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2016-04-25
Anisotropic transport and optical spectroscopy study on antiferromagentic triangular lattice EuCd_2As_2: an interplay between magnetism and charge transport properties
We present anisotropic transport and optical spectroscopy studies on EuCd_2As_2. The measurements reveal that EuCd_2As_2 is a low carrier density semimetal with moderate anisotropic resistivity ratio. The charge carriers experience very strong scattering from Eu magnetic moments, resulting in a Kondo-like increase of resistivity at low temperature. Below the antiferromagnetic transition temperature at $T_N$= 9.5 K, the resistivity drops sharply due to the reduced scattering from the ordered Eu moments. Nevertheless, the anisotropic ratio of $\rho_c/\rho_{ab}$ keeps increasing, suggesting that the antiferromagnetic coupling is along the c-axis. The optical spectroscopy measurement further reveals, besides an overdamped reflectance plasma edge at low energy, a strong coupling between phonon and electronic continuum. Our study suggests that EuCd_2As_2 is a promising candidate displaying intriguing interplay among charge, magnetism and the underlying crystal lattice.
1604.07114v2
2016-04-26
Multiband effects and the possible Dirac states in LaAgSb$_2$
Here we report the possible signature of Dirac fermions in the magnetoresistance, Hall resistivity and magnetothermopower of LaAgSb$_2$. The opposite sign between Hall resistivity and Seebeck coefficient indicates the multiband effect. Electronic structure calculation reveals the existence of the linear bands and the parabolic bands crossing the Fermi level. The large linear magnetoresistance was attributed to the quantum limit of the possible Dirac fermions or the breakdown of weak-field magnetotransport at the charge density wave phase transition. Analysis of Hall resistivity using two-band model reveals that Dirac holes which dominate the electronic transport have much higher mobility and larger density than conventional electrons. Magnetic field suppresses the apparent Hall carrier density, and also induces the sign change of the Seebeck coefficient from negative to positive. These effects are possibly attributed to the magnetic field suppression of the density of states at the Fermi level originating from the quantum limit of the possible Dirac holes.
1604.07819v1
2016-04-27
Superconductivity at 7.8 K in the ternary LaRu2As2 compound
Here we report the discovery of superconductivity in the ternary LaRu2As2 compound. The polycrystalline LaRu2As2 samples were synthesized by the conventional solid state reaction method. Powder X-ray diffraction analysis indicates that LaRu2As2 crystallizes in the ThCr2Si2-type crystal structure with the space group I4/mmm (No. 139), and the refined lattice parameters are a = 4.182(6) {\AA} and c = 10.590(3) {\AA}. The temperature dependent resistivity measurement shows a clear superconducting transition with the onset Tc (critical temperature) at 7.8 K, and zero resistivity happens at 6.8 K. The upper critical field at zero temperature m0Hc2(0) was estimated to be 1.6 T from the resistivity measurement. DC magnetic susceptibility measurement shows a bulk superconducting Meissner transition at 7.0 K, and the isothermal magnetization measurement indicates that LaRu2As2 is a type-II superconductor.
1604.07958v1
2016-06-02
First-principles calculation of the stabilities of lithium garnet compositions against hydration
A series of density functional electronic structure calculations were carried out to better understand the crystallographic factors governing the stability of LinA3B2O12 lithium garnet phases against hydration. The reaction studied is H2O + LinA3B2O12 = LiOH + HnA3B2O12. Most of the compositions are stable against pure water; the main driving force for instability in the atmosphere is the reaction of lithium hydroxide with CO2 to make lithium carbonate. The calculated hydration resistance scales with the Pauling bond valence on the oxygen atom contributed by the coordinating A and B ions. In the unexchanged Li-garnets, this bond valence must be balanced by lithium, so there is also a good overall correlation of hydration stability with lithium stoichiometry (n): hydration resistance increases in the order Li8-garnet < Li7-garnet < Li6-garnet < Li5-garnet < Li3-garnet. Only Li3A3B2O12 garnets have proton exchange energies sufficiently positive to overcome the decomposition energy of lithium hydroxide into lithium carbonate + water; the n=3 garnets are predicted to be stable to hydration under atmospheric conditions, in agreement with observations (Galven et al. Chem. Mater. 2012 24, 3335-3345). At a given lithium ion stoichiometry, hydration resistance is greater for A, B ions having smaller ionic radii.
1606.01807v1
2016-06-07
The temperature dependence of FeRh's transport properties
The finite-temperature transport properties of FeRh compounds are investigated by first-principles Density Functional Theory-based calculations. The focus is on the behavior of the longitudinal resistivity with rising temperature, which exhibits an abrupt decrease at the metamagnetic transition point, $T = T_m$ between ferro- and antiferromagnetic phases. A detailed electronic structure investigation for $T \geq 0$ K explains this feature and demonstrates the important role of (i) the difference of the electronic structure at the Fermi level between the two magnetically ordered states and (ii) the different degree of thermally induced magnetic disorder in the vicinity of $T_m$, giving different contributions to the resistivity. To support these conclusions, we also describe the temperature dependence of the spin-orbit induced anomalous Hall resistivity and Gilbert damping parameter. For the various response quantities considered the impact of thermal lattice vibrations and spin fluctuations on their temperature dependence is investigated in detail. Comparison with corresponding experimental data finds in general a very good agreement.
1606.02072v1
2016-06-21
Bad-Metal Relaxation Dynamics in a Fermi Lattice Gas
We report the discovery of phenomena consistent with bad-metal relaxation dynamics in the metallic regime of an optical-lattice Hubbard model. The transport lifetime induced by inter-particle scattering for a mass current of atoms excited by stimulated Raman transitions is measured, and the corresponding analog of resistivity is inferred. By exploring a range of temperature, we demonstrate incompatibility with weak-scattering theory and a key characteristic of bad metals: anomalous resistivity scaling consistent with $T$-linear behavior. We also observe the onset of two behaviors---incoherent transport and the approach to the Mott-Ioffe-Regel limit---associated with bad metals. The interaction and temperature scaling of resistivity are verified to be consistent with dynamic mean-field theory (DMFT) predictions of a bad metal, which is associated with the reduction of quasiparticle weight by strong interactions.
1606.06669v5
2016-07-11
The modification of the pore characteristics of activated carbon, for use in electrical double layer capacitors, through plasma processing
It was aimed to determine whether plasma processing could contribute to enhanced capacitance and energy density of activated carbon electrode based electrochemical capacitors, through the formation of additional surface charges. While an increase of up to 35% of the gravimetric capacitance, along with ~ 20% decrease in resistance, was obtained through optimal plasma processing, increased plasma exposure yielded a drastic reduction (/increase) in the capacitance (/resistance). It was also found that the capacitance and resistance modulation was a sensitive function of sample processing as well as electrochemical testing procedure. Considering the complexity of modeling realistic porous matrices, a metric to parameterize the reach of an electrolyte into the matrix has been posited.
1607.03201v1
2016-07-15
Chiral Phonons and Electrical Resistivity of Ferromagnetic Metals at Low Temperatures
Ferromagnetism is an exciting phase of matter exhibiting strongly correlated electron behavior and a standard example of spontaneously broken rotational symmetry: below the Curie temperature, atomic magnets in an isotropic single-domain ferromagnetic metal align along a spontaneously chosen direction. The scattering of conduction electrons from thermal perturbations to this spin order, together with electron-electron collisions, mark the material electrical behavior at low temperatures, where the resistivity varies mostly quadratically with the temperature. Around liquid-helium temperatures however, an interesting phenomenon occurs, giving rise to an extra \emph{linear} contribution to the variation of the electrical resistivity with temperature, whose theoretical explanation has encountered problems for a long time. Here I introduce a spin-flip scattering mechanism of conduction electrons in ferromagnetic metals arising from their interaction with the internal magnetic induction and mediated by chiral modes of the crystal lattice vibrations carrying spin 1. This mechanism is able to explain the above anomaly and give a good account of the spin-lattice relaxation times of iron, cobalt and nickel at room temperatures.
1607.04585v2
2016-11-01
Boundary conditions and heat resistance at the moving solid--liquid interface
Boundary conditions for the solid-liquid interface of the solidifying pure melt have been derived. In the derivation the model of Gibbs interface is used. The boundary conditions include both the state quantities of bulk phases are taken at the interface and the quantities characterizing interfacial surface such as the surface temperature and the surface heat flux. Introduction of the surface temperature as an independent variable allows us to describe the scattering energy at the interface. For the steady-state motion of the planar interface the expression for the temperature discontinuity across the phase boundary has been obtained. Effect of Kapitza resistance on the interface velocity is considered. It is shown that heat resistance leads to non-linearity in solidification kinetics, namely, in "velocity-undercooling" relationship. The conditions of the steady--state motion of the planar interface has been found.
1611.00160v1
2017-06-01
Edge transport in InAs and InAs/GaSb quantum wells
We investigate low-temperature transport through single InAs quantum wells and broken-gap InAs/GaSb double quantum wells. Non-local measurements in the regime beyond bulk pinch-off confirm the presence of edge conduction in InAs quantum wells. The edge resistivity of 1-2 $\mathrm{k\Omega/\mu m}$ is of the same order of magnitude as edge resistivities measured in the InAs/GaSb double quantum well system. Measurements in tilted magnetic field suggests an anisotropy of the conducting regions at the edges with a larger extent in the plane of the sample than normal to it. Finger gate samples on both material systems shine light on the length dependence of the edge resistance with the intent to unravel the nature of edge conduction in InAs/GaSb coupled quantum wells.
1706.00320v1
2017-09-21
Zero-Field Quantum Critical Point in Ce$_{0.91}$Yb$_{0.09}$CoIn$_5$
We present results of specific heat, electrical resistance, and magnetoresistivity measurements on single crystals of the heavy-fermion superconducting alloy Ce$_{0.91}$Yb$_{0.09}$CoIn$_5$. Non-Fermi liquid to Fermi liquid crossovers are clearly observed in the temperature dependence of the Sommerfeld coefficient $\gamma$ and resistivity data. Furthermore, we show that the Yb-doped sample with $x=0.09$ exhibits universality due to an underlying quantum phase transition without an applied magnetic field by utilizing the scaling analysis of $\gamma$. Fitting of the heat capacity and resistivity data based on existing theoretical models indicates that the zero-field quantum critical point is of antiferromagnetic origin. Finally, we found that at zero magnetic field the system undergoes a third-order phase transition at the temperature $T_{c3}\approx 7$ K.
1709.07161v3
2017-12-01
Titanium Contacts to Graphene: Process-Induced Variability in Electronic and Thermal Transport
Contact Resistance (RC) is a major limiting factor in the performance of graphene devices. RC is sensitive to the quality of the interface and the composition of the contact, which are affected by the graphene transfer process and contact deposition conditions. In this work, a linear correlation is observed between the composition of Ti contacts, characterized by X-ray photoelectron spectroscopy, and the Ti/graphene (Gr) contact resistance measured by the transfer length method. We find that contact composition is tunable via deposition rate and base pressure. Reactor base pressure is found to effect the resultant contact resistance. The effect of contact deposition conditions on thermal transport measured by time-domain thermoreflectance is also reported and interfaces with higher oxide composition appear to result in a lower thermal boundary conductance. Possible origins of this thermal boundary conductance change with oxide composition are discussed.
1712.00331v1
2017-12-04
Particle-hole symmetry reveals failed superconductivity in the metallic phase of two-dimensional superconducting films
Electrons confined to two dimensions display an unexpected diversity of behaviors as they are cooled to absolute zero. Noninteracting electrons are predicted to eventually "localize" into an insulating ground state, and it has long been supposed that electron correlations stabilize only one other phase: superconductivity. However, many two-dimensional (2D) superconducting materials have shown surprising evidence for metallic behavior, where the electrical resistivity saturates in the zero-temperature limit, the nature of this unexpected metallic state remains under intense scrutiny. We report electrical transport properties for two disordered 2D superconductors, indium oxide and tantalum nitride, and observe a magnetic field-tuned transition from a true superconductor to a metallic phase with saturated resistivity. This metallic phase is characterized by a vanishing Hall resistivity, suggesting that it retains particle-hole symmetry from the disrupted superconducting state.
