publicationDate
stringlengths
1
2.79k
title
stringlengths
1
36.5k
abstract
stringlengths
1
37.3k
id
stringlengths
9
47
2023-04-05
A dynamic Bayesian optimized active recommender system for curiosity-driven Human-in-the-loop automated experiments
Optimization of experimental materials synthesis and characterization through active learning methods has been growing over the last decade, with examples ranging from measurements of diffraction on combinatorial alloys at synchrotrons, to searches through chemical space with automated synthesis robots for perovskites....
2304.02484v1
2023-04-06
Dislocation density transients and saturation in irradiated zirconium
Zirconium alloys are widely used as the fuel cladding material in pressurised water reactors, accumulating a significant population of defects and dislocations from exposure to neutrons. We present and interpret synchrotron microbeam X-ray diffraction measurements of proton-irradiated Zircaloy-4, where we identify a tr...
2304.03084v1
2023-04-11
Effects of equivalent composition on superconducting properties of high-entropy REOBiS$_2$ (RE = La, Ce, Pr, Nd, Sm, Gd) single crystals
Superconductors are influenced by high-entropy alloys (HEAs); these have been investigated in various functional materials. REOBiS$_2$ (RE = La, Ce, Pr, Nd, Sm, and Gd in different combinations) single crystals with HEAs at the RE-site were successfully grown using the flux method. The obtained crystals were plate-shap...
2304.04993v1
2023-04-14
Recent progress in thermoelectric MXene-based structures versus other 2D materials
Thermoelectricity is a next-generation solution for efficient waste heat management. Although various thermoelectric materials exist, there is still a lot of scope for advancement, especially in room temperature applications. Recently, two-dimensional (2D) materials, including MXenes, showed promise as thermoelectric m...
2304.07015v2
2023-04-16
Earth shaped by primordial H$_2$ atmospheres
Earth's water, intrinsic oxidation state, and metal core density are fundamental chemical features of our planet. Studies of exoplanets provide a useful context for elucidating the source of these chemical traits. Planet formation and evolution models demonstrate that rocky exoplanets commonly formed with hydrogen-rich...
2304.07845v1
2023-04-17
Mechanical behavior of ion-irradiated ODS RAF steels strengthened with different types of refractory oxides
In the present work, authors focused on verifying structural and mechanical properties of Oxide Dispersed Strengthening (ODS) steels strengthened by three different types of refractory oxides submitted to ion-irradiation. Three materials strengthened with Y2O3 or Al2O3 or ZrO2 were produced by mechanical alloying and S...
2304.08266v1
2023-04-19
Evidence for current suppression in superconductor-superconductor bilayers
Superconducting radio frequency (SRF) cavities, which are critical components in many particle accelerators, need to be operated in the Meissner state to avoid strong dissipation from magnetic vortices. For a defect-free superconductor, the maximum attainable magnetic field for operation is set by the superheating fiel...
2304.09360v2
2023-04-26
Exploring the origins of perpendicular magnetic anisotropy in amorphous Tb-Co via changes in medium-range ordering
Amorphous thin films of Tb$_{17}$Co$_{83}$ (a-Tb-Co) grown by magnetron co-sputtering exhibit changes in magnetic anisotropy with varying growth and annealing temperatures. The magnetic anisotropy constant increases with increasing growth temperature, which is reduced or vanishes upon annealing at temperatures above th...
2304.13208v3
2023-04-29
Impact of MBE-grown (In,Ga)As/GaAs metamorphic buffers on excitonic and optical properties of single quantum dots with single-photon emission tuned to the telecom range
Tuning GaAs-based quantum emitters to telecom wavelengths makes it possible to use the existing mature technology for applications in, e.g., long-haul ultra-secure communication in the fiber networks. A promising method re-developed recently is to use a metamorphic InGaAs buffer that redshifts the emission by reducing ...
2305.00289v2
2023-05-03
Crystal Structure and Phonon Density of States of FeSi up to 120 GPa
The strongly correlated material FeSi exhibits several unusual thermal, magnetic, and structural properties under varying pressure-temperature (P-T) conditions. It is a potential thermoelectric alloy and a materials of several geological implications as a possible constituent at the Earth's core mantle boundary (CMB). ...
2305.02248v2
2023-05-08
AutoEIS: automated Bayesian model selection and analysis for electrochemical impedance spectroscopy
Electrochemical Impedance Spectroscopy (EIS) is a powerful tool for electrochemical analysis; however, its data can be challenging to interpret. Here, we introduce a new open-source tool named AutoEIS that assists EIS analysis by automatically proposing statistically plausible equivalent circuit models (ECMs). AutoEIS ...
2305.04841v2
2023-05-11
Designing Mixed-Metal Electrocatalyst Systems for Photoelectrochemical Dinitrogen Activation
Efficient artificial photosynthesis systems are currently realized as catalyst- and surfacefunctionalized photovoltaic tandem- and triple-junction devices, enabling photoelectrochemical (PEC) water oxidation while simultaneously recycling CO2 and generating hydrogen as a solar fuel for storable renewable energy. Althou...
2305.06877v1
2023-05-11
Kwinking as the plastic forming mechanism of B19' NiTi martensite
Irreversible plastic forming of B19$^\prime$ martensite of the NiTi shape memory alloy is discussed within the framework of continuum mechanics. It is suggested that the main mechanism arises from coupling between martensite reorientation and coordinated $[100](001)_{\rm M}$ dislocation slip. A heuristic model is propo...
