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2023-04-03
CVD Graphene Contacts for Lateral Heterostructure MoS${_2}$ Field Effect Transistors
Intensive research is carried out on two-dimensional materials, in particular molybdenum disulfide, towards high-performance transistors for integrated circuits. Fabricating transistors with ohmic contacts is challenging due to the high Schottky barrier that severely limits the transistors' performance. Graphene-based heterostructures can be used in addition or as a substitute for unsuitable metals. We present lateral heterostructure transistors made of scalable chemical vapor-deposited molybdenum disulfide and chemical vapor-deposited graphene with low contact resistances of about 9 k${\Omega}$${\mu}$m and high on/off current ratios of 10${^8}$. We also present a theoretical model calibrated on our experiments showing further potential for scaling transistors and contact areas into the few nanometers range and the possibility of a strong performance enhancement by means of layer optimizations that would make transistors promising for use in future logic circuits.
2304.01177v2
2023-09-21
Superconductivity in Compositionally-Complex Cuprates with the YBa$_2$Cu$_3$O$_{7-x}$ Structure
High-temperature superconductivity is reported in a series of compositionally-complex cuprates with varying degrees of size and spin disorder. Three compositions of Y-site alloyed YBa$_2$Cu$_3$O$_{7-x}$, i.e., (5Y)BCO, were prepared using solid-state methods with different sets of rare earth ions on the Y-site. Synchrotron X-ray diffraction and energy-dispersive X-ray spectroscopy confirm these samples have high phase-purity and homogeneous mixing of the Y-site elements. The superconducting phase transition was probed using electrical resistivity and AC magnetometry measurements, which reveal the transition temperature, T$_C$, is greater than 91 K for all series when near optimal oxygen doping. Importantly, these T$_C$ values are only $\approx$1$\%$ suppressed relative to pure YBCO (T$_C$ = 93 K). This result highlights the robustness of pairing in the YBCO structure to specific types of disorder. In addition, the chemical flexibility of compositionally-complex cuprates allows spin and lattice disorder to be decoupled to a degree not previously possible in high-temperature superconductors. This feature makes compositionally-complex cuprates a uniquely well-suited materials platform for studying proposed pairing interactions in cuprates.
2309.12535v1
2023-12-11
Local laser-induced solid-phase recrystallization of phosphorus-implanted Si/SiGe heterostructures for contacts below 4.2 K
Si/SiGe heterostructures are of high interest for high mobility transistor and qubit applications, specifically for operations below 4.2 K. In order to optimize parameters such as charge mobility, built-in strain, electrostatic disorder, charge noise and valley splitting, these heterostructures require Ge concentration profiles close to mono-layer precision. Ohmic contacts to undoped heterostructures are usually facilitated by a global annealing step activating implanted dopants, but compromising the carefully engineered layer stack due to atom diffusion and strain relaxation in the active device region. We demonstrate a local laser-based annealing process for recrystallization of ion-implanted contacts in SiGe, greatly reducing the thermal load on the active device area. To quickly adapt this process to the constantly evolving heterostructures, we deploy a calibration procedure based exclusively on optical inspection at room-temperature. We measure the electron mobility and contact resistance of laser annealed Hall bars at temperatures below 4.2 K and obtain values similar or superior than that of a globally annealed reference samples. This highlights the usefulness of laser-based annealing to take full advantage of high-performance Si/SiGe heterostructures.
2312.06267v1
2023-03-13
Unusual magnetotransport and anomalous Hall effect in quasi-two-dimensional van der Waals ferromagnet Fe$_4$GeTe$_2$
Fe$_4$GeTe$_2$, an itinerant vdW ferromagnet (FM) having Curie temperature (T$_C$) close to room temperature ($\sim 270$ K), exhibits another transition (T$_{SR}$ $\sim$ 120 K) where the easy axis of magnetization changes from in-plane to the out-of-plane direction in addition to T$_C$. Here, we have studied the magnetotransport in a multilayer Hall bar device fabricated on 300 nm Si/SiO$_2$ substrate. Interestingly, the zero field resistivity shows a negligible change in resistivity near T$_C$ unlike the typical metallic FM, whereas, it exhibits a dramatic fall below T$_{SR}$. Also, the resistivity shows a weak anomaly at T $ \sim $ 38 K (T$_Q$), below which the resistivity shows a quadratic temperature dependence according to the Fermi liquid behavior. Temperature-dependent Hall data exhibits important consequences. The ordinary Hall coefficient changes sign near T$_{SR}$ indicating the change in majority carriers. In a similar manner, the magnetoresistance (MR) data shows significantly large negative MR near T$_{SR}$ and becomes positive below T$_Q$. The observations of anomaly in the resistivity, sign-change of the ordinary Hall coefficient and maximum negative MR near T$_{SR}$, together suggest a possible Fermi surface reconstruction associated with the spin reorientation transition. Furthermore, analysis of the Hall data reveals a significant anomalous Hall conductivity (AHC) from $\sim 123 \Omega^{-1}$ cm$^{-1}$ (at T $\approx$ 5 K) to the maximum value of $\sim 366 \Omega^{-1}$ cm$^{-1}$ near T$_{SR}$. While the low-temperature part may originate due to the intrinsic KL mechanism, our analysis indicates that the temperature-dependent AHC is primarily appearing due to the side-jump mechanism as a result of the spin-flip electron-magnon scattering. Our study demonstrates an interplay between magnetism and band topology and its consequence on electron transport in Fe$_4$GeTe$_2$.
2303.07440v1
2020-03-04
Adaptive phase field modelling of crack propagation in orthotropic functionally graded materials
In this work, we extend the recently proposed adaptive phase field method to model fracture in orthotropic functionally graded materials (FGMs). A recovery type error indicator combined with quadtree decomposition is employed for adaptive mesh refinement. The proposed approach is capable of capturing the fracture process with a localized mesh refinement that provides notable gains in computational efficiency. The implementation is validated against experimental data and other numerical experiments on orthotropic materials with different material orientations. The results reveal an increase in the stiffness and the maximum force with increasing material orientation angle. The study is then extended to the analysis of orthotropic FGMs. It is observed that, if the gradation in fracture properties is neglected, the material gradient plays a secondary role, with the fracture behaviour being dominated by the orthotropy of the material. However, when the toughness increases along the crack propagation path, a substantial gain in fracture resistance is observed.
2003.04689v1
2020-09-04
Impact of interfaces on the radiation response and underlying defect recovery mechanisms in nanostructured Cu-Fe-Ag
Newest developments in nuclear fission and fusion technology as well as planned long-distance space missions demand novel materials to withstand harsh, irradiative environments. Radiation-induced hardening and embrittlement are a concern that can lead to failure of materials deployed in these applications. Here the underlying mechanisms are accommodation and clustering of lattice defects created by the incident radiation particles. Interfaces, such as free surfaces, phase and grain boundaries, are known for trapping and annihilating defects and therefore preventing these radiation-induced defects from forming clusters. In this work, differently structured nanocomposite materials based on Cu-Fe-Ag were fabricated using a novel solid-state route, combining severe plastic deformation with thermal and electrochemical treatments. The influence of different interface types and spacings on radiation effects in these materials was investigated using nanoindentation. Interface-rich bulk nanocomposites showed a slight decrease in hardness after irradiation, whereas the properties of a nanoporous material remain mostly unchanged. An explanation for this different material behavior and its link to recovery mechanisms at interfaces is attempted in this work, paving a concept towards radiation resistant materials.
2009.02039v1
2021-03-05
Effect of spoke design and material nonlinearity on non-pneumatic tire stiffness and durability performance
Non-pneumatic tire has been widely used due to their advantages of no run-flat, no need of air maintenance, low rolling resistance, and improvement of passengers comfort due to its better shock absorption. It has variety of application in the military vehicle, earthmovers, lunar rover, stair climbing vehicles etc. Recently UPTIS (Unique Puncture-Proof Tire System) non pneumatic tire has been introduced for passenger vehicles. In this study three different design configuration Tweel, Honeycomb and newly developed UPTIS have been compared. Effect of Polyurethane (PU) material nonlinearity have also been introduced by applying 5 different nonlinear PU material property in the spokes. The combined analysis of the PU material nonlinearity and spoke design configuration on the overall tire stiffness and spoke damage prediction is analysed using 3-Dimensional FEM simulations performed in ANSYS 16.0. It has been observed that Mooney Rivlin 5-parameter model is best to capture all 5 studied PU materials the nonlinearity. Effect of material nonlinearity on various spoke designs have been studied. The best combination of spoke design and the use of nonlinear material have been suggested in terms of riding comfort, tire stiffness and durability performance.
2103.03637v1
2023-01-24
Seebeck-driven transverse thermoelectric generation in magnetic hybrid bulk materials
The Seebeck-driven transverse thermoelectric generation in magnetic/thermoelectric hybrid materials (STTG) has been investigated in all-bulk hybrid materials. The transverse thermopower in a ferromagnetic Co$_2$MnGa/thermoelectric $n$-type Si hybrid bulk material with the adjusted dimensions reaches 16.0 $\mu$V/K at room temperature with the aid of the STTG contribution, which is much larger than the anomalous Nernst coefficient of the Co$_2$MnGa slab (6.8 $\mu$V/K). Although this transverse thermopower is smaller than the value for previously reported thin-film-based hybrid materials, the hybrid bulk materials exhibit much larger electrical power owing to their small internal resistance. This demonstration confirms the validity of STTG in bulk materials and clarifies its potential as a thermal energy harvester.
2301.09903v1
2023-01-24
Accelerate & Actualize: Can 2D Materials Bridge the Gap Between Neuromorphic Hardware and the Human Brain?
Two-dimensional (2D) materials present an exciting opportunity for devices and systems beyond the von Neumann computing architecture paradigm due to their diversity of electronic structure, physical properties, and atomically-thin, van der Waals structures that enable ease of integration with conventional electronic materials and silicon-based hardware. All major classes of non-volatile memory (NVM) devices have been demonstrated using 2D materials, including their operation as synaptic devices for applications in neuromorphic computing hardware. Their atomically-thin structure, superior physical properties, i.e., mechanical strength, electrical and thermal conductivity, as well as gate-tunable electronic properties provide performance advantages and novel functionality in NVM devices and systems. However, device performance and variability as compared to incumbent materials and technology remain major concerns for real applications. Ultimately, the progress of 2D materials as a novel class of electronic materials and specifically their application in the area of neuromorphic electronics will depend on their scalable synthesis in thin-film form with desired crystal quality, defect density, and phase purity.
2301.10277v1
2023-07-19
Emergence of high-temperature superconducting phase in the pressurized La3Ni2O7 crystals
The recent report of pressure-induced structure transition and signature of superconductivity with Tc = 80 K above 14 GPa in the La3Ni2O7 crystals has garnered considerable attention. To further elaborate this discovery, we carried out comprehensive resistance measurements on the La3Ni2O7 crystals grown with the optical-image floating zone furnace under oxygen pressure (15 bar) by using the diamond anvil cell (DAC) and cubic anvil cell (CAC), which employs the solid and liquid pressure transmitting medium, respectively. For the sample #1 measured in DAC, it exhibits a semiconducting-like behavior with large resistance at low pressures and becomes metallic gradually upon compression. At the pressures P >= 13.7 GPa, we observed the appearance of resistance drop as large as ~50% around 70 K, which evolves into a kink-like anomaly at pressures above 40 GPa and shifts to lower temperatures gradually with increasing magnetic field. These observations are consistent with the recent report mentioned above. On the other hand, the sample #2 measured in CAC retains the metallic behavior in the investigated pressure range up to 15 GPa. The hump-like anomaly in resistance around ~130 K at ambient pressure disappears at P >= 2 GPa. In the pressure range from 11 to 15 GPa, we observed the gradual development of a shoulder-like anomaly in resistance at low temperatures, which evolves into a pronounced drop of resistance by 98% below 62 K at 15 GPa, reaching a temperature-independent resistance of 20 uOhm below 20 K. Similarly, this resistance anomaly can be shifted to lower temperatures progressively by applying external magnetic fields, resembling a typical superconducting transition.
2307.09865v1
2023-07-27
High-temperature superconductivity with zero-resistance and strange metal behavior in La$_{3}$Ni$_{2}$O$_{7-δ}$
Recently signatures of superconductivity were observed close to 80 K in \LN\ under pressure. This discovery positions \LN\ as the first bulk nickelate with high-temperature superconductivity, but the lack of zero resistance presents a significant drawback for validating the findings. Here we report pressure measurements up to over 30 GPa using a liquid pressure medium and show that single crystals of \LNO\ do exhibit zero resistance. We find that \LNO\ remains metallic under applied pressures, suggesting the absence of a metal-insulator transition proximate to the superconductivity. Analysis of the normal state $T$-linear resistance suggests an intricate link between this strange metal behaviour and superconductivity, whereby at high pressures both the linear resistance coefficient and superconducting transition are slowly suppressed by pressure, while at intermediate pressures both the superconductivity and strange metal behaviour appear disrupted, possibly due to a nearby structural instability. The association between strange metal behaviour and high-temperature superconductivity is very much in line with diverse classes of unconventional superconductors, including the cuprates and Fe-based superconductors. Understanding the superconductivity of \LNO\ evidently requires further revealing the interplay of strange metal behaviour, superconductivity, as well as possible competing electronic or structural phases.