1712.00947v1
2018-01-15
A study of electron and thermal transport in layered Titanium disulphide single crystals
We present a detailed study of thermal and electrical transport behavior of single crystal Titanium disulphide flakes, which belongs to the two dimensional, transition metal dichalcogenide class of materials. In-plane Seebeck effect measurements revealed a typical metal-like linear temperature dependence in the range of 85 - 285 K. Electrical transport measurements with in-plane current geometry exhibited a nearly T^2 dependence of resistivity in the range of 10 - 300 K. However, transport measurements along the out-of-plane current geometry showed a transition in temperature dependence of resistivity from T^2 to T^5 beyond 200 K. Interestingly, Au ion-irradiated TiS2 samples showed a similar T 5 dependence of resistivity beyond 200 K, even in the current-in-plane geometry. Micro- Raman measurements were performed to study the phonon modes in both pristine and ion-irradiated TiS2 crystals.
1801.04677v1
2018-02-23
Possible charge-density-wave signatures in the anomalous resistivity of Li-intercalated multilayer MoS2
We fabricate ion-gated field-effect transistors (iFET) on mechanically exfoliated multilayer MoS$_2$. We encapsulate the flake by Al$_2$O$_3$, leaving the device channel exposed at the edges only. A stable Li$^+$ intercalation in the MoS$_2$ lattice is induced by gating the samples with a Li-based polymeric electrolyte above $\sim$ 330 K and the doping state is fixed by quenching the device to $\sim$ 300 K. This intercalation process induces the emergence of anomalies in the temperature dependence of the sheet resistance and its first derivative, which are typically associated with structural/electronic/magnetic phase transitions. We suggest that these anomalies in the resistivity of MoS$_2$ can be naturally interpreted as the signature of a transition to a charge-density-wave phase induced by lithiation, in accordance with recent theoretical calculations.
1802.08449v2
2018-03-13
Are thermal fluctuations the sole reason for finite longitudinal resistance in quantum anomalous Hall experiments?
In some recent experiments [A. J. Bestwick, et. al., Phys. Rev. Lett. 114, 187201 (2015), Cui-Zu Chang, et. al., Nat. Materials. 14, 473-477 (2015)] it has been shown that in observations of the quantum anomalous Hall (QAH) effect the longitudinal resistance $R_L$ increases as temperature $T$ increases, while Hall resistance $R_H$ loses its quantization with increase in $T$. This behavior was explained due to increased thermal fluctuations as $T$ increases. We show that similar effects arise in QAH samples with quasi-helical edge modes as disorder increases in presence of inelastic scattering or otherwise even at temperature $T=0$.
1803.04995v2
2018-03-21
Bad metallic transport in a modified Hubbard model
Strongly correlated metals often display anomalous transport, including $T$-linear resistivity above the Mott-Ioffe-Regel limit. We introduce a tractable microscopic model for such bad metals, by supplementing the well-known Hubbard model --- with hopping $t$ and on-site repulsion $U$ --- with a `screened Coulomb' interaction between charge densities that decays exponentially with spatial separation. This interaction entirely lifts the extensive degeneracy in the spectrum of the $t=0$ Hubbard model, allowing us to fully characterize the small $t$ electric, thermal and thermoelectric transport in our strongly correlated model. Throughout the phase diagram we observe $T$-linear resistivity above the Mott-Ioffe-Regel limit, together with strong violation of the Weidemann-Franz law and a large thermopower that can undergo sign change. At intermediate temperatures $t \ll k_B T \lesssim U$, the approximate $T$-linear resistivity arises from a cancellation between the nontrivial temperature dependence of both diffusivities and thermodynamic susceptibilities, as observed in recent transport experiments on cold atomic gases.
1803.08054v3
2018-04-06
Energy-Quality Scaling in Analog Mesh Computers
The recent push for post-Moore computer architectures has introduced a wide variety of application-specific accelerators. One particular accelerator, the resistance network analogue, has been well received due to its ability to efficiently solve partial differential equations by eliminating the iterative stages required by today's numerical solvers. However, in the ago of programmable integrated circuits, the static nature of the resistance network analogue, and other analog mesh computers like it, has relegated it to an academic curiosity. Recent developments in materials, such as the memristor, have made the resistance network analogue viable for inclusion in future heterogeneous computer architectures. However, selection of an appropriate sized mesh to be incorporated into a computer system requires that energy-quality trade-offs are made regarding the problem size and required resolution of the solution. This paper provides an in-depth study of the scaling of analog mesh computer hardware, from the perspective of energy per bit and required resolution, introduces a metric to aid in quantifying analog mesh computers with different parameters, and introduces a method of virtualization which enables an analog mesh computer of a fixed size to approximate the calculations of a larger-sized mesh.
1804.02389v2
2018-04-28
Nonequilibrium Mean-Field Theory of Resistive Phase Transitions
We investigate the quantum mechanical origin of resistive phase transitions in solids driven by a constant electric field in the vicinity of a metal-insulator transition. We perform a nonequilibrium mean-field analysis of a driven-dissipative anti-ferromagnet, which we solve analytically for the most part. We find that the insulator-to-metal transition (IMT) and the metal-to-insulator transition (MIT) proceed by two distinct electronic mechanisms: Landau-Zener processes, and the destabilization of metallic state by Joule heating, respectively. However, we show that both regimes can be unified in a common effective thermal description, where the effective temperature $T_{\rm eff}$ depends on the state of the system. This explains recent experimental measurements in which the hot-electron temperature at the IMT was found to match the equilibrium transition temperature. Our analytic approach enables us to formulate testable predictions on the non-analytic behavior of $I$-$V$ relation near the insulator-to-metal transition. Building on these successes, we propose an effective Ginzburg-Landau theory which paves the way to incorporating spatial fluctuations, and to bringing the theory closer to a realistic description of the resistive switchings in correlated materials.
1804.10733v1
2018-09-24
Fusion Between Frozen-Wave-Type Beams and Airy-Type Pulses: Diffraction-Dispersion-Attenuation Resistant Vortex Pulses in Absorbing Media
In this paper we perform a fusion between two important theoretical methodologies, one related to the Frozen Wave beams, which are non-diffracting beams whose longitudinal intensity pattern can be chosen a priori in an medium (absorbing or not), and the other related to the Airy-Type pulses, which are pulses resistant to dispersion effects in dispersive materials. As a result, a new method emerges, capable of providing vortex pulses resistant to three concomitant effects, i.e.: diffraction, dispersion and attenuation; while concurrently the spatial variation of the wave intensity along its axis of propagation can be engineered at will. The new approach can be seen as a generalization of the Localized Waves theory in the paraxial regime and the new pulses can have potential applications in different fields such as optics communications, nonlinear optics, micromanipulation, and so on.
1809.08740v1
2018-11-28
Investigation of effective thermoelectric properties of composite with interfacial resistance using micromechanics-based homogenisation
We obtained the analytical expression for the effective thermoelectric properties and dimensionless figure of merit of a composite with interfacial electrical and thermal resistances using a micromechanics-based homogenisation. For the first time, we derived the Eshelby tensor for a spherical inclusion as a function of the interfacial resistances and obtained the solutions of the effective Seebeck coefficient and the electrical and thermal conductivities of a composite, which were validated against finite-element analysis (FEA). Our analytical predictions well match the effective properties obtained from FEA with an inclusion volume fraction up to 15%. Because the effective properties were derived with the assumption of a small temperature difference, we discuss a heuristic method for obtaining the effective properties in the case where a thermoelectric composite is subjected to a large temperature difference.
1811.11340v2
2019-05-13
Quantum Oscillations of Electrical Resistivity in an Insulator
In metals, orbital motions of conduction electrons on the Fermi surface are quantized in magnetic fields, which is manifested by quantum oscillations in electrical resistivity. This Landau quantization is generally absent in insulators. Here we report a notable exception in an insulator, ytterbium dodecaboride (YbB12). Despite much larger than that of metals, the resistivity of YbB12 exhibits profound quantum oscillations. This unconventional oscillation is shown to arise from the insulating bulk, yet the temperature dependence of their amplitude follows the conventional Fermi liquid theory of metals. The large effective masses indicate the presence of Fermi surface consisting of strongly correlated electrons. Our result reveals a mysterious bipartite ground state of YbB12: it is both a charge insulator and a strongly correlated metal.
1905.05140v1
2019-09-27
Magnetoresistance effects in the metallic antiferromagnet Mn$_2$Au
In antiferromagnetic spintronics, it is essential to separate the resistance modifications of purely magnetic origin from other effects generated by current pulses intended to switch the N\'eel vector. We investigate the magnetoresistance effects resulting from magnetic field induced reorientations of the staggered magnetization of epitaxial antiferromagnetic Mn2Au(001) thin films. The samples were exposed to 60 T magnetic field pulses along different crystallographic in-plane directions of Mn2Au(001), while their resistance was measured. For the staggered magnetization aligned via a spin-flop transition parallel to the easy [110]-direction, an ansiotropic magnetoresistance of -0.15 % was measured. In the case of a forced alignment of the staggered magnetization parallel to the hard [100]-direction, evidence for a larger anisotropic magnetoresistance effect was found. Furthermore, transient resistance reductions of about 1 % were observed, which we associate with the annihilation of antiferromagnetic domain walls by the magnetic field pulses.
1909.12606v3
2020-03-22
Monitoring of the formation of strontium molybdate intergrain tunneling barriers in strontium ferromolybdate
This work is a contribution to the understanding of the electrical resistivity in strontium ferromolybdate (SFMO) ceramics. It demonstrates that an appropriate thermal treatment leads to the formation of dielectric SrMoO4 shells at the surface of SFMO nanograins. In samples without SrMoO4 shells, the sign of the temperature coefficient of resistance changes with increasing temperature from negative at very low temperature to positive at higher temperatures. Samples exhibiting a negative temperature coefficient contain SrMoO4 shells and demonstrate a behavior of the resistivity that can be described in terms of the fluctuation-induced tunneling model, and near room temperature the conductivity mechanism converts to a variable-range hopping one. The results of this work serve as a starting point for the understanding of the low-field magnetoresistance which is very promising for spintronic device application.
2003.09997v1
2014-08-15
Correlation between electrical and magnetic properties of phase separated manganites studied with a General Effective Medium model
We have performed electrical resistivity and DC magnetization measurements as a function of temperature, on polycrystalline samples of phase separated LaPrCaMnO. We have used the General Effective Medium Theory to obtain theoretical resistivity vs. temperature curves corresponding to different fixed ferromagnetic volume fraction values, assuming that the sample is a mixture of typical metallic like and insulating manganites. By comparing this data with our experimental resistivity curves we have obtained the relative ferromagnetic volume fraction of our sample as a function of temperature. This result matches with the corresponding magnetization data in excellent agreement, showing that a mixed phase scenario is the key element to explain both the magnetic and transport properties in the present compound.
1408.3599v1
2014-08-28
Room temperature giant baroresistance and magnetoresistance and its tunability in Pd doped FeRh
We report room temperature giant baro-resistance ($\approx$128\%) in $Fe_{49}(Rh_{0.93}Pd_{0.07})_{51}$. With the application of external pressure and magnetic field the temperature range of giant baro-resistance ($\approx$600\% at 5K and 19.9 kbar and 8 Tesla) and magnetoresistance ($\approx$-85\% at 5K and 8 tesla) can be tuned from 5 K to well above room temperature. As the AFM state is stabilized at room temperature under external pressure, it shows giant room temperature magnetoresistance ($\approx$-55\%) with magnetic field. Due to coupled magnetic and latticel changes, the isothermal change in room temperature resistivity with pressure (in the absence of applied magnetic field) as well as magnetic field (under various constant pressure) can be scaled together to a single curve when plotted as a function of X = T + 12.8*H - 7.2*P.
1408.6688v1
2017-01-18
Iron-based superconductivity extended to the novel silicide LaFeSiH
We report the synthesis and characterization of the novel silicide LaFeSiH displaying superconductivity with onset at 11 K. We find that this pnictogen-free compound is isostructural to LaFeAsO, with a similar low-temperature tetragonal to orthorhombic distortion. Using density functional theory we show that this system is also a multiband metal in which the orthorhombic distortion is likely related to single-stripe antiferromagnetic order. Electrical resistivity and magnetic susceptibility measurements reveal that these features occur side-by-side with superconductivity, which is suppressed by external pressure.
