publicationDate
stringlengths
10
10
title
stringlengths
17
233
abstract
stringlengths
20
3.22k
id
stringlengths
9
12
2018-07-18
2D Tunnel Field Effect Transistors (FETs) with a Stable Charge-Transfer-Type p$^+$-WSe$_2$ Source
Two-dimensional (2D) materials are highly promising for tunnel field effect transistors (TFETs) with low subthreshold swing and high drive current because the shorter tunnel distance and strong gate controllability can be expected from the van der Waals gap distance and the atomically sharp heterointerface formed independently of lattice matching. However, the common problem for 2D-2D TFETs is the lack of highly doped 2D materials with the high process stability as the sources. In this study, we have found that p+-WSe2 doped by charge transfer from a WOx surface oxide layer can be stabilized by transferring it onto a h-BN substrate. Using this p$^+$-WSe$_2$ as a source, we fabricate all-solid-state 2D-2D heterostructure TFETs with an Al2O3 top gate insulator, i.e., type-II p$^+$-WSe$_2$ /MoS$_2$ and type-III p$^+$-WSe$_2$ /WSe$_2$. The band-to-band tunneling and negative differential resistance trends are clearly demonstrated at low temperatures. This work suggests that high doped 2D crystal of the charge transfer type is an excellent choice as sources for TFETs.
1807.06762v1
2019-10-14
Plasmonic Titanium Nitride via Atomic Layer Deposition: A Low-Temperature Route
To integrate plasmonic devices into industry, it is essential to develop scalable and CMOS compatible plasmonic materials. In this work, we report high plasmonic quality titanium nitride (TiN) on c-plane sapphire by plasma enhanced atomic layer deposition (PE-ALD). TiN with low losses and high metallicity was achieved at temperatures below 500{\deg}C, by exploring the effects of chemisorption time, substrate temperature and plasma exposure time on material properties. Reduction in chemisorption time mitigates premature precursor decomposition at T_S > 375{\deg}C , and a trade-off between reduced impurity concentration and structural degradation caused by plasma bombardment is achieved for 25s plasma exposure. 85 nm thick TiN films grown at a substrate temperature of 450{\deg}C, compatible with CMOS processes, with 0.5s chemisorption time and 25s plasma exposure exhibited a high plasmonic figure of merit (|{\epsilon}^'/{\epsilon}^''|) of 2.8 and resistivity of 31 {\mu}{\Omega}-cm. These TiN thin films fabricated with subwavelength apertures were shown to exhibit extraordinary transmission.
2001.05063v1
2021-06-26
High Infrared Reflectance Modulation in VO2 Films Synthesized on Glass and ITO coated Glass substrates using Atmospheric Oxidation of Vanadium
Vanadium Dioxide (VO2) is a strongly correlated material, which exhibits insulator to metal transition at ~68 C along with large resistivity and infrared optical reflectance modulation. In this work, we use atmospheric pressure thermal oxidation of Vanadium to synthesize VO2 films on glass and ITO coated glass substrates. With the optimized short oxidation durations of 2 min and 4 min, the synthesized VO2 film shows high optical reflectance switching in long-wavelength infrared on glass substrates and mid-wavelength infrared on ITO coated glass substrates, respectively. Peak reflectance switching values of ~76% and ~79% are obtained on the respective substrates, which are among the highest reported values. Using the reflectance data, we extract VO2 complex refractive index in infrared wavelengths, in both the insulating and metallic phases. The extracted refractive index shows good agreement with VO2 synthesized using other methods. This demonstration of high optical reflectance switching in VO2 thin films, grown on low cost glass and ITO coated glass substrates, using a simple low thermal budget process will aid in enhancing VO2 applications in the optical domain.
2106.14006v1
2022-04-11
Emergent superconductivity in van der Waals Kagome material Pd3P2S8 under high pressure
Kagome lattice systems have been proposed to host rich physics, which provide an excellent platform to explore unusual quantum states. Here, we report on the discovery of superconductivity in van der Waals material Pd3P2S8 under pressure. The superconductivity is observed in Pd3P2S8 for those pressures where the temperature dependence of the resistivity changes from a semiconducting-like behavior to that of a normal metal. The superconducting transition temperature Tc increases with applied pressure and reaches ~ 6.83 K at 79.5 GPa. Combining high-pressure XRD, Raman spectroscopy and theoretical calculations, our results demonstrate that the observed superconductivity induced by high pressure in Pd3P2S8 is closely related to the formation of amorphous phase, which results from the structural instability due to the enhanced coupling between interlayer Pd and S atoms upon compression.
2204.05179v1
2001-07-21
Distinct origins of magnetic -field -induced resistivity irreversibility in two manganites with similar ground states : Pr$_{0.5}$Sr$_{0.41}$Ca$_{0.09}$MnO$_{3}$ and La$_{0.5}$Ca$_{0.5}$MnO$_{3}$
Our investigation of the magnetotransport in two charge ordered manganites with similar magnetic ground states reveals that the origin of magnetoresistance can not be concluded from the isofield resistivity, $\rho $(T, constant H), measurements alone. Both Pr$_{0.5}$Sr$_{0.41}$Ca$_{0.09}$MnO$_{3}$ (PrSrCa) and La$_{0.5}$Ca$_{0.5}$MnO$_{3}$ (LaCa) show a ferromagnetic transition (T$_{C}$ = 260 K for PrSrCa, 230 K for LaCa) followed by an antiferromagnetic transition (T$_{N}$ = 170 K for PrSrCa, 140 K for LaCa). These compounds show qualitatively similar magnetotransport : Below the irreversibility temperature T$_{IR}$, field cooled (FC) resistivity is lower than zero field cooled (ZFC) and decreases continuously with T, whereas the ZFC $\rho $(T, H) resembles $\ $the behavior of $\rho $(T, H = 0 T). The value of $\rho $(ZFC)/$\rho $(FC) is $\approx $ 10$^{4}$ at 5 K and $\mu_{0}$H = 7 T in both compounds. However, isothermal magnetic measurements suggest distinct origins of magnetoresistance : Field cooling enhances ferromagnetic phase fraction in LaCa whereas it drives PrSrCa into a metastable state with high magnetization. The distinct origins of magnetotransport is also reflected in other magnetic history dependent properties.
0107448v1
2006-09-15
Magneto Transport of high TCR (temperature coefficient of resistance) La2/3Ca1/3MnO3: Ag Polycrystalline Composites
We report the synthesis, (micro)structural, magneto-transport and magnetization of polycrystalline La2/3Ca1/3MnO3:Agx composites with x = 0.0, 0.1, 0.2, 0.3 and 0.4. The temperature coefficient of resistance (TCR) near ferromagnetic (FM) transition is increased significantly with addition of Ag. The FM transition temperature (TFM) is also increased slightly with Ag addition. Magneto-transport measurements revealed that magneto-resistance MR is found to be maximum near TFM. Further the increased MR of up to 60% is seen above 300 K for higher silver added samples in an applied field of 7 Tesla. Sharp TCR is seen near TFM with highest value of up to 15 % for Ag (0.4) sample, which is an order of magnitude higher than as for present pristine sample and best value yet reported for any polycrystalline LCMO compound. Increased TCR, TFM and significant above room temperature MR of La2/3Ca1/3MnO3:Agx composites is explained on the basis of improved grains size and connectivity with silver addition in the matrix. Better coupled FM domains and nearly conducting grain boundaries give rise to improved physical properties of the La2/3Ca1/3MnO3 manganites.
0609364v1
2007-09-05
Microwave surface resistance of pristine and neutron-irradiated MgB2 samples in magnetic field
We report on the microwave surface resistance of two polycrystalline Mg11B2 samples; one consists of pristine material, the other has been irradiated at very high neutron fluence. It has already been reported that in the strongly irradiated sample the two gaps merge into a single value. The mw surface resistance has been measured in the linear regime as a function of the temperature and the DC magnetic field, at increasing and decreasing fields. The results obtained in the strongly irradiated sample are quite well justified in the framework of a generalized Coffey and Clem model, in which we take into account the field distribution inside the sample due to the critical state. The results obtained in the pristine sample show several anomalies, especially at low temperatures, which cannot be justified in the framework of standard models for the fluxon dynamics. Only at temperatures near Tc and for magnetic fields greater than 0.5Hc2(T) the experimental data can quantitatively be accounted for by the Coffey and Clem model, provided that the upper-critical-field anisotropy is taken into due account.
0709.0618v2
2008-02-12
Two-Fluid Behaviour at the Origin of the Resistivity Peak in Doped Manganites
We report a series of magnetic and transport measurements on high-quality single crystal samples of colossal magnetoresistive manganites, La_{0.7} Ca_{0.3} Mn O_3 and Pr_{0.7} Sr_{0.3} Mn O_3. 1 % Fe doping allows a Moessbauer spectroscopy study, which shows (i) unusual line broadening within the ferromagnetic phase and (ii) a coexistence of ferro- and paramagnetic contributions in a region, T_1<T<T_2, around the Curie point T_C. In the case of Pr_{0.7} Sr_{0.3} Mn O_3, the resistivity peak occurs at a considerably higher temperature, T_{MI}>T_2. This shows that phase separation into metallic (ferromagnetic) and insulating (paramagnetic) phases cannot be generally responsible for the resistivity peak (and hence for the associated colossal magnetoresistance). Our results can be understood phenomenologically within the two-fluid approach, which also allows for a difference between T_C and T_{MI}. Our data indeed imply that while magnetic and transport properties of the manganites are closely interrelated, the two transitions at T_C and T_{MI} can be viewed as distinct phenomena.
0802.1664v3
2008-06-15
Anisotropy in the electrical resistivity and susceptibility of superconducting BaFe$_{2}$As$_{2}$ single crystals
Sizable single crystals of $BaFe_2As_2$ have been grown with self-flux method. The crystals are plate-like with c-axis perpendicular to the plane. The size can be as large as 3 x 5 x 0.2 $mm^3$. The resistivity anisotropy ($\rho_c/\rho_{ab}$) is as large as about 150, and independent of temperature. The transport in ab plane and along c-axis direction shares the same scattering mechanism. In contrast to the magnetic behavior of polycrystalline samples, no Curie-Weiss behavior are observed, a temperature linear dependent susceptibility occurs above spin-density-wave (SDW) transition. The susceptibility behavior is very similar to that of antiferromagnetic SDW chromium. Magnetic behavior of single crystal definitely gives evidence for existence of local moment except for the contribution to susceptibility from itinerant electrons. A resistivity minimum strongly dependent on magnetic field is observed. A log(1/T) divergency, similar to that of the underdoped cuprates, happens at low temperature. Here we first present intrinsic transport and magnetic properties, and their anisotropy from high quality single crystal.
0806.2452v2
2008-10-01
Qualitative explanation of the temperature behaviors of the transport properties and magnetic susceptibility of high-temperature superconductors in the normal state
A model based on the alternating structure of the imbedded conduction layers (the Cu-O2 planes) with the charge-transfer-insulator (CTI) layers is proposed. There are three kinds of carriers, each with a different behavior: conduction-like holes in the Cu-O2 layers and electrons and normal holes in the CTI matrix between the Cu-O2 layers. This structure explains the strong anisotropies. The relationship is obtained between the concentration nq of conduction-like holes in the Cu-O2 layers and the temperature T. The anomalous temperature behavior of the resistivity as well as the Hall constant also follows. We give the hole density in ab plane a definite physical meaning, and also define explicitly optimal doping, overdoping and underdoping. Our model gives the correct temperature dependence of the resistivity and the hole constant on optimal doping, overdoping and underdoping, and it predicts the temperature behavior of the cotangent of the Hall angle quite well. Based on this model, we can also understand that the HiTc materials become "Fermi Liquids" in the extremely overdoped region, and the dR/dT becomes negative below some temperature T<1.211T0 in the underdoped case. Based on this model, the thermal behaviors of the magnetic susceptibility in different doping can also be easily explained. The resistivity along c-axis is discussed.
0810.0169v2
2011-01-29
Crystal structure, physical properties and superconductivity in $A_{x}$Fe$_2$Se$_2$ single crystals
We studied the correlation among structure and transport properties and superconductivity in the different $A_x$Fe$_2$Se$_2$ single crystals ($A$ = K, Rb, and Cs). Two sets of (00$l$) reflections are observed in the X-ray single crystal diffraction patterns, and arise from the intrinsic inhomogeneous distribution of the intercalated alkali atoms. The occurrence of superconductivity is closely related to the {\sl c}-axis lattice constant, and the $A$ content is crucial to superconductivity. The hump observed in resistivity seems to be irrelevant to superconductivity. There exist many deficiencies within the FeSe layers in $A_x$Fe$_2$Se$_2$, while their $T_{\rm c}$ does not change so much. In this sense, superconductivity is robust to the Fe and Se vacancies. Very high resistivity in the normal state should arise from such defects in the conducting FeSe layers. $A_x$Fe$_2$Se$_2$ ($A$ = K, Rb, and Cs) single crystals show the same susceptibility behavior in the normal state, and no anomaly is observed in susceptibility at the hump temperature in resistivity. The clear jump in specific heat for Rb$_x$Fe$_2$Se$_2$ and K$_x$Fe$_2$Se$_2$ single crystals shows the good bulk superconductivity in these crystals.
