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2019-04-23
Genuine Ohmic van der Waals contact between indium and MoS2
The formation of an ideal van der Waals (vdW) contacts at metal/transition-metal dichalcogenide (TMDC) interfaces is a critical step for the development of high-performance and energy-efficient electronic and optoelectronic applications based on the two-dimensional (2D) semiconductors. In overcoming the key chal-lenges...
1904.10295v2
2019-04-26
Mixed magnetism, nanoscale electronic segregation and ubiquitous first order transitions in giant magnetocaloric MnFeSiP alloys detected by $^{55}$Mn NMR
We report on a study on a representative set of Fe$_{2}$P-based MnFePSi samples by means of $^{55}$Mn NMR in both zero and applied magnetic field. The first-order nature of the magnetic transition is demonstrated by truncated order parameter curves with a large value of the local ordered moment at the Curie point, even...
1904.11629v1
2019-04-26
One-step deposition of nano-to-micron-scalable, high-quality digital image correlation patterns for high-strain in-situ multi-microscopy testing
Digital Image Correlation (DIC) is of vital importance in the field of experimental mechanics, yet, producing suitable DIC patterns for demanding in-situ mechanical tests remains challenging, especially for ultra-fine patterns, despite the large number of patterning techniques in the literature. Therefore, we propose a...
1904.12047v2
2019-06-29
Terahertz Faraday and Kerr rotation spectroscopy of Bi$_{1-x}$Sb$_x$ films in high magnetic fields up to 30 Tesla
We report results of terahertz Faraday and Kerr rotation spectroscopy measurements on thin films of $\text{Bi}_{1-x}\text{Sb}_{x}$, an alloy system that exhibits a semimetal-to-topological-insulator transition as the Sb composition $x$ increases. By using a single-shot time-domain terahertz spectroscopy setup combined ...
1907.00137v1
2019-06-30
Superconducting phase diagram and nontrivial band topology of structurally modulated Sn$_{1-x}$Sb$_{x}$
We report the discovery of superconductivity in binary alloy Sn$_{1-x}$Sb$_{x}$ with $x$ in the range of 0.43 to 0.6, which possesses a modulated rhombohedral structure due to the incommensurate ordering of Sn and Sb layers along the $c$-axis. The specific heat measurements indicate a weakly coupled, fully gapped super...
1907.00320v1
2019-07-08
Combined measurement of velocity and temperature in liquid metal convection
Combined measurements of velocity components and temperature in a turbulent Rayleigh-B\'enard convection flow at a low Prandtl number of $\mathit{Pr}= 0.029$ and Rayleigh numbers between $10^6 \le \mathit{Ra} \le 6 \times 10^7$ are conducted in a series of experiments with durations of more than a thousand free-fall ti...
1907.03472v2
2019-07-11
Structural and magnetic properties of co-sputtered Fe0.8C0.2 thin films
We studied the structural and magnetic properties of \FeC~thin films deposited by co-sputtering of Fe and C targets in a direct current magnetron sputtering (dcMS) process at a substrate temperature (\Ts) of 300, 523 and 773\,K. The structure and morphology was measured using x-ray diffraction (XRD), x-ray absorption n...
1907.05150v1
2019-10-31
Time-resolving magnetic scattering on rare-earth ferrimagnets with a bright soft-X-ray high-harmonic source
We demonstrate the first time-resolved X-ray resonant magnetic scattering (tr-XRMS) experiment at the N edge of Tb at 155 eV performed using a tabletop high-brightness high-harmonic generation (HHG) source. In contrast to static X-ray imaging applications, such optical-pump X-ray-probe studies pose a different set of c...
1910.14263v1
2014-06-01
Semi-Empirical Parameterization of Interatomic Interactions and Kinetics of the Atomic Ordering in Ni-Fe-C Permalloys and Elinvars
Within the framework of the lattice-statics and static fluctuation-wave methods, the available energies of strain-induced interaction of interstitial-interstitial, interstitial-substitutional and substitutional-substitutional impurity atomic pairs are collected and analysed for f.c.c.-(Ni,Fe)-C solutions allowing for d...
1406.0164v1
2018-08-10
Development of low radioactivity photomultiplier tubes for the XMASS-I detector
XMASS-I is a single-phase liquid xenon detector whose purpose is direct detection of dark matter. To achieve the low background requirements necessary in the detector, a new model of photomultiplier tubes (PMTs), R10789, with a hexagonal window was developed based on the R8778 PMT used in the XMASS prototype detector. ...
1808.03617v2
2018-08-31
Density functional theory for the crystallization of two-dimensional dipolar colloidal alloys
Two-dimensional mixtures of dipolar colloidal particles with different dipole moments exhibit extremely rich self-assembly behaviour and are relevant to a wide range of experimental systems, including charged and super-paramagnetic colloids at liquid interfaces. However, there is a gap in our understanding of the cryst...
1808.10729v1
2018-12-21
Correlation between magneto-optical and transport properties of Sr doped manganite films
The features of electronic structure of La0.7Sr0.3MnO3, Pr0.8Sr0.2MnO3, and Pr0.6Sr0.4MnO3 polycrystalline films of different thickness have been investigated using magnetic circular dichroism (MCD) in the range of 1.1-4.2 eV. The temperature behavior of the samples electrical resistance were also has been studied. It ...
