ray luminosity in the soft state, of up to 10% or more of the total flux, indicates that there is a heating process that directly accelerates the electrons. This might point to the action of magnetic flares of disk magnetic fields reaching into the corona. Such flares have also been proposed by observations of the spectra of X-ray black hole binaries without a thermal cut-off around 200 keV.
1208.0265v1
2012-08-18
Gap-dependent quasiparticle dynamics and coherent acoustic phonons in parent iron pnictide CaFe2As2 across the spin density wave phase transition
We report ultrafast quasiparticle (QP) dynamics and coherent acoustic phonons in undoped CaFe_2As_2 iron pnictide single crystals exhibiting spin-density wave (SDW) and concurrent structural phase transition at temperature TSDW ~ 165 K using femtosecond time-resolved pump-probe spectroscopy. The contributions in transient differential reflectivity arising from exponentially decaying QP relaxation and oscillatory coherent acoustic phonon mode show large variations in the vicinity of T_SDW. From the temperature-dependence of the QP recombination dynamics in the SDW phase, we evaluate a BCS-like temperature dependent charge gap with its zero-temperature value of ~(1.6+/-0.2)k_BT_SDW, whereas, much above T_SDW, an electron-phonon coupling constant of ~0.13 has been estimated from the linear temperature-dependence of the QP relaxation time. The long-wavelength coherent acoustic phonons with typical time-period of ~100 ps have been analyzed in the light of propagating strain pulse model providing important results for the optical constants, sounds velocity and the elastic modulus of the crystal in the whole temperature range of 3 K to 300 K.
1208.3742v2
2012-08-29
Interpreting the near-infrared spectra of the 'golden standard' Type Ia supernova 2005cf
We present nine near-infrared (NIR) spectra of supernova (SN) 2005cf at epochs from -10 d to +42 d with respect to B-band maximum, complementing the existing excellent data sets available for this prototypical Type Ia SN at other wavelengths. The spectra show a time evolution and spectral features characteristic of normal Type Ia SNe, as illustrated by a comparison with SNe 1999ee, 2002bo and 2003du. The broad-band spectral energy distribution (SED) of SN 2005cf is studied in combined ultraviolet (UV), optical and NIR spectra at five epochs between ~ 8 d before and ~ 10 d after maximum light. We also present synthetic spectra of the hydrodynamic explosion model W7, which reproduce the key properties of SN 2005cf not only at UV-optical as previously reported, but also at NIR wavelengths. From the radiative-transfer calculations we infer that fluorescence is the driving mechanism that shapes the SED of SNe Ia. In particular, the NIR part of the spectrum is almost devoid of absorption features, and instead dominated by fluorescent emission of both iron-group material and intermediate-mass elements at pre-maximum epochs, and pure iron-group material after maximum light. A single P-Cygni feature of Mg II at early epochs and a series of relatively unblended Co II lines at late phases allow us to constrain the regions of the ejecta in which the respective elements are abundant.
1208.5949v1
2012-09-03
The Black Hole Spin and Soft X-ray Excess of the Luminous Seyfert Galaxy Fairall 9
We present an analysis of all XMM-Newton and Suzaku X-ray spectra of the nearby luminous Seyfert galaxy Fairall 9. Confirming previous analyses, we find robust evidence for a broad iron line associated with X-ray reflection from the innermost accretion disk. By fitting a spectral model that includes a relativistically ionized reflection component, we examine the constraints on the inclination of the inner accretion disk and the black hole spin, and the complications introduced by the presence of a photoionized emission line system. Employing multi-epoch fitting, we attempt to obtain robust and concordant measures of the accretion disk parameters. We also clearly see a soft X-ray excess in Fairall 9. During certain epochs, the soft excess can be described with same disk reflection component that produces the iron line. However, there are epochs where an additional soft component is required. This can be attributed to either an additional highly-ionized, strongly blurred disk reflection component, or a new X-ray continuum component.
1209.0468v1
2012-09-04
The enrichment history of the intracluster medium: a Bayesian approach
This work measures the evolution of the iron content in galaxy clusters by a rigorous analysis of the data of 130 clusters at 0.1<z<1.3. This task is made difficult by a) the low signal-to-noise ratio of abundance measurements and the upper limits, b) possible selection effects, c) boundaries in the parameter space, d) non-Gaussian errors, e) the intrinsic variety of the objects studied, and f) abundance systematics. We introduce a Bayesian model to address all these issues at the same time, thus allowing cross-talk (covariance). On simulated data, the Bayesian fit recovers the input enrichment history, unlike in standard analysis. After accounting for a possible dependence on X-ray temperature, for metal abundance systematics, and for the intrinsic variety of studied objects, we found that the present-day metal content is not reached either at high or at low redshifts, but gradually over time: iron abundance increases by a factor 1.5 in the 7 Gyr sampled by the data. Therefore, feedback in metal abundance does not end at high redshift. Evolution is established with a moderate amount of evidence, 19 to 1 odds against faster or slower metal enrichment histories. We quantify, for the first time, the intrinsic spread in metal abundance, 18+/-3 %, after correcting for the effect of evolution, X-ray temperature, and metal abundance systematics. Finally, we also present an analytic approximation of the X-ray temperature and metal abundance likelihood functions, which are useful for other regression fitting involving these parameters. The data for the 130 clusters and code used for the stochastic computation are provided with the paper.
