publicationDate
stringlengths
10
10
title
stringlengths
17
233
abstract
stringlengths
20
3.22k
id
stringlengths
9
12
2021-06-15
Charge Carrier Transport in Iron Pyrite Thin Films: Disorder Induced Variable Range Hopping
The origin of p-type conductivity and the mechanism responsible for low carrier mobility was investigated in pyrite (FeS2) thin films. Temperature dependent resistivity measurements were performed on polycrystalline and nanostructured thin films prepared by three different methods. Films have a high hole density and low mobility regardless of the method used for their preparation. The charge transport mechanism is determined to be nearest neighbour hopping (NNH) at near room temperature with Mott-type variable range hopping (VRH) of holes via localized states occurring at lower temperatures. Density functional theory (DFT) predicts that sulfur vacancy induced localized defect states will be situated within the band gap with the charge remaining localized around the defect. The data indicate that the electronic properties including hopping transport in pyrite thin films can be correlated to sulfur vacancy related defect. The results provide insights on electronic properties of pyrite thin films and its implications for charge transport
2106.08401v2
2021-06-24
Epitaxial growth of Ruddlesden-Popper neodymium nickelates Nd$_{n+1}$Ni$_{n}$O$_{3n+1}$ (${n}$ = 1-5)
A series of Ruddlesden-Popper nickelates, Nd$_{n+1}$Ni$_{n}$O$_{3n+1}$ (${n}$ = 1-5), have been stabilized in thin film form using reactive molecular-beam epitaxy. High crystalline quality has been verified by X-ray diffraction and scanning transmission electron microscopy. X-ray photoelectron spectroscopy indicates the ${n}$-dependent valence states of nickel in these compounds. Metal-insulator transitions show clear ${n}$ dependence for intermediate members (${n}$ = 3-5), and the low-temperature resistivities of which show logarithmic dependence, resembling the Kondo-scattering as observed in the parent compounds of superconducting infinite-layer nickelates.
2106.12941v1
2021-07-28
Narrow-gap semiconducting behavior in antiferromagnetic Eu$_{11}$InSb$_9$
Here we investigate the thermodynamic and electronic properties of Eu$_{11}$InSb$_9$ single crystals. Electrical transport data show that Eu$_{11}$InSb$_9$ has a semiconducting ground state with a relatively narrow band gap of $320$~meV. Magnetic susceptibility data reveal antiferromagnetic order at low temperatures, whereas ferromagnetic interactions dominate at high temperature. Specific heat, magnetic susceptibility, and electrical resistivity measurements reveal three phase transitions at $T_{N1}=9.3$~K, $T_{N2} =8.3$~K, and $T_{N3} =4.3$~K. Unlike Eu$_{5}$In$_{2}$Sb$_6$, a related europium-containing Zintl compound, no colossal magnetoresistance (CMR) is observed in Eu$_{11}$InSb$_9$. We attribute the absence of CMR to the smaller carrier density and the larger distance between Eu ions and In-Sb polyhedra in Eu$_{11}$InSb$_9$. Our results indicate that Eu$_{11}$InSb$_9$ has potential applications as a thermoelectric material through doping or as a long-wavelength detector due to its narrow gap.
2107.13145v1
2021-08-04
Theory of Huge Thermoelectric Effect Based on Magnon Drag Mechanism: Application to Thin-Film Heusler Alloy
To understand the unexpectedly high thermoelectric performance observed in the thin-film Heusler alloy Fe$_2$V$_{0.8}$W$_{0.2}$Al, we study the magnon drag effect, generated by the tungsten based impurity band, as a possible source of this enhancement, in analogy to the phonon drag observed in FeSb$_2$. Assuming that the thin-film Heusler alloy has a conduction band integrating with the impurity band, originated by the tungsten substitution, we derive the electrical conductivity $L_{11}$ based on the self-consistent t-matrix approximation and the thermoelectric conductivity $L_{12}$ due to magnon drag, based on the linear response theory, and estimate the temperature dependent electrical resistivity, Seebeck coefficient and power factor. Finally, we compare the theoretical results with the experimental results of the thin-film Heusler alloy to show that the origin of the exceptional thermoelectric properties is likely to be due to the magnon drag related with the tungsten-based impurity band.
2108.01880v1
2021-08-10
Nature of electrons from oxygen vacancies and polar catastrophe at LaAlO3/SrTiO3 interfaces
The relative significance of quantum conductivity correction and magnetic nature of electrons in understanding the intriguing low-temperature resistivity minimum and negative magnetoresistance of the two-dimensional electron gas at LaAlO3/SrTiO3 interfaces has been a long outstanding issue since its discovery. Here we report a comparative magnetotransport study on amorphous and oxygen-annealed crystalline LaAlO3/SrTiO3 heterostructures at a relatively high-temperature range, where the orbital scattering is largely suppressed by thermal fluctuations. Despite of a predominantly negative out-of-plane magnetoresistance effect for both, the magnetotransport is isotropic for amorphous LaAlO3/SrTiO3 while strongly anisotropic and well falls into a two-dimensional quantum correction frame for annealed crystalline LaAlO3/SrTiO3. These results clearly indicate that a large portion of electrons from oxygen vacancies are localized at low temperatures, serving as magnetic centers, while the electrons from the polar field are only weakly localized due to constructive interference between time-reversed electron paths in the clean limit and no signature of magnetic nature is visible.
2108.04532v1
2021-08-19
Chemomechanics: friend or foe of the "AND problem" of solid-state batteries?
Solid electrolytes are widely considered as the enabler of lithium metal anodes for safe, durable, and high energy density rechargeable lithium-ion batteries. Despite the promise, failure mechanisms associated with solid-state batteries are not well-established, largely due to limited understanding of the chemomechanical factors governing them. We focus on the recent developments in understanding solid-state aspects including the effects of mechanical stresses, constitutive relations, fracture, and void formation, and outline the gaps in the literature. We also provide an overview of the manufacturing and processing of solid-state batteries in relation to chemomechanics. The gaps identified provide concrete directions towards the rational design and development of failure-resistant solid-state batteries.
2108.10150v2
2021-09-01
Electrical switching of antiferromagnetic CoO | Pt across the Néel temperature
One of the most important challenges in antiferromagnetic spintronics is the read-out of the N\'eel vector state. High current densities up to 10$^8$ Acm$^{-2}$ used in the electrical switching experiments cause notorious difficulty in distinguishing between magnetic and thermal origins of the electrical signals. To overcome this problem, we present a temperature dependence study of the transverse resistance changes in the switching experiment with CoO|Pt devices. We demonstrate the possibility to extract a pattern of spin Hall magnetoresistance for current pulses density of $5 \times 10^7$ Acm$^{-2}$ that is present only below the N\'eel temperature and does not follow a trend expected for thermal effects. This is the compelling evidence for the magnetic origin of the signal, which is observed using purely electrical techniques. We confirm these findings by complementary experiments in an external magnetic field. Such an approach can allow determining the optimal conditions for switching antiferromagnets and be very valuable when no imaging techniques can be applied to verify the origin of the electrical signal.
2109.00293v2
2021-09-22
Dynamic Behaviors and Training Effects in TiN/Ti/HfO$_x$/TiN Nanolayered Memristors with Controllable Quantized Conductance States: Implications for Quantum and Neuromorphic Computing Devices
Controllable quantized conductance states of TiN/Ti/HfO$_x$/TiN memristors are realized with great precision through a pulse-mode reset procedure, assisted with analytical differentiation of the condition of the set procedure, which involves critical monitoring of the measured bias voltage. An intriguing training effect that leads to faster switching of the states is also observed during the operation. Detailed analyses on the low- and high-resistance states under different compliance currents reveal a complete picture of the structural evolution and dynamic behaviors of the conductive filament in the HfO$_x$ layer. This study provides a closer inspection on the quantum-level manipulation of nanoscale atomic configurations in the memristors, which helps to develop essential knowledge about the design and fabrication of the future memristor-based quantum devices and neuromorphic computing devices.
2109.10783v1
2021-09-27
Strongly electron-correlated semimetal RuI$_3$ with a layered honeycomb structure
A polymorph of RuI$_3$ synthesized under high pressure was found to have a two-layered honeycomb structure. The resistivity of RuI$_3$ exhibits a semimetallic behavior, in contrast to insulating properties in $\alpha$-RuCl$_3$. In addition, Pauli paramagnetic behavior was observed in the temperature dependence of a magnetic susceptibility and a nuclear spin-lattice relaxation rate 1/$T_1$. The band structure calculations indicate that contribution of the I 5$p$ components to the low-energy $t_\mathrm{2g}$ bands effectively decreases Coulomb repulsion, leading to semimetallic properties. The physical properties also suggest strong electron correlations in RuI$_3$.
2109.12864v2
2021-10-12
Single-component superconducting state in UTe2 at 2 K
UTe2 is a newly-discovered unconventional superconductor wherein multicomponent topological superconductivity is anticipated based on the presence of two superconducting transitions and time-reversal symmetry breaking in the superconducting state. The observation of two superconducting transitions, however, remains controversial. Here we demonstrate that UTe2 single crystals displaying an optimal superconducting transition temperature at 2 K exhibit a single transition and remarkably high quality supported by their small residual heat capacity in the superconducting state and large residual resistance ratio. Our results shed light on the intrinsic superconducting properties of UTe2 and bring into question whether UTe2 is a multicomponent superconductor at ambient pressure.
2110.06200v1
2021-10-13
Large-Gap Quantum Spin Hall State and Temperature-Induced Lifshitz Transition in Bi4Br4
Searching for new quantum spin Hall insulators with large fully opened energy gap to overcome the thermal disturbance at room temperature has attracted tremendous attention due to the one-dimensional (1D) spin-momentum locked topological edge states serving as dissipationless channels for the practical applications in low consumption electronics and high performance spintronics. Here, we report the investigation of topological nature of monolayer Bi4Br4 by the techniques of scanning tunneling microscopy and angle-resolved photoemission spectroscopy (ARPES). The topological non-triviality of 1D edge state integrals within the large bulk energy gap (~ 0.2 eV) is revealed by the first-principle calculations. The ARPES measurements at different temperature show a temperature-induced Lifshitz transition, corresponding to the resistivity anomaly caused by the shift of chemical potential. The connection between the emergency of superconductivity and the Lifshitz transition is discussed.
2110.06658v1
2021-11-09
Weak antilocalization and Shubnikov-de Haas oscillations in CaCuSb single crystal
Quantum oscillations in both linear and Hall resistivities and weak antilocalization (WAL) are barely observed in bulk single crystals. Here we report the transport properties of a CaCuSb single crystal that crystallizes in the hexagonal crystal structure. The magnetotransport studies reveal WAL and Shubnikov-de Haas (SdH) quantum oscillations with a unique frequency at 314 T. A cusp-like behavior in the low field regime of magnetotransport for J // (ab)-plane and B // [0001] confirms the WAL in CaCuSb. Angular-dependent normalized magnetoconductance and SdH oscillations studies reveal that the observed phenomena originate from the 2D transport channels. The high magnetic field (up to 45 T) experiments demonstrate plateau-like features in the Hall measurements. The first-principles calculations unfold that CaCuSb is a non-topological semimetal with dominant hole carries at the Fermi level. Our study reveals that CaCuSb is a promising candidate to explore the quasi-2D quantum transport phenomenon in the transition metal pnictide materials.
2111.04996v1
2021-11-29
High-Speed Light Focusing through Scattering Medium by Cooperatively Accelerated Genetic Algorithm
We develop an accelerated Genetic Algorithm (GA) system constructed by the cooperation of field-programmable gate array (FPGA) and optimized parameters of the GA. We found the enhanced decay of mutation rate makes convergence of the GA much faster, enabling the parameter-induced acceleration of the GA. Furthermore, the accelerated configuration of the GA is programmed in FPGA to boost processing speed at the hardware level without external computation devices. This system has ability to focus light through scattering medium within 4 seconds with robust noise resistance and stable repetition performance, which could be further reduced to millisecond level with advanced board configuration. This study solves the long-term limitation of the GA, it promotes the applications of the GA in dynamic scattering mediums, with the capability to tackle wavefront shaping in biological material.