2305.07125v3
2023-05-12
Striation lines in intermittent fatigue crack growth in an Al alloy
Fatigue failure of crystalline materials is a difficult problem in science and engineering, and recent results have shown that fatigue crack growth can occur in intermittent jumps which have fat-tailed distributions. As fatigue crack propagation is known to leave markings -- called striations -- on the fracture surface...
2305.07460v1
2023-05-12
High Density Fabrication Process for Single Flux Quantum Circuits
We implemented, optimized and fully tested over multiple runs a superconducting Josephson junction fabrication process tailored for the integrated digital circuits that are used for control and readout of superconducting qubits operating at millikelvin temperatures. This process was optimized for highly energy efficien...
2305.07607v2
2023-05-17
Emergence of superconductivity in single-crystalline LaFeAsO under simultaneous Sm and P substitution
We report on the high-pressure growth, structural characterization, and investigation of the electronic properties of single-crystalline LaFeAsO co-substituted by Sm and P, in both its normal- and superconducting states. Here, the appearance of superconductivity is attributed to the inner chemical pressure induced by t...
2305.10034v1
2023-05-21
Magnetic phase diagram of Ge1-x-ySnxMnyTe multiferroic semiconductors; coexistence of ferromagnetic and cluster glass ordering
We report the structural and magnetic results of polar {\alpha}-GeTe doped with Sn and Mn from x = 0.185 to 0.841 and y = 0.02 to 0.086, respectively. The magnetic results of Ge1-x-y(SnxMny)Te (GSMT) crystals identify Mn-clustering effect with scaling parameter, R = 0.033 for x ~ 0.2 and y = 0.06. The excessive Sn ions...
2305.12499v1
2023-05-21
CNN-based Dendrite Core Detection from Microscopic Images of Directionally Solidified Ni-base Alloys
Dendrite core is the center point of the dendrite. The information of dendrite core is very helpful for material scientists to analyze the properties of materials. Therefore, detecting the dendrite core is a very important task in the material science field. Meanwhile, because of some special properties of the dendrite...
2305.12506v1
2023-05-30
Strain Relaxation in Core-Shell Pt-Co Catalyst Nanoparticles
Surface strain plays a key role in enhancing the activity of Pt-alloy nanoparticle oxygen reduction catalysts. However, the details of strain effects in real fuel cell catalysts are not well-understood, in part due to a lack of strain characterization techniques that are suitable for complex supported nanoparticle cata...
2305.18686v1
2023-06-01
Microstructure quality control of steels using deep learning
In quality control, microstructures are investigated rigorously to ensure structural integrity, exclude the presence of critical volume defects, and validate the formation of the target microstructure. For quenched, hierarchically-structured steels, the morphology of the bainitic and martensitic microstructures are of ...
2306.00797v1
2023-06-06
Reconstruction, rumpling, and Dirac states at the (001) surface of a topological crystalline insulator Pb1-xSnxSe
Equilibrium atomic configuration and electronic structure of the (001) surface of IV-VI semiconductors PbTe, PbSe, SnTe and SnSe, is studied using the density functional theory (DFT) methods. At surfaces of all those compounds, the displacements of ions from their perfect lattice sites reveal two features characteristi...
2306.03582v2
2023-06-19
Unveiling the nucleation and growth of Zr oxide precipitates of internally oxidized Nb3Sn superconductors
We report on atomic-scale analyses of nucleation and growth of Zr oxide precipitates and the microstructural evolution of internally oxidized Nb3Sn wires for high-field superconducting magnet applications, utilizing atom probe tomography (APT), transmission electron microscopy (TEM), and first-principles calculations. ...
2306.10866v2
2023-06-20
High frequency oscillations in spin-torque nano oscillator due to bilinear coupling
Exchange coupling in an interfacial context is crucial for spin-torque nano oscillator (STNO) that consists of a non-magnetic spacer which is alloyed with a ferromagnetic material. Currently, investigations on the dynamics of the free layer magnetization and frequency enhancement in the STNO with bilinear coupling are ...
2306.11415v1
2023-06-27
Utilizing multimodal microscopy to reconstruct Si/SiGe interfacial atomic disorder and infer its impacts on qubit variability
SiGe heteroepitaxial growth yields pristine host material for quantum dot qubits, but residual interface disorder can lead to qubit-to-qubit variability that might pose an obstacle to reliable SiGe-based quantum computing. We demonstrate a technique to reconstruct 3D interfacial atomic structure spanning multiqubit are...
2306.15646v1
2023-07-04
Quasi-crystalline order in vibrated granular matter
Quasi-crystals are aperiodic structures that present crystallographic properties which are not compatible with that of a single unit cell. Their revolutionary discovery in a metallic alloy, less than three decades ago, has required a full reconsideration of what we defined as a crystal structure. Surprisingly, quasi-cr...
2307.01643v1
2023-07-05
Comparative Analysis of THz Signal Emission from SiO$_2$/CoFeB/Metal Heterostructures: Wideband and High-Frequency THz Signal Advantage of PtBi-based Emitter
Spintronic THz emitters have attracted much attention due to their desirable properties, such as affordability, ultra-wideband capability, high efficiency, and tunable polarization. In this study, we investigate the characteristics of THz signals, including their frequency, bandwidth, and amplitude, emitted from a seri...