2307.14819v2
2023-08-04
Stopping microfluidic flow
We present a cross-comparison of three stop-flow configurations--such as low-pressure (LSF), high-pressure open-circuit (OC-HSF), and high-pressure short-circuit (SC-HSF) stop-flow--to rapidly bring a high flow velocity within a microchannel to a standstill. The average velocities inside the microchannels were reduced from > 1 m/s to < 10 um/s within 2s of initiating the stop-flow. The performance of the three stop-flow configurations was assessed by measuring the residual flow velocities within microchannels having three orders-of-magnitude different flow resistances. The LSF configuration outperformed the OC-HSF and SC-HSF configurations within the high flow resistance microchannel, and resulted in a residual velocity of < 10 um/s. The OC-HSF configuration resulted in a residual velocity of < 150 um/s within a low flow resistance microchannel. The SC-HSF configuration resulted in a residual velocity of < 200 um/s across the three orders-of-magnitude different flow resistance microchannels, and < 100 um/s for the low flow resistance channel. We hypothesized that the residual velocity resulted from the compliance in the fluidic circuit, which was further investigated by varying the elasticity of the microchannel walls and the connecting tubing. A numerical model was developed to estimate the expanded volumes of the compliant microchannel and connecting tubings under a pressure gradient and to calculate the distance traveled by the sample fluid. A comparison of the numerically and experimentally obtained traveling distances confirmed our hypothesis that the residual velocities were an outcome of the compliance in the fluidic circuit. Therefore, a configuration with minimal fluidic circuit compliance resulted in the least residual velocity.
2308.02386v2
2009-06-02
The Evolution of Gas Clouds Falling in the Magnetized Galactic Halo: High Velocity Clouds (HVCs) Originated in the Galactic Fountain
In the Galactic fountain scenario, supernovae and/or stellar winds propel material into the Galactic halo. As the material cools, it condenses into clouds. By using FLASH three-dimensional magnetohydrodynamic simulations, we model and study the dynamical evolution of these gas clouds after they form and begin to fall toward the Galactic plane. In our simulations, we assume that the gas clouds form at a height of z=5 kpc above the Galactic midplane, then begin to fall from rest. We investigate how the cloud's evolution, dynamics, and interaction with the interstellar medium (ISM) are affected by the initial mass of the cloud. We find that clouds with sufficiently large initial densities (> 0.1 hydrogen atoms per cc) accelerate sufficiently and maintain sufficiently large column densities as to be observed and identified as high-velocity clouds (HVCs) even if the ISM is weakly magnetized (1.3 micro Gauss). We also investigate the effects of various possible magnetic field configurations. As expected, the ISM's resistance is greatest when the magnetic field is strong and perpendicular to the motion of the cloud. The trajectory of the cloud is guided by the magnetic field lines in cases where the magnetic field is oriented diagonal to the Galactic plane. The model cloud simulations show that the interactions between the cloud and the ISM can be understood via analogy to the shock tube problem which involves shock and rarefaction waves. We also discuss accelerated ambient gas, streamers of material ablated from the clouds, and the cloud's evolution from a sphere-shaped to a disk- or cigar-shaped object.
0906.0613v1
2018-10-30
THz-TDS time-trace analysis for the extraction of material and metamaterial parameters
We report on a method and an associated open source software, Fit@TDS, working on an average personal computer. The method is based on the fitting of a time-trace data of a terahertz time-domain-spectroscopy system enabling the retrieval of the refractive index of a dielectric sample and the resonance parameters of a metasurface (quality factor, absorption losses, etc.). The software includes commonly used methods where the refractive index is extracted from frequency domain data. However, these methods are limited, for instance in case of a high noise level or when an absorption peak saturates the absorption spectrum bringing the signal to the noise level. Our software allows to use a new method where the refractive indices are directly fitted from the time-trace. The idea is to model a material or a metamaterial through parametric physical models (Drude-Lorentz model and time-domain coupled mode theory) and to implement the subsequent refractive index in the propagation model to simulate the time-trace. Then, an optimization algorithm is used to retrieve the parameters of the model corresponding to the studied material/metamaterial. In this paper, we explain the method and test it on fictitious samples to probe the feasibility and reliability of the proposed model. Finally, we used Fit@TDS on real samples of high resistivity silicon, lactose and gold metasurface on quartz to show the capacity of our method
1810.12567v4
2020-05-28
Graphene-TiS$_3$ heterojunction for selective polar vapor sensing at room temperature
In this work, the room temperature polar vapor sensing behavior of two dimentional (2D) heterojunction Graphene-TiS3 materials and TiS3 nanoribbons is investigated. TiS3 nanoribbons were synthesized via chemical vapor transport (CVT) and their structure was investigated by scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), energy dispersive X- ray spectroscopy (EDS), X-ray diffraction (XRD), Raman spectroscopy and Fourier transform infrared spectroscopy (FT-IR) analysis. The gas sensing performance of the TiS3 nanoribbons was assessed through the observed changes in their electronic behavior. Sensing devices were fabricated with gold contacts and with lithographically patterned graphene (Gr) electrodes in a 2D heterojunction Gr-TiS3-Gr architecture.. It is observed that the gold contacted TiS3 device has a rather linear I-V behavior while the Gr-TiS3-Gr heterojunction forms a contact with a higher Schottky barrier (250 meV). I-V responses of the sensors were recorded at room temperature with a relative humidity of 55% and for different ethanol vapor concentrations (varying from 2 to 20 ppm). I-V plots indicated an increase in the resistance of Gr-TiS3-Gr by the adsorption of water and ethanol molecules with relatively high sensing response (~3353% at 2 ppm). Our results reveal that selective and stable responses to a low concentration of ethanol vapor (2 ppm) can be achieved at room temperature with transient response and recovery times of around 6 s and 40 s, respectively. Our proposed design demonstrate a new approach for selective molecular recognition using polar interactions between analyte vapors and heterojunctions of 2D-materials.
2005.14245v1
2022-01-06
A quantitative assessment of Imaging High-Z and Medium-Z materials using Muon Scattering Tomography
Muon Scattering Tomography (MST) has been shown to be a powerful technique for the non-invasive imaging of high-shielded objects. We present here the application of the MST technique to investigate two types of nuclear waste packages, a small-steel drum and a large nuclear waste cask, namely, a CASTOR V/52. We have developed a quantitative method using the contrast-to-noise ratio (CNR) to evaluate the performance of an MST detector system in differentiating between high-, medium-, and low-Z materials inside nuclear waste packages with different shielding types. This study reveals that our MST detector system is able to differentiate between a (10 $\times$ 10 $\times$ 10 cm$^3$) uranium cube, embedded within a concrete matrix inside the small-steel drum, and regions of background signal in six hours of muon exposure time with a CNR value of 3.1$\pm$0.2. During our investigation of the highly-shielded cask, the reconstructed images of the cask contents indicated the ability of our system to detect irregular baskets, such as empty baskets, with a CNR value of 5.0$\pm$0.3 after 30 days of muon exposure. These studies were done using a Monte Carlo simulation tuned to the performance of resistive plate chambers (RPCs) based muon tomography system built by the University of Bristol, which had a reported position resolution of 350 micron. Here we also report the dependence of the performance on the position resolution. We argue that using a combination of RPC and drift chambers (DC) detectors with 700 micron and 4 mm position resolutions respectively is able to generate tomographic images of well-shielded materials in a few hours of muon exposure time. With these position resolutions, our system needs six hours of muon exposure time to produce a good quality image of a cube of uranium with side-length of 10 cm shielded by a concrete matrix with CNR value of 2.4$\pm$0.25.
2201.01877v3
2023-03-07
Stacking disorder and thermal transport properties of $α$-RuCl$_3$
$\alpha$-RuCl$_3$, a well-known candidate material for Kitaev quantum spin liquid, is prone to stacking disorder due to the weak van der Waals bonding between the honeycomb layers. After a decade of intensive experimental and theoretical studies, the detailed correlation between stacking degree of freedom, structure transition, magnetic and thermal transport properties remains unresolved. In this work, we reveal the effects of a small amount of stacking disorder inherent even in high quality $\alpha$-RuCl$_3$ crystals. This small amount of stacking disorder results in the variation of the magnetic ordering temperature, suppresses the structure transition and thermal conductivity. Crystals with minimal amount of stacking disorder have a T$_N>$7.4\,K and exhibit a well-defined structure transition around 140\,K upon cooling. For those with more stacking faults and a T$_N$ below 7\,K, the structure transition occurs well below 140\,K upon cooling and is incomplete, manifested by the diffuse streaks and the coexistence of both high temperature and low temperature phases down to the lowest measurement temperature. Both types of crystals exhibit oscillatory field dependent thermal conductivity and a plateau-like feature in thermal Hall resistivity in the field-induced quantum spin liquid state. However, $\alpha$-RuCl$_3$ crystals with minimal amount of stacking disorder have a higher thermal conductivity that pushes the thermal Hall conductivity to be closer to the half-integer quantized value. These findings demonstrate a strong correlation between layer stacking, structure transition, magnetic and thermal transport properties, underscoring the importance of interlayer coupling in $\alpha$-RuCl$_3$ despite the weak van der Waals bonding.
2303.03682v2
2023-12-27
Combined effect of SiC and carbon on sintering kinetics, microstructure and mechanical properties of fine-grained binderless tungsten carbide
The study investigates the density, phase composition, microstructure and mechanical properties (microhardness, fracture toughness) of binderless WC + SiC and WC + SiC + C ceramics obtained by Spark Plasma Sintering (SPS). Nanopowders of a-WC produced by DC arc plasma chemical synthesis were used as raw materials. Powder compositions for sintering contained graphite (0.3, 0.5% wt.) or b-SiC (1, 3, 5% wt.) with 0.3% wt. graphite. It was shown that WC + 1% wt. SiC + 0.3% wt.C ceramics have a homogeneous fine-grained microstructure, high relative density, increased microhardness and Palmquist fracture toughness (Indentation Fracture Resistance). The kinetics of the initial sintering stage of WC + C and WC + C + SiC powder compositions was also analyzed using high-temperature dilatometry at the conventional pressureless sintering (CPS) conditions. The CPS and SPS activation energies of WC + SiC powder at the intensive shrinkage stage were determined using the Young-Cutler model. The CPS activation energies of WC, WC + C and WC + C + SiC powder compositions are close to the activation energy of diffusion of the carbon C along the a-WC grain boundaries. The SPS activation energies of WC + C and WC+ C + SiC powder compositions turn out to be lower than the activation energy of the C of a-WC grain boundary.
2312.16579v1
2022-07-26
Hysteresis-Free High Mobility Graphene Encapsulated in Tungsten Disulfide
High mobility is a crucial requirement for a large variety of electronic device applications. The state-of-the-art for high quality graphene devices is based on heterostructures made with graphene encapsulated in $>80\,$nm-thick flakes of hexagonal boron nitride (hBN). Unfortunately, scaling up multilayer hBN while precisely controlling the number of layers remains an elusive challenge, resulting in a rough material unable to enhance the mobility of graphene. This leads to the pursuit of alternative, scalable materials, which can be simultaneously used as substrate and encapsulant for graphene. Tungsten disulfide (WS$_2$) is a transition metal dichalcogenide, which was successfully grown in large ($\sim$mm-size) multi-layers by chemical vapour deposition. However, the resistance \textit{vs} gate voltage characteristics when gating graphene through WS$_2$ exhibit largely hysteretic shifts of the charge neutrality point (CNP) in the order of $\Delta n\sim$2.6$\cdot$10$^{11}$ cm$^{-2}$, hindering the use of WS$_2$ as a reliable encapsulant. The hysteresis originates due to the charge traps from sulfur vacancies present in WS$_2$. In this work, we report for the first time the use of WS$_2$ as a substrate and the overcoming of hysteresis issues by chemically treating WS$_2$ with a super-acid, which passivates these vacancies and strips the surface from contaminants. The hysteresis is significantly reduced below the noise level by at least a factor five (to $\Delta n<$5$\cdot$10$^{10}$ cm$^{-2}$) and, simultaneously, the room-temperature mobility of WS$_2$-encapsulated graphene is as high as $\sim$6.2$\cdot$10$^{4}$ cm$^{-2}$V$^{-1}$s$^{-1}$ at a carrier density $n$ $\sim$1$\cdot$ 10$^{12}$ cm$^{-2}$. Our results promote WS$_2$ to a valid alternative to hBN as encapsulant for high-performance graphene devices.
2207.12836v1
2000-06-23
Temperature-Dependence of the Resistivity of a Dilute 2D Electron System in High Parallel Magnetic Field
We report measurements of the resistance of silicon MOSFETs as a function of temperature in high parallel magnetic fields where the 2D system of electrons has been shown to be fully spin-polarized. A magnetic field suppresses the metallic behavior observed in the absence of a magnetic field. In a field of 10.8 T, insulating behavior is found for densities up to n_s approximately 1.35 x 10^{11} cm^{-2} or 1.5 n_c; above this density the resistance is a very weak function of temperature, varying less than 10% between 0.25 K and 1.90 K. At low densities the resistance goes to infinity more rapidly as the temperature is reduced than in zero field and the magnetoresistance diverges as T goes to 0.
0006379v4
2002-10-08
Resistivity of dilute 2D electrons in an undoped GaAs heterostructure
We report resistivity measurements from 0.03 K to 10 K in a dilute high mobility 2D electron system. Using an undoped GaAs/AlGaAs heterojunction in a gated field-effect transistor geometry, a wide range of densities, $0.16 \times 10^{10} {cm}^{-2}$ to $7.5 \times 10^{10} {cm}^{-2}$, are explored. For high densities, the results are quantitatively shown to be due to scattering by acoustic phonons and impurities. In an intermediate range of densities, a peak in the resistivity is observed for temperatures below 1 K. This non-monotonic resistivity can be understood by considering the known scattering mechanisms of phonons, bulk and interface ionized impurities. Still lower densities appear insulating to the lowest temperature measured.
0210155v1
2003-09-11
Superconductivity on the localization threshold and magnetic-field-tuned superconductor-insulator transition in TiN films
Temperature- and magnetic-field dependent measurements of the resistance of ultrathin superconducting TiN films are presented. The analysis of the temperature dependence of the zero field resistance indicates an underlying insulating behavior, when the contribution of Aslamasov-Larkin fluctuations is taken into account. This demonstrates the possibility of coexistence of the superconducting and insulating phases and of a direct transition from the one to the other. The scaling behavior of magnetic field data is in accordance with a superconductor-insulator transition (SIT) driven by quantum phase fluctuations in two-dimensional superconductor. The temperature dependence of the isomagnetic resistance data on the high-field side of the SIT has been analyzed and the presence of an insulating phase was confirmed. A transition from the insulating to a metallic phase is found at high magnetic fields, where the zero-temperature asymptotic value of the resistance being equal to h/e^2.
