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2016-04-07
The super-super exchange mechanism in iron-based antiperovskite chalco-halides
By using the first-principles electronic structure calculations, we have systematically studied the magnetism in three recently synthesized iron-based antiperovskite chalco-halides: Ba$_3$(FeS$_4$)Cl, Ba$_3$(FeS$_4$)Br, and Ba$_3$(FeSe$_4$)Br. These compounds consist of edge-sharing Ba$Q_6$ ($Q$=Cl or Br) octahedra intercalated with isolated Fe$X_4$ ($X$=S or Se) tetrahedra. We find that even though the shortest distances between the nearest-neighboring Fe atoms in these three compounds already exceed 6 \AA, much larger than the bond length of a chemical bonding, they all remarkably show antiferromagnetic (AFM) coupling along $b$ axis with very weak spin-spin correlation along $a$ axis. Our study shows that the mechanism underlying this novel AFM coupling is such a new type of exchange interaction between the nearest-neighboring Fe-based super-moments mediated by Ba cations, which we call the super-super exchange interaction, in which each magnetic Fe atom partially polarizes its four nearest-neighboring $X$ atoms to form a super-moment through $p$-$d$ orbital hybridization and the $X$ atoms in neighboring Fe$X_4$ tetrahedra along $b$ axis antiferromagnetically couple with each others through the intermediate Ba cations. Different from the conventional superexchange, here it is cations rather than anions that mediate two neighboring super-moments. According to the calculated strength of the AFM coupling, we predict that among these compounds the highest AFM phase transition temperature $T_N$ may reach 110 K in Ba$_3$(FeSe$_4$)Br, in comparison with the observed $T_N$s of 84 K in Ba$_3$(FeS$_4$)Br and 95 K in Ba$_3$(FeS$_4$)Cl.
1604.02044v1
2016-04-08
Detection of H2O and evidence for TiO/VO in an ultra hot exoplanet atmosphere
We present a primary transit observation for the ultra hot (Teq~2400K) gas giant expolanet WASP-121b, made using the Hubble Space Telescope Wide Field Camera 3 in spectroscopic mode across the 1.12-1.64 micron wavelength range. The 1.4 micron water absorption band is detected at high confidence (5.4 sigma) in the planetary atmosphere. We also reanalyze ground-based photometric lightcurves taken in the B, r', and z' filters. Significantly deeper transits are measured in these optical bandpasses relative to the near-infrared wavelengths. We conclude that scattering by high-altitude haze alone is unlikely to account for this difference, and instead interpret it as evidence for titanium oxide and vanadium oxide absorption. Enhanced opacity is also inferred across the 1.12-1.3 micron wavelength range, possibly due to iron hydride absorption. If confirmed, WASP-121b will be the first exoplanet with titanium oxide, vanadium oxide, and iron hydride detected in transmission. The latter are important species in M/L dwarfs, and their presence is likely to have a significant effect on the overall physics and chemistry of the atmosphere, including the production of a strong thermal inversion.
1604.02310v1
2016-04-12
A Statistical Study of the Average Iron Charge Distributions inside Magnetic Clouds for Solar Cycle 23
Magnetic clouds (MCs) are the interplanetary counterpart of coronal magnetic flux ropes. They can provide valuable information to reveal the flux rope characteristics at their eruption stage in the corona, which are unable to be explored in situ at present. In this paper, we make a comprehensive survey of the average iron charge state (<Q>Fe) distributions inside 96 MCs for solar cycle 23 using ACE (Advanced Composition Explorer) data. As the <Q>Fe in the solar wind are typically around 9+ to 11+, the Fe charge state is defined as high when the <Q>Fe is larger than 12+, which implies the existence of a considerable amount of Fe ions with high charge states (e.g., \geq 16+). The statistical results show that the <Q>Fe distributions of 92 (~ 96%) MCs can be classified into four groups with different characteristics. In group A (11 MCs), the <Q>Fe shows a bimodal distribution with both peaks higher than 12+. Group B (4 MCs) presents a unimodal distribution of <Q>Fe with its peak higher than 12+. In groups C (29 MCs) and D (48 MCs), the <Q>Fe remains higher and lower than 12+ throughout ACE passage through the MC, respectively. Possible explanations to these distributions are discussed.
1604.03205v1
2016-04-14
Study of Glass and Bakelite properties as electrodes in RPCs
India-based Neutrino Observatory (INO) collaboration is planning to build a magnetized Iron-CALorimeter detector (ICAL) for the study of atmospheric neutrinos. ICAL detector will be a stack of 151 layers of magnetized iron plates interleaved with Resistive Plate Chambers (RPCs) as active detector elements with a total mass of 50 kton. Resistive Plate Chambers are gaseous detectors made up of two parallel electrodes of high bulk resistivity like float glass and bakelite. These detectors are extensively used in several high energy physics experiments since 1980s because of high count rate, excellent time as well as spatial resolutions, simple to fabricate and operate. Due to detector aging issue, it is necessary to characterize electrode material so as to select appropriate electrode material before fabricating the detector. In the present studies, we measured bulk resistivity and surface current of glass as well as bakelite. Bulk resistivity of bakelite is ~ 100 times less than that of glass and surface current of bakelite is higher than that of glass. Also glass does not need any kind of surface treatment to achieve better surface uniformity. Therefore, glass electrodes are preferred over bakelite electrodes in most of the cases. Locally manufactured Asahi glass of ~2 mm thickness and bakelite sheets were tested during the studies as reported in this paper before the various stages of detector fabrication.
1604.04130v2
2016-04-25
Equilibrium and Sudden Events in Chemical Evolution
We present new analytic solutions for one-zone (fully mixed) chemical evolution models and explore their implications. In contrast to existing analytic models, we incorporate a realistic delay time distribution for Type Ia supernovae (SNIa) and can therefore track the separate evolution of $\alpha$-elements produced by core collapse supernovae (CCSNe) and iron peak elements synthesized in both CCSNe and SNIa. In generic cases, $\alpha$ and iron abundances evolve to an equilibrium at which element production is balanced by metal consumption and gas dilution, instead of continuing to increase over time. The equilibrium absolute abundances depend principally on supernova yields and the outflow mass loading parameter $\eta$, while the equilibrium abundance ratio [$\alpha$/Fe] depends mainly on yields and secondarily on star formation history. A stellar population can be metal-poor either because it has not yet evolved to equilibrium or because high outflow efficiency makes the equilibrium abundance itself low. Systems with ongoing gas accretion develop metallicity distribution functions (MDFs) that are sharply peaked, while "gas starved" systems with rapidly declining star formation have broadly peaked MDFs. A burst of star formation that consumes a significant fraction of a system's available gas can temporarily boost [$\alpha$/Fe] by 0.1-0.3 dex, a possible origin for rare, $\alpha$-enhanced stars with intermediate age or high metallicity. Other sudden transitions in system properties can produce surprising behavior, including backward evolution of a stellar population from high metallicity to low metallicity. An Appendix provides a user's guide for calculating enrichment histories, [$\alpha$/Fe] tracks, and MDFs for a wide variety of scenarios, including flexible forms of star formation history.
1604.07435v1
2016-05-01
Development of a method for measuring blood coagulation using superparamagnetic iron oxide nanoparticles and an alternating magnetic field
We developed a method for measuring blood coagulation using superparamagnetic iron oxide nanoparticles (SPIONs) and an alternating magnetic field (AMF). The 3rd and 5th harmonic signals from SPIONs mixed with blood induced by AMF were detected using a gradiometer coil. Blood coagulation was induced artificially by adding CaCl2 solution to whole blood of sheep at various temperatures and hematocrits. We calculated the coagulation rate (k) and normalized signal intensity at infinite time (Sinf) by fitting the time course of the normalized 3rd harmonic signal to S(t)=(1-Sinf)exp(-kt)+Sinf. The k values increased significantly with increasing temperature and decreased significantly with increasing hematocrit. The Sinf values decreased significantly with increasing temperature and tended to increase with increasing hematocrit. Blood anticoagulation was induced by adding heparin to the whole blood sampled from mice. There were significant differences in both the 3rd and 5th harmonic signals between groups with and without heparin at 25 min or more after adding heparin. We also calculated the 3rd and 5th harmonic signals for viscosities ranging from 0.001 to 1 kg/m/s, with an assumption that the magnetization and particle size distribution of SPIONs obey the Langevin theory of paramagnetism and log-normal distribution, respectively. The 3rd and 5th harmonic signals increased slowly with increasing viscosity and had peaks at approximately 0.015 and 0.025 kg/m/s, respectively. After these peaks, they decreased monotonically with increasing viscosity. These results confirm the rationale of our method. In conclusion, our method will be useful for measuring blood coagulation and anticoagulation and for studying their processes.
1605.00255v2
2016-06-02
Orbital selective spin excitations and their impact on superconductivity of LiFe1-xCoxAs
We use neutron scattering to study spin excitations in single crystals of LiFe$_{0.88}$Co$_{0.12}$As, which is located near the boundary of the superconducting phase of LiFe$_{1-x}$Co$_{x}$As and exhibits non-Fermi-liquid behavior indicative of a quantum critical point. By comparing spin excitations of LiFe$_{0.88}$Co$_{0.12}$As with a combined density functional theory (DFT) and dynamical mean field theory (DMFT) calculation, we conclude that wave-vector correlated low energy spin excitations are mostly from the $d_{xy}$ orbitals, while high-energy spin excitations arise from the $d_{yz}$ and $d_{xz}$ orbitals. Unlike most iron pnictides, the strong orbital selective spin excitations in LiFeAs family cannot be described by anisotropic Heisenberg Hamiltonian. While the evolution of low-energy spin excitations of LiFe$_{1-x}$Co$_x$As are consistent with electron-hole Fermi surface nesting condition for the $d_{xy}$ orbital, the reduced superconductivity in LiFe$_{0.88}$Co$_{0.12}$As suggests that Fermi surface nesting conditions for the $d_{yz}$ and $d_{xz}$ orbitals are also important for superconductivity in iron pnictides.
1606.00727v1
2016-06-03
Swift J174540.7-290015: a new accreting binary in the Galactic Center
We report on the identification of the new Galactic Center (GC) transient Swift J174540.7-290015 as a likely low mass X-ray binary (LMXB) located at only 16 arcsec from Sgr A*. This transient was detected on 2016 February 6th during the Swift GC monitoring, and it showed long-term spectral variations compatible with a hard to soft state transition. We observed the field with XMM-Newton on February 26th for 35 ks, detecting the source in the soft state, characterised by a low level of variability and a soft X-ray thermal spectrum with a high energy tail (detected by INTEGRAL up to ~50 keV), typical of either accreting neutron stars or black holes. We observed: i) a high column density of neutral absorbing material, suggesting that Swift J174540.7-290015 is located near or beyond the GC and; ii) a sub-Solar Iron abundance, therefore we argue that Iron is depleted into dust grains. The lack of detection of FeK absorption lines, eclipses or dipping suggests that the accretion disc is observed at a low inclination angle. Radio (VLA) observations did not detect any radio counterpart to Swift J174540.7-290015. No evidence for X-ray or radio periodicity is found. The location of the transient was observed also in the near-IR with GROND at MPG/ESO La Silla 2.2m telescope and VLT/NaCo pre- and post-outburst. Within the Chandra error region we find multiple objects that display no significant variations.
1606.01138v1
2016-06-17
Time dependence of Fe/O ratio within a 3D Solar Energetic Particle propagation model including drift
Context. The intensity profiles of iron and oxygen in Solar Energetic Particle (SEP) events often display differences that result in a decreasing Fe/O ratio over time. The physical mechanisms behind this behaviour are not fully understood, but these observational signatures provide important tests of physical modelling efforts. Aims. In this paper we study the propagation of iron and oxygen SEP ions using a 3D model of propagation which includes the effect of guiding centre drift in a Parker spiral magnetic field. We derive time intensity profiles for a variety of observer locations and study the temporal evolution of the Fe/O ratio. Methods. We use a 3D full orbit test particle model which includes scattering. The configuration of the interplanetary magnetic field is a unipolar Parker spiral. Particles are released instantaneously from a compact region at 2 solar radii and allowed to propagate in 3D. Results. Both Fe and O experience significant transport across the magnetic field due to gradient and curvature drifts. We find that Fe ions drift more than O ions due to their larger mass-to-charge ratio, so that an observer that is not magnetically well connected to the source region will observe Fe arriving before O, for particles within the same range in energy per nucleon. As a result, for the majority of observer locations, the Fe/O ratio displays a decrease in time. Conclusions. We conclude that propagation effects associated with drifts produce a decay over time of the Fe/O ratio, qualitatively reproducing that observed in SEP event profiles.
1606.05612v2
2016-07-05
Heavy Electron doping-induced antiferromagnetic phase as the parent for iron-oxypnictide superconductor LaFeAsO1-xHx
We perform transport measurements and band structure calculations of electron-doped LaFeAsO1-xHx over a wide range of x from 0.01 to 0.66. The T^2 and sqrt(T) dependency of the resistivity are observed at x ~ 0.17 and 0.41, respectively. The sign change of RH without opening of the spin-density-wave gap for 0.45 < x < 0.58 and T < TN as well as the calculated non-nested Fermi surface at x = 0.5 indicate the more localized nature of the AF2 as compared to spin density wave phase at non-doped sample. Considering the results from band calculations and the finite size of Hund' s rule coupling, the change of the normal conducting state with x is reasonably explained by a strong depression of the coherent scale owing to the increased effective Coulomb repulsion in the narrow anti-bonding 3dxy band that approaches the half-filled regime. The following transition from the paramagnet to AF2 is understood as the quenching or ordering of the less-screened spins with a large entropy at low temperature. These results suggest that the normal conducting properties over a wide doping range for the LaFeAsO1-xHx are strongly influenced by the local spins in the incoherent region. Thus, we conclude that the parent phase in LaFeAsO1-xHx is not the spin-density wave but the AF2, which may be primarily responsible for the singular superconducting properties of the 1111 type compared with other iron pnictides.
1607.01238v1
2016-07-05
Superconductivity-enhanced Nematicity and '$s+d$' Gap Symmetry in Fe(Se$_{1-x}$S$_x$)
Superconducting iron chalcogenide FeSe has the simplest crystal structure among all the Fe-based superconductors. Unlike other iron pnictides, FeSe exhibits no long range magnetic order accompanying the tetragonal-to-orthorhombic structural distortion, which raises the fundamental question about the role of magnetism and its associated spin fluctuations in mediating both nematicity and superconductivity. The extreme sensitivity of FeSe to external pressure suggests that chemical pressure, induced by substitution of Se by the smaller ion S, could also a be good tuning parameter to further study the coupling between superconductivity and nematicity and to obtain information on both the Fermi-surface changes and the symmetry of the superconducting state. Here we study the thermodynamic properties of Fe(Se$_{1-x}$S$_{x}$) for 3 compositions, $x=0$, 0.08 and 0.15, using heat-capacity and thermal-expansion measurements. With increasing S content we observe a significant reduction of the tetragonal-to-orthorhombic transition temperature T$_{s}$. However, this suppression of T$_{s}$ is counterintuitively accompanied by an enhancement of the orthorhombic distortion $\delta$ below T$_c$, which clearly indicates that superconductivity favors the nematic state. In parallel, the superconducting transition temperature T$_{c}$ is sizeably enhanced, whereas the increase of the Sommerfeld coefficient $\gamma_{n}$ is quite moderate. In the T$\to$ 0 limit, an unusually large residual density of states is found for $x>0$ indicative of significant substitution-induced disorder. We discuss these observations in the context of $s+d$ superconducting-state symmetry.
1607.01288v2
2016-07-07
Deciphering chemical order/disorder and material properties at the single-atom level
Correlating 3D arrangements of atoms and defects with material properties and functionality forms the core of several scientific disciplines. Here, we determined the 3D coordinates of 6,569 iron and 16,627 platinum atoms in a model iron-platinum nanoparticle system to correlate 3D atomic arrangements and chemical order/disorder with material properties at the single-atom level. We identified rich structural variety and chemical order/disorder including 3D atomic composition, grain boundaries, anti-phase boundaries, anti-site point defects and swap defects. We show for the first time that experimentally measured 3D atomic coordinates and chemical species with 22 pm precision can be used as direct input for first-principles calculations of material properties such as atomic magnetic moments and local magnetocrystalline anisotropy. This work not only opens the door to determining 3D atomic arrangements and chemical order/disorder of a wide range of nanostructured materials with high precision, but also will transform our understanding of structure-property relationships at the most fundamental level.