2307.02232v1
2023-07-10
NN-EVP: A physics informed neural network-based elasto-viscoplastic framework for predictions of grain size-aware flow response under large deformations
We propose a physics informed, neural network-based elasto-viscoplasticity (NN-EVP) constitutive modeling framework for predicting the flow response in metals as a function of underlying grain size. The developed NN-EVP algorithm is based on input convex neural networks as a means to strictly enforce thermodynamic cons...
2307.04301v1
2023-07-12
Extrinsic Anomalous Hall effect in Mn Doped GeSnTe Semiconductors in the Bad Metal Hopping Regime
We present high field magnetotransport studies of Ge1-x-y(SnxMny)Te bulk multiferroics with diamagnetic Sn and paramagnetic Mn concentration x = 0.38 to 0.79 and y = 0.02 to 0.086, respectively. The zero field resistivity, {\rho}(T) takes significant contribution from defects below T = 20 K however, a mixed scattering ...
2307.06271v1
2023-07-25
Electronic transport computation in thermoelectric materials: From ab initio scattering rates to nanostructures
Over the last two decades a plethora of new thermoelectric materials, their alloys, and their nanostructures were synthesized. The ZT figure of merit, which quantifies the thermoelectric efficiency of these materials increased from values of unity to values consistently beyond two across material families. At the same ...
2307.13800v1
2023-08-04
Scalable Path Level Thermal History Simulation of PBF process validated by Melt Pool Images
In this paper we outline the development of a scalable PBF thermal history simulation built on CAPL and based on melt pool physics and dynamics. The new approach inherits linear scalability from CAPL and has three novel ingredients. Firstly, to simulate the laser scanning on a solid surface, we discretize the entire si...
2308.02473v2
2023-08-04
Processing and mechanical properties of novel biodegradable poly-lactic acid/Zn 3D printed scaffolds for application in tissue regeneration
The feasibility to manufacture scaffolds of poly-lactic acid reinforced with Zn particles by fused filament fabrication is demonstrated for the first time. Filaments of 2.85 mm in diameter of PLA reinforced with different weight fractions of $\mu$m-sized Zn - 1 wt. \% Mg alloy particles (in the range 3.5 to 17.5 wt. \%...
2308.03790v1
2023-08-08
Absence of Tc-Pinning Phenomenon Under High Pressure in High-Entropy REO0.5F0.5BiS2 Layered Superconductor
Recently, robustness of superconductivity (transition temperature, Tc) under high pressures has been observed in high-entropy alloy (HEA), bcc-type Ti-Zr-Hf-Nb-Ta, and HEA-type compounds (Ag,In,Sn,Pb,Bi)Te with a NaCl-type structure. Since those materials have three-dimensional crystal structure, investigation on the p...
2308.04081v2
2023-08-11
Transcending the MAX phases concept of nanolaminated early transition metal carbides/nitrides -- the ZIA phases
A new potential class of nanolaminated and structurally complex materials, herein conceived as the Zigzag IntermetAllic (ZIA) phases, is proposed. A study of the constituent phases of a specific Nb--Si--Ni intermetallic alloy revealed that its ternary H-phase, \textit{i.e.}, the Nb$_3$SiNi$_2$ intermetallic compound (I...
2308.06408v1
2023-08-14
Domain branching in micromagnetism: scaling law for the global and local energies
We study the occurrence of domain branching in a class of $(d+1)$-dimensional sharp interface models featuring the competition between an interfacial energy and a non-local field energy. Our motivation comes from branching in uniaxial ferromagnets corresponding to $d=2$, but our result also covers twinning in shape-mem...
2308.07239v2
2023-08-16
Robust superconductivity and the suppression of charge-density wave in $\text{Ca}_{3}(\text{Ir}_{1-x}\text{Rh}_{x})_{4}\text{Sn}_{13}$ single crystals at ambient pressure
Single crystals of Ca$_3$(Ir$_{1-x}$Rh$_x$)$_4$Sn$_{13}$ (3-4-13) were synthesized by flux growth and characterized by X-ray diffraction, EDX, magnetization, resistivity and radio frequency magnetic susceptibility tunnel diode resonator (TDR) techniques. Compositional variation of the Rh/Ir ratio was used to study the ...
2308.08679v1
2023-09-05
Na-catalyzed rapid synthesis and characterization of intercalated graphite CaC6
In this study, we conducted experiments on CaC6 for elucidating the Na-catalyzed formation mechanism and achieving rapid mass synthesis of graphite intercalation compounds (GICs). Rapidly synthesized CaC6 was characterized by analysis of its crystal structure and physical properties. We found that the formation of the ...
2309.01942v1
2023-09-06
Benchmarking Inverse Optimization Algorithms for Materials Design
Machine learning-based inverse materials discovery has attracted enormous attention recently due to its flexibility in dealing with black box models. Yet, many metaheuristic algorithms are not as widely applied to materials discovery applications as machine learning methods. There are ongoing challenges in applying dif...
