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2012-05-15
Field-induced high coercive ferromagnetic state and magnetoresistance in the antiferromagnetically ordered compound Fe0.5TiS2
The measurements of the magnetic susceptibility, magnetization, electrical resistivity and magnetoresistance have been performed for the Fe intercalated compound Fe0.5TiS2. According to X-ray diffraction measurements the Fe0.5TiS2 compound synthesized in the present work has a monoclinic crystal structure (space group I12/m1) which results from the ordering of Fe ions and vacancies between S-Ti-S tri-layres. The changes in the heat-treatment conditions at temperatures below 1100 Celsius degrees do not lead to an order-disorder transition within the subsystem of intercalated Fe ions. It has been shown that this compound exhibits an antiferromagnetic (AF) ground state below the Neel temperature TN = 140 K. Application of the magnetic field at T < TN induces a metamagnetic phase transition to the ferromagnetic (F) state, which is accompanied by the large magnetoresistance effect (up to 27 %). The field-induced AF-F transition is found to be irreversible below ~ 100 K. The magnetization reversal in the metastable F state at low temperatures is accompanied by substantial hysteresis (~ 100 kOe) which is associated with the Ising character of Fe ions.
1205.3242v1
2012-05-16
A new approach for improving global critical current density in Fe(Se0.5Te0.5) polycrystalline materials
A novel method to prepare bulk Fe(Se0.5Te0.5) samples is presented, based on a melting process and a subsequent annealing treatment. With respect to the standard sintering technique, it produces much more homogeneous and denser samples, characterized by large and well interconnected grains. The resulting samples exhibit optimal critical temperature values, sharp resistive and magnetic transitions, large magnetic hysteresis loops and high upper critical fields are observed. Interestingly, the global critical current density is much enhanced as compared to the values reported in literature for bulk samples of the same 11 family, reaching about 103 A/cm2 at zero field at 4.2 K as assessed by magnetic, transport and magneto-optical techniques. Even more importantly, its field dependence turns out to be very weak, such that at \mu_{0}H = 7 T it is suppressed only by a factor \sim2.
1205.3618v2
2012-05-29
Transformation Electronics: Tailoring Electron's Effective Mass
The speed of integrated circuits is ultimately limited by the mobility of electrons or holes, which depend on the effective mass in a semiconductor. Here, building on an analogy with electromagnetic metamaterials and transformation optics, we describe a new transport regime in a semiconductor superlattice characterized by extreme anisotropy of the effective mass and a low intrinsic resistance to movement - with zero effective mass - along some preferred direction of electron motion. We theoretically demonstrate that such regime may permit an ultra fast, extremely strong electron response, and significantly high conductivity, which, notably may be weakly dependent on the temperature at low temperatures. These ideas may pave the way for faster electronic devices and detectors and new functional materials with a strong electrical response in the infrared regime.
1205.6325v2
2012-07-13
Association of indigo with zeolites for improved colour stabilization
The durability of an organic colour and its resistance against external chemical agents and exposure to light can be significantly enhanced by hybridizing the natural dye with a mineral. In search for stable natural pigments, the present work focuses on the association of indigo blue with several zeolitic matrices (LTA zeolite, mordenite, MFI zeolite). The manufacturing of the hybrid pigment is tested under varying oxidising conditions, using Raman and UV-visible spectrometric techniques. Blending indigo with MFI is shown to yield the most stable composite in all of our artificial indigo pigments. In absence of defects and substituted cations such as aluminum in the framework of the MFI zeolite matrix, we show that matching the pore size with the dimensions of the guest indigo molecule is the key factor. The evidence for the high colour stability of indigo@MFI opens a new path for modeling the stability of indigo in various alumino-silicate substrates such as in the historical Maya Blue pigment.
1207.3236v1
2012-08-09
The role of charge traps in inducing hysteresis: capacitance - voltage measurements on top gated bilayer graphene
Understanding the origin of hysteresis in the channel resistance from top gated graphene transistors is important for transistor applications. Capacitance - voltage measurements across the gate oxide on top gated bilayer graphene show hysteresis with a charging and discharging time constant of ~100 {\mu}s. However, the measured capacitance across the graphene channel does not show any hysteresis, but shows an abrupt jump at a high channel voltage due to the emergence of an order, indicating that the origin of hysteresis between gate and source is due to charge traps present in the gate oxide and graphene interface.
1208.1831v1
2012-08-15
A GEANT4 Simulation Studyof BESIII endcap TOF Upgrade
A GEANT4-based Monte-Carlo model is developed to study the performance of Endcap Time-Of-Flight (ETOF) at BESIII. It's found that the multiple scattering effects, mainly from the materials at the MDC endcap, can cause multi-hit on the ETOF's readout cell and significantly influence the timing property of ETOF. Multi-gap Resistive Plate Chamber (MRPC) with a smaller readout cell structure is more suitable for ETOF detector due to significantly reduced multi-hit rate, from 71.5% for currently-used scintillator-based ETOF to 21.8% or 16.7% for MRPC-based ETOF, depending on the readout pad size used. The timing performance of a MRPC ETOF is also improved. These simulation results suggest and guide an ETOF upgrade effort at BESIII.
1208.3049v1
2012-09-03
High Efficiency Graphene Solar Cells by Chemical Doping
We demonstrate single layer graphene/n-Si Schottky junction solar cells that under AM1.5 illumination exhibit a power conversion efficiency (PCE) of 8.6%. This performance, achieved by doping the graphene with bis(trifluoromethanesulfonyl)amide, exceeds the native(undoped) device performance by a factor of 4.5 and the best previously reported PCE in similar devices by a factor of nearly 6. Current-voltage, capacitance-voltage and external quantum efficiency measurements show the enhancement to be due to the doping induced shift in the graphene chemical potential which increases the graphene carrier density (decreasing the cell series resistance) and increases the built-in potential.
1209.0432v1
2012-09-12
Channel Length Scaling of MoS2 MOSFETs
In this article, we investigate electrical transport properties in ultrathin body (UTB) MoS2 two-dimensional (2D) crystals with channel lengths ranging from 2 {\mu}m down to 50 nm. We compare the short channel behavior of sets of MOSFETs with various channel thickness, and reveal the superior immunity to short channel effects of MoS2 transistors. We observe no obvious short channel effects on the device with 100 nm channel length (Lch) fabricated on a 5 nm thick MoS2 2D crystal even when using 300 nm thick SiO2 as gate dielectric, and has a current on/off ratio up to ~109. We also observe the on-current saturation at short channel devices with continuous scaling due to the carrier velocity saturation. Also, we reveal the performance limit of short channel MoS2 transistors is dominated by the large contact resistance from the Schottky barrier between Ni and MoS2 interface, where a fully transparent contact is needed to achieve a high-performance short channel device.
1209.2525v1
2012-09-24
Ba1-xNaxTi2Sb2O (0.0 <= x <= 0.33): A Layered Titanium-based Pnictide Oxide Superconductor
A new layered Ti-based pnictide oxide superconductor, Ba1-xNaxTi2Sb2O (0.0 <= x <= 0.33), is reported. X-ray studies reveal it crystallizes in the tetragonal CeCr2Si2C structure. The undoped parent compound, BaTi2Sb2O (P4/mmm; a=4.1196(1){\AA}; c=8.0951(2){\AA}), exhibits a CDW/SDW transition at 54K. Upon chemical doping with Na, the CDW/SDW transition is systematically suppressed and super-conductivity arises with the critical temperatures, Tc, increasing to 5.5 K. Bulk superconductivity is confirmed by resistivity, magnetic and heat capacity measurements. Like the high-Tc cuprates and the iron pnictides, superconductivity in BaTi2Sb2O arises from an ordered state. Similarities and differences to the cuprate and iron pnictide supercon-ductors are discussed.
1209.5447v2
2012-09-27
Fabrication and characterization of semiconducting half Heusler YPtSb thin films
The semiconducting half Heusler compound YPtSb was predicted theoretically to be capable of changing into topological insulator under proper strain. In this work, p type semiconducting half-Heusler YPtSb thin films were prepared by magnetron co-sputtering method from a specially designed target for the first time. Textured structure with (111) plane paralleling with (001) of MgO substrate was observed when YPtSb thin films were grown on MgO (100) substrate at 600{\deg}C.Electrical measurements show that the resistivity of YPtSb films decreases with increasing temperature, indicating a semiconductor-like behavior. The carrier density is as high as 1.15 X 10^21 cm-3 at 300 K. The band gap of YPtSb thin films obtained by infrared spectroscopy is around 0.1 - 0.15 eV, which is well in agreement with the theoretical prediction and the value measured in bulk YPtSb.
1209.6288v2
2012-10-08
Phonon thermal transport outside of local equilibrium in nanowires via molecular dynamics
We study thermal transport through Pt nanowires that bridge planar contacts as a function of wire length and vibrational frequency of the contacts. When phonons in the contacts have lower average frequencies than those in the wires thermal transport occurs under conditions away from local equilibrium with low-frequency phonons experiencing a higher thermal gradient than high-frequency ones. This results in a size-dependent increase in the effective thermal conductivity of the wire with decreasing vibrational frequencies of the contacts. The interfacial resistivity when heat flows from the wire to the contact is also size-dependent and has the same physical origin in the lack of full equilibration in short nanowires. We develop a model based on a 1D atomic chain that captures the salient physics of the MD results.
1210.2321v1
2012-10-19
Self-aligned graphene field-effect transistors with polyethyleneimine doped source/drain access regions
We report a method of fabricating self-aligned, top-gated graphene field-effect transistors (GFETs) employing polyethyleneimine spin-on-doped source/drain access regions, resulting in a 2X reduction of access resistance and a 2.5X improvement in device electrical characteristics, over undoped devices. The GFETs on Si/SiO$_2$ substrates have high carrier mobilities of up to 6,300 cm$^2$/Vs. Self-aligned spin-on-doping is applicable to GFETs on arbitrary substrates, as demonstrated by a 3X enhancement in performance for GFETs on insulating quartz substrates, which are better suited for radio frequency applications.
1210.5535v2
2012-10-22
Fabrication and characterization of the gapless half-Heusler YPtSb thin films
Half-Heusler YPtSb thin films were fabricated by magnetron co-sputtering method on MgO-buffered SiO2/Si(001) substrates. X-ray diffraction pattern and Energy dispersive X-ray spectroscopy confirmed the high-quality growth and stoichiometry. The temperature dependence of the resistivity shows a semiconducting-type behavior down to low temperature. The Hall mobility was determined to be 450 cm2/Vs at 300K, which is much higher than the bulk value (300 cm2/Vs). In-plane magnetoresistance (MR) measurements with fields applied along and perpendicular to the current direction show opposite MR signs, which suggests the possible existence of the topological surface states.
1210.5808v1
2012-10-29
Impact of graphene quantum capacitance on transport spectroscopy
We demonstrate experimentally that graphene quantum capacitance $C_{\mathrm{q}}$ can have a strong impact on transport spectroscopy through the interplay with nearby charge reservoirs. The effect is elucidated in a field-effect-gated epitaxial graphene device, in which interface states serve as charge reservoirs. The Fermi-level dependence of $C_{\mathrm{q}}$ is manifested as an unusual parabolic gate voltage ($V_{\mathrm{g}}$) dependence of the carrier density, centered on the Dirac point. Consequently, in high magnetic fields $B$, the spectroscopy of longitudinal resistance ($R_{xx}$) vs. $V_{\mathrm{g}}$ represents the structure of the unequally spaced relativistic graphene Landau levels (LLs). $R_{xx}$ mapping vs. $V_{\mathrm{g}}$ and $B$ thus reveals the vital role of the zero-energy LL on the development of the anomalously wide $\nu=2$ quantum Hall state.