1101.5670v1
2011-03-04
Measurements of thermodynamic and transport properties of EuC$_2$: a low-temperature analogue of EuO
EuC$_2$ is a ferromagnet with a Curie-temperature of $T_C \simeq 15\,$K. It is semiconducting with the particularity that the resistivity drops by about 5 orders of magnitude on cooling through $T_C$, which is therefore called a metal-insulator transition. In this paper we study the magnetization, specific heat, thermal expansion, and the resistivity around this ferromagnetic transition on high-quality EuC$_2$ samples. At $T_C$ we observe well defined anomalies in the specific heat $c_p(T)$ and thermal expansion $\alpha(T)$ data. The magnetic contributions of $c_p(T)$ and $\alpha(T)$ can satisfactorily be described within a mean-field theory, taking into account the magnetization data. In zero magnetic field the magnetic contributions of the specific heat and thermal expansion fulfill a Gr\"uneisen-scaling, which is not preserved in finite fields. From an estimation of the pressure dependence of $T_C$ via Ehrenfest's relation, we expect a considerable increase of $T_C$ under applied pressure due to a strong spin-lattice coupling. Furthermore the influence of weak off stoichiometries $\delta$ in EuC$_{2 \pm \delta}$ was studied. It is found that $\delta$ strongly affects the resistivity, but hardly changes the transition temperature. In all these aspects, the behavior of EuC$_2$ strongly resembles that of EuO.
1103.0980v1
2012-07-13
Synthesis and acid resistance of maya blue pigment
Maya blue is an organo-clay artificial pigment composed of indigo and palygorskite. It was invented and frequently used in Mesoamerica in ancient times (eighth to 16th centuries). We analyse in this paper one of the characteristics of Maya blue that has attracted the attention of scientists since its rediscovery in 1931: its high stability against chemical aggression (acids, alkalis, solvents, etc.) and biodegradation, which has permitted the survival of many works of art for centuries in hostile environments, such as the tropical forest. We have reproduced the different methods proposed to produce a synthetic pigment with the characteristics of the ancient Maya blue. The stability of the pigments produced using either palygorskite or sepiolite has been analysed by performing acid attacks of different intensities. The results are analysed in terms of pigment decolouration and destruction of the clay lattice, revealed by X-ray diffraction. Palygorskite pigments are much more resistant than sepiolite pigments. It is shown that indigo does not protect the clay lattice against acid aggression. We show that Maya blue is an extremely resistant pigment, but it can be destroyed using very intense acid treatment under reflux.
1207.3229v1
2013-04-07
Quasi-classical physics and T-linear resistivity in both strongly correlated and ordinary metals
We show that near a quantum critical point generating quantum criticality of strongly correlated metals where the density of electron states diverges, the quasi-classical physics remains applicable to the description of the resistivity \rho of strongly correlated metals due to the presence of a transverse zero-sound collective mode, reminiscent of the phonon mode in solids. We demonstrate that at T, being in excess of an extremely low Debye temperature T_D, the resistivity \rho(T) changes linearly with T, since the mechanism, forming the T dependence of \rho(T), is the same as the electron-phonon mechanism that prevails at high temperatures in ordinary metals. Thus, electron-phonon scattering leads to near material-independence of the lifetime \tau of quasiparticles that is expressed as the ratio of the Planck constant \hbar to the Boltzmann constant k_B, T\tau\sim \hbar/k_B. We find that at T<T_D there exists a different mechanism, maintaining the T-linear dependence of \rho(T), and making the constancy of \tau fail in spite of the presence of T-linear dependence. Our results are in good agreement with exciting experimental observations.
1304.2068v4
2013-09-13
1/f noise in graphene
We present a novel and comprehensive model of 1/f noise in nanoscale graphene devices that accounts for the unusual and so far unexplained experimental characteristics. We find that the noise power spectral density versus carrier concentration of single-layer sheet devices has a behavior characterized by a shape going from the M to the Gamma type as the material inhomogeneity increases, whereas the shape becomes of V type in bilayer sheet devices for any inhomogeneity, or of M type at high carrier concentration. In single-layer nanoribbons, instead, the ratio of noise to resistance versus the latter quantity is approximately constant, whereas in the bilayer case it exhibits a linear decrease on a logarithmic scale as resistance increases and its limit for zero resistance equals the single-layer value. Noise at the Dirac point is much greater in single-layer than in bilayer devices and it increases with temperature. The origin of 1/f noise is attributed to the traps in the device and to their relaxation time dispersion. The coupling of trap charge fluctuations with the electrode current is computed according to the electrokinematics theorem, by taking into account their opposite effects on electrons and holes as well as the device inhomogeneities. The results agree well with experiments.
1309.3420v1
2014-09-19
Absence of a quantum limit to charge diffusion in bad metals
Good metals are characterised by diffusive transport of coherent quasi-particle states and the resistivity is much less than the Mott-Ioffe-Regel (MIR) limit, $\frac{ha}{e^{2}}$, where $a$ is the lattice constant. In bad metals, such as many strongly correlated electron materials, the resistivity exceeds the Mott-Ioffe-Regel limit and the transport is incoherent in nature. Hartnoll, loosely motivated by holographic duality (AdS/CFT correspondence) in string theory, recently proposed a lower bound to the charge diffusion constant, $D \gtrsim \hbar v_{F}^{2}/(k_{B}T)$, in the incoherent regime of transport, where $v_F$ is the Fermi velocity and $T$ the temperature. Using dynamical mean field theory (DMFT) we calculate the charge diffusion constant in a single band Hubbard model at half filling. We show that in the strongly correlated regime the Hartnoll's bound is violated in the crossover region between the coherent Fermi liquid region and the incoherent (bad metal) local moment region. The violation occurs even when the bare Fermi velocity $v_F$ is replaced by its low temperature renormalised value, $v_F^*$.The bound is satisfied at all temperatures in the weakly and moderately correlated systems as well as in strongly correlated systems in the high temperature region where the resistivity is close to linear in temperature. Our calculated charge diffusion constant, in the incoherent regime of transport, also strongly violates a proposed quantum limit of spin diffusion, $D_{s} \sim 1.3 \hbar/m$, where $m$ is the fermion mass, experimentally observed and theoretically calculated in a cold degenerate Fermi gas in the unitary limit of scattering.
1409.5662v2
2016-05-26
Fast suppression of superconductivity with Fe site Ni substitution in Fe1-xNixSe0.5Te0.5 (x=0.0, 0.01, 0.03, 0.05, 0.07, 0.10 and 0.20) single crystals
We report the effect of Ni doping on superconductivity of FeSe0.5Te0.5. The single crystal samples of series Fe1-xNixSe0.5Te0.5 (x=0.0, 0.01, 0.03, 0.05, 0.07, 0.10 and 0.20) are synthesized via vacuum shield solid state reaction route and high temperature heating followed by slow cooling. All the crystals of Fe1-xNixSe0.5Te0.5 series with x up to 0.20, i.e., 20% substitution of Ni at Fe site are crystallized in single phase tetragonal structure with space group P4/nmm. The electrical resistivity measurements revealed that Tc decreases fast with increase of Ni concentration in Fe1-xNixSe0.5Te0.5. Namely the superconducting transition temperature (Tc) being defined as resistivity =0 decrease from 12K to around 4K and 2K for x=0.01 and 0.03 samples respectively. For x=0.05 (5at% Ni at Fe site) though Tconset is observed in resistivity measurements but \r{ho}=0 is not seen down to 2K. For x more than 0.07, neither the Tconset nor Tc\r{ho}=0 is seen down 2K in R-T measurements. It is demonstrated that Ni doping at Fe site in FeSe0.5Te0.5 superconductor suppresses superconductivity fast. The rate of Tc depression is albeit non monotonic. Summarily, a systematic study on suppression of superconductivity with Fe site Ni doping in flux free gown FeSe0.5Te0.5 single crystals is presented in the current communication.
1605.08217v2
2016-06-23
Resistive properties and phase diagram of the organic antiferromagnetic metal $κ$-(BETS)$_2$FeCl$_4$
The low-temperature electronic state of the layered organic charge-transfer salt $\kappa$-(BETS)$_2$FeCl$_4$ was probed by interlayer electrical resistance measurements under magnetic field. Both above and below $T_{\mathrm{N}}=0.47\,$K, the temperature of antiferromagnetic ordering of $3d$-electron spins of Fe$^{3+}$ localized in the insulating anion layers, a non-saturating linear $R(T)$ dependence has been observed. A weak superconducting signal has been detected in the antiferromagnetic state, at temperatures $\leq 0.2\,$K. Despite the very high crystal quality, only a tiny fraction of the sample appears to be superconducting. Besides a small kink feature in the resistivity, the impact of the antiferromagnetic ordering of localized Fe$^{3+}$ spins on the conduction $\pi$-electron system is clearly manifested in the Fermi surface reconstruction, as evidenced by Shubnikov-de Haas oscillations. The "magnetic field -- temperature" phase diagrams for the field directions parallel to each of the three principal crystal axes have been determined. For magnetic field along the easy axis a spin-flop transition has been found. Similarities and differences between the present material and the sister compound $\kappa$-(BETS)$_2$FeBr$_4$ are discussed.
1606.07331v3
2016-10-28
Asymmetric pentagonal metal meshes for flexible transparent electrodes and heaters
Metal meshes have emerged as an important class of flexible transparent electrodes. We report on the characteristics of a new class of asymmetric meshes, tiled using a recently-discovered family of pentagons. Micron-scale meshes were fabricated on flexible polyethylene terephthalate substrates via optical lithography, metal evaporation (Ti 10 nm, Pt 50 nm) and lift-off. Three different designs were assessed, each with the same tessellation pattern and linewidth (5 micron), but with different sizes of the fundamental pentagonal unit. The designs corresponded to areal coverage of the metal patterns of 27% (Design#1), 14% (Design#2) and 9% (Design#3), respectively. Good mechanical stability was observed for both tensile strain and compressive strain. After 1,000 bending cycles, devices subjected to tensile strain showed fractional resistance increases in the range 8% to 17% with the lowest changes observed for Design#2. Devices subjected to compressive strain showed fractional resistance increases in the range 0% to 7% with best results observed for Design#1. The performance of the pentagonal metal mesh devices as visible transparent heaters via Joule heating was also assessed. A saturation temperature of 88 +/- 1 degrees C was achieved at low voltage (5 V) with a fast response time (~ 20 s) and a high thermal resistance (168 +/- 6 degrees C cm2/W). Finally, de-icing was successfully demonstrated (45 s at 5 V) for an ice layer on a glass coupon placed on top of the PET substrate.
1611.02744v1
2018-11-06
Metallic surface states in a correlated d-electron topological Kondo insulator candidate FeSb2
The resistance of a conventional insulator diverges as temperature approaches zero. The peculiar low temperature resistivity saturation in the 4f Kondo insulator (KI) SmB6 has spurred proposals of a correlation-driven topological Kondo insulator (TKI) with exotic ground states. However, the scarcity of model TKI material families leaves difficulties in disentangling key ingredients from irrelevant details. Here we use angle-resolved photoemission spectroscopy (ARPES) to study FeSb2, a correlated d-electron KI candidate that also exhibits a low temperature resistivity saturation. On the (010) surface, we find a rich assemblage of metallic states with two-dimensional dispersion. Measurements of the bulk band structure reveal band renormalization, a large temperature-dependent band shift, and flat spectral features along certain high symmetry directions, providing spectroscopic evidence for strong correlations. Our observations suggest that exotic insulating states resembling those in SmB6 and YbB12 may also exist in systems with d instead of f electrons.
1811.02183v3
2016-03-09
Quantization of Hall Resistance at the Metallic Interface between an Oxide Insulator and SrTiO$_{3}$
The two-dimensional metal forming at the interface between an oxide insulator and SrTiO3 provides new opportunities for oxide electronics. However, the quantum Hall effect, one of the most fascinating effects of electrons confined in two dimensions, remains underexplored at these complex oxide heterointerfaces. Here, we report the experimental observation of quantized Hall resistance in a SrTiO3 heterointerface based on the modulation-doped amorphous-LaAlO$_{3}$/SrTiO$_{3}$ heterostructure, which exhibits both high electron mobility exceeding 10000 cm$^{2}$/Vs and low carrier density on the order of ~10$^{12}$ cm$^{-2}$. Along with unambiguous Shubnikov-de Haas oscillations, the spacing of the quantized Hall resistance suggests that the interface is comprised of a single quantum well with ten parallel conducting two-dimensional subbands. This provides new insight into the electronic structure of conducting oxide interfaces and represents an important step towards designing and understanding advanced oxide devices.