2111.14916v1
2021-12-01
Atomistic simulations of twin boundary effect on the crack growth behaviour in BCC Fe
In this paper, the effect of twin boundaries on the crack growth behaviour of single crystal BCC Fe has been investigated using molecular dynamics simulations. The growth of an atomically sharp crack with an orientation of (111)$<$110$>$ (crack plane/crack front) has been studied under mode-I loading at constant strain rate. In order to study the influence of twin boundaries on the crack growth behaviour, single and multiple twin boundaries were introduced perpendicular to crack growth direction. The results indicate that the (111)$<$110$>$ crack in single crystal BCC Fe grows in brittle manner. However, following the introduction of twin boundaries, a noticeable plastic deformation has been observed at the crack tip. Further, increasing the number of twin boundaries increased the amount of plastic deformation leading to better crack resistance and high failure strains. Finally, an interesting relationship has been observed between the crack growth rate and flow stress.
2112.00354v1
2022-01-10
Phase Boundary Segregation in Multicomponent Alloys: A Diffuse-Interface Thermodynamic Model
Microalloying elements tend to segregate to the matrix-precipitate phase boundaries to reduce the interfacial energy. The segregation mechanism is emerging as a novel design strategy for developing precipitation-hardened alloys with significantly improved coarsening resistance for high temperature applications. In this paper, we report a nanoscopic diffuse-interface thermodynamic model that describes multicomponent segregation behavior in two-phase substitutional alloys. Following classical approaches for grain boundaries, we employ the regular solution thermodynamics to establish segregation isotherms. We show that the model recovers the Guttmann multicomponent isotherm describing local interfacial concentrations, and the generalized Gibbs adsorption isotherm that governs the total solute excess and interfacial energy. A variety of multicomponent segregation behaviors are demonstrated for a model two-phase quaternary alloy. The nature of interfacial parameters and the resulting analytic solutions make the model amenable for parameterization and comparison with atomistic calculations and experimental characterizations.
2201.03117v1
2022-03-09
Magnetotransport due to conductivity fluctuations in non-magnetic ZrTe2 nanoplates
Transition metal dichalcogenides with nontrivial band structures exhibit various fascinating physical properties and have sparked intensively research interest. Here, we performed systematic magnetotransport measurements on mechanical exfoliation prepared ZrTe2 nanoplates. We revealed that the negative longitudinal magnetoresistivity observed at high field region in the presence of parallel electric and magnetic fields could stem from the conductivity fluctuations due to the excess Zr in the nanoplates. In addition, the parametric plot, the planar Hall resistivity as function of the in-plane anisotropic magnetoresistivity, has an ellipse-shaped pattern with shifted orbital center, which further strengthen the evidence for the conductivity fluctuations. Our work provides some useful insights into transport phenomena in topological materials.
2203.04486v1
2022-03-11
Ultrafast intrinsic optical-to-electrical conversion dynamics in graphene photodetector
Optical-to-electrical (O-E) conversion in graphene is a central phenomenon for realizing anticipated ultrafast and low-power-consumption information technologies. However, revealing its mechanism and intrinsic time scale require uncharted terahertz (THz) electronics and device architectures. Here, we succeeded in resolving O-E conversion processes in high-quality graphene by on-chip electrical readout of ultrafast photothermoelectric current. By suppressing the RC time constant using a resistive zinc oxide top gate, we constructed a gate-tunable graphene photodetector with a bandwidth of up to 220 GHz. By measuring nonlocal photocurrent dynamics, we found that the photocurrent extraction from the electrode is instantaneous without a measurable carrier transit time across several-micrometer-long graphene, following the Shockley-Ramo theorem. The time for photocurrent generation is exceptionally tunable from immediate to > 4 ps, and its origin is identified as Fermi-level-dependent intraband carrier-carrier scattering. Our results bridge the gap between ultrafast optical science and device engineering, accelerating ultrafast graphene optoelectronic applications.
2203.05752v1
2022-03-14
Little-Parks like oscillations in lightly doped cuprate superconductors
Understanding the rich and competing electronic orders in cuprate superconductors may provide important insight into the mechanism of high-temperature superconductivity. Here, by measuring Bi2Sr2CaCu2O8+x in the extremely underdoped regime, we obtain evidence for a distinct type of ordering, which manifests itself as resistance oscillations at low magnetic fields (<10 T) and at temperatures around the superconducting transition. By tuning the doping level p continuously, we reveal that these low-field oscillations occur only when p<0.1. The oscillation amplitude increases with decreasing p but the oscillation period stays almost constant. We show that these low-field oscillations can be well described by assuming a periodic superconducting structure with a mesh size of about 50 nm. Such a charge order, which is distinctly different from the well-established charge density wave and pair density wave, seems to be an unexpected piece of the puzzle on the correlated physics in cuprates.
2203.06971v1
2022-03-25
Hydrodynamic Interactions Between Charged and Uncharged Brownian Colloids at a Fluid-Fluid Interface
Hypothesis: The collective dynamics and self-assembly of colloids floating at a fluid/fluid interface is a balance between deterministic lateral interaction forces, viscous resistance to colloid motion along the surface and thermal (Brownian) fluctuations. As the colloid size decreases, thermal forces become important and can affect the self assembly into ordered patterns and crystal structures that are the starting point for various materials applications. Numerics: Langevin dynamic simulations involving two particles straddling a liquid/liquid interface with a high viscosity contrast are presented to describe the lateral interfacial assembly of particles in Brownian and non-Brownian dominated regimes. These simulations incorporate capillary attraction, electrostatic repulsion, thermal fluctuations and HI between particles (including the effect of the particle immersion depth). Simulation results are presented for neutrally wetted particles which form a contact angle of 90 degrees at the interface. Findings: Clustering, fractal growth and particle ordering are observed at critically large values of the Pe numbers, while smaller Pe numbers exhibit higher probabilities of yielding states in which particles remain uncorrelated in space and more widely separated.
2203.13925v2
2022-04-02
Upscaling of a reaction-diffusion-convection problem with exploding non-linear drift
We study a reaction-diffusion-convection problem with nonlinear drift posed in a domain with periodically arranged obstacles. The non-linearity in the drift is linked to the hydrodynamic limit of a totally asymmetric simple exclusion process (TASEP) governing a population of interacting particles crossing a domain with obstacle. Because of the imposed large drift scaling, this nonlinearity is expected to explode in the limit of a vanishing scaling parameter. As main working techniques, we employ two-scale formal homogenization asymptotics with drift to derive the corresponding upscaled model equations as well as the structure of the effective transport tensors. Finally, we use Schauder's fixed point theorem as well as monotonicity arguments to study the weak solvability of the upscaled model posed in an unbounded domain. This study wants to contribute with theoretical understanding needed when designing thin composite materials that are resistant to high velocity impacts.
2204.00931v1
2022-06-01
Charge density wave and superconductivity in 6R-TaS2
The layered transition metal dichalcogenide compounds 1T-TaS2 and 4H-TaS2 are well known for their exotic properties, which include charge density wave, superconductivity, Mott transition, etc., and lately quantum spin liquid. Here, we report the magnetic, transport and transmission electron microscopy study of the charge density wave and superconductivity in 6R-TaS2 which is a relatively less studied polymorph of this dichalcogenide TaS2. Our high temperature electron microscopy reveals multiple charge density wave transitions between room temperature and 650K. Magnetization, and the electrical resistivity measurements in the temperature range of 2-400 K reveal that 6R-TaS2 undergoes a charge density wave transition around 305 K and is followed by a transition to a superconducting state around 3.5 K. The low temperature specific heat measurement exhibits anomaly associated with the superconducting transition around 2.4 K. The estimated Ginzburg Landau parameter suggests that this compound lies at the extreme limit of type-II superconductivity.
2206.00281v3
2022-06-03
Effects of charge dopants in quantum spin Hall materials
Semiconductors' sensitivity to electrostatic gating and doping accounts for their widespread use in information communication and new energy technologies. It is demonstrated quantitatively and with no adjustable parameters that the presence of paramagnetic acceptor dopants elucidates a variety of hitherto puzzling properties of two-dimensional topological semiconductors at the topological phase transition and in the regime of the quantum spin Hall effect. The concepts of charge correlation, Coulomb gap, exchange interaction between conducting electrons and holes localized on acceptors, strong coupling limit of the Kondo effect, and bound magnetic polaron explain a short topological protection length, high hole mobilities compared with electron mobilities, and different temperature dependence of the spin Hall resistance in HgTe and (Hg,Mn)Te quantum wells.
2206.01613v3
2022-06-02
Modeling Defect-Level Switching for Highly-Nonlinear and Hysteretic Electronic Devices
Many semiconductors feature defects with charge state transition levels that can switch due to structure changes following defect ionization: we call this defect-level switching (DLS). For example, DX centers in III-V compounds, and oxygen vacancies in ZnO, can switch between deep and shallow donor configurations, and these bistable dynamics are responsible for persistent photoconductivity. We recently demonstrated highly-nonlinear, hysteretic, two-terminal electronic devices using DLS in CdS [H. Yin, A. Kumar, J.M. LeBeau, and R. Jaramillo, Phys. Rev. Applied 15, 014014 (2021).] The resulting devices operate without mass transport, and in the opposite sense to most resistive switches: they are in a high-conductivity state at equilibrium, and switch to a low-conductivity state at forward bias. Although DLS uses the same defect transitions that are responsible for persistent photoconductivity, DLS devices operate without light and can be orders-of-magnitude faster due to exponential tuning of transition rates with voltage. In this work we use theory and numerical simulation to explore the design space of DLS devices, emphasizing the tradeoff between speed and on/off ratio. Our results will be useful to guide future applications of these unusual devices.
2206.04108v1
2022-10-14
The Electrical Property of Large Few Layer Graphene Flakes Obtained by Microwaves Assisted Exfoliation of Expanded Graphite
Few layer graphene (FLG) was synthesized by $\mu$-wave assisted exfoliation of expanded graphite in toluene with an overall yield from c.a. 7% to 20%. A significant difference in the absorption of $\mu$-waves by the expanded graphite and toluene allowed a rapid heating of the medium. The number of FLG sheets varies from 3 to 12, while the lateral size of the sheets exceeds few $\mu$ms. The obtained FLG exhibits very low resistance with average value of 1.6 k$\Omega$ (500 $\Omega$ minimum) which is comparable to that of high quality graphenes synthesized by CVD methods, and lower than numbers of exfoliated graphenes.
2210.07627v1
2022-10-26
Superior damage tolerance of fish skins
Skin is the largest organ of many animals. Its protective function against hostile environments and predatorial attack makes high mechanical strength a vital characteristic. Here, we measured the mechanical properties of bass fish skins and found that fish skins are highly ductile with a rupture strain of up to 30-40% and a rupture strength of 10-15 MPa. The fish skins exhibit a strain-stiffening behavior. Stretching can effectively eliminate the stress concentrations near the pre-existing holes and edge notches, suggesting that the skins are highly damage tolerant. Our measurement determined a flaw-insensitivity length of several millimeters, which exceeds that of most engineering materials. The strain-stiffening and damage tolerance of fish skins are explained by an agent-based model of collagen network in which the load-bearing collagen microfibers assembled from nanofibrils undergo straightening and reorientation upon stretching. Our study inspires development of artificial skins that are thin, flexible, but highly fracture-resistant and widely applicable in soft robots.
2210.14651v1
2022-10-29
Magnetotransport Properties and Fermi Surface Topology of Nodal line Semimetal InBi
In the present study, we have discussed the up-turn behavior in the resistivity pattern of the topological nodal line semimetal InBi. We argued that such nature could be generalized with a mathematical model, that can be applied to any compounds exhibiting similar behavior. The extremely high magnetoresistance (XMR) has also been explained by the carrier compensation in the compound, estimated from the Hall conductivity. Moreover, from the study of Subhnikov-de Haas (SdH) oscillation and density functional theory (DFT), we obtained the complete three-dimensional (3D) Fermi surface topology of the compound InBi. A detailed understanding of carriers' behavior has been discussed using those studies. We have also unfurled the topology of each electron and hole pocket and its possible modulation with electron and hole doping.