2309.02646v2
2023-09-21
Post deposition interfacial Néel temperature tuning in magnetoelectric B:Cr2O3
Boron (B) alloying transforms the magnetoelectric antiferromagnet Cr2O3 into a multifunctional single-phase material which enables electric field driven {\pi}/2 rotation of the N\'eel vector. Nonvolatile, voltage-controlled N\'eel vector rotation is a much-desired material property in the context of antiferromagnetic s...
2309.12493v1
2023-09-21
Superconductivity in Compositionally-Complex Cuprates with the YBa$_2$Cu$_3$O$_{7-x}$ Structure
High-temperature superconductivity is reported in a series of compositionally-complex cuprates with varying degrees of size and spin disorder. Three compositions of Y-site alloyed YBa$_2$Cu$_3$O$_{7-x}$, i.e., (5Y)BCO, were prepared using solid-state methods with different sets of rare earth ions on the Y-site. Synchro...
2309.12535v1
2023-09-22
Assessing r2SCAN meta-GGA functional for structural parameters, cohesive energy, mechanical modulus and thermophysical properties of 3d, 4d and 5d transition metals
The recent development of the accurate and efficient semilocal density functionals on the third rung of Jacob's ladder of density functional theory such as the revised regularized strongly constrained and appropriately normed (r2SCAN) density functional could enable the rapid and highly reliable prediction of the elast...
2309.12554v1
2023-09-24
Deep learning based workflow for accelerated industrial X-ray Computed Tomography
X-ray computed tomography (XCT) is an important tool for high-resolution non-destructive characterization of additively-manufactured metal components. XCT reconstructions of metal components may have beam hardening artifacts such as cupping and streaking which makes reliable detection of flaws and defects challenging. ...
2309.14371v1
2023-09-24
CoSb3-based skutterudite nanocomposites prepared by cold sintering process with enhanced thermoelectric properties
We show here for the first time the use of a cold sintering process (CSP) to sinter CoSb3-based thermoelectric materials. CSP at 150 {\deg}C for 90 min under a uniaxial pressure of 750 MPa yields pieces with a relative density of 86 %, which is increased to around 92 % after a post-annealing at temperatures > 500 {\deg...
2309.14904v1
2023-09-24
Novel one-pot sol-gel synthesis route of Fe3C/few-layered graphene core/shell nanoparticles embedded in a carbon matrix
Fe3C/few-layered graphene core/shell nanoparticles embedded in a carbon matrix are synthesized by a novel two-step surfactant sol-gel strategy, where the processes of hydrolysis, polycondensation and drying take place in a one-pot. The present approach is based on the combined action of oleic acid and oleylamine, which...
2309.15858v1
2023-09-24
Dense strontium hexaferrite-based permanent magnet composites assisted by cold sintering process
The use of rare-earth-based permanent magnets is one of the critical points for the development of the current technology. On the one hand, industry of the rare-earths is highly polluting due to the negative environmental impact of their extraction and, on the other hand, the sector is potentially dependent on China. T...
2309.16038v1
2023-09-30
Thermal Metamaterials for Temperature Maintenance: From Advances in Heat Conduction to Future Convection Prospects
Maintaining temperature is crucial in both daily life and industrial settings, ensuring human comfort and device functionality. In the quest for energy conservation and emission reduction, several contemporary passive temperature control technologies have emerged, including phase change temperature control, shape memor...
2310.00487v1
2023-10-01
Effect of Spin Fluctuations on Magnetoresistance and Anomalous Hall Effect in the Chiral Magnet Co8Zn8Mn4
The beta Mn type Co-Zn-Mn alloys have seized significant attention due to their ability to host skyrmions at room temperature. Here we analyse the unconventional magneto-transport properties of Co8Zn8Mn4 single crystals with a Curie temperature of 275 K. A negative magnetoresistance is obtained over a wide temperature ...
2310.00739v1
2023-10-09
Composition and optical properties of (In,Ga)As nanowires grown by group-III-assisted molecular beam epitaxy
(In,Ga) alloy droplets are used to catalyse the growth of (In,Ga)As nanowires by molecular beam epitaxy on Si(111) substrates. The composition, morphology and optical properties of these nanowires can be tuned by the employed elemental fluxes. To incorporate more than 10% of In, a high In/(In+Ga) flux ratio above 0.7 i...
2310.05582v1
2023-10-10
Spatially resolved photoluminescence analysis of Se passivation and defect formation in CdSe$_{x}$Te$_{1-x}$ thin films
CdTe is the most commercially successful thin-film photovoltaic technology to date. The recent development of Se-alloyed CdSe$_{x}$Te$_{1-x}$ layers in CdTe solar cells has led to higher device efficiencies, due to a lowered bandgap improving the photocurrent, improved voltage characteristics and longer carrier lifetim...
2310.06496v1
2023-10-18
Substrate interaction mediated control of phase separation in FIB milled Ag-Cu thin films
Nanofabrication is an integral part of realization of advanced functional devices ranging from optical displays to memory devices. Focused ion beam (FIB) milling is one of the widely used nanofabrication methods. Conventionally, FIB milling has been carried out for patterning single-phase stable thin films. However, th...
2310.11682v1
2023-10-22
Controlling spin-orbit coupling to tailor type-II Dirac bands
NiTe2, a type-II Dirac semimetal with strongly tilted Dirac band, has been explored extensively to understand its intriguing topological properties. Here, using density-functional theory (DFT) calculations, we report that the strength of spin-orbit coupling (SOC) in NiTe2 can be tuned by Se substitution. This results i...