1603.02850v2
2017-07-21
Electrical characterization of structured platinum diselenide devices
Platinum diselenide (PtSe2) is an exciting new member of the two-dimensional (2D) transition metal dichalcogenide (TMD) family. it has a semimetal to semiconductor transition when approaching monolayer thickness and has already shown significant potential for use in device applications. Notably, PtSe2 can be grown at low temperature making it potentially suitable for industrial usage. Here, we address thickness dependent transport properties and investigate electrical contacts to PtSe2, a crucial and universal element of TMD-based electronic devices. PtSe2 films have been synthesized at various thicknesses and structured to allow contact engineering and the accurate extraction of electrical properties. Contact resistivity and sheet resistance extracted from transmission line method (TLM) measurements are compared for different contact metals and different PtSe2 film thicknesses. Furthermore, the transition from semimetal to semiconductor in PtSe2 has been indirectly verified by electrical characterization of field-effect devices. Finally, the influence of edge contacts at the metal - PtSe2 interface has been studied by nanostructuring the contact area using electron beam lithography. By increasing the edge contact length, the contact resistivity was improved by up to 70% compared to devices with conventional top contacts. The results presented here represent crucial steps towards realizing high-performance nanoelectronic devices based on group-10 TMDs.
1707.06824v1
2017-08-06
Electric-field-induced extremely large change in resistance in graphene ferromagnets
A colossal magnetoresistance ($\sim 100\times10^3\%$) and an extremely large magnetoresistance ($\sim 1\times10^6\%$) have been previously explored in manganite perovskites and Dirac materials, respectively. However, the requirement of an extremely strong magnetic field (and an extremely low temperature) makes them not applicable for realistic devices. In this work, we propose a device that can generate even larger changes in resistance in a zero-magnetic field and at a high temperature. The device is composed of a graphene under two strips of yttrium iron garnet (YIG), where two gate voltages are applied to cancel the heavy charge doping in the YIG-induced half-metallic ferromagnets. By calculations using the Landauer-B\"{u}ttiker formalism, we demonstrate that, when a proper gate voltage is applied on the free ferromagnet, changes in resistance up to $305\times10^6\%$ ($16\times10^3\%$) can be achieved at the liquid helium (nitrogen) temperature and in a zero magnetic field. We attribute such a remarkable effect to a gate-induced full-polarization reversal in the free ferromagnet, which results in a metal-state to insulator-state transition in the device. We also find that, the proposed effect can be realized in devices using other magnetic insulators such as EuO and EuS. Our work should be helpful for developing a realistic switching device that is energy saving and CMOS-technology compatible.
1708.01858v2
2018-08-30
Metallic glasses for spintronics: anomalous temperature dependence and giant enhancement of inverse spin Hall effect
Spin-charge conversion via inverse spin Hall effect (ISHE) is essential for enabling various applications of spintronics. The spin Hall response usually follows a universal scaling relation with longitudinal electric resistivity and has mild temperature dependence because elementary excitations play only a minor role in resistivity and hence ISHE. Here we report that the ISHE of metallic glasses shows nearly two orders of magnitude enhancements with temperature increase from a threshold of 80-100 K to glass transition points. As electric resistivity changes only marginally in the temperature range, the anomalous temperature dependence is in defiance of the prevailing scaling law. Such a giant temperature enhancement can be well described by a two-level thermal excitation model of glasses and disappears after crystallization, suggesting a new mechanism which involves unique thermal excitations of glasses. This finding may pave new ways to achieve high spin-charge conversion efficiency at room and higher temperatures for spintronic devices and to detect structure and dynamics of glasses using spin currents.
1808.10371v1
2018-07-06
MRPC3b mass production for CBM-TOF and eTOF at STAR
The Compressed Baryonic Matter (CBM) spectrometer aims to study strongly interacting matter under extreme conditions. The key element providing hadron identification at incident energies between 2 and 11 AGeV in heavy-ion collisions at the SIS100 accelerator is a Time-of-Flight (TOF) wall covering the polar angular range from $2.5^0$ --$25^0$ and full azimuth. CBM is expected to be operational in the year 2024 at the Facility for Anti-proton and Ion Research (FAIR) in Darmstadt, Germany. The existing conceptual design foresees a 120 m^2 TOF-wall composed of Multi-gap Resistive Plate Chambers (MRPC) which is subdivided into a high rate region, a middle rate region and a low rate region. The MRPC3b Multistrip-MRPCs, foreseen to be integrated in the low rate region, have to cope with charged particle fluxes up to 1 kHz/cm2 and therefore will be constructed with thin float glass (0.28 mm thickness) as resistive electrode material. In the scope of the FAIR phase 0 program it is planned to install about 36 \% of the MRPC3b counters in the east endcap region of the STAR experiment at BNL as an upgrade for the Beam Energy Scan campaign (BESII) in 2019/2020.
1807.02452v1
2019-01-03
Study of electrostatic septum design and its high-voltage discharge protection
In this paper, we introduce the design of electrostatic septum (ESS) for the accelerator of Shanghai Advanced Proton Therapy (SAPT), and discuss its mechanical structure and the material selection of the electrode. The beam loss on the septum is studied, and the calculation results are given by the particle simulation and by the formula which is related to the placement angle and the divergence angle in the horizontal direction. Considering the thermal effect of the beam loss on the head of the septum, the equilibrium temperature at work is calculated. In addition, the distribution of the electric field and the trajectory of the particles are also simulated. The phenomenon of vacuum discharge in the working ESS is analyzed in detail on the relationship between the working current and the enhancement factor of the electric field on the electrode surface. Based on the discharge mechanism, the importance of degassing and cleaning of ESS is analyzed. We also analyzed the effect of external series resistance from circuit and discharge mechanism. It is considered that series resistance within a certain range can increase the breakdown voltage between vacuum electrodes and reduce the irreversible damage to the surface of the electrode system caused by the discharge process. The formula for the value of the resistance is given.
1901.00646v3
2020-05-17
Remarkable low-energy properties of the pseudogapped semimetal Be$_5$Pt
We report measurements and calculations on the properties of the intermetallic compound Be$_5$Pt. High-quality polycrystalline samples show a nearly constant temperature dependence of the electrical resistivity over a wide temperature range. On the other hand, relativistic electronic structure calculations indicate the existence of a narrow pseudogap in the density of states arising from accidental approximate Dirac cones extremely close to the Fermi level. A small true gap of order 3 meV is present at the Fermi level, yet the measured resistivity is nearly constant from low to room temperature. We argue that this unexpected behavior can be understood by a cancellation of the energy dependence of density of states and relaxation time due to disorder, and discuss a model for electronic transport. With applied pressure, the resistivity becomes semiconducting, consistent with theoretical calculations that show that the band gap increases with applied pressure. We further discuss the role of Be inclusions in the samples.
2005.08327v2
2021-04-19
Various magnetism of the compressed antiferromagnetic topological insulator EuSn2As2
We report a comprehensive high-pressure study on the antiferromagnetic topological insulator EuSn2As2 up to 21.1 GPa through measurements of synchrotron x-ray diffraction, electrical resistance, magnetic resistance, and Hall transports combined with first-principles calculations. No evident trace of a structural phase transition is detected. The Neel temperatures determined from resistance are increased from 24 to 77 K under pressure, which is resulted from the enhanced magnetic exchange couplings between Eu2+ ions yielded by our first-principles calculations. The negative magnetoresistance of EuSn2As2 persists to higher temperatures accordantly. However, the enhancement of the observed N\'eel temperatures deviates from the calculations obviously above 10.0 GPa. In addition, the magnitude of the magnetoresistance, the Hall coefficients, and the charge carrier densities show abrupt changes between 6.9 to 10.0 GPa. The abrupt changes probably originate from a pressure induced valence change of Eu ions from a divalent state to a divalent and trivalent mixed state. Our results provide insights into variation of the magnetism of EuSn2As2 and similar antiferromagnetic topological insulators under pressure.
2104.09412v1
2021-04-20
Properties of MoO2 and MoO3 Films Prepared from the Chemically Driven Isothermal Close Space Vapor Transport Technique
Chemically _ driven isothermal close space vapour transport was used to prepare pure MoO2 films which were eventually converted to MoO3 by annealing in air. According to temperature_dependent Raman measurements, the MoO2/MoO3 phase transformation was found to occur in the 225 _ 350 oC range; no other phases were detected during the transition. A clear change in composition and Raman spectra, as well as noticeable modifications of the band gap and the absorption coefficient confirmed the conversion from MoO2 to MoO3. An extensive characterization of films of both pure phases was carried out. In particular, a procedure was developed to determine the dispersion relation of the refractive index of MoO2 from the shift of the interference fringes the used SiO2/Si substrate. The obtained refractive index was corrected taking into account the porosity calculated from elastic backscattering spectrometry. The Debye temperature and the residual resistivity were extracted from the electrical resistivity temperature dependence using the Bloch _ Gruneisen equation. MoO3 converted samples presented very high resistivity and a typical semiconducting behaviour. They also showed intense and broad luminescence spectra, which were deconvoluted considering several contributions; and its behaviour with temperature was examined. Furthermore, surface photovoltage spectra were taken and the relation of these spectra with the photoluminescence is discussed.
2104.10245v1
2021-08-21
Evolution of superconductivity and charge order in pressurized RbV$_3$Sb$_5$
The kagome metals $A$V$_3$Sb$_5$ ($A=$ K, Rb, Cs) under ambient pressure exhibit an unusual charge order, from which superconductivity emerges. In this work, by applying hydrostatic pressure using a liquid pressure medium and carrying out electrical resistance measurements for RbV$_3$Sb$_5$, we find the charge order becomes suppressed under a modest pressure $p_{\rm c}$ ($1.4<p_{\rm c}<1.6$ GPa), while the superconducting transition temperature $T_{\rm c}$ is maximized. $T_{\rm c}$ is then gradually weakened with further increase of pressure and reaches a minimum around 14.3 GPa, before exhibiting another maximum around 22.8 GPa, signifying the presence of a second superconducting dome. Distinct normal state resistance anomalies are found to be associated with the second superconducting dome, similar to KV$_3$Sb$_5$. Our findings point to qualitatively similar temperature-pressure phase diagrams in KV$_3$Sb$_5$ and RbV$_3$Sb$_5$, and suggest a close link between the second superconducting dome and the high-pressure resistance anomalies.
2108.09434v2
2021-08-22
Explainable Machine Learning using Real, Synthetic and Augmented Fire Tests to Predict Fire Resistance and Spalling of RC Columns
This paper presents the development of systematic machine learning (ML) approach to enable explainable and rapid assessment of fire resistance and fire-induced spalling of reinforced concrete (RC) columns. The developed approach comprises of an ensemble of three novel ML algorithms namely; random forest (RF), extreme gradient boosted trees (ExGBT), and deep learning (DL). These algorithms are trained to account for a wide collection of geometric characteristics and material properties, as well as loading conditions to examine fire performance of normal and high strength RC columns by analyzing a comprehensive database of fire tests comprising of over 494 observations. The developed ensemble is also capable of presenting quantifiable insights to ML predictions; thus, breaking free from the notion of 'blackbox' ML and establishing a solid step towards transparent and explainable ML. Most importantly, this work tackles the scarcity of available fire tests by proposing new techniques to leverage the use of real, synthetic and augmented fire test observations. The developed ML ensemble has been calibrated and validated for standard and design fire exposures and for one, two, three and four-sided fire exposures thus; covering a wide range of practical scenarios present during fire incidents. When fully deployed, the developed ensemble can analyze over 5,000 RC columns in under 60 seconds thus, providing an attractive solution for researchers and practitioners. The presented approach can also be easily extended for evaluating fire resistance and spalling of other structural members and under varying fire scenarios and loading conditions and hence paves the way to modernize the state of this research area and practice.
2108.09862v1
2021-11-27
Antiferromagnetism and large magnetoresistance in GdBi single crystal
Single crystal of the binary equi-atomic compound GdBi crystallizing in the rock salt type cubic crystal structure with the space group $Fm\bar{3}m$ has been grown by flux method. The electrical and magnetic measurements have been performed on well oriented single crystals. The antiferromagnetic ordering of the Gd moments is confirmed at $T_{\rm N} = 27.5$~K. The magnetization measurement performed at $2$~K along the principal crystallographic direction [100] did not show any metamagnetic transition and no sign of saturation up to $7$~T. Zero field electrical resistivity reveals a sharp drop at $27.5$~K suggesting a reduction in the spin disorder scattering due to the antiferromagnetic alignment of the Gd moments. The residual resistivity at $2$~K is 390~n$\Omega$cm suggesting a good quality of the grown crystal. The magneto resistance attains a value of $1.0~\times~10^{4}\%$ with no sign of saturation, in a field of $14$~T, at $T = 2$~K. Shubnikov de Hass (SdH) oscillations have been observed in the high field range of the magnetoresistance with five different frequencies corresponding to the extremal areas of the Fermi surface. Analysis of the Hall data revealed a near compensation of the charge carriers accounting for the extremely large magnetoresistance.