1812.09075v1
2019-02-04
Quantum-critical scale invariance in a transition metal alloy
Quantum-mechanical fluctuations between competing phases at $T=0$ induce exotic finite-temperature collective excitations that are not described by the standard Landau Fermi liquid framework. These excitations exhibit anomalous temperature dependences, or non-Fermi liquid behavior, in the transport and thermodynamic pr...
1902.01034v3
2019-02-10
Paradigm shift in electron-based crystallography via machine learning
Accurately determining the crystallographic structure of a material, organic or inorganic, is a critical primary step in material development and analysis. The most common practices involve analysis of diffraction patterns produced in laboratory XRD, TEM, and synchrotron X-ray sources. However, these techniques are slo...
1902.03682v1
2019-06-15
Designing, 3D Printing of a Quadruped Robot and Choice of Materials for Fabrication
Purpose-This paper is based on design of a quadruped robot and manufacturing it with 3-D printer followed by its detailed analysis. It focuses on the advantages of additive manufacturing rather than conventional manufacturing techniques and also highlights its limitations. The consequences of choice of different materi...
1906.06502v1
2019-06-25
Kondo Lattice Behavior Observed in the CeCu$_9$In$_2$ Compound
We report systematic studies of CeCu$_9$In$_2$, which appears to be a new Kondo lattice system. Electrical resistivity exhibits a logarithmic law characteristic of Kondo systems with a broad maximum at $T_{coh}\approx$45 K and it obeys the Fermi liquid theory at low temperature. Specific heat of CeCu$_9$In$_2$ is well ...
1906.10748v2
2020-04-02
An assessment of the J-integral test for a metallic foam
An assessment is made of the J-integral test procedure for initial crack growth in an open-cell aluminium alloy foam by combining finite element (FE) simulations with experiment. It is found experimentally that a zone of randomly failed struts develops ahead of the primary crack tip, and is comparable in size to that o...
2004.01053v1
2020-04-25
Reconciliation of experiments and theory on transport properties of iron and the geodynamo
The amount of heat transport from the core, which constrains the dynamics and thermal evolution of the region, depends on the transport properties of iron. Ohta et al.(2016) and Konopkova et al.(2016) measured electrical resistivity and thermal conductivity of iron, respectively, in laser-heated diamond anvil cells (DA...
2004.12035v1
2020-05-06
Microstructure evolution and thermal stability of equiatomic CoCrFeNi films on (0001)alpha-Al2O3
Homogeneous face-centered cubic (fcc) polycrystalline CoCrFeNi films were deposited at room temperature on (0001)alpha-Al2O3 (c-sapphire). Phase and morphological stability of 200 to 670 nm thick films were investigated between 973 K and 1423 K. The fcc-phase persists while the original <111> texture of 30-100 nm wide ...
2005.02883v1
2020-08-26
Understanding the role of Ca segregation on thermal stability, electrical resistivity and mechanical strength of nanostructured aluminum
Achieving a combination of high mechanical strength and high electrical conductivity in low-weight Al alloys requires a full understanding of the relationships between nanoscaled features and physical properties. Grain boundary strengthening through grain size reduction offers some interesting possibilities but is limi...
2008.11405v1
2021-03-07
Carbon Free High Loading Silicon Anodes Enabled by Sulfide Solid Electrolytes for Robust All Solid-State Batteries
The development of silicon anodes to replace conventional graphite in efforts to increase energy densities of lithium-ion batteries has been largely impeded by poor interfacial stability against liquid electrolytes. Here, stable operation of 99.9 weight% micro-Si (uSi) anode is enabled by utilizing the interface passiv...
2103.04230v1
2021-03-08
All-optical spin switching probability in [Tb/Co] multilayers
Since the first experimental observation of all-optical switching phenomena, intensive research has been focused on finding suitable magnetic systems that can be integrated as storage elements within spintronic devices and whose magnetization can be controlled through ultra-short single laser pulses. We report here ato...
2103.05066v1
2022-02-17
Effect of powder bed fusion process parameters on microstructural and mechanical properties of FeCrNi MEA: An atomistic study
In our study, molecular dynamics (MD) simulations of laser powder bed fusion (LPBF) have been conducted on equimolar FeNiCr medium entropy alloy (MEA) powders. With the development of newer LPBF technologies capable of printing at the microscale, an even deeper understanding of the underlying atomistic effects of the p...
2202.08568v1
2022-03-11
Superconducting dome associated with the suppression and re-emergence of charge density wave states upon sulfur substitution in CuIr2Te4 chalcogenides
We report the path from the charge density wave (CDW)-bearing superconductor CuIr2Te4 to the metal insulator transition (MIT)-bearing compound CuIr2S4 by chemical alloying with the gradual substitution of S for Te. The evolution of structural and physical properties of the CuIr2Te4-xSx polycrystalline system with the d...
2203.05817v1
2022-03-14
The Sabatier principle for Battery Anodes: Chemical Kinetics and Reversible Electrodeposition at Heterointerfaces
How surface chemistry influences reactions occurring thereupon has been a long-standing question of broad scientific and technological interest for centuries. Recently, it has re-emerged as a critical question in a subdiscipline of chemistry - electrochemistry at heterointerphases, where the answers have implications f...