1607.02051v1
2016-07-09
Theoretical modelling of the AGN iron-line vs continuum time-lags in the lamp-post geometry
Context: Theoretical modelling of time-lags between variations in the Fe K$\alpha$ emission and the X-ray continuum might shed light on the physics and geometry of the X-ray emitting region in active galaxies (AGN) and X-ray binaries. We here present the results from a systematic analysis of time-lags between variations in two energy bands ($5-7$ vs $2-4\,\mathrm{keV}$) for seven X-ray bright and variable AGN. Aims: We estimate time-lags as accurately as possible and fit them with theoretical models in the context of the lamp-post geometry. We also constrain the geometry of the X-ray emitting region in AGN. Methods: We used all available archival \textit{XMM-Newton} data for the sources in our sample and extracted light curves in the $5-7$ and $2-4\,\mathrm{keV}$ energy bands. We used these light curves and applied a thoroughly tested (through extensive numerical simulations) recipe to estimate time-lags that have minimal bias, approximately follow a Gaussian distribution, and have known errors. Using traditional $\chi^2$ minimisation techniques, we then fitted the observed time-lags with two different models: a phenomenological model where the time-lags have a power-law dependence on frequency, and a physical model, using the reverberation time-lags expected in the lamp-post geometry. The latter were computed assuming a point-like primary X-ray source above a black hole surrounded by a neutral and prograde accretion disc with solar iron abundance. We took all relativistic effects into account for various X-ray source heights, inclination angles, and black hole spin values.
1607.02625v2
2016-07-09
On the reality of broad iron L lines from the narrow line Seyfert 1 galaxies 1H0707-495 and IRAS 13224-3809
We performed time resolved spectroscopy of 1H0707-495 and IRAS 13224-3809 using long XMM-Newton observations. These are strongly variable narrow line Seyfert 1 galaxies and show broad features around 1 keV that has been interpreted as relativistically broad Fe L$\alpha$ lines. Such features are not clearly observed in other AGN despite sometimes having high iron abundance required by the best fitted blurred reflection models. Given the importance of these lines, we explore the possibility if rapid variability of spectral parameters may introduce broad bumps/dips artificially in the time averaged spectrum, which may then be mistaken as broadened lines. We tested this hypothesis by performing time resolved spectroscopy using long (> 100 ks) XMM-Newton observations and by dividing it into segments with typical exposure of few ks. We extracted spectra from each such segment and modelled using a two component phenomenological model consisting of a power law to represent hard component and a black body to represent the soft emission. As expected both the sources showed variations in the spectral parameters. Using these variation trends, we simulated model spectra for each segment and then co-added to get a combined simulated spectrum. In the simulated spectra, we found no broad features below 1 keV and in particular no deviation near 0.9 keV as seen in the real average spectra. This implies that the broad Fe L? line that is seen in the spectra of these sources is not an artifact of the variation of spectral components and hence providing evidence that the line is indeed genuine.
1607.02635v1
2016-07-11
Magnetotransport of multiple-band nearly-antiferromagnetic metals due to "hot-spot" scattering
Multiple-band electronic structure and proximity to antiferromagnetic (AF) instability are the key properties of iron-based superconductors. We explore the influence of scattering by the AF spin fluctuations on transport of multiple-band metals above the magnetic transition. A salient feature of scattering on the AF fluctuations is that it is strongly enhanced at the Fermi surface locations where the nesting is perfect ("hot spots" or "hot lines"). We review derivation of the collision integral for the Boltzmann equation due to AF-fluctuations scattering. In the paramagnetic state, the enhanced scattering rate near the hot lines leads to anomalous behavior of electronic transport in magnetic field. We explore this behavior by analytically solving Boltzmann transport equation with approximate transition rates. This approach accounts for return scattering events and is more accurate than the relaxation-time approximation. The magnetic-field dependences are characterized by two very different field scales, the lower scale is set by the hot-spot width and the higher scale is set by the total scattering amplitude. A conventional magnetotransport behavior is limited to magnetic fields below the lower scale. In the wide range in between these two scales the longitudinal conductivity has linear dependence on the magnetic field and the Hall conductivity has quadratic dependence. The linear dependence of the diagonal component reflects growth of the Fermi-surface area affected by hot spots proportional to the magnetic field. We discuss applicability of this theoretical framework for describing of anomalous magnetotransport properties in different iron pnictides and selenides in the paramagnetic state.
1607.03194v2
2016-07-19
Sensitivity of the Fe K-alpha Compton shoulder to the geometry and variability of the X-ray illumination of cosmic objects
In an X-ray reflection spectrum, a tail-like spectral feature generated via Compton down-scattering, known as a Compton shoulder (CS), appears at the low-energy side of the iron K$\alpha$ line. Despite its great diagnostic potential, its use as a spectral probe of the reflector has been seriously limited due to observational difficulties and modelling complexities. We revisit the basic nature of the CS by systematic investigation into its dependence on spatial and temporal parameters. The calculations are performed by Monte-Carlo simulations for sphere and slab geometries. The dependence is obtained in a two-dimensional space of column density and metal abundance, demonstrating that the CS solves parameter degeneration between them which was seen in conventional spectral analysis using photoelectric absorption and fluorescence lines. Unlike the iron line, the CS does not suffer from any observational dependence on the spectral hardness. The CS profile is highly dependent on the inclination angle of the slab geometry unless the slab is Compton-thick, and the time evolution of the CS is shown to be useful to constrain temporal information on the source if the intrinsic radiation is variable. We also discuss how atomic binding of the scattering electrons in cold matter blurs the CS profile, finding that the effect is practically similar to thermal broadening in a plasma with a moderate temperature of $\sim$5 eV. Spectral diagnostics using the CS is demonstrated with grating data of X-ray binary GX 301$-$2, and will be available in future with high-resolution spectra of active galactic nuclei obtained by microcalorimeters.
1607.05385v1
2016-07-19
Highly mobile carriers in orthorhombic phases of iron-based superconductors FeSe${}_{1-x}$S${}_{x}$
The field and temperature dependencies of the longitudinal and Hall resistivity have been measured for FeSe${}_{1-x}$S${}_{x}$ (x=0.04, 0.09 and 0.19) single crystals. The sample FeSe${}_{0.81}$S${}_{0.19}$ does not show a transition to an orthorhombic phase and exhibits at low temperatures the transport properties quite different from those of orthorhombic samples. The behavior of FeSe${}_{0.81}$S${}_{0.19}$ is well described by the simple two band model with comparable values of hole and electron mobility. In particular, at low temperatures the transverse resistance shows a linear field dependence, the magnetoresistance follow a quadratic field dependence and obeys to Kohler's rule. In contrast, Kohler's rule is strongly violated for samples having an orthorhombic low temperature structure. However, the transport properties of the orthorhombic samples can be satisfactory described by the three band model with the pair of almost equivalent to the tetragonal sample hole and electron bands, supplemented with the highly mobile electron band which has two order smaller carrier number. Therefore, the peculiarity of the low temperature transport properties of the orthorhombic Fe(SeS) samples, as probably of many other orthorhombic iron superconductors, is due to the presence of a small number of highly mobile carriers which originate from the local regions of the Fermi surface, presumably, nearby the Van Hove singularity points.
1607.05669v2
2016-08-02
Correlation of Fe-based Superconductivity and Electron-Phonon Coupling in an FeAs/Oxide Heterostructure
Interfacial phonons between iron-based superconductors (FeSCs) and perovskite substrates have received considerable attention due to the possibility of enhancing preexisting superconductivity. Using scanning tunneling spectroscopy, we studied the correlation between superconductivity and e-ph interaction with interfacial-phonons in an iron-based superconductor Sr$_2$VO$_3$FeAs ($T_c \approx$ 33 K) made of alternating FeSC and oxide layers. The quasiparticle interference measurement over regions with systematically different average superconducting gaps due to the e-ph coupling locally modulated by O vacancies in VO$_2$ layer, and supporting self-consistent momentum-dependent Eliashberg calculations provide a unique real-space evidence of the forward-scattering interfacial phonon contribution to the total superconducting pairing.
1608.00886v4
2016-08-03
Structure of spin excitations in heavily electron-doped Li0.8Fe0.2ODFeSe superconductors
Heavily electron-doped iron-selenide (HEDIS) high-transition-temperature (high-$T_{\rm{c}}$) superconductors, which have no hole Fermi pockets, but have a notably high $T_{\rm{c}}$, have challenged the prevailing $s$$_\pm$ pairing scenario originally proposed for iron pnictides containing both electron and hole pockets. The microscopic mechanism underlying the enhanced superconductivity in HEDIS remains unclear. Here, we used neutron scattering to study the spin excitations of the HEDIS material Li$_{0.8}$Fe$_{0.2}$ODFeSe ($T_{\rm{c}}$ = 41 K). Our data revealed nearly ring-shaped magnetic resonant excitations surrounding ($\pi$, $\pi$) at $\sim$ 21 meV. As the energy increased, the spin excitations assumed a diamond shape, and they dispersed outward until the energy reached $\sim$ 60 meV and then inward at higher energies. The observed energy-dependent momentum structure and twisted dispersion of spin excitations near ($\pi$, $\pi$) are analogous to those of hole-doped cuprates in several aspects, thus implying that such spin excitations are essential for the remarkably high $T_{\rm{c}}$ in these materials.
1608.01204v2
2016-08-04
Isotopic enrichment of forming planetary systems from supernova pollution
Heating by short-lived radioisotopes (SLRs) such as aluminum-26 and iron-60 fundamentally shaped the thermal history and interior structure of Solar System planetesimals during the early stages of planetary formation. The subsequent thermo-mechanical evolution, such as internal differentiation or rapid volatile degassing, yields important implications for the final structure, composition and evolution of terrestrial planets. SLR-driven heating in the Solar System is sensitive to the absolute abundance and homogeneity of SLRs within the protoplanetary disk present during the condensation of the first solids. In order to explain the diverse compositions found for extrasolar planets, it is important to understand the distribution of SLRs in active planet formation regions (star clusters) during their first few Myr of evolution. By constraining the range of possible effects, we show how the imprint of SLRs can be extrapolated to exoplanetary systems and derive statistical predictions for the distribution of aluminum-26 and iron-60 based on N-body simulations of typical to large clusters (1000-10000 stars) with a range of initial conditions. We quantify the pollution of protoplanetary disks by supernova ejecta and show that the likelihood of enrichment levels similar to or higher than the Solar System can vary considerably, depending on the cluster morphology. Furthermore, many enriched systems show an excess in radiogenic heating compared to Solar System levels, which implies that the formation and evolution of planetesimals could vary significantly depending on the birth environment of their host stars.
1608.01435v1
2016-08-29
Universal Lower Limit on Vortex Creep in Superconductors
Superconductors are excellent testbeds for studying vortices, topological excitations that also appear in superfluids, liquid crystals, and Bose-Einstein condensates. Vortex motion can be disruptive; it can cause phase transitions, glitches in pulsars, and losses in superconducting microwave circuits, and it limits the current carrying capacity of superconductors. Understanding vortex dynamics is therefore of fundamental and technological importance, and the competition between the effects of thermal energy and energy barriers defined by material disorder is not completely understood. In particular, early measurements of thermally-activated vortex motion (creep) in iron-based superconductors unveiled fast rates (S) comparable to measurements of YBa2Cu3O7 (YBCO). This was puzzling because S is thought to somehow positively correlate with the Ginzburg number (Gi), and Gi is orders of magnitude lower in most iron-based superconductors than in YBCO. Here, we report very slow creep in BaFe2(As0.67P0.33)2 films, and propose that there is a universal minimum realizable (where Tc is the superconducting transition temperature) that has been achieved in our films, few other materials, and violated by none. This limitation provides new clues on how to design materials with slow creep and helps elucidate open questions regarding the interplay between system-specific length scales and vortex dynamics.
1608.08092v2
2016-09-01
Influence of interstitial Fe to the phase diagram of Fe$_{1+y}$Te$_{1-x}$Se$_x$ single crystals
Superconductivity (SC) with the suppression of long-range antiferromagnetic (AFM) order is observed in the parent compounds of both iron-based and cuprate superconductors. The AFM wave vectors are bicollinear ($\pi$, 0) in the parent compound FeTe different from the collinear AFM order ($\pi$, $\pi$) in most iron pnictides. Study of the phase diagram of Fe$_{1+y}$Te$_{1-x}$Se$_x$ is the most direct way to investigate the competition between bicollinear AFM and SC. However, presence of interstitial Fe affects both magnetism and SC of Fe$_{1+y}$Te$_{1-x}$Se$_x$, which hinders the establishment of the real phase diagram. Here, we report the comparison of doping-temperature ($x$-$T$) phase diagrams for Fe$_{1+y}$Te$_{1-x}$Se$_x$ (0 $\leq$ $x$ $\leq$ 0.43) single crystals before and after removing interstitial Fe. Without interstitial Fe, the AFM state survives only for $x$ $<$ 0.05, and bulk SC emerges from $x$ = 0.05, and does not coexist with the AFM state. The previously reported spin glass state, and the coexistence of AFM and SC may be originated from the effect of the interstitial Fe. The phase diagram of Fe$_{1+y}$Te$_{1-x}$Se$_x$ is found to be similar to the case of the "1111" system such as LaFeAsO$_{1-x}$F$_x$, and is different from that of the "122" system.
1609.00105v1
2016-09-07
Efficiency of Planetesimal Ablation in Giant Planetary Envelopes
Observations of exoplanetary spectra are leading to unprecedented constraints on their atmospheric elemental abundances, particularly O/H, C/H, and C/O ratios. Recent studies suggest that elemental ratios could provide important constraints on formation and migration mechanisms of giant exoplanets. A fundamental assumption in such studies is that the chemical composition of the planetary envelope represents the sum-total of compositions of the accreted gas and solids during the formation history of the planet. We investigate the efficiency with which accreted planetesimals ablate in a giant planetary envelope thereby contributing to its composition rather than sinking to the core. From considerations of aerodynamic drag causing `frictional ablation' and the envelope temperature structure causing `thermal ablation', we compute mass ablations for impacting planetesimals of radii 30 m to 1 km for different compositions (ice to iron) and a wide range of velocities and impact angles, assuming spherical symmetry. Icy impactors are fully ablated in the outer envelope for a wide range of parameters. Even for Fe impactors substantial ablation occurs in the envelope for a wide range of sizes and velocities. For example, iron impactors of sizes below ~0.5 km and velocities above ~30 km/s are found to ablate by ~60-80% within the outer envelope at pressures below 10^3 bar due to frictional ablation alone. For deeper pressures (~10^7 bar), substantial ablation happens over a wider range of parameters. Therefore, our exploratory study suggests that atmospheric abundances of volatile elements in giant planets reflect their accretion history during formation.
1609.02143v1
2016-09-18
Spintronics Detection of Interfacial Magnetic Switching in a Paramagnetic Tris(8-hydroxyquinoline)iron(III) Thin Film
Organic semiconductors find increasing importance in spin transport devices due to the modulation and control of their properties through chemical synthetic versatility. The organic materials are used as interlayers between two ferromagnet (FM) electrodes in organic spin valves (OSV), as well as for magnetic spin manipulation of metal-organic complexes at the molecular level. In the latter, specifically, the substrate-induced magnetic switching in a paramagnetic molecule has been evoked extensively, but studied by delicate surface spectroscopies. Here we present evidence of the substantial magnetic switching in a nanosized thin film of the paramagnetic molecule, tris(8-hydroxyquinoline)iron(III) (Feq3) deposited on a FM substrate, using the magnetoresistance response of electrical spin-injection in an OSV structure, and the inverse-spin-Hall effect induced by state-of-art pulsed microwave spin-pumping. We show that interfacial spin control at the molecular level may lead to a macroscopic organic spin transport device, thus, bridging the gap between organic spintronics and molecular spintronics.