2111.13836v1
2022-06-13
Ultra-High-Precision Detection of Single Microwave Photons based on a Hybrid System between Majorana Zero Mode and a Quantum Dot
The ability to detect single photons has become increasingly essential due to the rise of photon-based quantum computing. In this theoretical work, we propose a system consisting of a quantum dot (QD) side-coupled to a superconducting nanowire. The coupling opens a gap in both the QD mode and the Majorana zero mode (MZM) at the nanowire edge, enabling photon absorption in the system. We show that the absorbed photoelectron decays via rapid (sub-nanosecond to nanosecond) nonradiative heat transfer to the nanowire phonon modes rather than by spontaneous emission. Furthermore, we calculate the temperature increase and associated resistance increase induced by the absorption of a photon for a given appropriate set of material and environmental parameters, yielding a temperature increase in the millikelvin range and a resistance increase in the kiloohm range, vastly exceeding the photon-absorption-induced temperature and resistance increases for competing 2D-3D hybrid systems by 5 and 9 orders of magnitude, respectively. Lastly, we determine the detector efficiency and discuss the system density required for deterministic photon number measurement, demonstrating that a photon absorption probability of over 99.9 percent can be achieved for an integrated system consisting of an array of nanowire-QD complexes on-chip inside a cavity. Our results thus provide a basis for a deterministic microwave photon number detector with an unprecedented photon-number-detection resolution.
2206.06521v4
2022-11-02
Beta-Ga2O3 MOSFETs with near 50 GHz fMAX and 5.4 MV/cm average breakdown field
This letter reports high-performance $\mathrm{\beta} Ga2O3 thin channel MOSFETs with T-gate and degenerately doped source/drain contacts regrown by MOCVD. Gate length scaling (LG= 160-200 nm) leads to a peak drain current (ID,MAX) of 285 mA/mm and peak trans-conductance (gm) of 52 mS/mm at 10 V drain bias with 23.5 Ohm mm on resistance (Ron). A low metal/n+ contact resistance of 0.078 Ohm mm was extracted from TLM measurement. Ron is dominated by interface resistance between channel and regrown layer. A gate-to-drain breakdown voltage of 192 V is measured for LGD = 355 nm resulting in average breakdown field (E_AVG) of 5.4 MV/cm. This E_AVG is the highest reported among all sub-micron gate length lateral FETs. RF measurements on 200 nm Silicon Nitride (Si3N4) passivated device shows a current gain cut off frequency (f_T) of 11 GHz and record power gain cut off frequency (f_MAX) of 48 GHz. The f_T.V_Br product is 2.11 THz.V for 192 V breakdown voltage. The switching figure of merit exceeds that of silicon and is comparable to mature wide-band gap devices.
2211.01088v1
2023-04-06
All-electrical operation of a Curie-switch at room temperature
We present all-electrical operation of a Fe$_x$Cr$_{1-x}$-based Curie switch at room temperature. More specifically, we study the current-induced thermally-driven transition from ferromagnetic to antiferromagnetic Ruderman-Kittel-Kasuya-Yosida (RKKY) indirect coupling in a Fe/Cr/Fe$_{17.5}$Cr$_{82.5}$/Cr/Fe multilayer. Magnetometry measurements at different temperatures show that the transition from the ferromagnetic to the antiferromagnetic coupling at zero field is observed at $\sim$325K. Analytical modelling confirms that the observed temperature-dependent transition from indirect ferromagnetic to indirect antiferromangetic interlayer exchange coupling originates from the modification of the effective interlayer exchange constant through the ferromagnetic-to-paramagnetic transition in the Fe$_{17.5}$Cr$_{82.5}$ spacer with minor contributions from the thermally-driven variations of the magnetization and magnetic anisotropy of the Fe layers. Room-temperature current-in-plane magnetotransport measurements on the patterned Fe/Cr/Fe$_{17.5}$Cr$_{82.5}$/Cr/Fe strips show the transition from the 'low-resistance' parallel to the 'high-resistance' antiparallel remanent magnetization configuration, upon increased probing current density. Quantitative comparison of the switching fields, obtained by magnetometry and magnetotransport, confirms that the Joule heating is the main mechanism responsible for the observed current-induced resistive switching.
2304.03040v2
2023-05-14
Response of the Verwey transition in magnetite to a controlled point-like disorder induced by 2.5 MeV electron irradiation
A controlled point-like disorder induced by low temperature 2.5 MeV electron irradiation was used to probe the nature of the Verwey transition in magnetite, $\text{Fe}_{3}\text{O}_{4}$. Two large single crystals, one with optimal transition temperature, $T_{V}\approx121$ K, and another with $T_{V}\approx109$ K, as well as biogenic nanocrystals, $T_{V}\approx110$ K, were examined. Temperature-dependent resistivity is consistent with the semiconductor-to-semiconductor sharp, step-like Verwey transition from a state with a small bandgap of around 60 meV to a state with a larger bandgap of about 300 meV. The irradiation causes an up-shift of the resistivity curves above the transition without transition smearing or broadening. It also causes an apparent down-shift of the resistivity maximum at high temperatures. In the lower $T_{V}$ crystal, the electron irradiation drives the transition temperature into a ``forbidden" regime believed to separate the first order from the second order phase transition. Contrary to this belief, the transition itself remains sharp and hysteretic without a significant change in the hysteresis width. We conclude that the sudden change of the bandgap accompanied by the monoclinic distortion and the change of magnetic anisotropy is the reason for the Verwey transition in magnetite and the effect of additional disorder is mostly in the smearing of the sharp gap edges near the Fermi level.
2305.08276v1
2023-09-12
Numerical study on the effects of fluid properties in electrohydrodynamic pulsating jet under constant voltage
Pulsating jet is one of the common working modes in electrohydrodynamic printing (EHDP) that process is highly affected by operating parameters and material properties. In this paper, the processes of pulsating jet for liquids with different physical properties were investigated using numerical simulation. An electrohydrodynamic solver was established, and a charge flux restricting step was adopted to ensure a realistic distribution of free charges. Three various ejection regimes were observed in our simulations: oscillating cone (OC), choked jet (CJ), and stable cone-jet (SJ). We found that three dimensionless numbers relating to liquid properties determined the ejection regime: the Ohnesorge number, Q0{\epsilon}r/Q, and Q0/(QRe). Based on those dimensionless numbers, the roles of liquid properties on pulsating jet (OC and CJ) were analyzed. In OC, the break of the jet is due to the significant oscillation of the Taylor cone, which is mainly affected by viscosity and conductivity. In CJ, the jet emission is terminated by the excessive resistant force in the cone-jet transition region. For liquids with low and medium viscosity, the dominant resistant force is the polarization force or viscous force when {\epsilon}rRe is larger or smaller than 1, respectively. For high viscosity liquids, the viscous force always becomes the major resistance. These results further reveal the physical mechanism of pulsating jet and can be used to guide its application.
2309.06277v1
2023-10-13
Controlling Umklapp scattering in bilayer graphene moir'e superlattice
In this Letter, we present experimental findings on electron-electron scattering in a two-dimensional moir'e heterostructure with tunable Fermi wave vector, reciprocal lattice vector, and band gap. We achieve this in high-mobility aligned heterostructures of bilayer graphene (BLG) and hBN. Around half-filling, the primary contribution to the resistance of BLG/hBN aligned superlattices arises from electron-electron Umklapp (Uee) scattering, making the resistance of graphene/hBN moir'e devices significantly larger than that of non-aligned devices (where Uee is forbidden). We quantify the strength of the Uee scattering and find that it follows a universal scaling with Fermi energy and has a non-monotonic dependence on the charge carrier density. The Uee scattering is strongly electric field tunable and affected by layer-polarization of BLG. It has a strong particle-hole asymmetry - the resistance when the chemical potential is in the conduction band is significantly lesser than when it is in the valence band, making the electron-doped regime more practical for potential applications.
2310.08906v2
2023-11-20
Absence of metallicity and bias-dependent resistivity in low-carrier-density EuCd2As2
EuCd2As2 was theoretically predicted to be a minimal model of Weyl semimetals with a single pair of Weyl points in the ferromagnet state. However, the heavily p-doped EuCd2As2 crystals in previous experiments prevent direct identification of the semimetal hypothesis. Here we present a comprehensive magneto-transport study of high-quality EuCd2As2 crystals with ultralow bulk carrier density (10^13 cm-3). In contrast to the general expectation of a Weyl semimetal phase, EuCd2As2 shows insulating behavior in both antiferromagnetic and ferromagnetic states as well as surface-dominated conduction from band bending. Moreover, the application of a dc bias current can dramatically modulate the resistance by over one order of magnitude, and induce a periodic resistance oscillation due to the geometric resonance. Such nonlinear transport results from the highly nonequilibrium state induced by electrical field near the band edge. Our results suggest an insulating phase in EuCd2As2 and put a strong constraint on the underlying mechanism of anomalous transport properties in this system.
2311.11515v1
2024-01-15
Alternating Bias Assisted Annealing of Amorphous Oxide Tunnel Junctions
We demonstrate a transformational technique for controllably tuning the electrical properties of fabricated thermally oxidized amorphous aluminum-oxide tunnel junctions. Using conventional test equipment to apply an alternating bias to a heated tunnel barrier, giant increases in the room temperature resistance, greater than 70%, can be achieved. The rate of resistance change is shown to be strongly temperature-dependent, and is independent of junction size in the sub-micron regime. In order to measure their tunneling properties at mK temperatures, we characterized transmon qubit junctions treated with this alternating-bias assisted annealing (ABAA) technique. The measured frequencies follow the Ambegaokar-Baratoff relation between the shifted resistance and critical current. Further, these studies show a reduction of junction-contributed loss on the order of $\approx 2 \times10^{-6}$, along with a significant reduction in resonant- and off-resonant-two level system defects when compared to untreated samples. Imaging with high-resolution TEM shows that the barrier is still predominantly amorphous with a more uniform distribution of aluminum coordination across the barrier relative to untreated junctions. This new approach is expected to be widely applicable to a broad range of devices that rely on amorphous aluminum oxide, as well as the many other metal-insulator-metal structures used in modern electronics.
2401.07415v2
2024-01-22
Self-pulsing of Dielectric Barrier Discharges at Low Driving Frequencies
This paper investigates the self-pulsing of Dielectric Barrier Discharges (DBDs) at low driving frequencies. In particular, (a) the dependence of current on the product pd of gas pressure p and the gas gap length d, (b) the effects of lossy dielectrics (in resistive discharges) and large dielectric permittivity (in ferroelectrics) on current dynamics, (c) the transition from Townsend to a dynamic Capacitively Coupled Plasma (CCP) discharge with changing pd values, and (d) the transition from Townsend to a high-frequency CCP regime with increasing the driving frequency. A one-dimensional fluid model of Argon plasma is coupled to an equivalent RC circuit for lossy dielectrics. Our results show multiple current pulses per AC period in Townsend and CCP discharge modes which are explained by uncoupled electron-ion transport in the absence of quasineutrality and surface charge deposition at dielectric interfaces. The number of current pulses decreases with an increasing applied frequency when the Townsend discharge transforms into the CCP discharge. The resistive barrier discharge with lossy dielectrics exhibits Townsend and glow modes for the same pd value (7.6 Torr cm) for higher and lower resistances, respectively. Finally,we show that ferroelectric materials can amplify discharge current in DBDs. Similarities between current pulsing in DBD, Trichel pulses in corona discharges, and subnormal oscillations in DC discharges are discussed. 1
2401.12410v3
2015-06-26
Conventional superconductivity at 203 K at high pressures
A superconductor is a material that can conduct electricity with no resistance below its critical temperature (Tc). The highest Tc that has been achieved in cuprates1 is 133 K at ambient pressure2 and 164 K at high pressures3. As the nature of superconductivity in these materials has still not been explained, the prospects for a higher Tc are not clear. In contrast, the Bardeen-Cooper-Schrieffer (BCS) theory gives a guide for achieving high Tc and does not put bounds on Tc, all that is needed is a favorable combination of high frequency phonons, strong electron-phonon coupling, and a high density of states. These conditions can be fulfilled for metallic hydrogen and covalent compounds dominated by hydrogen4,5. Numerous calculations support this idea and predict Tc of 50-235 K for many hydrides6 but only moderate Tc=17 K has been observed experimentally7. Here we studied sulfur hydride8 where a Tc~80 K was predicted9. We found that it transforms to a metal at pressure ~90 GPa. With cooling superconductivity was found deduced from a sharp drop of the resistivity to zero and a decrease of Tc with magnetic field. The pronounce isotope shift of Tc in D2S is evidence of an electron-phonon mechanism of superconductivity that is consistent with the BCS scenario. The superconductivity has been confirmed by magnetic susceptibility measurements with Tc=203K. The high Tc superconductivity most likely is due to H3S which is formed from H2S under its decomposition under pressure. Even higher Tc, room temperature superconductivity, can be expected in other hydrogen-based materials since hydrogen atoms provide the high frequency phonon modes as well as the strong electron-phonon coupling.