1210.7601v1
2012-11-02
Interface characterization of Co2MnGe/Rh2CuSn Heusler multilayers
All-Heusler multilayer structures have been investigated by means of high kinetic x-ray photoelectron spectroscopy and x-ray magnetic circular dichroism, aiming to address the amount of disorder and interface diffusion induced by annealing of the multilayer structure. The studied multilayers consist of ferromagnetic Co$_2$MnGe and non-magnetic Rh$_2$CuSn layers with varying thicknesses. We find that diffusion begins already at comparably low temperatures between 200 $^{\circ}$C and 250 $^{\circ}$C, where Mn appears to be most prone to diffusion. We also find evidence for a 4 {\AA} thick magnetically dead layer that, together with the identified interlayer diffusion, are likely reasons for the small magnetoresistance found for current-perpendicular-to-plane giant magneto-resistance devices based on this all-Heusler system.
1211.0489v2
2012-11-13
The giant plasticity of a quantum crystal
When submitted to large stresses at high temperature, usual crystals may irreversibly deform. This phenomenon is known as plasticity and it is due to the motion of crystal defects such as dislocations. We have discovered that, in the absence of impurities and in the zero temperature limit, helium 4 crystals present a giant plasticity that is anisotropic and reversible. Direct measurements on oriented single crystals show that their resistance to shear nearly vanishes in one particular direction because dislocations glide freely parallel to the basal planes of the hexagonal structure. This plasticity disappears as soon as traces of helium 3 impurities bind to the dislocations or if their motion is damped by collisions with thermal phonons.
1211.2976v2
2012-11-14
High-temperature structural phase transition in multiferroic LiCu_2O_2
LiCu_2O_2 single crystals were studied in the temperature range 300-1100 K by means of heating-cooling curves of differential thermal analysis (DTA), thermogravimetry (TG), X-ray powder diffraction and electrical measurements. A reversible first-order phase transition between orthorhombic and tetragonal phases was found to take place at 993 K. At the transition, a peak is observed in the DTA curves, as well as jumps of the unit cell parameters and electrical resistivity. Considering the crystal structure of LiCu_2O_2 and the entropy change associated with the phase transition, it is concluded that the phase transition is related to processes of order-disorder of the Cu2+ and Li+ cations onto their crystallographic positions.
1211.3275v1
2012-11-14
Anisotropy and directional pinning in YBaCuO with BaZrO3 nanorods
Measurements of anisotropic transport properties (dc and high-frequency regime) of driven vortex matter in YBa$_2$Cu$_3$O$_{7-x}$ with elongated strong-pinning sites (c-axis aligned, self-assembled BaZrO$_3$ nanorods) are used to demonstrate that the effective-mass angular scaling takes place only in intrinsic physical quantities (flux-flow resistivity), and not in pinning-related Labusch parameter and critical currents. Comparison of the dynamics at different time scales shows evidence for a transition of the vortex matter toward a Mott phase, driven by the presence of nanorods. The strong pinning in dc arises partially from a dynamic effect.
1211.3311v2
2012-11-23
1D to 3D Dimensional Crossover in the Superconducting Transition of the Quasi-One-Dimensional Carbide Superconductor Sc3CoC4
The transition metal carbide superconductor Sc3CoC4 may represent a new benchmark system of quasi-1D superconducting behavior. We investigate the superconducting transition of a high-quality single crystalline sample by electrical transport experiments. Our data show that the superconductor goes through a complex dimensional crossover below the onset Tc of 4.5 K. First, a quasi-1D fluctuating superconducting state with finite resistance forms in the CoC4 ribbons which are embedded in a Sc matrix in this material. At lower temperature, the transversal Josephson or proximity coupling of neighboring ribbons establishes a 3D bulk superconducting state. This dimensional crossover is very similar to Tl2Mo6Se6, which for a long time has been regarded as the most appropriate model system of a quasi-1D superconductor. Sc3CoC4 appears to be even more in the 1D limit than Tl2Mo6Se6.
1211.5430v4
2012-11-26
Local transport measurements at mesoscopic length scales using scanning tunneling potentiometry
Under mesoscopic conditions, the transport potential on a thin film with current is theoretically expected to bear spatial variation due to quantum interference. Scanning tunneling potentiometry is the ideal tool to investigate such variation, by virtue of its high spatial resolution. We report in this {\it Letter} the first detailed measurement of transport potential under mesoscopic conditions. Epitaxial graphene at a temperature of 17K was chosen as the initial system for study because the characteristic transport length scales in this material are relatively large. Tip jumping artifacts are a major possible contribution to systematic errors; and we mitigate such problems by using custom-made slender and sharp tips manufactured by focussed ion beam. In our data, we observe residual resistivity dipoles associated with topoographical defects, and local peaks and dips in the potential that are not associated with topographical defects.
1211.6088v2
2012-12-06
Effects of spin density wave quantization on the electrical transport in epitaxial Cr thin films
We present measurements of the electrical resistivity, $\rho$, in epitaxial Cr films of different thicknesses grown on MgO (100) substrates, as a function of temperature, $T$. The $\rho(T)$ curves display hysteretic behavior in certain temperature range, which is film thickness dependent. The hysteresis are related to the confinement of quantized incommensurate spin density waves (ISDW) in the film thickness. Our important finding is to experimentally show that the temperature $T_{mid}$ where the ISDW changes from $N$ to $N$\,+\,1 nodes {\it decreases} as the film thickness {\it increases}. Identifying $T_{mid}$ with a first order transition between ISDW states with $N$ and $N$\,+\,1 nodes, and using a Landau approach to the free energy of the ISDW together with Monte Carlo simulations, we show that the system at high temperatures explores all available modes for the ISDW, freezing out in one particular mode at a transition temperature that indeed decreases with film thickness, $L$. The detailed dependence of $T_{mid}(L)$ seems to depend rather strongly on the boundary conditions at the Cr film interfaces.
1212.1408v1
2013-01-09
Hall effect measurements on epitaxial SmNiO3 thin films and implications for antiferromagnetism
The rare-earth nickelates (RNiO3) exhibit interesting phenomena such as unusual antiferromagnetic order at wavevector q = (1/2, 0, 1/2) and a tunable insulator-metal transition that are subjects of active research. Here we present temperature-dependent transport measurements of the resistivity, magnetoresistance, Seebeck coefficient, and Hall coefficient (RH) of epitaxial SmNiO3 thin films with varying oxygen stoichiometry. We find that from room temperature through the high temperature insulator-metal transition, the Hall coefficient is hole-like and the Seebeck coefficient is electron-like. At low temperature the N\'eel transition induces a crossover in the sign of RH to electron-like, similar to the effects of spin density wave formation in metallic systems but here arising in an insulating phase ~200 K below the insulator-metal transition. We propose that antiferromagnetism can be stabilized by bandstructure even in insulating phases of correlated oxides, such as RNiO3, that fall between the limits of strong and weak electron correlation.
1301.1968v3
2013-01-11
Batch-fabricated cantilever probes with electrical shielding for nanoscale dielectric and conductivity imaging
This paper presents the design and fabrication of batch-processed cantilever probes with electrical shielding for scanning microwave impedance microscopy. The diameter of the tip apex, which defines the electrical resolution, is less than 50 nm. The width of the stripline and the thicknesses of the insulation dielectrics are optimized for a small series resistance (< 5 W) and a small background capacitance (~ 1 pF), both critical for high sensitivity imaging on various samples. The coaxial shielding ensures that only the probe tip interacts with the sample. The structure of the cantilever is designed to be symmetric to balance the stresses and thermal expansions of different layers so that the cantilever remains straight under variable temperatures. Such shielded cantilever probes produced in the wafer scale will facilitate enormous applications on nanoscale dielectric and conductivity imaging.
1301.2402v1
2013-01-14
Pressure-Induced Superconductivity and Its Scaling with Doping-Induced Superconductivity in the Iron Pnictide with Skutterudite Intermediary Layers
The Ca10(PtnAs8)(Fe2As2)5 (n=3,4) compounds are a new type of iron pnictide superconductors whose structures consist of stacking Ca-PtnAs8-Ca-Fe2As2 layers in a unit cell. When n=3 (the 10-3-8 phase), the undoped compound is an antiferromagnetic (AFM) semiconductor, while, when n=4 (the 10-4-8 phase), the undoped compound is a superconductor with the transition temperature of 26K. Here we report the results of high-pressure studies on the 10-3-8 compound obtained through a combination of in-situ resistance, magnetic susceptibility, and Hall coefficient measurements. We find that its AFM order can be suppressed completely at 3.5 GPa and then superconducting state appears in the pressure range of 3.5-7 GPa. The pressure dependence of superconducting transition temperature displays a dome-like shape.
1301.2863v2
2013-02-08
Electrical transport across Au/Nb:SrTiO3 Schottky interface with different Nb doping
We have investigated electron transport in Nb doped SrTiO$_3$ single crystals for two doping densities. We find that the resistivity and mobility are temperature dependent in both whereas the carrier concentration is almost temperature invariant. We rationalize this using the hydrogenic theory for shallow donors. Further, we probe electrical transport across Schottky interfaces of Au on TiO$_2$ terminated n-type SrTiO$_3$. Quantitative analysis of macroscopic I-V measurements reveal thermionic emission dominated transport for the low doped substrate whereas it deviates from such behavior for the high doped substrate. This work is relevant for designing devices to study electronic transport using oxide-semiconductors.
1302.2096v1
2013-02-14
Transport studies of dual-gated ABC and ABA trilayer graphene: band gap opening and band structure tuning in very large perpendicular electric field
We report on the transport properties of ABC and ABA stacked trilayer graphene using dual, locally gated field effect devices. The high efficiency and large breakdown voltage of the HfO2 top and bottom gates enables independent tuning of the perpendicular electric field and the Fermi level over an unprecedentedly large range. We observe a resistance change of six orders of magnitude in the ABC trilayer, which demonstrates the opening of a band gap. Our data suggest that the gap saturates at a large displacement field of D ~ 3 V/nm, in agreement with self-consistent Hartree calculations. In contrast, the ABA trilayer remains metallic even under a large perpendicular electric field. Despite the absence of a band gap, the band structure of the ABA trilayer continues to evolve with increasing D. We observe signatures of two-band conduction at large D fields. Our self-consistent Hartree calculation reproduces many aspects of the experimental data, but also points to the need for more sophisticated theory.
1302.3432v1
2013-02-21
Superconductivity induced by U-doping in the SmFeAsO system
Through partial substitution of Sm by U in SmFeAsO, a different member of the family of iron-based superconductors was successfully synthesized. X-ray diffraction measurements show that the lattice constants along the a and c axes are both squeezed through U doping, indicating a successful substitution of U at the Sm site. The parent compound shows a strong resistivity anomaly near 150 K, associated with spin-density-wave instability.U doping suppresses this instability and leads to a transition to the superconducting state at temperatures up to 49 K. Magnetic measurements confirm the bulk superconductivity in this system. For the sample with a doping level of x = 0.2, the external magnetic field suppresses the onset temperature very slowly, indicating a rather high upper critical field. In addition, the Hall effect measurements show that U clearly dopes electrons into the material.