2203.08609v3
2022-03-19
Inferring topological transitions in pattern-forming processes with self-supervised learning
The identification and classification of transitions in topological and microstructural regimes in pattern-forming processes are critical for understanding and fabricating microstructurally precise novel materials in many application domains. Unfortunately, relevant microstructure transitions may depend on process para...
2203.10204v2
2022-03-22
High-field magnetoresistance of microcrystalline and nanocrystalline Ni metal at 3 K and 300 K
The magnetoresistance (MR) and the magnetization isotherms were studied up to high magnetic fields at T = 3 K and 300 K for a microcrystalline ($\mu$c) Ni foil corresponding to bulk Ni and for a nanocrystalline (nc) Ni foil. At T = 3 K, for the $\mu$c-Ni sample with a residual resistivity ratio (RRR) of 331, the field ...
2203.11568v1
2022-03-28
The glass-forming ability of binary Lennard-Jones systems
The glass-forming ability (GFA) of alloys, colloidal dispersions, and other particulate materials, as measured by the critical cooling rate $R_c$, can span more than ten orders of magnitude. Even after numerous previous studies, the physical features that control the GFA are still not well understood. For example, it i...
2203.15087v1
2022-03-30
One Dimensional Wormhole Corrosion in Metals
Corrosion is a ubiquitous failure mode of materials in extreme environments. The more localized it is, the more difficult it is to detect and more deleterious its effects. Often, the progression of localized corrosion is accompanied by the evolution of porosity in materials, creating internal void-structures that facil...
2203.16312v1
2022-03-31
Refinements for Bragg coherent X-ray diffraction imaging: Electron backscatter diffraction alignment and strain field computation
Bragg coherent X-ray diffraction imaging (BCDI) allows the three-dimensional (3D) measurement of lattice strain along the scattering vector for specific microcrystals. If at least three linearly independent reflections are measured, the 3D variation of the full lattice strain tensor within the microcrystal can be recov...
2203.17015v3
2016-03-16
Dielectric anomalies and magnetodielectric coupling behavior of single crystalline Ca3Co2O6, a geometrically frustrated magnetic spin-chain system
The dielectric behavior of the single crystals of the spin-chain system Ca3Co2O6, undergoing geometrically frustrated antiferromagnetic ordering below 25 K, has been investigated as a function of temperature and magnetic field (H) and compared with magnetization (M) behavior. The results provide evidence for anisotropi...
1603.05055v1
2017-02-02
Enhanced IR Light Absorption in Group IV-SiGeSn Core-Shell Nanowires
Sn-containing Si and Ge alloys belong to an emerging family of semiconductors with the potential to impact group IV semiconductor devices. Indeed, the ability to independently engineer both lattice parameter and band gap holds the premise to develop enhanced or novel photonic, optoelectronic, and electronic devices. Wi...
1702.00682v1
2017-10-12
Structural origin of the midgap electronic states and the Urbach tail in pnictogen-chalcogenide glasses
We determine the electronic density of states for computationally-generated bulk samples of amorphous chalcogenide alloys As$_{x}$Se$_{100-x}$. The samples were generated using a structure-building algorithm reported recently by us ({J. Chem. Phys.} ${\bf 147}$, 114505). Several key features of the calculated density o...
1710.04362v3
2018-04-03
Spontaneous Repairing Liquid Metal/Si Nanocomposite as a Smart Conductive-Additive-Free Anode for Lithium-ion Battery
Silicon is a promising candidate for negative electrodes due to its high theoretical specific capacity (~3579 mAh g-1) and low lithiation potential (~0.40 V vs Li). However, its practical applications in battery have been inhibited by the large volume change (~400%) induced by Li+-insertion into Si lattices. Here, we a...
1804.00773v2
2018-04-06
Residual Entropy and Refinement of the Third-Law Expression
Although the third law of thermodynamics was established almost a century ago, it is not yet universally considered to be a fundamental law of physics. A major problem is that there are many materials having residual entropy. Amorphous materials and random alloy systems are well-known examples. A conventional view is t...
1804.02122v3
2019-03-07
Accurate reconstruction of EBSD datasets by a multimodal data approach using an evolutionary algorithm
A new method has been developed for the correction of the distortions and/or enhanced phase differentiation in Electron Backscatter Diffraction (EBSD) data. Using a multi-modal data approach, the method uses segmented images of the phase of interest (laths, precipitates, voids, inclusions) on images gathered by backsca...
1903.02988v2
2019-05-07
QuantumATK: An integrated platform of electronic and atomic-scale modelling tools
QuantumATK is an integrated set of atomic-scale modelling tools developed since 2003 by professional software engineers in collaboration with academic researchers. While different aspects and individual modules of the platform have been previously presented, the purpose of this paper is to give a general overview of th...
1905.02794v2
2019-07-30
Investigating radiation damage in nuclear energy materials using JANNuS multiple ion beams
Ion accelerators have been used by material scientists for decades to investigate radiation damage formation in nuclear materials and thus to emulate neutron-induced changes. The versatility of conditions in terms of particle energy, dose rate, fluence, etc., is a key asset of ion beams allowing for fully instrumented ...