1701.05010v3
2017-03-09
Oxygen migration during resistance switching and failure of hafnium oxide memristors
While the recent establishment of the role of thermophoresis/diffusion-driven oxygen migration during resistance switching in metal oxide memristors provided critical insights required for memristor modeling, extended investigations of the role of oxygen migration during ageing and failure remain to be detailed. Such detailing will enable failure-tolerant design, which can lead to enhanced performance of memristor-based next-generation storage-class memory. Here we directly observed lateral oxygen migration using in-situ synchrotron x-ray absorption spectromicroscopy of HfOx memristors during initial resistance switching, wear over millions of switching cycles, and eventual failure, through which we determined potential physical causes of failure. Using this information, we reengineered devices to mitigate three failure mechanisms, and demonstrated an improvement in endurance of about three orders of magnitude.
1703.03106v1
2018-10-09
Electron scattering by short range defects and resistivity of graphene
The electron scattering by the short-range defects in the monolayer graphene is considered in the framework of the flatland model. We analyze the effect of this scattering on the electronic resistivity of the monolayer graphene (direct problem) and develop a procedure for determination of the defect potential from resistivity data (inverse problem). We use an approximation of the short-range perturbation by the delta-shell potential that is reasonable since it suppresses irrelevant short wavelength excitations. Our theoretical results proved to be in a good agreement with experiment on suspended monolayer graphene. It means that our model correctly describes essential features of the physical problem under consideration. It gives possibility to consider the inverse problem, i.e. on the basis of our results for direct problem to develop a procedure for determination of parameters of the monolayer graphene sample using experimental measurements for it. Thus the obtained results give new important possibilities, which can be used in numerous applications.
1810.03897v1
2018-10-16
Studies of two-dimensional MoS2 on enhancing the electrical performance of ultrathin copper films
Copper nanowires are widely used as on-chip interconnects due to superior conductivity. However, with aggressive Cu interconnect scaling, the diffusive surface scattering of electrons drastically increases the electrical resistivity. In this work, we studied the electrical performance of Cu thin films on different materials. By comparing the thickness dependence of Cu films resistivity on MoS2 and SiO2, we demonstrated that two-dimensional MoS2 can be used to enhance the electrical performance of ultrathin Cu films due to a partial specular surface scattering. By fitting the experimental data with the theoretical Fuchs Sondheimer model, we obtained the specularity parameter at the Cu MoS2 interface in the temperature range 2K to 300K. Furthermore, first principle calculations based on the density functional theory indicates that there are more localized states at the Cu amorphous SiO2 interface than the Cu MoS2 interface which is responsible for the higher resistivity in the Cu SiO2 heterostructure due to more severe electron scattering. Our results suggest that Cu MoS2 hybrid is a promising candidate structure for the future generations of CMOS interconnects.
1810.06772v1
2019-02-01
Graph Resistance and Learning from Pairwise Comparisons
We consider the problem of learning the qualities of a collection of items by performing noisy comparisons among them. Following the standard paradigm, we assume there is a fixed "comparison graph" and every neighboring pair of items in this graph is compared $k$ times according to the Bradley-Terry-Luce model (where the probability than an item wins a comparison is proportional the item quality). We are interested in how the relative error in quality estimation scales with the comparison graph in the regime where $k$ is large. We prove that, after a known transition period, the relevant graph-theoretic quantity is the square root of the resistance of the comparison graph. Specifically, we provide an algorithm that is minimax optimal. The algorithm has a relative error decay that scales with the square root of the graph resistance, and provide a matching lower bound (up to log factors). The performance guarantee of our algorithm, both in terms of the graph and the skewness of the item quality distribution, outperforms earlier results.
1902.00141v2
2019-02-06
AlGaN /GaN superlattice based p-channel field effect transistor (pFET) with TMAH treatment
To realize the full spectrum of advantages that the III-nitride materials system offers, the demonstration of p-channel III-nitride based devices is valuable. Authors report the first p-type field effect transistor (pFET) based on an AlGaN/GaN superlattice (SL), grown using MOCVD. Magnesium was used as the p-type dopant. A sheet resistance of 11.6 k{\Omega}/sq, and a contact resistance of 14.9{\Omega}.mm was determined using transmission line measurements (TLM) for a Mg doping of 1.5e19cm^-3 of Mg. Mobilities in the range of 7-10 cm\^2/Vs and a total sheet charge density in the range of 1e13-6e13 cm-2 were measured using room temperature Hall effect measurements. Without Tetramethylammonium hydroxide (TMAH) treatment, the fabricated pFETs had a maximum drain-source current (IDS) of 3mA/mm and an On-Resistance (RON) of 3.48 k{\Omega}.mm, and did not turn-off completely. With TMAH treatment during fabrication, a maximum IDS of 4.5mA/mm, RON of 2.2k{\Omega}.mm, and five orders of current modulation was demonstrated, which is the highest achieved for a p-type transistor based on (Al,Ga)N.
1902.02022v2
2019-02-26
Au-Ge alloys for wide-range low-temperature on-chip thermometry
We present results of a Au-Ge alloy that is useful as a resistance-based thermometer from room temperature down to at least \SI{0.2}{\kelvin}. Over a wide range, the electrical resistivity of the alloy shows a logarithmic temperature dependence, which simultaneously retains the sensitivity required for practical thermometry while also maintaining a relatively modest and easily-measurable value of resistivity. We characterize the sensitivity of the alloy as a possible thermometer and show that it compares favorably to commercially-available temperature sensors. We experimentally identify that the characteristic logarithmic temperature dependence of the alloy stems from Kondo-like behavior induced by the specific heat treatment it undergoes.
1902.10111v2
2019-07-11
DC Electrical Degradation of YSZ: Voltage Controlled Electrical Metallization of A Fast Ion Conducting Insulator
DC electrical degradation as a form of dielectric and resistance breakdown is a common phenomenon in thin-film devices including resistance-switching memory. To obtain design data and to probe the degradation mechanism, highly accelerated lifetime tests (HALT) are often conducted at higher temperatures with thicker samples. While the mechanism is well established in semiconducting oxides such as perovskite titanates, it is not in stabilized zirconia and other fast oxygen-ion conductors that have little electronic conductivity. Here we model the mechanism by an oxygen-driven, transport-limited, metal-insulator transition, which finds support in rich experimental observations - including in situ videos and variable temperature studies - of yttria-stabilized zirconia. They are contrasted with the findings in semiconducting titanates and resistance memory, and provide new insight into ceramic processing with extremely rapid heating and cooling such as flash sintering and melt processing.
1907.05479v2
2020-02-17
Transport mechanism in amorphous molybdenum silicide thin films
Amorphous molybdenum silicide compounds have attracted significant interest for potential device applications, particularly in single-photon detector. In this work, the temperature-dependent resistance and magneto-resistance behaviors were measured to reveal the charge transport mechanism, which is of great importance for applications but is still insufficient. It is found that Mott variable hopping conductivity dominates the transport of sputtered amorphous molybdenum silicide thin films. Additionally, the observed magneto-resistance crossover from negative to positive is ascribed to the interference enhancement and the shrinkage of electron wave function, both of which vary the probability of hopping between localized sites.
2002.06884v3
2020-09-17
Restored strange metal phase through suppression of charge density waves in underdoped YBa$_2$Cu$_3$O$_{7-δ}$
The normal state of optimally doped cuprates is dominated by the "strange metal" phase that shows a linear temperature ($T$) dependence of the resistivity persisting down to the lowest $T$. For underdoped cuprates this behavior is lost below the pseudogap temperature $T^*$, where Charge Density Waves (CDW) together with other intertwined local orders characterize the ground state. Here we show that the $T$-linear resistivity of highly strained, ultrathin and underdoped YBa$_2$Cu$_3$O$_{7-\delta}$ films is restored when the CDW amplitude, detected by Resonant Inelastic X-ray scattering, is suppressed. This observation points towards an intimate connection between the onset of CDW and the departure from $T$-linear resistivity in underdoped cuprates. Our results illustrate the potential of using strain control to manipulate the ground state of quantum materials.
2009.08398v3
2007-10-03
The effect of ozone oxidation on single-walled carbon nanotubes
Exposing single-walled carbon nanotubes to room temperature UV-generated ozone leads to an irreversible increase in their electrical resistance. We demonstrate that the increased resistance is due to ozone oxidation on the sidewalls of the nanotubes rather than at the end caps. Raman and x-ray photoelectron spectroscopy show an increase in the defect density due to the oxidation of the nanotubes. Using ultraviolet photoelectron spectroscopy we show that these defects represent the removal of pi-conjugated electron states near the Fermi level, leading to the observed increase in electrical resistance. Oxidation of carbon nanotubes is an important first step in many chemical functionalization processes. Since the oxidation rate is controllable with short exposures, UV-generated ozone offers the potential for use as a low-thermal budget processing tool.
0710.0803v1
2012-01-13
Intermediate state switching dynamics in magnetic double layer nanopillars grown by molecular beam epitaxy
We observe a stable intermediate resistance switching state in the current perpendicular to plane geometry for all Co/Cu/Co double layer nanopillar junctions grown by molecular beam epitaxy. This novel state has a resistance between the resistances of the parallel and antiparallel alignment of both Co-layer magnetizations. The state, which originates from an additional in-plane magnetic easy axis, can be reached by spin transfer torque switching or by an external magnetic field. In addition to spin torque-induced coherent small-angle spin wave modes we observe a broad microwave emission spectrum. The latter is attributed to incoherent magnetic excitations that lead to a switching between the intermediate state and the parallel or antiparallel alignment of both ferromagnetic layers. We conclude that the additional magnetic easy axis suppresses a stable trajectory of coherent large-angle precession, which is not observed in our samples.
1201.2752v1
2012-01-14
Length dependence of the resistance in graphite: Influence of ballistic transport
Using a linear array of voltage electrodes with a separation of several micrometers on a $20 $nm thick and 30 $\mu$m long multigraphene sample we show that the measured resistance does not follow the usual length dependence according to Ohm's law. The deviations can be quantitatively explained taking into account Sharvin-Knudsen formula for ballistic transport. This allows us to obtain without free parameters the mean free path of the carriers in the sample at different temperatures. In agreement with recently reported values obtained with a different experimental method, we obtain that the carrier mean free path is of the order of $\sim 2 \mu$m with a mobility $\mu \sim 10^7 $cm$^{2}$V$^{-1}$s$^{-1}$. The results indicate that the usual Ohm's law is not adequate to calculate the absolute resistivity of mesoscopic graphite samples.
1201.3004v1
2012-01-14
Temperature dependence of the thermal boundary resistivity of glass-embedded metal nanoparticles
The temperature dependence of the thermal boundary resistivity is investigated in glass-embedded Ag particles of radius 4.5 nm, in the temperature range from 300 to 70 K, using all-optical time-resolved nanocalorimetry. The present results provide a benchmark for theories aiming at explaining the thermal boundary resistivity at the interface between metal nanoparticles and their environment, a topic of great relevance when tailoring thermal energy delivery from nanoparticles as for applications in nanomedicine and thermal management at the nanoscale
1201.3034v1
2014-01-07
Images of edge current in InAs/GaSb quantum wells
Quantum spin Hall devices with edges much longer than several microns do not display ballistic transport: that is, their measured conductances are much less than $e^2/h$ per edge. We imaged edge currents in InAs/GaSb quantum wells with long edges and determined an effective edge resistance. Surprisingly, although the effective edge resistance is much greater than $h/e^2$, it is independent of temperature up to 30 K within experimental resolution. Known candidate scattering mechanisms do not explain our observation of an effective edge resistance that is large yet temperature-independent.