0309281v2
2003-10-02
Electrical resistivity of the Ti4O7 Magneli phase under high pressure
We have measured resistivity as a function of temperature and pressure of Ti4O7 twinned crystals using different contact configurations. Pressures over 4kbar depress the localization of bipolarons and allow the study of the electrical conduction of the bipolaronic phase down to low temperatures. For pressures P > 40 kbar the bipolaron formation transition is suppressed and a nearly pressure independent behavior is obtained for the resistivity. We observed an anisotropic conduction. When current is injected parallel to the principal axis, a metallic conduction with interacting carrier effects is predominant. A superconducting state was not obtained down to 1.2 K, although evidences of the proximity of a quantum critical point were noticed. While when current is injected non-parallel to the crystal's principal axis, we obtained a logarithmic divergence of the resistivity at low temperatures. For this case, our results for the high pressure regime can be interpreted in the framework of interacting carriers (polarons or bipolarons) scattered by Two Level Systems.
0310048v1
2004-03-17
Interaction Correction to the Longitudinal Conductivity and Hall Resistivity in High Quality Two-Dimensional GaAs Electron and Hole Systems
We present a systematic study of the corrections to both the longitudinal conductivity and Hall resistivity due to electron-electron interactions in high quality GaAs systems using the recent theory of Zala et al. [Phys. Rev. B 64, 214204 (2001)]. We demonstrate that the interaction corrections to the longitudinal conductivity and Hall resistivity predicted by the theory are consistent with each other. This suggests that the anomalous metallic drop in resistivity at B=0 is due to interaction effects and supports the theory of Zala et al.
0403411v1
2005-05-19
Universal scaling behavior of the c-axis resistivity of high-temperature superconductors
We propose and show that the c-axis transport in high-temperature superconductors is controlled by the pseudogap energy and the c-axis resistivity satisfies a universal scaling law in the pseudogap phase. We derived approximately a scaling function for the c-axis resistivity and found that it fits well with the experimental data of Bi$_2$Sr$_2$CaCu$_2$O$_{8+\delta}$, Bi$_2$Sr$_2$Ca$_2$Cu$_3$O$_{10+\delta}$, and YBa$_2$Cu$_3$O$_{7-\delta}$. Our works reveals the physical origin of the semiconductor-like behavior of the c-axis resistivity and suggests that the c-axis hopping is predominantly coherent.
0505480v2
2006-07-27
Effect of DC electric field on longitudinal resistance of two dimensional electrons in a magnetic field
The effect of a DC electric field on the longitudinal resistance of highly mobile two dimensional electrons in heavily doped GaAs quantum wells is studied at different magnetic fields and temperatures. Strong suppression of the resistance by the electric field is observed in magnetic fields at which the Landau quantization of electron motion occurs. The phenomenon survives at high temperature where Shubnikov de Haas oscillations are absent. The scale of the electric fields essential for the effect is found to be proportional to temperature in the low temperature limit. We suggest that the strong reduction of the longitudinal resistance is the result of a nontrivial change in the distribution function of 2D electrons induced by the DC electric field. Comparison of the data with recent theory yields the inelastic electron-electon scattering time $\tau_{in}$ and the quantum scattering time $\tau_q$ of 2D electrons at high temperatures, a regime where previous methods were not successful.
0607741v1
2009-05-07
Correlation between linear resistivity and Tc in organic and pnictide superconductors
A linear temperature dependence of the electrical resistivity as T -> 0 is the hallmark of quantum criticality in heavy-fermion metals and the archetypal normal-state property of high-Tc superconductors, yet in both cases it remains unexplained. We report a linear resistivity on the border of spin-density-wave order in the organic superconductor (TMTSF)2X (X = PF6, ClO4), whose strength scales with the superconducting temperature Tc. This scaling, also present in the pnictide superconductors, reveals an intimate connection between linear-T scattering and pairing, shown by renormalization group theory to arise from antiferromagnetic fluctuations, enhanced by the interference of superconducting correlations. Our results suggest that linear resistivity in general may be a consequence of such interference and pairing in overdoped high-Tc cuprates is driven by antiferromagnetic fluctuations, as in organic and pnictide superconductors.
0905.0964v1
2010-02-25
Signatures of pressure induced superconductivity in insulating Bi2212
We have performed several high pressure electrical resistance experiments on Bi1.98Sr2.06Y0.68Cu2O8, an insulating parent compound of the high-Tc Bi2212 family of copper oxide superconductors. We find a resistive anomaly, a downturn at low temperature, that onsets with applied pressure in the 20-40 kbar range. Through both resistance and magnetoresistance measurements, we identify this anomaly as a signature of induced superconductivity. Resistance to higher pressures decreases Tc, giving a maximum of 10 K. The higher pressure measurements exhibit a strong sensitivity to the hydrostaticity of the pressure environment. We make comparisons to the pressure induced superconductivity now ubiquitous in the iron arsenides.
1002.4672v1
2010-05-10
Analysis and Design of Ultra Thin Electromagnetic Absorbers Comprising Resistively Loaded High Impedance Surfaces
High-Impedance Surfaces (HIS) comprising lossy Frequency Selective Surfaces (FSS) are employed to design thin electromagnetic absorbers. The structure, despite its typical resonant behavior, is able to perform a very wideband absorption in a reduced thickness. Losses in the frequency selective surface are introduced by printing the periodic pattern through resistive inks and hence avoiding the typical soldering of a large number of lumped resistors. The effect of the surface resistance of the FSS and dielectric substrate characteristics on the input impedance of the absorber is discussed by means of a circuital model. It is shown that the optimum value of surface resistance is affected both by substrate parameters (thickness and permittivity) and by FSS element shape. The equivalent circuit model is then used to introduce the working principles of the narrowband and the wideband absorbing structure and to derive the best-suited element for wideband absorption. Finally, the experimental validation of the presented structures is presented.
1005.1553v1
2011-07-05
Resistive Solutions for Pulsar Magnetospheres
The current state of the art in the modeling of pulsar magnetospheres invokes either the vacuum or force-free limits for the magnetospheric plasma. Neither of these limits can simultaneously account for both the plasma currents and the accelerating electric fields that are needed to explain the morphology and spectra of high-energy emission from pulsars. To better understand the structure of such magnetospheres, we combine accelerating fields and force-free solutions by considering models of magnetospheres filled with resistive plasma. We formulate Ohm's Law in the minimal velocity fluid frame and construct a family of resistive solutions that smoothly bridges the gap between the vacuum and the force-free magnetosphere solutions. The spin-down luminosity, open field line potential drop, and the fraction of open field lines all transition between the vacuum and force-free values as the plasma conductivity varies from zero to infinity. For fixed inclination angle, we find that the spin-down luminosity depends linearly on the open field line potential drop. We consider the implications of our resistive solutions for the spin down of intermittent pulsars and sub-pulse drift phenomena in radio pulsars.
1107.0979v2
2011-11-02
Development and Performance of spark-resistant Micromegas Detectors
The Muon ATLAS MicroMegas Activity (MAMMA) focuses on the development and testing of large-area muon detectors based on the bulk-Micromegas technology. These detectors are candidates for the upgrade of the ATLAS Muon System in view of the luminosity upgrade of Large Hadron Collider at CERN (sLHC). They will combine trigger and precision measurement capability in a single device. A novel protection scheme using resistive strips above the readout electrode has been developed. The response and sparking properties of resistive Micromegas detectors were successfully tested in a mixed (neutron and gamma) high radiation field, in a X-ray test facility, in hadron beams, and in the ATLAS cavern. Finally, we introduced a 2-dimensional readout structure in the resistive Micromegas and studied the detector response with X-rays.
1111.0426v1
2011-11-09
Nonequilibrium phenomena in high Landau levels
Developments in the physics of 2D electron systems during the last decade have revealed a new class of nonequilibrium phenomena in the presence of a moderately strong magnetic field. The hallmark of these phenomena is magnetoresistance oscillations generated by the external forces that drive the electron system out of equilibrium. The rich set of dramatic phenomena of this kind, discovered in high mobility semiconductor nanostructures, includes, in particular, microwave radiation-induced resistance oscillations and zero-resistance states, as well as Hall field-induced resistance oscillations and associated zero-differential resistance states. We review the experimental manifestations of these phenomena and the unified theoretical framework for describing them in terms of a quantum kinetic equation. The survey contains also a thorough discussion of the magnetotransport properties of 2D electrons in the linear response regime, as well as an outlook on future directions, including related nonequilibrium phenomena in other 2D electron systems.
1111.2176v3
2011-12-12
Resistivity Calculations for Cuprate Superconductor Systems using an Electronic Phase Separation
The resistivity as function of temperature of high temperature superconductors is very unusual and despite its importance lacks an unified theoretical explanation. It is linear with the temperature for overdoped compounds but it falls more quickly as the doping level decreases, and for weakly doped samples it has a minimum, increases like an insulator before it drops to zero at low temperatures. We show that this overall behavior can be explained by calculations using an electronic phase segregation into two main component phases with low and high densities. The total resistivity is calculated by the various contributions through several random picking processes of the local resistivities and using the Random Resistor Network approach.
1112.2631v1
2017-11-19
Global current circuit structure in a resistive pulsar magnetosphere model
Pulsar magnetospheres have strong magnetic fields and large amounts of plasma. The structures of these magnetospheres are studied using force-free electrodynamics. To understand pulsar magnetospheres, discussions must include their outer region. However, force-free electrodynamics is limited in it does not handle dissipation. Therefore, a resistive pulsar magnetic field model is needed. To break the ideal magnetohydrodynamic (MHD) condition $E \cdot B = 0$, Ohm's law is used. In this work, I introduce resistivity depending upon the distance from the star and obtain a self-consistent steady state by time integration. Poloidal current circuits form in the magnetosphere while the toroidal magnetic-field region expands beyond the light cylinder and the Poynting flux radiation appears. High electric resistivity causes a large space scale poloidal current circuit and the magnetosphere radiates a larger Poynting flux than the linear increase outside of the light cylinder radius. The formed poloidal current circuit has width, which grows with the electric conductivity. This result contributes to a more concrete dissipative pulsar magnetosphere model.
1711.07471v1
2018-10-10
Test particles in relativistic resistive magnetohydrodynamics
The Black Hole Accretion Code (BHAC) has recently been extended with the ability to evolve charged test particles according to the Lorentz force within resistive relativistic magnetohydrodynamics simulations. We apply this method to evolve particles in a reconnecting current sheet that forms due to the coalescence of two magnetic flux tubes in 2D Minkowski spacetime. This is the first analysis of charged test particle evolution in resistive relativistic magnetohydrodynamics simulations. The energy distributions of an ensemble of 100.000 electrons are analyzed, as well as the acceleration of particles in the plasmoids that form in the reconnection layer. The effect of the Lundquist number, magnetization, and plasma-$\beta$ on the particle energy distribution is explored for a range of astrophysically relevant parameters. We find that electrons accelerate to non-thermal energies in the thin current sheets in all cases. We find two separate acceleration regimes: An exponential increase of the Lorentz factor during the island coalescence where the acceleration depends linearly on the resistivity and a nonlinear phase with high variability. These results are relevant for determining energy distributions and acceleration sites obtaining radiation maps in large-scale magnetohydrodynamics simulations of black hole accretion disks and jets.
1810.04323v2
2019-07-07
First demonstration of 200, 100, and 50 um pitch Resistive AC-Coupled Silicon Detectors (RSD) with 100% fill-factor for 4D particle tracking
We designed, produced, and tested RSD (Resistive AC-Coupled Silicon Detectors) devices, an evolution of the standard LGAD (Low-Gain Avalanche Diode) technology where a resistive n-type implant and a coupling dielectric layer have been implemented. The first feature works as a resistive sheet, freezing the multiplied charges, while the second one acts as a capacitive coupling for readout pads. We succeeded in the challenging goal of obtaining very fine pitch (50, 100, and 200 um) while maintaining the signal waveforms suitable for high timing and 4D-tracking performances, as in the standard LGAD-based devices.
1907.03314v3
2020-09-01
On resistive spiking of fungi
We study long-term electrical resistance dynamics in mycelium and fruit bodies of oyster fungi P. ostreatus. A nearly homogeneous sheet of mycelium on the surface of a growth substrate exhibits trains of resistance spikes. The average width of spikes is c.~23~min and the average amplitude is c.~1~kOhm. The distance between neighbouring spikes in a train of spikes is c.~30~min. Typically there are 4-6 spikes in a train of spikes. Two types of resistance spikes trains are found in fruit bodies: low frequency and high amplitude (28~min spike width, 1.6~kOhm amplitude, 57~min distance between spikes) and high frequency and low amplitude (10~min width, 0.6~kOhm amplitude, 44~min distance between spikes). The findings could be applied in monitoring of physiological states of fungi and future development of living electronic devices and sensors.
2009.00292v1
2020-09-21
Contact resistance assessment and high-frequency performance projection of black phosphorus field-effect transistor technologies
In this work, an evaluation of the contact quality of black phosphorus (BP) field-effect transistors (FETs) from different technologies previously reported is performed by means of an efficient and reliable contact resistance extraction methodology based on individual device practical characteristics. A good agreement is achieved between the extracted values with the Y-function method used here and reference values obtained with other methods considering internal values as well as with more expensive methods involving fabricated test structures. The method enables a direct evaluation of different steps in the same technology and it embraces the temperature dependence of the contact characteristics. Channel phenomena have no impact on the extracted contact resistance values. High-frequency performance projections are obtained for fabricated devices based on the extracted contact resistance.