1506.08190v1
2014-05-01
Effect of Electrical Properties on Gd modified BiFeO3-PbZrO3
The 0.5(BiGdxFe1-xO3)-0.5(PbZrO3) composite was synthesized using a high temperature solid-state reaction technique. Preliminary X-ray structural analysis confirms the formation of the composite. The dielectric constant and loss tangent have been studied. The hysteresis loop suggest that the material is lossy. The impedance parameters were studied using an impedance analyzer in a wide range of frequency (102-106 Hz) at different temperatures for all samples. The Nyquist plot suggests the contribution of bulk effect as well as grain boundary effect and the bulk resistance deceases with rise in temperature for all samples. The electrical transport confirms the presence of hopping mechanism in the material. The dc conductivity increases with rise in temperature. The frequency variation of ac conductivity shows that the compound obeys Jonschers universal power law and confirms the Small Polaron (SP) tunneling effect due to low activation energy for all samples. Temperature dependence of dc and ac conductivity indicates that electrical conduction in the materials are thermally activated process.
1405.0104v1
2019-02-13
Cu-substituted Fe2P: An emerging candidates for magnetic RAM application
We propose that Cu-substituted Fe$_2$P, (Fe$_{1-x}$Cu$_x$)$_2$P ($x\sim 0.16$), to be an outstanding contender for the STT-MRAM application. Using first principles based calculations in the framework of density functional theory and through Monte Carlo simulations, we demonstrate that this material can be used as ferromagnetic electrode in the magnetic tunnel junction (MTJ) of STT-MRAM due to its moderate perpendicular magnetic anisotropy (PMA), large tunnel magneto-resistance (TMR), good thermal stability and high ferromagnetic transition temperature. We point out that the simplicity in the synthesis, huge abundance, and non-toxicity make this material a very good candidate to replace the current MTJ materials for STT-MRAM such as FePt,~FeCo or FeCoB.
1902.04876v1
2012-06-01
Novel highly conductive and transparent graphene based conductors
Future wearable electronics, displays and photovoltaic devices rely on highly conductive, transparent and yet mechanically flexible materials. Nowadays indium tin oxide (ITO) is the most wide spread transparent conductor in optoelectronic applications, however the mechanical rigidity of this material limits its use for future flexible devices. Here we report novel transparent conductors based on few layer graphene (FLG) intercalated with ferric chloride (FeCl3) with an outstandingly high electrical conductivity and optical transparency. We show that upon intercalation a record low sheet resistance of 8.8 Ohm/square is attained together with an optical transmittance higher than 84% in the visible range. These parameters outperform the best values of ITO and of other carbon-based materials, making these novel transparent conductors the best candidates for future flexible optoelectronics.
1206.0001v1
2020-11-16
First-principles study of the electronic, magnetic, and crystal structure of perovskite molybdates
The molybdate oxides SrMoO$_3$, PbMoO$_3$, and LaMoO$_3$ are a class of metallic perovskites that exhibit interesting properties including high mobility, and unusual resistivity behavior. We use first-principles methods based on density functional theory to explore the electronic, crystal, and magnetic structure of these materials. In order to account for the electron correlations in the partially-filled Mo $4d$ shell, a local Hubbard $U$ interaction is included. The value of $U$ is estimated via the constrained random-phase approximation approach, and the dependence of the results on the choice of $U$ are explored. For all materials, GGA+$U$ predicts a metal with an orthorhombic, antiferromagnetic structure. For LaMoO$_3$, the $Pnma$ space group is the most stable, while for SrMoO$_3$ and PbMoO$_3$, the $Imma$ and $Pnma$ structures are close in energy. The $R_4^+$ octahedral rotations for SrMoO$_3$ and PbMoO$_3$ are found to be overestimated compared to the experimental low-temperature structure.
2011.08323v2
2020-11-21
Flash microwave pressing of zirconia
Microwave Pressing is a promising way to reduce microwave sintering temperatures and stabilize microwave powder materials processing. A multi-physics simulation was conducted of the regulated pressure-assisted microwave cavity. This simulation took into consideration resonance phenomena and the nonlinear temperature-dependent material parameters of zirconia. The intrinsic behaviors of microwave systems and zirconia make the regulation of the microwave pressing difficult. However, the same phenomena can be used to activate flash sintering. Flash microwave sintering uses high electric fields of the resonant microwave profile, the Negative Temperature Behavior (NTC) of zirconia resistivity, and the mechanical pressure applied to the powder via a die compaction configuration. The resulting flash microwave pressing still needs improvement in terms of the processed material structure homogeneity, but it has the capacity to become the fastest sintering treatment as it allows room temperature activation where the total process time only takes a few seconds. In addition, this 10-20s processing technique has shown good potential for improving the transparency of alumina pre-sintered specimens.
2011.14009v1
2021-03-28
Acoustic-pressure-assisted engineering of aluminium foams
Foaming metals modulates their physical properties, enabling attractive applications where lightweight, low thermal conductivity or acoustic isolation are desirable. Adjusting the size of the bubbles in the foams is particularly relevant for targeted applications. Here we provide a method with a detailed theoretical understanding how to tune the size of the bubbles in aluminium melts in-situ via acoustic pressure. Our description is in full agreement with the high-rate three-dimensional X-Ray radioscopy of the bubble formation. We complement our study with the intriguing results on the effect of foaming on electrical resistivity, Seebeck coefficient and thermal conductivity from cryogenic to room temperature. Compared to bulk materials the investigated foam shows an enhancement in the thermoelectric figure of merit. These results herald promising application of foaming in thermoelectrics materials and devices for thermal energy conversion.
2103.15225v1
2023-04-21
Probabilistic selection and design of concrete using machine learning
Development of robust concrete mixes with a lower environmental impact is challenging due to natural variability in constituent materials and a multitude of possible combinations of mix proportions. Making reliable property predictions with machine learning can facilitate performance-based specification of concrete, reducing material inefficiencies and improving the sustainability of concrete construction. In this work, we develop a machine learning algorithm that can utilize intermediate target variables and their associated noise to predict the final target variable. We apply the methodology to specify a concrete mix that has high resistance to carbonation, and another concrete mix that has low environmental impact. Both mixes also fulfill targets on the strength, density, and cost. The specified mixes are experimentally validated against their predictions. Our generic methodology enables the exploitation of noise in machine learning, which has a broad range of applications in structural engineering and beyond.
2304.11226v1
2024-03-08
Superconductivity of the New Medium-Entropy Alloy V4Ti2W with a Body-Centered Cubic Structure
Medium- and high-entropy alloy (MEA and HEA) superconductors have attracted considerable interest since their discovery. This paper reports the superconducting properties of ternary tungsten-containing MEA V4Ti2W for the first time. V4Ti2W is a type II superconductor with a body-centered cubic (BCC) structure. Experimental results of resistivity, magnetization, and heat capacity indicate that the superconducting transition temperature of the MEA V4Ti2W is roughly 5.0 K. The critical magnetic fields at the upper and lower ends are 9.93(2) T and 40.7(3) mT, respectively. Interestingly, few BCC MEA superconductors with VEC greater than 4.8 have been found. The addition of tungsten leads to a VEC of 4.83 e/a for V4Ti2W, which is rarely higher than the 4.8 value. Adding tungsten element expands the variety of MEA alloys, which may improve the microstructure and mechanical properties of materials and even superconducting properties. This material could potentially offer a new platform for the investigation of innovative MEA and HEA superconductors.
2403.05115v1
2024-03-28
Challenges in extracting nonlinear current-induced phenomena in Ca2RuO4
An appealing direction to change the properties of strongly correlated materials is to induce nonequilibrium steady states by the application of a direct current. While access to these novel states is of high scientific interest, Joule heating due to current flow often constitutes a hurdle to identify nonthermal effects. The biggest challenge usually resides in measuring accurately the temperature of a sample subjected to direct current, and to use probes that give direct information of the material. In this work, we exploit the simultaneous measurement of electrical transport and magnetisation to probe non-equilibrium steady states in Ca2RuO4. In order to reveal non-thermal current-induced effects, we employ a simple model of Joule self-heating to remove the effects of heating and discuss the importance of temperature inhomogeneity within the sample. Our approach provides a solid basis for investigating current-induced phenomena in highly resistive materials.
2403.19210v1
2000-01-07
Near-Field Microwave Microscopy of Materials Properties
Near-field microwave microscopy has created the opportunity for a new class of electrodynamics experiments of materials. Freed from the constraints of traditional microwave optics, experiments can be carried out at high spatial resolution over a broad frequency range. In addition, the measurements can be done quantitatively so that images of microwave materials properties can be created. We review the five major types of near-field microwave microscopes and discuss our own form of microscopy in detail. Quantitative images of microwave sheet resistance, dielectric constant, and dielectric tunability are presented and discussed. Future prospects for near-field measurements of microwave electrodynamic properties are also presented.
0001075v2
2010-08-18
A Stepped Oxide Hetero-Material Gate Trench Power MOSFET for Improved Performance
In this work, we propose a new Stepped Oxide Hetero-Material Trench (SOHMT) power MOSFET with three sections in the trench gate (an N+ poly gate sandwiched between two P+ poly gates) and having different gate oxide thicknesses (increasing from source side to drain side). The different gate oxide thickness serves the purpose of simultaneously achieving (i) a good gate control on the channel charge and (ii) a lesser gate to drain capacitance. As a result, we obtain higher transconductance as well as reduced switching delays, making the proposed device suitable for both RF amplification and high speed switching applications. In addition, the sandwiched gate with different work function gate materials modifies the electric field profile in the channel resulting in an improved breakdown voltage. Using two-dimensional simulations, we have shown that the proposed device structure exhibits about 32% enhancement in breakdown voltage, 25% reduction in switching delays, 20% enhancement in peak transconductance and 10% reduction in figure of merit (product of ON-resistance and gate charge) as compared to the conventional trench gate MOSFET.
1008.3022v1
2016-10-05
A Novel Nanoporous Graphite Based on Graphynes: First Principles Structure and Carbon Dioxide Preferential Physisorption
Ubiquitous graphene is a stricly 2D material representing an ideal adsorbing platform due to its large specific surface area as well as its mechanical strength and resistance to both thermal and chemical stresses. However, graphene as a bulk material has the tendency to form irreversible agglomerates leading to 3D graphitic structures with a significant decrease of the area available for adsorption and no room for gas intercalation. In this paper a novel nanoporous graphite formed by graphtriyne sheets is introduced: its 3D structure is theoretically assessed by means of electronic structure and molecular dynamics computations within the DFT level of theory. It is found that the novel layered carbon allotrope is almost as compact as pristine graphite but the inherent porosity of the 2D graphyne sheets and its relative stacking leads to nanochannels that cross the material and whose sub-nanometer size could allow the diffusion and storage of gas species. A molecular prototype of the nanochannel is used to accurately determine first principles adsorption energies and enthalpies for CO2, N2, H2O and H2 within the pores. The proposed porous graphite presents no significant barrier for gas diffusion and it shows a high propensity for CO2 physisorption with respect to the other relevant components in both pre- and post-combustion gas streams.
1610.01313v1
2017-06-30
Role of anisotropy in determining stability of electrodeposition at solid-solid interfaces
We investigate the stability of electrodeposition at solid-solid interfaces for materials exhibiting an anisotropic mechanical response. The stability of electrodeposition or resistance to the formation of dendrites is studied within a linear stability analysis. The deformation and stress equations are solved using the Stroh formalism and faithfully recover the boundary conditions at the interface. The stability parameter is used to quantify the stability of different solid-solid interfaces incorporating the full anisotropy of the elastic tensor of the two materials. Results show a high degree of variability in the stability parameter depending on the crystallographic orientation of the solids in contact, and point to opportunities for exploiting this effect in developing Li metal anodes.
1707.00064v3
2021-02-27
van der Waals heterostructures based on atomically-thin superconductors
Van der Waals heterostructures (vdWHs) allow the assembly of high-crystalline two-dimensional (2D) materials in order to explore dimensionality effects in strongly correlated systems and the emergence of potential new physical scenarios. In this work, it is illustrated the feasibility to integrate 2D materials in-between 2D superconductors. Particularly, it is presented the fabrication and electrical characterization of vertical vdWHs based on air-unstable atomically-thin transition metal dichalcogenides formed by NbSe2/TaS2/NbSe2 stacks, with TaS2 being the insulator 1T-TaS2 or the metal 2H-TaS2. Phase transitions as 1T-TaS2 charge density wave and NbSe2 superconductivity are detected. An enhancement of the vdWH resistance due to Andreev reflections is observed below the superconducting transition temperature of the NbSe2 flakes. Moreover, in the NbSe2 superconducting state, the field and temperature dependence of the normalized conductance is analyzed within the Dynes' model and the overall behavior is consistent with the Bardeen-Cooper-Schrieffer theory. This vdWH approach can be extended to other 2D materials, such as 2D magnets or topological insulators, with the aim of exploring the new emergent properties that may arise from such combinations.