1302.5155v1
2013-04-10
Pinning in a Porous Bi2223
The current-voltage characteristics of a porous superconductor Bi2Sr2Ca2Cu3Ox (Bi2223) have been measured at temperature range from 10 to 90 K. The experimental dependences have been analyzed within the model allowing for pinning by clusters of a normal phase with fractal boundaries, as well as the model taking into account phase transformations of vortex matter. It has been found that the electrical resistance of the superconductor material significantly increases at temperatures of 60-70 K over the entire range of magnetic fields under consideration without changing in the sign of the curvature of the R(I) dependence. The melting of the vortex structure occurs at these temperatures. It has been assumed that this behavior is associated with the specific feature of the pinning in a highly porous high-temperature superconductor, which lies in the fractal distribution of pinning centers in a wide range of self-similarity scales.
1304.2844v1
2013-04-10
Multi-band superconductivity and nanoscale inhomogeneity at oxide interfaces
The two-dimensional electron gas at the LaTiO3/SrTiO3 or LaAlO3/SrTiO3 oxide interfaces becomes superconducting when the carrier density is tuned by gating. The measured resistance and superfluid density reveal an inhomogeneous superconductivity resulting from percolation of filamentary structures of superconducting "puddles" with randomly distributed critical temperatures, embedded in a non-superconducting matrix. Following the evidence that superconductivity is related to the appearance of high-mobility carriers, we model intra-puddle superconductivity by a multi-band system within a weak coupling BCS scheme. The microscopic parameters, extracted by fitting the transport data with a percolative model, yield a consistent description of the dependence of the average intra-puddle critical temperature and superfluid density on the carrier density.
1304.2970v1
2013-04-22
Electrical transport in C-doped GaAs nanowires: surface effects
The resistivity and the mobility of Carbon doped GaAs nanowires have been studied for different doping concentrations. Surface effects have been evaluated by comparing upassivated with passivated nanowires. We directly see the influence of the surface: the pinning of the Fermi level and the consequent existence of a depletion region lead to an increase of the mobility up to 30 cm^2/(V*s) for doping concentrations lower than 3*10^18 cm^-3. Electron beam induced current measurements show that the minority carrier diffusion path can be as high as 190 nm for passivated nanowires.
1304.5891v1
2013-05-23
Electronic origin of the orthorhombic Cmca structure in compressed elements and binary alloys
Formation of the complex structure with 16 atoms in the orthorhombic cell, space group Cmca (Pearson symbol oC16) was experimentally found under high pressure in the alkali elements (K, Rb, Cs) and polyvalent elements of groups IV (Si, Ge) and V (Bi). Intermetallic phases with this structure form under pressure in binary Bi-based alloys (Bi-Sn, Bi-In, Bi-Pb). Stability of the Cmca - oC16 structure is analyzed within the nearly free-electron model in the frame of Fermi sphere - Brillouin zone interaction. A Brillouin-Jones zone formed by a group of strong diffraction reflections close to the Fermi sphere is the reason for reduction of crystal energy and stabilization of the structure. This zone corresponds well to the 4 valence electrons in Si and Ge and leads to assume a spd-hybridization for Bi. To explain the stabilization of this structure within the same model in alkali metals, that are monovalent at ambient conditions, a possibility of an overlap of the core and valence band electrons at strong compression is considered. The assumption of the increase in the number of valence electrons helps to understand sequences of complex structures in compressed alkali elements and unusual changes in their physical properties such as electrical resistance and superconductivity.
1305.5341v1
2013-05-29
Intrinsic and extrinsic origins of low-frequency noise in GaAs/AlGaAs Schottky-gated nanostructures
We study low-frequency noise in current passing through quantum point contacts fabricated from several GaAs/AlGaAs heterostructures with different layer structures and fabrication processes. In contrast to previous reports, there is no gate-dependent random telegraph noise (RTN) originating from tunneling through a Schottky barrier in devices fabricated using the standard low-damage process. Gate-dependent RTN appears only in devices fabricated with a high-damage process that induces charge trap sites. We show that the insertion of AlAs/GaAs superlattices in the AlGaAs barrier helps to suppress trap formation. Our results enable the fabrication of damage-resistant and thus low-noise devices.
1305.6701v1
2013-06-29
Coexistence of Half-Metallic Itinerant Ferromagnetism with Local-Moment Antiferromagnetism in Ba{0.60}K{0.40}Mn2As2
Magnetization, nuclear magnetic resonance, high-resolution x-ray diffraction and magnetic field-dependent neutron diffraction measurements reveal a novel magnetic ground state of Ba{0.60}K{0.40}Mn2As2 in which itinerant ferromagnetism (FM) below a Curie temperature TC = 100 K arising from the doped conduction holes coexists with collinear antiferromagnetism (AFM) of the Mn local moments that order below a Neel temperature TN = 480 K. The FM ordered moments are aligned in the tetragonal ab-plane and are orthogonal to the AFM-ordered Mn moments that are aligned along the c-axis. The magnitude and nature of the low-T FM ordered moment correspond to complete polarization of the doped-hole spins (half-metallic itinerant FM) as deduced from magnetization and ab-plane electrical resistivity measurements.
1307.0091v2
2013-07-22
Dimensional-Crossover-Driven Mott Insulators in SrVO3 Ultrathin Films
High-quality epitaxial SrVO3 (SVO) thin films of various thicknesses were grown on (001)-oriented LSAT substrates by pulsed electron-beam deposition technique. Thick SVO films (~25 nm) exhibited metallic behavior with the electrical resistivity following the T2 law corresponding to a Fermi liquid system. We observed a temperature driven metal-insulator transition (MIT) in SVO ultrathin films with thicknesses below 6.5 nm, the transition temperature TMIT was found to be at 50 K for the 6.5 nm film, 120 K for the 5.7 nm film and 205 K for the 3 nm film. The emergence of the observed MIT can be attributed to the dimensional crossover from a three-dimensional metal to a two-dimensional Mott insulator, as the resulting reduction in the effective bandwidth W opens a band gap at the Fermi level. The magneto-transport study of the SVO ultrathin films also confirmed the observed MIT is due to the electron-electron interactions other than localization.
1307.5819v2
2013-07-26
Electron-phonon coupling in cuprate and iron-based superconductors revealed by Raman scattering
Electron-phonon coupling (EPC) is one of the most common and fundamental interactions in solids. It not only dominates many basic dynamic processes like resistivity, thermal conductivity etc, but also provides the pairing glue in conventional superconductors. But in high-temperature superconductors (HTSC), it is still controversial whether or not EPC is in favor of paring. Despite the controversies, many experiments have provided clear evidence for EPC in HTSC. In this paper, we briefly review EPC in cuprate and iron-based superconducting systems revealed by Raman scattering. We introduce how to extract the coupling information through phonon lineshape. Then we discuss the strength of EPC in different HTSC systems and possible factors affecting the strength. The comparative study between Raman phonon theories and experiments allows us to gain insight into some crucial electronic properties, especially superconductivity. Finally we summarize and compare EPC in the two existing HTSC systems, and discuss what role it may play in HTSC.
1307.6972v1
2014-02-10
Evolution and defect analysis of vertical graphene nanosheets
We report catalyst-free direct synthesis of vertical graphene nanosheets (VGNs) on SiO2/Si and quartz substrates using microwave electron cyclotron resonance - plasma enhanced chemical vapor deposition. The evolution of VGNs is studied systematically at different growth stages. Raman analysis as a function of growth time reveals that two different disorder-induced competing mechanisms contributing to the defect band intensity. The VGNs grown on SiO2/Si substrates predominantly consists of both vacancy-like and hopping defects. On the other hand, the VGNs grown on quartz substrates contain mainly boundary-like defects. XPS studies also corroborate Raman analysis in terms of defect density and vacancy-like defects for the VGNs grown on SiO2/Si substrates. Moreover, the grown VGNs exhibit a high optical transmittance from 95 to 78 % at 550 nm and the sheet resistance varies from 30 to 2.17 kohms/square depending on growth time.
1402.2074v3
2014-02-19
Phase Diagram of Micron-Size Bridges of SrTiO$_3/$LaAlO$_3$ Interface: Link Between Multiple Band Structure and Superconductivity
The rich phase diagram of the two dimensional electron gas (2DEG) at the \STO/\LAO interface is probed using Hall and longitudinal resistivity. Thanks to a special bridge design we are able to tune through the superconducting transition temperature T$_c$ and to mute superconductivity by either adding or removing carriers in a gate bias range of a few volts. Hall signal measurements pinpoint the onset of population of a second mobile band right at the carrier concentration where maximum superconducting T$_c$ and critical field H$_c$ occur. These results emphasize the advantages of our design, which can be applied to many other two dimensional systems assembled on top of a dielectric substrate with high permittivity.
1402.4646v1
2014-03-04
Effect of modulations of doping and strain on the electron transport in monolayer MoS_2
The doping and strain effects on the electron transport of monolayer MoS_2 are systematically investigated using the first-principles calculations with Boltzmann transport theory. We estimate the mobility has a maximum 275 cm^2/(Vs) in the low doping level under the strain-free condition. The applying a small strain (3%) can improve the maximum mobility to 1150 cm^2/(Vs) and the strain effect is more significant in the high doping level. We demonstrate that the electric resistance mainly due to the electron transition between K and Q valleys scattered by the M momentum phonons. However, the strain can effectively suppress this type of electron-phonon coupling by changing the energy difference between the K and Q valleys. This sensitivity of mobility to the external strain may direct the improving electron transport of MoS_2.
1403.0695v2
2014-03-29
Two components for one resistivity in LaVO3/SrTiO3 heterostructures
A series of 100 nm LaVO3 thin films have been synthesized on (001)-oriented SrTiO3 substrates using the pulsed laser deposition technique, and the effects of growth temperature are analyzed. Transport properties reveal a large electronic mobility and a non-linear Hall effect at low temperature. In addition, a cross-over from a semiconducting state at high-temperature to a metallic state at low-temperature is observed, with a clear enhancement of the metallic character as the growth temperature increases. Optical absorption measurements combined with the two-bands analysis of the Hall effect show that the metallicity is induced by the diffusion of oxygen vacancies in the SrTiO3 substrate. These results allow to understand that the film/substrate heterostructure behaves as an original semiconducting-metallic parallel resistor, and electronic transport properties are consistently explained.
1403.7648v2
2014-04-07
Directional pinning and anisotropy in YBa2Cu3O7-x with BaZrO3 nanorods: intrinsic and nanorods-induced anisotropy
We present a study of the anisotropic vortex parameters as obtained from measurements of the microwave complex resistivity in the vortex state with a tilted applied magnetic field in YBa2Cu3O7-x thin films with BaZrO3 nanorods. We present the angular dependence of the vortex viscosity $\eta$, the pinning constant k_p and the upper limit for the creep factor \chi_M. We show that the directional effect of the nanorods is absent in \eta, which is dictated by the mass anisotropy \gamma. By contrast, pinning-mediated properties are strongly affected by the nanorods. It is significant that the pinning and creep affected by the nanorods is detectable also at our very high operating frequency, which implies very short-range displacements of the vortices from their equilibrium position.