2310.14202v1
2023-10-24
Nanoscale transient polarization gratings
We present the generation of transient polarization gratings at the nanoscale, achieved using a tailored accelerator configuration of the FERMI free electron laser. We demonstrate the capabilities of such a transient polarization grating by comparing its induced dynamics with the ones triggered by a more conventional i...
2310.15734v1
2023-10-24
Characteristics of $\langle a \rangle$ Screw Dislocations Basal Slip in Titanium
Plasticity in hexagonal close packed (HCP) metals and alloys such as Titanium (Ti) and Zirconium (Zr) is carried out by the motion of $\langle a \rangle$ dislocations. Above room temperature, in situ transmission electron microscopy straining experiments have shown that basal slip of $\langle a \rangle$ screw dislocati...
2310.15954v1
2023-10-26
Multiband $k \cdot p$ theory for hexagonal germanium
The direct bandgap found in hexagonal germanium and some of its alloys with silicon allows for an optically active material within the group-IV semiconductor family with various potential technological applications. However, there remain some unanswered questions regarding several aspects of the band structiure, includ...
2310.17366v2
2023-10-30
Interfacial Tension Hysteresis of Eutectic Gallium-Indium
When in a pristine state, gallium and its alloys have the largest interfacial tensions of any liquid at room temperature. Nonetheless, applying as little as 0.8 V of electric potential across eutectic gallium indium (EGaIn) placed within aqueous NaOH (or other electrolyte) solution will cause the metal to behave as if ...
2310.19298v1
2023-10-30
Strong in-plane magnetic anisotropy (Co0.15Fe0.85)5GeTe2/graphene van der Waals heterostructure spin-valve at room temperature
Van der Waals (vdW) magnets are promising owing to their tunable magnetic properties with doping or alloy composition, where the strength of magnetic interactions, their symmetry, and magnetic anisotropy can be tuned according to the desired application. However, most of the vdW magnet based spintronic devices are so f...
2310.19618v1
2023-11-02
Magnesium hydride films deposited on flexible substrates: Structure, morphology and hydrogen sorption properties
1.8 micrometer-thick magnesium hydride films were synthesized in a single-step process by reactive plasma-assisted sputtering. The MgH2 thin films, which were deposited on two types of flexible surfaces (namely graphite and polyimide foils) were found to adhere on both substrates. In all cases, XRD analysis revealed an...
2311.01071v1
2023-11-02
Emergent half-metal with mixed structural order in (111)-oriented (LaMnO$_3$)$_{2n}$|(SrMnO$_3$)$_n$ superlattices
Using first-principles techniques, we study the structural, magnetic and electronic properties of (111)-oriented (LaMnO$_3$)$_{2n}$$\vert$(SrMnO$_3$)$_{n}$ superlattices of varying thickness ($n=2,4,6$). We find that the properties of the thinnest superlattice ($n=2$) are similar to the celebrated half-metallic ferroma...
2311.01081v2
2023-11-02
Transient grating spectroscopy on a DyCo$_5$ thin film with femtosecond extreme ultraviolet pulses
Surface acoustic waves (SAWs) are excited by femtosecond extreme ultraviolet (EUV) transient gratings (TGs) in a room-temperature ferrimagnetic DyCo$_5$ alloy. TGs are generated by crossing a pair of EUV pulses from a free electron laser (FEL) with the wavelength of 20.8\,nm matching the Co $M$-edge, resulting in a SAW...
2311.01399v2
2023-11-02
Expanded stability of layered SnSe-PbSe alloys and evidence of displacive phase transformation from rocksalt in heteroepitaxial thin films
Bulk PbSnSe has a two-phase region or miscibility gap as the crystal changes from a Van der Waals-bonded orthorhombic 2D layered structure in SnSe-rich compositions to the related 3D-bonded rocksalt structure in PbSe-rich compositions with large contrast in the electrical, optical, and thermal properties across this tr...
2311.01514v2
2023-11-04
Long nanomechanical resonators with circular cross-section
Fabrication of superconducting nanomechanical resonators for quantum research, detectors and devices traditionally relies on a lithographic process, resulting in oscillators with sharp edges and a suspended length limited to a few 100 micrometres. We report a low-investment top-down approach to fabricating NbTi nanowir...
2311.02452v1
2023-11-04
Uncertainty Quantification in Multivariable Regression for Material Property Prediction with Bayesian Neural Networks
With the increased use of data-driven approaches and machine learning-based methods in material science, the importance of reliable uncertainty quantification (UQ) of the predicted variables for informed decision-making cannot be overstated. UQ in material property prediction poses unique challenges, including the mult...
2311.02495v2
2023-11-06
Phase-field simulations of the effect of temperature and interface for zirconium $δ\mbox{-}$hydrides
Hydride precipitation in zirconium cladding materials can damage their integrity and durability.Service temperature and material defects have a significant effect on the dynamic growth of hydrides. In this study, we have developed a phase field model based on the assumption of elastic behaviour within a specific temper...
2311.03162v1
2023-11-08
Interaction of monoclinic ZrO$_2$ grain boundaries with oxygen vacancies, Sn and Nb -- implications for the corrosion of Zr alloy fuel cladding
We used density-functional-theory simulations to examine the structural and electronic properties of the $\Sigma 180{\deg}(100)[001] $ grain boundary in monoclinic ZrO$_2$, which is a very low-energy (0.06Jm$^{-2}$) twin boundary present in experimental oxide texture maps, with suggested special properties. This equili...