2210.16527v1
2022-11-30
Mixed Valence Pseudobrookite Al$_{1.75}$Ti$_{1.25}$O$_5$: High Temperature Phase Transitions, Magnetism and Resistivity
Dark blue single crystals of Al$_{1.75}^{3+}$ Ti$_{1.0}^{4+}$ Ti$_{0.25}^{3+}$O$_5$ were grown with a novel synthesis method based on the reaction of a Ti3+/Ti4+ containing langbeinite melt and Al$_2$O$_3$. The obtained needles crystallize in the pseudobrookite structure and undergo two reversible phase transitions from orthorhombic Cmcm to C2/m first and subsequently to C2 symmetry. Like the known aluminum titanate pseudobrookites, anistropic thermal expansion is observed. The temperature evolution of the crystal structure reveals some insights into the mechanism leading to the decomposition of the Al$_{1.75}$Ti$_{1.25}$O$_5$ above 725$^\circ$C. The magnetic and electrical properties are discussed and compared to other reported aluminum titanate pseudobrookites.
2211.17252v2
2022-12-14
Study of the V$_2^0$ state in neutron-irradiated silicon using photon-absorption measurements
Pieces of $n$-type silicon with 3.5 k$\Omega \cdot $cm resistivity have been irradiated by reactor neutrons to fluences of (1, 5 and 10) $\times 10^{16}$ cm$^{-2}$. Using light-transmission measurements, the absorption coefficients have been determined for photon energies, $E_\gamma $, between 0.62 and 1.30 eV for the samples as irradiated and after 15 min isochronal annealing with temperatures between 80{\deg}C and 330{\deg}C. The radiation-induced absorption coefficient, $\alpha_\mathit{irr}$, has been obtained by subtracting the absorption coefficient for non-irradiated silicon. The $E_\gamma $-dependence of $\alpha_\mathit{irr}$ shows a resonance peak, which is ascribed to the neutral divacancy, V$_2^0$, sitting on a background, and $\alpha_\mathit{irr} (E_\gamma )$ is fitted by a Breit-Wigner line shape on a parameterized background. It is found that at an annealing temperature of 210{\deg}C the V$_2^0$ intensity is reduced by a factor 2, and that at the meV level, the position and the width of the fitted Breit-Wigner do not change with irradiation dose and annealing.
2212.07320v2
2023-01-18
Schramm-Loewner evolution in 2d rigidity percolation
Amorphous solids may resist external deformation such as shear or compression while they do not present any long-range translational order or symmetry at the microscopic scale. Yet, it was recently discovered that, when they become rigid, such materials acquire a high degree of symmetry hidden in the disorder fluctuations: their microstructure becomes statistically conformally invariant. In this Letter we exploit this finding to characterise the universality class of central-force rigidity percolation (RP), using Schramm-Loewner Evolution (SLE) theory. We provide numerical evidences that the interfaces of the mechanically stable structures (rigid clusters), at the rigidification transition, are consistently described by SLE$_\kappa$, showing that this powerful framework can be applied to a mechanical percolation transition. Using well-known relations between different SLE observables and the universal diffusion constant $\kappa$, we obtain the estimation $\kappa\sim2.9$ for central-force RP. This value is consistent, through relations coming from conformal field theory, with previously measured values for the clusters' fractal dimension $D_f$ and correlation length exponent $\nu$, providing new, non-trivial relations between critical exponents for RP. These findings open the way to a fine understanding of the microstructure in other important classes of rigidity and jamming transitions.
2301.07614v2
2023-01-26
3D-imaging of Printed Nanostructured Networks using High-resolution FIB-SEM Nanotomography
Networks of solution-processed nanomaterials are important for multiple applications in electronics, sensing and energy storage/generation. While it is known that network morphology plays a dominant role in determining the physical properties of printed networks, it remains difficult to quantify network structure. Here, we utilise FIB-SEM nanotomography to characterise the morphology of nanostructured networks. Nanometer-resolution 3D-images were obtained from printed networks of graphene nanosheets of various sizes, as well as networks of WS2 nanosheets, silver nanosheets and silver nanowires. Important morphological characteristics, including network porosity, tortuosity, pore dimensions and nanosheet orientation were extracted and linked to network resistivity. By extending this technique to interrogate the structure and interfaces within vertical printed heterostacks, we demonstrate the potential of this technique for device characterisation and optimisation.
2301.11046v1
2023-03-08
Optical rogue waves in spheroids of tumor cells
Rogue waves are intense and unexpected wavepackets ubiquitous in complex systems. In optics, they are promising as robust and noise-resistant beams for probing and manipulating the underlying material. Localizing large optical power is crucial especially in biomedical systems, where, however, extremely intense beams have not yet been observed. We here discover that tumor-cell spheroids manifest optical rogue waves when illuminated by randomly modulated laser beams. The intensity of light transmitted through bio-printed three-dimensional tumor models follows a signature Weibull statistical distribution, where extreme events correspond to spatially-localized optical modes propagating within the cell network. Experiments varying the input beam power and size indicate the rogue waves have a nonlinear origin. We show these optical filaments form high-transmission channels with enhanced transmission. They deliver large optical power through the tumor spheroid, which can be exploited to achieve a local temperature increase controlled by the input wave shape. Our findings shed new light on optical propagation in biological aggregates and demonstrate how extreme event formation allows light concentration in deep tissues, paving the way to using rogue waves in biomedical applications such as light-activated therapies.
2303.04553v1
2023-04-28
Experimental observation of metallic states with different dimensionality in a quasi-1D charge density wave compound
TaTe$_4$ is a quasi-1D tetrachalcogenide that exhibits a CDW instability caused by a periodic lattice distortion. Recently, pressure-induced superconductivity has been achieved in this compound, revealing a competition between these different ground states and making TaTe$_4$ very interesting for fundamental studies. Although TaTe$_4$ exhibits CDW ordering below 475 K, transport experiments have reported metallic behavior with a resistivity plateau at temperatures lower than 10 K. In this paper, we study the electronic structure of TaTe$_4$ using a combination of high-resolution angle-resolved photoemission spectroscopy and density functional calculations. Our results reveal the existence of the long-sought metallic states. These states exhibit mixed dimensionality, while some of them might have potential topological properties.
2305.00053v1
2023-05-15
Magnetic order and electronic transport properties in the Mn$_3$Al compound: the role of the structural state
Electronic transport and magnetic properties of bulk and rapid melt quenched samples of the Mn$_3$Al Heusler alloy were studied. A correlation between the magnetic and structural states was established. For a cast sample, there is no ferromagnetic moment, and the behavior of the magnetic susceptibility (break at low temperatures and the Curie-Weiss law with high values of the paramagnetic Curie temperature) indicates a frustrated antiferromagnetic state. At the same time, for a rapid melt quenched sample, a ferrimagnetic state is observed with a moment close to compensation. The results of measurements of the electrical resistivity and the Hall effect evidence as well in favor of the implementation of these magnetic states.
2305.08646v1
2023-06-01
Native defect association in beta-Ga2O3 enables room-temperature p-type conductivity
The room temperature hole conductivity of the ultra wide bandgap semiconductor beta Ga2O3 is a pre-requisite for developing the next-generation electronic and optoelectronic devices based on this oxide. In this work, high-quality p-type beta-Ga2O3 thin films grown on r-plane sapphire substrate by metalorganic chemical vapor deposition (MOCVD) exhibit Rho = 50000Ohm.cm resistivity at room temperature. A low activation energy of conductivity as Ea2=170 meV was determined, associated to the oxygen - gallium native acceptor defect complex. Further, taking advantage of cation (Zn) doping, the conductivity of Ga2O3:Zn film was remarkably increased by three orders of magnitude, showing a long-time stable room-temperature hole conductivity with the conductivity activation energy of around 86 meV.
2306.01115v1
2023-06-07
Phase formation in hole- and electron-doped rare-earth nickelate single crystals
The recent discovery of superconductivity in hole-doped infinite-layer nickelates has triggered a great interest in the synthesis of novel nickelate phases, which have primarily been examined in thin film samples. Here, we report the high-pressure optical floating zone (OFZ) growth of various perovskite and perovskite-derived rare-earth nickelate single-crystals, and investigate the effects of hole-, electron-, and self-doping. For hole-doping with Ca and Sr, we observe phase separations during the growth process when a substitution level of 8% is exceeded. A similar trend emerges for electron-doping with Ce and Zr. Employing lower doping levels allows us to grow sizeable crystals in the perovskite phase, which exhibit significantly different electronic and magnetic properties than the undoped parent compounds, such as a decreased resistivity and a suppressed magnetic response. Our insights into the doping-dependent phase formation and the resulting properties of the synthesized crystals reveal limitations and opportunities for the exploration and manipulation of electronic states in rare-earth nickelates.
2306.04157v1
2023-07-21
Superexchange Interaction in Insulating EuZn$_{2}$P$_{2}$
We report magnetic and transport properties of single-crystalline EuZn$_{2}$P$_{2}$, which has trigonal CaAl$_2$Si$_2$-type crystal structure and orders antiferromagnetically at $\approx$23~K. Easy $ab$-plane magneto-crystalline anisotropy was confirmed from the magnetization isotherms, measured with a magnetic field applied along different crystallographic directions ($ab$-plane and $c$-axis). Positive Curie-Weiss temperature indicates dominating ferromagnetic correlations. Electrical resistivity displays insulating behavior with a band-gap of $\approx\,$0.177~eV, which decreases to $\approx\,$0.13~eV upon application of a high magnetic field. We explained the intriguing presence of magnetic interactions in an intermetallic insulator by the mechanism of extended superexchange, with phosphorus as an anion mediator, which is further supported by our analysis of the charge and spin density distributions. We constructed the effective Heisenberg model, with exchange parameters derived from the \textit{ab initio} DFT calculations, and employed it in Monte-Carlo simulations, which correctly reproduced the experimental value of N\'eel temperature.
2307.11924v1
2023-08-04
Learning to Shape by Grinding: Cutting-surface-aware Model-based Reinforcement Learning
Object shaping by grinding is a crucial industrial process in which a rotating grinding belt removes material. Object-shape transition models are essential to achieving automation by robots; however, learning such a complex model that depends on process conditions is challenging because it requires a significant amount of data, and the irreversible nature of the removal process makes data collection expensive. This paper proposes a cutting-surface-aware Model-Based Reinforcement Learning (MBRL) method for robotic grinding. Our method employs a cutting-surface-aware model as the object's shape transition model, which in turn is composed of a geometric cutting model and a cutting-surface-deviation model, based on the assumption that the robot action can specify the cutting surface made by the tool. Furthermore, according to the grinding resistance theory, the cutting-surface-deviation model does not require raw shape information, making the model's dimensions smaller and easier to learn than a naive shape transition model directly mapping the shapes. Through evaluation and comparison by simulation and real robot experiments, we confirm that our MBRL method can achieve high data efficiency for learning object shaping by grinding and also provide generalization capability for initial and target shapes that differ from the training data.
2308.02150v1
2023-08-16
Growth of millimeter-sized high-quality CuFeSe$_2$ single crystals by the molten salt method and study of their semiconducting behavior
An eutectic AlCl$_3$/KCl molten salt method in a horizontal configuration was employed to grow millimeter-sized and composition homogeneous CuFeSe$_2$ single crystals due to the continuous growth process in a temperature gradient induced solution convection. The typical as-grown CuFeSe$_2$ single crystals in cubic forms are nearly 1.6$\times$1.2$\times$1.0 mm3 in size. The chemical composition and homogeneity of the crystals was examined by both inductively coupled plasma atomic emission spectroscopy and energy dispersive spectrometer with Cu:Fe:Se = 0.96:1.00:1.99 consistent with the stoichiometric composition of CuFeSe$_2$. The magnetic measurements suggest a ferrimagnetic or weak ferromagnetic transition below T$_C$ = 146 K and the resistivity reveals a semiconducting behavior and an abrupt increase below T$_C$.
2308.08223v1
2023-08-25
WSTac: Interactive Surface Perception based on Whisker-Inspired and Self-Illuminated Vision-Based Tactile Sensor
Modern Visual-Based Tactile Sensors (VBTSs) use cost-effective cameras to track elastomer deformation, but struggle with ambient light interference. Solutions typically involve using internal LEDs and blocking external light, thus adding complexity. Creating a VBTS resistant to ambient light with just a camera and an elastomer remains a challenge. In this work, we introduce WStac, a self-illuminating VBTS comprising a mechanoluminescence (ML) whisker elastomer, camera, and 3D printed parts. The ML whisker elastomer, inspired by the touch sensitivity of vibrissae, offers both light isolation and high ML intensity under stress, thereby removing the necessity for additional LED modules. With the incorporation of machine learning, the sensor effectively utilizes the dynamic contact variations of 25 whiskers to successfully perform tasks like speed regression, directional identification, and texture classification. Videos are available at: https://sites.google.com/view/wstac/.