1404.1670v1
2014-05-07
Anisotropic giant magnetoresistance in NbSb2
The extremely large transverse magnetoreistance (the magnetoresistant ratio $\sim 1.3\times10^5\%$ in 2 K and 9 T field, and $4.3\times 10^6\%$ in 0.4 K and 32 T field, without saturation), and the metal-semiconductor crossover induced by magnetic field, are reported in NbSb$_2$ single crystal with electric current parallel to the $b$-axis. The metal-semiconductor crossover is preserved when the current is along the $ac$-plane but the magnetoresistant ratio is significantly suppressed. The sign reversal of the Hall resistivity in the field close to the crossover point, and the electronic structure calculation reveals the coexistence of a small number of holes with very high mobility and a large number of electrons with low mobility. These effects are attributed to the change of the Fermi surface induced by the magnetic field.
1405.1719v2
2014-06-05
Current transport and thermoelectric properties of very high power factor Fe3O4 / SiO2 / p-type Si (001) devices
The current transport and thermoelectric properties of Fe3O4 / SiO2 / p-type Si(001) heterostructures with Fe3O4 thicknesses of 150, 200, and 350 nm have been investigated between 100 and 300 K. We observe a sharp drop of the in-plane resistivity at 200K due to the onset of conduction along the Si / SiO2 interface related to tunneling of electrons from the Fe3O4 into the accumulation layer of holes at the Si / SiO2 interface, whose existence was confirmed by capacitance-voltage measurements and a two band analysis of the Hall effect. This is accompanied by a large increase of the Seebeck coefficient reaching +1000 {\mu}V/K at 300K that is related to holes in the p-type Si(001) and gives a power factor of 70 mW/K2m when the Fe3O4 layer thickness is reduced down to 150 nm. We show that most of the current flows in the Fe3O4 layer at 300 K, while the Fe3O4 / SiO2 / p-type Si(001) heterostructures behave like tunneling p-n junctions in the transverse direction.
1406.1282v1
2014-06-20
Anomalous Hall Effect in Ge(1-x-y)Pb(x)Mn(y)Te Composite System
The purpose of this study was to investigate the magnetotransport properties of the Ge(0.743)Pb(0.183)Mn(0.074)Te mixed crystal. The results of magnetization measurements indicated that the compound is a spin-glass-like diluted magnetic semiconductor with critical temperature TSG = 97.5 K. Nanoclusters in the sample are observed. Both, matrix and clusters are magnetically active. Resistivity as a function of temperature has a minimum at 30 K. Below the minimum a variable-range hopping is observed, while above the minimum a metallic-like behavior occurs. The crystal has high hole concentration, p = 6.6E20 cm-3, temperature-independent. Magnetoresistance amplitude changes from -0.78 to 1.18% with increase of temperature. In the magnetotransport measurements we observed the anomalous Hall effect (AHE) with hysteresis loops. Calculated AHE coefficient, RS = 2.0E6 m3/C, is temperature independent. The analysis indicates the extrinsic skew scattering mechanism to be the main physical mechanism responsible for AHE in Ge(0.743)Pb(0.183)Mn(0.074)Te alloy.
1406.5294v1
2014-07-22
Universal scaling of the critical temperature for thin films near the superconducting-to-insulating transition
Thin superconducting films form a unique platform for geometrically-confined, strongly-interacting electrons. They allow an inherent competition between disorder and superconductivity, which in turn enables the intriguing superconducting-to-insulator transition and believed to facilitate the comprehension of high-Tc superconductivity. Furthermore, understanding thin film superconductivity is technologically essential e.g. for photo-detectors, and quantum-computers. Consequently, the absence of an established universal relationships between critical temperature ($T_c$), film thickness ($d$) and sheet resistance ($R_s$) hinders both our understanding of the onset of the superconductivity and the development of miniaturised superconducting devices. We report that in thin films, superconductivity scales as $d^.$$T_c(R_s)$. We demonstrated this scaling by analysing the data published over the past 46 years for different materials (and facilitated this database for further analysis). Moreover, we experimentally confirmed the discovered scaling for NbN films, quantified it with a power law, explored its possible origin and demonstrated its usefulness for superconducting film-based devices.
1407.5945v2
2014-09-18
Electrical and optical properties of ITO thin films prepared by DC magnetron sputtering for low-emitting coatings
Optimized DC magnetron sputtering system for the deposition of transparent conductive oxides (TCOs), such indium tin oxide (ITO) on glass substrate has been applied in order to achieve low-emitting (low-e) transparent coatings. To obtain the concerned electrical resistance and high infrared reflection, first the effect of applied sputtering power then oxygen flow on the properties of films have been investigated. The other depositions parameters are kept constant. Film deposition at at temperature 400 degree of Celsius in oxygen flow of 3 Standard Cubic Centimeters per Minute results in transparent and infrared reflecting coatings. Under this condition the highest attained average reflectance in the infrared is ({\lambda}=3-25 micron) 89.5% (lowest emittance equals to less than 11%), whereas transparency in the visible is 85% approximately. Plasma wavelength and carrier concentration was measured.
1409.5293v1
2014-09-25
Characterisation of Glass Electrodes and RPC Detectors for $INO-ICAL$ Experiment
India-based Neutrino Observatory (INO) is a planned neutrino experiment to be build up in southern part of India.The INO observatory will host a 51 kton Iron Calorimeter (ICAL) detector to detect atmospheric neutrinos. Resistive Plate Chamber (RPC) has been chosen as the active detector element for the ICAL experiment. The ICAL experiment will consist of about 28,000 RPC's of dimension $2~m\times 2~m$, divided into three modules. The experiment is planned to take data at least for 20 years from its start date. Due to the large number of RPC needed for ICAL experiment and the long lifetime of the experiment, it is necessary to carry out detailed $R\&D$ to optimise each and every parameter of the detector performance. We report on the performance studies carried out on the RPC's made with these electrodes, and finally compare the detector performance with that of the material properties to optimise the detector parameters.
1409.7184v1
2014-11-24
Thermoelectric power of bulk black-phosphorus
The potential of bulk black-phosphorus for thermoelectric applications has been experimentally studied. The Seebeck Coefficient (S) has been measured in the temperature range from 300 K to 385 K, finding a value of S = +335 +- 10 uV/K at room temperature (indicating a naturally occurring p-type conductivity). S increases with temperature, as expected for p-type semiconductors, which can be attributed to an increase of the charge carrier density. The electrical resistance drops up to a 40 % while heating in the studied temperature range. As a consequence, the power factor at 385 K is 2.7 times higher than that at room temperature. This work demonstrates the feasibility of black-phosphorus in thermoelectric applications, such as thermal energy scavenging, which typically require devices with high performance at temperatures above room temperature.
1411.6468v2
2014-11-26
Towards high mobility InSb nanowire devices
We study the low-temperature electron mobility of InSb nanowires. We extract the mobility at 4.2 Kelvin by means of field effect transport measurements using a model consisting of a nanowire-transistor with contact resistances. This model enables an accurate extraction of device parameters, thereby allowing for a systematic study of the nanowire mobility. We identify factors affecting the mobility, and after optimization obtain a field effect mobility of $\sim2.5\mathbin{\times}10^4$ cm$^2$/Vs. We further demonstrate the reproducibility of these mobility values which are among the highest reported for nanowires. Our investigations indicate that the mobility is currently limited by adsorption of molecules to the nanowire surface and/or the substrate.
1411.7285v2
2014-12-22
Large anisotropic thermal conductivity of intrinsically two-dimensional metallic oxide PdCoO$_2$
The highly conductive layered metallic oxide \pdcoo{} is a near-perfect analogue to an alkali metal in two dimensions. It is distinguished from other two-dimensional electron systems where the Fermi surface does not reach the Brillouin zone boundary by a high planar electron density exceeding $10^{15}$ cm$^{-2}$. The simple single-band quasi-2D electronic structure results in strongly anisotropic transport properties and limits the effectiveness of electron-phonon scattering. Measurements on single crystals in the temperature range from 10-300K show that the thermal conductivity is much more weakly anisotropic than the electrical resistivity, as a result of significant phonon heat transport. The in-plane thermoelectric power is linear in temperature at 300\,K and displays a purity-dependent peak around 50K. Given the extreme simplicity of the band-structure, it is possible to identify this peak with phonon drag driven by normal electron-phonon scattering processes.
1412.6919v1
2015-02-06
Anomalous Pressure Dependence of magnetic Ordering Temperature in Tb to 141 GPa: Comparison with Gd and Dy
In previous studies the pressure dependence of the magnetic ordering temperature $T_{\text{o}}$ of Dy was found to exhibit a sharp increase above its volume collapse pressure of 73 GPa, appearing to reach temperatures well above ambient at 157 GPa. In a search for a second such lanthanide, electrical resistivity measurements were carried out on neighboring Tb to 141 GPa over the temperature range 3.8 - 295 K. Below Tb's volume collapse pressure of 53 GPa, the pressure dependence $T_{\text{o}}(P)$ mirrors that of both Dy and Gd. However, at higher pressures $T_{\text{o}}(P)$ for Tb becomes highly anomalous. This result, together with the very strong suppression of superconductivity by dilute Tb ions in Y, suggests that extreme pressure transports Tb into an unconventional magnetic state with an anomalously high magnetic ordering temperature.
1502.01785v1
2015-02-07
Interband Tunneling for Hole Injection in III-Nitride Ultra-violet Emitters
Ultra-violet emitters have several applications in the areas of sensing, water purification, and data storage. While the III-Nitride semiconductor system has the band gap region necessary for ultraviolet emission, achieving efficient ultraviolet solid state emitters remains a challenge due to the low p-type conductivity and high contact resistance in wide band gap AlGaN-based ultra-violet light emitters. In this work, we show that efficient interband tunneling can be used for non-equilibrium injection of holes into ultraviolet emitters. Polarization-engineered tunnel junctions were used to enhance tunneling probability by several orders of magnitude over a PN homojunction, leading to highly efficient tunnel injection of holes to ultraviolet light emitters. This demonstration of efficient interband tunneling introduces a new paradigm for design of ultra-violet light emitting diodes and diode lasers, and enables higher efficiency and lower cost ultra-violet emitters.
1502.02080v1
2015-02-27
Quantum oscillations, thermoelectric coefficients and the Fermi surface of semi-metallic WTe2
We present a study of angle-resolved quantum oscillations of electric and thermoelectric transport coefficients in semi-metallic WTe$_{2}$, which has the particularity of displaying a large B$^{2}$ magneto-resistance. The Fermi surface consists of two pairs of electron-like and hole-like pockets of equal volumes in a "Russian doll" structure. Carrier density, Fermi energy, mobility and the mean-free-path of the system are quantified. An additional frequency is observed above a threshold field and attributed to magnetic breakdown across two orbits. In contrast to all other dilute metals, the Nernst signal remains linear in magnetic field even in the high-field ($\omega_c\tau \gg 1$) regime. Surprisingly, none of the pockets extend across the c-axis of the first Brillouin zone, making the system a three-dimensional metal with moderate anisotropy in Fermi velocity yet a large anisotropy in mean-free-path.
1502.07797v2
2015-05-19
Energy Exchange between Phononic and Electronic Subsystem Governing The Nonlinear Conduction in DCNQI$_2$Cu
We present a dynamical study on the nonlinear conduction behaviour in the commensurate charge-density-wave phase of the quasi-one-dimensional conductor DCNQI$_2$Cu below 75 K. We can accurately simulate magnitude and time-dependence of the measured conductivity in response to large voltage pulses by accounting for the energy exchange between the phononic and electronic subsystems by means of an electrothermal model. Our simulations reveal a distinct non-equilibrium population of optical phonon states with an average energy of E$_{ph}$ = 19 meV being half the activation energy of about $\Delta$E$_a$ = 39 meV observed in DC resistivity measurements. By inelastic scattering, this hot optical phonon bath generates additional charge-carrying excitations thus providing a multiplication effect while energy transferred to the acoustic phonons is dissipated out of the system via heat conduction. Therefore, in high electric fields a preferred interaction of charge-carrying excitations with optical phonons compared to acoustic phonon modes is considered to be responsible for the nonlinear conduction effects observed in DCNQI$_2$Cu.