1609.05421v1
2016-10-04
Tomographic reflection modelling of quasi-periodic oscillations in the black hole binary H 1743-322
Accreting stellar mass black holes (BHs) routinely exhibit Type-C quasi-periodic oscillations (QPOs). These are often interpreted as Lense-Thirring precession of the inner accretion flow, a relativistic effect whereby the spin of the BH distorts the surrounding space-time, inducing nodal precession. The best evidence for the precession model is the recent discovery, using a long joint XMM-Newton and NuSTAR observation of H 1743-322, that the centroid energy of the iron fluorescence line changes systematically with QPO phase. This was interpreted as the inner flow illuminating different azimuths of the accretion disc as it precesses, giving rise to a blue/red shifted iron line when the approaching/receding disc material is illuminated. Here, we develop a physical model for this interpretation, including a self-consistent reflection continuum, and fit this to the same H 1743-322 data. We use an analytic function to parameterise the asymmetric illumination pattern on the disc surface that would result from inner flow precession, and find that the data are well described if two bright patches rotate about the disc surface. This model is preferred to alternatives considering an oscillating disc ionisation parameter, disc inner radius and radial emissivity profile. We find that the reflection fraction varies with QPO phase (3.5 sigma), adding to the now formidable body of evidence that Type-C QPOs are a geometric effect. This is the first example of tomographic QPO modelling, initiating a powerful new technique that utilizes QPOs in order to map the dynamics of accreting material close to the BH.
1610.00948v1
2016-09-29
Thin layered drawing media probed by THz time-domain spectroscopy
Dry and wet drawing materials were investigated by THz time-domain spectroscopy in transmission mode. Carbon-based and iron-gall inks have been studied, some prepared following ancient recipes and others using current synthetic materials; a commercial ink was studied as well. We measured the THz signals on thin film of liquid inks deposited on polyethylene pellicles, comparing the results with the thick pellets of dried inks blended with polyethylene powder. This study required the implementation of a new experimental method and data analysis procedure able to provide a reliable extraction of the material transmission parameters from a structured sample composed of thin layers, down to thickness of few tens of micrometers. THz measurements on thin ink layers enabled the determination of both the absorption and the refractive index in an absolute scale in the 0.1 - 3 THz range, as well as the layer thickness. THz spectroscopic features of a paper sheet dyed by one of the iron-gall inks were also investigated. Our results showed that THz time-domain spectroscopy enables to discriminate the various inks on different supports, including the application on paper, together with a proper determination of the absorption coefficients and indices of refraction.
1610.01025v1
2016-10-31
Chromium analogues of Iron-based superconductors
We theoretically investigate the $d^4$ (Cr$^{2+}$) compound BaCr$_2$As$_2$ and show that, despite non-negligible differences in the electronic structure, its many-body physics mirrors that of BaFe$_2$As$_2$, which has instead a $d^6$ (Fe$^{2+}$) configuration. This reflects a symmetry of the electron correlation effects around the half-filled $d^5$ Mott insulating state. The experimentally known metallic antiferromagnetic phase is correctly modeled by dynamical mean-field theory, and for realistic values of the interaction it shows a moderate mass enhancement of order $\sim$2. This value decreases if the ordered moment grows as a result of a stronger interaction. The antiferromagnetic phase diagram for this $d^4$ shows similarities with that calculated for the $d^6$ systems. Correspondingly, in the paramagnetic phase the influence of the half-filled Mott insulator shows up as a crossover from a weakly correlated to an orbitally differentiated "Hund's metal" phase which reflects an analogous phenomenon in $d^6$ iron compounds including a strong enhancement of the compressibility in a zone just inside the frontier between the normal and the Hund's metal. The experimental evidence and our theoretical description place BaCr$_2$As$_2$ at interaction strength slightly below the crossover which implies that negative pressures and/or electron doping (e.g. Cr $\rightarrow$ Mn,Fe or Ba $\rightarrow$ Sc,Y,La) might strongly enhance the compressibility, thereby possibly inducing a pairing instability in this non-superconducting compound.
1610.10054v1
2016-11-17
Deformation behaviour of body centered cubic iron nanopillars containing coherent twin boundaries
Molecular dynamics simulations were performed to understand the role of twin boundaries on deformation behaviour of body-centred cubic (BCC) iron (Fe) nanopillars. The twin boundaries varying from one to five providing twin boundary spacing in the range 8.5 - 2.8 nm were introduced perpendicular to the loading direction. The simulation results indicated that the twin boundaries in BCC Fe play a contrasting role during deformation under tensile and compressive loadings. During tensile deformation, a large reduction in yield stress was observed in twinned nanopillars compared to perfect nanopillar. However, the yield stress exhibited only marginal variation with respect to twin boundary spacing. On the contrary, a decrease in yield stress with increase in twin boundary spacing was obtained during compressive deformation. This contrasting behaviour originates from difference in operating mechanisms during yielding and subsequent plastic deformation. It has been observed that the deformation under tensile loading was dominated mainly by twin growth mechanism, due to which the twin boundaries offers a negligible resistance to slip of twinning partials. This is reflected in the negligible variation of yield stress as a function of twin boundary spacing. On the other hand, the deformation was dominated by nucleation and slip of full dislocations under compressive loading. The twin boundaries offer a strong repulsive force on full dislocations resulting in the yield stress dependence on twin boundary spacing. Further, it has been observed that the curved twin boundary can acts as a source for full dislocation. The occurrence of twin-twin interaction during tensile deformation and dislocation-twin interaction during compressive deformation were presented and discussed.
1611.05575v1
2016-12-16
Pressure-Induced Metallization in Iron-Based Ladder Compounds Ba$_{1-x}$Cs$_x$Fe$_2$Se$_3$
Electrical resistivity measurements have been performed on the iron-based ladder compounds Ba$_{1-x}$Cs$_x$Fe$_2$Se$_3$ ($x$ = 0, 0.25, 0.65, and 1) under high pressure. A cubic anvil press was used up to 8.0 GPa, whereas further higher pressure was applied using a diamond anvil cell up to 30.0 GPa. Metallic behavior of the electrical conductivity was confirmed in the $x$ = 0.25 and 0.65 samples for pressures greater than 11.3 and 14.4 GPa, respectively, with the low-temperature $\log T$ upturn being consistent with weak localization of 2D electrons due to random potential. At pressures higher than 23.8 GPa, three-dimensional Fermi-liquid-like behavior was observed in the latter sample. No metallic conductivity was observed in the parent compounds BaFe$_2$Se$_3$ ($x $ = 0) up to 30.0 GPa and CsFe$_2$Se$_3$ ($x$ = 1) up to 17.0 GPa. The present results indicate that the origins of the insulating ground states in the parent and intermediate compounds are intrinsically different; the former is a Mott insulator, whereas the latter is an Anderson insulator owing to the random substitution of Cs for Ba.
1612.05394v1
2016-12-29
Molecular nucleation theory of dust formation in core-collapse supernovae applied to SN 1987A
We model dust formation in the core collapse supernova explosion SN 1987A by treating the gas-phase formation of dust grain nuclei as a chemical process. To compute the synthesis of fourteen species of grains we integrate a non-equilibrium network of nucleating and related chemical reactions and follow the growth of the nuclei into grains via accretion and coagulation. The effects of the radioactive cobalt, titanium, and sodium on the thermodynamics and chemistry of the ejecta are taken into account. The grain temperature, which we allow to differ from the gas temperature, affects the surface-tension-corrected evaporation rate. We also account for He$^+$, Ne$^+$, Ar$^+$, and O weathering. We combine our dust synthesis model with a crude prescription for anisotropic radioactive nickel dredge-up into the core ejecta, the so-called `nickel bubbles', to compute the total dust mass and molecular-species-specific grain size distribution. The total mass varies between $0.41\,M_\odot$ and $0.73\,M_\odot$, depending on the bubble shell density contrast. In the decreasing order of abundance, the grain species produced are: magnesia, silicon, forsterite, iron sulfide, carbon, silicon dioxide, alumina, and iron. The combined grain size distribution is a power law $dN/da\propto a^{-4.39}$. Early ejecta compaction by expanding radioactive nickel bubbles strongly enhances dust synthesis. This underscores the need for improved understanding of hydrodynamic transport and mixing over the entire pre-homologous expansion.
1612.09013v2
2017-01-11
Antiferromagnetic structure and electronic properties of BaCr2As2 and BaCrFeAs2
The chromium arsenides BaCr2As2 and BaCrFeAs2 with ThCr2Si2 type structure (space group I4/mmm; also adopted by '122' iron arsenide superconductors) have been suggested as mother compounds for possible new superconductors. DFT-based calculations of the electronic structure evidence metallic antiferromagnetic ground states for both compounds. By powder neutron diffraction we confirm for BaCr2As2 a robust ordering in the antiferromagnetic G-type structure at T_N = 580 K with mu_Cr = 1.9 mu_B at T = 2K. Anomalies in the lattice parameters point to magneto-structural coupling effects. In BaCrFeAs2 the Cr and Fe atoms randomly occupy the transition-metal site and G-type order is found below 265 K with mu_Cr/Fe = 1.1 mu_B. 57Fe Moessbauer spectroscopy demonstrates that only a small ordered moment is associated with the Fe atoms, in agreement with electronic structure calculations with mu_Fe ~ 0. The temperature dependence of the hyperfine field does not follow that of the total moments. Both compounds are metallic but show large enhancements of the linear specific heat coefficient gamma with respect to the band structure values. The metallic state and the electrical transport in BaCrFeAs2 is dominated by the atomic disorder of Cr and Fe and partial magnetic disorder of Fe. Our results indicate that Neel-type order is unfavorable for the Fe moments and thus it is destabilized with increasing iron content.
1701.03127v1
2017-01-16
Comprehensive Timing and X-ray Spectral Analysis of GX 1+4
We present analysis of RXTE--PCA observations of GX 1+4 between March 3, 2001 and January 31, 2003 together with the CGRO--BATSE X-ray flux and frequency derivative time series between 1991 and 1999. From the timing analysis of RXTE-PCA observations, we are able to phase connect pulse arrival times of the source within two different time intervals and obtain corresponding timing solutions. Using these pulse arrival times, we contribute to long term pulse frequency history of the source. We look for episodic correlations and anti-correlations between torque and X-ray luminosity using CGRO--BATSE X-ray flux and frequency derivative time series and find that correlation state of GX 1+4 seems to change on $\sim$ 100-200 days long intervals. We estimate torque noise of the source and observe flickering noise ($f^{-1}$). We achieve to measure the longest observed timescale for a noise process among accretion powered X-ray pulsars by extending the noise estimate for a time scale ranging from 31 days to 44 years. Spectral analysis of individual RXTE-PCA observations indicates a significant correlation between iron line flux and unabsorbed X-ray flux. Pulse phase resolved spectra of the source indicate a broadening of iron line complex at the bin corresponding to the pulse minimum.
1701.04328v2
2017-01-17
Phase diagram and neutron spin resonance of superconducting NaFe$_{1-x}$Cu$_x$As
We use transport and neutron scattering to study the electronic phase diagram and spin excitations of NaFe$_{1-x}$Cu$_x$As single crystals. Similar to Co- and Ni-doped NaFeAs, a bulk superconducting phase appears near $x\approx2\%$ with the suppression of stripe-type magnetic order in NaFeAs. Upon further increasing Cu concentration the system becomes insulating, culminating in an antiferromagnetically ordered insulating phase near $x\approx 50\%$. Using transport measurements, we demonstrate that the resistivity in NaFe$_{1-x}$Cu$_x$As exhibits non-Fermi-liquid behavior near $x\approx1.8\%$. Our inelastic neutron scattering experiments reveal a single neutron spin resonance mode exhibiting weak dispersion along $c$-axis in NaFe$_{0.98}$Cu$_{0.02}$As. The resonance is high in energy relative to the superconducting transition temperature $T_{\rm c}$ but weak in intensity, likely resulting from impurity effects. These results are similar to other iron pnictides superconductors despite the superconducting phase in NaFe$_{1-x}$Cu$_x$As is continuously connected to an antiferromagnetically ordered insulating phase near $x\approx 50\%$ with significant electronic correlations. Therefore, electron correlations is an important ingredient of superconductivity in NaFe$_{1-x}$Cu$_x$As and other iron pnictides.
1701.04874v1
2017-01-20
Tuning sizes, morphologies, and magnetic properties of mono- vs. multi-core iron oxide nanoparticles through control of added water in the polyol synthesis
The polyol route is a versatile and up-scalable method to produce large batches of iron oxide nanoparticles with well-defined structure and magnetic properties. Controlling parameters such as temperature and duration of reaction, heating profile, nature of polyol solvent or of organometallic precursors were reported in previous studies of literature, but none of them described yet the crucial role of water in the forced hydrolysis pathway, whose presence is mandatory for nanoparticle production. This communication investigates the influence of the water amount and temperature at which it is injected in the reflux system for either pure polyol or mixture with a poly(hydroxy) amine. Distinct morphologies of nanoparticles were thereby obtained, from ultra-ultra-small smooth spheres down to 4 nm in diameter to large ones up to 37 nm in diameter. Nanoflowers were also synthesized, which are well-defined multi-core assemblies with narrow grain size dispersity. A diverse and large library of samples was obtained by playing on the nature of solvents and amount of water traces while keeping all the other parameters fixed. The varied morphologies lead to magnetic nanoparticles well-fitting to required applications among magnetic hyperthermia and MRI contrast agent, or both.
1701.05858v3
2017-01-28
Deep Recurrent Neural Network for Protein Function Prediction from Sequence
As high-throughput biological sequencing becomes faster and cheaper, the need to extract useful information from sequencing becomes ever more paramount, often limited by low-throughput experimental characterizations. For proteins, accurate prediction of their functions directly from their primary amino-acid sequences has been a long standing challenge. Here, machine learning using artificial recurrent neural networks (RNN) was applied towards classification of protein function directly from primary sequence without sequence alignment, heuristic scoring or feature engineering. The RNN models containing long-short-term-memory (LSTM) units trained on public, annotated datasets from UniProt achieved high performance for in-class prediction of four important protein functions tested, particularly compared to other machine learning algorithms using sequence-derived protein features. RNN models were used also for out-of-class predictions of phylogenetically distinct protein families with similar functions, including proteins of the CRISPR-associated nuclease, ferritin-like iron storage and cytochrome P450 families. Applying the trained RNN models on the partially unannotated UniRef100 database predicted not only candidates validated by existing annotations but also currently unannotated sequences. Some RNN predictions for the ferritin-like iron sequestering function were experimentally validated, even though their sequences differ significantly from known, characterized proteins and from each other and cannot be easily predicted using popular bioinformatics methods. As sequencing and experimental characterization data increases rapidly, the machine-learning approach based on RNN could be useful for discovery and prediction of homologues for a wide range of protein functions.
1701.08318v1
2017-02-28
Neutrino Emission from Supernovae
Supernovae are the most powerful cosmic sources of MeV neutrinos. These elementary particles play a crucial role when the evolution of a massive star is terminated by the collapse of its core to a neutron star or a black hole and the star explodes as supernova. The release of electron neutrinos, which are abundantly produced by electron captures, accelerates the catastrophic infall and causes a gradual neutronization of the stellar plasma by converting protons to neutrons as dominant constituents of neutron star matter. The emission of neutrinos and antineutrinos of all flavors carries away the gravitational binding energy of the compact remnant and drives its evolution from the hot initial to the cold final state. The absorption of electron neutrinos and antineutrinos in the surroundings of the newly formed neutron star can power the supernova explosion and determines the conditions in the innermost supernova ejecta, making them an interesting site for the nucleosynthesis of iron-group elements and trans-iron nuclei. In this Chapter the basic neutrino physics in supernova cores and nascent neutron stars will be discussed. This includes the most relevant neutrino production, absorption, and scattering processes, elementary aspects of neutrino transport in dense environments, the characteristic neutrino emission phases with their typical signal features, and the perspectives connected to a measurement of the neutrino signal from a future galactic supernova.
1702.08713v1
2017-03-24
Role of the orbital degree of freedom in iron-based superconductors
Almost a decade has passed since the serendipitous discovery of the iron-based high temperature superconductors (FeSCs) in 2008. The question of how much similarity the FeSCs have with the copper oxide high temperature superconductors emerged since the initial discovery of long-range antiferromagnetism in the FeSCs in proximity to superconductivity. Despite the great resemblance in their phase diagrams, there exist important disparities between FeSCs and cuprates that need to be considered in order to paint a full picture of these two families of high temperature superconductors. One of the key differences lies in the multi-orbital multi-band nature of FeSCs, in contrast to the effective single-band model for cuprates. Due to the complexity of multi-orbital band structures, the orbital degree of freedom is often neglected in formulating the theoretical models for FeSCs. On the experimental side, systematic studies of the orbital related phenomena in FeSCs have been largely lacking. In this review, we summarize angle-resolved photoemission spectroscopy (ARPES) measurements across various FeSC families in literature, focusing on the systematic trend of orbital dependent electron correlations and the role of different Fe 3d orbitals in driving the nematic transition, the spin-density-wave transition, and implications for superconductivity.