1401.1531v2
2016-03-12
Spin Hall Effect and Origins of Nonlocal Resistance in Adatom-Decorated Graphene
Recent experiments reporting unexpectedly large spin Hall effect (SHE) in graphene decorated with adatoms have raised a fierce controversy. We apply numerically exact Kubo and Landauer- Buttiker formulas to realistic models of gold-decorated disordered graphene (including adatom clustering) to obtain the spin Hall conductivity and spin Hall angle, as well as the nonlocal resistance as a quantity accessible to experiments. Large spin Hall angles of 0.1 are obtained at zero-temperature, but their dependence on adatom clustering differs from the predictions of semiclassical transport theories. Furthermore, we find multiple background contributions to the nonlocal resistance, some of which are unrelated to SHE or any other spin-dependent origin, as well as a strong suppression of SHE at room temperature. This motivates us to design a multiterminal graphene geometry which suppresses these background contributions and could, therefore, quantify the upper limit for spin current generation in two-dimensional materials.
1603.03870v3
2016-03-17
Electrical Writing of Magnetic and Resistive Multistates in CoFe Films Deposited onto Pb[Zr$_x$Ti$_{1-x}$]O$_3$
Electric control of magnetic properties is an important challenge for modern magnetism and spintronic development. In particular, an ability to write magnetic state electrically would be highly beneficial. Among other methods, the use of electric field induced deformation of piezoelectric elements is a promising low-energy approach for magnetization control. We investigate the system of piezoelectric substrate Pb[Zr$_x$Ti$_{1-x}$]O$_3$ with CoFe overlayers, extending the known reversible bistable electro-magnetic coupling to surface and multistate operations, adding the initial state reset possibility. Increasing the CoFe thickness improves the magnetoresistive sensitivity, but at the expenses of decreasing the strain-mediated coupling, with optimum magnetic thin film thickness of the order of 100 nm. The simplest resistance strain gauge structure is realized and discussed as a multistate memory cell demonstrating both resistive memory (RRAM) and magnetoresistive memory (MRAM) functionalities in a single structure.
1603.05476v1
2018-08-26
Supercondutivity in SnSb with natural superlattice structure
We report the results of electrical resistivity, magnetic and thermodynamic measurements on polycrystalline SnSb, whose structure consists of stacks of Sb bilayers and Sn4Sb3 septuple layers along the c-axis. The material is found to be a weakly coupled, fully gapped, type-II superconductor with a bulk Tc of 1.50 K, while showing a zero resistivity transition at a significantly higher temperature of 2.48 K. The Sommerfeld coefficient and upper critical field, obtained from specific heat measurements, are 2.29 mJ/mol K and 520 Oe, respectively. Compositional inhomogeneity and strain effect at the grain boundaries are proposed as possible origins for the difference in resistive and bulk superconducting transitions.In addition, a comparison with the rock-salt structure SnAs superconductor is presented. Our results provide the first clear evidence of bulk superconductivity in a natural superlattice derived from a topological semimetal.
1808.08500v2
2019-03-03
Scaling parameters in anomalous and nonlinear Hall effects depend on temperature
In the study of the anomalous Hall effect, the scaling relations between the anomalous Hall and longitudinal resistivities play the central role. The scaling parameters by definition are fixed as the scaling variable (longitudinal resistivity) changes. Contrary to this paradigm, we unveil that the electron-phonon scattering can result in apparent temperature-dependence of scaling parameters when the longitudinal resistivity is tuned through temperature. An experimental approach is proposed to observe this hitherto unexpected temperature-dependence. We further show that this phenomenon also exists in the nonlinear Hall effect in nonmagnetic inversion-breaking materials and may help identify experimentally the presence of the side-jump contribution besides the Berry-curvature dipole.
1903.00810v5
2019-03-19
Composition dependence of magnetoresistance in Fe$_{1-x}$Ni$_{x}$ alloys
Resistance of Fe$_{1-x}$Ni$_x$(x=0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7 and 0.9) has been measured using four probe method from 5K to 300K with and without a longitudinal magnetic field of 8T. The zero field resistivity of x=0.1 and 0.9 alloys, predominant contribution to resistivity above near room temperature is due to electron-phonon scattering, whereas for x=05 and 0.7 alloys electron-magnon scattering is dominant. Alloys with x=0.1 and 0.9 exhibit positive magnetoresistance(MR) from 5K to 300K. For x=0.5 and 0.7 alloys, magnetoresistance changes sign from positive to negative with increase in temperature. The temperature at which sign changes increase with Ni concentration in the alloy. The field dependent magnetoresistance is positive for x=0.1, 0.7 and 0.9 alloys whereas it is negative for x=0.5 alloy. MR follows linear behaviour with field for x=0.1 alloy. MR of all other alloys follow a second order polynomial in field.
1903.08230v3
2019-03-26
Controlled inter-state switching between quantized conductance states in resistive devices for multilevel memory
A detailed understanding of quantization conductance (QC), their correlation with resistive switching phenomena and controlled manipulation of quantized states is crucial for realizing atomic-scale multilevel memory elements. Here, we demonstrate highly stable and reproducible quantized conductance states (QC-states) in Al/Niobium oxide/Pt resistive switching devices. Three levels of control over the QC-states, required for multilevel quantized state memories, like, switching ON to different quantized states, switching OFF from quantized states, and controlled inter-state switching among one QC states to another has been demonstrated by imposing limiting conditions of stop-voltage and current compliance. The well defined multiple QC-states along with a working principle for switching among various states show promise for implementation of multilevel memory devices.
1903.10688v1
2019-12-11
Current-induced fragmentation of antiferromagnetic domains
Electrical and optical pulsing allow for manipulating the order parameter and magnetoresistance of antiferromagnets, opening novel prospects for digital and analog data storage in spintronic devices. Recent experiments in CuMnAs have demonstrated giant resistive switching signals in single-layer antiferromagnetic films together with analog switching and relaxation characteristics relevant for neuromorphic computing. Here we report simultaneous electrical pulsing and scanning NV magnetometry of antiferromagnetic domains in CuMnAs performed using a pump-probe scheme. We observe a nano-scale fragmentation of the antiferromagnetic domains, which is controlled by the current amplitude and independent on the current direction. The fragmented antiferromagnetic state conserves a memory of the pristine domain pattern, towards which it relaxes. Domain fragmentation coexists with permanent switching due to the reorientation of the antiferromagnetic moments. Our simultaneous imaging and resistance measurements show a correlation between the antiferromagnetic domain fragmentation and the largest resistive switching signals in CuMnAs.
1912.05287v1
2019-12-12
Aharonov-Bohm oscillations of four-probe resistance in topological quantum rings in silicene and bilayer graphene
We consider observation of Aharonov-Bohm oscillations in clean systems based on the flow of topologically protected currents in silicene and bilayer graphene. The chiral channels in these materials are defined by the flips of the vertical electric field. The line of the flip confines chiral currents flowing along it in the direction determined by the valley. We present an electric field profile that forms a crossed ring to which four terminals can be attached, and find that the conductance matrix elements oscillate in the perpendicular magnetic field in spite of the absence of backscattering. We propose a four-probe resistance measurement setup, and demonstrate that the resistance oscillations have large visibility provided that the system is prepared in such a way that a direct transfer of the chiral carriers between the current probes is forbidden.
1912.05876v2
2021-01-13
Hinge Spin Polarization in Magnetic Topological Insulators Revealed by Resistance Switch
We report on the possibility to detect hinge spin polarization in magnetic topological insulators by resistance measurements. By implementing a three-dimensional model of magnetic topological insulators into a multi-terminal device with ferromagnetic contacts near the top surface, local spin features of the chiral edge modes are unveiled. We find local spin polarization at the hinges that inverts sign between top and bottom surfaces. At the opposite edge, the topological state with inverted spin polarization propagates in the reverse direction. Large resistance switch between forward and backward propagating states is obtained, driven by the matching between the spin polarized hinges and the ferromagnetic contacts. This feature is general to the ferromagnetic, antiferromagnetic and canted-antiferromagnetic phases, and enables the design of spin-sensitive devices, with the possibility of reversing the hinge spin polarization of the currents.
2101.05293v2
2021-01-26
Demystifying strange metal and violation of Luttinger theorem in a doped Mott insulator
Metallic states coined strange metal (SM), with robust linear-$T$ resistivity, have been widely observed in many quantum materials under strong electron correlation, ranging from high-$T_{c}$ cuprate superconductor, organic superconductor to twisted multilayer graphene and MoTe$_{2}$/WSe$_{2}$ superlattice. Despite decades of intensive studies, the mystery of strange metal still defies any sensible theoretical explanation and has been the key puzzle in modern condensed matter physics. Here, we solve a doped Mott insulator model, which unambiguously exhibits SM phenomena accompanied with quantum critical scaling in observables, e.g. resistivity, susceptibility and specific heat. Closer look at SM reveals the breakdown of Landau's Fermi liquid without any symmetry-breaking, i.e. the violation of Luttinger theorem. Examining electron's self-energy extracted from numerical simulation provides the explanation on the origin of linear-$T$ resistivity and suggests that the long-overlooked static fluctuations in literature play an essential role in non-Fermi liquid behaviors in correlated electron systems.
2101.10611v3
2012-06-15
A ferroelectric memristor
Memristors are continuously tunable resistors that emulate synapses. Conceptualized in the 1970s, they traditionally operate by voltage-induced displacements of matter, but the mechanism remains controversial. Purely electronic memristors have recently emerged based on well-established physical phenomena with albeit modest resistance changes. Here we demonstrate that voltage-controlled domain configurations in ferroelectric tunnel barriers yield memristive behaviour with resistance variations exceeding two orders of magnitude and a 10 ns operation speed. Using models of ferroelectric-domain nucleation and growth we explain the quasi-continuous resistance variations and derive a simple analytical expression for the memristive effect. Our results suggest new opportunities for ferroelectrics as the hardware basis of future neuromorphic computational architectures.
1206.3397v1
2015-04-30
Study of the Negative Magneto-Resistance of Single Proton-Implanted Lithium-Doped ZnO Microwires
The magneto-transport properties of single proton-implanted ZnO and of Li(7\%)-doped ZnO microwires have been studied. The as-grown microwires were highly insulating and not magnetic. After proton implantation the Li(7\%) doped ZnO microwires showed a non monotonous behavior of the negative magneto-resistance (MR) at temperature above 150 K. This is in contrast to the monotonous NMR observed below 50 K for proton-implanted ZnO. The observed difference in the transport properties of the wires is related to the amount of stable Zn vacancies created at the near surface region by the proton implantation and Li doping. The magnetic field dependence of the resistance might be explained by the formation of a magnetic/non magnetic heterostructure in the wire after proton implantation.
1504.08230v1
2015-07-29
Integration of a 2D Periodic Nanopattern Into Thin Film Polycrystalline Silicon Solar Cells by Nanoimprint Lithography
The integration of two-dimensional (2D) periodic nanopattern defined by nanoimprint lithography and dry etching into aluminum induced crystallization (AIC) based polycrystalline silicon (Poly-Si) thin film solar cells is investigated experimentally. Compared to the unpatterned cell an increase of 6% in the light absorption has been achieved thanks to the nanopattern which, in turn, increased the short circuit current from 20.6 mA/cm2 to 23.8 mA/cm2. The efficiency, on the other hand, has limitedly increased from 6.4% to 6.7%. We show using the transfer length method (TLM) that the surface topography modification caused by the nanopattern has increased the sheet resistance of the antireflection coating (ARC) layer as well as the contact resistance between the ARC layer and the emitter front contacts. This, in turn, resulted in increased series resistance of the nanopatterned cell which has translated into a decreased fill factor, explaining the limited increase in efficiency.
1507.08341v1
2019-06-03
Observations of zero electrical resistance of Au-Ag thin films near room temperature
Recent observations of superconducting like transition at 286 K in Ag and Ag nanostructures by Thapa et al. (arxiv: 1807.08572) have rekindled the hope for room temperature superconductivity under ambient conditions. We also investigated the electrical properties of Ag-Au nanostructure in the form of thin film grown on SiO2/Si substrate by DC sputtering and observed signature of zero resistance in the temperatures range of 243 K to 275 K. While the observed electrical resistance of samples shows intriguing and perplexing behavior under temperature cycling and external magnetic field; the large spatial inhomogeneity present in thin film hampers the reproducibility indicating the stability issues associated with superconducting like phase.