2009.09661v3
2012-06-25
Performances of silicone coated high resistive bakelite RPC
Performances of several single gap (gas gap 2 mm) prototype Resistive Plate Chambers (RPC) made of high resistive ({\rho} \sim 1010 - 1012 {\Omega} cm) bakelite, commercially available in India have been studied in recent times. To make the inner electrode surfaces smooth, a thin coating of silicone has been applied. An efficiency > 90% and time resolution \sim 2 ns (FWHM) have been obtained for both the streamer and the avalanche mode. The induced charge distributions of those silicone coated RPC are studied and the results are presented. A numerical study on the effect of surface roughness of the resistive electrodes on the electric field of the device has been carried out using Garfield-neBEM code. A few results for a simplified model representing surface roughness, measured using a surface profilometer for the bakelite surfaces, have also been presented.
1206.5627v1
2022-08-18
Observation of Fermi liquid phase with broken symmetry in a single crystalline nanorod of Pr$_2$Ir$_2$O$_7$
We report experimental evidence of emergent broken symmetry Fermi liquid state in an isolated single crystalline nanorod of $\rm Pr_2 Ir_2 O_7$. We find clear signature of the onset of the Fermi liquid behavior at low temperature marked by the sign inversion of magnetoresistance from negative at high temperature, characteristic of incoherent Kondo scattering, to positive as well as a $\rm T^2$ dependence of resistivity at low temperature. A resistive anomaly is observed, which is accompanied by thermal hysteresis in the presence of magnetic field, suggesting itinerant metamagnetism. The observed high field negative magnetoresistance with quadratic field dependence at low temperature, which is most likely due to suppression of itinerant spin fluctuation, and the irreversibility of the magneto-resistive properties in the Fermi liquid regime suggest existence of an unusual state with broken spin rotation and time reversal symmetry, hallmark of `hastatic' order. The major features of such temperature dependence of resistivity and magnetoresistance can be explained in a phenomenological model incorporating two distinct hybridization channels, which is physically consistent with the possibility of the formation of the `hastatic' Fermi liquid phase.
2208.08811v1
2022-09-16
Prediction of Cross-Fitness for Adaptive Evolution to Different Environmental Conditions: Consequence of Phenotypic Dimensional Reduction
How adaptive evolution to one environmental stress improves or suppresses adaptation to another is an important problem in evolutionary biology. For instance, in microbiology, the evolution of bacteria to be resistant to different antibiotics is a critical issue that has been investigated as cross-resistance. In fact, recent experiments on bacteria have suggested that the cross-resistance of their evolution to various stressful environments can be predicted by the changes to their transcriptome upon application of stress. However, there are no studies so far that explain a possible theoretical relationship between cross-resistance and changes in the transcriptome, which causes high-dimensional changes to cell phenotype. Here, we show that a correlation exists between fitness change in stress tolerance evolution and response to the environment, using a cellular model with a high-dimensional phenotype and establishing the relationship theoretically. The present results allow for the prediction of evolution from transcriptome information in response to different stresses before evolution. The relevance of this to microbiological evolution experiments is discussed.
2209.07756v2
2023-09-29
Pressure-induced superconductivity in polycrystalline La3Ni2O7
We synthesized polycrystalline La3Ni2O7 samples by using the sol-gel method without post-annealing under high oxygen pressure, and then measured temperature-dependent resistivity under various hydrostatic pressures up to 14.5 GPa in a cubic anvil cell apparatus. We find that the density-wave-like anomaly in resistivity is progressively suppressed with increasing pressure and the resistivity drop corresponding to the onset of superconductivity emerges at pressure as low as 7 GPa. Zero resistivity is achieved at 9 GPa below 6.6 K, which increases quickly with pressure to 35.6 K at 14.5 GPa. The observation of zero-resistance state in the polycrystalline La3Ni2O7 samples under high pressures not only corroborates the recent report of superconductivity in the pressurized La3Ni2O7 crystals but also facilitates further studies on this emerging family of nickelate high-Tc superconductors.
2309.17378v2
2005-10-12
Magnetodielectric effect without multiferroic coupling
The existence of a magnetodielectric (magnetocapacitance) effect is often used as a test for multiferroic behavior in new material systems. However, strong magnetodielectric effects can also be achieved through a combination of magnetoresistance and the Maxwell-Wagner effect, unrelated to multiferroic coupling. The fact that this resistive magnetocapacitance does not require multiferroic materials may be advantageous for some practical applications. Conversely, it also implies that magnetocapacitance per se is not sufficient to establish multiferroic coupling.
0510313v1
2007-09-24
External Control of a Metal-Insulator Transition in GaMnAs Wires
Quantum transport in disordered ferromagnetic (III,Mn)V semiconductors is studied theoretically. Mesoscopic wires exhibit an Anderson disorder-induced metal-insulator transition that can be controlled by a weak external magnetic field. This metal-insulator transition should also occur in other materials with large anisotropic magneto resistance effects. The transition can be useful for studies of zero-temperature quantum critical phase transitions and fundamental material properties.
0709.3847v2
2008-01-28
Evidence for hyperconductivity and thermal superconductivity
Physical explanation of hyperconductivity and thermal superconductivity existence is done in given article on the basis of inherent atomic nuclei oscillations in atoms of materials which are connected with electrons and phonons and in accordance with the well known Bardeen-Cooper-Schrieffer superconductivity theory. It is shown that hyperconductivity is the self-supporting, independent physical phenomenon which is caused by oscillations of atomic nuclei in atoms of materials and the minimal temperature of its existence does not reach absolute zero temperature. Hyperconductivity represents the typical dynamic condition of a material with zero electrical and zero thermal resistances.
0801.4212v1
2009-11-24
The possible superconductivity at 109 K in YBaCuO materials
The new YBaCuO superconductors are synthesized by using the standard solid state reaction method as Y5-6-11, Y7-9-16, Y5-8-13, Y7-11-18, Y156, Y3-8-11, and Y13-20-23. We find that all material obtained are shown the Meissner effect at 77 K. The resistivity measurements are used by the four-probe method .The Y 7-11-18 has the highest onset as 109 K . The XRD spectra are shown that they have the same crystal structure as Y123 with some impurities peaks .
0911.4524v1
2012-12-20
Thermoelectricity in ternary rare-earth systems
Crystallographic data, Seebeck coefficient, electrical resistance and thermal conductivity are reported for a large number of rare-earth compounds, manifestations of the Kondo effect being discussed. In more detail, thermoelectric properties of Yb3Co4Ge13 and Yb3Co4Sn13 compounds and Yb2CeCo4Ge13 and Yb2.3La0.7Co4Ge13 solid solutions are presented.
1212.4995v1
2015-05-07
Computer modelling of hafnium doping in lithium niobate
Lithium niobate, LiNbO3, is an important technological material with good electro-optic, acousto-optic, elasto-optic, piezoelectric and nonlinear properties. Doping LiNbO3 with hafnium, Hf has been shown to improve the resistance of the material to optical damage. Computer modelling provides a useful means of determining the properties of doped and undoped LiNbO3, including its defect chemistry, and the effect of doping on the structure. In this paper, Hf doped LiNbO3 has been modelled, and the final defect configurations are found to be consistent with experimental results.
1505.01661v2
2022-11-24
Anisotropic magnetoresistance: materials, models and applications
Resistance of certain (conductive and otherwise isotropic) ferromagnets turns out to exhibit anisotropy with respect to the direction of magnetisation: R$_\parallel$ different from R$_\perp$ with reference to the electric current direction. This century-old phenomenon is reviewed both from the perspective of materials and physical mechanisms involved. More recently, this effect has also been extended to antiferromagnets. This opens the possibility for industrial applications reaching far beyond the current ones, e.g. hard drive read heads or position sensors.
2212.03700v2
2024-05-15
The Detection of Unconventional Quantum Oscillations in Insulating 2D Materials
In strongly correlated quantum materials, electrons behave in ways that often extend beyond the confines of conventional Fermi-liquid theory. Interesting results include the observation of low-temperature metallic behavior in systems that are highly resistive. Here we provide an overview of experiments in which insulators exhibit characteristics of a metal such as the Shubnikov de Haas like quantum oscillations, focusing on recent findings in the correlated insulating states of two-dimensional WTe2. We discuss the status of current research, clarify the debates and challenges in interpreting the experiments, rule out extrinsic explanations and discuss promising future directions.
2405.09666v2
1998-06-30
Transport, optical and electronic properties of the half metal CrO2
The electronic structure of CrO_2 is critically discussed in terms of the relation of existing experimental data and well converged LSDA and GGA calculations of the electronic structure and transport properties of this half metal magnet, with a particular emphasis on optical properties. We find only moderate manifestations of many body effects. Renormalization of the density of states is not large and is in the typical for transition metals range. We find substantial deviations from Drude behavior in the far-infrared optical conductivity. These appear because of the unusually low energy of interband optical transitions. The calculated mass renormalization is found to be rather sensitive to the exchange-correlation functional used and varies from 10% (LSDA) to 90% (GGA), using the latest specific heat data. We also find that dressing of the electrons by spin fluctuations, because of their high energy, renormalizes the interband optical transition at as high as 4 eV by about 20%. Although we find no clear indications of strong correlations of the Hubbard type, strong electron-magnon scattering related to the half metallic band structure is present and this leads to a nontrivial temperature dependence of the resistivity and some renormalization of the electron spectra.
9806378v1
2002-08-14
Nonlinear microwave response of epitaxial YBaCuO films of varying oxygen content on MgO substrates
We have investigated the nonlinear microwave properties of electron-beam coevaporated YBaCuO films on MgO, using stripline resonators at 2.3 GHz and temperatures 1.7-80 K. The oxygen content of the films ranged from strongly underdoped to overdoped. Above 20 K, the nonlinear response of the resonators was dominated by the superconductor. We could establish clear correlations between the nonlinear surface resistance, two-tone intermodulation (IMD), and oxygen content of the films, which indicate that the superconducting order parameter is important for the nonlinearities. An exponential rather than a power-law representation of the nonlinear current-voltage relation would be required to explain our results phenomenologically. Below 20 K, the dielectric loss tangent of MgO dominated the nonlinear response of the resonators. With increasing power, the dissipation losses decreased markedly, accompanied by enhanced IMD. The surface reactance passed through a shallow minimum at about 5 K, independent of power. We attribute these effects to resonant absorption by impurity states in MgO.
0208285v1
2004-04-13
Quantum Transparency of Anderson Insulator Junctions: Statistics of Transmission Eigenvalues, Shot Noise, and Proximity Conductance
We investigate quantum transport through strongly disordered barriers, made of a material with exceptionally high resistivity that behaves as an Anderson insulator or a ``bad metal'' in the bulk, by analyzing the distribution of Landauer transmission eigenvalues for a junction where such barrier is attached to two clean metallic leads. We find that scaling of the transmission eigenvalue distribution with the junction thickness (starting from the single interface limit) always predicts a non-zero probability to find high transmission channels even in relatively thick barriers. Using this distribution, we compute the zero frequency shot noise power (as well as its sample-to-sample fluctuations) and demonstrate how it provides a single number characterization of non-trivial transmission properties of different types of disordered barriers. The appearance of open conducting channels, whose transmission eigenvalue is close to one, and corresponding violent mesoscopic fluctuations of transport quantities explain at least some of the peculiar zero-bias anomalies in the Anderson-insulator/superconductor junctions observed in recent experiments [Phys. Rev. B {\bf 61}, 13037 (2000)]. Our findings are also relevant for the understanding of the role of defects that can undermine quality of thin tunnel barriers made of conventional band-insulators.
0404271v2
2004-06-17
Phase formation of polycrystalline MgB2 at low temperature using nanometer Mg powder
The MgB2 superconductor synthesized in a flowing argon atmosphere using nanometer magnesium powder as the raw materials, denoted as Nano-MgB2, has been studied by the technique of in-situ high temperature resistance measurement (HT-RT measurement). The MgB2 phase is identified to form within the temperature range of 430 to 490 C, which is much lower than that with the MgB2 sample fabricated in the same gas environment using the micron-sized magnesium powder, denoted as Micro-MgB2, reported previously. The sample density of the Nano-MgB2 reaches 1.7 g/cm3 with a crystal porosity structure less than a micrometer, as determined by the scanning electron microscope (SEM) images, while the Micro-MgB2 has a much more porous structure with corresponding density of 1.0 g/cm3. This indicates that the Mg raw particle size, besides the sintering temperature, is a crucial factor for the formation of high density MgB2 sample, even at the temperature much lower than that of the Mg melting, 650 C. The X-ray diffraction (XRD) pattern shows a good MgB2 phase with small amount of MgO and Mg and the transition temperature, TC, of the Nano-MgB2 was determined as 39 K by the temperature dependent magnetization measurement (M-T), indicating the existence of a good superconducting property.
0406398v1
2004-08-27
Spin reorientation and in-plane magnetoresistance of lightly doped La_{2-x}Sr_{x}CuO_{4} in magnetic fields up to 55 T
The magnetoresistance (MR) in the in-plane resistivity is measured in magnetic fields up to 55 T in lightly doped La_{2-x}Sr_{x}CuO_{4} in the N\'eel state (x = 0.01) and in the spin-glass state (x = 0.03) using high-quality untwinned single crystals. In both cases, a large negative MR is observed to appear when the magnetic order is established. For x = 0.01, it is found that the MR is indicative of a one-step transition into a high-field weak-ferromagnetic state at around 20 T when the magnetic field is applied from the spin easy axis (b axis), which means that there is no spin-flop transition in the N\'eel state of this material; this is contrary to a previous report, but is natural in light of the peculiar in-plane magnetic susceptibility anisotropy recently found in this system. In the spin-glass state, we observe that the large (up to \sim20%) negative MR saturates at around 40 T, and this MR is found to be essentially isotropic when the magnetic field is rotated within the ab plane. Our data show that the large negative MR is inherent to LSCO in a magnetically ordered state, in which the weak-ferromagnetic (WF) moment becomes well-defined; we discuss that the observed MR is essentially due to the reorientation of the WF moments towards the magnetic field direction both in the N\'eel state and in the spin-glass state.