1505.04907v2
2015-08-19
Argument on superconductivity pairing mechanism from cobalt impurity doping in FeSe: spin ($s_{\pm}$) or orbital ($s_{++}$) fluctuation
In high-superconducting transition temperature ($T_{\rm c}$) iron-based superconductors, interband sign reversal ($s_{\rm \pm}$) and sign preserving ($s_{\rm ++}$) $s$-wave superconducting states have been primarily discussed as the plausible superconducting mechanism. We study Co impurity scattering effects on the superconductivity in order to achieve an important clue on the pairing mechanism using single crystal Fe$_{1-x}$Co$_x$Se and depict a phase diagram of a FeSe system. Both superconductivity and structural transition / orbital order are suppressed by the Co replacement on the Fe sites and disappear above $x$ = 0.036. These correlated suppressions represent a common background physics behind these physical phenomena in the multiband Fermi surfaces of FeSe. By comparing experimental data and theories so far proposed, the suppression of $T_{\rm c}$ against the residual resistivity is shown to be much weaker than that predicted in the case of a general sign reversal and a full gap $s_{\pm}$ models. The origin of the superconducting paring in FeSe is discussed in terms of its multiband electronic structure.
1508.04605v2
2015-08-19
Electric field control of spin lifetimes in Nb-SrTiO$_3$ by spin-orbit fields
We show electric field control of the spin accumulation at the interface of the oxide semiconductor Nb-SrTiO$_{3}$ with Co/AlO$_{x}$ spin injection contacts at room temperature. The in-plane spin lifetime $\tau_\parallel$ as well as the ratio of the out-of-plane to in-plane spin lifetime $\tau_\perp/\tau_\parallel$ is manipulated by the built-in electric field at the semiconductor surface, without any additional gate contact. The origin of this manipulation is attributed to Rashba Spin-Orbit Fields (SOFs) at the Nb-SrTiO$_3$ surface and shown to be consistent with theoretical model calculations based on SOF spin flip scattering. Additionally, the junction can be set in a high or low resistance state, leading to a non-volatile control of $\tau_\perp/\tau_\parallel$, consistent with the manipulation of the Rashba SOF strength. Such room temperature electric field control over the spin state is essential for developing energy-efficient spintronic devices and shows promise for complex oxide based (spin)electronics
1508.04649v1
2015-09-13
Effects of Cr substitution on the magnetic and transport properties and electronic states of SrRuO3 epitaxial thin films
The effect of Cr substitution in a SrRuO3 epitaxial thin film on SrTiO3 substrate was investigated by measuring the magnetic and transport properties and the electronic states. The ferromagnetic transition temperature of the SrRu0.9Cr0.1O3 film (166 K) was higher than that of the SrRuO3 film (147 K). Resonant photoemission spectroscopy experimentally revealed that the Cr 3dt2g orbital is hybridized with the Ru 4dt2g orbital in the SrRu0.9Cr0.1O3 film, supporting the assumption that the enhancement of the ferromagnetic transition temperature through Cr substitution stems from the widening of energy bands due to the hybridization of Cr 3dt2g and Ru 4dt2g orbitals. Furthermore, we found that the Hall resistivity of the SrRu0.9Cr0.1O3 film at low temperature is not a linear function of magnetic field in the high-field region where the out-of-plane magnetization was saturated; this result suggests that the SrRu0.9Cr0.1O3 film undergoes a structural transition at low temperature accompanied with the modulation of the Fermi surface.
1509.03804v1
2015-10-22
Anomalous transport and thermoelectric performances of CuAgSe compounds
The copper silver selenide has two phases: the low-temperature semimetal phase ({\alpha}-CuAgSe) and high-temperature phonon-glass superionic phase (\b{eta}-CuAgSe). In this work, the electric transport and thermoelectric properties of the two phases are investigated. It is revealed that the \b{eta}-CuAgSe is a p-type semiconductor and exhibits low thermal conductivity while the {\alpha}-CuAgSe shows metallic conduction with dominant n-type carriers and low electrical resistivity. The thermoelectric figure of merit zT of the polycrystalline \b{eta}-CuAgSe at 623 K is ~0.95, suggesting that superionic CuAgSe can be a promising thermoelectric candidate in the intermediate temperature range.
1510.06616v1
2015-11-12
Experimental and numerical analysis of tribological behavior of CrAl(Si)N films during Scratch
Scratch sliding tests with a ZrO2 ball and CrAlSiN films with different Si content were conducted due to CrAlSiN films having high hardness and good wear resistance. After up to 6000 cycles the specimens were analyzed by Scanning Electron Microscopy. The friction coefficient of CrAlSiN was lower than that of CrAlN film.A corresponding three-dimensional finite element model was constructed with the help of the ABAQUS to describe the mechanical response during scratch. A comparison of experimental and computational results revealed that the small elastic deformation took place in the films and substrates;the deformation friction coefficient was negligible in comparison with the Coulomb friction coefficient;and with increasing Young's modulus, the stress concentration was more obvious in CrAlSiN than in CrAlN.
1511.04092v2
2015-12-27
Room-temperature paramagnetoelectric effect in magnetoelectric multiferroics Pb(Fe1/2Nb1/2)O3 and its solid solution with PbTiO3
We have observed the magnetoelectric response at room temperature and above in high-resistive ceramics made of multiferroic Pb(Fe1/2Nb1/2)O3 (PFN) and PFN-based solid solution 0.91PFN-0.09PbTiO3 (PFN-PT). The value of the paramagnetoelectric (PME) coefficient shows a pronounced maximum near the ferroelectric-to-paraelectric phase transition temperature, T_C, and then decreases sharply to zero for T>T_C. The maximal PME coefficient in PFN is about 4x10(-18) s/A. The theoretical description of the PME effect, within the framework of a Landau theory of phase transitions allowing for realistic temperature dependences of spontaneous polarization, dielectric and magnetic susceptibilities, qualitatively reproduces well the temperature dependence of the PME coefficient. In particular, the Landau theory predicts the significant increase of the PME effect at low temperatures and near the temperature of the paraelectric-to-ferroelectric phase transition, since the PME coefficient is equal to the product of the spontaneous polarization, dielectric permittivity, square of magnetic susceptibility and the coefficient quantifying the strength of the biquadratic magnetoelectric coupling
1512.08217v1
2015-12-31
Intrinsic Nanotwin Effect on Thermal Boundary Conductance in Bulk and Single-Nanowire Twinning Superlattices
Coherent twin boundaries form periodic lamellar twinning in a wide variety of semiconductor nanowires, and are often viewed as near-perfect interfaces with reduced phonon and electron scattering behaviors. Such unique characteristics are of practical interest for high-performance thermoelectrics and optoelectronics; however, insufficient understanding of twin-size effects on thermal boundary resistance poses significant limitations for potential applications. Here, using atomistic simulations and ab-initio calculations, we report direct computational observations showing a crossover from diffuse interface scattering to superlattice-like behavior for thermal transport across nanoscale twin boundaries present in prototypical bulk and nanowire Si examples. Intrinsic interface scattering is identified for twin periods larger than or equal to 22.6 nm, but also vanishes below this size to be replaced by ultrahigh Kapitza thermal conductances. Detailed analysis of vibrational modes shows that modeling twin boundaries as atomically-thin 6H-Si layers, rather than phonon scattering interfaces, provides an accurate description of effective cross-plane and in-plane thermal conductivities in twinning superlattices, as a function of the twin period thickness.
1512.09357v2
2016-02-20
Investigation of the electron-phonon interaction in $N{{b}_{3}}Sn$ with the aid of microcontacts
The method of microcontact spectroscopy in the superconducting state was used to investigate weak nonlinearities of the current-voltage characteristics of point contacts made of $N{{b}_{3}}Sn$ single crystals. The nature of the spectrum of the electron-phonon interaction was found to vary considerably from contact to contact, indicating considerable deviations of the composition of the surface of $N{{b}_{3}}Sn$ from stoichiometry. A correlation was established between the nature of the spectrum and the magnitude of the gap singularities of the current-voltage characteristics. In the case of "dirty" high-resistance contacts with strong gap singularities the microcontact spectra were reasonably reproducible, which made it possible to relate them sufficiently closely to the microcontact function of the electron-phonon interaction in the bulk material. It was found that microcontact spectroscopy of this interaction was possible in the superconducting state not only in dirty $S-c-S$ contacts, but also in dirty $S-c-N$ contacts.
1602.06398v1
2016-04-11
Single crystal growth of CeTAl$_3$ (T = Cu, Ag, Au, Pd and Pt)
We report single crystal growth of the series of CeTAl$_3$ compounds with T = Cu, Ag, Au, Pd and Pt by means of optical float zoning. High crystalline quality was confirmed in a thorough characterization process. With the exception of CeAgAl$_3$, all compounds crystallize in the non-centrosymmetric tetragonal BaNiSn$_{3}$ structure (space group: I4mm, No. 107), whereas CeAgAl$_3$ adopts the related orthorhombic PbSbO$_2$Cl structure (Cmcm, No. 63). An attempt to grow CeNiAl$_3$ resulted in the composition CeNi$_2$Al$_5$. Low temperature resistivity measurements down to $\sim$0.1K did not reveal evidence suggestive of magnetic order in CePtAl$_3$ and CePdAl$_3$. In contrast, CeAuAl$_3$, CeCuAl$_3$ and CeAgAl$_3$ display signatures of magnetic transitions at 1.3K, 2.1K and 3.2K, respectively. This is consistent with previous reports of antiferromagnetic order in CeAuAl$_3$, and CeCuAl$_3$ as well as ferromagnetism in CeAgAl$_3$, respectively.
1604.03146v1
2016-04-14
Large magnetothermopower and Fermi surface reconstruction in Sb$_2$Te$_2$Se
We report the magnetoresistance, magnetothermopower and quantum oscillation study of Sb$_2$Te$_2$Se single crystal. The in-plane transverse magnetoresistance exhibits a crossover at a critical field $B^*$ from semiclassical weak-field $B^2$ dependence to the high-field unsaturated linear magnetoresistance which persists up to the room temperature. The low-temperature Seebeck coefficient is negative in zero field contrary to the positive Hall resistivity, indicating the multiband effect. The magnetic field induced the sign reversion of the Seebeck coefficient between 2 K and 150 K, . The quantum oscillation of crystals reveals the quasi-two-dimensional (quasi-2D) Fermi surface. These effects are possibly attributed to the large Fermi surface which touches Brillouin zone boundary to becomes quasi-2D and the variation in the chemical potential induced by the magnetic field.