2103.00203v1
2022-11-18
Pressure-Tuning Superconductivity in Noncentrosymmetric Topological Materials ZrRuAs
Recently, the hexagonal phase of ternary transition metal pnictides TT'X (T = Zr, Hf; T'= Ru; X = P, As), which are well-known noncentrosymmetric superconductors, were predicted to host nontrivial bulk topology. In this work, we systematically investigate the electronic responses of ZrRuAs to external pressure. At ambient pressure, ZrRuAs show superconductivity with Tc ~ 7.74 K, while a large upper critical field ~ 13.03 T is obtained for ZrRuAs, which is comparable to the weak-coupling Pauli limit. The resistivity of ZrRuAs exhibits a non-monotonic evolution with increasing pressure. The superconducting transition temperature Tc increases with applied pressure and reaches a maximum value of 7.93 K at 2.1 GPa, followed by a decrease. The nontrivial topology is robust and persists up to the high-pressure regime. Considering both robust superconductivity and intriguing topology in this material, our results could contribute to studies of the interplay between topological electronic states and superconductivity.
2211.10289v1
2023-03-28
On optimization of heterogeneous materials for enhanced resistance to bulk fracture
We propose a novel approach to optimize the design of heterogeneous materials, with the goal of enhancing their effective fracture toughness under mode-I loading. The method employs a Gaussian processes-based Bayesian optimization framework to determine the optimal shapes and locations of stiff elliptical inclusions within a periodic microstructure in two dimensions. To model crack propagation, the phase-field fracture method with an efficient interior-point monolithic solver and adaptive mesh refinement, is used. To account for the high sensitivity of fracture properties to initial crack location with respect to heterogeneities, we consider multiple cases of initial crack and optimize the material for the worst-case scenario. We also impose a minimum clearance constraint between the inclusions to ensure design feasibility. Numerical experiments demonstrate that the method significantly improves the fracture toughness of the material compared to the homogeneous case.
2303.15801v1
2024-01-23
Electronic Noise Spectroscopy of Quasi-2D van der Waals Antiferromagnetic Semiconductors
We investigated low-frequency current fluctuations, i.e. electronic noise, in FePS3 van der Waals, layered antiferromagnetic semiconductor. The noise measurements have been used as noise spectroscopy for advanced materials characterization of the charge carrier dynamics affected by spin ordering and trapping states. Owing to the high resistivity of the material, we conducted measurements on vertical device configuration. The measured noise spectra reveal pronounced Lorentzian peaks of two different origins. One peak is observed only near the Neel temperature and it is attributed to the corresponding magnetic phase transition. The second Lorentzian peak, visible in the entire measured temperature range, has the characteristics of the trap-assisted generation-recombination processes similar to those in conventional semiconductors but shows a clear effect of the spin order reconfiguration near the Neel temperature. The obtained results contribute to understanding the electron and spin dynamics in this type of antiferromagnetic semiconductors and demonstrate the potential of electronic noise spectroscopy for advanced materials characterization.
2401.12432v1
2015-04-24
Graphene surpasses GaAs/AlGaAs for the application of the quantum Hall effect in metrology
The quantum Hall effect (QHE) theoretically provides a universal standard of electrical resistance in terms of the Planck constant $h$ and the electron charge $e$. In graphene, the spacing between the lowest discrete energy levels occupied by the charge carriers under magnetic field is exceptionally large. This is promising for a quantum Hall resistance standard more practical in graphene than in the GaAs/AlGaAs devices currently used in national metrology institutes. Here, we demonstrate that large QHE devices, made of high quality graphene grown by propane/hydrogen chemical vapour deposition on SiC substrates, can surpass state-of-the-art GaAs/AlGaAs devices by considerable margins in their required operational conditions. In particular, in the device presented here, the Hall resistance is accurately quantized within $1\times 10^{-9}$ over a 10-T wide range of magnetic field with a remarkable lower bound at 3.5 T, temperatures as high as 10 K, or measurement currents as high as 0.5 mA. These significantly enlarged and relaxed operational conditions, with a very convenient compromise of 5 T, 5.1 K and 50 $\mu$A, set the superiority of graphene for this application and for the new generation of versatile and user-friendly quantum standards, compatible with a broader industrial use. We also measured an agreement of the quantized Hall resistance in graphene and GaAs/AlGaAs with an ultimate relative uncertainty of $8.2\times 10^{-11}$. This supports the universality of the QHE and its theoretical relation to $h$ and $e$, essential for the application in metrology, particularly in view of the forthcoming Syst\`eme International d'unit\'es (SI) based on fundamental constants of physics, including the redefinition of the kilogram in terms of $h$.
1504.06511v1
2009-12-24
Nanostructural Superconducting Materials for Fault Current Limiters and Cryogenic Electrical Machines
Materials of the Y-Ba-Cu-O (melt-textured YBa2Cu3O7-d-based materials or MT-YBCO) and Mg-B-O (MgB2-based materials) systems with high superconducting performance, which can be attained due to the formation of regularly distributed nanostructural defects and inhomogenities in their structure can be effectively used in cryogenic technique, in particular in fault current limiters and electrical machines (electromotors, generators, pumps for liquid gases, etc.). The developed processes of high-temperature (900-800 oC) oxygenation under elevated pressure (16 MPa) of MT-YBCO and high-pressure (2 GPa) synthesis of MgB2-based materials allowed us to attain high SC (critical current densities, upper critical fields, fields of irreversibility, trapped magnetic fields) and mechanical (hardness, fracture toughness, Young modulus) characteristics. It has been shown that the effect of materials properties improvement in the case of MT-YBCO was attained due to the formation of high twin density (20-22 micron-1), prevention of macrockracking and reduction (by a factor of 4.5) of microcrack density, and in the case of MgB2-based materials due to the formation of oxygen-enriched as compared to the matrix phase fine-dispersed Mg-B-O inhomogenities as well as inclusions of higher borides with near-MgB12 stoichiometry in the Mg-B-O matrix (with 15-37 nm average grain sizes). The possibility is shown to obtain the rather high Tc (37 K) and critical current densities in materials with MgB12 matrix (with 95 percent of shielding fraction as calculated from the resistant curve).
0912.4899v1
2010-11-01
Modeling materials with optimized transport properties
Following demands for materials with peculiar transport properties, e.g. in magnetoelectronics or thermoelectrics, there is a need for materials modeling at the quantum-mechanical level. We combine density-functional with various scale-bridging tools to establish correlations between the macroscopic properties and the atomic structure of materials. For examples, magnetic memory devices exploiting the tunneling magneto-resistance (TMR) effect depend crucially on the spin polarization of the electrodes. Heusler alloys, e.g. Co2MnSi, if perfectly ordered, are ferromagnetic half-metals with (ideally) 100% spin polarization. Their performance as electrodes in TMR devices is limited by atomic disorder and deviations from perfect stoichiometry, but also by interface states at the tunneling barrier. We use ab initio thermodynamics in conjunction with the cluster expansion technique to show that excess manganese in the alloy and at the interface helps to preserve the desired half-metallic property. As another example, nanostructured materials with a reduced thermal conductivity but good electrical conductivity are sought for applications in thermoelectrics. Semiconductor heterostructures with a regular arrangement of nanoscale inclusions ('quantum dot superlattices') hold the promise of a high thermoelectric figure of merit. Our theoretical analysis reveals that an increased figure of merit is to be expected if the quantum dot size, the superlattice period and the doping level are all suitably fine-tuned. Such a superlattice thus constitutes a material whose transport properties are controlled by geometrical features at the nanoscale.
1011.0324v1
2023-05-15
Thermal conductivity of macroporous graphene aerogel measured using high resolution comparative infrared thermal microscopy
Graphene aerogel (GA) is a promising material for thermal management applications across many fields due to its lightweight and thermally insulative properties. However, standard values for important thermal properties, such as thermal conductivity, remain elusive due to the lack of reliable characterization techniques for highly porous materials. Comparative infrared thermal microscopy (CITM) is an attractive technique to obtain thermal conductance values of porous materials like GA, due to its non-invasive character, which requires no probing of, or contact with, the often-delicate structures and frameworks. In this study, we improve upon CITM by utilizing a higher resolution imaging setup and reducing the need for pore-filling coating of the sample (previously used to adjust for emissivity). This upgraded setup, verified by characterizing porous silica aerogel, allows for a more accurate confirmation of the fundamental thermal conductivity value of GA while still accounting for the thermal resistance at material boundaries. Using this improved method, we measure a thermal conductivity below 0.036 W/m$\cdot$K for commercial GA using multiple reference materials. These measurements demonstrate the impact of higher resolution thermal imaging to improve accuracy in low density, highly porous materials characterization. This study also reports thermal conductivity for much lower density (less than 15 mg/cm$^3$) GA than previously published studies while maintaining the robustness of the CITM technique.
2305.09033v3
2024-04-18
Assessing the Risk of Proliferation via Fissile Material Breeding in ARC-class Fusion Reactors
Construction of a nuclear weapon requires access to kilogram-scale quantities of fissile material, which can be bred from fertile material like U-238 and Th-232 via neutron capture. Future fusion power plants, with total neutron source rates in excess of $10^{20}$ n/s, could breed weapons-relevant quantities of fissile material on short timescales, posing a breakout proliferation risk. The ARC-class fusion reactor design is characterized by demountable high temperature superconducting magnets, a FLiBe liquid immersion blanket, and a relatively small size ($\sim$ 4 m major radius, $\sim$ 1 m minor radius). We use the open-source Monte Carlo neutronics code OpenMC to perform self-consistent time-dependent simulations of a representative ARC-class blanket to assess the feasibility of a fissile breeding breakout scenario. We find that a significant quantity of fissile material can be bred in less than six months of full power operation for initial fertile inventories ranging from 5 to 50 metric tons, representing a non-negligible proliferation risk. We further study the feasibility of this scenario by examining other consequences of fissile breeding such as reduced tritium breeding ratio, extra heat from fission and decay heat, isotopic purity of bred material, and self-protection time of irradiated blanket material. We also examine the impact of Li-6 enrichment on fissile breeding and find that it substantially reduces breeding rate, motivating its use as a proliferation resistance tool.
2404.12451v1
2022-01-10
A theory for anisotropic magnetoresistance in materials with two vector order parameters
Anisotropic magnetoresistance (AMR) and related planar Hall resistance (PHR) are ubiquitous phenomena of magnetic materials. Although the universal angular dependences of AMR and PHR in magnetic polycrystalline materials with one order parameter are well known, no similar universal relation for other class of magnetic materials are known to date. Here I present a general theory of galvanomagnetic effects in magnetic materials with two vector order parameters, such as magnetic single crystals with a dominated crystalline axis or polycrystalline non-collinear ferrimagnetic materials. It is shown that AMR and PHR have a universal angular dependence. In general, both longitudinal and transverse resistivity are non-reciprocal in the absence of inversion symmetry: Resistivity takes different value when the current is reversed. Different from simple magnetic polycrystalline materials where AMR and PHR have the same magnitude, and $\pi/4$ out of phase, the magnitude of AMR and PHR of materials with two vector order parameters are not the same in general, and the phase difference is not $\pi/4$. Instead of $\pi$ periodicity of the usual AMR and PHR, the periodicities of materials with two order parameters are $2\pi$.
2201.03316v1
2003-11-04
Resistive transition in $π$-junction superconductors
The resistivity behavior of inhomogeneous superconductors with random $\pi$ junctions, as in high-$T_c$ materials with d-wave symmetry, is studied by numerical simulation of a three-dimensional XY spin glass model. Above a concentration threshold of antiferromagnetic couplings, a resistive transition is found in the chiral-glass phase at finite temperatures and the critical exponents are determined from dynamic scaling analysis. The power-law exponent for the nonlinear contribution found in recent resistivity measurements is determined by the dynamic critical exponent of this transition.
0311083v1
2004-07-28
Universal behavior of giant electroresistance in epitaxial La0.67Ca0.33MnO3 thin films
We report a giant resistance drop induced by dc electrical currents in La0.67Ca0.33MnO3 epitaxial thin films. Resistance of the patterned thin films decreases exponentially with increasing current and a maximum drop shows at the temperature of resistance peak Tp. Variation of resistance with current densities can be scaled below and above Tp, respectively. This work can be useful for the future applications of electroresistance.
0407719v2
2005-06-17
Experimental Evidence for Zero DC Resistance of Superconductors
Even after nearly a century of discovery of superconductivity, there has been no direct experimental proof of the expected zero resistance of superconductors. Indeed, it has been believed that it is impossible to experimentally show that the resistance has fallen exactly to zero. In this work we demonstrate that the dc resistivity of a superconducting material below the transition temperature has to be exactly zero.
0506426v2
2007-11-29
Increase of Thermal Resistance Between a Nanostructure and a Surface due to Phonon Multireflections
The thermal resistance between a nanostructure and a half-body is calculated in the framework of particle-phonons physics. The current models approximate the nanostructure as a thermal bath. We prove that the multireflections of heat carriers in the nanostructure significantly increase resistance in contradiction with former predictions. This increase depends on the shape of the nanostructure and the heat carriers mean free path only. We provide a general and simple expression for the contact resistance and examine the specific cases of nanowires and nanoparticles.