1703.08622v2
2017-07-04
Blocking metal accretion onto population III stars by stellar wind
Low-mass population III (PopIII) stars of $\lesssim 0.8 M_{\odot}$ could survive up until the present. Non-detection of low-mass PopIII stars in our Galaxy has already put a stringent constraint on the initial mass function (IMF) of PopIII stars, suggesting that PopIII stars have a top-heavy IMF. On the other hand, some claims that the lack of such stars stems from metal enrichment of their surface by accretion of heavy elements from interstellar medium (ISM). We investigate effects of the stellar wind on the metal accretion onto low-mass PopIII stars because accretion of the local ISM onto the Sun is prevented by the solar wind even for neutrals. The stellar wind and radiation of low-mass PopIII stars are modeled based on knowledge of nearby low-mass stellar systems including our Sun. We find that low-mass PopIII stars traveling across the Galaxy forms the stellar magnetosphere in most of their life. Once the magnetosphere is formed, most of neutral interstellar particles are photoionized before reaching to the stellar surface and are blown away by the wind. Especially, the accretion abundance of iron will be reduced by a factor of $< 10^{-12}$ compared with Bondi-Hoyle-Lyttleton accretion. The metal accretion can enhance iron abundance [Fe/H] only up to $\sim -14$. This demonstrates that low-mass PopIII stars remain pristine and will be found as metal free stars and that further searches for them are valuable to constrain the IMF of PopIII stars.
1707.00989v1
2017-07-05
Interactions between Coherent Twin Boundaries and Phase Transition of Iron under Dynamic Loading and Unloading
Under high pressures, phase transition, as well as deformation twins, are constantly reported in many BCC metals, whose interactions are of fundamental importance to understand strengthen mechanism of these metals under extreme conditions. However, the interactions between twins and phase transition in BCC metals are remain largely unexplored. In this work, interactions between coherent twin boundaries and $\alpha \to \epsilon$ phase transition of iron are investigated using both non- equilibrium molecular dynamics simulations and nudge elastic band method. Mechanisms of both twin-assisted phase transition and reverse phase transition are studied and orientation relationships between BCC and HCP phase are found to be <11-1>BCC || <-12-10>HCP and <1-10>BCC || <0001>HCP for both cases. The twin boundary corresponds to after the phase transition. It is amazing that the reverse transition seems to be able to "memory" and recover the initial BCC twins. The memory would partly loss when plastic slips take place in the HCP phase before the reverse transition. In the recovered initial BCC twins, three major twin spacing are observed, which are well explained in terms of energy barriers of the transition from HCP phase to BCC twin. Besides, variant selection rule of the twin assisted phase transition is also discussed. The results of present work could be expected to give some clues for producing ultra-fine grain structure in materials exhibiting martensitic phase transition.
1707.01276v1
2017-07-06
Phonon Spectra in the Parent Superconducting Iron-tuned Telluride Fe$_{1+x}$Te from Inelastic Neutron Scattering and Ab Initio Calculations
We report inelastic neutron scattering measurements of phonon spectra in the parent superconductor iron-tuned chalcogenide Fe$_{1+x}$Te, for two different x contents (x $\leq$ 0.11), using neutron time-of-flight technique. Thermal neutron spectroscopy allowed to collect the low-temperature Stokes spectra over an extended Q-range, at 2, 40 and 120K - hence covering both the magnetic monoclinic and the paramagnetic tetragonal phases. Whereas cold-neutrons allowed to measure high-resolution anti-Stokes spectra at 140, 220 and 300K, thus covering the tetragonal phase. Our results evidence a spin-phonon coupling behaviour towards the observed noticeable temperature-dependent change of the Stokes spectra across the transition temperatures. On the other hand, the anti-Stokes spectra reveal a pronounced hardening of the low-energy, acoustic region, of the phonon spectrum, upon heating, indicating a strong anharmonicity and a subtle dependence of phonons on structural evolution within the tetragonal phase. Experimental results are accompanied by ab initio calculations of phonon spectra of the tetragonal stoichiometric phase for a comparison with the high-resolution anti-Stokes spectra. Calculations included different density functional methods. Spin polarization and van der Waals interaction, were either considered or neglected, individually or concomitantly, in order to study their respective effect on lattice dynamics description. Our results suggest that including van der Waals interaction has only a slight effect on phonon dynamics, however, phonon spectra are better described when spin polarization is included, in a cooperative way with van der Waals interactions.
1707.01970v2
2017-07-17
Coupling of structure to magnetic and superconducting orders in quasi-one-dimensional $\text{K}_2\text{Cr}_3\text{As}_3$
Quasi-one-dimensional $A_2\text{Cr}_3\text{As}_3$ (with $A = \text{K, Cs, Rb}$) is an intriguing new family of superconductors which exhibit many similar features to the cuprate and iron-based unconventional superconductor families. Yet in contrast to these systems, no charge or magnetic ordering has been observed which could provide the electronic correlations presumed necessary for an unconventional superconducting pairing mechanism - an absence which defies predictions of first principles models. We report the results of neutron scattering experiments on polycrystalline $\text{K}_2\text{Cr}_3\text{As}_3$ $(T_c \sim 7\text{K})$ which probed the low temperature dynamics near $T_c$ . Neutron diffraction data evidence a strong response of the nuclear lattice to the onset of superconductivity while inelastic scattering reveals a highly dispersive column of intensity at the commensurate wavevector $q = (00\frac{1}{2})$ which loses intensity beneath $T_c$ - indicative of short-range magnetic fluctuations. Using linear spin-wave theory we model the observed scattering and suggest a possible structure to the short-range magnetic order. These observations suggest that $\text{K}_2\text{Cr}_3\text{As}_3$ is in close proximity to a magnetic instability and that the incipient magnetic order both couples strongly to the lattice and competes with superconductivity - in direct analogy with the iron-based superconductors.
1707.05286v1
2017-07-20
Nuclear absorption and emission in the AGN merger NGC 6240: the hard X-ray view
We present the analysis of four NuSTAR observations of the luminous infrared galaxy merger NGC 6240, hosting a close pair of highly obscured active galactic nuclei (AGN). Over a period of about two years, the source exhibits hard X-ray variability of the order of 20 per cent, peaking around 20 keV. When the two AGN are resolved with Chandra, column densities in the range $N_\textrm{H} \sim 1-2 \times 10^{24}$ cm$^{-2}$ are estimated for both of them. The exact values are hard to determine, as they appear to depend on aspects that are sometimes overlooked in Compton-thick objects, such as the covering factor of the absorber, iron abundance, and the contamination in the Fe-K band from foreground hot-gas emission. Nearly spherical covering and slightly subsolar iron abundance are preferred in this case. While the southern nucleus is suggested to be intrinsically more powerful, as also implied by the mid-IR and 2-10 keV brightness ratios, solutions involving a similar X-ray luminosity of the two AGN cannot be ruled out. The observed variability is rather limited compared to the one revealed by the Swift/BAT light curve, and it can be fully explained by changes in the continuum flux from the two AGN, without requiring significant column density variations. NGC 6240 is hereby confirmed to represent a unique opportunity to investigate the X-ray (and broad-band) properties of massive galaxy mergers, which were much more frequent in the early Universe.
1707.07613v1
2017-08-18
Superconductivity across Lifshitz transition and anomalous insulating state in surface K-dosed (Li0.8Fe0.2OH)FeSe
In the iron-based superconductors, understanding the relation between superconductivity and electronic structure upon doping is crucial for exploring the pairing mechanism. Recently it was found that in iron selenide (FeSe), enhanced superconductivity (Tc over 40K) can be achieved via electron doping, with the Fermi surface only comprising M-centered electron pockets. Here by utilizing surface potassium dosing, scanning tunneling microscopy/spectroscopy (STM/STS) and angle-resolved photoemission spectroscopy (ARPES), we studied the electronic structure and superconductivity of (Li0.8Fe0.2OH)FeSe in the deep electron-doped regime. We find that a {\Gamma}-centered electron band, which originally lies above the Fermi level (EF), can be continuously tuned to cross EF and contribute a new electron pocket at {\Gamma}. When this Lifshitz transition occurs, the superconductivity in the M-centered electron pocket is slightly suppressed; while a possible superconducting gap with small size (up to ~5 meV) and a dome-like doping dependence is observed on the new {\Gamma} electron pocket. Upon further K dosing, the system eventually evolves into an insulating state. Our findings provide new clues to understand superconductivity versus Fermi surface topology and the correlation effect in FeSe-based superconductors.
1708.05635v1
2017-09-01
Two-dimensional Massless Dirac Fermions in Antiferromagnetic AFe2As2 (A = Ba, Sr)
We report infrared studies of AFe$_{2}$As$_{2}$ (A = Ba, Sr), two representative parent compounds of iron-arsenide superconductors, at magnetic fields (B) up to 17.5 T. Optical transitions between Landau levels (LLs) were observed in the antiferromagnetic states of these two parent compounds. Our observation of a $\sqrt{B}$ dependence of the LL transition energies, the zero-energy intercepts at B = 0 T under the linear extrapolations of the transition energies and the energy ratio ($\sim$ 2.4) between the observed LL transitions, combined with the linear band dispersions in two-dimensional (2D) momentum space obtained by theoretical calculations, demonstrates the existence of massless Dirac fermions in antiferromagnetic BaFe$_{2}$As$_{2}$. More importantly, the observed dominance of the zeroth-LL-related absorption features and the calculated bands with extremely weak dispersions along the momentum direction $k_{z}$ indicate that massless Dirac fermions in BaFe$_{2}$As$_{2}$ are 2D. Furthermore, we find that the total substitution of the barium atoms in BaFe$_{2}$As$_{2}$ by strontium atoms not only maintains 2D massless Dirac fermions in this system, but also enhances their Fermi velocity, which supports that the Dirac points in iron-arsenide parent compounds are topologically protected.
1709.00203v1
2017-09-08
Machine learning modeling of superconducting critical temperature
Superconductivity has been the focus of enormous research effort since its discovery more than a century ago. Yet, some features of this unique phenomenon remain poorly understood; prime among these is the connection between superconductivity and chemical/structural properties of materials. To bridge the gap, several machine learning schemes are developed herein to model the critical temperatures ($T_{\mathrm{c}}$) of the 12,000+ known superconductors available via the SuperCon database. Materials are first divided into two classes based on their $T_{\mathrm{c}}$ values, above and below 10 K, and a classification model predicting this label is trained. The model uses coarse-grained features based only on the chemical compositions. It shows strong predictive power, with out-of-sample accuracy of about 92%. Separate regression models are developed to predict the values of $T_{\mathrm{c}}$ for cuprate, iron-based, and "low-$T_{\mathrm{c}}$" compounds. These models also demonstrate good performance, with learned predictors offering potential insights into the mechanisms behind superconductivity in different families of materials. To improve the accuracy and interpretability of these models, new features are incorporated using materials data from the AFLOW Online Repositories. Finally, the classification and regression models are combined into a single integrated pipeline and employed to search the entire Inorganic Crystallographic Structure Database (ICSD) for potential new superconductors. We identify more than 30 non-cuprate and non-iron-based oxides as candidate materials.
1709.02727v2
2017-09-15
Angular dependence of vortex instability in a layered superconductor: the case study of Fe(Se,Te) material
Anisotropy effects on flux pinning and flux flow are strongly effective in cuprate as well as iron-based superconductors due to their intrinsically layered crystallographic structure. However $\textrm{Fe(Se,Te)}$ thin films grown on $\textrm{CaF}_2$ substrate result less anisotropic with respect to all the other iron based superconductors. We present the first study on the angular dependence of the flux flow instability, which occurs in the flux flow regime as a current driven transition to the normal state at the instability point ($I^*$,$V^*$) in the current-voltage characteristics. The voltage jumps are systematically investigated as a function of the temperature, the external magnetic field, and the angle between the field and the $\textrm{Fe(Se,Te)}$ film. The scaling procedure based on the anisotropic Ginzburg-Landau approach is successfully applied to the observed angular dependence of the critical voltage $V^*$. Anyway, we find out that $\textrm{Fe(Se,Te)}$ represents the case study of a layered material characterized by a weak anisotropy of its static superconducting properties, but with an increased anisotropy in its vortex dynamics due to the predominant perpendicular component of the external applied magnetic field. Indeed, $I^*$ shows less sensitivity to angle variations, thus being promising for high field applications.
1709.05089v3
2017-10-04
Surface abundance and the hunt for stratification in chemically peculiar hot subdwarfs: PG 0909+276 and UVO 0512-08
Edelmann (2003) identified two chemically peculiar hot subdwarfs, PG 0909+276 and UVO 0512-08, as having very high overabundances of iron-group elements. We obtained high-resolution ultraviolet spectroscopy in order to measure abundances of species not observable in the optical, and to seek evidence for chemical stratification in the photosphere. Abundances were measured in three wavelength regions; the optical 3900\AA-6900\AA\ range was re-analysed to confirm consistency with Edelmann. Ultraviolet spectra were obtained with the Space Telescope Imaging Spectrograph (STIS) on the Hubble Space Telescope (HST), covering the far-UV (1140\AA-1740\AA) and the near-UV (1740\AA-2500\AA). We computed a grid of theoretical LTE spectra to find basic parameters (effective temperatures, surface gravity, surface hydrogen and helium fractions). We measured abundances using a spectral-synthesis approach in each wavelength range. We confirm that several iron-group metals are highly enriched, including cobalt, copper and zinc, relative to typical sdB stars. We detect gallium, germanium, tin, and lead, similar to analysis of ultraviolet spectra of some other sdB stars. Our results confirm that PG 0909+276 and UVO 0512-08 exhibit peculiarities which make them distinct from both the normal H-rich sdB and intermediate He-rich sdB stars. The process which leads to this particular composition has still to be identified.
1710.01663v1
2017-10-18
Using MRI Cell Tracking to Monitor Immune Cell Recruitment in Response to a Peptide-Based Cancer Vaccine
Purpose: MRI cell tracking can be used to monitor immune cells involved in the immunotherapy response, providing insight into the mechanism of action, temporal progression of tumour growth and individual potency of therapies. To evaluate whether MRI could be used to track immune cell populations in response to immunotherapy, CD8+ cytotoxic T cells (CTLs), CD4+CD25+FoxP3+ regulatory T cells (Tregs) and myeloid derived suppressor cells (MDSCs) were labelled with superparamagnetic iron oxide (SPIO) particles. Methods: SPIO-labelled cells were injected into mice (one cell type/mouse) implanted with an HPV-based cervical cancer model. Half of these mice were also vaccinated with DepoVaxTM, a lipid-based vaccine platform that was developed to enhance the potency of peptide-based vaccines. Results: MRI visualization of CTLs, Tregs and MDSCs was apparent 24 hours post-injection, with hypointensities due to iron labelled cells clearing approximately 72 hours post-injection. Vaccination resulted in increased recruitment of CTLs and decreased recruitment of MDSCs and Tregs to the tumour. We also found that MDSC and Treg recruitment was positively correlated with final tumour volume. Conclusion: This type of analysis can be used to non-invasively study changes in immune cell recruitment in individual mice over time, potentially allowing improved application and combination of immunotherapies.
1710.06817v1
2017-11-02
Constraining planet structure and composition from stellar chemistry: trends in different stellar populations
The chemical composition of stars that have orbiting planets provides important clues about the frequency, architecture, and composition of exoplanet systems. We explore the possibility that stars from different galactic populations that have different intrinsic abundance ratios may produce planets with a different overall composition. We compiled abundances for Fe, O, C, Mg, and Si in a large sample of solar neighbourhood stars that belong to different galactic populations. We then used a simple stoichiometric model to predict the expected iron-to-silicate mass fraction and water mass fraction of the planet building blocks, as well as the summed mass percentage of all heavy elements in the disc. Assuming that overall the chemical composition of the planet building blocks will be reflected in the composition of the formed planets, we show that according to our model, discs around stars from different galactic populations, as well as around stars from different regions in the Galaxy, are expected to form rocky planets with significantly different iron-to-silicate mass fractions. The available water mass fraction also changes significantly from one galactic population to another. The results may be used to set constraints for models of planet formation and chemical composition. Furthermore, the results may have impact on our understanding of the frequency of planets in the Galaxy, as well as on the existence of conditions for habitability.