2308.13241v1
2023-09-03
Validation of the Wiedemann-Franz Law in solid and molten tungsten above 2000 K through thermal conductivity measurements via steady state temperature differential radiometry
We measure the thermal conductivity of solid and molten tungsten using Steady State Temperature Differential Radiometry. We demonstrate that the thermal conductivity can be well described by application of Wiedemann-Franz Law to electrical resistivity data, thus suggesting the validity of Wiedemann-Franz Law to capture the electronic thermal conductivity of metals in their molten phase. We further support this conclusion using ab initio molecular dynamics simulations with a machine-learned potential. Our results show that at these high temperatures, the vibrational contribution to thermal conductivity is negligible compared to the electronic component.
2309.01062v1
2023-10-05
Demonstration of a monocrystalline GaAs-$β$-Ga$_2$O$_3$ p-n heterojunction
In this work, we report the fabrication and characterizations of a monocrystalline GaAs/$\beta$-Ga$_2$O$_3$ p-n heterojunction by employing semiconductor grafting technology. The heterojunction was created by lifting off and transfer printing a p-type GaAs single crystal nanomembrane to an Al$_2$O$_3$-coated n-type$\beta$-Ga$_2$O$_3$ epitaxial substrate. The resultant heterojunction diodes exhibit remarkable performance metrics, including an ideality factor of 1.23, a high rectification ratio of 8.04E9 at +/- 4V, and a turn on voltage of 2.35 V. Furthermore, at +5 V, the diode displays a large current density of 2500 A/cm$^2$ along with a low ON resistance of 2 m$\Omega\cdot$cm$^2$.
2310.03886v1
2023-11-03
Effects of Cr content on ion-irradiation hardening of FeCrAl ODS ferritic steels with 9 wt\% Al
FeCrAl ODS steels for accident tolerant fuel claddings are designed to bear high-Cr and Al for enhancing oxidation resistance. In this study, we investigated the effects of Cr content on ion-irradiation hardening of three ODS ferritic steels with different Cr contents added with 9 wt\% Al, Fe12Cr9Al (SP12), Fe15Cr9Al (SP13), and Fe18Cr9Al (SP14). The specimens were irradiated with 6.4MeV Fe\textsuperscript{3+} at 300 \textdegree C to nominal 3 dpa. The irradiation hardening was measured by nanoindentation method, and the Nix-Gao plots were used to evaluate the bulk-equivalent hardness. The results showed that the irradiation hardening decreased with increasing Cr content. The reason is due to the growth of dislocation loops hindered by solute Cr atoms. TEM observations showed both $\langle 100\rangle$ and $1/2\langle 111\rangle$ dislocation loops existed in the irradiated area. The irradiation hardening was estimated by dispersed barrier hardening (DBH) model with dislocation loops.
2311.01879v1
2023-11-11
Evidence of Ordering in Cu-Ni Alloys from Experimental Electronic Entropy Measurements
Phase diagrams exhibiting extended solid-solution and lens-like melting are often reproduced using ideal solutions, where ideal mixing considers a fully random configurational entropy of mixing. In the field of irreversible thermodynamics, experimental measurements of the composition variation of high-temperature electronic transport and molten-state properties suggest however a strong role for short-range atomic ordering in these systems. Herein, measurements of the thermopower and resistivity are reported for Cu-Ni solid-solutions as a function of temperature and composition. The electronic transport properties were interpreted with an irreversible thermodynamic framework, revealing a large electronic contribution to the entropy of mixing. Through appeal to a cluster model for the configurational entropy that uses the electronic contribution to inform the existence of ordered associates, we rationalize such contribution of the electronic entropy with the notion of an ideal entropy of mixing commonly used to model such systems. These results suggest that the short range order (S.R.O.) of the atoms plays a significant role in both the solid and molten states, even when there are no dominant intermetallic compounds in these alloys.
2311.06603v2
2023-11-12
First-principles pressure dependent investigation of the physical properties of KB2H8: a prospective high-TC superconductor
Using the density functional theory (DFT) based first-principles investigation, the structural, mechanical, hardness, elastic anisotropy, optoelectronic, and thermal properties of cubic KB2H8 have been studied within the uniform pressure range of 0 - 24 GPa. The calculated structural parameters are in good agreement with the previous theoretical work. The compound KB2H8 is found to be structurally and thermodynamically stable in the pressure range from 8 GPa to 24 GPa. Single crystal elastic constants Cij and bulk elastic moduli (B, G and Y) increase systematically with pressure from 8 GPa to 24 GPa. In the stable phase, KB2H8 is moderately elastically anisotropic and ductile in nature. The compound is highly machinable and fracture resistant. The Debye temperature, melting temperature and thermal conductivity increases with pressure. The results of electronic band structure calculations and optical parameters at different pressures are consistent with each other. The compound is optically isotropic. The compound KB2H8 has potential to be used as a very efficient solar energy reflector. The electronic energy density of states at the Fermi level decreases systematically with increasing pressure. The same trend is found for the repulsive Coulomb pseudopotential. Possible relevance of the studied properties to superconductivity has also been discussed in this paper.
2311.06709v1
2023-12-08
Gate-controlled neuromorphic functional transition in an electrochemical graphene transistor
Neuromorphic devices have gained significant attention as potential building blocks for the next generation of computing technologies owing to their ability to emulate the functionalities of biological nervous systems. The essential components in artificial neural network such as synapses and neurons are predominantly implemented by dedicated devices with specific functionalities. In this work, we present a gate-controlled transition of neuromorphic functions between artificial neurons and synapses in monolayer graphene transistors that can be employed as memtransistors or synaptic transistors as required. By harnessing the reliability of reversible electrochemical reactions between C atoms and hydrogen ions, the electric conductivity of graphene transistors can be effectively manipulated, resulting in high on/off resistance ratio, well-defined set/reset voltage, and prolonged retention time. Overall, the on-demand switching of neuromorphic functions in a single graphene transistor provides a promising opportunity to develop adaptive neural networks for the upcoming era of artificial intelligence and machine learning.
2312.04934v2
2023-12-20
Collective dynamics and long-range order in thermal neuristor networks
In the pursuit of scalable and energy-efficient neuromorphic devices, recent research has unveiled a novel category of spiking oscillators, termed "thermal neuristors". These devices function via thermal interactions among neighboring vanadium dioxide resistive memories, emulating biological neuronal behavior. Here, we show that the collective dynamical behavior of networks of these neurons showcases a rich phase structure, tunable by adjusting the thermal coupling and input voltage. Notably, we identify phases exhibiting long-range order that, however, does not arise from criticality, but rather from the time non-local response of the system. In addition, we show that these thermal neuristor arrays achieve high accuracy in image recognition and time series prediction through reservoir computing, without leveraging long-range order. Our findings highlight a crucial aspect of neuromorphic computing with possible implications on the functioning of the brain: criticality may not be necessary for the efficient performance of neuromorphic systems in certain computational tasks.
2312.12899v2
2024-01-30
Momentum Matching for 2D-3D Heterogeneous Ohmic van der Waals Contact
Construction of ohmic contact is a long-standing challenge encountered by two-dimensional (2D) device fabrication and integration. van der Waals contacts, as a new solution for 2D contact construction, can effectively eliminate issues, such as Fermi-level pining and formation of Schottky barrier. Nevertheless, current research primarily considers energy band alignment, while ignoring the transverse momentum conservation of charge carriers during the quantum tunneling across the van der Waals contacts. In this study, by comparing the IV characteristics and tunneling spectra of graphene-silicon tunneling junctions with various interfacial transverse momentum distribution, we demonstrate the importance of charge carrier momentum in constructing high-performance 2D contact. Further, by conditioning the van der Waals contacts and minimizing the momentum mismatch, we successfully enhanced the quantum tunneling current with more than three orders of magnitude and obtain ohmic-like contact. Our study provide and effective method for the construction of direction 2D-3D contact with low resistance and can potentially benefit the heterogeneous of integration of 2D materials in post-CMOS architectures.
2401.17114v1
2024-02-11
Langmuir-like model of dilute impurities in concentrated solid solutions
High-entropy alloys have drawn recent interest for their promising mechanical properties and irradiation resistance. Various properties, namely transport properties, are controlled by point defect concentration, which must be known before performing atomistic simulations to compute transport coefficients. In this work, we present a general Langmuir-like model for impurity concentration in an arbitrarily complex solid solution and apply this model to generate expressions for concentrations of vacancies and small interstitial atoms. We then calculate the vacancy concentration as a function of temperature in the equiatomic CoNiCrFeMn and FeAl alloys with modified embedded-atom-method potentials for various chemical orderings, showing there is no clear correlation between vacancy thermodynamics and chemical ordering in the CoNiCrFeMn alloy but clear systematic patterns for FeAl.
2402.07324v1
2024-02-28
Strange metal in the doped Hubbard model via percolation
Many strongly correlated systems, including high-temperature superconductors such as the cuprates, exhibit strange metallic behavior in certain parameter regimes characterized by anomalous transport properties that are irreconcilable with a Fermi-liquid-like description in terms of quasiparticles. The Hubbard model is a standard theoretical starting point to examine the properties of such systems and also exhibits non-Fermi-liquid behavior in simulations. Here we analytically study the two-dimensional hole-doped Hubbard model, first identifying a percolation transition that occurs in the low-energy sector at critical hole doping $p_c\sim 0.19$. We then use the critical properties near this transition to rewrite the Hubbard Hamiltonian in a way that motivates a large-$N$ model with strange metallic properties. In particular, we show that this model has the linear-in-$T$ resistivity and power-law optical conductivity $\sim |\omega|^{-2/3}$ observed in the strange metal regime of cuprates, suggesting potential relevance for describing this important class of materials.
2402.18626v2
2024-03-25
Facile synthesis of micro-flower NiCo2O4 assembled by nanosheets efficient for electrocatalysis of water
Effective regulation of the morphology of transition metal spinel structures is crucial for creating efficient and stable bifunctional catalysts for electrocatalysis of water. In this work, micro-flower NiCo2O4 (F-NCO) assembled by nanosheets via a chemical template method for the simultaneous promotion of hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Electronic microscope analysis revealed that the thickness of the F-NCO catalyst was only 2.7% of that of the NiCo2O4 bulk (B-NCO), and this ultrathin lamellar structure was conducive to further exposure of the active site and improved reaction kinetics. The F-NCO catalyst exhibited superior HER and OER performance (10 = 236 and 310 mV) and robust long-term stability over the B-NCO catalyst in 1.0 M KOH, with a 2.68-fold and 4.16-fold increase in active surface area and a 0.42-fold and 0.61-fold decrease in charge transfer resistance values, respectively. This micro-flower-structured electrode has remarkable electrocatalytic property and long-term durability, providing a novel insight for characterizing cost-effective and high-performance bifunctional electrocatalysts.
2403.17744v1
2024-04-30
Aluminum nuclear demagnetization refrigerator for powerful continuous cooling
Many laboratories routinely cool samples to 10 mK, but relatively few can cool condensed matter below 1 mK. Easy access to the microkelvin range would propel fields such as quantum sensors and quantum materials. Such temperatures are achieved with adiabatic nuclear demagnetization. Existing nuclear demagnetization refrigerators (NDR) are "single-shot", and the recycling time is incompatible with proposed sub-mK experiments. Furthermore, a high cooling power is required to overcome the excess heat load of order nW on NDR pre-cooled by cryogen-free dilution refrigerators. We report the performance of an aluminum NDR designed for powerful cooling when part of a dual stage continuous NDR (CNDR). Its thermal resistance is minimized to maximize the cycling rate of the CNDR and consequently its cooling power. At the same time, its susceptibility to eddy current heating is minimized. A CNDR based on two of the aluminum NDR presented here would have a cooling power of approximately 40 nW at 560 $\mu$K.
2404.19352v1
2024-05-10
Effects of vortex and anti-vortex excitations in underdoped Bi-2223 bulk single crystals
To gain insights into mechanisms underlying superconducting transition in copper oxide high-transition temperature ($T_c$) superconductors, we studied transport properties of underdoped Bi$_2$Sr$_2$Ca$_2$Cu$_3$O$_{10+\delta}$ (Bi-2223) bulk single crystals. The power exponent $\alpha$ ($V \propto I^{\alpha}$) reached 3 just below $T_c$, and the temperature dependence of in-plane resistivity ($\rho_{ab}$) exhibited typical tailing behavior, consistent with Kosterlitz--Thouless transition characteristics. Thus, with increasing temperature, copper oxide high-$T_c$ superconductors undergo transition to the normal state because of destruction of its phase correlations, although a finite Cooper pair density exists at $T_c$.