1908.00627v1
2019-08-20
Ta, Ti and Hf effects on Nb$_3$Sn high-field performance: temperature-dependent dopant occupancy and failure of Kramer extrapolation
The increasing demand for improving the high-field (16-22 T) performance of Nb$_3$Sn conductors requires a better understanding of the properties of modern wires much closer to irreversibility field, H$_{Irr}$. In this study we investigated the impact of Ta, Ti and Hf doping on the high-field pinning properties, the up...
1908.07548v1
2019-08-26
Excitons in InP, GaP, GaInP quantum dots: Insights from time-dependent density functional theory
Colloidal quantum dots (QDs) of group III-V are considered as promising candidates for next-generation environmentally friendly light emitting devices, yet there appears to be only limited understanding of the underlying electronic and excitonic properties. Using large-scale density functional theory with the hybrid B3...
1908.09430v1
2019-09-05
Polymer-derived SiOC Replica of Material Extrusion-based 3-D Printed Plastics
A promising method for obtaining ceramic components with additive manufacturing (AM) is to use a two-step process of first printing the artifact in polymer and then converting it to ceramic using pyrolysis to form polymer derived ceramics (PDCs). AM of ceramic components using PDCs has been demonstrated with a number o...
1909.02442v1
2019-09-18
Electronic correlations in dense iron: from moderate pressure to Earth's core conditions
We discuss the role of dynamical many-electron effects in the physics of iron and iron-rich solid alloys under applied pressure on the basis of recent ab initio studies employing the dynamical mean-field theory (DMFT). Electronic correlations in iron in the moderate pressure range up to 60 GPa are discussed in the firs...
1909.08482v1
2019-09-23
Space test of the Equivalence Principle: first results of the MICROSCOPE mission
The Weak Equivalence Principle (WEP), stating that two bodies of different compositions and/or mass fall at the same rate in a gravitational field (universality of free fall), is at the very foundation of General Relativity. The MICROSCOPE mission aims to test its validity to a precision of $10^{-15}$, two orders of ma...
1909.10598v1
2020-01-30
Scale bridging materials physics: Active learning workflows and integrable deep neural networks for free energy function representations in alloys
The free energy plays a fundamental role in descriptions of many systems in continuum physics. Notably, in multiphysics applications, it encodes thermodynamic coupling between different fields. It thereby gives rise to driving forces on the dynamics of interaction between the constituent phenomena. In mechano-chemicall...
2002.02305v5
2020-02-11
Direct measurement of temporal correlations above the spin-glass transition by coherent resonant magnetic x-ray spectroscopy
In the 1970s a new paradigm was introduced that interacting quenched systems, such as a spin-glass, have a phase transition in which long time memory of spatial patterns is realized without spatial correlations. The principal methods to study the spin-glass transition, besides some elaborate and elegant theoretical con...
2002.04259v1
2020-02-28
Stability and energetics of 2D surface crystals in liquid AuSi thin films and nanoscale droplets
Segregation at surfaces of metal-covalent binary liquids is often non-classical and in extreme cases such as AuSi, the surface crystallizes above the melting point. In this study, we employ atomic-scale computational frameworks to study the surface crystallization of AuSi films and droplets as a function of composition...
2002.12542v1
2020-03-29
Influence of Pr substitution on physical properties of Ce$_{1-x}$Pr$_x$CoGe$_3$ system: A combined experimental and first-principles study
We present the results of our investigations of physical properties for the novel Ce$_{1-x}$Pr$_x$CoGe$_3$ system performed with a number of experimental methods: magnetic susceptibility, specific heat, electrical resistivity, magnetoresistance, and thermoelectric power. Moreover, the electronic structure was studied b...
2003.13131v3
2020-06-08
Effect of epitaxial strain on the electronic structure and magnetic correlations in infinite-layer (Nd,Sr)NiO$_2$
We present a theoretical study of the effect of electron-electron interactions and Sr doping on the electronic structure of infinite-layer (Nd,Sr)NiO$_2$ using the density functional+dynamical mean-field theory approach. In particular, we explore the impact of epitaxial compressive strain that experience (Nd,Sr)NiO$_2$...
2006.05295v2
2020-06-14
Deformation mechanisms of Inconel-718 at nanoscale by molecular dynamics
Ni-based superalloy Inconel-718 is ubiquitous in metal 3D printing where high cooling rate and thermal gradient are present. These manufacturing conditions are conducive to high initial dislocation density and porosity or void in the material. This work proposes a molecular dynamics (MD) analysis method that can examin...
2006.07973v1
2020-07-21
Atom probe characterisation of segregation driven Cu and Mn-Ni-Si co-precipitation in neutron irradiated T91 tempered-martensitic steel
The T91 grade and similar 9Cr tempered-martensitic steels (also known as ferritic-martensitic) are leading candidate structural alloys for fast fission nuclear and fusion power reactors. At low temperatures (300 to 400 $^\circ$C) neutron irradiation hardens and embrittles these steels, therefore it is important to inve...