1711.00777v1
2017-11-08
Matrix-assisted fabrication and exotic charge mobility of (Li,Fe)OHFeSe superconductor films
Superconducting (Li1-xFex)OHFe1-ySe films are attractive for both the basic research and practical application. However, the conventional vapor deposition techniques are not applicable in synthesizing the films of such a complex system. So no intrinsic charge transport measurements on the films are available so far to reveal the nature of charge carriers, which is fundamental to understanding the iron-based superconductivity mechanism. Herein we report a soft chemical film technique (matrix-assisted hydrothermal epitaxial growth), by which we have succeeded in growing a series of (Li1-xFex)OHFe1-ySe films covering the whole superconducting regime, with the superconducting transition temperature (Tc) from 4 K up to 42 K. This film technique opens up a new way for fabricating other complex functional materials as well. Furthermore, our systematic transport investigation on the film samples indicates that both the electron and hole carriers contribute to the charge transport, with the scattering rates deviating from the Fermi liquid. We find that the superconductivity occurs upon the electron and hole mobility becoming divergent. And in the high Tc samples, the electron carriers are found much more mobile than the holes, a feature distinct from the low Tc samples. Hence, our transport results provide key insights into the underlying physics for iron-based high-Tc superconductivity.
1711.02920v1
2017-11-17
Nematic superconducting state in iron pnictide superconductors
Nematic order often breaks the tetragonal symmetry of iron-based superconductors. It arises from regular structural transition or electronic instability in the normal phase. Here, we report the observation of a nematic superconducting state, by measuring the angular dependence of the in-plane and out-of-plane magnetoresistivity of Ba0.5K0.5Fe2As2 single crystals. We find large twofold oscillations in the vicinity of the superconducting transition, when the direction of applied magnetic field is rotated within the basal plane. To avoid the influences from sample geometry or current flow direction, the sample was designed as Corbino-shape for in-plane and mesa-shape for out-of-plane measurements. Theoretical analysis shows that the nematic superconductivity arises from the weak mixture of the quasi-degenerate s-wave and d-wave components of the superconducting condensate, most probably induced by a weak anisotropy of stresses inherent to single crystals.
1711.06383v1
2017-11-17
Frustrated magnetism in tetragonal CoSe, analogue to superconducting FeSe
Recently synthesized metastable tetragonal CoSe, isostructural to the FeSe superconductor, offers a new avenue for investigating systems in close proximity to the iron-based superconductors. We present magnetic and transport property measurements on powders and single crystals of CoSe. High field magnetic susceptibility measurements indicate a suppression of the previously reported 10 K ferromagnetic transition with the magnetic susceptibility exhibiting time-dependence below the proposed transition. Dynamic scaling analysis of the time-dependence yields a critical relaxation time of $\tau^{*} = 0.064 \pm 0.008 $ s which in turn yields an activation energy of $E_{a}^{*}$ = 14.84 $\pm$ 0.59 K and an ideal glass temperature $T_{0}^{*}$ = 8.91 $\pm$ 0.09 K from Vogel-Fulcher analysis. No transition is observed in resistivity and specific heat measurements, but both measurements indicate that CoSe is metallic. These results are interpreted on the basis of CoSe exhibiting frustrated magnetic ordering arising from competing magnetic interactions. Arrott analysis of single crystal magnetic susceptibility has indicated that the magnetic moments lie in the $ab$-plane so frustration may arise from intralayer magnetic fluctuations as well as interlayer coupling. The results have implications for understanding the superconductivity in the iron chalcogenide systems as well as utilizing CoSe as a host for chemical and physical manipulation to tune and explore emergent phenomena within an expanding new class of transition metal chalcogenides.
1711.06725v2
2017-11-21
The X-ray footprint of the CircumNuclear Disk
We studied the central regions of the Galactic Centre to determine if the CircumNuclear Disk (CND) acts as an absorber or a barrier for the central X-rays diffuse emission. After reprocessing 4.6Ms of Chandra observations, we were able to detect, for the first time, a depression in the X-ray luminosity of the diffuse emission whose size and location correspond to those of the CND. We extracted the X-ray spectra for various regions inside the CND footprint as well as for the region where the footprint is observed and for a region located outside the footprint. We simultaneously fitted these spectra as an optically thin plasma whose absorption by the interstellar medium and by the local plasma were fitted independently using the MCMC method. The hydrogen column density of the ISM is 7.5x10^22 cm^-2. The X-ray diffuse emission inside the CND footprint is formed by a 2T plasma of 1 and 4keV with slightly super-solar abundances except for the iron and carbon which are sub-solar. The plasma from the CND, in turn, is better described by a 1T model with abundances and local hydrogen column density which are very different to those of the innermost regions. The large iron abundance in this region confirms that the CND is dominated by the shock-heated ejecta of the Sgr A East supernova remnant. We deduced that the CND rather acts as a barrier for the Galactic Centre plasma and that the plasma located outside the CND may correspond to the collimated outflow possibly created by Sgr A* or the interaction between the wind of massive stars and the mini-spiral material.
1711.07841v1
2017-11-28
SFXTs versus classical SgXBs: Does the difference lie in the companion wind?
We present a comparative study of stellar winds in classical supergiant high mass X-ray binaries (SgXBs) and supergiant fast X-ray transients (SFXTs) based on the analysis of publicly available out-of-eclipse observations performed with Suzaku and XMM-Newton. Our data-set includes 55 observations of classical SgXBs and 21 observations of SFXTs. We found that classical SgXBs are characterized by a systematically higher absorption and luminosity compared to the SFXTs, confirming the results of previous works in the literature. Additionally, we show that the equivalent width of the fluorescence K{\alpha} iron line in the classical SgXBs is significantly larger than that of the SFXTs (outside X-ray eclipses). Based on our current understanding of the physics of accretion in these systems, we conclude that the most likely explanation of these differences is to be ascribed to the presence of mechanisms inhibiting accretion for most of the time in the SFXTs and leading to a much less efficient photoionization of the stellar wind compared to classical SgXBs.We do not find evidence for the previously reported anti-correlation between the equivalent width of the fluorescence iron line and the luminosity of SgXBs.
1711.10510v3
2017-12-04
Chemical fingerprints of hot Jupiter planet formation
The current paradigm to explain the presence of Jupiters with small orbital periods (P $<$ 10 days; hot Jupiters) that involves their formation beyond the snow line following inward migration, has been challenged by recent works that explored the possibility of in situ formation. We aim to test whether stars harbouring hot Jupiters and stars with more distant gas-giant planets show any chemical peculiarity that could be related to different formation processes. Our results show that stars with hot Jupiters have higher metallicities than stars with cool distant gas-giant planets in the metallicity range +0.00/+0.20 dex. The data also shows a tendency of stars with cool Jupiters to show larger abundances of $\alpha$ elements. No abundance differences between stars with cool and hot Jupiters are found when considering iron peak, volatile elements or the C/O, and Mg/Si ratios. The corresponding $p$-values from the statistical tests comparing the cumulative distributions of cool and hot planet hosts are 0.20, $<$ 0.01, 0.81, and 0.16 for metallicity, $\alpha$, iron-peak, and volatile elements, respectively. We confirm previous works suggesting that more distant planets show higher planetary masses as well as larger eccentricities. We note differences in age and spectral type between the hot and cool planet hosts samples that might affect the abundance comparison. The differences in the distribution of planetary mass, period, eccentricity, and stellar host metallicity suggest a different formation mechanism for hot and cool Jupiters. The slightly larger $\alpha$ abundances found in stars harbouring cool Jupiters might compensate their lower metallicities allowing the formation of gas-giant planets.
1712.01035v2
2017-12-04
Protonation induced high-Tc phases in iron-based superconductors evidenced by NMR and magnetization measurements
Chemical substitution during growth is a well-established method to manipulate electronic states of quantum materials, and leads to rich spectra of phase diagrams in cuprate and iron-based superconductors. Here we report a novel and generic strategy to achieve nonvolatile electron doping in series of (i.e. 11 and 122 structures) Fe-based superconductors by ionic liquid gating induced protonation at room temperature. Accumulation of protons in bulk compounds induces superconductivity in the parent compounds, and enhances the Tc largely in some superconducting ones. Furthermore, the existence of proton in the lattice enables the first proton nuclear magnetic resonance (NMR) study to probe directly superconductivity. Using FeS as a model system, our NMR study reveals an emergent high-Tc phase with no coherence peak which is hard to measure by NMR with other isotopes. This novel electric-field-induced proton evolution opens up an avenue for manipulation of competing electronic states (e.g. Mott insulators), and may provide an innovative way for a broad perspective of NMR measurements with greatly enhanced detecting resolution.
1712.01191v4
2017-12-06
Constraining the final fates of massive stars by oxygen and iron enrichment history in the Galaxy
Recent observational studies of core-collapse supernovae suggest only stars with zero-age main sequence masses smaller than $16$-$18\ M_\odot$ explode when they are red supergiants, producing type IIP supernovae. This may imply that more massive stars produce other types of supernovae or they simply collapse to black holes without giving rise to bright supernovae. This failed supernova hypothesis can lead to significantly inefficient oxygen production because oxygen abundantly produced in inner layers of massive stars with zero-age main sequence masses around $20$-$30\ M_\odot$ might not be ejected into the surrounding interstellar space. We first assume an unspecified population of oxygen injection events related to massive stars and obtain a model-independent constraint on how much oxygen should be released in a single event and how frequently such events should happen. We further carry out one-box galactic chemical enrichment calculations with different mass ranges of massive stars exploding as core-collapse supernovae. Our results suggest that the model assuming that all massive stars with $9$-$100\ M_\odot$ explode as core-collapse supernovae is still most appropriate in explaining the solar abundances of oxygen and iron and their enrichment history in the Galaxy. The oxygen mass in the Galaxy is not explained when assuming that only massive stars with zero-age main sequence masses in the range of 9-17 $M_\odot$, contribute to the galactic oxygen enrichment. This finding implies that a good fraction of stars more massive than $17M_\odot$ should eject their oxygen layers in either supernova explosions or some other mass loss processes.
1712.02013v1
2017-12-06
Interaction of the accretion flows in corona and disk near the black hole in AGN
Accretion flows toward black holes can be of a quite different nature, described as an optically thick cool gas flow in a disk for high accretion rates or as a hot coronal optically thin gas flow for low accretion rates, possibly affected by outflowing gas. The detection of broad iron emission lines in active galactic nuclei (AGN) indicates the coexistence of corona and disk. The appearance and relative strength of such flows essentially depends on their interaction. Liu et al. suggested that condensation of gas from the corona to the disk allows to understand accretion flows of comparable strength of emission. Matter inflow due to gravitational capture of gas is important for the condensation process. We discuss observational features predicted by the model. Data from simultaneous observations of AGN with {\it {Swift's}} X-ray and UV-optical telescopes are compared with the theoretical predictions. The frequent detection of broad iron K$\alpha$ emission lines and the dependence of the emitted spectra on the Eddington ratio, described by the values of the photon index $\Gamma$ and the two-point spectral index $\alpha_{\rm{ox}}$ are in approximate agreement with the predictions of the condensation model; the latter, however, with a large scatter. The model further yields a coronal emission concentrated in a narrow inner region as is also deduced from the analysis of emissivity profiles. The accretion flows in bright AGN could be described by the accretion of stellar wind or interstellar medium and its condensation into a thin disk.
1712.02031v1
2017-12-24
Search For Gravitational Redshifted Absorption Lines In LMXB Serpens X-1
The equation of state for ultra-dense matter can be tested from observations of the ratio of mass to radius of neutron stars. This could be measured precisely from the redshift of a narrow line produced on the surface. X-rays bursts have been intensively searched for such features, but so far without detection. Here instead we search for redshifted lines in the persistent emission, where the accretion flow dominates over the surface emission. We discuss the requirements for narrow lines to be produced, and show that narrow absorption lines from highly ionized iron can potentially be observable in accreting low mass X-ray binaries (low B field) which have either low spin or low inclination so that Doppler broadening is small. This selects Serpens X-1 as the only potential candidate persistent LMXB due to its low inclination. Including surface models in the broad band accretion flow model predicts that the absorption line from He-like iron at 6.7 keV should be redshifted to $\sim$ 5.1 - 5.7 keV (10 - 15 km for $1.4\mathrm{M_\odot}$) and have an equivalent width of 0.8 - 8.0 eV for surface temperatures of 7 - 10 $\times$ 10$^6$ K. We use the high resolution Chandra grating data to give a firm upper limit of 2 - 3 eV for an absorption line at $\sim 5$ keV. We discuss possible reasons for this lack of detection (the surface temperature and the geometry of the boundary layer etc.). Future instruments with better sensitivity are required in order to explore the existence of such features.
1712.08918v1
2018-01-09
Diverse fluctuations and anisotropic Gr{\" u}neisen parameter behavior in iron-based superconductor Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$ and their correlation with superconductivity
In this study, the temperature dependence of elastic constants $C_{11}$, $C_{33}$, $C_{\rm E} = (C_{11}-C_{12})/2$, $C_{66}$ and $C_{44}$ of the iron-based superconductor Ba(Fe$_{1-x}$Co$_{x}$)$_{2}$As$_{2}$ (0 $\leqq x \leqq$ 0.245) have been measured. This system shows a large elastic softening in $C_{66}$ towards low temperatures. In addition to $C_{66}$, which originates from orthorhombic structural fluctuation, the samples near the optimal concentration show remarkable structural fluctuation in $C_{11}$ and $C_{33}$ elastic modes, which correspond to $\Gamma_{1}$ (C4) symmetry. It suggests the existence of diverse fluctuations in this system. Gr{\" u}neisen parameters were analyzed under some assumptions for structural and magnetic transition temperatures. Results showed that the Gr{\" u}neisen parameters for the inter-plane strain are remarkably enhanced toward the QCP, while those for the in-plane stress tend to turn down near the QCP. Gr{\" u}neisen parameters for the superconducting transition are anisotropic and shows remarkable Co-concentration dependence, suggesting that the in-plane isotropic compression and inter-layer elongation enhance the superconductivity. The correlation of Gr{\" u}neisen parameters between $T_{\rm S}$, $T_{\rm N}$ and $T_{\rm sc}$ shows $c$-axis elongation and its relevant role in the emergence of superconductivity in this system.
1801.02791v1
2018-01-13
Advanced first-principles theory of superconductivity including both lattice vibrations and spin fluctuations: The case of FeB$_4$
We present an advanced method to study spin fluctuations in superconductors quantitatively, and entirely from first principles. This method can be generally applied to materials where electron-phonon coupling and spin fluctuations coexist. We employ it here to examine the recently synthesized superconductor iron tetraboride (FeB$_4$) with experimental $T_{\mathrm{c}}\sim 2.4$ K [H. Gou \textit{et al.}, Phys. Rev. Lett. \textbf{111}, 157002 (2013)]. We prove that FeB$_4$ is particularly prone to ferromagnetic spin fluctuations due to the presence of iron, resulting in a large Stoner interaction strength, $I=1.5$ eV, as calculated from first principles. The other important factor is its Fermi surface that consists of three separate sheets, among which two nested ellipsoids. The resulting susceptibility has a ferromagnetic peak around $\textbf{q}=0$, from which we calculated the repulsive interaction between Cooper pair electrons using the random phase approximation. Subsequently, we combined the electron-phonon interaction calculated from first principles with the spin fluctuation interaction in fully anisotropic Eliashberg theory calculations. We show that the resulting superconducting gap spectrum is conventional, yet very strongly depleted due to coupling to the spin fluctuations. The critical temperature decreases from $T_{\mathrm{c}}= 41$ K, if they are not taken into account, to $T_{\mathrm{c}}= 1.7$ K, in good agreement with the experimental value.