0711.4718v1
2009-09-07
Low-Temperature Resistivity Anomalies in Periodic Curved Surfaces
Effects of periodic curvature on the the electrical resistivity of corrugated semiconductor films are theoretically considered. The presence of a curvature-induced potential affects the motion of electrons confined to the thin curved film, resulting in a significant resistivity enhancement at specific values of two geometric parameters: the amplitude and period of the surface corrugation. The maximal values of the two parameters in order to observe the corrugation-induced resistivity enhancement in actual experiments are quantified by employing existing material constants.
0909.1135v1
2011-02-23
Pt/Ti/Al2O3/Al tunnel junctions showing electroforming-free bipolar resistive switching behavior
We investigated electroforming-free bipolar resistive switching behavior in Pt/Ti/Al2O3/Al tunnel junctions where the Al2O3 tunnel barrier was naturally formed on Al in air. Various compliance current values for the junction's set switching successfully lead to various resistance values in its low resistance state, suggesting the possibility for multi-level-operation. A mechanism for the bipolar switching is qualitatively discussed in terms of the modulation of the tunnel barrier by the reactive Ti layer on top of the barrier.
1102.4720v1
2013-05-09
Electrostatic gating of metallic and insulating phases in SmNiO3 ultrathin films
The correlated electron system SmNiO3 exhibits a metal-insulator phase transition at 130 {\deg}C. Using an ionic liquid as an electric double layer (EDL) gate on three-terminal ultrathin SmNiO3 devices, we investigate gate control of the channel resistance and transition temperature. Resistance reduction is observed across both insulating and metallic phases with ~25% modulation at room temperature. We show that resistance modulation is predominantly due to electrostatic charge accumulation and not electrochemical doping by control experiments in inert and air en-vironments. We model the resistance behavior and estimate the accumulated sheet density (~1-2 x 10^14 cm^-2) and EDL capacitance (~12 {\mu}F/cm^2).
1305.2111v1
2013-06-18
Some features of anomalous conductivity of vinylene and vinyl chloride copolymer films
Manifestations of anomalous conductivity in polar dielectric films is demonstrated for the first time on samples of copolymer of vinylene and vinyl chloride, as was previously observed on modified PVC samples. On the base of these experimental results important new insights into the physical sense of traditionally used in these conditions specific resistivity indicators, both volume and surface, should be replaced by transverse and longitudinal resistance (according to polymer film surface) respectively, because the specific resistivity of polymer composite does not permits to calculate as usual the resistance of sample of arbitrary form..
1306.4127v1
2013-07-02
The density of states of graphene underneath a metal electrode and its correlation with the contact resistivity
The density of states (DOS) of graphene underneath a metal is estimated through a quantum capacitance measurement of the metal/graphene/SiO2/n+-Si contact structure fabricated by a resist-free metal deposition process. Graphene underneath Au maintains a linear DOS - energy relationship except near the Dirac point, whereas the DOS of graphene underneath Ni is broken and largely enhanced around the Dirac point, resulting in only a slight modulation of the Fermi energy. Moreover, the DOS of graphene in the contact structure is correlated with the contact resistivity measured using devices fabricated by the resist-free process.
1307.0690v1
2013-08-06
Correct nonlinearity and hysteresis of volt-ampere characteristics of spin valves, magnetic tunnel junctions and memristors
There are essential achievements in synthesis of interesting for creation of compact electronic memory switched by own current structures of spin valves and magnetic tunnel junctions with hysteretic current dependences of resistance. In the offered message the attention to discrepancy to physical principles of a hysteresis of resistance represented in publications is paid. It is schematically presented how the dependences of resistance on current should look not contradicting the energy conservation law for hysteresis dependence of resistance on current and corresponding volt-ampere characteristic.
1308.1220v1
2015-09-28
Multi-level Resistive Switching Characteristics of W/Co:TiO2/FTO Structures
In the present work, multi-level resistive switching (RS) in W/Co:TiO2/FTO structures induced by a multi-mixed mechanism was studied. It was found that the devices could be reproducibly programmed into three nonvolatile resistance states. And the directly switching between any resistance states was realized. This increases the operation speed and lowers the complexity of control circuit of multi-state nonvolatile memory.
1509.08211v1
2020-09-16
The electric pulses induced multi-resistance states in the hysteresis temperature range of 1T-TaS2 and 1T-TaS1.6Se0.4
The electric pulse-induced responses of 1T-TaS2 and 1T-TaS1.6Se0.4 crystals in the commensurate charge-density-wave (CCDW) phase in the hysteresis temperature range have been investigated. We observed that abrupt multiple steps of the resistance are excited by electric pulses at a fixed temperature forming multi metastable like states. We propose that the response of the system corresponds to the rearrangements of the textures of CCDW domains and the multi-resistance states or the nonvolatile resistance properties excited simply by electric pulses have profound significance for the exploration of solid-state devices.
2009.07587v1
2012-01-26
Resistive switching effects on the spatial distribution of phases in metal-complex oxide interfaces
In order to determine the key parameters that control the resistive switching mechanism in metal-complex oxides interfaces, we have studied the electrical properties of metal / YBa2Cu3O7-d (YBCO) interfaces using metals with different oxidation energy and work function (Au, Pt, Ag) deposited by sputtering on the surface of a YBCO ceramic sample. By analyzing the IV characteristics of the contact interfaces and the temperature dependence of their resistance, we inferred that ion migration may generate or cancel conducting filaments, which modify the resistance near the interface, in accordance with the predictions of a recent model.
1201.5670v1
2019-08-21
Artificial Spin Ice Phase-Change Memory Resistors
We study the implications of the anisotropic magnetic resistance on permalloy nanowires, and in particular on the property of the resistance depending on the type of lattice. We discuss how the internal spin configuration of artificial spin ice nanowires can affect their effective resistive state, and which mechanisms can introduce a current-dependent effect dynamic resistive state. We discuss a spin-induced thermal phase-change mechanism, and an athermal domain-wall spin inversion. In both cases we observe memory behavior reminiscent of a memristor, with an I-V hysteretic pinched behavior.
1908.08073v1
2020-07-09
Modeling Resistive Switching in Nanogranular Metal Films
Films produced by assembling bare gold clusters well beyond the electrical percolation threshold show a resistive switching behavior whose investigation has started only recently. Here we address the challenge to charaterize the resistance of a nanogranular film starting from limited information on the structure at the microscopic scale by the means of Bruggeman's approach to multicomponent media, within the framework of Effective Medium Approximations. The approach is used to build a model that proves that the observed resistive switching can be explained by thermally regulated local structural rearrangements.
2007.04710v2
2019-01-12
Development of the Micro Pixel Chamber with resistive electrodes
We developed a novel design of a Micro Pixel Chamber ($\mu$-PIC) with resistive electrodes for a charged-particle-tracking detector in high-rate applications. Diamond-Like Carbon (DLC) thin film is used for the cathodes. The resistivity can be controlled flexibly ($\mathrm{10^{5-7}k\Omega/sq.}$) at high uniformity. The fabrication-process was greatly improved and the resistive $\mu$-PIC could be operated at 10$\times$10 $\mathrm{cm^2}$. Resistors for the HV bias and capacitors for the AC coupling were completely removed by applying PCB and carbon-sputtering techniques, and the resistive $\mu$-PIC became a very compact detector. The performances of our new resistive $\mu$-PIC were measured in various ways. Consequently, it was possible to attain high gas gains ($\mathrm{> 10^{4}}$), high detection efficiency, and position resolution exceeding 100 $\mu$m. The spark current was suppressed, and the new resistive $\mu$-PIC was operated stably under fast-neutrons irradiation. These features offer solutions for a charged-particle-tracking detector in future high-rate applications.
1901.03836v1
2015-10-13
Interface-mediated thermomechanical effects during high velocity impact between monocrystalline surfaces
High velocity impact between crystalline surfaces is important for a range of material phenomena, yet a fundamental understanding of the effect of surface structure, energetics and kinetics on the underlying thermo-mechanical response remains elusive. Here, we employ non-equilibrium molecular dynamics (NEMD) simulations to describe the nanoscale dynamics of the high velocity impact between commensurate and incommensurate monocrystalline (001) copper surfaces. For impact velocities in the range 100-1200 m/s, the kinetic energy dissipation involves nucleation and emission of dislocation loops from defective sites within the rapidly forming interface, well below the bulk single-crystal yield point. At higher velocities, adiabatic dissipation occurs via plasticity-induced heating as the interface structurally melts following the impact. The adhesive strength of the reformed interface is controlled by the formation and nucleation of dislocations and point defects as they modify the interfacial energy relative to the deformed bulk. As confirmation, the excess interface energy decreases monotonically with increasing impact velocity. The relative crystal orientation of the surfaces equally important; the grain boundaries formed following incommensurate impact exhibit higher impact resistance, with smaller defect densities and interfacial enthalpies, suggesting an enhanced ability of the grain boundaries to absorb the non-equilibrium damage and therefore facilitate particle bonding. Our study highlights the key role played by the atomic-scale surface structure in determining the impact resistance and adhesion of crystalline surfaces.
1510.03775v1
2007-10-03
Directional-dependent thermally activated motion of vortex bundles and theory of anomalous Hall effect in type-II conventional and high-Tc superconductors
The anomalous Hall effect for type-II conventional and high-Tc superconductors is studied based upon the theory of thermally activated motion of vortex bundles jumping over the directional-dependent energy barrier. It is shown that the Hall anomaly is universal for type-II conventional and high-Tc superconductors as well as for superconducting bulk materials and thin films, provided certain conditions are satisfied. We find that the directional-dependent potential barrier of the vortex bundles renormalizes the Hall and longitudinal resistivities, and Hall anomaly for superconductors is induced by the competition between the Magnus force and the random collective pinning force of the vortex bundle. We also find that the domain of anomalous Hall effect includes two regions: the region of thermally activated motion of the small vortex bundles and that of the large vortex bundles separated by the contour of the quasiorder-disorder first-order phase transition, or the peak effect of the vortex system. The Hall and longitudinal resistivities as functions of temperature as well as applied magnetic field have been calculated for type-II superconducting films and bulk materials. The conditions for occurring the double sign reversal or reentry phenomenon is also investigated. All the results are in agreement with the experiments.
0710.0700v2
2022-04-20
Superconducting bimodal ionic photo-memristor
Memristive circuit elements constitute a cornerstone for novel electronic applications, such as neuromorphic computing, called to revolutionize information technologies. By definition, memristors are sensitive to the history of electrical stimuli, to which they respond by varying their electrical resistance across a continuum of nonvolatile states. Recently, much effort has been devoted to developing devices that present an analogous response to optical excitation. Here we realize a new class of device, a tunnelling photo-memristor, whose behaviour is bimodal: both electrical and optical stimuli can trigger the switching across resistance states in a way determined by the dual optical-electrical history. This unique behaviour is obtained in a device of ultimate simplicity: an interface between a high-temperature superconductor and a transparent semiconductor. The microscopic mechanism at play is a reversible nanoscale redox reaction between both materials, whose oxygen content determines the electron tunnelling rate across their interface. Oxygen exchange is controlled here via illumination by exploiting a competition between electrochemistry, photovoltaic effects and photo-assisted ion migration. In addition to their fundamental interest, the unveiled electro-optic memory effects have considerable technological potential. Especially in combination with high-temperature superconductivity which, beyond facilitating the high connectivity required in neuromorphic circuits, brings photo-memristive effects to the realm of superconducting electronics.
2204.09255v1
2018-11-03
Modern Data Analytics Approach to Predict Creep of High-Temperature Alloys
A breakthrough in alloy design often requires comprehensive understanding in complex multi-component/multi-phase systems to generate novel material hypotheses. We introduce a modern data analytics workflow that leverages high-quality experimental data augmented with advanced features obtained from high-fidelity models. Herein, we use an example of a consistently-measured creep dataset of developmental high-temperature alloy combined with scientific alloy features populated from a high-throughput computational thermodynamic approach. Extensive correlation analyses provide ranking insights for most impactful alloy features for creep resistance, evaluated from a large set of candidate features suggested by domain experts. We also show that we can accurately train machine learning models by integrating high-ranking features obtained from correlation analyses. The demonstrated approach can be extended beyond incorporating thermodynamic features, with input from domain experts used to compile lists of features from other alloy physics, such as diffusion kinetics and microstructure evolution.