1604.04281v1
2016-04-15
Electronic Structure Descriptor for Discovery of Narrow-Band Red-Emitting Phosphors
Narrow-band red-emitting phosphors are a critical component in phosphor-converted light-emitting diodes for highly efficient illumination-grade lighting. In this work, we report the discovery of a quantitative descriptor for narrow-band Eu2+-activated emission identified through a comparison of the electronic structure of known narrow-band and broad-band phosphors. We find that a narrow emission bandwidth is characterized by a large splitting of more than 0.1 eV between the two highest Eu2+ 4f7 bands. By incorporating this descriptor in a high throughput first principles screening of 2,259 nitride compounds, we identify five promising new nitride hosts for Eu2+-activated red-emitting phosphors that are predicted to exhibit good chemical stability, thermal quenching resistance and quantum efficiency, as well as narrow-band emission. Our findings provide important insights into the emission characteristics of rare-earth activators in phosphor hosts, and a general strategy to the discovery of phosphors with a desired emission peak and bandwidth.
1604.04581v1
2016-04-18
Superconductivity in undoped CaFe2As2 single crystals
Single crystals of undoped CaFe2As2 were grown by a FeAs self-flux method, and the crystals were quenched in ice-water rapidly after high temperature growth. The quenched crystal undergoes a collapsed tetragonal structural phase transition around 80 K revealed by the temperature dependent X-ray diffraction measurements. Superconductivity below 25 K was observed in the collapsed phase by resistivity and magnetization measurements. The isothermal magnetization curve measured at 2 K indicates that this is a typical type-II superconductor. For comparison, we systematically characterized the properties of the furnace cooled, quenched, and post-annealed single crystals, and found strong internal crystallographic strain existing in the quenched samples, which is the key for the occurrence of superconductivity in the undoped CaFe2As2 single crystals.
1604.04964v1
2016-04-22
Multiband behavior and non-metallic low-temperature state of K$_{0.50}$Na$_{0.24}$Fe$_{1.52}$Se$_{2}$
We report evidence for multiband transport and an insulating low-temperature normal state in superconducting K$_{0.50}$Na$_{0.24}$Fe$_{1.52}$Se$_{2}$ with $T_{c}\approx 20$ K. The temperature-dependent upper critical field, $H_{c2}$, is well described by a two-band BCS model. The normal-state resistance, accessible at low temperatures only in pulsed magnetic fields, shows an insulating logarithmic temperature dependence as $T \rightarrow 0$ after superconductivity is suppressed. This is similar as for high-$T_{c}$ copper oxides and granular type-I superconductors, suggesting that the superconductor-insulator transition observed in high magnetic fields is related to intrinsic nanoscale phase separation.
1604.06793v1
2016-05-30
High-field electron transport in bulk ZnO
Current-voltage dependence is measured in (Ga,Sb)-doped ZnO up to 150 kV/cm electric fields. A channel temperature is controlled by applying relatively short (few ns) voltage pulses to two-terminal samples. The dependence of electron drift velocity on electron density ranging from 1.42$\times$10$^{17}$ cm$^{-3}$ to 1.3$\times$10$^{20}$ cm$^{-3}$ at a given electric field is deduced after estimation of the sample contact resistance and the Hall electron mobility. Manifestation of the highest electron drift velocity up to $\sim$1.5$\times$10$^{7}$ cm/s is estimated for electron density of 1.42$\times$10$^{17}$ cm$^{-3}$ and is in agreement with Monte Carlo simulation when hot-phonon lifetime is below 1 ps. A local drift velocity maximum is observed at $\sim$1.1$\times$10$^{19}$ cm$^{-3}$ and is in agreement with ultra-fast hot phonon decay.
1605.09117v1
2016-06-27
Hafnium carbide formation in oxygen deficient hafnium oxide thin films
On highly oxygen deficient thin films of hafnium oxide (hafnia, HfO$_{2-x}$) contaminated with adsorbates of carbon oxides, the formation of hafnium carbide (HfC$_x$) at the surface during vacuum annealing at temperatures as low as 600 {\deg}C is reported. Using X-ray photoelectron spectroscopy the evolution of the HfC$_x$ surface layer related to a transformation from insulating into metallic state is monitored in situ. In contrast, for fully stoichiometric HfO$_2$ thin films prepared and measured under identical conditions, the formation of HfC$_x$ was not detectable suggesting that the enhanced adsorption of carbon oxides on oxygen deficient films provides a carbon source for the carbide formation. This shows that a high concentration of oxygen vacancies in carbon contaminated hafnia lowers considerably the formation energy of hafnium carbide. Thus, the presence of a sufficient amount of residual carbon in resistive random access memory devices might lead to a similar carbide formation within the conducting filaments due to Joule heating.
1606.08227v1
2016-06-29
Improved model for the thermal conductivity of binary metallic systems
We extended and corrected Mott's two-band model for the composition-dependence of thermal and electrical conductivity in binary metal alloys based on high-throughput time-domain thermoreflectance (TDTR) measurements on diffusion multiples and scatterer-density calculations from first principles. Examining PdAg, PtRh, AuAg, AuCu, PdCu, PdPt, and NiRh binary alloys, we found that the nature of the two dominant scatterer-bands considered in the Mott model changes with the alloys, and should be interpreted as a combination of the dominant element-specific s- and/or d-orbitals. Using calculated orbital and element-resolved density-of-states values calculated with density functional theory as input, we determined the correct orbital mix that dominates electron scattering for all examined alloys and find excellent agreement between fitted models and experiments. The proposed description of the composition dependence of the resistivity can be readily implemented into the CALPHAD framework.
1606.09287v2
2016-06-30
Superconductivity at 5.5 K in Nb2PdSe5 compound
We report superconductivity in as synthesized Nb2PdSe5, which is similar to recently discovered Nb2PdS5 compound having very high upper critical field, clearly above the Pauli paramagnetic limit [Sci. Rep. 3, 1446 (2013)]. A bulk polycrystalline Nb2PdSe5 sample is synthesized by solid state reaction route in phase pure structure. The structural characterization has been done by X ray diffraction, followed by Rietveld refinements, which revealed that Nb2PdSe5 sample is crystallized in monoclinic structure with in space group C2/m. Structural analysis revealed the formation of sharing of one dimensional PdSe2 chains. Electrical and magnetic measurements confirmed superconductivity in Nb2PdSe5 compound at 5.5K. Detailed magneto-resistance results, exhibited the value of upper critical field to be around 8.2Tesla. The estimated Hc2(0) is within Pauli Paramagnetic limit, which is unlike the Nb2PdS5.
1606.09369v2
2016-08-01
Phase Transition in IrTe$_2$ induced by spin-orbit coupling
IrTe$_2$ has been renewed as an interesting system showing competing phenomenon between a questionable density-wave transition near 270 K followed by superconductivity with doping of high atomic number materials. Higher atomic numbers of Te and Ir supports strong spin-orbital coupling in this system. Using dynamical mean field theory with LDA band structure I have introduced Rashba spin orbit coupling in this system to get the interpretation for anomalous resistivity and related transition in this system. While no considerable changes are observed in DMFT results of Ir-5d band other than orbital selective pseudogap pinned to Fermi level, Te-p band shows a van Hove singularity at the Fermi level except low temperature. Finally I discuss the implications of these results in theoretical understanding of ordering in IrTe$_2$.
1608.00467v1
2016-08-03
Edge-induced Schottky barrier modulation at metal contacts to exfoliated molybdenum disulfide flakes
Ultrathin two-dimensional semiconductors obtained from layered transition-metal dichalcogenides such as molybdenum disulfide (MoS2) are promising for ultimately scaled transistors beyond Si. Although the shortening of the semiconductor channel is widely studied, the narrowing of the channel, which should also be important for scaling down the transistor, has been examined to a lesser degree thus far. In this study, the impact of narrowing on mechanically exfoliated MoS2 flakes was investigated according to the channel-width-dependent Schottky barrier heights at Cr/Au contacts. Narrower channels were found to possess a higher Schottky barrier height, which is ascribed to the edge-induced band bending in MoS2. The higher barrier heights degrade the transistor performance as a higher electrode-contact resistance. Theoretical analyses based on Poisson's equation showed that the edge-induced effect can be alleviated by a high dopant impurity concentration, but this strategy should be limited to channel widths of roughly 0.7 micrometers because of the impurity-induced charge-carrier mobility degradation. Therefore, proper termination of the dangling bonds at the edges should be necessary for aggressive scaling with layered semiconductors.
1608.01061v1
2016-08-23
Chiral anomaly and longitudinal magnetotransport in type-II Weyl semimetals
In the presence of parallel electric and magnetic fields, the violation of separate number conservation laws for the three dimensional left and right handed Weyl fermions is known as the chiral anomaly. The recent discovery of Weyl and Dirac semimetals has paved the way for experimentally testing the effects of chiral anomaly via longitudinal magneto-transport measurements. More recently, a type-II Weyl semimetal (WSM) phase has been proposed, where the nodal points possess a finite density of states due to the touching between electron- and hole- pockets. It has been suggested that the main difference between the two types of WSMs (type-I and type-II) is that in the latter, chiral anomaly and the associated longitudinal magneto-resistance are strongly anisotropic, vanishing when the applied magnetic field is perpendicular to the direction of tilt of Weyl fermion cones in a type-II WSM. We analyze chiral anomaly in a type-II WSM in quasiclassical Boltzmann framework, and find that the chiral anomaly induced positive longitudinal magneto-conductivity is present along any arbitrary direction.
1608.06625v2
2016-10-19
Anomalous Thermal Diffusivity in Underdoped YBa$_2$Cu$_3$O$_{6+x}$
We present local optical measurements of thermal diffusivity in the $ab$ plane of underdoped YBCO crystals. We find that the diffusivity anisotropy is comparable to reported values of the electrical resistivity anisotropy, suggesting that the anisotropies have the same origin. The anisotropy drops sharply below the charge order transition. We interpret our results through a strong electron-phonon scattering picture and find that both electronic and phononic contributions to the diffusivity saturate a proposed bound. Our results suggest that neither well-defined electron nor phonon quasiparticles are present in this material.
1610.05845v2
2016-10-22
High performance THz emitters based on ferromagnetic/nonmagnetic heterostructures
We report a THz emitter with excellent performances based on nonmagnetic (NM) and ferromagnetic (FM) heterostructures. The spin currents are first excited by the femtosecond laser beam in the NM/FM bilayer, and then transient charge currents are generated by inverse spin Hall effect, leading to THz emission out of the structure. The broadband THz waves emitted from our film stacks have a peak intensity exceeding 500 um thick ZnTe crystals (standard THz emitters). Our device is insensitive to the polarization of an incident laser beam which indicates the noise resistive feature. In contrast, the polarization of THz waves is fully controllable by an external magnetic field. We have also fabricated the devices on flexible substrates with a great performance, and demonstrated that the devices can be driven by low power lasers. Together with the low cost and mass productive sputtering growth method for the film stacks, the proposed THz emitters can be readily applied to a wide range of THz equipment. Our study also points towards an alternative approach to characterize spintronic devices with NM/FM bilayers.
1610.07020v1
2016-10-26
S2DS: Physics-Based Compact Model for Circuit Simulation of Two-Dimensional Semiconductor Devices Including Non-Idealities
We present a physics-based compact model for two-dimensional (2D) field-effect transistors (FETs) based on monolayer semiconductors such as MoS2. A semi-classical transport approach is appropriate for the 2D channel, enabling simplified analytical expressions for the drain current. In addition to intrinsic FET behavior, the model includes contact resistance, traps and impurities, quantum capacitance, fringing fields, high-field velocity saturation and self-heating, the latter being found to play a strong role. The model is calibrated with state-of-the-art experimental data for n- and p-type 2D-FETs, and it can be used to analyze device properties for sub-100 nm gate lengths. Using the experimental fit, we demonstrate feasibility of circuit simulations using properly scaled devices. The complete model is implemented in SPICE-compatible Verilog-A, and a downloadable version is freely available on the nanoHUB.org.