1801.04421v1
2018-01-15
Unconventional Charge Density Wave Order in the Pnictide Superconductor Ba(Ni$_{1-x}$Co$_x$)$_2$As$_2$
Ba(Ni$_{1-x}$Co$_x$)$_2$As$_2$ is a structural homologue of the pnictide high temperature superconductor, Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$, in which the Fe atoms are replaced by Ni. Superconductivity is highly suppressed in this system, reaching a maximum $T_c$ = 2.3 K, compared to 24 K in its iron-based cousin, and the origin of this $T_c$ suppression is not known. Using x-ray scattering, we show that Ba(Ni$_{1-x}$Co$_x$)$_2$As$_2$ exhibits a unidirectional charge density wave (CDW) at its triclinic phase transition. The CDW is incommensurate, exhibits a sizable lattice distortion, and is accompanied by the appearance of $\alpha$ Fermi surface pockets in photoemission [B. Zhou et al., Phys. Rev. B 83, 035110 (2011)], suggesting it forms by an unconventional mechanism. Co doping suppresses the CDW, paralleling the behavior of antiferromagnetism in iron-based superconductors. Our study demonstrates that pnictide superconductors can exhibit competing CDW order, which may be the origin of $T_c$ suppression in this system.
1801.04874v2
2018-01-26
Models for the Unusual Supernova iPTF14hls
Supernova iPTF14hls maintained a bright, variable luminosity for more than 600 days, while lines of hydrogen and iron in its spectrum had different speeds, but showed little evolution. Here several varieties of models are explored for iPTF14hls-like events. They are based upon circumstellar medium (CSM) interaction in an ordinary supernova, pulsational pair-instability supernovae (PPISN), and magnetar formation. Each is able to explain the enduring emission and brightness of iPTF14hls, but has shortcomings when confronted with other observed characteristics. The PPISN model can, in some cases, produce a presupernova transient like the one observed at the site of iPTF14hls in 1954. It also offers a clear path to providing the necessary half solar mass of material at $\sim 5 \times 10^{16}$ cm for CSM interaction to work, and can give an irregular light curve without invoking additional assumptions. It explains the 4000 km s$^{-1}$ seen in the iron lines, but without additional energy input, strains to explain the nearly constant 8000 km s$^{-1}$ velocity seen in H$_{\alpha}$. Magnetar models can also explain many of the observed features, but give a smooth light curve and may require an evolving magnetic field strength. Their dynamics may be difficult to reconcile with the observation of slow-moving hydrogen at late times. The various models predict different spectral characteristics and a remnant that, today, could be a black hole, magnetar, or even a star. Further observations and calculations of radiation transport will narrow the range of possibilities.
1801.08666v1
2018-03-01
Hydrogen Diffusion and Trapping in α-Iron: The Role of Quantum and Anharmonic Fluctuations
We investigate the thermodynamics and kinetics of a hydrogen interstitial in magnetic {\alpha}-iron, taking account of the quantum fluctuations of the proton as well as the anharmonicities of lattice vibrations and hydrogen hopping. We show that the diffusivity of hydrogen in the lattice of BCC iron deviates strongly from an Arrhenius behavior at and below room temperature. We compare a quantum transition state theory to explicit ring polymer molecular dynamics in the calculation of diffusivity and we find that the role of phonons is to inhibit, not to enhance, diffusivity at intermediate temperatures in constrast to the usual polaron picture of hopping. We then address the trapping of hydrogen by a vacancy as a prototype lattice defect. By a sequence of steps in a thought experiment, each involving a thermodynamic integration, we are able to separate out the binding free energy of a proton to a defect into harmonic and anharmonic, and classical and quantum contributions. We find that about 30% of a typical binding free energy of hydrogen to a lattice defect in iron is accounted for by finite temperature effects and about half of these arise from quantum proton fluctuations. This has huge implications for the comparison between thermal desorption and permeation experiments and standard electronic structure theory. The implications are even greater for the interpretation of muon spin resonance experiments.
1803.00600v1
2018-03-02
Topological Dirac semimetal phase in the iron-based superconductor Fe(Te,Se)
Topological Dirac semimetals (TDSs) exhibit bulk Dirac cones protected by time reversal and crystal symmetry, as well as surface states originating from non-trivial topology. While there is a manifold possible onset of superconducting order in such systems, few observations of intrinsic superconductivity have so far been reported for TDSs. We observe evidence for a TDS phase in FeTe$_{1-x}$Se$_x$ ($x$ = 0.45), one of the high transition temperature ($T_c$) iron-based superconductors. In angle-resolved photoelectron spectroscopy (ARPES) and transport experiments, we find spin-polarized states overlapping with the bulk states on the (001) surface, and linear magnetoresistance (MR) starting from 6 T. Combined, this strongly suggests the existence of a TDS phase, which is confirmed by theoretical calculations. In total, the topological electronic states in Fe(Te,Se) provide a promising high $T_c$ platform to realize multiple topological superconducting phases.
1803.00845v1
2018-03-20
Further insight on the hypervelocity white dwarf, LP 40-365 (GD 492): a nearby emissary from a single-degenerate Type Ia supernova
The recently discovered hypervelocity white dwarf LP 40-65 (aka GD 492) has been suggested as the outcome of the failed disruption of a white dwarf in a sub-luminous Type Ia supernova (SN Ia). We present new observations confirming GD 492 as a single star with unique spectral features. Our spectroscopic analysis suggests that a helium-dominated atmosphere, with ~ 33 percent neon and 2 percent oxygen by mass, can reproduce most of the observed properties of this highly unusual star. Although our atmospheric model contrasts with the previous analysis in terms of dominant atmospheric species, we confirm that the atmosphere of GD 492 is strongly hydrogen deficient, log(H/He) < -5, and displays traces of eleven other alpha- and iron-group elements (with sulfur, chromium, manganese, and titanium as new detections), indicating nuclear processing of carbon and silicon. We measure a manganese-to-iron ratio seven times larger than Solar. While the observed abundances of GD 492 do not fully match any predicted nuclear yields of a partially-burned supernova remnant, the manganese excess strongly favors a link with a single-degenerate SN Ia event over alternative scenarios.
1803.07564v1
2018-04-07
Bare and Polymer Coated Iron Oxide Superparamagnetic Nanoparticles for Effective Removal of U (VI) from Acidic and Neutral Aqueous Medium
Superparamagnetic {\gamma}-Fe2O3 nanoparticles (5 nm diameter) were synthesized in water. The bare particles exhibit good colloidal stability at ~ pH 2 because of the strong electrostatic repulsion with a surface charge of +25 mV. The polyacrylic acid (PAA)-coated particles exhibit remarkable colloidal stability at ~ pH 7 with abundant free carboxyl groups as reactive sites for subsequent functionalization. In this work, we used zeta potential analysis, transmission electron microscopy, small angle X-ray scattering, and Inductively coupled plasma mass spectrometry to investigate the adsorption behavior of U (VI) on bare and coated colloidal superparamagnetic nanoparticles at pH 2 and pH 7. At pH 2, uranyl ion (UO22+) absorbed on the surface of the bare particles with decreasing particle surface charge. This induced particle agglomeration. At pH 7, uranyl ion (UO22+) hydrolyzed and formed plate-like particles of uranium hydroxide that were ~ 50 nm in diameter. The PAA-coated iron oxide nanoparticles absorbed on the surface of these U (VI) hydroxide plates to form large aggregates that precipitate to the bottom of the dispersion. At both pH 2 and pH 7, the resulting U (VI)/nanoparticle complex can be easily collected and extracted from the aqueous environment via an external magnetic field. The results show that both bare and polymer-coated superparamagnetic {\gamma}-Fe2O3 nanoparticles are potential absorbents for removing U (VI) from water.
1804.02522v1
2018-04-10
Absence of superconductivity in iron polyhydrides at high pressures
Recently, C. M. P\'epin \textit{et al.} [Science \textbf{357}, 382 (2017)] reported the formation of several new iron polyhydrides FeH$_x$ at pressures in the megabar range, and spotted FeH$_5$, which forms above 130 GPa, as a potential high-\tc \ superconductor, because of an alleged layer of dense metallic hydrogen. Shortly after, two studies by A.~Majumdar \textit{et al.} [Phys. Rev. B \textbf{96}, 201107 (2017)] and A.~G.~Kvashnin \textit{et al.} [J. Phys. Chem. C \textbf{122}, 4731 (2018)] based on {\em ab initio} Migdal-Eliashberg theory seemed to independently confirm such a conjecture. We conversely find, on the same theoretical-numerical basis, that neither FeH$_5$ nor its precursor, FeH$_3$, shows any conventional superconductivity and explain why this is the case. We also show that superconductivity may be attained by transition-metal polyhydrides in the FeH$_3$ structure type by adding more electrons to partially fill one of the Fe--H hybrid bands (as, e.g., in NiH$_3$). Critical temperatures, however, will remain low because the $d$--metal bonding, and not the metallic hydrogen, dominates the behavior of electrons and phonons involved in the superconducting pairing in these compounds.
1804.03572v2
2018-04-13
A Long Serendipitous XMM-Newton Observation of the Intermediate Polar XY Ari
XY Ari is one of the few known eclipsing intermediate polars. We present results from a detailed analysis of an unpublished archival observation using XMM-Newton EPIC pn and MOS data in a quiescent state of XY Ari. The X-ray orbital modulation and spin pulse variations were investigated for energy dependent modulations in different energy bands. The broad orbital modulation observed with various observations was confirmed with XMM-Newton at hard X-ray (>1.6 keV). The EPIC light curves folded at the spin phases show a double peak profile as expected from two pole accretion. The pulse profile is found to be energy dependent. Hardness ratio variations and energy modulation depth during spin modulation can be explained by photoelectric absorption. The simultaneously fitted EPIC spectra with CEVMKL model yield maximum plasma temperature of $28^{+3.1}_{-2.9}$ keV with an iron abundance $\mathrm{Fe}/\mathrm{Fe}_\odot=0.37^{+0.06}_{-0.05}$. We find two intrinsic partial covering absorption columns of $6.2^{+1.0}_{-0.9} \times 10^{22}$ and $105.3^{+35.4}_{-30.4} \times 10^{22} \,\mathrm{cm^{-2}}$ with covering fractions of $0.53^{+0.05}_{-0.04}$, $0.41^{+0.14}_{-0.13}$ respectively. In addition, a Gaussian emission line at $6.43^{+0.01}_{-0.02}$ keV with an equivalent width of $51^{+12}_{-10}$ eV is required to account for fluorescent emission from neutral iron. The X-ray luminosity of the source is $4.2 \times 10^{32} \,\mathrm{erg \,s^{-1}}$ in the 0.2-10.0 keV energy band.
1804.04825v1
2018-04-23
Spectral and Timing Properties of Atoll Source 4U 1705-44 : LAXPC/AstroSat Results
In this paper, we present the first results of spectral and timing properties of the atoll source 4U 1705-44 using $\sim$ 100 ks data obtained with Large Area X-ray Proportional Counter (LAXPC) onboard {\it AstroSat}. The source was in the high-soft state during our observations and traced out a {\it banana track} in the Hardness Intensity Diagram (HID). We study {\bf the} evolution of the Power Density Spectra (PDS) and the energy spectra along the HID. PDS show presence of a broad Lorentzian feature (Peaked Noise or PN) centered at $1-13$ Hz and a very low frequency noise (VLFN). The energy spectra can be described by sum of a thermal Comptonized component, a power-law and a broad iron line. The hard tail seen in the energy spectra is variable and contribute $4-30$\% of the total flux. The iron line seen in this source is broad (FWHM $\sim$ 2 keV) and strong (EW $\sim$ $369-512$ eV). Only relativistic smearing in the accretion disc can not explain the origin of this feature and requires other mechanism such as broadening by Comptonization process in the external part of the `Comptonized Corona'. A subtle and systematic evolution of the spectral parameters (optical depth, electron temperature etc.) is seen as the source moves along the HID. We study the correlation between frequency of the PN and the spectral parameters. PN frequency seems to be correlated with the strength of the corona. We discuss the implication of the results in the paper.
1804.08371v1
2018-05-10
A Tale of Two Metals: contrasting criticalities in the pnictides and hole-doped cuprates
The iron-based high temperature superconductors share a number of similarities with their copper-based counterparts, such as reduced dimensionality, proximity to states of competing order, and a critical role for 3d electron orbitals. Their respective temperature-doping phase diagrams also contain certain commonalities that have led to claims that the metallic and superconducting properties of both families are governed by their proximity to a quantum critical point (QCP) located inside the superconducting dome. In this review, we critically examine these claims and highlight significant differences in the bulk physical properties of both systems. While there is now a large body of evidence supporting the presence of a (magnetic) QCP in the iron pnictides, the situation in the cuprates is much less apparent, at least for the end point of the pseudogap phase. We argue that the opening of the normal state pseudogap in cuprates, so often tied to a putative QCP, arises from a momentum-dependent breakdown of quasiparticle coherence that sets in at much higher doping levels but which is driven by the proximity to the Mott insulating state at half filling. Finally, we present a new scenario for the cuprates in which this loss of quasiparticle integrity and its evolution with momentum, temperature and doping plays a key role in shaping the resultant phase diagram.
1805.03866v1
2018-05-10
Stabilization of $s$-wave superconductivity through arsenic $p$-orbital hybridization in electron-doped BaFe$_2$As$_2$
Using random-phase approximation spin-fluctuation theory, we study the influence of the hybridization between iron $d$-orbitals and pnictide $p$-orbitals on the superconducting pairing state in iron-based superconductors. The calculations are performed for a 16-orbital Hubbard-Hund tight-binding model of BaFe$_2$As$_2$ that includes the As-$p$ orbital degrees of freedom in addition to the Fe-$d$ orbitals and compared to calculations for a 10-orbital Fe-$d$ only model. In both models we find a leading $s^\pm$ pairing state and a subleading $d_ {x^2-y^2}$-wave state in the parent compound. Upon doping, we find that the $s^\pm$ state remains the leading state in the 16-orbital model up to a doping level of 0.475 electrons per unit cell, at which the hole Fermi surface pockets at the zone center start to disappear. This is in contrast to the 10-orbital model, where the $d$-wave state becomes the leading state at a doping of less than 0.2 electrons. This improved stability of $s^\pm$ pairing is found to arise from a decrease of $d_{xy}$ orbital weight on the electron pockets due to hybridization with the As-$p$ orbitals and the resulting reduction of near $(\pi,\pi)$ spin-fluctuation scattering which favors the competing $d$-wave state. These results show that the orbital dependent hybridization of Fermi surface Bloch states with the usually neglected $p$-orbital states is an important ingredient in an improved itinerant pairing theory.
1805.04181v2
2018-05-30
Tracking the Iron K$α$ line and the Ultra Fast Outflow in NGC 2992 at different accretion states
The Seyfert 2 galaxy NGC 2992 has been monitored eight times by XMM-Newton in 2010 and then observed again in 2013, while in 2015 it was simultaneously targeted by Swift and NuSTAR. XMM-Newton always caught the source in a faint state (2-10 keV fluxes ranging from 0.3 to 1.6$\times10^{-11}$ erg cm$^{-2}$ s$^{-1}$) but NuSTAR showed an increase in the 2-10 keV flux up to 6$\times10^{-11}$ erg cm$^{-2}$ s$^{-1}$. We find possible evidence of an Ultra Fast Outflow with velocity $v_1=0.21\pm0.01c$ (detected at about 99% confidence level) in such a flux state. The UFO in NGC 2992 is consistent with being ejected at a few tens of gravitational radii only at accretion rates greater than 2% of the Eddington luminosity. The analysis of the low flux 2010/2013 XMM data allowed us to determine that the Iron K$\alpha$ emission line complex in this object is likely the sum of three distinct components: a constant, narrow one due to reflection from cold, distant material (likely the molecular torus); a narrow, but variable one which is more intense in brighter observations and a broad relativistic one emitted in the innermost regions of the accretion disk, which has been detected only in the 2003 XMM observation.
1805.12149v1
2018-06-04
Towards a systematically improvable many-body description of antiferromagnetic iron oxide
We report variational and fixed-node diffusion quantum Monte Carlo (QMC) calculations of anti-ferromagnetic iron oxide (FeO) in the ground state B1 crystal structure. The goal of this study was a systematic investigation of the sensitivity of several ground state properties to a variety of QMC wave function generation techniques including advanced wave functions such as multi-determinant expansions and backflow transformations. We found that the predicted lattice distortion was largely controlled by the choice of single particle orbitals used to construct the wave function, rather than by subsequent wave function optimization techniques within QMC. However, the absolute magnetic moment was remarkably insensitive to the method of wave function construction. QMC estimates of total spin density indicate that in addition to strong electronic correlation of the Fe $3d$ states, charge transfer may be an important but challenging piece of physics to accurately capture within existing QMC methods. Finally, we highlight the need for advanced and systematically improvable many-body wave functions suitable for accurately describing challenging real systems.