1209.0565v1
2012-10-04
Manipulation and detection of spin state of Iron-Porphyrin by dedicated chemisorption on magnetic substrates
One of the key factors behind the rapid evolution of molecular spintronics is the efficient realization of spin manipulation of organic molecules with a magnetic center. The spin state of such molecules may depend crucially on the interaction with the substrate on which they are adsorbed. In this letter, we demonstrate, using ab initio density functional calculations, that the stabilization of a high spin state of an iron porphyrin (FeP) molecule can be achieved via a dedicated chemisorption on magnetic substrates of different species and orientations. It is shown that the strong covalent interaction with the substrate increases Fe-N bond lengths in FeP and hence a switching to a high spin state (S=2) from a low spin state (S=1) is achieved. A ferromagnetic exchange interaction is established through a direct exchange between Fe and substrate magnetic atoms as well as through an indirect exchange via the N atoms in FeP. The mechanism of exchange interaction is further analyzed by considering structural models constructed from ab initio calculations. Finally, we illustrate the possibility of detecting a change in the molecular spin state by x-ray magnetic circular dichroism, Raman spectroscopy and spin-polarized scanning tunneling microscopy.
1210.1376v1
2012-12-07
Poly(acrylic acid)-coated iron oxide nanoparticles : quantitative evaluation of the coating properties and applications for the removal of a pollutant dye
In this work, 6 to 12 nm iron oxide nanoparticles were synthesized and coated with poly(acrylic acid) chains of molecular weight 2100 g/mol. Based on a quantitative evaluation of the dispersions, the bare and coated particles were thoroughly characterized. The number densities of polymers adsorbed at the particle surface and of available chargeable groups were found to be 1.9 +/- 0.3 nm-2 and 26 +/- 4 nm-2, respectively. Occurring via a multi-site binding mechanism, the electrostatic coupling leads to a solid and resilient anchoring of the chains. To assess the efficacy of the particles for pollutant remediation, the adsorption isotherm of methylene blue molecules, a model of pollutant, was determined. The excellent agreement between the predicted and measured amounts of adsorbed dyes suggests that most carboxylates participate to the complexation and adsorption mechanisms. An adsorption of 830 mg/g was obtained. This quantity compares well with the highest values available for this dye.
1212.1580v1
2012-12-07
Magneto-optic Faraday effect in maghemite nanoparticles/silica matrix nanocomposites prepared by the Sol-Gel method
Bulk monolithic samples of {\gamma}-Fe2O3/SiO2 composites with different iron oxide/silica ratios have been prepared by the sol-gel technique. Iron oxide nanoparticles are obtained in-situ during heat treatment of samples and silica matrix consolidation. Preparation method was previously optimized to minimize the percentage of antiferromagnetic {\alpha}-Fe2O3 and parallelepipeds of roughly 2x5x12 mm3, with good mechanical stability, are obtained. RT magnetization curves show a non-hysteretic behavior. Thus, magnetization measurements have been well fitted to an expression that combines the Langevin equation with an additional linear term, indicating that some of the nanoparticles are still superparamagnetic as confirmed by X-ray diffraction and electron microscopy measurements. Zero field cooled /field cooled experiments show curves with slightly different shapes, depending on the size and shape distribution of nanoparticles for a given composition. Magneto-optical Faraday effect measurements show that the Faraday rotation is proportional to magnetization of the samples, as expected. As a demonstration of their sensing possibilities, the relative intensity of polarized light, measured at 5{\deg} from the extinction angle, was plotted versus applied magnetic field.
1212.1690v1
2012-12-13
Dopant Clustering, Electronic Inhomogeneity, and Vortex Pinning in Iron-Based Superconductors
We use scanning tunneling microscopy to map the surface structure, nanoscale electronic inhomogeneity, and vitreous vortex phase in the hole-doped superconductor Sr$_{0.75}$K$_{0.25}$Fe$_2$As$_2$ with $T_c$=32 K. We find the low-$T$ cleaved surface is dominated by a half-Sr/K termination with $1\times 2$ ordering and ubiquitous superconducting gap, while patches of gapless, unreconstructed As termination appear rarely. The superconducting gap varies by $\sigma/\bar{\Delta}$=16% on a $\sim$3 nm length scale, with average $2\bar{\Delta}/k_B T_c=3.6$ in the weak coupling limit. The vortex core size provides a measure of the superconducting coherence length $\xi$=2.3 nm. We quantify the vortex lattice correlation length at 9 T in comparison to several iron-based superconductors. The comparison leads us to suggest the importance of dopant size mismatch as a cause of dopant clustering, electronic inhomogeneity, and strong vortex pinning.