1906.00708v1
2019-06-24
Combination of informational storage and logical processing based on an all-oxide asymmetric multiferroic tunnel junction
Multiferroic tunnel junctions (MFTJs) have already been proved to be promising candidates for application in spintronics devices. The coupling between tunnel magnetoresistance (TMR) and tunnel electroresistance (TER) in MFTJs can provide four distinct resistive states in a single memory cell. Here we show that in an all-oxide asymmetric MFTJ of La0.7Sr0.3MnO3 /PbZr0.2Ti0.8O3 /La0.7Te0.3MnO3 (LSMO/PZT/LTMO) with p-type and n-type electrodes, the intrinsic rectification is observed and can be modified by the ferroelectric polarization of PZT. Owing to the combined TMR, TER and diode effects, two different groups of four resistive states under opposite reading biases are performed. With two parallel asymmetric junctions and the appropriate series resistance, the coexistence of logic units and quaternary memory cells can be realized in the same array devices. The asymmetric MFTJ structure enables more possibilities for designing next generation of multi-states memory and logical devices with higher storage density, lower energy consumption and significantly increased integration level.
1906.09993v1
2019-10-04
Nonvolatile Multilevel States in Multiferroic Tunnel Junctions
Manipulation of tunneling spin-polarized electrons via a ferroelectric interlayer sandwiched between two ferromagnetic electrodes, dubbed Multiferroic Tunnel Junctions (MFTJs), can be achieved not only by the magnetic alignments of two ferromagnets but also by the electric polarization of the ferroelectric interlayer, providing great opportunities for next-generation multi-state memory devices. Here we show that a La0.67Sr0.33MnO3 (LSMO)/PbZr0.2Ti0.8O3(PZT)/Co structured MFTJ device can exhibit multilevel resistance states in the presence of gradually reversed ferroelectric domains via tunneling electro-resistance and tunneling magnetoresistance, respectively. The nonvolatile ferroelectric control in the MFTJ can be attributed to separate contributions arising from two independent ferroelectric channels in the PZT interlayer with opposite polarization. Our study shows the dominant role of "mixed" ferroelectric states on achieving accumulative electrical modulation of multilevel resistance states in MFTJs, paving the way for multifunctional device applications.
1910.02002v1
2020-06-02
Ultra-fast Kinematic Vortices in Mesoscopic Superconductors: The Effect of the Self-Field
Within the framework of the generalized time-dependent Ginzburg-Landau equations, we studied the influence of the magnetic self-field induced by the currents inside a superconducting sample driven by an applied transport current. The numerical simulations of the resistive state of the system show that neither material inhomogeneity nor a normal contact smaller than the sample width are required to produce an inhomogeneous current distribution inside the sample, which leads to the emergence of a kinematic vortex-antivortex pair (vortex street) solution. Further, we discuss the behaviors of the kinematic vortex velocity, the annihilation rates of the supercurrent, and the superconducting order parameters alongside the vortex street solution. We prove that these two latter points explain the characteristics of the resistive state of the system. They are the fundamental basis to describe the peak of the current-resistance characteristic curve and the location where the vortex-antivortex pair is formed.
2006.01335v1
2020-07-09
Coupling-independent, Real-time Wireless Resistive Sensing through Nonlinear PT-symmetry
We report the realization of coupling-independent, robust wireless sensing of fully-passive resistive sensors. PT-symmetric operation obviates sweeping, permitting real-time, single-point sensing. Self-oscillation is achieved through a fast-settling nonlinearity whose voltage amplitude is proportional to the sensor's resistance. These advances markedly simplify the reader. A dual time-scale theoretical framework generalizes system analysis to arbitrary operating conditions and a correction strategy reduces errors due to detuning from PT-symmetric conditions by an order of magnitude.
2007.05077v4
2020-07-29
An electro-thermal computational study of conducting channels in dielectric thin films using self-consistent phase-field methodology: A view toward the physical origins of resistive switching
A large number of experimental studies suggest two-terminal resistive switching devices made of a dielectric thin film sandwiched by a pair of electrodes exhibit reversible multi-state switching behaviors; however coherent understanding of physical and chemical origins of their electrical properties needs to be further pursued to improve and customize the performance. In this paper, phase-field methodology is used to study the formation and annihilation of conductive channels resulting in reversible resistive switching behaviors that can generally occur in any dielectric thin films. Our focus is on the dynamical evolution of domains made of electrical charges under the influence of spatially varying electric field and temperature resulting in distinctive changes in electrical conductance.
2007.15123v1
2020-08-24
Peierls-type metal-insulator transition in carbon nanostructures
We report the observation of Peierls-type metal-insulator transition in carbon nanostructures formed by chemical vapor deposition inside the pore network of the ZSM-5 zeolite. The Raman spectrum of this nanocarbon@ZSM-5 indicates a clear signature of the radial breathing mode (RBM) for (3,0) carbon nanotubes that can constitute the carbon network segments. Electrical transport measurements on multiple few-micron-sized nanocarbon@ZSM-5 crystals showed metallic temperature of resistance dependence down to 30 K, at which point the resistance exhibited a sharp upturn that is accompanied by the opening of a quasigap at the Fermi level as indicated by the differential resistance measurements. Further Hall measurements have yielded both the sign of the charge carrier and its density. The latter demonstrated excellent consistency with the quasigap data. We employed first-principles calculations to verify that there can indeed be softening of the phonon modes in the (3,0) carbon nanotubes.
2008.10160v1
2020-10-22
Electrical and Thermal Transport Properties of the beta-Pyrochlore Oxide CsW2O6
We report the electrical resistivity, thermoelectric power, and thermal conductivity of single-crystalline and sintered samples of the 5d pyrochlore oxide CsW2O6. The electrical resistivity of the single crystal is 3 mohm cm at 295 K and gradually increases with decreasing temperature above 215 K (Phase I). The thermoelectric power of the single-crystalline and sintered samples shows a constant value of approximately -60 uV K-1 in Phase I. These results reflect that the electron conduction by W 5d electrons in Phase I is incoherent and in the hopping regime, although a band gap does not open at the Fermi level. The thermal conductivity in Phase I of both samples is considerably low, which might be due to the rattling of Cs+ ions. In Phase II below 215 K, the electrical resistivity and the absolute value of thermoelectric power of both samples strongly increase with decreasing temperature, corresponding to a transition to a semiconducting state with a band gap open at the Fermi level, while the thermal conductivity in Phase II is smaller than that in Phase I.
2010.11404v1
2020-11-11
Elastic turbulence generates anomalous flow resistance in porous media
Diverse processes rely on the viscous flow of polymer solutions through porous media. In many cases, the macroscopic flow resistance abruptly increases above a threshold flow rate in a porous medium---but not in bulk solution. The reason why has been a puzzle for over half a century. Here, by directly visualizing the flow in a transparent 3D porous medium, we demonstrate that this anomalous increase is due to the onset of an elastic instability. We establish that the energy dissipated by the unstable flow fluctuations, which vary across pores, generates the anomalous increase in flow resistance through the entire medium. Thus, by linking the pore-scale onset of unstable flow to macroscopic transport, our work provides generally-applicable guidelines for predicting and controlling polymer solution flows.
2011.06036v1
2021-02-08
Double magnetic phase transitions and magnetotransport anomalies in a new compound Gd$_\textbf{2}$AgSi$_\textbf{3}$
Dc and ac-magnetic susceptibility ($\chi$), specific heat ($C_\mathrm{P}$), electrical resistivity ($\rho$) and magnetoresistance measurements performed on the new polycrystalline compound $\mathrm{Gd_2AgSi_3}$, crystallizing in the $\alpha$-$\mathrm{ThSi_2}$ tetragonal structure, are reported. Two magnetic phase transitions were observed in dc and ac susceptibility, specific heat, and resistivity measurements at temperatures $\mathrm{T_{N_1}} = 11$ K and $\rm{T_{N_2}} = 20$ K, despite a single site occupied by Gd atom, which is an indication of the complex magnetic behavior. $\mathrm{Gd_2AgSi_3}$ turns out to be one of the rare Gd compound in which a minimum is observed in the temperature dependence of resistivity in the paramagnetic state and also negative magnetoresistance over a wide temperature range (above $\rm{T_{N_2}}$), mimicking the behavior of exotic $\mathrm{Gd_2PdSi_3}$, in this ternary family. The isothermal magnetic entropy and adiabatic temperature changes reach a value of 9.5 J/kg-K and 7.5 K respectively for the field change of 9 T.
2102.04096v2
2021-04-23
Ab initio inspection of thermophysical experiments for zirconium near melting
We present quantum molecular dynamics calculations of thermophysical properties of solid and liquid zirconium in the vicinity of melting. An overview of available experimental data is also presented. We focus on the analysis of thermal expansion, molar enthalpy, resistivity and normal spectral emissivity of solid and liquid Zr. Possible reasons of discrepancies between the first-principle simulations and experiments are discussed. Our calculations reveal a significant volume change on melting in agreement with electrostatic levitation experiments. Meanwhile, we confirm a low value of enthalpy of fusion obtained in some pulse-heating experiments. Electrical resistivity of solid and liquid Zr is systematically underestimated in our simulations, however the slope of resistivity temperature dependencies agrees with experiment. Our calculations predict almost constant normal spectral emissivity in liquid Zr.
2104.11521v2
2021-06-16
Statistical Analysis of Contacts to Synthetic Monolayer MoS2
Two-dimensional (2D) semiconductors are promising candidates for scaled transistors because they are immune to mobility degradation at the monolayer limit. However, sub-10 nm scaling of 2D semiconductors, such as MoS2, is limited by the contact resistance. In this work, we show for the first time a statistical study of Au contacts to chemical vapor deposited monolayer MoS2 using transmission line model (TLM) structures, before and after dielectric encapsulation. We report contact resistance values as low as 330 ohm-um, which is the lowest value reported to date. We further study the effect of Al2O3 encapsulation on variability in contact resistance and other device metrics. Finally, we note some deviations in the TLM model for short-channel devices in the back-gated configuration and discuss possible modifications to improve the model accuracy.
2106.08673v3
2021-06-19
Dopant Precursor Adsorption into Single-Dimer Windows: Towards Guided Self-Assembly of Dopant Arrays on Si(100)
Atomically precise dopant arrays in Si are being pursued for solid-state quantum computing applications. We propose a guided self-assembly process to produce atomically precise arrays of single dopant atoms in lieu of lithographic patterning. We leverage the self-assembled c(4x2) structure formed on Br- and I-Si(100) and investigate molecular precursor adsorption into the generated array of single-dimer window (SDW) adsorption sites with density functional theory (DFT). The adsorption of several technologically relevant dopant precursors (PH$_3$, BCl$_3$, AlCl$_3$, GaCl$_3$) into SDWs formed with various resists (H, Cl, Br, I) are explored to identify the effects of steric interactions. PH$_3$ adsorbed without barrier on all resists studied, while BCl$_3$ exhibited the largest adsorption barrier, 0.34 eV, with an I resist. Dense arrays of AlCl$_3$ were found to form within experimentally realizable conditions demonstrating the potential for the proposed use of guided self-assembly for atomically precise fabrication of dopant-based devices.
2106.10556v1
2021-07-07
Large Magneto-Electric Resistance in the Topological Dirac Semimetal alpha Sn
The spin-momentum locking of surface states in topological quantum materials can produce a resistance that scales linearly with magnetic and electric fields. Such a bilinear magneto-electric resistance (BMER) effect offers a completely new approach for magnetic storage and magnetic field sensing applications. The effects demonstrated so far, however, are relatively weak or for low temperatures. Strong room-temperature BMER effects have now been found in topological Dirac semimetal alpha-Sn thin films. The epitaxial alpha-Sn films were grown by sputtering on silicon substrates. They showed BMER responses that are 10^6 times larger than previously reported at room temperature and also larger than that previously reported at low temperatures. These results represent a major advance toward realistic BMER applications. The data also made possible the first characterization of the three-dimensional, Fermi-level spin texture of topological surface states in alpha-Sn.