2311.04667v1
2023-11-08
Depth resolved study of annealing in IrMn/(Fe, Co, CoFe) exchange bias systems
Depth resolved study of structural and magnetic profiles of antiferromagnetic/ferromagnetic (AFM/FM) system upon annealing was performed in this work. We studied systems comprising of AFM IrMn and FM (Co, Fe, Co$_{70}$Fe$_{30}$) structures using polarized neutron and soft X-ray scattering, secondary neutral spectrometr...
2311.04992v1
2023-11-09
Optically Induced Ferromagnetic Order in a Ferrimagnet
The parallel or antiparallel arrangement of electron spins plays a pivotal role in determining the properties of a physical system. To meet the demands for innovative technological solutions, extensive efforts have been dedicated to exploring effective methods for controlling and manipulating this arrangement [1]. Amon...
2311.05507v2
2023-11-20
Comparison of PM-HIP to Forged SA508 Pressure Vessel Steel Under High-Dose Neutron Irradiation
Powder metallurgy with hot isostatic pressing (PM-HIP) is an advanced manufacturing process that is envisioned to replace forging for heavy nuclear components, including the reactor pressure vessel (RPV). But PM-HIP products must at least demonstrate comparable irradiation tolerance than forgings in order to be qualifi...
2311.11548v1
2023-11-22
Nanoporous gold thin films as substrates to analyze liquids by cryo-atom probe tomography
Cryogenic atom probe tomography (cryo-APT) is being developed to enable nanoscale compositional analyses of frozen liquids. Yet, the availability of readily available substrates that allow for the fixation of liquids while providing sufficient strength to their interface, is still an issue. Here we propose the use of 1...
2311.13224v1
2023-11-22
Phase-selective growth of $κ$- vs $β$-Ga$_2$O$_3$ and (In$_x$Ga$_{1-x}$)$_2$O$_3$ by In-mediated metal exchange catalysis in plasma-assisted molecular beam epitaxy
Its piezo- and potentially ferroelectric properties make the metastable kappa polymorph of Ga$_2$O$_3$ an interesting material for multiple applications, while In-incorporation into any polymorphs of Ga$_2$O$_3$ allows to lower their bandgap. In this work, we provide a guideline to achieve single phase $\kappa$-, $\bet...
2311.13318v1
2023-11-24
Can tunneling current in molecular junctions be so strongly temperature dependent to challenge a hopping mechanism? Analytical formulas answer this question and provide important insight into large area junctions
{Analytical equations like Richardson-Dushman's or Shockley's provided a general, if simplified conceptual background, which was widely accepted in conventional electronics and made a fundamental contribution to advances in the field. In the attempt to develop a (highly desirable, but so far missing) counterpart for mo...
2311.14415v1
2023-11-15
Inexpensive High Fidelity Melt Pool Models in Additive Manufacturing Using Generative Deep Diffusion
Defects in laser powder bed fusion (L-PBF) parts often result from the meso-scale dynamics of the molten alloy near the laser, known as the melt pool. For instance, the melt pool can directly contribute to the formation of undesirable porosity, residual stress, and surface roughness in the final part. Experimental in-s...
2311.16168v1
2023-11-29
DisMech: A Discrete Differential Geometry-based Physical Simulator for Soft Robots and Structures
Fast, accurate, and generalizable simulations are a key enabler of modern advances in robot design and control. However, existing simulation frameworks in robotics either model rigid environments and mechanisms only, or if they include flexible or soft structures, suffer significantly in one or more of these performanc...
2311.18126v3
2023-11-30
Mid-infrared top-gated Ge/Ge$_{0.82}$Sn$_{0.18}$ nanowire phototransistors
Achieving high crystalline quality Ge$_{1-x}$Sn$_{x}$ semiconductors at Sn content exceeding 10\% is quintessential to implementing the long sought-after silicon-compatible mid-infrared photonics. Herein, by using sub-20 nm Ge nanowires as compliant growth substrates, Ge$_{1-x}$Sn$_{x}$ alloys with a Sn content of 18\%...
2311.18569v1
2023-12-06
A Unified Empirical Equation for Determining the Mechanical Properties of Porous NiTi Alloy: From Nanoporosity to Microporosity
The mechanical characteristics of a monolithic (non-porous) crystalline or amorphous material are described by a well-defined set of quantities. It is possible to change the mechanical properties by introducing porosity into this material: as a rule, the strength values decrease with the introduction of porosity. Thus,...
2312.03308v1
2023-12-11
Investigating intrinsic silicon oxide and a lightly doped p-type layer for evolution of tail states and estimating its impact as a passivation layer in a HIT type device
Hydrogenated amorphous silicon is well known for its various alloys and wide ranging opto-electronic properties. Hydrogenated silicon sub-oxide (aSiO:H) is one of them. The effect of boron doping on optoelectronic properties of the aSiO:H have been investigated with intrinsic and delta-doped materials. The Urbach energ...