1212.3240v3
2013-01-07
Persistent high-energy spin excitations in iron pnictide superconductors
Motivated by the premise that superconductivity in iron-based superconductors is unconventional and mediated by spin fluctuations, an intense research effort has been focused on characterizing the spin excitation spectrum in the magnetically ordered parent phases of the Fe-pnictides2,3 and - chalcogenides4. For these undoped materials it is well-established that the spin excitation spectrum consists of a sharp, highly dispersive magnon spanning an energy range of up to 200 meV (ref. 3). The fate of these high-energy magnetic modes upon sizable doping is hitherto unresolved. Using resonant inelastic x-ray scattering we show that optimally doped superconducting Ba0.6K0.4Fe2As2 retains well defined, dispersive high-energy modes of magnetic origin. These paramagnon modes are softer than, though as intense as, the magnon of undoped antiferromagnetic BaFe2As2. The persistence of spin excitations well into the superconducting phase suggests that, if spin fluctuations are responsible for superconducting pairing, they originate from a distinctly correlated spin-state. This connects Fe-pnictide superconductors to the high-Tc cuprates, for which in spite of fundamental differences in the electronic structure, similar paramagnon modes are present5.
1301.1289v1
2013-02-21
The Mid-Infrared and Optical Decay of SN 2011fe
We measure the decay rate of the mid-IR luminosity from type Ia supernova 2011fe between six months and one year after explosion using Spitzer/IRAC observations. The fading in the 3.6 micron channel is 1.48+/-0.02 mag/100d, which is similar to that seen in blue optical bands. The supernova brightness fades at 0.78+/-0.02 mag/100d in the 4.5 micron channel which is close to that observed in the near-IR. We argue that the difference is a result of doubly ionized iron-peak elements dominating the bluer IRAC band while singly ionized species are controlling the longer wavelength channel. To test this, we use Large Binocular Telescope spectra taken during the same phases to show that doubly ionized emission lines do fade more slowly than their singly ionized cousins. We also find that [Co III] emission fades at more than twice the radioactive decay rate due to the combination of decreasing excitation in the nebula, recombination and cobalt decaying to iron. The nebular emission velocities of [Fe III] and [Co III] lines show a smaller blue-shift than emission from singly ionized atoms. The Si II velocity gradient near maximum light combined with our nebular velocity measurements suggest SN 2011fe was a typical member of the `low velocity gradient' class of type Ia. Analyzing IRAC photometry from other supernovae we find that mid-IR color of type Ia events is correlated with the early light curve width and can be used as an indicator of the radioactive nickel yield.
1302.5421v1
2013-02-24
The X-ray Spectrum Of The Black Hole Candidate Swift J1753.5-0127
We present a spectral analysis of the black hole candidate and X-ray transient source Swift J1753.5 0127 making use of simultaneous observations of XMM-Newton and Rossi X-ray Timing Explorer (RXTE) in 2006, when the source was in outburst. The aim of this paper is to test whether a thermal component due to the accretion disc is present in the X-ray spectrum. We fit the data with a range of spectral models, and we find that for all of these models the fits to the X-ray energy spectra significantly require the addition of the disc black-body component. We also find a broad iron emission line at around 6.5 keV, most likely due to iron in the accretion disc. Our results confirm the existence of a cool inner disc extending near or close to the innermost circular orbit (ISCO).We further discovered broad emission lines of NVII and OVIII at ~ 0.52 keV and 0.65 keV, respectively in the RGS spectrum of Swift J1753.5-0127.
1302.5882v2
2013-03-04
Soft lags in neutron star kHz Quasi Periodic Oscillations: evidence for reverberation?
High frequency soft reverberation lags have now been detected from stellar mass and super massive black holes. Their interpretation involves reflection of a hard source of photons onto an accretion disk, producing a delayed reflected emission, with a time lag consistent with the light travel time between the irradiating source and the disk. Independently of the location of the clock, the kHz Quasi-Periodic Oscillation (QPO) emission is thought to arise from the neutron star boundary layer. Here, we search for the signature of reverberation of the kHz QPO emission, by measuring the soft lags and the lag energy spectrum of the lower kHz QPOs from 4U1608-52. Soft lags, ranging from ~15 to ~40 microseconds, between the 3-8 keV and 8-30 keV modulated emissions are detected between 565 and 890 Hz. The soft lags are not constant with frequency and show a smooth decrease between 680 Hz and 890 Hz. The broad band X-ray spectrum is modeled as the sum of a disk and a thermal comptonized component, plus a broad iron line, expected from reflection. The spectral parameters follow a smooth relationship with the QPO frequency, in particular the fitted inner disk radius decreases steadily with frequency. Both the bump around the iron line in the lag energy spectrum, and the consistency between the lag changes and the inferred changes of the inner disk radius, from either spectral fitting or the QPO frequency, suggest that the soft lags may indeed involve reverberation of the hard pulsating QPO source on the disk.
1303.0750v2
2013-03-07
Abundances of neutron-capture elements in stars of the galactic disk substructures
The aim of this work is to present and discuss the observations of the iron peak (Fe, Ni) and neutron-capture element (Y, Zr, Ba, La, Ce, Nd, Sm, and Eu) abundances for 276 FGK dwarfs, located in the galactic disk with metallicity -1 < [Fe/H] < +0.3. Atmospheric parameters and chemical composition of the studied stars were determined from an high resolution, high signal-to-noise echelle spectra obtained with the echelle spectrograph ELODIE at the Observatoire de Haute-Provence (France). Effective temperatures were estimated by the line depth ratio method and from the H_{\alpha} line-wing fitting. Surface gravities (log g) were determined by parallaxes and the ionization balance of iron. Abundance determinations were carried out using the LTE approach, taking the hyperfine structure for Eu into account, and the abundance of Ba was computed under the NLTE approximation. We are able to assign most of the stars in our sample to the substructures of the Galaxy thick disk, thin disk, or Hercules stream according to their kinematics. The classification of 27 stars is uncertain. For most of the stars in the sample, the abundances of neutron-capture elements have not been measured earlier. For all of them, we provide the chemical composition and discuss the contribution from different nucleosynthesis processes.