1610.08489v2
2016-11-14
Nonlinear Transport of Graphene in the Quantum Hall Regime
We have studied the breakdown of the integer quantum Hall (QH) effect with fully broken symmetry, in an ultra-high mobility graphene device sandwiched between two single crystal hexagonal boron nitride substrates. The evolution and stabilities of the QH states are studied quantitatively through the nonlinear transport with dc Hall voltage bias. The mechanism of the QH breakdown in graphene and the movement of the Fermi energy with the electrical Hall field are discussed. This is the first study in which the stabilities of fully symmetry broken QH states are probed all together. Our results raise the possibility that the v=6 states might be a better target for the quantum resistance standard.
1611.04221v1
2016-11-15
Encapsulated Nanowires: Boosting Electronic Transport in Carbon Nanotubes
The electrical conductivity of metallic carbon nanotubes (CNTs) quickly saturates with respect to bias voltage due to scattering from a large population of optical phonons. Decay of these dominant scatterers in pristine CNTs is too slow to offset an increased generation rate at high voltage bias. We demonstrate from first principles that encapsulation of 1D atomic chains within a single-walled CNT can enhance decay of "hot" phonons by providing additional channels for thermalisation. Pacification of the phonon population growth reduces electrical resistivity of metallic CNTs by 51% for an example system with encapsulated beryllium.
1611.04867v2
2016-12-06
Enhanced Structural Stability and Photo Responsiveness of CH3NH3SnI3 Perovskite via Pressure-Induced Amorphization and Recrystallization
An organic-inorganic halide perovskite of CH3NH3SnI3 with significantly improved structural stability is obtained via pressure-induced amorphization and recrystallization. In situ high-pressure resistance measurements reveal an increased electrical conductivity by 300% in the pressure-treated perovskite. Photocurrent measurements also reveal a substantial enhancement in visible-light responsiveness. The mechanism underlying the enhanced properties is demonstrated to be associated with the improved structural stability.
1612.01649v1
2016-12-20
Enhanced Superconductivity in TiO Epitaxial Thin Films
Titanium oxides have many fascinating optical and electrical properties, such as the superconductivity at 2.0 K in cubic titanium monoxide TiO polycrystalline bulk. However, the lack of TiO single crystals or epitaxial films has prevented systematic investigations on its superconductivity. Here, we report the basic superconductivity characterizations of cubic TiO films epitaxially grown on (0001)-oriented Al2O3 substrates. The magnetic and electronic transport measurements confirmed that TiO is a type-II superconductor and the record high Tc is about 7.4 K. The lower critical field (Hc1) at 1.9 K, the extrapolated upper critical field Hc2(0) and coherence length are about 18 Oe, 13.7 T and 4.9 nm, respectively. With increasing pressure, the value of Tc shifts to lower temperature while the normal state resistivity increases. Our results on the superconducting TiO films confirm the strategy to achieve higher Tc in epitaxial films, which may be helpful for finding more superconducting materials in various related systems.
1612.06506v1
2017-02-02
Two-temperature equations of state for d-band metals irradiated by femtosecond laser pulses
The cold curves for energy and pressure of Copper, Iron, and Tantalum were obtained using methods of the density functional theory. We consider hydrostatic and uniaxial deformations in the range from double compression of the initial volume per atom to double stretching. The presence of allotropic transformation from $\alpha$ - phase of Iron to the hexaferrum with the growth of pressure is observed. In the case of hydrostatic deformations we also have obtained analogous cold curves, but with non-zero electronic temperatures in the range up to 5 eV. The similar volume and electronic temperature ranges have been considered recently. The behavior of electronic internal energy, pressure, and density of states was investigated in the volume and temperature ranges called above. The maximum hydrostatic strains and the types of lattice instabilities were theoretically predicted for the considered metals. The influence of high electronic temperature on the electronic heat conductivity and electric resistivity has been provided for d-band metals by the approach based on the solution of Boltzmann kinetic equation in $\tau$-approximation. This data is compared with the results of quantum molecular dynamics for Gold.
1702.00825v3
2017-02-15
New bulk p-type skutterudites DD0.7Fe2.7Co1.3Sb12-xXx (X = Ge, Sn) reaching ZT>1.3
The best p-type skutterudites so far are didymium filled, Fe/Co substituted, Sb-based skutterudites. Substitution at the Sb-sites influences the electronic structure, deforms the Sb4-rings, enhances the scattering of phonons on electrons and impurities and this way reduces the lattice thermal conductivity. In this paper we study structural and transport properties of p-type skutterudites with the nominal composition DD0.7Fe2.7Co1.3Sb11.7{Ge/Sn}0.3, which were prepared by a rather fast reaction-annealing-melting technique. The Ge-doped sample showed impurities, which did not anneal out completely and even with ZT > 1 the result was not satisfying. However, the single-phase Sn-doped sample, DD0.7Fe2.7Co1.3Sb11.8Sn0.2, showed a lower thermal and lattice thermal conductivity than the undoped skutterudite leading to a higher ZT=1.3, hitherto the highest ZT for a p-type skutterudite. Annealing at 570 K for 3 days proved the stability of the microstructure. After severe plastic deformation (SPD), due to additionally introduced defects, an enhancement of the electrical resistivity was compensated by a significantly lower thermal conductivity and the net effect led to a record high figure of merit: ZT = 1.45 at 850 K for DD0.7Fe2.7Co1.3Sb11.8Sn0.2.
1702.04498v1
2017-02-24
Out-of-plane easy-axis in thin films of diluted magnetic semiconductor Ba1-xKx(Zn1-yMny)2As2
Single-phased, single-oriented thin films of Mn-doped ZnAs-based diluted magnetic semiconductor (DMS) Ba1-xKx(Zn1-yMny)2As2 (x = 0.03, 0.08; y = 0.15) have been deposited on Si, SrTiO3, LaAlO3, (La,Sr)(Al,Ta)O3, and MgAl2O4 substrates, respectively. Utilizing a combined synthesis and characterization system excluding the air and further optimizing the deposition parameters, high-quality thin films could be obtained and be measured showing that they can keep inactive-in-air up to more than 90 hours characterized by electrical transport measurements. In comparison with films of x = 0.03 which possess relatively higher resistivity, weaker magnetic performances, and larger energy gap, thin films of x = 0.08 show better electrical and magnetic performances. Strong magnetic anisotropy was found in films of x = 0.08 grown on (La,Sr)(Al,Ta)O3 substrate with their magnetic polarization aligned almost solely on the film growth direction.
1702.07506v1
2017-06-16
An argon ion beam milling process for native $\text{AlO}_\text{x}$ layers enabling coherent superconducting contacts
We present an argon ion beam milling process to remove the native oxide layer forming on aluminum thin films due to their exposure to atmosphere in between lithographic steps. Our cleaning process is readily integrable with conventional fabrication of Josephson junction quantum circuits. From measurements of the internal quality factors of superconducting microwave resonators with and without contacts, we place an upper bound on the residual resistance of an ion beam milled contact of 50$\,\mathrm{m}\Omega \cdot \mu \mathrm{m}^2$ at a frequency of 4.5 GHz. Resonators for which only $6\%$ of the total foot-print was exposed to the ion beam milling, in areas of low electric and high magnetic field, showed quality factors above $10^6$ in the single photon regime, and no degradation compared to single layer samples. We believe these results will enable the development of increasingly complex superconducting circuits for quantum information processing.
1706.06424v1
2017-06-29
Magnetotransport properties of MoP$_2$
We report magnetotransport and de Haas-van Alphen (dHvA) effect studies on MoP$_2$ single crystals, predicted to be type-2 Weyl semimetal with four pairs of robust Weyl points located below the Fermi level and long Fermi arcs. The temperature dependence of resistivity shows a peak before saturation, which does not move with magnetic field. Large nonsaturating magnetoresistance (MR) was observed, and the field dependence of MR exhibits a crossover from semicalssical weak-field $B^2$ dependence to the high-field linear-field dependence, indicating the presence of Dirac linear energy dispersion. In addition, systematic violation of Kohler's rule was observed, consistent with multiband electronic transport. Strong spin-orbit coupling (SOC) splitting has an effect on dHvA measurements whereas the angular-dependent dHvA orbit frequencies agree well with the calculated Fermi surface. The cyclotron effective mass $\sim$ 1.6$m_e$ indicates the bands might be trivial, possibly since the Weyl points are located below the Fermi level. Interestingly, quasi-two dimensional(2D) band structure is observed even though the crystal structure of MoP$_2$ is not layered.
1706.09830v1
2017-09-11
Massive fermions with low mobility in antiferromagnet orthorhombic CuMnAs single crystals
We report the physical properties of orthorhombic o-CuMnAs single crystal, which is predicted to be a topological Dirac semimetal with magnetic ground state and inversion symmetry broken. o-CuMnAs exhibits an antiferromagnetic transition with TN ~ 312 K. Further characterizations of magnetic properties suggest that the AFM order may be canted with the spin orientation in the bc plane. Small isotropic MR and linearly field-dependent Hall resistivity with positive slope indicate that single hole-type carries with high density and low mobility dominate the transport properties of o-CuMnAs. Furthermore, the result of low-temperature heat capacity shows that the effective mass of carriers is much larger than those in typical topological semimetals. These results imply that the carriers in o-CuMnAs exhibit remarkably different features from those of Dirac fermions predicted in theory.
1709.03394v2
2017-09-13
Ultra-broadband photodetectors based on epitaxial graphene quantum dots
Graphene is an ideal material for hot-electron bolometers, due to its low heat capacity and weak electron-phonon coupling. Nanostructuring graphene with quantum dot constrictions yields detectors with extraordinarily high intrinsic responsivity, higher than 1x10^9 V/W at 3K. The sensing mechanism is bolometric in nature: the quantum confinement gap causes a strong dependence of the electrical resistance on the electron temperature. Here we show that this quantum confinement gap does not impose a limitation on the photon energy for light detection and these quantum dot bolometers work in a very broad spectral range, from terahertz, through telecom to ultraviolet radiation, with responsivity independent of wavelength. We also measure the power dependence of the response. Although the responsivity decreases with increasing power, it stays higher than 1x10^8 V/W in a wide range of absorbed power, from 1 pW to 0.4 nW.
1709.04498v1
2017-09-27
Pressure-induced Lifshitz transition in NbP: Raman, x-ray diffraction, electrical transport and density functional theory
We report high pressure Raman, synchrotron x-ray diffraction and electrical transport studies on Weyl semimetals NbP and TaP along with first-principles density functional theoretical (DFT) analysis. The frequencies of first-order Raman modes of NbP harden with increasing pressure and exhibit a slope change at P$_c$ $\sim$ 9 GPa, and its resistivity exhibits a minimum at P$_c$. The pressure-dependent volume of NbP exhibits a change in its bulk modulus from 207 GPa to 243 GPa at P$_c$. Using DFT calculations, we show that these anomalies are associated with pressure induced Lifshitz transition which involves appearance of electron and hole pockets in its electronic structure. In contrast, results of Raman and synchrotron x-ray diffraction experiments on TaP and DFT calculations show that TaP is quite robust under pressure and does not undergo any phase transition.