2007.10710v1
2020-09-17
High-Throughput Computational-Experimental Screening Protocol for the Discovery of Bimetallic Catalysts
For decades of catalysis research, the d-band center theory that correlates the d-band center and the adsorbate binding energy has successfully enabled the accelerated discovery of novel catalyst materials. Recent studies indicate that, on top of the d-band center value, the full consideration of the d-band shapes desc...
2009.08048v1
2020-09-30
Local and electronic structure of Sr1-xGdxTiO3 probed by X-ray absorption spectroscopy
Gadolinium-doped strontium titanate is a typical perovskite structure material which has been studied due their thermomechanical, termoelectrical and electrochemical properties. In this study, local and electronic structure of Sr1-xGdxTiO3 samples were analyzed through X-ray absorption spectroscopy measurements. The re...
2010.00094v1
2020-10-20
Epitaxial single-crystal growth of transition metal dichalcogenide monolayers via atomic sawtooth Au surface
Growth of two-dimensional van der Waals layered single-crystal (SC) films is highly desired to manifest intrinsic material sciences and unprecedented devices for industrial applications. While wafer-scale SC hexagonal boron nitride film has been successfully grown, an ideal growth platform for diatomic transition metal...
2010.10097v1
2020-11-30
A regime diagram for the slurry F-layer at the base of Earth's outer core
Seismic observations of a slowdown in P wave velocity at the base of Earth's outer core suggest the presence of a stably-stratified region known as the F-layer. This raises an important question: how can light elements that drive the geodynamo pass through the stably-stratified layer without disturbing it? We consider ...
2011.14863v2
2020-12-04
Transition from steady to oscillating convection rolls in Rayleigh-Bénard convection under the influence of a horizontal magnetic field
In this study we consider the effect of a horizontal magnetic field on the Rayleigh-B\'enard convection in a finite liquid metal layer contained in a cuboid vessel (200 \times 200 \times 40 mm^3). Laboratory experiments are performed for measuring temperature and flow field in the alloy GaInSn at Prandtl number Pr = 0....
2012.02714v1
2020-12-08
Superconductivity at 253 K in lanthanum-yttrium ternary hydrides
Polyhydrides offer intriguing perspectives as high-temperature superconductors. Here we report the high-pressure synthesis of a series of lanthanum-yttrium ternary hydrides: cubic hexahydride $(La,Y)H_{6}$ with a critical temperature $T_{C}$ = 237 +/- 5 K and decahydrides $(La,Y)H_{10}$ with a maximum $T_{C}$ ~${253 K}...
2012.04787v1
2020-12-22
Hierarchically nanostructured thermoelectric materials: Challenges and opportunities for improved power factors
The field of thermoelectric materials has undergone a revolutionary transformation over the last couple of decades as a result of the ability to nanostructure and synthesize myriads of materials and their alloys. The ZT figure of merit, which quantifies the performance of a thermoelectric material has more than doubled...
2012.12149v1
2020-12-23
Fluctuations in crystalline plasticity
Recently acoustic signature of dislocation avalanches in HCP materials was found to be long tailed in size and energy, suggesting critical dynamics. Even more recently, the intermittent plastic response was found to be generic for micro- and nano-sized systems independently of their crystallographic symmetry. These rat...
2012.12780v2
2021-01-24
Improved-Sensitivity Integral SQUID Magnetometry of (Ga,Mn)N Thin Films in Proximity to Mg-doped GaN
Nominally 45 nm GaN:Mg/ 5 nm (Ga,Mn)N / 45 nm GaN:Mg trilayers structures prepared by molecular beam epitaxy on GaN-buffered Al2O3 substrates are investigated to verify whether the indirect co-doping by holes from the cladding layers can alter the spin-spin interaction in (Ga,Mn)N. The four investigated structures, dif...
2101.09804v2
2021-01-26
Data-driven design of a new class of rare-earth free permanent magnets
A new class of rare-earth-free permanent magnets is proposed. The parent compound of this class is Co$_3$Mn$_2$Ge, and its discovery is the result of first principles theory combined with experimental synthesis and characterisation. The theory is based on a high-throughput/data-mining search among materials listed in t...
2101.10773v1
2021-01-28
Direct Opto-Electronic Imaging of 2D Semiconductor - 3D Metal Buried Interfaces
The semiconductor-metal junction is one of the most critical factors for high performance electronic devices. In two-dimensional (2D) semiconductor devices, minimizing the voltage drop at this junction is particularly challenging and important. Despite numerous studies concerning contact resistance in 2D semiconductors...
2101.12203v1
2021-02-11
Paraelectric KH$_2$PO$_4$ Nanocrystals in Monolithic Mesoporous Silica: Structure and Lattice Dynamics
Combining dielectric crystals with mesoporous solids allows a versatile design of functional nanomaterials, where the porous host provides a mechanical rigid scaffold structure and the molecular filling adds the functionalization. Here, we report a study of the complex lattice dynamics of a SiO$_2$:KH$_2$PO$_4$ nanocom...
2102.06268v1
2021-02-16
Lattice dynamics of the excitonic insulator Ta$_2$Ni(Se$_{1-x}$S$_x$)$_5$
Recently, we employed electronic polarization-resolved Raman spectroscopy to reveal the strongly correlated excitonic insulator (EI) nature of Ta2NiSe5, Volkov et al. [arXiv:2007.07344], and also showed that for Ta$_2$Ni(Se$_{1-x}$S$_x$)$_5$ alloys the critical excitonic fluctuations diminish with sulfur concentration ...