1303.1730v1
2013-03-28
New Diluted Ferromagnetic Semiconductor isostructural to 122 type iron pnictide superconductor with TC up to 180 K
Diluted magnetic semiconductors (DMS) have received much attention due to its potential applications to spintronics devices. A prototypical system (Ga,Mn)As has been widely studied since 1990s. The simultaneous spin and charge doping via hetero-valence (Ga3+,Mn2+) substitution, however, resulted in severely limited solubility without availability of bulk specimens. Previously we synthesized a new diluted ferromagnetic semiconductor of bulk Li(Zn,Mn)As with Tc up to 50K, where isovalent (Zn,Mn) spin doping was separated from charge control via Li concentrations. Here we report the synthesis of a new diluted ferromagnetic semiconductor (Ba1-xKx)(Zn1-yMny)2As2, isostructural to iron 122 system, where holes are doped via (Ba2+, K1+), while spins via (Zn2+,Mn2+) substitutions. Bulk samples with x=0.1-0.3 and y=0.05-0.15 exhibit ferromagnetic order with TC up to 180K, comparable to that of record high Tc for Ga(MnAs), significantly enhanced than Li(Zn,Mn)As. Moreover the (Ba,K)(Zn,Mn)2As2 shares the same 122 crystal structure with semiconducting BaZn2As2, antiferromagnetic BaMn2As2, and superconducting (Ba,K)Fe2As2, which makes them promising to the development of multilayer functional devices.
1303.7157v1
2013-03-29
Seeing the orbital ordering in Iron-based superconductors with magnetic anisotropy
The orbital fluctuation of the conduction electrons in the Iron-based superconductors is found to contribute significantly to the magnetic response of the system. With the use of a realistic five-band model and group theoretical analysis, we have determined the orbital magnetic susceptibility in such a multi-orbital system. At $n=6.1$, the in-plane orbital magnetic susceptibility is predicted to be about 10$\mu_{\mathrm{B}}^{2}/\mathrm{eV}$, which is more than 2/3 of the observed total susceptibility around 200 K in 122 systems(of about 14$\mu_{\mathrm{B}}^{2}/\mathrm{eV}$ or $4.5\times10^{-4}\mathrm{erg}/\mathrm{G}^{2}\mathrm{mol}_{\mathrm{AS}}$\cite{Klingeler}). We find the in-plane orbital magnetic response is sensitive to the breaking of the tetragonal symmetry in the orbital space. In particular, when the observed band splitting(between the $3d_{xz}$ and the $3d_{yz}$-dominated band) is used to estimate the strength of the symmetry breaking perturbation\cite{Shen}, a 4.5% modulation in the in-plane orbital magnetic susceptibility can be produced, making the latter a useful probe of the orbital ordering in such a multi-orbital system. As a by product, the theory also explains the large anisotropy between the in-plane and the out-of-plane magnetic response observed universally in susceptibility and NMR measurements.
1303.7302v2
2013-04-01
Carbon and Oxygen Abundances in the Hot Jupiter Exoplanet Host Star XO-2N and its Binary Companion
With the aim of connecting the compositions of stars and planets, we present the abundances of carbon and oxygen, as well as iron and nickel, for the transiting exoplanet host star XO-2N and its wide-separation binary companion XO-2S. Stellar parameters are derived from high-resolution, high-signal-to-noise spectra, and the two stars are found to be similar in their Teff, log g, iron ([Fe/H]), nickel ([Ni/H]) abundances. Their carbon ([C/H]) and oxygen ([O/H]) abundances also overlap within errors, although XO-2N may be slightly more C-rich and O-rich than XO-2S. The C/O ratios of both stars (~0.60+/-0.20) may also be somewhat larger than solar (C/O~0.50). The XO-2 system has a transiting hot Jupiter orbiting one binary component but not the other, allowing us to probe the potential effects planet formation might have on the host star composition. Additionally, with multiple observations of its atmosphere the transiting exoplanet XO-2b lends itself to compositional analysis, which can be compared to the natal chemical environment established by our binary star elemental abundances. This work sets the stage for determining how similar/different exoplanet and host star compositions are, and the implications for planet formation, by discussing the C/O ratio measurements in the unique environment of a visual binary system with one star hosting a transiting hot Jupiter.