1811.01239v1
2021-01-24
Electronic structure and transport properties of sol-gel-derived high-entropy Ba(Zr0.2Sn0.2Ti0.2Hf0.2Nb0.2)O3 thin films
High-entropy perovskite thin films, as the prototypical representative of the high-entropy oxides with novel electrical and magnetic features, have recently attracted great attention. Here, we reported the electronic structure and charge transport properties of sol-gel-derived high-entropy Ba(Zr0.2Sn0.2Ti0.2Hf0.2Nb0.2)O3 thin films annealed at various temperatures. By means of X-ray photoelectron spectroscopy and absorption spectrum, it is found that the conduction-band-minimum shifts downward and the valence-band-maximum shifts upward with the increase of annealing temperature, leading to the narrowed band gap. Electrical resistance measurements confirmed a semiconductor-like behavior for all the thin films. Two charge transport mechanisms, i.e., the thermally-activated transport mechanism at high temperatures and the activation-less transport mechanism at low temperatures, are identified by a self-consistent analysis method. These findings provide a critical insight into the electronic band structure and charge transport behavior of Ba(Zr0.2Sn0.2Ti0.2Hf0.2Nb0.2)O3, validating it as a compelling high-entropy oxide material for future electronic/energy-related technologies.
2101.09633v2
2015-06-16
Unforeseen high temperature and humidity stability of FeCl$_3$ intercalated few layer graphene
We present the first systematic study of the stability of the structure and electrical properties of FeCl$_3$ intercalated few-layer graphene to high levels of humidity and high temperature. Complementary experimental techniques such as electrical transport, high resolution transmission electron microscopy and Raman spectroscopy conclusively demonstrate the unforeseen stability of this transparent conductor to a relative humidity up to $100 \%$ at room temperature for 25 days, to a temperature up to $150\,^\circ$C in atmosphere and up to a temperature as high as $620\,^\circ$C in vacuum, that is more than twice higher than the temperature at which the intercalation is conducted. The stability of FeCl$_3$ intercalated few-layer graphene together with its unique values of low square resistance and high optical transparency, makes this material an attractive transparent conductor in future flexible electronic applications.
1506.04907v1
2009-12-24
Properties of MgB2 bulk
The review considers bulk MgB2-based materials in terms of their structure, superconducting and mechanical properties. Superconducting transition temperatures of 34.5-39.4 K, critical current densities of 1.8-1.0 x E6 A/sq.cm in self field and 103 in 8 T field at 20 K, 3-1.5xE5 A/sq. cm in self field at 35 K, HC2 15 T at 22 K and Hirr 13 T at 20 K have been registered for polycrystalline materials. As TEM and SEM study show, dispersed higher borides and rather big amount (5-14 percents) of oxygen (bonded simultaneously with Mg and B) can be present in the structure even if X-ray pattern contains only reflexes of well crystallized MgB2 with traces of MgO. Materials with such a rather high oxygen content demonstrated high superconducting characteristics. At present it is established that nanosized MgB12 grains provide effective pinning in polycrystalline material. Besides, additions can introduce the MgB2 structure inducing disorder in lattice sites (for example, C substitution for B). The disorder increases the normal state resistivity, magnetic penetration depth, and the upper critical field, but reduces the transition temperature and anisotropy. It is highly probable that the additives (Ti, Ta, Zr, SiC) together with synthesis or sintering temperature can affect the distribution of oxygen and hydrogen in the material structure as well as the formation of grains of higher borides, thus influencing superconducting properties. The superconductivity of materials with matrix close to MgB12 in stoichiometry (Tc=37 K) has been defined.
0912.4906v1
2017-10-23
Realization of a hole-doped Mott insulator on a triangular silicon lattice
The physics of doped Mott insulators is at the heart of some of the most exotic physical phenomena in materials research including insulator-metal transitions, colossal magneto-resistance, and high-temperature superconductivity in layered perovskite compounds. Advances in this field would greatly benefit from the availability of new material systems with similar richness of physical phenomena, but with fewer chemical and structural complications in comparison to oxides. Using scanning tunneling microscopy and spectroscopy, we show that such a system can be realized on a silicon platform. Adsorption of one-third monolayer of Sn atoms on a Si(111) surface produces a triangular surface lattice with half-filled dangling bond orbitals. Modulation hole-doping of these dangling bonds unveils clear hallmarks of Mott physics, such as spectral weight transfer and the formation of quasi-particle states at the Fermi level, well-defined Fermi contour segments, and a sharp singularity in the density of states. These observations are remarkably similar to those made in complex oxide materials, including high-temperature superconductors, but highly extraordinary within the realm of conventional sp-bonded semiconductor materials. It suggests that exotic quantum matter phases can be realized and engineered on silicon-based materials platforms.
1710.08065v1
2020-04-12
Investigation on the Mechanical Properties of Functionally Graded Nickel and Aluminium Alloy by Molecular Dynamics Study
Functionally graded materials (FGMs), have drawn considerable attention of the worldwide researchers and scientific community because of its unique mechanical, thermal and electrical properties which may be exploited by varying the compositions gradually over volume. This makes FGM multifunctional material (properties changing continuously in a certain direction) for specific purpose without creating any phase interface thus making it superior to its composite counterparts. In this paper, we applied Molecular Dynamics (MD) approach to investigate the mechanical properties of functional graded Ni-Al alloy with Ni coating by applying uniaxial tension. Nickel-Aluminum (Ni-Al) alloy has been used extensively in the industry due to its remarkable mechanical and thermal properties. Our aim is to find the difference in material behavior when we change the grading function (linear, elliptical and parabolic), temperature and crystallographic direction. We also observe distinct type of failure mechanism for different grading function at different temperature. Close observation reveals that elliptically graded Ni-Al alloy has high tensile strength at low temperature whereas at high temperature, the highest tensile strength is found for parabolic grading. Besides, at any temperature, the parabolically graded Ni-Al alloy shows superior elasticity than its elliptical and linear counterpart. Moreover, it is also observed that [111] crystallographic direction for this alloy demonstrates more resistivity towards failure than any other crystallographic direction. It is found that lattice disorder plays a significant role on the mechanical properties of Functionally Graded Materials (FGMs). This paper details a pathway to tune the mechanical properties like Young's Modulus, plasticity and yield strength at molecular level by varying the composition of materials along different grading functions.
2004.05651v1
1997-03-03
Longitudinal and transverse dissipation in a simple model for the vortex lattice with screening
Transport properties of the vortex lattice in high temperature superconductors are studied using numerical simulations in the case in which the non-local interactions between vortex lines are dismissed. The results obtained for the longitudinal and transverse resistivities in the presence of quenched disorder are compared with the results of experimental measurements and other numerical simulations where the full interaction is considered. This work shows that the dependence on temperature of the resistivities is well described by the model without interactions, thus indicating that many of the transport characteristics of the vortex structure in real materials are mainly a consequence of the topological configuration of the vortex structure only. In addition, for highly anisotropic samples, a regime is obtained where longitudinal coherence is lost at temperatures where transverse coherence is still finite. I discuss the possibility of observing this regime in real samples.
9703035v1
1997-08-19
Metallization of Fluid Hydrogen
The electrical resistivity of liquid hydrogen has been measured at the high dynamic pressures, densities and temperatures that can be achieved with a reverberating shock wave. The resulting data are most naturally interpreted in terms of a continuous transition from a semiconducting to a metallic, largely diatomic fluid, the latter at 140 GPa, (ninefold compression) and 3000 K. While the fluid at these conditions resembles common liquid metals by the scale of its resistivity of 500 micro-ohm-cm, it differs by retaining a strong pairing character, and the precise mechanism by which a metallic state might be attained is still a matter of debate. Some evident possibilities include (i) physics of a largely one-body character, such as a band-overlap transition, (ii) physics of a strong-coupling or many-body character,such as a Mott-Hubbard transition, and (iii) processes in which structural changes are paramount.
9708144v1
1997-09-16
The Metallic-Like Conductivity of a Two-Dimensional Hole System
We report on a zero magnetic field transport study of a two-dimensional, variable-density, hole system in GaAs. As the density is varied we observe, for the first time in GaAs-based materials, a crossover from an insulating behavior at low-density, to a metallic-like behavior at high-density, where the metallic behavior is characterized by a large drop in the resistivity as the temperature is lowered. These results are in agreement with recent experiments on Si-based two-dimensional systems by Kravchenko et al. and others. We show that, in the metallic region, the resistivity is dominated by an exponential temperature-dependence with a characteristic temperature which is proportional to the hole density, and appear to reach a constant value at lower temperatures.
9709184v3
1998-04-23
Hysteretic behavior and evidence for domain formation in a double-layer quantum Hall system at total filling factor 2
We report anomalous behavior in a double-layer two dimensional hole gas (2DHG) at even integer filling factors which includes hysteresis in the longitudinal and Hall resistances and a very weak temperature dependence of the resistance minima. All anomalies disappear and the conventional quantum Hall effect behavior recovers when a thin metal film is placed on top of the 2DHG. The behavior is attributed to presence of the theoretically predicted magnetic ordering at even integer filling factors which causes the formation of macroscopic spin-charge domains.
9804256v2
1998-11-18
Hall-effect in LuNi_2B_2C in normal and superconducting mixed states
The Hall resistivity rho_{xy} of LuNi_2B_2C is negative in the normal as well as in the mixed state and has no sign reversal typical for high-T_c superconductors. A distinct nonlinearity in the rho_{xy} dependence on field H was found in the normal state for T < 40K, accompanied by a large magnetoresistance reaching +90% for mu_0H=16T at T=20K. The scaling relation rho_{xy} ~ \rho_{xx}^\beta (\rho_{xx} is the longitudinal resistivity) was found in the mixed state, the value of \beta being dependent on the degree of disorder.
9811273v1
1999-07-22
Charge carrier density collapse in La_0.67Ca_0.33MnO_3 and La_0.67Sr_0.33MnO_3 epitaxial thin films
We measured the temperature dependence of the linear high field Hall resistivity of La_0.67Ca_0.33MnO_3 (T_C=232K) and La_0.67Sr_0.33MnO_3 (T_C=345K) thin films in the temperature range from 4K up to 360K in magnetic fields up to 20T. At low temperatures we find a charge carrier density of 1.3 and 1.4 holes per unit cell for the Ca- and Sr-doped compound, respectively. In this temperature range electron-magnon scattering contributes to the longitudinal resistivity. At the ferromagnetic transition temperature T_C a dramatic drop in the number of current carriers $n$ down to 0.6 holes per unit cell, accompanied by an increase in unit cell volume, is observed. Corrections of the Hall data due to a non saturated magnetic state will lead a more pronounced charge carrier density collapse.
9907346v1
1999-08-05
Fermi-level alignment at metal-carbon nanotube interfaces: application to scanning tunneling spectroscopy
At any metal-carbon nanotube interface there is charge transfer and the induced interfacial field determines the position of the carbon nanotube band structure relative to the metal Fermi-level. In the case of a single-wall carbon nanotube (SWNT) supported on a gold substrate, we show that the charge transfers induce a local electrostatic potential perturbation which gives rise to the observed Fermi-level shift in scanning tunneling spectroscopy (STS) measurements. We also discuss the relevance of this study to recent experiments on carbon nanotube transistors and argue that the Fermi-level alignment will be different for carbon nanotube transistors with low resistance and high resistance contacts.
9908073v3
1999-08-25
Hall effect of epitaxial double-perovskite Sr_2FeMoO_6 thin films
We prepared high epitaxial thin films of the compound Sr_2FeMoO_6 with narrow rocking curves by pulsed laser deposition. The diagonal and nondiagonal elements of the resistivity tensor were investigated at temperatures from 4 K up to room temperature in magnetic fields up to 8 T. An electronlike ordinary Hall effect and a holelike anomalous Hall contribution are observed. Both coefficients have reversed sign compared to the colossal magnetoresistive manganites. We found at 300 K an ordinary Hall coefficent of -1.87x10^{-10} m^3/As, corresponding to a nominal charge carrier density of four electrons per formula unit. At low temperature only a small negative magnetoresistance is observed which vanishes at higher temperatures. The temperature coefficient of the resistivity is negative over the whole temperature range. A Kondo like behavior is observed below 30 K while above 100 K variable range hopping like transport occurs.
9908361v2
1999-10-15
Electronic Transport in a Three-dimensional Network of 1-D Bismuth Quantum Wires
The resistance R of a high density network of 6 nm diameter Bi wires in porous Vycor glass is studied in order to observe its expected semiconductor behavior. R increases from 300 K down to 0.3 K. Below 4 K, where R varies approximately as ln(1/T), the order-of-magnitude of the resistance rise, as well as the behavior of the magnetoresistance are consistent with localization and electron-electron interaction theories of a one-dimensional disordered conductor in the presence of strong spin-orbit scattering. We show that this behaviour and the surface-enhanced carrier density may mask the proposed semimetal-to-semiconductor transition for quantum Bi wires.
9910241v1
2000-01-25
Pressure Induced Quantum Critical Point and Non-Fermi-Liquid Behavior in BaVS3
The phase diagram of BaVS3 is studied under pressure using resistivity measurements. The temperature of the metal to nonmagnetic Mott insulator transition decreases under pressure, and vanishes at the quantum critical point p_cr=20kbar. We find two kinds of anomalous conducting states. The high-pressure metallic phase is a non-Fermi liquid described by Delta rho = T^n where n=1.2-1.3 at 1K < T < 60K. At p<p_cr, the transition is preceded by a wide precursor region with critically increasing resistivity which we ascribe to the opening of a soft Coulomb gap.
0001371v2