0408604v1
2005-06-27
Strong-coupling theory of high-temperature superconductivity and colossal magnetoresistance
We argue that the extension of the BCS theory to the strong-coupling regime describes the high-temperature superconductivity of cuprates and the colossal magnetoresistance (CMR) of ferromagnetic oxides if the phonon dressing of carriers and strong attractive correlations are taken into account. The long-range Froehlich electron-phonon interaction has been identified as the most essential in cuprates providing "superlight" lattice polarons and bipolarons. Here some kinetic, magnetic, and more recent thermomagnetic normal state measurements are interpreted in the framework of the strong-coupling theory, including the Nernst effect and normal state diamagnetism. Remarkably, a similar strong-coupling approach offers a simple explanation of CMR in ferromagnetic oxides. The pairing of oxygen holes into heavy bipolarons in the paramagnetic phase and their magnetic pair-breaking in the ferromagnetic phase account for the first-order ferromagnetic phase transition, CMR, isotope effects, and pseudogaps in doped manganites. Here we propose an explanation of the phase coexistence and describe the shape of resistivity of manganites near the transition in the framework of the strong-coupling approach.
0506706v3
2006-06-05
Phenomenological theory of current driven exchange switching in ferromagnetic nanojunctions
Phenomenological approach is developed in the theory of spin-valve type ferromagnetic junctions to describe exchange switching by current flowing perpendicular to interfaces. Forward and backward current switching effects are described and they may be principally different in nature. Mobile electron spins are considered as being free in all the contacting ferromagnetic layers. Joint action of the following two current effects is investigated: the nonequilibrium longitudinal spin-injection effective field and the transverse spin-transfer surface torque. Dispersion relation for fluctuations is derived and solved for a junction model having spatially localized spin transfer torque: depth of the torque penetration into the free layer is assumed much smaller than the total free layer thickness. Some critical value of the well known Gilbert damping constant is established for the first time. Spin transfer torque dominates in the instability threshold determination for small enough damping constants, while the spin-injection effective field dominates for high damping. Fine interplay between spin transfer torque and spin injection is necessary to provide a hysteretic behavior of the resistance versus current dependence. The state diagram building up shows the possibility of non-stationary (time dependent) nonlinear states arising due to instability development. Calculations lead to the instability rise time values of the order of 0.1 ns. Spin wave resonance frequency spectrum softening occurs under the current growing to the instability threshold. Magnetization fluctuations above the threshold rise oscillating with time for low damping, but rise aperiodically and much more rapid for high damping.
0606102v2
2007-02-28
A local field emission study of partially aligned carbon-nanotubes by AFM probe
We report on the application of Atomic Force Microscopy (AFM) for studying the Field Emission (FE) properties of a dense array of long and vertically quasi-aligned multi-walled carbon nanotubes grown by catalytic Chemical Vapor Deposition on a silicon substrate. The use of nanometric probes enables local field emission measurements allowing investigation of effects non detectable with a conventional parallel plate setup, where the emission current is averaged on a large sample area. The micrometric inter-electrode distance let achieve high electric fields with a modest voltage source. Those features allowed us to characterize field emission for macroscopic electric fields up to 250 V/$\mu$m and attain current densities larger than 10$^5$ A/cm$^2$. FE behaviour is analyzed in the framework of the Fowler-Nordheim theory. A field enhancement factor $\gamma \approx$ 40-50 and a turn-on field $E_{turn-on} \sim$15 V/$\mu$m at an inter-electrode distance of 1 $\mu$m are estimated. Current saturation observed at high voltages in the I-V characteristics is explained in terms of a series resistance of the order of M$\Omega$. Additional effects as electrical conditioning, CNT degradation, response to laser irradiation and time stability are investigated and discussed.
0702682v1
2007-11-09
Defect healing at room temperature in pentacene thin films and improved transistor performance
We report on a healing of defects at room temperature in the organic semiconductor pentacene. This peculiar effect is a direct consequence of the weak intermolecular interaction which is characteristic of organic semiconductors. Pentacene thin-film transistors were fabricated and characterized by in situ gated four-terminal measurements. Under high vacuum conditions (base pressure of order 10E-8 mbar), the device performance is found to improve with time. The effective field-effect mobility increases by as much as a factor of two and mobilities up to 0.45 cm2/Vs were achieved. In addition, the contact resistance decreases by more than an order of magnitude and there is a significant reduction in current hysteresis. Oxygen/nitrogen exposure and annealing experiments show the improvement of the electronic parameters to be driven by a thermally promoted process and not by chemical doping. In order to extract the spectral density of trap states from the transistor characteristics, we have implemented a powerful scheme which allows for a calculation of the trap densities with high accuracy in a straightforward fashion. We show the performance improvement to be due to a reduction in the density of shallow traps <0.15 eV from the valence band edge, while the energetically deeper traps are essentially unaffected. This work contributes to an understanding of the shallow traps in organic semiconductors and identifies structural point defects within the grains of the polycrystalline thin films as a major cause.
0711.1457v1
2008-04-05
Strain rate effects in the mechanical response of polymer anchored carbon nanotube foams
Super-compressible foam-like carbon nanotube films have been reported to exhibit highly nonlinear viscoelastic behaviour in compression similar to soft tissue. Their unique combination of light weight and exceptional electrical, thermal and mechanical properties have helped identify them as viable building blocks for more complex nanosystems and as stand-alone structures for a variety of different applications. In the as-grown state, their mechanical performance is limited by the weak adhesion between the tubes, controlled by the van der Waals forces, and the substrate allowing the forests to split easily and to have low resistance in shear. Under axial compression loading carbon nanotubes have demonstrated bending, buckling8 and fracture9 (or a combination of the above) depending on the loading conditions and on the number of loading cycles. In this work, we partially anchor dense vertically aligned foam-like forests of carbon nanotubes on a thin, flexible polymer layer to provide structural stability, and report the mechanical response of such systems as a function of the strain rate. We test the sample under quasi-static indentation loading and under impact loading and report a variable nonlinear response and different elastic recovery with varying strain rates. A Bauschinger-like effect is observed at very low strain rates while buckling and the formation of permanent defects in the tube structure is reported at very high strain rates. Using high-resolution transmission microscopy
0804.0868v1
2008-04-10
Electrical transport and ferromagnetism in Ga1-xMnxAs synthesized by ion implantation and pulsed-laser melting
We present a detailed investigation of the magnetic and magnetotransport properties of thin films of ferromagnetic Ga1-xMnxAs synthesized using ion implantation and pulsed-laser melting (II-PLM). The field and temperature-dependent magnetization, magnetic anisotropy, temperature-dependent resistivity, magnetoresistance, and Hall effect of II-PLM Ga1-xMnxAs films have all of the characteristic signatures of the strong p-d interaction of holes and Mn ions observed in the dilute hole-mediated ferromagnetic phase. The ferromagnetic and electrical transport properties of II-PLM films correspond to the peak substitutional Mn concentration meaning that the non-uniform Mn depth distribution is unimportant in determining the film properties. Good quantitative agreement is found with films grown by low temperature molecular beam epitaxy (LT-MBE) and having the similar substitutional Mn_Ga composition. Additionally, we demonstrate that II-PLM Ga1-xMnxAs films are free from interstitial Mn_I because of the high temperature processing. At high Mn implantation doses the kinetics of solute redistribution during solidification alone determine the maximum resulting Mn_Ga concentration. Uniaxial anisotropy between in-plane [-110]and [110] directions is present in II-PLM Ga1-xMnxAs giving evidence for this being an intrinsic property of the carrier-mediated ferromagnetic phase.
0804.1612v1
2010-01-26
Signature of checkerboard fluctuations in the phonon spectra of a possible polaronic metal La1.2Sr1.8Mn2O7
Charge carriers in low-doped semiconductors may distort the atomic lattice and trap themselves forming so-called small polarons. High carrier concentrations can lead to short range ordered polarons (large polarons) and even to long range charge and orbital order. Both systems should be insulating with a large electrical resistivity, which decreases with increasing temperature. However, photoemission measurements recently found a polaronic pseudogap, in a metallic phase of La2-2xSr1+2xMn2O7. This layered manganite is famous for colossal magnetoresistance (CMR) associated with a phase transition from this low-temperature metallic phase to a high temperature insulating phase. Broad charge order peaks due to large polarons observed by neutron and x-ray scattering in the insulating phase disappear when La2-2xSr1+2xMn2O7 becomes metallic. We report results of inelastic neutron scattering measurements showing that polarons remain inside the metallic phase as fluctuations that strongly broaden and soften certain phonons near the wave vectors where the charge order peaks appeared in the insulating phase. Our findings imply that polaronic signatures in metals may generally come from a competing insulating charge-ordered phase. It is highly relevant to cuprate superconductors with both a pseudogap, and a similar phonon effect associated with a competing stripe order.
1001.4636v1
2010-04-28
Synthesis, Structure and Properties of Tetragonal Sr2M3As2O2 (M3 = Mn3, Mn2Cu and MnZn2) Compounds Containing Alternating CuO2-Type and FeAs-Type Layers
Polycrystalline samples of Sr2Mn2CuAs2O2, Sr2Mn3As2O2, and Sr2Zn2MnAs2O2 were synthesized. Their temperature- and applied magnetic field-dependent structural, transport, thermal, and magnetic properties were characterized by means of x-ray and neutron diffraction, electrical resistivity rho, heat capacity, magnetization and magnetic susceptibility measurements. These compounds have a body-centered-tetragonal crystal structure (space group I4/mmm) that consists of MO2 (M = Zn and/or Mn) oxide layers similar to the CuO2 layers in high superconducting transition temperature Tc cuprate superconductors, and intermetallic MAs (M = Cu and/or Mn) layers similar to the FeAs layers in high-Tc pnictides. These two types of layers alternate along the crystallographic c-axis and are separated by Sr atoms. The site occupancies of Mn, Cu and Zn were studied using Rietveld refinements of x-ray and neutron powder diffraction data. The temperature dependences of rho suggest metallic character for Sr2Mn2CuAs2O2 and semiconducting character for Sr2Mn3As2O2 and Sr2Zn2MnAs2O2. Sr2Mn2CuAs2O2 is inferred to be a ferrimagnet with a Curie temperature TC = 95(1) K. Remarkably, we find that the magnetic ground state structure changes from a G-type antiferromagnetic structure in Sr2Mn3As2O2 to an A-type ferrimagnetic structure in Sr2Mn2CuAs2O2 in which the Mn ions in each layer are ferromagnetically aligned, but are antiferromagnetically aligned between layers.
1004.5038v1
2011-06-21
Transport properties and anisotropy in rare earth doped CaFe2As2 single crystals with Tc above 40 K
In this paper we report the superconductivity above 40 K in the electron doping single crystal Ca1-xRexFe2As2 (Re = La, Ce, Pr). The x-ray diffraction patterns indicate high crystalline quality and c-axis orientation. the resistivity anomaly in the parent compound CaFe2As2 is completely suppressed by partial replacement of Ca by rare earth and a superconducting transition reaches as high as 43 K, which is higher than the value in electron doping FeAs-122 compounds by substituting Fe ions with transition metal, even surpasses the highest values observed in hole doping systems with a transition temperature up to 38 K. The upper critical field has been determined with the magnetic field along ab-plane and c-axis, yielding the anisotropy of 2~3. Hall-effect measurements indicate that the conduction in this material is dominated by electron like charge carriers. Our results explicitly demonstrate the feasibility of inducing superconductivity in Ca122 compounds via electron doping using aliovalent rare earth substitution into the alkaline earth site, which should add more ingredients to the underlying physics of the iron-based superconductors.
1106.4208v1
2012-02-13
Graphene-on-Diamond Devices with Enhanced Current-Carrying Capacity: Carbon sp2-on-sp3 Technology
Graphene demonstrated potential for practical applications owing to its excellent electronic and thermal properties. Typical graphene field-effect transistors and interconnects built on conventional SiO2/Si substrates reveal the breakdown current density on the order of 1 uA/nm2 (i.e. 10^8 A/cm2) which is ~100\times larger than the fundamental limit for the metals but still smaller than the maximum achieved in carbon nanotubes. We show that by replacing SiO2 with synthetic diamond one can substantially increase the current-carrying capacity of graphene to as high as ~18 uA/nm2 even at ambient conditions. Our results indicate that graphene's current-induced breakdown is thermally activated. We also found that the current carrying capacity of graphene can be improved not only on the single-crystal diamond substrates but also on an inexpensive ultrananocrystalline diamond, which can be produced in a process compatible with a conventional Si technology. The latter was attributed to the decreased thermal resistance of the ultrananocrystalline diamond layer at elevated temperatures. The obtained results are important for graphene's applications in high-frequency transistors, interconnects, transparent electrodes and can lead to the new planar sp2-on-sp3 carbon-on-carbon technology.
1202.2886v1
2012-07-12
Structure and electronic transport in graphene wrinkles
Wrinkling is a ubiquitous phenomenon in two-dimensional membranes. In particular, in the large-scale growth of graphene on metallic substrates, high densities of wrinkles are commonly observed. Despite their prevalence and potential impact on large-scale graphene electronics, relatively little is known about their structural morphology and electronic properties. Surveying the graphene landscape using atomic force microscopy, we found that wrinkles reach a certain maximum height before folding over. Calculations of the energetics explain the morphological transition, and indicate that the tall ripples are collapsed into narrow standing wrinkles by van der Waals forces, analogous to large-diameter nanotubes. Quantum transport calculations show that conductance through these collapsed wrinkle structures is limited mainly by a density-of-states bottleneck and by interlayer tunneling across the collapsed bilayer region. Also through systematic measurements across large numbers of devices with wide folded wrinkles, we find a distinct anisotropy in their electrical resistivity, consistent with our transport simulations. These results highlight the coupling between morphology and electronic properties, which has important practical implications for large-scale high-speed graphene electronics.