2102.07912v3
2021-02-26
Damage accumulation during high temperature fatigue of Ti/SiC$_f$ metal matrix composites under different stress amplitudes
The damage mechanisms and load redistribution of high strength TC17 titanium alloy/unidirectional SiC fibre composite (fibre diameter = 100 $\mu$m) under high temperature (350 {\deg}C) fatigue cycling have been investigated in situ using synchrotron X-ray computed tomography (CT) and X-ray diffraction (XRD) for high cy...
2102.13575v1
2021-04-23
Roadmap of spin-orbit torques
Spin-orbit torque (SOT) is an emerging technology that enables the efficient manipulation of spintronic devices. The initial processes of interest in SOTs involved electric fields, spin-orbit coupling, conduction electron spins and magnetization. More recently interest has grown to include a variety of other processes ...
2104.11459v2
2021-06-17
Molecular beam epitaxy of single-crystalline bixbyite (In$_{1-x}$Ga$_x$)$_2$O$_3$ films ($x \leq 0.18$): Structural properties and consequences of compositional inhomogeneity
In this work, we show the heteroepitaxial growth of single-crystalline bixbyite (In$_{1-x}$Ga$_x$)$_2$O$_3$ films on (111)-oriented yttria-stabilized zirconia substrates using plasma-assisted molecular beam epitaxy under various growth conditions. A pure In$_2$O$_3$ buffer layer between the substrate and (In$_{1-x}$Ga$...
2106.09612v1
2021-06-18
Revealing in-plane grain boundary composition features through machine learning from atom probe tomography data
Grain boundaries (GBs) are planar lattice defects that govern the properties of many types of polycrystalline materials. Hence, their structures have been investigated in great detail. However, much less is known about their chemical features, owing to the experimental difficulties to probe these features at the atomic...
2106.10027v1
2021-06-28
Alloying driven transition between ferro- and antiferromagnetism in UTGe compounds: the UCo1-xIrxGe case
The evolution of magnetic properties of isostructural and isoelectronic solid solutions of the superconducting itinerant 5f-electron ferromagnet UCoGe with antiferromagnet UIrGe was studied by magnetization, AC susceptibility, specific heat, and electrical resistivity measurements of a series of UCo1-xIrxGe compounds i...
2106.14502v2
2021-09-16
MEAM parameterization for cyclic and tensile deformations of Gold-Silver core-shell systems
Gold-Silver (Au-Ag) core-shell nanostructures are gaining importance in stretchable electronics where high tensile and fatigue resistance is of paramount importance. This work proposes the parameterization of a modified embedded atomic model (MEAM) interatomic potential through density functional theory (DFT) calculati...
2109.08196v2
2021-09-24
Quantitative Matching of Forensic Evidence Fragments Utilizing 3D Microscopy Analysis of Fracture Surface Replicas
Fractured surfaces carry unique details that can provide an accurate quantitative comparison to support comparative forensic analysis of those fractured surfaces. In this study, a statistical analysis comparison protocol was applied to a set of 3D topological images of fractured surface pairs and their replicas to prov...
2109.11972v1
2021-09-30
Origins of the hydrogen signal in atom probe tomography
Atom Probe Tomography (APT) analysis is being actively used to provide near-atomic-scale information on the composition of complex materials in three-dimensions. In recent years, there has been a surge of interest in the technique to investigate the distribution of hydrogen in metals. However, the presence of hydrogen ...
2109.14981v1
2021-10-07
Mapping Structural Heterogeneity at the Nanoscale with Scanning Nano-structure Electron Microscopy (SNEM)
Here we explore the use of scanning electron diffraction coupled with electron atomic pair distribution function analysis (ePDF) to understand the local order as a function of position in a complex multicomponent system, a hot rolled, Ni-encapsulated, Zr$_{65}$Cu$_{17.5}$Ni$_{10}$Al$_{7.5}$ bulk metallic glass (BMG), w...
2110.03589v4
2021-10-14
A Low Temperature Structural Transition in Canfieldite, Ag$_8$SnS$_6$, Single Crystals
Canfieldite, Ag$_8$SnS$_6$, is a semiconducting mineral notable for its high ionic conductivity, photosensitivity, and low thermal conductivity. We report the solution growth of large single crystals of Ag$_8$SnS$_6$ of mass up to 1 g from a ternary Ag-Sn-S melt. On cooling from high temperature, Ag$_8$SnS$_6$ undergoe...
2110.07508v1
2021-10-19
First principle design of new thermoelectrics from TiNiSn based pentanary alloys based on 18 valence electron rule
In this study, we have reported electronic structure, lattice dynamics, and thermoelectric (TE) transport properties of a new family of pentanary substituted TiNiSn systems using the 18 valence electron count (VEC) rule. From our calculated band structures and density of states, we show that by preserving the 18 VEC th...