1304.0395v1
2013-04-03
Molybdenum, Ruthenium, and the Heavy r-process Elements in Moderately Metal-Poor Main-Sequence Turnoff Stars
The ratios of elemental abundances observed in metal-poor stars of the Galactic halo provide a unique present-day record of the nucleosynthesis products of its earliest stars. While the heaviest elements were synthesized by the r- and s-processes, dominant production mechanisms of light trans-ironic elements were obscure until recently. This work investigates further our 2011 conclusion that the low-entropy regime of a high-entropy wind (HEW) produced molybdenum and ruthenium in two moderately metal-poor turnoff stars that showed extreme overabundances of those elements with respect to iron. Only a few, rare nucleosynthesis events may have been involved. Here we determine abundances for Mo, Ru, and other trans-Fe elements for 28 similar stars by matching spectral calculations to well-exposed near-UV Keck HIRES spectra obtained for beryllium abundances. In each of the 26 turnoff stars with Mo or Ru line detections and no evidence for s-process production (therefore old), we find Mo and Ru to be three to six times overabundant. In contrast, the maximum overabundance is reduced to factors of three and two for the neighboring elements zirconium and palladium. Since the overproduction peaks sharply at Mo and Ru, a low-entropy HEW is confirmed as its origin. The overabundance level of the heavy r-process elements varies significantly, from none to a factor of four, but is uncorrelated with Mo and Ru overabundances. Despite their moderate metallicity, stars in this group trace the products of different nucleosynthetic events: possibly very few events, possibly events whose output depended on environment, metallicity, or time.
1304.1050v1
2013-04-04
Learning from Nature to Improve the Heat Generation of Iron-Oxide Nanoparticles for Magnetic Hyperthermia Applications
The performance of magnetic nanoparticles is intimately entwined with their structure, mean size and magnetic anisotropy. Besides, ensembles offer a unique way of engineering the magnetic response by modifying the strength of the dipolar interactions between particles. Here we report on an experimental and theoretical analysis of magnetic hyperthermia, a rapidly developing technique in medical research and oncology. Experimentally, we demonstrate that single-domain cubic iron oxide particles resembling bacterial magnetosomes have superior magnetic heating efficiency compared to spherical particles of similar sizes. Monte Carlo simulations at the atomic level corroborate the larger anisotropy of the cubic particles in comparison with the spherical ones, thus evidencing the beneficial role of surface anisotropy in the improved heating power. Moreover we establish a quantitative link between the particle assembling, the interactions and the heating properties. This knowledge opens new perspectives for improved hyperthermia, an alternative to conventional cancer therapies.
1304.1298v1
2013-04-18
Hadron energy response of the Iron Calorimeter detector at the India-based Neutrino Observatory
The results of a Monte Carlo simulation study of the hadron energy response for the magnetized Iron CALorimeter detector, ICAL, proposed to be located at the India-based Neutrino Observatory (INO) is presented. Using a GEANT4 modeling of the detector ICAL, interactions of atmospheric neutrinos with target nuclei are simulated. The detector response to hadrons propagating through it is investigated using the hadron hit multiplicity in the active detector elements. The detector response to charged pions of fixed energy is studied first, followed by the average response to the hadrons produced in atmospheric neutrino interactions using events simulated with the NUANCE event generator. The shape of the hit distribution is observed to fit the Vavilov distribution, which reduces to a Gaussian at high energies. In terms of the parameters of this distribution, we present the hadron energy resolution as a function of hadron energy, and the calibration of hadron energy as a function of the hit multiplicity. The energy resolution for hadrons is found to be in the range 85% (for 1GeV) -- 36% (for 15 GeV).
1304.5115v2
2013-04-19
Understanding the re-entrant superconducting phase diagram of an iron-pnictide Ca$_4$Al$_2$O$_6$Fe$_2$(As$_{1-x}$P$_x$)$_2$
Recently, a very rich phase diagram has been obtained for an iron-based superconductor Ca4Al2O6Fe2(As1-xPx)2. It has been revealed that nodeless (x=0) and nodal (x = 1) superconductivity are separated by an antiferromagnetic phase. Here we study the origin of this peculiar phase diagram using a five orbital model constructed from first principles band calculation, and applying the fluctuation exchange approximation assuming spin fluctuation mediated pairing. Based on the calculation results, we propose a scenario where the frustration in momentum space degrades superconductivity in the intermediate x regime, while antiferromangetism takes place due to a very good nesting. In order to see whether the present theoretical scenario is consistent with the actual nature of the competition between superconductivity and antiferromagnetism, we also perform hydrostatic pressure experiment for Ca4Al2O6Fe2(As1-xPx)2. In the intermediate x regime where antiferromagnetism occurs at ambient pressure, applying hydrostatic pressure smears out the antiferromagnetic transition, but superconductivity does not take place. This supports our scenario that superconductivity is suppressed by the momentum space frustration in the intermediate x regime, apart from the presence of the antiferromangnetism.
1304.5360v1
2013-04-24
Deriving precise parameters for cool solar-type stars. Optimizing the iron line list
Temperature, surface gravity, and metallicitity are basic stellar atmospheric parameters necessary to characterize a star. We aim to improve the description of the spectroscopic temperatures especially for the cooler stars where the differences with the Infrared Flux Method are higher, as presented in previous work. Our spectroscopic analysis is based on the iron excitation and ionization balance, assuming Kurucz model atmospheres in LTE. The abundance analysis is determined using the code MOOG. We optimize the line list using a cool star with high resolution and high signal-to-noise spectrum, as a reference in order to check for weak, isolated lines. We test the quality of the new line list by re-deriving stellar parameters for 451 stars with high resolution and signal-to-noise HARPS spectra, that were analyzed in a previous work with a larger line list. The comparison in temperatures between this work and the latest IRFM shows that the differences for the cooler stars are significantly smaller and more homogeneously distributed than in previous studies for stars with temperatures below 5000 K. We use the new line list to re-derive parameters for some of the cooler stars that host planets. Finally, we present the impact of the new temperatures on the [Cr I/Cr II] and [Ti I/Ti II] abundance ratios that previously showed systematic trends with temperature.