1207.2994v1
2012-09-06
Terahertz time-domain spectroscopic ellipsometry: Instrumentation and calibration
We present a new instrumentation and calibration procedure for terahertz time-domain spectroscopic ellipsometry (THz-TDSE) that is a newly established characterization technique. The experimental setup is capable of providing arbitrary angle of incidence in the range of $15^\circ$--$85^\circ$ in the reflection geometry, and with no need for realignment. The setup is also configurable easily into transmission geometry. For this setup, we successfully used hollow core photonic band gap fiber with no pre-chirping in order to deliver a femtosecond laser into a THz photoconductive antenna detector, which is the first demonstration of this kind. The proposed calibration scheme can compensate for the non-ideality of the polarization response of the THz photoconductive antenna detector as well as that of wire grid polarizers used in the setup. In the calibration scheme, the ellipsometric parameters are obtained through a regression algorithm which we have adapted from the conventional regression calibration method developed for rotating element optical ellipsometers, and used here for the first time for THz-TDSE. As a proof-of-principle demonstration, results are presented for a high resistivity silicon substrate as well as an opaque Si substrate with a high phosphorus concentration. We also demonstrate the capacity to measure a few micron thick grown thermal oxide on top of Si. Each sample was characterized by THz-TDSE in reflection geometry with different angle of incidence.
1209.1294v2
2013-05-09
Fermilab experience of post-annealing losses in SRF niobium cavities due to furnace contamination and the ways to its mitigation: a pathway to processing simplification and quality factor improvement
We investigate the effect of high temperature treatments followed by only high-pressure water rinse (HPR) of superconducting radio frequency (SRF) niobium cavities. The objective is to provide a cost effective alternative to the typical cavity processing sequence, by eliminating the material removal step post furnace treatment while preserving or improving the RF performance. The studies have been conducted in the temperature range 800-1000C for different conditions of the starting substrate: large grain and fine grain, electro-polished (EP) and centrifugal barrel polished (CBP) to mirror finish. An interesting effect of the grain size on the performances is found. Cavity results and samples characterization show that furnace contaminants cause poor cavity performance, and a practical solution is found to prevent surface contamination. Extraordinary values of residual resistances ~ 1 nOhm and below are then consistently achieved for the contamination-free cavities. These results lead to a more cost-effective processing and improved RF performance, and, in conjunction with CBP, open a potential pathway to acid-free processing.
1305.2182v2
2013-06-03
Electrical switching dynamics and broadband microwave characteristics of VO2 RF devices
Vanadium dioxide is a correlated electron system that features a metal-insulator phase transition (MIT) above room temperature and is of interest in high speed switching devices. Here, we integrate VO2 into two-terminal coplanar waveguides and demonstrate a large resistance modulation of the same magnitude (>10^3) in both electrically (i.e. by bias voltage, referred to as E-MIT) and thermally (T-MIT) driven transitions. We examine transient switching characteristics of the E-MIT and observe two distinguishable time scales for switching. We find an abrupt jump in conductivity with a rise time of the order of 10 ns followed by an oscillatory damping to steady state on the order of several {\mu}s. We characterize the RF power response in the On state and find that high RF input power drives VO2 further into the metallic phase, indicating that electromagnetic radiation-switching of the phase transition may be possible. We measure S-parameter RF properties up to 13.5 GHz. Insertion loss is markedly flat at 2.95 dB across the frequency range in the On state and sufficient isolation of over 25 dB is observed in the Off state. We are able to simulate the RF response accurately using both lumped element and 3D electromagnetic models. Extrapolation of our results suggests that optimizing device geometry can reduce insertion loss further and maintain broadband flatness up to 40 GHz.
1306.0292v1
2013-07-16
ZnS/Diamond Composite Coatings for Infrared Transmission Applications Formed by the Aerosol Deposition Method
The deposition of nano-crystalline ZnS/diamond composite protective coatings on silicon, sapphire, and ZnS substrates, as a preliminary step to coating infrared transparent ZnS substrates from powder mixtures by the aerosol deposition method is presented. Advantages of the aerosol deposition method include the ability to form dense, nanocrystalline films up to hundreds of microns thick at room temperature and at a high deposition rate on a variety of substrates. Deposition is achieved by creating a pressure gradient that accelerates micrometer-scale particles in an aerosol to high velocity. Upon impact with the target substrate the particles fracture and embed. Continued deposition forms the thick compacted film. Deposition from an aerosolized mixture of ZnS and diamond powders onto all targets results in linear trend from apparent sputter erosion of the substrate at 100% diamond to formation of a film with increasing fractions of ZnS. The crossover from abrasion to film formation on sapphire occurs above about 50% ZnS and a mixture of 90% ZnS and 10% diamond forms a well-adhered film of about 0.7 \mu m thickness at a rate of 0.14 \mu m/min. Resulting films are characterized by scanning electron microscopy, profilometry, infrared transmission spectroscopy, and x-ray photoemission spectroscopy. These initial films mark progress toward the future goal of coating ZnS substrates for abrasion resistance.
1307.4319v1
2013-10-01
Unexpected Giant Superconducting Fluctuation and Anomalous Semiconducting Normal State in NdO1-xFxBi1-yS2 Single Crystals
The BiS2-based superconductors were discovered recently. The superconductivity has been proved by many other groups. Since the previous experiments were all done on polycrystalline samples, therefore there remains a concern whether the superconductivity is really derived from the materials intrinsically or from some secondary phases. Experiments on single crystals are highly desired. In this paper, we report the successful growth of the NdO1-xFxBi1-yS2 single crystals. Resistive and magnetic measurements reveal that the bulk superconducting transition occurs at about 5 K, while an unexpected giant superconducting fluctuation appears at temperatures as high as 2-4 kBTC. Analysis based on the anisotropic Ginzbaug-Landau theory gives an anisotropy of 30-45. Two gap features with magnitudes of about 3.5+-0.3 meV and 7.5+-1 meV were observed by scanning tunneling spectroscopy. The smaller gap is associated with the bulk superconducting transition at about 5 K yielding a huge ratio 2Delta_s/kBTc =16.8, the larger gap remains up to about 26 K. The normal state recovered by applying a high magnetic field shows an anomalous semiconducting behavior. All these suggest that the superconductivity in this newly discovered superconductor cannot be formatted into the BCS theory.
1310.0377v1
2014-06-26
Electron localization and possible phase separation in the absence of a charge density wave in single-phase 1T-VS$_2$
We report on a systematic study of the structural, magnetic and transport properties of high-purity 1T-VS$_2$ powder samples prepared under high pressure. The results differ notably from those previously obtained by de-intercalating Li from LiVS$_2$. First, no Charge Density Wave (CDW) is found by transmission electron microscopy down to 94 K. Though, \textit{ab initio} phonon calculations unveil a latent CDW instability driven by an acoustic phonon softening at the wave vector ${\bf q}_{CDW} \approx$ (0.21,0.21,0) previously reported in de-intercalated samples. A further indication of latent lattice instability is given by an anomalous expansion of the V-S bond distance at low temperature. Second, infrared optical absorption and electrical resistivity measurements give evidence of non metallic properties, consistent with the observation of no CDW phase. On the other hand, magnetic susceptibility and NMR data suggest the coexistence of localized moments with metallic carriers, in agreement with \textit{ab initio} band structure calculations. This discrepancy is reconciled by a picture of electron localization induced by disorder or electronic correlations leading to a phase separation of metallic and non-metallic domains in the nm scale. We conclude that 1T-VS$_2$ is at the verge of a CDW transition and suggest that residual electronic doping in Li de-intercalated samples stabilizes a uniform CDW phase with metallic properties.
1406.6945v1
2014-11-07
Upgrade of the ALICE Inner Tracking System
During the Long Shutdown 2 of the LHC in 2018/2019, the ALICE experiment plans the installation of a novel Inner Tracking System. It will replace the current six layer detector system with a seven layer detector using Monolithic Active Pixel Sensors. The upgraded Inner Tracking System will have significantly improved tracking and vertexing capabilities, as well as readout rate to cope with the expected increased Pb-Pb luminosity of the LHC. The choice of Monolithic Active Pixel Sensors has been driven by the specific requirements of ALICE as a heavy ion experiment dealing with rare processes at low transverse momenta. This leads to stringent requirements on the material budget of 0.3$% X/X_{0}$ per layer for the three innermost layers. Furthermore, the detector will see large hit densities of $\sim 19 \mathrm{cm}^{-2}/\mathrm{event}$ on average for minimum-bias events in the inner most layer and has to stand moderate radiation loads of 700 kRad TID and $1\times 10^{13}$ 1 MeV n$_\mathrm{eq}/\mathrm{cm}^{2}$ NIEL at maximum. The Monolithic Active Pixel Sensor detectors are manufactured using the TowerJazz 0.18 $\mu$m CMOS Imaging Sensor process on wafers with a high-resistivity epitaxial layer. This contribution summarises the recent R&D activities and focuses on results on the large-scale pixel sensor prototypes.
1411.1802v2
2014-12-26
High Pressure Induced Binding Between Linear Carbon Chains and Nanotubes
Recent studies of single-walled carbon nanotubes (CNTs) in aqueous media have showed that water can significantly affect the tube mechanical properties. CNTs under hydrostatic compression can preserve their elastic properties up to large pressure values, while exhibiting exceptional resistance to mechanical loadings. It was experimentally observed that CNTs with encapsulated linear carbon chains (LCCs), when subjected to high hydrostatic pressure values, present irreversible red shifts in some of their vibrational frequencies. In order to address the cause of this phenomenon, we have carried out fully atomistic reactive (ReaxFF) molecular dynamics (MD) simulations for model structures mimicking the experimental conditions. We have considered the cases of finite and infinite (cyclic boundary conditions) CNTs filled with LCCs (LCC inside CNTs) of different lengths (from 9 up to 40 atoms). Our results show that increasing the hydrostatic pressure causes the CNT to be deformed in an inhomogeneous way due to the LCC presence. The LCC-CNT interface regions exhibit convex curvatures, which results in more reactive sites, thus favoring the formation of covalent chemical bonds between the chain and the nanotube. This process is irreversible with the newly formed bonds continuing to exist even after releasing the external pressure and causing an irreversibly red shift in the chain vibrational modes from 1850 to 1500 cm$^{-1}$.
1412.7966v1
2015-01-29
Superconducting properties of sulfur-doped iron selenide
The recent discovery of high-temperature superconductivity in single-layer iron selenide has generated significant experimental interest for optimizing the superconducting properties of iron-based superconductors through the lattice modification. For simulating the similar effect by changing the chemical composition due to S doping, we investigate the superconducting properties of high-quality single crystals of FeSe$_{1-x}$S$_{x}$ ($x$=0, 0.04, 0.09, and 0.11) using magnetization, resistivity, the London penetration depth, and low temperature specific heat measurements. We show that the introduction of S to FeSe enhances the superconducting transition temperature $T_{c}$, anisotropy, upper critical field $H_{c2}$, and critical current density $J_{c}$. The upper critical field $H_{c2}(T)$ and its anisotropy are strongly temperature dependent, indicating a multiband superconductivity in this system. Through the measurements and analysis of the London penetration depth $\lambda _{ab}(T)$ and specific heat, we show clear evidence for strong coupling two-gap $s$-wave superconductivity. The temperature-dependence of $\lambda _{ab}(T)$ calculated from the lower critical field and electronic specific heat can be well described by using a two-band model with $s$-wave-like gaps. We find that a $d$-wave and single-gap BCS theory under the weak-coupling approach can not describe our experiments. The change of specific heat induced by the magnetic field can be understood only in terms of multiband superconductivity.
1501.07346v1
2015-09-28
Thermoelectric properties of rare earth filled type-I like Clathrate, Dy8Al16Si30
Type-I clathrates with a cage structure are known to be of importance for thermoelectric applications as the cage can be filled with a guest atom which leads to reduced thermal conductivity. Among the type-I clathrates, Si-based alloys are of relevance for high temperature application and most importantly because they are made of earth abundant elements. Dysprosium, Dy has been chosen as the guest atom because of its large mass and small size compared to divalent alkali metal ion. The Dy8Al16Si30, DAS, alloy has been synthesized by arc melting of pure elements followed by annealing at 780 K for 7 days. Structural characterization performed using XRD and SEM indicates presence of both binary and ternary silicides, DySi2, DyAl2Si2 together with Al solid solution and Si. The phase mixture remains unchanged even after annealing. The microstructure has a typical dendritic structure with interdendritic phases, signifying a slow, liquid transformation after arc melting. The Seebeck coefficient is found to be positive, a p-type and increases with increasing temperature both before and after annealing. The resistivity is found to be low in the whole temperature range, 2 to 10 micro Ohm m and increases with increasing temperature. The power factor in the as-prepared state is found to be higher at all temperatures in the range 300 K to 700 K compared to annealed state. The thermal conductivity however has been found to decrease on annealing from an unusually high value of 100 W/m K to 50 W/m K.
1509.08277v1
2016-01-06
Observation of quantum Hall plateau-plateau transition and scaling behavior of the zeroth Landau level in graphene p-n-p junctions
We report distinctive magnetotransport properties of a graphene p-n-p junction prepared by controlled diffusion of metallic contacts. In most cases, materials deposited on a graphene surface introduce substantial carrier scattering, which greatly reduces the high mobility of intrinsic graphene. However, we show that an oxide layer only weakly perturbs the carrier transport, which enables fabrication of a high-quality graphene p-n-p junction through a one-step and resist-free method. The measured conductance-gate voltage $(G-V_G)$ curves can be well described by a metal contact model, which confirms the charge density depinning due to the oxide layer. The graphene p-n-p junction samples exhibit pronounced quantum Hall effect, a well-defined transition point of the zeroth Landau level (LL), and scaling behavior. The scaling exponent obtained from the evolution of the zeroth LL width as a function of temperature exhibits a relatively low value of $\kappa=0.21\pm0.01$. Moreover, we calculate the energy level for the LLs based on the distribution of plateau-plateau transition points, further validating the assignment of the LL index of the QH plateau-plateau transition.