1806.01383v2
2018-09-04
Anomalous peak effect in iron-based superconductors Ba$_{1-x}$K$_x$Fe$_2$As$_2$ ($x \approx$ 0.69 and 0.76) for magnetic-field directions close to the $ab$ plane and its possible relation to the spin paramagnetic effect
We report magnetic torque measurements on iron-pnictide superconductors Ba$_{1-x}$K$_x$Fe$_2$As$_2$ ($x \approx$ 0.69 and 0.76) up to an applied field of $B_a$ = 45 T. The peak effect is observed in torque-vs-field curves below the irreversibility field. It is enhanced and becomes asymmetric as the field is tilted from the $c$ axis. For field directions close to the $ab$ plane, increasing- and decreasing-field curves peak at markedly different fields, and exhibit a sharp jump, suggestive of a first-order phase transition, on the high- and the low-field side of the peak, respectively. Complicated history dependence of the torque is observed in the peak-effect region. We construct and discuss the temperature ($T$)--applied-magnetic-field ($B_a$) phase diagram. Since the upper critical field for the $ab$-plane direction is comparable to the Pauli limit, we also consider possible influence of the spin paramagnetic effect on the anomalous peak effect.
1809.00762v3
2018-09-07
Electron-magnon scattering in elementary ferromagnets from first principles: lifetime broadening and band anomalies
We study the electron-magnon scattering in bulk Fe, Co, and Ni within the framework of many-body perturbation theory implemented in the full-potential linearized augmented-plane-wave method. To this end, a $\mathbf{k}$-dependent self-energy ($GT$ self-energy) describing the scattering of electrons and magnons is constructed from the solution of a Bethe-Salpeter equation for the two-particle (electron-hole) Green function, in which single-particle Stoner and collective spin-wave excitations (magnons) are treated on the same footing. Partial self-consistency is achieved by the alignment of the chemical potentials. The resulting renormalized electronic band structures exhibit strong spin-dependent lifetime effects close to the Fermi energy, which are strongest in Fe. The renormalization can give rise to a loss of quasiparticle character close to the Fermi energy, which we attribute to electron scattering with spatially extended spin waves. This scattering is also responsible for dispersion anomalies in conduction bands of iron and for the formation of satellite bands in nickel. Furthermore, we find a band anomaly at a binding energy of 1.5~eV in iron, which results from a coupling of the quasihole with single-particle excitations that form a peak in the Stoner continuum. This band anomaly was recently observed in photoemission experiments. On the theory side, we show that the contribution of the Goldstone mode to the $GT$ self-energy is expected to (nearly) vanish in the long-wavelength limit. We also present an in-depth discussion about the possible violation of causality when an incomplete subset of self-energy diagrams is chosen.
1809.02395v2
2018-09-21
Electronic Spin transition in FeO$_{2}$: evidence for Fe(II) with peroxide O$_{2}^{2-}$
The discovery of FeO$_{2}$ containing more oxygen than hematite (Fe$_{2}$O$_{3}$) that was previously believed to be the most oxygen rich iron compounds, has important implications on the study of the deep lower mantle compositions. Compared to other iron compounds, there are limited reports on FeO$_{2}$ making studies of its physical properties of great interest in fundamental condensed matter physics and geoscience. Even the oxidation state of Fe in FeO$_{2}$ is the subject of debate in theoretical works and there have not been reports from experimental electronic and magnetic properties measurements. Here, we report the pressure-induced spin state transition from synchrotron experiments and our computational results explain the underlying mechanism. Using density functional theory and dynamical mean field theory, we calculated spin states of Fe with volume and Hubbard interaction $U$ change, which clearly demonstrate that Fe in FeO$_{2}$ consists of Fe(II) and peroxide O$_{2}^{2-}$. Our study suggests that localized nature of both Fe 3$d$ orbitals and O$_{2}$ molecular orbitals should be correctly treated for unveiling the structural and electronic properties of FeO$_{2}$.
1809.07969v1
2018-09-24
The Variable Relativistic Outflow of IRAS 13224-3809
The discovery of an ultrafast outflow has been reported in the z=0.0658 narrow line Seyfert galaxy IRAS 13224-3809 (Parker et al. 2017a). The ultrafast outflow was first inferred through the detection of highly blueshifted absorption lines (Parker et al. 2017a) and then confirmed with a principal component analysis (PCA) (Parker et al. 2017b). Two of the reported properties of this outflow differed from those typically detected in other AGN with ultrafast outflows. First, the outflow velocity was found not to vary with v=0.236c +/- 0.006c. Second, the equivalent width of the highly blueshifted absorption line was reported to be anti-correlated with the 3-10 keV flux of this source. We present a re-analysis of the XMM-Newton observations of IRAS 13224-3809 considering the influence of background. We also undertook a different analysis approach in combining the spectra and investigated the change of the properties of the outflow as a function of 3-10 keV flux and time. We confirm the presence of an ultrafast outflow in IRAS 13224-3809, however, we find that the background spectra used in the Parker et al. analyses dominate the source spectra for energies near the blueshifted iron lines. By reducing the source extraction regions to improve the signal-to-noise ratio we discover larger than previously reported outflow velocities and find that the outflow velocity varies from ~0.2c to ~0.3c and increases with 3-10~keV flux. The previously reported anti-correlation between equivalent width of the iron line and 3-10 keV flux disappears when the background spectra are reduced by optimizing the source extraction regions.
1809.09138v1
2018-11-06
Energy scale of nematic ordering in the parent iron-based superconductor:BaFe2As2
Nematicity plays an important role in the physics of iron-based superconductors (IBS). Its microscopic origin and in particular its importance for the mechanism of high-temperature superconductivity itself are highly debated. A crucial knowledge in this regard is the degree to which the nematic order influences the electronic structure of these materials. Earlier angle-resolved photoemission spectroscopy (ARPES) studies found that the effect is dramatic in three families of IBS including 11, 111 and 122 compounds: energy splitting reaches 70 meV and Fermi surface becomes noticeably distorted. More recent experiments, however, reported significantly lower energy scale in 11 and 111 families, thus questioning the degree and universality of the impact of nematicity on the electronic structure of IBS. Here we revisit the electronic structure of undoped parent BaFe2As2 (122 family). Our systematic ARPES study including the detailed temperature and photon energy dependencies points to the significantly smaller energy scale also in this family of materials, thus establishing the universal scale of this phenomenon in IBS. Our results form a necessary quantitative basis for theories of high-temperature superconductivity focused on the nematicity.
1811.02430v2
2018-11-14
Giant anisotropy in superconducting single crystals of CsCa$_2$Fe$_4$As$_4$F$_2$
CsCa$_2$Fe$_4$As$_4$F$_2$ is a newly discovered iron-based superconductor with $T_\mathrm{c}\sim$ 30 K containing double Fe$_2$As$_2$ layers that are separated by insulating Ca$_2$F$_2$ spacer layers. Here we report the transport and magnetization measurements on CsCa$_2$Fe$_4$As$_4$F$_2$ single crystals grown for the first time using the self flux of CsAs. We observed a huge resistivity anisotropy $\rho_c(T)/\rho_{ab}(T)$, which increases with decreasing temperature, from 750 at 300 K to 3150 at 32 K. The $\rho_c(T)$ data exhibit a non-metallic behavior above $\sim$140 K, suggesting an incoherent electronic state at high temperatures due to the dimension crossover. The superconducting onset transition temperature in $\rho_{ab}$ is 0.7 K higher than that in $\rho_c$, suggesting two-dimensional (2D) superconducting fluctuations. The lower and upper critical fields also show an exceptional anisotropy among iron-based superconductors. The $H_{c1}^\bot(T)$ data are well fitted using the model with two $s$-wave-like superconducting gaps, $\Delta_1(0)=6.75$ meV and $\Delta_2(0)=2.32$ meV. The inter-plane coherence length $\xi_c(0)$ is $3.6$ \AA, remarkably smaller than the distance between conducting layers (8.6 \AA), consolidating the 2D nature in the title material.
1811.05706v1
2018-12-04
Adsorption and dissociation of iron phthalocyanine on H/Si(111): Impact of van-der-Waals interactions and perspectives for subsurface doping
The adsorption of iron phthalocyanine (FePc) on the passivated H/Si(111) surface is explored from first principles. We find that the organic molecule is predominantly physisorbed with a distance to the surface of $2.6 \pm 0.1$ Angstrom, but also exhibits sizable resonance with the underlying substrate. This establishes the present system as interesting mixed covalent-van-der-Waals-bound test case, which we use to compare the impact of different approaches to van-der-Waals interactions. (Spin-polarized) scanning tunneling microscopy (SP STM) images are simulated, selectively accessing different molecular orbitals via the applied bias voltage in the spirit of scanning tunneling spectroscopy. Comparison with experimental STM images reveals very good agreement. We find a significant magnetic contrast exceeding $\pm 1$ Angstrom in the SP STM images for $-2$ and $+1.5$ V. Binding energies of different (transition metal) atoms in the center of the Pc ring are presented, which particularly show that Fe is strongly bound in the molecule (about $9.6$ eV). Finally, we discuss different reactions for subsurface doping by room-temperature FePc deposition and point out two feasible reactions.
1812.01639v3
2018-12-06
Artificially Engineered Nanostrain in Iron Chalcogenide Superconductor Thin Film for Enhancing Supercurrent
Although nanoscale deformation, such as nanostrain in iron chalcogenide (FeSexTe1-x, FST) thin films, has attracted attention owing to the enhancement of general superconducting properties, including critical current density (Jc) and critical transition temperature, its formation has proven to be an extremely challenging and complex process thus far. Herein, we successfully fabricated an epitaxial FST thin film with uniformly distributed nanostrain by injection of a trace amount of CeO2 inside FST matrix using sequential pulsed laser deposition. Using transmission electron microscopy and geometrical phase analysis, we verified that a trace amount of CeO2 injection forms nanoscale fine defects with a nanostrained region, which has a tensile strain (ezz ~ 0.02) along the c-axis of the FST matrix. The nanostrained FST thin film achieves a remarkable Jc of 3.5 MA/cm2 for a self-field at 6 K and a highly enhanced Jc under the entire magnetic field with respect to a pristine FST thin film.
1812.02380v3
2018-12-13
Emergent XY electronic nematicity in iron-based superconductors
Electronic nematicity, a correlated state that spontaneously breaks rotational symmetry, is observed in several layered quantum materials. In contrast to their liquid-crystal counterparts, the nematic director cannot usually point in an arbitrary direction (XY nematics), but is locked by the crystal to discrete directions (Ising nematics),resulting in strongly anisotropic fluctuations above the transition. Here, we report on the observation of nearly isotropic XY-nematic fluctuations, via elastoresistance measurements, in hole-doped Ba$_{1-x}$Rb$_{x}$Fe$_{2}$As$_{2}$ iron-based superconductors. While for $x=0$ the nematic director points along the in-plane diagonals of the tetragonal lattice, for $x=1$ it points along the horizontal and vertical axes. Remarkably, for intermediate doping, the susceptibilities of these two symmetry-irreducible nematic channels display comparable Curie-Weiss behavior, thus revealing a nearly XY-nematic state. This opens a new route to assess this elusive electronic quantum liquid-crystalline state, which is a candidate to host unique phenomena not present in the Ising-nematic case.
1812.05267v2
2018-12-13
Visualizing the Nonlinear Coupling between Strain and Electronic Nematicity in the Iron Pnictides by Elasto-Scanning Tunneling Spectroscopy
Mechanical strain is a powerful technique for tuning electronic structure and interactions in quantum materials. In a system with tetragonal symmetry, a tunable uniaxial in-plane strain can be used to probe nematic correlations in the same way that a tunable magnetic field is used to probe magnetic correlations. Here, we present a new spectroscopic scanned probe technique that provides atomic-resolution insight into the effect of anisotropic strain on the electronic structure. We use this technique to study nematic fluctuations and nematic order across the phase diagram of a prototypical iron-based superconductor. By extracting quantitatively the electronic anisotropy as function of applied strain, we show that while true long range nematic order is established at the tetragonal to orthorhombic structural transition temperature, sizable nematic fluctuations persist to high temperatures and also to the overdoped end of the superconducting dome. Remarkably, we find that uniaxial strain in the pnictides significantly enhances the amplitude of the nematic fluctuations, indicating a strong nonlinear coupling between structure and electronic nematicity.
1812.05287v1
2018-12-20
The long-term evolution and appearance of Type Iax postgenitor stars
Type Iax supernovae may arise from failed explosions of white dwarfs that leave behind a bound remnant (i.e., a "postgenitor" star) that could be identified in wide field surveys. To understand their observational signatures, we simulate these white dwarf (WD) postgenitors from shortly after explosion until they move back down the WD cooling track, and we consider several possible WD masses and explosion energies. To predict the peculiar surface abundances of the WD postgenitors, our models take into account gravitational settling and radiative levitation. We find that radiative levitation is significant at temperatures above a mass-dependent critical temperature, typically in the range Teff ~ 50-100 * 10^3 K, significantly increasing surface abundances of iron-group elements. Due to enhanced iron group opacity compared to normal WDs, the postgenitor peak luminosity and cooling timescale depend sensitively on mass, with more massive WDs becoming brighter but cooling much faster. We discuss our results in light of recently discovered hypervelocity white dwarfs with peculiar surface compositions, finding that our low-mass postgenitor models match many of their observational characteristics. Finally, we explore the effects of thermohaline diffusion, tentatively finding that it strongly suppresses abundance enhancements created by radiative levitation, but more realistic modeling is required to reach a firm conclusion.
1812.08793v2
2019-02-14
Photoionization Emission Models for the Cyg X-3 X-ray Spectrum
We present model fits to the X-ray line spectrum of the well known High Mass X-ray binary Cyg X-3. The primary observational dataset is a spectrum taken with the $Chandra$ X-ray Observatory High Energy Transmission Grating (HETG) in 2006, though we compare it to all the other observations of this source taken so far by this instrument. We show that the density must be $\geq 10^{12}$ cm$^{-3}$ in the region responsible for most of the emission. We discuss the influence of the dust scattering halo on the broad band spectrum and we argue that dust scattering and extinction is not the most likely origin for the narrow featureseen near the Si K edge. We identify the features of a wind in the profiles of the strong resonance lines and we show that the wind is more apparent in the lines from the lighter elements. We argue that this wind is most likely associated with the companion star. We show that the intensities of most lines can be fitted, crudely, by a single component photoionized model. However, the iron K lines do not fit with this model. We show that the iron K line variability as a function of orbital phase is different from the lower energy lines, which indicates that the lines arise in physically distinct regions. We discuss the interpretation of these results in the context of what is known about the system and similar sys
1902.05589v3
2019-02-28
Quantum phase transition inside the superconducting dome of Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$ probed by optical magneto-sensing using NV-centers in diamond
While unusual normal state properties, such as non-Fermi liquid behavior of the resistivity, are commonly associated with strong quantum fluctuations, evidence for its presence inside the superconducting dome are much scarcer. In this paper, we use sensitive and minimally invasive optical magnetometry based on NV-centers in diamond to probe the doping evolution of the $T=0$ penetration depth in the electron-doped iron-based superconductor Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$. A non-monotonic evolution with a pronounced peak in the vicinity of the putative magnetic QPT is found. This behavior is reminiscent to that previously seen in isovalently-substituted BaFe$_2$(As$_{1-x}$P$_x$)$_2$ compounds, despite the notable differences between these two systems. Whereas the latter is a very clean system that displays nodal superconductivity and a single simultaneous first-order nematic-magnetic transition above, and even somewhat below, $T_c$, the former is a significantly dirtier system with fully gapped superconductivity and split second-order nematic and magnetic transition above $T_c$. Thus our observation that such distinct systems display remarkably similar penetration depth peaks, combined with the theoretical result that a QPT alone does not ensure the existence of a peak, unveils a puzzling and seemingly universal manifestation of quantum fluctuations in the iron pnictides.