1304.6639v1
2013-04-28
Point Contact Spectroscopy of Fe Pnictides & Chalcogenides In The Normal State
We review the current status of point contact spectroscopy on the iron based superconductors, focusing on their normal state. Point contact spectroscopy is generally used to study superconductors via Andreev reflection, but in recent years it has also proved to be a useful bulk probe of strongly correlated electron systems. Point contact spectroscopy picks up a conductance enhancement in the normal state, above the structural phase transition, of certain iron based compounds. These include Co doped $\rm{BaFe_2As_2}$, $\rm{SrFe_2As_2}$, $\rm{Fe_{1+y}Te}$ and F doped $\rm{SmFeAsO}$ and $\rm{LaFeAsO}$. Two materials which do not show this conductance enhancement are $\rm{CaFe_2As_2}$ and K doped $\rm{BaFe_2As_2}$. This conductance enhancement is thought to be tied to orbital fluctuations. Orbital fluctuations in the normal state of these compounds increases the single particle density of states at the Fermi level, indicating that PCS is sensitive to this excess density of states. The enhancement is only observed at those temperatures and dopings where an in-plane resisitve anisotropy in the detwinned compounds is known to occur. Thus point contact spectroscopy provides strong indications of electronic nematicity in such materials. We also present diagnostics on how to judge if a junction is impacted by joule heating or not. We conclude with the outstanding challenges in the field and the new experiments that need to be carried out.
1304.7426v1
2013-05-08
A fully quantum mechanical calculation of the diffusivity of hydrogen in iron using the tight binding approximation and path integral theory
We present calculations of free energy barriers and diffusivities as functions of temperature for the diffusion of hydrogen in bcc-Fe. This is a fully quantum mechanical approach since the total energy landscape is computed using a new self consistent, transferable tight binding model for interstitial impurities in magnetic iron. Also the hydrogen nucleus is treated quantum mechanically and we compare here two approaches in the literature both based in the Feynman path integral formulation of statistical mechanics. We find that the quantum transition state theory which admits greater freedom for the proton to explore phase space gives result in better agreement with experiment than the alternative which is based on fixed centroid calculations of the free energy barrier. We also find results in better agreement compared to recent centroid molecular dynamics (CMD) calculations of the diffusivity which employed a classical interatomic potential rather than our quantum mechanical tight binding theory. In particular we find first that quantum effects persist to higher temperatures than previously thought, and conversely that the low temperature diffusivity is smaller than predicted in CMD calculations and larger than predicted by classical transition state theory. This will have impact on future modeling and simulation of hydrogen trapping and diffusion.
1305.1772v1
2013-05-10
Carbon Deflagration in Type Ia Supernova: I. Centrally Ignited Models
A leading model for Type Ia supernovae (SNe Ia) begins with a white dwarf near the Chandrasekhar mass that ignites a degenerate thermonuclear runaway close to its center and explodes. In a series of papers, we shall explore the consequences of ignition at several locations within such dwarfs. Here we assume central ignition, which has been explored before, however, the problem is worth revisiting, if only to validate those previous studies and to further elucidate the relevant physics for future work. A perturbed sphere of hot iron ash with a radius of ~100 km is initialized at the middle of the star. The subsequent explosion is followed in several simulations using a thickened flame model in which the flame speed is either fixed --- within the range expected from turbulent combustion --- or based on the local turbulent intensity. Global results, including the explosion energy and bulk nucleosynthesis (e.g. 56Ni of 0.48--0.56 $\Msun$) turn out to be insensitive to this speed. In all completed runs, the energy released by the nuclear burning is adequate to unbind the star, but not enough to give the energy and brightness of typical SNe Ia. As found previously, the chemical stratification observed in typical events is not reproduced. These models produce a large amount of unburned carbon and oxygen in central low velocity regions, which is inconsistent with spectroscopic observations, and the intermediate mass elements and iron group elements are strongly mixed during the explosion.
1305.2433v1
2013-05-16
Effect of doping on the magnetostructural ordered phase of iron arsenides: A comparative study of the resistivity anisotropy in the doped BaFe$_2$As$_2$ with doping into three different sites
In order to unravel a role of doping in the iron-based superconductors, we investigated the in-plane resistivity for BaFe$_2$As$_2$ doped at either of the three different lattice sites, Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$, BaFe$_2$(As$_{1-x}$P$_x$)$_2$, and Ba$_{1-x}$K$_x$Fe$_2$As$_2$, focusing on the doping effect in the low-temperature antiferromagnetic/orthorhombic (AFO) phase. A major role of doping in the high-temperature paramagnetic/tetragonal (PT) phase is known to change the Fermi surface by supplying charge carriers or by exerting chemical pressure. In the AFO phase, we found a clear correlation between the magnitude of residual resistivity and resistivity anisotropy. This indicates that the resistivity anisotropy originates from the anisotropic impurity scattering from dopant atoms. The magnitude of residual resistivity is also found to be a parameter controlling the suppression rate of AFO ordering temperature $T_s$. Therefore, the dominant role of doping in the AFO phase is to introduce disorder to the system, distinct from that in the PT phase.