1601.01155v1
2017-02-07
Resonant spin transfer torque nano-oscillators
Spin transfer torque nano-oscillators are potential candidates for replacing the traditional inductor based voltage controlled oscillators in modern communication devices. Typical oscillator designs are based on trilayer magnetic tunnel junctions which are disadvantaged by low power outputs and poor conversion efficiencies. In this letter, we theoretically propose to use resonant spin filtering in pentalayer magnetic tunnel junctions as a possible route to alleviate these issues and present device designs geared toward a high microwave output power and an efficient conversion of the d.c. input power. We attribute these robust qualities to the resulting non-trivial spin current profiles and the ultra high tunnel magnetoresistance, both arising from resonant spin filtering. The device designs are based on the nonequilibrium Green's function spin transport formalism self-consistently coupled with the stochastic Landau-Lifshitz-Gilbert-Slonczewski's equation and the Poisson's equation. We demonstrate that the proposed structures facilitate oscillator designs featuring a large enhancement in microwave power of around $775\%$ and an efficiency enhancement of over $1300\%$ in comparison with typical trilayer designs. We also rationalize the optimum operating regions via an analysis of the dynamic and static device resistances. This work sets stage for pentalyer spin transfer torque nano-oscillator device designs that extenuate most of the issues faced by the typical trilayer designs.
1702.01869v1
2017-02-18
Ultralow 1/f Noise in a Heterostructure of Superconducting Epitaxial Cobalt-Disilicide Thin Film on Silicon
High-precision resistance noise measurements indicate that the epitaxial CoSi$_2$/Si hetero-structures at 150 K and 2 K (slightly above its superconducting transition temperature $T_c$ of 1.54 K) exhibit an unusually low 1/f noise level in the frequency range of 0.008-0.2 Hz. This corresponds to an upper limit of Hooge constant $\gamma \leq 3 \times 10^{-6}$, about 100 times lower than that of single-crystalline aluminum films on SiO$_2$ capped Si substrates. Supported by high-resolution cross-sectional transmission electron microscopy studies, our analysis reveals that the 1/f noise is dominated by excess interfacial Si atoms and their dimer reconstruction induced fluctuators. Unbonded orbitals (i.e., dangling bonds) on excess Si atoms are intrinsically rare at the epitaxial CoSi$_2$/Si(100) interface, giving limited trapping-detrapping centers for localized charges. With its excellent normal-state properties, CoSi$_2$ has been used in silicon-based integrated circuits for decades. The intrinsically low noise properties discovered in this work could be utilized for developing quiet qubits and scalable superconducting circuits for future quantum computing.
1702.05566v1
2017-06-03
Electronic in-plane symmetry breaking at field-tuned quantum criticality in CeRhIn5
Electronic nematics are exotic states of matter where electronic interactions break a rotational symmetry of the underlying lattice, in analogy to the directional alignment without translational order in nematic liquid crystals. Intriguingly such phases appear in the copper- and iron-based superconductors, and their role in establishing high-temperature superconductivity remains an open question. Nematicity may take an active part, cooperating or competing with superconductivity, or may appear accidentally in such systems. Here we present experimental evidence for a phase of nematic character in the heavy fermion superconductor CeRhIn5. We observe a field-induced breaking of the electronic tetragonal symmetry of in the vicinity of an antiferromagnetic (AFM) quantum phase transition at Hc~50T. This phase appears in out-of-plane fields of H*~28T and is characterized by substantial in-plane resistivity anisotropy. The anisotropy can be aligned by a small in-plane field component, with no apparent connection to the underlying crystal structure. Furthermore no anomalies are observed in the magnetic torque, suggesting the absence of metamagnetic transitions in this field range. These observations are indicative of an electronic nematic character of the high field state in CeRhIn5. The appearance of nematic behavior in a phenotypical heavy fermion superconductor highlights the interrelation of nematicity and unconventional superconductivity, suggesting nematicity to be a commonality in such materials.
1706.00963v1
2017-09-03
Giant tunnel magnetoresistance with a single magnetic phase-transition electrode
Magnetic phase transition tunnel magnetoresistance (MPT-TMR) effect with a single magnetic electrode has been investigated by first-principles calculations. The calculations show that the MPT-TMR of FeRh/MgO/Cu tunnel junction can be as high as hundreds of percent when the magnetic structure of FeRh changes from G-type antiferromagnetic (GAFM) to ferromagnetic order. This new type of MPT-TMR may be superior to the tunnel anisotropic magnetoresistance because of its huge magneto-resistance effect and similar structural simplicity. The main mechanism for the giant MPT-TMR can be attributed to the formation of interface resonant states at GAFM-FeRh/MgO interface. A direct FeRh/MgO interface is found to be necessary for achieving high MPT-TMR experimentally. Moreover, we find the FeRh/MgO interface with FeRh in ferromagnetic phase has nearly full spin-polarization due to the negligible majority transmission and significantly different Fermi surface of two spin channels. Thus, it may act as a highly efficient and tunable spin-injector. In addition, electric field driven MPT of FeRh-based hetero-magnetic nanostructures can be utilized to design various energy efficient tunnel junction structures and the corresponding lower power consumption devices. Our results will stimulate further experimental investigations of MPT-TMR and other fascinating phenomenon of FeRh-based tunnel junctions that may be promising in antiferromagnetic spintronics.
1709.00687v2
2017-11-08
X-ray photoelectron spectroscopy, Magnetotransport and Magnetization study of Nb2PdS5 superconductor
In the present report, we investigate various properties of the Nb2PdS5 superconductor. Scanning electron microscopy displayed slabs like laminar growth of Nb2PdS5while X-ray photoelectron spectroscopy exhibited the hybridization of Sulphur (2p) with both Palladium (3d)and Niobium (3d). High field (140kOe) magneto-transport measurements revealed that superconductivity (Tc onset =7K and Tc R = 0 = 6.2K) of the studied Nb2PdS5material is quite robust against magnetic field with the upper critical field (Hc2) outside the Pauli paramagnetic limit. Thermally activated flux flow (TAFF) of the compound showed that resistivity curves follow Arrhenius behaviour. The activation energy for Nb2PdS5 is found to decrease from 15.15meV at 10kOe to 2.35meV at 140kOe. Seemingly, the single vortex pinning is dominant in low field regions, while collective pinning is dominant in high field region. The temperature dependence of AC susceptibility confirmed the Tc at 6K, further varying amplitude and frequency showed well coupled granular nature of superconductivity. The lower critical field (Hc1) is extracted from DC magnetisation measurements at various T below Tc. It is found that Hc1(T) of Nb2PdS5 material seemingly follows the multiband nature of superconductivity.
1711.02830v1
2017-11-10
Thermodynamic Studies of \b{eta}-Ga2O3 Nanomembrane Field-Effect Transistors on a Sapphire Substrate
The self-heating effect is a severe issue for high-power semiconductor devices, which degrades the electron mobility and saturation velocity, and also affects the device reliability. On applying an ultrafast and high-resolution thermoreflectance imaging technique, the direct self-heating effect and surface temperature increase phenomenon are observed on novel top-gate \b{eta}-Ga2O3 on insulator field-effect transistors. Here, we demonstrate that by utilizing a higher thermal conductivity sapphire substrate rather than a SiO2/Si substrate, the temperature rise above room temperature of \b{eta}-Ga2O3 on the insulator field-effect transistor can be reduced by a factor of 3 and thereby the self-heating effect is significantly reduced. Both thermoreflectance characterization and simulation verify that the thermal resistance on the sapphire substrate is less than 1/3 of that on the SiO2/Si substrate. Therefore, maximum drain current density of 535 mA/mm is achieved on the sapphire substrate, which is 70% higher than that on the SiO2/Si substrate due to reduced self-heating. Integration of \b{eta}-Ga2O3 channel on a higher thermal conductivity substrate opens a new route to address the low thermal conductivity issue of \b{eta}-Ga2O3 for power electronics applications.
1711.03672v1
2018-03-28
Study of nitrogen ion doping of titanium dioxide films
This study reports on the properties of nitrogen doped titanium dioxide $TiO_2$ thin films considering the application as transparent conducting oxide (TCO). Sets of thin films were prepared by sputtering a titanium target under oxygen atmosphere on a quartz substrate at 400 or 500{\deg}C. Films were then doped at the same temperature by 150 eV nitrogen ions. The films were prepared in Anatase phase which was maintained after doping. Up to 30at% nitrogen concentration was obtained at the surface, as determined by in situ x-ray photoelectron spectroscopy (XPS). Such high nitrogen concentration at the surface lead to nitrogen diffusion into the bulk which reached about 25 nm. Hall measurements indicate that average carrier density reached over $10^{19} cm^{-3}$ with mobility in the range of $0.1$ to $1 cm^2V^{-1}s^{-1}$. Resistivity about $3.10^{-1} \Omega cm$ could be obtained with 85% light transmission at 550 nm. These results indicate that low energy implantation is an effective technique for $TiO_2$ doping that allows an accurate control of the doping process independently from the TiO2 preparation. Moreover, this doping route seems promising to attain high doping levels without significantly affecting the film structure. Such approach could be relevant for preparation of $N:TiO_2$ transparent conduction electrodes (TCE).
1803.10828v1
2018-06-15
Quantum anomalous Hall multilayers grown by molecular beam epitaxy
Quantum anomalous Hall (QAH) effect is a quantum Hall effect that occurs without the need of external magnetic field. A system composed of multiple parallel QAH layers is an effective high Chern number QAH insulator and the key to the applications of the dissipationless chiral edge channels in low energy consumption electronics. Such a QAH multilayer can also be engineered into other exotic topological phases such as a magnetic Weyl semimetal with only one pair of Weyl points. This work reports the first experimental realization of QAH multilayers in the superlattices composed of magnetically doped (Bi,Sb)$_2$Te$_3$ topological insulator and CdSe normal insulator layers grown by molecular beam epitaxy. The obtained multilayer samples show quantized Hall resistance $h/Ne$$^2$, where $h$ is the Planck's constant, $e$ is the elementary charge and $N$ is the number of the magnetic topological insulator layers, resembling a high Chern number QAH insulator.
1806.05923v1
2018-09-26
Rare earth permanent magnets prepared by hot deformation process
Hot deformation process is one of the primary methods to produce anisotropic rare earth permanent magnets. Firstly, rapidly quenched powder flakes with nanocrystal structure are condensed into the full dense isotropic precursors by hot pressing process. And then, the prepared isotropic precursors are hot deformed to produce high-anisotropy uniaxial bulk rare earth permanent magnets, in which the highly textured structure is obtained in the hot plastic deformation process. The obtained hot-deformed magnets possess many advantages, such as near net-shape, outstanding corrosion resistance and ultrafine-grain structure. The noteworthy effects of preparation parameters employed in hot-pressing and deformation processes on the magnetic properties and microstructures characterizations are systemically summarized in this academic monograph. As a near net-shape technique, hot deformation process has noteworthy advantages in producing irregular shape magnets, especially for radially oriented ring-shape magnets with high length-diameter ratio or thin wall. The difficulties in producing crack-free, homogeneous and non-decentered ring-shaped magnets are basically resolved through mold design, adjustment of deformation parameters and application of theoretical simulation. Considering the characteristics of hot-deformed magnets, such as the grain shapes and sizes, anisotropic distribution of intergranular phases, etc., there is practical significance to study and improve the mechanical, electric properties and thermal stability to enlarge the applicable area of hot-deformed magnets or ring-shaped magnets.
1809.09838v1
2018-11-05
SkyLogic - A proposal for a skyrmion logic device
This work proposes a novel logic device (SkyLogic) based on skyrmions, which are magnetic vortex-like structures that have low depinning current density and are robust to defects. A charge current sent through a polarizer ferromagnet (P-FM) nucleates a skyrmion at the input end of an intra-gate FM interconnect with perpendicular magnetic anisotropy (PMA-FM). The output end of the PMA--FM forms the free layer of an MTJ stack. A spin Hall metal (SHM) is placed beneath the PMA-FM. The skyrmion is propagated to the output end of the PMA-FM by passing a charge current through the SHM. The resistance of the MTJ stack is low (high) when a skyrmion is present (absent) in the free layer, thereby realizing an inverter. A framework is developed to analyze the performance of the SkyLogic device. A circuit-level technique is developed that counters the transverse displacement of skyrmion in the PMA-FM and allows use of high current densities for fast propagation. The design space exploration of the PMA-FM material parameters is performed to obtain an optimal design point. At the optimal point, we obtain an inverter delay of 434 ps with a switching energy of 7.1 fJ.
1811.02016v1
2019-09-06
Electronic correlation determining correlated plasmons in Sb-doped Bi$_2$Se$_3$
Electronic correlation is believed to play an important role in exotic phenomena such as insulator-metal transition, colossal magneto resistance and high temperature superconductivity in correlated electron systems. Recently, it has been shown that electronic correlation may also be responsible for the formation of unconventional plasmons. Herewith, using a combination of angle-dependent spectroscopic ellipsometry, angle resolved photoemission spectroscopy and Hall measurements all as a function of temperature supported by first-principles calculations, the existence of low-loss high-energy correlated plasmons accompanied by spectral weight transfer, a fingerprint of electronic correlation, in topological insulator (Bi$_{0.8}$Sb$_{0.2}$)$_2$Se$_3$ is revealed. Upon cooling, the density of free charge carriers in the surface states decreases whereas those in the bulk states increase, and that the newly-discovered correlated plasmons are key to explaining this phenomenon. Our result shows the importance of electronic correlation in determining new correlated plasmons and opens a new path in engineering plasmonic-based topologically-insulating devices.