1903.00053v2
2019-03-01
Observations of the Ultraviolet-Bright Star Barnard 29 in the Globular Cluster M13 (NGC 6205)
We have analyzed FUSE, COS, GHRS, and Keck HIRES spectra of the UV-bright star Barnard 29 in M13 (NGC 6205). By comparing the photospheric abundances derived from multiple ionization states of C, N, O, Si, and S, we infer an effective temperature T_eff = 21,400 +/- 400 K. Balmer-line fits yield a surface gravity log g = 3.10 +/- 0.03. We derive photospheric abundances of He, C, N, O, Mg, Al, Si, P, S, Cl, Ar, Ti, Cr, Fe, Ni, and Ge. Barnard 29 exhibits an abundance pattern typical of the first-generation stars in M13, enhanced in oxygen and depleted in aluminum. An underabundance of C and an overabundance of N suggest that the star experienced nonconvective mixing on the RGB. We see no evidence of significant chemical evolution since the star left the RGB; in particular, it did not undergo third dredge-up. Previous workers found that the star's FUV spectra yield an iron abundance about 0.5 dex lower than its optical spectrum, but the iron abundances derived from all of our spectra are consistent with the cluster value. We attribute this difference to our use of model atmospheres without microturbulence, which is ruled out by careful fits to optical absorption features. We derive a mass M_*/M_sun = 0.45 - 0.55 and luminosity log (L_*/L_sun) = 3.26 - 3.35. Comparison with stellar-evolution models suggests that Barnard 29 evolved from a ZAHB star of mass M_*/M_sun between 0.50 and 0.55, near the boundary between the extreme and blue horizontal branches.
1903.00350v1
2019-03-04
Structural and magnetic properties in sputtered iron oxide epitaxial thin films -- Magnetite Fe$_3$O$_4$ and epsilon ferrite e-Fe$_2$O$_3$
Epitaxial thin film fabrication of iron oxides including magnetite Fe3O4 and epsilon-ferrite epsilon-Fe2O3 with the potential for advancing electromagnetic devices has been investigated, which led to the first ever epsilon-ferrite epitaxial layer being synthesized in the conventional sputtering process. Concerning Fe3O4 (100) / MgO (100) films, a cube-on-cube epitaxial relationship and sharp rocking curves with FWHM of 50 - 350 arcsec were confirmed regardless of the small amount of Ge additions. Sputtering Ar gas pressure PAr heavily influenced their magnetic and transport properties. High PAr = 15 mTorr caused a high magnetization of 6.52 kG for the Ge added sample and the clear Verwey transition at 122 K for the non Ge addition case. Conversion electron Mossbauer spectroscopy (CEMS) measurements revealed that low PAr < 10 mTorr causes Fe/O off-stoichiometry on the oxidizing side for the non Ge addition case and the reductive side for the Ge addition case, respectively. Regarding the epsilon-Fe2O3 (001) / SrTiO3(111) epilayer synthesis, bilayer microstructure composed of an approximately 5nm thick initially grown epsilon-Fe2O3 (001) epilayer and subsequently grown e-Fe2O3 (001) epilayer was confirmed from cross-sectional TEM observations. The coexistence of magnetically hard and soft phases was confirmed from the magnetization measurements. As a possible application of the single nm thick epsilon-Fe2O3 layer, 4-resistive-state multiferroic tunnel junction (MFTJ) is considered.
1903.01022v1
2019-03-11
The Nematic Energy Scale and the Missing Electron Pocket in FeSe
Superconductivity emerges in proximity to a nematic phase in most iron-based superconductors. It is therefore important to understand the impact of nematicity on the electronic structure. Orbital assignment and tracking across the nematic phase transition prove to be challenging due to the multiband nature of iron-based superconductors and twinning effects. Here, we report a detailed study of the electronic structure of fully detwinned FeSe across the nematic phase transition using angle-resolved photoemission spectroscopy. We clearly observe a nematicity-driven band reconstruction involving dxz, dyz, and dxy orbitals. The nematic energy scale between dxz and dyz bands reaches a maximum of 50 meV at the Brillouin zone corner. We are also able to track the dxz electron pocket across the nematic transition and explain its absence in the nematic state. Our comprehensive data of the electronic structure provide an accurate basis for theoretical models of the superconducting pairing in FeSe.
1903.04557v2
2019-03-14
3D visualizations of nano-scale phase separation and ultrafast dynamic correlation between phases in (Na0.32K0.68)0.95Fe1.75Se2
Phase separation of metallic and antiferromagnetic (AFM) insulating phases in alkaline iron selenides (AxFe2-ySe2) continues to attract intense interest because the relationship between two peculiar features probably is a key to clarifying the pairing mechanism of AxFe2-ySe2 superconductors. Here we report that the 3D visualizations of nano-scale phase separation in (Na0.32K0.68)0.95Fe1.75Se2 single crystals are revealed by hybrid focused-ion-beam scanning electron microscopy and the superconducting paths are fully percolative in 3D. Moreover, the phase-related ultrafast dynamics in (Na0.32K0.68)0.95Fe1.75Se2 is studied by dual-color pump-probe spectroscopy. The anomalous changes in the electron and acoustic phonon components of transient reflectivity change ({\Delta}R/R) identify two characteristic temperatures T*~100 K (the onset temperature of coupling between nano-metallic and AFM phases) and TH~230 K (the onset temperature of metallic-interface-phase). An energy-transfer channel between the nano-metallic and AFM phases is inferred. This proposed channel provides a new insight into the pairing mechanism of alkaline iron selenide superconductors.
1903.05797v1
2019-03-15
Band-selective clean- and dirty-limit superconductivity with nodeless gaps in the bilayer iron-based superconductor CsCa$_2$Fe$_4$As$_4$F$_2$
The optical properties of the new iron-based superconductor CsCa$_2$Fe$_4$As$_4$F$_2$ with $T_c \sim 29$~K have been determined. In the normal state a good description of the low-frequency response is obtained with a superposition of two Drude components of which one has a very low scattering rate (narrow Drude-peak) and the other a rather large one (broad Drude-peak). Well below $T_c \sim 29$~K, a pronounced gap feature is observed which involves a complete suppression of the optical conductivity below $\sim$ 110~cm$^{-1}$ and thus is characteristic of a nodeless superconducting state. The optical response of the broad Drude-component can be described with a dirty-limit Mattis-Bardeen-type response with a single isotropic gap of $2\Delta \simeq 14$~meV. To the contrary, the response of the narrow Drude-component is in the ultra-clean-limit and its entire spectral weight is transferred to the zero-frequency $\delta(\omega)$ function that accounts for the loss-free response of the condensate. These observations provide clear evidence for a band-selective coexistence of clean- and dirty-limit superconductivity with nodeless gaps in CsCa$_2$Fe$_4$As$_4$F$_2$.
1903.06466v1
2019-05-07
Single-parameter scaling in the magnetoresistance of optimally doped La$_{2-x}$Sr$_{x}$CuO$_4$
We show that the recent magnetoresistance data on thin-film La$_{2-x}$Sr$_{x}$CuO$_4$ (LSCO) in strong magnetic fields ($B$) obeys a single-parameter scaling of the form MR$(B,T)=f(\mu_H(T)B)$, where $\mu_H^{-1}(T)\sim T^{\alpha}$ ($1\le\alpha\le2$), from $T=180$K until $T\sim20$K, at which point the single-parameter scaling breaks down. The functional form of the MR is distinct from the simple quadratic-to-linear quadrature combination of temperature and magnetic field found in the optimally doped iron superconductor BaFe${}_2$(As${}_{1-x}$P${}_x$)${}_2$. Further, low-temperature departure of the MR in LSCO from its high-temperature scaling law leads us to conclude that the MR curve collapse is not the result of quantum critical scaling. We examine the classical effective medium theory (EMT) previously used to obtain the quadrature resistivity dependence on field and temperature for metals with a $T$-linear zero-field resistivity. It appears that this scaling form results only for a binary, random distribution of metallic components. More generally, we find a low-temperature, high-field region where the resistivity is simultaneously $T$ and $B$ linear when multiple metallic components are present. Our findings indicate that if mesoscopic disorder is relevant to the magnetoresistance in strange metal materials, the binary-distribution model which seems to be relevant to the iron pnictides is distinct from the more broad-continuous distributions relevant to the cuprates. Using the latter, we examine the applicability of classical effective medium theory to the MR in LSCO and compare calculated MR curves with the experimental data.
1905.02737v1
2019-05-13
Kinetics of phase separation, border of miscibility gap in Fe-Cr and limit of Cr solubility in iron at 832 K
Kinetics of phase decomposition accompanied by precipitation of sigma-phase in a Fe73.7Cr26.3 alloy isothermally annealed at 832 K was studied by means of M\"ossbauer spectroscopy. Two stage decomposition process has been revealed by three different quantities viz. the average hyperfine field, <H>, the short-range parameter, alpha1, and the probability of atomic configuration with no Cr atoms within the first two coordination shells around the probe Fe atoms, P(0,0). The first stage, that has terminated after ca.300 h of annealing, has been associated with the decomposition into Fe-rich phase in which the concentration of Cr, determined as 20.9 at.%, can be interpreted as the border of the metastable miscibility gap at 832 K. The second stage can be regarded as a continuation of the phase decomposition process combined with a precipitation of sigma. The three relevant parameters for this stage have also saturation-like behavior vs. annealing time and the saturation can be interpreted as termination of the two processes. The concentration of Cr in the Fe-rich phase has been determined as 19.8 at.% and this value can be regarded as the limit of Cr solubility in iron at 832 K. Both stages of the kinetics were found to be in line with the Johnson-Mehl-Avrami-Kolgomorov equation yielding values of the rate constant and the Avrami exponent. The activation energy of the second-stage process was determined to be by ca.12 kJ/mol higher.
1905.05156v1
2019-05-24
The empirical aspects of Eliashberg formalism for the superconducting mechanism in Iron-based superconductors
We have investigated experimentally how properties of NdFeAsO0.8F0.2 superconductor affected due to the substitution of the Ca2+/Nd3+ doping. Based on the XRD data refinement, various structural parameters such as lattice parameters, bond angles, bond length, and etc. were studied. We have determined the upper limit of the calcium solubility in the NdFeAsO0.8F0.2 phase and it is restricted to x=0.05. Also, we have found that the lattice parameters and the cell volume decreased by increasing the calcium content. According to the XRD data analysis, we have argued that these reductions are due to the variations in the bond lengths and the bond angles of (O/F)-Nd-(O/F) and As-Fe-As i.e. alpha, beta upon increasing the calcium dopant. So, we have expected that the superconducting transition temperature (TC) will be sensitive to the calcium doping values. Experimentally, the TC of our samples was reduced from 53 K (for x = 0) to 48 K (for x = 0.01) and 27 K (for x=0.025) and disappeared for our other sample. Then we have studied the dependence of TC and bond angles, bond length, the pnictogen height, and the lattice parameter to examine the available theories from an empirical point of view. The consistency of our experimental results and the theoretical reports based on the spin- and the orbital-fluctuation theories shows that these models play an important role in the pairing mechanism of the iron-based superconductors.
1905.11378v1
2019-05-28
Photo-induced Superconducting State with Long-lived Disproportionate Band Filling in FeSe
Photo-excitation is a very powerful way to instantaneously drive a material into a novel quantum state without any fabrication, and variable ultrafast techniques have been developed to observe how electron-, lattice-, and spin-degrees of freedom change. One of the most spectacular phenomena is photo-induced superconductivity, and it has been suggested in cuprates that the transition temperature Tc can be enhanced from original Tc with significant lattice modulations. Here we show another photo-induced high-Tc superconducting state in the iron-based superconductor FeSe with semi-metallic hole and electron bands. The transient electronic state in the entire Brillouin zone is directly observed by the time- and angle-resolved photoemission spectroscopy using extreme ultraviolet pulses obtained from high harmonic generation. Our results of dynamical behaviors on timescales from 50 fs to 800 ps consistently support the favorable superconducting state after photo-excitation well above Tc. This finding demonstrates that multiband iron-based superconductors emerge as an alternative candidate for photo-induced superconductors.
1905.12138v1
2019-05-29
Photoinduced nematic state in FeSe$_{0.4}$Te$_{0.6}$
FeSe$_{x}$Te$_{1-x}$ compounds present a complex phase diagram, ranging from the nematicity of FeSe to the $(\pi, \pi)$ magnetism of FeTe. We focus on FeSe$_{0.4}$Te$_{0.6}$, where the nematic ordering is absent at equilibrium. We use a time-resolved approach based on femtosecond light pulses to study the dynamics following photoexcitation in this system. The use of polarization-dependent time- and angle-resolved photoelectron spectroscopy allows us to reveal a photoinduced nematic metastable state, whose stabilization cannot be interpreted in terms of an effective photodoping. We argue that the 1.55 eV photon-energy-pump-pulse perturbs the $C_4$ symmetry of the system triggering the realization of the nematic state. The possibility to induce nematicity using an ultra-short pulse sheds a new light on the driving force behind the nematic symmetry breaking in iron-based superconductors. Our results weaken the idea that a low-energy coupling with fluctuations is a necessary condition to stabilize the nematic order and ascribe the origin of the nematic order in iron-based superconductors to a clear tendency of those systems towards orbital differentiation due to strong electronic correlations induced by the Hund's coupling.
1905.12448v1
2019-05-30
Quantum dynamics of hydrogen in iron-based superconductor LaFeAsO0.9D0.1 measured with inelastic neutron spectroscopy
Inelastic neutron scattering was performed for an iron-based superconductor LaFeAsO0.9D0.1, where most of D (deuterium) replaces oxygen, while a tiny amount goes into interstitial sites. By first-principle calculation, we characterize the interstitial sites for D (and for H slightly mixed) with four equivalent potential minima. Below the superconducting transition temperature Tc = 26 K,new excitations emerge in the range 5-15 meV, while they are absent in the reference system LaFeAsO0.9F0.1. The strong excitations at 14.5 meV and 11.1 meV broaden rapidly around 15 K and 20 K, respectively, where each energy becomes comparable to twice of the superconducting gap. The strong excitations are ascribed to a quantum rattling, or a band motion of hydrogen, which arises only if the number of potential minima is larger than two.
1905.12826v2
2019-05-30
Changes in long-term properties of the Danube river level and flow induced by damming
In this paper we assessed changes in scaling properties of the river Danube level and flow data, associated with building of Djerdap/Iron Gates hydrological power plants positioned on the border of Romania and Serbia. We used detrended fluctuation analysis (DFA), wavelet transform spectral analysis (WTS) and wavelet-based modulus maxima method (WTMM) to investigate time series of river levels and river flows recorded at hydrological stations in the vicinity of dams and in the area of up to 480 km upstream from dams, and time series of simulated NOAA-CIRES 20th Century Global Reanalysis precipitation records for the Djerdap/Iron Gates region. By comparing river dynamics during the periods before and after construction of dams, we were able to register changes in scaling that are different for recordings from upstream and from downstream (from dams) areas. We found that damming caused appearance of human-made or enhancement of natural cycles in the small time scales region, which largely influenced the change in temporal scaling in downstream recording stations. We additionally found disappearance or decline in the amplitude of large-time-scale cycles as a result of damming, that changed the dynamics of upstream data. The most prominent finding of our paper is a demonstration of a complete or partial loss of annual cycles in the upstream stations' data that we found to extend as far as 220 km from dams. We discussed probable sources of such found changes in scaling, aiming to provide explanations that could be of use in future environmental assessments.
1905.13144v2
2019-08-06
FeOOH instability at the lower mantle conditions
Goethite, {\alpha}-FeOOH, is a major component among oxidized iron species, called rust, which formed as a product of metabolism of anoxygenic prokaryotes (1, 2) inhabiting the Earth from about 3.8 billion years (Gy) ago until the Great Oxidation Event (GOE) of about 2.5 Gy ago. The rust was buried on the ocean floor (1, 2) and had to submerge into the Earth mantle with subducting slabs due to the plate tectonics started about 2.8 Gy ago (3). The fate and the geological role of the rust at the lower mantle high-pressure and high-temperature(HPHT) conditions is unknown. We studied the behavior of goethite up to 82(2) GPa and 2300(100) K using in situ synchrotron single-crystal X-ray diffraction. At these conditions, corresponding to the coldest slabs at the depth of about 1000 km, {\alpha}-FeOOH decomposes to various iron oxides (Fe2O3, Fe5O7, Fe7O10, Fe6.32O9) and an oxygen-rich fluid. Our results suggest that recycling of the rust in the Earth mantle could contribute to oxygen release to the atmosphere and explain the sporadic increase of the oxygen level before the GOE linked to the formation of Large Igneous Provinces(4).
1908.02114v1