2405.06272v1
2024-05-15
Unraveling impacts of polycrystalline microstructures on ionic conductivity of ceramic electrolytes by computational homogenization and machine learning
The ionic conductivity at the grain boundaries (GBs) in oxide ceramics is typically several orders of magnitude lower than that within the grain interior. This detrimental GB effect is the main bottleneck for designing high-performance ceramic electrolytes intended for use in solid-state Lithium-ion batteries, fuel cells, and electrolyzer cells. The macroscopic ionic conductivity in oxide ceramics is essentially governed by the underlying polycrystalline microstructures where GBs and grain morphology go hand in hand. This provides the possibility to enhance the ion conductivity by microstructure engineering. To this end, a thorough understanding of microstructure-property correlation is highly desirable. In this work, we investigate numerous polycrystalline microstructure samples with varying grain and grain boundary features. Their macroscopic ionic conductivities are numerically evaluated by the finite element homogenization method, whereby the GB resistance is explicitly regarded. The influence of different microstructural features on the effective ionic conductivity is systematically studied. The microstructure-property relationships are revealed. Additionally, a graph neural network-based machine learning model is constructed and trained. It can accurately predict the effective ionic conductivity for a given polycrystalline microstructure. This work provides crucial quantitative guidelines for optimizing the ionic conducting performance of oxide ceramics by tailoring microstructures.
2405.09227v1
2024-05-20
High-Mobility Carriers in Epitaxial IrO2 Films Grown using Hybrid Molecular Beam Epitaxy
Binary rutile oxides of 5d metals such as IrO2, stand out as a paradox due to limited experimental studies despite the rich predicted quantum phenomena. Here, we investigate the electrical transport properties of IrO2 by engineering epitaxial thin films grown via hybrid molecular beam epitaxy. Our findings reveal phonon-limited carrier transport and thickness-dependent anisotropic in-plane resistance in IrO2 (110) films, the latter suggesting a complex relationship between strain relaxation and orbital hybridization. Magneto-transport measurements reveal a previously unobserved non-linear Hall effect. A two-carrier analysis of this effect shows the presence of minority carriers with mobility exceeding 3000 cm2/Vs at 1.8 K. These results point towards emergent properties in 5d metal oxides that can be controlled using dimensionality and epitaxial strain.
2405.11716v1
2024-05-21
A single crystal study of Kagome metals U$_2$Mn$_3$Ge and U$_2$Fe$_3$Ge
Single crystals of U$_2$Mn$_3$Ge and and U$_2$Fe$_3$Ge with a Kagome lattice structure were synthesized using a high-temperature self-flux crystal growth method. The physical properties of these crystals were characterized through measurements of resistivity, magnetism, and specific heat. U$_2$Fe$_3$Ge exhibits ferromagnetic ground state and Anomalous Hall Effect, and U$_2$Mn$_3$Ge demonstrates a complex magnetic structure. Both compounds exhibit large Sommerfeld coefficient, indicating coexistence of heavy Fermion behavior with magnetism. Our results suggest that this U$_2$TM$_3$Ge (TM = Mn, Fe, Co) family is a promising platform to investigate the interplay of magnetism, Kondo physics and the Kagome lattice.
2405.12905v1
2007-07-30
Control of the Casimir force by the modification of dielectric properties with light
The experimental demonstration of the modification of the Casimir force between a gold coated sphere and a single-crystal Si membrane by light pulses is performed. The specially designed and fabricated Si membrane was irradiated with 514 nm laser pulses of 5 ms width in high vacuum leading to a change of the charge-carrier density. The difference in the Casimir force in the presence and in the absence of laser radiation was measured by means of an atomic force microscope as a function of separation at different powers of the absorbed light. The total experimental error of the measured force differences at a separation of 100 nm varies from 10 to 20% in different measurements. The experimental results are compared with theoretical computations using the Lifshitz theory at both zero and laboratory temperatures. The total theoretical error determined mostly by the uncertainty in the concentration of charge carriers when the light is incident is found to be about 14% at separations less than 140 nm. The experimental data are consistent with the Lifshitz theory at laboratory temperature, if the static dielectric permittivity of high-resistivity Si in the absence of light is assumed to be finite. If the dc conductivity of high-resistivity Si in the absence of light is included into the model of dielectric response, the Lifshitz theory at nonzero temperature is shown to be experimentally inconsistent at 95% confidence. The demonstrated phenomenon of the modification of the Casimir force through a change of the charge-carrier density is topical for applications of the Lifshitz theory to real materials in fields ranging from nanotechnology and condensed matter physics to the theory of fundamental interactions.
0707.4390v1
2014-09-03
The influence of the Al stabilizer layer thickness on the normal zone propagation velocity in high current superconductors
The stability of high-current superconductors is challenging in the design of superconducting magnets. When the stability requirements are fulfilled, the protection against a quench must still be considered. A main factor in the design of quench protection systems is the resistance growth rate in the magnet following a quench. The usual method for determining the resistance growth in impregnated coils is to calculate the longitudinal velocity with which the normal zone propagates in the conductor along the coil windings. Here, we present a 2D numerical model for predicting the normal zone propagation velocity in Al stabilized Rutherford NbTi cables with large cross section. By solving two coupled differential equations under adiabatic conditions, the model takes into account the thermal diffusion and the current redistribution process following a quench. Both the temperature and magnetic field dependencies of the superconductor and the metal cladding materials properties are included. Unlike common normal zone propagation analyses, we study the influence of the thickness of the cladding on the propagation velocity for varying operating current and magnetic field. To assist in the comprehension of the numerical results, we also introduce an analytical formula for the longitudinal normal zone propagation. The analysis distinguishes between low-current and high-current regimes of normal zone propagation, depending on the ratio between the characteristic times of thermal and magnetic diffusion. We show that above a certain thickness, the cladding acts as a heat sink with a limited contribution to the acceleration of the propagation velocity with respect to the cladding geometry. Both numerical and analytical results show good agreement with experimental data.
1409.1186v1
2020-01-10
A barrier/seed system for electroless metallization on complex surfaces using (aminomethylaminoethyl)phenethyltrimethoxysilane self-assembled films
High frequency signals propagate along the edges of conductors. If the conductors are electroplated, then the seed layer forms at least one edge, so care must be taken to insure the electrical quality of these layers. In this work, we study the initial quality of SAM-based seed layers that are compatible with complex surfaces including through-silicon vias (TSVs), as are used in via-last three-dimensional semiconductor device packaging. The conformal and electrical quality of the seed metal is very important. Also important for a multifunction seed layer is its ability as a barrier layer, which protects the substrate from high temperature diffusion of the deposited metal. Thus, the barrier layer must be robust enough to withstand diffusion, yet thin enough to provide a conformal surface that allows metal seed layer deposition. Standard barrier layer deposition methods such as evaporation or sputtering require either a line of sight from the source or aspect ratios large enough to provide scattering from the background gas within the structure to coat all surfaces. Electrochemical and chemical vapor deposition provide alternatives, but concerns arise about contamination and compatibility with radio frequency or high-speed digital signals. We propose a barrier layer based on an aromatic self-assembled monolayer (SAM) for use in electroless copper seed layer deposition. The viability of the SAM barrier layer is determined by the quality of the deposited copper seed film, judged quantitatively by thin film resistivity and qualitatively by surface adhesion and morphological properties such as cracks and bubbles. Insights to the origins of problems and an optimal scheme are described. Extensions for use as a photolithographic resist layer are suggested. Our SAM approach for TSV applications yields a 'smart' seed layer that can be used with a 'simple,' scalloped, easy to fabricate, via hole.
2001.03295v1
2022-04-04
Exceptional fracture toughness of CrCoNi-based medium- and high-entropy alloys close to liquid helium temperatures
Medium- and high-entropy alloys based on the CrCoNi-system have been shown to display outstanding strength, tensile ductility and fracture toughness (damage-tolerance properties), especially at cryogenic temperatures. Here we examine the JIc and (back-calculated) KJIc fracture toughness values of the face-centered cubic, equiatomic CrCoNi and CrMnFeCoNi alloys at 20 K. At flow stress values of ~1.5 GPa, crack-initiation KJIc toughnesses were found to be exceptionally high, respectively 235 and 415 MPa(square-root)m for CrMnFeCoNi and CrCoNi, with the latter displaying a crack-growth toughness Kss exceeding 540 MPa(square-root)m after 2.25 mm of stable cracking, which to our knowledge is the highest such value ever reported. Characterization of the crack-tip regions in CrCoNi by scanning electron and transmission electron microscopy reveal deformation structures at 20 K that are quite distinct from those at higher temperatures and involve heterogeneous nucleation, but restricted growth, of stacking faults and fine nano-twins, together with transformation to the hexagonal closed-packed phase. The coherent interfaces of these features can promote both the arrest and transmission of dislocations to generate respectively strength and ductility which strongly contributes to sustained strain hardening. Indeed, we believe that these nominally single-phase, concentrated solid-solution alloys develop their fracture resistance through a progressive synergy of deformation mechanisms, including dislocation glide, stacking-fault formation, nano-twinning and eventually in situ phase transformation, all of which serve to extend continuous strain hardening which simultaneously elevates strength and ductility (by delaying plastic instability), leading to truly exceptional resistance to fracture.
2204.01635v1
2023-10-16
Electronic Transport and Fermi Surface Topology of Zintl phase Dirac Semimetal SrZn2Ge2
We report a comprehensive study on the electronic transport properties of SrZn$_2$Ge$_2$ single crystals. The in-plane electrical resistivity of the compound exhibits linear temperature dependence for 80 K < T < 300 K, and T^2 dependence below 40 K, consistent with the Fermi liquid behavior. Both the transverse and longitudinal magnetoresistance exhibit a crossover at critical field B* from weak-field quadratic-like to high-field unsaturated linear field dependence at low temperatures (T \leq 50 K). Possible sources of linear magnetoresistance are discussed based on the Fermi surface topology, classical and quantum transport models. The Hall resistivity data establish SrZn$_2$Ge$_2$ as a multiband system with contributions from both the electrons and holes. The Hall coefficient is observed to decrease with increasing temperature and magnetic field, changing its sign from positive to negative. The negative Hall coefficient observed at low temperatures in high fields and at high temperatures over the entire field range suggests that the highly mobile electron charge carriers dominate the electronic transport. Our first-principles calculations show that nontrivial topological surface states exist in SrZn$_2$Ge$_2$ within the bulk gap along the {\Gamma}-M path. Notably, these surface states extend from the valence to conduction band with their number varying based on the Sr and Ge termination plane. The Fermi surface of the compound exhibits a distinct tetragonal petal-like structure, with one open and several closed surfaces. Overall, these findings offer crucial insights into the mechanisms underlying the electronic transport of the compound.
2310.10621v2
2023-06-24
High Strength Refractory AlHfNbTiV B2 High Entropy Alloys with High Fracture Strains
We demonstrate the development of a series of refractory high-entropy alloys containing aluminum AlRHEAs in the ordered BCC-B2 phase by varying the aluminum content within 10 to 25 atomic percent, with the goal of high strength and good ductility synergy. The AlRHEAs obtained are found to show promising potential for high-temperature applications. The incorporation of Al lowers the density and promotes the long-range atomic ordering, which in turn stabilizes the B2 formation, and strengthens the material but usually deteriorates ductility. Several B2 AlRHEAs that contain a combination of Ti, Hf, Nb, and V with moderate to high Poisson ratios are investigated for high strength and ductility. Furthermore, through statistical analysis, we identify a valley around the valence electron concentration VEC of 6 where low ductility is prominently observed. Machine-learning models are employed to screen the vast compositional space of AlRHEA alloys to predict B2 formation and toughness indicated by the yield strength and fracture strain. High prediction accuracies are achieved. As the Al content decreases, the B2 atomic ordering decreases, compression yield strengths decrease from 1500 MPa to 1200 MPa, and compression fracture strains increase from 0.06 to over 0.5. Notably, Al10Hf20Nb22Ti33V15 retains a compression yield strength exceeding 800 MPa up to 700 C, tensile yield strength of 1100 MPa, and fracture strain of 0.083. Our findings on enhancing ductility in pure B2 alloys pave the way for further research on Al-RHEA superalloys, striving to achieve high strength and ductility, reduced density, and improved oxidation resistance.