2110.09827v1
2021-11-26
Microstructure and correlated mechanical properties study of Ni-(Fe, Co)-Mn-(Al, In) as-spun ribbons
The Ni-Mn-based shape memory alloys as a promising candidate of elastocaloric material has been reported in many literatures, especially on bulk samples. The as-spun ribbon, which has a larger surface area and is more efficient for heat transfer, is rarely studied and hence of importance. In the present work, we succee...
2111.13397v1
2021-11-29
Limited ferromagnetic interactions in monolayers of MPS$_3$ (M=Mn, Ni)
We present a systematic study of the electronic and magnetic properties of two-dimensional ordered alloys, consisting of two representative hosts (MnPS$_3$ and NiPS$_3$) of transition metal phosphorus trichalcogenides doped with $3d$ elements. For both hosts our DFT+U calculations are able to qualitatively reproduce th...
2111.15004v3
2021-12-06
Modified Band Alignment Method to Obtain Hybrid Functional Accuracy from Standard DFT: Application to Defects in Highly Mismatched III-V:Bi Alloys
This paper provides an accurate theoretical defect energy database for pure and Bi-containing III-V (III-V:Bi) materials and investigates efficient methods for high-throughput defect calculations based on corrections of results obtained with local and semi-local functionals. Point defects as well as nearest-neighbor an...
2112.02798v1
2021-12-09
Enhanced superconductivity with possible re-appearance of charge density wave states in polycrystalline Cu$_{1-x}$Ag$_x$Ir$_2$Te$_4$ alloys
In this study, we determined the effect of doping with the noble metal Ag on Ir$_2$Te$_4$ superconductors. Based on the resistivity, magnetization, and heat capacity, we explored the changes in the superconductivity and charge density wave for Cu$_{1-x}$Ag$_x$Ir$_2$Te$_4$ as a function of isoelectric substitution. We a...
2112.04676v1
2021-12-14
Exploring yttrium doped C$_{24}$ fullerene as a high-capacity reversible hydrogen storage material: DFT investigations
By employing the state-of-the-art density functional theory, we report the hydrogen storage capability of yttrium decorated C$_{24}$ fullerene. Single Y atom attached on C$_{24}$ fullerene can reversibly adsorb a maximum number of 6 H$_2$ molecules with average adsorption energy -0.37 eV and average desorption temperat...
2112.07151v2
2021-12-15
The role of solute concentration in interface instability during alloy solidification: A viewpoint from the free energy
Solidification structures are determined by the interaction between the interfacial processes and transport processes of heat and solute. In this paper, we investigate planar instability in directional solidification. Firstly, the interfacial evolution at the initial growth stage is simulated, indicating the planar ins...
2112.07886v7
2022-01-18
A Nanomechanical Testing Framework Yielding Front&Rear-Sided, High-Resolution, Microstructure-Correlated SEM-DIC Strain Fields
The continuous development of new multiphase alloys with improved mechanical properties requires quantitative microstructure-resolved observation of the nanoscale deformation mechanisms at, e.g., multiphase interfaces. This calls for a combinatory approach beyond advanced testing methods such as microscale strain mappi...
2201.08249v2
2022-05-30
Chemical bonding in large systems using projected population analysis from real-space density functional theory calculations
We present an efficient and scalable computational approach for conducting projected population analysis from real-space finite-element (FE) based Kohn-Sham density functional theory calculations (DFT-FE). This work provides an important direction towards extracting chemical bonding information from large-scale DFT cal...
2205.14836v7
2022-08-20
Topological superconductivity in a topological insulator
Topological superconductivity is an exotic quantum phenomenon with coupled nontrivial topological order and superconductivity together. A direct idea for producing topological superconductors is to create superconductivity based on the well recognized topological insulators. The topological insulating states in highly ...
2208.09609v1
2022-09-05
Glassy atomic vibrations and blurry electronic structures created by local structural disorders in high-entropy metal telluride superconductors
The motivation of this work is our recent observation of the robustness of superconductivity in a High-entropy (HE) superconductor Ag0.2In0.2Sn0.2Pb0.2Bi0.2Te (CsCl-type) to external pressure. The superconducting transition temperature (Tc) of Ag0.2In0.2Sn0.2Pb0.2Bi0.2Te is almost constant with pressure, described as r...
2209.01905v1
2022-09-09
Quantitative analysis of thin metal powder layers via transmission X-ray imaging and discrete element simulation: Blade-based spreading approaches
Spreading uniform and dense layers is of paramount importance to creating high-quality components using powder bed additive manufacturing (AM). Blade-like tools are often employed for spreading powder metal feedstocks, especially in laser powder bed fusion and electron beam melting, where powders are characterized by a...
2209.04320v1
2022-09-12
A deep Aurum reservoir: Stable compounds of two bulk-immiscible metals under pressure
The Earth's crust is known to be depleted of gold, among other slightly heavy noble metals transported by magma from the Earth's mantle to the crust. The bulk silicate Earth (BSE) model also suggests significant depletion of Au in the silicate mantle itself, which cannot be explained by the amount of Au in the mantle's...
2209.05652v1
2022-09-22
Computational Discovery of Energy-Efficient Heat Treatment for Microstructure Design using Deep Reinforcement Learning
Deep Reinforcement Learning (DRL) is employed to develop autonomously optimized and custom-designed heat-treatment processes that are both, microstructure-sensitive and energy efficient. Different from conventional supervised machine learning, DRL does not rely on static neural network training from data alone, but a l...