1305.3744v1
2013-05-31
Supernova Ejecta in the Youngest Galactic Supernova Remnant G1.9+0.3
G1.9+0.3 is the youngest known Galactic supernova remnant (SNR), with an estimated supernova (SN) explosion date of about 1900, and most likely located near the Galactic Center. Only the outermost ejecta layers with free-expansion velocities larger than about 18,000 km/s have been shocked so far in this dynamically young, likely Type Ia SNR. A long (980 ks) Chandra observation in 2011 allowed spatially-resolved spectroscopy of heavy-element ejecta. We denoised Chandra data with the spatio-spectral method of Krishnamurthy et al., and used a wavelet-based technique to spatially localize thermal emission produced by intermediate-mass elements (IMEs: Si and S) and iron. The spatial distribution of both IMEs and Fe is extremely asymmetric, with the strongest ejecta emission in the northern rim. Fe Kalpha emission is particularly prominent there, and fits with thermal models indicate strongly oversolar Fe abundances. In a localized, outlying region in the northern rim, IMEs are less abundant than Fe, indicating that undiluted Fe-group elements (including 56Ni) with velocities larger than 18,000 km/s were ejected by this SN. But in the inner west rim, we find Si- and S-rich ejecta without any traces of Fe, so high-velocity products of O-burning were also ejected. G1.9+0.3 appears similar to energetic Type Ia SNe such as SN 2010jn where iron-group elements at such high free-expansion velocities have been recently detected. The pronounced asymmetry in the ejecta distribution and abundance inhomogeneities are best explained by a strongly asymmetric SN explosion, similar to those produced in some recent 3D delayed-detonation Type Ia models.
1305.7399v1
2013-05-31
Space Velocities of Southern Globular Clusters VII. NGC 6397, NGC 6626 (M 28) and NGC 6656 (M 22)
We have measured the absolute proper motions of globular clusters NGC 6397, NGC 6626 (M 22) and NGC 6656 (M 28) as part of our ongoing Southern Proper-Motion Program. The reference system is the ICRS via Hipparcos stars for these three low galactic latitude clusters. Formal errors range between ~0.3 and 0.7 mas/yr. Notable is the result for NGC 6397 which differs by 2.5 mas/yr from two HST determinations, while agreeing with previous ground-based ones. We determine orbits for all three clusters in an axisymmetric and barred model of the Galaxy and discuss these in the context of globular-cluster formation. M 22 is a well-known cluster with an iron abundance spread; such clusters are now believed to have formed in massive parent systems that can retain ejecta of core-collapsed SNe. We find that the five currently-accepted globular clusters with iron/calcium abundance spread show orbits unrelated to each other, thus suggesting at least five independent, massive progenitors that have contributed to the build-up of the Milky-Way halo.
1305.7431v1
2013-06-26
Are there missing bond paths in Trimethylenemethane-Iron-tri-carbonyl [(CO)3Fe-(C4H6)] complex?
In a recent paper [J. Organomet. Chem. (2013) doi: 10.1016 /j.jorganchem. 2013.03.047] analyzing the bonding mode of Trimethylenemethane (TMM) with some metal carbonyls, Mousavi and Frenking have declared the absence of bond paths, the so-called missed bond paths, between metal atoms and terminal carbon atoms in several complexes. In this communication, it is first demonstrated that the presupposition of the equivalence of a bond path and a chemical bond within the context of the quantum theory of atoms in molecules (QTAIM) is superficial and basically flawed which is not only against with the recent strict declaration on the contrary [R.F.W. Bader, J. Phys. Chem. A 113 (2009) 10396], but also in odd with the foundations of the QTAIM. Then, it is demonstrated that the so-called missed bond paths indeed appear in molecular graphs of some non-equilibrium geometries that are energetically quite accessible at room temperatures. To emphasize on the importance of this observation the term passionate neighbors is coined referring to the atomic basins that do not share an inter-atomic surface at the equilibrium geometry but are neighbors, share an inter-atomic surface, at non-equilibrium geometries accessible by nuclear vibrations. Using the delocalization index as well as other evidence from previous literature it is demonstrated that the QTAIM analysis is indeed compatible with the presence of chemical bonds between iron metal and terminal carbons in (CO)3Fe-TMM complex. Finally, some general discussions are done to unravel the delicate relationship between the QTAIM proposed concepts, e.g. bond paths and molecular graphs, and some orthodox concepts of chemistry, e.g. chemical bonds and chemical structures, emphasizing that there is no one-to-one relationship between these two categorizes.