2306.14057v2
1998-04-04
Ohmic Decay of Magnetic Fields due to non-spherical accretion in the Crusts of Neutron Stars
We consider magnetic field evolution of neutron stars during polar-cap accretion. The size of the polar cap increases as the field decays, and is set by the last open field line before the accretion disk. Below the polar cap we find the temperature to be so high that electron-phonon scattering dominates the resistivity. Outside the polar cap region, the temperature is such the resistivity is dominated by temperature independent impurity scattering which can be a few orders of magnitude larger than the electron- phonon resistivity. The time-scale for field decay is therefore initially given by impurity scattering dominated resistivity. When the field strength has been reduced to $\sim 10^8 gauss$ the accretion is spherical and the time scale for field decay is given by the smaller electron-phonon scattering resistivity. The field strength is now reduced rapidly compared to before and this could be a reason for there being no pulsars known with field strengths below $10^8 gauss$. We also investigate the evolution of multipoles at the neutron star surface. We find that contribution from higher-order multipoles are at most 30% to that of the dipole mode.
9804047v1
2000-01-10
The Effect of Resistivity on the Nonlinear Stage of the Magnetorotational Instability in Accretion Disks
We present three-dimensional magnetohydrodynamic simulations of the nonlinear evolution of the magnetorotational instability (MRI) with a non-zero Ohmic resistivity. The properties of the saturated state depend on the initial magnetic field configuration. In simulations with an initial uniform vertical field, the MRI is able to support angular momentum transport even for large resistivities through the quasi-periodic generation of axisymmetric radial channel solutions rather than through the maintenance of anisotropic turbulence. Simulations with zero net flux show that the angular momentum transport and the amplitude of magnetic energy after saturation are significantly reduced by finite resistivity, even at levels where the linear modes are only slightly affected. This occurs at magnetic Reynolds numbers expected in low, cool states of dwarf novae, these results suggest that finite resistivity may account for the low and high angular momentum transport rates inferred for these systems.
0001164v1
1998-10-15
The Quantized Hall Insulator: A New Insulator in Two-Dimensions
Quite generally, an insulator is theoretically defined by a vanishing conductivity tensor at the absolute zero of temperature. In classical insulators, such as band insulators, vanishing conductivities lead to diverging resistivities. In other insulators, in particular when a high magnetic field (B) is added, it is possible that while the magneto-resistance diverges, the Hall resistance remains finite, which is known as a Hall insulator. In this letter we demonstrate experimentally the existence of another, more exotic, insulator. This insulator, which terminates the quantum Hall effect series in a two-dimensional electron system, is characterized by a Hall resistance which is approximately quantized in the quantum unit of resistance h/e^2. This insulator is termed a quantized Hall insulator. In addition we show that for the same sample, the insulating state preceding the QHE series, at low-B, is of the HI kind.
9810172v1
1999-03-05
Comment on ``Evidence for Anisotropic State of Two-Dimensional Electrons in High Landau Levels''
In a recent letter M. Lilly et al [PRL 82, 394 (1999)] have shown that a highly anisotropic state can arise in certain two dimensional electron systems. In the large square samples studied, resistances measured in the two perpendicular directions are found to have a ratio that may be 60 or larger at low temperature and at certain magnetic fields. In Hall bar measurements, the anisotropy ratio is found to be much smaller (roughly 5). In this comment we resolve this discrepancy by noting that the anisotropy of the underlying sheet resistivities is correctly represented by Hall bar resistance measurements but shows up exponentially enhanced in resistance measurements on square samples due to simple geometric effects. We note, however, that the origin of this underlying resistivity anisotropy remains unknown, and is not addressed here.
9903086v3
1999-12-01
Fractional-flux Little-Parks resistance oscillations in disordered superconducting Au$_{0.7}$In$_{0.3}$ cylinders
Resistance of disordered superconducting Au$_{0.7}$In$_{0.3}$ cylindrical films was measured as a function of applied magnetic field. In the high-temperature part of the superconducting transition regime, the resistance oscillated with a period of $h/2e$ in the unit of the enclosed magnetic flux. However, at lower temperatures, the resistance peaks split. We argue that this splitting is due to the emergence of an oscillation with a period of $h/4e$, half of the flux quantum for paired electrons. The possible physical origin of the $h/4e$ resistance oscillation is discussed in the context of new minima in the free energy of a disordered superconducting cylinder.
9912003v3
2000-04-05
Linear response conductance and magneto-resistance of ferromagnetic single-electron transistors
The current through ferromagnetic single-electron transistors (SET's) is considered. Using path integrals the linear response conductance is formulated as a function of the tunnel conductance vs. quantum conductance and the temperature vs. Coulomb charging energy. The magneto-resistance of ferromagnet-normal metal-ferromagnet (F-N-F) SET's is almost independent of the Coulomb charging energy and is only reduced when the transport dwell time is longer than the spin-flip relaxation time. In all-ferromagnetic (F-F-F) SET's with negligible spin-flip relaxation time the magneto-resistance is calculated analytically at high temperatures and numerically at low temperatures. The F-F-F magneto-resistance is enhanced by higher order tunneling processes at low temperatures in the 'off' state when the induced charges vanishes. In contrast, in the 'on' state near resonance the magneto-resistance ratio is a non-monotonic function of the inverse temperature.
0004082v3
2001-09-10
Transport properties of MgB2
In this paper we present the resistivity, the Seebeck effect, and the thermal conductivity measurements on a MgB2 sintered sample. Such transport properties highlight the role of the junctions between the grains to a different extent. In particular, the temperature dependence of resistivity may be explained with the assumption that grain boundaries have a resistance, independent of temperature, in series with the resistance of grains. Also the behaviour of the Seebeck effect, as long as the scattering at the grain boundaries is elastic, is not affected at all by granularity. Thus, the thermopower can be a useful tool to provide information on the electronic structure. On the other hand, the grain boundary resistance affects the thermal conductivity strongly, masking the superconducting transition completely.
0109174v2
2003-10-22
Unconventional superconductivity and normal state properties of epsilon-iron at high pressure
Following the discovery of superconductivity in epsilon-iron, subsequent experiments hinted at non-Fermi liquid behaviour of the normal phase and sensitive dependence of the superconducting state on disorder, both signatures of unconventional pairing. We report further resistive measurements under pressure of samples of iron from multiple sources. The normal state resistivity of epsilon-iron varied as rho_0+AT^{5/3} at low temperature over the entire superconducting pressure domain. The superconductivity could be destroyed by mechanical work, and was restored by annealing, demonstrating sensitivity to the residual resistivity rho_0. There is a strong correlation between the rho_0 and A coefficients and the superconducting critical temperature T_c. Within the partial resistive transition there was a significant current dependence, with V(I)=a(I-I_0)+bI^2, with a >> b, possibly indicating flux-flow resistivity, even in the absence of an externally applied magnetic field.
0310519v1
2003-12-10
Phase slips in superconducting films with constrictions
A system of two coplanar superconducting films seamlessly connected by a bridge is studied. We observe two distinct resistive transitions as the temperature is reduced. The first one, occurring in the films, shows some properties of the Berezinskii-Kosterlitz-Thouless (BKT) transition. The second apparent transition (which is in fact a crossover) is related to freezing out of thermally activated phase slips (TAPS) localized on the bridge. We also propose a powerful indirect experimental method allowing an extraction of the sample's zero-bias resistance from high-current-bias measurements. Using direct and indirect measurements, we determined the resistance $R(T)$ of the bridges within a range of {\em eleven orders of magnitude}. Over such broad range, the resistance follows a simple relation $R(T)=R_N \text{exp} [-(c/t)(1-t)^{3/2}]$, where $c=\Delta F(0) / kT_c$ is the normalized free energy of a phase slip at zero temperature, $t=T/T_c$ is normalized temperature, and $R_N$ is the normal resistance of the bridge.
0312268v2
2004-10-04
The "normal" state of superconducting cuprates might really be normal after all
High magnetic field studies of cuprate superconductors revealed a non-BCS temperature dependence of the upper critical field $H_{c2}(T)$ determined resistively by several groups. These determinations caused some doubts on the grounds of both the contrasting effect of the magnetic field on the in-plane and out-of-plane resistances reported for large Bi2212 sample and the large Nernst signal \emph{well above} $T_{c}$. Here we present both $\rho_{ab}(B)$ and $\rho_{c}(B)$ of tiny Bi2212 crystals in magnetic fields up to 50 Tesla. None of our measurements revealed a situation when on the field increase $\rho_c$ reaches its maximum while $\rho_{ab}$ remains very small if not zero. The resistive %upper critical fields estimated from the in-plane and out-of-plane $H_{c2}(T)$ estimated from $\rho_{ab}(B)$ and $\rho_{c}(B)$ are approximately the same. Our results support any theory of cuprates that describes the state above the resistive phase transition as perfectly normal with a zero off-diagonal order parameter. In particular, the anomalous Nernst effect above the resistive phase transition in high-$T_{c}$ cuprates can be described quantitatively as a normal state phenomenon in a model with itinerant and localised fermions and/or charged bosons.
0410075v1
2008-04-03
Pressure-temperature Phase Diagram of Polycrystalline UCoGe Studied by Resistivity Measurement
Recently, coexistence of ferromagnetism (T_Curie = 2.8K) and superconductivity (T_sc = 0.8K) has been reported in UCoGe, a compound close to a ferromagnetic instability at ambient pressure P. Here we present resistivity measurements under pressure on a UCoGe polycrystal. The phase diagram obtained from resistivity measurements on a polycrystalline sample is found to be qualitatively different to those of all other ferromagnetic superconductors. By applying high pressure, ferromagnetism is suppressed at a rate of 1.4 K/GPa. No indication of ferromagnetic order has been observed above P ~ 1GPa. The resistive superconducting transition is, however, quite stable in temperature and persists up to the highest measured pressure of about 2.4GPa. Superconductivity would therefore appear also in the paramagnetic phase. However, the appearance of superconductivity seems to change at a characteristic pressure P* ~ 0.8GPa. Close to a ferromagnetic instability, the homogeneity of the sample can influence strongly the electronic and magnetic properties and therefore bulk phase transitions may differ from the determination by resistivity measurements.
0804.0500v1
2008-08-18
Upper critical field, anisotropy, and superconducting properties of Ba$_{1-x}$K$_x$Fe$_2$As$_2$ single crystals
The temperature dependent resistivity of Ba$_{1-x}$K$_x$Fe$_2$As$_2$ (x = 0.23, 0.25, 0.28 and 0.4) single crystals and the angle dependent resistivity of superconducting Ba$_{0.6}$K$_{0.4}$Fe$_2$As$_2$ single crystals were measured in magnetic fields up to 9 T. The measurements of temperature dependent resistivity for samples with different doping levels revealed very high upper critical fields which increase with the transition temperature monotonously, and a very low superconducting anisotropy ratio $\Gamma=H_{c2}^{ab}/H_{c2}^c \approx$ 2. By scaling the resistivity in the frame of the anisotropic Ginzburg-Landau theory, the angle dependent resistivity of the Ba$_{0.6}$K$_{0.4}$Fe$_2$As$_2$ single crystal measured with different magnetic fields at a certain temperature collapsed onto one curve. As the only scaling parameter, the anisotropy $\Gamma$ was determined alternatively for each temperature and was found to be between two and three.
0808.2392v3
2009-04-28
Complete pressure dependent phase diagrams for SrFe2As2 and BaFe2As2
The temperature dependent electrical resistivity of single crystalline SrFe2As2 and BaFe2As2 has been measured in a liquid medium, modified Bridgman anvil cell for pressures in excess of 75 kbar. These data allow for the determination of the pressure dependence of the higher temperature, structural / antiferromagnetic phase transitions as well as the lower temperature superconducting phase transition. For both compounds the ambient pressure, higher temperature structural / antiferromagnetic phase transition can be fully suppressed with a dome-like region of zero resistivity found to be centered about its critical pressure. Indeed, qualitatively, the temperature dependence of the resistivity curves closest to the critical pressures are the closest to linear, consistent with possible quantum criticality. For pressures significantly higher than the critical pressure the zero resistivity state is suppressed and the low temperature resistivity curves asymptotically approach a universal, low temperature manifold. These results are consistent with the hypothesis that correlations / fluctuations associated with the ambient-pressure, high-temperature, tetragonal phase have to be brought to low enough temperature to allow superconductivity, but if too fully suppressed can lead to the loss of the superconducting state.