1909.02703v1
2020-03-30
Growth and transport properties of Mg3X2 (X = Sb, Bi) single crystals
The discovery of high thermoelectric performance in n-type polycrystalline Mg3(Sb,Bi)2 based Zintl compounds has ignited intensive research interest. However, some fundamental questions concerning the anisotropic transport properties and the origin of intrinsically low thermal conductivity are still elusive, requiring the investigation of single crystals. In this work, high-quality p-type Mg3Sb2 and Mg3Bi2 single crystals have been grown by using a self-flux method. The electrical resistivity \r{ho} of Mg3Bi2 single crystal displays an anisotropy with \r{ho} in-plane twice larger than out-of-plane. The low-temperature heat capacity and lattice thermal conductivity of Mg3Sb2 and Mg3Bi2 single crystals have been investigated by using the Debye-Callaway model, from which the existence of low-lying vibration mode could be concluded. Large Gr\"uneisen parameters and strong anharmonicity are found responsible for the intrinsically low thermal conductivity. Moreover, grain boundary scattering does not contribute significantly to suppress the lattice thermal conductivity of polycrystalline Mg3Sb2. Our results provide insights into the intrinsic transport properties of Mg3X2 and could pave a way to realize enhanced thermoelectric performance in single-crystalline Mg3X2-based Zintl compounds.
2003.13313v1
2017-03-13
Extremely high magnetoresistance and conductivity in the type-II Weyl semimetals WP2 and MoP2
The peculiar band structure of semimetals exhibiting Dirac and Weyl crossings can lead to spectacular electronic properties such as large mobilities accompanied by extremely high magnetoresistance. In particular, two closely neighbouring Weyl points of the same chirality are protected from annihilation by structural distortions or defects, thereby significantly reducing the scattering probability between them. Here we present the electronic properties of the transition metal diphosphides, WP2 and MoP2, that are type-II Weyl semimetals with robust Weyl points. We present transport and angle resolved photoemission spectroscopy measurements, and first principles calculations. Our single crystals of WP2 display an extremely low residual low-temperature resistivity of 3 nohm-cm accompanied by an enormous and highly anisotropic magnetoresistance above 200 million % at 63 T and 2.5 K. These properties are likely a consequence of the novel Weyl fermions expressed in this compound. We observe a large suppression of charge carrier backscattering in WP2 from transport measurements.
1703.04527v3
2017-03-20
Exceptional Anti-Icing Performance of Self-Impregnating Slippery Surfaces
A heat exchange interface at subzero temperature in a water vapor environment, exhibits high probability of frost formation due to freezing condensation, a factor that markedly decreases the heat transfer efficacy due to the considerable thermal resistance of ice. Here we report a novel strategy to delay ice nucleation on these types of solid-water vapor interfaces. With a process-driven mechanism, a self-generated liquid intervening layer immiscible to water, is deposited on a textured superhydrophobic surface and acts as a barrier between the water vapor and the solid substrate. This liquid layer imparts remarkable slippery conditions resulting in high mobility of condensing water droplets. A large increase of the ensuing ice coverage time is shown compared to the cases of standard smooth hydrophilic or textured superhydrophobic surfaces. During deicing of these self-impregnating surfaces we show an impressive tendency of ice fragments to skate expediting defrosting. Robustness of such surfaces is also demonstrated by operating them under subcooling for at least 490hr without a marked degradation. This is attributed to the presence of the liquid intervening layer, which protects the substrate from hydrolyzation enhancing longevity and sustaining heat transfer efficiency.
1703.07349v1
2019-02-03
Non-monotonic pressure dependence of high-field nematicity and magnetism in CeRhIn$_5$
CeRhIn$_5$ provides a textbook example of quantum criticality in a heavy fermion system: Pressure suppresses local-moment antiferromagnetic (AFM) order and induces superconductivity in a dome around the associated quantum critical point (QCP) near $p_{c} \approx 23\,$kbar. Strong magnetic fields also suppress the AFM order at a field-induced QCP at $B_{\rm c}\approx 50\,$T. In its vicinity, a nematic phase at $B^*\approx 28\,$T characterized by a large in-plane resistivity anisotropy emerges. Here, we directly investigate the interrelation between these phenomena via magnetoresistivity measurements under high pressure. As pressure increases, the nematic transition shifts to higher fields, until it vanishes just below $p_{\rm c}$. While pressure suppresses magnetic order in zero field as $p_{\rm c}$ is approached, we find magnetism to strengthen under strong magnetic fields due to suppression of the Kondo effect. We reveal a strongly non-mean-field-like phase diagram, much richer than the common local-moment description of CeRhIn$_5$ would suggest.
1902.00970v3
2020-02-11
Observation of an antiferromagnetic quantum critical point in high-purity LaNiO$_3$
Amongst the rare-earth perovskite nickelates, LaNiO$_3$ (LNO) is an exception. While the former have insulating and antiferromagnetic ground states, LNO remains metallic and non-magnetic down to the lowest temperatures. It is believed that LNO is a strange metal, on the verge of an antiferromagnetic instability. Our work suggests that LNO is a quantum critical metal, close to an antiferromagnetic quantum critical point (QCP). The QCP behavior in LNO is manifested in epitaxial thin films with unprecedented high purities. We find that the temperature and magnetic field dependences of the resistivity of LNO at low temperatures are consistent with scatterings of charge carriers from weak disorder and quantum fluctuations of an antiferromagnetic nature. Furthermore, we find that the introduction of a small concentration of magnetic impurities qualitatively changes the magnetotransport properties of LNO, resembling that found in some heavy-fermion Kondo lattice systems in the vicinity of an antiferromagnetic QCP.
2002.04159v1
2020-09-18
Nanoscale structural and electrical properties of graphene grown on AlGaN by catalyst-free chemical vapor deposition
The integration of graphene (Gr) with nitride semiconductors is highly interesting for applications in high-power/high-frequency electronics and optoelectronics. In this work, we demonstrated the direct growth of Gr on Al0.5Ga0.5N/sapphire templates by propane (C3H8) chemical vapor deposition (CVD) at temperature of 1350{\deg}C. After optimization of the C3H8 flow rate, a uniform and conformal Gr coverage was achieved, which proved beneficial to prevent degradation of AlGaN morphology. X-ray photoemission spectroscopy (XPS) revealed Ga loss and partial oxidation of Al in the near-surface AlGaN region. Such chemical modification of a 2 nm thick AlGaN surface region was confirmed by cross-sectional scanning transmission electron microscopy (STEM) combined with electron energy loss spectroscopy (EELS), which also showed the presence of a bilayer of Gr with partial sp2/sp3 hybridization. Raman spectra indicated that the deposited Gr is nanocrystalline (with domain size 7 nm) and compressively strained. A Gr sheet resistance of 15.8 kOhm/sq was evaluated by four-point-probe measurements, consistently with the nanocrystalline nature of these films. Furthermore, nanoscale resolution current mapping by conductive atomic force microscopy (C-AFM) indicated local variations of the Gr carrier density at a mesoscopic scale, which can be ascribed to changes in the charge transfer from the substrate due to local oxidation of AlGaN or to the presence of Gr wrinkles.
2009.08673v1
2017-07-28
3D laser printing by ultra-short laser pulses for micro-optical applications: towards telecom wavelengths
Three dimensional (3D) fast (< 0.5 hour) printing of micro-optical elements down to sub-wavelength resolution over 100 micrometers footprint areas using femtosecond (fs-)laser oscillator is presented. Using sub-1 nJ pulse energies, optical vortex generators made of polymerised grating segments with an azimuthally changing orientation have been fabricated in SZ2080 resist; width of polymerised rods was ~150 nm and period 0.6-1 micrometers. Detailed phase retardance analysis was carried out manually with Berek compensator (under a white light illumination) and using an equivalent principle by an automated Abrio implementation at 546 nm. Direct experimental measurements of retardance was required since the period of the grating was comparable (or larger) than the wavelength of visible light. By gold sputtering, transmission-type optical vortex generators were turned into reflective ones with augmented retardance, n.h defined by the form birefringence, n, and the height h = 2d where d is the thickness of the polymerised structure. Retardance reached 315 nm as measured with Berek compensator at visible wavelengths. Birefringent phase delays of 180 degrees (or half-wavelength) required for high purity vortex generators can be made based on the proposed approach. Optical vortex generators for telecom wavelengths with sub-wavelength patterns of azimuthally oriented gratings are amenable by direct laser polymerisation.
1707.09365v1
2017-08-14
High-Kinetic Inductance Additive Manufactured Superconducting Microwave Cavity
Investigations into the microwave surface impedance of superconducting resonators have led to the development of single photon counters that rely on kinetic inductance for their operation. While concurrent progress in additive manufacturing, `3D printing', opens up a previously inaccessible design space for waveguide resonators. In this manuscript, we present results from the first synthesis of these two technologies in a titanium, aluminum, vanadium (Ti-6Al-4V) superconducting radio frequency resonator which exploits a design unattainable through conventional fabrication means. We find that Ti-6Al-4V has two distinct superconducting transition temperatures observable in heat capacity measurements. The higher transition temperature is in agreement with DC resistance measurements. While the lower transition temperature, not previously known in literature, is consistent with the observed temperature dependence of the superconducting microwave surface impedance. From the surface reactance, we extract a London penetration depth of $8\pm3{\mu}$m - roughly an order of magnitude larger than other titanium alloys and several orders of magnitude larger than other conventional elemental superconductors. This large London penetration depth suggests that Ti-6Al-4V may be a suitable material for high kinetic inductance applications such as single photon counting or parametric amplification used in quantum computing.
1708.04273v1
2018-08-13
Ultra-compact graphene plasmonic photodetector with the bandwidth over 110GHz
Graphene-based photodetectors, taking advantage of high carrier mobility and broadband absorption in graphene, have recently experienced rapid development. However, their performances with respect to the responsivity and bandwidth are still limited by either weak light-graphene interaction or large resistance-capacitance product. Here, we demonstrate a waveguide coupled integrated graphene plasmonic photodetector on the silicon-on-insulator platform. Benefiting from plasmonic enhanced graphene-light interactions and subwavelength confinement of the optical energy, we present a small-footprint graphene-plasmonic photodetector with bandwidth beyond 110GHz and intrinsic responsivity of 360mA/W. Attributed to the unique electronic bandstructure of graphene and its ultra-broadband absorption, the operational wavelength range extending beyond mid-infrared, and possibly further, can be anticipated. Our results show that the combination of graphene with plasmonic devices has great potential to realize ultra-compact and high-speed optoelectronic devices for graphene-based optical interconnects.
1808.04815v3
2019-03-22
Structure and mechanical behavior of ultrafine-grained aluminum-iron alloy stabilized by nanoscaled intermetallic particles
Ultrafine-grained aluminum alloys offer interesting multifunctional properties with a combination of high strength, low electrical resistivity, and low density. However, due to thermally induced grain coarsening, they typically suffer from an intrinsic poor thermal stability. To overcome this drawback, an Al-2%Fe alloy has been selected because of the low solubility of Fe in Al and their highly positive enthalpy of mixing leading to the formation of stable intermetallic particles. The two-phase alloy has been processed by severe plastic deformation to achieve simultaneously submicrometer Al grains and a uniform distribution of nanoscaled intermetallic particles. The influence of the level of deformation on the microstructure has been investigated thanks to transmission electron microscopy and atom probe tomography and it is shown that for the highest strain a partial dissolution of the metastable Al6Fe particle occurred leading to the formation of a Fe super saturated solid solution. The thermal stability, and especially the precipitation of particles from the ultrafine-grained solid solution and the way they pin grain boundaries has been investigated both from static annealing and in-situ transmission electron microscopy experiments. The correlation between microstructural features and microhardness has been established to identify the various strengthening contributions. Finally, it is 2 shown that ultrafine grained high purity Al with less than 0.01 at. % Fe in solid solution could preserve a grain size only 300nm after 1h at 250$^\circ$C.
1903.09391v1
2019-03-27
Homogeneous hierarchical NiMoO4@NiMoO4 nanostructure as a high-performance anode material for electrochemical energy storage
Here we report the extraordinary electrochemical energy storage capability of NiMoO4@NiMoO4 homogeneous hierarchical nanosheet-on-nanowire-arrays (SOWAs) synthesized on nickel substrate by a two-stage hydrothermal process. Comparatively speaking, the SOWAs electrode displays improved electrochemical performances than the bare NiMoO4 nanowire arrays. Such improvements can be ascribed to the characteristic homogeneous hierarchical structure which not only effectively increases the active surface areas for fast charge transfer, but also reduces the electrode resistance significantly by eliminating the potential barrier at the nanowire/nanosheet junction, which is usually an issue in other reported heterogeneous architectures. We further evaluate the performances of the SOWAs by constructing an asymmetric hybrid supercapacitor (ASC) with the SOWAs and activated carbon (AC). The optimized ASC shows excellent electrochemical performances with 47.2 Wh/kg in energy density at 1.38 kW/kg at 0-1.2 V. Moreover, the specific capacity retention can be as high as 91.4% after 4000 cycles, illustrating the remarkable cycling stability of the NiMoO4@NiMoO4//AC ASC device. Our results show that this unique NiMoO4@NiMoO4 SOWAs display great prospect for future energy storage applications
1903.11513v1
2019-04-29
Type-II Ising superconductivity and anomalous metallic state in macro-size ambient-stable ultrathin crystalline films
Recent emergence of two-dimensional (2D) crystalline superconductors has provided a promising platform to investigate novel quantum physics and potential applications. To reveal essential quantum phenomena therein, ultralow temperature transport investigation on high quality ultrathin superconducting films is critically required, although it has been quite challenging experimentally. Here we report a systematic transport study on the ultrathin crystalline PdTe2 films grown by molecular beam epitaxy (MBE). Interestingly, a new type of Ising superconductivity in 2D centrosymmetric materials is revealed by the detection of large in-plane critical field more than 7 times Pauli limit. Remarkably, in perpendicular magnetic field, we provide solid evidence of anomalous metallic state characterized by the resistance saturation at low temperatures with high quality filters. The robust superconductivity with intriguing quantum phenomena in the macro-size ambient-stable ultrathin PdTe2 films remains almost the same for 20 months, showing great potentials in electronic and spintronic applications.
1904.12719v2