1306.6350v2
2013-07-01
SWEET-Cat: A catalogue of parameters for Stars With ExoplanETs I. New atmospheric parameters and masses for 48 stars with planets
Due to the importance that the star-planet relation has to our understanding of the planet formation process, the precise determination of stellar parameters for the ever increasing number of discovered extra-solar planets is of great relevance. Furthermore, precise stellar parameters are needed to fully characterize the planet properties. It is thus important to continue the efforts to determine, in the most uniform way possible, the parameters for stars with planets as new discoveries are announced. In this paper we present new precise atmospheric parameters for a sample of 48 stars with planets. We then take the opportunity to present a new catalogue of stellar parameters for FGK and M stars with planets detected by radial velocity, transit, and astrometry programs. Stellar atmospheric parameters and masses for the 48 stars were derived assuming LTE and using high resolution and high signal-to-noise spectra. The methodology used is based on the measurement of equivalent widths for a list of iron lines and making use of iron ionization and excitation equilibrium principles. For the catalog, and whenever possible, we used parameters derived in previous works published by our team, using well defined methodologies for the derivation of stellar atmospheric parameters. This set of parameters amounts to over 65% of all planet host stars known, including more than 90% of all stars with planets discovered through radial velocity surveys. For the remaining targets, stellar parameters were collected from the literature.
1307.0354v1
2013-07-17
The role of the Gamma-Eddington ratio relation on the X-ray Baldwin effect in Active Galactic Nuclei
The X-ray Baldwin effect is the inverse correlation between the equivalent width (EW) of the narrow component of the iron Kalpha line and the X-ray luminosity of active galactic nuclei (AGN). A similar trend has also been observed between Fe Kalpha EW and the Eddington ratio (lambda_Edd). Using Chandra/HEG results of Shu et al. (2010) and bolometric corrections we study the relation between EW and the lambda_Edd, and find that log EW = (-0.13+/-0.03)log(lambda_Edd) + 1.47. We explore the role of the known positive correlation between the photon index of the primary X-ray continuum (Gamma) and lambda_Edd on the X-ray Baldwin effect. We simulate the iron Kalpha line emitted by populations of unabsorbed AGN considering 3 different geometries of the reflecting material: toroidal, spherical-toroidal and slab. We find that the Gamma-lambda_Edd correlation cannot account for the whole X-ray Baldwin effect, unless a strong dependence of Gamma on lambda_Edd, such as the one recently found by Risaliti et al. (2009) and Jin et al. (2012), is assumed. No clear correlation is found between EW and Gamma. We conclude that a good understanding of the slope of the Gamma-lambda_Edd relation is critical to assess whether the trend plays a leading or rather a marginal role in the X-ray Baldwin effect.
1307.4507v2
2013-07-23
Variable X-ray reflection from 1H~0419--577
We present detailed broadband X-ray spectral variability of a Seyfert 1 galaxy 1H~0419--577 based on an archival \suzaku{} observation in July 2007, a new \suzaku{} observation performed in January 2010 and the two latest \xmm{} observations from May 2010. All the observations show soft X-ray excess emission below $2\kev$ and both \suzaku{} observations show a hard X-ray excess emission above $10\kev$ when compared to a power-law. We have tested three physical models -- a complex partial covering absorption model, a blurred reflection model and an intrinsic disk Comptonization model. Among these three models, the blurred reflection model provided statistically the best-fit to all the four observations. Irrespective of the models used, the soft X-ray excess emission requires contribution from a thermal component similar to that expected from an accretion disk. The partial covering absorption model results in a nonphysical high temperature ($kT_{in} \sim 100\ev$) for an accretion disk and is also statistically the worst fit among the three models. 1H~0419--577 showed remarkable X-ray spectral variability. The soft X-ray excess and the power-law both became weaker in January 2010 as well as in May 2010. A moderately broad iron line, detected in July 2007, is absent in the January 2010 observation. Correlated variability of the soft X-ray excess and the iron $K\alpha$ line strongly suggest reflection origin for both the components. However, such spectral variability cannot be explained by the light bending model alone and requires changes in the accretion disk/corona geometry possibly arising from changes in the accretion rate.
1307.6223v1
2013-08-15
Structural and optical investigations of the iron-chalcogenide superconductor Fe$_{1.03}$Se$_{0.5}$Te$_{0.5}$ under high pressure
Iron-chalcogenide superconductor Fe$_{1.03}$Se$_{0.5}$Te$_{0.5}$ has been investigated under high pressure using synchrotron based x-ray diffraction and mid-infrared reflectance measurements at room temperature. Pressure dependence of the superconducting transition temperature (T$_c$) of the same sample has been determined by temperature-dependent resistance measurements up to 10 GPa. Although the high pressure orthorhombic phase ($\textit{Pbnm}$) starts emerging at 4 GPa, structural transition becomes clearly observable above 10 GPa. A strong correlation is observed between the Fe(Se,Te)$_{4}$ tetrahedral deformation in the tetragonal phase ($\textit{P4/nmm}$) and the sharp rise of T$_c$ up to $\sim$4 GPa, above which T$_c$ is found to be almost pressure independent at least up to 10 GPa. A subtle structural modification of the tetragonal phase is noticed above 10 GPa, suggesting a structural transition with possible Fe$^{2+}$ spin-state transition. The evolution with pressure of the optical conductivity shows that the Drude term increases systematically with pressure up to 5.4 GPa, indicating the evolution of the tetragonal phase towards a conventional metallic state. At further higher pressures the Drude term reduces drastically implying a poor metallic character of the high pressure orthorhombic phase. Our results suggest that occurrence of large onset T$_c$ above 4 GPa is due to a systematic increase of high pressure orthorhombic phase fraction.
1308.3367v1