0904.4488v1
2011-01-17
The magnetoresistance and Hall effect in CeFeAsO: a high magnetic field study
The longitudinal electrical resistivity and the transverse Hall resistivity of CeFeAsO are simultaneously measured up to a magnetic field of 45T using the facilities of pulsed magnetic field at Los Alamos. Distinct behaviour is observed in both the magnetoresistance Rxx({\mu}0H) and the Hall resistance Rxy({\mu}0H) while crossing the structural phase transition at Ts \approx 150K. At temperatures above Ts, little magnetoresistance is observed and the Hall resistivity follows linear field dependence. Upon cooling down the system below Ts, large magnetoresistance develops and the Hall resistivity deviates from the linear field dependence. Furthermore, we found that the transition at Ts is extremely robust against the external magnetic field. We argue that the magnetic state in CeFeAsO is unlikely a conventional type of spin-density-wave (SDW).
1101.3170v1
2013-07-23
Nonlocal resistance and its fluctuations in microstructures of band-inverted HgTe/(Hg,Cd)Te quantum wells
We investigate experimentally transport in gated microsctructures containing a band-inverted HgTe/Hg_{0.3}Cd_{0.7}Te quantum well. Measurements of nonlocal resistances using many contacts prove that in the depletion regime the current is carried by the edge channels, as expected for a two-dimensional topological insulator. However, high and non-quantized values of channel resistances show that the topological protection length (i.e. the distance on which the carriers in helical edge channels propagate without backscattering) is much shorter than the channel length, which is ~100 micrometers. The weak temperature dependence of the resistance and the presence of temperature dependent reproducible quasi-periodic resistance fluctuations can be qualitatively explained by the presence of charge puddles in the well, to which the electrons from the edge channels are tunnel-coupled.
1307.6115v3
2013-08-01
Resistive Threshold Logic
We report a resistance based threshold logic family useful for mimicking brain like large variable logic functions in VLSI. A universal Boolean logic cell based on an analog resistive divider and threshold logic circuit is presented. The resistive divider is implemented using memristors and provides output voltage as a summation of weighted product of input voltages. The output of resistive divider is converted into a binary value by a threshold operation implemented by CMOS inverter and/or Opamp. An universal cell structure is presented to decrease the overall implementation complexity and number of components. When the number of input variables become very high, the proposed cell offers advantages of smaller area and design simplicity in comparison with CMOS based logic circuits.
1308.0090v1
2014-02-03
The Effect of Magnetic Fields, Temperature and Current on the Resistivity of Bi-2223 High Temperature Superconductors
The electrical resistivity of polycrystalline Bi2Sr2Ca2Cu3O10-x (Bi-2223) was measured vs. applied magnetic fields up to 0.45 T, applied currents up to 1 A, and temperature from liquid nitrogen temperature (LN2) to room temperature. In the lowest temperature region, the only truly zero resistivity was observed when the magnetic field was zero; otherwise, a quadratic dependence on the magnetic field occurred. Hysteresis was noted at the higher currents. Current vs. voltage curves in this region revealed a non-ohmic resistivity. In the transition region to the mixed state, indications of negative resistivity and suggestions of a phase change were observed. Arrhenius plots yielded activation energies of around 0.05 eV/molecule. In the mixed state region up to the transition temperature of ~110K, analysis implied that 4 superconducting quantum states exist and that they are cooperatively filled by the superconducting charge carriers. The occupation of the superconducting quantum states is negatively affected by the applied magnetic field and by the applied current. No effect on the polarity or direction of the magnetic field with respect to the direction of the current was observed.
1402.0436v1
2014-10-06
Low Resistance Metal Contacts to MoS2 Devices with Nickel-Etched-Graphene Electrodes
We report an approach to achieve low-resistance contacts to MoS2 transistors with the intrinsic performance of the MoS2 channel preserved. Through a dry transfer technique and a metal-catalyzed graphene treatment process, nickel-etched-graphene electrodes were fabricated on MoS2 that yield contact resistance as low as 200 ohm-um. The substantial contact enhancement (~2 orders of magnitude) as compared to pure nickel electrodes, is attributed to the much smaller work function of nickel-graphene electrodes, together with the fact that presence of zigzag edges in the treated graphene surface enhances tunneling between nickel and graphene. To this end, the successful fabrication of a clean graphene-MoS2 interface and a low resistance nickel-graphene interface is critical for the experimentally measured low contact resistance. The potential of using graphene as an electrode interlayer demonstrated in this work paves the way towards achieving high performance next-generation transistors.
1410.1328v2
2017-06-14
Kinetic theory of transport for inhomogeneous electron fluids
The interplay between electronic interactions and disorder is neglected in the conventional Boltzmann theory of transport, yet can play an essential role in determining the resistivity of unconventional metals. When quasiparticles are long-lived, one can account for these intertwined effects by solving spatially inhomogeneous Boltzmann equations. Assuming smooth disorder and neglecting umklapp scattering, we solve these inhomogeneous kinetic equations and compute the electrical resistivity across the ballistic-to-hydrodynamic transition. An important consequence of electron-electron interactions is the modification of the momentum relaxation time; this effect is ignored in the conventional theory. We characterize precisely when interactions enhance the momentum scattering rate, and when they decrease it. Our approach unifies existing semiclassical theories of transport and reveals novel transport mechanisms. In particular, we explain how the resistivity can be proportional to the rate of momentum-conserving collisions. We compare this result with existing transport mysteries, including the disorder-independent $T^2$ resistivity of many Fermi liquids, and the linear-in-$T$ "Planckian-limited" resistivity of many strange metals.
1706.04621v3
2017-10-11
Zero-field quantum anomalous Hall metrology as a step towards a universal quantum standard unit system
In the quantum anomalous Hall effect, the edge states of a ferromagnetically doped topological insulator exhibit quantized Hall resistance and dissipationless transport at zero magnetic field. Up to now, however, the resistance was experimentally assessed with standard transport measurement techniques which are difficult to trace to the von-Klitzing constant R$_K$ with high precision. Here, we present a metrologically comprehensive measurement, including a full uncertainty budget, of the resistance quantization of V-doped (Bi,Sb)$_2$Te$_3$ devices without external magnetic field. We established as a new upper limit for a potential deviation of the quantized anomalous Hall resistance from RK a value of 0.26 +- 0.22 ppm, the smallest and most precise value reported to date. This provides another major step towards realization of the zero-field quantum resistance standard which in combination with Josephson effect will provide the universal quantum units standard in the future.
1710.04090v1
2019-09-20
Phenomenology of anomalous transport in disordered one-dimensional systems
We study anomalous transport arising in disordered one-dimensional spin chains, specifically focusing on the subdiffusive transport typically found in a phase preceding the many-body localization transition. Different types of transport can be distinguished by the scaling of the average resistance with the system's length. We address the following question: what is the distribution of resistance over different disorder realizations, and how does it differ between transport types? In particular, an often evoked so-called Griffiths picture, that aims to explain slow transport as being due to rare regions of high disorder, would predict that the diverging resistivity is due to fat power-law tails in the resistance distribution. Studying many-particle systems with and without interactions we do not find any clear signs of fat tails. The data is compatible with distributions that decay faster than any power law required by the fat tails scenario. Among the distributions compatible with the data, a simple additivity argument suggests a Gaussian distribution for a fractional power of the resistance.
1909.09507v2
2019-06-29
Ultra-Low Surface Resistance via Vacuum Heat Treatment of Superconducting Radiofrequency Cavities
We report on an effort to improve the performance of superconducting radiofrequency cavities by the use of heat treatment in a temperature range sufficient to dissociate the natural surface oxide. We find that the residual resistance is significantly decreased, and we find an unexpected reduction in the BCS resistance. Together these result in extremely high quality factor values at relatively large accelerating fields Eacc ~20 MV/m: Q0 of 3-4x10^11 at <1.5 K and Q0 ~5x10^10 at 2.0 K. In one cavity, measurements of surface resistance versus temperature showed an extremely small residual resistance of just 0.63+/-0.06 nOhms at 16 MV/m. SIMS measurements confirm that the oxide was significantly dissociated, but they also show the presence of nitrogen after heat treatment. We also present studies of surface oxidation via exposure to air and to water, as well as the effects of very light surface removal via HF rinse. The possibilities for applications and the planned future development are discussed.
1907.00147v1
2012-03-21
Magnetoplasmon resonance in 2D electron system driven into a zero-resistance state
We report on a remarkably strong, and a rather sharp, photoresistance peak originating from a dimensional magnetoplasmon resonance (MPR) in a high mobility GaAs/AlGaAs quantum well driven by microwave radiation into a zero-resistance state (ZRS). The analysis of the MPR signalreveals a negative background providing experimental evidence for the concept of absolute negative resistance associated with the ZRS. When a system is further subject to a dc field, the maxima of microwave-induced resistance oscillations decay away and a system reveals a state with close-to-zero differential resistance. The MPR peak, on the other hand, remains essentially unchanged, indicating surprisingly robust Ohmic behavior under the MPR conditions.
1203.4781v1
2015-04-21
Radiation-induced resistance oscillations in a 2D hole gas: a demonstration of a universal effect
We report on a theoretical insight about the microwave-induced resistance oscillations and zero resistance states when dealing with p-type semiconductors and holes instead of electrons. We consider a high-mobility two-dimensional hole gas hosted in a pure Ge/SiGe quantum well. Similarly to electrons we obtain radiation-induce resistance oscillations and zero resistance states. We analytically deduce a universal expression for the irradiated magnetoresistance, explaining the origin of the minima positions and their $1/4$ cycle phase shift. The outcome is that these phenomena are universal and only depend on radiation and cyclotron frequencies. We also study the possibility of having simultaneously two different carriers driven by radiation: light and heavy holes. As a result the calculated magnetoresistance reveals an interference profile due to the different effective masses of the two types of carriers.
1504.05564v2
2019-10-03
Modeling of Electrical Resistivity of Soil Based on Geotechnical Properties
Determining the relationship between the electrical resistivity of soil and its geotechnical properties is an important engineering problem. This study aims to develop methodology for finding the best model that can be used to predict the electrical resistivity of soil, based on knowing its geotechnical properties. The research develops several linear models, three non-linear models, and three artificial neural network models (ANN). These models are applied to the experimental data set comprises 864 observations and five variables. The results show that there are significant exponential negative relationships between the electrical resistivity of soil and its geotechnical properties. The most accurate prediction values are obtained using the ANN model. The cross-validation analysis confirms the high precision of the selected predictive model. This research is the first rigorous systematic analysis and comparison of difference methodologies in ground electrical resistivity studies. It provides practical guidelines and examples of design, development and testing non-linear relationships in engineering intelligent systems and applications.
1910.01325v1
2019-10-16
$T$-linear resistivity in models with local self-energy
A theoretical understanding of the enigmatic linear-in-temperature ($T$) resistivity, ubiquitous in strongly correlated metallic systems, has been a long sought-after goal. Furthermore, the slope of this robust $T$-linear resistivity is also observed to stay constant through crossovers between different temperature regimes: a phenomenon we dub "slope invariance". Recently, several solvable models with $T$-linear resistivity have been proposed, putting us in an opportune moment to compare their inner workings in various explicit calculations. We consider two strongly correlated models with local self-energies that demonstrate $T$-linearity: a lattice of coupled Sachdev-Ye-Kitaev (SYK) models and the Hubbard model in single-site dynamical mean-field theory (DMFT). We find that the two models achieve $T$-linearity through distinct mechanisms at intermediate temperatures. However, we also find that these mechanisms converge to an identical form at high temperatures. Surprisingly, both models exhibit "slope invariance" across the two temperature regimes. We thus not only reveal some of the diversity in the theoretical inner workings that can lead to $T$-linear resistivity, but we also establish that different mechanisms can result in "slope invarance".