2312.06111v1
2023-12-12
Microscale stress-geometry interactions in an additively manufactured NiTi cardiovascular stent: A synchrotron dual imaging tomography and diffraction study
This study explores cardiovascular stents fabricated using laser powder bed fusion (LPBF); an emerging method to offer patient-specific customisable parts. Here, the shape memory alloy NiTi, in a near equiatomic composition, was investigated to deconvolve the material response from macroscopic component effects. Specif...
2312.07480v1
2023-12-15
Bridging the Semantic-Numerical Gap: A Numerical Reasoning Method of Cross-modal Knowledge Graph for Material Property Prediction
Using machine learning (ML) techniques to predict material properties is a crucial research topic. These properties depend on numerical data and semantic factors. Due to the limitations of small-sample datasets, existing methods typically adopt ML algorithms to regress numerical properties or transfer other pre-trained...
2312.09744v1
2023-12-19
Fermi-level pinning in ErAs nanoparticles embedded in III-V semiconductors
Embedding rare-earth pnictide (RE-V) nanoparticles into III-V semiconductors enables unique optical, electrical, and thermal properties, with applications in THz photoconductive switches, tunnel junctions, and thermoelectric devices. Despite the high structural quality and control over growth, particle size, and densit...
2312.12184v1
2023-12-19
On the role of Grain Boundary Character in the Stress Corrosion Cracking of Nanoporous Gold Thin Films
For its potential as a catalyst, nanoporous gold (NPG) prepared through dealloying of bulk Ag-Au alloys has been extensively investigated. NPG thin films can offer ease of handling, better tunability of the chemistry and microstructure of the nanoporous structure, and represent a more sustainable usage of scarce resour...
2312.12235v1
2023-12-20
Ultraclean two-dimensional hole systems with mobilities exceeding 10$^7$ cm$^2$/Vs
Owing to their large effective mass, strong and tunable spin-orbit coupling, and complex band-structure, two-dimensional hole systems (2DHSs) in GaAs quantum wells provide rich platforms to probe exotic many-body physics, while also offering potential applications in ballistic and spintronics devices, and fault-toleran...
2312.13491v1
2023-12-22
Suppressing instabilities in mixed baroclinic flow using an actuation based on receptivity
This paper presents a method to stabilise oscillations occurring in a mixed convective flow in a nearly hemispherical cavity, using an actuation modelled on the receptivity map of the unstable mode underpinning these oscillations. This configuration represents a simplified model inspired from the continuous casting of ...
2312.15121v1
2024-01-09
Unbiased Atomistic Predictions of Crystal Dislocation Dynamics using Bayesian Force Fields
Crystal dislocation dynamics, especially at high temperatures, represents a subject where experimental phenomenological input is commonly required, and parameter-free predictions, starting from quantum methods, have been beyond reach. This is especially true for phenomena like stacking faults and dislocation cross-slip...
2401.04359v1
2024-01-10
Phase discovery with active learning: Application to structural phase transitions in equiatomic NiTi
Nickel titanium (NiTi) is a protypical shape-memory alloy used in a range of biomedical and engineering devices, but direct molecular dynamics simulations of the martensitic B19' -> B2 phase transition driving its shape-memory behavior are rare and have relied on classical force fields with limited accuracy. Here, we t...
2401.05568v1
2024-01-22
Quantitative measurement of figure of merit for transverse thermoelectric conversion in Fe/Pt metallic multilayers
This study presents a measurement method for determining the figure of merit for transverse thermoelectric conversion ($ z_\mathrm{T}T $) in thin film forms. Leveraging the proposed methodology, we comprehensively investigate the transverse thermoelectric coefficient ($ S_\mathrm{T} $), in-plane electrical conductivity...
2401.11692v1
2024-01-22
Exploring descriptors for titanium microstructure via digital fingerprints from variational autoencoders
Microstructure is key to controlling and understanding the properties of metallic materials, but traditional approaches to describing microstructure capture only a small number of features. To enable data-centric approaches to materials discovery, allow efficient storage of microstructural data and assist in quality co...
2401.11967v1
2024-01-24
Comparative study of the high-pressure behavior of ZnV2O6, Zn2V2O7, and Zn3V2O8
We report a study of the high-pressure structural behavior of ZnV2O6, Zn2V2O7, and Zn3V2O8, which has been explored by means of synchrotron powder x-ray diffraction. We found that ZnV2O6 and Zn3V2O8 remain in the ambient-pressure structure up to 15 GPa. In contrast, in the same pressure range, Zn2V2O7 undergoes three p...
2401.13440v1
2024-01-24
Equilibrium structure and shape of Ag and Pt nanoparticles grown on silica surfaces: from experimental investigations to the determination of a metal-silica potential
A combination of experimental and numerical calculations on metallic silver and platinum nanoparticles deposited on silica substrates is presented, with a focus on the metal-substrate interactions. Experimentally, the nanoparticles are elaborated under ultra-high vacuum and characterized by Grazing-Incidence Small-Angl...
2401.13528v1
2024-01-31
Unravelling the polarity of InN quantum dots using a modified approach of negative-spherical-aberration imaging
InN quantum dots (QDs) are considered to be promising nanostructures for different device applications. For any hexagonal AB stacking semiconductor system, polarity is an important feature which affects the electronic properties. Therefore, the determination of this characteristic on any wurtzite (semi)polar III nitrid...