2209.11259v1
2022-11-08
An Incremental Phase Mapping Approach for X-ray Diffraction Patterns using Binary Peak Representations
Despite the huge advancement in knowledge discovery and data mining techniques, the X-ray diffraction (XRD) analysis process has mostly remained untouched and still involves manual investigation, comparison, and verification. Due to the large volume of XRD samples from high-throughput XRD experiments, it has become imp...
2211.04011v1
2022-11-15
Atomic motifs govern the decoration of grain boundaries by interstitial solutes
Grain boundaries, the two-dimensional (2D) defects between differently oriented crystals, control mechanical and transport properties of materials. Our fundamental understanding of grain boundaries is still incomplete even after nearly a century and a half of research since Sorby first imaged grains. Here, we present a...
2211.08261v2
2022-12-16
Electronic Structure and Core Spectroscopy of Scandium Fluoride Polymorphs
The microscopic knowledge of the structural, energetic, and electronic properties of scandium fluoride is still incomplete, despite the relevance of this material as an intermediate for the manufacturing of Al-Sc alloys. In a work based on first-principles calculations and x-ray spectroscopy, we assess the stability an...
2212.08556v2
2023-01-05
Virtual Node Graph Neural Network for Full Phonon Prediction
The structure-property relationship plays a central role in materials science. Understanding the structure-property relationship in solid-state materials is crucial for structure design with optimized properties. The past few years witnessed remarkable progress in correlating structures with properties in crystalline m...
2301.02197v1
2023-01-19
A Cahn-Hilliard phase field model coupled to an Allen-Cahn model of viscoelasticity at large strains
We propose a new Cahn-Hilliard phase field model coupled to incompressible viscoelasticity at large strains, obtained from a diffuse interface mixture model and formulated in the Eulerian configuration. A new kind of diffusive regularization, of Allen-Cahn type, is introduced in the transport equation for the deformati...
2301.08341v1
2023-01-31
A numerical study of the effect of discretization methods on the crystal plasticity finite element method
The present report describes a big data numerical study of crystal plasticity finite element (CPFE) modelling using static and grain-based meshing to investigate the dependence of the results on the discretization approach. Static mesh refers to the integration point-based representation of the microstructure in which ...
2301.13713v1
2023-01-31
Triple Halide Wide Bandgap Perovskites for Efficient Indoor Photovoltaics
Indoor photovoltaics are receiving tremendous attention due to the continuous development of the Internet of Things (IoT). Here we report a triple anion (TA) perovskite CH3NH3PbI2.6(BrCl)0.2 with a tailored bandgap suitable for maximizing indoor light harvesting compared to methyl ammonium lead iodide CH3NH3PbI3. The b...
2301.13772v1
2023-02-16
Observation of Conventional Near Room Temperature Superconductivity in Carbonaceous Sulfur Hydride
The phenomenon of high temperature superconductivity, approaching room temperature, has been realized in a number of hydrogen-dominant alloy systems under high pressure conditions1-12. A significant discovery in reaching room temperature superconductivity is the photo-induced reaction of sulfur, hydrogen, and carbon th...
2302.08622v2
2023-03-01
Thermodynamically consistent non-isothermal phase-field modelling of elastocaloric effect: indirect vs direct method
Modelling elastocaloric effect (eCE) is crucial for the design of environmentally friendly and energy-efficient eCE based solid-state cooling devices. Here, a thermodynamically consistent non-isothermal phase-field model (PFM) coupling martensitic transformation with mechanics and heat transfer is developed and applied...
2303.00309v4
2023-03-08
Modeling the evolution of representative dislocation structures under high thermo-mechanical conditions during Additive Manufacturing of Alloys
Mesoscale simulations of discrete defects in metals provide an ideal framework to investigate the micro-scale mechanisms governing the plastic deformation under high thermal and mechanical loading conditions. To bridge size and time-scale while limiting computational effort, typically the concept of representative volu...
2303.04476v2
2023-03-16
A simply solvable model capturing the approach to statistical self-similarity for the diffusive coarsening of bubbles, droplets, and grains
Aqueous foams and a wide range of related systems are believed to coarsen by gas diffusion between neighboring domains into a statistically self-similar scaling state, after the decay of initial transients, such that dimensionless size and shape distributions become time independent and the average grows as a power law...
2303.09612v2
2023-03-18
Terahertz-to-infrared converters for imaging the human skin cancer: challenges and feasibility
Purpose: The terahertz (THz) medical imaging is a promising noninvasive technique for monitoring the skin's conditions, early detection of the human skin cancer, and recovery from burns and wounds. It can be applied for visualization of healing process directly through clinical dressings and restorative ointments, mini...
2303.10518v1
2023-04-10
In-situ crack and keyhole pore detection in laser directed energy deposition through acoustic signal and deep learning
Cracks and keyhole pores are detrimental defects in alloys produced by laser directed energy deposition (LDED). Laser-material interaction sound may hold information about underlying complex physical events such as crack propagation and pores formation. However, due to the noisy environment and intricate signal content...
2304.04598v1