1709.09368v1
2017-10-27
Unusual behavior of cuprates explained by heterogeneous charge localization
The cuprate high-temperature superconductors are among the most intensively studied materials, yet essential questions regarding their principal phases and the transitions between them remain unanswered. Generally thought of as doped charge-transfer insulators, these complex lamellar oxides exhibit pseudogap, strange-metal, superconducting and Fermi-liquid behaviour with increasing hole-dopant concentration. Here we propose a simple inhomogeneous Mott-like (de)localization model wherein exactly one hole per copper-oxygen unit is gradually delocalized with increasing doping and temperature. The model is percolative in nature, with parameters that are experimentally constrained. It comprehensively captures pivotal unconventional experimental results, including the temperature and doping dependence of the pseudogap phenomenon, the strange-metal linear temperature dependence of the planar resistivity, and the doping dependence of the superfluid density. The success and simplicity of our model greatly demystify the cuprate phase diagram and point to a local superconducting pairing mechanism involving the (de)localized hole.
1710.10221v1
2017-11-05
Investigations of a Robotic Testbed with Viscoelastic Liquid Cooled Actuators
We design, build, and thoroughly test a new type of actuator dubbed viscoelastic liquid cooled actuator (VLCA) for robotic applications. VLCAs excel in the following five critical axes of performance: energy efficiency, torque density, impact resistence, joint position and force controllability. We first study the design objectives and choices of the VLCA to enhance the performance on the needed criteria. We follow by an investigation on viscoelastic materials in terms of their damping, viscous and hysteresis properties as well as parameters related to the long- term performance. As part of the actuator design, we configure a disturbance observer to provide high-fidelity force control to enable a wide range of impedance control capabilities. We proceed to design a robotic system capable to lift payloads of 32.5 kg, which is three times larger than its own weight. In addition, we experiment with Cartesian trajectory control up to 2 Hz with a vertical range of motion of 32 cm while carrying a payload of 10 kg. Finally, we perform experiments on impedance control and mechanical robustness by studying the response of the robotics testbed to hammering impacts and external force interactions.
1711.01649v2
2017-11-07
Epitaxial stabilization of pulsed laser deposited Sr$_{n+1}$Ir$_n$O$_{3n+1}$ thin films: entangled effect of growth dynamics and strain
The subtle balance of electronic correlations, crystal field splitting and spin--orbit coupling in layered Ir$^{4+}$ oxides can give rise to novel electronic and magnetic phases. Experimental progress in this field relies on the synthesis of epitaxial films of these oxides. However, the growth of layered iridates with excellent structural quality is a great experimental challenge. Here we selectively grow high quality single--phase films of Sr$_2$IrO$_4$, Sr$_3$Ir$_2$O$_7$, and SrIrO$_3$ on various substrates from a single Sr$_3$Ir$_2$O$_7$ target by tuning background oxygen pressure and epitaxial strain. We demonstrate a complex interplay between growth dynamics and strain during thin film deposition. Such interplay leads to the stabilization of different phases in films grown on different substrates under identical growth conditions, which cannot be explained by a simple kinetic model. We further investigate the thermoelectric properties of the three phases and propose that weak localization is responsible for the low temperature activated resistivity observed in SrIrO$_3$ under compressive strain.
1711.02767v3
2017-11-09
Magnetic phase separation and strong AFM nature of hexagonal Gd$_5$Sb$_3$
We report on the combined results of structural, magnetic, transport and calorimetric properties of Mn$_5$Si$_3$-type hexagonal Gd$_5$Sb$_3$. With decreasing temperature, it exhibits a ferromagnetic-like transition at 265 K, N\'{e}el transition at 95.5 K and a spin-orientation transition at 62 K. The system is found to be in AFM state down to 2 K in a field of 70 kOe. Magnetic phase coexistence is not noticeable despite large positive Curie-Weiss temperature. Instead low-temperature AFM and high-temperature FM-like phases are separated in large temperature. Temperature-magnetic field ($H$-$T$) phase diagram reveals field-driven complex magnetic phases. Within the AFM phase, the system is observed to undergo field-driven spin-orientation transitions. Field-induced tricritical and quantum critical points appear to be absent due to strong AFM nature and by the intervention of FM-like state between PM and AFM states. Electrical resistivity along with large Sommerfeld parameter suggests metallic nature.
1711.03263v1
2017-11-29
Pressure-induced ferromagnetism due to an anisotropic electronic topological transition in Fe1.08Te
A rapid and anisotropic modification of the Fermi-surface shape can be associated with abrupt changes in crystalline lattice geometry or in the magnetic state of a material. In this study we show that such an electronic topological transition is at the basis of the formation of an unusual pressure-induced tetragonal ferromagnetic phase in Fe$_{1.08}$Te. Around 2 GPa, the orthorhombic and incommensurate antiferromagnetic ground-state of Fe$_{1.08}$Te is transformed upon increasing pressure into a tetragonal ferromagnetic state via a conventional first-order transition. On the other hand, an isostructural transition takes place from the paramagnetic high-temperature state into the ferromagnetic phase as a rare case of a `type 0' transformation with anisotropic properties. Electronic-structure calculations in combination with electrical resistivity, magnetization, and x-ray diffraction experiments show that the electronic system of Fe$_{1.08}$Te is instable with respect to profound topological transitions that can drive fundamental changes of the lattice anisotropy and the associated magnetic order.
1711.10745v1
2018-01-15
Improving Graphene-metal Contacts: Thermal Induced Polishing
Graphene is a very promising material for nanoelectronics applications due to its unique and remarkable electronic and thermal properties. However, when deposited on metallic electrodes the overall thermal conductivity is significantly decreased. This phenomenon has been attributed to the mismatch between the interfaces and contact thermal resistance. Experimentally, one way to improve the graphene/metal contact is thorough high-temperature annealing, but the detailed mechanisms behind these processes remain unclear. In order to address these questions, we carried out fully atomistic reactive molecular dynamics simulations using the ReaxFF force field to investigate the interactions between multi-layer graphene and metallic electrodes (nickel) under (thermal) annealing. Our results show that the annealing induces an upward-downward movement of the graphene layers, causing a pile-driver-like effect over the metallic surface. This graphene induced movements cause a planarization (thermal polishing-like effect) of the metallic surface, which results in the increase of the effective graphene/metal contact area. This can also explain the experimentally observed improvements of the thermal and electric conductivities.
1801.04785v1
2018-01-31
Commensurability Oscillations in One-Dimensional Graphene Superlattices
We report the experimental observation of commensurability oscillations (COs) in 1D graphene superlattices. The widely tunable periodic potential modulation in hBN encapsulated graphene is generated via the interplay of nanopatterned few layer graphene acting as a local bottom gate and a global Si back gate. The longitudinal magneto-resistance shows pronounced COs, when the sample is tuned into the unipolar transport regime. We observe up to six CO minima, providing evidence for a long mean free path despite the potential modulation. Comparison to existing theories shows that small angle scattering is dominant in hBN/graphene/hBN heterostructures. We observe robust COs persisting to temperature exceeding $T=150$ K. At high temperatures, we find deviations from the predicted $T$-dependence, which we ascribe to electron-electron scattering.
1802.00016v2
2018-03-22
High density carriers at a strongly coupled graphene-topological insulator interface
We report on a strongly coupled bilayer graphene (BLG) - \bise\ device with a junction resistance of less than 1.5 k$\Omega\mu$m$^2$. This device exhibits unique behavior at the interface, which cannot be attributed to either material in absence of the other. We observe quantum oscillations in the magnetoresistance of the junction, indicating the presence of well-resolved Landau levels due to hole carriers of unknown origin with a very large Fermi surface. These carriers, found only at the interface, could conceivably arise due to significant hole doping of the bilayer graphene with charge transfer on the order of 2$\times$10$^{13}$ cm$^{-2}$, or due to twist angle dependent mini-band transport.
1803.08260v1
2018-03-27
Large-Scale Fabrication of RF MOSFETs on Liquid-Exfoliated MoS2
For the first time, thousands of RF MOSFETs were batch-fabricated on liquid-exfoliated MoS2 below 300 {\deg}C with nearly 100% yield. The large-scale fabrication with high yield allowed the average performance instead of the best performance to be reported. The DC performance of these devices were typical, but the RF performance, enabled by buried gates and on the order of 100 MHz, was reported for the first time for liquid-exfoliated MoS2. To resolve the dilemma of thin vs. thick films, gate recess was used on 20-nm thick films to improve the gate control while keeping the contact resistance lower than that on 10-nm films. These innovations may enable thin-film transistors to operate in the microwave range.
1803.09906v1
2018-05-20
Autonomous actuation of zero modes in mechanical networks far from equilibrium
A zero mode, or floppy mode, is a non-trivial coupling of mechanical components yielding a degree of freedom with no resistance to deformation. Engineered zero modes have the potential to act as microscopic motors or memory devices, but this requires an internal actuation mechanism that can overcome unwanted fluctuations in other modes and the dissipation inherent in real systems. In this work, we show theoretically and experimentally that complex zero modes in mechanical networks can be selectively mobilized by non-equilibrium activity. We find that a correlated active bath actuates an infinitesimal zero mode while simultaneously suppressing fluctuations in higher modes compared to thermal fluctuations, which we experimentally mimic by high frequency shaking of a physical network. Furthermore, self-propulsive dynamics spontaneously mobilise finite mechanisms as exemplified by a self-propelled topological soliton. Non-equilibrium activity thus enables autonomous actuation of coordinated mechanisms engineered through network topology.
1805.07728v2
2018-06-06
Pressure Evolution of Magnetism in URhGa
In this paper, we report the results of an ambient and high pressure study of a 5f-electron ferromagnet URhGa. The work is focused on measurements of magnetic and thermodynamic properties of a single crystal sample and on the construction of the p-T phase diagram. Diamond anvil cells were employed to measure the magnetization and electrical resistivity pressures up to ~ 9 GPa. At ambient pressure, URhGa exhibits collinear ferromagnetic ordering of uranium magnetic moments {\mu}U ~ 1.1 {\mu}B (at 2 K) aligned along the c-axis of the hexagonal crystal structure below the Curie temperature TC = 41K. With the application of pressure up to 5GPa the ordering temperature TC initially increases whereas the saturated moment slightly decreases. The rather unexpected evolution is put in the context of the UTX family of compounds.
1806.02686v1
2018-06-25
Ferromagnetism above 1000 K in highly cation-ordered double-perovskite insulator Sr3OsO6
Magnetic insulators have been intensively studied for over 100 years, and they, in particular ferrites, are considered to be the cradle of magnetic exchange interactions in solids. Their wide range of applications include microwave devices and permanent magnets . They are also suitable for spintronic devices owing to their high resistivity, low magnetic damping, and spin-dependent tunneling probabilities. The Curie temperature is the crucial factor determining the temperature range in which any ferri/ferromagnetic system remains stable. However, the record Curie temperature has stood for over eight decades in insulators and oxides (943 K for spinel ferrite LiFe5O8). Here we show that a highly B-site ordered double-perovskite, Sr2(SrOs)O6 (Sr3OsO6), surpasses this long standing Curie temperature record by more than 100 K. We revealed this B-site ordering by atomic-resolution scanning transmission electron microscopy. The density functional theory (DFT) calculations suggest that the large spin-orbit coupling (SOC) of Os6+ 5d2 orbitals drives the system toward a Jeff = 3/2 ferromagnetic (FM) insulating state. Moreover, the Sr3OsO6 is the first epitaxially grown osmate, which means it is highly compatible with device fabrication processes and thus promising for spintronic applications.
1806.09308v1