2402.00213v1
2024-02-05
Thermal expansion and temperature dependence of Raman modes in epitaxial layers of Ge and Ge$_{1-x}$Sn$_{x}$
Temperature dependence of vibrational modes in semiconductors depends on lattice thermal expansion and anharmonic phonon-phonon scattering. Evaluating the two contributions from experimental data is not straightforward, especially for epitaxial layers that present mechanical deformation and anisotropic lattice expansio...
2402.02967v1
2024-02-04
High temperature internal friction in a Ti-46Al-1Mo-0.2Si intermetallic, comparison with creep behaviour
Advanced g-TiAl based intermetallics Mo-bearing have been developed to obtain the fine-grained microstructure required for superplastic deformation to be used during further processing. In the present work we have studied an alloy of Ti-46Al-1Mo-0.2Si (at%) with two different microstructures, as-cast material with a co...
2402.03389v1
2024-02-15
Quasicrystals as an intermediate form of matter between crystalline and amorphous solids
Quasicrystals have been observed in a variety of materials ranging from metal alloys to block copolymers and represent an "intermediate" form of matter between crystals and amorphous materials (glasses and liquids) in that their structural and dynamical properties can not readily described in terms of conventional soli...
2402.10295v1
2024-02-19
Breaks in the Hall-Petch Relationship after Severe Plastic Deformation of Magnesium, Aluminum, Copper, and Iron
Strengthening by grain refinement via the Hall-Petch mechanism and softening by nanograin formation via the inverse Hall-Petch mechanism have been the subject of argument for decades, particularly for ultrafine-grained materials. In this study, the Hall-Petch relationship is examined for ultrafine-grained magnesium, al...
2402.11798v1
2024-02-21
Discrete slip plane analysis of ferrite microtensile tests: On the influence of dislocation source distribution and non-Schmid effects on slip system activity
The slip system activity in microtensile tests of ferrite single crystals is compared with predictions made by the discrete slip plane model proposed by Wijnen et al. (International Journal of Solids and Structures 228, 111094, 2021). This is an extension of conventional crystal plasticity in which the stochastics and ...
2402.14168v1
2024-02-22
Pressure tunable magnetic skyrmion phase in Co8Zn8Mn4 single crystals
In a magnetic skyrmion phase, magnetic moments form vortex-like topological textures which are of both fundamental and industrial interests. In $\beta$-Mn-type Co-Zn-Mn alloys, chrial magnetic skyrmions emerge above room temperature, providing a unique system for studying the skrymion physics and exploring spintronics ...
2402.14477v1
2024-02-25
Accurate predictions of keyhole depths using machine learning-aided simulations
The keyhole phenomenon is widely observed in laser materials processing, including laser welding, remelting, cladding, drilling, and additive manufacturing. Keyhole-induced defects, primarily pores, dramatically affect the performance of final products, impeding the broad use of these laser-based technologies. The form...
2402.16190v1
2024-02-27
Field, frequency and temperature dependence of the surface resistance of nitrogen diffused niobium superconducting radio frequency cavities
We report the RF performance of several single-cell superconducting radio-frequency cavities subjected to low temperature heat treatment in nitrogen environment. The cavities were treated at temperature 120 - 165 C for an extended period of time (24 - 48 hours) either in high vacuum or in a low partial pressure of ultr...
2402.17458v2
2024-03-04
SciAssess: Benchmarking LLM Proficiency in Scientific Literature Analysis
Recent breakthroughs in Large Language Models (LLMs) have revolutionized natural language understanding and generation, igniting a surge of interest in leveraging these technologies in the field of scientific literature analysis. Existing benchmarks, however, inadequately evaluate the proficiency of LLMs in scientific ...
2403.01976v2
2024-03-06
Chemically Tailored Growth of 2D Semiconductors via Hybrid Metal-Organic Chemical Vapor Deposition
Two-dimensional (2D) semiconducting transition-metal dichalcogenides (TMDCs) are an exciting platform for new excitonic physics and next-generation electronics, creating a strong demand to understand their growth, doping, and heterostructures. Despite significant progress in solid-source (SS-) and metal-organic chemica...
2403.03482v1
2024-03-07
Investigation of low band gap silicon alloy thin film solar cell for improving short and long wavelength response
Numerical simulation of a solar cell can provide various information that can be useful to maximize its power conversion efficiency (PCE). In that respect we carried out a set of numerical simulation using AFORS-HET simulation program. Separately, in order to get a better understanding, the optical absorption in indivi...
2403.04637v2
2024-03-11
VLEIBot: A New 45-mg Swimming Microrobot Driven by a Bioinspired Anguilliform Propulsor
This paper presents the VLEIBot^* (Very Little Eel-Inspired roBot), a 45-mg/23-mm^3 microrobotic swimmer that is propelled by a bioinspired anguilliform propulsor. The propulsor is excited by a single 6-mg high-work-density (HWD) microactuator and undulates periodically due to wave propagation phenomena generated by fl...
2403.07073v1
2024-03-13
Robust Chemiresistive Behavior in Conductive Polymer/MOF Composites
Metal-organic frameworks (MOFs) are promising materials for gas sensing but are often limited to single-use detection. We demonstrate a hybridization strategy synergistically deploying conductive MOFs (cMOFs) and conductive polymers (cPs) as two complementary mixed ionic-electronic conductors in high-performing stand-a...
2403.08914v1