2107.03472v1
2021-10-21
Magnetic critical behavior and anomalous Hall effect in 2H-Co$_{0.22}$TaS$_{2}$ single crystals
We report ferromagnetism in 2H-Co$_{0.22}$TaS$_2$ single crystals where Co atoms are intercalated in the van der Waals gap, and a systematic study of its magnetic critical behavior in the vicinity of $T_c \sim 28$ K. The obtained critical exponents $\beta$ = 0.43(2), $\gamma$ = 1.15(1), and $\delta = 3.54(1)$ fulfill the Widom scaling relation $\delta = 1+\gamma/\beta$ and follow the scaling equation. This indicates that the spin coupling in 2H-Co$_{0.22}$TaS$_2$ is of three-dimensional Hersenberg type coupled with long-range magnetic interaction, and that the exchange interaction decays with distance as $J(r)\approx r^{-4.69}$. 2H-Co$_{0.22}$TaS$_2$ exhibits a weak temperature-dependent metallic behavior in resistivity and negative values of thermopower with dominant electron-type carriers, in which obvious anomalies were observed below $T_c$ as well as the anomalous Hall effect (AHE). The linear scaling behavior between the modified anomalous Hall resistivity $\rho_{xy}/\mu_0H$ and longitudinal resistivity $\rho_{xx}^2M/\mu_0H$ implies that the origin of AHE in 2H-Co$_{0.22}$TaS$_2$ should be dominated by the extrinsic side-jump mechanism.
2110.11350v1
2022-01-21
Anomalous metals: from "failed superconductor" to "failed insulator"
Resistivity saturation is found on both superconducting and insulating sides of an "avoided" magnetic-field-tuned superconductor-to-insulator transition (H-SIT) in a two-dimensional In/InO$_x$ composite, where the anomalous metallic behaviors cut off conductivity or resistivity divergence in the zero-temperature limit. The granular morphology of the material implies a system of Josephson junctions (JJ) with a broad distribution of Josephson coupling E$_J$ and charging energy E$_C$ , with a H-SIT determined by the competition between E$_J$ and E$_C$ . By virtue of self-duality across the true H-SIT, we invoke macroscopic quantum tunneling effects to explain the temperature-independent resistance where the "failed superconductor" side is a consequence of phase fluctuations and the "failed insulator" side results from charge fluctuations. While true self-duality is lost in the avoided transition, its vestiges are argued to persist, owing to the incipient duality of the percolative nature of the dissipative path in the underlying random JJ system.
2201.08801v1
2022-03-12
Quantifying active and resistive stresses in adherent cells
To understand cell migration, it is crucial to gain knowledge on how cells exert and integrate forces on/from their environment. A quantity of prime interest for biophysicists interested in cell movements modeling is the intracellular stresses. Up to now, three different methods have been proposed to calculate it, they are all in the regime of the thin plate approximation. Two are based on solving the mechanical equilibrium equation inside the cell material (Monolayer Stress Microscopy, and Bayesian Inference Stress Microscopy) and one is based on the continuity of displacement at the cell/substrate interface (Intracellular Stress Microscopy). We show here using 3D FEM modeling that these techniques do not calculate the same quantities (as was previously assumed), the first techniques calculate the sum of the active and resistive stresses within the cell, whereas the last one only calculate the resistive component. Combining these techniques should in principle permit to get access to the active stress alone.
2203.06475v2
2022-03-23
Quantum oscillations and weak anisotropic resistivity in the chiral Fermion semimetal PdGa
We perform a detailed analysis of the magnetotransport and de Haas-van Alphen (dHvA) oscillations in crystal PdGa which is predicted to be a typical chiral Fermion semimetal from CoSi family holding a large Chern number. The unsaturated quadratic magnetoresistance (MR) and nonlinear Hall resistivity indicate that PdGa is a multi-band system without electron-hole compensation. Angle-dependent resistivity in PdGa shows weak anisotropy with twofold or threefold symmetry when the magnetic field rotates within the (1$\bar{1}$0) or (111) plane perpendicular to the current. Nine or three frequencies are extracted after the fast Fourier-transform analysis (FFT) of the dHvA oscillations with B//[001] or B//[011], respectively, which is confirmed to be consistent with the Fermi surfaces (FSs) obtained from first-principles calculations with spin-orbit coupling (SOC) considered.
2203.12772v1
2022-05-04
Percolative Superconductivity in Electron-Doped Sr$_{1-x}$Eu$_{x}$CuO$_{2+y}$ Films
Electron-doped infinite-layer Sr$_{1-x}$Eu$_{x}$CuO$_{2+y}$ films over a wide doping range have been prepared epitaxially on SrTiO$_3$(001) using reactive molecular beam epitaxy. In-plane transport measurements of the single crystalline samples reveal a dome-shaped nodeless superconducting phase centered at $x$ $\sim$ 0.15, a Fermi-liquid behavior and pronounced upturn in low temperature resistivity. We show that the resistivity upturn follows square-root temperature dependence, suggesting the emergence of superconductivity via a three-dimensional percolation process. The percolative superconductivity is corroborated spectroscopically by imaging the electronic phase separation between superconducting and metallic phases with low-temperature scanning tunneling microscopy. Furthermore, we visualize interstitial and apical oxygen anions that rapidly increase in number as $x>$ 0.12, and elucidate their impacts on the superconductivity and normal-state resistivity.
2205.01844v1
2022-05-10
Effect of substrate temperature on the optoelectronic properties of DC magnetron sputtered copper oxide films
Copper oxide thin films are deposited on quartz substrates by DC magnetron sputtering and the effect of deposition temperature on their optoelectronic properties is examined in detail. Scanning Electron Microscopy (SEM), X-ray diffraction (XRD) analysis, Raman spectroscopy, UV-Vis spectroscopy, and four-probe sheet resistance measurements are used to characterize the surface morphology, structural, optical, and electrical properties respectively. Deposition is carried out at room temperature and between 200 and 300 {\deg}C. XRD analysis indicates that the oxide formed is primarily Cu$_2$O and the absorption spectra show the films have a critical absorption edge at around 300 nm. The sheet resistance gradually decreases with increase in deposition temperature thereby increasing the conductivity of these thin films. Also observed is the increase in band gap from 2.20 eV for room temperature deposition to 2.35 eV at 300 {\deg}C. The optical band gap and the variation of sheet resistance with temperature shows that the microstructure plays a vital role in their behavior. These transformation characteristics are of huge technological importance having variety of applications including transparent solar cell fabrication.
2205.05615v1
2022-08-10
Spin-carrier coupling induced ferromagnetism and giant resistivity peak in EuCd$_2$P$_2$
EuCd$_2$P$_2$ is notable for its unconventional transport: upon cooling the metallic resistivity changes slope and begins to increase, ultimately 100-fold, before returning to its metallic value. Surprisingly, this giant peak occurs at 18K, well above the N\'{e}el temperature ($T_N$) of 11.5K. Using a suite of sensitive probes of magnetism, including resonant x-ray scattering and magneto-optical polarimetry, we have discovered that ferromagnetic order onsets above $T_N$ in the temperature range of the resistivity peak. The observation of inverted hysteresis in this regime shows that ferromagnetism is promoted by coupling of localized spins and itinerant carriers. The resulting carrier localization is confirmed by optical conductivity measurements.
2208.05499v1
2022-10-04
Time-domain impedance method for transient photovoltage analysis
In this work, we approximate the surface photovoltage (SPV) transients in nm-sized ZnO films by the equivalent RC circuit model. The SPV rises in time in time for about 90 mcs after the exciting light pulse at 275 nm is off at different pulse widths ranging from 1.2 to 12 mcs. The key to this observation is a considerable amount of defects in the films, which form a trap capacitance in the equivalent circuit. The photogeneration of nonequilibrium electrons and holes near the film surface is described by charging of a capacitance by the current source whereas the rate of their spatial separation is determined by a resistance. This resistance reflects an obstacle in the carrier movement while another capacitance determines the charge separation distance. The electron-hole recombination is account for a second resistance introduced into the equivalent circuit. The resulting modeled SPV transient allows to reproduce the observed experimental curve rather well.
2210.07928v1
2022-10-17
Multiscale modeling of resistive switching in gold nanogranular films
Metallic nanogranular films display a complex dynamical response to a constant bias, showing up as atypical resistive switching mechanism which could be used to create electrical components for neuromorphic applications. To model such a phenomenon we use a multiscale approach blending together an ab initio treatment of the electric current at the nanoscale, a molecular dynamical approach dictating structural rearrangements, and a finite-element solution of the heat equation for heat propagation in the sample. We also consider structural changes due to electromigration which are modelled on the basis of experimental observations on similar systems. Within such an approach, we manage to describe some distinctive features of the resistive switching occurring in nanogranular film and provide a physical interpretation at the microscopic level.
2210.09379v1
2022-10-27
Green's Functions For Random Resistor Networks
We analyze random resistor networks through a study of lattice Green's functions in arbitrary dimensions. We develop a systematic disorder perturbation expansion to describe the weak disorder regime of such a system. We use this formulation to compute ensemble averaged nodal voltages and bond currents in a hierarchical fashion. We verify the validity of this expansion with direct numerical simulations of a square lattice with resistances at each bond exponentially distributed. Additionally, we construct a formalism to recursively obtain the exact Green's functions for finitely many disordered bonds. We provide explicit expressions for lattices with up to four disordered bonds, which can be used to predict nodal voltage distributions for arbitrarily large disorder strengths. Finally, we introduce a novel order parameter that measures the overlap between the bond current and the optimal path (the path of least resistance), for a given resistance configuration, which helps to characterize the weak and strong disorder regimes of the system.
2210.15562v3
2022-12-19
Anisotropic resistance with a 90-degree twist in a ferromagnetic Weyl semimetal, Co2MnGa
Co$_2$MnGa is a ferromagnetic semimetal with Weyl nodal lines identified by ARPES. We studied electrical transport in thin Co$_2$MnGa lamellae (10 $\times$ 10 $\times$ 0.4-5 microns) cut from single-crystals using a focused ion beam. These crystals exhibit an unexpected and highly unusual planar resistance anisotropy ($\sim$10 times) with principal axes that rotate by 90 degrees between the upper and lower faces. Using symmetry arguments and simulations, we find that the observed resistance anisotropy resembles that of an isotropic conductor with anisotropic surface states that are impeded from hybridization with bulk states. The origin of these states awaits further experiments that can correlate the surface bands with the observed 90$^\circ$-twist geometry.
2212.09738v1
2022-12-29
Stateful Logic using Phase Change Memory
Stateful logic is a digital processing-in-memory technique that could address von Neumann memory bottleneck challenges while maintaining backward compatibility with standard von Neumann architectures. In stateful logic, memory cells are used to perform the logic operations without reading or moving any data outside the memory array. Stateful logic has been previously demonstrated using several resistive memory types, mostly by resistive RAM (RRAM). Here we present a new method to design stateful logic using a different resistive memory - phase change memory (PCM). We propose and experimentally demonstrate four logic gate types (NOR, IMPLY, OR, NIMP) using commonly used PCM materials. Our stateful logic circuits are different than previously proposed circuits due to the different switching mechanism and functionality of PCM compared to RRAM. Since the proposed stateful logic form a functionally complete set, these gates enable sequential execution of any logic function within the memory, paving the way to PCM-based digital processing-in-memory systems.
2212.14377v1
2023-03-15
Two-fold anisotropic superconducting state in topological superconductor Sn$_4$Au
Here we report the anisotropic magnetotransport properties in the superconducting state of Sn$_4$Au single crystal. Sn$_4$Au single crystal is synthesized through an easy melt growth method. Superconducting properties are evidenced by resistivity vs. temperature and DC magnetization measurements. Isothermal magnetization measurements hint toward type-II superconductivity in Sn$_4$Au. In-plane and out-of-plane resistivity measurements show anisotropic behavior of the upper critical field at temperatures below superconducting transition (T$_c$ = 2.3 K). The observed anisotropy is more elucidated in resistivity measurements performed below Tc at different tilt angles. The anisotropy parameter is found to be 1.26. The observed results show the presence two-fold anisotropic superconducting state in Sn$_4$Au single crystal, which may be induced due to the layered structure of synthesized Sn$_4$Au single crystal.