1910.07530v2
2020-05-28
Contact resistance extraction of graphene FET technologies based on individual device characterization
Straightforward contact resistance extraction methods based on electrical device characteristics are described and applied here to graphene field-effect transistors from different technologies. The methods are an educated adaptation of extraction procedures originally developed for conventional transistors by exploiting the drift-diffusion-like transport in graphene devices under certain bias conditions. In contrast to other available approaches for contact resistance extraction of graphene transistors, the practical methods used here do not require either the fabrication of dedicated test structures or internal device phenomena characterization. The methodologies are evaluated with simulation-based data and applied to fabricated devices. The extracted values are close to the ones obtained with other more intricate methodologies. Bias-dependent contact and channel resistances studies, bias-dependent high-frequency performance studies and contact engineering studies are enhanced and evaluated by the extracted contact resistance values.
2005.13926v1
2021-10-29
Influence of Device Geometry on Transport Properties of Topological Insulator Microflakes
In the transport studies of topological insulators, microflakes exfoliated from bulk single crystals are often used because of the convenience in sample preparation and the accessibility to high carrier mobilities. Here, based on finite element analysis, we show that for the non-Hall-bar shaped topological insulator samples, the measured four-point resistances can be substantially modified by the sample geometry, bulk and surface resistivities, and magnetic field. Geometry correction factors must be introduced for accurately converting the four-point resistances to the longitudinal resistivity and Hall resistivity. The magnetic field dependence of inhomogeneous current density distribution can lead to pronounced positive magnetoresistance and nonlinear Hall effect that would not exist in the samples of ideal Hall bar geometry.
2110.15589v1
2022-04-14
DC-coupled resistive silicon detectors for 4-D tracking
In this work, we introduce a new design concept: the DC-Coupled Resistive Silicon Detectors, based on the LGAD technology. This new approach intends to address a few known features of the first generation of AC-Coupled Resistive Silicon Detectors (RSD). Our simulation exploits a fast hybrid approach based on a combination of two packages, Weightfield2 and LTSpice. It demonstrates that the key features of the RSD design are maintained, yielding excellent timing and spatial resolutions: a few tens of ps and a few microns. In the presentation, we will outline the optimization methodology and the results of the simulation. We will present detailed studies on the effect of changing the ratio between the n+ layer resistivity and the low-resistivity ring and on the achievable temporal and spatial resolution.
2204.07226v1
2022-10-19
Vector graphics extraction and analysis of electrical resistance data in Nature volume 586, pages 373-377 (2020)
In this paper, I present an analysis of the electrical resistance graphs in Nature volume 586, pages 373-377 (2020), which reported the discovery of room temperature superconductivity in a carbonaceous sulfur hydride and was subsequently retracted on September 26th, 2022. I show that, over a single temperature interval, the electrical resistance data can be decomposed into at least two signals of differing digital precision, thus raising questions concerning the methods used to obtain the published data. Since the raw data-files for the electrical resistance measurements have not been made available, in order to perform this analysis, I have developed a set of python scripts to extract the data-points with high precision from the internal structure of the vector graphics image files. I describe the data extraction method. Example code and the resulting electrical resistance vs temperature data-files are made available in public repositories.
2210.10766v1
2023-06-26
Towards Optimal Effective Resistance Estimation
We provide new algorithms and conditional hardness for the problem of estimating effective resistances in $n$-node $m$-edge undirected, expander graphs. We provide an $\widetilde{O}(m\epsilon^{-1})$-time algorithm that produces with high probability, an $\widetilde{O}(n\epsilon^{-1})$-bit sketch from which the effective resistance between any pair of nodes can be estimated, to $(1 \pm \epsilon)$-multiplicative accuracy, in $\widetilde{O}(1)$-time. Consequently, we obtain an $\widetilde{O}(m\epsilon^{-1})$-time algorithm for estimating the effective resistance of all edges in such graphs, improving (for sparse graphs) on the previous fastest runtimes of $\widetilde{O}(m\epsilon^{-3/2})$ [Chu et. al. 2018] and $\widetilde{O}(n^2\epsilon^{-1})$ [Jambulapati, Sidford, 2018] for general graphs and $\widetilde{O}(m + n\epsilon^{-2})$ for expanders [Li, Sachdeva 2022]. We complement this result by showing a conditional lower bound that a broad set of algorithms for computing such estimates of the effective resistances between all pairs of nodes require $\widetilde{\Omega}(n^2 \epsilon^{-1/2})$-time, improving upon the previous best such lower bound of $\widetilde{\Omega}(n^2 \epsilon^{-1/13})$ [Musco et. al. 2017]. Further, we leverage the tools underlying these results to obtain improved algorithms and conditional hardness for more general problems of sketching the pseudoinverse of positive semidefinite matrices and estimating functions of their eigenvalues.
2306.14820v1
2023-08-22
Non-Hermitian topological ohmmeter
Measuring large electrical resistances forms an essential part of common applications such as insulation testing, but suffers from a fundamental problem: the larger the resistance, the less sensitive a canonical ohmmeter is. Here we develop a conceptually different electronic sensor by exploiting the topological properties of non-Hermitian matrices, whose eigenvalues can show an exponential sensitivity to perturbations. The ohmmeter is realized in an multi-terminal, linear electric circuit with a non-Hermitian conductance matrix, where the target resistance plays the role of the perturbation. We inject multiple currents and measure a single voltage in order to directly obtain the value of the resistance. The relative accuracy of the device increases exponentially with the number of terminals, and for large resistances outperforms a standard measurement by over an order of magnitude. Our work paves the way towards leveraging non-Hermitian conductance matrices in high-precision sensing.
2308.11367v1
2019-09-12
Analysis of RF losses and material characterization of samples removed from a Nb3Sn-coated superconducting RF cavity
Nb3Sn (Tc ~ 18 K and Hsh ~ 400 mT) is a prospective material to replace Nb (Tc ~ 9 K and Hsh ~ 200 mT) in SRF accelerator cavities for significant cost reduction and performance enhancement. Because of its material properties, Nb3Sn is best employed as a thin film (coating) inside an already built RF cavity structure. A particular test cavity noted as C3C4 was a 1.5 GHz single-cell Nb cavity, coated with Nb3Sn using Sn vapor diffusion process at Jefferson Lab. Cold measurements of the coated cavity indicated the superconducting transition temperature of about 18 K. Subsequent RF measurements indicated field-dependent surface resistance both at 4.3 K and 2.0 K. After initial cold measurements, the cavity RF loss distribution was studied with a thermometry mapping system. Loss regions were identified with thermometry and were cut out for material analysis. The presence of significantly thin patchy regions and other carbon-rich defects is associated with strong local field-dependent surface resistance. This paper summarizes RF and thermometry results correlated with material science findings.
1909.05695v1
2020-02-27
A simple approach to bulk bioinspired tough ceramics
The development of damage-resistant structural materials that can withstand harsh environments is a major issue in materials science and engineering. Bioinspired brick-and-mortar designs have recently demonstrated a range of interesting mechanical properties in proof-of-concept studies. However, reproducibility and scalability issues associated with the actual processing routes have impeded further developments and industrialization of such materials. Here we demonstrate a simple approach based on uniaxial pressing and field assisted sintering of commercially available raw materials to process bioinspired ceramic/ceramic composites of larger thickness than previous approaches, with a sample thickness up to 1 cm. The ceramic composite retains the strength typical of dense alumina ($430~\pm 30MPa$) while keeping the excellent damage resistance demonstrated previously at the millimeter scale with a crack initiation toughness of $6.6MPa.m^{1/2}$ and fracture toughness up to $17.6 MPa.m^{1/2}$. These results validate the potential of these all-ceramic composites, previously demonstrated at lab scale only, and could enable their optimization, scale-up, and industrialization.
2003.11898v1
2021-10-09
Fracture Diodes: Directional asymmetry of fracture toughness
Toughness describes the ability of a material to resist fracture or crack propagation. It is demonstrated here that fracture toughness of a material can be asymmetric, i.e., the resistance of a medium to a crack propagating from right to left can be significantly different from that to a crack propagating from left to right. Such asymmetry is unknown in natural materials, but we show that it can be built into artificial materials through the proper control of microstructure. This paves the way for control of crack paths and direction, where fracture -- when unavoidable -- can be guided through pre-designed paths to minimize loss of critical components.
2110.04613v1
2022-07-20
Do thermoelectric generator modules degrade due to nickel diffusion
The paper shows by calculation that the diffusion of nickel even for 50 years does not lead to degradation of thermoelectric generator modules. In the process, we used the theory of composites to calculate the electrical contact resistance, our own diffusion theory of electrical contact resistance, as well as the method for approximating the temperature dependences of thermoelectric material characteristics from the experimental data. When using the above method, it was assumed that the main mechanism of scattering of free charge carriers in a thermoelectric material is their scattering on the deformation potential of acoustic phonons with a free path length independent of energy but inversely proportional to temperature, and the main mechanism of phonon scattering is phonon-phonon scattering with Umklapp, which is not affected by the nickel impurity in the thermoelectric material. Thus, it was believed that the role of nickel is reduced only to a change in the concentration of free charge carriers in the material.
2207.12122v1
2023-03-10
Engineering heat transport across epitaxial lattice-mismatched van der Waals heterointerfaces
Artificially engineered 2D materials offer unique physical properties for thermal management, surpassing naturally occurring materials. Here, using van der Waals epitaxy, we demonstrate the ability to engineer extremely insulating ultra-thin thermal metamaterials based on crystalline lattice-mismatched Bi2Se3/MoSe2 superlattices and graphene/PdSe2 heterostructures with exceptional thermal resistances (70-202 m^2K/GW) and ultralow cross-plane thermal conductivities (0.01-0.07 Wm^-1K^-1) at room temperature, comparable to those of amorphous materials. Experimental data obtained using frequency-domain thermoreflectance and low-frequency Raman spectroscopy, supported by tight-binding phonon calculations, reveal the impact of lattice mismatch, phonon-interface scattering, size effects, temperature and interface thermal resistance on cross-plane heat dissipation, uncovering different thermal transport regimes and the dominant role of long-wavelength phonons. Our findings provide essential insights into emerging synthesis and thermal characterization methods and valuable guidance for the development of large-area heteroepitaxial van der Waals films of dissimilar materials with tailored thermal transport characteristics.
2303.05808v1
2023-09-25
Integrated bolometric photodetectors based on transparent conductive oxides from near- to mid-infrared wavelengths
On-chip photodetectors are essential components in optical communications as they convert light into an electrical signal. Photobolometers are type of photodetector that functions through a resistance change caused by electronic temperature fluctuations upon light absorption. They are widely used in the broad wavelength range from UV to MIR and can operate on a wide material platform. In this work, I introduce a novel waveguide-integrated bolometer that operates in a wide wavelength range from NIR to MIR on the standard material platform with the transparent conductive oxides (TCOs) as the active material. This material platform enables the construction of both modulators and photodetectors using the same material, which is fully CMOS compatible and easily integrated with passive on-chip components. The photobolometers proposed here consist of a thin TCO layer placed inside the rib photonic waveguide to enhance light absorption and then heat the electrons in the TCO to temperatures above 1000 K. This rise in electron temperature leads to decreasing electron mobility and consequential electrical resistance change. In consequence, a responsivity exceeding 10 A/W can be attained with a mere few microwatts of optical input power. Calculations suggest that further improvements can be expected with lower doping of the TCO, thus opening new doors in on-chip photodetectors.
2309.14454v1
2023-10-04
Current-driven magnetic resistance in van der Waals spin-filter antiferromagnetic tunnel junctions with MnBi$_2$Te$_4$
The field of 2D magnetic materials has paved the way for the development of spintronics and nanodevices with new functionalities. Utilizing antiferromagnetic materials, in addition to layered van der Waals (vdW) ferromagnetic materials, has garnered significant interest. In this work, we present a theoretical investigation of the behavior of MnBi$_2$Te$_4$ devices based on the non-equilibrium Green's function method. Our results show that the current-voltage (I-V) characteristics can be influenced significantly by controlling the length of the device and bias voltage and thus allow us to manipulate the tunneling magneto-resistance (TMR) with an external bias voltage. This can be further influenced by the presence of the boron nitride layer which shows significantly enhanced TMR by selectively suppressing specific spin channels for different magnetic configurations. By exploiting this mechanism, the observed TMR value reaches up to 3690\%, which can be attributed to the spin-polarized transmission channel and the projected local density of states. Our findings on the influence of structural and magnetic configurations on the spin-polarized transport properties and TMR ratios give the potential implementation of antiferromagnetic vdW layered materials in ultrathin spintronics.
2310.02830v1