2303.08520v1
2023-03-28
Effect of atomic anti-site disorder on the AMR in FeCo alloys
In order to understand the anti-site disorder effect on the anisotropic magnetoresistance (AMR) effect in alloys, $\rm{Fe}_{50}Co_{50}$ alloys were studied in this work using the fully relativistic spin-polarized screened (KKR) method. The anti-site effect was modeled by interchanging Fe and Co atoms and treated by the coherent potential approximation (CPA). We find that the anti-site disorder broadens the spectral function and decreases the conductivity. Our work emphasizes that the absolute variations of resistivity under magnetic moment rotation are less affected by atomic disorders. The annealing procedure improves the AMR by reduction of the total resistivity. At the same time, we also find that the fourth-order term in the angular dependent resistivity becomes weaker when the disorder increases, resulting from increased scattering of the states around the band-crossing.
2303.15726v1
2023-03-28
Superconductivity in boron-doped carbon nanotube networks
By using the five Angstrom diameter pores of calcined zeolite as the template, we have fabricated boron doped carbon nanotube networks via the chemical vapor deposition method. Raman data indicate the network to comprise segments of interconnected carbon nano tubes. Transport measurements showed a superconducting transition initiating at 40K, with a sharp downturn around 20K to a low resistance state at 2K, accompanied by a low resistance plateau in the current voltage characteristic, fluctuating around zero resistance. Magnetic measurements exhibited the Meissner effect characteristic of thin superconducting wire networks in which the superconducting wire radius is much smaller than the London penetration length. At low magnetic field, the negative diamagnetic susceptibility was observed to persist beyond 200K. The transport and magnetic data are reconciled on the basis of a physical model based on weak links comprising short, one-dimensional superconducting nano tubes, that govern the global transport behavior.
2303.15980v1
2023-04-12
Measuring a Soft Resistive Strain Sensor Array by Solving the Resistor Network Inverse Problem
Soft robotics is applicable to a variety of domains due to the adaptability offered by the soft and compliant materials. To develop future intelligent soft robots, soft sensors that can capture deformation with nearly infinite degree-of-freedom are necessary. Soft sensor networks can address this problem, however, measuring all sensor values throughout the body requires excessive wiring and complex fabrication that may hinder robot performance. We circumvent these challenges by developing a non-invasive measurement technique, which is based on an algorithm that solves the inverse problem of resistor network, and implement this algorithm on a soft resistive, strain sensor network. Our algorithm works by iteratively computing the resistor values based on the applied boundary voltage and current responses, and we analyze the reconstruction error of the algorithm as a function of network size and measurement error. We further develop electronics setup to implement our algorithm on a stretchable resistive strain sensor network made of soft conductive silicone, and show the response of the measured network to different deformation modes. Our work opens a new path to address the challenge of measuring many sensor values in soft sensors, and could be applied to soft robotic sensor systems.
2304.05828v1
2023-05-22
Ion-selective scattering studied by the variable-energy electron irradiation of Ba$_{0.2}$K$_{0.8}$Fe$_2$As$_2$ superconductor
Low-temperature variable-energy electron irradiation was used to induce non-magnetic disorder in a single crystal of hole-doped iron-based superconductor, Ba$_{1-x}$K$_x$Fe$_2$As$_2$, $x=$0.80. To avoid systematic errors, the beam energy was adjusted non-consequently for five values between 1.0 and 2.5 MeV, whence sample resistance was measured in-situ at 22 K. For all energies, the resistivity raises linearly with the irradiation fluence suggesting the creation of uncorrelated dilute point-like disorder (confirmed by simulations). The rate of the resistivity increase peaks at energies below 1.5 MeV. Comparison with calculated partial cross-sections points to the predominant creation of defects in the iron sublattice. Simultaneously, superconducting $T_c$, measured separately between the irradiation runs, is monotonically suppressed as expected since it depends on the total scattering rate, hence total cross-section, which is a monotonically increasing function of energy. Our work confirms experimentally an often-made assumption of the dominant role of the iron sub-lattice in iron-based superconductors.
2305.13217v1
2023-06-05
Multilayer GZ/YSZ Thermal Barrier Coating from Suspension and Solution Precursor Plasma Spray
Gas turbines rely on thermal barrier coating (TBC) to thermally insulate the nickel-based superalloys underneath during operation; however, current TBCs, yttria stabilised zirconia (YSZ), limit the operating temperature and hence efficiency. At an operating temperature above 1200{\deg}C, YSZ is susceptible to failure due to phase instabilities and CMAS (Calcia-Magnesia-Alumina-Silica) attack. Gadolinium zirconates (GZ) could overcome the drawback of YSZ, complementing each other with the multi-layer approach. This study introduces a novel approach utilising axial suspension plasma spray (ASPS) and axial solution precursor plasma spray (ASPPS) to produce a double-layer and a triple-layer TBCs with improved CMAS resistance. The former comprised suspension plasma sprayed GZ and YSZ layers while the latter had an additional dense layer deposited through a solution precursor to minimise the columnar gaps that pre-existed in the SPS GZ layer, thus resisting CMAS infiltration. Both coatings performed similarly in furnace cycling test (FCT) and burner rig testing (BRT). In the CMAS test, triple-layer coating showed better CMAS resistivity, as evidenced by the limited CMAS infiltration observed on the surface.
2306.02720v1
2024-01-31
Effect of severe plastic deformation realized by rotary swaging on the mechanical properties and corrosion resistance of near-a-titanium alloy Ti-2.5Al-2.6Zr
The research aims to analyze the impact that severe plastic deformation arising during Rotary Swaging has on mechanical properties and corrosion resistance of a near-a-titanium alloy Ti-2.5Al-2.6Zr (Russian industrial name PT7M). The nature of corrosion decay in fine-grained alloys caused by hot salt corrosion is known to vary from pit corrosion to intercrystalline corrosion at the onset of recrystallization processes. Resistance to hot salt corrosion in a fine-grained titanium alloy Ti-2.5Al-2.6Zr is shown to depend on the structural-phase state of grain boundaries that varies during their migration as a result of covering corrosive doping elements (aluminum, zirconium) distributed in the crystal lattice of a titanium alloy.
2401.17672v1
2024-03-17
Observation of diamagnetic strange-metal phase in sulfur-copper codoped lead apatite
By codoping sulfur and copper into lead apatite, the crystal grains are directionally stacked and the room-temperature resistivity is reduced from insulating to $2\times10^{-5}~\Omega\cdot$m. The resistance-temperature curve exhibits a nearly linear relationship at low temperature suggesting the presence of strange-metal phase, and a second-order phase transition is then observed at around 230~K during cooling the samples. A possible Meissner effect is present in dc magnetic measurements. Further hydrothermal lead-free synthesis results in smaller resistance and stronger diamagnetism, demonstrating the essential component might be sulfur-substituted copper apatite and the alkalis matter as well. A clear pathway towards superconductivity in this material is subsequently benchmarked.
2403.11126v3
2024-04-09
Transport resistance strikes back: unveiling its impact on fill factor losses in organic solar cells
The fill factor ($FF$) is a critical parameter for solar cell efficiency, yet its analytical description is challenging due to the interplay between recombination and charge extraction processes. An often overlooked yet significant factor contributing to $FF$ losses, beyond recombination, is the influence of charge transport. In most state-of-the-art organic solar cells, the primary limitation of the $FF$ arises not from recombination but rather from low conductivity, highlighting the need for refined models to predict the $FF$ accurately. Here, we extend the analytical model for transport resistance to a more general case. Drawing from a large set of experimental current-voltage and light intensity-dependent open-circuit voltage data, we systematically incorporate crucial details previously omitted in the model. Consequently, we introduce a straightforward set of equations to predict the $FF$ of a solar cell, enabling the differentiation of losses attributed to recombination and transport resistance. Our study provides valuable insights into strategies for mitigating $FF$ losses based on the experimentally validated analytical model, guiding the development of more efficient solar cell designs and optimization strategies.
2404.06190v1
2024-05-09
Negative longitudinal resistance of monolayer graphene in the quantum Hall regime
In the quantum Hall regime the charge current is carried by ideal one-dimensional edge channels where the backscattering is prohibited by topology. This results in the constant potential along the edge of the Hall bar leading to zero 4-terminal longitudinal resistance r_xx. Finite scattering between the counter-propagating edge states, when the topological protection is broken, commonly results in r_xx > 0. However, a local disorder, if allowing intersection of the edge states, can result in a counter-intuitive scenario when r_xx<0. In this work we report the observation and a systematic study of such unconventional negative longitudinal resistance seen in an encapsulated monolayer graphene Hall bar device measured in the quantum Hall regime. We supplement our findings with the numerical calculations which allow us to outline the conditions necessary for the appearance of negative r_xx and to exclude the macroscopic disorder (contamination bubble) as the main origin of it.
2405.05515v2
2012-08-01
Spin-fluctuations in Ti$_{60}$V$_{40}$ alloy and its influence on the superconductivity
We report experimental studies of the temperature and magnetic field dependence of resistivity and dc magnetic susceptibility and the temperature dependence of zero field heat capacity in a Ti$_{0.6}$V$_{0.4}$ alloy. The temperature dependence of the normal state dc magnetic susceptibility in this Ti$_{0.6}$V$_{0.4}$ alloy shows T$^2$lnT behavior. The temperature dependence of resistivity follows a T$^2$ behaviour in the range 20-50 K. On the other hand, a term $T^3$ lnT is needed in the expression containing the electronic and lattice heat capacities to explain the temperature dependence of heat capacity at temperatures where $T^2$ dependence of resistivity is observed. Such temperature dependence of dc magnetic susceptibility, resistivity and heat capacity are indications of the presence of spin-fluctuations in the system. Further experimental evidence for the spin fluctuations is obtained in the form of a negative value of T$^5$ term in the temperature dependence of resistivity. The influence of spin-fluctuations on the superconducting properties of Ti$_{0.6}$V$_{0.4}$ is discussed in detail. We show from our analysis of resistivity and the susceptibility in normal and superconducting states that the spin fluctuations present in Ti$_{0.6}$V$_{0.4}$ alloy are itinerant in nature. There is some evidence of the existence of preformed Cooper-pairs in the temperature range well above the superconducting transition temperature. Our study indicates that the interesting correlations between spin-fluctuations and superconductivity may actually be quite widespread amongst the superconducting materials, and not necessarily be confined only to certain classes of exotic compounds.
1208.0181v3
2016-06-14
On the multiferroic skyrmion-host GaV4S8
The lacunar spinel GaV4S8 exhibits orbital ordering at 44 K and shows a complex magnetic phase diagram below 12.7 K, which includes ferromagnetic and cycloidal spin order. At low but finite external magnetic fields, N\'eel-type skyrmions are formed in this material. Skyrmions are whirl-like spin vortices that have received great theoretical interest because of their non-trivial spin topology and that are also considered as basic entities for new data-storage technologies. Interestingly, we found that the orbitally ordered phase shows sizable ferroelectric polarization and that excess spin-driven polarizations appear in all magnetic phases, including the skyrmion-lattice phase. Hence, GaV4S8 shows simultaneous magnetic and polar order and belongs to the class of multiferroics, materials that attracted enormous attention in recent years. Here, we summarize the existing experimental information on the magnetic, electronic, and dielectric properties of GaV4S8. By performing detailed magnetic susceptibility, resistivity, specific heat, and dielectric experiments, we complement the low-temperature phase diagram. Specifically, we show that the low-temperature and low-field ground state of GaV4S8 seems to have a more complex spin configuration than purely collinear ferromagnetic spin order. In addition, at the structural Jahn-Teller transition the magnetic exchange interaction changes from antiferromagnetic to ferromagnetic. We also provide experimental evidence that the vanadium V4 clusters in GaV4S8 can be regarded as molecular units with spin 1/2. However, at high temperatures deviations in the susceptibility show up, indicating that either the magnetic moments of the vanadium atoms fluctuate independently or excited states of the V4 molecule become relevant.
1606.04511v1
2016-10-24
Self-aligned local electrolyte gating of 2D materials with nanoscale resolution
In the effort to make 2D materials-based devices smaller, faster, and more efficient, it is important to control charge carrier at lengths approaching the nanometer scale. Traditional gating techniques based on capacitive coupling through a gate dielectric cannot generate strong and uniform electric fields at this scale due to divergence of the fields in dielectrics. This field divergence limits the gating strength, boundary sharpness, and pitch size of periodic structures, and restricts possible geometries of local gates (due to wire packaging), precluding certain device concepts, such as plasmonics and transformation optics based on metamaterials. Here we present a new gating concept based on a dielectric-free self-aligned electrolyte technique that allows spatially modulating charges with nanometer resolution. We employ a combination of a solid-polymer electrolyte gate and an ion-impenetrable e-beam-defined resist mask to locally create excess charges on top of the gated surface. Electrostatic simulations indicate high carrier density variations of $\Delta n =10^{14}\text{cm}^{-2}$ across a length of 10 nm at the mask boundaries on the surface of a 2D conductor, resulting in a sharp depletion region and a strong in-plane electric field of $6\times10^8 \text{Vm}^{-1}$ across the so-created junction. We apply this technique to the 2D material graphene to demonstrate the creation of tunable p-n junctions for optoelectronic applications. We also demonstrate the spatial versatility and self-aligned properties of this technique by introducing a novel graphene thermopile photodetector.
1610.07646v2
2020-09-22
Half-Metal Spin-Gapless Semiconductor Junctions as a Route to the Ideal Diode
The ideal diode is a theoretical concept that completely conducts the electric current under forward bias without any loss and that behaves like a perfect insulator under reverse bias. However, real diodes have a junction barrier that electrons have to overcome and thus they have a threshold voltage $V_T$, which must be supplied to the diode to turn it on. This threshold voltage gives rise to power dissipation in the form of heat and hence is an undesirable feature. In this work, based on half-metallic magnets and spin-gapless semiconductors we propose a diode concept that does not have a junction barrier and the operation principle of which relies on the spin-dependent transport properties of the HMM and SGS materials. We show that the HMM and SGS materials form an Ohmic contact under any finite forward bias, while for a reverse bias the current is blocked due to spin-dependent filtering of the electrons. Thus, the HMM-SGS junctions act as a diode with zero threshold voltage $V_T$, and linear $I-V$ characteristics as well as an infinite on:off ratio at zero temperature. However, at finite temperatures, non-spin-flip thermally excited high-energy electrons as well as low-energy spin-flip excitations can give rise to a leakage current and thus reduce the on:off ratio under a reverse bias. Furthermore, a zero threshold voltage allows one to detect extremely weak signals and due to the Ohmic HMM-SGS contact, the proposed diode has a much higher current drive capability and low resistance, which is advantageous compared to conventional semiconductor diodes. We employ the NEGF method combined with DFT to demonstrate the linear $I-V$ characteristics of the proposed diode based on two-dimensional half-metallic Fe/MoS$_2$ and spin-gapless semiconducting VS$_2$ planar heterojunctions.
2009.10463v1
2020-11-22
Quasi-two-dimensional heterostructures (K$M_{1-x}$Te)(LaTe$_{3}$) ($M$ = Mn, Zn) with charge density waves
Layered heterostructure materials with two different functional building blocks can teach us about emergent physical properties and phenomena arising from interactions between the layers. We report the intergrowth compounds KLa$M$$_{1-x}$Te$_{4}$ ($M$ = Mn, Zn; $x\approx$ 0.35) featuring two chemically distinct alternating layers [LaTe$_3$] and [K$M$$_{1-x}$Te]. Their crystal structures are incommensurate, determined by single X-ray diffraction for the Mn compound and transmission electron microscope (TEM) study for the Zn compound. KLaMn$_{1-x}$Te$_{4}$ crystallizes in the orthorhombic superspace group $Pmnm$(01/2${\gamma}$)$s$00 with lattice parameters $a$ = 4.4815(3) {\AA}, $b$ = 21.6649(16) {\AA} and $c$ = 4.5220(3) {\AA}. It exhibits charge density wave (CDW) order at room temperature with a modulation wave vector $\mathbf{q}$ = 1/2$\mathbf{b}$* + 0.3478$\mathbf{c}$* originating from electronic instability of Te-square nets in [LaTe$_{3}$] layers. The Mn analog exhibits a cluster spin glass behavior with spin freezing temperature $T_{\mathrm{f}}$ $\approx$ 5 K attributed to disordered Mn vacancies and competing magnetic interactions in the [Mn$_{1-x}$Te] layers. The Zn analog also has charge density wave order at room temperature with a similar $\mathbf{q}$-vector having the $\mathbf{c}$* component ~ 0.346 confirmed by selected-area electron diffraction (SAED). Electron transfer from [K$M_{1-x}$Te] to [LaTe$_{3}$] layers exists in KLa$M_{1-x}$Te$_{4}$, leading to an enhanced electronic specific heat coefficient. The resistivities of KLa$M_{1-x}$Te$_{4}$ ($M$ = Mn, Zn) exhibit metallic behavior at high temperatures and an upturn at low temperatures, suggesting partial localization of carriers in the [LaTe$_{3}$] layers with some degree of disorder associated with the $M$ atom vacancies in the [$M_{1-x}$Te] layers.
2011.11068v2
2021-06-09
Fracture Mechanics-Based Quantitative Matching of Forensic Evidence Fragments
Fractured metal fragments with rough and irregular surfaces are often found at crime scenes. Current forensic practice visually inspects the complex jagged trajectory of fractured surfaces to recognize a ``match'' using comparative microscopy and physical pattern analysis. We developed a novel computational framework, utilizing the basic concepts of fracture mechanics and statistical analysis to provide quantitative match analysis for match probability and error rates. The framework employs the statistics of fracture surfaces to become non-self-affine with unique roughness characteristics at relevant microscopic length scale, dictated by the intrinsic material resistance to fracture and its microstructure. At such a scale, which was found to be greater than two grain-size or micro-feature-size, we establish that the material intrinsic properties, microstructure, and exposure history to external forces on an evidence fragment have the premise of uniqueness, which quantitatively describes the microscopic features on the fracture surface for forensic comparisons. The methodology utilizes 3D spectral analysis of overlapping topological images of the fracture surface and classifies specimens with very high accuracy using statistical learning. Cross correlations of image-pairs in two frequency ranges are used to develop matrix variate statistical models for the distributions among matching and non-matching pairs of images, and provides a decision rule for identifying matches and determining error rates. A set of thirty eight different fracture surfaces of steel articles were correctly classified. The framework lays the foundations for forensic applications with quantitative statistical comparison across a broad range of fractured materials with diverse textures and mechanical properties.
2106.04809v1
2021-06-16
Role of surface termination in the metal-insulator transition of V$_2$O$_3$(0001) ultrathin films
Surface termination is known to play an important role in determining the physical properties of materials. It is crucial to know how surface termination affects the metal-insulator transition (MIT) of V$_2$O$_3$ films for both fundamental understanding and its applications. By changing growth parameters, we achieved a variety of surface terminations in V$_2$O$_3$ films that are characterized by low energy electron diffraction (LEED) and photoemission spectroscopy techniques. Depending upon the terminations, our results show MIT can be partially or fully suppressed near the surface region due to the different filling of the electrons at the surface and sub-surface layers and change of screening length compared to the bulk. Across MIT, a strong redistribution of spectral weight and its transfer from high-to-low binding energy regime is observed in a wide-energy-scale. Our results show total spectral weight in the low-energy regime is not conserved across MIT, indicating a breakdown of `sum rules of spectral weight', a signature of a strongly correlated system. Such change in spectral weight is possibly linked to the change in hybridization, lattice volume ({\it i.e.,} effective carrier density), and spin degree of freedom in the system that happens across MIT. We find that MIT in this system is strongly correlation-driven where the electron-electron interactions play a pivotal role. Moreover, our results provide a better insight in understanding the electronic structure of strongly correlated systems and highlight the importance of accounting surface effects during interpretation of the physical property data mainly using surface sensitive probes, such as surface resistivity.
2106.08555v1
2022-03-24
Influence of generated defects by Ar-implantation on the thermoelectric properties of ScN
Nowadays, making thermoelectric materials more efficient in energy conversion is still a challenge. In this work, to reduce the thermal conductivity and thus improve the overall thermoelectric performances, point and extended defects were generated in epitaxial 111-ScN thin films by implantation using argon ions. The films were investigated by structural, optical, electrical, and thermoelectric characterization methods. The results demonstrated that argon implantation leads to the formation of stable defects (up to 750 K operating temperature) were identified as interstitial type defect clusters and so-called argon-vacancy complexes. The insertion of those specific defects induces acceptor-type deep levels in the bandgap yielding to a reduce of the free carrier mobility. With a reduce electrical conductivity, the irradiated sample exhibited higher Seebeck coefficient maintaining the power factor of the film. The thermal conductivity is strongly reduced from 12 to 3 W.m-1.K-1 at 300 K, showing the effect of defects in increasing phonon scattering. Subsequent high temperature annealing, at 1573 K, leads to the progressive evolution of defects: the initial clusters of interstitial evolved to the benefit of smaller clusters and the formation of bubble. Thus, the number of free carriers, the resistivity and the Seebeck coefficient are almost restored but the mobility of the carriers remains low and a 30% drop in thermal conductivity is still effective (8.5 W.m-1.K-1). This study shows that the control defect engineering with defects introduced by irradiation using noble gases in a thermoelectric coating can be an attractive method to enhance the figure of merit of thermoelectric materials.
2203.13227v4
2022-03-29
Dose rate effects in radiation-induced changes to phenyl-based polymeric scintillators
Results on the effects of ionizing radiation on the signal produced by plastic scintillating rods manufactured by Eljen Technology company are presented for various matrix materials, dopant concentrations, fluors (EJ-200 and EJ-260), anti-oxidant concentrations, scintillator thickness, doses, and dose rates. The light output before and after irradiation is measured using an alpha source and a photomultiplier tube, and the light transmission by a spectrophotometer. Assuming an exponential decrease in the light output with dose, the change in light output is quantified using the exponential dose constant $D$. The $D$ values are similar for primary and secondary doping concentrations of 1 and 2 times, and for antioxidant concentrations of 0, 1, and 2 times, the default manufacturer's concentration. The $D$ value depends approximately linearly on the logarithm of the dose rate for dose rates between 2.2 Gy/hr and 70 Gy/hr for all materials. For EJ-200 polyvinyltoluene-based (PVT) scintillator, the dose constant is approximately linear in the logarithm of the dose rate up to 3400 Gy/hr, while for polystyrene-based (PS) scintillator or for both materials with EJ-260 fluors, it remains constant or decreases (depending on doping concentration) above about 100 Gy/hr. The results from rods of varying thickness and from the different fluors suggest damage to the initial light output is a larger effect than color center formation for scintillator thickness $\leq1$ cm. For the blue scintillator (EJ-200), the transmission measurements indicate damage to the fluors. We also find that while PVT is more resistant to radiation damage than PS at dose rates higher than about 100 Gy/hr for EJ-200 fluors, they show similar damage at lower dose rates and for EJ-260 fluors.
2203.15923v2
2022-04-11
Thermal insulation and heat guiding using nanopatterned MoS2
In the modern electronics overheating is one of the major reasons for device failure. Overheating causes irreversible damage to circuit components and can also lead to fire, explosions, and injuries. Accordingly, in the advent of 2D material-based electronics, an understanding of their thermal properties in addition to their electric ones is crucial to enable efficient transfer of excess heat away from the electronic components. In this work we propose structures based on free-standing, few-layer, nanopatterned MoS2 that insulate and guide heat in the in-plane direction. We arrive at these designs via a thorough study of the in-plane thermal conductivity as a function of thickness, porosity, and temperature in both pristine and nanopatterned MoS2 membranes. Two-laser Raman thermometry was employed to measure the thermal conductivities of a set of free-standing MoS2 flakes with diameters greater than 20 um and thicknesses from 5 to 40 nm, resulting in values from 30 to 85 W/mK, respectively. After nanopatterning a square lattice of 100-nm diameter holes with a focused ion beam we have obtained a greater than 10-fold reduction of the thermal conductivities for the period of 500 nm and values below 1 W/mK for the period of 300 nm. The results were supported by equilibrium molecular dynamic simulations for both pristine and nanopatterned MoS2. The selective patterning of certain areas results in extremely large difference in thermal conductivities within the same material. Exploitation of this effect enabled for the first time thermal insulation and heat guiding in the few-layer MoS2. The patterned regions act as high thermal resistors: we obtained a thermal resistance of 4x10-6 m2K/W with only four patterned lattice periods of 300 nm, highlighting the significant potential of MoS2 for thermal management applications.
2204.04999v1